SCIENTIFIC ABSTRACT MATEROVA, YE.A. - MATES, F.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001032820014-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 14, 2000
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

"The
ory of the Glass Electrode. IV. Experimental
Verification of the Exchange Nature of the Glass
Palectrode Poteatial," B. P. Nikoll.skiy, Ye. A.
HAterova, L!;Dningrad State V imeni. A. A. Zh4Anov
."Z,hur Fiz.MAe' Vol XXV, No 11, PP 1335.-1346
:~~Uvestigoted interaction of glass powders of
dt (no 11 boron gl
~~Jiiiatro $lags ass (56 2), and.-
kiiss No 23 L "Druzhnays Gorka" (contg s=LU amtj,,"~
Fe, Mg
K, oxides) vith &4 'zorins coutg jail
Bal,.i=,.-,b_v ,potentiometric methodj,L ~ -By:
metbod, investi gated 'Absoj*40n. Of

HATBWVA, YO.A.; YWHINA, S.B.: TSUBINA, Ye. I.
Cation exchange on synthetic resins. Part 1. Acidic properties of
ion exchanging resize having various active groups. Uch.z&p.I-8n.1m.
163:93-111 153. (mLRA 9:6)
(Resins, Synthetic) (Ion exchange)

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Ye,"BILYUSTIN, A.A.
Production of rubidium and cesium glass** and Investigation of some
of their properties. Dokl. AIT SSSR 113 to.4t824-827 AV 157.
(KWA IOW
1. lenbgradekiy gosudarstvanM unlyersitet Is, A#A. Rdsmaya.
Prodstarleno almdemikom A,N, TerenTwo,
(Glass) (Rubidium) (Cesium)

/~ / '- - '_-' ~^ ( j /-7' /_ //
AUTHOR- MOMMEEV'rV.V.., MAMOVA,E.A., BELMTIM,A.A. PA -- 2763
TITLE: The Production o7 _Riibidium and Cesium Glasses and IzYT~.,stagation of
Sow of their Properties. (Polucb-"nVe I isaledo-7aniye nekotor7kh
rsvoyst-7 rubidiy,--,97kh i taeziye-rvkJ,. stekol, RuBsian)
FERIODICAL- Doklady Akad~.mii N9.7A SSSR, 1957~ Vol 113, Nr 4. pp 824-827 (U.S.S.R.)
Received: 6 / 4957 Reviewed; 7 / 1957
ABSTRACT: The mtuly of composed ail-toate glasges in which the only &1kaline ocm--
ponent is rubidi-m of cesium makes it possible to acquire ntew knowledge
concerning the infl-iijroe emeroised by a3k&lint ions on the proper-tists
of glasso v0hich is- of importance far the productiam of glass electrodez.
Above all, the interaction between glass and solution o&n be studied.
This interaction leadw -to the potential difference between glass and
solution which is a result of the ion exchange between glass a-ud tLe
solution. Tha produotion of rabidium and oellium glass is df.ffiolclt
cause these aystem are difficalt to melt (1600 - 16,roo C). In electrode
glass vdth hydrogen function scoatimes small additions of theme metalA
are usod (2--At. as they pvevent *odium ions from penetrat;ng into thj!t
glansp by whioh the alkaline err-or of the glass electrode is diminished.
After initial. diffiaaltiea the authors were able to melt 2 types of
rubidium glassr the data of whil-oh are given In fom. of a table. How-
ever, they wera still very Synthetization was finally carried
out of rubidium and oeal-,im glaaa. 60% SiO2D 20% B PY' 15% R-20"
Card 1/2

PA -- 2763
The Production of Rubidium aM Cesium Glasses and Investigacior of
Some of thair Propsrtio~s.
9 10% B i-% R20, 2% U90 and
% M90, 31,C GeO al"I 50% Si021 12-03,
3% CaD, whar-t R.;~O ~ Rt>,)O. Alzo wi*j 21, B,,,0 it is possible to
auce glasa of All types of glaas proiuoed
ratmot 3-ight cor,51degaMV ",tre). When oomparing
oharaoterizdng chemical cawcinul~yv ive fiiA that, in the c4lbe of a
Idgh oontent Of B20.3 sodl,=- ar-d potaxg-lum glasees am of approe-
mately equttl -,~wjtanay. The :c-eaulta obtained have only qualitative
oharaoter aA the measuring err-or amun-~,--d to about 25%.
(I IlluBtxutior- 2 Tal,.-Le6i, 4 CitatiOns fr-am Slav Publicationz).
ASSOCIATION: Leningrad S-cate Univenity "A.A.ZHDANOV"
FFSMENM BM A.N.TEMIN, member of the AoadenW
SURKITTED: ig.ii.56
AVAILABLEt Libmr-y of Congress
Card 2,/2

C) V# 1 4 /IfI,
418 Cal Chenistry '4tics, CombuBtion, MWlosions, Topo-
713 ~chenistry, Oats,17sis. B-9
AbsJour: Referat. 23mirml ftini7a, No 3, 1958, 7248-
Author Ye. A. Wterova' N.G. Elyukins.
Inst qOW-State University.
Title of Cats3,vtic. Activity of Alumosi3lcate Catalysts
On Their~Rxihmge Capability'and Stractmv.
Orig Pab: Uch.- zap. - IMi 1957, No 211, 179-187 -
Abstract:' fte napitudes of t3w exchange m]*billty,(determined by the
fjLftL (&teZ=jZsd V
of Be Ions),,_ specific ~sw y the
::_aAsmVtIon of wtbylene~blue), porosityl:,~ the I rtmvesLof
-and toluene sor M), catalytic S&tiVity (deternined
steam ytii
tae cracking of solar at 50 and 4750Y' ra 07 g3AUemite
(I), clay (T-I)j, famdry lom (III), MukbovskLy kab3in kIV) and
art1f1cia3 per=t;ite M preliminarily treated vith 0.1 n. solu-
tien of EC1 and of the 41-113 trial catalysts of Omdri iple t=ms-
Card 1/2 -30-

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(C",,.

5(4) SOV/76-33-4-22/3'2
AUTHORS: Materova, Ye. A., Hoiseyev, V. V., Shmitt-Fogelevich, S. P.
TITLE: Comparative Study of the Electrodic and Exchange Properties
of Glass Electrodesby the Use of Radioactive Indicators
(Sravnitellnoye issledovaniye elektrodnykh i obmennykh svoystv
steklyannogo elektroda a primeneniyem radioaktivnykh indikato-
rov).LBehavior of Sodium Glass Electrode in Solutions of
Silver Nitrate (I. Povedeniye natriyevogo steklyannogo elektroda
v rastvorakh azotnokislogo serebra)
PERIODICAL: Zhurnal fizicheskoy khimii, 1959, Vol 33, Nr 4, PP 893-902
(USSR)
ABSTRACT: With referenceto various data found in publications concerning
the behavior of glass electrodes (Refs 1-12) it may be assumed
that owing to the similarity of the ion radii of sodium and
silver, the sodium glass electrode (GE) may be easily con-
verted to the function of a silver electrode. In the work under
review, the authors measured on the one hand th6 quantity of
silver ions absorbed by the sodium glass as a function of
time, and on the other hand they investigated the process of
the passage of (GE) to the function of a silver electrode.
Card 1/3 Three different galvanic cells were applied. The glass electrode

SOV/76-33-4-22/32
Comparative Study of the Electrodic and Exchange Properties of Glass Electrodes
by the Use of Radioactive Indicators. I. Behavior of Sodium Glass Electrode
in Solutions of Silver Nitrate
(GE) was prepared from glass having the following composition:
sio - 71mol%, B 0 11 mol%, Al 0 L
2 2 3 - 2 3 - 3 m0'%, N20 - 15 mol%
(glass Nr 2 (Ref 3)), whereasthe metallic silver- and silver
chloride electrodes were prepared in the usual way (Ref 20).
The cation absorption through g1788 was d?termined radiometri-
cally by the aid of isotopes Agi and Na 4 (Ref 23) with an
aluminum P-counter (AS-2) on the instrument of the B type.
The spherical shaped (GE) were left 1 month in a 10% silver
nitrate solution, and the electromotive force (emf) was measur-
ed with tvo galvanic cells in 0.1 to 0.001 m AgNO 3- solution
(Table 1). The (GE) were found to behave like silver electrodes
as early as after 18 hours in A,-,I!O 3- solution. ExTeriments were
carried out with the (GE) in solution mixtures of AgNO + rla!!O3
and it -was observed that with a concentration ratio 'a A~+
1 : 1, the 'Ia-glass electrode acts like a silver electrode
(an approximate constant (e-mf) was ob ervV also by A. Y.
Card 2/3 11osevich on Na-Class electrodec in Na -Ag solution mi,_tures'.

SOV,/76-33-4-22/32
Comparative Study of the Electrodic and Exchange Properties of 11laaf_- gloctrcdes
by the Use of Radioactive Indicators. I. Behavior of Sodium Glass Electrode
in Solutions of Silver Nitrate
Radiation data showed that the absorption rate of Dn
(GE) surpasses conaidern~ly that sf Na-iov. The pnotant of
the exchange reaction Pla,l,,s + A9801 , Nasol + '.1ig glass was
computed according to an equation by B. P. ffikoll~kiy ~,Ref3 1,24)
(Table 2), and is in the order of magnitude of 10 , which+faci:
points to the conliderably higher solidity of the bond Ag lass,
as compared to Na glass. On the reaction of Glass with aqueous
salt solutions, the ion diffusion in the glass plays a major
role (Ref 25), rhich also applies to the present case (ri.-: 5).
In this connection, an initially rapid absorption of the
Ag-ionn takes place at the glass surface and this "silver
layer" diffuses into the glass (Figure 6 diagram of the Ag dis-
tribution in the glass). In conclusion, gratitude is expressed
to Professor B. P. Nikollskiy. There are 9 figures, 2 tables,
and 26 references, 12 of which are 3oviet.
ASSOCIATIOV: Leningradskiy gosudarstvennyy universitet im. A.A. Shdanova
(Leningrad State University imeni A. A. Zhdanov)
SUBIAITTED: October 1, 1957
Card 3/3

va-CrOzz." ove-cn-1ye P. 5d, i-ahZrad, 1959.
O~toyajyr; tm6,y Tret-y~,,a ~vucyazno~o sovesbehaniYO 1,ent"jr4d,
hoy-brx- 1959 (Vitr- St.t,; T-h-t-tiona Of t- 71,11d All-u-i- Con-
f.rIence on. the Vitrew. State, Held 1. 1959) M-cn,
17,14-ro AR SSSH, 1960. 534 P. Errata Up Inserted. 5,P00 copies printed. /J
(S-le%: Its: T-dy)
Spon-w--ins 4enclec: JOstitut Ithizill vlllkato~ Akxdi-il nnuk S=R. Vtceoyuznc7e
W-i-h..k.ye obshch~.t- lee-i D.I. Ycnd~I~Wcva and 0-d-t-nnyy
L._.._ orti he.kiy instittl ie.i S.I. V.,11.-
RdIto"al Bo--d: A.Z. A~CwtJnlk, VIP. r.mko-my, M.A. Dezbo,od-, 0-r. Dot~lnkl.,
V.T.Urbri., A.G. Vlasm, K.S. Ye-troy'y-, A.A. M.k. Keit-y-, V.S.
A.L. Y,,.Il,r, T~.k. C-4-Ith, N.A. Toropav, V.A.
ylcrl-4", A.K. Yo-k-likitul; Ed. of P.IILI~ht.a Ho-II: I.V. S-.mAr; Tech. Ed.:
V.T. 10cheeer.
FWU'07%., This b,"k 10 Intended for reararehe" In the oclence shd
CIA--
C06ERAZZ: The back contains the report* shd dle-siona of the Third All-Urdon,
C..f - - the Vltm~ StAte, held in tocniagmi on N-ber 16~19, 19~9.
T~~Y deal vith the methods and results of st~dyine Inc at-ture of Classes, the.
relsdics, bct~cn the tm t,.tre and P";,ertica Of 41-ce, the nature or the
cb-dral bond -a g,1-# st-ewre, -a the -y.talloch-l.ty of gl-., F%ucd
allica, e,echanism, Of 'Itrifictic'." optical prve rtien and glaab structure, ethd
the electrical properties of sla4nee am also diac-ed. A n=bcr or tho m-
Ports deal vlth the dependeace of glass properties On cwpoeltice, the tinting of
Cl"sea~ and radlatim effects, and x"henIce.1, technical, and chvelcal prarer-
Use of Cl-ca. Other papers treat Clove re-ilconductors atn4 soda borvall-1c,te
The Conference ~ attended by a- v- ~00 d,Icp,t.. rr- GO'I,t -a
T"t Ge- .,it.tific erg-t-tion.. ;tmong. t--,. partlIelp-tu 1. the &1.e-lon.
wrv N.V. Solw1h, Te. V. Xuvuhinzkjy, Ju.A. Gustry. V.P. Pryahishnlkov, Tu. I..
GIat-Ule. O.P. Mcb~4:1-?.trosyau, G.P. MIM.yl-, S.M. Ptr-' A.R. Lt-~' D.I.
A.V. Sbatil-, X.T. Flolhchi.~kly, A.?.. K=-,t-, E.V. Dog-tyArcra. DIV.
ly-urganovaIrm7a, A.A. Xalrnov, X~K. Skornyakone, F-Yw- b o~ln, E.K. Keller, Yn.A.
r-et-, V.P. Fmdvav, R.S. Sh-Iffivich, Z.G. Pla,k,r. -d O.S. Halton-
T~b r1wd session or the COhfvmnce Ints add-5ved by Professor III. Kithygorodmidy,
fi-It-d rcS..tI.t -d Engine-. Doctor or Technical Sciences. Tl!e roll-Ing
'catil.te- -e- cited fcr their to the d.-I.,,-..t of Class science
a=d technology: Cosuderstrennyy rtich"~j, I..-Itut (State Optical Institute),
lostItut Wile,I I silAkttov AJI SSFn (institute of SilienLe Cbmi. Iry, AS USSR).
11'"Icit..kly In'tit"t All SSSR (MAYALC4 Institute AS USSR), Fitilto-tekh"ch-itly
"'"tut JL.4 SSSR ("'by""tec"hicAl Institute kS US-SR), lostitut rlzlki All ?,SSR,
ft "t (I astItUte 0.1 rb"ics, Acad-y of Sciences, Bcl-~,Oyx SSR, K1.1k),
Latboratto,7 or Fbyoie.1 ch"Istry Or 5111-tOs Of t4e InOtIt"t obshch,y I neorgant-
tbea`kvY khlz!l AN B&SR, YJwk (Institate of Gesers-1 and laorg-le Chm,Ijst'Y,
A~2e'AY Of Sciences ftslo~zYayn S-111 Minsk), Inatitut rrsol,.=ojrkuIy%m'kb
%c7.dI ... iy An SS~:R(Ifttlt~te or High'K01-Iar Cmp~dA. AS USSR), GO-AAratven-
W" Inatitut -tekla (State InatIttite for Class), 0-Inrot-nrqy InattUt atek-
LC`oIO"-- (St^t- Inctttmte for Cl"s Fiber,a), Goaud-t-hyy Jaztitut *Icktrotet--
xdchoskogo otekla (State Institute for ElectrIcAl r1atk-
te,chnift-kuy 1-tit.t, T-k (SIL-1- Phyaltatochnieml MAtAtUtg, Tmftk),Ienjh&rs4.
.1 urdearsittt (I-l.Ara4 St.t. 11.1-ity), M-ko-ki, kbielk-
t't~thol.glentsltly inptltat (Mon- Institute of ChI-lcal TrthnOIO,~),t,vntn,-d*Yly
'.. k. -1
.' o,;Icheskly iwtit-it 12. I-O-ta (EcuI,.tm4 T-chnoloic.l Juatlt~t Imeni
Le,aaC-t), bcI*-tkJy POLIt-kbnI-k1j tafitlL~t Klark (Pel~xvl- rolytecartic
1-titut., Mi..k), X-cc-k--kly 1-t1tt (N--t-k-k
FO~!~-hhlc Ins%$tute), and 2-rdl-lty poll t,khnIchvAkiy Institut
rvV%1chnjc Ihitjt~te). Tne Chnf-ren- -5 y-or,d by t , Inntit,,La of Silicate
C--aIIItry t-1, U~ZR (JkItting Dir-to, . A ..q. I`I,,tllb), thA Vsc-y-Ore
I.. D.J. K-d'j~ye- Ch-l-l Society I.-i C1.1.
st,rnd,leyey). ~d t- rnAtUrvIt-Ay, nrl- Lent- opt1rh16~0Y thstit-If 1-1
9.3. V" 11- fst'te "Drl- of L-In" (pt-1 Imen, S.I. V-11").
Tkw 15 recluki"Al or t", to n
C"ter,~O,r th, I -1-T cf -rds-ting the to II&IIII, a h-
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pf.V. t.T. r-~IA-., Ji.r. -1
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vit"We state (Cont.)
Checticia Pr.irU.- Of 01--a-
Dubrovo, S.K. Comical Pro;crtles of Olas-o 418
Nikol-.Lly D.P. Yed,:..~.r-. -1 V.V. st~dl c!' the lqt-
' 'S M."_VrWSol.tl- by Mew.- of U. R'..4-LI_
ctlan of Eloct;v e
I.&U.tor Method 423
bero"U7, V.A., and T.S. Pubm~vkay- Cc the Cmpo~ltlm of tb.
8-f%- FU~ of C-L-Li- SIlI-', 428
kokorl", v.r. rffeet Of kik.,u t.-th m~t.l cxia~. on t?,. chumi
atabillty Of Glim"s 4p
Abr.-,Y", AN. Le-htnz of Fxts.-l Vitmv- 13~mlt. Vith Aqu~c- Add
6olutloo. and the State cr the OxAdea In thO stm~t_ of V_.It al~.a 435
Razelev, L.Ta. Vltrlflmtlcm md Fro;-t-eo or Dorate 437
C-d 18/22
vit-O.- State (C-t.) sov/5035
Betb.,Od", M.A., E.r. "t-, -4 V-5- On "1 11-11 Of Al-i.- 1.
Al-i-;~honptmt. GL-- 441
Bre)~C'Ocllh , S.N., .,I! Y.N. Fythool. ". '-v in
P-I~rtl- a.- Bar.$- 444
Di..-.Im 446
5CM M, CU3 SM=tS OF A SP7--IAL r~%WM
Scalcoad..t.r Gl-.e.
tolo.1yot., D.T. S-Ae-d.et.r GI-.e. 449
Wf.' V.A., I.V. P.tri-, and S.V. Pobero-Iya. Eleetri-I P-wrti- of
Scat Semiecd-t.r 0~ldo Gl-ez 454
Kolmiyets, t.T., JI.A. Gwr-, mnd V_r. ShIlo. Vlt~o,ft State to
Kolmlyets, B.7. cad P.T. Pawl- Optleal PrtTtrtJc3 of cb~l~qcewd_ al..-, 4,10
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VLt_o,. S.-te (Ccat.)
Kol-lyets, B.T., T.N. F~tmu, ~d T.F. K~-ova. El,~rlcul
Of Chleozmlde GZ-. 465
Vaywlin, A-A., and T-A. Poray-K-hll-..~ [Debtor of Phyul~ -1 J4:th-ticzj.
I-R.y DIff-tl- St~:jy or Vjt_- or t--~nj~ 470
R-ukfy, V.A. , -4 V.V. T-- St-t- -1 T-A-y L. Vltrlfl
of S.1fid- of C-;' V 1. t- P-111-1c of D.I. 4 ~'l
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1:57 ly 4 00 B02O/BO67
AUTHORS. Materova, Ye. A., Alagova, Z. S. 82088
TITLEt An Attempt of Using Membrane Electrodes in Hydrofluoric
Acid Solutions
PERIODICAL: Vestnik Leningradskogo universiteta. Seriya fiziki i
khimii, 1960, No. 3, pp. 80-64
TEXTt In the present paper the authors try to use membrane electrodes
consisting of ion exchanger resins to investigate HF-solutions. It is
known that electrodes consisting of cation exchanger resins give a
theoretical hydrogen function in acid solutions in a wide concentration
range; in fluoride solutions electrodes consisting of anion exchanger
resins show opposite behavior with respect to the V ion. Hence reasons
exist to assume that membrane electrodes in BF-solutions can be used for
measuring the pB and for determining the anion composition. The equili-
brium in EF-solutions was investigated by many authors, and it was found
that hydrofluoric acid dissociates according to the following sohemet
S/05A/60/000/003/008/021
Card 1/3 LK",

8 2 ""q 9
An Attempt of Uaing )Yembr an e t- rodes in 5/05 60/000/003/008/'02-1
Hydrofluoric Acid Solutions B020YB067
+ F- ; K (P- 11
I lit "F-JI \~-HF'
HF + F- = HF- ; K (a )Aa ar (2)
2 2 HFj RF
The methods of determining the quantities K 1 and K2 are given in the
monograph by I. G. RysB (Ref. 5). The authors determined the values of
these activitj coefficients at 15, 25 and 350C in a concentration range
from 0.001 to 1.0 M. To investigate the hydrogen function ip HF-solutions,
membrane electrodes consisting of sulfocationites CUC(SBS)*Iand KY -2
(KU-2)lwere used. The fluorine function was investigated by means of
;Iectr des made of the monofunctional anionite Af?-17(AV-17) and the
polyfunctional anionites 3,61 -101T (EDE-IOP), AH-2~ (AN-2F), and MMF -1
(MIG-1). The hydrogen function of the membrane electrodes was studied
in HF-solutions by means of the galvanic cells I and II. The pH values
measured for the e.m.f. of cells I and II and for those measured with
a hydrogen electrode are listed in Table 1, and graphically shown in
Fig. 1. The table shows that, in the concentration range investigated,
E1 remains constant with an accuracy of tI mv. Table 2 shows that
Card 2/3

An Attempt of Using Membrane Electrodes in B/054/60/000/003/008/021
Hydrofluoric Acid Solutions B020/BO67
62088
AE exp agrees with AE" theor with an accuracy of some millivolts in the
entire concentration range investigated which confirms the hypothesis of
the mixed function of membrane electrodes consisting of anion exchanger
resins in HF-solutions. There are I figure, 2 tables, and 9 referencesi
5 Soviet, 2 USA, I British, and 1 German.
L'ir
Card 3/3

8633t
S/054/60/000/004/005/0 15
BO04/BO56
AUTHOR:
TITLE: Ion Exchange and Electrodic Properties of Ion Exchangers
PERIODICAL: Vestnik Leningradskogo universiteta. Seriya fiziki i khimii,
1960, No. 4, pp. 26-39
TEXT: The present paper gives a report on research work carried out at the
kafedra fizicheskoy khimii Leningradskogo universiteta (Chair of Physical
Chemistry of Leningrad University) concerning the ion exchange and elec-
trodic properties of various ion exchangers. This work is based upon
B. P. Nikollskiyfe conceptions of the occurrence of potential on glass
films. For various types of cation exchangers, such as KY-2 (KU-2),
KMA(M), KOY(KFU), CBC(BBS), P(P(RF), MC45(MSF), P (R), and ~(F), the
exchange constants KNa-K' KNa-H' KNa-HN 9 KNa-Ca' KNa-Ba' KH-Ag' KB-Pb
4
were determined. The theory by K. R. Meyer, I. F. Sievers, and T. Teorell
(Refs. 12, 13) on membranes made from ion exchangers is discussed. The
preparation and study of membrane electrodes is explained. The resin
Card 1/3

86332
Ion Exchange and Electrodic Properties of Ion S/054/60/0&O/004/00"//O1 5
Exchangers B004/BO56
powder saturated with the ion is poured into the binding agent (poly-
styrene in toluene) dissolved in an organic solvent. The mass which is
thickened by heating is dried on a metal foil. It is then out into slices
which are glued onto a p6lystyrene tube by means of polystyrene dissolved
in toluene. The tube is filled with a 0.1 M electrolyte, and the reference
electrode is made of AgCl. The Na, K, Li, Ba, Ca, Ag, and NE functions
are determined for cation-exchanger, and the Cl, Br, and F fuActions,for
anion-exchanger. By means of a membrane-hydrogen electrode, the pH of acil
solutions, including HF, can be determined up to high concentrations. De-
termination of the cation function of a membrane electrode made from an
SBS sulfo-cation exchanger within certain ranges of concentration showed
that the function E = f(-Iog a +) is linear. At a high concentration
(more than 0.2 - 0-5 M) deviations from linearity occur due to the diffu-
sion of anions. Membrane-s with anion functions may be used in fluoride
solutions of up to 0.8 M, in chlorides, UP to 0.5 M, and in bromides, up
to 0.2 M. Deviations from linearity are here due to the diffusion of caticM
The more mobile the anion, the wider is the linear range of the function.
The electrodic properties of cation exchangers are compared with those of
glass electrodes, the similar nature of the ion exchange potential being
Card 2/3

86332
Ion Exchange and Electrod ic Properties of Ion S705-41/60/000/004 !D0_1/01
Exchangers B004/BO56
pointed out. The use of membrane electrodes for potentiometric titration is
then described. Further, the interactions between glasses and solutions
are studied by means of radioactive indicators. For the sodium glass elec-
trode, a direct interrelation between the potential of the glass and the
quantity of silver absorbed by the glass was disclosed by means of
110
Ag . Electrodes are now being developed, which are specially designed
for certain ions. M. M. Shullts and F. A. Belinskava are mentioned. There
are 9 figures, 4 tables, and 22 references: 17 Soviet, 1 US, 2 British,
1 German, and 1 Swiss.
Card 3/3

,zH&T]RDVA, Ye.A.; AIAGOVA. Z.S.
XxPeriment in using membrane eleetrides in hydrofluoric acid solutions.
Vest. IGU 15 no.16:80-84 160. (KM 13:8)
Mrdrofluoric acid) (Blectrodes)

< PAMO!&_LQJL--
11 -------
Ion-excbange and electrode properties of ionites [with s,,--ary
in Bnglish] - Vest. IM 13 no.22:26-39 160. (MIRA 13:11)
(Ion exchange)

68259
B/076/60/034/012/011/027
B02O/BO67
blo
AUTHORS: Materova, Ye. A, and Alagova, 2. S.
TITLE: Study of the Electrode Properties of knion-exch&nging
Membranea
PERIODICAL: Zhurn&7 fizioheekoy khimii, 1960, Vol. 34, Vo. Ii,
pp. 2752-2758
TEXT: The authors attempted to study the electrode propertiea of the
anion exchangers of different basicity and different chemical character in
halide solutions with special consideration of the chlorine-, bromine,
and fluorine functions of the anionite membranes. The electrode membranes
were produced from the resins AB -17 (AV-17),OAL., AG-16 (AV-16), _~A_i-101
(EIDE-10P), AN -2 ~ (AN-27) and MMf- -1 (HUG -1) . To study the chlorine f unc-
tion, electrodes were produced from resins saturated with chlorine ions.
The bromine electrode membranes and some fluorine electrodes were
produced from chlorine electrodes by introducing them into a 1.0 liar
or NaF solution. The remaining fluorine electrodes were produced from
resins which had been converted into the fluorine form. An AgCl-, AgBr-
Card 1/3

t I ~'Plp
58259
Study of the Electrode Properties of
Anion-exchanging Membranes
S/076,/60/034/012/01 1/027
B020/B067
and a sodium-glass electrode served as reference electrodes. The emf of
the current circuit with electrode membrane was measured by an ordinary
potentiometer. An amplifier with electrometric tube was connected to the
current circuit when using glass electrodes. The measuring accuracy was
0.2 - 0-5 mv. Usually, 10 to 12 electrodes of each resin were studied.
All experiments were made at room temperature. The results of measurement
of the membrane potentials with different galvanic cells are illustrated
in Figs. 1-3, by representing emf as a function of the negative logarithm of
the mean activity of the electrolyte. The figures on the axis of ordinates
refer to the lower curve. For better illustration each of the following
curves is displaced in upward direction by 40 MV as compared to the
preceding one. The membrane potentials measured by some galvanic cells
are given in Tables 1-4. The chlorine function of thp anion-exchanging
membranes was studied in KC1, NaCl and HC1 solutions. Fig. 1 shows that
the linear relation obtained between the potential and logarithm of the
mean activity of NaCl for all electrodes within the limits of measuring
errors holds in a concentration range of 0.005 to 0.5 M with the angular
coefficient of the straight line corresponding to the theoretical value.
The bromine function of the electrode membranes was studied in NaBr
Card 2/3

Study of the Electrode Properties of
Anion-exchanging Membranes
S/076/60/034/012/01 1/027
B020/BO67
solutions. As is shown by Fig. 2 a linear dependence of the electrode
potential on the logarithm of the mean activity of NaBr was obtained in
the concentration range of from 0.005 to 0-2 mole. The same holds for
the fluorine function in the concentration range from 0.05 to 0.8 mole.
There are 3 figures, 4 tables, and 12 references: 3 SovIet, 3 US, 4
British, 1 German, and I Indian.
ASSOCIATION: Leningradskiy gosudarstvennyy universitet im. A. A. Zhdanova
(Iteningrad State University imeni A. A.-Zhd&rcv)
SUBMITTED: March 19, 1959
Card 3/3

S/078/61/006/001/008/019
13017/BO54
AUTHORSs Materova, Ye. A., Rozhanakaya, T. I.
TITLEi Potentiometric and Ion-exchange Investigations of the State
of Boron in Fluoboric Acid Solutions
PERIODICAL; Zhurnal neorganicheakoy khimii, 1961, Vol. 6, No. 1,
pp. 177 - 181
TEXT: Tetrafluoboric acid solutions of different concentrations were
studiod by potentiometric titrations and anion exchange. Fig.1 shows the
potentiometric titration curves for 0.016, 0.13, and 0.11 molar
solutions. The curves show jumps suggesting the existence of various forms
of fluoborie acid. Tetrafluoboric and hydroxy fluoboric acids are
neutralized at pH - 2-5, hydroxy fluaborates are neutralized at pH - 6-8,
Table I gives the hydrolysis constants calculated on the basis of the
potentionetric titration curves. Figs.2 and 3 show the adsorption of the
boron ion from 0.13 molar solutions of HBF 4 on the anion exchanger
4A)-10ir (EDE-10p). Adsorption of the boron ion from tetrafluoboric
Card 1/2

Potentiometric and Ion-exchange Investigatilne S/078/61/006/001/008/019
of the State of Boron in Fluoborio Acid B017/BO54
Solutions
solutions is complete in the acid region. Adsorption of boron from tetra-
fluoboric acid solutions is 5.5 tines greater than from aqueous solutions.
Adsorption of boron on strovgly basic anion exchangers increases with the
addition of hydrofluoric said to the boron solutions to form fluoboric
acid complexes. N. V. Gortikova assisted in the experiments. There are
3 figures, 2 tabl*s, and 8 referencest 5 Soviet, 2 US, and 1 British.
ASSDCIkTIONs Leningradskiy gosudaretyennyy universitst, Kafedra
fizicheskoy khimii (Leningrad State University, DeDartment
of Physical Chemistry)
SUBMITTEDs October 8, 1959
Card 2/2

MATEROVA, Ye.A.; YUMIENKO, V.S.
Use of membrane electrodes mde of ion exchange resins for potenttzrwetrie
titration. Zhur,, anal. khim. 16 no. 4:388-394 J1-Ag 161a
(MIRA 14:7)
1. A.A. Zhdanov ningrad State University.
(Iop excbange resins) (Potentiometric analysis)

MATMWAV Ye.Ae; VALYUSHKO, M.G.; PARSHIKOVA, 16.ffla; YEVNINA, S.B.
Investigating borate solutions
JZU 16 no.10:1.25-1N 161#
(Boraten)
by the ion exchange
method. Vest.
(MIRA 14:5)
(Ion exchmWe)

ARKFANGELISKIY, 1J.. VOYEVODINA, A.A.; MATEROVA Y
Interaction of ion exchange resins with water. Vest LGU 16 no.22;
102-120 161. (M11A 24:11)
(Ion exchange resins) Nater vapor)

11' A.; BSLINSKAYA, F.A.
Electrode properties of ion exchange membranes. Usp.khim.
120 no-7:914-931 n 161. (MM 14:8)
1. Leningradskiy gosudarstvennyy universitet, kafedra
fizicheskoy khimii.
(Ion exchange) (Electromotive force)

HUMOVA, le.A*; MOMIEVv V.V.; BZMUSTIN,, A.A.
Capparative-study of the electrode and exchange properties of the
--gbws electrode by use of radioactive tracers. Part 2x Behavior of
the potassium glass electrode in jqlkj;li metal salt solutions. Zhur.fiz.
khime 35 no*6-61258-~264 Je 16le (MMA 14:7)
1. Leningradskiy goaudarstvennyy univervitet imeni A.A.Zhdanovae
(Electrodes., GlaBs) (Alkali metal salts)

MATERCYVA, E. A. [Materova, Ye. A.); BELINSKAIA, F. A. [Belinskaya, F. A.]
Electrode properties of the iron-Mhanging membranes. Analele
chimie 17 no.1:23-43 Ja-Mr 62.

CHERNOBROV, S.M., otv. red.; LASKORIN, B.N.j, red.; KLYACHKO, V.A.,
red:; MATEROVA,_Ie.A*,, red.; LANGE, A.Z.j red.; VITTIKH,
M.V red.; SAVENKO, O.D., red.;
ZYKOVA,, V.V.., red.; GIAZYRIWA, D.M., red.; ALFEROVA, P.F.,
tekhn, red.
[Theory and practice of ion exchange] Teoriia i praktika ion-
nogo obmena; trudy. Alma-Ata, Izd-vo AN Kaz.SSR, 1963. 186 p.
(MIRA 17:3)
1. Kazakhstanskoye reepublikanskoye nauclino-tekhnicheskaye so-
veshchaniye po ionnomu obmenu. 1962. (MIRA 17:3)

STEFANOVA, O.K.,- SHULITS, M.M.1 MATEROVA, Te.A.; NIKOLISKIY, B.P.
Electromotive force of galvanic cells vith ion exchange ;aeenbranes.
Vests LGU 18 no.4:93-98 163. (NMA 16-3)
MBetric batteries) (Electromotive force) (Ton exchange)

MkTEROVA, Ye.A..; RDZHANSKAYA, T.I.
Electrode properties of anion exchange membranes in alkaline
solutions.. Zhur. fiz. khim. 37 no.12:2668-2671 D 163.
(MIRA 17:1)
1. Leningradskiy gosudarstvennyy universitet.

STEFANOVA, O.K.; MATMVA, Ye.A.; NIKOLISKIYP B.P.
Ion-exchanRe and electrochemical properties of sulfo cation
exchmnRere in solutions of some 1-:1 charge electrolyUs,
Dokl. AN SSSA 150 no-3:604-607 Hy 163. (MIRA 16:6)
1. Laningradskiy gosudarstvenMy universitet im. A.A. Zbdanmm.
2. Cblen-korrespondent AN SSSR (for Nikollaldy).
(Ion exchanize)
(Electrolyte solutions)

NIKOLISKIY, B.F.; MATEROVA,, Ye.A.;'SkABICHEVSK-TY, P.A.
Ion exchange and the electrochemical properties of zirconyl
phosphates. Dokl. AN SSSR 152 no.6tl360-1362 0 063 jMMA 16:11)
1. Leningradskiy gosudarstvennyy universitet ir. A.A. Zhdanova.
2. Chlen-korrespondent AN SSSR Xfor NikolOskiy). I

ACMM(K RR: AAalft
S/OD5h/6k/OOD/0D2/OD65/ODT3
AVMOP: Haterova, Ye. A.; ftebicbevoklyp P* A.
7MIE: Ion ezebange properties of zirconyl j*o9phmtee Is Investigation of the
depw9ence of Lou exchange Prwertles of sftcmyl pbos*&t* an the conditions of
Its production@
SOMM3 Leningrade Universitato Vestnike Beriya fiziki: I WhIallp noe 2l 19640
65-T3
TMIC TAGS: zireMl pbosphatev I= exchange propertyp production conditionp
re ta
preparation method., titration cum, Ion exehmW cepacityj, drying p elpi tion
-:'i condition, component ratio
ASMM The offects of the precipitation conditions (concentrationsp acidityp
Zro IF '05 ratio 0 to" -preparation of alremyl phoopMte on its cois-
ratum) In the
W902; and Ion exam propertlen were studied. From the potentimetric Mrs-
t1m curm. of strecial pbompbates, which allfor In their ps a It was shown
that the Icim esobmp comity of airconyl pbosphal?m is a fmatim -of the saw'
campoidtim, 6amp1m bwwb* a vmJAr mtlo. of tT%ft2Q~ 101=1 cmder than IL bavo a
1/3

ACCEMC6 NR: AVA1635
snaller number or runctional strongly said ionogen grmips with a reduced ability
to dissociate and hence a lower ion exchange capacity. The conditions for obtain-
Ing zircozW1 pbosphate samples having maxIsm ion exchange capacity,, i.e.. Zr4)2/
]P,%Oq closest to I.' Include the use or freshly prepared zirconlun salt solutions
(8.6-0.5K) containing 4-5M 00,3 or BM, am 0*2-IN B.^. More concentrated zirconm
lum, solution or bigber acidity causes formation of a precipitate wbicb Is hard to
filter., The rate and order of pouring the solutions -does not affect the properties
of the precipitated zl:rcomyl pboapbate. Increasing the temperature of dr7ing the
zirconyl pbospbate precipitate up to 30DO has no effect on the lon exchange proper-
ties, but drying at higber teaqmratures (50D-85W) comes irreversible changes
(probably formation of -P-0-P- bonds) which sharply reduce the ion exchange capaci-'
ty of zirconyl pboapbstee "In conclusion the authors express their sincere
appreciation to M am szoociate r Be Ps filkol'sk for valuable advice in the
course of the work and In preparing the manuscript for printing*" Orig. arte has,.
5 figures*
ASSOC=M. flone
i stawymi ovia:763 ENCL: 00
Card 2/3

ACCESMON Iffl: AP4041836 8/0054/64/ODO/w2/OOT4/0083
AVXHOH: Haterwa, Ye. A.; Skabicheavokiyo P. A.
TITIE: Ion exchange properties of zirconyl phosphate. 11o Investigation of
exchange of a series of mono-and divalent cations for the zirconyl phosphate
hydrogen ions.
SOURCE: leningrad. Universitet. VestuA. Seriya fiziki I khimii, no. 2, 1964,,
74-83
TOPIC TAGS: zirconyl phosphatep ion exchange capacity, monovalent Ion sorption,,
divalent ion sorptiong zirconyl phosphate composition, phosphate content
AMRACT: The sorption by zirconyl phosphate of a series of mono- and divalent
Ions in a wide concentration range (0.02-1.0M for alka.1ij and 0.02-0.5M for
alkaline earth compounds) and in the pH range of 1-12 vas inveatieated to establish
a relationship between the sorption of these ions and 1%e zirconyl phosphate
composition. Samples of zirconyl phosphate having a wlar r tio of Z /P 0
a T02 5 of
1.07p 1.44 and 1.89 were usede The amDunt of sorption at the same p1l and Cc Sam
solution concentration depended on the tirconyl phosphate sample composition and
Card k 1/2

Acawicw NR: AM41-836
the nature and the charge of the ion. In samples low in phosphate the absorption
curves for the divalent Iona differ sharply from curves with samples vhere the
Iratio approaahes 1; the phosphate-poor samples do not have strongly acid phosphate
i groups. The sorption of divalent Ions decre&aed in the series: Cu 7Zn -.-Ba> Ca-.-Mg4
i The sorption of K) 'Nal U., Ca and Ba ions by zirconyl. phosphate having the ratio
approaching unity obey the principal equations of ion exchange. plotting the pH
vu. activity of the metallic ions in acid media gave a straight line vitb an incli-
nation near theoretical (cK = -1 for monovalenti, I for divalent Ions); at higher
I -2T
~pB there are deviations. In acid media the ex9hange constant for Ba" - Na-"z 8-1)
Ca pa 4
1for = 6.4. "In conclusion the authors express their sincere apprecia-
tion to AN SWR associate member Nikollsk B. P. for valuable information in the
course of the vork and for preparing the manuscript for publication." Orig. art*
has: 3 tables, 4 figme wA.6 equations.
ASSOGMIONt None
suBaTm: maj63 ENCL., 00
Stm C009: IC, GC NO RN owl 001 OTHER: ODT
Card 2/2

Acassion NR: Ar4o41836 8/0O54/64/00D/00?_/0D74/0DB3
AWHOR: Katerova,, Ye. A.; Skabicheevskiy.. P. A.
TITIE: Ion exchange properties of zirconyl phosphate, II, Investigation of
exchange of a series of mono-and divalent cations for the zirconyl phosphate
hydrogen ions.
SOURCE: laningrad. Univeraiteto Vestnik. Seriya fiziki I khimii, no. 2p 1964p
174-83
TOPIC TAGS: zirconyl phosphates ion exchange capacity, monovalent ion sorption,
divalent ion sorption, zirconyl phosphate composition, phosphate content
ABSTRACT: The sorption by zirconyl phosphate of a series of mono- and divalent
lone in a wide concentration range (0.02-1.014 for n1kn1i, and 0.02-0.5M for
aLkaline earth compounds) and In the pH range of 1-12 vao investigated to establish
a relationship between the sorption of these ions and the zirconyl phosphate
composition. Samples of zirconyl phosphate having a molar ratio of Zr02/F 0 of
1*QTp 1.44 and 1989 were used. The amount of sorption at the saw p11 wad 1rh9 cam
solution concentration depended on the zirconyl phosphate ample composition and
:Card

ACCESSION RR: AM41836
the nature and the charge of the ion. In samples low in phosphate the absorption
curves for the divalent ions differ sharply from curves with samples where the
!ratio approaches 1; the phosphate-poor samples do not have strongly acid phosphate
groups. The sorption of divalent ions decreased in the series: Cu -;,. Zn -,-Ba,> Ca-.- Mg#
The sorption of K, Na, IA j, Ca and Ba ions by zirconyl. phosphate having the ratio
japproaching, unity obey the principal equations of ion exchange: plotting the pH
vs. activity of the metallic ions in acid media gave a straight line with an incli-
nation near theoretical -1 for monovalent.. 4for divalent iona)j at higher
+
:pH there are deviatioun. In acid media the ex91=ge constant for Ba" - Va = 8.10
;for Ca jj& 4z 6.4. nIn conclusion the authors express their sincere apprecia-
Ition to AN SSGR associate member Ilikollsk B. P. for vUuable information in the
course of the work and for preparing the manuscript for publication." Orig. art,
has: 3 tablesp 4 figures and.6 equations.
ASSOCIATION: None
suBaTTED: ortay63 ENCL: 00
StM OODB-. IC, 'GC NO MW SOV: 001 OMER:
007
Cord 2/2

ACCESSION NR: AT4042426 8/0000/63/000/000/0075/0081
AUTHOR: Materova, Ye. A., Belinskaya, F. A., Militaina, E. A.
TITLE: Some of the electrochemical properties of ion exchange membranes
SOURCE: Respublikanskoye nauchno-teknicheskoye soveslichaniye po ionnomu obmenu.
Alma-Ata, 1962, Teoriya I praktika ionnogo obmena (Theory and practice of Ion exchange);
trudy* soveshchaniya. Alma-Ata, Izd-vo An KazSSR, 1963, 75-81
TOPIC TAGS: Ion exchange membrane, ion exchange resin, polymer film, electro-
chemistry, mernbrwie potential, resorcinol exchange resin, pH measurement, galvanic
cell
ABSTRACT: TI)e difference between tho inembrano potentials of various ion exchange
disphragms prepared form sulfocarboxyl resins, hydroxyl cation exchange resins, basic
anion exchange resins and some inorganic ionites was investigated at tho Ion excha~ngc
laboratoryof Leeningrad University. The membrances were prepared in the form of small
disks either by pressing a fine powder with polystyrene, polyethylene orpolymethylmetli'a-
crylate as the binders, or by molding a binder with the diBpersod powder of an exchange resin
-7-.1/2

IIt
ACCESSION NR: AT4042426
from an organic solvent. Technical ion exchange membranes prepared in the laboratory
of Ye. B. Trostyanskaya at 1AkhTI and at the NIIPM were also studied. The galvanic
cells AG I AgCl, M~Cl I ion exchange membrane I M++Cl, AgCl I Ag and Ag I AgCl,
M' Cl I ion exchanges membrane I M++Cl, sat'd. IM, 1192C12 1 lig were used
to measure the membrane potentials in a variety of electrolytes. Despite a relatively
low selectivity with respect, to hydrogen ions, membrane electrodes were found to match
the glass electrode in measuring pH in aggressive !media. Thus, a resoreinol cation
exchange resin was able to measure the pH of 0. 015 - 13.7 N HF. - Ile investigation
of Ion exchange resin membrane potentials shows them to be an important characteristic
ot the chemical and electrochemical properties of Ion-exchange materials. "Some of
the experimental data were obtained by A. Zub, P. Skabichevskiy and T. 1. Rozhanskaya!'
Orig. art. has: 6 figures, 1 table and 2 equations.
ASSOCIATION: Leningradsidy gosuniversitet im. A A. Zhdanova (Leningrad State
University)
SUBBUTTED: 13Nov63 ENCL: 00
MM CODE: )Q
NO REP BOV: 007 OTHER: 000
Card _?/2

~IATEROVA, 'JO.A.; SKABIC111ITSM, P.A. (1,3ningrad)
Electrochemical properties of zirconyl phosphate. Part 1. Zhur.
fiz. khim. 38 no.3:676-680 Vir 164. (MIRA 17:7)
1. Jeningradskiy gosudarstvennyy universitat imeni A.A. Zhd&nova.

"ACCESSION NR: A_P4034585 B/0076/64/038/004/0985/0989
,AUTHORS: Materovar Ye.A.; Skabichevskiy, P.A.
TITLE: Electrochemical properties of zirconyl phosphate, :1. Rela-
tionship between the electric conductivity of ziroonyl phosphate
samples and their composition.
SOURCE: Zhurnal fizicheskoy khimil, v. 38, no. 4, 1964, 985-989
TOPIC TAGS: zirconyl phosphate, composition, ZrO2 P20 ratio,
electrochemical property, ton exohawfcapaoity, eleNric conductivity,
.water sorption, zirconyl phosphate 1i orm, zirconyl phosphate Na+
form, energy of activation, hydrogen Ion mobility
ABSTRACT: The dependence of the electric conductivity of zirconyl
iphosphate on the sarople composition was Investigated. The electric
'conductivity of the granular Ionite was determined by finding the
point at which it was equal to the conduct6ace of a solution In
,equilibrium with the ion exchanger, and measuring the electric con-
Auctivity of the ziroonyl phosphate-solvent system. Work was done
'at 250, PH = 3, using and HCl solution and +silver chloride electrodes;
jor determinations on the Ionite In the Na form the solution con-
Corcl-I 1/)

ACCESSION NR: A.P4034585
.taining 0.1 equivalents/liter of Na* was buffered to pH 4.94 with
acetic acid and sodium acetate. It was found the electric conduc-
tivity of zirconyl phosphate decreased as the amount of phosphorus
in the samDle decreased (i.e., as the Zr02/P 02 ratio k Increased).
As the valu-e of k approached 1, the number oi trongly acid ionogen
groups increased; Increasing the Zr02 content decreased the ability
of the phosphate groups to dissociate. Water sorption by different
samples of zirconyl phosphate was a factor which, In addition to the
composition of the sample, determined the electric conductivity.
,The greater the ability to absorb water the greater the electric
conductivity. However, samples with anomalously~high conductivity
did not have greater exchange capacity, so the dissociation of the
phosphate groups was not Increased; the electric conductivity was
therefore caused by the greater mobility of the hydrogen Ions In the
samples containing more water. The mobility of the sodium ton in
zirconyl phosphate was considerably less than of the hydrogen ions:
.the condugtance of zirconyl phosp4ate ly the Na+ form (k = 1.11) was
0.7 X 10- compared to 2.29 x 10---l ohm- cm-1 for the H+ form. The
en Eg of D?~~vatijn of thA elzctr~c cotduotlyity al ltte the
met 0 am en, J. Else roe em,
00;' 19 for
2/3
Card,.
- - - - - - - - - - - - - - - - - - - - - - - -

ACCESSION NR: A24034585
sampl6s where k = 1.20, 1.65 and 1.07 was 2.6, 2.5, and 0.9 kcal/
mol. Orig. art. has: 2 tables and 3 figures.
ASSOOIATION: Leningradekiy gosudarstvenny*y universitet Im. A.A.
Zhdanova (Leningrad State University)
SUBMITTED: 15kpr63
ENOL: 00
SUB OODE:- IC NR REP SOVt 002 OTHER: 003
Gcr-4 3/3

M~WMA"TJ
in~ 2 ~'J TO-
-.1 ~319-97-65 VT-k'r')/VFk
s/oooo/64/000/000/0096/0103
-NR-
ACCESSION AT5002303
btebovslay, P. A.
ye.
-UTHOR:. --Mate'rovat
7 Os of ziri,,onyl pho sphiLte
~~a wo~
Ve svoystv joncobmemiykh

MA
no-
Polyi*TID'
IU) n th
-T: in a stu of e on exc ange belia-vior of Ihe tompound as an f ctio of G
MM ZrO2
ratio in its molecule, the authors prepared 20 varieties of zirconyl pho-sph-te
V __Ora OW,
4- -A 7

on
tofi-bi4flie Vefiip e~ of-drying wore -
e on btthi~ bifl&n 0-6qd4brI -bolut
10" 0 ba.factors in the process. The ton exchangecapacity of samples dried at
OP - -oar
7 and 650C dr pod sharply. Heterogeneous membranes weae pre- ed from
S as of the ziremyl plics phaties Mth polymethylinethacrylate and polystyrerw as trio
binders and ',-Wr m- tential was measured. "In conclusion, the autborB thank 1~1,
Nikollskiy, (wrresponding m embez- of the AN S-MR, for valuable advice an, (lie c. p!r
Wor,
-M64A and on the manxiscript. Origg. am. has. I table, 7 fligwres and 3
S, ;IATIOM X
T SUB M. T E D.- 06AW04 ENCL-. 00 SUB CODE: IC
REF SM 002 OTHER: ID13
4
Card

ACCESSION NR, AT50620
some t~6re6iW~wff
-BOURCE,, AN SSSR. D)BtitUt fiZlolle2hoy Issledovanlya avoystv tonoobmarmptu'l
--l-4-a nf ion-AxnhnntrA mrtfAriftlgl. Mon o -vo

Ch'
-ex ange re --electrode
electrolyte concentration, PhC'-'r'hOmOIYIAa:tO eleoft6de''~ -80thear, =01ft-,
polystyrene, polymethawnrylal te,polVathylene
ABSTRKOT.- The authors studied the effect of the concentration of k, 14C1 (0- 0 1-'
~(d. 00:1-~3 M), mcl (0. 091 - 3 M), IACI (Q. 001 - 2 M), and CSCI (0. 001 - I M) eI':-C!tTO-
:1*O-*.I'UW-1qACl-(0a001'- IM) -KCI 10,01 or 0.1M), Narl (0,001 - 1m) - IACI 10.03 o-
0. 1 CoCI (0. 001 - I M) - NaCl (0, 01 M), NaCl - HCI, and NaCI - NaOH binaxy ek: um-
olectrodes, vvingthe a-mmonium salt of couiple-x
raq.i rpmo, ALL
1% .4 Na&-a~&d,14ax zoo s)

glauconite,as the -electrode membri-no material. lrijeo.5- 1, o MTn thic1c high quality
electrode meimhr--nes were prepa-red by pressing m"ires of 40-80% of the inorganic
.1 1 - I--- -- -- - t~t

MIAO
ENC
-g(w: W. OTHF,.q- 009

XATEROVA. Yle A.; RCOHANSKAYAv T.I.; SIROTA# Z.M.
41 Faectrochemical properties of membranes from anion exchangers
Tdth different ionogenic group structure, Part ls Nonexchange
absorption of electrolytes by membranes. Elektrokhimiia I no.7t
79/,,799 J1 165. (MIRA 18-.10)
IL. Leningradskiy gosudarstvannyy universitet imeni Zhdanova.

MATF,RCVI,y Ye.A., ROZHANSKIYA, T.L
Elec tr cic heir.! cal prcTertit;s of an!Gn-exchange iriembranee w"n
structure of the lonogemic grcup. Part 3,, Flectrocorjrluctj--.~ty cr,
membrares in voluti-av. of hydre-chIcxic a,~.'d ELDd Sodlum 0,,Ilori-je.
1 nc.8i916-921 Ag 165. (.vlw~ ~.? -4..
1. Len~ngradqkiy go~iii-narstvannyy univorsltet imeni A,A.Zh-~-nc,va.

iL

77-
~664onento--wat bode--
66 to,
the
DO on,
.So; re -a W,
go; toWt
valculati be: obwd at
ibi4tlza~ io-c- of
0 ..,oppearanoe~ f 'I
6t n or,41
t
a one
Ahis!
".p see cas
Ate --zos
ottlvw~'Of lntetaotlons,~-
ASS Tsui'. - '' - _ ' N ' -
A-~*exo VM n-2 a
-0th
In,'-pre orenbc.over are,
_-,t,_ _ij
-he In t) a
ems"'exani
"hid
h "'T rom a-,. i.--iiftusa zpp-
it
texo n66~1,68 fin
'Al
1 t t ,- h
_8_~~Asp A k:_. or~:-oxonp 0-.J~F a ----Sys smo-An-v 0
lot -'ronalats, -ftfi6t1633i --Of- th6lr.:oonoen-.
iidti Ahe
Y7 origo,;t art,
A"D I Uzi
0. a
- ~ ?o
MG'

WT~',ROII'A, Ye.A.1 GREROVICH, A.L.-, GORTTKOVA, N.V.
interaction in aqueous solutions of boric and
studied by the methods of Ion exchange and potent~;onetrlc
titration. VestolZU 20 no,22e122-130 165,
(Mlql 18:1?)

BOBROV, V.S.; LUTUGINAY N.V.; MOLODENKO, P.Ta.; ZAKHARIYEVSKIY,
M.S.; SMANOVA, O.K.; BELYUSTIN., A.A.j MATEROVA
NIKOLISKIY, B.P.., otv. red.j FOZDYSBEVA, . ., red.
(Theoretical and practical guide to laboratory work in
physical chemistry] Teoreticheskoe i prakticheskoe ruko-
vodstvo k laboratornym rabotam po fizicheskoi khimii.
(Leningrad) Izd-vo Leningr. univ. Pt.l. 1965. 197 p.
(MIRA 18:12)
1. Leningrad. Universitet. 2. Chlen-korrespondent AN SSSR
(for Nikollskiy).

MA=TEU'r
in anemia in children, adulti k ex-eriaental
fUeetrocardiogra-3h:)
animals. Pediat. ~)~i ~ ska ~_~ no. 4: 391-399 Apr 57.
1. Z Zakladu Fizjopatulogii Instytutu Hatki I Dzipcl:a w .-die.
Dyrektor Instytutu: )ro:'. dr Med. Rr. Grover Kiero.e.AK_'rxkIadu:
doe. dr -ned. A. Chroicicki. Adrea~ Warszawa, ul. 17,
InF;tytii'. 14-t;r! i Dziec,,a
(AMNIA, )Ixysij'-
in .,,,jrious dis,
anwdia ("o1))

kntani; M&TIVISU, Teresa; SWIDE56KI, Jerzy
;--1'.Iet4ys=ograpbW in be diagnosis of ct4rdia~: failu--t-
32 ao. ' 5: ~4ny 57.
-~aklamm Amjopato-,i~ Instytutu Matki i z-aclrt d ei-r
..yrai.tor Iristytutu: orof. dr zted. Fr. Groer
--ascicki. Aw-es: Warsza:wa. u1.
Ch
photopleth;i:.-nography in eoa-gaa.
child., ula . value (?D!))
DIS?ILSE;3. 4a inf. & child
diag., pt-,ot~)Aethyslo,~,raphy in

197 /9 rldi c A-
Anton-,; -ere-.a; ~3EIDERSKI. Jc-j,zy
:=rxu_- :,f extracardliac origin i.:i ~:hi.-_'_-~n
_Q -f-5;5'0-575 XhY57-
-~.a_: _acu Z. )Jt~.t 0 1i Im, tytltu Hat), i I J~_- iecka -.1 War,, z
LVrekt3r i~u; prof. ur -:-.ec. Y'r. Groer
A. i~ardiaiogi~zcxj 11 int~i
?. R Prof. dr med. M.
I:,- -_.vtlAt 14nt