SCIENTIFIC ABSTRACT GUBIN, S.P. - GUBIN, V.V.

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SCIENTIFIC ABSTRACT
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25856 3/020/61/139/004/0'06/025 3 103/B206 AUTHORSt Nesmeyanov, A. Ns, Academician. Pp.avaiova, E. G., Gubin, 3, F. , Kikitina, T. V. , Ponomarenko, A A., and Shilovfs~eva, TITLEt Properti~,s of phanyl ferrocene 0 PERIODICAL# Akademiya nauk SSSR. Doklady, v. )39F lo, 4~ 9 al TEXTs The authors investigatedt 1) the amino me-c vion, 2) sulfona- tion, 3) concurrent (with ferrocene) aoetylation, a 4) nitration of phenyl ferrocene. They established that the alky2 up, if linked with the ferrocene ring, facilitates the subsejuent elec pnillii~ substitution. ,:: -, t~~ In this case, the cyclopentadianyl ring to which the i~lkyl group is bonded, is more strongly activated. In relation to the ferrc~enyl group, the phanyl group is an eleotron-acceptor group (A. N, Nesmayanov et al. Ref - 51 DAN, 103, 81 (1955)). These data by the authora were confirmed by 24, Rosenblum (Jo Am. Chem. Soc-o 81,4530 (1959))% The electrophilic aulbsti- tution of the hydrogen atoms in the ferrocene ring is deactivated by the phenyl group. 1) Amino methylation. To a mixture of 70 m! of g2acial Cardl/6 25850 S10?01611139'/004/016/02-5 Properties of phenyl ferrocene B103/B206 acetic acid and 4 9 of H3PO 49 cooled to 10 OC, 2.25 g (0.019 mole) of tetramethyldiaminoethane is gradually added, and then 4 9 (0-015 mole) of phenyl ferrocene. The reaction mass was stirred for I hr at room temperature and for 10 hr at 110 - 115 0C in a nitrogen current and sub- sequently diluted with water to the double amount. The ferrocene (1.5 g)' which had not entered into reaction was extracted with benzene, 4C~ NaOff solution was added to the acidic solution, and the formed (N, N-dimethyl- aminometh,yl)-phenyl ferrocene was extracted with other. After distilling off the other, 2.6 g of the above-mentioned compound was obtained as a viscous, darK, reddish-brown oil. The yield amounted to 54% of the theoretical one (related to phenyl, forrocone) and to 86~ of the phenyl ferrocene reacted. The final product was distilled in 7acuo-Its boiling point 0 20 was 150-160 C/3 mm Hg; n,, 1.6315- In the infrared spectrum of the final product, weak absorption bands existed in the range 1000 and '1100 cm- i. From this, the authors assume the formation of a mixture from the hetero- and homoannular isomers. The latter seems to form in small quant-itis.9, The methiodide of the final produot was produced by addition of CH 31 to Card 2/6 a 020J611139100410161025 Properties of phenyl ferrocene B105/B206 I a solution of 3.2 g in absolute Ch OR (or in benzene) with precipitafion 3 after 15 min by h_areat amount of anhydrous other. An almoot,quantitative (4-3 9) amount O(flmethiodida was produced. It is a yellow, cryatall~ne -substance with the decompo8ltion Point 70 - 750C- Since in the infrared spectrum of the mothiodide which wan produced from the distflled tipal product, absorption at 1000 and 1100 om" I is mioolng, the authors conclude that the substituting groups are in various cyciopentaalanyl rings. Through reduction of the methiodide by sodium amalgam, the,-he'tvroannular. 1 -methyt-phenyi -f 4rrocene was obtained (se~ reaction no. 1 C4Hs ICH.). NCHjNjV1#)j Fe H.Po' CHiN (CH4 CIHS CH.J W CA Noftle \/_ Fe Fe + CH2N (CH4 J a 1, Car.4 316 S102 6111'391004101,61025 Properties of phenyl ferrocene B103YB206 The yield was 1..8 g(71% of the theoretical one). Absorption at 1000 and'. 1100 cm -1 was missing in its.infrared spectrum. A free cyclopentadienyl. ring can only be proved spectroscopically in the substance which was isolated from the.mother liquor. The authors came to the conclusio?) that I the hetepoannular isomer was the.main component of the mixture yroduced bi: amino methylation. Thersfnre,.th~j.reaction mainly occurs In the free. cyclopentadienyl ring. 2) To,..a,,sqlution of 10 g (0 O~8 mols)'~f phenyl ferrooene in 100 ml of dichloroefl%ne., .10 g (0.060 mois of freshly prepared dioxane sulfoVrioxide..wq,%.,added while cooling with ios. Under the conditions of formation of.,feVgooene.monosulfonic acid; 11, 1 pheny.1 ferrocene sulfonic acid was obtaI494,1. 50 -dioxane C6H5C5H4FeC5 H5 3 4 C 6H5C5fl:-,Fqq~H4SO 3H. This acid was Isolated as lead salt, which crystallize&.withj4,,jwater molecules, Absorption'at 1-000 and 1100 cm-I *as here als 'o-m44qAn~; 'the yhonyl,and sulto groups - are therefore in different oyclopenti4ioa)KI, rings. The formation of het*ro. annular sulfonia acid 1e also proof of a lower reactivity of the.ring Card 4A S/020 611139100410161025 Properties of phenyl ferrocene BlOVB206 linked with phenol. 3) The deactivating effect of the phanyl gropp on the ferrocenyl ring is specially marked during the Friedel-Craftt reaction. A solution of 1.4 ml of acetyl chloride and 2.66 g of AIC1 3 in 10 ml of absolute ether vu.!3 added in thd course of 20 min to a solution of ferrocene (3-72 ~) and phenyl ferrocene (5.42 g). in 100 ml of CS 2' All components were ujt2d at a molar retio of-1.1:1:1. The authors obtained acetyl ferrocene only with a yield of 25~ of the theoretical one, and a mixture of acetyl phenyl ferrocenes of Only 5%, 64% of phenyl ferxocene and 30% of ferrocene being recove'red unchanged. From this, the authors conclude that f errocene may be acetylated more easily thanphenyl ferrocene ' 4) Phenyl ferrocene was nitratei by means of ethyl nitrate in CS 2 in the presence of AM Y The authors obtained a 13% yield (of the theoretical one) of p-nitro-Dhqnyl ferrocene (see reaction no. Z). NO C,H,ONOJ\ Fe - Fe Card 5/6 3102 61/'139/004/6116/025 Properties 'of phenyl ferrocene B1 03YB206 The main quantity of this final product is isolated together with part of the nonreacted phenyl ferrocene in nonoxidized state (and not as a cation). The authors presume that nitration does not take place with the phenyl . ferrocene cation but with phenyl ferrocene. The continuance of the ferro- cenyl ring under these conditions is noticeab-le, probably as a consequence of a reduced capability of being oxidized to a cation as compared with ferrocene. Ferrocene itself cannot he nitrated under these conditions. Attempts of the authors to nitrate ferrocene %,vith various other reagents (e. g., nitronium borofluoride) also failed. Only oxidation of ferrocene to the cation which is inert in reactions of the elWtrophilic substitution, was brought about. There are 9 references: 7 Soviet-bloc and 3 non- ` Soviet-bloc. One refereace to English-language publications is given in.the body of the abstract, the anothL~r one reads: Lt. Rosenblum, R. B. ffoodward, J. Am. Chem. Soc., 80, 5443 (1958)). ASSOCIATION: J,1o_z.kovskiy gosudarstvannyy universitet,im. M. V. Lomonosova (bloscow State University imeni 14. 7. -Lomonosov) SUBMITTED- April 19, 19061 Card 6/1 S/020/62/143/006/016/024 B106/B138 AUTHORS. Gubin, S. P., and Perevalova, E. G. TITLE: Formal redox potentials of monosubstituted ferrocenes PERIODICAL: Akademiya nauk SSSR- Doklady, v. 10, no. 6, 1962, 1551-1554 TEXT: The formal redox potentials of 30 monosubstituted ferrocenes were determined by potentiometric titration with potassium bichromate in a mixture of acetic acid and aqueous perchloric acid. Relative quantitative data were thus obtained on the effect of substituents on the oxidation of the ferrocene nucleus to the ferricinium cation. The determinations were conducted by the method of J. G. Mason and M. Rosenblum (flef.2s J..Am.Chew.. Soc., 62, 42o6 (196o)) at 25 t 0-10C in nitrogeii atmosphere. Table 1 shows the results. The differences of the logarithms of the equilibrium constants for the reactions of substituted and unsubstituted ferrocene were calculated from the corresponding potentials (Column 4, Table 1) and compared with the constants 6* and 00 according to Taft (Ref. 10; M. S. Nlyumen, Prostranstvennyye effekty v organicheskoy khimii (M. S. Newman, Steric effects in organic chemistry), IL, 1960) 591), and a[a and Card 1A S/02 62/143/006/016/024 Formal redox potentials of... Blo6%13a 6n according to Hammett (Ref. 11s D. R. McDaniel, H. C. Brown, J. Org. Chem., 23, 420 (1958)). No relations have been found to the constants 6 a0, and am, while there is a (not very good) relation to the constants d n In a diagram (log K/K 01 an), the ferrocenes with the substituents -OCH 31 V -OCOCH 31 -CH 3, -C2H 50 iso-C3H7lie on a straight line with Q - -4.23, on which the ferrocene itself also lies (correlation coefficient 0.985), whereas the ferrocenes with the substituents -C 6 H51 -C 6H4NO 2-PI -COOH, -COOCH3, -I, -Cl, -Br lie on a straight line with q - -7.94 (correlation coefficient 0.982). In the case of the ferrocenes which lie on the former straight line, the substituents interact with the iron atom by mechanisms of inductive, conjugation and, possibly, field effects, the latter only as far as thia effect is reflected by the value of a n. In the case of the ferrocenes which lie on the straight line with Q - -7-94, the substituents interact with the iron atom by the field effect mechanism much more intensely than is reflected by the a n values. This agrees with a Card 2/ 5 S/020/62/143/006/016/024 Formal redox potentials of... B1061B138 published statement that hydrogen and alkyl substituents cannot interact with the reaction center by the field effect mechanism (Ref. 9: V. A. Pallm, Usp. khim., 3o, 1o6q (1961)). The interaction by the field effect mechanism occurs over a shorter distance, which leads to an in- crease in the absolute value of Q. Academician A. 11. Nesmeyanov is thanked for cooperation and advice. There are 1 figure and 1 table. The most important English-language references read an followai T. Kuwana, D. B. Bublitz, G. Hoh, J. Am. Chem. Soc., 82, 5811 (1960); H. H. Jaffe, Chem. Rev., 53, 191 (1953); D. S. Trifan, R. Baskai, Tetrahedron Letters, 1960, no. 13, 1; J. D. Roberts, R. A. Carboni, J. Am. Chem. Soc-9 77P 5554 (1955). ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. lit. V. Lomonosova (Moscow State University imeni M. V. Lomonosov) PRESENTEDs December 12, 1961, by A. N. Nesmeyanov, Academician SUBMITTEDs November 9, 19061 Card 3/5 S/020/62/143/006/016/024 Formal redox potentials of... B106/B138 Table 1. Formal redox potentials of monosubstituted ferrocenes C 5H 5FeC5 H4X (formulas do not take account of changes in the reaction medium). Logendt (I) E f , v (according to a standard calomel olectrode); W) W., 0C; (III) b OC; (IV) under decomposition; 2 calculated from the t Hg X - H 3 formula (E0 EOWO-0591 - log K/K o; only the primary 6 n values obtained from the dissociation constants of the corresponding p-substituted benzoic acids have been used; 4 the potentials of these compounds differ slightly from published data; the potential differences between forrocene and phenyl ferrocene, and between ferrocene and p-nitrophenyl*ferrocene, are constant within the error limits of the experiment; 5 from published data; 6 the value for the -COOC H$ group from published data has been used. In oolumn 2t V-SO - i80; p., M; A - P. Card 4/5 s/o2o/62/147/002/015/021 B1o6/B101 AUTHORS: Perevalova, E. G., Gubin, S. P., Smirnova, S. &.1 Nesmeyanov, A. N.; Ac1t#-mrc-1ai--' TITLE: Redox properties of compounds containing tuo ferrocenyl groups PERIODICAL: Akademiya nauk SSSR. -Doklady, v. 147, no. 2, 1962,- 384-387 TEXT: The authors studied the effect produced by one ferrocene ring on the redox properties of a second ferrocene ring bound to the first either directly (diferrocenyl) or by groups Y of different conductivity (-Hg-, -CH 2-# -CH 2-CH 2-9 -CH 2- O-CH 2-' -CH2-N+(CH 3)2-C-H2-) . They measured the and J;11 *(Table 1). The significance first and second redox potentials Ei. f0 11 of Eio and E f0 is evident from the following scheme: Card 1/4 Redox properties of compounds ... Y_, 7- .e Fe Fe+ Fe + Ef'o S/020/62/147/002/015/021 B106/B101 1e Fe Fe t--=:z Ell \Y fo _Y_ V Fe+ Fe+ +Ie- "j, Under the chosen conditions diferrocenyl was oxidized at one Fe atom only. When two ferrocene rings interact, the electron density increases at the ring oxidized. The redox potentials indicate that the methylene group transfers to the other nucleus; hardly any of the electron-donor effect of the ferrocenyl group, whereas the effect of the positively charged ferricinium ion is transferred even across bridges of 3 atoms. The investigations covered also how some substituents in the methyl group of methyl ferrocene affect the redox potentials (Table 2): in this case, too, the effect of electron-acceptor substituents was transferred via the methylene group to a notably greater extent than that of electron-donor substituents. There are 4 figures and 2 tables. The most important English-language references are: R., W. Taft Jr., J. Am. Chem. Soc-t 759 Card 2/4 S/020/62/147/002/015/621 Redox properties of compounds B106/B101 4231 (1953); 9- H. Jaffe, Chem. Rev., 53- 191, (1953).- ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosava (moscow State University imeni M4 V. Lomonosov) SUBIMITTED: July 18, 1962 Table 1. Redox potentials of compounds with two ferrocenyl groups C5H5FeC5H4- Y-C5H4FeC5H5(in v, related to the standard calomel electrode). Legend: (1) melting point, 0C; (2) diferrocenyl; obtained by reduction of diferrocenyl ketone; (3) with de.composition. Table 2. Redox potentials of some monosubstituted ferrocenes C5H5FeC5H4CH2X. Legend; (1) v, related to the standard calomel electrode; ,K mean deviation from the Ef values indicated t0.003 Y Card 3/4 NESWYANOV, A.N.; KOZLOVSKIY, A.G.; GUBIN, S.P.; PM,VALOVA, E.G. Protolysis of meroury derivatives of ferrocene. Izv. AN SSSR. Ser. khim. no.3s580 165. (MIRA 18:5) 1. Moskovskiy gosudarstveftnyy universitet im. M.V.Lomonosova i Institut elementoorganichaskikh soyedineniy AN SSSR. -- -. .-M- --- - " I I . j ~.- -q, r. 1", ~,~ T ' i I ~ 14' --,1 F~. nt -I -I - I 1 7 i I - ; I *;' 1 % I I I : I ~ A. , : I ; I . r~.. . F . J7 . I ; I z ri L 46186.~ ACCESSIOWUR. APS007562 H4 h -It was found.that the chemical shifts of protoinis. of' the uh4,ilbsti uted rin g 4re cbiefl_* dete ined b~:the induction diffect:of th sub titutkots. 1he: Obser4ed r= s, of .the shifts 6 an d 6 indl6at6-a co6si4iiabU'~ eifk~ldt. bfEt~e~~60ii 94': YK value b c id: of the: ipo6ti~ the substituent on the chemlc&l shifts. of proton pinji. ~j ~iCor-.." relatil6ns-are~presented between the values ok..:S 6 and! conjugation c6t~stahts j -C ~!~'ang the io"A%ictW~~ cbnstaks:'of ifthe' of the substituents, between the 66mica1:shifts. cal I jroionb~ d ihejubsiit~t4~~ih~ substituents j, and: between the chemi ~h fts:.Of and:the Hammett constants. 0-..0f the-substftuenfs,~~-. The retl~its of thds d r Aiakd It possible~to'diliaw_ a close Alogy betweisu'l~heioi*,Li~*d-"i,~a,n,dl,l,~e,h~kr,;,L6tar of, fltiencw of the slubstituents ci this W a 'a t-n6ft,104-iltid Ip M:: ~cenyl: nueleus .band corresponcunkly, Op.,:th!s t*. a 0-, aral .1V Its: ~~A h Ori lbus. g. ind th.e-.'p,,.efiy1 nuc, .2 ',~tib A i L - Tt, fl i 4iff" L 46186-65 ACCESSION NR*.. :AP5007562- M141 -P SSSR It ASSOCIATION, ~-:Instittit khi~il rir6dnykh,~6c7e& 6fily. A4446t! ai4 Chemistry of Nat~i4l de i.A ca devy- of~ sbbincdd~ S1699P InOtittit elimnto- i, o f Compoun" Apyedninan~yFMSRI-.nauk a !,Org -organicheskikh .*f iSci nciab SSSR) -i~ po4nds Acade MY 6 P. S( CM W J- Nr -PUT", 0 .zt .4 j ~j :1:22 1z 1; MR~ R vk~ Mr. -:1A T U- ZYa- rd 3 7 1. II)STA"O. mit, -I Matr -W, - e . I I . 3136A-66 Ee-P(J)/EWT(m) IjP(c) RM ACC NRs AP6021104 SOURCE CODE: AUTHOR: Gubin, S. P.j Shepilov, 1. P.; Neemeyanov, A. N 6-1 11-- .15 ORG: Institute of Organoelemental CqUounds, AN SS5R (Institut elementoorganicheskil soyedineniy) TITLE: Acetylation of ferrocenelby the complex 2CH sub 3 COM.BF sub 3 SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 2, 1966, 384 TOPIC TAGS; ferrocene, acetylene compound, reaction rate, activation energy, spectrophotometric analysis, catalysis, chemical reaction kinetics ABSTRACT: T~e authors determined rates of acetylation of ferrocene by the complex 2CEL3-COOH-B in glacial acetic acid under paeudo-first order conditions. The reaction wa- arrested by pouring the sample (1 ml) into 20 ml of absolute ethanol. The ferrocene and acety1ferrocene concentrations in the solution were determined spectrophotometrically at 337 millimicrons on the SF-4A unit. The apparent energy of activation is 22-4 kcal/mole. When the catalyst concentration is increased, the reaction rate rises. The data obtained shows that ferrocene is 200-300 times more active than anisole in the acetylation reaction. (JPRS1 SUB CODE: .07 / SUBK DATE*. l7Kov65 / OTH ]REF-. 001 1/1 A,A- UM 542--957 + 546-72 + 66-095-11 ACC NR. AP6017876 SOURCE CODE: UR/0062/66/000/005/0832/0839 AUTHOR: Porev lova, E. G.; Grandbgrgg K. I.; meyanov, A. N ORG: Mospow State University im, M, V, Lomonos (Moskovskiy gosudarstvennyy univor-1 sitet); Institute of Organometallic Cormounds,, Academy of Sciences., SSSR (In- stitut elementoorganicheakikh soyedinenly Akademit TITLE: Electronic influence of ferrocenyl as a substituent SOURCES AN SSSR. Izvestiya, Seriya khimichoskayap no. 5p 1966, 832-839 TOPIC TAGS: ferrocene, dissociation constant, aniline, benzoic acid, phenols substi-11 tuent, amine ABSTRACTS By determining values of Hammett's C( p the authors studied certain elec- tronic effects of forrocanyl as a substituent. Using acid-bass potentiometric titra- tionp they determined the dissociation constants of p-, m-p and o-ferroconylbonzoic acids* a series of substituted benzoic acids and ferrocenecarboxylic acid In 70% di- axane, and the dissociation constants of p-ferrocenylphenol and a series of p-substi- tuted phenols in 50% ethanol. The basicity constants of p-,, m-, and o-ferrocenylani- linesp a series of p-substituted anillnes, and ferrocerqlamine in 80% ethanol were also determined. The data obtained were treated by the least-squares methodp f val- U*s were calculated for the reaction series studied, 6 values were found for ferro- UDC1 541 + 541-49 + 547.1*3s541-132 ACC NR: Ap6017876 canyl as a substituent in various positions of the phenyl ring, and the induction co stant Or was determined. The data showed that in the series of ferrocenylbenzoic acidst tL strongest is o-ferrocenylbenzoic acid; p- and m-forrocenylbenzoic acids are comparable in strength and are respectively 1.5 and 1.6 times stronger than ferro- canecarboxylic acidq which therefore is the weakest acid. p-Ferrocenylphenol is a weaker acid than phenol (by a factor of 1-3), The opposite relationship is observed in ferrocenyl derivatives of anilinet o-forrocenylaniline is the weakest base, 300 times weaker than ferrocenylamine. 7he strongest base, ferrocenylamine, is 42 times stronger than aniline and almost 28 times stronger than p-forroconylaniline. It is concluded that ferrocenyl has a strong positive inductive effect and a weak positive conjugation of ot. Orig. art. bast 7 tables and 2 formulas. r SUB CODES 0711SUBM DAM 27Doo63/ ORIG REFS 009/ OTH REFS 014 211 :'CC NR; AF7012420 SOURCE CODE: UR/0062*66,'000*011 1938,'1943 AUTHOR: Nesmeyanov, A. N.; Perevalova, E. G. 7yurin, V. D.; Gubin, S. P. ORG: Moscow State University Im. M. V. lamnosov (Hosimyskiy gosudarstvennyy universitet) TITLE: Hetallation of alkylferrocenes SOURCE: AN SSSR. Izvestlya. Serlyn khlmlcheskay;a, no. 11, 1966, 1938-1943 70PIC TAGS: ferrocene, lithium compound, ferrocenyllithium SUB CODE: 07 ABSTRACT: The rBtallation of methyl-, ethyr-, and n-propy1ferrocene with -excess n-butyllithium at room temperature vas studied. Mixtures of mono- and The monometallated alkylferrocenes dimetallated alkylferrocenes were obtained. were found to possess a heteroannular structure- The mixture of mono- and dimet-, allated alkylferrocenes.. after carboxylation, were converted to a mixture of ;mono- and dicarboxylic aci'ds. Metallation of alkylferrocenes proceeded with -greater difficulty than that.of ferrocene itself. Approximately 2-2-5 times as much of.the Monometallated alky1ferrocene was formed as of the dimetallated derivative- d alkylferracenes were also usecl for the synthesis The metalUze of heteroannular njtroaUWjferrocene6 by the reaction trith propyl nitrate* hyl-, nitroethyl-, apd, pitr_opropylferrocenes were obtained in low Card 542o91 + 547.113 + 546.72 0932 05 I ~6 11 1 t.. ACC NR; AP7013134 SOURC_~- CON: UR/0062J'66 000 009 155lil558 AUTHOR: Gubin, S. P. ORG: Instituto of Heteroorganic Compounds, AN SSSR (Institut elementoorganicheskikh soyedineniy j%N_SSSR) TITLE: Electronic effects of substituents In ferrocene and Its derivatives SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 9, 1966, 1551-1558 TOPIC TAGS: feriocene, chemical substituent SUR CODE: 07 ABSTRACT: In.a re rt presented at the General Meeting of the.Departnient of d_en_e,r_al__,_and_,*Technical Chemistry, Academy of Sciences USSR, on f6 December 1965, the author describes a detailed study of the nature of the interring electron effects in the ferrocene molecule. Classical methods, such as measurement of -the dissociation constants of the acids and study of the absorption spectra in the ultraviolet and visible region, andcomparatively nev methods, such as study of the proton magnetic resonance and nuclear gamma resonance spectra were -used to study the transmission of electronic effects in the ferrocene r.Dlecule, and a reaction specific for ferrocene derivatives was also investigated: rever..: sible oxidation at the iron atom. *The numerical data obtained were treated by methods of correlatiopal analysis. The transmission-of. the. i.nflgence of sub- -Card'. 1/2 UL)C: 541+542.957+546.~72 ACC NR. AP7013134 stituents along tho ring-metal bond was found to be predominantly Inductive In character; Orig. art. has: 9 figures. LJ'1-RS: 40,422 GUBIN, S.S. Ifew developments in the financing of inCormaticn organn. NTI no.9:5-6 165. (MIRA 1911) KAYZERKAN, M.M., mayor meditainskoy-sluzhby; ZAVRAZHINj, M.K., podpol- kovnik meditoinakoy aluzhb7; KNYAZEV, S.V., podp6lkoynik medi- toinskoy sluzhbyl KOBUKOV,, N.Isp podpolkovtik meditsitskey sluzhby; DOUCHAM, G.M., pod~olkovnlk m9cUtxJmskoyl-#luzhby; PIETNEVI NN,, polkoynik meditsinskay sl~zhiby;' KHCHOSHCHEVO V.D.t podpolkoTnik meditsinskay sluzhby; GORBACHIK,Ye,.D., podpolkoyna msdiUinskoy sluzhby; DRUKERp Yu.S.; NAZAROV, X.M.; K(HOGOROV, P.R., polkovnik meditsirmkoy sluzhby; KLIMENK01, A.V.,, podpolkovnik meditainskoy sluzhby; RTAKHOVSKIYp I.Ye.'p podpolkovrAk meditsinskoy sluzhby; IVANIKOVICH F.Aj; GUBIN _�_tV,; kEtpitan meditsinskoy sluzhby; ZOPTOV, I.G.: kap ta~nl ~me lisl~;koy sluzhby; LEONOVA, Ye.I.; BUNTOVSKIY,, P.A., mayor meditainskoy oluzhby; GERAS13407, A.N., podpolkovnik meditainskoy sluzhby; GUR17EV, I.A., kapitan medi- tsinskoy sluzhby; KOIJ)OBSKIY, S.Z., mayor meditsinskoy sluzhby Abetracts, Voen. med. zhur. no.10:74-79 0 165. (MIRA 18:12) GUBIN, V.,sudlya respublikanekoy kategorii Competing for seconds. Voen.znan. 36 no.11:30-31 U160. (MIRA 13:11) (Aquatic syortm) V. -? ti 14n the design b~,Arenuo. Tp-k'h.ent. no.502 1tv 165. (KIRA 1846) 9(6) S/146/59/002/06/004/016 D002/DOO6 AUTHORS-. Sitnikov, O.P., Perminov, Yu.A. 1atrbtV___r_ TITLE: A Device for Measuring the Errors of A Control �y hems . PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Priborostroy- eniye, 1959, Nr 6, pp 23-28 (USSR) ABSTRACT: Detailed information is given on a device (Figure I an12) for measuring the errors of automatic control systems. It is a decoupling lowfrequency amplifier with a relatively wide dynamic range and has a double triode whose grid receives the voltage from the integration chains serving as the error signal input. The signal causes a disbalance of the triode currents, which is recorded by an indicating instru- ment. The device measuring the mean square error value consits of a preamplifier, a detector, a squaring de- Card 112 9(6) S/146/59/002/ 06/004/016 D002/DO06 A Device for Measuring the Errors of Automatic Control Systems vice, an operation amplifier, and an integrating am- plifier. Good results can be obtained with stabilized feed sources of +300 volts, - 300 volts, - 190 volts, and +80 volts. V.S. Pugachev's random functions the- ory fRef. 1-7 was used in selecting the optimal aver- agi-g interval. The article was recommended by the Kafedra apparatury avtomaticheskogo upravelniya (Chair of Automatic-Control Devices). There are 2 diagrams, 2 graphs, and I Soviet reference. ASSOCIATION: Urallskiy politekhnicheskiy institut imeni S. M. Kirova (Ural Polytechnic Institute imeni S.M. Kirov). SUBMITTED: December 29, 1958 Card 2/2 LAPTEVA-POPOVA, M.S.; GUBIR, V.A. - -.1.1 111-,,~~'. Changes in the formmtion of blood caused by Itogi nauki.Biol. nauki no.1:214-261 '57. (RADIATION-PHYSIODDGICAL EMGT) ionizing rAdintlons. (MIRA 11:3) (BLOOD) GUBIN, V.A. Nomogram for the color Index Rnd absolute number of thrombocytes, noutrophile and lymphocytes. Problogemnt. I parel.krovi I no.3:6i-62 Mr-je 158 (MDU 11:6) (13WOD GHLIS, nomogram for color Indox & aboolute number of blood plateleta, neutrophils & lymphocytei3 (Rua)) CMD1, T*A* Certain histochemical studies of blood cells In acute radiation sick- ness. Med.rad. 4 no.10:3--9 0 159. (KnU 13:2) (RADUTION INJURY exper.) (BWOD 03LLS radiation eff.) 1;- -1 ~ i-I - I. I ,~_ GUBIN, V.A. (Moskva) Studying leucocytes of the peripheral blood in rabbits by supravital staining in acute radiation injuries. Probl. gemat. i Pere'. krovi 4 no, 10:19-22 0 159. (MIRA 13:8) (x RLYS-PHYSIOLOGICAL EFI,'ECT) (LEUKOCYTES) GUBIN, V.A. (Moskva, D-182, Mal.Shchukinskaya u1., 15, kv-32) In vitro cultivation of bone marrow and spleen of rabbits irradiated with roentgen rays. Arkh.anat.gist.i embr. 39 no.11:3-10 N 160. (MIRA 14:5) 1. Ministerstvo zdravookhraneniya SSSR (nauchnyy rukavoUte'll - deystvitelinyy chlen AM WSR of, N.A.Krayevskiy) . (14ARROW) (SPN;NF (RADIATION--PHM31OLOGICAL MECT) L 03781-67 EWT(m) (Z C C - - N R_ i -A- T -6-0-2 - 9__ 6__ 1 -9 SOURCE COD%s UR/0000/66/000/0 AF001-5010-1-5-7- AUTHORs Volokbovaq N. A.; Gubib V, A, Dareasks as No G,; Kozoovs, L. B.1 raof-choultia. V. 1.1 Nevskara-.-G-6 F.1 Sedow, V,-V, ORGI none TITLZI Peculiarities of clinical manifestations of radlatlo~901ckuees in theses monkeys during asma&-ray Irrad lation.L SOURCII Voprosy obahchey radisbielogiL (Problems of SoAarat radio- biology). Moscow, Atomisdat, 1966, 150-157 TOPIC TAGSt -radiat;oq biologic effect, nonk&T, dog,,Lrdialatioa ABSTRACTs A comprehensive clinical examination of ganna-irradiated ,:onkays was conducted, and the data were compared with results of sizilor-, xaminations of dogs. Seventeen sonkoys (Hacaca rheaus) of both 9 zes#~' weighing 2.0 to 4.0 kg, were subjected to game Irradiation from a: EGO-2 apparatus with a dose rate of 357-313 r/sis, Prior to Irradia tion, all monkey@ had been under clinical observation for 2-3 weeksol Eleven of the 14 monkey* irradiated with 300 r died (average duration of life 16.5 days), while two of the 3 monkey@ irradiated with 350 r died (29Le5 and 36.2 days after Irrediation)e Both groups of gauna-. cmd I/1. ; ~ 4- NZ I L L 0,3781-67-- ACC NRi AT6029629 irradiated monkeys were considered together, since the clinical mani- festatLona of radiation sickness were similar in both groups. Experi- mental data were compared with data from analogous dog experiments, using a 300-r dose of gamma rays, and no essential differences in the radiation affect were noted between the two species. However, the spread of life duration& in monkeys (6.5-36.2 days) was wider than fo dogs (11.5-18.5 days), The primary reaction to radiation was more pronounced and developed more rapidly In monkeys than In doRse The primary radiation reaction was absent In 2 out of 17 monkeys, as com- pared with 18 out of 28 dogs. Furthermoreo seven monkeys experienced severe primary radiation reactions, while none of the dogs did. In the first 10-11 days after irradiation, no essential differences were noted between the temperature reactions of monkeys and dogs. However, by the time of death dogs had elevated body temperatures (average 1.5C above normal), whereas monkeys' temperatures had fallen considerably below normal. Symptoms of radiation sickness appeared later (15-18 days after Irradiation) and developed more gradually in monkeys than in dogs (7-12 days). Autonomic dysfunction to considered responsible for the lability of symptoms In monkeys in the early postradiation period. This hypothesis is substantiated* by the considerable varls- tLons in blood pressure, the unstable heart rhythm. etc. HematopoletLe changes in monkeys in response to radiation had a phase character, demonstrating the different course of the radiation reaction In diffem 2/3 L 03781-67 AT6029629 types of calls. Since blood regeneration occurred even in monkeys dying after 30-36 days, it was concluded that blood changes were-not the primary factor in animal deaths. The lower lethal dose values encountered in these experiments are partially explained by differing experimental conditions, but require further study, Orig. art# hast 2 figures and 1--table. [is) SUB CODII 061. SUBM DATEs 23Apr66/ ORIG REY: 0081 OTH RIFt 006 ATD PREM uvcf~ Card 3 / 3 RCONSUKOV. Mikhail Gavrilovich; GUBIN, V.A., inzh.. rotsenzent; BUDAFOSEVI, S.S., inzh., retsenzent; OSIPOV, V.D., red.; GORYUNOVA, L,K., red.izd-va; IKOFSMSHM, A.S., takhn.red. [Mechanizing the felling and the division of timber] Makhani- zataiia valki i razvedki lose. Moskva, Goolesbum12dat. 1960. 138 P. (MIRA 13:7) (&iumboring) I , I . : 1,-! 1 , ; - - "rr"p: z,! tim !:,f t, I I-,,: - T . . . ! -, I I' I I - I ~ , - , , , , , - - - -- , - , .., MBIN, V. A. 25881 Vliyanto vremennago otsuistviya matki na medosbor (C. primech. red) Pchelovodetvo,, 1949, No. 8, a. 13-17. SO: Letoptal No. 34 - I . I - I~~ I IAl ` t. ~ i z . . I ~ ! 1. . 10 - . I - I ;j 1 :1 ;T ; . ~ ti " ~ I - - - - - 1 1 1 j ~ : : , 1. V. A. GUBIN 2. USSit (600) 4. Bee Culture 7. Can the departure of natural swarm be hastenedi Pctieiovodstvo 29 no. 12. 1952. 9. Monthl List of Russian Accessions, Library of Congress, April 1953, Uncl. MITHIN, V. A. ,Microscope and ',microscopy Box for measuring the proboscis and other parts of bees' bodies. Pchelovodstvo 30, No. 2, 1953. Monthly List of Russian Accessions, Library of Congress, J= 1953. Unclassified. OSR/Fam., i'mii-mls - Honey Boo Q- 7 Abs Jour Rof Zhur - Biol., No 6,1958, No 26255 Author Inst Not Given Title z On the Shnrpnoss of the Sense of Smoll in YLallifcrous Boon (0 tonlcosti obonynniye u r-edonospykh pchol) Orig Pub : Pcl-clovodstvol 1957, No 7, 17-19 Abstract : It was established oxperivontrlly that boos acqunintod with -.-dxod snoll are erpeble of dictinguishing molls of the ooparato components of the r2.ixturo. Cnrd 1 1/1 '5-y KHA IFKAN, I.; GUBIN, V..A. Aleksandr Fedorovich Chbin. Moskva, 1958. 37 P. (MIRA 13:8) Oubin. Aleksandr Fedorovich) GUBB, Vadim Aleksandrovich; ZUBKOVp M.A., otv. red.; SHEXCHENKO, G.N.p ~ ~ - I- -tekbh* red*- - ' - - [School apiary] ShkolInaia. paseka. Moskva, Gos. iad-vo detskoi lit- ry M-va proov. RSFSR, 1960. 109 p. WU 3-4:7) (Bee culture-Study and teaching) GUHN, V.I., vaterinarnyy vrach. O"HWOWUMORMi Therapeutic utilization of the milkin machine. Voterinariia )0 no.9:51 s '53. (KLHA 6:8) 1. Mksperimentalluaya baza ordena Lenin& sellskokhozyaystyannoy skademii imeni X.A. Timiryazeya. V.I., otv. red.; KO;',Alj', M., red. [Numerical methods of synoptic meteorology] voprosy sinopticheskoi "Nauka" UzSSR, 1964. weather forecasting and problems of Chislennye me tody prognoza pogody i meteorologii. Tashkent, Izd-vo 100 (MitA 18:1) 1. Akadeniya nauk Uzbekskoy SSR, Tashkent. Institut mate- matiki. 2. Chlon-korrespondent AN Uzbekskoy SSR (for Gubin). GUBIN,V.I., kandidat tekhnicheskikh nauk Now woolen fabrics. Tekst.prom.15 no.8:12-17 Ag'55- (NW 8:11) 1. Direktor TSentrallnogo Nauchno-ineledovatellskogo institute, shersti (Voolen and worsted mmufacture) GUBIN, V.I., kandidat tekhnicheakikh nauk; GUSEV, V.Ye., kandidat tekhiche- nauk. Reorganization of spinning In the cloth industry. Tekst.prom. 16 no.1:34-37 Ja 156. (MIRA 9:4) l.Direktor TSentrallnego nauchn*-imaledevatel'skege instituta shersti (for Gubin)o (Woolen and worsted spinning) HLRGULIS, Te.M., insh.; GUBIN, V.L. inih.; Y=NGUW7. T.To. Achievements of mine builders In shaft sinidag in Dshezkazgan. Shakht.etrol. 4 no.9:18-20 S 160. OUAL 13: 8) 1. Dshesimsganskoys shafttoppokhodcheekoys upravlonlys tresta, Stalinshakhtoprokbodia (for Nargulls). 2. Institut gornogo del& Aiademli nauk lasSSIL (for Oubin. Tesengulov). (fthaskazSm-Shaft sinkIM) BAKAYEV, M.T.; GUBIN, V.I. Evaluation-of methods of mining ore In the Dzhezkaagan Nine. Trudy Inst. gor. dela kN Kazakh. =R 10&67-74 163. (KMA 160) (Dzhezkazgan District-Mining engineering) UBE;, V. 1. Gubin, V. I. and 'Nosenko, B. M. "On the thtory of the Ha-,I)el effect," Trudy Flz,-teklin. in-ta (Akad. nauk Uz'~)ak SSR), Vol. II, Issue 2, 19119, P. 45-49 SO: U-5241, 17 Deceriber 1953, (LaLonis t1iurnal livkh Ao. 2~.),11;61 .)) ~ :I ; f : r ~! - 'I . I -,!I t f ; , - I j- 11 1 : ! I i GTJBIN, V. I. One method of precalculation of advective changes of temperature and pressure. Trudy Inst.mat. I makh. AN Us.SSR no.12:91-96 153. (Weather forecasting) (KLPA 8:1) SOV '/124 - 57--8--q 147 Translation from: Referativnyy zhurnal, Mekhanika, 1957, Nr 8, p 82 (USSR) AUTHOR: Gubin, V.I. TITLE- On the Vertical Wind Shear (0 sdvige vetra s vvsotoy) PERIODICAL- V kn, : Meteorol. i gidrol. .- (Jzbek-!stane, Tdshkert,, AN UzSSR, 1955, pp 111-120 ABSTRACT: The author examines the system cf different'.al equations c.-A, a frictionless atmosphere du dv -a a P a W, T 9 d t 8X dt K T C Here u, v, and w are the components of the wind-,.elcc:1Ly vector alcng the x, y, and z axes, respectively-, pis the pressure and a the spec-i- fic volume of the atmospheric air; g is the acceleration due to the force of gravity; f :=I .9 =2 w sin (~ , L , cos tD , where rD 'Is the geographic latitude of a point; and w is the angular velocity of the rotation of the Earth. Upon transsforrnat;nn and e--.-aluatlon of the orders of magnitude of the terms system (1) reduces to the iollew,".nig Card 1/?. form: On the Vertical Wind Shear d au r) v (CL , P) TF -5-z -5-z xz where (a , P) aa aa ap 'j:.~ aa 71-.x xz SOV/124 571 8 -4147 d av+ u = (CL , p) -d-t -5-z -5-z YZ a a P 22 and (a , p)L 2(L YZ ov i)z az ~) Y (2) System (2) affords an approximate determination of the verticai wind shear-, wherein in a first approximation the problem is considered to be stationar .1-, Some qualitative deductions are made. The p.,per contains lypegraph1cal errors. Sh.. A.. Musave: y,Iv Card 212 S 0 V1 124-57-7-8036 Translation from: Referativnyy zhurnal. Mekhanika, 1957, Nr 7, p 85 (USSR) AUTHOR: Gubin, V. 1. TITLE: Frontogenesis and Pressure Changes (Frontogenez i izmeneniye davleniya) PERIODICAL: Dokl. AN UzSSR, 1955, Nr 12, pp 3-6 ABSTRACT: The author examines the relationship between frontogenetic condi- tions and the variation with time in the elevation of a constant.- pressure surf-ace. The vorticity equation, written in tern-is of a system of inde-- pendent variables x , y , 1) and t (p being the. pressure) is eni- ployed in the form: d (Q - VT) (K2 - V )dT =0 -Ut dt wherein 0 is the vorticity vector, T the temperature,. and t the time. The vorticity components along the axes x and y and with re- spect to the pressure p are assumed, respectively, to have the forms Card 1/2 0 A(b 1. 1Q = R 0 T Q ~. R JT x TP 7, y 'P ~y Frontogenesis and Pressure Changes SO V / i2z.-57- 7-8036 wherein (D is the geopotential, I the Coriolis parameter, and R the gas constant. Whence the author arrives at the followina equ2tion: RT RT V . V A(D- - (F' 4- 2F") + T + I-T (3) t pT p p2T p Here T=dp/dt and -y= dl /dt, and the expressions F1 = I V T -V dT and F" -L V T - V v V T (4) TV I I Ct TV I I (wherein TV = I VIT I and VIis the horizontal Hamilton operator) characterize an individual frontogcnesis defined as the degree of variation with time in the modulus of the horizontal temperature gradient. By using equation (3) the author is able to elucidate qualitatively the relationship between the conditions that lead to a variation in the elevation of a constant- pressure surface and the conditions of frontogenesis. V. V. B ykov Card 2 /Z GUBIN.V. 1. Determining wind velocity on the basis of a pressure field. Trudy Inst.mat.1 nekh"N U%.SSR no.14:3-10 155. (NIU 8:8) (Winds) (Atmospberic preevure) 124-57-1-698 Translation from: Referativnyy zhurnal, Mekhanika, 1957, Nr 1. p 90 (USSR) AUTHOR: Gubin, V.I. TITLE: To a Theory of Local Frontogenesis (K teorii lokal'nogo frontogeneza) PERIODICAL: Tr- In-ta matem. i mekhan. AN UzSSR, 1955, Nr 14, pp ll-Z6 ABSTRACT: A rhathematical "local frontogenesis index" is proposed, as follows a' 'VT ~~;rt - abVT 8t T - b 'Ve) (1) IT e VTt VTt vet at where is the density of the air, IV T is the temperature gradient, 76 is the pressure gradient at the 700- Card I /Z millibar surface, and a and b are nearly constant quantities 124-57-1-698 To a Theory of Local Frontogenesis The aboveintroduced index reveals that a full analysis of local frontogenetic conditions can be performed geometrically by means of an investigation of the particularities of the isallothermic and isallobaric fields, also the struc- ture of the temperature and pressure fields of the lower half of the tropo- sphere. The index (P also affords a means - after some relatively simple transformations of Equation (1) - to identify mathematically conditions of frontogenesis (d) > 0) and frontolysis ((P < 0) in any area from the initial temperature- pre' ssure field of the troposphere. N. 1. Zverev 1. Meteorology--Mathematical analysis 2. Weather forecasl.,ing--Troposphere effects--Theory Card 2 /Z SOV/124-58-1-841 T;-anslation from: Referativnyy zhurnal, Mekhanika, 1958, Nr 1, p 110 (USSR) AUTHOR: Gubin, V.I. TITLE: -__0n Variations of Some Meteorological Elements Witnin Frontal Zones (Ob izmenenii nekotorykh mete o rologiche ski kh elementov vnutri frontallnykh zon) PERIODICAL: Izv. AN UzSSR, ser. fiz. -matem. n. , 1957, Nr 1. pp 53-73 ABSTRACT: In order to determine the vertical currents, as well as the varia- tions of the temperature and geopotential height of cons tant-pre s sure surfaces, the author starts from the vorticity equation written in the p system: d ( 92 - V T) (JQ V ) dT (Tt- dt where Q is the absolute vorticity, T the temperature, V the Hamilton operator in the p system, and t the time. The nongeo- strophic corrections in the horizontal wind-velocity vector component Card 1/3 are accounted for only in the heat-advection equation SOV/124-58-1-841 On Variations of Some Meteorological Elements Within Frontal Zones dT RT y Q T - = a dt 9 P C (2) where q is the heat advected in one second to a unit mass 'Y is the adiabatic lapse rate, p is the pressure, g is the acceleration due to the force of gravity, is the specific heat at constant pressure, and R is the gas constant. Equation (CF) in the geostrophic approximation is written in the form a -D - Lk ( a T ~T-' + ~n t z LT 'IT 0, As + 1 (3) ') t 6p C P ax ax, ay ay P where A= 2 2 (A, B) 8A 8B aA aB X2 + ~- Y2 ax ay ay ax 0 is the geopotential, and I is the Coriolis parameter. From equations (2) and (3) the author, upon enlisting the equation of static equilibrium Card 2/3 aO RT ap P SOV/124-58-1-841 On Variations of Some Meteorological Elements Within Frontal Zones determines 8 0/ at aT/8t , and T first in the geostrophic approxima tion and then, in order to account for the nongeostrophic correction, he employs the horizontal components of the wind-velocity vector, u and v, in the heat-advection equation, to obtain the expressions: I ID 1 2 1 2 72 [ " + ('D' u T -57y- 1 ) + T ax at T _FX_ ax ap I az4D 82 V _~ I ( 'D , at T -g-,)p I CIX -L,2 ay at T Dy y C 1 Sh. A. Musayelyan Card 3/3 GUBIN, V.I., ljoc phys vath Sci - (dir..,i) "on the problem of the hydrodynamic theory of frontogenesis." Tashkent, Pub doase of Acad Sci UzSSR, 1958, 12 pp (Acad 'ci UzSSR. ln!3t of Mathematics and Mechanics im V.I. Pomanovskiy) 200 c-Aea (KL, 27-58, 101) - 1 - GUBIN, V.I. Numerical forecasting of the geopotential height of Isobaric surfaces. Trudy Sred.-As.nauch.-isel.gidrometeor.inst. no.2:92-96 159. (KIRA 13:6) (Atmospheric pressure) 3(7),10(6) AUTHORs Gubin,V.I. SOVI/10'6-59-3-6/11 TITLE: On the Calculation of Vertical Flows PERIODICAL: Izvestiya Akademii nauk Uzbekskoy SSR, Seriya f1ziko- matematicheskikh nauk, 1959, Nr 3t PP 39-46 lussn) ABSTRACT: Since the immediate measurement of the vertical air flows being essential for the weather forecast is unperformable, they must be obtained from the hydro-thermodynamic equations. The author establishes the corresponding system of differential equations and completes it by roughly approximating boundary conditions. For the solution of the system the author uses the difference method and the electronic computer "Strela". As an example the vertical flows in the time from November 14 to 18, 1954 are calculated. There are 2 figures, and 4 references, 1 of which is Soviet, 2 American, and I English. ASSOCIATION:Institut matematiki imeni V.I.Romanovskogo AN Uz SSR (Mathematical Institute imeni V.I.Romanovskiy AS Uz SSR) SUBMITTED: January 31, 1959 Card 1/1 S/049/59/000/03/01?/019 AUTHORS:-Gubin. zhordzhio, V. Petrosyants, M. A. M"'"~oy,_ 9-.-N. TITLE: Book Review PERIODICAL: Izvestiya Akademii nauk SSSR, Seriya geofizicheskaya, 1959j Nr 3, pp 489-492 (USSR) ABSTRAOT: The following book is reviewed: I. A. Kibell "Intro- jl~ duction to the Hydrodynamic Methods of 9hoF_-Period_J9aat&e-r, Q'j- Forecastingil, The book originated as a course of,lectures given Fy Tr-ofessor I. A. Kibell in 1955 to 1956 at the Moscow State University. According to the reviewers, this is the first real monograph embodying the whole field of meteorology at the highest level, never before published in the USSR. Card 1/1 00 THE CALCUIATICK OF TKE KFASURE Of FlOw=!XE5IS AT Av"FRAZE L:74M (The theses at the Sysiposim L. Holoinkl) 1. An absolute derivation or 2oduius or logarUbA gra4iont teaporatum Is "opted A. & fACtGP (,MaaxU- ) of frontogenesla. Th* factor (.... ") di.t,t- but Character at this or the isobaric surfave wW at thu -rat* level as solle'(W-500) "ko possible to"Judge about the deforsatLon 41~tlw of too hviot frontal Ioa.. 2. the s-hoaa; or the calculation of fmmogano~l. a--- at 1-1 AT-500 is gimn. ,, . applied for the *CCount = the Glactronic Th. Calculation ..h. to based on to-l-led Model or atooophoM. --'a on the electronic coaputer ~Str%W. The sash .1th S, rogim consisted t 371 unit- (ZW7) I . 250 i. top. A. Account axaaiples of rractoganools conlitions am given for so,aa Concrete situation with the analysis of the generated results. 31"ort #Wml%ted for tbA ]al C*mssl A&soubty of tbo rmzl. Uniza of Cwodss7 Lod Goopb"Ics, 1.14takI ,FI.Ud. n J.11 - 6 AlWait 196C. PHASE I BOOK EXPLOITATION SOV/4349 Gubin, V. 1. K gidrodinamicheakoy teorii frontogeneza (Hydrodynamic Theory of Frontogenesis) Tashkent, Izd-vo AN Uzbekskoy SSR, 1960. 141 p. Errata slip inserted. 1,000 copies printed. Sponsoring Agency: Akademiya nauk Uzbekskoy SSR. Institat matematiki. Ed.: V. A. Dzhordzhio, Doctor of Geographical Sciences; Ed. of Publishing House: Ye. P. Yakovenko; Tech. Ed.: Z. P. Gorlkovaya. PURPOM This book is intended for specialists in the field of dynamic and synoptic meteorology. COVERAGE: The book deals with the theoretical foundations of frontogenesis and frontolysis - the process of the forma- tion and decay of frontal zones, particularly planetary altitudinal frontal zones - on the basis of hydrothermody- namic equations and the modern theory of the variation of Gard_4i75_ Hydrodynamic Theory (Cont.) SOV/4349 pressure and other meteorological elements. The terms proportional to frontogenesis are preserved, and their complete analytic solution is given. Qualitative and quantitative conditions favorable for frontogenesis are discussed. Since frontogenesis cannot be considered Isolated from other processes in the atmosphere, parti- cularly cyclogenesis, an attempt to made to establish the relationship between these two phenomena. The quantities which characterize frontogenesis and cyclogen- esis were calculated on an electronic computer of the 'NStrelan type. Some practical conclusions of a prelimi- nary nature are made on the basis of an analysis of the distribution of these quantities. The author states that the problems of the jet stream, which should be in- cluded In a complete theory of frontogenesis, are not covered In this book since they require a separate thorough investigatiori. The author thanks I. A. Kibel I, Corres- ponding Member, Academy of Sciences USSR, for his advice. There are 58 references: 39 Soviet, 16 English, and 3 German. Ca.pd-2-/-5-- S/166/60/000/03/06/011 C111/C222 AUTHORS: Gubin, V.I. and Karimberdyyeva, S. I TITLE: Forecast of the Height AT - 700 With the Aid of the Electronic Computer "Ural" PERIODICALt Izvestiya Akademii nauk Uzbekskoy SSR, Seriya fiziko-matemati- cheskikh nauk, 1960, No- 3, PP- 38 - 43 TEXT% The.authors consider a scheme for the\? forecast of the geopotential height 700 mb of the isobaric surface with the aid of the electronic computer "Umal" of the.R"earch Center of the Institute of Mathematics AS Uz SSR. The barotropic atmospheric model is used. The comparison of the calculated and the real.sinoptical situation for November 15, 1954 yields a partial a greepent t There are 2 figures and 2,Soviet references. ASSOCIATIONs Inatitut matematiki imeni V.I. Romanovskogo AN Uz SSR (Institute of Mathematics imeni V.I. Romanovskiy AS Uz S01 SUBMITTEDt January 27, 196o Card 1/1 S/044/62/OW/OC).9/037/069 A06OIA000 0 AUTHOR: Gubin, V. I. TITLEt Evaluatingthe altitudes of isobaric surfaces for the two-layer model of the atmosphere on the electronic computer "Ural" PERIODICAL: Referativnyy zhurnal, MatematiRa, no..9, 1962, 21, abstract'gV109 (In collection: "Materialy Soveshchaniya Koordinats. komfs* ' po chisl. metodam prognoza". Leningrad, Gidrometeoizdat, ig6i, 53 54) TEXT: The paper describes some results of computations carriedout ac- cording to a numerical method elaborated by the author, for-forecasting the geo potential for a two-layer model of the atmosphere. The forecast is given by time-steps. At each step three requisite functions of the variables x, y am determined by solving the Poisson equition for each of them. The Poisson equa- tion is solved "locally" for the neighborhood of each point of the grid. [Abstratter's notet Complete translation] S. L Belousov Card 1/1 -) 3 G' 3 S / 16 9/ 6 1 / 0 0 0 /0 12 /0 6 Q / 0 D228/D305 AUTHOR-. Gubin,- V.--,-I, TITLE: The equation describing intense frontal zrln- I (~'- , , PERIODII04AL: Referativnyy zhurnal Geofiz1ka, no. 12, jr: 59, abstract 12B371 NzSSR Panlar Akad,. dari, Dokl. AN UzSSR, 1961, no, 4, !:-14) TEXT.! The equations of hydrothermodynamics for hi,gh froatfi-';. zones with large temperature gradients are recordcd. in 'Llie. x, y, p on the assumption of a quaoi-static atmosphere and flat terrain. The equation of the vortex of velocity is recc~i-d,-~-d in a geostrophic approximation, ageostrophic correcLiozis br-~Inlil takent'intu'o account in the equation of heat inflow! 2 2 2 W, + I n (A) r Card 1/3 S / 16 9/ 6 1 /0 0 C/O The equation describing,- V22SID30-, where is the geopotential, V R L T n -- 1) p- is the quayltily ?,av i,ng Oie 12 and meaninp-, of the propagati.-Mal Speed of tkie met~r~rcllol`c elements, and R j~v the ga, B T T , ( 4, ~- ) 1 T, Z7 K Y Th.~~ recoi-ded equ:-itiono- are colkv-d undler C-ard 2/3 S/ 169/6 1/000.101, 2/"-I-"E:9/:-!)-. The equation describinIr.. D228/D3051, diti~)n.~t in relation to The hyperbolic c-i"u%'Lion 2 2 I n R + 6f A + - B 2 2 is finally derived for defines the renjon f L) reasonnble solutions which lie within a characteri:;ti,I-- c o,-i This r.,Leans that for an arbitrary height t. is nececcsarv take into account the influence on the observation.,,-tl. only those sources which lie in a circle of r,`adiu~; 2 2 x P (y _ Y') ,~-Abstracter's note; Complete tranclation.2 Card GUBIN, V.I., gornyy inah. DetermWng the correction factor fdr establishing the sise of pieces of broken ore. Gar. shur. no.12:54 D 162. (miRA i5m) 1. Institut gornogo dela AN Kazakbskoy M. (Dshozkazan listrict-Ore harAling) GUBINY V.I. Equations describing intensive frontal zones. Tnidy Inst. mat. AN Uz. SSR no.25sl-16 162. (Meteorology) (MIRA 16:8) BAKAYEV, M.T.; G1,31ki, V.I.; SAPARGALIYEV, M.S. Using straight cutB before drilling with a self-prope2lod drilling ria. Trudy Inst. gor. dela AN Kaza~h.SSR 12:22-29 0 163. (MIRA 17:8) -.7 5,7? 1 11 t f ACC NRa AT6025881 SOURCE CODE: UR/0000/65/000/000/0048/0051 AUTHOR: Gubin, V. 1. (corresponding member AN UzSSR) ORG: none TITLE: A method of precalculatiod of horizontal components of wind in the atmosphere S3URCE: AN UzSSR. Inatitut matematiki. Dinamicheskaya meteorologiya (Dynamic meteorology). Tashkent, Izd-vo Nauka UzSSR# 1965, 48-51 TOPIC TAGS: wind, wind direction, wind velocity, wind profile ABSTRACT. A simple method for precalculation of horizontal wind velocity components in the atmosphere is described. In the method the inital horizontal velocity compon- ents are used to calculate their future component values. Motion equations for the - plane case are found and the future horizontal wind components are calculated from the curl and the divergence of these equations by using finite time differences. All of the above calculations can easily be performed by a computer. Orig. art. hast 18 formulas.- SUB CODE: 04/ SUBM DATE: 14Det65/ ORIG REP: 002 ACC NR. Aj6'~j_58_8_2 SOURCE CODE: UR/0000/65/000/000/001'-2/0056 AUTHOR: Gubin, V. L(Correspanding member AN UzSM); TillyasbaYkhova, R- ORG: none TITLE: A graphical method for evaluating the success of precalculation of isobarid surfaces SOURCE: AN UzSSR. Inatitut matematiki. Dinamicheakaya meteorologiya (Dynamic meteorology). Tashkent, Izd-vo Nauka UzSSR, 1965, 52-56 TOPIC TAGS: meteorology, j"& -1 chawed, weather forecasting, atmospheric pressure ABSTRACT: A graphical method for evaluating the accuracy of precalculated isobaric surfaces is described. The accuracy of the precalculated isobaric surfaces is found by plotting a difference field representing the difference between precalculated and actual fields; a blank plot would indicate a perfect accuracy. The accuracy of a precalculated prognosis for a two-level geopotential field is considered as an example The calculated geopotential field for the example given was obtained by solving the theoretical equations by finite difference methods. Orig. art. has: 3 formulas and 3 figures. SUB CODE: 04,12/ SUBM DATE: l4Dec65/ ORIG REF: 002 Card 1/1 ------------ ACC NR, AT6025883 SOURCE CODEt UR/0000/65/000/000/0057/0064 AUTHOR. Gubin, V. I. (Corresponding member AN UzSSR); Til2yaahaykham) R. ORG: none-_._______ TITLE: Use of Green's functions for hydrodynamic weather prognosis SOURCE: AN UzSSR. Institut matematiki. Dinamicheskaya meteorologiya (Dynamic meteorology). Tashkent, Izd-vo Nauka UzSSR, 1965, 57-64 TOPIC TAM weather forecasting, meteorology, Green function ABSTRACT: An attempt is made to calculate the improper integral which is usually neglected in Green's functions. A pressure prognosis, found by use of equations developed by N. 1. Buleyev and G. 1. Marchuk, for a three-layer model of the atmos-... phere is given by considering and neglecting the above improper integral. It in seen that inclusion of the improper integral improves the correspondence between prognostacized and factual fields by 0. Z. Height calculations of an isobaric sur- face are given as an example. Orig. art. has:. 3 formulas.and 3 figures. SUB CODE: 04/ SUBH DATE., 14Dec65/ ORIG,REF: 001 ~ACC N'%: SOUR02 CODE. UR/0000/66/000/GW/0018/0026 XLMMYLS: Gubin (Corresponding member AN UzSSR); Tillyashaykhova, R. ORG: none .TITILE: Examples of forecasting the geopotontial field from afour-levol aTmospheria model SOURCE: AN UzSSR.~ Institut matematiki. Resheniye uravneniy gidrotermodinamiki pri;,n.cnitellno k zadacham meteorologii (Solution of equations in hydrotfhermodyna m.'cs applied to problems in meteorology) Tashkent, Izd-vo F21 UzSS11, 1966, 18-26 TOPIC TAGS: atmospheric"model, weather forecasting, weather map, atmospheric geopotential, integral equation, isobar jUSTRACT: The authors forecast pressure for a four-level atmosplieric model fromthe equ~-'Wion of N. I. Buleyev and G. I. Marchuk (0 dinamike krapnomasshtabnykh atnosfarnykh protsessov, Trudy Instituta. fiziki atmosfery, No. 2, X., Izd-vo L%l SSSR' 1958). The equation is used in the gom: G2 A. dx' dy' d~'- ~-~G A dx'dy'Af.' 7F 2nig g r T ACC NRt AT7002808 The influence functions have the formi G. 2 Y-W .(in r) + a(in r) + 0 - 2a) o~- VIC e(72L (a, r) da dG2. or V AT5()O, and AT300 were used as starting data. The The surfaces AT850, AT7001 caiculatioa results are compared with the results obtained by the influence-function mothod with a three-lovel atmospheric model. Estimates of the success factors show thaz, the three-level model has a certain advantage over the four-level. It i's fourA that ATa5o has the lowest correctnes3 *factors. Orig. ar~t. hast 6 for=las, 2 tables, and 2 maps. Sua COZZ: 04, 12/ SUM DATFt .2&UY66/ ORIG REFz 003 Card 2/2 GUB 2b.14, inzhenor. - Proportion of stainless chromius-nickel steel smelted In vacuu furnaces. Sbor. Inst. stall. no.35tZ83-289 156. (MLAA 100) 1. Xafedrs elektrometalluxT11, (S%oelg ftainless-Testing) (Vacuum apparatus) GUBIN, V.N.. inzh.; LOTCHMIKO, V.I., manhinist-instruktor Wheal olip current relay. Blek. i tepl.tiaga 2 no.4:22-23 Ap '.~4& (KIRA 12:3) (Electric relays) (Electric locomotives) GUBIR. Y.N., inzhe (stantaiya Ilookovka, Omakayet doroga); MAL'TSR7, S.S., mashinist elelctrovoza (stantsiya Mostrovka, Omakaya doroga) More information pertaining to the emergency circuits for electric locomotives. BlekA tePI-tiags 3 no.11:41-42 N '59. (KMA 13:3) Mectric locomotives) V.11., inzh. (Vepo Hoskovka, Oaskaya doroga) Means for extending the lifespan of antifrictional disks in electric locomotives. Alsk.1 tepl.tiaga. 4 no.6:15-17 Je 16o. (MIRA 13:6) Oilectrie locomotives) (Bearings (Machinery)) . 1:- 1 1 ~ ~ I .'' :4 BOCRAROV, Yu.D., master komplekenoy brigady; STEPANOVICH, M.G., master komplekanoy brigady;-rzl~IN, V.N., inzh. How we organized periodic repair of electric locomotives. Blek. i tepl. tiaga 4 no.11:1-6 N 160. (MIRA 13:12) (Blectric,locomotives-Repairing) I GUBINI V.14., inzh.; BAMOV, N.A., inzh. conclusiona deriVed from the-analysi.9 of the operation of IM-406 traction'motors. Elek. i tepl. tiaga 5 no.6:10-13 Je 161. (MIRA 14:10) 1. Depo Moskovka Zapadno-Sibirskoy dorogi. (ElectrIc railway motors) GUBIN., V.N., inzhe Radiator system for drying traction engines. Blek.i tepl. tiaga 5 no.10:13-14 0 161. (MIR& 14:10) 1. LDkomotivnoye depo Moskovka Zapadno-Sibirskoy dorogi. (Electric railway motors-Maintenance and repair) (Drying apparatus) GUBIN, V.S., inzb. Automation of ball mille operating on wet roal. Energetik 9 no.2~.9-10 F 161. (MIRA 16!.7) (Coal.) (Automatic-'rontrol) 0 1. !::~ I . , ~, : t ! !I p .. ! i, I III 'I I I ! V. q P i I . I I I ;~ I - 11 , GUBIN, V-V- ; MAKAROV, Tu.N.; AKSJNOV, B-Ye. Mine testing of coal extraction by means of chain sau. Ugoll 35 no.11:27-30 11 1609 (K= 13:12) 1. Pechorekly nauchno-teeledovatellekly uVllzWy lustitut (for Ombin, Makarow). 2a GlavzWy Inshemer shakhty No.1-2 "Mud"mer-Yu" (for Akeenov). (Coal mines and mining) (Coql sliming machinery) GdBINP V.V. . I - of wall rock In mining coal with a wire line saw. Vop. gor. davl. no.7327-34 161. (KRA 1W) 1. Sibirskly metallurgicheskiy inatitut.