25856
3/020/61/139/004/0'06/025
3 103/B206
AUTHORSt Nesmeyanov, A. Ns, Academician. Pp.avaiova, E. G., Gubin, 3,
F. , Kikitina, T. V. , Ponomarenko, A A., and Shilovfs~eva,
TITLEt Properti~,s of phanyl ferrocene
0
PERIODICAL# Akademiya nauk SSSR. Doklady, v. )39F lo, 4~ 9
al
TEXTs The authors investigatedt 1) the amino me-c vion, 2) sulfona-
tion, 3) concurrent (with ferrocene) aoetylation, a 4) nitration of
phenyl ferrocene. They established that the alky2 up, if linked with
the ferrocene ring, facilitates the subsejuent elec pnillii~ substitution.
,:: -, t~~
In this case, the cyclopentadianyl ring to which the i~lkyl group is bonded,
is more strongly activated. In relation to the ferrc~enyl group, the
phanyl group is an eleotron-acceptor group (A. N, Nesmayanov et al. Ref -
51 DAN, 103, 81 (1955)). These data by the authora were confirmed by 24,
Rosenblum (Jo Am. Chem. Soc-o 81,4530 (1959))% The electrophilic aulbsti-
tution of the hydrogen atoms in the ferrocene ring is deactivated by the
phenyl group. 1) Amino methylation. To a mixture of 70 m! of g2acial
Cardl/6
25850
S10?01611139'/004/016/02-5
Properties of phenyl ferrocene B103/B206
acetic acid and 4 9 of H3PO 49 cooled to 10 OC, 2.25 g (0.019 mole) of
tetramethyldiaminoethane is gradually added, and then 4 9 (0-015 mole) of
phenyl ferrocene. The reaction mass was stirred for I hr at room
temperature and for 10 hr at 110 - 115 0C in a nitrogen current and sub-
sequently diluted with water to the double amount. The ferrocene (1.5 g)'
which had not entered into reaction was extracted with benzene, 4C~ NaOff
solution was added to the acidic solution, and the formed (N, N-dimethyl-
aminometh,yl)-phenyl ferrocene was extracted with other. After distilling
off the other, 2.6 g of the above-mentioned compound was obtained as a
viscous, darK, reddish-brown oil. The yield amounted to 54% of the
theoretical one (related to phenyl, forrocone) and to 86~ of the phenyl
ferrocene reacted. The final product was distilled in 7acuo-Its boiling point
0 20
was 150-160 C/3 mm Hg; n,, 1.6315- In the infrared spectrum of the final
product, weak absorption bands existed in the range 1000 and '1100 cm- i.
From this, the authors assume the formation of a mixture from the hetero-
and homoannular isomers. The latter seems to form in small quant-itis.9,
The methiodide of the final produot was produced by addition of CH 31 to
Card 2/6
a 020J611139100410161025
Properties of phenyl ferrocene B105/B206
I
a solution of 3.2 g in absolute Ch OR (or in benzene) with precipitafion
3
after 15 min by h_areat amount of anhydrous other. An almoot,quantitative
(4-3 9) amount O(flmethiodida was produced. It is a yellow, cryatall~ne
-substance with the decompo8ltion Point 70 - 750C- Since in the infrared
spectrum of the mothiodide which wan produced from the distflled tipal
product, absorption at 1000 and 1100 om" I is mioolng, the authors conclude
that the substituting groups are in various cyciopentaalanyl rings.
Through reduction of the methiodide by sodium amalgam, the,-he'tvroannular.
1 -methyt-phenyi -f 4rrocene was obtained (se~ reaction no. 1
C4Hs
ICH.). NCHjNjV1#)j
Fe
H.Po' CHiN (CH4
CIHS
CH.J W CA Noftle \/_
Fe Fe
+
CH2N (CH4 J a 1,
Car.4 316
S102 6111'391004101,61025
Properties of phenyl ferrocene B103YB206
The yield was 1..8 g(71% of the theoretical one). Absorption at 1000 and'.
1100 cm -1 was missing in its.infrared spectrum. A free cyclopentadienyl.
ring can only be proved spectroscopically in the substance which was
isolated from the.mother liquor. The authors came to the conclusio?) that I
the hetepoannular isomer was the.main component of the mixture yroduced bi:
amino methylation. Thersfnre,.th~j.reaction mainly occurs In the free.
cyclopentadienyl ring. 2) To,..a,,sqlution of 10 g (0 O~8 mols)'~f phenyl
ferrooene in 100 ml of dichloroefl%ne., .10 g (0.060 mois of freshly
prepared dioxane sulfoVrioxide..wq,%.,added while cooling with ios. Under
the conditions of formation of.,feVgooene.monosulfonic acid; 11, 1 pheny.1
ferrocene sulfonic acid was obtaI494,1.
50 -dioxane
C6H5C5H4FeC5 H5 3 4 C 6H5C5fl:-,Fqq~H4SO 3H. This acid was Isolated
as lead salt, which crystallize&.withj4,,jwater molecules, Absorption'at
1-000 and 1100 cm-I *as here als 'o-m44qAn~; 'the yhonyl,and sulto groups - are
therefore in different oyclopenti4ioa)KI, rings. The formation of het*ro.
annular sulfonia acid 1e also proof of a lower reactivity of the.ring
Card 4A
S/020 611139100410161025
Properties of phenyl ferrocene BlOVB206
linked with phenol. 3) The deactivating effect of the phanyl gropp
on the ferrocenyl ring is specially marked during the Friedel-Craftt
reaction. A solution of 1.4 ml of acetyl chloride and 2.66 g of AIC1 3
in 10 ml of absolute ether vu.!3 added in thd course of 20 min to a
solution of ferrocene (3-72 ~) and phenyl ferrocene (5.42 g). in 100 ml of
CS 2' All components were ujt2d at a molar retio of-1.1:1:1. The authors
obtained acetyl ferrocene only with a yield of 25~ of the theoretical one,
and a mixture of acetyl phenyl ferrocenes of Only 5%, 64% of phenyl
ferxocene and 30% of ferrocene being recove'red unchanged. From this, the
authors conclude that f errocene may be acetylated more easily thanphenyl
ferrocene ' 4) Phenyl ferrocene was nitratei by means of ethyl nitrate
in CS 2 in the presence of AM Y The authors obtained a 13% yield (of the
theoretical one) of p-nitro-Dhqnyl ferrocene (see reaction no. Z).
NO
C,H,ONOJ\
Fe - Fe
Card 5/6
3102 61/'139/004/6116/025
Properties 'of phenyl ferrocene B1 03YB206
The main quantity of this final product is isolated together with part of
the nonreacted phenyl ferrocene in nonoxidized state (and not as a cation).
The authors presume that nitration does not take place with the phenyl .
ferrocene cation but with phenyl ferrocene. The continuance of the ferro-
cenyl ring under these conditions is noticeab-le, probably as a consequence
of a reduced capability of being oxidized to a cation as compared with
ferrocene. Ferrocene itself cannot he nitrated under these conditions.
Attempts of the authors to nitrate ferrocene %,vith various other reagents
(e. g., nitronium borofluoride) also failed. Only oxidation of ferrocene
to the cation which is inert in reactions of the elWtrophilic substitution,
was brought about. There are 9 references: 7 Soviet-bloc and 3 non- `
Soviet-bloc. One refereace to English-language publications is given in.the
body of the abstract, the anothL~r one reads: Lt. Rosenblum, R. B. ffoodward,
J. Am. Chem.
Soc., 80, 5443 (1958)).
ASSOCIATION: J,1o_z.kovskiy gosudarstvannyy universitet,im. M. V. Lomonosova
(bloscow State University imeni 14. 7. -Lomonosov)
SUBMITTED- April 19, 19061
Card 6/1
S/020/62/143/006/016/024
B106/B138
AUTHORS. Gubin, S. P., and Perevalova, E. G.
TITLE: Formal redox potentials of monosubstituted ferrocenes
PERIODICAL: Akademiya nauk SSSR- Doklady, v. 10, no. 6, 1962, 1551-1554
TEXT: The formal redox potentials of 30 monosubstituted ferrocenes were
determined by potentiometric titration with potassium bichromate in a
mixture of acetic acid and aqueous perchloric acid. Relative quantitative
data were thus obtained on the effect of substituents on the oxidation of
the ferrocene nucleus to the ferricinium cation. The determinations were
conducted by the method of J. G. Mason and M. Rosenblum (flef.2s J..Am.Chew..
Soc., 62, 42o6 (196o)) at 25 t 0-10C in nitrogeii atmosphere. Table 1
shows the results. The differences of the logarithms of the equilibrium
constants for the reactions of substituted and unsubstituted ferrocene
were calculated from the corresponding potentials (Column 4, Table 1) and
compared with the constants 6* and 00 according to Taft (Ref. 10;
M. S. Nlyumen, Prostranstvennyye effekty v organicheskoy khimii (M. S.
Newman, Steric effects in organic chemistry), IL, 1960) 591), and a[a and
Card 1A
S/02 62/143/006/016/024
Formal redox potentials of... Blo6%13a
6n according to Hammett (Ref. 11s D. R. McDaniel, H. C. Brown, J. Org.
Chem., 23, 420 (1958)). No relations have been found to the constants 6
a0, and am, while there is a (not very good) relation to the constants d n
In a diagram (log K/K 01 an), the ferrocenes with the substituents -OCH 31 V
-OCOCH 31 -CH 3, -C2H 50 iso-C3H7lie on a straight line with Q - -4.23, on
which the ferrocene itself also lies (correlation coefficient 0.985),
whereas the ferrocenes with the substituents -C 6 H51 -C 6H4NO 2-PI -COOH,
-COOCH3, -I, -Cl, -Br lie on a straight line with q - -7.94 (correlation
coefficient 0.982). In the case of the ferrocenes which lie on the former
straight line, the substituents interact with the iron atom by mechanisms
of inductive, conjugation and, possibly, field effects, the latter only as
far as thia effect is reflected by the value of a n. In the case of the
ferrocenes which lie on the straight line with Q - -7-94, the substituents
interact with the iron atom by the field effect mechanism much more
intensely than is reflected by the a n values. This agrees with a
Card 2/ 5
S/020/62/143/006/016/024
Formal redox potentials of... B1061B138
published statement that hydrogen and alkyl substituents cannot interact
with the reaction center by the field effect mechanism (Ref. 9:
V. A. Pallm, Usp. khim., 3o, 1o6q (1961)). The interaction by the field
effect mechanism occurs over a shorter distance, which leads to an in-
crease in the absolute value of Q. Academician A. 11. Nesmeyanov is
thanked for cooperation and advice. There are 1 figure and 1 table. The
most important English-language references read an followai T. Kuwana,
D. B. Bublitz, G. Hoh, J. Am. Chem. Soc., 82, 5811 (1960); H. H. Jaffe,
Chem. Rev., 53, 191 (1953); D. S. Trifan, R. Baskai, Tetrahedron Letters,
1960, no. 13, 1; J. D. Roberts, R. A. Carboni, J. Am. Chem. Soc-9 77P
5554 (1955).
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. lit. V. Lomonosova
(Moscow State University imeni M. V. Lomonosov)
PRESENTEDs December 12, 1961, by A. N. Nesmeyanov, Academician
SUBMITTEDs November 9, 19061
Card 3/5
S/020/62/143/006/016/024
Formal redox potentials of... B106/B138
Table 1. Formal redox potentials of monosubstituted ferrocenes C 5H 5FeC5 H4X
(formulas do not take account of changes in the reaction medium).
Logendt (I) E f , v (according to a standard calomel olectrode); W) W.,
0C; (III) b OC; (IV) under decomposition; 2 calculated from the
t Hg
X - H 3
formula (E0 EOWO-0591 - log K/K o; only the primary 6 n values obtained
from the dissociation constants of the corresponding p-substituted benzoic
acids have been used; 4 the potentials of these compounds differ slightly
from published data; the potential differences between forrocene and
phenyl ferrocene, and between ferrocene and p-nitrophenyl*ferrocene, are
constant within the error limits of the experiment; 5 from published data;
6 the value for the -COOC H$ group from published data has been used. In
oolumn 2t V-SO - i80; p., M; A - P.
Card 4/5
s/o2o/62/147/002/015/021
B1o6/B101
AUTHORS: Perevalova, E. G., Gubin, S. P., Smirnova, S. &.1
Nesmeyanov, A. N.; Ac1t#-mrc-1ai--'
TITLE: Redox properties of compounds containing tuo ferrocenyl groups
PERIODICAL: Akademiya nauk SSSR. -Doklady, v. 147, no. 2, 1962,- 384-387
TEXT: The authors studied the effect produced by one ferrocene ring on
the redox properties of a second ferrocene ring bound to the first either
directly (diferrocenyl) or by groups Y of different conductivity (-Hg-,
-CH 2-# -CH 2-CH 2-9 -CH 2- O-CH 2-' -CH2-N+(CH 3)2-C-H2-) . They measured the
and J;11 *(Table 1). The significance
first and second redox potentials Ei. f0
11
of Eio and E f0 is evident from the following scheme:
Card 1/4
Redox properties of compounds ...
Y_,
7-
.e Fe Fe+ Fe +
Ef'o
S/020/62/147/002/015/021
B106/B101
1e Fe Fe t--=:z
Ell
\Y fo
_Y_
V
Fe+ Fe+ +Ie-
"j,
Under the chosen conditions diferrocenyl was oxidized at one Fe atom
only. When two ferrocene rings interact, the electron density increases
at the ring oxidized. The redox potentials indicate that the methylene
group transfers to the other nucleus; hardly any of the electron-donor
effect of the ferrocenyl group, whereas the effect of the positively
charged ferricinium ion is transferred even across bridges of 3 atoms.
The investigations covered also how some substituents in the methyl group
of methyl ferrocene affect the redox potentials (Table 2): in this case,
too, the effect of electron-acceptor substituents was transferred via the
methylene group to a notably greater extent than that of electron-donor
substituents. There are 4 figures and 2 tables. The most important
English-language references are: R., W. Taft Jr., J. Am. Chem. Soc-t 759
Card 2/4
S/020/62/147/002/015/621
Redox properties of compounds B106/B101
4231 (1953); 9- H. Jaffe, Chem. Rev., 53- 191, (1953).-
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosava
(moscow State University imeni M4 V. Lomonosov)
SUBIMITTED: July 18, 1962
Table 1. Redox potentials of compounds with two ferrocenyl groups
C5H5FeC5H4- Y-C5H4FeC5H5(in v, related to the standard calomel electrode).
Legend: (1) melting point, 0C; (2) diferrocenyl; obtained by
reduction of diferrocenyl ketone; (3) with de.composition.
Table 2. Redox potentials of some monosubstituted ferrocenes
C5H5FeC5H4CH2X. Legend; (1) v, related to the standard calomel electrode;
,K mean deviation from the Ef values indicated t0.003 Y
Card 3/4
NESWYANOV, A.N.; KOZLOVSKIY, A.G.; GUBIN, S.P.; PM,VALOVA, E.G.
Protolysis of meroury derivatives of ferrocene. Izv. AN SSSR. Ser.
khim. no.3s580 165. (MIRA 18:5)
1. Moskovskiy gosudarstveftnyy universitet im. M.V.Lomonosova i
Institut elementoorganichaskikh soyedineniy AN SSSR.
-- -. .-M- --- - "
I I . j ~.- -q, r. 1", ~,~ T ' i I ~ 14' --,1 F~. nt -I -I - I 1 7 i I - ; I *;' 1 % I I I : I ~ A. , : I ; I
. r~.. . F . J7 . I ; I z
ri
L 46186.~
ACCESSIOWUR. APS007562
H4
h
-It was found.that the chemical shifts of protoinis. of' the uh4,ilbsti uted rin
g 4re
cbiefl_* dete ined b~:the induction diffect:of th sub titutkots. 1he: Obser4ed
r=
s, of .the shifts 6 an d 6 indl6at6-a co6si4iiabU'~ eifk~ldt. bfEt~e~~60ii 94': YK
value
b c
id: of the: ipo6ti~
the substituent on the chemlc&l shifts. of proton pinji. ~j ~iCor-.."
relatil6ns-are~presented between the values ok..:S 6 and! conjugation c6t~stahts j
-C
~!~'ang the io"A%ictW~~ cbnstaks:'of ifthe'
of the substituents, between the 66mica1:shifts.
cal I jroionb~ d ihejubsiit~t4~~ih~
substituents j, and: between the chemi ~h fts:.Of
and:the Hammett constants. 0-..0f the-substftuenfs,~~-. The retl~its of thds d r Aiakd It
possible~to'diliaw_ a close Alogy betweisu'l~heioi*,Li~*d-"i,~a,n,dl,l,~e,h~kr,;,L6tar of,
fltiencw of the slubstituents ci this W a 'a
t-n6ft,104-iltid
Ip M::
~cenyl: nueleus .band corresponcunkly, Op.,:th!s t*. a 0-, aral
.1V
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h Ori
lbus. g. ind
th.e-.'p,,.efiy1 nuc, .2 ',~tib
A i
L -
Tt,
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i
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L
46186-65
ACCESSION NR*.. :AP5007562-
M141
-P SSSR It
ASSOCIATION, ~-:Instittit khi~il rir6dnykh,~6c7e& 6fily. A4446t! ai4
Chemistry of Nat~i4l de i.A ca devy- of~ sbbincdd~ S1699P InOtittit elimnto- i,
o
f Compoun"
Apyedninan~yFMSRI-.nauk a !,Org
-organicheskikh
.*f iSci nciab SSSR) -i~
po4nds Acade
MY 6
P.
S(
CM W
J-
Nr
-PUT",
0
.zt
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Mr.
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7
1. II)STA"O.
mit, -I Matr -W,
- e . I I
. 3136A-66 Ee-P(J)/EWT(m) IjP(c) RM
ACC NRs AP6021104 SOURCE CODE:
AUTHOR: Gubin, S. P.j Shepilov, 1. P.; Neemeyanov, A. N 6-1
11-- .15
ORG: Institute of Organoelemental CqUounds, AN SS5R (Institut elementoorganicheskil
soyedineniy)
TITLE: Acetylation of ferrocenelby the complex 2CH sub 3 COM.BF sub 3
SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 2, 1966, 384
TOPIC TAGS; ferrocene, acetylene compound, reaction rate, activation energy,
spectrophotometric analysis, catalysis, chemical reaction kinetics
ABSTRACT: T~e authors determined rates of acetylation of ferrocene by the complex
2CEL3-COOH-B in glacial acetic acid under paeudo-first order conditions. The
reaction wa- arrested by pouring the sample (1 ml) into 20 ml of absolute ethanol.
The ferrocene and acety1ferrocene concentrations in the solution were determined
spectrophotometrically at 337 millimicrons on the SF-4A unit. The apparent energy
of activation is 22-4 kcal/mole. When the catalyst concentration is increased,
the reaction rate rises. The data obtained shows that ferrocene is 200-300 times
more active than anisole in the acetylation reaction. (JPRS1
SUB CODE: .07 / SUBK DATE*. l7Kov65 / OTH ]REF-. 001
1/1 A,A- UM 542--957 + 546-72 + 66-095-11
ACC NR. AP6017876 SOURCE CODE: UR/0062/66/000/005/0832/0839
AUTHOR: Porev lova, E. G.; Grandbgrgg K. I.;
meyanov, A. N
ORG: Mospow State University im, M, V, Lomonos (Moskovskiy gosudarstvennyy univor-1
sitet); Institute of Organometallic Cormounds,, Academy of Sciences., SSSR (In-
stitut elementoorganicheakikh soyedinenly Akademit
TITLE: Electronic influence of ferrocenyl as a substituent
SOURCES AN SSSR. Izvestiya, Seriya khimichoskayap no. 5p 1966, 832-839
TOPIC TAGS: ferrocene, dissociation constant, aniline, benzoic acid, phenols substi-11
tuent, amine
ABSTRACTS By determining values of Hammett's C( p the authors studied certain elec-
tronic effects of forrocanyl as a substituent. Using acid-bass potentiometric titra-
tionp they determined the dissociation constants of p-, m-p and o-ferroconylbonzoic
acids* a series of substituted benzoic acids and ferrocenecarboxylic acid In 70% di-
axane, and the dissociation constants of p-ferrocenylphenol and a series of p-substi-
tuted phenols in 50% ethanol. The basicity constants of p-,, m-, and o-ferrocenylani-
linesp a series of p-substituted anillnes, and ferrocerqlamine in 80% ethanol were
also determined. The data obtained were treated by the least-squares methodp f val-
U*s were calculated for the reaction series studied, 6 values were found for ferro-
UDC1 541 + 541-49 + 547.1*3s541-132
ACC NR: Ap6017876
canyl as a substituent in various positions of the phenyl ring, and the induction co
stant Or was determined. The data showed that in the series of ferrocenylbenzoic
acidst tL strongest is o-ferrocenylbenzoic acid; p- and m-forrocenylbenzoic acids
are comparable in strength and are respectively 1.5 and 1.6 times stronger than ferro-
canecarboxylic acidq which therefore is the weakest acid. p-Ferrocenylphenol is a
weaker acid than phenol (by a factor of 1-3), The opposite relationship is observed
in ferrocenyl derivatives of anilinet o-forrocenylaniline is the weakest base, 300
times weaker than ferrocenylamine. 7he strongest base, ferrocenylamine, is 42 times
stronger than aniline and almost 28 times stronger than p-forroconylaniline. It is
concluded that ferrocenyl has a strong positive inductive effect and a weak positive
conjugation of ot. Orig. art. bast 7 tables and 2 formulas.
r
SUB CODES 0711SUBM DAM 27Doo63/ ORIG REFS 009/ OTH REFS 014
211
:'CC NR; AF7012420 SOURCE CODE: UR/0062*66,'000*011 1938,'1943
AUTHOR: Nesmeyanov, A. N.; Perevalova, E. G. 7yurin, V. D.; Gubin, S. P.
ORG: Moscow State University Im. M. V. lamnosov (Hosimyskiy gosudarstvennyy
universitet)
TITLE: Hetallation of alkylferrocenes
SOURCE: AN SSSR. Izvestlya. Serlyn khlmlcheskay;a, no. 11, 1966, 1938-1943
70PIC TAGS: ferrocene, lithium compound, ferrocenyllithium
SUB CODE: 07
ABSTRACT: The rBtallation of methyl-, ethyr-, and n-propy1ferrocene with
-excess n-butyllithium at room temperature vas studied. Mixtures of mono- and
The monometallated alkylferrocenes
dimetallated alkylferrocenes were obtained.
were found to possess a heteroannular structure- The mixture of mono- and dimet-,
allated alkylferrocenes.. after carboxylation, were converted to a mixture of
;mono- and dicarboxylic aci'ds. Metallation of alkylferrocenes proceeded with
-greater difficulty than that.of ferrocene itself. Approximately 2-2-5 times as
much of.the Monometallated alky1ferrocene was formed as of the dimetallated
derivative- d alkylferracenes were also usecl for the synthesis
The metalUze
of heteroannular njtroaUWjferrocene6 by the reaction trith propyl nitrate*
hyl-, nitroethyl-, apd, pitr_opropylferrocenes were obtained in low
Card 542o91 + 547.113 + 546.72
0932 05
I
~6
11 1 t..
ACC NR; AP7013134 SOURC_~- CON: UR/0062J'66 000 009 155lil558
AUTHOR: Gubin, S. P.
ORG: Instituto of Heteroorganic Compounds, AN SSSR (Institut elementoorganicheskikh
soyedineniy j%N_SSSR)
TITLE: Electronic effects of substituents In ferrocene and Its derivatives
SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 9, 1966, 1551-1558
TOPIC TAGS: feriocene, chemical substituent
SUR CODE: 07
ABSTRACT: In.a re rt presented at the General Meeting of the.Departnient of
d_en_e,r_al__,_and_,*Technical Chemistry, Academy of Sciences USSR, on f6 December 1965,
the author describes a detailed study of the nature of the interring electron
effects in the ferrocene molecule. Classical methods, such as measurement of
-the dissociation constants of the acids and study of the absorption spectra
in the ultraviolet and visible region, andcomparatively nev methods, such as
study of the proton magnetic resonance and nuclear gamma resonance spectra were
-used to study the transmission of electronic effects in the ferrocene r.Dlecule,
and a reaction specific for ferrocene derivatives was also investigated: rever..:
sible oxidation at the iron atom. *The numerical data obtained were treated by
methods of correlatiopal analysis. The transmission-of. the. i.nflgence of sub-
-Card'. 1/2 UL)C: 541+542.957+546.~72
ACC NR. AP7013134
stituents along tho ring-metal bond was found to be predominantly Inductive
In character; Orig. art. has: 9 figures. LJ'1-RS: 40,422
GUBIN, S.S.
Ifew developments in the financing of inCormaticn organn.
NTI no.9:5-6 165. (MIRA 1911)
KAYZERKAN, M.M., mayor meditainskoy-sluzhby; ZAVRAZHINj, M.K., podpol-
kovnik meditoinakoy aluzhb7; KNYAZEV, S.V., podp6lkoynik medi-
toinskoy sluzhbyl KOBUKOV,, N.Isp podpolkovtik meditsitskey
sluzhby; DOUCHAM, G.M., pod~olkovnlk m9cUtxJmskoyl-#luzhby;
PIETNEVI NN,, polkoynik meditsinskay sl~zhiby;' KHCHOSHCHEVO V.D.t
podpolkoTnik meditsinskay sluzhby; GORBACHIK,Ye,.D., podpolkoyna
msdiUinskoy sluzhby; DRUKERp Yu.S.; NAZAROV, X.M.; K(HOGOROV,
P.R., polkovnik meditsirmkoy sluzhby; KLIMENK01, A.V.,, podpolkovnik
meditainskoy sluzhby; RTAKHOVSKIYp I.Ye.'p podpolkovrAk meditsinskoy
sluzhby; IVANIKOVICH F.Aj; GUBIN _�_tV,; kEtpitan meditsinskoy
sluzhby; ZOPTOV, I.G.: kap ta~nl ~me lisl~;koy sluzhby; LEONOVA, Ye.I.;
BUNTOVSKIY,, P.A., mayor meditainskoy oluzhby; GERAS13407, A.N.,
podpolkovnik meditainskoy sluzhby; GUR17EV, I.A., kapitan medi-
tsinskoy sluzhby; KOIJ)OBSKIY, S.Z., mayor meditsinskoy sluzhby
Abetracts, Voen. med. zhur. no.10:74-79 0 165.
(MIRA 18:12)
GUBIN, V.,sudlya respublikanekoy kategorii
Competing for seconds. Voen.znan. 36 no.11:30-31 U160.
(MIRA 13:11)
(Aquatic syortm)
V.
-? ti
14n the design b~,Arenuo. Tp-k'h.ent. no.502 1tv 165.
(KIRA 1846)
9(6) S/146/59/002/06/004/016
D002/DOO6
AUTHORS-. Sitnikov, O.P., Perminov, Yu.A. 1atrbtV___r_
TITLE: A Device for Measuring the Errors of A
Control �y hems .
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Priborostroy-
eniye, 1959, Nr 6, pp 23-28 (USSR)
ABSTRACT: Detailed information is given on a device (Figure I
an12) for measuring the errors of automatic control
systems. It is a decoupling lowfrequency amplifier
with a relatively wide dynamic range and has a
double triode whose grid receives the voltage from
the integration chains serving as the error signal
input. The signal causes a disbalance of the triode
currents, which is recorded by an indicating instru-
ment. The device measuring the mean square error value
consits of a preamplifier, a detector, a squaring de-
Card 112
9(6)
S/146/59/002/ 06/004/016
D002/DO06
A Device for Measuring the Errors of Automatic Control Systems
vice, an operation amplifier, and an integrating am-
plifier. Good results can be obtained with stabilized
feed sources of +300 volts, - 300 volts, - 190 volts,
and +80 volts. V.S. Pugachev's random functions the-
ory fRef. 1-7 was used in selecting the optimal aver-
agi-g interval. The article was recommended by the
Kafedra apparatury avtomaticheskogo upravelniya
(Chair of Automatic-Control Devices). There are 2
diagrams, 2 graphs, and I Soviet reference.
ASSOCIATION: Urallskiy politekhnicheskiy institut imeni S. M.
Kirova (Ural Polytechnic Institute imeni S.M. Kirov).
SUBMITTED: December 29, 1958
Card 2/2
LAPTEVA-POPOVA, M.S.; GUBIR, V.A.
- -.1.1 111-,,~~'.
Changes in the formmtion of blood caused by
Itogi nauki.Biol. nauki no.1:214-261 '57.
(RADIATION-PHYSIODDGICAL EMGT)
ionizing rAdintlons.
(MIRA 11:3)
(BLOOD)
GUBIN, V.A.
Nomogram for the color Index Rnd absolute number of thrombocytes,
noutrophile and lymphocytes. Problogemnt. I parel.krovi I no.3:6i-62
Mr-je 158 (MDU 11:6)
(13WOD GHLIS,
nomogram for color Indox & aboolute number of blood
plateleta, neutrophils & lymphocytei3 (Rua))
CMD1, T*A*
Certain histochemical studies of blood cells In acute radiation sick-
ness. Med.rad. 4 no.10:3--9 0 159. (KnU 13:2)
(RADUTION INJURY exper.)
(BWOD 03LLS radiation eff.)
1;- -1 ~ i-I - I. I
,~_ GUBIN, V.A. (Moskva)
Studying leucocytes of the peripheral blood in rabbits by
supravital staining in acute radiation injuries. Probl. gemat.
i Pere'. krovi 4 no, 10:19-22 0 159. (MIRA 13:8)
(x RLYS-PHYSIOLOGICAL EFI,'ECT) (LEUKOCYTES)
GUBIN, V.A. (Moskva, D-182, Mal.Shchukinskaya u1., 15, kv-32)
In vitro cultivation of bone marrow and spleen of rabbits irradiated
with roentgen rays. Arkh.anat.gist.i embr. 39 no.11:3-10 N 160.
(MIRA 14:5)
1. Ministerstvo zdravookhraneniya SSSR (nauchnyy rukavoUte'll -
deystvitelinyy chlen AM WSR of, N.A.Krayevskiy) .
(14ARROW) (SPN;NF (RADIATION--PHM31OLOGICAL MECT)
L 03781-67 EWT(m) (Z
C C - - N R_ i -A- T -6-0-2 - 9__ 6__ 1 -9 SOURCE COD%s UR/0000/66/000/0 AF001-5010-1-5-7-
AUTHORs Volokbovaq N. A.; Gubib V, A, Dareasks as No G,; Kozoovs,
L. B.1 raof-choultia. V. 1.1 Nevskara-.-G-6 F.1 Sedow, V,-V,
ORGI none
TITLZI Peculiarities of clinical manifestations of radlatlo~901ckuees
in theses monkeys during asma&-ray Irrad lation.L
SOURCII Voprosy obahchey radisbielogiL (Problems of SoAarat radio-
biology). Moscow, Atomisdat, 1966, 150-157
TOPIC TAGSt -radiat;oq biologic effect, nonk&T, dog,,Lrdialatioa
ABSTRACTs A comprehensive clinical examination of ganna-irradiated
,:onkays was conducted, and the data were compared with results of sizilor-,
xaminations of dogs. Seventeen sonkoys (Hacaca rheaus) of both 9 zes#~'
weighing 2.0 to 4.0 kg, were subjected to game Irradiation from a:
EGO-2 apparatus with a dose rate of 357-313 r/sis, Prior to Irradia
tion, all monkey@ had been under clinical observation for 2-3 weeksol
Eleven of the 14 monkey* irradiated with 300 r died (average duration
of life 16.5 days), while two of the 3 monkey@ irradiated with 350 r
died (29Le5 and 36.2 days after Irrediation)e Both groups of gauna-.
cmd I/1.
; ~ 4- NZ
I L
L 0,3781-67--
ACC NRi AT6029629
irradiated monkeys were considered together, since the clinical mani-
festatLona of radiation sickness were similar in both groups. Experi-
mental data were compared with data from analogous dog experiments,
using a 300-r dose of gamma rays, and no essential differences in the
radiation affect were noted between the two species. However, the
spread of life duration& in monkeys (6.5-36.2 days) was wider than fo
dogs (11.5-18.5 days), The primary reaction to radiation was more
pronounced and developed more rapidly In monkeys than In doRse The
primary radiation reaction was absent In 2 out of 17 monkeys, as com-
pared with 18 out of 28 dogs. Furthermoreo seven monkeys experienced
severe primary radiation reactions, while none of the dogs did. In the
first 10-11 days after irradiation, no essential differences were
noted between the temperature reactions of monkeys and dogs. However,
by the time of death dogs had elevated body temperatures (average 1.5C
above normal), whereas monkeys' temperatures had fallen considerably
below normal. Symptoms of radiation sickness appeared later (15-18
days after Irradiation) and developed more gradually in monkeys than in
dogs (7-12 days). Autonomic dysfunction to considered responsible
for the lability of symptoms In monkeys in the early postradiation
period. This hypothesis is substantiated* by the considerable varls-
tLons in blood pressure, the unstable heart rhythm. etc. HematopoletLe
changes in monkeys in response to radiation had a phase character,
demonstrating the different course of the radiation reaction In diffem
2/3
L 03781-67
AT6029629
types of calls. Since blood regeneration occurred even in monkeys
dying after 30-36 days, it was concluded that blood changes were-not
the primary factor in animal deaths. The lower lethal dose values
encountered in these experiments are partially explained by differing
experimental conditions, but require further study, Orig. art# hast
2 figures and 1--table. [is)
SUB CODII 061. SUBM DATEs 23Apr66/ ORIG REY: 0081 OTH RIFt 006
ATD PREM uvcf~
Card 3 / 3
RCONSUKOV. Mikhail Gavrilovich; GUBIN, V.A., inzh.. rotsenzent; BUDAFOSEVI,
S.S., inzh., retsenzent; OSIPOV, V.D., red.; GORYUNOVA, L,K.,
red.izd-va; IKOFSMSHM, A.S., takhn.red.
[Mechanizing the felling and the division of timber] Makhani-
zataiia valki i razvedki lose. Moskva, Goolesbum12dat. 1960.
138 P. (MIRA 13:7)
(&iumboring)
I , I . : 1,-! 1 , ; - - "rr"p: z,! tim !:,f t, I I-,,: -
T . . . ! -, I I' I I - I ~ , - , , , , , - - - -- , - , ..,
MBIN, V. A.
25881
Vliyanto vremennago otsuistviya matki na medosbor (C. primech. red) Pchelovodetvo,,
1949, No. 8, a. 13-17.
SO: Letoptal No. 34
- I . I - I~~ I IAl ` t. ~ i z . . I ~ ! 1. . 10 - . I - I
;j 1 :1 ;T ; . ~ ti " ~ I - - - - - 1 1 1 j ~ : : ,
1. V. A. GUBIN
2. USSit (600)
4. Bee Culture
7. Can the departure of natural swarm be hastenedi Pctieiovodstvo 29 no. 12.
1952.
9. Monthl List of Russian Accessions, Library of Congress, April 1953, Uncl.
MITHIN, V. A.
,Microscope and ',microscopy
Box for measuring the proboscis and other parts of bees' bodies. Pchelovodstvo 30, No. 2,
1953.
Monthly List of Russian Accessions, Library of Congress, J= 1953. Unclassified.
OSR/Fam., i'mii-mls - Honey Boo Q- 7
Abs Jour Rof Zhur - Biol., No 6,1958, No 26255
Author
Inst Not Given
Title z On the Shnrpnoss of the Sense of Smoll in YLallifcrous Boon
(0 tonlcosti obonynniye u r-edonospykh pchol)
Orig Pub : Pcl-clovodstvol 1957, No 7, 17-19
Abstract : It was established oxperivontrlly that boos acqunintod with
-.-dxod snoll are erpeble of dictinguishing molls of the
ooparato components of the r2.ixturo.
Cnrd 1 1/1
'5-y
KHA IFKAN, I.; GUBIN, V..A.
Aleksandr Fedorovich Chbin. Moskva, 1958. 37 P. (MIRA 13:8)
Oubin. Aleksandr Fedorovich)
GUBB, Vadim Aleksandrovich; ZUBKOVp M.A., otv. red.; SHEXCHENKO, G.N.p
~ ~ - I- -tekbh* red*- - ' - -
[School apiary] ShkolInaia. paseka. Moskva, Gos. iad-vo detskoi lit-
ry M-va proov. RSFSR, 1960. 109 p. WU 3-4:7)
(Bee culture-Study and teaching)
GUHN, V.I., vaterinarnyy vrach.
O"HWOWUMORMi
Therapeutic utilization of the milkin machine. Voterinariia )0
no.9:51 s '53. (KLHA 6:8)
1. Mksperimentalluaya baza ordena Lenin& sellskokhozyaystyannoy
skademii imeni X.A. Timiryazeya.
V.I., otv. red.; KO;',Alj', M., red.
[Numerical methods of
synoptic meteorology]
voprosy sinopticheskoi
"Nauka" UzSSR, 1964.
weather forecasting and problems of
Chislennye me tody prognoza pogody i
meteorologii. Tashkent, Izd-vo
100 (MitA 18:1)
1. Akadeniya nauk Uzbekskoy SSR, Tashkent. Institut mate-
matiki. 2. Chlon-korrespondent AN Uzbekskoy SSR (for Gubin).
GUBIN,V.I., kandidat tekhnicheskikh nauk
Now woolen fabrics. Tekst.prom.15 no.8:12-17 Ag'55- (NW 8:11)
1. Direktor TSentrallnogo Nauchno-ineledovatellskogo institute,
shersti
(Voolen and worsted mmufacture)
GUBIN, V.I., kandidat tekhnicheakikh nauk; GUSEV, V.Ye., kandidat tekhiche-
nauk.
Reorganization of spinning In the cloth industry. Tekst.prom. 16
no.1:34-37 Ja 156. (MIRA 9:4)
l.Direktor TSentrallnego nauchn*-imaledevatel'skege instituta
shersti (for Gubin)o
(Woolen and worsted spinning)
HLRGULIS, Te.M., insh.; GUBIN, V.L. inih.; Y=NGUW7. T.To.
Achievements of mine builders In shaft sinidag in
Dshezkazgan. Shakht.etrol. 4 no.9:18-20 S 160.
OUAL 13: 8)
1. Dshesimsganskoys shafttoppokhodcheekoys upravlonlys
tresta, Stalinshakhtoprokbodia (for Nargulls). 2. Institut
gornogo del& Aiademli nauk lasSSIL (for Oubin. Tesengulov).
(fthaskazSm-Shaft sinkIM)
BAKAYEV, M.T.; GUBIN, V.I.
Evaluation-of methods of mining ore In the Dzhezkaagan Nine.
Trudy Inst. gor. dela kN Kazakh. =R 10&67-74 163. (KMA 160)
(Dzhezkazgan District-Mining engineering)
UBE;, V. 1.
Gubin, V. I. and 'Nosenko, B. M. "On the thtory of the Ha-,I)el
effect," Trudy Flz,-teklin. in-ta (Akad. nauk Uz'~)ak SSR),
Vol. II, Issue 2, 19119, P. 45-49
SO: U-5241, 17 Deceriber 1953, (LaLonis t1iurnal livkh Ao. 2~.),11;61 .))
~ :I ; f : r ~! - 'I . I -,!I t f ; , - I j- 11 1 : ! I i
GTJBIN, V. I.
One method of precalculation of advective changes of temperature and
pressure. Trudy Inst.mat. I makh. AN Us.SSR no.12:91-96 153.
(Weather forecasting) (KLPA 8:1)
SOV '/124 - 57--8--q 147
Translation from: Referativnyy zhurnal, Mekhanika, 1957, Nr 8, p 82 (USSR)
AUTHOR: Gubin, V.I.
TITLE- On the Vertical Wind Shear (0 sdvige vetra s vvsotoy)
PERIODICAL- V kn, : Meteorol. i gidrol. .- (Jzbek-!stane, Tdshkert,, AN UzSSR,
1955, pp 111-120
ABSTRACT: The author examines the system cf different'.al equations c.-A, a
frictionless atmosphere
du dv -a a P
a W, T 9
d t 8X dt K
T C
Here u, v, and w are the components of the wind-,.elcc:1Ly vector alcng
the x, y, and z axes, respectively-, pis the pressure and a the spec-i-
fic volume of the atmospheric air; g is the acceleration due to the
force of gravity; f :=I
.9 =2 w sin (~ , L , cos tD , where rD 'Is the
geographic latitude of a point; and w is the angular velocity of the
rotation of the Earth. Upon transsforrnat;nn and e--.-aluatlon of the
orders of magnitude of the terms system (1) reduces to the iollew,".nig
Card 1/?. form:
On the Vertical Wind Shear
d au r) v (CL , P)
TF -5-z -5-z xz
where
(a , P) aa aa ap
'j:.~ aa 71-.x
xz
SOV/124 571 8 -4147
d av+ u = (CL , p)
-d-t -5-z -5-z YZ
a a P 22
and (a , p)L 2(L
YZ ov i)z az ~) Y
(2)
System (2) affords an approximate determination of the verticai wind shear-,
wherein in a first approximation the problem is considered to be stationar .1-,
Some qualitative deductions are made. The p.,per contains lypegraph1cal errors.
Sh.. A.. Musave: y,Iv
Card 212
S 0 V1 124-57-7-8036
Translation from: Referativnyy zhurnal. Mekhanika, 1957, Nr 7, p 85 (USSR)
AUTHOR: Gubin, V. 1.
TITLE: Frontogenesis and Pressure Changes (Frontogenez i izmeneniye
davleniya)
PERIODICAL: Dokl. AN UzSSR, 1955, Nr 12, pp 3-6
ABSTRACT: The author examines the relationship between frontogenetic condi-
tions and the variation with time in the elevation of a constant.- pressure
surf-ace. The vorticity equation, written in tern-is of a system of inde--
pendent variables x , y , 1) and t (p being the. pressure) is eni-
ployed in the form:
d (Q - VT) (K2 - V )dT =0
-Ut dt
wherein 0 is the vorticity vector, T the temperature,. and t the
time. The vorticity components along the axes x and y and with re-
spect to the pressure p are assumed, respectively, to have the forms
Card 1/2 0 A(b 1. 1Q = R 0 T Q ~. R JT
x TP 7, y 'P ~y
Frontogenesis and Pressure Changes
SO V / i2z.-57- 7-8036
wherein (D is the geopotential, I the Coriolis parameter, and R the gas constant.
Whence the author arrives at the followina equ2tion:
RT RT
V . V A(D- - (F' 4- 2F") + T + I-T (3)
t pT p p2T p
Here T=dp/dt and -y= dl /dt, and the expressions
F1 = I V T -V dT and F" -L V T - V v V T (4)
TV I I Ct TV I I
(wherein TV = I VIT I and VIis the horizontal Hamilton operator) characterize
an individual frontogcnesis defined as the degree of variation with time in the modulus
of the horizontal temperature gradient. By using equation (3) the author is able to
elucidate qualitatively the relationship between the conditions that lead to a variation
in the elevation of a constant- pressure surface and the conditions of frontogenesis.
V. V. B ykov
Card 2 /Z
GUBIN.V. 1.
Determining wind velocity on the basis of a pressure field.
Trudy Inst.mat.1 nekh"N U%.SSR no.14:3-10 155. (NIU 8:8)
(Winds) (Atmospberic preevure)
124-57-1-698
Translation from: Referativnyy zhurnal, Mekhanika, 1957, Nr 1. p 90 (USSR)
AUTHOR: Gubin, V.I.
TITLE: To a Theory of Local Frontogenesis (K teorii lokal'nogo
frontogeneza)
PERIODICAL: Tr- In-ta matem. i mekhan. AN UzSSR, 1955, Nr 14,
pp ll-Z6
ABSTRACT: A rhathematical "local frontogenesis index" is proposed, as
follows a' 'VT ~~;rt - abVT 8t
T - b 'Ve) (1)
IT e
VTt VTt vet at
where is the density of the air, IV T is the temperature
gradient, 76 is the pressure gradient at the 700-
Card I /Z millibar surface, and a and b are nearly constant quantities
124-57-1-698
To a Theory of Local Frontogenesis
The aboveintroduced index reveals that a full analysis of local frontogenetic
conditions can be performed geometrically by means of an investigation of
the particularities of the isallothermic and isallobaric fields, also the struc-
ture of the temperature and pressure fields of the lower half of the tropo-
sphere. The index (P also affords a means - after some relatively simple
transformations of Equation (1) - to identify mathematically conditions of
frontogenesis (d) > 0) and frontolysis ((P < 0) in any area from the initial
temperature- pre' ssure field of the troposphere.
N. 1. Zverev
1. Meteorology--Mathematical analysis 2. Weather forecasl.,ing--Troposphere
effects--Theory
Card 2 /Z
SOV/124-58-1-841
T;-anslation from: Referativnyy zhurnal, Mekhanika, 1958, Nr 1, p 110 (USSR)
AUTHOR: Gubin, V.I.
TITLE: -__0n Variations of Some Meteorological Elements Witnin Frontal
Zones (Ob izmenenii nekotorykh mete o rologiche ski kh elementov
vnutri frontallnykh zon)
PERIODICAL: Izv. AN UzSSR, ser. fiz. -matem. n. , 1957, Nr 1. pp 53-73
ABSTRACT: In order to determine the vertical currents, as well as the varia-
tions of the temperature and geopotential height of cons tant-pre s sure
surfaces, the author starts from the vorticity equation written in the
p system:
d ( 92 - V T) (JQ V ) dT
(Tt- dt
where Q is the absolute vorticity, T the temperature, V the
Hamilton operator in the p system, and t the time. The nongeo-
strophic corrections in the horizontal wind-velocity vector component
Card 1/3 are accounted for only in the heat-advection equation
SOV/124-58-1-841
On Variations of Some Meteorological Elements Within Frontal Zones
dT RT y Q T
- = a
dt 9 P C
(2)
where q is the heat advected in one second to a unit mass 'Y is the adiabatic
lapse rate, p is the pressure, g is the acceleration due to the force of gravity,
is the specific heat at constant pressure, and R is the gas constant. Equation
(CF) in the geostrophic approximation is written in the form
a -D - Lk ( a T ~T-' + ~n t z LT 'IT 0, As + 1 (3)
') t 6p
C
P ax ax, ay ay P
where
A= 2 2 (A, B) 8A 8B aA aB
X2 + ~-
Y2 ax ay ay ax
0 is the geopotential, and I is the Coriolis parameter. From equations (2)
and (3) the author, upon enlisting the equation of static equilibrium
Card 2/3
aO RT
ap P
SOV/124-58-1-841
On Variations of Some Meteorological Elements Within Frontal Zones
determines 8 0/ at aT/8t , and T first in the geostrophic approxima
tion and then, in order to account for the nongeostrophic correction, he employs the
horizontal components of the wind-velocity vector, u and v, in the heat-advection
equation, to obtain the expressions:
I ID 1 2 1 2
72 [ " + ('D'
u T -57y- 1 ) + T
ax at T _FX_ ax ap
I az4D 82
V _~ I ( 'D , at T -g-,)p
I CIX -L,2
ay at T Dy y C
1
Sh. A. Musayelyan
Card 3/3
GUBIN, V.I., ljoc phys vath Sci - (dir..,i) "on the problem
of the hydrodynamic theory of frontogenesis." Tashkent, Pub
doase of Acad Sci UzSSR, 1958, 12 pp (Acad 'ci UzSSR. ln!3t of
Mathematics and Mechanics im V.I. Pomanovskiy) 200 c-Aea
(KL, 27-58, 101)
- 1 -
GUBIN, V.I.
Numerical forecasting of the geopotential height of Isobaric surfaces.
Trudy Sred.-As.nauch.-isel.gidrometeor.inst. no.2:92-96 159.
(KIRA 13:6)
(Atmospheric pressure)
3(7),10(6)
AUTHORs Gubin,V.I. SOVI/10'6-59-3-6/11
TITLE: On the Calculation of Vertical Flows
PERIODICAL: Izvestiya Akademii nauk Uzbekskoy SSR, Seriya f1ziko-
matematicheskikh nauk, 1959, Nr 3t PP 39-46 lussn)
ABSTRACT: Since the immediate measurement of the vertical air flows
being essential for the weather forecast is unperformable,
they must be obtained from the hydro-thermodynamic equations.
The author establishes the corresponding system of differential
equations and completes it by roughly approximating boundary
conditions. For the solution of the system the author uses the
difference method and the electronic computer "Strela". As an
example the vertical flows in the time from November 14 to 18,
1954 are calculated.
There are 2 figures, and 4 references, 1 of which is Soviet,
2 American, and I English.
ASSOCIATION:Institut matematiki imeni V.I.Romanovskogo AN Uz SSR
(Mathematical Institute imeni V.I.Romanovskiy AS Uz SSR)
SUBMITTED: January 31, 1959
Card 1/1
S/049/59/000/03/01?/019
AUTHORS:-Gubin. zhordzhio, V. Petrosyants, M. A.
M"'"~oy,_ 9-.-N.
TITLE: Book Review
PERIODICAL: Izvestiya Akademii nauk SSSR, Seriya geofizicheskaya,
1959j Nr 3, pp 489-492 (USSR)
ABSTRAOT: The following book is reviewed: I. A. Kibell "Intro- jl~
duction to the Hydrodynamic Methods of 9hoF_-Period_J9aat&e-r,
Q'j- Forecastingil, The book originated as a course of,lectures
given Fy Tr-ofessor I. A. Kibell in 1955 to 1956 at the
Moscow State University. According to the reviewers, this
is the first real monograph embodying the whole field of
meteorology at the highest level, never before published
in the USSR.
Card 1/1
00 THE CALCUIATICK OF TKE KFASURE Of
FlOw=!XE5IS AT Av"FRAZE L:74M
(The theses at the Sysiposim L. Holoinkl)
1. An absolute derivation or 2oduius or logarUbA gra4iont teaporatum Is
"opted A. & fACtGP (,MaaxU- ) of frontogenesla. Th* factor (.... ") di.t,t-
but Character at this or the isobaric surfave wW at thu -rat* level as
solle'(W-500) "ko possible to"Judge about the deforsatLon 41~tlw of too
hviot frontal Ioa..
2. the s-hoaa; or the calculation of fmmogano~l. a--- at 1-1 AT-500
is gimn. ,, . applied for the *CCount = the Glactronic Th.
Calculation ..h. to based on to-l-led Model or atooophoM.
--'a on the electronic coaputer ~Str%W. The sash
.1th S,
rogim consisted t 371 unit- (ZW7)
I . 250 i. top.
A. Account axaaiples of rractoganools conlitions am given for so,aa Concrete
situation with the analysis of the generated results.
31"ort #Wml%ted for tbA ]al C*mssl A&soubty of tbo rmzl. Uniza of Cwodss7 Lod
Goopb"Ics, 1.14takI ,FI.Ud. n J.11 - 6 AlWait 196C.
PHASE I BOOK EXPLOITATION SOV/4349
Gubin, V. 1.
K gidrodinamicheakoy teorii frontogeneza (Hydrodynamic
Theory of Frontogenesis) Tashkent, Izd-vo AN Uzbekskoy
SSR, 1960. 141 p. Errata slip inserted. 1,000 copies
printed.
Sponsoring Agency: Akademiya nauk Uzbekskoy SSR. Institat
matematiki.
Ed.: V. A. Dzhordzhio, Doctor of Geographical Sciences; Ed.
of Publishing House: Ye. P. Yakovenko; Tech. Ed.: Z. P.
Gorlkovaya.
PURPOM This book is intended for specialists in the field
of dynamic and synoptic meteorology.
COVERAGE: The book deals with the theoretical foundations of
frontogenesis and frontolysis - the process of the forma-
tion and decay of frontal zones, particularly planetary
altitudinal frontal zones - on the basis of hydrothermody-
namic equations and the modern theory of the variation of
Gard_4i75_
Hydrodynamic Theory (Cont.) SOV/4349
pressure and other meteorological elements. The terms
proportional to frontogenesis are preserved, and their
complete analytic solution is given. Qualitative and
quantitative conditions favorable for frontogenesis are
discussed. Since frontogenesis cannot be considered
Isolated from other processes in the atmosphere, parti-
cularly cyclogenesis, an attempt to made to establish
the relationship between these two phenomena. The
quantities which characterize frontogenesis and cyclogen-
esis were calculated on an electronic computer of the
'NStrelan type. Some practical conclusions of a prelimi-
nary nature are made on the basis of an analysis of the
distribution of these quantities. The author states
that the problems of the jet stream, which should be in-
cluded In a complete theory of frontogenesis, are not
covered In this book since they require a separate thorough
investigatiori. The author thanks I. A. Kibel I, Corres-
ponding Member, Academy of Sciences USSR, for his advice.
There are 58 references: 39 Soviet, 16 English, and 3
German.
Ca.pd-2-/-5--
S/166/60/000/03/06/011
C111/C222
AUTHORS: Gubin, V.I. and Karimberdyyeva, S.
I
TITLE: Forecast of the Height AT - 700 With the Aid of the Electronic
Computer "Ural"
PERIODICALt Izvestiya Akademii nauk Uzbekskoy SSR, Seriya fiziko-matemati-
cheskikh nauk, 1960, No- 3, PP- 38 - 43
TEXT% The.authors consider a scheme for the\?
forecast of the geopotential
height 700 mb of the isobaric surface with the aid of the electronic computer
"Umal" of the.R"earch Center of the Institute of Mathematics AS Uz SSR. The
barotropic atmospheric model is used. The comparison of the calculated and
the real.sinoptical situation for November 15, 1954 yields a partial
a greepent
t
There are 2 figures and 2,Soviet references.
ASSOCIATIONs Inatitut matematiki imeni V.I. Romanovskogo AN Uz SSR
(Institute of Mathematics imeni V.I. Romanovskiy AS Uz S01
SUBMITTEDt January 27, 196o
Card 1/1
S/044/62/OW/OC).9/037/069
A06OIA000
0
AUTHOR: Gubin, V. I.
TITLEt Evaluatingthe altitudes of isobaric surfaces for the two-layer
model of the atmosphere on the electronic computer "Ural"
PERIODICAL: Referativnyy zhurnal, MatematiRa, no..9, 1962, 21, abstract'gV109
(In collection: "Materialy Soveshchaniya Koordinats. komfs* ' po
chisl. metodam prognoza". Leningrad, Gidrometeoizdat, ig6i, 53
54)
TEXT: The paper describes some results of computations carriedout ac-
cording to a numerical method elaborated by the author, for-forecasting the geo
potential for a two-layer model of the atmosphere. The forecast is given by
time-steps. At each step three requisite functions of the variables x, y am
determined by solving the Poisson equition for each of them. The Poisson equa-
tion is solved "locally" for the neighborhood of each point of the grid.
[Abstratter's notet Complete translation] S. L Belousov
Card 1/1
-) 3 G' 3
S / 16 9/ 6 1 / 0 0 0 /0 12 /0 6 Q / 0
D228/D305
AUTHOR-. Gubin,- V.--,-I,
TITLE: The equation describing intense frontal zrln-
I (~'- , ,
PERIODII04AL: Referativnyy zhurnal Geofiz1ka, no. 12, jr:
59, abstract 12B371 NzSSR Panlar Akad,.
dari, Dokl. AN UzSSR, 1961, no, 4, !:-14)
TEXT.! The equations of hydrothermodynamics for hi,gh froatfi-';.
zones with large temperature gradients are recordcd. in 'Llie.
x, y, p on the assumption of a quaoi-static atmosphere and
flat terrain. The equation of the vortex of velocity is recc~i-d,-~-d
in a geostrophic approximation, ageostrophic correcLiozis br-~Inlil
takent'intu'o account in the equation of heat inflow!
2 2 2
W, + I n (A)
r
Card 1/3
S / 16 9/ 6 1 /0 0 C/O
The equation describing,- V22SID30-,
where is the geopotential, V
R L T
n -- 1) p- is the quayltily ?,av i,ng Oie
12
and meaninp-, of the propagati.-Mal Speed of tkie
met~r~rcllol`c elements, and R j~v the ga,
B T T
, ( 4, ~- ) 1 T,
Z7 K
Y
Th.~~ recoi-ded equ:-itiono- are colkv-d undler
C-ard 2/3
S/ 169/6 1/000.101, 2/"-I-"E:9/:-!)-.
The equation describinIr.. D228/D3051,
diti~)n.~t in relation to The hyperbolic c-i"u%'Lion
2 2
I n R
+ 6f A + - B
2 2
is finally derived for defines the renjon f
L)
reasonnble solutions which lie within a characteri:;ti,I-- c o,-i
This r.,Leans that for an arbitrary height
t. is nececcsarv
take into account the influence on the observation.,,-tl.
only those sources which lie in a circle of r,`adiu~;
2 2
x
P (y _ Y')
,~-Abstracter's note;
Complete tranclation.2
Card
GUBIN, V.I., gornyy inah.
DetermWng the correction factor fdr establishing the sise
of pieces of broken ore. Gar. shur. no.12:54 D 162. (miRA i5m)
1. Institut gornogo dela AN Kazakbskoy M.
(Dshozkazan listrict-Ore harAling)
GUBINY V.I.
Equations describing intensive frontal zones. Tnidy Inst. mat.
AN Uz. SSR no.25sl-16 162. (Meteorology) (MIRA 16:8)
BAKAYEV, M.T.; G1,31ki, V.I.; SAPARGALIYEV, M.S.
Using straight cutB before drilling with a self-prope2lod
drilling ria. Trudy Inst. gor. dela AN Kaza~h.SSR 12:22-29
0
163. (MIRA 17:8)
-.7 5,7?
1 11 t f
ACC NRa AT6025881 SOURCE CODE: UR/0000/65/000/000/0048/0051
AUTHOR: Gubin, V. 1. (corresponding member AN UzSSR)
ORG: none
TITLE: A method of precalculatiod of horizontal components of wind in the atmosphere
S3URCE: AN UzSSR. Inatitut matematiki. Dinamicheskaya meteorologiya (Dynamic
meteorology). Tashkent, Izd-vo Nauka UzSSR# 1965, 48-51
TOPIC TAGS: wind, wind direction, wind velocity, wind profile
ABSTRACT. A simple method for precalculation of horizontal wind velocity components
in the atmosphere is described. In the method the inital horizontal velocity compon-
ents are used to calculate their future component values. Motion equations for the -
plane case are found and the future horizontal wind components are calculated from
the curl and the divergence of these equations by using finite time differences. All
of the above calculations can easily be performed by a computer. Orig. art. hast 18
formulas.-
SUB CODE: 04/ SUBM DATE: 14Det65/ ORIG REP: 002
ACC NR. Aj6'~j_58_8_2 SOURCE CODE: UR/0000/65/000/000/001'-2/0056
AUTHOR: Gubin, V. L(Correspanding member AN UzSM); TillyasbaYkhova, R-
ORG: none
TITLE: A graphical method for evaluating the success of precalculation of isobarid
surfaces
SOURCE: AN UzSSR. Inatitut matematiki. Dinamicheakaya meteorologiya (Dynamic
meteorology). Tashkent, Izd-vo Nauka UzSSR, 1965, 52-56
TOPIC TAGS: meteorology, j"& -1 chawed, weather forecasting, atmospheric
pressure
ABSTRACT: A graphical method for evaluating the accuracy of precalculated isobaric
surfaces is described. The accuracy of the precalculated isobaric surfaces is found
by plotting a difference field representing the difference between precalculated and
actual fields; a blank plot would indicate a perfect accuracy. The accuracy of a
precalculated prognosis for a two-level geopotential field is considered as an example
The calculated geopotential field for the example given was obtained by solving the
theoretical equations by finite difference methods. Orig. art. has: 3 formulas and
3 figures.
SUB CODE: 04,12/ SUBM DATE: l4Dec65/ ORIG REF: 002
Card 1/1
------------
ACC NR, AT6025883 SOURCE CODEt UR/0000/65/000/000/0057/0064
AUTHOR. Gubin, V. I. (Corresponding member AN UzSSR); Til2yaahaykham) R.
ORG: none-_._______
TITLE: Use of Green's functions for hydrodynamic weather prognosis
SOURCE: AN UzSSR. Institut matematiki. Dinamicheskaya meteorologiya (Dynamic
meteorology). Tashkent, Izd-vo Nauka UzSSR, 1965, 57-64
TOPIC TAM weather forecasting, meteorology, Green function
ABSTRACT: An attempt is made to calculate the improper integral which is usually
neglected in Green's functions. A pressure prognosis, found by use of equations
developed by N. 1. Buleyev and G. 1. Marchuk, for a three-layer model of the atmos-...
phere is given by considering and neglecting the above improper integral. It in
seen that inclusion of the improper integral improves the correspondence between
prognostacized and factual fields by 0. Z. Height calculations of an isobaric sur-
face are given as an example. Orig. art. has:. 3 formulas.and 3 figures.
SUB CODE: 04/ SUBH DATE., 14Dec65/ ORIG,REF: 001
~ACC N'%: SOUR02 CODE. UR/0000/66/000/GW/0018/0026
XLMMYLS: Gubin (Corresponding member AN UzSSR); Tillyashaykhova, R.
ORG: none
.TITILE: Examples of forecasting the geopotontial field from afour-levol aTmospheria
model
SOURCE: AN UzSSR.~ Institut matematiki. Resheniye uravneniy gidrotermodinamiki
pri;,n.cnitellno k zadacham meteorologii (Solution of equations in hydrotfhermodyna m.'cs
applied to problems in meteorology) Tashkent, Izd-vo F21 UzSS11, 1966, 18-26
TOPIC TAGS: atmospheric"model, weather forecasting, weather map, atmospheric
geopotential, integral equation, isobar
jUSTRACT: The authors forecast pressure for a four-level atmosplieric model fromthe
equ~-'Wion of N. I. Buleyev and G. I. Marchuk (0 dinamike krapnomasshtabnykh
atnosfarnykh protsessov, Trudy Instituta. fiziki atmosfery, No. 2, X., Izd-vo L%l SSSR'
1958). The equation is used in the gom:
G2 A. dx' dy' d~'- ~-~G A dx'dy'Af.'
7F 2nig g r T
ACC NRt AT7002808
The influence functions have the formi
G. 2 Y-W .(in r) + a(in r)
+ 0 - 2a) o~- VIC e(72L (a, r) da
dG2.
or V
AT5()O, and AT300 were used as starting data. The
The surfaces AT850, AT7001
caiculatioa results are compared with the results obtained by the influence-function
mothod with a three-lovel atmospheric model. Estimates of the success factors show
thaz, the three-level model has a certain advantage over the four-level. It i's
fourA that ATa5o has the lowest correctnes3 *factors. Orig. ar~t. hast 6 for=las,
2 tables, and 2 maps.
Sua COZZ: 04, 12/ SUM DATFt .2&UY66/ ORIG REFz 003
Card 2/2
GUB 2b.14, inzhenor.
-
Proportion of stainless chromius-nickel steel smelted In vacuu
furnaces. Sbor. Inst. stall. no.35tZ83-289 156. (MLAA 100)
1. Xafedrs elektrometalluxT11,
(S%oelg ftainless-Testing) (Vacuum apparatus)
GUBIN, V.N.. inzh.; LOTCHMIKO, V.I., manhinist-instruktor
Wheal olip current relay. Blek. i tepl.tiaga 2 no.4:22-23
Ap '.~4& (KIRA 12:3)
(Electric relays) (Electric locomotives)
GUBIR. Y.N., inzhe (stantaiya Ilookovka, Omakayet doroga); MAL'TSR7,
S.S., mashinist elelctrovoza (stantsiya Mostrovka, Omakaya
doroga)
More information pertaining to the emergency circuits for
electric locomotives. BlekA tePI-tiags 3 no.11:41-42
N '59. (KMA 13:3)
Mectric locomotives)
V.11., inzh. (Vepo Hoskovka, Oaskaya doroga)
Means for extending the lifespan of antifrictional disks in
electric locomotives. Alsk.1 tepl.tiaga. 4 no.6:15-17 Je
16o. (MIRA 13:6)
Oilectrie locomotives) (Bearings (Machinery))
. 1:- 1 1 ~
~ I .'' :4
BOCRAROV, Yu.D., master komplekenoy brigady; STEPANOVICH, M.G., master
komplekanoy brigady;-rzl~IN, V.N., inzh.
How we organized periodic repair of electric locomotives. Blek.
i tepl. tiaga 4 no.11:1-6 N 160. (MIRA 13:12)
(Blectric,locomotives-Repairing)
I
GUBINI V.14., inzh.; BAMOV, N.A., inzh.
conclusiona deriVed from the-analysi.9 of the operation of IM-406
traction'motors. Elek. i tepl. tiaga 5 no.6:10-13 Je 161.
(MIRA 14:10)
1. Depo Moskovka Zapadno-Sibirskoy dorogi.
(ElectrIc railway motors)
GUBIN., V.N., inzhe
Radiator system for drying traction engines. Blek.i tepl.
tiaga 5 no.10:13-14 0 161. (MIR& 14:10)
1. LDkomotivnoye depo Moskovka Zapadno-Sibirskoy dorogi.
(Electric railway motors-Maintenance and repair)
(Drying apparatus)
GUBIN, V.S., inzb.
Automation of ball mille operating on wet roal. Energetik 9
no.2~.9-10 F 161. (MIRA 16!.7)
(Coal.) (Automatic-'rontrol)
0
1. !::~ I . , ~, : t ! !I p .. ! i, I III 'I I I ! V. q P i I . I I I ;~ I - 11 ,
GUBIN, V-V- ; MAKAROV, Tu.N.; AKSJNOV, B-Ye.
Mine testing of coal extraction by means of chain sau. Ugoll 35
no.11:27-30 11 1609 (K= 13:12)
1. Pechorekly nauchno-teeledovatellekly uVllzWy lustitut (for Ombin,
Makarow). 2a GlavzWy Inshemer shakhty No.1-2 "Mud"mer-Yu"
(for Akeenov). (Coal mines and mining) (Coql sliming machinery)
GdBINP V.V.
. I - of wall rock In mining coal with a wire line saw.
Vop. gor. davl. no.7327-34 161. (KRA 1W)
1. Sibirskly metallurgicheskiy inatitut.