1. CHEMICAL INDUSTRY, NO. 7, 1955 2. CHEMISTRY AND CHEMICAL TECHNOLOGY, NO. 1, 1956

• Document Type: CREST
• Collection: General CIA Records
• Document Number (FOIA) /ESDN (CREST): CIA-RDP83-00418R004500120001-7
• Release Decision: RIPPUB
• Original Classification: C
• Document Page Count: 282
• Document Creation Date: December 20, 2016
• Document Release Date: November 5, 2007
• Sequence Number: 1
• Publication Date: May 28, 1956
• Content Type: REPORT

Approved ForRelease2b07/11/05 CIA-RDP83-00418R004500120001-7
PROCESS'gG c057:1(
2
25X1
CENTRAL INTELLIGENCE AGENCY
INFORMATION REPORT
CONFIDENTIAL
1)60iS95
This material contains information affecting the Na-
tional Defense of the United States within the mean-
ing of the Espionage Laws, Title 18, U.S.C. Secs. 793
and 794, the transmission or revelation of which in
any manner, to an unauthorized person is prohibited
bylaw.
COUNTRY USSR
REPORT
SUBJECT 1.
Chemical Industry, No. 7, 1955 DATE DISTR.
28 May 1956
2.
Chemistry and Chemical Technology,
No. 1, 1956
NO. OF wes 125X1
DATE OF INFO.
REQUIREMENT NO. RD
PLACE ACQUIRED
REFERENCES
Al J.ACIT317N1
This is UNEVALUATED Information
THE SOURCE EVALUATIONS IN THIS REPORT ARE DEFINITIVE.
THE APPRAISAL OP CONTENT IS TENTATIVE.
(POE KEY
Khimicheskaya Promyshlennost No. 7 1955 and Khimiya
i Khimicheskaya Tekhnologiya, No. 1. 1456
The publications are
unclassified
CONFIDENTIAL
25X1
25X1
25X1
25X1
[ ARMY
NAVY
AI
FBI
AEC
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25X1
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
1111111111111111111111.1
XVIMI/144ECKAII
TEXHOJIM/111
IlEPEBOAbl
113 HHOCTPAHHOR TIEP110,4119ECKOR
JINIEPATYPb1
it
9 5 6
143,4ATEIlbCTBO HHOCTPAHHOR JIHTEPATYPb1
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
X klf 1/151[
XI4MMEMECKA5IE
TEX1-10A0F11451
CBOPHHK FIEPEBOA0B
HHOCTPAHHOR FIEPHO,LIFILIECK0171
JIHTEPATYPbI
1 (72)
1956
ceabmoa coo uadatitui
14 * A
143AATEJIbCTBO
HHOCTPAHHOR JIHTEPATYPIDI
MOCKea
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
OTBenTEtemibie peaaKTopu pa3,4e.nos c6opluma
.xxhilig 14 X14MHgECKAH TEXH0J101'11H*:
HIM. M. C. Aicymun, HH)K. JI. H. Eapanoe, AOKTOp XHM. Hap( npocp.
B. H. BeA08, Ka11,11. XHM. flayK E. B. rep6ypm, KaH,14. XHM. Hayx
B. O. Eecmpamoe, KaHn. TeXH. HayK (1). 17. 116aHOEICKIla, =IA.-Kopp. AH CCCP
npoit. H. M. Kapaeaee, AOKTOp XHM. Hay K npocto? B. H. Kyenetioe, xaHg.
XHM. nap{ M. H. Jlantuun, AeticTs. 11.11ex AH BCCP npoc1). C. M. Jlunamoe,
KaH,11. TeXH. Hap< B. F. MU.408, Kan,a? xiim? Hayx H. M. Mopoeoe, A9KTOp
TeXH. HayK npocp. A. H. Ilium06C1Clia, Aowrop XHM. Hayx B. H. YOuAttoe,
npocp. C. H. ILIenkun.
B oT6ope maTepHa.noB H COCTaBJIBHHH C6OpHHKOB nepeso,tkoe
(XHMHH H xlimmecKati TeXHOJI01'HFD ytiacTspor COTpyaHHKH HayHHO-
HCCJIB,710BaTeJlbCKHX HHCTHTyTOB MHHHCTepCTBa xionitiecKoil Hp0-
MbILUABHHOCTH CCCP, M
-OCKOBCKOr0 HHCTHTyTa XHMHHeCK0r0 mum-
HocTpoemisi, MOCKOBCK0r0 opAeHa JIBHHHa XHMHK0-TeXHOJI0tH4eCKOr0
HHCTHTyTa }MEM Th. H. MBH,aaJleaBa, MOCKOBCK0r0 TaKCTH.KbH0r0
HHCTHTyTa MHHHCTepCTBa BbICLUer0 o6pa3osaeusi CCCP, MOCK0B-
CK0r0 43HaHa.Ka UeHTpaabnoro HayHHO-HCCJIBa0BaTeBbCKOr0 HHCTH-
TyTa Opium MionicTepensa 6ymaAmok H Aepesoo6pa6arbusafouteA
npombiLIIJIeHHOCTH CCCP.
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
OT H3J1ATEJ1bCTBA
Cep1151 C6OpHHKOB nepesollos OXIIMI311 H XIIMINeCKaH TeXHOJIMISID, H3,4aHae-
MbIX C 1950 r., HMT LIeJ1b10 cucTemaTHHecHH muttopmHpoHaTb inHpoHHe xpyra
HH)HeHepTo-TexmitrecHHx pa6oTHHHort pa3.T1141111b1X oTpacneti Ilp0Mb1111J1eHHOCTH,
3aBOACKHX J1a6opaTopHil, oTpacoeswx Harfflo-Hcc.neAoHaTeabcHllx 14HCTHTyTOB
H BbIC11111X XI4M1It1eCKHX H TexHHtlecHHx pie6Hwx 3aHeAemici 0 cymecTseHHbix
pa6oTax, ny6aHHyembix B 3apy6e)HHoil nepHoAHliecHoil negaTH no Honpocam
Xl4MHH H nimmecHoil TeXHOJI0r1111.
OT6op maTepHanos, noAroTomq H OTBeTCTBeHHOe pepAHTHporiaHHe 11p0113-
B0,11,51T KOMIleTeHTHble B Haxutori AaHHoil 06J1aCTH cneuHanHcTw.
Ilepemm .maTepHanos npoH3HopATc1 TaK1IM o6pa3om, liTo6b1 0cHo6oAHTb
HHTaTezen OT He06X0AIIMOCTH o6paulaTbeH K IIHOCTpaHHbIM opHrimanam; CTaTbH
COI1p0BOX{4aKYTCH OCHOBHbIMH cxemamm, pncymcamH, Ta6J1HnamH4 H AHarpam-
mamH.
C6opHHH nepeBoAos ?XHMI431 H xHmlimecHaH TexHo.norHH? ounitmeTcH OT pe-
cPepaTHHHwx H3AaHH1i Tem, TO B HM ocHeinaloTcH JIHILIb cymecTHeHHwe no Hamc-
Itomy pa3iteay pa6oTw; OHH ;Lam BO3MO/KHOCTb turraTeoHm, pa6oTalonom Ha
nepotepHH, o6xoottuTbcH 6e3 rIepBOHCTOtIHFIKOB.
B 1956 r. B c6opHHHax 6yAyT nomenoTbcH nepeso,abi CTaTeil H 0630pw 113
HHOCTpaHHOCI nepHOHqeCKOi1 no cze,ttyl0W,I4M pa3,Re.nam XHMHH
H xHmHtiecHoti TexHonorHH: KaTaJIH3 H HaTaJamaTopw, xnmmecHmil allaAH3,
npoueccw H annapaTm, KOHTp0J1bHO-H3MeplITeJlbHbIe ripH6opw, HeopraHHtlecHHe
HeuRecTsa H mHHepaabHme yAo6peHHH, TOHJIHBO H npo,rtywrbi er0 nepepa6oTHH.
ocHosHoil opraHmtlecHkal CHHTe3, HpacHTeAH H nozynpo/AyHTH, (1)113HKO-XHMIPle-
CKHe CBOACTBa BbICOKOMalIeKy.1111pHbIX BeIBeCTB H HcHyccTseHHoe BOJIOKHO, 1.1eJIJI10-
J103a H 6ymara, JIaKH, HpacHH H pacTsopHTemi, HcHyceTHeHHwe CM0J1b1 H IIJIaCTH-
tleCKHe MaCCbl, KaytlyK H pe3I1Ha, 01113CTKa CTOtilibIX B0,1t?
B CepHH C6OpHHKOB OXHM1151 H XHMIltleCKa51 TexHanorHH? 6y,tlyT neTiaTaTbcn
HaHmeHosaHHH HHOCTpaHHbIX KHHT, HOJIrleHHbIX 143,aaTe.TIbCTBOM IIHOCTpaHHOA
JIHTepaTypb1.
B pa3Re.fle ?K pHTHKa H 6 11,6 .TI Horpa 4)H H? 6y,RyT nomentaTbcH
peueH3HH Ha OTaeJIbHbIe KHHT13 H moHorpacimx, BbnueAume 3a py6excom no XHMHH,
H XI4MHtleCK011 TeXHOJI0rHH.
CepHsI C6OpHHKOB 6y,TleT COCTOHTb 113 12 BbIrIyCKOB 06bemom 17 yq.-H3,R. Jr.
HamtAbnl. B noczemem, 12-m, HbinycKe 6yART nomemeH npeAmernwil yHa3aTent.
? coopHHHam.
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4 OT H3BATEJIbCTBA
flo,anHcHau u,eHa Ha 1 c6opHHK 11 py6neil 90 icon.;
Ha 6 mecuueu 71 py6. 40 Kon.;
Ha ro,a 142 py6.
-- KOH.
TIOAHHCKB HpHHHmaeTcn B ropo,acKux H pacIOHHIDIX urile.nax Colo3negaTu,
Kowropamu H OTABOBHHHMH CBH3H, a Tax?Ke ynomuomotleHHuma B ytie6Hb1x mite-
ygpe?KAeHilux H oprammunnx.
143,4aTeabCTBO npourr tIHTaTeJTei Hanpamfah.,CB014 aametiamin, noaceaaHusi
H npexioNieHun no aApecy: r. MocKsa, 14-164, Houo-A..nexceeacKan yanua, ACM(
Ne 52?peitaxuull xHmutiecKoll awrepaTyphi.
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
XHIMINECKIIFI AHAJI143
flo,a pe4taximeil AoKTopa XHM. Hap{ npocP. B. H. Ky3Her4oea
Becoime onpeitemane canau,a joyaameukenabima Awraoaap6amaTama. Brema-
nis E., Schaible L., Bergner K. G., Z. a n a 1. C h e m., 145, N2 1, 18-23, 1955.
A. IlpHmeHeHHe asy3ameu1eHHux aHTHoxap 6 amaTos
B KalrecTHe FYHfl0BbIX peaKTHHoa
flo AaHHbim F.neH H Lilsa6a (A n g. C h e m., 62, 320, 1950), Asy3ameureHHbie
AswrifoKap6amaTbr (coxpameHHoe Ha3Hamie oxap6aTbi?) irpHro,aHbi rpyrinoHoro
ocaxcleHHH MeTaJIJI0B. aTHMH ?Ke asTopamil 6bhno H3ytieHo H3anm0,aeficTHHe 3TFIX
peaKTHBOB CO HcemH meTaxnamH. YCTaHOBJIeHO, LITO oCa,LlKH o6pa3y}oT HOHbI
cae,ayionmx a.riemeHTOB:
1) B meow-ma cpe,ae ripH ao6aa.neHHH NaOH B ripHcyTcTHHH TapTpaTos
(pfl-,14): Co (III), Ni, Cu, Ag, Au, Cd, Hg, TI, Pb H meTa.a.nbt noaTHHosofr
rpynnbi.
2) B ammHatmoft CpeAe B 1-1pHCyTCTBHH TapTpaTos }Tome Hume-
Ha3BaHlib1X MeTaJIJI0B, o6pa3yloT ocaxcH Taioke: Mn (II), Mn (III), Fe (II),
Fe (III), Co (II), Zn, In, Sn (II), Sb (III), Bi, Te (IV). ?
3) B yKCyCHOKHCJIOCI cpeite B npHcyTcraHH TaperpaTos (pH-,5): V (IV),
V (V), Nb, Cr (III), .Mo (VI), U (VI), Ga, Sn (IV), As (III), Se (VI)1).
4) B c.ria6o ammilaxmbtx H B coa6o KHCJIbIX pacrHopax npH Harpesamm HOHLA
As (V), Sb (V) H Fe (III) ocamq,aturcH mexneHHo H Heno.rmo.
Bce ocTaabHbie meTanom?me.notmo3eme.nbHbie, pexcHe 3em.nH H Ti, Zr,
Th, U (IV), Ta, W, Re, Al, Ge, Se (VI) ? B HHAe Kap6aTos He oca}xikaroTcH.
no ,traHHbIM Fzea H IIIHa6a, HOHIDI 3aemexTos, nepetincaeHublx B gen:apex
rpyrmax, MOIKHO ,nerico OT,TI,e.TIHTb B HHAe Kap6aTori OT Apyrkix 3J1eMeHT0B. Flpe-
HmymecrHamll TaK0F0 OTACTIeHHH SIBJISHOTCH: HCKJI1011eHHe ceporio,aopo,aa, npocToTa
pa3.r1o}meHHa HOJITIeHHbIX oca,rucos Kap6aTos KHriameHHem C KHCJI0TaMH C aa.nb-
Hamm HccneaoaaHHem HX 06b111HbIMH meToaamH; BO3M03KHOCTb pa3J10)KeHHH
I136bITKa ocaaxreoH xlmsmeHHem cpimurpaTa C KIICJI0TaMH B IlpHeyTCTBHH OKIICJIH-
Te,ne1t?a3OTHOIA KHCJI0T131 14J114 nepexHcH ao,aopo,aa.
B. Kap 6 aT KK peaxTHH Ha cHHHeu H TaJIJIH
DxcneptimeHTanbno yeTaHoaneHo, TO B npucyreTHHH U,HaHH):10B npm3eaeHHbie
BbIllle B rpyrmax 1 II 2 HOHb1 B apiae Kap6aTos He oca)K,aaioTcH. PICKJ11011eHHeM
HBOHIOTCH TOJIbK0 CBBHU H Ta.TIJIHH. 3T0 CBOACTBO MO)KeT 6EITb HCII0J1b30BaHO
oT,RezeHHH cam-maIIOqTH OT Hcex MeTaJIJI0B, npaxTmeeKH Hcrpetralom,Hxor
B aliaoH3e. ,L(a.nee 6brao Tax>Ke YCTaHOBJleHO, oca,Rox Kap6aTa cHHHHa npe,a-
cTaturHeT co6of4 BecoHylo cpopmy C BeCbMa 6.flaronpH5lTmum xo314xlmmitewrom nepe-
egeTa. 06ura5I cpopmyna Kap6aTos caHm.ta caeAylomaa:
Ri
Pb( ?S--C?N/(
R2)2
B KairecTHe peawrsaa- ITHMeHSIJIH FJIaBHEIM o6pa3om C0e,41,1HeHlle, Ha3BaHHoe
ITheem H 1.1_1Ba6om maTpHil-n-Kap6am. arm' peaKTYIB JIeFKO H ripocTo cHHTe3HpyloT
B opurtitiaae, nosiwimomy, onetiaTi(a. CaejoreT gFITaTb Se (IV).-17pum. pea.
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6 XIIMWIECKkin AHAJIH3
C xopounimH imixon,amH. CocTars ero oTseqaeT c.neAyfoulert ckopmy.ne:
C? H2,
Na?S--C--N(' ;CH2
11 \CH2?CH2f
MageKynsipilbdi sec n-sap6aTa CBHHIJa pasex 527,77, a xosclxiquilieHT
nepe-
cqea n 201)19ATITO sno.nHe cosnafiaeT C OnLITHIAMI4 AaHHLIMH. Kpome Toro, csHHeu
onpeAesnium Taloxe npx IlOMOLIAH 2H3TH.n,TH4TH0sap6amaTa HaTpHs, H3BeCTHOTO
xax peasms Ha meAb H OTIOBO. Pe3yobTami, nanyqemime npH OAHHaKOBLIX yCJI0BMIX
onpeyte.noms, BrIOJIHe yztos.neTsopHTe.nbHm, KO94O1J11IMeHT nepecqeTa paBeH 0,4113.
06mas meT0Hxa onpeAe.neHHs csHHaa B B H ,a e
xap 6 aTa B npHcyTcTBHHAs,Sb,Sn,Cu,Fe, ZB, CO H Ni.
PeaKTHB hi. BHHHaR KHCJI0Ta, spHcTa.n.nmecicas, q. ,q. a.; 33%-Hiul
pacTsop NaOH; KCN, Tsepmaii; 10%-xmca sommcf pacTsop HaTpHeBOil COJIH
n-xap6aTa; 1 %-xmil BOAHLICI pacTsop HaTpHesoli COJUI n-icap6aTa, npHmeHsemmil
IWOMLIBKH. 06a IIOCJleAHHX pacTsopa npHmeHmoT csoxenpHroTosaemimmx
ii nepeA ynoTpe6neHHem TPHJIbTpylOT.
MeT0A 0 npeAe.neHH.s. KpacTsopy COJIH CBHHUa HJIH CBHHHOBOTO
cnaasa Ao6aB.ns1oT BIIHHy10 KHCJI0Ty 113 pacqeTa npmviepHo 1,0 e KHCJI0Thi Ha
xamimio 0,1 e meTa.n.na (pacqeT BeAyT Ha 06mee co/tep)KaHHe Tmse.ntax meTa.n.nos).
PacTsop HeilTpammyloT 33%-i1Im paCTB0p0M NaOH no 4eH0ix1yraneHxy H 3aTem
Ao6as.nsuoT eme NaOH H3 pacqeTa 10 MA me.noqH Ha xaKame 100 dliit pacTRopa,
1-2 a KCN,pacTsopeHHoro B He60JIbILI0M KOJIHMeCTBe BOMA H, HaKolieu, npH
nepemeumusaHHH pacTBop ocaAHTe.ns H3 pacqeTa 10 MA pacTsopa ocawre.ns Ha
0,1 e CBHHIja. flpH He3HatIHTeJIbHOm compwaHHH csmula (go 1-2 me) cpa3y
o6pa3yeTcs onanecimpytoulas MyTb, xoTopas noc.ne 5 MHH. CTOSIH101 H xlaCTOTO
nepemeumsamis npespauLaeTcs B oca,aox C xleTKOrf xpncTanJumecsoil cTpysTypoff.
60aBillem co,RepscaHHH CBHHaa 6e.nbul ocaottox 61JcTpo npespaujaeTcs
B mensHe HroJibliaTbie spHCTaJklibi. 'gapes 10 MHH. ?cams oTclumbTposbismoT
1iepe3 cpapckoposBul cistnbTpylouwil THTeJIb A-2, npommsafoT 8-10 pa 3 He60.Th-
11I51MH II0p1JHHMH np0MLIBHOrl ?KHAKOCTH H 110,11KOHeIJ 3 pa3a He601IbILIHM KOJIHtle-
CTBOM B0,1b1. OCaJJOK cyluaT 1 qac HH 110-130?. MeT0A AaeTBO3M0)KHOCTb onpe-
io 2 me cBHHua. Howl HHTpaTa, au,eTaTa, cy,nbcpaTa H x.nopa onpeAe.neHmo
xe memaxn.
B. Ilomexil, o6yc.n0B.neHHbie npricyicTsHem Ka,LIMHSI,
cepeopa, sHcmyTa, pTyTH H marHH
PTyTb HeJ1b351 KOJilnieCTBeHHO 0T):JeJIHTb OT CBHHIJa npH ocax{,neHHH ero
B BHJle sap6aTa, Tax KK npm 60,nb11iem coilepaKeHroHaTbnI
oca,aox Hap6aTa nepeocamcla.all, xax onHcaHo H meroAe B.
Ta6Au4a 4
onbiTa
HaBecKa,
B3HTO Pb,
AW
Ka p6ar
CBHH4a,
AW
HatiAelio Pb,
M2
Outh6xa
Ma
1
0,0222 crinalia
16,5
41,9
16,4
--0,1
--0,6
2
0,0635 Bi
27,2
68,7
27,0
--0,2
--0,7
3-
0,150 Bi
27,2
69,0
27,1
--0,1
--0,4
4
0,200 Eli
27,2
68,9
27,0
-0,2
--0,7
5. OrIpe,geJIeHlle CBHHII,a B Hp14CyTCTI3HI4 KMHR
H cep e 6p a. Pe3yJIbTaTbI OIIbITOB ripaseiteabi BTa?I. 5. B onwax 1 H 2 K pac-
THopam C H3BeCTHbIM coikep}KaHHem COJIH cHkunta Ao6aHmuni onpe,gezeimbie
HommecTsa pacTsopa aHeTaTa KaAmHH. B 011bITaX 3 H 4 K pacrHopam COJIH CBHHIIa
01[96aanaza paciltopm COJIH cepe6pa. Oca,RHH Kap6aTa nowropHo nepeocaKaa.nH,
KK OIIHCaHO B Meme B.
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XIM14IIECKH11 AHAJ1H3
9
?
Ta6Autia 5
K2 onbrra
liamma,
a
BWITO Pb,
"
Kap6aT
csantka,
ma
Haftaeno Pb,
me
? Orun6xa
me
%
1
2
3
4
0,16 Cd
0,26 Cd
0,20 Ag
0,40 Ag
54,4
27,2
27,0
27,0
139,0
69,1
68,6
69,3
54,6
27,1
26,9
27,2
+0,2
-0,1
-0,1
+0,2
+0,4
-0,4
-0,4
+0,7
OnpeAeoeHHe cBHHu,a B BHAe xap6aTa Hccoe
oTotte.neHHH ero THOMOileBHHOri
ECM CBHHell, OT/11,e.115:110T OT FHX meTaJmoB no meTo,ay Mapa H ane B Blue
KOM11.11eKCH0c0 coeameHHH c THomogemmoil, TO (1)14JIbTpaT MO)KHO HCII0J1b30BaTb
,I1J151 onpe,Ae.nemm Apyrxx MeTaJIJI0B. Flp14 TaKOM meTo,n,e paa,u,eoeHHH cmmen. MO)KHO
Taxwe onpepg..71HTB B BH,ae xap6aTa. PacTsopsuar no.nytieHHoe KOMI1J1eKCHOe coe,a,H-
HeHHe B Bo;:ke c ,LI,o6aaneHHem He6o.nbaloro KOJUILIeCTBa pa36ameHHoil a3OTHOCI
KHCJI0Tb1 H aueTaTHoro 6yckepa. FlOC.I1e 3TOTO CBIlHeU ocaKaaloT B BH,Re Hap6aTa.
OcTaioinaHcH B pacTsope THomogeBHHa onpeolte.neHmo He meinaeT.
B bI B o J bI
01IIICaH HOBb111 BecoBori meToA onpeAe.nemm CBIIHII,a B npkicyTcTBHH ApyrHx
T5)KeJ1b1X meTarmots ocaNcrAeHHem ero AHTHoxap6amaTamH. MeTog, 6o.nee 6bicTptal,
gem maccHtlecxHil Cy.I114aTHbIll, H ,tkaeT BO3M0>KHOCTb? onpeAeoHTB otieHB TO,IHO
o 2 me cBHHua. OnpeAe.neHmo He menialoT c.neAylonme TH)Heame meTa.nabi: As,
Sb, Sn, Cu, Co, Ni, Fe, Zn. B nplicyTcTBHH Cd, Ag H Bi oca4kox Hap6aTa cenHaa
cze,ayeT nepeocaKaaTB. Taamiti ocaKstaeTcH IcomitiecTBeHHo H no3Tomy oTAeofleTCH
BcerAa BmecTe CO CBHHUOM. PTyTb H MarH141 memarar onpeflezemno. floBeAeHHe
30JI0Ta H MeTaJIJI0B mnaTHHoBoCi rpyrumi He 6m.no Hcc.ne,goBaHo.
17epeeoa Pa6utioeuri.
PeaKu,lisi o6pa3oBamisi moan6AeHoBori CHHH H onpepgaemie imallopa ft Bos,ax,
cop,epwaupix MblifibilK7 Kpeminift H repmanHil. Levine H., Powe J. J., Grimaldi
F. S., A n a 1. C h e m., 27, N2 2, 258-262, 1955.
OnpeLtezemno (Pocd)opa no peaxuHH o6pa3oBaHHH mooH6AeHosoii cumi no-
cminexa o61umpHaH JurrepaTypa. B OCHOBy onpe,ae.geHHH nozo>metio o6pa3csaime
(1)ou4)optiomo.r114624elionoil KHCJI0TbI 1,1 nocneylomee ee BoccTaHoBaeHHe B neuiecTso,
oxpaineimoe B CHHHC1 UBeT. MeT0, nepBoHatm.riBHo npe,a.no)KeHHBal ,L1eHmKe [1],
our' BnocaexTB1414 BULI,OH3MeHeH JJ51 onpe,ae.neHHH cpocd)opa B mopcxoil Bo
FlpeAcTasasuoT m-rrepec pa6oTbi no ana.T1143y B0b1, OIly6J114K0BaHHbIe 11,14HIla3e
[8], KaJule [4], Pei14914J113,110M H coTpy,54-114xam11 [5], ByOM H coTpy,ammamu [7],
Xapneem [3] 14 P0614H3OHOM H COTpyAHHKaMH [6].
Peaxmm o6pa3oBaHHH m0nH6,4eH0Boi1 CHHH He SIBJ151eTCS1 crieunikitieckoii kJ Is'
cpoccPopa, TK KK C011HeHH51 MbILUbilKa (V), repmamm H xpemmm ripH BaaHmo-
AeticTBHH c mom46,LtaTamx Taxwe o6pa3ytoT reTeptiloommicaoTbi, ripo,Ekywrbi BOC-
CTaHOBJ1eHHST KOTOpbIX oxpameHm B CHHHil II,BeT. PeFyJUIpySI KHCJIOTHOCTb cpeikm,
MO)KHO 410614TbCH HeKOTOpOfi 113614paTe.11bHOCTH .3T011 peaKumi ikasi cpoopaTos.
Hanpilmep, flH 3HaIIHTeJ1bH011 KHCJIOTHOCTH cpeAbi pealcuml BOCCTaHOBri('inisi
re'reponom4m4c.n0T (Poccloopa H MbIIIIb54Ka mo)KeT 6bITb ripose,aelia 6e3 nomexii CO
CT0p0Hb1 MaJIbIX KO.TIFitleCTB xpemHHH H repmambi. flpH alia.max mopcKori B0,11,b1
speppoe 13.11H5THHe apceHaToB MO)KHO HCKJI1OLIHTb BoccTaHomeithem HX B apcennTbi,
npeAu11ecTBy101.11,13M Ao6aBaeHmo M0JI116AaTa ammoHHH. BOccTaHOBJ1e1114F1
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
10
XPIMII4ECKH11.AHAJ1143
MbILI11351Ka 6bum npexno)KeHbi paanHnHhie BOCCTaHOBI4Te.1114 (HanpHmep, 6Hcy.nb4HT
HaTpHH), 0,1(HaK0 B JnfrepaType HmeeTcn mHoro npoTHuopenHsbix ,aaHHbIX no nouo,ny
3144exTHBHOCTH HX ,RetiCTBHCI HMelOTC51 TaloKe yKa3aHHH, TITO HHTefICHBHOCTb
cHuefi oxpacKH BOCCTaHOBJIeHHOil II1/0C430pHOMOJIH6,1keHOBOCI KHC.TIOThl B nplicyT-
CTBHH apCeHHTOB yue.aHRHuaeTcH.
Orpemucb HailTH yCJI0BH51 no.nytleftHH Ham6o.nee ycToruniBOro C14Hero KOM-
nzeKCHOTO coeAHHeHHH MOJ1H6,11eHa H c,ne.naTb peaKII,H10 MeHee TlyBCTBHTeJ1bHOR
K 11pHCyTCTBH10 memaiounix HOHOB, ZJ1H BOCCTaHOBJ1eHH54 ItOCC110pHOMOJI146,11eHOBbIX
KHCJIOT .nplimefuum pa3Hb1e BOCCTaHOBHTeJIH.
1,1,e.nb HacToHatero Hcc.ne,noBaHHH-yeTaHOBHTb yCJIOBI4H, B KOTOpbIX 1:1)oc4lop,
MbI111bH K Kpemfairi H repmaHHfi o6pa3y1oT mozH62JeHosylo CHHb. flo.nytieHHbie
AaHHbie ,ROJINCHbI 6b1.11H pacumpwrb 3HaHH51 0 XHMHH reTeponoammc.noT Ha3B3H-
HbIX 3JIeMeHTOB H nomomb yeTaHOHHTb pa3JIHIIHH B 14X noBeAeHHH, KoTopue MOTJIH
6bI 6bITb HCII0J1b30BaHb1 ripH pa3pa6once aHanlinniecxxx meToAos. ,aaJiee npe,a-
no.nara.nocb pa3pa6oTam meToA onpeikezeHHH c.nefi,ou cpoapopa, npHmeHHmbnl
ARA aHamma uoA, co,nep?KaatHx apceHaThi, CHJIHKaTbI H repmaHaTm.
1,13ytieHHe peaKHHH o6pa304BaHHH
mo.nH6,neH0uoil CHHH
143yRann BJIHHHHe c.ne,gyiontHx ifiawropos: KHCJIOTHOCTH cpe,nbi, KoHuellTpauHil
mo.nH6,1kaTa H BOCCTaHOBHTeJIS1. BbIJIH nposeileHbi Be,7:0 cepHH 011bITOB. B ?Alia
CHH B xatiecTue B0CCTaHOBI4TeJ151 npHmeHHAH x.nopHA o.nosa (II), B Apyro11-
1-ammio-2-Hagrro.n-4-cy.nbilioicHc.noTy, npemowenHylo CDHCKOM H Ca66appoy [2].
3T11 HemecTua 6b1J1H Bbi6palibi KaK HaH6o.nee ynoTpe6HTe.nbHbie B HacTosmee spemH
BOCCTaHOBI4TeJIH, H, Kpome TOM, 04H0 143 1-114X FIBacieltst Heopramilleciom, a Apy-
roe-opraHmecium BOCCTaHOBirrezem. ?
MeToA nposeAeHnu HCCJ1e,40'111aHHCI. FIpH 14CCJIe,40BaHHH
npHmeHH.nH c.neoviouvio oftylo meTommy. B Ko.n6y Ha 100 MA nomeina.nx 5 .?KJI
pacTuopa, co,nep?Kamero B nepecReTe Ha OKHCJIbI 10 7 P205, 25 As205, 25 7 S108
H.T11125 Ge02. ,L1o6as.nHAH onpe,nezeHHoe KOJIHTleCTBO C0J151110t1 KHCJIOTH, ,ROBOAHJIH
oftem A? 25 MA ,RecTHAJniposaHHoff B0,110f4, IIpHJIHBaJIH H3BeCTHOe KOJIHTleCTBO
pacTuopa mo.nH62aTa aMMOHHH H A0B0,414:11H o6lem ,no 45 MA. HaKoHeH, ,406aBJISIJIH
onpe4e.neHHoe KOJIIPleCTBO B0CCTaHOBI4TeJ151 H ,ROBO1HJ114 oftem no 50 MA.
B CHH onbrrou, rAe uoccTaHouwre.nem c.nyx(H.n SnC12, cueTonor.nouteHHe pac-
Tuopa H3Mep5IJIH ripH 735 Att.!, nepe3 3 MHH. nocne 11p14TOTOBJ1eHH5I cmecH B moseTe
B 1 CM HH LuHpHHe tue.nH 0,06 MM (34xPeKT11BHas1 umpHHa 110JIOCBI 3,3 MR). ,ELT1H
cpasHeHHH 6pa.nll Boy. AHa.norwmo CTaBHJIH 011b1Tb1 C npilmeHeHHem 1-amHHo-
2-HatiTOJI-4-CyJ1140KHCJI0Tb1, ec.nll npoom co,nepxca.nq KpeMHHCI H repmaHHII.
npo6u, coAepmcaunie Cl/OCCP0p H MbILLIb51K, noc.ne ,u,o6allne1-IH5 peaKTHBOB
HarpermaH KHIIeHHSI, ox.na?K,na.nH H H3mepHAH cueTonor.nouteime. B 3TOM CJIY-
Tlae HarpeHaHHe Tpe6yeTcu AJIS1 ycKopeHHH B0CCTaH0BJIeHH51 FeTep0110JIHKHCJIOT,
TaK Kai( B lipliCyTCTBHH opramitlecKoro B0CCTaHOBI4TeJISI peaKu,Hu npH KOMHaTHOR
Temneparype npoTeicaeT mememio.
BJI1151104e K0Hue0Tpau,HH MC,J1H6AaTa H KHCJIOTHOCTI4 cpe,nbi 143rIaAH 021H0-
spememio. Hcc.ne,nosaHo 40 pa3JIH4HibIX K0M6HHaL1,14, B KOTOpbIX KOJIHIleCTBO Ao-
6aumiemoro mo.nH6,naTa aMMOHHH MeHCIJIH OT 0,5 ,go 10 MA c HHTepsa.nom B 2 MA,
a KOJIHTleCTBO COJISIHOCI KHCJI0TbI OT 0,02 ,zko 5 MA c HHTepHa.nom B 1 MA.
Ha pHc. 1 H 2 H3o6pmeHbr rpacinniecKH 06JIaCTH 06pa30BaH1451 M0JIH6,11eHOEta
CHHH. Taxa rpalcnNecKHC4 meToit H306pmeHH1 3aHmcTu0saH y Xapuen [3].
flo OCH a6cuHcc OTKJIa):113IBaeTC51 KOJIHTIeCTBO C0JISIH0C1 KHCJI0TbI, npHgem flpH
npHmeHeHHH B KaRecTue BOCCTaHOBIITeJ151 x.nopirma OJI0Ba (II) cma BX0HT Taime
H C0J151Haf1 KHCJ10Ta, 3alunotiatoutaucH B 3TOM pearettre. Pe3yJIbTaTbI ,11J1F1 KpemHHsi
H repmaHHH H3o6paxceHh1 Ha oovom rpacinu{e, TaK KaK AJIH 060HX 3THX anemeHTou
no.nygeHbi QAHHaKouble ,naHHhie. To x(e camoe OTHOCHTCH H K 1410031)Opy H Mb11111)51KY.
lipeAno.naraeTcH, TITO peaKun o6pa3oBaHHH mo.n116,neH0soil CH1114 npHmeHHma
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
XHM1411ECK14171 AHAJ1143 11
1'OJIbK0 Tor,na, KOT,11a cHeTonoroomeHHe B c.nenom onbne OtleHb ma.no (> Mg0 > A1203 > ZnO > TiO2 > Cr203 > Fe203,
ripaqe OKHCb me,nu 3HatIliTeJ1b110 npesocxonHT B 3TOM OTHOIlleHHII npyre OKHCJIbI.
jjawe npkt ebmoKonopHcroll noeepxHocTH Fe203 HJIH Cr203 He MOT AOCTIITHyTb,
?{OTR 5W 11P116JIH3HTeJ1bH0, KaTaJIHTHIleCK01 aKTHBHOCTH CHO, NiO HJIH COO
O CPaBHHTeJ1bH0'60J1ee ?r.ria,iwori? nosepxHocTbio.
0 3HageH1111 XHM1111eCKOTO cpoAcTsa pearHpylontux sentecm K saTammaTopy
6bi.no pice paHee yKa3aHo Illemcom [54] H XIOITIITOM [55] (npas,a,a, B CBSI3/1 C APY-
rftmH sonpocamH).
; YeKopsuoulee AeAcTeHe TeepAoro KaTa.nH3aTopa OCHOBaHO Ha TOM, tITO OH
nepeeoAHT OAHH 11.7111 HeCKOJIbK0 yllaCTHIIKOB ra3osoci peaKAHH B aKTHBHOB COCTOSI-
tale' B pe3y.nbTaTe xemocoponim Ha nosepxHocTH KaTaaH3aTopa. KaK ye yKa3bd-
Biallf3Cb, xeMocop6gHsi c 0c.na6.neHHem HJIH pa3pbIBOM CBH3& B mosneicy.ne momceT
npoH3oRTH TOJIbK0 ripH yqaCTHH B 3TOM npouecce 3J1eKTp0H0B, npusommtem
K HoHH3aaHH xemocop6HposaHHoro ra3a (KeHHoe Bykkapom [58] TO.TIKOBaHHe pe3y.nbTaTOB pa6oTbi
BarHepa He y6e/urreabHo.
' B aToil CB51314 ?Ke.naTenbxo Bbrklic 9Heprkno nepexo/ka B.neicrpoHa OT no.ny-
nposo/unfica K xemocop6HpoBaHHomy BeakecTBy H o6paTHo, KK 3TO 6bmo c/ke.nallo
JJrneKOTOpbIX Hp0CMIX c.rlygaes [15, 17, 18].
,r(oyaeH [4] c/ke.gaa HOIMITKy 011eHHTb 3Ty BeJnigHHy H AaTb efi 0,13HgecHylo
HHTepnpeTakuno Ha OCHOBe npocTo11 30HHOR mo/ke.nu no.nynposo/kHHHa. ECJIH
Ant npeAcTameHHH pacampHTb, IICX0):01 H3 6onee coBeplueHHoro TOJIKOBaHHH
JIeKTPOHHOPO nepexo,ga, H IlpHHHTb BO BHHmaHHe npollcxo/makHe npH 3TOM
B oftemHom 3apB/ke SIBJIeHHH, TO OHH HmeloT 3BaHHTeJIbily10 HeHHOCTIa; B 9THX npe/k-
cTameHHHx, Bo-nepsbuc, no/kgepHHyro penialoakee 3HageHHe nose/keHH.H BzeHTpo-
BBB ppx HaTaJm3e H, BO-BTOPbIX, /kalla ynpou.keHHaH cxema mexaHH3ma 3JIeKTp0H-
nor? o6meHa.
C.ne/kyeT, 0,411aKO, OTMeTHTb, HTO gpe3mepHoe ynpokkkeHHe 30HHOR moikeJni
mo)KeT npHBecTH K OLLIFI6011HbIM 3aKJII0HeHHHM. HH B Hoem caygae HeJIb3H CHIlTaTb,
tn.? xemocop6HHB ra3os, HoTopme xemocop6HpyloTcH c 3axBaTom aneHTpoHa, npo-
kcxo/wr TOJIbK0 Ha 3JIeKTp0HHbIX HaTammaTopax H He MO)KeT npaHTHgecHH Ha6Juo-
/kaTbcH Ha AbipogHom HaTanH3aTope B HpliCyTCTBHH TKHX ra3oB, KaK CO, KOTOpbIe
TipH xemocop6HHH OT,PIOT 3JIeKTp0HbI 03CJIeJACTBHe BbITeCHeHHH ra3om, oTAato-
HAIM 3J1eKTp0Hbp. Kai( 6yAeT noHa3aHo HkuHe, peinaloakyro pOJIb B 3TOM
Bonpoce Hr?aernoameHHe noTeHnna.na croepmll Ham 3HageHHe xllmmiecxoro noTeH-
imam 3JIeKTp0HOB B HpaeBom caoe HaTamnaTopa.
143meHeHHe KaTaJIFITHHeCKOCI aKTHBEIOCTH
B0311IIKaeT BOIWOC, KaKHM nyTem HaTaannigecHaH aKTIIBHOCTb HaTaaH3aTopa
npH HOCTOSIHHbIX yc.noimix TemnepaTyphi .14 cocTaBa ra3oBoil ciaecH mo}HeT 6bab
bnpe,zke.neHHum o5pa3om H3meHeHa. 9TOT Bonpoc 6bui peukeH H aHalepHmeHTa.nbHo
nomBepxylen ii caygast pacna/ka. N20 [56, 59]. Kali noHa3aHo Ha pHc. 16, HaTaJtH-
THgecHaB aKTHBHOCTb NiO 3HaHHTeAbH0 Bbnue, gem CuO, HTO comacyeTcH c mane-
npHse/keHHumn paccy?H/kekummn. B comacktll C 3THM HaxomiTcH OfIbITHbIe ;Ian-
Hble [601 no pacna/ky ND Ha Abipotmoil CoO, HaTaJnaHgecHasi aKTIIBHOCTb HoTopoti
taca3a.nacb HaH6o.nee BbICOKOcl. KaTaJurritgecxylo aKTIIBHOCTb NiO B OTHOLIIeHHH
pacnalka N20, MO)KHO elite HOBbICHTb Ao6asKamFf He6onbunix KoJnigecTB Li20
(0,1-0,3 mo.n.%) 6.naro,kkapH noBbauernuo KoHuewrpauHH AbIpOK
Li20 +_-> 2 Li '(Ni) + 2 e 2 NiO.2 aa3) + (41)
? Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KATAJ1M KATAJ1113ATOPM 39
Bum x(e yBeJIHIMBaTb corkepwaHHe Li20 B NiO ,ao 3-5 MOJI. %, B pe3y.nuraTe
ger? npoHcxoArrr AaabHeinuee nosbnneHHe KoHuieHTpaHHH AbipoK 1611, TO B 3TOM
caygae BCJNACTBHe o6pa3oHaHHH 1,1Impoimoro 60.TIOTa>> IIHCAO 3.11eKTp0HOB B pernence,
HJ1H xrimmecicHil noTeHuriaa 3J1eKTp0H0B, HaCTO.TIbK0 ymeHbameTcH, TO ye.TIOBI4H
meHsuoTcH B o6paTHyD3 cTopoHy, T. e. B 3TOM c.nyirae xemocop6HHH fypasHeHHe
(37)1 He moNteT npoTexaTb C AOCTHT011H0c1 6ucTpoToil H CTaHOBYITCH CaMOM meik-
.neHHoci, c.neAoHaTeribHo, onpeAe.moateil cHopocrb Beer? npouecca craAHeil.
BmecTe C TM na,RaeT KaTa.TurrHgecKaH aKTHBHOCTb NiO (cm. pmc. 16).
100
80
80
It
ts 40
20--
0
oo
savvo N,"
W .Pr
'oit'A MI MI
rommennan u
cmestogma9
Peaxliuu
400 500 804, 700
Temmmvnypa..0
800
900
P H C. 16. 38BHCHMOCTb cTenenn npenpamennH a AnH pacnaAa N20 H8 CHO H NiO
C p83.11H4HIIIM coAepmannem Li20 H 41203 OT TemnepaTypm (no ray441e, rnanry
H 9Hreal0).
Coma raaa: 14% N20 H 86% BoaAyxa.
CKOpOCTb ram: 1200 cmspiac
aroT 31ccnepHmeHTaabHIA pe3yAbTaT MONKHO HOHHTb, paccm1TpimaH )Be
CTaAHH npouecca:
N20(ra3) N20-(0) e(R), (37a)
(cTaAHH C HC110J1b30BaHHeM 3J1eKTp0H0B; mexnetmasi)
N20-(1) --4D-(q)+N2(ra3) (42)
(cTaAHH HecrrpaabHaH; 6bicTpaH).
1/13 o6eHx npome)HyTotiHux peaxuHR, coroacHo OrIbITHbIM ,gaHHbIM (CKOpOCTb
pearcHHH pN20), craam nurpe6.neaasi 3neKTp0HOB [ypaBHeHHe (37a)] 5113.71HeTC1
meNieHnoti 14 noyromy oripeAe.rmeT CKOpOCTb xemocopouaa. 143 ypaaaeaasi (37a)
ANSI CKOpOCTH xemocopou,aa Ha Ab1p0IIHOM KaTann3aTope HbrrexaeT Bbipa)KeHHeit
N20
k 0- ?n(H?)
_?exp ( d-eVDIkT),
A .
P2?
dt N 2 2
a Ha 3./IeKTp0HHOM Kan:tam-rope
dnN20
kipN2o ? ngl) .exp ( ? eV DIkT) ?
- dt
(43)
(44)
^e nN('2)0-- HoHuewrpaHHH xemocop6HpoBaHHbuc mo.nexya N20 Ha 1 cm2 nonepx-
HOCTH H n(H) ? iconuewrparum rtbipOK HIM CB050AlibIX 3J1eKTp0HOB BO HllyTpeH-
? cpa3e. BTOpbIMH imenamn B ypaBHeHHH (43) HJIH (44) MON{HO npeneopegb,
(H
eC.TIH B nem:3?m corme r 7
D AOCTaTOITHO MaJIbI, a BO BTOpOM no Aocra-
TOLIHO BeJIHKO. CooTnercrnytomme HbipaxceHHH xis capiaH, icor/ra CKOpOCTb peax-
II,HH onpeAeaHercsi cTa,weil Aecop6HHH, Ha OCHOBaHHH ypasHeHHH (4) 6y,TlyT:
-dt = k2. no-?PN2o? nG3, ? exp (+ eV DI kT)
(45)
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
40 KATAJI143 .14 KATAJIH3ATOPbI
dn02
-F dt
= k4 ? nO71 ?PN20 - k5rt(011)?exp ( - eVD/kT). (46)
CKOpOCTb AeC0p6U,HH AOJIHCHa B IlepBOM CJIpiae [ypaBHeHHe (5)] BO3pacTaTb
c yse.rumemiem VD 14 KoHneHTpawix AbIpOK, BO sTopom [ypasHeHHe (46)] -
y6bmaTb c yse.rffitieHHem KOHL1eHTpaHHH CB060,1111131X 9J1eKTp0H0B, HO pacn4 c yse-
JffiveHHem VD. 011bIT noATsepTau 9TOT Bb1B0,11 [59].
AJOI CJITIaH 9J1eKTp0HH0TO OKHCJIa noKasaHo [62], 'TIT? no mepe yseallge-
HHH Ao6as0K Ga203 K OKHCH UHHKa. sHeprHs aKTHBa11,HH pacna,ga N20 HOBb1-
inaeTcsi OT 48 ICKaA I .410.0 IIHCTOF0 ZnO AO 64 ICKaA1.41011b npH corkepwaHHH
1 - 2 mo.n.% Ga203. FlpoTHEtopelmsoe HmeHHe. Ha6morka.nocb ripH MaJIbIX Ao6as-
Kax Li20 (Ao 0;5 mo.n.%). 9TO HBJ1eHHe HaX0AHTCH B C1351314 C Tem, =no npH
110HIDKeHHH XHMHIleCKOTO noTenwana 3J1eKTp0HOB ('?-? In ne) y.nyvmaeTcs npouecc
2ecop6u,HH, npH KoTopoivi 9J1eKTp0Hb1 BbilleJIHIOTCH. flpH ,ita.nbHeilmem CHH}KeHHH
KoHu,eHTpawin CB060,414b1X 9J1eKTp0HOB scaeAcTsHe 110BbILIIeHHH c0,4epKaim51 L120
B ZnO Aecop6um y.nytiumeTcH, nosKulmomy, ewe 6o.nee, 04HaKo XeM000p611,1151
CHHHCaeTCH sc.neAcTsHe otieHb manor() npHToxa CB060211bIX 9J1eKTp0H0B, H TorAa
cxopocTb pacna4ta N20 onpeAezseTcH memeHHo npoTexalow,Hm nponeccom xemo-
cop6usH HO ypasHemno (38). Taxa! mexaHH3m 061,51CHHeT nosbaume sHeprHH
aKTHsau,HH no mepe 110BbILUeH1141 co,r(epwaHHs Li20 > 0,5 M0J1.%.
AHaJlOTHIIHaS1 KapTH-Ha na6.THQ1aeTc51 Ha ,rualpotwom NiO. Bc.neAcTsHe HOBbl-
memisi KoHu,eHTpau,HH AblpOK HO mepe ysemplewis ,ao6asox Li20 K NiO sTopoci
tizeH B ypasHeHHH (43) CTaHOBHTCA sce 6o.nbuie, a xemocop6uHs COOTBeTCTBeH-
HO - sce metibme; Taithm o6pa3om, c nosbuneHmem coAepx{aHlls Li20 (> 1 mo.a.%).
B NiO KHHeTHKa pacna,ga N20 HatuthaeT onpeileasTbcs sce ymeHbmatowefics
cKopocTblo xem0cop6aHH. Kai( BHAHO 143 Ta6J1H11,61, HaH6o.nee aKTHBHblifl xaTanH-
saTop HmeeT campo inisicyro sHeprmo aKTHBaLIHH H 110P511OK peaK141411.
143MEHEHHE 110P5lAKA PEAKIA1414 H 9HE1311414 AKTHBAU,HH
11P14 PACHAAE N20 aa N10-L120-KATA.11143ATOPAX
KaTaJIH3BTO p
MO c Ao6as-
Kamm 1.120,
noimepluaft
nopsukox
3lleprvg
aKTHBEIBB11,
tacaA I J1d0Ab
KoHge2Tpa-
BHA Abipoic
BO BH3Prpe2-
Heil 4123e,
IillipliHa
xpaeBoro
? C.BOB (rpy-
6asi ogexica
MOB. %
peamput
N20
moabubie
)IOBB
npm 4001,
A
0,1
8/4
15,9
-0,001
a(oao 1000
0,5
1
19,1
-0,005
< 1000
1,0
3/2
24,6
-0,01
< 1000
-
8/2
31,7
OKOJIO 10-4
> 1000
3,0
2
61,8
-0,03
< 1000
....
YmeHbweHHe KaTaiiHTHIleCKOri aKTHBHOCTH NiO npH Ao6as.nemix OKHCJIOB
C 'Jaime BbICOK0f1 BaJIeHTHOCTb10 (HanpHmep, 1n203,'Cr203) CTaHOBHTCA 110HATHbIM,
euni plecTb, =no Taime Ao6arocH 110HH}Ka1OT Kom.teHTpawno AbIpOK B pesyab-
TaTe tier? CHH1liaeTc51 cKopocTb Aecop6u,lill, KoTopas onpeAeaseT CKOpOCTI:a
scero npouecca.
Oco6eHHo HHTepecHoil Ka)KeTCH B 9T0PI C13513H 11113Ka51 KaTanHTHElecKas ax-
THBHOCTE. Ablpotmoti Cr203. Kai( 11oKa3a.im f,ay4)(1)e H tBJ1OK [63], 9TH .4131pKH
o6pa3y1OTCH He TaKHM CII0C060M, KK B CJ1yvae NiO, CoO, Cu20 H T. A.,
KOT,Ija B pesyabTaTe nor.noutemis H36bITKa KHcsopoita, T. e. B pesy.nbTaTe OT-
KJI0HeHlifl OT cTexHomeTpHH, nporicxoAHT 06pa3osaHHe 9KBHBaJ1eHTH01.0 tmc.na
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KATAJ1H3 H KATAJ1143ATOPbI 41
AblpOK H 9J1eKTp0HHbIX AeCPeKTOB. B AaHHom Hce czynae npollcxo,RHT r.namium
o6pa3om oco6oe HapywenHe pemeTHH no ypaltHemuo
Cr203 (6e3 Hy.TIb +Grp +ED. (47)
OTC/0)1a HCHO, tITO B caynae npHmeHeHHH Cr203 B KagecTse HaTanHaaTopa He 6y,nyT
HaTanHallposaThcH npomewyTotnibie peaHHHH HH rioypaBHeHHIO (37), HH no (39a)
100
80
60
20
+
kpefr4,
d
0,
0 rommemos
U elnegoefila.g
pearepu
?
I
400 500 600 700
Temnepamypa,?C
800
goo
P 0 C. 17. 3aBHCHMOCTb CTelleral npeHpaineHHH a AAA pacnaAa N20 Ha
pa341114HbIX oHHcaax OT TemnepaTypu.
nail (40a). TaKHM o6pa3om, Ao6aHneHHe HOCTOpOHHHX OKHCJIOB C KaT140HaMH Apy-
roc' BaReHTHOCTH He mo?HeT npaHTHnecHH H3MeHHTb HaTaoHTHnecHylo aKTHBHOCTb
(CM. pHc. 17).
B 06.1IaCTH HI43KHX H cpeAmix TemnepaTyp Hy)KHO ynHTbIBaTb npenmyine-
CTBeHHy10 xem0c0p6muo HHc.nopoAa C o6pa3oHaHHem o6lemHo aapsuHeHHbix Hpae-
BbIX CJI0eB, a TaH)He no.nsipHaausoHHHe SIBJ1eHl4S1 [641, B 0006eHH0CTH B Hana.ne
H runt ycTaHoHHHaTemcg xemocop6HHoH-
HOM pasHosecHH. npH 60JIee,..13b1COKHX
TemnepaTypax I1pHX0AHTCH CLIHTaTbCSI
C 3aMeTHb1M HHeApeHHem HHc.nopo,aa
B peuleTHy HaTa.nHaaTopa. Xemocop6H-
posainible aTOMbl micnopoAa npenpa-
ukaloTcH B 06b1,4HbIe 140H11 peIlleTKH npH
110MOLItH Bb1X045111414X H3 peinemn Ka-
THOHOB, HanpHmep, B caynae 1Lbipon-
? Cu20 no cxeme
0?(?) Cu20 + 2 Cu6 -I- 634.
FlpH HayneHHH pacnaAa N20 Ha
Cu20-HaTanH3aTopax, 110.11ytleHHbIX H3
JIHCTOBOri Me,E1H, na6mo,ita.noch [65],
trro xemocop6HposaHHbal N20 HJIH o6-
pa3pouudicsi npH 3TOM xemocop6npo-
BaHHb1ci KHCJ10p0,11 B 3HatIFITeJlbH011
creneHH pacxo,ayeTcH yxce npH 60? Ha
Aa.nbHecnuee oxHc.neHHe Cu. floc.ne
npe/(HapHTe.lbHoil 06pa6oTHH Cu20-Ha-
TammaTopa micaopoikom CKOpOCTb pacna,ga N20 HoapacTaeT B 10 paa
(cm. pHc. 18). Ha OCHOBaHHH 3T01'0 (Paicra mommo npeRno.nox(HTb, tITO nHcTaH
Aecop6HHH [ypasHeHHe (39a)] He Hmeer 3Ha4eHHH BO cpannefuno C peanuneft no
ypanneinuo (40a). lipeAaapnTemaan o6pa6oTHa HHc.nopo,nom Cu20-HaTanH3aTopa
06yc.nosammeT B npHHumne Te ?He aixpewrbi, 11TO H Hae,neHHe MaJlbIX KOJIHtleCTB
L120 (>0,3 MOJ1. %) B pemeTHy NiO, a HMeHHO: yHeoHneHHe HoHgeHTpausH
pOK B HpaeHom c.noe H noamHeinie aneprmi aHTHHanHH gecop6uHm, onpeAeasnomeri
100 200
Bpems, ham
300
P H c. 18. CHopocm pacna,la N20 Ha o6e3-
ra)He0140m (KpliBbie I H //) H HOKpbITOM 02
(HpHimie /// H /1/) HaTanHawrope Cu20 npn
600 (no ,E1enio, CTOHy H THaefi).
p02=100 H 15 Atht pr. CT.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
42
KATAJI133 H KATAJIH3ATORbI
o6inylo CKOpOCTb peaKu,HH. COOTBeTCTBeHHO, npeAHapHTeabHaH o6pa6oTxa Cu20-
HaTaJTH3aTopa napamH Hum Ao.n.H{Ha 3a,HepHamaTb pacna,g N20 Hc.HeAcTHHe 110H11-
>KeHHSI HoHnewrpaium Ampox, COIVIaCHO ypasHefuno (21). ECJIH 1-1p1IHSITb BO BH13-
ivianne 9TH saKoHomepHocm, TO CTaHOBHTCH 1.10H5ITHOrl 3aBHCHMOCTb xai'ajun'uqe-
CKOi OT TeMllepaTypbI H XapaKTepa npeiwapwreabHoti o6pa6oTHH
HaTami3aTopa. ,Lt.nH c.nyHaH, HanpHmep, pacnaAa N20 Ha c n
Ha...AeHo [66], 'ITO
sHeprHH aKTHBaH1314 JIHHeI1110 Ho3pacTaeT B HHTepHa.ne 11-42 1C1Ca.41Marlb c yse-
allmeHHem TemnepaTyphi npeAHapwreabHoil o6pa60TKH KaTamH3aTopa. AHanorHH-
Hym 3aBHCHMOCTb aHeprHH aKTHBaHHH OT TeMIIepaTypbI H npeAriapHTeabHoil
o6pa6oTHH Ha6m,ga.HH [67] TwoHe npH pacna,ge mypaBbHHoil KHCJI0TbI Ha ce-
pe6pHnom nopounte.
11.1Ha6 [68] cAe.Han nonbrrHy Ha OCHOBe 3J1eKTp0HHOr0 mexaHH3ma, COOTBeT-
ernyxngero BbIaienpime,RenHbIM npeAcTaBABHHHM, 06'b5ICHHTb HaTaJIHTFIlleCKoe
AefiCTBHe cPeppwra HHHKa, HansnomerocH 0HI3M 113 npeAcTaHkrreaefi unmHe.neti,
Ha pacna,g H202 H oicHcaeHHe CO. QHHaK0 B AaHHom caiyHae SIBJIeHHH OKa3aJIHCb
ropa3,zto c.nox(Hee, TTem B c.nyHae npocTux moic.Hos c xy6HHecHoil peineTKoti, Hcze,4-
cmHe HeAocTaToHkoro eme 3HaH1351 xapaxTepa 3J1eKTp0HHbIX Aeltoewros H mexaHH3-
ma 9.newrponposo,mocTH B LunHHeimx.
MexaHH3m OKHCJIeHHSI CO Ha TDepAbrx oHnc.nax
17potfeccu Ha Cu20-Kamanu3amopax. OKHCJIeHHe CO Ha Cu20 Hcc.rie4oHaH0
? o,n,HospemeHHEam onpe,n,e.neHHem xemocop6aHH KHCJI0p02La H OKHCH yr.nepo,ga
[691. Xemocop6aH5I HHcalopo,ga Ha Cu20, KoTopylo Ha61110,10JIH npu H3mepeHHH
azexTponposoimocTH, ? npoTeHana B HifrepHane TemnepaTyp 100-2700 311aHH.
TeJIMIO 6bicTpee, Hem oicHc.neHHe Cu2O. 9TH AaHuble yKa3b1Ba1OT Ha npeo6.na,gatow,y10
-xemocoponmo HHcaopoAa c o6pa3oHaHHem HpaeHoro CJIOR, o6orameHHoro AupHa-
MB, HoTopme H 06yCJIOSJIHBalOT II0BbIIIIeHHy10 3.11eKTp011p0BOAHOCTb Kpaenoro C11051.
ilajtee, oTcm,aa MO}KHO 3aKJHOLIHTb, xemocop6Hposaimbin HHc.nopojA 6o.nee
apeaHnHoHHocnoco6eHD, Hem KHCJI0p0A B pemeTHe Cu20. Ten.noTa xemocop6uHH
cocTaHasula 61 Kica.a/moith npH 5% OT maKcHma.nbHoro 110KpbITFIR H nommaaach
zko 55 ICKaAIM0.4b npH 50% II0KpbITHSI. 9THpe3PHDTaTb1 He Tpe6yroT npe,ano.nwKeHHH
O He0H0p0AHOCTli noHepxHocTH B CMbICJIe cTapux npeAcTaaneHHil. Bonee TOTO,
113 TeOpH14 o6pa3oHaHH5I Hpaersoro CJIOSI irpH XeM000p6IIHH M0)1(110 BbIBeCTH ypas-
Hume AJIST Tel-MOTH xemocopouni H1 B 3aBHCHMOCTI3 OT HpemeHH t C HCHOJIB-
3onannem ypasHeHHH" (16):
2ne 1
Ail ? ? 444 {(nOt,03?(nntl, (48)
e nil
ce
(n:19.)j?paHHoHecHaH KOHHeHTpaIIHS1 xemocop6HposaHnoro mic.nopolka
npH nocToHHHoft TemnepaType H ,Hamernin HHcoopo,ga, a hca.,?HazopmecHH11 KO-
3412131IlleHT nepecHeTa.
Ha pHc. 19 cxemaTHHecHH noHa3aHo noinpHeHHe Te1IJI0TbI xemocop6up
? yEseaHHeHHem HomieHTpau,Ha xemocop6HpoBaHHoro HeutecTHa Ha 110BepXHOCTI3.
ECJIH HacbnneHHbifi xemocop6nposaHHum Huc.impo,rkom Cu20-HaTanH3aTop
o6iia6aTbmaTb B TegeHHe HeCKOJIbKIIX Aller1 OKHCb10 yr.nepo,ro npH KOMHaTHOR
TemnepaType, TO o6pa3yeTcH CO2. ,aa.nee, xemocop6aHH CO npH 20? [70] npoTexaer
ropamo 6bicTpee, Hem HHc.nopoAa, a Hpome TOP0,?o6paTnmo. flpH aerHom Harpe-
BaHHH AO 50? xemocop6HpoBaHHaH CO Buorke.nHeTcH. B TO )He 'yew' 6bICTpbal
HarpeH ,Tto 100? 13bI3bIBaeT H3aHmo,aeficTsHe xemocop6Hporiamibtx MOJIeKyJI CO
C HOHaMH xuczopma, HaXOXIIIIHMFICSI B pemeTKeCu20, J11160 C o,n,HospemeHHo xemo-
cop6HpoBaHHumH aTomamH HHczopo,ga; oopa3pornasicH CO2 Aecop6HpyeTcH B ra-
30Hym c1a3y.
Ha nosepxHocTH Cu20, npeiwapHTe.ribHo o6pa6oTaHHal B HaHyyme, xemocop6-
JAHR CO, otieHb mana. B TO .}Ke HpemH B IlpHUTCTBIIH HHc.nopo,aa HJIH nocze. npe,it-
BapwreabHoll o6pa6oTHH nosepxHocTH HHc.impoikom. Ha6.mg1aeTcH 3HaHHTe.nbHaH
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KATARR3 R.KATAJIH3ATOPbI
43
xemocop6uHH. Ha OCHOBaHHH 3T01'0 FapHep H coTpyAHHKH [69] npHHHmatur CAB-
zytoutpai mexaHH3m xemocop6uHH:
CO2(?3) 0-() ---> CO;(0. (49)
JAWKHO HOHHTE) 310T CPaKT H 6e3 npeAnoawKennH
ecall HpHHHTb BO BHHMaHHB camcl)oTepHbicu>
T. e. pleCTb, B xemocop6HposaHHom COCTOH-
HHH CO2 moaceT HaX0AHTIICH B mike CX)i- H B BH-
Ae CO-. 11BpBaSI BO3MOM{HOCTb (aaxriaT aaeKTpo-
Hos) 0cymecianHeTcHrJlaBHblMo6pa3omnpHxemo-
cop6gHH Ha meTamax H Ha 3ABKTp0HHIDIX0KHCOaX
CBIDICOKHM XHMINBCKHM noTeHuHaaom aaexTpoHos,
B TO spemH KK OTAaga aaeKTpoHoH npoHcxoAHT
npeanotrruTeabHo Ha TaKHX KpHcTaaaax, y KO-
TOpbIX XHMHLIBCKHil noTenumaa AbipoKAOCTaTOMHO
BBRHK, TITO KK pa a ocymecianHeTcH B Kpaenom
caoe Cu20 B peayabTaTe npeAsapHTeamoil xemo-
cop604H KHcaopoAa. Ha OCHOBaHHH 3THX COO6pa-
xcemil MO3KHO cxemy (49) npeAcTaawrb HHatie:
1/2?2(raa) 0?(a)+G(R),
(49a)
CO2(ra3)? CO:.
(496)
K aTomy moweT npHcoe,itHHHTbcH peanu4H
0-(?)+CO,+(a) ?*CO:(*),
(49H)
BAH >ice
0-0) CO2(?3) CO;-(3).
(49r)
0 cymecTsoBaHHH.Komnaexca
3.1IBKTp0HHUA xapaKTep OD,
(n(60t \it
P H C. 19. Cxema yMeHbIlleH1451
Te11JI0Tb1 xemocop6uma Alli C po-
CTOM norseppmcmoil KOHneHT-
paLum xemocop6aposaaaoro Be-
mecTsa.
(r/))(?
0.?/t??paHHoHecHaH HoHRenrpa-
Him xemocop6HponaHHoro Huc.nopoAa
0)
Ha HOBepXHOCTH H ?COOTBeT-
CTBY1014HA BeJ7mH4eHHHHat. B melon' Bpe-
B IlpOTHBOTIOJIWKHOCTb ypaBHeH1410 (49) 3,rtecb npollcxo,AHT B o6Luem xemocop6-
11,1453 3.nexTpH4ecHH HeftTpaammix KOMIIJIBKCOB CO3, HoTopme moryT o6pa3oHaTb
?Hap6oHaTuble HOHbID, Kam K HHM IlpH6JIH3HTCH KaTHOHbI 03 peuieTHH HJIH ecoH
cam KaTaHH3aTop o6HaAaeT A0CTaT0,1H0 60JIMIIHM xllmHilecxmm noTeHu,Ha.nom
cHo6oxibix alleKTp0H0B. HOBbIe Hcc.ne,aoHaHHH KHalla H COTpy,AHYIKOB [71, 72]
OTH0CHTBAbH0 XeM000p6LIRH CO2 Ha IIIIIIIHeabHbIX ZI-10 ? ZnO/Cr203-KaTaaH3a-
Topax no,RTHep}H,rtaioT Hmuienpm3eikermbill mexami3m xemocop6H,HH CO2.
B HeCK0JIbK0 H3meHeHH0fi cloopme, HO coHepuleHHo anaaornimo FapHepy,
MONCHO npeAcTaHHTb cxemy H3aHmo,leikTHHH CO H mic.nopo/Ta Ha nosepxHocTsix
Cu20:
1/202 (ra3) (') ED(R) ? 55 KKal 1 I SIOAb, (50a)
CO(ras)-+G(R) ?4 C0+() ?20 ICKCl/11.410.4b. (506)
B npoTHHono.noxmocTb CO2 OKHCb yroepozka Hum xemocop6HpyeTcH c oTae
WIBKTp0HOB. flpH o6onx npoueccax xemocop6uHH Hp0HCX0A1T caeAyKaune no-
BepXHOCTlible peamuni:
CO+ (1) + 0? CO2x (a), (500
CO2X (a) CO2 (ra3) - (50r)
,
npn 3TOM CTaAHH (5013) npoTeKaeT meAaenHee HO cpameHmo c (500, H, TaKHM
o6pa3om, (500 H (50r) MOSKHO paccmaTpHsaTb npoTeKarolummll KK 6b1H OAHOM
al(Te:
C0+() + 0?() " CO2 (ra3),
C0(ra3) 0?() EB(R) CO2 (ra3) ?
(50A)
(50e)
flpH KOMHaTHOR TemnepaType neo6xottnmo THITUBaTb o6pa3osamne KOM-
naelica CO3 no ypamennsim (49) HRH (49a)--(494 FlpemmymecTHemoe npoTe-
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
44 KATAJ1H3 H KATATIMATOPbI
Kamm TOCI RAH HHOrl eTaAHH 6)/AeT 3aBHCeTb OT pacripejleneHHH AbIPOK B xpae-
BOM c.noe xaTaaH3aTopa.
PeaxHHH Ha NiO-, Cu0- H Zn0-xaTaaH3aTopax
COTJIaCHO KHHeTlitleCKHM Hccae,aoHaHHHm no OKHCJIeHHIO CO ripH 20?, CKO-
POCTb OKIICJIeHHH nponopuHoHaabua ,aarkrieHino KHeaopua, a xemocop6uH1 CO?
HaH6o.nee 6bicTpaH Haqa.nbHaH peaxuHR; B nom c.nytme cxopocTb npouecca
onpe,Re.rmeTcH craaleti xemocop6uHH mic.nopoAa, npoTexamueti no yparsHeHmo,
(50a) HJIH comacHo cymmapHoR peamum
CO) +1/202(ra3) CO2(ra3) e(R). (50)x)
B TO >1.0e spew' HH 6o.nee Bb1COKHX TemnepaTypax coe,rtyeT IIPHHHTb Apyrofi
mexaHH3m npouecca [2]. Mew/Ay 250 ii 725? KHHeTHKa OKHCJIeHHH CO Ha
NiO- H CuO4o.nbre He 3aBHCHT OT napuHanbHoro AaBJIBHHH xllc.nopoxta,
a nponopuHoHauHa napuHam)Homy ;waneImo CO. aro 6bmo ycTaHort.neHc.
B psuke Hcc.neAoHaHHIA [73 ? 75] B umpoxom HHTepHa.ne TemnepaTyp, HO 000-
6e11H0 npH 250?. flpH mmeperu4Rx saexTponposo,rtHocTH Ha Ni0 B npouecce
KaTa.rummecical peamuni o6HappxeHo, XOTH H He6oabwoe, HO 3ameTHoe 110H11-
}Kenne anexTponposo,n,HocTH KK AJIH peaxu,HoHHori cmecH CO ? 02, TaK H
02?N2 npH 0,111/HaK0BO 3a,laHHom napuHaabHom ,t(aBABHHil mic.nopo,Lka. 3T14
ikaHHhie yxa3bmaioT, Tim npH TIOBblaleHHbIX TemnepaTypax XeM0C0P6111151 KHC.110-
poAa npoTexaeT 6bicTpo, Tor,ga KK XeMOCOP611.1451 CO no ypaHHemmo (506).
a Tawe npsimafl peaxu,HH c mcknexy.namH CO no ypasHeHmo
CO(ra3) 0-0) e(R) CO2 (raa) (51)
npoTexaeT memeHHo H n03Tomy 5113JIHeTCH onpejLemnouleft cxopocTb npouecca
cTaAneti.
Tax KK a6comoTHoe qHCJI0 Ampox Ha norsepxHocTH OKHCHOTO xaTaaH3a-
Topa HMT 3HaveHHe ,zung cxopocTH OKHCJIeHHH CO, TO BTIOJIHe 110HFITHO,
aKTHBHOCTb xaTanH3aTopa npH 6o.nee Bb1COKHX TemnepaTypax cHHHcaeTcH Hc.ne,11--
CTBHe yMeHbLUBHHH ero 344exTHDHo4 noHepxHocTH ?B pe3y4bTaTe ocnexaHHso,.
a HmecTe c TM ymeHbumeTcH H KOHCTaHTa CKOPOCTH. 0006bICI HHTePeC npea-
cTamageT HarmeHHan 3aBHCHMOCTb 3HePTHH aKTHBBHHH -Ha NiO H Z110 OT Ao6a-
BOK KaTHOHOB C 60J1ee BbICOKOrl H HH3K0c1 BaJ1eHTHOCTMO, HanpHmep Li20,
Cr203, Ga208 [75]. B COOTBeTCTBHH C 110H11)KeHHeM KOHLIgHTPaIJAH Abipox B NiO
6.naroAapsi ,t(o6auxam Cr203 HaH Ga202
2E134+ I' t\2Cr 411 (Ni) -1- 2Ni0 +11202(ra3)
(52)
3neprnn aKTHBalIHH Ha NiO-xaTa.TH43aTope nonbunaeTcsi OT 15 ICKaill MO.0 (AJISI
11HCTOTO NiO) ;to 19 ICKaA1.4404b nocae Ao6aBaeinisi 1 moo.% Cr208. B c.ny-
qae 3J1eKTPOHHOTO ZnO, Hao6opoT, npH ,/106aBJIeHHH Ga203 11HCJI0 CB060,RHIDIX
3JIeKTPOHOB yHeaummaeTcH
Ga203 2Ga ? (Zn) d- ze+ 2Zn0+1/202(ra3), (53)
a 3Heprm aKTHBa1111H, pauHaH A.1151 inicToro ZnO 28 /Mal 1 I .410/1b, CHHWaeTCH
npH Ao6ameHHH 1 man.% Ga203 ,ao 19 KICaA I dlia/lb. nPOTHB0110J10>KHbIe COOTHO,
1.11eHHH Ha6mo1Ja1arc5I ripH Ao6aanemill Lip.
3aBHCHMOCTb sHeprith aKTHBBHHH OKHCJIeH1451 CO Ha NiO-xaTalunaTopax
OT co,ztepwaHHH Li2O MOWHO 0613FICHHTb cae,aylow,Hm o6pa3om (pHc. 20). Ecall
11PeATIOJI0)KlITb, peaxu,HR B3a1IMO,LIOICTBH51 MOJIeKYJI CO C xemocop6HposaH-
Hb1MH aTomamm xHcaopoAa no ypasHeHmo (51) (k Po) HansieTcH crameti,
onpe,Itemnomeil cxopocTb npouecca, TO nosbnueHHe xoHugHTpatum AbIPOK B Ni0
no ypasHemuo (41) npH p,o6aBKax Li20 normegeT 3a co6oil nommemie 9Hep-
CHH aKTHBBHHH H TIOBBILLIeHHe CKOPOCTH OKHCJIeH1151. 0,4HaKO, ec.nE .1ko6ama
Li2O HJIH COOTBeTCTBeHHO xoHueH-Tpau,HH AbIPOK CJIHII1KOM BeJIHKa, TO npouece
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KATAJIH3 H KATAJIH3ATOPbI 45
xem0c0p6uHH KHcoopoila 6yaeT BHepreTwiecKH HeBbirop,Hum, H TorAa xemo-
cop6usH cTaHeT peamweil, onpeAe.rulioluefi cKopocTb npouecca, noAo6Ho Tomy
Hai( ye onnetia.noeb B OTHOILIeHHH pacnaila N20. aro 6bizo 6b1 paBH0CHAbH0
TIOBblaIeHHIO 9HeprHH axTHBaukm npH 60JIee BbICOKOM coAepmaHHH Li20
(>1 MOJI. %), qToHa pHc. 20 He noKaBaHo.
aro Bax{ymeecH npoTHBopetme momcio TIOHHTb, ecoH ytlecTb, TO 110 mepe
IlOBblWeH1451 KOHlteHTpaHHH AbIpOK B KpaeBom caoe BaTa.ralBaTopa xemocop6uHH
CO no ypaBnemno (506) AeaaeTcH sHepreTHqe-
CKH 6oRee BbiroAHoci. ECJIH 3TH npe,ncTameHHH
COOTBeTCTBylOT AelleTBHTe.abHOCTH, TO MWKHO
30
no.nyturrb Ha IllicTom NiO-KaTaaH3aTope B Ka- lc,
tleCTBe HatlaTIbHOR 6bicTpoft peamum rJlaBHbIM 28
?o6pa3om xemocop6umo KHcaopoAa, KoTopaH no
mepe noBbnueHkui co,uep}KaHHH Li20 B NiO-Ka- z 24
-Ta.nHaaTope 6yAeT CMeHHTbCH xemocop6uHeil CO, g 22
OTcloAa c.ne,uyeT, tiTo npH noBbnueHHom.coAep-
)KaHHH L120 B3aHmop,eficTsHe xemocop6HpoBaH- ,1 fa
HbIX HOHOB KHc.nopo,Ra C CO no ypaBHeHmo
(50A) HJIH (50e) TepHeT 3HatleHlle, H 6yijeT
flpoTeKaTb npenmymecTseHHo KaTaJIHTHLIeCKaa
peaKuHH no ypasHeHmo (506), KaK HatlanbHaB,
22
11 no ypasHefuno (50w), KK cymmapHaH. Ha
20
43CHOBaHHII Toro cpal{Ta, TO Ha NiO?Li2O-Ka- z
a. 18
Ta.numaTopax k Pco, caeAyeT cin4TaTb xemo- I le
cop6uHio CO HaH6o.nee mexneHHoft H noBTomy
tC 14
onpeAe.nmoutefi cKopocTb npou il. ecca cTaane
'd 12
3Ta peammi npeAcTaBaHeT co6on oco6eH-
10
HO TIOpa3HTeabHbICI npHmep TOTO, KK mmeHe-
HHe BoHaeHTpaHHH AbipoK, BbiBbmaemoe Ao6aB-
Ho1l nocTopommx OKHCJIOB, MO)KeT cosepineHHo
H3MeHHTb mexaHH3m KaTaJIHTHtleCK011 peaxuHH. P H c. 20. 3HeprHH a KTI4BaltHl1
06cywAaembite SIBJIeHH51 ripeAcTaBneHbi cxemaTH- omic.neHvisi CO Ha Zn0- H NiO-Ha-
meciu4 Ha pile. 21. Ta.nHaaTopax npH yseoHgeHH11 co-
AepwaHHH 0, Ga203 H Cr203
KPHBaFI / noKaabmaeT naAe Lia
im
HHe 3aepr (no Illaa6y H &Twig).
aKTHBaU,Hil C BoBpacTaHHem coitepwaHHH Li20.
B COOTBeTCTBHH C ypasHeHHem (51) CHH)KeHHe BHeprHH auTHBaunil COOTBeT-
CTByeT yBea HtleHmo CKOpOCTH dlteC0p6LIHH. FlpH KpkITHIleCKOrI KoHueHTpa-
uHH , 4, czeijoBa.no 6b1 om{H,gaTb BoBpaeTaHHH 3HepTHH aKTHBaU1414 C yseame-
HHem co,r_kep)BaHHH Li2O COOTBeTCTBeHHO o6o3HatieHHoti IlyHKTHp0M KpHBOil I.
OAHaKO, coroacHo axcnepHmeHTaabHum LaHHbIM 1.1.1Ba6a H BJI0Ka (CM. pile. 206),
3HepTHH aKTHBaU1411 npH AaabHeflunix Ao6aBxax Li2O ocTaeTcH Ha HH3KOM
yponHe. 3ToT cpaKT CTaHOBHTCH HOHHTHbIM, ecau ytleCTb, UTO npu peon-
'WHIM KOHneHTpallaH Li2O B NiO xemocop6uH51 CO cTaHOBilTCH Bee 6o.nee
BbiroAHoci sHepreTHgeemi H TIH x BameHneT xemocop6uHi0 micoopolla (1TH-
BaCi 2). B.neso OT X MW Hmeem seerAa npeHmyinecTBeHHo xemocop6ukno KHC.110-
poAa, a BnpaBo OT x ? rnamium o6pa3om xemocop6umo CO.
flappaBaHo [74] Towe Hcc.nellorian OKHCJIeHHe CO Ha IIHCTOM NiO H C Ao-
6am(amx pa3.11111111b1X 1-, 3- H 4-BaJIeHTHbIX OKHCJIOB (Ag2O, L120, Cr203, Ce02,
WO,) npH TemnepaTypax 160 ? 250?. FIOJITIeHHble B 3THX OTIbITaX ki3MeHeHHH
3Hepr14H aKTHBaUHH He COOTBeTCTBylOT AaHHbIM II1Ba6a H anolta: noBbnueHHe
3Heprim alKeHHbIe KOpOTKO
B KHHTe FIOT3HCKOTO [82]. Pa6oTa B 3TOM HanpamneHHH ye lip0B01,HTCH.
Oco6eHHo HHTepecHyio rpynny xaTaaH3aT0p0s o6pa3y}oT cy.nbcto,nbi meTan-
J10B, KoTopbie xpacme Ba)KHb1 B xallecTse rwapHpyrow,Hx H ,II,erkutpuppoutHx
KaTankmaTopos [83]. Bb1.110 3amegeHo, 11TO CyJIb4314,13( HHKe.TISI oco6eHHo aKTHBeH
npH HeAocTaTxe cepu 11.1114 COOTBeTCTBeHHO npH H36bITKe meTazna. HaCKOJIbK0
Heo6xoalma npomeNcyrolniaB xpHcTa.n.mtlecKaB cpopma Ni
?.3-2, B HacTosnuee
BpemB eme HeJIb311 yCT3H0BI4Tb. 011eHb Ba}KHO 6b1J10 6bI HCCJIe7.1,0133Tb KITHeTHKy
xemocop6mul BoAopona H a.n4aTHcecKHx, a Taxwe apomaTmecionc coeiumeHml
npH op,HospemeHHom npoBeBRHHH,npocTbix peammil nul,pHpoBaHHB H ,nerHApHpo-
BHHHH Ha COOTBeTCTBy1OW,11X cy.nbcimi,Rax, HanpHmep NiS u CdS, C TOIIKH 3peHH51
H3J103KeHH0T0 npeAcTaaneHHB o porn! 3J1eKTp0HHbIX Ael:Peicros H SIBJ1eHlicI B Kpae
BOM czoe. 561.110 6bi BnanHe csoespemeHHo Ha OCHOBe Tenpin! 06pa3oBaHH1
KpaeBoto CJIOH H HapymeHHil pemenui B TBep,nbix Teaax paccmoTpeTb HatiaTbie
1.11TenHepom [80] pa6orbi no peaKuHH AerHApouHx.runaukui Ha Cr203 c Ao6aH-
Haw,' H 6e3 Ao6aBox TIOCTOpOHHHX OKHCJIOB, a Taioxe Ha MoS2, LITO6b1 ,1:10611TbC5I
60JIee courBeTcTsylow,ero HCTHHe 061HCHeHHC1 mexaHH3ma peam.um. 3Aecb moryT
npHrowbcsi, B cBeTe pa6oT BHHTepa [84], HeKoropme 1130T011131 oftsicHe-
HHH mexaHH3m'a peaKuHH o6meHa meKlly pearHpyloulllm ra3om H aTomamm xaTa-
J1H3aTopa.
AerHApHpoBaHHe TterHApaTaunsi cruipToB
Oco6bnI HHTepec B 3T011 CBS1311 npe,ncTaanBeT nonbrma [85, 86] 061.5:1CHHTb
,nerimpHpoBaHHe H AempaTau,fflo cnHyrot TJI3B11131M o6pa3om Ha ZnO H A1203
Ha ocHoBe ,nonyakeHHB 3H31-114TeJIbHOTO azeKTpoHHoro o6mena mexcly cmpTom
H OKHCHbIM KaTaoH3aTopom. flpexamKeHHbffi mexaHH3m mo)KeT 6b1Tb B11A0H3Me-
HeH B CBT e Teopm4 xemocop6u,H11, tiTo6bi 60J113111e IlpH6J1H31,1Tb ero K ,neficTBH-
TejlbHOMy mexaHH3my npou,ecca. Bo BCHKOM caytiae momulo TBep,no CIIHTaTb, t1TO
nanomieHHe HOHOB Zn H 0 Ha nosepxHocTH He moweT Hmem nepBocTeneHHoro
3HatleHH51 A.1151 H36HpaTe.THDHOCTI4 AeticTBHB, T. e. Aasi npe06aaAaHHH peaKusH
AerpLapHponaHHH J11160 AerKapaTau,HH. npeAHapwreabHum ycoomem Ansi npoTe-
KaH1151 pealouni B onpe,ne.neHHom HanpaBaeHHH 5113J151eTCSI XHMIVIeCKHII noTeHuHaa
9.11eKTp0H0B 14.1114 noTeHuHan cDepmm B nanynposonHHKe (KaTamaTope) H noTeH-
usa.nbHbal 6apbep BAH 3.neicrpmecKoe no.ne KpaeBoro C.T1051, Koropoe npeop,oneBaior
Ha csoem nyTH 9J1eKTp0HbI npu o6MeHe. irkerupaTau,HH Haonponarionoro
cnHpTa npexiaraeTcH caeApaggi mexaHH3m:
(HH HH
HC ? C ? CH, ),,a3 HC? C ? CH3.i- e (R) ,
H OH ZnO I OH
H.q.)
Xemocop6nun vepes npoTonbi
H H ZnO H H
HC ?C ? CH3+ e (R) -- HC ? C ? CH3
I OH I \
H+(0) 1-14-(0) OH?(?)
XemocoptStum gepes npoTotibi II OH-Houhl
H H
HC? C ? CH3
i I
H+(a) OH?()
ZnO
(HH
\,.HC = C ?CH3)(ra3) 1120(ra3)
Aecop6u,nn
(54a)
(546)
(54s)
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
48 KATAJIH3 H KATAJIH3ATOPH
H COOTBeTCTBeHHO Aon AernApnponamin cAemitommil mexanm3m:
?113
H3C ? C? OH
ras
ZnO
3C? C ? OH + e (R)
H+(a)
Xemocop6u,na gapes rfpwroina
CH3 CH3
FI3C ?C? OH H3C ? G? 0-(a)
I
H+( \?) H+(')
XemocoOnns nocpeacTsom nepecTanoattn 9.4BKTp0HOB B moseayse
(55a)
(556)
CH3 CH3
-I-26(R) H2(ras) H3C?C--:=0 (55s)
I \
I1+() HI" (g)
Hecop6win soaopona
CH CH3
H3C?C=0-(') (H3C--C = 0)(ra3) e(R)
4ecop6u,an aneTona
(55r)
Bo H36e}KaHlie 01.1.1H6OK neo6xoximo etue pa 3 HaHOMHHTb, 11TO 110.110)KH-
TeJ1bH01 HJIH urpnuaTeabablii 3HaKH Ha OAHOM H3 aTomos mo.nexy.n 0603HallalOT
HCKJI101114TeJ1bH0 cocTosunie aapfula no OTHOIlIeHHIO K oxppsaiotHeil cpeAe,
H JIHIJJb B npe,geobnom czygae HOHHOCI cop6uan MO)K110 FOB0pHTb 06 OTIlatle
An6o o 3axnaTe.wieKTpona.
CONIaCHO BHKKe [86], Aecop6HHH aueToHa Ao.n>ima SIB.1151TbCH CTaAHeil,
onpeAeanKnuefi cKopocTb npouecca, nocKoabKy npeAnapnTeabnan aAcopounn
aueToHa TOpM03HT . AerKapHposaHHe HaCTOJIbKO, npeo6.11a,gaioulell CTaHO-
BHTCH AerimpaTaung. ECJIH cxema peaKHHH, sbipamcaemas ypasHeHmems (55),
npasmbHa, TO nosumeHHe Koiniewrpaum4 CB060,1(HbIX 3J1eKTp0HOB (HanpHmep,
nyTem Ao6anaentin 0a203 K ZnO) 40JI)KHO aamexurrb Aecop6unio aueToHa,
a smecTe c Tem H cymmapHylo peamuno AerHApHposaHHH. Hao6opoT, He6oJIb-
luBe Li20 K ZnO 6JfarO1lap$1 110IMKeHHIO KoHugHTpagHH CB0600E(HbIX
3J1eKTp0HOB AOJI}Klibl ycicopwrb AerimpllpoBamie. el1ecop6HHH so,aopoAa HO
ypaBHeHHIO (55B) AOJOKHa, nowanmomy, npoTeKaTb AOCTaT0qH0 6b1CTp0. FlpHH-
II1IlHaabH0 Ba}KHO 6b1J10 6bI 110Ka3aTb, He 6y,E(yT JIB ,11b1p0,1HbIe OKHCJ1b1 H
4)HAbI C HeBbICOK0f1 KoHnewrpaHHeil ,abipoic aytninimm KaTa.usaTopamH AerKapH-
posaHHsi, 9J1eKTp0HHbIe OKHCJIbI If CyJIMPHAbl?
06men so,gopoi:ka C AeriTepuem
OtleHb HwrepecHN B 9TOM OTHOLIleHHH pa6ona [87], BbISICHSH0111,He 3aBHCH-
MOCTb KHHeTHKH so,qopoAHoro. o6meHa OT A06aBOK nocTopymax OKHCJIOB K ZnO.
KaK SHAH? 143 pHc. 22, CKOpOCTb o6meHa naAaeT npH Ao6as.neHHH' Li20 K ZnO
ncaeAcTnne CH11}KeHHH KOHUHTpaIIHH CB0601Hba 3NeKTp0HOB, B TO we apemn
CKOpOCTb o6mena nonbiluaeTcn npa A06aBACHHH A1203, H ocofienno (32203.
STH peay.nbTaTbi 11pHBOASIT K BbIBOAy, CKOpOCTb Aecop6aHH no ypasHemno
(56s) HOHOB H+ 11 .D+_camaH mexneHHaH cTa.lH1. ECJ1H camp? nopruno Kara-
JniaaTopa ZnO cHagaza 110Kpb1Tb c.noem xemocop6HposaHHoro sHczopou, TO
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KATA.TIH3 H KATA.1103ATOPb1
49
noc.nemmil ye cnycTR Koponioe npemn scaeAcTnne BaailmoiletIcTann C
poom oyAeT yamen C nosepxriocT14; noyromy MO3KHO aanneaTb cae/ipouvio
cxemy peamnin:
H2 (ra3) 2H" +2e , (56a)
D2 (ra3) 2D+ (?) 2G(R) ObICTp0,
(566)
H+(')+D+(')d- 2e(R) HD(ra3) me,a.nenno. (56B)
B TO }Ke apemn B npncyTennin KHCJI0p0,LIsa anomie BO3MO}KHO oopaaonamie
Ha noaepxnocern KaTammaTopa xemocoponponammx OH--rpynn [87, 88]. Flpn
oopaooTKe B03,21)7X0M HJIH npn xpanem414 aKTHBH0r0 KaTannaaTopa (nanpnmep,
ZnO) Ha Boaayxe ero nonepxnocTb, noitpuTan no,gopoitom, CHOBa OKHCJI51eTC51,
npngem BCJIeACTBHe nown4 cTexHomeTplitiecKoro cocTana noaepxnocT14 CB060,11,HbIe
9J1eKTp0HbI, neo6xox4mbre ;win KaTannaa, npaxTmlecK14 HCIle3a10T, H KaTa.nnaaTop
B peayouraTe AeaawrnImpyeTcn. B 11pHeyTCTBHH xnc.nopma, c.neAonaTeabrio,
nponcxodin4T paapymenne 3a110.11HeHHOF0 CB060,4HbIMH anewrponamn o6oraulernioro
KpaeBoro CJI051. 0,IeHb Ba3K110 1103TOMy II0BepXHOCTb 9J1eKTp0HHOTO OKHCJIa nepe,a
nponeAennem peaKunki o6pa5aTbinaTB noikopo,tkom. Paamitimple OKHCJIbI mom46,aena,
no.abcppama H ypana, a TaKwe no.n4pamoaan 6pon3a CTaHOBSITC5I aKTHBHbIMH
B OTH011IeHHH ao,lopoxioro oomeria TOJIbK0 noc.ne o5pa5oTro4, anaaorninioff
aKTI3BaL1HH ZnO.
,[1a.abneilunie Aainible no mexamiamy peaKunii rnApnponamin italOT nec.ae4,o-
BaHH51 opTo-napa-npenpantennn no,aopo,ga na 011,HaMaTIIIITHbIX OKHCJIaX (nanpnmep,
Ti02) [90]. HakIeHO, tJTOycKopenne peaKurn4 H0,3, AericTsHem xnc.nopo,aa, naxo-
munerocn na noaepxnocTri TiO2, o5yczos.rieno, B OCO6eHHOCTH npn HH3KHX Tem-
nepaTypax (oKo.no ?183?), He xemocop6una KHCJI0p0,11,11bIX aTomon, a (1)1431111e-
cKoti a4cop6urret1 mo.nexya xmczopo,aa. Lame npn Amneamiori peaKunn (10 qac.)
np14 3THX TemnepaTypax HeJIb351 na6JnoitaTb xemocopounn.
linTepecnbrn maTepna.ri ,itaxyr pa6oTbi Karana H COTpy,LIHHKOB [91], na6.rnoilan-
wnx npn 484? Ha Karaan3aTopaxCr203?K20?A12036wiee 6bicTpoe npenpamenne
B TO.T1y0JI renTena, gem renTana. Ha TOM }Ke KaTam43aTope npn 280? nponcxow
npeAnotanTeabno o5men iketiTepasi B meginne, a npn 330??o6men B renTane.
arcioola cAe.nan BbIB0,71, apomaTnaannn napactinnos HT me,a.nennee, gem wieckf-
HOB. B TOM ?Ke nanpan.neHnn npono,anTcn ncc.ne,Aonafain IIJIaT3 H Tapacosoil
[92] no CKOpOCTH npenpainennn B TOJIy0J1 cmeceil renTan?renTen, renTan?TOJIy0J1
H renTen?TOJIy0.11 npn 480? na V205, nanecennom na A1203.
POIIIHCKH171 H coTpy,runnul [93] To?Ke BbICOK.351 KaTamiTntlecKan ?
aKTHBHOCTb OKIICJI0B H CyJH4H1(OB B OTHOLLIeHHH peaKunii rKapnponannn H Aern-
,apnponarn4n, a TaK>Ke unx.iniaaunn am4c1)aTkplecKnx ymeao,ztopo,tkon 11p0IICX0,1114T
3a CLIeT n0,11)314}KHOCTH CB060,41-1bIX 3J1eKTp0HOB. rpHCIXINITC H coTpy,AFIHKH [94]
ycTanaBonnaioT KatiecTsennbie CB513H MeKay 3J1eKTp0HHbIMH Aectiewram14 H KIIHeTH-
K011 peaKunn. Ha 3J1eKTp0HHOM M002 OHII noKaaaan, 'ITO npn ,Tko6aa.1em414 4 MOJI. %
Sip nao.rnoaaeTen maxenma.abnoe ynemmenne nosepxnocT14, a Talome MIIHH-
MajIbHaSI 3J1eKTp011p0BOAHOCTb. CliJIbH0e ymenbinenne 3.I1eKTp011p0B0,11HOCTII npn
400? 061,5ICHHeTC51, 110BH,LIHMOMy, TM }Ke mexannamom, TITO H npn na,Ren1414 npono-
,1nmocT14 na noccranomennom TiO2 C ito6aaKamn ZrO2 [95]. OTclozka c.ne,ayeT, TITO
aKTHBHbIM B OTHOLLIeHHH pacna,Eka yroeno,rtopoAa icaTammaTopom AOJDKBH 6bITb ne
monnoiken, a IVIo02. aro connajlaeT C BbICKa3bIBaHHFIMH FepnHrTorla H
[96], KoTopme CIIHTalOT OKHCJIbI 6o,nee aKTHBHbIMH xaTaanaaTopamn ,T(J151 cnnTeaa
apomanmecmix yr.nenojtopo,aon H3 aanclmTmecKnx.
Allexannvecxne cnoilcTna KaTa.nnaaTopos
FlpHrOAHOCTb KaTammaTopa o6yczonammeTcsi ne TOJIbK0 npannabnum 3Ha-
tiemiem noTemmana (Depm14, HO H ero mexanmecxumn cnoileTnamn (conponimenne
HCTIlpaHH10) H TepmnilecKoil ycToiltninocTbm. 3ameTnoe ocnexanneD KaTammaTopa
4 )(Hung, M
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
50
KATAJI143 H KATAJ1113ATOPbI
npH TemnepaTypax nposel.teHHH waTaawrmecworo npouecca He)weaaTeabHo, Taw
KK BCJIeACTBHe 3T01'O ymeHbumeTcH nosepxHocTb, a c Heii H tIHCJI0 aKTHBHbIX
LigHTp0B. ,I1,06aBKH L120 YCHJII1BalOT cneKaHne Zn0; Hao6opoT, Ao6aBwH Ga203
CHIDKalOT cneHaemocTb [871 9TH AaHHble comacyHyrcH c pe3youraTamH, no.nytiemibi-
MH J1H CKOpOCTH OKHCJIeHH51 Ha a-mai:lax nimxa, Taxwe Ha&no,ita.nocb [971
nosbnueHne CKOpOCTH OKHCJIeHH51 npn 1p6aaneHHH JIHTI451 H cnafi, no,zt ;Om:mem
Ao6asox BJHOMHHH51. 9TH SIBJ1eHH51Hmetur oomee 3HaTienne H moryT 6bITb npHmeHeHbi
TK)K KApyrHm OKIICHb1M 11 CyJ114:113AHbIM waTa.rmaTopam. 110.1160p0M COOTBeT-
.
cispounix HOCTOpOHHHX OKHCJIOB H FIX KOJIHtleCTB MONCHO tlacTo ,40614MCSI Han-
6anee 6naronpHwrHb1x ycaoHnti wara.nma.
IlpHroTort.neHHe AbIP0t1HbIX (p)- ii 3J1eKTp0H11bIX (n)-
KaTa.71143aT0p0B
Lia npHmepe HeCKOJIbKHX OT,ReJlEabIX peaxuAti noxamHo, Tao /psi oAHlix
peaxHHA TpeopoTcH xaTanmaTopm C Atupotwoil nposoximocTbio, Ansi Apyritx?
C 9.11eKTp0HH01:1. KaKHM )1{e o6pa3om iviowHo no.ityqHTb b1pOilHMe H 9J1eKTp0HHble
xaTannaTopbt. Boo6in,e B HOHHOM wpHcra.n.ne Ha6.11Io1,aeTcH .nH6o AbipottHaH p-,
JIH60 9.newrp0HH8H rt-nposommOCTb, T. e. cyW,eCTByeT H36bIT0t1Ha51 KOHI1eH-
Tpauna 9,newrpoHmlx-Ae4eicros im6o CB0601albIX 9J1eKTp0H0B, HaX0,11511.11HXCH cam
;Loma?. aro yrsepmeHme OCHOBaHO Ha TOM cpaHTe, TITO BC e OKHC,11b1, Cy.11b4113)1b1 H T. n.
ncer,Ra o6.na,usaioT 6o.nee Hall enee 3HatIHTeJ1bHbIM H36bITKOM meTanaa, Jui6o ero
HeAOCTaTKOM (OTKJI0HeHlie OT CTeXHOMeTp1111). l'13MeHeHHeM TeMIIepaTypb1 H napu,H-
aabHOTO AaaneHHH meraznokuta mowHo Hoo6uke H3MeHHTb xointeHTpalmo 3J1eK-
Tp0HHbIX Hapyinemin H no.nmweHHe noTeHuHa.na (DepmH B xaTammaTope, HO HeJIb351
H3MeHHTb xapawrepa HapymeHHil petueTHH. McHmogeHHe cocTaBASIKYT amcpo-
TepHbie no.nynpono,aHHxH, KaK, HanpHmep, CaO H PbS. B ainiom caytme momtho
HOCpeACTBOM H3MeHe111351 napuHaabHoro Aaanexpoi mera.n.nowka npenpaTnTb
na-
laJIbHyIO p,b1p011Hy10 11p0BOAHMOCTb B npeo6.naflawauyio 3J1eKTp0HHy10. 1'13 3T01'O
431awTa HuaHo, irro He06X0AHMO r114THBaTh. napullaribHoe itameHne meramouzta
npH nposefigHHH KaTaJIHT141.1eCKHX peaKIIHR. FlpH HaJIH111111 HelKeJIaTe.11bHOTO Hap-
11HaJIMIOTO AameHHH BO HpemH waTa.nHTHtiecworo npouecca MON(110 peKOMeHBOBBTb
mexteHne ?HcnomoraTeabHoro ram?, HamageHHe wifroporo COCTOHT B TOM, IITO6b1
BOCCTaHOBHTb HeH36e)KHO Hapyamembirf noi AeticTriHem Hewe.naTeabHOTO nap-
illiaabHOTO aBJ1eHH1 noTeHuHaa criepmH HJIH XHMHtleCKFIcI 110TeHHIlaJI ,11,b1p0K
H 9J1eKTp0HOB nposo,/tHmocTH B xpaesom czoe xaTamt3aTopa. Taxon mexaHmm
mower HMeTb 3liatienne B reTeporeHHom KaTaame n oco6eHHo xopoluo AeficimoHaTb
B COOTBeTCTBy1011.114X peawumix npx yczoHHH ,1106aBKH cambix MaJleHbK1IX KOJIHIleCTB
TaKHX Kaarpaanemici), KaK KHCJI0p0/1 H ceposofi,opo,a?
MeToit bl Hcc.ne,goBaHHA xaTa.nHTHgecxtix peaxitHil
aaHHaSI CTaTb51, 110C13511.1IeHHaci 113J1011CeHHIO HOBbIX npeAcTaHneHHil B 06JIaCTH
rereporeHHoro KaTa.nma c munocTpau,Heri HeKOTOpbIMH npHmepamH, He mower
HH B Koem czytiae npereHRosam Ha nonHuti OXBaT Hceil courrseTc-rapoLueA JIHTe-
paTypw. Ue.nb craTbn?AaTb XHMHKaM, pa6oTaKaumm B 06.71aCTH npomblimeHHoro
reTeporeHHoro xaTaaH3a, TOJIIIOK K HOBbIM HCCJIe/10BaHH5IM.
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HCC.11e,A0BaHHH.
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CTHO CO cneuHaancramH no crpywrype mo.neKy.n, no BO3MOWHOCTH C TOIIKH 3peH1111
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KATAJ1143 H KATA.11143ATOPb1 51
snexTpoimoro H3aHmo,1eficTHHH pearHpyiounix HeatecTH H npomemcyroxlimix
npoi.kywrou. Ha OCHOBe TaKoro o6cyKaeHH1 BbIFIBSITCH mexteHnbie cTaAHH npo-
Hecca, Korophie Heo6xoximo JIH60 KaTaJIH3Hp0BaTb, JIH60 3aTOpM03HTb (eCJIH OHH
HeAyr npou,ecc B H)KeaaTeabHom HanpaHaeHHH). Bo3HHKaioutHe npH 3TOM BO-
ripocur (mexaHH3m szeicrpoHHoro o6meHa npn xemocop6HHH H ,aecopaum, 110HH)Ke-
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TeKaHHe peaxHHH B )KeJ1aTe.1113H0M HanpaimeHHH) c.neA,yer pa3peuniTb nyTem COB-
mecnioti pa6oTbi XHMI4KOB H 1:1)H3HK0B?cnewiamicTos B 06JIaCTH 110.113111p0B0AHHKOH.
EcaH, HanpHmep, 6buto HafukeHo, t1TO cTameg, onpep,e.nsuometi KHHeTHKy, SIBJIHeTCH
.,aecop6HHH npomexcyroxmoro HJIH KOHegHOTO ripo,ayaTa, ripareaaiouosi C Bb14eJle-
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noTeHuHa.mHoil BOJIHbI 3J1eKTp0HHOr0 o6meHa) H HanpaszeHHem peaKHHH (i(erivipH-
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a Taxwe 110JIHOCTb10 110,11aBJI5!Tb HmenaTeAbHbie n060qHme peaKHHH.
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JHBaTopos. EnaHHoti Ilpe1w0CbIJIK011 1lCCJIe,a0BaHH1 AOJI>KHO 6bITb BbIHCHeHHe
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J1HTEPATYPA
I. Hauffe K., N at ur w is s., 25, 193, 1951.
2. Wagner C., Hauffe K., Z. E le k tr oche m., 44, 172, 1938.
3. Wagner C., J. c h e m. P h y s., 18, 69, 1950.
4. Dowden D. A., C hem. 1 n d., 320, 1949; J. C he m. So c., 242, 1950.
5. Anderson J. S., Disc. Faraday So c., 4,163, 1948.
6. Garner W. E., Gray T. J., Stone F. S., P r o c. R o y. S o c., 197A, 294, 1949.
7. Schwab G. M., Block J., Z. E I ek t r oche m., 58, 756, 1954.
8. Krauss W., Z. E I.e k t r oc he m., 53, 320, 1948.
9. Benard J., In d. c him. Beige, 17, 553, 1952.
10. Taylor H. S., D i s c. Far a day So c., 8, 9, 1950.
11. Boudart M., I n d. En g. C he m., 45, 898, 1953.
12. Ilschner B., Hauffe K., Z. E le k t r oche m., 58, 382. 154.
13. Schottky W., N a t ur w is s., 26, 843, 1938; Z. P h y s., 113, 367, 1939; 118, 539,
1942; Schottky W., Spenke E., Vv i s s. V er 6f ft 1. S ie me n s-W e r k e,
18, 25, 1939.
4*
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52 KATA.T1143 fl KAIA11143ATOPM
14- aaublaou.5., J. P Ii y s. (U.S.S.R.) 1, N2 2, 1939; Mott N. F., P r o c. Roy. S o C. S e r.
171A, 944, 1939.
45.'Aigraii P., Dugas C., Z. E 1 ekt roehe m., 56, 363, 1952.
16. Hauffe K., Engell H. J., Z. E 1 e k t r och e m., 56, 366, 1952.
17, Weisz p. B. J. C h e m. P h y s., 20, 1483, 1952; 21, 1531, 1953.
18,, Engell H. J., Hauffe K., Z. El e k t r oc he m., 57, 762, 773, 1953.
19., Bevan D. M., Shelton J. P., Anderson J. S., J. C h e m. S o c., 1729, 1948.
2G. Miller P. H., Semiconducting Materials, London 1951, 172ff; Hahn E. E., J. Appl.
Phys., 22, 855, 1951; Henisch H. K., Z. Phys. Chem., 198, 41, 1951.
21. anureuxo B. H., Crenxo 14. 14., 14 3 B. A H CCCP (cep. 4)143.) 16, 274, 1952.
22. Hauffe K., Block J., Z. Ph y s. C he m., 196, 438, 1951.
23. Mott, N. F., Semiconducting Materials, London, 5, 1931.
24, Engell H. J., qRandschichteffekte an der Grenzflache Halbleiter/Vakuum u. Halbleiter/
Gasraum>o, in Halbleiterprobleme, I, 249ff, herausgeg. von Schottky, Braunschweig
1954.
25. Tamm 14. E., Ph ys i k. Z., Sowletunion 1, 733, 1932.
26. Brattain W. H., Shockley W., P hy s. R e v., 73, 345, 1947; Bardeen J., Brattain W. H.,
P h y s. R e v., 75, 1208, 1949; Shockley W., Pearson G. L., P h y s. R e v., 74,
? 232, 1948.
27. Brattain W. H., Bardeen J., Bell System tech n. J., 32, 1, 1953.
28. Dubar, L., C. R., 202, 1330, 1936.
29. Bevan D. J. M., Anderson J. S., D i s c. Faraday S o c., 8,238, 1950.
30. Hahn E. E., J. A p p 1. P h y s., 22, 855, 1951.
31. VOlger J., P h y s. R e v., 79, 1023, 1950.
32. Brauer P., A n n. Ph ys i k, 5, 25, 609, 1936.
33. Morrison S. R., J. P h y s. C h e m., 57, 860, 1953.
34.?Muscheid Diss. Humbol d t?U n i v e.F., Berlin 1952; Ann. Physi k., 6,
13, 305, 1953.
35. Hedvall J. A., A n g. C h e m., 54, 505, 1941; Hedvall J. A., Cohn G., K 0 1 1. Z.,
88, 224, 1939.
36. M5glich F., Rompe R., P h y s. Z., 44, 77, 1943.
37. Rubin T. R., Calvert J. G., Rankin G. T., McNevin, J. A m. C h e m. S o c., 75,
2850, 1953.
38. Markham M. Cl., Hannan M. C., Evans S. W., J. A m. C h e m. S o c., 76, 820, 1954.
39. Suhrmann R., Z. E lektr oche m., 56, 351, 1952; Suhrrnann R., Schulz K., Natu r-
w i s s., 40, 139, 1953; Suhrmann R., A d. C a t. (B negaru).
40. anoanti C. 10., >Ka6pona F. M., >KO X, 13, 1761, 1775, 1939.
41. Taylor H. S., Strother C. 0., J. A m. C h e m. S o c., 55, 586, 1933.
42. Sickman D. V., Taylor H. S., J. A m. C h e m. S o c., 54, 602, 1932.
43. Taylor H. S., Liang Sh. Ch., J. A m. C h e m. S o c., 69, 1306, 1947.
44. Sastri M. V. C., Ramanathan K. V., J. P h y s. C h e m., 56, 220, 1952.
45. Taylor H. A., Thon N., J. Am. C hem. S o c., 74, 4169, 1952.
46. Burwell R. L., Taylor H. S., J. A m. C hem. S o c., 58, 697, 1936.
47. Williamson A. T., Taylor H. S., J. Am. Chem. So c., 53, 2168, 1931.
48. Smith E. A., Taylor H. S., J. ik m. Chem. S o c., 60, 362, 1938.
49. Boabxemurefur D. (13:, )K 4:13 X, 23, 917, 1949.
50. Boabaeuurreflu ci., Bonm-Bpyeauti B. J1., >K 9 T (13, 20, 624, 1950.
51. Fypeantr,U. B.,-To.acroft H. A., tieocpu.non 11. Fl., }K 3 T 43, 20, 769, 1950.
52. Kpbmosa E. C., ?K 3 T (1), 20, 905, 1950.1
53. Schwab G. M., Schultes H., Z. Physi k. C he m., 9B, 265, 1930; 25, 411, 1934;
Schwab G. M., Staeger R., von Baumbach H. H., Z. P h y s. C h e m., 21, 26, 1933.
.54. Schenck R., An g. C he m., 49, 649, 1936; Rabes J., Schenck R., Z. a nor g. C he m.,
260, 154, 1949.,
55.? Huttig G. F.; D i s c. Far a day So c., 8,215, 1950.
t56.- Hauffe K., Glang R., 'Engel! H. J., Z. Physi k. C he nr, 201, 223, 1952.
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KATAJIH3 H KATA.TIH3ATOPb1 53
57. Hauffe K., Trankler G., Z. Physi k, 136, 166, 1953.
58. Boudart, J. C h e m. P h y s., 18, 571, 1950.
59. Engell H. J., Hauffe K., Z. roe oche m., 57, 776, 1953.
60. Schmidt G., Keller N., Nat urwis s., 37, 42, 1950.
61. Verwey E. J. W., Haaijman P. W., Rorneijn F. C., C he m. Week b 1., 44, 705,
1948.
62. Schwab G. M., Block J., Z. P h y s. C h e m., 1, 42, 1954.
63. Hauffe K., Block J., Z. Ph y S. C h e m., 198, 232, 1951.
64. Weisz P. B., J. Chem. P h y s., 21, 1531, 1953.
65. Dell R. M., Stone F. S., Tiley P. F., T ran s. Faraday Soc., 49,201, 1953.
66. Cremer E., Marshall E., Monats h. C h e m., 82, 840, 1951.
67. Rienkker G., Bremer H., Unger S., N at urwis s., 39, 57, 1952.
68. Schwab G. M., Chimia (Zfirich), 6, 247, 1952. \
69. Garner W. E., Gray T. J., Stone F. S., D i s c. Faraday So c., 8, 246?1950;
Gray T. J., Proc. o y. S o c., 197A, 314, 1949; Garner W. E.,-Stone FS.
Tiley P. F., P roe. R o y. S o c., 211A, 472, 1952.
70. Stone F. S., Tiley P. F., Disc. Faraday So c., 8,256, 1950; Natur e, 167;
654, 1951.
71. Kwan T., Kinuyama T., Fujita Yu., J. R e s. I n s t. Cat alysi s, Hokkaido
Univ., 3, 28, 1953.
72. Kwan T.,Fujita Yu.,J.Res.Inst.Catalysis, 2, 110, 1953; Nature, 171,
705, 1953.
73. POrHHCKIIA C. 3., UeJ1141ICKag T. C., }K (10 X, 22, 1350, 1948.
74. Parravano G., J. A m. C h e m. S o-c., 75, 1448, 1952.
75. Schwab G. M., Block J., Z. Elektroche m., 58, 756, 1954.
76. ABrurnma T., (Dpocr A. B., }Ic (13 X, 24, 861, 1950.
77. Rienkker G., Burmann R., Z. anor g. C h e m., 258, 280, 1949.
78. Rienkker G., Birkenstaedt M., Z. anor g. C h e m., 262, 81, 1950.
79. Selwood P. W., B u 1 1. S o c. c h i m. Franc e, 489, 1949.
80. Steiner H., D i s c. Faraday Soc., 8, 264, 1950.
81. Wittig G. F., D i s c. Faraday So c., 8, 215, 1950.
82. Poganski S., Elektronik der Doppel?Randschichten und dfinnen Zwischenschichten
in Halbleiterprobleme, 1, 275ff, 1954, herausgegeben von Schottky W.
Braunschweig, 1954.
83. Kirkpatrick W. J., Nickel Sulfide Catalysts, A d v. C a t., 3, 329, 1951, New York;
Adkins H., Rae D. S., Davis J. W., Hager G. F., Hoyle K., J. A m. C h e m. S o c.,
70, 381, 1948.
84. Winter E. R. S., D is c. Far aday Soc., 8, 231, 1950; J. Che m. Soc., 1522,
1954; Houghton S., Winter E. R. S., Natur e, 164, 1130, 1949.
85. Eucken A., Naturwis s., 36, 48, 1949; Eucken A., Heuer K., Z. P h y s. C he m.,
196, 40, 1950.
86. Wicke E., Z. Elek troche m., 52, 86, 1948; 53, 279, 1949.
87. Molinari E., Parravano G., J. A m. C h e m. S o c., 75, 5233, 1953.
88. Roberts L. E. J., Anderson J. S., R e v. pure app 1. C h e m., 2, 1, 1952.
89. Holm V. C. F., Blue R. W., I n d. E n g. C he m., 44, 107, 1952.
90. Sandler J. L., J. P h y s. C he m., 58, 54, 58, 1954.
91. Karaii M. R., EpuBancicaB .TI. A., TpoclmmoBa 14. B., 14 3 B. A H CCC P, 82, 913,
1952.
92. 1-1.naT3 A. 43., TapacoBa F. A., }l< 0 X, 22, 765, 1952.
93. PoruncKuil C. 3., ,L1 A H CCC P, 67, 97, 1949.
94. Griffith R. H., Chapman P. H., Lindars P. R., D i s c. Faraday So c., 8, 258,
1950.
95. Johnson P., Weyl W. A., J. A m. C e r. S o c., 32, 398, 1949.
96. Herington S., Rideal E. K., P r o c. R o y. S o c., 184A, 434, 1945.
97. Gensch Ch., Hauffe K., Z. P h y s. C h e m., 196, 427, 1950.
Ilepeepo .11. Ane.4b6ayma, H. Ky.orcoeofi.
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'fort 4)040pHOii KHCJI0T61. Honston E. C., Yates L. D., Haunschild R. D.,
J. Agr. Food Chem., N2 1, 43-48; 1955, 6Ht5.n. 8 Haut.
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
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genna AnammonnficpoccpaTa 113 3KCTpaKHHOHHOr1 0:1)0C-
cpopH011 KHCJI0T131.
?clig.nbTp; 2 ?oca,urreab; 3 ?annapaT AJI51 Pa3NCHWel11151 OT-
OnbrpoBaHnofk neneuncii; 4?xcrtapitTe.nb; 5?KpacTannmarop;
6? ReFrrpHityra; 7?cmecwreab; 8? cyunuma.
C H p b e. 3KCTpaK11,0000y10 KHCJI0Ty, npumemiemylo B 01IbITaX, 1-10.11y11aJIH
03 aeo6omo11 c1130HH0IlMD ?If0d1413 eadamme waedieo wahedu 'eeedliedead
-0IfEJ odomiodAwawodu WaHHEEIOEEd90 3 I@1I1 amoted mrodedo 14313M0 EaLHHD
eirodedo (4311)10
Isturesoeud90 oda adaw OLI lewadoeo EH ElMicndLI
tswairatricra ododd31e9 waucu ow-plead 41HdOM3ic 011M110W SA1016011 'avad3 Ltommeti
-mead a isomemintoxeri 'empluad ewadolAvodu HaudEowdod, edoncleodu aweeoeudyo
eitairtmodu agh1c1f3 H?(ead 0' a)?EHaI1'131? 13311340 ISHHEEIOEEd90 HI30d0M3 ammtaw
011cIlfalllhEHE arialreuodu H311M0 ISHHEEIOEEd90 c1130dOMD ?E11.1,114l1a1fE 010a0HOHLIOdll
aHHEHOCUd90 a0HcHfOlHhUHE IllrOX3H0d11 ahUHH mem MEI 'Ow % ii> dewdano
eadadom `edoatiee ouiearnua ?ramrod edetmeeroupe otpeolk wode edll ?mtaultde
14311M0 aHH1EI0?E'd90 XHITIOIEHHWOILEH 'XIIHROlf3A a IISIT0/10dLI mianmodu (Demo
gH H dlillJdo If XHO1f11110 d LI aHHalfIcHAIOn,wfia.ww g'j FIHEEd `wactgo 1:1,iunoafl
-Read wevoxgoae alledveddoirx 151411ahS.1f011 131f11. 3inta1oli3 tiotidawaraxXelf edu
?HHHaIlWd04)0 INOHdiCIedELILIE a 1514HaH1Adius 1llfEMHHEOEI cST
ttdu a 'ampule emtalwratIA 0.10)1ENHH careen' aH ledAdadauwad aHH@WHH011 aam
-ipeetral/ 'adra./CITodu ettomee awamdratiA a0Hc1falHhEHEalf 01farelt ogc iedAdadau
-wad aH113HCHH0LI IfllIfEIE1303 110X1ail ///2 01, etnneddeadmom tide E '0/09'6g 011
IfEVELI VOXIcra 01 `11/2 09 E1f151fEWIDO3 atiedreddoirxeareuodu eenaddeatmom 141f3a
'YR g xmradtadu a eirusamedaniou amddlieadoexitaireuodu onmaddearmom anom
admAndu 0.10HhaH0M %L6 qD?IfkihAVOLI woitaintuodu 0 //72 9 r() Ed01fX aariadiun
-11034 Hdll aogt edu ?UH@WHIG rawamedeadu edu watt `aaemreo admicliodu "Tomtit'
H1311190 EH daetpre edodmaad EMaVOXFHI EH mdedlieadoirxearreuodu Berteddean
-Flom ?alTH9H 01AHHE314110 `1311llalfAMdlill A111a13HD .1.01151131k11dLI SWOIEOLI H `14H1311111f
-au uoriced9oo3aira1r HM3@h11IAI0HOME 011 EINAndL1 011111EdIHMIHOM eloattoll voxodu
?HI1110 a OHWOIAIE0110H aLh `OHItHEI X1cIHHEV XH1G EH *Ed01fX ///2 g`oWhaalf09 cI,Luwdal/
-03 IaM{01A1 ll aEact" HEH11013 mtairtmodu 151111B110EcI1f0113ll aUhiclf3 ',LOEE '11E110(111
'itude 'Imlay," mem `XHMEI `EIO?E.1 XIcIll1daH11 113OW3 EH 11101303 EU II0HaIlE130 *EHaIf
-H110d11 %917 aalrog on medal:too aedteo amittodovoidairaic. mroa `009-09 dAdadauwad
31farclauffi a weandedeadu tide Hann? edieg dawow dttidoirXHI/ 3}1{ aog ?mtairtmodu
0,10I311h EH varmeod000 ?waedieo o I01E109Ed H1f33 'W09030113 MIMES, eoedeireliA
dawow on Intdorxtel weirawed aairog aeaulmodu weamedeadu ad11?Ficatf" uodode
eadaAsedgo on adodxuad a EnaL a `14HHO1f0M axdau EH HWEEEJ HINHITIISVOXIO
69 toucavdedau ode Faxmiodu H O11H1f1101 aowevidoxoll
L-1-000Z1-0091700181-1700-?8dCl-V10 90/1-1-/LOOZ eseeiej -101 penaiddV
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
70 PICKOTIAEMOE TO11.1114B0 14 TIPOJIYKTN Ero nEpEpABoTicH
ranoanosogopona 11p0FICX0414T B npncyTcTsaH yxcycHoll KHCJI0Tb1, a B peammoH-
Hotl 4a3e npoAyier He1Tpa.n143yeTc51 seutecTsom Tana xap6oHaTa KaJIMI,HH AJIH
ymeHblueHHa KHCJIOTHOCTH pacTsopa. B npoTHsHom c.nyaae KHC.HaH cpe,na cnoco6-
cmyeT o6pa3osamo aq4eHHJI3THJIOBOTO craipTa. Pa6oTaie TemnepaTyphi HaXO,KSITCH
B npe,nenax 70-90?. FlosbnneHHe TemnepaTypu >90? npusoAHT K r1Unpo.nH3y
aTOMOB x.nopa E ,11Hx.nopitne c o6pa3osaHHem 9110KCH,1a. B3aHmoAeffcTsHe npo-
Aywros peamaiti c HepacTsopHmoci B soAe rameHoli 143BeCTb10 MO}KHO ocyntecTsHTb,
npHmeHaa 9THJIOBb1/1 CIIHPT B KatiecTse pacTsopHTe.na. HaCbIII1eHHOCTb crawToso4
(1/a3b1 peareHTom, onaemonomm ra.nomoso,nopo,n, o6yczos.nitsaeTca H36bITKOM
TBeimoro aueTaTa KaJIbUHS1 (pacTsopilMOCTI3 aueTaTa Ka.111,11H51 B 9THJIOBOM
amp-re sec. %). 06fludi imam OKHCH CTIWOJIa COCTaBJIFIeT -,83% OT Teope-
THtleCKOTO (HCX01 143 cTHpo.na, H3pacxop,0saHH0r0 Ha peamano).
HenocpeAcTseHHoe OKHCJIeHlle 9T14.11eHa
B Hacroaatee spew HenocpeAcTsemibim OKHCJIeHHeM 0J1e4H1HOB no.nyamoT
TOJIbK0 OKHCb sTH,neHa. 3ToT cnoco6 ponyaeHaa oidicH 3TH.neHa npesocxoAHT
cnoco6 no.nyaemia OKHCH aTH.neHa x.noprimpHHHum meTo,nom. Bo scex npomban-
JIBHHbIX yeTaHosxax OKHCJIHTejleM npH sToil peamm CJIYHCHT so3,nyx, xaTa.nH-
3aTopom?cepeopo. FlpespauleHHe 9THJIeHa B OKHCb sTEneHa conposoaQaeTca
He3HaHHTeJIbHbIM shitte.neHHem Ten.na-29,2 ICKAZAI Ata4b. flpM 110JIHOM C/Ellraiffla
amneHa )10 yr.nexHc.noro ra3a H BO,KbI BIDIKeJISIeTCH 317 xxcuLitto.o. arioxotga
B 9TOM c.nyaae He no.nyaaeTca, H 11060HHbIe peanum He npoTexaroT. 1109TOMy
BaHCHO He KOTTYCKaTb 110.11HOTO CHCHTaHHH, TK KK npH 9TOM ymeHbalaeTcH sbixo,n
snoxcana H 14o314141He Oen-
3 14 Hbl, nanytieinibie npn 110JIyKOKCOBaHHH FIJIH npH raanctinzaun yrii no,R itanne-
nHem, noaTomy caeAyeT ynomnnyTb, TO 9TOT cnoco6 npHroAen 14 AJI5I 011HCTKH
6e1-13HH0B. 3,ttecb 6yAyT oTmetieHbi TOJIbK0 pe3y.mTaTbi OH bITOB C 6eH3HHOM,
no.nytieHHhim ripH IIOJIyKOKCOBaHHH xamennoro yron.
B 33BHCHMOCTH OT Bbi6opa yCJIOBHIA rHApHpoBaHHH noapialar otmuleHHbal
ripoAyHT, cBoticTsa KoToporo H3MeH14IOTC5T B ripeAe.max, yHa3aHnbix B T36.11. 3,
Approved For Release 2007/11/05 : CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
78 HCXOTIAEMOE TOHJIHBO H HP0,11YKTb1 aro FIEPEPABOTKI4
Ta6Autia 3
01111CTKA BEH3HHA 1-10JIYKOKCOBAHHH non Aika.naHuam
floica3aTe.nb
MCX0AHUR 6eH3HH
nozyKoKcoBamin
0,1MgeHHHA
6eH3111-1170J1y-
KOXCOBaHlISI
Bec rips 150 ,
0,753
0,740-0,750
IirlaJTO KHI1eH1I, ?C
46
Tleperossercs, o6. %:
o80?
26
Ao 100?
60
95% Bb11{1411aeT ,go, ?C
170
Koseu Kunesss, ?C
,-190
Bpomsoe tisc.no, e/100.m.4
90
0,1--1,5
1:13eH0.111.1, sec. %
1,4
Coilepwasse cep', Bee. %
0,2
0,005 --0,070
FlpeAe.nai KIIIIeHHH Ot1HILIRHHOTO npoAywra OT.T1HilaIOTCH He3HaIIIITeAbH0 OT
npeAe.noa KIIIIeHH51 HCX0,11110TO CblpbH.
3aKa1otieHHe
IlpHroilHocTb KaTaminitiecaoil 011HCTKH no,a AameHuem CbIpbIX 6e1130.110B
AOKa3aHa Ha npawrince, a otnnueHHhal ripoAyKT o6J1aAaeT 00060 Bb1COKHM Kage-
CTBOM. B 3aBHCHMOCTH OT MeCTHbIX ye.nomifi npou,ecc MOYKHO IIpOBOAHTb 110,11 60,1Iee
BbICOKHM HJIH 6o.nee HII3KHM Aaa.neHmem, c BoAopo,i(co,ttep)aamumH raaamu 11.1111
C 11HCTbIM BoAopoottom. 113 pa6oTaxmmx yCTaHOBOK HaH6o.nmuyio Hp0H3BOAHTe.7113-
HOCTb amen ycTaHoaaa C Hp01,13B0,1111Te.11bH0CTb10 20 000 ml.mec. 3KOHOMIPleCKH
ae.necoo6pa3Hbi Taxace H ma.meHbithe yCTaHOBKH C IW0H3B0,411TeJlbHOCTb10 500 mimec.
Ha ocHose aToro meToAa nocTpoen PHA yCTaHOBOK. B CLIIA Taaace npucTyniuni
CTpORTeJ1bCTBy ycTatiomm 0x1HCTKH 6eHao,na LIQ Aaa.aeHHem.
B. 3axaperaco.
Hoseliunte pe3yabTaTbi mccaeixoBaimg rymycoB. Welte E., A ng. C hem.,.
67, X9 5, 153-155, 1955.
Haxo,4Hatmecff B notme oTmepume opramitiecmfe BetuecTsa o6o3ftagator
o6autm Tephuniom erymyo.). aror Tepmmi oxaaTamaeT rpyrinbi cambix pa3Ho-
o6pa3wba opraantlecaux Bemecrs, NTH KOTOpb1X B03M0)KHa Aa.nbHecnuaa XII-
MHIleCKaH Knaccwimucamist. CpeAx HHX oco6oe sHattemie HmekoT ryMHHOBble setae-
CTBB?rpyrma coemineHml HeH3BeCTHOTO CTpOeHHH, OTJIHIMICIIIMXCH 0,11HIIM 06W,HM
noKaaaTeAem---TemHofi oxpacKoti, ,rurnignoti jJiH rymyca (aHaJlOTHIIHER cnexTpu
a6cop6Lum). Fymkmoable Betnecraa o6aaAatur paaaHmHoil.pacinopilmocndo B pme
BOAHbIX aacTparuppoulux pearemos, 0c06eHno Aaloulnx me.nomaytc. peamuno,
HRH a neJ1OqHb1X COJIHX, H3 KOTOpbIX UH Ao6aBxe KHCJI0Tb1 BbmaAaioT rymimorible
KHCJI0Tb1.
1-la OCHOBaHHH 3TOTO csoricTaa BO3MWKHa HX AanbHetiman a.naccolni-
Kauuk.
CpeAx TyMHHOBbIX aeulecin aaampo p0J1b HrpaloT rymaHoabie KHCJI0Tbl,
pacTaopHmme B tue.noxm H abicawarsaemale KHCJ10TaMH. TH cowl-lei-am, o6pa3o-
BaBWHeCH B rickgse B peay.nbTaTe X.HMHIleCKHX HJIH 6Hoxiimmecimx peaminci,
Hmeayr xapaaTepnoe ,a.aa AaHmoii nomabi pacnpeAe.neHue. Ha OCHOBaHHH KOJI0-
plimeTpH4ecxxx xapawreimcnix momolo cyAirrb 0 HJI0A0p0AHOCTH 110,113bl.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
PICKOTIAEMOE TOHJIFIBO Ft TIPOAYKTbI Ero 11EPEPABOTKH
79
OIlpeorieJIeHIle ryMHHOBbIX KHCJIOT Ha OCHOBaHHH
C ex Tp os a6c0p6uHH
flpH Hcc.ne,noBaHHH cnexTpos a6cop6uHH TyMHHOBbIX KHCJIOT, sEcTparnpo-
BaHHbIX H3 nonem H no,LuseprHyTbix OTIHCTKe, pa3aHnaloT )113a THna: 6ypyio ry-
MI4H0By10 KHCJI0Ty H cepyio. 06a THria xapaxTepH3parcn noma3aTe.nEmH uEeTa.
flpH H3yileHHH MHOTOITHCJIeHHbIX enexTpos a6cop6uHH A.1151 cepHilHoro onpe-
,Re.neHHE num xmc.noT 6bi.nH Ebi6paHm BOJIHN ,TIJIHH011 472 ii 664 Jail, immepeH-
Hble npH sToil BOJIHN 9KCTIIHKLIHIT E4 FI E6 HCII0J1b30BaJTH AJIYI BbITIHCJIe-
HTIFI noxasaTe.nE uEeTa
E4
4/ =
'? /6 E6
Y 6ypux TyMPTHOBbIX KFICJIOT sHatieHHe Q4/6 COOTBeTCTByeT 5-5,5,
a y THITHLIHbIX cepbix rymHHoBbix micaur 2,2-- 2,8. B caynae cepoii rpm-lotion'
KHC.710Tbl noxa3aTe.nb urieTa B 3HatIHTeJ1bH0c1 CTerleHH 3aBlICHT OT coitepwaHHE
asoTa: C yneanneHHem coAepKaHHE a3oTa Haslino,ilaiarcH 6o.nee HH3KHe aliatie-
HHH. 06a mina KHCJIOT pelixo EcTpenararcE B npnpoi.te B tificTom mite. 06b1tnio
IlpHX0):(14TCH HMeTb ;lex) co crviecHmH, 'compile B 3aBHCHMOCTI4 OT 3HaneHHE
coAep)Kar 6o.nee 3HatufreabHoe KOJIHIleCTBO Cepa HJI14 6ypoff' FyMHHOBOh KHC.TIOTbl.
ECJIH H3mepeHHoe sHagenne npetuawaeT npeAe.n,
yKa3anHbliA xnE 6ypo ryMHHOBOil KHC.TIOTH, TO 34
9To caKtieTe.ribCTByeT 0 IlpHCyTCTBHH TyMHHO- 32 k - 9'71 10-3
BbIX BelnecTB, He BbICa)KHBaembIX KHCJIOTO .
30 0,776 -
TaK KK rymnHoebie KHCJ10TbI npH ,nocTaToxmom
pa36ameHHH 110,LTITHHHIOTCH 3aKoHy Jlam6epTa ? 28
Q 'I
6
i6
Bepa, TO E = kcd, a npH nocToEHH911 To.nunme
CJI051 E=kc. ZJTH psma ryMPIHOBbIX KHCJIOT 6b1- af
JI-! HamepeHbi KO3C140I41114eHTb1 9KCTHHKUHH (3Ha- 22
tleraisi k) FT maTemaimmecKH aPopmy.nHposaHa 20
11 /8
0_
6' 1
`?
3aBHCHMOCTb mexoly 3THMIT 3HalleHFISIMH H 3Ha-
tiennem Q4/6. KO3C14HLIPIeHTb1 9KCTHHKLIHH (3a-
Tyxamt5i) le, (k =- 472 .4c 11) MO&HO onpe,leawrb
ypaBHeH1110
k4 ?
a
b? Q
r,ne a 14 b ? KOHCTaHTbI BetuecTEa.
HakneHbi c.ne,nywnilHe npeAnapHTeabHbie 3HaneHHE 3THX KOHCTaHT (compue
)10JOKHbI 6b1Tb eme nposepeHN )1.1151 nanytienHE a6C0.7110THbIX sHatieHHA):
a = 9,71 ? 10-3; b = 0,776.
C ygeTOM 9TPIX 3HalleHI1 MONCHO TIOCTp0HTb KpHsylo, xapawrepH3yioulyio
3aBHCHMOCTb mexcAy xo3c1xlmuy1emom 31(CTHHKLIFTH k4 H noEa3aTe.nem uEeTa Q
(pHc. 28).
TaKHM o6pa3om, BO3M0)KHO Ha OCHOBaHHH HamepeHHH sHaneHHE Q4/6 tieno-
cpeitcnieHHo xcoopHmeTpwiecicH onpe,ue.nHTb KonueHTpaunto rymHHosoti KHCJI0Tb1.
onpee.nemig KoHniewrpaHHH Ebine,neHo ypaimieHHe
c=mE4? nE8,
a
1412 2
1 2 4 6 7 81/0
----- fe
? tt C. 28.
a 1
?riAe m = -' n , ebipa}Keuo B mn.n.aHrpammax rymmional KHCJI0TbI Ha 100
b a
cyxoi maccm).
TaKHM o6pa3om, Ha OCHOBaHHH H3mepeHHH Ailyx 3KCTHHKIIHIA ripH Asyx
somiax pa3.111,111H0fi AJIHHbI BO3MO}KHO ojkHospemeHHo onpe,neawrb u,BeToBoti THII
H KoHuempau,Hro rymimonoil KHCJI0Tb1. 0E1,.115I ynpow,eHHH TeXHHKH 143MepeH1-ISI
cKoHcTpyHporiaH HOBblfl cneuHa.nbHmil Ko.nopHmerp, TIO3B0J1511014Hfi BbITIOJIHATb
60JIbIllOe KOJIllgeCTBO cepHilimix aHaJIH308.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
80 HCKOHAEMOE TonamEo H IIPOAYKTH Ero HEPEPABOTKM
10pH3OHT
rymmuonue
KHCTIOTbl,
HBeTOBOti THIT
Q 4/6
KoHeHTpa-
111151 %
HaqaJlbHble
cra):011i.
nBeTOBOn
THn Q 4/6
KontienTpa-
HHH C. %
A,
5,40
5,09
12,96
0,43
A,
2,99
1,33
15,20
0,03
A2
2,88
0,49
13,70
0,02
3,17
3,40
9,14
0,49
B2
3,20
0,72
11,00
0,27
B/C
3,58
0,17
0,06
B KanecTEe npHmepa cepHAHoro HamepeHHH B Ta6mme npHEeAeno pac-
ripextenetuie TyMHHOBbIX KHCJIOT H Hana.nbHbnc cramil TyMHHOBbIX KHCJIOT B n0A-
30.1IFICT0R nonse (npocim.nb KHe3e6ex).
Taimm o6pa3om, B ropHaowre A1 H A2 npeHmylitecTEeHHo HaX0MITCH cepue
TymmiosmeKHCJIOTbI, Tor,na KK B r0p1130HTe Ao npeo6.na,1aJoT 6ypme tyMHHOBbIe
KHCJI0TbI, KOJIHtleCTBO KOTOpbIX BHOBb yaeoHnHEaeTcH nocae npoxoKgeHHH nepe3
1'OpH3OHT pa3mbn3a.
STOT oTmenaembdi B npocimne scixpeKT pameneHHH B 3Hat1rreabHoti cTeneHH
3aBFICHT OT painHnHofx meicrpo.nwrmecxoil tlyBCTBHTeJIbHOCTH 060HX LiBeTOBbIX
ninon.
Paa,ne.neHHe nyTem 9.nexTpolpopea a
HCXOJAH H3 paammoro pacnpene.neHHH 6ypbuc H cepux TyMHHOBbIX KHCJIOT
B OAHOCI H TOR )Ke HOTIBe H HaJII441451 cmeceti 060HX THIIOB B OTAe.TIbHbIX ropH3oHTax,
6bIJIH cAe.naHm nonbrrxH ,lanbHetimero paa,ne.neHHH TyMHHOBbIX KHCJIOT. 110,1(06-
Hoe paa,ne.neHHe yilaJI0Cb ocymecTEHTb nyTem
3.nexTpocpopeaa (pHc. 29). IIpH 3TOM 6ypaH
rymHHorian KHcaoTa, npeo6AaAaloinaH B ropH-
30HTe Ao H0P0JIHCT0r0 npalm.nH, Aa.na Ase
cppaxuHH uaera oxpw, Tor,na KK cepble rymH-
HOBbIe KFICJI0TbI, npeo6.na,nalowle B ropHaoHTe
H A2 6bIJIH pawle.neHbi ,t)a?Ke Ha 3 fziwaKHHH.
HenepemecTnamancH #am),HH B 3TOM HBeTO-
BOM THne H ckpanuin c Haft6o.nee HH3K011 CKO-
pOCTIDIO nepemeateHHH HmeaH HEeT ym6p11 co
c.na6o 4:1146.TIeTOBbIM OTTeHKOM. OpaKII,HH c HaH-
6o.nbuiell cKopomio nepemeineHHH Hmeaa Ko-
pHnHesyto oxpacxy. B ropHaoffre B Bce (1:)pax-
IAHH 060HX aBeTOBbIX THHOB nepeKpbu3a.n1cb
mexcAy CO6OCI.
Pe3y.lIbTaTbI Hcc.nejloBaHlici nyTem 9nexTpo-
cpope3a noxaabmaroT, TO npHHHTaH go CHX
flop Ha OCHOBaHHH CIlexTpapoTomeTpHtiecKHx
P H C. 29. 3nempo4ieporpammary- HamepeHnil 0,11110p0AHOCTb 6ypux HJiH cepux
MHHOBbIX KHCJIOT 113 1101130JIHCTO11 ryMHHOBbIX KHCJIOT He cooTaercTayeT
eHcTBg-
flO11Bbl. TeJIbHOCTH. TaKilm o6pa3om, caeAyeT npeAno-
JION{HTb, ecTecTsemiom o6pa3osamin
TOM H.TIH Apyroro usemEoro THna cymecTayloT napa.n.neabHo H omospe-
MBHHO npoTexamigHe macumbie npoueccbi, riplisoAsugrie K Komnaexcy, KOTO-
pbal npe,ncTamnHeT co6off CaMOCTOYITeJIbHbICI useTosoff TUB.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
L-1-000Z1-0091700181-1700-?8dC1-V10 90/1-1-/LOOZ eseele JOd pa/wick:IV
W Ix 9
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-EMO 141f311 1:101? 11If l'IOHVOJHdLI aemoug Isimaireeru I4diCIEdaIDAral, ISIIHaWHHOLI
IIHH31f311dLI0 1,1131AL1 }wan uointaelfamc q1i(HdH,L3Or1 14901,h `111faLHdOELL3Ed arl11dae1
-a1411101X111.313E1000 4,1,Ed9OVOU garnrunquou '101f01411 X14?10HHIAIAd 133XHITIO1AEHIf
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
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npH 10-15?.. Ilepecoa C. Heicpacoaa.
tE)
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
PICKOTIAEMOE TOIIIIHBO PI FIPDXIYKTbI Ero ITEPEPABOTKPI 85,5.
KHCAble cmonm nepoogooft CM0.1161. Strube11 W., C h e m. T ec h n., 7,
N2 3, 164-,--165, 1955.
FlpH ximmtlecicon o6pa6oTEe CMOJI HJ1H HX AeCTHJIJISITOB CepH0c1 KPICJIOT04
yoaaaReTcH pH,21 BemecTE: 1:13eHOJIbI H rnipHAHHoEhle OCHOBaHP151, a TaloKe CM0,11b1
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JIHeT C06011 CJION(11b1171 xlmnittecKHCI npouecc, elite He B110.1111e BbIACHeHHb111. Ha Kyma-
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HaX0)1,51TC51 B KHCJIbIX cmonax. refic.nep ycTaHomm, cio cepHaa K11CJI0Ta o6pa3ye1
C 9THJIeHOBbIMH yraeBoxiopoaamll HerrrpaabHbie KPICJIbIe 34:14phi. Bb1X0,4 TaKHX
OCTaT011HbIX CMOJI, KaK 113BeCTHO, Hechma 3HatmTe.neH. OJAHaK0 nepepa6oTKa 3T11x"
pcTaTEoE npeAcTamnHeT OtleHb CJIWKHy10 npo6.nemy, TK xaK cocTas no.nytmembut
CMOJI H KHCJIOT Eecbma pammieH. b1JIH 11p0BeAeHbI HHHHbI 011bITb1 H3E.netiemia
paCTBOpliTe.I151M13 113 KPICJIbIX CMOJI: 6HTymoH, CyJIbCPOKHCJIOT H CMOJIHCTbIX Beatecna..
41,J151 CBOHX 011bITOB asTop npHmeHE.ri KHCJIy10 CMOJIy C K0m6HHaTa ?OTTO 1'poTe-
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uEeTa c HenpHHTHEam 3artaxom; ee 11HaJIH3bI coe,aylouwe pe3y.nbTaTbi:
%coo HeriTpaammuopi. . 1,4--2,0 BA3KOCTb, CeK 20-27
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npli K11115111eH11PI C BO(01:1 9Ta cmoJta pa321e.nsulacb Ha Ana C/1051: 1) EepxHHili
COCT0511.1.114171P13 BO,LI,b1H 6yphix x.rionbeE H co,aepwam,m1 43eHOTICyJIbC1)0KHCJI0Tb1H ,apy7
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neperomm BeatecTna 9TOTO CJI051 c.ne,aylounie.
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TetieHHe tiaca C HaCblateHHbIM Ha X0J10,ay BO1HbIM pacTsopom x.nopHaa pTyTH
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9TOM 110,11p1a.TIPI cppaimmi C 11pHSITHb1M sanaxom.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
86
C.1(011AEMOE TOHJIHBO M TIP0,RYKTb1 Ero 11EPEPABOTKH
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fir.11b1. 110C/1eAHHe OT,E(eJISIJIH OT 11pH3M H BHOBb onpe,aenHAH HX TemnepaTypy
TIJIaBJleHHE, KoropaH oKa3anacb pasHoil 119-120,5?. THTp0BaHHe IIHKpaTa Aano
sHatieHHe moneKynHpHoro seca 383, noKa3bisaioulee, IITO 910 AHMeTH.T1Ha4itaJIHH
(mon. sec 385).
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KaK o6bigHbril cnoco6 pawteneHHH CeJleKTHBHMMH pacTsopwrensimH 6bin HenpH-
PABHHM BMW pacTsopHmocTH BTMX cppaKuHil notiTH BO scex oprampiecKm pacTso-
pwrensix. flpH neperomce HOHBJUI.TICH 3anax ceportonopoAa, H 6ymawKa, cmotieHHaH
aueTaTom csHHua, qepHena: JleCTHAJlaToonajtaa 11pHSITHb1M3anaxom. Ero loinnTH.rm
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C cemHKap6a3Hn0m o6pa30BancH TsepAblii rH2pa30H B mule CHHHX
n0Ka3aBLIIHri nocne nepeKPIICTaJLTIH3aLIHH T. 111.11. 136,8-137,5?. HaftligH-
Hbl ero MOJleKyJISIpHblit sec 130,1 noKa3bisaeT, qT0 9T0 MeTHZ9TH.TIKeT0H;
BbP4HC.IleHHblri e MOJleKyJ151pHbIll sec 129,16 COOTBeTCTBOBail cemmKap6a3oHy.
ttopaKHHH 4 H 5 compwanH 3HagHTe.TIbHble KommecTsa nkippona, nplicyrcTsHe
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TemnepaType npeAcTasnsa co6oti nnacTHqHylo qepHylo maccy npHHTHoro 3anaxa
C TemnepaTypoR KannenmeHHH 63?. 11pH sape 3Toro neKa c cepot H npollysKe
npoAywra peamum KHc.nopoAom s03nyxa o6pa3osanacb qepHag macca c Temne-
paTypoti Kan.nenaAeHHH 196?. TaKoft >Ice pe3yabTaT nanytieH npH KH115111eHHH neKa
C nepmafiraHaTom KaJIHS1. BbmeneHabie ac4anbTb1 IlpHrommi Ana nopowHoro
crpoHrenbCTBa. 17epeeoa C. Hercpacoea.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
L-1-000Z1-0091700181-1700-?8dCl-V10 90/1-1-/LOOZ eSeeiei JOd penaiddV
9141061 `IclireHdaLew alcIHINEIHOH auxoahuwwalapt aog ?HNIHM.LHH HINFIElaHHHWOilfa 3
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?1 ?Irgad a ratattasiddu sonquo FaudqvAEad ?adoainas xidataudtmomooria a3xtratoucE
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V0111.10EHO9 EaL3OhH1f0X 0.10M(11f09OH Alf0161H11-11 X plaiudawae9ott orlawandavaddauome
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EH otawanaluAo HISHIfa aH `Elf0HH9dEX 0LL13OhH1f0X OlfEakihHIfOilic H eadoalnaa
oda'muuurnomoma OEL13OhnIf0X OlfEllic1HOPIA HI1ItHN 0.10If3HXOWJA 3dmatrae9o17
?oommead 0110aHlf113A IAIOXAVE013 H 1A101f0WH1141
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-111fON XHalcIHOPI g ?ll'0HH9dEHIfH1140,L-U-IfHlalAIHV H If0A1f011fELOIIE-21 `If01A1011-1.1-H11
:c131WHYSH HWEINA1/0d11 HINFIHHea0d1411HCI111HOVH danacataerj ?ailHalf3H110 otrat'ox
-otiodu `odaullaw-aou IIHHOLIHM Nh0LN LIONEHlf9 `adAdudauistad }Ida IfOIAIH11-11 Eadah
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aa ott Amaodadau .(womada-u-al) HE1A91fHlf0I-U-111T-Vg-nuavonr-E`z NH)! ?HHELL3VOlf3
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L-1-000Z1-0091700181-1700-?8dCl-V10 90/1-1-/LOOZ eseeiej JOd penaiddV
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
88? OCHOBHOPI OPFAH14IECK14171 CHHTE3
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Hume itHmepa; 3TO oco6eHHo OTHOCHTCH K cepe6py H xaAmmo.
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a KOJIHTIeCTBO inimepHoro coeAHHeHHH Ho3pacTaao Ao 22,9%. llpH 6o.nee HH3KOrI
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
OCHOBHOH OPrAHHITECKHH CHHTE3 . 89
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peaK11,1451 cosepmeHHo He Hula. Topmomuge AerICTBile KIICJIOT, BO3MOJKHO, HB.IISIeTCH
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600 a B3onpornin6eB3oaa, KOHTaKTHafi Bacazwa-400 Auz, CKOpOCTb riponycKamia Bo31yxa-
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JIeHHH n-immoaa ycTaHosaeHo, LITO amomHHHeBbie 8111KM ybeaHtmsaiar B2-3 pa3a
Hbixo,a 2,3-,11meTHa-2,3-a11ifteHHa6yTaHa (Anxymoaa) 3a cLieT aueTocpeHoHa H Anme-
THJICI)eHH.TIKap6IIHOJIa. Ha116OJIMIIHri Bb1X0-,a ,11,Hxym0na paBHHJICH 27%, cliwraff
Ha npopearHpoBaHnnul H3onpornia6ef3oo. B oTaHtme OT n-usmona (sc.ne,acTsHe
OTCyTCTBI4H MeTHJibHOil rpynnbi B mime) 1130T1p0IIHJI6eH3OJI Aasaa JIHILlb olleHb
man() opraHHgecmix KHCJIOT. nosHanmomy, nO.3TOR IIpFPIHHe KOJIWIeCTBO BbICOKO-
KHIIHIII,HX npo,ltywros 6bIJI0 0THOCHTeabH0 He60JIMIIHM, noTomy H{e H HOTaLII OKa3bI-
BaJI OqeHb He60abLuoe BJIHHHHe Ha peaKukno. nepeicHcHoe Immo npo,rkyKTa OKIICJIe-
HRH H3onponHa6eH3ona owl? Hume nepeKHcHoro THicaa npo,Ryx.ra OKHCJIeHHSI
n-numoila. nocae,aHee 06CTOHTeJIbCTBO, 1303M0)KHO, HIKTISIJI0Cb pe3yabTaTom 6oaee
HH3KO1l TemnepaTypbi peamuHH,- o6ycaosaeHHoii13 CB010 ogepe,ab 60JIee HH3KOri Tem-
neparypoR KI4I1e111154 H3onponHa6eH3oaa.
1130 3 onponlia6e83 OKHCJIHTeJIbHaH KOHAeHCaIIIIH Heorpa-
11141111BaeTCH TOJIbK0 ap0MaTiPleCKHM11 yraeHoaopo,Aamn H pacnpocTpaHHeTcH Ha
HX npoH3Boxibie. npu 133aHm0ilericTBH1i cmecH o-, en- H /2-XJI0pI430Hp0IIHJI6eH3OJI0B
C s03ikyx0m H B yCJI0BMIX 0IIbITOB 3 11 7 (Ta6a. 1) 6bIJI11 noaytieubi He6oabw1e
Koamiecisa awcaopHymoaa c sbuco,gom 1 H 7%. MCX0AHbIci npo,gyxT npeAcTaBaHa
cmecb xaopxymoaos, nosTomy He 6b1ao crte.naHo TIOIMITOK HikeHTHCIMII11p0BaTb
1BJ13110JA14XCA mintarropahm?-//pum. pea.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
90 OCHOBHOH OPTAHHHECKHH CHHTE3
TsepAbl' Allx.nopKymOJI, KOTOPbIFI npm 166-167?. npottyKT peaKaHH
coup)Kan mime x.nopaileTocpenox H XJIOARHHJIJIHMeTHJIKaP6HHOJI.
Mex a HH3M peaKaH H. 06pa3osamie pa3J1HqHbIX npogywroB OKHCJIe?
HHH moweT 6bITb 061HCHeHO CB060,3,110-pa1,HKaJIbHbIM mexaHH3M0M.
HeKOTOpbIe CTa14H 3TOTO mexaumma aHaJIOTHHHbI CTaAHSIM AAA 3KHAKO4M3HOTO
KaTaJIHTHReCKOTO OKHCJIeHHH 3THJI6eH30JIa (J. A m. C h e m. S o c., 70, 3764,
1948).
Mexammm nocTpmpyeT o6pa3onamie H3 fl-IIHMOJIa (I) CB060AHOTO paxama.na
AliMeTHJI-n-TOJIHJIMeTHJIa (II). 110CJIeAHH npespaataercsi B cooTBeTcTspompo
rHAponepemicb n-uxmo.na (III), KoTopasi npH palnoxiexim mo>KeT o6pa3osaTb n-me-
TwnaueToctoemoll (IV), AHMeTHJI-n-T0JIHJIKaP6HH0JI (V) H CB0602LHbIll pamiKa.ii CH3.
B pe3y.ribTaTe B3aHmo2eficTrim fl-LIHMOJIa H CB060,11HOTO 'pairsKaaa meTH.na o6pa-
3yeTcsi MeTaH H BHOBb perellepHpyeTcH II. B3ammo,rke1cTaxem Asyx MeTHJIbHbIX
pammanots HO.TlyHaeTCH 3TaH. TBePAbIH' cimmep, 2,3-1HMeTHJI-2,3-AH-rt-TOJIHJI6yTaH
(VI), o6pa3yeTcs, nOBHAHMOMY, B pe3yAbTaTe KOHAeHCauHH Asyx cao6o1U1blX
pamKanOB II.
Clig
I
,\
I 11 -1-CH3.
?3.
CH3? CI ? CH3
111
I H .
CH3 CH,
I
HI .11 ?
N'/
\b ' LCH,
CH,? ?CH45
CH3 CH3
I I
\ I\
I II --? HI ?*
N/
CH3?--CH3 CH, ? ? CH,
I
00H
Iv
CH3 CH,
11+11 CH3_()?\/ s1,-- CH,
_=
CH, als
III
CH,.
?o
CH,
I \
IN/II
CHs ?C ? CH,
81-1
VI
1VIeTaHoz o6pa3yeTc5I, BePOHTHO, B pe3y.nbTaTe c.ne,ityloamx peaKallft:
H3c. +0, H3C00.,
H3C00. H8cooRi,
(R' ? = II HJIII Apyromy cso60AllomY PaIIHKany)
H3cooR' H,CO. + R10.,
H,CO. + I CH,OH + II,
R10. + I R'OH + II.
fIplicyTcTspontat B >KW:Mal gAHMePHORD cpciaKtum 2-meTwri-2,4-AH-n-Tonan-
rienTax (VII) moiKeT o6pa3oabnatarbcs B peayabTaTe IIPHC0eAHHEHHH II K
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
OCHOBHOH OPTAHWIECKHH CHHTE3
91-
TIponenturro.nyozy (VIII)
CH3 CH3 -CH3
I \r ? ?I\ \11
11 d?!
CH
/N/ 3 \ CH3
CH3
CH3 ? C ? CH3 CH2 = C ? CH3
11 VIII IX
I+IX
CH3
I\ ?
) CI H3 &I, I 11
\CH3
CH3
+ II
VII
flpHcyTcTsHe n-H3onponeHanTanyo.na moweT 6bITb pe3YJIbTaT0M Aerwapa-
Taium AHmeTH.n-n-nankhnHap6HHana o6pa3yl01UHmHcst opraHmecHnmH KHCJI0TaMH
HJIH micnponopunomipoBaHHH HoRopo,na npn B3a11M011,eACTBHH II C Apyrnm CHO-
60AHLilm pamma.nom:
II + R. --> VIII + RH.
>KHAKaH gimmepHaso> 4ipaHm4H coAepwaza TaH}He -HeHoTopoe KOJIHIleCTBO
HeHaCbIrneHHbIX apomaTmecxxx yr.neHollopo,RoH, KOTOPbIe MOTJIH 06Pa30BaTbCH
npH peaHHHH paAHHana IX C Apyrkim cH000mbim paAHHanom no yparmemno
IX+R"? -->
CH3
RP
N/ 3 I j
/ \ CH3
CH,
X
ABTOpm He yrsepKnalar, wro Henpe,neabHble coeAHHeHHH, II0A06Hble X,
mor.nx o6pa3oHaTbcH Hc.neAcTaHe 11o.nHmepH3aHHH VIII no Hap6oHHeHomy mexa-
HH3MY, TK KK peaxu.HoHHaH cpeAa B HeKOTOPbIX CJITIaSIX co,nepwana opraHH-
qecithe KHCJI0Tbl. lloc.ne,RHHe 06Pa3OBblBaJIHCb npH OKHCJIeHHH 60K0B01 MeTHJIb-
HOfi rpynnbi n-uHmo.na.
HentefrruclmuliposaHHble BbICOKOKHIIIIIII,He KHCJI0pOXIIIbIe coe,z:LHHeHHH B03.
HHKJIH, BePOHTHO, B pe3y.nbTaTe H3aHmo,neficTHH5I cHo6o1Horo paxma.na IX
C KHCJI0P0A0M. Mar-lei-mug npH 9TOM B Haqecnte nepHimoro npo,nyHTa CB0-
602IHbici nepexHcHbdi pamHan MOT npespamTbcH B JUILIHMHJIOBbIfI CHHPT
110 MeXaHH3My, ornicaHHomy Bballe.
3HcnePHmeHTaabHasi qacTi,
Annap a Ty p a H MeT0 HK a. 011bITb1 nposo,nHaH B KPYTJIOAOHHOR
.1114'qm:toi1 H0.n6e, cHa6)HeHHoft THJIb3Ofi IJIIlTepmonapbi H HaniumnpHbim HHopom
11.7111 so3Ayxa, AoxoAHIHHm ;to IUHa Ko.n6bi. Ko.n6a c pearewram0 6blJIa npH-
coeoHeHa K PeKTH4/11KaIIHOHHO1 KOJIOHKe 34XPeKTIIBHOCTI,10 6 ? 8 TeopeTHqe-
CKHX TapeJIOK H HarpeHanachJU0 HnneHHH coxtepammoro. B03,RYX CO CK0P0CTb10
12 Aprac nponycHanH, HaH o61.ilinio, BTegeHHe 18 qac. ,11.q51 nomepHaHHH
IlOCTOHHHOR TemnepaTyphi clmermbi BoAHylo qaCTb AecTH.n.naTa no mepe o6pa-
30BaH1151 ee Y,RaJIHJIH epea neperoHnrio KOJIOHHY. 0Txomuun1 ra3 nponycHanH
qepe3 .noHyancy, ox.naw,naemyto THeNtoil YTJleKHCJI0T011 C augToHom. B HeKo-
Topux cariasix HecHowteHcHposasinylocH qaCTb rasa aHann3Hp0aanH. B 1KHAKOM
1Ip04H.Te onpe,nenHAH nepeHHcHoe qHCJIo H KOJIHIleCTBO KHCJI0Tbl.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
92 OCHOBHOH OprAHHtlECKIM CHHTE3
B OIMITHX, TIpOBOAHHILIHXCH 6e3 /(06au.neHHH yr.neHHc.noro KaJIHH, npottyHT
peaHuHli npomb13aoH ?VTR yfla.neHHH opratinuecHHx KHCJIOT -HbIM B0,11Hb1M pac-
Tuopom excoro HaTpa; flH 9TOM yAa.nu.nach H 6OJlbuJaHtlaCTb nepemicH. floc.ne
tne.notmon 11p0MbIBKH npoAyHT npombisaaH B0)1011 H CyinHJIH 6e3T10,1111b1M noTa-
wom. >KHAHHil npoityHT pa3r0H5.1114 B npHcyTcTunti He60J1bMOTO KOJIHtleCTBa
yroeHnc.noro Hamill, KOTOpbth Ao6a13.nuaH AAR ripe,noTHpanteHHu ,nerHapaTauHH
Kap6HH0JI0B. HenpopearHposamutth apomaTHnecHuil yr.neHoikopo,n oTroHHAH npit
aTmoccPepHom AaH.neHHH, OCTaTOK otpalutHoHHposaall c HaHyymom. Opamuno,
Hilnuntyto B npefle.nax KHrieHHH HeToHa H Hap6HH0.na, aHaati3Hp0Ha.nH nocpea-
CTBOM HH4)paHpacHoti cneHTpocHonHH. OCT9TOK ox.naxionaatt H ORPHJIbTp0BbIBaJIH
/1.1151 TOTO, T06b1 onpe,ne.rniTb KOJIHtleCTBO npHcyTcTsyrontero HpucTanatmecHoro
?Asmepa?. 143 n-utimo.na H H3onportm6eH3o.na 6b1JIH nanyneHbi KpFICTaJIJIHtleCKHe
npoayHTbi 2,3-AumeTun-2,3-,au-n-Toam6yTau H 2,3-Aumerna-2,3-1143eH11.116yTaH
COOTBeTCTBeHHO.
Hcc.ne,noBaHHe )KH,IIKOCTI4, KMI5IHer1 BbMle HeToHa H Hapanio.na, no.nyneH-
Ha H3 n-uHmo.na, noHa3a.no, Lao 6o.nee HOJI0BHHb1 ee COCTOHJI0 H3 1130MepHbIX
,T1H-fl-IMMOJI0B. 14H4)paxpacHbIti cneHTp um,nHoti AHmepHoti cl)paHHHH B pe337.11b-
TaTe oT,ae.nemiu OT Hee HHc.noponco,nepHaunix doe,ntmeHHil HilnuneHHem c HaTpH7
em i noc.ne CeJieKTHBHOTO rHApHposaHnu HmeHnnHxcH ABOt1HbIX CB513e171 yKa3biBaJ1
Ha coogepacaHHe BO CIVHKIMH TOJIbK0 napa-AH3ameinennbix apomaTHnecHllx yr.ne-
B01opOn0B.
CpameHme nozyneHHoro HtHivaxpacHoro cneHTpa co cnexTpamH tIFICTBIX
2,3-AHMETI4J1-2,3-Ax-n-Tomm6yTeHa s 2-meTH.I-2,4-AH-n-TanHaneHTaHa yKa3b1Ba,10
Ha ymepeHH3no HoHneHTpanmo nepuoro H OTHOCHTe.111,H0 BbICOKy10 HoHneHTpanwo
uToporo. OCTHTOK (1)paKIHM COCTOHJI 113 H3omept1bix yr.neso,aopoAoH.
MaTepHan hi. /2-14'UMOA BCTpfIXHBaJ111 CO CBeNCHMH 1101)1114FIMH 96%-Hoti
cepHoti KHCJI0Tb1 ,1110 Tex nop, noHa H3meHeHHe oHpacHH He CTaHOBH.110Cb OtleHb
He3HatillTeJ1bHb1M, npombusami BO.LL0i, neperomm C BOAHHbIM napom H3 cmecH
c 3%-Hum Bo/mum pacTuopom NaOH H pa3r0HHJIH Ha aCtxpeKTHEHofi Kon0HKe;
nTS 1,4902. HucppaKpacuaff cnexTporpamma aHa.norutma cneHTporpamme n-uH-
mo.na, npHse,aeHHoti B npoeHTe J\12 44 AmepuxaucKoro HeelyruHoro HHCTHTyTa (API).
H3onponuA6eH3art oxnuna.nu aHanorutmo ti-IMMOJiy; T. K1111. 151?, ni:`,) 1,4912;
InuPpaHpacHutl cneHTp corina,na.n c itaHHHIMH API B npoeHTe N.9 44.
XAopu3onponuA6ett3a2 nozynanti o6pa6oTHofi 830 e mop6eH3o.na 300 e H30.
nporm.nosoro crnipTa B TipHeyTCTBHH 2800 AM 80%-Hoti cepHoti KHCJI0Tbl no cum&
caHtromy paHee meTo/ky (Meyer H., Bernhauer K., Monats h., 53-54, 721,
1929). T. Hun. (PpaHHHH x.nopH3onponm6eH3o.na 185-1890, tzt3 1,5147-1,5157.
14cc.ne,gosamie nwlvaxpacuoil cneicrporpammbi noKasa.no, t1TO cppaxuast npeA-
cTaarm.na co6ofi cmech opmo-, mema- H napa-H3omepoH.
o y n e H.H e 2-M e T H H-n-T 0 ,11 H JI neHTaH a. a) 4-MeTH.n4
4 n-TOJIHJI-2-11eHTHHOH no.nyueH o6pa6oTHocr Tanyana OKHCb10 Me3HTHJIa B HpliCyT,
CTBHH x.nopHcToro aJHOMHHHH A m. C h e m. S o c., 70, 2123, 1948).
6) 4-MeTwa-2,4-An-n-TOJIHJI-2-neHTaHOJI npHroToH.neH HotuteHcautiefl Bbillie-
yKa3aHHoro HeToua c n-r0ommarimi16p0muitoivt (J. A m. C h e M. S 0 C., 70,
2123, 1948).
13) 2-MeTI4J1-2,41114-fl-TOJIHJIneHTaH no.nytreH AuyxcTainfilHoti peammeti,
B HoTopon suuteyHa3aHHati cnHpT AerHApaTuporsaH Hllnunermem co inase.ne-
BOA KHCJIOTOCI B TOJIyane 0cooTHeTcumomero o.napHHa, T. min. 127-128?/0,3
nf> 1,5605. 0.114HH CeJieKTHBHO rHApHposaH ripm 100 am H 80? B
CTB1,111 meinioxpomosoro HaTa.ntmaTopa (J. A m. C h e m. S o c., 75, 3323, 1953)
? 2-meTH.1-2,41(H-n-TommeHTaH, T. KHII. 132?/0,4 MN, ni3 1,5420. BbitMCJIeHO
JA.TIFf C20H26 : C 90,16; H 9,84; Harmello C 90,15; H 9,78.
,auhtemun-n-mamtAlcapounoA H n-Aiemu.4-a-htemuAcmtipa4 6bIJIH no.nyueHbx HO
meToAHHe al3T0p0B (J. A m. C h e m. S o c., 70, 2123, 1948).
OKHCJIHTeAbHaH x o eHcanHu n-H H M 0 If a. Coe,ainieR-
Hhie )1(14,11KHe cppaitium, o6o3Hatielmbie B Ta6.n. 1 KK Hal,11KOCTB, HHnuinau Hume
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
OCHOBH011 OPFAHHITECKNPI CHHTE3
93
240?, 6131J111pa3orHana HOBTOpHO. qaCTb, KHnsunan B npeAe.nax Ktmemni o,aHmepa?,
6b1J1 cHoBa neperHaHa HaA, HaTpHem 4,J1S1 yaa.neHnn KHc.nopop,corkep}Kammx npo-
AyKTOB. ,LIecTH.n.naT (T. Kiln. 132-145?/2 Atm, nt? 1,5454), co,aepicaumil
HenpeAeabHue coe,AHHemm (no nepmaHraHaTHori npo6e), ce.neKTHBHo rimpftpoBaH
no4, ikaB.neHnem npn 80? B npHcyrcTBHH me,nHoxpomoBoro KaTa.im3aTopa. Ko.nme-
CTBO nor.nomeHHoro Boaopo,Eka yKaBbmaeT, =no ?AHmepHoN cppaxuHH npkixo-
AHJI0Cb Ha 0.1141,111b1. T. Kiln. TputpupoBaHHoro npo,nywra 140-150?/2 "um,
a 1,5435.
anemeHTapnbth aHaJIH3 ilaCTH CeJIeKTPIBHO rHApHpoBaHHoro BeatecTsa,
T. loin. 141-144?/2 Atm, nn 1,5438, Ha KoTopyio npnxonprrcit 75% Bcero npo-
AyKTa, c.neAyionual: Bbitmc.neHo A.nyr C20H26 : C 90,16; H 9,84; HailAeHo C 89,76;
H 9,87.
YobTpacimo.neroBbiti cneicrpaabHmil aHaJm3 }1{14KOTO quimepHoroD n-unmo.na
Aa.n Te ?Ke 110.110CbI 110TJIOILIeHHH, II ,141151 TBeRaoro 2,3-AnmeTH4-2,3-AH-n-Tomm-
6yTaria, HO C 6o.nee 11113KIIM K0340141.1,14eHTOM nor.nomeHmi.
HfutpaKpacHbiti cnexTp noxa3a.n, xauman cAHmepHaB? cppammn n-unmana
npeAcTaB.rm.na B OCHOBHOM napalunamemeHHme apomaTmecKHe coexmeHHB. Ha-
Jumne no.noc 1795 PI 1910 cm-' HBJ151.110Cb SICHbIM AOKa3aTeJIbCTBOM napa-Ansame-
LueHHoci apomanmecKofi cTpyxTypm. 14HTeHCHBHOCTb 3THX 110.110C yKashma.na, LiTo
npaxTmecxn Bce nplicyrcTBylomme coejAHHeHHH?napalm3amelueHHb1e apomanme-
cxne Bem,ecTBa. AHaJ1143 noaTBep,rmacn IIIITeHCHBHOCI napa-no.nocoil B 06J1aCTH
820 c.4c1 H oTcyTcTmiem sterna- H opmo-no.noc B 06JIaCTH 780 H 760 cm-1.
B >Kw:ma ?immepHoilD ckpaximm n-unmoza, nomummomy, npHcyTcTBoBa.no
Ao 10% 2,3-,an-n-Tomm6yTana (110J10Cb1 950 H 1150 cm-1). FJ1aBHOri ?ice cocTaBHoil
qacTmo NKeT 6b1Tb npHmeHeHa BmecTo ee aHniztpH,aa AAR no.npieHHH I,
TK KK B 9TOM czynae B xaHecTse r.naimoro npo,nyitTa 3TIOKCHA311.11H o6pa3yercH
nepexHcb xeroHa.
3xcnepHm.e.HTaabHaH tiacTb
HavrpHcloTopyxcycHno KHCAOTy (I) 110J1y11310T Ao6annemiem
17,46 .m.4 (0,6 mo.nH) 85%-Hoil nepexHcH Bo,itopoAa K 116,9 a (0,794 momi) TpH-
dyropyxcycHoro aHrimpH,aa. aro KOJItIlleCTBO aHrH.EtpKna AocTaToHHo ;Iasi TOTO,
CBS133Tb BO,gy, Haxo,nsugylocH B nepemicH Bo,nopo.aa. ao6aB.r1eHHe H202 nposo-
MIT npH 5-10? B Tegenne no.nyropa tiacort. CT36HJIBHOCTb I Taxoria, MO)KHO
TIPHMeHSITI) H 60Jlee BbICOKy10 TeMIIepaTypy; 3T0 coxpain,aeT BpemH peaxHHH.
fl p 0 II eCC OK HC A e H H H. OKHCAeHHe Hp0BOUTBLIIHpOKOTOpJ10i1 emxo-
cTmo 250 MA xo.n6e apneHmeilepa, cHa6weHHoci TepmomeTpom, meina.nxoti H xane.nb-
H0/1 BOpOHKOA. Ko.n6y ox.naKaaioT Ha .neBHHoil 6aHe. LI,HKAHLIeCKHcl KeT0H Bo6aB-
JIHIOT K pacTsopy I B TpulyropyxcycHoci KHCAOTe; I 6epyT c 5%-Hum H36bITKOM.
,ao6aaneHHe xeToina BeAyr c 'Taxa CKOpOCTb10, IIT06b1 TemnepaTypa ocTaBanacb
B npe.ne.nax R
Ha 3T0 06b111H0 Tpe6yeTcH 40 MHH. THTpoBaHHe ripoBeAex-
Hoe HenocpeAcTBeHHo TIOC.11e OKOHIT3HHA IlpHJIHBaHHf1 xeToHa, noxaBbiBaeT HaAHHHe
I B cmecH B KOAHLIeCTBe, 6J133KOM K 0)KHAlleMbIM 5%. PeantHoHllyio CNI.tCb pa36aB-
.nmoT 250 MA x.nopos:Dopma H BhumBalar, nepememBaH H ox.naxiAasi, B HachnueHHIA
paerBop noTaula B xo.nmecTse, Ha 7% npeBbmialomem Heo6xoBlimoe Ansi HetiTpa.nx-
3111.114H. 41,063BJ15110T B0,71y AAR pacTsopeHHH Bbinamero oca,nita TpH4rropaueTaTa
Ka.111451; CAOH pamensuoT H BOAlly10 tlaCTb axcTparHpyiar nopuHHmH 100, 50 14 50 .MA
x.nopo4)opma. Bec cbiporo iipoBywra COCT3BASIeT AO 95% (TeOpeTWIeCKOTO), 11TO yxa-
3b1HaeT Ha masnyio cTenetib RAH OTCyTCTBHe rwripooH3a npH BxcTparHpoBaHHH.
LnopocPopmBbiA pacTBop cyinaT CeplIOKHCAbIM marimem, pacTsopwreab yilasnmoT npx
KOMHaTHOri TemnepaType c Baxyymom H npoziyicr neperoHmoT npH AaaneHHH 2 MM.
PeByribTaTbi onbrroB npeAcTas.neFibi B Ta6.nHue.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
OCHOBHOH OPTAHHtlECKHH CHHTE3
95
KeTon
Staxo71
npoilywra,
20
nD
T. 17J1. l'HApa3HAa, ?C
na3nanne
K0.11114e.
CTBO,
*NW
1110,00H0
Aannue
nwrepa-
Typw
natiAeno
amibie All-
TepaTypu
UHKJIOrleHTaHOH
0 0964
80,7
1,4613
1,4605
IIINKJ1011eHTFIHOH
0 0964
88,3
1,4600
114-115
114-115
1.1,14K.TIOreKCaHOH
0,1130
76,1
1,4513
1,4568
1.1,14KJIOITKCaHOH
0,1130
66,6
1,4522
105-106
105--106
IlpollasoaHTb OHCTKY pexomeHayeTcH HemearieHHo, TK KK B curpom
npo,ayicre, npocToRsmem 2 CyTOK 6e3 OT-IHCTKH, HailaeHo OT 10 ,i1,0 20% ripHmeceA
micAoTHoro xapakTepa; npH Hemea.neHHon otmcme coAepkaHHe 14X cocTas.nsier
2-5%. YkaaaHmale umppim flOJTHb1 THTposaHnem npo6, onmnemmix neperoHkoft.
I-IonbITKH OTIHCTKH neperouKoci H ,apyrHmH cnoco-
6 a M H. np0AYKT, no.nytieHHuri H3 0,106 MOJIH uHx.riorexcaHoHa H 0,0964 MOJIH I,
paaorHaH ripH 2 Aut ,71,0CT11)KeHHH B icy6e TemnepaTypu 150?. I-locale yaa.nem4H
TpwlyropykcycHoci KHC.TIOTbI no.nyHeHo 11,3 a seulecTsa KHCJIOTHOTO XapaKTepa
H 2,24 e sHakoro ocTaTka. To, HT? o6mge KOJIHTleCTBO MaTepliana npesbnuario Teope-
THtleCKH BO3MON{HbIcI sec oakroHa, a K034:1CIMItheHT pecfipammit ogeHb HH3OK, CBH-
AeTe.lIbCTBOBaJI0 0 aarpHarieHHH KaKHM-TO Ilp0H3BOAHbIM TpwlyropylicycHori KHCJI0TbI,
Hanpnmep TpwtrropaaeroxancanpoHosofi KHCJIOTOR. nOTIbITKH yaa.nHTb KHCJIOTHbIe
sarpHaHeHHH HarmanHammel TPH3THJIaMHBOM npHserm K 06Pa30BaHHIO TpyaHo
o6pa6aTbmaembix cHponos. HefiTparmaaum IIHPHAHHOM BbI3BaJla ocaacaeHHe
TaKHX 60J1bIlHIX KOJIHIleCTB TBep,aoro semecTsa npo,aykTa, TITO npormcr He (PHJIbTp0-
BaJICH. 34np, KK H npe,anoriararm, o6pa3osbisan c TpluirropyxcycHoil KHCJIOTOti
anoTpon, Ho otmcma nporlywra aaeoTponHoti neperomwa He npeacTas.HH.na npe-
HmyulecTs nepea o6mtmoil.
B JI HHHHe H36 bi TKa aHrHapH ,a a. lipoaywr OKHCJIeHHH, no.ny-
tieHliblrl H3 0,245 M0j1H umcnorexcaHoHa, 0,25 MOJICI I H H36bITKa 0,003 MO.T15I TpH-
4:rropykcycHoro aHritapima H CFOHBUIHt1 LO 011HCTKII B TeHeHne Heae./m, aa.ri 18,6 a
npoaywra, T. min. 121?/1,5 Aut, ni3 1,3934, 3KBHBaJIeHT HecrrpanH3aLmx 114.
MameHeHHe OKpacKH, KOTOPOe K cepeanHe THTposaHHH Hallam) HcHeaaTb, K KoHuy
CTaJI0 yCTOcIIIHBblM. TpHoirropaseToxcHxanpoHosasi KHCJI0Ta, KoTopaH aorpima 6buia
6b1 pearsposaTb c nepsbim mozem OCHOBaHHH HememeHHo, a co wropum-npH Hame-
pHMOri CKOpOCTII, HMT MOJI. sec. 228.
B JI HHHHe BO ;LW. K PaCTBOpy 0,1 mo.nsi 85?6-Ho il nepemicH soaopoaa
B 0,2 MOJIH TpwirropymycHoti KHC.110Tbl,Ro6aimeti LtilKJIOITKCaHOH.Cmecb nepemeum-
BalOT IIH 10-15?. nOCJIe o6aB.l1eHHsi 110JI0BHHbl Teopenitlecxoro KOJIlilleCTBa
KeToma sbmaaaeT 6e.nbnl ocaaok, scnbixHsaiounici npH nzas.neHHH Ha mnaTene.
T. no. 129,8-130,8? corriacyeTcH c seaHHHHoR 132?, onHcaHHoff AJIH nepexHcH
umcnorexcaHoHa (J. prak t. C h e m., 154, 219, 1940). flepeeoa B. Meptcasa.
TepmwiecKoe Damoxeithe anamanukponepeanceil. Thomas J. R., J. Am.
Chem. S o c., 77, Np. 1, 246k, 1955.
CymecTsyeT o6inge mHeime, LITO opraHmecicHe rHaponepexHcH HaIISHOTCH
asTokaTamiTHHecidimx npomexcyrotniumH npoapiTamH BO MHOTHX peaku,Hsx OKHC-
zemisi opraHHHemix mo.nexya MOJleKyJIHpHbIM KHCJI0p0A0M. MHorHe TeopHH
OKHCJIMHSI 06'bfICHHIOT pe3K0 shipa)keHHoe BJIHHHHe cTpoeHHH yr.nesoaopoaa Ha
JIeTKOCTb ero OKHCJIeHHH 3HaI1liTeJlbHbIM BJIHHHHeM cTpoeHHH Ha romorniTHHeckylo
TepmnHeckylo AHccomiatuno npommyrotmo o6pa3pow,HxcH nepexHceil no ypas-
HeHHIO (I)
ROOH --> RO. +OH'. (1)
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
96
OCHOBH0171 OPT'AHHTIECKHR CHHTE3
, Ha npeAnozaraemym 3aBHCHMOCTb CKOpOCTII OKIICJIeHHH OT TePMHTIeCKORCT011-
KOCTH ril,aponepexHceii BJIH11OT, KOHeT1110, H KOHKpeTHbIe yCJIOBWR AeficTspo-
mero mmeTwiecKoro mexam13ma. Ha OCHOBaHHH AaHHbIX no napo4pa3Homy OKHCIfe-
HHIO [1] H KHHeTHTleCKOMy HCTOJIKOBaH1410 12] BJIHHHHe cTpyKTyphi oTpmaeTcH Ha
113MeHeHHH TepmHtlecKoil CTOFIKOCTH amm.nrimponepexHcefi Ha BealltmHy nopfut-
xa 1000 pa 3 (npH 200?).
HecmoTpH Ha Ba)KHOCTb peammu Tepmullecxoro pamoRceHHH rH,aponepeKH-
ceil, TOTIHUX cBeAeHHil 0 Heti mazo. C 011101 CTOpOHM, 3T0, ?c.TreAcTimie HeAocTyn-
HOCTH- rHAponepemicefl, 3a Hcx.rnotieHHem HeMHOTHX 113 HHX, no.nriemie
KOTOPI1X He npeAcTasaBeT 3aTpy,rmeHHti, H C Apyr0ti---06ycz0BaeH0 CJI0)KHOCTMO
peammx p,a3.nmeHHH. B oAmix ycaoBHHx pa3.TioxeHHe rHAponepexpicell B pacTsope
npoTeica.no ABHO 110 nepsomy KHHeTmecKomy nopH,Axy, a B ApyrHx?no BTopomy.
13 HeKoTopbtx. CJITIaSIX 3T0 pa3aHtme, nomummomy, CBA3aHO C cymecTBoBaHHem
npH pa3.nmeHmi KaK MOHOMepHbIX, TaK H AHmepHux BH,A0B. flpaxTmecKH BO
Bcex Hcc.rie,loBaHmix rimponepexHcH BOBJIeKaJIHCb BO BTOplITIHOe HenHoe pa3.rm-
>keHHe, TITO ABJIaJI0 COMHHTeJ1bHbIM TOTIHOCTb H3ygeH11H nepBoHatia.mbHoro pacnaAa
no ypaBHeH1110 (1).
B OIIHCaHHOFI pa6oTe coo6ma1OTCH pe3y.ribTaTbI TepMHTIeCKOro pa3J10}KeHHA
B pacTsopax nepButmon, BTOpHT1H01 H iwyx TPeTHTIHbIX rHaponepemiceil. Ilpe,a-
no.naraeTcH, TITO Ii3MepHJI0Cb TOJIbK0 nepBoHaqa.THDHoe pa3amem11e.
axcnepHmeHTaabHaH tiacTL,
113.4tepettue ocopocmu. B 60JIbILIHHCTBe onbITOB B KatleCTBe paCTB0pHTeJIH
AJIA rimponepexHcefi npHmeusum 6e.noe meAHHHHcKoe MaCJIO. 3Heprmo aKTHBaIllIH
pa3.n0)KeHHH rHAponepexHcH TeTpamMa onpeAeasum Tame H B n-okTa,geKaHe.
HaTimbHaH KoHuenTpaumi rHAponepeKHcH 6bina 0,06 M BO Bcex caytiafix, xpome
Tex, B KOTOPMX H3ria.im BJIHHHHe icoHueHTpaHHH. (DeHH.n-a-HaqyrznamHH, HHTH613-
Top peamH4H, ynoTpe60HAH B KOHLIeHTPa11,14H 0,02 M. CKOpOCTII pa3J10}KCHH51 onpe-
Ae.TISLIII3 rips oT6ope ,I(J151 aHamma aJIHKBOTHbIX TlaCTefi nepemiceil 113 3axyn0peHHbix
CTeKJIHHHbIX cocy,goB c npHTepTbimm npo6KamH, TIOrpy}KeHHbIX B MaCJISIHy10 6amo
H TepmocTampoBaHHux C TOT-IHOCTMO ? 0,01?. flpOCTpaHCTBO Hajt yposHem A{H,TIKO-
CTH B cocmax 6bkno 3ano.r1HeHo a3OTOM, He co,aepB{au.mm Kilc.nopo,aa. 1-H,B,ponepeKHcH
wipe/lens:um no peaxHHH C HOAHCTbIM KanHem B cmecH J1eAHHOr1 yKcycHoil K11CJI0Tb1
H x.impocpopma B aTmoccpepe CO, c noc.nexiymamm THTpoBaHHem HOpMaJIbHbIM
TH0CyJI4aT0m.
_ Mamepuanbt. Bezoe me,ImumicKoe maul? npHmemum 6e3 Aaablietiludi OTIHCTKH.
ti-OKTmkeKaH 01114LUAJIH neperomwil. (DeHILTI-Ct-Ha4)THJIaM11H nepexpHcTa.rwm3oBbi-
BaJIll H3 cmecH 6eH3o.na H cnllpTa. l'HitponepeKHcb TeTpamma, npHroToB.rieHHylo no
meToBy, yKa3aHHomy B AHTepaType [31, nepeicppicTazaH3oBbmaoH 113 rexcaHa.
2,4,4-TpHmenumeHT11JI-2-r11AponepeKHcb no.nytieHa 143 wiegmHa 141 H otmateHa
Liepe3 HaTpHeBym COJIb. FHAponepexHcb H-OKTHJIa BbICOKOfi T-IHCTOTbI nanytieHa no
113BeCTHOMy MeT0,1_13/ [5]. FHAponepexHcb H30IIPOIIHJI6eH30J1a npHmemum B juvx,
o6pa3usax. FlepBmil (90%-Hoil KomieHTpaHHH) owl nozytieH oKHc.TieHHem H3onpo-.
nu.n6en3o.na c /lampBening oTrom{ok yr.nesorpopo,aa. ,apyroil 6bur otmmeH tlepe3
HaTpHeByto COJIb. Mem{,By 06011m11 o6pa3HamH pa3JIH,11151 B II0Be2teHH11 He Ha6mo,qa-
JIOCb. 11 emop-ByTHantaponepexpicm 6bum nanytieHbi no onHcagHomy me roAy [61.
P e 3 y Jl bTaT bI. 13ce H3mepemB1 cicopoctH pa3.BmeHAB BOTITH COOTBBT-I
CTBOBaJIH xkmeTnliecmim yparsHeHmim nepBoro nopHAxa. KOHCTaHTbI CKOpOCTII pa3-
.110}1{e11145lnepsoronopH,Rxa npH 148,7? ,I1JIA rHAponepexHcH TeTpaaHHa B6e.nom meAH-
HHHcKom mac.ne npH HallaJIbHOPI KoHueHTpauHH rHaponepexHcH 0,015, 0,03,
0,06 110,12 M COOTBeTCTBeHHO PaBHAJIHCb 61, 61, 71 H 79x 10-4 MH11-1, TITO yKa3bi-
BaeT Ha nepBbdi nopHAoK.
BCe CKOpOCTI4 pa3110.7KeH11FI onpe,ttenemA B ITHCyTCTBI114 0,02 M cl)eHHa-2-Ha41-
T11JIaMHHa, 113BeCTH0f0 B KatiecTse 11HrH6HTopa OKHCJIeHHA, o6.flaikatomero J1a611J1b-
flialM B0,11,0p0AHbIM aTomom. Ero yhoTpe&LHAH A.BH Toro, liTo6bi H3mepHemaH CKOpOCTb
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
? OCHOBHOn OPrAHHtlECKHPICHHTE3 97
I4Ctle3HOBeHHFIrkmponepemicll COOTBeTCTBOBaJIa CKOpOCTH Hatia.nblioilAFICC011,Hani1H.
CBH,LIeTeAbCTBOM TOT?, TO cpemia-a-Haciminammi 344eKTHBHO mirB6Hpyer uelmoe
painmemie n4Aponepemiceri, BB.nBeTcsi c.newomee: a) B pacTsopwreasix, Boiropme
344eKTHBHO mwqmpyloT Bemme paBamelme, 1Lo6aBika 0,02 M toeHHJI-a-HaCI)THJI-
ammia BbI3BaJIa minnwanioe ymem,meime CKOpOCTH pa3.710}Kem4; B pa3JIHIIHbIX
paCTI3OpHTeJIAX BJIHAHHe CileHHJI-Ct-HaCDTHJIammia Bcerika CBOAHJIOCb K ymellb-
memno Immepermoci CKOpOCTH 11Ctle3HOBeHH51 nepeKHCH H 13) HHKpeMeHTHaFI
3443eKT1413HOCTb BJIHAHHH 3TOTO BeIneCTBa Ha H3MepeHHyI0 CKOpOCTb pa3J10)KeHHFI
riaAa.na HyJI51 no Mepe yBeJIHtleHHH er0 KOHneHTpanHH. THHW1HBIM npFIMepOM
BAHRHHA 143eHHJI-Ct-Ha4YrHJIaMHHa Ha KlilleTHKy pa300){eHH5! SIBJISIeTCA H3MeHeHHe
KOHCTaHTbI CKOpOCTH pa3J10}KeHHA THApOnepeKHCH TeTpaJIHHa B 6e.TIOM Me011111HH-
CKOM MaCJIe npH 0,06 M Haxiamdfoci Boimeturpamm H 152?. flpH KoHueinpauHsix
4)eHHJI-Ct-Hal3THJIaM1Ma, paBHbIX 0, 0,01, 0,02 II 0,04 An
KOHCTaHTbI IlepB0r0
nOpSIAKa CKOpOCTH pa3JIMeHHA paBlISIJIHCb COOTBeTCTBeHHO 133, 99, 92
14 91 x10-4
,11.01 ruponepemiceil 2,4,4-TpHMeTHAneHTHAa-2, TeTpaAHHa, H3011p0IIHJI6eH-
30J1a H H-OKTHJIa 6bIJIH OnpejIeJIeHbI KOHCTaHTbI CKOpOCTH pa3J101KeHHH no nep-
Bomy nopmviy B HHTepBaJIe TeMIlepaTyp OT 120 jo 170?. MaKCHMaAbHaff pa3HOCTb
B KOHCTaHTaX CKOpOCTII pa3JI0)KeHH51 pa3.111411HbIX THApOnepeKHCeCI .npFI Hak160J1ee
BbICOKOR TeMnepaType OTIpeAeJIHeTCA KO34XIMInleHTOM 2. aleprBB amliBaum4 part-
Ha 29,0+1 ICKaAl MOIlb Ii THApOnepeKHCeil TeTpaJIHHa H 1,130npOTIHJI6eH3OJIa
H 26,9+1 KKaal MO/lb AAA THApOnepeKFICerl H-OKTHJIa H 2,4,4-TpHMeTHJIIIeHTHAa-2.
COOTBeTCTBylOLLI,He K034XIM4IIHeHTbI IlaCTOTH paBHbI 1,3x1011 H IX 101?CeK
3HeprIBI aKTHBankIH pa3J10A{efIHR rknIpOnepeKHCH TeTpaJIHHa B H-OKTaiteKaHe paB-
Ha 28,5 KlCalll ht0Ab
HOJITIeHbI Tal0Ke OpHeHTIVOBOtIllbIe 3HalleHHA KOHCTaHT CKOpOCTH pa3JIONceHHSI
AAR rll,aponepexuceri mpem-6ymna, 8mop-6yTmna H H-6yTHJIa (BCe IlpH OAHOrI
TeMnepaType). CKOpOCTH pa3.710)KeHHA 3THX BeLneCTB OAHHaKOBbI B rIpeAeJIaX K031:1)-
4)HuHeiaa 2 H He OTJIWIalOTCH OT COOTBeTCTBy10InlIX 3HatleHIA AAA THAp011epeKHCH
TeTpaJIHHa B TeX )1{e yCJIOBFIFIX,
0 6 C y }I{ e H H e. He6oabmoe pa3.7mtme 13eAkItIHH KOHCTaHT ? CKOpOCTH
pacriaAa yKaBbmaeT, tiTO BAHFIHHe CTp0eHHSI Ha TepMkPieCKy10 CTa6HJIbHOCTb
aJIKHJIbHbIX THApOnepeKH-Cen. HeBeJIHKO. FleAaBHO [7] npH H3ytleHHH TepmmecKoro
pa3110)KeH1351 BTOpHtIHbIX THApOnepeKHCeil, Bblorle.lIeHHBIX 113 OKHCJIeHHOTO Aexatia,
HaLeHo,TO B npOTHBOHOJIONMOCTb 06IneMy MHeHHIO Me)K,Iky CTa6HAbHOCTb10 BTO-
pill1HbIX H TpeTHIIHbIX rHApOnepeKHCerl HT CyIneCTBeHHOr0 pa3m4T411H. Ha OCHOBa-
HHH HCCJIe,g0BaHHA no.immemnalum pa3J1Ht1Hb1M11 rH,1ponepeKHC-
MB He,/jaBHO [8] 61IJI0 C4eJ1aHO npeArIOJIONSeHHe, TO pa3JIIPMe B HX CTa6HAb-
HOCTH He MO)KeT 6bITb BeJIHKO. TO IIOATBep)KAaeTCH COTIOCTaBJIeHHeM HMe10111,14XCSI
Ta6Atala 1
KOHCTAHTbI CKOPOCTH PA3JIMKEHH1 PA3JIPILIFIbIX 1-14,11130nEPEKHCE11 nPki 1500
raKporiepemicb
k X I 04 Him
A(E aim),
1c1c12.4 M0.41,
Pa cniopwrenb
.1111TepaTYPa
TeTpaninia
81
0,0
Beaoe mexi-
umicKoe maul?
Ornicauwe
HccaejloBamie
143011p0HHJI6eH30Jla
81
0,0
To me
To me
H-OKTHaa
56
0,4
?
? ?
2,4,4-TpnmenumeHni1a-2
56
0,4
? ?
?
tnpem-Byrkina
5
2,4
H-OKTaH
1101
4i1cnorexcatia
19
1,2
LIHKnoreiccaH
(11]
,L1examma
54
0,4
41exanmi
[12]
emop-Aewina
24
1,1
H-AeKati
[7]
7 XHAINTI, N2 1
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
98 0CH0BH0171 OPFAH1414ECKHII CHHT3 ?
KOHCTaHT CKOpOCTII nepnoro nopn,axa XI 51 peaKHHH pa3.Tio?KeHll5 rHAponepexHceii
npH 150?, npHnejteHnba B Ta6JI. 1. Pa3HOCTI4 3HeprHil axTHEtaw4H, BblIIHC.TIeHHbIe
B npeanoao)KeHHH, 4T0 (1)axTopm tlaCTOTbI jIJ151 9T0f4' cepHH pOACTBeHHbIX conieHHA
HAeHlwaHm [9], ,LkatoT OTKJI0HeHHe B npeAe.nax He 6oaee 2,4 KICa./11M0.46.
ConocTanaenHe 143BeCTHbIX Be.11 1411 I4H 3HeprHH aKTHBaLIAH pa3awKemin HeKOTO-
pux rup,ponepexHca, npHseiteHHoe B Ta6JI. 2, n0xa3hinaeT B ,ilsaHHom caytiae 66.71b-
nip? pa36pocalm0crb pe3yourwron, t1TO oc06eHHo OTHOCHTC51 K mpem-6yTHarnApo-
nepexHcH. flonHAHmomy, 9T0 paccennHe oTpaixaeT Tpy,11,H0CTb noaymemin HaAmtibix
Ta6Aut4a 2
911EPr1451 AK THBAL1,1414 14 (13AKTOPbI tIACTOTbI TEPMHLIECKOTO PA3.110)KEHI451
PA3J11411HbIX 11EPEKI4CER
rK,Aponepex titb
EaKT'
FM:MIXON,
ko, cel
PacTsopliTem,
JhrrepaTypa
TeTpanxiia
29,0
1,3 x 10,1
Be.noe Men-
alnicKoe mem
Ornicamioe
Acc.rieAosainie
Ilsonponn.n6eR3o.na
29,0
1,3 x 1011
To me
To x{e
tt-OKTILna
26,9
1,0 x1010
* *
2,4,4-Tplimenhanewrii.na -2 . . .
26,9
1,0 x1012
* *
* *
mpem-Byinna
39,0
1,2x10'5
H-OKTax
[10]
IIHK.noreiccatia
34,0
1,2 x 1013
UHKJIOreKeaH
[11]
aeKaaHlia
32,1
8,5x 1013
AeKaJIHH
[12]
emop-,I1eum.na
31,7
1,0x 1012
rt-,Eleicari
171
T-tannbix no 3HeprnH aKTHBa1.114H, oco6eHHo ,I(.1151 ,tkaHHofi peaxnkm, noxsepweHHoil
MHOPHM BO3MONOMJIyI OCJI0)1{HeHH1M. ann weinemm, HCCJIB,ZIOBBHHbIX B 0,IIHHBKOBbIX
yezosHnX, BAHHHHe CTpOeHHSI Ha aliepriito aKTHBBII,HH oKa3b1Baercsi He60JIbLIIHM.
AHaJIorHtirnii BbIBO,I 6bui nanytieH npn lice...nemBamili Teprariecicoro pa3J10}KeHIBI
opramtiecium HHTpHTOB [9].
SHeprHsi AHccouHaakin CBH3H 0-0. ECJIH eAHHCIBBHHb1M Ha-
npaBaeiniem pammeimw rHAponepexncH sIBJISIeTCH moHomoaexyAnpHbul pacnaA, no
ypaBHeHHIO (1), TO H3mepexHasi aHep aKTHBBLIHH 6yollgT COOTBeTeTBOBBTb 2efleTBH-
TeJIbH0rI sHeprinfolIHCCOUHBLUIH nepexHcHoil CB51314 AJIH IlpHMeHSIBLIIHXCH paCTnopl{-
H ye.nowidi. ECJIH ?xe 3Hati1TeabHan tlaCTb nepewHcH paexwAyeTcn B pe3y.nbTa-
Te Apyrnx nepnwqHmx peaximii (Hanpnmep, reTeponwriltiecxoro paCulenaeHHH,
BnyTpHmo,nexyanpHoro pa3.noweHm HJIH peaxusHH nepeHoca 3JIBKTp0HOB C yqacTH-
em pacrtiopHTenn), TO nonytieHmam 3HeprHsim aKTHBa111114 c.neAyeT AaTb HHoe HCTOJI-
KosaHne. XOT51 803M0)KHOCTb 110,406HbIX peaxu,Hfi H Bbi,zumra.nacb, oi.waxo awrop
nonaraeT, o OKOHtlaTeJIbHbIe ,aaHHbie, Aenaloame Heo6xo1Hmb1m paccmoTpeHHe
14X B AaHHbIX yCJI0B1451X, OTCyTCTBytOT.
ilpHHSITHe 9T14X KHHeTHIleCKHX ,1:1aHHI3IX KK mepbi 3HeprHH AlicconHankni
a.TIKI4J1bHbIX rH,aponepewHcell After AAA noc.ne,aHeil Beantamy 29 KICaAIMOJIb. ara
wealltnnia coilocramima CO 3HatleH1451MH 31,7 H 36,0 KKaAl ht0Ab A.T1 51 AH3THanepexucH
H AJ151 AH-mpent-6yritimepem4cH, xoTopme obIJIII onpe,zteaenbi He Bb13bIBa101g14M14 COM-
HeHH51 1{HHeT1411eCKHMH meToitamH [13, 141. OAHaxo 3Heprnn AlleconHainni rlepeKH-
CR onpe,/le.neHHan TepmoAHHamHgeum [15], ropamo 6anbare H panHa
52 ICIWAIM0Ab. Ha 6oxibmoe pa3.nHtme me>x,gy 3HepriiHmH AucconHamni nepexucH
no,lkopo,ita H ,1111aJIKI4J1bHbIX nepexHcefi ywa3bmaroT Taioxe Apyrne Hcc.neAosaTemi
[13]. Hafukei10 [10], tITO aHepring AHCCOUHaLIHIA mpem-6yTHarK1ponepexHcH
H AH-mpem-6yTHanepexHcH panHbi, H oTmegeHa He0H{14,LtaHHOCTb Taxoro conna,geHH}f,
oco6eHHo ec.r1H ytieffb seaHt[HHy 3Heprm4 ,LIHCCOLI,HBLIHH ikon nepexncH BoAopo,rka.
ConnaileHHe alleprHtl ,aliccou,HanH0 aJIKHJIbHbIX rHAponepexHeetl H AHBJIKHJIbHbIX
nepeKFical, eCJIH 3T14 BeJI 14,1F1Hb1 51BJIHIOTC5T peaJlbHbIMH, yKa3bisaeT, TITO aJIKI4J1b-
HbIe 3amecTHTeau He OKa3b1BatOT 51BHOTO BJ1 1451H14 51 HH Ha nepexHcHylo CBH3b, H14 Ha
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
OCHOBHON OPFAHMIIECKPIFICHHTE3
99
pe3oHaricHylo cTa6Hak3aluito paAkntaaa RO., TITO Tpe6oBa.nocb6b1,1V151 06'bFICHeHHA
Aeficrimisi a.TIKH.TIbHOTO aamewseHH9 ripH 110H1-1)KeH111-1 3Heprkill AHCC01114aLLI414 nepe-
KHCH so,aopoAa.
AHTEPATVPA
1. Cullis C. F., Hinshelwood C. N., Disc s. Faraday So c., 2, 117, 1947.
2. Mulcahy M. F. R., Disc s. Fara d'a y S o c., 10, 259, 1951.
3. Hock H., Susemihl W., C h e m. B e r., 66, 61, 1933.
4. Milas N. A., Surgenor D. M., J. A m. C h e m. S o c., 68, 205, 1946.
5. Mosher H. S., J. Am. C he m. S o c., 76, 2984, 1954.
6. Lindstrom E. G., J. A m. C h e m. S o c., 75, 5123, 1953.
7. TwiggG.H.,Discs. Faraday Soc., 14, 240, 1953.
8. Cooper W., J. Chem. S o c., 1267, 1953.
9. Szwarc M., C h e m. R e v s., 47, 75, 1950.
10. Bell E. R., Raley J. H., Rust F. F., Seubold F. H., Vaughan W. E., Disc s. F a r a-
day Soc., 10, 242, 1951.
11. Farkas A., Passaglia E., J. A m. C he m. S o c., 72, 3333, 1950.
12. Tipper C. F. H., J. C h e m. S o c., 1675, 1953.
13. Rebbert R. E., Laidler K. J., J. C h e m. P h y s., 20, 574, 1952.
14. Murawski J., Roberts J. S., Szwarc M., J. C h e m. P h y s., 19, 698, 1951.
15. Giguere P. A., C a n. J. R e s., 28 B, 17, 1950.
Ilepeeoa B. Mepcoea.
7*
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KPACHTEJ111 14 110JIYIW0,E1YKTb1
Flo,A pe,Ekaxulleil AoHTopa xHm? Hap< B. H. ill cfiuhttima
0 HOBOM meTofig noariemisi N, NCHAKHJIHPOBaHHIAX HHAHrOHHbIX Kpacwreacti
143 Texintgeocia HHAHro3o.neli. IV. 06 HHAHrOHAliblX Kpacwreagx. Pummerer R?P
Meininger F., L i e b. A n n., 590, N2 3, 173-194, 1954, 6H6.71. 19 Han.
CIIHTe3 N, N'1114aJIKHJIHp0BaHHbIX HH,EI,HPOHJIHbIX HpacHTeneti OCyHjeCTBJI5110T
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cnoco6oH HCTIOJIb30BaH I.JIff 110JIrleHHH pHAa aJIKHJI- H apanxHaHHAHro.
? Batlep [31 OTMeTkIJI 0,IIHy H3 XapaKTepHbIX OCO6eHH0CTeil HHAHro--Hecnoco6-
HOCTb aJIKHJIH130BaTbCfl. B noxrHepKgeHHe sToro aBTOpll HacTofnugil CTaTbH ycm-
110B13.1114, qT0 HH ,IkeilCTBHH AHMeTHJIcyabcpaTa Ha HHAHr0 o6pa3yeTc5i cmecb
cepycoitepHam,Hx coemmeHHil HeBbIFICHeHHOD3 cocTana, H LITO HH,EkHro He BcTynaer
B peaHumo C AllaaomeTaHom [4]. TO HmeTcH cTpaHHum, TaK KaK czeAoHano 0}1{11-
orkaTI:), rpynna CO B Opr/20-1I0J10}KeHHH npfutaeT KHCJIOTHbal XapaKTep rpynne
NH HHAIITO. TaHHe CBOrICTBa CTaHOBSITCfI 11011fITHHMH UH paccmoTpeHHH no.nHp-
HOR CPOPMbI [5] HH.1u1r0, B KOTOpOil npHcyTcTsyeT He TpeTHIMbIfl, a Tmumo aJIKHJIII-
ppouviticsi IleTBepTHTHIbIcl aTOM aaciTa. ,LtinceToHHaH cfoopma HHAHTO [6] CO Cl3f1351MH
B HHAe ,110110JIHHTejIbHbIX Ba.neHTHocTeff memc,zky rpynnamH NH H CO TaH)He ZOJflK-
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B TaKHX czygasix TOBOpfIT 0 BOAPPOAHOR CBSI3H, o6.1a,aal0akeil 3HatIHTeJIbH0c1
KOCTb10. 1-10CJIe OKOHtlaHHFI sToti pa6oTbi TIO5IBHJI0Cb coo6w,eHHe amepliKaHCKHX
Hcc.neAoHaTe.neik, B KOTOpOM Ha OCHOBaHHH HH(DpaHpacHba cnewrpos npeAcTaHaeHa
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awrpa30J151?B ropflgeM 42% -HOM pacTsope eAHoro HaTpa npH pH 14,5-15
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C COOTBeTCTBeHHO C ,LI,H9THJICyJIMPaTOM 11.1111 C XJ10pHeTbIM 6eH3HJIOM o6pa-
3yercH o.nee 90% AHCepHOKHCJIOTO act)Hpa zefixocoeAHHeHHH N,
ro (II), KOTOpbdi oneHb CTOeK K Aeficunno ropmmx xpenxlix Insenotieti. flpespa-
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KPACHTEJIH H
101
akeHHe 9T01-0 3411pa B N, N''HBOKHJIHH,EI,HTO (III) TJIaAKO npoxo,urr B CJIa6OKHCJIOM
paCTBOPe B IlpliCyTCTBHI4 COJIH Fe3+. Ehriaro,aapH 3TOMy no.nytieHHe ma.rucHanpo-
BaHHbIX Hp0H3B0,1111bIX HHAHro CTaJI0 Hno.rme
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LIteHHH onlicaHbi B mrrepaType H nogruepKgeHm B HaCTOHIII,eM HCCJIeA0BaHHH. 3TH
AaHHbie HmeloT 3HatieHHe inymeHHH HHTepeeHoro SIBJIeHHH?,aeaJmnanponaann
H MOH0aJIKHJIHHAHTO, npollexo;m1Hero npH nponycKaHHH Homyxa. ,E1H6eH3H.Ium-
AHro IlepeX0,1I,HT B MOH06eH311JIHHAIITO npH KHIIeHHH B.TIe,AHHOrl yKcycHoil KHCJI0Te
H nponycxamm Homyxa B Tetienne 1 qaca. AHanorimHasi peaxuHH npoTexaeT B OT-
KPbITOR KOJI6e npH 60-65? B 6eH30.11bHOM pacTuope B TetieHHe 5 qac. B oTcyrcTrme
H03,ayxa Aea.rucHallposamm He npoHcxo,RHT. CHOCO6HOCTb K Aeaamiakiposainno
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IIOJITIHTb amm.nHposaHHem c.rie,ayioumx awrpa3o.neA.
4. HHAHr030JIb A3eT r, H3 .neilxocoe,AHHeHHH aoH3apHH-
HHAHr0 Opopmy.na
5. AHTpa30JIb caaniiAJIH neqaTH I/IFF-0,1AHH 113 JJL1IIJHX CHHHX KpacnTeoeff
,anu neqaTH?,zumaTpHeriau COJIb XIHCepHOKHCJIOTO scimpa 4-x.nopHa4yra.nHH-2-
(4'-meTHA-5'-x.nop-7'-meToKcHHHAo.n)-2%.ne1x0HHAHro (cpopmy.na V). IlonyqeHnbift
aJIKH.T1Hp0BaHHhIci HH,1114f030JIb npH OKHCJIHTeJIbHOM npoHaneHHH .nerico Aea.nKH-
JIHpyeTcH C o6pa30BaHHem COOTBeTCTBypoutero aerHAa (3e.neHbIn KpaCHTejlb).
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
102 KPAcHTE.g.? H 110JIIMPOAYKTbI
6, AnTpa3oab CHHWIA AAH nemaTH HB-5,7-Allx.nopTeHalyreH-2-(4'-menui-5'-
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MONCHO a.TIKH.JIHp0BaTb no a3oTy, 0,71HdKo aJIKHJIbHa51 rpynna unnenaHeTcH npH
OKHCJIHTeJIbHOM nposumeHHH c o6pa3oHaHHem cHHero HCXOAHOTO npo,aymTa.
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3o.nem npnnena K o6pa3oHainno TOJIbK0 czeikon (1)I3OneTOBOTO Kpaarreasi.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KPACIFTEJIH ki 1-10.TIYFIP0,11,YKTbI
103
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0,L1HaK0 B TelexHe 6o.riee 11p0,LIOJI)KHTeJ1bH0r0 HpemeHH, arm 9T01'o npHmeHmoT
paCTB0p FeC13, no,axnc.neHHhail COJIHHOil KHCJI0T01. J1ymiii BbIXO,LI no.ay-
HatoT CO CTallAapTHbIM paCTB0p0M Pyrran (Ae.He3oammom4f1Hbie KBaC11,111 B pa3-
6ameHHog cepHofi KHCJ10Te), xoTopuil pacw,enaHeT HH,11111.030J1b B xpacHTeab npH
20? meHee Hem c 2%-Hbim nepeoloczeHnem. B npoTHHono.noAnocTb npocTecnnemy
11H,IFHT030J110, ,z1.1151 HH,5,111'030J1f1, 3amemeHHoro y aToma a3oTa, He me,ayeT npHmeHHTb
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npoayxTos.
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MO3KHO paculen.awrb He TOJIbK0 FeCI3, HO 14 a3OTHOCI KHCJIOTOil HJIII Aaxe 6Hxpoma-
TOM KaJIHR H KHCJIOTOil. 9TH 14HA111.030JIH ma.ao peaxu,HoHHocrioco6na H Tpe6poT
npoHeikeHHH peaxu,km npn 50-70? B TeHeHHe 15-30 MHH.
HecHmmeTpHgnme N-aJIKHJIHH)1,141'030JIH C OAHHM HHAOKCHJ1bHbIM OCTaTKOM pac-
IlleHJIHIOTCH npH ,get1cn3140 BblilleyKa3aHHbIX OKHCJIHTeJ1e14, 0,N,FlaK0 C HCKJ11011HTeJ1b-
HOB' JIUKOCTb10 TepsnoT npH 3TOM aJIKHJIbHbIci OCTaTOK B BH,LIe cooTHeTcTspouiero
armaerma. flpii 3TOM IlacTo Ha6.rno,aaeTcH o6pa3osamie npomewyToHnbix npo,ayxTon
HeBbISICHeHHOTO cTpoeHHH, FlpH KFICJIOTHOM OKHCJIeH1314 4-x.nopHacirraoHH-2-
(N-menui-4'-meTH.n-5'-x.nop-7'-meToxcHHH,ao.n)-2f-HHAHro npH 20? Bbina,aaeT HHatia.ne
6ecuseTHaH (Ito caa6o3e.neHoro) .nefixomic.noTa, npespaulalowaHcH npu 30-35?
B xpacHo-clmozeTonmil XJ1011be1314Hblil oca,a,ox, KOTOpb111 npH 55? oxpannmeTcH
B TemHo3e.aeHblil u,HeT H o6pa3yeT N-a.rn{HoHposaHHE.41 xpacHTe.ab. FlpH 70? ocaaox
oxpanumeTcH B CHHIA u,HeT B pe3yabTaTe ,aea.inthauposaHHH H onuen.neHHH (top-
ma.ab,aeritaa. ,fllearmumposaHHe no Hbixo,ay xpacHTeaH npoTexaeT Ha 94,3%, a no
xomplecTny BbI,TIeJ1eHHOF0 CPopmanb,gerkuk-AHHHTpa4leimarkutpa3oHa?Ha 80,5%.
1/13 N,V-itHaJIKHJIHHAHT011,21HbIX xpacHTeaell TOJIbK0 AIIMeTH.T111p0H3B0Hble
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TeJlbHbIe KOJIHIleCTBa MOHOMeTHJIHHAFIFO .nerxo y,aansnoTcH. ,II,H9THJI- H ,L1H6eH3HJIHH-
AHFO nooxo xpomaTorpaitHpyloTcH ncoe,acTHHe npenpaar,emul, oco6eHHo 6LacTpo
npoTexaroui,Hx npH ocnem,enHH. 3TH xpacHTemt otnnuaioTcH xpHcTa.a.rmaauneil H3
6eH30Jla HJIII neTpo.lefffloro alonpa B OTCyTCTBIle Boa,uxa H anarH; conpumocHose-
Hue c B03,11)7X0M IlpHBOAHT K tiacTHHHomy IleanKkumposaHmo. flyHme cHatia.na oHH-
LU,aTb am{Homposamimil HH,11,111.030.11b xpHeTa.n.nmau,Heil 113 BO,I1bI HJIH 143 cmecH
cruipTa c acinwom H aaiem pacmen.nenHem ero no.HyHaTb HHCTIACI xpacHTenb. HH,11111-0-
30J1b HJIII ero rHapaT (cm. Hkoxe) yao6Ho xpaHHTb B Haxyym-9xcHxaTope H3 KOp1411-
Hesoro cTex.Ha. FlpH OKHCJIeI11114 N-aJIKIIJIIIp0BaHHEIX H1111,141.0H,11,0B a3o1Hoil KHCJIO-
TOCI B .ne,aaHoil yxcycHoil KHCJIOIC o6pa3yeic5l pf1,11 N-aJIKHJIHp0BaHHb1X 143aT11-
HOB, TO 5113JIHeTCH y,1106Hb1M CII0C060M HX
N-A.HicHamposamnbie HHAIITOHAbI B icatiecTHe xpacHTeaeri
BHOBb no.nymeHHble N-3amentennuel1H,IIIITOHAHbIe xpacHTean FICI1b1TaHbIB OTHO-
meinni npHroi(HocTH ,11,1151 xpaineHHH. OKa3aJI0Cb, tITO HX Ileab3S1 npHmexHTb AJIFI
neHaTH no x.nonxy HJIH ,I1,J151 Kpamenin vionxa. HeCKOJIbK0 .nylunne pe3yjIbTaTbI
nozyHaxyr npH xpainenHH Luepcm; o,rwaxo ,a.T1H TaK01.0 xpaineHnH CTOHMOCTb npo-
,ayxTa CJIIIIIIKOM BbICOKa.
KpacueNue xAontca. Bce paccmorpeHHbie mecb npe,acTaHHTe.nn pia HHAHro3o-
zeil o6pa3yroT c.aa6o3e.neHbie TOHa npH npHmeneHHH o6bitnibix meToaon Kpamemisi
XJ10IIKa FIFIAHT030JIAMH. BBeaeHHe N-aJIKHJIbHbIX rpynn B HH,A141.011AHbIe xpacHTeini,
a Taioxe coAepHow,He 33 4- H 6-namxeHHHx aTOMEd 6poma, allatme.ribllo oc.na6.715leT
Hbi6HpaemocTb HHAHroao.nerr, a Taxxte .neilxocoe,anHeHH11. 1/13 yxcycHoxHcoofi Bali-
HbI Bbi6HpaemocTb FIWIHT030J151 BOJIOKHOM HeCKOJIbK0 *arum. Bbn(pacxn Hmeloi
H133Ky10 11p0IIHOCTb K AeAcTmuo cHeTa, K cTHpxe, K nepexpannisainuo.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
104
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HH3Ka51 Cy6CTaHTHBHOCTb N-aJIKHJIHp0BaHHbIX secraocoes,HHeHHil aHanorwma
ApyrHm caytraHm HOHIDKeHHH Cy6CTaHTHBHOCTH npH aJIKHJIHp0BaHHH rpynnbi NH
(HanpHmep, Halmos AC). Cy6CTaHTHBHOCTb 061HCHSTIOT Haswraem Horkopozmoft
CBH3H MeKE1y rpynnamx NH H CO. TpyAHOCTb aJIKHJIIWOBaHHH HO TOM y a3oTa
BbICOKO6p0MIlp0BaHHbIX ITH4HT0H,T111111X xpacHTeseti 3acapxrameT BHHMaH1111.
Kpatueriue tuepcniu. 1133711eHHble HH2WT030J111 HmeHyr otieHb xopompo BbI6H-
paemocTE. impend% 0,E(HaK0 C Texmitiecxori TOI1KH 3peHHH 11J10X0 0MbIJIHIOTC5T
H OKHCJIHIOTCH. H11TpkITHbIA CII0C06, oco6eHHo AAR aJIKHJIHp0BaHHIAX 4,4"-sHxsop-
5,5'-AH6pom- H rexca6pom11Hssro3oseil, 11p13BOAHT K 06pa30Ba111410 HpKHX 3esentilx
oxpacox. FIOTITH BO Hcex csytrafix oxpacim Hmexrr xopompo CTORKOCTb K cTupxe
H cHeTy. MeTa,a npoHBJIBHIla K2Cr207 HeY,T106eH, Tax xaK IIpH 3TOM LuepCTb
itesaeTcH s(ecTicoil H BCJIeACTBHe 3T01'o CHJIbH0 ymeHbumercH npotraocTH Ha
pa3pbra.
,UHMeTHJI- H sH6eH3HsTeTpa6pomHHAHro3osH o6sa4aioT xoporaeri 11p0IMOCTE.10
K cTHpice; npH Hasxe oxpacio CTaHOBHTCH HeCKOJIbK0 cHeTsee H s(esTee. arll xpacH-
TeJIH maso Bb11113eTaIOT H HmeloT xoporapo 11p0IIHOCTb K xap6oHH3auHH.
CHoficTsa asxm JIHp0BaHHbIX HH,11 H TO30J1eri
otiknuemibie N-a.TIKHJIHp0BaHHbIe 11HJAHT030JIH o6pa3poTcH B Hue 6ecuseT-
Horo cHeTamesToro xpHcTassmecxoro noporaxa, xoTopbdi o6bH4Ho Tpy,Emo
pacTsopHm B CHJIbH01.11eJ1011H0f1 peammoHHorl >1(11):1KOCT11 H 113 Hee BbIKpHCTaJIJI14-
30BbIBaeTCH. IlepexpHCTaJIJIH30BaHH1 H3 B0,11bI IIpenapar tiacTo HmeeT CJIa6o
raesotmpo pealanno, B TO HpemH Kai( nepexpHarassH3oHaHmic4 H3 meTHsoHoro
crrapTa 11J111 113 cmecH crrapTa c scimpom?HetiTpasbHpo peamuno. 0,1:max? 3T0 coe-
AHHeHHe cnycTH HeCKOJIbK0 sHeil nos AeficTmiem B0321yXa H cHeTa noxpbraaeTcH
Temuo3eseHorinJxeHKo. Pa3so}KeHHe, Hanaimneecn B O,1HOii TOI1Ke, mmeT pacnpo-
CTpaHHTBCH Ha BeCb KpIICTaJIJI. B Haxyym-3xcraraTope 113 xopHtmeHoro cTexsa He-
Imam? coxpaHHeTcH B TetieHHe HeCKOJIbKI4X Hejleab HJ111 mecfraa; TemnepaTypa
IIJIaBJ1e111151 HH 6bICTp0M Harpesamm 100-150? (pa3s.).
npoBe,geH aHaJII43 Al4MeTHJI- ,Z1H3T14.11- H All6eH313J1140,1111ro3oaeil?np0143B0,1A-
HbIX HHAHro H 5,5', 7, 7'-TeTpa6pomHuHro, OCTaabHbIe FICIIbITaHb1 Ha tikICTOTyJIHIIIb
110 COAep)KaHHIO Kpacwrean nyTem OKHCJIeHHH.
N,N'-asiduraposaHHbla IIHAHT'030JIH B Huse HaTpHeBbrx coseil o6pa3poT xpa-
CHBbIe xplicTasslltiecirae rHspaTm, o6bitrao C tieTbipbmH mosexyzamx B0,11bI (HHorsa
C ,traymm mosexyaamH). KpHarazaH3airaoHHpo BOJ Y Y2aJ15110T B oTcyTcTHHe cBeTa
B aTmoccpepe a3oTa H B BbICOKOM Haxyyme HaA IISITHOKHCb10 4OCC100pa npH 100'.
06e3smeHHbie 11H,r(Hro3osH HCKJ1101111TeabH0 T11rpocK011H11HbI. Kpome Harpnenoll
CO.TII4, nosytieHm Asa 1311,/(Hr030JIR B Hilse aHHJIHHOBOil H 1111PHAHHOB011 condi
(C ArtymH monexysamH ocHoHarara).
LlacTo BO3HHKaeT He06X0,11,14MOCTb B xpomaTorpalratlecxom pa3seseHHH Ha
A1203 HHAHro3oseti, oc. o6eHHo Ansi 3T13.71eH- H TpHmeTuseHHHAHro; Heasxkurapo-
BaHHbIe H11,11111.030J114 6bICTp0 Bb1MbIBalOTC5, OAHaK0 344eKTI413HOCTb pa3AeseHHH
He3HatarreabHa. Pa3,4eseHHe 6e3Ho1Hmx COJIei HuHro3oseri syquie npoxo,3,HT
B 1114pHAHHOBOM pacTsope.
3xcnepHmeHTasbHaH tiacTb
A. AJIKHJIHp0BaHHe ,4HcepHoxii C.J1b1 X 341 Hpos
JIe11KOHHAHFO
Onpeaeneriue coaepoicatiusi atimpa3am 0. TexHimecxral npenapaT aHTpa3o.Tra
O (HHAHro3osb 0) CO,LIep)KaJI ?KOJI() 10% HeopraHmecxoti C0J111 H npH OKHCJIHTe.Thb-
HOM paculenseHHH o6pa3oHbraas 27,5% *HHAHTO, iio cooTHercn3yeT co,gepsraHmo
6e3HosHoro HHAH1?030JIH C16F11008N2S2Na2 ?KOJI() 48%. Orme,/leseHlle coAepsraHHH
meTo,Rom OKIICJIeHHH 11p0BOXIT no cnoco6y PyrrsH [7].
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KPACHTE.1114 14 TIOJIYTIPO,RYKTb1
105
I. Memuimpoeauue
AJIH nporse,AeHHH peaxusH npHmemoT nsiTHrop.nylo xo.n6y CO Lumxpamm
(eMKOCTb 1 C meniaaxoti, ABymsi Kalle.11bHb1MH Bop?Hxamil H o6pambim X0J10,11HJIb-
H14KOM. 0,71Ho ropao CJIY}KHT J11 B35IT1151 npo6bi. 20 2 aHTpa30JIH 0 (27,5%) pacno-
psnoT B 70 MA TOp5P-Ieri Bum, cimabTpyloT 14 HamisaloT B xo.n6y. ,II,o6aBasuoT no
Kan.aHm 70 MA 42%-Horo pacTsopa excoro HaTpa (600 e excoro HTP Ha Ha 1 A),
3aTem npli 45-50? H nepemeumsaHHH npHnHaaloT 200 MA Hmeni.ncyabcpaTa H
170 MA 42%-Horo pacTaopa e,axoro HaTpa. CKOpOCTb IIPHJ11413aH1411,, ,IIHMeTHJICyjIb-
IPaTa ?1-2 KalIJIH B1 cex., me.notm-2-3 KaIIJIH B 1 cex. Xo;:k peaxu,HH H KOHeII,
MeTHJII4p0BaHH51 onpe,aeamoT nyo6ori, KoTopylo npH.TniaaloT B npo6Hpxy, co,aep-
>Kamp? COJIHHy10 KI4CJI0Ty (1:1) H pacmop FeCl3. MenumposaHme C114-
TaIOT 3aKOHIleHHbIM, KorAa BbinasinHe XJ10111351 xpacHTeasi pacTsopsnoTcsi B opra-
HH4CCKOM pacTsopHTeoe C cHHe-3e.neHum oxpaumaaHHem, a npH xpomaTorpa4llipo-
BaH1414 10-20 MA 6eH30J1bH0F0 pacmopa B Tpy6xe, 3ano.nHeHHoR A1203, o6Hapy}KH-
saeTcsi TOJIbK0 TemHo3e,neHafi 30H a,acop6HposaHHoro,aHMeTHJIHHAH1.0 Hail e= ?Alia
CHHH51 30Ha?MOHOMeTHJIHHAI4r0.
Ye B nepabie 30 MHH. 113 peaKaHoHHoti }KHAKOCTH Bb1aeJ151eTCH mHoro weaToro
xplicTanaHtlecxoro N,N'-,1114MeT11JIHH,411r030J131. HO OKOHMaH1414 meTHamposaHHH,
npoikonxamaerocH 2-3 qaca, npoAywr nepemeunisaiar 1 mac npH 50-60?. 3aTem
OCTaBJIHIOT CTOSITb HeCKOJIbK0 qacoB, Bbniaaume KP14CTaJIJIb1 0414JIbTp0BbIBalOT
14 ABOJK)161 KpHCTaJ1.11143y1OT 413 He60J1b11114X KOJIINeCTB ropsitieti BQII,bI.
2. OKUCAUMeAbliOe pacurnneuue N ,N' -0UMMUAUliall2030A.R.
5 a N,N'-1411MeTI4JIHH,1.111r030JIH pacTsopsnoT B 300 MA )1,eCTIIJIJI11p0BaHHO1 BO,EIbl
H OKHCJIHIOT 250 MA cTaH,aapTHoro pacTaopa Pyrrou. lipH 20? 11011BJI51eTCH TOJIbK0
3e.neHoe oxpaumBaHHe; niui oca)KikeHusi xpacHTeast HarpesaioT 20 MI411. o 50-
60? H 3aTem sbi,u,epmmaamT 1 mac npH 20?. TemHbail C11He41140J1eTOBb111 MI4KpOKpI4CTaJI-
JIHT-IeCKI4c1 oca,aox (Hrobi) OTCPIIJIbTp0BbIBaIOT H npombiaatoT 500 MA BO)IbI ,a0 6ecu,seT-
H01'041llabTpaTa. I/13 20 aHTpa30JISI 0 noariaiDT 5,82 atmcToro
air? (95% OT Teopenpiecxoro), KOTOpb1f1 Ha TJIHHHHOM IlepenKe ;Lau 3eaeHyto tiepTy
H B 14HAHC14/epeHTHOM pacTsopirrene paCTBOpfleTCH C ma.laxmoso-3eaeHoil oxpacxoti,
B a1,eTom4TpHoe?C CHHHM oxpaumaaHHem, B X0J10)111011 KoHu,eHTpHposaHHoil cep-
HO 4.11140JleTOBbIM. CMeffle1114eM H scTpsixm3aH11em 6eH30J1bH01.0 pacmopa
AHmeTHJIHHAHro C KoHgeHTpHposaHHoil COJIHHOil KHCJIOTOil noarialoT CHHHA XJ10p-
nmpaT. A11MeTHJIHH111-0 pa3mHrmaeTcsi npx 171? H IIJIaBHTCH npH 182-183?.
IlepexpHcTazaH3osaHHa1 143 6eH3o.na H abicymeHHaH npH 100? npo6a Hmeaa COCTaB
C181-114N202; cmealaHHaR npo6a c npo,Ltywrom, no.nytieHH"um no meToAy BpaaxmaHa,
noaaH.nacb npH 182-183?.
flpH OKHCJIeHHH a3OTHOR KHCJIOTOrl Ha xono,ay B J1e,51Hoil yxcycHoil KIICJI0Te
(1 : 15) KpacHTeab o6pa3yeT N-MeTIIIIH3aTHH, T. MI. 131?.
3. ,aucepuoKucAbta ,Oup AeaKocoeautienun N dy' -aumemuimuaueo
,autiampue6aR COAb. 2 2 npoAyxTa, TpH pa3a nepexplicTaxmoBaHHoro 113
BO,abI, pacTsopsnoT B 20 MA meTH.noaoro cnHpTa, HarpeamoT 30 MHH. HH 50? H OT-
4JHJIbTp0BbIBalOT. OT HepacmopHamerocH BeniecTaa (0,01 2). ECJIH nocae Ao6aBae-
H1151 10 MA acimTpa npHmecH 60J1b111e He shmaatoT, TO ,I1,o6aBasiroT 30 MA acimpa
(6 nopiTHR) B TegeHlle 15 MHH. H OCTaBJIHIOT AJIH 110JIHOTbI Kp11cTaami3a1THH B X0-
J1014JIbHOM amacky Ha 2 maca. BecuseTHEdik KpI4CTaJ1J11411eCKHil oca,goK OTIPTIb-
Tp0BbIBalOT, OTHU4Ma1OT H cymaT HH 50? B TemeHme 20 MHH. O HCile3H0BeHHH
3ariaxa 34)11pa ii meTHaosoro crmpTa. MeTaHOJIbH0-34HpHa1 011HCTKa CJIyNCIIT npexuke
scero ,a.T151 yAaJleHllil HeopraHmmecKHx
Tempaeuapam. 1 a abule.neHHoro npo,m(Ta paCTB0pHIOT B 5 MA BO,abI H pacTsop
crylualoT HcnapeHHem npH 20? B TemHoTe o Bb4aeJICHHH KpHCTaJIJI0B. ,II,JIHHHble
LumpoicHe Hram nocae BEacyumsaHHH Ha sowtyxe coAep)KaT 4 MOJIeKy.i1b1KpHcTa.mmi-
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
106
KPACHTEJIH H TIOJIYIIPOAYKTbI
3aHHoHHoPi sum (C18H1408N2S2Na2?4H20). 3Ta COJIb HmeeT crtemo)xe.riTylo
oxpacxy H oneHb ropbmin sxyc. IlpH Harpeeamin Ha Bovyxe KITH B Tpy6xe pa3-
.naraeTcH npH 135? C cmie-tiepHEam oxpaumBaHnem.
Beoeoanyto CO./lb MON{110 IIOJITIHTb TOJIbK0 Tpexxpambim npo,aysaHHem a30Ta
npH 100?/0,3 MM H sucyunisaHHem HpH 100? B Tex-lel-me 3 qac. Ha jk TI5ITHOKHCb10
4)040Pa B 9KC11KaTOpe, 3aKpbITOM qepHbim maTepHamm. Be3somm1 CO.T1b IICKJ110-
11HTeJ1bH0 rHrpocxonwma H AAR aHamma AOJI}I{Ha 6bITb eine pa 3 Bbicymerm, KaK
01111CaHO BbIIIIe, B TeneHme 1 qaca npn 100?/0,3 AIM B aTmoatepe a3oTa H B OTCyTCTB1le
crieTa. COCTaB npoxTa cooTseTcmyeT itopmy.ne C18F11408N2S2Na2.
KOJI114eCTBO no.nyneHHoro 11H,411T030JIH onpeAe.nntoT CTaH11apTHhIM pacTs.opom
PyrraH. B TemHoTe ripo6a ,11,14MeTHJIHH)114T030J151 coxpaHnercn B TeTienHe He,ae.rm
6e3 H3MeHeHHF1.
Attu/eta-wean COAb. 1 0 TeTparHpaTa paCTB0pHI0T B 60 MA B021bI H o6pa6aTbi-
Bai0T pacTsopom 1 a COJIHHOKHCJIOTO aHHJIHHa B 6 MA B0,11b1. CllyCTF1 14 Mac. BIDITIa-
AaroT 6emmeTHbie limpoicHe TIJIaCTHHK13, xoTopme npombmaroT B TemHoTe He60JIMIIHM
KOJIHtleCTBOM BObI, 3aTem scimpom H cymaT B saxyyme Ha ik XJ10pliCTbIM xa.nbutiem.
CocTaB npo,LlyxTa C18H16081\12S2?2C6H5NH2.
IIPH mHxpoaHamminecitom onpe,4e.neHHH yrnepo,im npo,ayxT cmeumBaioT
C II5ITHOKHCb10 saHamm; ;Ian onpe,Re.neHnH so,aopo,aa sToro He Tpe6yeTcH.
.1111Plialin06C1R COAb. 1 2 TeTparHApaTa, pacTsopeHHoro B 30 MA Boikbi,gcmenni-
BatoTtco cBesKenpHroToB.Tiemium pacTsopom 1 2 COJIHHOKHCJIOTO rfflpHmum B 4 MA
BUM H Bb1,11eP}KHBal0T B TeneHHe 1101114. Oca,aox xplicTaammyloT 113 He60J1b1.110TO
xommecTsa BoAbi rip H 55? H cyLuaT Ha,n, em(Hm HaTpom. 110BepXHOCTb 6ecuseT-
HbIX KpHCTaJIJI0B 6bICTp0 npHoopeTaeT CBeT.1103eJ1eHbIi1 I1BeT. CocTas npo,n,yxTa
Cis Hie0? N2S2 ? 2C5H5N.
4. 30,611CUMOCMb peaKuuu htemuAupoeanu.g 0171 eeuuit pH
Memumpoeanue npu pH 4-5. 5 a aHTpa3o.nn 0 paCTB0pHIOT B 50 MA BO,abI,
014:114JIbTpOBBIBaIOT OT HepaCTB0pHB11161CH ilacTll H meTHanpyloT HH 50-60? 80 MA
AHmeTH.ncyabctiaTa H 100 MA 30%-Horo eAxoro HaTpa; npn aTom nomep?KHBaloT pH
4-5, ycTaHoaneHnoe ,a06armeHnem pa36aBaeHHoil cepHoil KHCJI0Tb1. 1/1C11b1TbIBaIOT
npn 110M01.1111 AncpaHoscxoil 6yMar14 HJ1H KaIleJIbHbIM mimuKaTopom, HaHecemmim
Ha 4NIJIbTp0BaJ113Hy10 6ymary. lipH OKHCJIeHHH BbLae.115110T 113 peaxunoHHoti cmecH
3 a TemH03e.aeHoro 110p0U1Ka, KOTOpbal pacTBopneTcs B aueToHe C 3eJIeHbIM H xpacno-
3e.TIeHbIM mixpoimmom. 01{He.rieHHem clmnbTpaTa 5% -1-IbIM paCTB0p0M FeCl3 H CO-
.TIFIHOPI KHCJIOTOCI (1:1) nanyqaloT 50 .412 N-MOHOMeTHJIHIVAIITO H 25 me HHAHTO; )1,14-
MeTHJIHHAIITO oTcyTcTsyeT.
MemuAupoeanue npu.pH 8-10.10 a allTpa3oon 0 c 27,50%-Hbim coAepmmtniem
xpacHTeas paCTB0p51OT B 50 MA BOAbI H menumpyroT npH 60-65? 100 MA AHmeTH.Ti-
cy.nb4mTa H 130 At4 30%-Horo emcoro HaTpa, npHonsan nepe3 xanutbie 2 cex.
1 Karim? AHmeTH.ncyabcpaTa. ,Jo6as.neHHe (no xananm) ate.nonn pery.TmpyroT Tax,
mTo6bi pH Bce BpemH C0OTBeTCTBOBaJI0 8-10. B nepsbal qac CKOpOCTb TIO,L1a11H me-
JI0T-111 2-3 Kamm B 1 cex., B c.rie,ayloame 30 MHH.-1 KaTIJISI B 1 cex. H ewe B Teme-
HHe 30 la1H.-1 Kal1J151 B 3 cex. B TeneHme 2 sac. npH6as.nntoT?secb JAHMeTHJICy.11b-
cpaT, 3aTem cnycTs iO MHH. npexpamaloT Ao6asaeL1He mg.notm H nepemeumsaloT
1 nac rip H 70?.
Peammom-13no cmecb o6pa6aTbmatoT FeCl3 H COJI5TH011 KHCJIOTOR H limp-m.10T
3 a cHHero amoixporo nopounm, KOTOpbIci npeAcTaBaneT co6oti cmecb MOHO- H
menunntilmro. amyl xpomaTorpacpmecxoro pa3Ae,neHns no.nyqemibin nopolnox
pacTsopsnoT B 300 MA 6ei3oga H OT(1)14.11bTp0BbIBalOT npnmecb 0,6 2 HHAHro. ATICOp6-
11,140HHy10 Tpy6xy AJIHI-1011 B 20 CM H ,I1,HameTp0m 5 CM HaTIOJIHSHOT A1203 H yeTaHaBJIH-
BaloT B TemHyro xamepy. J1O nponaneHHH no.nynatoT c.ne,AylomHe nozocbi: nepHo-
3e.rieHoro HBeTa (1/2 CM), TemHo3eaeHoro (7 cm) H TemHocHHero useTa (10 cm); nocae
npons.neHHH 200 MA 6el3ona?xopHinieBo-fnepHa1 (1/2 cm), }xe.nTo-3e.neHan (4,4 cm),
TemHo3e.neHan (10 cm) H TeMHOCHHHSI (8 CM) TIOJI0Cb1 H TeMH0CH111411 (1)4JIbTpaT.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KPACHTEJ114 H 1-10.TIYHP0,11,YKTbI
107
3eJIelly10 H CHHI010 30HbI OT2IseJ15110T H Ka Kum B OTAe.TIbHOCTH paCTB0p51IOT B 200 MA
aueToHa. Flocae ynapHBaHHH B TOKe a3oTa KpHCTa.TIJIH3y1OTCY1 TYPICTble MOHO- H
COOTBeTCTBeHHO AHMeTHJIHHA141.0. N-MOHOMeTkIJIHHAHFO, oxpaLueHHbai B 1-1HCTbal
CHHHil 11,BeT, pacTsopHeTcH B opraHmecKnx paCTBOPHTeJIS1X MHOFO aerge, qeM
HHAHFO, H KpHCTaJIJIH3yeTCH H3 neTpoaeRHoro 9c1)Hpa B mule cvnie-clmo.neToBbix 111.11,
npH 254? 11J1aBl4TCH, npH 258? CHOBa 3aTtlepAesaeT H 3aTem o 300' He TIJIaBHTCH,
npH 200? HaqHHaeT MeXTICHHO Cy6J111MHp0BaTbCH, HH 233-234?-6bicTpo.
Pe3yobTaTbi aHaJuna COOTBeTCTBylOT cocTaBy C171-112N202?
?Ins' onpeae.meHHH CTOIIKOCTH K cBeTy MOHO- H ,11,HMeTHJIHHAHFO a,acop6u,HoH-
KOJIOHKy, nposumeHHylo H eate 3ancoHenHyto 6eH30J10M, Bbi,ReNKHBatoT npH
30? Ha COJIHellHOM CBeTy. CIlyCTH 1 qac TemHo3eaeHaB 30H )Ke.wreeT H 3aTem o6ecaBe-
14HBaeTcB, B TO Bpemm KK MOHOMeTHJIHHAHFO H3meH51eTcH B Tet'exile 3 Aueff?TeMHO-
CHHilii 1I,BeT npespamaeTcH B KpacHo-cimaTeToribici, TemBoxpacHufi H, HaKoHeu,
BHOBb B KpacHo-cl)HameToBbici; o6pa3oBameecH coexmeHHe 11.11aB14TC1 npH 284?
YI HainmaeT Cy6JIHMHp0BaTbCH npH 210---2200
.
5. fia.4brietimee memuAupoeariue N-mottamemuAurtaueo3oAR
N-MOHOMeTHJIHHAHr030,Thb pacTBopHeTcH aertie N,N'-14MeT14.TIIIHAlir030JISI. 143
menumpoBaHHori }KHAKOCTH Bbkae.TISHOTCH BHaim.nre tieTbipexrpaHHbie 6.necTsnue
11.11aCTIIHKH AHMenITIC0eAHHeHHH. FIOCJIe Bbulep?KHBanHH BHue 3 CyTOK B ma-
TO1THOM pacTsope o6pa3y1oTcH xpncTammbi MOHOMeTkIJIHHAHF030JIYI B 1314,Tke npH3m,
KoTopme npH OKHCJIeHHH AaioT 11HCTbIl1 CHHHil xpacHTeab; moHomeTH.THHAHro3oab
nepexpHeTa.n.m1430BbIBalOT 113 10% -Horo pacTe.opa noBapeHHoil calm.
3,4 a N-MOHOMeTHJIHRTAHF030.1131 paCTBOIMOT B 30 MA Boabi, meTHanpyloT npH
40' B TetieHme 15 MI-IF!. 45 MA AmmenuicyabcpaTa H 100 MA 42 % -Horo pacTBopa ea-
Koro HaTpa H 3aTem nepemeumBaioT 1 tiac HH OKHcawreabHoe pactitenaenue
IlpHBOLIFIT K 06pa30BaHHIO 1,8 a 3e.neHoro amopctmoro nopoma, KoTopbul nepexpH-
CTaJIJIH3OBbIBalOT 113 6eH3OTIa; T. FIJI. 182-183?, pe3yabTaTbi aHaan3a COOTBeT-
CTBylOT AHMeTHJIHHAfir0.
II. H 3 T H JI 11 HAHro
/. PeaKtitifrl 317111AtiPoeantaz
20 a auTpa3o.rm 0 (27,5%) pacTsopsuoT B 70 MA BOAbI ripH ymepeHHom Harpe-
Baiiiill H o6pa6aTbmatoT, KK ripH menumposaHHH, 100-130 MA ,r04.3TH.Tcyab4aTa
H 150 MA 42% -Horo pacTsopa ejtxoro HaTpa npH 70-80? pi cHabHom nepememBaHHH;
nocoe Ao6aB.ReHHH pacTsopos nepemeumBaHHe npo4o.Twalar elite 3 xiaca npn 80?.
HatiameecH Buria,aemie KpHCTaJIJI0B AH3THJIIIHAPIF030J1F1 ycH.ramaeTcH npu ox.ma-
waeHH14. OKHCJIHTeJIbHbIM pacnieruleHHem no.nytiatoT 6 a N ,N' -AH3TH.HHHHro
(92% OT TeopenmecKoro).
B opraHHgecKnx paCTBOpilTe.TISIX ,L1H3T11JIHHAY1F0 pacTBopHeTcH C 3eJ1eHbIM
oxpaumBaHnem; c KoHugHTpHpoBaHHoil cepnofi, XJ10PHOF1 H COJIHHOIA KI4C.TIOTaMH
o6pa3yeT HHTeHCHBHbIe TeMHOCHHHe pacTsophi, coxpaHmouwe HBeT, KK H ;lame-
THJIHHAHFO, Her1po4o.n>KHTeabHoe spemH. Kpacwreab pa3msirgaeTcs1 ripm 150? 14
IIJIaBHTCH npH 161?; cocTap. c0fi1802N2.
arm KpameHHH aeaecoo6pa3Ho llpHMeHHTb He cso6o,Tmbal KpacHTe.mb, a cTa-
614J1H311p0BaHHbal He60JIbLIIHM KOJIHTleCTBOM NaHCO, N,N'-A143T14,11HHAHr030J1b,
K9T0pb1l Bcera MOHKHO nepeBecTH B aHaJIHTHileCKH TIHCTbal KpacHTeJlb.
N,N'-,LI143THJIIIHAHCO OKIICJIHeTCH B N-3THJIH3aTHH Ha xo.no,ay KoHugHTpHpoBanHa
230THOII KHCJIOTOil B ae,aHHoil yKcycHoil KHC.TIOTe B ,TeileHHe 2-3 !lac.; T. Ha. 94,5?.
2.? Hampueeasi COAb aucepnoKucAozo xibupa AetitcocoeaunexuR
N, N'-ouNnuntinaueo
06pa3ylow,llficH npil 3THJIHPOBaHHH ripojkyKT co,Itepx{HT TOJIbK0 70% 6e3-
soilHoro HH,IHF030J1S1; Houle TpexKpaTHoft KplICTaJ1J1113aIkHH 113 BOAbI noarialoT
Approved For Release 2007/11/05 : CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP. 83-00418R004500120001-7
108
KPACHTEJM H 110JIYIIPO,LIYKTbI
6aecTuume, co,gepKaume Bogy IIPH3MbI, He o6.na,gaioutHe B IIpOTHBOHOJI0}KHOCTb
1HmeTHanpoH3BoaHomy rOpbKIIM BKyCOM. rIpH 110-115? BeatecTuo HammaeT pa3-
aaraTbcq, npH 9Tom uHaLlane 1105IBJIgeTC51 HeCKOJIbK0 TemHooxpaineHHbix TOtleK;
pa3.no)KeHHe pacnpocTpamieTcq Aaabuie H o6pa3yeTc1 cHHe-qepHbul nopowox.
BogHbifi pacmop Hmeer oTTeHb c.na6po )Ke.rrryio oxpacKy; B au,eToHe, crmpTe H IMF
piimme BemecTso xopotuo pacmopmeTcH; B yKcycHoil KHC.TIOTe o6pa3ro-
1.11,13ACH uHaqa.ne 6ecuseTHbifi pacTuop oxpaumBaeTcq npH HarpeBaHHH B ray6oicHti
TeMH03eJIeHbIti nueT; TaKaSI )Ke oxpacKa *Ha6moAaeTcH H B oTcyrcTuHe Bowtyxa.
OKIICJIeHHe nprI 110MOLIIH FeC13 H COJIHHOrl KFICJI0TbI npoxo,RHT meivieHHee, gem ;time-
THanpoH3Bomoro; oKHczetme cTaKaapTHEilm pacTuopom PyrraH?B TetieHHe OKO.TIO
10 MM. npH 60?. 06pa3yeTcw )1143THJIIIHAHr0 B BH Ae (PHOJIeTOBO-CHHHX Hra, xoTopme
Ha TJIHHAHOM xlepenice AaioT 3e.TIeHy10 qepTy. I-1pH OKHCJIHTeJIbHOM paagenneHHH
a3OTH01 KHCJIOTOR cpa3y o6pa3yeTcq Kopp-mem:di npouxT, KOTOpbui eme max)
Hcc,ne,RoBaH.
011HCanfIbItil HH)Ke meToA oqucTKH IlpHBOAHT K o6pa3oBaHmo onpe,ae.neHHoro
rupaTa )1113TFIJIHH,EIHr030JIA. 1,5 e TexHHT-lecxoro npoAyma, KplICTaJIJIH30BaHHOr0
3 pa3a H3 BO,AbI, pacTuopsuoT B 35 .m.4 meTHaouoro cmipTa rip H HarpeuaHHH, B36aJI-
TbIBaIOT ()KOJI? 20 MM. npH 50? H OT4JkIJIbTp0BbIBalOT HepacTriopkulluylocH Heopra-
Hmecxylo COJIb (0,05 a) . Ec.im no ox.naKgeHHH H ,1(o6aaneHHH 50 MA 34oHpa ocaAoK
60.TIbUle He Bbma,gaeT, TO ,406aBJ15110T B Tegeime 15 MHH. 3 x10 MA scImpa H nocze
Haqaaa xpHcTalumailHH?eule 50 MA atIcopa, nocae tier? Bbutep)KHBaioT 2 qaca
B XOJIOAHJIbHOM Luxacpy. KpIICTaJIJIH3y1OT H3 BOXI, cyluaT 2 qaca. npH 40? H
? TeTparHApar (C201-11808N2S2Na2. 4H20).
01;151 y,ga.neHHH KPHCTaJIJIH3aLIHOHHOti BOAM (KaK H /IASI ,E1Hmenumpoll3B0A-
Horo) TeTparHApaT cymaT HH IIOJIHOM OTCyTCTBHH Tio3Ayxa B BbICOKOM Baxyyme
npH 110? B TetleHHe 5 qac. Ljici Tolmoro onpeAe.neHHH coitep)KaHHH BoonsopoAa Ha-
Becicy C)KHralOT 6e3 TIBTHOKHCH BaHamm. COCTaB npoAyirra C20H1808N2S2Na2.
3. N-MOtiO9MUAlllialle0
20 aaHTpa30JISI 0 paCTB0p5110T B 100 .114A BObI H 3THJIHpylOT npH 70? (pH 10)
H aHeprwmom nepemeumaHHH 60 MA ,4113THJICyab4JaTa H 100 MA 35% -Horo pacTuopa
excoro HaTpa, 3aTem nepemeummalar eine 1 qac nini 90?. flo oxaamKeJITbIfi nHeT, B X0-
JIO,EIHOR BoAe nJI0X0 pacTsopRIOTCH, B TopHqefi?xop01.110. XOJIO,IIHme paCTB0pbI
o6.HajlaioT cza6bim ropmthm Hxycom. BbicyluexHoe Ha Ho3,Ryxeseuiecino no cocTaBy
COOTBeTCTByeT TeTparH,ApaTy c..? 0 H22 N202 S2Na2? 4H20.
,L1a.ribHeilaipo cyamy Ii ana0B3 npOBO,IIHT TK }Ke, KaK AHMeTHJIIIp0H3BOAHOTO,
pe3YJIbTaTb1 anaan3a noc.ne cyuncH COOTBeTCTBy1011 cl:lopmy.ne c0H22N20232Na2,
4. N-M01.1066113UAUHalie0
aH6eH3B.ra1Hg11ro rip H npoRyBaHm4 Bo3Ayxa B Texierme 1 qaca B minsniteti
..fleAHHOPI yKcycHoil KHCJI0Te nepexo,AHT B MOH06eH3HJIHHAHTO. 3T0 npespaugHHe
B 6eH3o.abHom pacTsope npn 6Q-65? H oTxpbuoil xo.n6e npoxo,RHT B TegeHne 5 qac.
B OTCyTCTBile B03,411,yXa FIHKaKHX H3MeHeHHil He npoHcxo,RHT. ,E1H6eH3H.TH4posaHne
MO)KHO Ha6mo,RaTb no B0.3HHKHOBeHHIO cHHeil oxpacKH pacTsopa; noc.rie HcnapeHHH
pacTsopHTe.um ocTaeTcH MOH06eH3HJI11HAHTO, n.nasHunificH HH 210? (c npe,RHapH-
TeJlbHbIM pa3mHrHeHmem).
ECJIH HbHueornicaHHoe 6eH3H,TimposaHHe IIPOBOAHTb TOJIbK0 C 8 MA x.nopHeroro
6e11314.71a B Teqemie 30 MHH., TO o6pa3yeTcH cmech HHAHT030JIetl, 113 KOTOp011 BbI-
AeJIHIOT moHo6eH3HanpoH3Ho2Hoe B BH):Ie cHHeil 30HbI Ha A1203. H 320 a aHTpa3o.ng 0
nanyHatoT 3 a N-MOH06eH314.31311,11131.0.
B. N,N'-3 H e pnmeTH JIeHHHAHTO. I. N,N1-9 T
eHHH All r 0
20 a HH11T030JIH 0(27,50%) pacTHopsuor B 80 MA SWIM B n51T11T0pJI0ii Hpyr.no-
AoHHoti xo.116e H Ao6aBaynoT B TeHeHHe 1 Haca HH 70? H 3HeprHHHom nepemeullma-
HMI 40 MA 6pomucToro HTH.Tiella H 200 MA 42% -Horo pacmopa eAxoro HaTpa. B )KHA-
KOCTb npoilyHalar a3oT, He coAepHauniil KHc.nopoAa, H 3aTem HarpeBaroT eine 3 Haca.
IlocJie HbukepNwHaHHH B TeHeHne CyTOK HbinaHandi KpacHo-)Kezruil HJIH
? OCaRoic OTCPHJIbTp0BbIBalOT, np0MblBaloT 34mpOM H cyinar B HaKyyme
Ha,Ik XJI0pHCTbIM Haabusem H napackHHom; Hee ocaxca 4,3 2. B cluipTosom pacTsope
ep,Koro KaJIHpaCTB0p BmeeT ?KeaT0-3e.neHylo (1).71yopecneHnmo, a He KoplitnieBaTylo,
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
110 ? KPACHTEJIM H 110JIYIIPOPYKTbI
KK y ilHCTOTO3THJIeHHHAVITO. 1103TOMy N,Nf-3TH.IleHH1-iAHr030J1b oqHmatoT xpomaTo-
rpacpHposaHHem. flocie pacTsopeHHH B 50 MA son,m a,ncop6HpyloT Ha xo.noHHe
c A1203 (50 x 2,5 cht); A1203 aKTHBHpylOT 3 pa3a soaonposonHofi B040c1 H pacTsop
nponycKatoT CO CKOpOCTb10 1 Kamm B 1 ceic. BbIMbIBalOT 300 miz AeCTI4J1.7114p0BaHHOFI
BOAbI H no.nyqaroT 5 cppanutti, npo6m KOTOpbIX 11p05TBTIHIOT pacTsopom FeC13
C0J151H0f1 KHCJIOTOCI. FlepBble 3 eppaKu,HH coaepHaT CHHH HpacHTeab, a 4- H 5-H
Amor Hopmniesbie (no 3e.neHo-HopHqHesmx)ocaaHH npumeceg. (DpaHu,HH 1-3 OKHC'
JIHIOT CTaH,RapTHbIM paCTB0p0M PyrraH, HpacHTe.nb OTCPHJIbTp0BbIBaIOT H npo-
MbIBBIOT ropfmeti BOA0c1; BbIX0,11, 2,5 e (40%).
KpacHTe.nb ;VIA 011HCTKI4 OT HHAHro paCTI3OpFHOT B 200 .4M nflpHaHHa,
cHJIb-
TpyIoT, eme pa3 aacop6HpyloT Ha A1203 H TIpOSIBJIHIOT 300 mit impHaHHa. OCHOBH0e
KOJIHIleCTBO pacmopa (200 AtA), HMelomero HHTCHCI4BHbIll 1:1)H0J1eTOBO-CHHHfi user,
cinunapyloT Ha ciniabTpe MoTTa, 3aTem cmeinHsatoT B Tetietme 2 qac. c 450 MA 34)14pa
(110pII,HHMH 110 110 .41Z); npH 3TOM BbIAeJIHIOTCH KOpHTIlleB0-4)H0J1eTOBbIe 11J1aCTHIIKH
H npH3mbh ITOCJIe Bb1,11eNK1413aHHH B cyToK B XOJIOAHJIbHOM 1.11Kali)y OTC1)14J1b"
TPOBbIBalOT HpacHTeab, csofIcTsa KoToporo 110JIHOCTb10 COOTBeTCTBylOT 011HCaHHbIM;
BbIX0,11 ?KOZO 30N. COCTaB npo,nyHTa (no AaHHbIM aHamma):
B KatiecTae npome?HyTotmoro seiAecTsa o6pa3yeTc51Anio.neToso-KpacHmil HpacHTe.nb,
KoTopmfl 110,IT14 He Hccae,nosaH.
CnexTp N,Nf-3TH.TICHHHAHr0 oxieHb 6.nH3oH no xapaxTepy H se.mqHHe IMMO-
uietnisi K HHAHFO. no o6pa3osaHmo caneti 3TI4J1eHHHAHTO non,o6eH N,Nf-AHMeTHJI-
1411,11Hro.
II. N,1\1f-TpHMeTHJIeHHH)1,HTO
20 e HH,1114T030JIH 0 paCTBOMOT B 70 MA BOAN B TIFITHTOPJIOR KOJI6e eMKOCTMO 1 .4.
K noxygeHHomy pacTsopy I.105aBJ1Fl1OT no KanaHm npH 85-90? 10 MA 6pompicToro
TpHmeTH.neHa (1 KaIIJIH 1 ceic.) H 100 .4M 42%-Horo pacTsopa excoro HaTpa
(2-3 Kamm B 1 cex.). Bpomncluti TpHmenmeH npHmisaloT B TexieHme 10 MHH. H ate-
.110qb-15-20 MHH. CaycTH 10 MHH. Har4HHaeT sbmanaTb HopHimesaft mac.natificTast
macca, H epea 1 qac peaHuun aaHawnisaeTcH. >KHAKOCTb, c.na6o oHpaineHHylo
B }KeJablil 1.1,BeT, cmisalar, cmany pacmpatoT Ha TJIHHHHOM TlepenKe, npombisaloT
HeCKOJIbK0 pa 3 6eH30.TIOM H cymaT Ha A x.nopHumm Haabuxem H napa4m-1?m;
no.nyqatoT 15 e weaTo-HopmHesoro nopounm, coaepHamero N,Nf-TpHMeTH.neHHH-
,II,HTO smecTe c HeoprammecHHmH COJIHMH H 3arp5J3HeHHHmH.
lipoayHT pacrsomoT B 400 MA BORN, K1411FITHT 15 MHH. C aKTHBHpOBBHHIAM
yr.nem H 4)14J1bTpy1OT epea cH.na,nqaTmil 4314JIbTp. PaCTB0p c.na6o 110,4KHCJIHI0T
COJ151HO1 KHC.TI0TOC1 (1 : 1) H cmeumsatoT c pacTsopom FeC13 (He60J11,1110f4 1436brroK)
npH 35?. CHJIbHbIlV.1, BCTp H X14BaHl4eM Bb1,4eJIHIOT KpacHTeab B X0pOILIO (1)llabwr0atetica
clopme. 014)14JIbTp0BbIBalOTH cymaT npH 40? B saHyyme.FlpH 3TOM 3eneHaH Komno-
HeHTa B KOp1411HeB0-3eZeHOM 110pOILIKe HpacHTe.nH pa3.naraeTcH H oHpacHa pacTsopa
B rnipHAHHe npHommaeTcH K lipaBHJIbH0c1; BbIX0,11 nponywra 4,1 e (64,7%).
?11.11H aahHetimeil 01-111CTKH seatecTso pacTsomoT Ha X0J10,gy B 140 MA tHipH-
AHHa H xpomaTorpacimproT Ha A1203 (40x4 am). floc.ne 11p0HBJ1eHHH o6pa3poTcH
c.ne,nylontHe TIOJI0CbI: HHTeHCHBHOTO 3e.neHo-qepHoro useTa (3,5 cm), 14HTeHCHBHOTO
KpacHOBaTO-CHHero (30 c.m) H CBeTJI0ro rpH3Ho-}KeaT0-3e0enoro useTa (4 c.u).
Bb1Mb1BaIOT 1114pHAHHOM (300 MA) H nanytialoT c.ne,nyfoin,He pacTsopm: (ppanum /-
40 MA, Hopmmeso-)Ke.nToro useTa; cppaHHHH 2-25 MA, cinio.neTosoro u,seTa (cmecb
1 H 3); civaKaHR 3-180 MA, cHHe4Ho.neTos0ro usem; H cppaimasi 4-30 MA, cHHero
useTa. ctopaHuHH 4 coaep}HHT tnicTbifi, a cppaHHHH 3-110qT11 HCTbI TpHmeTH.neH-
HHAHro. 3TH pacTsopm HcnapsHoT J0 He6o.nbmoro oftema B 9KCHKaT0pe npH 1-Ie6o.nb-
mom pa3pe)HeHHH B TOKe a3oTa H OCTaTOK cmeanmatoT c acimipom. TpHmem.neHHH-
miro HpHcm.a.nH3yeTcH 143 impHaHHa B sH,ae npH3m HJIH 11J1aCTHH0K C meTa.n.nn-
qecHilm 6.necHom, HoTopme, KaK H 3T14J1eHHHAHTO, B npoxoaHmem cseTe }mem'
Hopmmeso-clmo.neTosylo oxpacHy. B HoHHeHTpuposaHHoci C0J1511-10c1 KI4CJI0Te pac-
TsopHeTcH C CHHHM oHpaumsaHHem, B HoHuewrpliposaHHoll cepHoil KHCJI0Te Ha X0-
norky?t c1IHe-3e.neHbim U npH HarpesaHHH?C CHHHM oxpaunisaHHem; B noc.neolHem
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KPACHTEJIH H TIOJIYIIPO,RYKTbI
111
c.nytme npoHcxo,u,HT cyab4)HposaHHe. B neTpo,netiHom 3(1)Hpe HpacHTe.nb Hepac-
TB0pHM, B scimpe, B OTAH4He OT 3THJIeHHHAHTO, caa6o pacTuopseTcs C 4:1110.TheTOBbIM
oxpau1Hn3aHHem (Booaue paCTB0p1IMOCTb no cpasHeHmo C 3THJIeHIIHAFITO HeCKOJIb-
KO .nytnue). B 6eH3o.ne, AHoKeane, x.n0p6eH30.nre H ammonom cnHpTe Ha xo,noily
pacTuopseTcs ymepeHHo C CHHHM oHpauffluaHnem, HoTopoe npH Harpeeatoth npH-
06peTaeT HHTeHCHBHbIlA HpacnouaTbig oTTeHoK. fleAsHas yHcycHas KHC.TIOTa CpaBHH-
TeJII3H0 ?nerHo pacTuopseT Bear,ecTuo C IIHCTbIM CHHHM ospaum3aHHem. flpH AefICTB1114
ute.nogeil npolicxoAHT paino?HeHue, oxialco 6e3 xapawrepHoci cilnyopecuemum,
nosuosHometics npH paino)HeHHH 3THJIeH- H CTHpHJIIIHAVITO. K ,neficTumo HHcaopoAa
TpHmeTwneHHHAHro 6o.nee CTOeK, =rem 3THJIeHHHIII3c0; T. IIJI. 214? (Hcnpau.neHHas
T. n,n. 220,5'). 11.nas,neHHe conposomc,naeTcs painwHeHHem, ospaumBauHem
B HopHT4Hesb1 llueT H o6pa3oHaHHem cy6aHmaTa B HHAe CHHHX KplICTaJIJI0B. COCTaB
ripo,aywra (no AaHHbIM ananH3a) C191-1102N2?
FlpH OKFICJIeHHH a3OTHOR KHCJIOTOR Ha xo,noAy B J1e1HO1 yHcycHoil KIICJICITe
o6pa3yeTcs Hpacno-HopHsHeublil pacTuop, H3 KOTOpOTO npH ox,nalH,neHHH
JISHOTCH HpacHo-opauxceame KplICTaJIJIbI TpHMeTHJIeH2uH13aTHHa (140 .we H3 150 Me,
84,4% OT TeopemsecHoro). BemecTrio (C191-11404N2) noc.ne ,nrsyx HpucTaa.nmauHil
H3 .ne,nsHoil yHcycHoil KHCJI0TbI HMT T. 11.1I. 239?. 3TOT rgio,nyHT TaloHenoiyaio
CHHTe30M H3 H3aTHH-HaTplIH H OpomHcToro TpHmeTH.neHa.
B. AJIKHJIHp 0 BaHHe ra.non,u,HponaHlibix Aticepm
KIICJIbIX 3 Cl)Hp 0 B aefixoHHAHro. I. AHTpa 3 OA b 04B
1. MemuAupocatiue
20 e HHAHr030JIH 5,7,5',7'-TeTpa6pomHHAHro (coAep)Hamero 66,99%, no
pactieTy 73,71% HpacHTeas, 90,88% IIIICTOTO aHTpa30.7151 04B) paCTB0pHIOT B 100M2
IrOpfigerl BOJbI H meTH.nupyloT 30 MA 42% -HOTO pacTuopa ex{oro HaTpa H 230 MA
AFIMeTHJICyJII4aTa (1 Hamm B 1 ceH.) HH 50-55?, CnycTs 1,5 qaca meTH.nHpouaHHe
3aHaHtmuaeTcs, 0,n,HaHo nepemelum3aHHe npoAo.n?HaloT euke 2 maca npH 60-65?.
B npou,ecce peamAHH umnaikaeT 6ecuseTHEdti HJIFI )KeJITOBaTb1f1 nopomoH, KO-
? otunHaroT Bbi,ne.neHHem H3 memsouoro cruipTa Ampom. 5 C AHmeTHaTeTpa-
6pomHHAHro3o.ns ,n,J1i1 TIOJITIeHHH HpacHTe.ns pacTuopcnoT B 200 MA SWIM H OKHCJISI-
10T npH 70? 10 MA FeC13 H 10 MA COJIHHOR KHCJIOTI1 (1: 1); IIOLITH KOJIHtleCTBeHHO
BbIiIeJIHBLIIHCICH HpacHTeab (1)FIJIbTpyl0T, npombn3a1Or BO,II0f1 H CIIHpTOM H CyllIaT.
N,N)-,11,HmeTH.n-5,7,5',7'-TeTpa6p0MHHAIITO pacTuopHeTCH B 06bIgHbIX paCTBO-
pilTeJISIX HemHOro Aerie, IleM HCX0,411oe seatecTuo, nytnue Beer? paCTB0pHercsi
B ropssem nHpHHHe, ymepeHHo?B 6eH3o.ne H AHoKcalie, ma.no?B ne,nsHoft yKCyC-
HOi Bce pacTuopm oHpalueHbi OT CBeT,TIO- H O HHTeHCHBH03eneH0I-0 u,BeTa;
B KOHUgHTpHp0BaHHOi1 CepHOR KHCJI0Te Ha xono,ny H npH Harpesami pacTuopseTcs
C CHHHM oHpaunmaHHem; B x.nopHoil KFICJI0Te (60% -Has) B OTJ1HH OT ,LIFIMeTHJIIIHAH-
ro He pacTuopseTcs. I/13 mipHAHHa HpHcTaznH3yeTcs B sHike TIJIaCTHHOK, HatIHHa10-
[AUX mnamTcs ripH 220? C 3e.neH0fi ospacxofi; OCHOBHaH l!eillecTBa, painaraeT-
? nepexo,ns Hepacn.nameHHoe COCTOHHHe c cHHefi oxpacHoil; Bpi,' 230? u,BeT n.na-
Ha CTaHOBHTCH KOpHITHeBbIM, BK/IeJI5HOTC51 cHHHe KplICTaJIJIN. Ky6 ma.no npHro,neH
xis Hpamemni XJI0IIKa. COCTaB npo,nyHTa (no AaHHbIM aHamma): C181-11002N2BT4.
OKHCJIeHHeM a3oTHoti KHCJIOTOA B ne,11,51H011 yHcycHoil KHCJI0Te 110JITIalOT
N-meTm-5,7-,nn6pomH3aTHH (T. IIJI. 182-183?), KOTOpbal o6pa3yeT 3-amm?Hpac-
Hue KpHCTaJIJIbI, T. FIJI. 158? (pain.). AHaJIH3 COC/TBeTCTByeT cpopmyae
,II,HmeTHaTeTpaopommitHroaanb xpomaTorp atop par Ha A1203; H3 TpeTbeil cl)paH-
mill pacTuopa mexneHHEAm HcnapeHHem B TemnoTe BbI,LIeJISHOT KpHCTaJIJIbI AH-
rHApaTa (C18H10O8N2Br4S2Na2. 2H20).
OKHCJIeHHe C o6pa3oBaHmem HpacHTens npoxo,nHT B ,naHHOM c.nytme xopomo
C a30THCT0cI KHCJIOTOFI npH ymepeHnoct TemnepaType. B TemHoTe HHAIII'030JIb COXpa-
HHeTCH B TegeHHe mecHua, Ha AHeBHOM CBT y 6bIcTpo3e.neHeeT. B yJuDTpacimaneTosom
cHeTe noKaabmaeT KopligHeHo-mepHylo cpayopecuentmo, B TO HpemH KaK ,1114MeTFIJI-
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
112
KPACHTE.T111 H TIOJIYTIPOILYKTbI
HHA1T030J1b?CBeTJ10040J1eTOBy/0. Be3sop,Hoe sentecTso (C14H1002N2Br4S2Na2)
110JITIHIOT BbICyUIHBaHHeM B BbICOKOM saKyyme ripH 100? HaA TIFITH0KHCb10 4/OC410pa
B Teqemie 6 qac.
N-Monamemu.4-5,7,5',7'-mempa6pohumoueo. ,(1.1151 H3yHeHH51 AemeniaHposa-
HMI 1,3652 0 AHMeT14.T111p0H3B0,111-10TO B 100 AA ae,asmoti yKcycHoil KIICJI0TbI KHIPITSIT
Ha mac.rismoil 6aHe B Tegemie 4 qac. npH nponycHaHHH somyxa. Yanexaembn1 B03-
Ayxom cpopma.nb,aerHA nponycKalar qepe3 ;Ise npombisa.rnm, ox.naxi,aaemble abom
H co,aep)Haanie no 50 MA so,gbi, a 3aTem qepe3 TpeTbio, coAepHialnylo 20 MA pac-
Tsopa 2HHHTp4eHH.nrupa3HHa B 2 H. COJIHHOR KHC.110Te. B noc.ne,aHeil npombmaaHe
()cum< He suna,T.taeT, B nepsoil H wropoil npH o6pa6ome AHHHTp04eHHJITHApa3HH0M
o6pa3yeTcH 0,1412 0 AHHHTp04VHHJITHApa3oHa, TITO cooiseTcTsyeT 29,82% (oT
TeoperHqecKoro), cinfraH Ha o6pa3osaHnnalcH cflopmanwterHA. 143 peamworworo
pacTsopa BbIlleJ15110T 0,40852 MOHOMeTHJITeTpaop0ml4H2U1r0 (30,63%), KOTOpb1 HpH-
CTaJ1J11,13yeTC1 B sH,ge HIV! 133 CHHeTO pacTsopa B HHTpo6eH3q.ne,_ flpH 300? pama-
raeTcH C olipaunisaHHem B K0pHHHeBbIc1 LIBeT. CocTas npo,1JyKTa.(110 AaHHbIM aHa-
.743a): C17H802N2Br4.
2, amuAupoeauue all171PC1.30AJI 04E
aTHJIHpylOT I1H3THJICyJIMIMTOM aHa.normHo 0111ICHHHOMy B nyHwre 1 H 110J1y-
HHIOT TeTparwapaT N,N'-,AH3TH.q-5,7,5',7'-TeTpa6pomHHAHro3o.nH, KOTOpblii KpH-
CTHJIJIH3yeTC51 143 B0,11140TO cru4pTa B sHAe 6ecuseTHbix 11.113CTIMOK, pamararoaulxcH
npx 121? (C201-1/402N2Br4S2Na2 ? 4H20)? Ilo.nygeHa 6e3soma5I AHHarpHesa51,
a TaioKe aHHJIIIHOBa51 H nHpHAHHosaH COJ1H HHA1IT030J151, co,aepwani,He 2 moaH 0C-
H0BHHH51.
Xpanamoepcufiutteacoe pa3amettue au3mu4mempa6pomuttoueo3oAst u mempa-
6pomux3ueo3a2R. 0,1% -Huff pacTsop 060HX HHIIHT030J1efl nponycKaicrr no 20 MA
smecTe C 50 MA B0,11,131 epea KOJIOHKy C A1203 (pa3mep KOJIOHKH 180 x 25 ca); noc.ne
npocatnisaHHH pacTsopa qepe3 CT0JI6HK A1203 11p05113.11HIOT BOI10c1 nopuHstmll no
5 MA. B 641 cppaicu,HH 11051BJI14eTC1 HHAHT030.11b 04B, B 7-1241 4pammix?o6a se-
nwcTsa, B 1341 4)paKuHH?TOJIbK0 1U13THJITeTpa6p0MHHAHTO? XpomaTorpacImposa-
HHe BOAHOTOpacTsopa AaeTHe3HaqineJibHblri 34X1/eKT pa3,4e.neHH14, ayqunie pe3yab-
TaTbl no.nyqafar C 6e3so2LHum HH,11,HT030J1eM B nllpHAHHe.
. N,N'-,ail3THJI-5,7,5',7'-TeTpa6p0MHHAIITO 110JIygalOT 143 14111HT030JIH 14 5% -HO-
TO FeC13 B sue TeMH03eJ1eHbIX x.nonbes, HoTopme KpHCT14JIJIH3y1OT 143 nHpHAHHa.
I-1pH KH1151HeHHH nHpHAHHoeoro pacTsopa HaqHHaeTcH ,Rea.HHH.nHposaHHe, KOTOpOe
MONCHO Ha6J110,14aTb no yse.Turqemno cHHeil OxpacKH. FloaTomy KplICTUJIJIH33111410 He-
06X0AH1VIO 11p0B0,1114Tb 6bicTpo HJIH B OTCyTCTBHe so3,gyxa, CocTaH npo,Rywra (HO
)1,3H11111M aHa.HH3a): C201-11402N2Br4.
lipll IleaJIKHJI1p0BaHHH o6pa3parcH aneTaabAerHA H MOHO3THJITeTpa6p0MHHAH-
TO B 3KB11B3J1eHTHbIX KOJIHHeCTBaX. HOCJIeIIHHCI 143 pacisopa B .neAHHoil yKcycHoil
KHCJI0Te o6pa3yeT 6.HecT11InHe, 6poH3Hpyio11nie 14TJIbI, HoTopue pacTsopsnoTcH BO
scex paCTB0pHTeJI11X C CHHHM oHpaumsanHem; aerxo pacTsopsuarcH B TOpflHeM HH-
Tpo6eH3ane HJIH nHpHHHHe. T. 11./1. 225? (a 6aoHe). AHHJI143 Hpacirre.HH COOTBeTCTBy-
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HOR yKcycHoil KHCJI0Te, T. n.n. 128-129?,
flpH npfimom 110JITIeHHH MOHO3THJIKpaCHTeJIH anTpa3o.nb 046 3THJIHpylOT Ka-
oHesoil comao 3THJICyJI143TH. 10 2 HHAHT030J151, 60 MA BON H 15 MA 42%-Horo
pacTsopa excoro H aTpa Ho6as.nsuoT no KM-1.1151M B TexieHHe 2 HaC.. K 150 2 KanHesoil
COJIH 9THJICyJI4UTa B 200 Am B0,11131 H 200 MA 42% -HOTO pacTiopa eJIKOTO HaTpa npH
70-750, 3aTem npH6aaasnoT eute 50 2 TsepAoil KaaHesoil C0.1111 3THJICyJ1143TH He-
60J1bILIHMH 110p1.11451MH B TeceHHe 30 MHH. H noc.ne 3TOTO nepemennisaloT 3 qaca npH
800. OpaHnHoHHoil KpHcra.n.qH3a1.Heil 14HAHro3o.nH (Hai< H nanyqeHHoro 113 TpeTbeil
4)paHnHH KpacHTe.nH) BbIge.115110T 400 M2 MOHO3THJITeTpa6p0MHH1LHro (5,7%)
(T. WI. 225?), H 30 we AH3TH.TrreTpa6pomHHAHro (0,41%). B co,aosom pacTsope
HJIKH.1114p0BaHHe aHTp33an5i 046 He npoxo,aHT.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KPACHTEJM H 1-10JIYIIPO,LIYKTb1
113
3. Bell3Ullupoetvitie atimpa3avz 04B
B ana.norHnHux yCJI0BMIX (Kai( npH HeopomHposaHHom npozkyKTe) Huna,naeT
HHatia.ne B mute CMOTIbI AH6eH3HJIHH11T030J1b, OKHCJIeHHeM KOTOpOTO FeCI, no.ny-
LiatoT N,N'-,n,H6eH3H.1-5,7,5',7'-TeTpa6pomliffaHr0 (3e.neHoro nHeTa) C BbIXO-
ppm 87,6%. 143 3e.neHoro pacTsopa B CC14 KpacHTe.nb KpkICTaJ1J1113yeTC5I FlOCJIe
OCTOpOWHOTO ,no6aaneHH5I 34:mpa B 1311,11e 1-1J1aCTHHOK, KOTOpbIe B aTmoaPepe
a3oTa cneKaloTcH HH 157-160? H 1-1,11aBHTC5I npH 163-164?. PacTsopmeTcH
? 6eH3o.ne H nHpHAHHe (ymepeHHo), Aram B x.nopapopme, AHoiccaHe H CC14.
CocTaH: C30F11802 N213r4.
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143 )3,146eH3Humponaunioro xpacHTe.nH npH ,neAcTHHH a3oTHoil KIICJI0TbI B aeitsi-
HOR yKcycHoil KHCJI0Te no.nyinakoT N-6eH3Ha-5,7-,AH6pomH3aTHH KHpnwmo-Kpac-
HOTO useTa, ?KeaTelonkal npH HarpesaHHH, T. no. 149-150?. CocTaH: (C13H302NBr2).
II. AHTpa3o,nb 041'
AHTpa30J1b 04F?npoH3Ho,nHoe 4,4'-ilmx.nop-5,5'-,nn6pomHHon,Hro?npli OKII-
CJIeHHH o6pa3yeT 28,40% KpacHTeoH. PacTHop 20 aaHTpa3OJIH B 100M2 BOAbI meTH-
JthpyloT, KaK onHcano BbILUe, 150 MA AllmeniacyampaTa H 180 .u.a 42%-Horo pac-
THopa e,nxoro HaTpa npn 60?B Tetienne 1?,5 tlaca H 3aTem 1 qac npH 70?. OTIPIIJIbTp0BaH-
Hp? HaTpHeHylo COJIb pactsopsnoT B 0,5 .4 ropHgefi BO,LIbI, KM151MT KOPOTKOe spew"
C aKTHBHp0BaHHb1M ynnem H 3aTem OKHCJI5110T He60.11bLIIHM H36bITKOM pacTsopa FeC13
B N,N'-,nnmeTHJI-4,4'-,numop-5,5'-,AH6pomHHAHro; BbIXO,LI 3e.neHoro KpacHTenH
5,71 a (95% OT TeopeTvpiecxoro). 143 HHTp06eH3o.na BbI,LIeJ151eTCH neTponaHum 3c1m-
pom BInnite 3eJleHbIX C CHHeBaTbIM OTTeHKOM mHxpocKonmecKnx npH HarpeHa-
HHH B BbICOKOKH115114HX pacTHopHTe.nHx (Hanpnmep, B HHTpo6en30.ne) pacTHopHeTcH
C 3e.neHum oxpanun3aHHem, nepexoitHw.Hm 3aTem B CHH ee npn ,LIsemenuniponamni
11pH 200? cnexaeTcH, npespanisaHcf; B TemHylo maccy; T. mu. 209?. CocTari:
,C1,13r2. XJ101-111aT06yMa)HHOe BOJIOKHO He H3H.nexaeT STOTO xpacHTe.nH
C181-11.0?2N
143 >meaToro Ky6a.
HOJIHOe ,neamcH.nuiposanHe xpacHTeofi npoHcxo,nsT npH npoayBaHHH Ho3,3,yxa
B TetieHne 8 tlaC. B pacTsop 2 a KpacHTe.nH B 150 JIM icHnsimeti .ne,AHHok yKcycHoti
KIICJI0TbI. 06pa3oHatuuHflcH cpopma.nbAermit Bb1,21eJ15110T B mme AHHHTpoctieHHarKapa-
3oHa; xpacHTe.nb, nanytieHHbdi H3 peammoHHoro pacTsopa, He co,nepxK0 OHWOW ?OnclIfOM 1,101111Add0d,L14H
aodurige g?elidondm OH `g HIM 9 ocHoworou `SIAIONIHTEHHOLI `,LHELIA,L0H EUIISd.1
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-014E.1.330H 153cuedclast1o11 wine nmxifoliedOlfX IqWo1 dDied OHIlaYs114 ABIOIEOU 14
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?IJOdAINAdi3 IJOHhHdlaInIIAIH30X001c1E1 tIonHawolfliadu ciderer
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tiogoHaheddide-naHVedHauoiniccdorxenod EH (odomoohdidadoad 10 %1 oadiaini)
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L-1-000Z1-0091700181-1700-?8dCl-V10 90/1-1-/LOOZ eseeiej JOd peAaiddV
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KPACHTEJ1H U 110JIYIIPOAYKTb1
121
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(XVIII).
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araHH-5,7-1Hcy.nbitosncooTbi (XIX), ',meTomell 6o.nbmoe 3HaxieHHe. XVI cyobcDH-
pyeTcH B 2-HHTpoHaciTram,TH-5,7-,micy.abcPosHczoTy (XVII) H 3TM BOCCTaHaBJ111-
BaeTcn ,uo XIX. HO aaHHbIM Beperra, HHTposal-THe XVI B 6e3sQ2Woll cpeue moNceT
npmsecTH K o6pa3osanmo 2,71[1,11-111Tp0HaCkTaJIHH-5-CyJIbCDOKIICJI0Tbl.
DxcneplimeHTanbHaH qacTb
Hcxo J H e ma Tep Han bI. flpHmenHemb1 rexcax.HopuT4x.HonewraimeH
HmeeT tmcTury 94+2%. HaciTraorm?qemplqaTbiii, IIOBTOpHO cy6HHmilposaHHb1i.
OcTaJIbHbIe p e a KTHBbI-06bIgHbIe, n p Qua}K H .
Ho y qeHHe II. Memoa A. Cmecb 128 e (1,0 mo.rm) Hairraarma H 595 e
(2 MOJIA) 92% -HOF() rexcax.nopuHK.noneHTaimeHa HarpesatOT B Kpyr.nouoHHoci
Ko.n6e 120 qac. um,' 155-160?. IlpH HarpesaHHH coepH{Fimoe so.n6bi o6pa3yeT
11p03patinbal pacTi3op, xoTopbdi TemHeeT no mepe npoxox{,ueHHH peamum. HO
OK01111aHHH Harpesamia peaxuHoHHylo cmecb ox.ria}sAmOT J11),11,0M, nocze ger? 113
pacTsopa nocTeneHHo BbI,T1eJIHeTCH 6o.nbmoe KOJIIITIeCTBO HplicTa.TuumecHoro se-
mecum. KpHCTaJIJ1b1 OT,11eJ15110T oTcacbisannem H 11P0MbIBalOT Ha cluuTbTpe He60J1b-
LIIHMH nopusHmil xo.Tio,Tmoro aueToHa. HanytieHHbnl 6ecuseTHbdi xpucTa.1.11HT-Te-
cHlul II naaswrcH IIDH 211,5-213,5?. Bbixo,u 166 e (29,6%). HowropHaH Hpn-
cTaximaunsi 113 renTaHa nosbnuaeT TemnepaTypy nnas.neHHH )10 214-215?.
Memca E. Cmecb 296 e (1 moob) 92%-Horo rexcax.nopumi.HonewrauHeHa
H 512e (4 M0JI51) Hacirrarama HarpesmoT B CTeKJIYIHHOil HaTT6e 200 qac. npH 150-160?.
HPH Harpesamm COAel:O4kanisx
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,40JDKHN o6aa,itaTb TeKCT11JIblibIMI4 CBOIICTBaMH H CII0C06HOCTb10 .nerxo
oicpaumBaTbcg; 'Tome Toro, ynpoutaeTcH npouecc 4:10pM0BaHHH BOJIOKOH. B Katie-
CTBe BTOpOTO KOMII0HeHTa npH conwiHmepmainni MO)KHO HCII0J1b30BaTb BHHHJIaI2e-
TaT, 34)HpHbie rpynnbi KoToporo B conoaHmepe nyTem a.nitorainma MO)KHO npespa-
THTb B rwocimabHbie rpynnbi OH. BOJIBIII0r1 HHTepeC npeAcTailimeT conozHmepH-
3a111451 C sHHHaxaopaneTaTom, TK KK mmeukatouniti aTom xaopa B cono.immepe
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cTsa no.rmmepa K KHCJIOTHbIM xpacHTe.imm [1]. AHaJIOTIPIHb1Mil CB0fICTBaM11 ripH
iwanieHHH o6..r1aaeT conarnimep aKpliJIOHHTpHJIa H BHHHJIII1WHAHHa. AmepHicaH-
cxoe BOJIOKHO oaxpkinaHD npe,acTaalmeT co6oil momcimicaLuno nomfaxpwribrioro
BOJIOKHa, OHO co,aepx(HT He6o.ribunie KOJIHtleCTBa BHHH.naueTaTa H BHHHJIIIHpHAIIHa.
Kpome Toro, 600b1110e 3Hatieline B xatiecTse BTOpOTO komnoHeHTa npHoopea aKplIJI-
num. BOJIOKHO 113 corioaHmepa aicpHooHHTpH.ria H axpkinamKria 6anee TH4pOCPHJIbH0,
tiem BOJIOKHO 113 11HCTOTO no.rulaxpwrioHHTpHoa, Aerie oxpaumsaeTcH H o6..na,aaeT
CTORKOCTIDIO K HcmpaHmo 121.
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11,1413 conaiiHmepmau,HH. flpH HCCJle,LI0BaHHH BJIHHH1151 3amecTHTe.rieil Ha misamyto
yrzepo,a?yraepo,AHylo CBSI3b cieye tIHTbIBHTb cTpykTypubie 3ak0H0mepHocTH, Ha
OCHOBaHHH KOTOpbIX MO)KHO cAe.maTb 3aiunotieHHe o CHOCO6HOCTH OT,geJIbHbIX KOMI-10-
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He rip0BOAHJI0Cb.
B HacToRateti pa6oTe asTophi II011bITaJIHCb BbIFICHHTb, Kart BJIHFHOT He600muHe
Ao6asicH sToporo KOMI10HeHTa npm conomimepH3annH c aKpHJ101-114TpILTIOM Ha csoci-
cTsa BOJIOKOH. B KatiecTse riToporo KOMII0HeHTa HCIIOJIb30BaHbI ai(pH.namH,ri H axpli-
J10Ba5I KHCJI0Ta, HtieAeHHe KOTOpbIX AOJDKHO npHsecTH K o6pa3obaHmo no60inibix
ci3H3eil meKay IIOJIHMepHbIMH uensimH, a Tax)Ke BHHH.riaueTaT, meTaiTH.noHHTpki.ii
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cyTcTsHem MeTHJIbHbIX TpyIIII.
PeakuHoHHaH CHOCO6HOCTb K0MII0HeHT0B
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uni. KpkiTepHem ripoTekaHHH peammH conai1imepH3aHHH JI51 Ka}KAOCI KOM6HHa-
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Tbl CKOpOCTI4 peamum. KOHCTaHTbI e H Q He 3aBlICHT OT ubi6opa KOM61fHaII,HH. Flep-
Ban KOHCTaHTa csfmaHa C BJIIIHHHeM 3aMeCTHTeJIH Ha 06111,Hci 3apsuk yr.nepo,it?yroe-
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
128 cm3tlx0-xiimpui BbICOKOHOJIHMEpOB 14 HCKYCCIBEHHOE BOAOKHO
po,anon 4BOAH0171 CBSI 3 14, 3HalleHHe B.Topoil KoHcTaHTb1 oripeae.iineTcn B.11 1451H1404
CTB614J1113aHH14 pa,34414a.no3 (Bc.neAcTBHe pe3oHaHca) Ha 14x peamumonHyro cnoco6HocTb.
B Ta6.n. 1 npe,acTaszeHbi 3HatIeHHFI TIOCTOSIHHbIX AAR KOMII0HeHTOB, HCII0J1b30Balf-
Hb1X npn conwnimepnaalum. Paannxwe meac,ay HeKOTOpb1M14 KOMII0HeHTaMli yrca3a-
no na pm. 31 H 32.
Ta6.4u4a 1
BT0p00 KOMIKIHeHT
rl
r2
(aKpHJIOHHT-
pHJI)
111'2
JIHTepa-
Typa
Biimi.naueTaT
0,061?0,013
4,05?0,3
0,25
--0,5
0,01
151 Ii 161
PiBpHaamput
1,3:1-0,2
0,88?0,08
1,14
H-1,073
0,605
[3]
MeTH.TimeTaxpwriaT
1,35E0,1
0,18?0,10
0,24
H-0,4
0,74
171 H [8]
MeTaK p14.101111TpliJI
2,776
0,346
0,96
+1,0
1,0
/91a)
AK pl4J10Ba A .KIICJI0Ta
4,009
0,327
1,3
+1,012
1,564
[1016)
AK pkI.TIOHFITpliJI
--
--
--
H-1,2
0,44
[Ili
a) BeJIH4HH131 r1 H r2 paccqraaribi Ha ocHoHaHHH 3HaveHHA KOHCTHHT e H Q.
6) 143 coovioweimq co clliponom pacc,nrraHm aHaveami eHQH oTcm,aa C1 H r2.
Ha pHc. 31 npHse24eHa 3aBHCHMOCTb mexuky KOJIHtleCTBOM (MOJI.%) monomepa
B peamwoHnon cmecH 14 onpe,aeaeinibim anammitiecKnm nyTem KOJIHtleCTBOM
(moo. %) 3Toro moHomepa B conozumepe Ha nepBoil cTaAHH n0.nHmepH3aw4H. Ecols
AvunomumpuR 8 cmecu motiome-
fxmr, man.%
P 14 C. 31. KpHBbie concummermsautuf
axpicnolorrpwria c Apyrinvui moHome-
p
1?Binut.naLleTaT; 2? aHpHaamHA; 3?meTHH-
meral(pHaaT; 4--arcipHaoHaH KHCAOT2; 5 ?
meTaKpHoolimTpna.
0
-e
P II C. 32. )1Barpamma Q?e moHome-
poB, HCF10.T1b3013aHHbl X 1J.T131 C0110J111-
mep143aurni c a KIMI.110H fiTp HJIOM.
a?HHHHHatkeTaT; 41--aHpHaoHlrrpHa; L\?
axpmnamHA; 411.--axplaHoHasi KHCOOTH; X
meTaxpliaoHmTpmn; 0--meTnameramplulaT.
paa.nntnibie manapnbie xolatenTpaunn moilomepos B peanwoHHoil cmecH [M11
H [M2] H B cononnmepe d[A41] dEM21 TIOACTBBIlTb B ypaBHeHHe Anciven 14 Fo.nb-
41:44Hrepo
d [Md [A41] r1iA411-kiM2i
d[M2]? [A42] + ra [M2]
(1)
TO rpacimilecm4m nyTem MON{HO onpeoleJnim analienne napameTpoB r1 H r2 [31. lip14
3HatieHHH r1 HMT mecTo 96paTHoe naneHHe.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
(1)14311K0-X14MHB BbICOKOTIOJIHMEPOB H HCKYCCTBEHHOE BOJIOKHO 129
Ha OCHOBaHHH Kp1,113bIX conoakmepn3auffli (pie. 31), a TaK>Ke no 31-Lakennkm
r1 H r2 (Ta6.71. 1) MWEHO 3aKJII0T-IHTb, TO conagnmepmaukk aKpIVIOHHTpHJIa C BHHHJ1-
aueTaTom pe3KO OTJIHIlaeTCH OT con0Jinmepn3au4k C Apyrkmn K0MII0HeHTaMH.
AKpHJIOHHTNIJI 6o.nee CKJI0HeH K pa3,aeabnoil no.rnimepn3aukk, kem K cono.nitmepu-
3aum4 C BinnmaueTaTom, B TO >Ice Bpemk mmk.riaueTaT aerie o6pa3yeT conoanmep
C aKpH,TIOHHTpH.TIOM, kem no.nkskumnaueTaT. OTcloAa BuTexaeT coe,aytoutak cxema
o6pa3oBankk conoakmepa:
? ? ? (M1)n M2 (M1)n M2 (M1)? ? ? ? ,
(2)
rfig A41---manexy.ria axpmnonuTpitria M2?mo.nexyaa Bmik.naueTaTa. Flpk C011eTa-
HHH C Apyrnmn KOMII0HeHTaMH CKJIOHHOCTb aKpHJIOHHTplIJIa K COTIOJIHMepH3aILHH
6o.nbuie, mem 1{ pa3,71eamok' no.nkmepH3aum4. B 3TOM caykae nplimenuma caeAyio-
utak cxema:
? ? ? 1141(A42)?1144 (A42). A41 ? ? , (3)
rAe./141?manexy.ka axpwrionuTpx.ka, a M2?sTopoil xomnonenT.
Bo Bcex paCCMOTpeHHbIX clicTemax na6,Tno,ztaeTck oiniocTopotnikk Teuaemuts
k cononnmepmaukk. Pery.nkpnocTb npncoepunieinik komnonenToB ripn conainime-
pHaaluill KOJIHIleCTBeHHO onpe,AeakeTck npon3BeAenkem r1r2 [4]. gem 6mke
3T0 npok3Be1tenne K HyJ1 10, TM BbIll1 CKJIOHHOCTb K con0mmepk3aunk. B.karoi(apk
3Tomy BHHHJIaReTaT H MeTHJIOBbICI 34:op meTaxpk.noBoil KHCJI0T131 6yyT zerke BCTy-
TIaTb B peaxukno conoonmepk3aunn, kem aiwn.namm H ampimoBak KHCJI0Ta, AAR
KOTOpbIX npon3BeAeinie r1r2>1. Conakiimephi aKpHJIOHHTpHJIa C BHHHJIaLlIeTaTOM
HJIH C MeTHJIOBbIM 9C1)Hp0M meTaxpk.noBoR xac.nroTbi kmeioT pery.akpnoe cTpoekke.
Yka3aFnible HBJIeHEIR 110,21TBeNK,LIalOTCH npn paccmoTpemin KOHCTaHT e H Q
(pnc. 32). C yBeankennem 3JIH411H meKu 3HalleHHHM11 e (T. e. OTJIPPille B nankplio-
cTk) 060RX KOMII0HeHTOB so3pacTaeT HX B3aTimnoe npliTsukefuie. B caykaeBHHHJIalle-
TaTa H aKpHJIOHHTpHJIa 1,1X cPyincukona.ablibie rpynnunpoTkBocTokT KK ,110H0p 3.11eK-
Tp0HOB H akuenTop. C Apyroci cToporibr, kem &mice 3nakeli11k Q cono.numepk3ponuix-
CH KOMTIOHeHTOB ,Tem 6o.nee paBno3Flatinoi1 cTanoBinck cTa614..mnocTb pa2Wmal1ort H HX
peakukoimak CTIOCO6HOCTb H TM Jierge H parmo- ,
mem-lee npokcxoAkT conookmepinaukk. BbIB0,4b1
OTHOCHTeJI 13H0 concokmeppmaunn, BuTexakkune
113 conocTamennk npon3Beaennil r1r2 H 3Ha-
geHnil e H Q J1H COOTBeTCTB37101RHX komno-
HeHTOB, coBna,r(aloT.
Flo.nykenne cono.nkmepos
LIjij nagykerink conoonmepa c onpe,Tteaen-
Hb1M cooTkomennem 060HX KOMTIOHeHTOB neo6-
xokumo c camoro naka.na nporie,l(eFnik npouecca
A0311p0BaTb nuatly KOMII0HeHTa, o6aailakmue-
TO 60.11 &Ha CKOpOCTIDIO noonmepn3aunn. To.
onpeilezeunk COOTHOLI1eHHH KOMII0HeHTOB B peak-
LIHOHHOil cmeck C IiJIbIO TIOJITIeHHH conookmepa
onpe,zkezeunosi cocTaBa MO)KHO HCII0J1b30BaTb
xpnBbie conookmepk3aukk (pnc. 33). Kpome
Toro, neo6xoximoe COOTHOmeHlle monomepos
B peammoinfoci cmeck mown? paccturraTb,
eCJII1 B yparmenke conankmepk3au11ni AJI(PpeS1
H Fo.nbAnnirepa 110,/ICTaBHTb H3BecTnue 3nakeunk r. B npouecce noakmepk3a-
LIHH 3T0 COOTHOIlleHHe cmemaeTck JIHR1b B cTopony yMeHbIlIeHFIR B cmecii KOJIWIeCT-
ea KOMII0HeHTa, o6.71a,aaloutero 60J1 bIllef1 CKOpOCTb10 npespauleunk. 1103TOMy
npose,gennk conookimepll3auk11 3TOT KOMII0HeHT nykcio Pce Bpemk BBOHTb B TaKOM
icomikecTse, tiToom noxaeinkkBaTb nepBokakanbuoe cooTnomenke KOMTIOReHTOB.
9 XHUHR, Ns 1
AKp11.170HU177pLU7 8 cmecu MOHO-
Mep06, mon. X
P II c. 33. OnpeAezeithe cooniome-
HI4SI motiomepoB B peaKuptomia
cmecn K Hatia.ny peaKulin cono.ni-
mepinatum A.11f1 HOJIygeliklH cono-
JuimepoB oripeAe.neimoro cocTaBa.
I -BIM imaikeTaT?
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
130
011314KO-XHMHR BbICOKOIIOJIHMEPOB H IICKYCCTBEHHOE BOJIOKHO
nponecc conannmepmanim MO)KHO KOHTPOJIHp0B3Tb nyTem ana,n143a npo6, R3HTbIX
BO spew' no.rnimepnaantni. 06inee KOJIHReCTBO KOMII0HeHTa C 60J1bIlleft CKOpOCTb10
cononamepn3aum4 [T. e. cymma nepaonagazhnoro (a1) n AO6aBJIeHHOTO BO spema
nposeaeansi npouecca (a2)[ OTHOCHTCH K KOJIHReCTBy Apyroro Komnonewra, KaK HX
Becoabie aoannecTaa B roToaom no.nlimepe (A : B):
a1+ a2 A
b B ?
(4)
B Ta6.n. 1 ripmse,aenbi napameTpu peaxwm conannmepnaanfix axpn.nonnTpmna
pa3J1W1H1IMH KOM11011eliTaMH.
Ta64uaa 2
COCTAB COPOJIHNIEPH3ATOB
.1?,2
B iropoil somnosesT (2)
nps conossmepasasms
C liKpHAOHHITPHAOM (1)
Hanassimiti
cooras cmecs,
sec %
Ao6as,neSse
BO spems
peas sss
e
"Thelma-
aortae,
Sec. %
igLIII.H!
Ramo,
%
AlipHAOliHT -
PHA, /1"1* %
(I)
(2)
,co-
nosesT
Sec.
%
110110-
mep
sons-
mep.
1
EiMminau,etaT
40
10
(1)
50
90
23,78
94
95
2a
AKpm.nammA
95
5
?
?
90
25,70
bii
94
26
Axpluiaman
90
10
--
--,
90
25,36
92
92
2a
AK pliJIMIHR
90
10
--
--
80
25,04
92
90
36
MermomeTaapa.naT . .
89
3
(2)
8
65
22,79
94
93
36
MeTznmeraxpa.naT . .
.
89
5
(2)
6
60
23,22
94
94
.4a
Meraapaaomfrpan . .
?
90
5
(2)
6
BO
24,88
92
90
46
MeT8KIMAOHMTpHJI . .
.
80
10
(2)
10
60
24,04
83
71
5a
AK pt./1088S ICYICROT8 .
.
81
5
(2)
14
48
23,92
86
94
56
Alcpwaoaaa MICROTM ?
.
87
4
(2)
9
65
23,07
91
? 92 ?
B Ta6.n. 2 yaaaanbi aoangecTaa Komnonewron (sec. %), HCROJIb30BaHLIbIe NIA
cono.nnmeploamin. B CHCTeMy aKpHJIOHHTpHJI?axpuaamu ,ao naqa?ila nonnmepn-
3aLT,H14 BBOAHJIH see neo6xo,nnmoe KOJIHIleCTBO KOMII0HeHTOB, TK KK apnBan 110J1H-
mematum AAR yrori CHCTeMbI JIHUTh neanatmenbno OTKJI01151eTCH OT AHaT0HaJIH,
oTsetlaioukeri COCTORHI410 H,1eajIbH01 conannmepmannw. B ,apyrllx czyilasix KOMII0-
HeHT, o6ana2axannil 6o.nbuieti CKOpOCTb10 pealcum4, ,R,06aBJIHJIH gepe3 onpen,e-nefixbie
npommymn spemena B peaKusHommdi cocy,a, rAe 11p0133BOAHJI0Cb nepemeanmanne.
noznimepinaumo nposoman HJIH B BO1H0f1 cpue, HJIH B pacTsope meTanon?so,ga
(npll cono.nnmermaumn C MeTaKpHJI0HHTpHJI0M) B BOCCTaHOBHTeJIMIO-OKHCJIHTejIb-
HbIX cHcTemax, COCTORLItHX H3 nepcy.nbcDaTa KaJIHR, meTa60cy.n40Ta KaJIHH H m(e-
Jfe30aMMOHHAFIbIX xBacnos, npx pH 2 H nocTenemio nosbnnaloatericH TemnepaType.
noc.ne AOCTIUKeHHR MaKCHMajIbHOR TemnepaTypu IIOJIHMepH3aIIHR pacTsop sbi,nep-
mcnsan14 npx 3TOR TeMllepaType OKOJIO qaca, a 3aTem 4IHJIbTp0BaJIH, oca,nOK npombi-
BaJIH, CyLIIHJIH H
Coomomemie KomnomenTos B cOno.nnMepax onpeAe.nsum no compicannio aaoTa
(meTQA Kbenb,aann) (Ta6a. 2). ConocTanzenne COOTHOLUeHHH MOHOMepOB B peamixon-
}foil cmecx H B COHOJIHMepe 1103BOJIHJI0 yCTaHOBHTb, RTO K0MR0HeHTbI C 6O.T1b11111M
3nagemiem r 06b1x1110 HeCKOJIbKO.nytnne cono.nllmepnyroTcn. TIHLUb AJIH aKpliZOBOCI
KHCJIOTIA na6.nloaaeTc14 o6paTnoe RBJleHHe. B 3TOM c-nyqae HeJIb3R ROJIytIlfrb COHO-
aHmep pery.nsipnoro crpoem4H, Tax xax_rir2-= 1,3. OTKJI0HeHHe B MOJIHpHOM COOT-
HOIlleHHH Apyrxx KOMII0HeHT0B B cononnmepax 06151CHSIeTCH TJIaBHbIM o6pnom Tem,
mT0 npn pactieTe KOJIHReCTBa MOHOMepOB HCX01iHJIH 143 yCJI0B1451 POJIHOTO npoleKa-
HHfi T. e. 100%-i-tor? nbixo,aa. DAR conommepos, no.nytmemblx C BbIXO,ROM
3HaTIHTeJIbH0 mime 100%, 9TH OTKJIOHBHHCI MOUT 6b1Tb cymecTneiniumn. Kpome
cacTembi aapn.rionnTpna?meTaKranonnTpna BO Bcex c-nyqasix momipxbie COOTHO-
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
(1)14311KO.X11M11.51 BbICOKOTIOJIHMEPOB H HCKYCCTBEHHOE BOJIOKHO 131
tueHHH B conoimmepax HaX01151TCH B npe,ge.flax 92-95% aKpILTIOHliTp11.11a H 8-5%
Apyroro moHomepa. B cncTeme, coollep)Kaineci meTaxpH.noinfrpHo, 66.nbulaH tiacTb
moHomepos yqacTsyeT B peaxaHH conoaHmepHaasHH, TK KaK CpaBHHTEJIbH0 C Apy-
nimll KomnoHeHTamH OH ()gel-lb 6J1H3OK HO crpoeHmoK axpH.nomapH.ny, ?TAW-la/Mb
JIHIllb Tem, liTo cx-so,Ropo,a aameingH Ha MeTHJIbHy10 rpynny.
flo.nygeHHe ripsi AHJIbH0r0 pacTsopa
rIpH nonytieHHH BOJIOKOH 113 COHOJIHMepOB IICTIOJIb3y1OT pacTsopu COHOJIHMepOB
B AHmerimpopmamHole. ,11.nn 110JITIeHH51 COTIOCTaBHMbIX pe3y.TibTaTOB yCJI0BH9
comannmepHaannH no,a6Hpa.nH TaxHm o6pa3om, LITO6b1 3HatIeHH51 OTHOCHTe.11bH0A
B513KOCT11 0,5% -HOTO pacTsopa B AliMeTHA-
ckopmamime (20?, sHcxoaHmeTp OcTsa.nb-
A,a) HaX0AHJIHCb B HHTepsa.ne 2,2-3,1
(ra6.n. 3 H 4). 25000
,a 0 cllx flop eate He H3ytieHla TeK-
CTHJIbHbIe cHolIcTsa BOJIOKOH, nanytieHHblx
133 9THX C0110JIHMep0B. Te >tie yc.nonHH no-
.r1imepH3au,HH npHroAHbi ;yin no.nygeHHH
nonHaHpH.noHHTpHaa, Karopbth npime,geH
07.611H conocTameHHH c conammepamH. C.ne-
,gyeT OTMeTHT13,. pacTsopm, npHroxible
;pH npsuteHHH, moacHo no.nytiaTb B6o.nee-
umpoxom HHTepsa.ne 3H'IHH BH3KOCTH.
Onpeo.neHHe B513KOCT1I pa36as.neimbix pac-
TB0p0B He06xo,mm0 J1HWb ;IASI no,46opa
KoHueHTpauHH npH,TAHJIbH0ro pacTsopa.
B Kagemme KOHTp0J151 11p0B0,11,HJ113 Talc-
?Ke namepeHHH BbICOKOB513KHX pacTsopoB
B 131ICKO3HMeTpe rennaepa npH 80?. 0611a-
prKeHo, pacTsopbt conoaHmepos ottaioT
BOJIOKHa C BbICOKOR TIp011HOCTb10 B 6o.nee
11111p0KOM 13HTepsa.rie B513KOCTII (OT 7000
AO 30 000 catanunya3), 'ie m pacTsopm 1111-
croro no.rmaxpl4J101-111TpilJla, AJICI KOTOpO-
FO mce pe3yAbTaTb1 MO>KHO nozyturrb
.1111111b B HHTepsane 12 000-20000 can-
munya3.
rIpHse,ReHHbie 3HameHHH 13513KOCTH caeayeT paccmaTpHsaTb KaK OTHOCHTEJIbHble.
Pe3yJIbTaTb1 Hccoe,EkosaHHil atte.nbmaHa [12] noxaabisaioT, lam pacTsopu 110J11iaKp11-
a0mfrpitna CHJIbH0 cTpyKTypHposaHm. Cae,aosaTeabHo;no.nygeHHble 3Hatleinis cy-
utecrBeinio 3aBHCHT OT CKOpOCTII HCTelleHH51 pacTsopa.
3aBlICHMOCTb B513KOCTH (catuna nya3) npH pa3J1141111131X KoHueHTpaumnx pacTsopa
OT OTHOCHTeJ1bH01i B513KOCTH 0,5% -HOTO pacTsopa (pHc. 34) noxaabtsaeT, tiTo JJII
cono.uHmepos 3HageHH51 06bVIHO H1DKe, tleM )10H nalmaxpwnoHHTp0.na. C.ne,aosaTe.nb-
HO, KomkeHTpauHn IlpHWIJIbHOTO pacTsopa A.Tis conommepos mo)ReT 6bITb Hume,
gem AJTH tillcToro no.nuaxpwrioHwrpHaa. LEAH no.nytieHHH romoreHHbix ROHUeHTpH-
POBHHbIX TIOJIHaKplIJIOHHTplIJIa (6e3 tiacTntieK rens) Tpe6yeTcH oMeHb
TalaTeobtioe H HHTEHCHBHOE nepemeumsaHne; pacmopeHHe conoaHmepoH rIpOHCXO-
JHT iere H 6b1CTpee.
30000
000
f5000
- f?0000
ink
5000
? ?
2 2,5 3,0
P H c. 34. 3aBHC1IMOCTb BR3ROCTH (can-
munya3) KOHIleHTNip0BaHHbIX pacraopoo
OT OTHOCHTeabH011 13513KOCTH 10 H. pa3-?
6aBJleHHbIX paCTB0p0B (0,5%).
1 ?110.711111KpliJIOHMTp HA (20%); 2 ? nOrinamp If.
.7101111113H/1 (19%); 3?nonmaxp MOH HTp HJI (18 %);
4 ? COROJIHmep BitHif.naueTaTa c 11JIORHTPH-
.nOm (19%); 5 ? no.n maxp Ihnoutrrp 11.11 (17%).
P?cono.niimep meniJimeTaxr IlinaTa (20%);
A?cono.ntimep meiti.nmeTaxpLnaTa (19%);
C?cortemimep axp 14/10BOR KFICJI0Tb1 (19%)
1.?conOnHmep axp ihn am Rica (18%); 0?co-
no.niudep akoinamHAa (17%).
OopmoBaHHe H Bb1T1X{Ka BOJIOKHa
Conwnimepu, yxaaaHHbie B Ta6a. 2, no.uytieHm 133 Ilp51/111J1bHbIX pacTsopos no
moxpomy meToAy 4)opmosaHHH Ha ma.noti ycTaHosxe (1 A pacTsopa); npH 9TOM trpe-
mioneb nomepimsaTb HOCTOHHHbIe yCJI0BHA (popmosaillisi H BbITSITHBaHHH BOROKH9..
9*
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Ta6Auqa 3
13513KOCTb PACTBOPOB COHOJIHMEPOB H TEKCTHJIIDHEJE
CBOrICTBA BOJIOKOH
0
PaCTHOp,
%
BH3KOCTI.,
canmunya3
Pa 31761 HHHH npognocrb
Pa3pbasHoe
yg.nHFretwe,
I denbe
KM
a) ConoAumep atcpuAwiumpuAa u eutamauemama
(momtptioe coomtiotueuue 95:5)
2,45
20
10 700
5,32
47,4
31
2,56
20
9 000
5,44
48,9
31
2,72
19
18 900
5,33
48,0
28
2,80
19
9 000
5,34
48,1
31
2,87
19
15 400
_ 5,32
47,4
33
3,13
19
21 800
5,45
49,1
30
6) ,lloAuaK WIOHUMptill
2,18
19
21 000
4,33
39,0
22
4,29
13,6
21 000
4,60
41,5
21
Ta6imua 4
H0JIY4EHHE BOJIOKOH 113 COTIOJIHMEPOB
=
PacTBop, %
eO.
YcaAxa ripn I 00?, %
TBTp BoJIoxHa, ambe
Pavms-
Hoe
yAAHHe-
Jule, %
' Pa3putmaH
npogHocTE,
2
BTOB03 KOMIIOHBHT
m
4
x
KM
81aefibe
,
. '
X 0
0
Z
B cyxom C 0 CTOMHHH
a) Ha mama annapamype
1
BBIlligaueTaT . . .
95
2,61
19
1330
21,9
3,25
19,3
32,3
3,58
2g
AgpligamBA
94
2,83
17
1430
20,9
1,91
19,6
41,2
4,58
26
PuicimgamBA
92
2,98
18
1140
23,7
3,47
24,2
36,7
4,08
2s
AgpgaamKg
90
3,01
16
1000
30,0
4,10
42,0
39,5
4,39
3a
114emameTagpmaT . .
93
2,69
18
1020
20,0
3,01
23,0
29,5
3,27
3B
/4eTBameTagpgaaT . .
94
2,38
20
1270
21,9
2,81
19,3
28,4.
3,15
4a
MeTagpmammTpm . .
90
2,23
18
1430
20,0
2,00
19,4
33,5
3,72
4B
MeTagpB.nomfrpga . :
71
2,62
18
1430
18,2
1,93
18,4
31,7
3,52
5a
ABRB.goBan glicaoTa .
94
2,24
18
1310
26,3
3,82
37,0
39,8
4,42
5B
AlcimgoBasi ggcgoTa .
92
2,90
18
1230
31,9
5,37
50,0
35,0
3,89
HOJIllaKpihr101ikapliJI . .
100
2,70
16
1200
20,0
3,01
26,0
38,3
4,26
6) Ha 6olthluoit annapamype
a
BmigalleTaT . . . .
95
2,70
19
1100
22,0
2,43
31,1
47,3
5,27
6
AleTBAmeTagpmaT .
94
2,40
N20
1000
22,0
2,33
30,0
42,6
4,71
B
AK plUlaMHA
92
2,80
18
1000
25,0
2,09
33,0
44,8
4,98
n0J114aKpHJI0HHTpHJI . .
100
2,60
19
1200
20,0
2,16
25,0
47,1
5,23
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
(614314K0-XHM1451 BbICOKOHOJIHMEPOB H HCKYCCTBEH HOE BOJIOKHO
133
cpasHeHHH Ha Tofl )Ke ycTaHoHxe H HO 3TOMy )14e meToAy no.nytia.nH BOJIOKHO 113
tHICTOr0 nozHaHpHaoHHTpwria. 1-1To6b1 H36e?4{aTb caymaimbie OTK.110HeH1151 B npouecce
H 1100311114Tb anee oAHopo,a,Hble BOJIOKHa A.1141 Tpex cono.nHmepon, riposomtan ()op-
mosamie Ha 10-.1mTponoti ycTanonHe. CpeAfiliti COCTaB conomimepont 95 mon.%
axpH.HoHuTpuna H 5 moa.% 13HHHaaueTaTa, 94 mo.a.% aHpH.nolurrpH.na H 6 man.%
meTHameTaKpH.naTa, 92 mo.n.% axpHooHHTpx.na H 8 mo.n.% aKpmnamima.
Pa3.HHHHe meKay Ma.110r1 H 60J1b1110i4 annapaTypoil Ansi izpopmonaHHH no.noxoll
COCTOHT r.TianHbim o6pa3om B TOM, TO Ha 60J1bLUOrl ycTaHonHe me)HayocaAHTeabHoll
BaHHOil H BaHHOil, B KOTOp011 nponoiniTcH BbIT11314Ka, ycTaHanaHrialoT saxHy AAA
11p0MbIBK14 BOJIOKHa.
Ilp0MbITOe BalIOKHO C o6eHx ycTaHonoH HamaTbmaaH Ha =yak' (13 BbITS1HyTOM
COCTOSIH11 11), CCTIHBaJIH, 11p0B011JIH ycaing npH 1000 B MOTKaX, 3aTem cyunum
H 011pe,I1e.TIHJIH.TeKCTI4J1bHbIe cnotAcTrsa BOJIOKHa.
TeKCTIIJIbHbIe CB0fiCTBa
a) CBOUCM8a 80.40KOH, nadytteaRbtx Ha 6oAbutoa u maAoli ycmaHoeHax. flpn
COHOCTaB.TIeHHH npHne,aeHnbix B Ta6.H. 4, npe)H,Ete Bcero Heo6xo,rwmo oTme-
THTb cyfftecTrieHHoe painHHHe me>Hay o6pa3uamH, 110J1pleHHb1MH Ha 6o.nbLuofi
ma.noti ycTaHonHax. BaarogapH HaJIHt1H10 Ha 6comnoil ycTaHonHe npombn3Hoi1 Barr-
HbI nepea BbIT5D14K04,1 11p0HCX0Z1HT 6o.nee no.HHoe yaa.neHme paCTBONITeJ151 H3 BOJIOK-
Ha, H nc.HeAcTnne aToro BbrrHrimaHHe BOJIOKHa npm3oHHT K 60JIMIIHM H3MeHeHH51M
B cTpyKType, XOT51 B oftem cTeneHb BbiTHrHnaHHH Hime. YHa3aHHbie B Ta6.n. 4
3HaHeHHH cTeneHH BbITYIII4BaHHY1 FIBJIYHOTC54 BepXHel rpanHneil BbITMKKII. COOTBeT-
CTBeHHO no3pacTank10 BbIT51}KKH j7neaminnaeTcH pa3pb1nna5 1-1p0IIHOCTb. 0,anaHo
B ,LI,aHHOM cayHae oTmeHaeTcH, xpome Toro, 3Ha4HTeJIbH0e no3pacTaHHe pa3pb13H010
yATIHHeHVISI B0.T10KHa. CJIe,LIOBaTeJIbH0, B yCJI0B1451X 60J1bLUOil 37CTaHOBKH
o6pa3yroTcsi BOJIOKHa, o6.naHa1oi4ne 6.naroAapH 3HatIFITeJ1bHOil OpHeHT811,HH 6o.nee
BbICOKHM pa3p13113HbIM yjoktHenHem, CBOPICTBeHHbIM cono.riHmepnbim BOJIOKHaM.
BOZOKOH, 1-10J1rIeHHbIX. Ha 600b1.11011 ycTaHomie, B Ta6.n. 4 npHne,aeHbi cpe,AHecTaTul
CT1411eCKHe 3HalleHH31.
6) B.I1URHUe maaspHoa aimu emopoeo HomnoHeHma Ha MeKCMU.OHble C130aCM13a
130AOKHa. Bo ncex cayHaHx conoonmepHoe BOJIOKHO CJIe,ayeT no,HyHaTb H3 npo-
AyKTOB, coH,ep>Haunix npeo6aa1alompo HaCTb axpll.nonnTpH.Tia, TaK KaK C yBeJ111-
11e1114eM KOJI1P4eCTBa BTOp0c0 KOM110HeHTa ClIOCO6HOCTb BOJIOKHa K BbITSIIIIBaH1110
H TM cambim 11p0IIHOCTb Ha pa3pb13 ymeHbinaroTcH. 3T0 cHmHeHHe 06151CHKeTCH
F.TIaBHbIM o6pa3om Tem, TITO aKp14.110H14Tp13.11 o6.na,aaeT Han6o.nee 110J1S1pHb1MH 4))7HK-
11,140HaJIbHbIMH rpyrinamH [13]. Bcae,acTnne 3TOFO 1313e,aeHme B HatiecTne BT0p01.0,
KOMII0HeHTa AO 30 MOJI. % meTaxpliJIOHHTpUla 3ameTHo He 143Me1151eT CBOIACTBa BOJIOK-
Ha. Pa3pbinHafi 11p011HOCTb BOJIOKHa H3 TaHoro C0110JIHMepa BbILLIe pa3pbn3Holl
11p011HOCTH conoonmepon C MeHb1.1114M coHep}KaHHem meTnameTaxpHaaTa. BOJIOKHa
113 conoanmep03, coH,epHaw,Hx He6oabnioe KOJIIIT4eCTBO axpnaamn,aa H aKIMIJIOBOA
1411CJI0TbI, OTAHLIa1OTC11 6o.Hee 3HaT11TeJ1bH01 ycaxmoil H pa3pb1mb1m 37,4oHlleHHem.
0,11,11aK0 ea .7TH MO/KHO 061,51CHHTb TaHne OCO6eHHOCTH .111411113 C TOTIK11 3peHHHcTpyH-
Typbi 3T14X K0MHOHeHT013.
B) CpameHue MUMS 80AOKOH, noizytieHHbix U3 paaiumbtx cononumepoe.
BOJIOKHa, no.nytiennbie H3 conommepon, o6.Haila1oT cae,Hyrounimil xapairrepHbimn
OCO6eHHOCTHMH. BOJIOKHa, compKaakne B Kagecree nToporo KOM110HeHTa aHpmn-
aM14,13, H aKp11a0By10 KHCJI0Ty, OTJ11411a1OTCY1 BbICOK0c1 Ilp011HOCTb10 Ha pa3pbu3 6.naro- '
Aapn nomipHomy xapaKTepy HX CPyHKII,H0Ha.T1bHbIX rpynn. Kpome TOTO, BOJIOKHa,
co,rtepwaLue aKpHJI0B3TIO KHCJ10Ty, H, B menbnieft crenenn, BOJIOKHa 143 axpH.namma
HmeroT 6(5.abLuyio ycaHxy ripH Kli 1151,1eHH14 B Boae, a TaloKe COOTBeTCTBeHHO 6o.nee
BbICOKHe pa3pbn3Hbie y,14,J11411eHlIFI. 11pH HarpenaHHH B no,ae BOJIOKOH, C0,11,e11/KaLII,HX
axpwrionylo KHCJI0Ty, O emneparypbi 100-200? (a anToH.Hane) HaabHeffinaH
ycaxca He Ha6.rnoAaeTcH. B TO lKe spemH no.noicHa, coHepHcanwe B Kagecraewroporo -
KomnolienTa aHpHaamHA, npH HarpenaHHH nbune 170? no,anepraloTcH Amu16111mA
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
134
,3)143 HKO-X11M11 BbICOKOHOJIHMEPOB H HCKYCCTBEHHOE BOJIOKHO
yealtHe: Mime OTHOCHTe.KbH0 6o.nbuipo npolmocTb Ha paapbta HMelOT B0.110KHa,
BTOpbP4 KOMHOHeHTOM KOTOpbIX HBAHeTCH mfmcnaueTaT. 3TOT KOM11011eHT B OTAHLMe
oT Apyrlix.o6na4aeT CHOCO6HOCTb/0 acTynaTb B peamuno cono.numepHaainui c aHpH-
.110HEITpH.TIOM (Ta6.11. 1). He6o.nbutaff Bempunia KOHCTKHT131 r yHaabmaeT Ha perynHp-
Hoe pacnpeile.neHHe BHHFutaueTaTa B mo.neay.ne cono.namepa (cxema 5). AIM Apyrxx
KOMII0HeHT0B, y ?KOTOpbIX r> 1, cae,ityeT 11p14H14Tb cxemy 6.
? ? ? (M1)n M2 (411)n M2 (M1). ? ? ? ,
? ? ? (Mi)n (A/11)n (1142)m (MOn ? ? ?
(m < n, En:Etn. 90: 10)
Cxema (6) COOTBeTCTByeT cTpoefnuo nanHmepos, Ha3bmaemmx ceftqac m6.nom-
no.nHmepam1L? [14]. gem 6o.nbine m, TM Tpymee o6pa3poTcH HpHcTa.n.nHqecHHe
12
. 10
E 8
(4) 5
(5)
(6)
0 2 4 6 8 10 12 14 16 18 20 22 2426 28 303234
eaficiee,
P 14 C. 35. ariacnigecitae cBoricTBa BOJIOKOH, no.nytieH-
tibix 143 conommepos (Ta6.11. 4). 3JIHCTH4eCK8H MaCTb
406mero y,l.ntutermsr.
? -?410J1 HEMP ihTIOH 14TP KJI; -conomimep MeTalip14/10H11TP11.718. (4a);
?-cono.numep HHHHaaHeTa?ra (1); A -cononumep meninmerax-
p ma aTa (3a); 41)--conoaHmep ElKp IL/10B0 6 101CJIOTM (56); X -cono-
atimep aHpHaamHaa (26).
yqacnui aHyrpH aKp14.110HHTpHabH01"4 utIaCTHo conoaHmepa BCJIKACTBHe HaeaeHHH
Broporo KomnoHenTa, ofinajkatoulero meHee nonsipHbimH 4yHKLIHOHKJIbHb1MH rpyn-
namH, a TaloKe B pe3y.nbTaTe npocTpaHuBemmix BaTpy?T.tHeHml. 3T0 BJIHHHHe OCO-
6eHHO aameTHo AAR aHpH.norsoft KHCJI0TbI, HoTopaH HMT 3HatieHHe r=4,009
(Ta6.n. 1). An H x.n .na
Ansi cono.nmepa ampoHwrpH c
48 aKpHJIaMHAOM (3HaxieHHe r npH6rnimeTcH K
47 mule) Taawe MO)KHO AOrlyCTHTb Hepery.nHpHoe,
48 czyqatiHoe qepe,noBaHHe paIIIHHHbIX o6.nacTefi.
45 - - 3HaturreabHaH ycamca H yx1HHemle BOJIOKOH 143
3THX C011011FlmepOB, BepOSITHO, 061FICHReTcH
44
.6ss5......,?''..s?---. -_____-- Hmeinio 3THM.
* 43 BCJleAcTskie npocTpaHCIBBHHbIX 3aTpy1uxe-
1 42 Hat 14 sapaHHpylomero acixpemTa, B1313BKHHOT0
?C 0, f HKJIHTIHeM MeTHJ1bHbIX rpynn, B0.110KHK, coAep-
t 0. i . I . I .1 Hcanufe meTH.nmeTaHpH.naT, xpHe BbITFITHBKIOTCH
10 20 30, 40 H, c.ne,roBaTe.nbno, HMelOT meHmuyio pa3p1mHylo
Haepy3ga , KeAem- 11p011HOCTb.?B TO )14e apemq BOJ1OKHK, COmpiia-
P He. 36. CHIDKCHHe cTeneHm 3J1a- Luxe ?qamie 60.11b11.1 He KOJIWIECTBK _MeTaKpH.110H14T-
eTHMIOCTH corionumeptuax BOJIOKOH pH.na 6.naroAapH otieHb nomipsibim rpynnam CN
npm HO3p8CT3HHH Harpy3K4. xopoino BbITHTHBKIOTCH 14 o6naztaxyr 6o.nbtuoti
t --conoa ;amp meTaxp MIMI HTP HIM (4 4); IIP0q1-10CTb10.
2- non it aicp 1010 H HTpHa; 3 - conoaHMep
putt toutikersTa (1); 4-eononamep me- Pe3y.lIbTaTb1 HCCJIe1.10BKH1411 3JIKCTHIleCKH X
rsobleTaxp kloaTa (3a): 5 - conoakimep
liKP 11.40806 K FICA? Tbf (SB); 6 - CO110.11 Hmep CBOACTB BOZOKOH 143 cono.nHmepos, oco6eHHO
?aKp mamma (26). B 06.11aCTH He60.11b11114X HarpyaoH, eme He
, HO3BOJI14IOT cae.naTb onpe,ge.neHHbIX BbIB0,110B
o Bo3eAelo114 OTAe.11bHbIX BOJIOKOH (plc. 35 11 36). flpH Harpyam, pas-
Hok 30 ic,e/mAt2, cononmepbt MO>KHO paCHOJION414Tb no y6bmaamo cTeneHH aTiaCTIN-
HOCIII B c..neitylouLem nopHaice: conommep, compmautHil meTaHpLaoHHTpHri, nom-,
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
43 143 14K0-X14MYIR BbIC0K0110,11 HMEPOB 14 14CKYCCTBEHHOE BOJIOKHO
135
aKpI4J10HHTpHJI, C0110JIHMep aKpii.110HHTpHJIa C HHHH.naueTaTom, meTH.nmeTaHpHaa-
TOM, axpll.nosoil KlICJIOTOCI H axpH.namH,Rom. 110BH,11,14M0My, MOHCHO CHRTaTb, HTO
cono.nHmepu, Hmeimume cTpoeHHe u6.1oHno.uHrdepos?, o6aa1LaioT He TOJIbK0 onee
Bb1COKHM y,a.nnHeHHervi, HO H meHbuleil 9llaCTINHOCTb10. MeTaxpimoHHTmn?Homno-
HeHT, HaH6o.nee 6J1H3Kif1l no upyHType K aHpHoomiTpHay,?menee Bcero CHH}KaeT
cTe11eHb3J1aCTHIIHOCTI4 BOJIOKOH. BHHnnaueTaT?KOM110HeHT C HaH6anbuleil TeHARH-
K co11ar1imepH3au,km ?14 meTH.nmeraxpmnaT 6.naro,uapH alipaHHporiamno no.nHp-
HIAX rpynn ifeCKOJIbK0 CH14)KaIOT cTeneHb 3J1aCTINHOCTH BOJIOKOH.
,LI,J1ii 60JIee no.nHoti xapaxTepHcTHHH BJIHHHHSI HToporo KOMII0HeHTa 6y,1J,yT npo-
HeAeHbi HcaueppaaHHH o6pa3uoa, 51BJ151 1011114XCH npefigabHbus4 czygaem ?11J10X0fi?
cono.nHmepH3au,HH, T. e. 6.110K- H rpaPTcono,nHmepos, a TaH)Ke cmeceff no.numepos
(no.nHmepH3a1,H1 HomnoHeHToH, He cnoco6Hbix K coamecTHoii no.undepH3anHH). I43
3THX npoHywros 6y,1LyT no.nytieHbi BOJIOKHa H 143yHeH131 HX cHoticTsa. oco6eHHo BAH-
HHHC He60.11b111HX KOJIIPIeCTB BT0p0F0 KOMII0HeHTa Ha TepM14HeCKy10 yTOMIHBOCTb.
BbiBoAbl
CAezaHa nonbmo yCTaii0BilTb 3aBHCHMOCTb meKay mexaHH3mom cono.numepH-
3aaHH, crpywrypoil 4:IyHKIIHOHaJIbilb1X rpynn H TeKCTHJIbHbIMH CBOACTBaMH B0J10-
KOH 143 COHOJIHMepOB C npeo6.naAaHHem aKpH.110HHTpH.11a. AJI14 CpaBHeH1451 npHaem-
Hbl coomeTcraylom,He cpeHHHe 3HatleHHH AJISI 110J1 HaKpH.TIOHHTpHJIa, no.nyHeHHoro
no TOM )K meTo,ay H Ha TO me ycTaHosHe. NieTaHpwiloHkrrpHa 6.naro,aapH 6o.nb-
utomy cxoAcTay B cTpoeHHH MO)KHO BB0,21,HTb B conoaHmep B 60JIbIlleM KOJIHHeCTBe
Op 30 MOJI.%) 6e3 cymecTaelmbix H3meneHHil TeKCTHJIbHbIX CB0fiCTB aKpHJIOHHTpH-
BHHH.naugTaT, Hmemumil Han6o.nbrnyio TeHolfeHIRHIO K conannmepH3aH1414
C aKpHJIOHHTpHJI0M, o6pa3yeT npH co,RepHaHHH 5 M0J1.% BOJIOKHa C TOR >Ke 11p0H-
HOCTb10, KK H HHCTbIe aKp13.110H14TpH.TIbHb1e BOJIOKHa. 010C06HOCTb 111iyHKII,140HaJ1b-
HbIX rpynn aHpH.narnHAa H axpicaosofi KHCJI0Th1 o6pa3osbmaTb n060inibie CBS1311
06yCJIOBJII4BaeT 0TH0C14TenbH0 BbICOKy10 pa3pbn3Hyto 11p0t1H0CTb BOJIOKOH, comp-
Now,Hx ,ao 10 MOJI.% 3THX KOMII0HeHTOB. Blile,ifeHife 6 Man.% meTH.umeTa-
HpHaaTa 11pin30,rtHT K CH14)KeHil10 11p0HHOCTI4 BOJIOKOH. YCaKa if y,uJI 14 lieHHe BOJIO-
KOH 143 acex cono.nmsiepoa, HCKJHOHaf1MeTaKpHJIOHHTpHJIbHb1H, Hume, HeM BOJIOKOH
143 tu4cToro no.rmaHpHaoHHTpH.na; 0co6eHH0 yHempumaioTcH 3114 3HaeHHH ,E1J1i1 BOJIO-
KOH, BTOpbIM KOM110HeHTOM KOTOpbIX SI BARUCH aHpH.namHA H axplulosaH KHCJI0Ta.
3THX C0110JIHMep0B npon3BeAeHHe r1r2 >1. apyHTypHble OCO6eHHOCTH H C110-
CO6HOCTb K nar1HmepH3anHH MO)KHO xapaKTepH3oBaTb TanHe cTeneHbio 3J1aCTIPI-
HOCTH BOJIOKOH npH abicoHllx Harpy3Hax. Flo 3J1aCTIPIeCKHM csoficTsam 6.noKe scex
K no.anaHpHAbHomy BOJIOKHy HaX0AHTC1 conoaHmep C meTaKpmoHHTpHaom,
60.11gIllee 0TKJI0HeilHe 110Ka3b1BalOT conoaHmepu, BTOpbIM KOMII0HeHT0M HoTopux
SIBJISIeTCH aHpihnamitu 14 aHpH.noaaH K14CJI0Ta.
JIHTEPATVPA
1. Ham G. E., Gann P. W., I n d. E n g. C h e m., 45, N2 10, 2320, 1953.
2. BASF, Ludwigshafen, FP 1040336, 1943.
3. Reichert H., Faserforsch. Textiltechn., 5, N2 5, 204, 1954.
4. Alfrey T., Goldfinger G., J. C hem. Ph y s., 14, 115, 1946,
5. Mayo F. R., Walling C., Lewis F. M., Hulse W. E., J. A m. C h e m. S o c., 70, 1523,
1948.
6. Agron P., Alfrey T., Bohrer J., Haas H., Wecksler H., J. P o 1 y m. S c., 3, 157, 1948.
7. Lewis F. M., Mayo F. R., Hulse W. F., J. A m. C he m. S o c., 67, 1701, 1945.
8. Lewis F. M., Walling C., Cummings W., Briggs E. R., Mayo F. R., J. A m. C h e m.
S o c., 70, 1519, 1948.
9. Lewis F. M., Walling C., Cummings W., Briggs E. R., Wenisch W. J., J. A m. C h e m.
S o c., 70, 1527, 1948.
10. Chapin E. C., Ham G. E., Mills C. L., J. P o 1 y m. S c., 4, 597, 1949.
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
136 41.14314K0-X14MHH BbICOKOHOJIHMEPOB 14 14CKYCCTBEHHOE BOJIOKHO
11. Mayo F. R., Lewis F. M., Hulse W. F., J. Am. C hem. S o c., 67, 1703, 1945.
12. Edelmann K., Faserforsch. Textiltechn., 3, N2 10,412, 1952.
13. Carpenter A. S? J. S o c. Dyers Co 1., 65, Ns 10, 469, 1949.
14. Goodman J., Researc h, 6, N9 11, 428, 1953.
17epeeoa C. 3e4wc.mati.
143ymemie KHHTHKH o5pa3oBatnisi IlkeJ104H0171 LIgJIJ110303b1. Philipp B., F a-
serforsch. Textiltechn., 6, Np. 4, 180-181, 1955.
HecmoTpn Ha 6o.lbmoe K0.111411eCTBO pa6oT, 110CB5111.WHHbIX H3rieHmo cHcTembi
Lten.iiro.no3a?NaOH--H20, ,ao UDC flop cymecTspoT pacxo?KaeHlisi Kax no sormocy
o cTexHomeTpimecKom cocTarse menoimoil uezni0JI03bi, Talc H 0 KI4lieTHKe
OTHOCHTeabH0 COCTOHHHH parmoBecHn peaxwm nonpexcHemy HMelOTCH )1Be Toinui
3peHHH: npe,ano.no)KeHHe, Hbun3Hraemoe TJIaBHbIM o6pa3om Jlimepom, o mmle.rump-
? nosepxHocTHoil peaxwm c o6pa3oBaHHem coeamieHHH 2 ug.n.n.: 1 NaOH H mHe-
HHe Illsaputcompa 0 nepmyTopLaHom npoTexaHHH peanum c o6pa3osaHHem coeaRHe-
Miff 1 num.: 1 NaOH; 0 KHHeTHKe 3TO1 peaximH HMel0TC51 J114111b yxa3aHHH, qTO
peaxinTH ripoxo,aHT ?otieHb 6bicTpo?. B ,aaHHoti pa6oTe AJIH BbHICHeH1451 TFIX Honpo-
COB npoBeaeHbi KI4lieTHtleCKI4e HCCJIe)A0BaH1451 1101V1011.1eHHYI me.notm HeJ1J110J103011
H3 B0,411bIX pacTti0p0i3 (13 HifrepBane KoHuewrpaustm eAxoro HaTpa 2-30%). ?am'
Bcex H3mepeHHti 14C11011b30BaHa 06b111Ha}1 COCHOBaH He.n.rno.ao3a Cyab4MTH0ci BapxH
c 89%-maim co,aep)KaHHem a-HeJ1,1110,1103b1 (6o.nee noapo6Hbie j_taimbie aHaaH3a cm.
Schwabe K., Philipp B.,H o lz f or , sch.,R 1 1QS4\
? accmoTpeHo TaH>Ke H.ITHH-
HHe TemnepaTypha cyan{H (20? B Haxyyme H 105? npH aTmoccpepHom Aas.nerimi) Ha
HHHeTHxy o6pa3osaHHH me.notmoil 1en.1110J103b1. TK KK 3TOT Honpoc HMT
woe ripaxmtiecxoe 3HaneHHe npH nanytieHHH BI4CKO3H0r0 BOJ1OKHa.
MeToaxixa 3KCflHMHTa
Ann onpeae.nemin norameHHH 1.1.1e.110,114 HeJIJ110.11030171 HCII0J1b30BaHa HeCK0.11b-
KO sHaommeHeHHasi meTomixa, ormcaHHan iHapuxoncl)om (Z. E1ektroche-
rn i e, 38, 353, 1932). aTOT meTo,a CE1513aH C onpe,ae.neHHbimil 3KCIlepHMeHTaJIbHb1-
MI4 Tpy,TVIOCTSIMII, 0,LI,HaK0 6.naro,2lapn BO3MWKHOCTII onpeaezeHHH HcTHHHoro
H xa)Kyaterocsi 1101V101.1.1eHH5111.1eJ10,1H H B0,1111 OH HMT npeumymecnia no cpaaHeHmo
c anclatt)epemmaabHum C1100060M THTp0BaHHH HO CDHBery (B e r. chem., 40, 3876,
1907), no xoTopomy onpe,ae.nneTcn .11H111b Ka)KymeecH nor.nouteHHe me.notm.
' H3mepeHlisi nporio,amini c.neaylow,Hm o6pa3om. flpeasapwre.nbHo npocymeimbie
B onpe,Lke.neHHbix yCJI0BHHX 11J1aCTHHKII 11eJ1J110J103bI Hecom OKOJIO 0,5 e H nonepeqHmm
celleHHem 25 Atst nepeHocHaH B 6imcc, coaermanmil 50 MA nw.notm (c ao6asxoti
Tpo.rmTa-2% 6p0mHaa HaTpm1). BIOKCbI nomemaam B TepmocTaT. 1eJ1J110J103y OT-
)1{11MaJ111 B Tegemie 20 cex., 3TM ripo6y nepeHocHall B apneHmeileposcxylo ao.n6y,
cHa6)KeHHylo npmmuuDosaHHoil npo6xoti (eMKOCTb 100 AO, B KOTOpOR HaX0,72(HJI0Cb
onpe,ae.neHHoe K0JIHT-1eCTBO 0,1 HJIH 0,5 H. cepHoil KHCJI0Tb1. Ko.n6y B3BeIIIHBaJIH )20
H none nomemeHlln unKaToci HeJ1./110J103b1 H no pa3HocTH onpe,ae.nwill sec HeJ1.1110-
.1103b1. nocae pa3pbIXJ1eHlISI 11eJ1J110J103b1 CTeKJIHHH01 llaJIMIKOR H Harpesam451 ao
TemnepaTypu xpineHHH pacTriop OTTHTp0BbIBaJII4 1.1.1eJ1011b10 B 11pHCyTCTBHH MeTI4J10-
BOTO Kpacaoro o riepexo,aa oxpacKH B )1(eJITbIci user. CorkeNkaHHe map6oHaToll
11pH 3Tom He ytiHTbmaeTcH, TK KK HX KOJIHtleCTBO HeHemixo npem.max 0111116KH
THTposaHHH). nocze ,ao6aaneHHH pa36ameHHoci yxcycHoil KHCJI0Tb1 4/11.1IbTp0BaJ114
Liepe3 cl)pHTTa G2, ocaaox npombisaJm yxcycHoil KHCJI0T0c1, 3TM rOpHtleti H X0J10,/1,-
? B040c1. Lke.runo.no3y CyLIIHJIH npH 105?B Tegeillie 12 mat. H B3BeLIIIIBal1H. B CPHJIb-
TpaTe (oxano 1 .11) noTemmomeTpwiecmim MeTO,ROM onpe,ae.nsum KointeHTpaamo
Bec cnpeccosaHHoil maccbi, a Tax>ice xo.ininecTBo eaxoro HaTpa H 6po-
MIICTOTO HaTpHH nepecturrbmaAH Ha 1 2 HeJ1J110J103b1. KOJIWIeCTBO B01aI, noraoingH-
Hai 1 2 HeJIJII0J103b1, onpeae.nHAH no pa3HocTH: 2 H2O=Hec cripeccosaHHoil maccm?
(1 a He.n.mano3b1+ a Na0H-l-e NaBr). ECJIH no ocH, opaHHaT HaHecTH coaepicamie
NaOH H NaBr, a no OCH a6cmicc?co,aepicaHHe H20, TO no 3KCIIeplIMeHTaJIbHb1M '
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
014314K0-XHM1451 BbICOKOHOJIHMEPOB H HCKYCCTBEHHOE BOJIOKHO 137
KplIBbIM MO)KHO paCCHHTHTb lICTHHHOe H xamcyweecs noraomeHHe me.notm H B0,11,b1
ue.Tbruano3off. JJ,jii nocTpoeuHs KpHBbIX 11p0BOAHJIH aHami3 6 npo6 npn_pa3J114T-1H0f4
cTeneHH onimma meaotwori 11,eJ1J110J103b1.
Pe3y./IbTaTbI H3MepeHHiA H paceT
ripeKae tiem npHcTyrarrb K 143yHeHHIO KHHeTHKH peanwH, Heo6xo,usmo pac-
cmoTpeTb cocTosHHe pasHosecHs, npwiem rJIHBHbIM 06pa3OM npeAcTas.nsieT HHTepec
HcczeAosaHHe BJIHHHHH KomieHTpau,km atenomil, TemnepaTypbi peaxwill H Temnepa-
Typhi cyunw HeJ1J110J103bI. Ha pm. 37 110Ka3a1-1b1 pasHosecHme 3HalleHH51 HCTHHHOTO
H Ka)Kywerocs nor.nowemis erworo HaTpa H BObIAJ1H pacTsopos c KoHueHTpanHerr
erworo HaTpa OT 2 Ao 30 sec.% ripH TemnepaType 20? H spemeHH norpyweHHs 24 qa-
ca. Bo BCM HHTepsa.ne KoHugHTpanHi3/4 He obbno o6HapysceHo B.TIHHHHH TemnepaTy-
pbt CyIIIKH Ha semmHy pasHo-
BeCHbIX KoHneHTpaiwil. Xapax-
Tep KpHBbIX 6J1H30K K pe3y.nb-
TaTam, nozytieHHum Lllsapus{on-
(tom AJIH B0J1OKHa pamH. B
HH-
epajie KoHueHTpau,Hil ea,Koro
HaTpa HH}Ke 8% Ha6.r1!o,aaeTcs
no.norHil norrbem xpHsoil HCTHH-
HOTO TIOTJIOLL4eHH51 ezworo HaTpa
(CBH3b1Balille we.notm nooxo yno-
p51011eHHbIMPI yqacTKamll 14eJ1J110-
J103bI), 3TM Ocoee KpyTofi ytia-
CTOK (nocTeneHHo npoTeKalow,as
peanws B KpHCTaJIJIHTaX), H,
HaKOHe11,, B HHTepsa.ne 17-25%
ejworo HaTpa npoHcxoAHT o6pa-
3osaHHe onpeikeneHHoro xHmwie-
cicoro C0e)1(41HeHHH ? Na-ue.rullo-
J103bI I, cocTas KOTOpOil (1 NaOH: 1 C6) ocTaeTcs HOCTOHHHbIM B nmpoxom HHTepsa.ne
KoHugHTpaiwil wenolm; BTop ctmTaeT, TITO 3T0 coemmeHHe ripeacTathnseT CO6Off
110HHb1 AHTIOJIb TH,n,paTHposaHHhail 3-4 monexy.namH B0bI . HO KpHsoff KaNgwerocs
noraow,enis NaOH 06JIaCTb of6pa3osalms Na-HeJ1J110J103b1 I COOTBeTCTByeT COOTHO-
Luemno 0,58 MOJI51 NaOH: 1 C6, TITO xopomo comacyeTcs C COCTaBOM, yKa3HHHbIM
(1)Hserom (1 NaOH : 2 LleJI,11.). TaKHm o6pa3om, pe3yabTaTbi, nanytieHHble
HO 06oHm meTo,rwm, He npoTHsopettaT 0,a14H Apyromy, mill yT-IHTb1BaTb, TITO MeTO,J1.
cl3Hsera ikaeT 3HatreHHs Ka}mymerocs nonnoweHms ate.uotm.
flpe,gsapHTenbnle OflbITbI, npose,leHHbie npH 0 14 ?20?, noxa3a.rill, TITO COCTaB
Na-aexmano3bi I He 3aBHCHT OT TemnepaTypbi H COOTBeTCTByeT cooTHomeHmo
1NaOH : I C6, B TO }Ke spew' nor.noweHHe excoro HaTpa Ha aikcop6uHoimom ytia-
CTKe Kpllsoil 3ameTHo so3pacTaeT HH CI114}KeHHH TemnepaTypu; 3TO AerKo 06'1351C-
HHTb, eCJIH ylleCTb 9K3oTepmwiecxH11 acpcpexT peaxwm H rimpoaH3 HoHHoro ,rwrions
Hez.n.-0-HoHNa+.
FlpH nposeikeHHH KHHeT14T-IeCKI4X Hcc.neolosamici H3MeH5JJ1H KoHueHTpaumo
e):woro HaTpa H TemnepaTypy Cy1.11KI4 ljeJ1J110J103bI; Kpome Toro, 143ygeHa Temne-
paTypHas 3aBlICHMOCTb peaxumi npu TenumecKH saNcHoci xontenTpaww tu,e-
JIOHH 17,5%.
FlpHse,LkeHbt pe3yabTaTbi cepHH H3mepeHml (pHc. 38)?nor.noweHHe we-
JIOHH 143 3,8%-Horo pacTsopa e,Lworo HaTpa. ,E(as npoTeKaHHs peanum BO HMI HC-
cae,Rosaimal o6.nacTH KoHaeHTpaiwil xapaxTepHo coelkylomee: BHatia.ne peaxwm
nponcxoAHT 4pe3sbma1lHo 6b.mTpoe nor.noweHHe eiworo HaTpa; cnycTs 1 =lac ilea-
mano3a CB5131A3aeT 90% HJIH 6o.nee OT pasHosecHoro KoamecTsa nor.nomeHHoro
icor? HaTpa. Kpome TOTO, 3ameTHo 3HaxmTenbHoe BJIHHHHe TemnepaTypm CyLUKH Ha
cicopocTb nornom,eHHs ute.rwini; norzoweHHe weaolm H Ha6yxaHHe B swig npoTe-
10 15 20 25 30
NaOH, eec.
P c. 37. PasHosecuble 3Hatteinu1 noraou.keiniR
eAKoro naTpa 1 B0,11b1.
??cyuma npH 105; 0?cymHa Hp"! 200;
j?HcTHHH0e norsou.keHHe eAHoro HaTpa; 2 ?xamcyuAeecsi
nor.notgeHHe excoro HaTpa; 3?noraoLHeHne
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
138
cb113141W-XHMk151 BbICOK01-10JIHMEPOB H HCKYCCTBEHHOE BOJIOKHO
KalOT 3HatIHTeJIBHO meA.neHHee Ansi 06pa3nos, cyluxa HoTopux npollcxo,rana npH
105?, no cparmeHmo C o6pa3namH, BbICyllIeHHb1MH npH 20?.
Flor.nomemie e,axoro HaTpa B 3aBHCHMOCTH OT HpemeHH ARK CyLIIKH npH 20?
MO3KHO BbIpa3PITB ypasHeHHem Ha6yxaHHH HeJ1J110003b1 B 1114CTUX )1(11,aKOCTSIX
at
0,141aK0 011,J151 o6pmos, BblCy1IIeHHbIX npH 105?, BTO ypasHeHHe
HenpHmemmo. 3aBHCHMOCTb CKOpOCTH peamuni OT TemnepaTypu (A.TIA xapaHTepH-
CTHK14 ckopocTH HCII0J1b30BaHO KK Mepa Haqa.nbHocr CKOpOCTH KOJIHIleCTBO exco-
ro HaTpa, nor.noakeHHoro cnycTH 2,5 WILL) o.nee 3amema AJI51 geJIJII0J103b1, Hwy-
ineHHoil rim{ 105?, qem B copme cynnut npH 20?. ,E1erICTBHTeabH0, II0Bb1IlleHHe Tem-
nepatypur pacTsopa excoro Harpa Ha 20 H nepHom c.nyqae npnio/tar K 6onee
a" 0,15
a
-43 NaOH
? 410 6 oi
Z.
5 a
2
4 Pigt
tk'a 3
1:3
/
a
P c. 38.
10 I 30 40 50 60 24
Bpentst
KHHeTHKa TION10111eHHH war() Hana H 130/I61 H3 I H.
pacTaopa eAKoro HaTpa ripH 200.
I -emain HaTp (1050); 2 -extxllti HT p (209; 3-Boa (105?); 4-ao,aa (209.
MUM. vacm
Nem qeTbipexxpaTHomy 320%) Ho3pacTaHmo CKOpOCTH, a AJIS1 o6pa3nos, BblCy-
ILIeHHbIX ripH 20?,-J11111.11, K In3yHpaTHomy (80%). ABTOp npeAno.naraeT, AJIK 06-
pa3uoa, HbicymenHbuc rip H 20?, CKOpOCTb peaHHHH onpeAeaffeTcH He C06CTBeHH0
XII-
MB'ICKHM 3amenteHHem HeJ1J110J103b1 KHM HaTpom, xoTopoe KK HOHHaS1 peaHHHH
npoTeHaeT HCKJ1101IHTeJ1bH0 6bICTp0, a B 60J1b11161 cTeneHH nponeccamH ,a1144y314H
H Ha6yxaHHH. Ha OCHOBaHHH HMeioni,erocsi marepHa.na HeJ1b351 ,aaTb Hamm-tor?
06151CHeHH51 BbICOKOMy TemnepaTypHomy K034101:11311HeHTy peaHuam ;ATM o6pa3uoH,
BbICyLlIeHHbIX npH 105?. Pe3y.nbTanal H3mepeHnil HH4:9axpacHb1x cnexTpos IIOTJ10-
1.1WHHH 1-10Ka3b1BalOT, 11TO neamo.no3a, HbicytuermaH npH 105?, He HMT CB060,1MbIX
TH,VOKCHJIblIbIX rpynn. MON(110 npe,ano.nomourb 6pa3oHaHHe CB0e06pa3H0c1 CeTKH,
B KOTOpOrl rice rpyrnmi OH CB513aHbl BoAop6AHEamH MOCTHKaMH (Chedin J., K o 1-
1 o i d. Z., 125, 65, 1952). flpH cyunce ue.n.i1Io.1o3b1 npu Temneparype- fume 50?
Haxyyme B o6pa3uax coxpaHmoTcH CB060,41111e THapOKCHJIbHble rpynnbi. CO6CT-
BeHHO XHMHIleCK0c1 peaxu,HH AwnicHo npe.quiecTHoHaTb pa3pynieHHe Hortopombix
cHH3e11 mexciAy UeHBMH, npuqem JIB o6pa3tors, BbICyMeHHbIX npH 105?, 3TO npo-
SIBJISIeTCH B 3H8lIHTeJ1bH0 60,313111dt creneHH, qem ,a.na o6pa3i0H, BbICy1I1e1H1b1X npH
20? B Haxyyme. BO3MONCHO, npH HsaHmo/ketIcTHHH ine.notni C HeJ1J110J1030171, ebicy-
ineHHoti npri 20?, C camoro Hagana HmeeTcH ,IAOCTaT0qH0e KOJIWIeCTBO CB060,a1IbIX
r14.1LpOKCHablibIX rpynn, 6.narorkapH qemy CKOpOCTb peammH onpe,ge.nsieTcH npo-
TeHaHHem nponeccos 1UI4x1)3/3HH HJIH Ha6yxaHHH c o6bilmo Heo0J1b11111M Temnepa-
TypHb1M KO34XIM11,HeHT0M.
LIAR 11,e11J110403b1, Hbicyurernmil HH 105?, p0J1b AomHHHpyloinero ctraHTopa
npHo6peTaeT CKOpOCTb peaKII,HH pavymeHHH Boaopombix cHH3en, HoTopaH HmeeT
TemnepaTypubni Kosclxinumear, HpHcyamil xHmHqecKoil peaxaHH. HarepecHo npo-
separb sTy runoTesy Ha Apyrkix aHa.norHtnio npoTeHafoumx peaHnimx 11,e0.1110J103b1
(HanpHmep, HHTpahHH).
KIIHAHHe KoHneaTpaum4 eAxoro HTP a Ha KHHeTHKy 3ameineHHH MO)KHO Timm-
3aTb npn cpasHeHHH Haqa.mHba cxopocTeil peamutH (HCTHHHOe noraoineHHe
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
(131131,1K0-XHM1451 BbICOK0110.1114MEPOB H HCKYCCTBEHHOE BOJIOKHO -
139
KOr0Tpa cnycni 2,5 Mill!. 'mule norpy)Kennn, oTnecemioe K paBHOBeCHOMy 3Ha-
meinno ii abipa}Kennoe B nponewrax) (pile. 39). KaK 11c.nextona.no 0)KHAaTb, Kpnaan,
no.nytiennasi AJIH o6pa3ta, Bbicytuelmoro npii 20?, JIMHT 3HatIHTeabH0 B131111e
A.THI o6pa3u,a, abicymeimoro npn 105?. 06e Kpmmie knnefor rIpkI5J11,131,1TeRbH0
P1,11,eHTHt1Hy10 cl)opmy: B murepnane KonneuTpauldi eAKoro HaTpa 12-20% na6mo-
AaeTcn HJI0CKHi maKci4mym, KoTopbal nanommmer maKcnmym noraoineunK no,abi
A.rni panuonecnoro COCTOSIHHH (pile. 37). C.T1e,110BaTe.1113H0, B 3TOM nwrepna.ne KOHIleH-
Tpau,Hil peaKnKK npoTeKaeT nan6o.nee 6bicTpo, npKnem 11p01,1CX0AHT 3HatlIfre.11bHaSI
rupaTaim. Heo)KKgannum SIBJISIeTCH CHJIbH0e cinoKenne CK0p0CT1,1 peaKunki ,I1.1151
* 80
70
60
50
1/0
30
g 20
a_10
0 5 rb 1 io 25 30
cz) NaOH, eec.
P ii c. 39. HaumbHaH CKOpOCTb HeTHHHOCO 110-
rnolgemisi eAHoro HaTpa B 3KBHCHM0CTI4 OT
ero KOHIleHTNIKHH.
1?cyulKa npH 200 H HaHyyme; 2?cyunca npH 105?.
06pa3I.LOB, Bb1Cy1.11eHHbIX npn 105?, B infrepria.ne KonuenTpaunci moro RaTpa 20-
25%, T. e. B TOM )Ke mrrepna.ne, B KOT0p0M, noAaHHbIM BaperyneKa (P apie r,
7, 153, 1953), namemneTcn KaK BaaHmoAefIcTnne cepoynnepoola c eAKHM HaTpom,
TK H peau nn Kcawrorennponamui UeJIJ110J103b1. nOJIrleHH131c1 anTopamK pe3y.nb-
TT no,n,Tnep>KAaeT oftsicnenne BapTyneKa, KOTOpb111 yKa3binaa, tITO
B pacTnopax, co,aep)Kauwx cnbnue 23% exioro HaTpa, npaicrwiecKK BCH Boika npm-
mimaeT ynacTne B o6pa3onamm rimpambix o6o.notieK BoKpyr Anno.neft efixoro
HaTpa, r103TOMy A.1151 rimpaTanmi CS, HJ1H COJIbBaTaU,HH 1.11,eJ10t1H0r1 1.1e./1.1110J103b1
B0,11,bI HeAOCTaT0t1H0. 17epeeoa C. 3eAwcmati
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
IAEJIJ110J103A 11 BYMAIA
flo peAakumea KaHa. TeXH. Hap< E. F. muAoea
Pa3MelgeHHe geJ1J110.1103b1 H remiiikezatoao3 B KaeT?11H0A cTemie eaH, 6epe3bE
H x.nonKa. Asunmaa S., Lange P. W., Svensk Pap., 57, N214, 501-516, 1954,
6116a. 12 Ha313.
3aAatia ,oanHofi pa6oTbi?susicHemie OTHOCHTeabHOTO pacnpeagaeHmi neaaro-
JI03bI H remmie.runoao3 B nonepetmom CelleHH11 KTIeT0IIH0R CTeHKH apeoecHHEJ eau
(Picea excelsa), 6epe3bi (Betula verrucosa) H xaommoro BoaomHa (Gossypiunt
herbaceum).
noik Tepmimom remmieaJII0J103a aoTopm 110HHMalOT yraeBO,LIHme HeniecTna,
pacTsopsuoaniecH npHIL1eJ1011HOil HJIH KHCJ10THO o6pa6ome BOJIOKOH, H He coraac-
HbI C onpeagaenHem HX KK K0MI1J1eKCH0fi cmecH no.rnicaxapitoos C maao 113BeCTHbI-
MB CB0rICTBaMH. HopmaH [1,2] orpaHip-mHaa 310 onpeiieaeHHe pacTuopHmbimll
meaotiax nomicaxamiamH, riLop0aH3yr0unimHcH B pa36ariaeHHbIX KHCJI0TaX
caxapoo H caxapHbIX KHCJIOT.
FlOCKOJIbKy TOLIHOCTb mmipocnewrporpacimitieclioro meToaa HYDKe o6uienpn-
HHTbIX aHamiTmecmix cnoco6os onpe,aeaeHHEI K0MI10HeHT0B KJIeTOT-IHOCI CTeHKH,
np000xi,n11 npeAeapirreabHoe rpy6oe pa3aeaeHHe Heaaloao3m H remimeamoao3
o6bi4moil IueJIoqHo 06pa60ni0il H KHCJIOTHbIM FII,VOJIH30M. BO3M0)KHOCTb KOJI11,1e-
cTneinforo onpeaeaeHHH yraecoapB pacTHTe.m)HoR KJIeTKII nocpeacTcom ee sTepii-
CDHKaLtHH B XJ10pHCTOM n-f:Dem4aa3o6e1-13oHae yxie 6bma aolia3aHa awropamil
paHee [3]. BbIJ10 noapieHo HenocpexiaeHHoe BOJIOKHO, olipaineEmoe B opaHaieso-
iipacHbal useT. CTe11eHb noraomeHHH crieTa B nonepetnibix cpe3ax oTepalanuiposaH-
Horo BOJIOKHa MO)KHO oripeaeaHTb minipocneliTporpacinitiecEmm meToom; o,oHako
caeayeT p-IHTbIBaTb, T4T0 OAHOBPeMeHHO c norzoweHHem cceTa HccaeayemEim Beige-
cToom Ha6aio,ziaeTcsi ,1(on0JIHI4TeJIbH0e IIa,aenne HHTeHCHBHOCTH CBeTa BCJIe,ncTnne
reTeporeHHoil crpyliTypm 3TeplI4111114p0BaHHOr0 BOJIOKHa. arm yMeHbIlleHHH B.111451-
HHFI 3THX noTepb CBT a Ha n0lia3aTeall 3aTyxaHmi ero npH minipocneliTporpalm-
gecmix Hccae,Rosamisix Heo6xormm0, tiT06m cpe3m BOJIOKHa 6b1.1114 HOJIHOCTb10
cmotietim B mipHaHHe. Honepetmme cpe3m BOOOKHa B CHJIbH0 Ha6yXalOT,
H cae,oyeTlIpHHHMaTb BO 'BHHMaHHe11011paBKH Ha H3meHeHHe pa3mep0H npenapaTa.
OripeaeaeHHH cTenemi noraouiemisi ceeTa nonepex Ha6yxitiefi KlIeTOT-1110c1 CTeHKH
B TO Hie EspemH capkaT n0xa3aTeasimii paciipeaeaeHHH yraeHoom B KJIeTKe. ileTaab-
Hoe onHcamie mmipocnewrporpacInitieckoro meToria H npHmeHHemoro npH 910m o6o-
py,1(0Bamia Ohm? coo6HieHo RaHre B npe,omaymiix ero CTaTbAX [4].
;Iasi ymeHbmeHHH HeTotniocTefi nolia3aTeneil npH no,oroTomie npenapaToo 6maa
11pHHSITa caeayioniafi meTowitia. rionepetmme cpe3m BOJIOKOH, noaytieHHme pytiHmm
minipoTomom Xapan, cHatiaaa pacemaTpHHaaH npH yHealitieHHH (N30)
kocme-
H nospexiaeHHme cpe3m om6pacbmaaH, OCTaabHble BT0pHt1H0 npoHepHaH npH
yoemitieHHH (X650). C ueabro noaplemisi xapaliTepHofi ,21.1151 HCCJIeAyMOTO BOJI0K-
micToro maTepHaaa mpHsoft cpeaHero pacnpeAeaeHHH Henieciza B nonepetmom
cetiemill cpe3a Kpl4BbIX no 110ka3aTea1m 3aTyxaHH5I coeTa B pa3-
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HOM coaepkaHHH Hem,ecTaa, noraomalomero cseT B pa3JIIVIHIAX CJIOHX KJIeT011HOCI
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
HEJI.1110003A H BYMArA 141
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BaHbI npnmemembie B Hams:1=e Hpems1 MeTO,I1bI, a TaloKe Honpocbt y1o6cma HX
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MapTeHcy). B TetieHHe 3T0T0 HpemeHH He o6HappHeHo 4:lawros, KOTOpbIe 1103HO/151011
6bI CIIHTaTb 0111H60t1HbIM peineHHe o 11pHMITHH 6pnTaHcHoro meToAa.
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norHH H yKa3aHbl npellmyinecTsa 6pHTaHcworo meToAa.
MeTo,rk bl HClibITaHll 51 TenaocronKourii
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TamH:
1. Bemiwo6pHTaHHH: cfbacTlltiecicoe oce,aaHHe?, 6pHTaHcKne cTaKaapTbi
(B.S.), 448: 1948; 771 : 1948 H 1322 :1946.
15mm U
-tmm/1-?
2500e
I 0,254 mm 1
12,71k1fif 0 1.5mm 0
127mm 102mm T-1.,MN 1-6- --.-4.--=-1354s7is;---1
. ID
8
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P 14 C. 51. Pa3mepw o5pa3ton, nanpmenne H npeAenbi xani6a npki HC111)1-
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a ?repmatiomfl meToA, malccumaribiwe HanpsoKetme 50 Kelcm2; 6-6p ifTaHCKlitt
MaKciimanbaoe Hanpsixteritie 12 xe/c.os t; 8?meT0,4 CHIA, maxemmaamwe Hanps-
menme 18,6 Ica/cm2; e-4)pari1,y3cmil1 meT0A, maxotmaabnoe HanpsacenHe 16,7 Ka/c/42.
2. repmankin: qTelIJIOCTOCIKOCTb no MarencyD, ?C0103 Hemewx mmeHepos)
(V. D. E.) 0302/111.43; crawlapTut (D. I. N.) 53458 H 53462.
3. ?I/13r116 npn narpesainno, A. S. T. M. R648-41T, 11,648-45T,
4. Opanuisi: dloseAeHHe npn HarpersaHHHD, U. S. E.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
HCKYCCTBEHHHE CMOJIM H TIJIACTMACCM
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cHuiero OT HpemeHH, 110,11,11HHFIeTCH JIHHeCIHOMY 3aKOHy, HO CKOpOCTb nocTeneHHo
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CKOPOCTMO.
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npeKae qem CKOpOCTb ,a8:1)opmau,HH TIOHH3HTCH, H o6inan ,214opmannn 3a AaHHoe
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6bnb pa3.5o)KeH0 Ha Ana OCHOBHbIX KOMII0HeHTa HanpH)HeHH11?pacTH)HeHHe (Hall
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
160 HCKYCCTBEHHb1E CMOJIbI H IIJIACTMACCbI
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naacTHqecK oe oceAaHHe B AHHamxtiecxxx menu-
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
HCKYCCTBEHHblE CMOJIbI FIJIACTMACCbl 161
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(4)
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rlocze noacTaHoexx B riper? qaCTb yparsHeHHH (4) 3Hat4eHH1 e' H3 ypas-
He111451 (2) 14 HHTerpmponaHHH no.nymam
hem (a/3) co (ego' ? 1).
?
(5)
KpHeasi nporH6a Ha pnc. 53 icopocno cor.aacyeTcH c ypasHeHHem (5), ecaH
(c0) c, = 0,0122 H 3 0,0667; npH BbIlIHCJIeHHH 3THX Ko9434muliewros
cpemuolo TemnepaTypy o6pa3u,a. PactleTHbie H siccnepHmewraabHbie
aH-
j4brertOKaaHb1 B Ta6.n. 2.
Ta6Autia 2
CPABHEHHE TEOPETHHECKHX 14 HABJ110,ZIAEMbIX 3HA4EH14H
TIPOrl4BA 11J151 KPHBOVI HA P1-IC. 53
Bpemm OT
nava,na,
HCMATBHHTI,
MRH.
TemnepaTypa
Bonkyxa B
TepmocTaTe.
?C
Cpeilasot
TemnepaTypa
o6pa3u,a,
?C
pporn6, hum
na6.nioAae-
Mblii
Bblq1,1C.rteHHIAll
40
71
56
0,1
0,03
60
88
73
0,2
0,1
80
105
90
0,5
0,4
100
121
106
1,4
1,1
110
129
114
2,2
2,0
120
138
123
3,6
3,5
130
146
131
6,0
6,1
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
HCKYCCTBEHHHE CMOJIbI H njIACTMACCbl 163
Y40BJIeTB0pHTe.11bH0e coanaAetnie Ha6moAaemoil H BbIlinCJIeHHOcI BeJIHIIHH
nporH6a, npuBeitemiaix B Ta6a. 2, noxraepHAaeT npaBHJIbHOCTb aHamma xpHaori
nporE6a. lioAo6Hoe coana;:ketnie noaygeHo H AJIH Apyrtax maTepHama.
BJIHHHHe cxopocTH IIOBNIlleHHH TemnepaTypH ripH AHHaMH-
ilecKom FICnbITaHlIkl
COTAaCHO ypamemno (5), oceAatnie (nporn6) npH AtniamHgecxom HCTIblTaHHH
3aBHCHT OT Tpex napamarpos: co, a H (3. a CJIpICHT mepoti CKOpOCTH naBblaleHHH
TemnepaTypai, nosTomy ee 3Hageme MOWHO H3MeHHTb. flpeAnonoxcHm, tITO
CKOpOCTb TIOBbIllleHHH TemnepaTypu COCTal3JIHeT 300 B tin (BMeCTO 50? a gac
COOTBeTCTBeHHO Hemeuxomy cTatutapTy). KosclximumeHT (a/(3) Co ARA MaTepliaza
(pHc. 53) COCTaBHT 0,0122 x 50/30, HJIH 0,0204. OTCTaBaHHe TemnepaTypEd
o6pania OT TemnepaTyphi ao3oayxa B TepmocTaTe 6y,a,eT CHH>KeHO; ero MO)KHO
IlpHHHTb paBHbIM 9? amecTo 150. FlpH TaKHX yCJI0BHFIX TemnepaTypa, COOTBeT-
CTBytolgasi cTaKaapTHOMy nporH6y to
6 Avit, ripH BblEIHCJIeHHH ee H3 ypaa-
HeHHSI (5) COCTaBHT 132,5? amecTo
146?.
flporH 6 KK CtiyHKII,HH
apemeHH B meToAe 6p H-
TaHcaoro cTaHAapTa
COMaCHO meTuy 6p1.Iiaticxoro
cTawkapTa, nporH6 no.nygaloT npH
onpe,tteneHHoti Harpy3xe H nOCTOSIH-
H0fI TemnepaType. 06pa3eu, Harpe-
BalOT B TegeHHe 6 gac. HopmHposaH-
Hag Beangtnia nporH6a 5 Atm.
Pa3mepu o6pa3na, Harpy3xa,
apemH Harpesamisi H BeJIMIHHa
Cmcwc7opmffold npoeu5
1,
IG/7747Ht3071MH2)0 8peALS7
2
10 15
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P H C. 54. KpmEnle 3aBlICHMOCTH nporH6a OT
HpemeHH no 6p wraHcHomy meTomr.
1?maTepHaa HH3K011 TeILTIOCTOAHOCTH (t=65?, Ea3eH?
HOBblit nnacTxx): 2?maTepnan BbICOKOR TeIIJIOCTOAKO-
CTH (t=150?, cpeHormacT).
rH6a TIgaTeJlbH0 noogo6paub1 TaKHM
o6pa3om, IITO6bI OHM arnue COOTBeTCTBOBaJIH sxcn.nyaTauHommim yCJI0BH5IM.
Ha pHc. 54 noica3atibi xapawrepHaie cpopmbi HpHaux nporH6a, noaymaembix npH
HCTIblTaHHH no 6pHTaHcHomy cratiRapTy. CKOpOCTb HapacTaHHH nporH6a atiaga.ne
BLICOKa, HO 3aTet1 ymeHaumeTcH HJIH ,aa?He CTaHOBHTCH pasHoil Hy.T110. MaTepHaara
C HYBKOri TenTIOCTOIIKOCTb10 noHa3amaioT B o6m,em 6o.nbwee npHpameHne nporH6a
cnycTH 6 qac., gem maTepHaabi C BbICOK011 TeTIJIOCTOCIKOCTb10.
Ta6Aima 3
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Tel1J10-
CTO-
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no Map-
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no mei0AY
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58
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cHHapoinero H ac6ecTa HAM C./H01bl . .
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
- 164
HCKYCCTBEHHNE CMOJIbI H FIJIACTMACCH
B Ta6.n. 3 npHse,EkeHbi cpasHHTe.nbHue JI,amabie TeHJIOCTOCIKOCTII no MapTeHcy
(HemeuxHil sTaHAapT) H no 6pliTaHocomy cTaHaapTy. ;las maTepHanos HH3K0171 Ten-
JIOCTOAKOCTII Aamibie Hcnbrrawis no MapTeHcy npesbuwwoT Taxosbie HO 6puTaHcxo-
my cTaHaapTy, a AAR MaTepiimos BbICOKOR TeIIJIOCTOrIKOCTH?Hao6opur.
17epeeoa M. rypapusi.
nopaweHme macTmacc naece H H BO3MOHCH OCT H sawHTbl. Doleiel B.,
Chem..priimysl, 5, N2, 80-82, 1955.
PaspymeHHe pasawnibix maTepHanos?TeKCTIIJIH, Aepesa, KO}KH, aaxos,
meTa.n.nos?npH AelACT131114 n.necemi H Apyrux mHxpooprawismos XOpOILIO 11313eCTHO
H no,apo6Ho 011HC300. OHaKo CTOCIKOCTb noacTmacc K n.neceHH CpaBHHTeJ1bH0 ma.no
HsytieHa. 3To 06B0CHReTC5I Tem, ,ITO noacTmaccbi Kw{ maTepHa.n, no.nytwembifl CHH-
TeTINeCKHM nyTem, O noc.neaHero spemeHH ctu4Tami HerIplITOAHUMII AJIH IIIIT3H1151
nnecerm H Apyrxx mimpoopramumos. FlpHmeHeHme macTmacc B cTpaHax C Terunam
H B.TIBAHLIM KJIHMaTOM noKasa.no, trro mHorHe macTmaccbi noasepsceHbi nopas(eHmo
H sHaturreabHomy paspymeHwo n.neceHmo.,aeficTsHe noeceHH, oaHaxo, nposiinseT-
CH He TOJIbK0 B Tponmecxxx cxpaHax. B 4ex0caosaxm4 Taxsce 6bIJIH OTMelleHbl
c.nytiau pocTa noeceHH Ha no.nHamHaax, no.nHHHHH.nx.nommom n.nacTHxaTe H CPBHO-
TIJIBCTaX C TeKCTIVIbHbIM Hano.nHHTenem. ,ELo CHX flop ew,e He pellleHbl HexoTopue
OCHOBIlblft BOI1p0Cbl npo6.nembi croAxocT0 noacTmacc K n.neceHH. He ycTaHoaneHo,
HaCKOJIbK0 CHJIbil0 nneceHb BJIHHeT Ha csof4cTria macTmacc, IlpHBOAHT JIH oHa
? II3MeHeHHIO XHMINeCK0r0 cocTasa IIJIaCTHKOB H T. II.
B cTaTbe npHsexteH xpaTxHi4 0630p 0tly6JIIIKOBaHHbIX paHee Hcc.neaosaHH11 HO
CTORKOCTH macTmacc K n.neceHH, a TwoKe pesy.nbTaTbi pa6oT 4exocaosauxoro ?
HarlHO-FICCJIe,aosaTe.nbCKOTO HHcniTyra 3am,HTb1 maTepllamB.
rthacTmaccbi He BOCIIPIIHMIIHBbI TOJIbK0 K onpeae.neHHomy skuty n.necewi.
1/13 nopasceHHbix maTepHanos 6bIJIH sbule,neHm Paecilomyces varioty, Penicillium
brevi-compactum (Bb1,11eJ1eH 03 nopaweHHoro TIOJI1iBHIIHJIXJ1opHitHoro n.nacTmcaTa)
o Aspergillus niger.
Ta6 nu tf a I
CTORKOCTb FIOJIVIMEPOB K EFICTB1410 IIJIECEHI4
Ilo.namep
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cpe,aa, coAep-
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4:13eaoncl)opma.nb11erHnHa5i cmona
Menamamxpopmania,aeranaaa cmona
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Cpenaaila)
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a) Peayabrat no.nygea 4eXQC,TIOBal4KHM 41HCTIITyTOM 3a111,HTb1 ,maTeimanos.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
14CKYCCTBEHHblE CMOJIb1 14 I1J1ACTMACCb1 165
IlopaweHHe n.nacTmacc noeceHblo 3asHcHT OT sHeunmx yczosHiA (TemnepaTy-
pu 14 OTHOCHTeJMHO B.TIMHOCTH), XHM14tIeCKOTO cocTasa 11.11aCTHKOB 14 cougpscaHHH
B HHX n.nacTHcinmaTopos H Hano.nHHTe.neri. B Ta6JI. 1 npHs.elleHbi AaHHHe no CTOAKO-
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cbeHonitopmanbAerHAHue 14 me.namHHocpopmanwlerHAHme CMOJIM, HHTp011e.1131 10-
JI03a H 110JI1BHHHJIalleTaT c.ny)KaT liCTOtIHKOM nliTaHHH aJIH n.neceHH. MogesHHo-
(bopma.nbAerHAHme CM0J1b1 o6.na2JaloT itiyHTH11,14AHMM AeficTsHem, xoTopoe MO}KHO
0615ICHHTb onsemneHnem (1)opma.nb,RecH1La. OcTanbmae smcoxono,nHmepia, XOTH 14 He
noxtepsuisaloT pocTa n.neceHH, Ho H He no,lassnmoT ero. ECJIH 9TH smcoxono.nHmepbt
6y,1LyT HaX0AHTbCH B COTIpHKOCHOBeH1414 C seisecTaamn, xoTopue nomepxKeHHH,
TITO Hano.aHHTeab COCTOHT 113 ccliepHnecHHx qacTHu oAHHaHoBoro pa3mepa. B 1 E
HananHHTenH compicHTcH 3 ccpepHtiecmix qacmu, re S ?37,2:team-ILIA sec.
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Kaxylas apepa HMT nosepxsocT6 41R2, no3Tomy o6inasi nosepxsocTs 1 e
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ilpHmepHo 3T0 3HameHHe yAe.AbHor4 nosepxHocm H HailjteHO AAR zerHo
o6pa6ammaemoil KaHaJIbHOCI camui.
npaKTntiecKne meTopsm onpeAe.nenns yAe.nbnoil no-
sepxnocTn H pa3mepa TlaCTHILI
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qecKnx tlaCT11, C0e,TAIIHeHHbIX B HeII01111bIe arperaTm, KOTOpbIe co6pansi B pbix-
Able arraomepaTu. Ha OCHOBaHHH no,ActieTa tlacTsu pa3J111qHbIX pa3mepos MONCHO
IIOCTp0HTb xapaHTepHylo ?IASI ,Lkasnori caxcll xplisylo pacnpe,ge.nenng. 110eKOJIbKy
BecosaffOJIH MaJIbIX TlaCTHII meHmue, TleM 60JIbILIHX, cpexiss secosaff JIHHH53
6yAe'r cmemeHa B cfopoHy 66.IbinHx AHameTpos; noAo6Hoe Hce paccpHAeHHe np14-
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LIU Hmexyr npeumpnecTBeHHo citepHqecHyto topmy, flJ1OLUab KOHTaKTa HX me>HAy
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3HatieHHe n.ruxuaAH mo)HeT ObITb TOTIHO IIOACTIIITaHO H AocTnraeT 3natiendi
? II0BepXH0CTH, no.nyqeHHEdx 3JIeKTp0HHOMHKpOCKOHlitleCKHM meToAom. .
BTopoii meToik oupe,ile.nenns y,aeobnori nosepx]nocTn HaIIOJIHHTeTIH ocnosa
Ha H3mepeHHH aACOp6ll,14H, 'lame Bcero a3OTOM npu HI431{11X TemnepaTypax. 3rm-
meTo1?o&L1enpHHHTbIti B JIa6opaTopiiHX, pa6oTaIOLLI,FIX C BbICOKOAFICIlepCHbIMI4
HaIlOJIHHTe.TIHMH. MeTo,u, OCHOBaH Ha onpeAe.leHHH 06pa3poulerocH MOHOCJI0H a3oTa
Ha II0BepXHOCTH qacTHu HaIIOJIHHTeJISI H Ha pa3mepax MOJIeKyJIbI a30Ta B 9TOM
MOHOCJI0e. HeCMOTFISI Ha xopouvio BocnpoH3BoAnmocTB, meToA munotmeT pHA
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KAWLIWK H PE3HHA 169
ripeintono?KeHlui 0TH0CHTeRbH0 nnou.ta,TAH, noupbmaemoil ?Alia maneuynoil a3oTa,
H COOTBeTCTBHH TOLIKH nepern6a Ha H30Tepme aAc0p611,1H o6pa3oHanmo M0110C.TIOH
Ha nosepxHocTH.
HecmoTpH Ha pa3J1H1:1HbIe HCTOHHHKH 01.111460K, o6a meToAa psatoT BeJIH4H1-161
yiteabHoil nosepxllocTH, coroacyionmecH meN{Ay co6oll 4,Jui mHorux npombuu.neH-
HbIX limos ca}u. B pH,Re myqaes, oi_utatco, HartgeHHaH no aAcop6HHH noaepxHocTb
npesbnuaeT ?Iv) 4-5 pa 3 nosepxHocTb, noActmTaHHylo no 3J1eKTp0HHOMHKpOCK011H-
HeCKHM CHHMKaM. TaK0e 60J1b1110e OTKJI0HeHHe AaloT uaHanbHbie caucH CleHb
TOHKHMH HaCTHHaMH, ii3OrI0JIH11Te.11bH0 o6pa6oTaHHbie camm, tlepHHJIblibIe cauicAy 3HalleHHHMH yrtenbHori noBepxHocT14, onpeAe.nex-
Hb1M14 3J1eKTp0HHOMHKpOCK0111,01ecKHM meToA0m H eri0C050M aAc0p6umm a3oTa.
1 --TeoperwiecKasi Koppe.nstuffia.
500
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J1511.114S1 mexQy 3HatieHHHmn y,Tle.11bH0rI nosepxHotTH, 143MepeHHUMI4 3THMI4 Asymsi
meTop,amH, n0ua3aHa Ha pHc. 57, uoTopbth HaJnocTpHpyeT, T0 meTo,aom a,acop6uHH
HeKOTOpbIX TH110B TOHKPIX cauc onpeAgaynoT 3HatIHTeJIbH0 60JIee BbIC0Ky10 yaeob-
Hylo nosepxHocTb, Item mero,aom C 3J1eKTp0HHbIM MHKpOCK0110M.
aTOT scixpeKT npHnHcbmaeTcH nopnCTOCTH cwu: ckaKTOp ice nopBAKa, H nopm, yKa-
3aHHb1e Ha pHc. 58. ECJIH KHCJ10p0A, Aerf-
CTB)751 Ha KpYICTa.JIJIHTbI, -c)KHraeT cHa-
gana Te 143 HHX, KoTopme opHeHTHpoBa-
Hbl 6o.nee HJ1H meHee nepneHAHKy.nBpHo
K noBepxHocTH tlaCTHILbI, TO o6pa3oBaB-
innecE OTBepCTHH 1-10X0)KH Ha HileaabHble
110p131. CKOpOCTb OKHCJIeHHH KplICTaJIJIH-
TOE yr.nepoAa B HanpaBoeHHH, napaJi-
JleJlbHOM rpackHToBblm ILTIOCKOCTSIM, npx-
mepHo B 17 pa 3 6o.nblue, mem B nepneHAH-
KymipHom HanpaimeHHH.
143mepeHHB cpaKTopa otkHaJieKTpHgecKmc
noTepb AmcnepcHil 3T1-IX camc B KaygyKe
npH pa3J1HxIHbIX tlacToTax noKa3b1BaloT
maKcHmym, cABHraiontHficsi K 60JIee Bb1COKHM tlaCTOTaM ,AJIH ca)K c 6anbineil
ymJibHoil LIOBepXHOCTb10. COTJIaCHO TeopHH MaKcBezna?BarHepa, 310 HBJIeHHe
CB513aHO C nouoKeHHem 344eKTHBHoi1 AllaneKTpHgecKoti TIOCTOHHH011, KoTopoe
061:61CM:110T TOJIbK0 TIOpliCTOCTb10. 11,1tea.lbHb1f1 BHA AeficTslin KHeztopo,Ra HE ca-
xceBylo IlaCTHILy IH Ha pHc. 59.
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tlaCTb10 Hp01,13BOACTBeHHOTO nponecca, TaK ca?KH CO 3HatIHTeJ1bH0f1 1IOpHCTOCTb10
moryT 6bITb nanygend npH Ilp01-13BOACTBel1HbIX onepanaRx.
A
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negHbim cnoco6om
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oripeAeJleHHbix no aacop61.LHH a3oTa. C ;Tyra' CT0p0Hb1, MO)KHO TK H3MeHHTb
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cpeAHero pa3mepa gacTHn.
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cooTBeTcTByeT pa3mep gacTHu, 3THX OribITHbIX caw. B czeayloinell AaHb1 npe,geabi
noKa3aH14il 1.1.1KaJIbI HHrpomeTpa )051 Ka)KAoro THna ca)KH, 3T14 3HatleHHH HBJISHOTCH
mepoif gepHoTbi HJIH nnyambi BBeTa H 20.1oT KocBeHHoe yKa3aHne Ha pa3mep
gacTnu: gem Bbnue noKa3aHH51 uncanbi, Tem meHee gepHa ca?Ka H Tem 6oJibuie
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
172
KAYLIYK 14 PE3HHA
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(d0),
Atp.
YAeabHa,,
nonePx.
HOCTb
(no HA"
C01,1511,HIS
NOAH),
M2/e
FEF (npitAatouo H cmeem aeritylo atripm-
-
IvemocTO
94-95
113-138
63
30
28-199
HAF (ripmAakmosi ByJIKBHH3aTaM abicoxoe
conpoTimnexiie FicTiipaHitio)
89-90
166-188
74
24
52-104
ISAF (nimiAmouyasi symtaini33Tam Otlenb
BEdC0K0e COnpOTHB.lieHme liCTHpaHH10)
86-87
215-244
121
16
84-186
SAF (npki,aalonian Bynicanif3aTam csepX-
BbICOKOe conpoTHB.nemie licTxpaillito)
82-84
238-260
142
14
83-151
paamep ee qacTHu. KO11e631114f1 nowa3aHmil 1.11K3J1b1 B Ta6Junle OtleHb M?IbI (OT 1 AO
2 eAHHHH) H coDTBeTcasylorwHe HM H3MeHeHH51 B pa3mepe gamin!, Tawwe eima pa3-
JIHMI4MbI npH nomoam 3J1eKTp0HH0T0 MI4KpOCK0113. 3HatleHHSI ?Kpotorweft cnoco6-
HOCTH) Taxwe xapaKTepH3yiar pa3mep gamut, npmem BbICOKHe 3HatleHHFI COOT-
BeTCTBylOT MeHb11114M pa3mepam qacerHu. Kaw MOMIHO BH,tIeTb, 3HatleHHII glip01911Lefl
C11OCO6HOCTHD moryT CJI)DKHTb 0CH0B0f1 A.TIR KJIaCCHCP11Ka1LHH 3TI4X caw no THnam,
IIOCKOJ1bKy npaimitiecwH ?Aim psi A 3Hamemiti He nepexpbmae pyroil 'B noc.ne,g-
Heft' rpacpe npHriefAeHbi ripe,ae.hbi wo.ne6aHHB yrke.nbHoti nosepxHocTH, 06b11iHo
Ha6moilaemb1e A.nsi npo6 c onbrrHoti ycTaHoBwH. FlpHBeAeHHble 3HatieHHH onpe,ge.ne-
H11 110 3AC0p61H414 HoAa H3 pacTsopa no meTorw, KOTOpH131 amnHpwrecKH Koppem4-
15yeTc1 c meToAom mowoTemnepaTypHoil a?Icop6u,HH a3oTa H 110CTO1HHO npHmeHBeTcH
AJISI KOHTpOJIII 11p0H3BOACTBa H HeKOTOpbIX na6opwropHbix pa6oT. OtieBwaHo, TO
HenocpeAcTBeHHo B new! MO3KHO H31'OTOBHTb J11060f1 THu HJ114 copT ca31{14 C
pOKI4MH npeAe.namH 3HaireHHA yikeabHoti nosepxHocTH H cymecTBeHHo TIOCTOSIMiblM
pa3mepom qacTHH.
Ho Bonpocy o pa3mepe caweBba TracTilw, pH H upywType 011)76JIHKOBaHbI
mHorotnic.neHHbie HCCJIeA0BaHH51, HO AalltIbIX 0 BJ11451HHH nopHcTocTH tlacTim Ha
noBeAeHHe caw B pe3HH0Bb1x cmecsix He HmeeTcB. OnHcaHHoe Hcc.neitoBaHHe, ?CHO-
Balmoe Ha nplimeHeHHH AJI51 01IbITOB caw, oxBaTbiBarowx wpacHmenpeAeabi3Hatie-
HHP1 yi4e.nbHoll nosepxrrocTH npu IIOCTOHHHOM pa3mepe qacTHH, no1a3a.no, =no nopH-
CTOCTb HPHBQILHT K Tpem 3ac.nywkwa10akum 13IIHM3H H F1 BcpckewTam Hat6anee Bbipawen-
Hbdi 94-41exT 110B131111eHH51 meabHoil noBepxHocTH 3ax.r1I0iraeTcH B 3amemeHHH
CKOpOCTH ByJIK3H14331.1HH pe3HH. ?Upyroe CB0fICTBO ByJIK3H1433T0B, Haxo,anweecB
B 3aBHCHMOCTII OT 110pHCTOCT14,-3T0 ynpyrocTb, K0T0pf151 3ameTH0 CHimaeTcH
C yriezmieHHem nosepxHocTx. anewrponpoBoAHocTb, coo6ataemasi pe3HHe cawect,
pe3w0 noBbuHaeTcsi c yBeJnitieHHem ygeabHoil nosepxHocTH. 3T14 011131TbInpoBeAeHm
npH 110CT0SIHH0M pa3mepe qacTilw.
3ameaneHue awitcanu3a4uu. Ca}KH (H, B tlaCTHOCTI4, KHCJIbIe waHaabHme) HMelOT
TemgeHmuo K 3ame1J1eHmo CKOpOCTI1 By.axaHH3ausH. aro 3ameTHo, eCJIH conocTa-
BilTb CKOpOCTb ByawaHH3aHHH H3110JIHeHHbIX H HeH3110J111e14HbIX cmeceft. BbICK333H0
npeAno.noweHHe o TOM, 11TO cawa TOpM03HT By.riwaHH3aHHi0, (1)143HtiecwH artcop6Hpysi
arewrbi BYJIKHH3UHH H TaKI4M o6pa3om HX 143 06.113CTH B3aHmo1eficTBH1
C waytlywoBoff CJ1e,II0BaTeJIIDHO, B wayqywe OCTa/OTCH meHbunie no cpartHe-
HHIO C BBe1LeHHb1MH KOJI14qeCTBa ycwopHTemi cepu HJ1H arewroB ByJIK3H143314HH, t1TO
npuBoAHT K CH14)KeHHIO CKOpOCTI4 3T0r0 npouecca. C yBeameHmem y,r4e.nb1{oil
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KAYLIYK H PE314HA
173
noHepxHocTH a4cop6u,H5l areHTob ByJIKaHH3aLIHH nosbnuaeTcH, 3TOT 3(.14eKT
1oKa3aH Ha pHc. 60-62.
B onHcaHHot1 pa6oTe Hbi6paHa cepHH ca ,K Trina nerHoil, coo6Insalow,e1A nyoKaHH-
3aTam BbICOKOe conpoTHanemie HcerHpaHmo(HAF), C ,R0B0JIbH0 y3K14MH npe,ne.namH
Ko.ne6aHnil y7ie.nbacd4 nobepxHocTH; ?AnaKo ,L1a)Ke 31H npe,ne.nbi He xapawrepHbi ,/1,J151
TeXHHIleCKHX COpTOB ca)KH HAF, KOTOpOrl CBOACTBeHHbI elite 6o.nee y3Klle
Bce 3T11 camul B OCHOBHOM pasHougHHbi no CBOHM ycHoHnaiolunm CBOIICTBaM,
1.8
2.
1
1.
1.
a
a
a
a
1.7
46
1.5
14
1.3
0
1.2
1.1
2
1,0
0.9
0
3
08
0,7
0.6
05
0.4
0.3
60 70 80 X
Yden6/1a.9 noeepxllocma,m40
P 14 c. 60. BAHHHH0 y,40.11E.H0r1 nosepx-
HOCTH camo4 Tana nealloa HAF (coo6-
inaa14eil peallae BbICOKy10 143HOCO-
CTOCIKOCTO aa CKOpOCTb By.TIK3H4133-
ami.
5171CTp0HyJIK311H33,10111,371CH 71p0TeKTOpHaH
cmecb 113 HK (c 0,5 Bec. HanTaxca).
E2 0 MIIH.
I -0THOLUeHHe YAJIHHeHHH npH
Ha-
.80 mini.
rpysHe 28 Ice/c.40; 2 -0THOLLIeHHe conpoTHH-
T20
.11e10171 paapbasy 3 - oTHoweime
60 mint.
L20 MHH.
mo,ayneil 17PH 300%-H0m y4Jni-
L-60 Milli.
HeHHH.
0
7
?
1
7
I
a
0
I
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7
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sin ,
Wows flO8epiJIOCflTh, .W
P H C. 61. B.11HHHHe yxte.nbaoR no-
BepXHOCTH neaBoA caam Tana HAF
Ba CKOpOCTb Byaaaamaauma.
Hopma.nbHo ByaxanHayloulamcs npoTeRTopHax
cmecb 113 BCK, nonyveHHoro noanmepnaauxen
npn H113/CHX TemnepaTypax (1,25 Bec. 4. call-
E20 1.11111.
TOKlopa). 1 -oTHoinenHe YATIHHeHHIti
?80 mHH.
npH HarpyaHe 28 aaica(2; 2 -0THOIlleHlie Co-
T20 mini.
lipOTHBJlelille paapbmy ; 3 -cyr-
' 60 MHH.
L20 MI1H.
HoWeHne mo,ay.neti npx 300%-nom
MHH.
YA.81111eHHH.
eCJ1H HX CpaBH14BaTb .1a6opaTopHumH meTonamH B onTHmymeByJIKaH143aHHH. BJIHH-
HHe Ha CKOpOCTb ByJIKaHH3a111414 o6HappKHHaeTcH, ee...1113 rparpHnecKH 143o6pamcwrb
OTHOLIIeHHR conpoTHanernal Ta3pbuty H moAy.nerl A.nsi pe3HH, ByJIKaHH30BaHHbIX
B TeneHHe 20 H 60 MI4H. OTHOLUeHHH yas.inmeHHti npH 3aAaHHbix Harpy3Kax B351Tb1
,naH 20 14 80 MHH. ByJIKaHH3a1.11414. AAR cmecH, noKa3aHH0fl Ha pHc. 60, 09eBHH0,
910 ribi6paHHbie npe,ne.nbi H3meHeHHsi yne.nbHoil nosepxHocTH ma.no BJIHRIOT Ha CKO-
pOCTb ByJIKaHH3a141111. 09eB14,11110, 9T0 9T cmecb HmeeT 1436bITOK arewroB sy.nKaHH3a-
mai H no3Tomy ma.no nyBcTHHTe.nbHa K yseminernllo a1cop6u,HH HX C yHemmeHHem
y,neabHoll nobepxHocm.
PHC. 61 noKa3bmaeT Ty )Ke cepHio ca}K B MeAJIeHHO nynKaHH3porneficH TeXHH-
tiecKoil cmecH H3 BCK, no.nymeHHoro nanHmepH3auHeil npH HH3KHX TemnepaTypax.
B 3Tom caynae 3amexneHHb1il xapawrep ByJIKaH143aHH14, 09eBH,11H0, sbrreKaeT H3
110H13)KeHHOr0 ypoHHH OTHOIlleHHc1 COIWOTIMJIeH1451 pa3pbuty H MO,IkyJ151 H 110BbIWeH-
nor? ypoHHH oTHoIueHHi yJIHHeH11fi. Bo.nee HbipalKeHHbth HaKJI0H J11411H11 yKa-
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
174 xAvqyx H PE3IIHA
3b1BaeT Ha 3ameTHy10 qyBCTBHTBAbHOCTb K aCop5uHH areHTos ByJIKaHH3aILIIII, CB5I-
3ainiog c ysemitieHHem yAe.nsHori nosepxHocTH.Taimm o6pa3om, B cmecsx, KOTOpbIe
sym(aHH3y1oTcH OTHOCHTeAbH0 me,wieHHo, pammHe B a1cop6HHH arewros sym(a-
HH3HUHH npH pa3Hsix 374eJIbHbIX nosepxHocTsx caw 3ameTHo BJIHEeT Ha CKOpOCTb
ByJIKaHH3aILHH.
Ha pHc. 62 noxa3aHm ,gasHble FICCJIeA0BaHFIFI cmececi H3 TOTO )Ke Kayqyxa,
compwatusx HeAocraTotmoe KOJIHtleCTBO ycxopHTexeil. 9TH cmecH HCKJIIOLIIITeJIbH0
tlyBCTBHTeJIbHbl K He60JIbILIHM KOJIHtleCTBaM TeTpameTHATHypammicyabcfnma (TNIT,11)
H Amor 3HaIIIITeJIbH0 60JIee BbICOKHe noxa3aTeAH, eC.TIH compwaHHe TNITLI yse.rni-
imsaeTcs no 0,15-0,20 q. B c...nytme npH-
meHemis 0,125 q. TMT,E1 B Teqemie 20 Num.
ByJIKaHH3aU,1114 He Ha6.rno,gaercs, TaK !ITO
CBMICTBa pe3HH 80-MHHyTHOR ByJIKaH13a-
8 IIHH Il0Ka3aHbI Ha pHc. 62 B HX a6COJHOTHNX
3Hatiem4sx, a He KaK OTHOLIIeHHA K aHa.no-
8
.
I
'0
2
t'S.
W
4
csoficTsam pe3HH 20-mHHyTHoft
By.T1KaHH3aIIIIH. 113 pHc. 62 BHHbI
yposeHb conpomn
nIeHHti pa3pbmy H CHJIbH0
56 \
shIpaweHHbie x0Jne6amis B 3aBlICHMOCTH OT
yaeasHoil nosepxHocTH. 3TOT pEjj KpHBbIX
42 noxa3bmaeT, BJIHSIHIle caw Ha CKOpOCTb
ByJIKaHH3aLIHH B 3HatIFITeAbH0fi cTenemi 3a-
BHCHT OT cocTaria npamemiemba cmecect I4
"ITO pa3JIHIMH B nose,aenini rip! By.incannaa-
una, CBSI3aHHble c yite.nbnoci 110BepXHOCTID/O,
npH courBercTsyloakem no,a6ope peuenTypil,
7
MOUT 6bITb cae,r4enbi K mHHHmymy.
B./MARI/2 eHympeHHeii noeepxHocmu Ha
ynpy.eua OMCKOK . Ha pac. 63 noxaaaao co-
P H C. 62. BaHHIIHe y,ae.mbH011 ITOBep X- oTHomeHHe mew,rty ynpyrHm OTCKOKOM H
HOCTH ca/KH THna HAF Ha ByJIKHHH-
yne.abnori nosepxliocTbio )1J151 Asyx neqHmx
3au,Hio.
C}1{ H3 }Kniworo CbIpbSI C pa3JIHIMbIM pa3-
HpoTexTopHan cstecs H3 BCK, nonymeHHoro
noannepusasHeil npH HH3KHX Temnep aryp ax, mepom qacmg. OTCKOK B 060HX
C HeAOCTEITO,Illight COAePHCHH Hem ycHop wrens
(0, 125 sec. v. TerpameTHATHypiiMAHCYJIb- czyliasx Bbipaxien B npouenTax KaTomy
clniaa); synxennsagma 80 MPH., npli 145?.
1? conponisseHme paspusy: 2 ?mo.ay Jib rip"!
300%-Hou y AAHHeii NH; ?yjuimHetthe TIPH
HarpysHe 28 rcalcm%% (s npeaenax 260?
420%). meti sy.axaHH3aTam BbICOKOe conpoTHsneHme
HtTlipaHHIO.
BepXH515I JIHHHFI rpynnbi IICCJIeLIOBaHHbIX caw THIla HAF (anatieima HO
un(a.ne HHrpomeTpa .newaT B npem.nax 89-90) noxa3bisaer H3meHemie To.ribxo
Ha 5% npx yBe.THPIeHHH yzteabiloil nosepxllocTa Arksoe B npe,ae.nax 50-100 .4121e.
HIDKHESI Kpnaan OTHOCHTCH K rpynne HCCJIeLIOBaHHbFX caw THria netniori ISAF -
(coo6atatomeil By.qxammaTam OtleHb BbICOKOE conpoTHs.neHHe HCTHpaHH10) C 6o.nee
TOHKHMH qacTimamH, qem y caw HAF(3HalleHHFI ILIKaJIbI 86-87). 143melleHme ynpy--
roro OTCKOKa AJI5I nocze,LtHeil Cepl4H COCTaBJBleT 6% npii yBeJIHtleHHH II0LiepXHOCTII
BABOe .B npe,ge.nax 90-180 Aele.
4TO6bI no BO3MO}KHOCTH H36e)KaTb BJIHSIH1451 cTeneHH synxamnaHHH Ha
SJIaCTH,IHOCTb, noxa3aHHsie ,a.ns BepxHeil Kpnaoil Kpymamn, a AAA
HHwHell?TpeyroasioncamH, sbi6paHbi ,41151 ByJIKaHH3aTOB, HMelOILIHX 6JIH3KHe
M0,1437JIH rim( 300%-H0m y,IIJIHHeHHH.
tITO yse.natieHHe nopmciocui caw npHsoAHT K HOBbIaleHH/0 rncTe-
peancnbix noTepb. FlpHHSITO CIIHTaTb, noTepH 3HeprHil np0HCX0,IIHT Ha no-
sepXHOCTH paae.na Kayqyx?Hano.nHHTeJlb, nosTomy Ha6zio,aa MUM ri CH wixliewr
He YIBJIFIeTCSI lie03K141IaHHUM, XOTFI Tpy.aHo npeAcTasirrb AeTa.mH ero mexam43ma.
BO3M0)KHO, lEITO B ,gaHHom czyqae HMT anageinie yaeameane LuepoxoaaTocTn.
noaepxaocTa.
60 70 80 90
Wows noeepAwocmkAtlie
noxa3aTemo AAR KOHTpOJIbH0f1 craH,garrHoil
pe314Hbi c nequoil cax(eA HAF, coo6mato-
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KAYtlYK H PE3HHA
175
nopHcTbie ca}KH ,TIOJI)KHbI co,ilepKaTb 6o.ribmee tniczo macTHH B eAHHHHe Beca,
eCJIH npH OKHCJIeHHH coxpaHHeTcH IlOCTOSIHCTBO pa3mepa qacTHH. 11pH pm:mom Be-
COBOM HallOJIHeHHH pe3HH 6ozee BbICOKaSI ILTIOTHOCTb tiacTHH B eAHHHne oftema
IlpHBOAHT K 60.11bIlleMy In4c.ny KOHTaKTOB meHtAy qacTHHamH, TO moHteT or.taTb CO-
oTseTcTspouniti noxbem P4CTepe3I4CHbIX noTepb. YHe.rumeHne =mum qacTHu, B e,n,H-
HHneo&bema,zpH caytiaes, noKa3aHHbix Ha pHc. 63, ycTaHomeHo pasHbim TO.T1bK0
4% is HaH6o.nee Ancnepcubix o6pa3Hos camcH THna HAF H 8 % npeAeob-
73
? 0
Oo?
0 0
.
0
0
98
76
74
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72
c(-1
63
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nes III
YU 1W LIU 13U ifu
Maim] 1?ocepxliocm6,/d/a
P H C. 63. 3aBlICHMOCTb noxaaaTe.neri ynpyroro
OTCKOKa OT y2eJthH0H nonepXHOCTH caxm ;on
cmeeeti 113 ECK, no.ny4eanoro noo11mepn3anme1
npn HH3KHX TemnepaTypax.
o MOAY/lb 17p H 300 %-HOM pacTsmenHli. 103-112% (OT
mor(y.ns KOH Tr011bH0A cmecH), 89-90 no ['mane Bvirpo-
merpa; aBanorwmpit( moBy.nb npH 300%-Mom pacTB)Be-
HHH, 86-87 no nma.ne BlarpomeTpa.
HOTO CJIyulaH B CHH cax.c TH-
na ISAF. 3TH BeJ1141114HbI Toro
nopsmxa, tITO H npougHT 143-
menenna ynpyroro OTCKOKa B 11C-
CJIe/I0BaHHbIX !Tem./lax H3MeHe-
HHI nosepxHocTx.
60 100 140 180 220
Weimmas noeepxllocam, Al
P H C. 64. 3aBlICHMOCTb y,aeJ1bH01-0
C0111)0THBACH1411 OT yAeabnoti noBepx-
HOCTII ne=nibix ca 3 x(waxoro
Cblpba.
CMeCH H3 HK, coBepwauvie 50 Bec.
Ca&H.
H3ytieHHe 3.nexTponpoBoAHocTH cmeceti C nopHcTbimH camlleHbr CBMICTBa OKHelleHHOci THna HAF B cmecox
143 HK C 40 q. HaTI0JIHHTeJ151. ara rpyrma 011131TOB Aa.na pe3yabTaTta, onpoBep-
ratom,He BJIHHHHe 110pHCTOCTH 14 yireabHoil nosepxHocTH, yCTaHOBJleHHbIe Ha
OCHOBaHHH HaylleHull CBOACTB nellHux caot C BbICOKOR yoe.nbHot1 110BepXHOCTb10,
n0,nylleHm4x HenocpeAcTBeHHo B npoH3B000cTBeHHo1l netm.
E,TIHHCTBeHHOe no,ATBepKaeHHe CBOPICTB 011bITHbIX netowx caw Ha o6pa344ax,
B za6opaTopun, noaylleHo B COOTH0111eH1414 meKoy yoeobHoil noBepx-
HOCTb10 H CKOpOCTb10 By.rmaHH3ankm.
0,oHallo yrreabHoe conpoTHBaeHlle H ynpyrinl OTCKOK He caeopoT pollee
ycTaHormeHHog 3aBlICHMOCTH. 3eCb yrre.nbHoe C011p0THBJIeHHe 01/3KTIVIeCKII
yBeaHllm3aeTcll c B03pacTaHllem noBepxHocTll, llTo npoTHBopellHT pe3y.nbTaTam,
no.nyllerumim Ha 1-1CCJle,E(OBBHHUX neton4x ca)llax. Ynpyruti OTCKOK ocTaeTcll 6e3
133MBHB1114,1, 3a HCKJI1OtleHHeM TOr0, icor,oa y,rkeabHall 110BepXH0CTID COCTaBOSI-
aa 504 .4121e. OileBHAFio, 11TO B 3TOM cayllae caxKe H CKOpOCTH pa3,a1pa) 3aBlICHT,
OT TemnepaTypm oHpyHmioineil cpe,abl H TemnepaTypu bllyrpn o6pa3ua. Pe3yJIbTli-
ppotusaH TemnepaTypa B HenocpeacTuenHofi 6JIH3OCTI1 K Tpem,HHe H3MepHeTCH
C 60JIbILIHM Tpyzkom.
Bce H3mepeHHH Hp0BO,LIIIJIHCb npH HacToTe 4 et. B.IIFIHFIHe IlaCTOTbI HCIIbITaHHH
Ha pe3y.11bTaTbl H3mepeHHH oTmeHariocb paHee [5]. Ha OCHOBaHlIFI H3mepeHHil
TemriepaTyphi HHyTpH o6pa3na aBTOpOM ycTaHoH.HeHo, noBbnueHne IlaCTOTb1
Bbl3bIBaeT no,Trbem TemnepaTypbi, a CJIe,210BaTeJ1bH0, H H3meHeHne cHopocTH pa3,4Hpa.
B cTaTbe 113JI0]KeH Bonpoc TOJIbK0 06 ypAHHeHHHx, KOTOpbIM 6bIJIII no?Eksepr-
HyTbl o6pa3um. DTO 061.FICHFIeTCH Tem, IITO yroHneHne MO}KHO oco6eHHo zenco
H TO'FHO 143MepHTb. BO3M0>KHO, ?bIJIO 6bI 60JIee IlpaBlIJIbHbIM umecTo 31'0r0 yKa3bI-
BaTb npHmeHHemble HanpfieHHH. OAHaHo onpe,aemyrb HanpH}KeHHe 3HatIHTeJIbH0
Tpy,anee. Hpn paCTSDKeHHH 3JIaCTIP-1HbIX maTepHanon cHaa, Heo6x04imaH XIII CO-
3,4aHH51 KaKOTO-JIH60 yAJIHHeHHH, 113MeFISIeTCH B TeHeHHe npemeHH Ha6Juo,u,eHHH.
B 3Tom cayHae Ha6.1noHaloTcH peaaHcarnioHHme npolleccm. Ha OCHOBaHHH H3.10-
?KeInf0r0 BTO He AaeT 3HatieHnfl E (M0,1131551 ynpyrocTH), BIDPIHCJIeHHbIX H3 HaripH-
)KeHHH H yJIHHeHII51, HecmoTpH Ha HOCTOSIHHbIe TLIIaTeJIbHbIe 3amepbi CHJIbI H no-
nepetmoro cetieHHH o6pa3Ha eratoKe B HarppHeHHom COCTOHHHH).
7. iteTaAH rip0Be,eHh1H HCHbITaH11/1 Ha pacTpecKii?
HanHe
)1,J151 TIOHCliel1142 maTepHaaa, H3ao}Kenlioro B ripeAblAymux pa3Aenax, coo6-
mmoTcH HeKoTopme A0110JIIIIITBAblible ,Ltamibie o npou,ecce
HmeeTcH mHoro pa6oT, Hacaloun4xcH BJTHHHH5I cpopmbi Ho?Ha HJIII HFJIbI [6].
flpH TLIFaTeJIbHOM paccmoTpeHHH HaKapro (H3 II0Ka3aIIHbIX Ha pnc. 78) nope3a
OTtleTTIHBO o6Hapy>KHBaeTcH roa,aHasi noHepxHocTb Ha,a LuepoxoriaToil mlocHocTmo
pa3pymem4H. Qua HBJIHeTC51 pe3yAbTaT0m nepexo,aa 113 cTaAHH HatiaabHoil TpeigHHEa
B 06JIaCTb 3epHHCT0R IIJIOCKOCTH pa3pymeHHH. IIJIOCKOCTH pa3pymeHHH pa3pacTa-
10TCF1 B cope TIOJIyalLIIIRICOHAa. HpH 3TOM B AaabHeihnem pOCT He 3aBHCHT OT
iratiaabHoro nope3a.
3111 AaHHble 1-10.Thrienbir auTopom y}Ke 113 paccm0TpeH1151 pa3pe3a Tpeunill.
OilnaHo Hatiaabilbnl nope 3 6bhn naneceH Taloke npn nomoni,H nppicnoco6,HeHHH,
13 xlimIN, N2 1
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
194 KAYLIYK H PE3HHA
cxemaTHHecHH Howa3aHHOTO Ha p HC.89. 06p a3eu, y Kpen.neH Ha CTOJIB, KOTOpbal MO>K110,
ripH6TH4)KaTE. K HO)Ky. nOpe3, TaKHM o6pa3om, oco6eHHo oerwo ocyntecTH.nHeTcH
H onpem.nneTcH. B pe3yabTaTe HpHmeHeHHH aToro annapwra 6bLanHbi Te
>we 3HalleHHTI CKOpOCTIT pa3HHpa , TITO H C ycrpocicTsom, 110K33aHHbIM Ha pric. 71.
Katt pm yKaabma.loch H pawkeoe 1, pa3mepu 33}KaT0r0 o6pa3ua cocTaanHam
80 x 25 x 6 MM. EcTecTseHtio, ripw orumawoHoti AJIHHe 3a}HaToro o6pa3lla ?bIJla
H3yHeHa Taw)He Heawnnia Apyriix H3mepeHHP1. CIle,ayeT CTpeMHTbC54 BbI6HpaTb,
pa3mepu TaKHM o6pa3om, HT061D1 CKOpOCTb pacTpecHHHaHHH He 3amiceza OT
o6pa3u,a. aro ycaosHe HaAewHo o6ecnelmHaeTcH Tor,aa, wor,aa AJIHHa Tpew,HHbr
maaa no cpaBnennto c ampnuoil otipa3na n r.nOnna rpenumbi ma.ria no cpaa-
nemno c To.numoii o6pa3n,a. ?lineal-mat pa6oToil noKa3ano, tiro yBemitienue
nmpunbi oopanta OT 25 ao 45 ALM ne npnnoiniT K H3menetuno cKopocTu pa3Anpa_
TLipaccma-rpnnaemux c.nynaen (Amnia ipeunnn.i
CnpeBbmaaa 9 MM) AocTaToqua unipHHa 25 .44m. Bo-
.Hee 3arrpy,AHHTe.neH BbIBO,Et o HoHxoAsiw,eti TOJILLTITHe
o6pa3ua. IlpH HccoeoBaHHH TJ1y6HHISI TpeIgHlibl otto
3 MM coe,HyeT lipe,11110J10)KHTb, IITO H3meHeHHe TO.11-
111,HHb1 o6pa3ua OT 6 Ao 9 MM ymeHbuTHT CKOpOCTb
pa34,Hpa. lipH paccmoTpeHHH EsbnuenpHse,ReHHoci Ta-
6.HHubi OKa3b1BaeTCH, 0,4113KO, tITO yHezwieHHe TOJI-
11.1,14HbI o6pa3Ita HpHBOAHT K nosbnueHmo TemnepaTy-
pm. 110BbIIIIBHHe TemnepaTyptd BbI3b1BaBT yHe.nwHeHHe
pOCT a Tpeaum pe3I414 H3 HK [1]. Il09T0my H3me-
P c. 89. liptcnoco6.neinte peHHH Ha o6pa3uax TOJITITHHOil 9 MM AaJIH 60Jlee
JA.1151 Hanecenna nope3a. BblcoKHe cwopocTH pa3H.Hpa. Awrop cHHTawr Sb!-
6op o6pa3u,a 9 MM 60Jlee 110)1X0MIIIMM.
1?HOAC) 2?o6pa3eg; 8?CTOA.
B 310M czyHae ray6HHa TpeTII,HHbI (npH AOCTH)4eH1414
pa3mepa ee ito 3 Am) cocTaH.nHeT 1/3 o6tweil
o6paaua. 0 BJTHHHHIT AJTHHbI 06pa3wa mexcay 3amuimamH [1] ywa3bn3a.Hocb.
(pHc. 70). B ycTaHoHwe AAR onHcaHHEa 011bITOB (plic. 73) TIOJIOCKH 3aHmma1oTcH
6e3 H3TH6a. HecmoTpH Ha 3TO, HczeAcTHHe umnacTHHecworo y2JTHHBHH5Th 3J1aCTO-
mepos aaHHa o6pa3u,a npH HarppHeHHH HeH36emo yHeJTHHHHaeTcH. lips wo3wpa-
MeHHH B HCX0aH0e noaoaceHHe o6pa3eu aaer He3HatIHTBJ1bHblfl 53rH6 (TIOAO6H0 530-
6pamcemi0my Ha pHc. 69,6). YKa3aHHOB BJTHHHHe Hcc.ne,lortaHo 6o.nee noApo6Ho.
aim 3Toil u,eani oaHH o6pa3eu Home Ha)Moro HarppweHHH B TeHeHHe 1 MHH. pa3-
rpyHca.rm H H3mepH.nH, Toraa KaK ApyrHe o6pa3abi OCTaBJISIJIH B 14C11131TaTe.T1bHOil
maunme B Teqemie 15 MHH., O oHoHHaTe.nbHoro HX CHSITH51. IlpH OAHOM H TOM >we
oluem HpemeHH HCTIbITaHHST B Tex Ace yCJI0BHFiX o6pa3eu, no,rtHeprammulcH 6o-
.nee nacTum HarpyweHHHm, noHa3bumeT HeCKOTIbK0 60Jlee BbICOKy10 CKOpOCTb pa3-
11Hpa (He6o.nbume pa3aHi45e B MaKCHMaJlbHOM ymmleHHH). 0JIHaK0 3TO He3Ha-
HHTeJlbH0 BJIHHeT Ha pe3yabTaTbi H 1103TOMy He HpHHHmaeTcH BO HHHmaHHe.
11011TH npH Hcex o6cyaQaembix B HacTomweti pa6oTe H3mepeHHHx (3a HCKJI10-
tieHHem yKa3aHHoro Ha pHc. 87) ray6HHa Tpear,HHbi onpeHe.rimacb npu TIOM0111,14
mHxpocKona, KaK noHa3aHo Ha pHc. 72. arm' meToa BITOJIHe npHroaeH AAA o6pa3u,oH
B mute HOJIOCOK. OaHaKo yKa3HHHbIM MeTOTkOM TpyoltHO H3mepwrb ray6HHy Tpeaumbi
B H3,11eJIHH, Hanpitmep Hume. 4TO6b1 MON(110 6b1JI0 npHsecTH aaHHble no ray6HHe
TpelaHHbl H B 310M cayqae, 6bia 1131'OTOBJleH oray6HHHEa11 30HAD. MHKpOMeTp 1103B?-
Jil1eT OTCIIHTaTb TlyTb (AB Ha pHc. 72), KOTOpblft Ilp0X0,Z(HT 30H,a noa TIOCTOSMHbIM
AHHaeHHem npyaumbir. IlpH f1p0H3B0J1bHOM 3amepe psmom C TpeutHHoil Ha6.rnoaaeT-
CH npoHHHHoseHHe 3oHaa B HenospeataeHHylo coceammo 110BepXHOCTb o6pa3ua.
3TOT nyrb rips H3mepemui BbITHITalOT. Y,aaJlOCb AOCTI,ITHyTb ,a0B0J1bH0 xopomero
coHnamHHH noHa3amul npH6opa C H3mepeHHHmH ups nomouni mHHpocHona.
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HeHHH maTepHaaa, HO 3Ta 3aBHCHMOCTb aBTOpOM noApo6Ho He Hcc.neaoHaaacb.
HalblTaHHH oopa3uos H3 HK Hat1HHaJIHCb, equialio, He paHee qem cnycTH 48 qac.
uocae ByJIKaHH3aHHH.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KAY'-WK Fl PE3111IA 105
ABTop onHcbmaeT npHmep HCIMITaHHB Tpex o6pa3uoa OAHHaKOBbIX pe3HH
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AJIHHbl H IVIy6HHbI TpeumHbi OT spemeHH HarmoKeHHH. ,L(He xpHable 611113KH
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xapaxTep, TM xax ?B.MHBaIOTCH B rpamituipo
KplispoD? flpHtirmy pa3oHim0r0 HoHetzleHHH
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H141114TbCH 06J1aCTb10 rpaHHImoil xprmoti. CKOpOCTb pa3,aHpa, TaKHM o6pa3om,
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
196 KAYtlYK 1,1 PE3MIA
no.nytialar KK BeaHnHxy, npknurrylo ;via oneHm4 Aa.nblleihnero pa3pacTaHHa
B 3aBHCHMOCTH OT ,14JIHHb1 (a Taxx{e TJ1y6HlibI no pHc. 91). Kax noxaabmaioT
pc. 92, a H 92, 6, ace TpH o6pa3na ByJIKOJIJIaHa AaroT A0B0JIbH0 xopoutee
coana,aeHne CKOp0CT14 pawmpa.
8. flepcnexTHabi Hcc.neogoBaHHa
B pa3JI11IMbIX p aap,e.nax 3T011 pa6oTbi no.nygeHai xopomo B0CHp0143B0,114mbie 143Me-
peHHH nopaapacTaHmo Tpeunm. CKOpOCTb pa3,414pa Bae,21eHa xax aemiluma, yAo6-
Hay' Ana 014eHK41. IIpI4 9TOM HmeeTca BO3MWKHOCTb npose,TkeHHH Ha,aem{Haix cepHiA-
HbIX HCI1b1TaHlift. flpH CepHiHbIX HCI1bITaHHHX BMeCTO mHxpocxona ;via 014eHK11
Toyama' TpeatHHai npHmeHHeTcH r.ny6HHHanl aoHA.
B 01114Ca111414 nposeAeHHba 041bITOB npeAcTaa.mouniecH BO3MO}KHOCT14, 0)4HaKO,
He HcnepnamaioTca. floc.ne HaxoaQeHHH npHroAHoro memo He06x0)THmo Hccae-
AOBaTb 3aBlICHMOCT14, HMH B Buy, tITO CKOpOCTb pa3,4Hpa orloamma 6bITb caHaalla
C Apyrnmn xapaxTepHcmxamx 3.nacTomepos.
414cTo xanecTaexHaa 3aBHCHM0CTb rxe no.nygeHa. Tax, 143 pHc. 85 BHAI10,
TITO 06yc.n0mneHH0e cTpywrypoci BbICOKOHOJIHMepa pa3BeTaneHHe Tpeiumx npHao-
AHT K ymeHbmeHmo CKOpOCTH paaAHpa. CHJIbH0 BJ1HHeT Ha peayabTaTm Hamepe-
HHH H3meHeHHe HarIOJIHHTeJIH. FlpHmepom HBJ15110TC1 nano>xemia rpaHl4nHbIX
KpHBbIX I 14 IV Ha pm. 82, a c.neaoaaTeabHo, H CKOpOCTb pa3,414pa, xoTopaa
HameHaeTcn TOJIbK0 C HameHeHHem THna HarIOJIHHTeJIH np14 ripotmx paatibix xa-
paxTepimcnixax cocTaaa By.rmaHHaaTa.
Tame MO}KHO npmITH H K K0.111411eCTBeHHb1M noxaaaTe.nam. lipeA{Ae Beer?,
xaNceTca BTIOJ1He BepOSITHbIM HeKaTb 3aBHCHM0CTb Me)KAy CK0p0eTb10 pampa
H moAy.nem ynpyrocTH E. TpyorwocTH, BO3HFIKa10111,14e HH Totmom Hamepemia
E, ye paccMoTpeHm B paaame 6. Ha ocHose npeikanwunix Hcc.neAoaamifi aaTop
yTaepaukaeT, LITO noameHHe rpaHmtmon' KpHnoci H BezHnHHa CKOpOCTI4 pa3,m4pa
3aB1ICSIT OT E. TO,IHbIX AaHHbIX noxa eine He no.nytieHo. HaxmxeHHe 9To1i 3aaHcH-
mocTu--3aikaga Aa.naHetlinero HeeZeA0BaHH11.
J1HTEPATVPA
1. Buist J. M., Iran s. JR I, 29, 72, 1953.
2. Newton R. G., Scott J. R., J. R u b b. R e s., 16, 245, 1947.
3. Buist J. M., Williams G. E., Tran s. I R I, 27, 209, 1951.
4. Holt W. Tr., Knox E. 0., R u b b. A g e, 60, 689, 1947.
5. Rainier E. T., Gerke R. H., I n d. E n g. h e m., analy t. E d t., 7, 368, 1953.
6. Buist J. M., Powell E. F., Tran s. I R I, 27, 49, 1951.
Ilepood A. ilyKomowii.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
01-114CTKA CTOLIMIX BOA
Hog pellaiumeti KaHn. XHM. Hap( M. H. ilanulutia
HCH0.11b30BaHHe npyp,oB A.351 01111CTKH CTOLIHMX BOA meTaaaypnitiecnix 3aBOA0B.
Griffith Ch. R., Sewage In d. Was t., 27, Ns. 2, 180-189, 1955..
06 HCIIOJIb30BaHHH npyaos AJIH 0111,ICTKH CT0tIHbIX BOA ony6orix0Bari pa,g
pa6oT; HOBbIM B HaCTOSIIHeCI cTaTbe HB.11HeTCH?ycTanoa.nenne BO3MO}KHOCTH 011HCTKH
B ripmax np0MbIl11.11eHHbIX CTOTIHbIX BOA, corkep)Kankrix amyabcriri macea, oTpa6o-
Tarnibie KHCJI0Tbl H me.notin.
B BacTosimeil cTaTbe paccmaTpaBaiarca CTOLIHbIe BOAbI, copacbmaembie alma-
11140HHbIM H aBTOMO6IVIblIbIM aaBoaamB, HMelOLLIAMH CX0AHbICI Texiio.norkitiecicafi
npougcc, BKJIIOnaIOLUHFI B OCHOBHOM onepamn4nopeaamno H LLIJIH4)0BKe CTaJIH,
a Tax}me no oT,Reaxe H coopxe ,aeTaneil. XapairreplicTuma, HCTOTIHHKH o6pa3oBanrisi
H CHCTeMbi xaHaJ1H3aILHi, B BoTopbie c6pacbmaiurc1 CT011HbIe BOAbI, npriBe,gefibi
B Ta6a. 1.
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(ccukemicauktiecsi B HHX norimec11)
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cTogithie BoAbi
Album ki ineocgmbie molonme
cpeACTBa
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CTOLIHbIX BOA, nocrynaBunix B 141 npyrt, COCT3BAH.11 B cpemiem 45-56 .413/itac;
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
198 O4HCTKA CT0t1HbIX BOA
TeopeTHnecxoe Hpemm npe6b1BaHHH CT0x111131X BOA B 1-M npy,ny AOCTlitaJ10 ???-? 3 CyTOK
(4:0/(THIleCKH OHO 6bIJI0 meHbale)..3a Hpemsi npeousaHHH CTOIMbIX BOA B 1-M nPy,1137
coAepHaumecH B UHXMacaa- Bcn.nbma.nH Ha noBepxHocTb, a TH)KeJlble rpy60,nHc-
nepcHbie npHmecH ocaMfAaJIHCb Ha AHO. Ha sbixoAe CTOIlliblX BOA H3 nepHoro
npyi.ta ycTaHomneHa no.nynorpyweHHasi ,nocHa, 3ailep}HHHaioakasi ?OTAeJIHBIIIHeCH
mac.na H ApyrHe Hcn.nbmakowe npHmecH. rloc.neAHHe co6HpatoTcH npH nomonut
Tpy6b1 c npope3HmH 'H nepeHanimalarcH H AlicTepHbr, STH mac.na H npHmecH Ha-
X0AHJIH npHmeHeHHe.
KomieHTpaHHH macea B CTOKe, nocTynagmnem B 141 npyA, B cpemem pasHaH
2543 Me/jt, Ha Hbixone 113 STOTO npma cocTaansuia 92,2 Me/A, COOTBeTCTBeHHO
HomleHTpanHst TOHy1.11,HX rpy6o,nHenepcHb1X npHmeceil CHH)KaJlaCb C 1484 pp 79 me/A,
U38, ;CIMIKOMble
cinovx e anew
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P If C. 93. CXeMa 011HCTKH CT MMX BOA.
1-
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2-fl npyA no,1o6eH 1-my Hai( no cpopme (pa3mepam), Tax H no xapaHTepy BbIHOJI-
xxembix cpyinumii. 01ttaxo OTHOCHTeJlbHbla 94X4)eKT 011HCTKH CT011HbIX BOA p Hem
3Hat1HTeabH0 1114>Ke. Ha Hbixo,ne H3 Hero HoHHeHTpaHHH B Hue macen B OTAeJlbHbIX
CJIrlaSIX CHIDKaJlaCb ;to 1,8% (OT nepHoHananbHoil KOHI.LeHTpaltHil FIX B CT0t1H0r1
BoAe), TOHylAHX rpy6oAHcnepcHb1x npHmeceti ,no 2%, Bnic ,no 9,5%. AHanormHoe
ycipocicmo coopy){eHo B HM if AAR c6opa BCI1J1b1Ba10111,HX mace.n; OAHaK0 B HaCTOSI-
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1-11 npyA, He 6y1eT BbIKJI1011eH H3 pa6oTbi AAR ero OTIHCTKH.
flo npOexTy npe,nycmoTpeHa 01.1HCTKa npy,nos npH nomom Homna.
Kai< 110Ka3bmalOT aHaJIH3b1, B 1-M npy,ny 3a onHH pa6onfitl AeHb oT.naraeTcH
2 m cyxoro HeMecisa, BO 2-m 3a STO }He spemH Ke camaH psicxa npeAcTaansinaco6oi npeKpacHbal CPHJIbTp, ciumasiumil
!comma-Talmo macez B CTOKe 113 craporo tipyAa. nixes pfiCKH B cacTeme HOBbIX
npyaoa He Hmea ycnexa: pacKa 3a apema ripoaeAemia CTp0HTeJIbCTBa HCtle3JIa.
Houle oHapy.KeHH 11 acripaanewasi abaueyKa3aimbix aHaJIHTHtleCKHX 01111460K,
AonyukeHHbix npH B3BeIIIHBaHHH npo6 jo OTTOHICH pacTsopHTe.rm, HcnpaaneHHoe
cpeAHee 3HaHeHHe KoHueHTpaHHH mac.en B CTOKe, BbIXOAFILLIeM 113 HOBOR CHCTeMbI
npy,ttos, OKa3aJI0Cb paBHb1M 7,2 mthz, HT? connuneT C HX KOHIleHTpanHeil B CTOKe,
BbIXOAHBLIIeM 113 CTapOil CHCTeMbI npyAon.
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me/A
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o6inee KOJIHtleCTBO, M2/4 ,
neTrate, me/A
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8,5 13 15
9,2 10,7 3,0
75,9 98,5 30,0
4,7 5,9 4,4
84 87 90
7,88 8,31 7,84
0 20 0
242 230 297
22 23 17
6 9 5
40,8 32,6 33,5
B Ta6JI. 3 npeAcrameHa xapaHTepHumca MeCTHbIX BOAOTOKOB. npo6b1 BOAbl
H3 pein(H obuni oTo6paHbi BbILLIe CJIHHHHH ee C pytibem, B KOTOpbdi copacbmaioTca
CTOLIHbIe BOAbl 113 npyAon. KoHnewrpauHH pacTriopeHHoro B BO) e Kac.nopo,ga B pee
spemeHamH CHIDICaJlaCb Jlp 0,5 Me/.4 H TOJIbK0 B penyAbTaTe BnaAeHHH B Hee pyllbfl
CO3AaBaJIHCb yCJI0BH51, He06xoximb1e AJIH )1(H3HH pb16. MIK B pribe HIINCe meaa
c6poca CTOilHbIX BOA 6bIJI0 paBHO 5,9 MO/A 11 npenblluano (MIK) 'mane mecTa aria-
,lel-111H HX Ha 1,2 M2/.4 H Ha 1,7 me/.4 MIK copacbmaembix CT0t1HbIX BOA; HeCOOT-
HeTcTHHe AaHHbIX MO)KHO OTHeCTH 3a cHeT 01111160K npn oT6ope npo6, a, Kpome TOTO,
Ha penyAbTaTax aHaJmna MOTJIH CKa3aTbal 3arpH3HeHH5I, BHOCHMbIe B pytieri
cToKamH 113 CeIITI,IKTeHKOB (coopyweima AAR pan.no)KeHHH oca,gKon CT011HbIX B04)?
rIpHmeHeHHe npyRDB AJIH OtHICTKH CTOIMbIX 1302 pacunipaeTcH, n03T0my Boripocu
EX npoeKTHportaHHH H ycrporicrsa CTaHOBHTCH necbma aKTyaJIbHbIMH. OTpHuaTezb-
Hoe oTHorneHHe K npyikam B npomnom ocHorthmanoch Ha HeyAOBJIeTB0pHTeJIbHOM
npoeKTHportaHHH H IIJIOXOCI aHcruiyaTaHHH coopyweHHfi. ilpy,abi paccmaTpHsamicb
KaK penepsyapu AJIH spemeHHoro HaKomneHHH CTOTIHbIX 130A nepeA c6pocom HX
B B010eMbI HJIH nepe,rt noAaHeri Ha 6Ho4ntribTp; npH 3Tom He npHAananH HHKaKOTO
3HatieHHH npoTeKalowm B HMX 6110XHMIPIeCKIIM H XHMI,PleCKHM npougccam, mory-
utam KOpeHHbIM o6pa3om IlOBJIHHTb Ha cocTan npHmeceti CTOtilibIX BOA. TaKHM o6pa-
30M, npyikbi, XOTH OHH H He moryT 6bITb peKomemonaHbi Alm 011HCTKH acex a14,11,0a
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
204 011HCTKACTOLIHbIX BOA
11p0MbITUJIeHHbIX CTOHHI3IX BOA, 6bIJIH Hecnpasexxxso 3a6bITbl. flpy.iu,i Tpe6ymT
nooma;keft 3HaIIHTeJIbH0 66.nbunix, tiem npH ripHmeHeHHH Apyrkix meToAms OHHCTKH
CTOIIHNX BOA. rIpH npaHHAbHo COCTaBJIeHHOM npoexTe, pacclurraHHom Ha HX MHHH-
MaJIbHbICI oftem, yeTpacTso npy?Ios mmeT OKa3aTbCH 3KOHOMHtleCKH BIIOJIHe
BbITOAHbIM.
flpyAbi 3auniata1oT BoAoembi OT e4HHoripemeHHbix c6pocon B HHX HpeAHbix
npHmeceil, II03BOJIHSI 3a ctier pa36a.H.neHH5I CHH3HTb HX TOKCHIllibIe KOHIleHTIMLI,H11
o BeJIWIHH, AOIVCTHIsibIX ripH c.6poce CTOHHbIX BOA B BO40eMbl. ?pram)! oxpaHbt
Ho,[koemoa HifrepecyloT He cpeAHHe AaHnbie, noaygeHHIge B pe3yobTaTe OHHCTKH
CTOHIMIX BOA, a Te, xoTopme moryT 6bITb npH HaHxyjnneti 3xcnnyarauHH CHCTeMbI
OHHCTKII. 3T0 BbI3BaHO Tem, TITO c6poc B )3o,Roemb1 npHmeceil B TOKCHHHbIX KOHLIgHT-
paIIHHX XOTH 6b1 B Te1eHHeTOJIbK0 0,711-10r0,41151 B ro,ay MO)KeT nosecTH K maccosocr
rH6e.rin B HM pbi6. B 3TOM OTHOUIeHHH npy,rkw Hmexyr 3HaxIHTeJ1bHbIe npeHmynecTsa
nepe,g Apyrnmu sitikamH 0111,ICTKI4 CTOHHbIX BOA.
lipeAnpHHTHH, 3aHHTepecosaHHble BO BTOpHIIHOM HCIIOJIb30BaHlIkl BObI, moryr
paccmaTpHHaTb npyAbi KaK Ha,ae}xxbdi peep H ;pH npoTHHonmapHux nezen
H BoAocHa6}KeHHH. Ilepesoa C. Kotio6eeea.
?
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
IlIPHHATME COKPAMEH1151 HA3BAHH? )1(YPHAJ10B
Anal. Chem. Analytical Chemistry
Ang. Chem. Angewandte ,Chemie
Brennst. Brennstoff-Chemie
Brit. Plast British Plastics
Chem. PrOmysl. Chemicky PrOmysl
Chem. Techn. Chemische Technik
ErdOl Kohle Erdol und Kohle
Faserforsch, Textiltechn. Faserforschung und Textiltechnik
Ind. Eng. Chem. Industrial and Engineering Chemistry
J. Agr. Food Chem. Journal of Agricultural Food Chemical
J. Am. Chem. Soc. Journal of the American Chemical Society
Kautschuk, Gummi Kautschuk und Gummi
Lieb. Ann. Justus Liebigs Annalen der Chemie
Paint Manuf. Paint Manufacturer
Peint. pigm. vern. Peintures, pigments, vernis
Sewage Ind. Wast. Sewage and Industrial Wastes
Svensk Pap. Svensk Papperstidning
Z. anal. Chem. Zeitschrift fur analytische Chemie
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
K1314THKA 14 B145.111401'PA01451
PYKOBOACTBO no PACTBOPHTEJIAM H ,CMEACHI,IM BEIIIECTBAM C TABJIHUEA
lix PACTBOPHMOCTH
SOLVENTS AND ALLIED SUBSTANCES MANUAL WITH SOLUBILITY CHART
COMPILED AND EDITED BY C. MARSDEN
London, Cleaver?flume press, 1954, 429 p.
06utHil oftem moHorpa4mni-429 'vrtv.,"Himonaa yxa3aTeab npommumeHmbix HpeA-
11pliSITHA, ynomHHaemmx B Texcte, a TaK2Ke 11pe)ZileTlibIR yxa3aTeab HeinecTH, npHmeHnembiX
? xanecnie pacTsopaTeneft. KpoMe TOO, B HaTIELne KHHrH AaHbl npexHcaosHe, oraaaneHse
H xpaTicoe 011HCatille yCJIOBHA, B KOTOpbIX onpexeminHcb 4H3HTleCKHe KOHCTaHTbI ,11,a m :p acts ci-
p TeaeA. B OTAe,11bHbIX C./Vila/IX 9TH Or1HCal1H51 A0B0J1bH0 no,1po6Hb1. B HattecTHe npHmelia
moxmo npHisecTH onpeAeneHHe TOTIKH nJIaB.neHnsI KaK TemnepaTypu, npH xoToport Tue.p.Aoe
amecTso HaXWAHTCH B pamosecHH c )1(11,IIKOCTb10; anTop oTmenaeT, TITO TemnepaTypy,.tpH
KOT0p0171 THepuble ..nacTunm Hnerimae? nepexoxsur B XHAKOCTb, 6bIJI0 bI tonHee sonpeAex-HTb
K8K gTOTIKy 3aMep3aH1IFIA' 0 AITO B TeXKHqeCKOtI HHItiOpMaII,HOHHOR JIHTepaType "o6a TepmHHa
nacTo nyTaior..13 monorpactikH no)1 3ToA It0HCraHTOR noApa3ymeHaloT TeMnepaTypy, flp? KOTO-
po .ininnocTBio 3acTiguaeT, 'HO He o6H3aTenblio. B onpeAexeHHHx Tex HoHcTauT,
xoTopme 3aBHCHT OT aTmocepHoro ,4813.11eHlift,'Bcerita .oTmenaeTcH, nTo yKa3aHHb10 B 'mitre
BeJIHTIHRb1 npluse,genba:K cTalmapTHomy .xaHaethno 760 .mm pT. CT., Hanpnmep npH onpexe-
JleHHH T04KH KIIIIeHHA, Temnepatypta BCI1b1111K/I, CKpbITOA TeHJI0Tb1 ncriapeHHH. PaCTB0pHTe./111
xapaxTepH3ToTcH CJIe,ay1011kHMH 41113HTleCKHMH HoacTaHTamH: TOTIKOA KHIleHHH, T.OTIKOIR
11.71a13.11eHHA, TemnepaTypoit-H6nbaukx H .CamosocripiameHemm, YAe.71bHbIM BeCOM, noxasaTenem
npeaom.neHHH, B3phIBTIaTOCTIA0 HB Ho3,xyxe, xo340HuHeHTom !xy60necxoro pacinpennn,
yAeabHoft? Te1140eMKOCT.1,10; expuToPI Tennotoil HcnapeHHH H CKpbITOR TellJIOTOR nimanemoi,
3J1eKTp011p0BOAHOCTb10, AH3.nexTpHnecxofi HOCTORHHOR, KpHTHTleCKHMH TeMllepaTypaMH, AaH-
..neHHem H IIJIOTHOCTb10, a TaK)Ke CHOCO6HOCTIA0 AaHaTb a3eoTponHble cxecH.
OCHOBHy10 nacTb moHorpactmu cocTaanHeT onHcaftHe CBOC1CTB pacTsopHTexeil, pacno.no-
AMH11131X B KHHre B aJKIMBIITHOM nope (370 cTp.); 3aTem HxyT I1pHJ10)KeHH11 (48 cTp.).
Kpome Toro, nmeeTcH 6o.nbulaH Ta6aHna c yxa3aHHem oTHolueHHH paCTBOpHTeJIef K npo-
MIAIllneHHIIM oftexTam, KaK, HanpHmep, p83J11111HUM COTM Haynyxa, naacTexithy, napa-
CPHHaM H T. x. B npeitHcaoHHH asTop OTMeTlaeT, TITO H3AaHHe 3T0 KH11111 Bbl3BaHO pacTymeR
noTpe6HocTmo B pacTHopHTeanx OTAe.111:41b1X oTpacneA xHmHtiecxoff 11p0MbillIneHHOCTH, 6ypHo
pa3BHBa10111,HX01 3a nocnexHee jt eCoTHJIeTHe.
OTCyTCTBHe He06X0AHMbIX crtexeHHA 3aCTaBH.TIO aBTOpa CO6paTb maTepnaz Hcxoxsi 03
.1.1)H311TleCKHX CBOACTB IIpHBO,IIHMEJX B moHorpailmm pacTHopHTeneti.
B KHIlre co6paHbi cHtztemin o 220 neukecTuax, ABJ1f11011.(HXCH HJIH HHAHHHxya.nbtthimm
XHMHTleCKHMH C0eAHHeHliSIMH, HJIH cmecHmil pacTsopHTenefi npombnuaeHHoro 3HaTleHHH, KaK,
HanpHmep, pacTHopHTe.nb KaymyKa (cTp. 326), uenan CepHfl paCTB0pHTelIen, HMe10111,11X onpe-
,4e.neHHEae ToproHme mapxH.
? CrioAcTua pacTHopHTexeil 03J10)KeHb1 no exHHomy nnaHy, HO ec.71H HemecTso HmeeT npaxTH-
necxoe 3HaneHHe, 0 HHX r0B0pHTCH 3HaTIHTeJlbH0 noxpo6Hee. ECJIH CpaBHHTb aneTaxb?pac-
TBOpHTeJlb, ABJIS1101.11,HACH a3eoTponHotk emend() ,a113THJIaLleTaJISI H 9TaH0JIa .I1 60Jlee aKTHBHbIM
pacTHopHTenem, nem itaxoloe H3 COCTa3./15110111,HX HHAHBH,/lyaJlbHbIX HenkecTH, c aueToHom, TO
/1.1151 IlepB0r0 paCTB0pHTeJ151 B xanecTse 1:13113HTleCKHX xapaxTepHcnix HHTepHan Temnepa-
Typta AAR 11eper0HKH, TOTIKa rfaaHaeHHH, 'yxeabHmA sec H onpexexeHHe KHCJIOTHOCTH; AAA
aneToHa npmEtoxsiTcH AaHume no seem 0:1>1311,1eCKHM XapaKTepHCTHKaM, yrIOMRHyTbIM Bb1111e,
a TaX)Ke Ta6J1(11.111 ylleJIbHbIX BeCOB B HHTepsane OT 0 AO 50?, tiepe3 5?, yxeabHux Hecou cmecH
Boxa?EineT0H (10.--100/0 alIeT0Ha), YnPYrOCTH IlapOB OT--94,8 ,Ito 56,2?, Ba3KOCTH aueToHa
o ero cmecell c Bojo; xpanco roHopHTcH o npoH3BoAcTHe H a3e0Tp011HbIX CMeCSIX Ana ABOAHIAX
H TpoliHmx cmecell c psixom pacTHopliTenort. Kpome Toro, npHHeAeHbi cHe.xeHHH 0 4011300/10r11-
tiecKom AefiCTBHH, onpe,xeneHHH au,eToHa B Ho3Ayxe, o6 yCJI0BHAX XpaHeHHA, a TaxxeCIIHCOK
npommumeanmx npeAnpHHTHil. TaKHe )Ke noitpo6mue AaHHbIe yxa3aHm H AJISI pH,Lia Apyria
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
KPHTHKA H BHBAHOTPACDHH 207
pacTaopwreneli, Hanpmmep Ansi 6eH30/1a, TOJIYOJIa, LumnoreKcatioHa H ItHK.noreKcanona, 9TH?
zonoro 34mpa, cntipTa, 9TH/IeHTJIHKOJIH, meTnnonoro cimpTa H ap. KaK yam OTMeMaJI0Cb,
pacTHopwrenH pacnoncoKeHm no ampaaHTy 6e3 C06/I10,t(eHHH KJIaCCOB H rpynn coemuieHH11.
B moHorpa4mH npimoawrcii TIOBO/IbH0 mHoro pacTsopwreneti, Hmeionoix onpeaenenHylo Top?
rorsylo mapKy, 0 cocTase KOTOpbIX HeT n0apo6Hbtx cHeAeHHR; 9T0 OTHOCHTCH K rpynne pacTao-
pHTeneA CSo/tro/s), npHmeH.Hembtx B pe3HHOB0A 11p0MbIIIIJIeHHOCTII, K pacTtiopHTeasim mapoK
((Loboso/sy, npeacTaHnsnowiix cmecb KeTOHOH, 34mpos H CIIHPTOB H JP.
B IlpH/10)KeHHH 1 Aatta XHMIPleCKaSI KJIaCCHCPHKaIIHSI pacraopwreneil, KoTopme aBTOp
noapa3AenKer Ha rpynribt: yrneaoAopoAon (a.mpannecKoro, ap0MaTIPleCKOTO !Dula H Ilapa?
44/11HOB), x.nopconepacaukkix yraeBoaoponois, CIIHPTOB (01uI0? H MHOTOaTOMHEIX), 94/Hp0B npo-
,CTbIX H CJIO&HbIX, acimpors raHKoneA, KeTOHOB, anbiAermloa H rerepOPHKJIMOCKIIX pacraopH-
Tula. Ana KaiKnoA rpyrinbi pacTaopHTenea KpaTKo 011HCblBalOTCH XHMH4eCKHe CBOACTBa.
B IlpH/ICOKeHHH 2 Ann. caeAeHHH o 3HageHHH cKopocTH HcnapeHHH pacraopurenell
C ymeTom BAHHHHH Ha 9TOT npouecc psuta 4mKTop0a, HanpHmep CKpbITOA Ten/WTI:al Hcna-
penHa H B TIPHJIONSeHHAX 3-6 01-1HCaHll yCJI0BH5T 06SeMHOTO onpenenernia 94:1Hp0B, BO-
AopacTBopHmbix H HepacTaopHmbix B Boae anbaerHAoa H KeTOHOB H onpeaeneHHH cao6oanbix
alIbAeTHAOB B aueTanax. B npH.TIONCOHMIX 7-10 ripHae,4eHbi "Ta6nHabi nepeaoAa TemnepaTypu
B rpanycm 1.1,enbcHK, Ta6nHubt YAejlboHbIX BeCOB, 13/13KOCTH, CpairropoB nepecgeTa pa3/IH'IHbIX
eAHHHIR H3mepeHHa B TIPHHHTbIX meacayHapoatibix o6o3HageHHHx.
B OCTa/IbHbIX IIPH/10)KeHHHX yKa3aHa TOKCHIIHOCTb pacTaopHTeneff onpe,aeneHHE nepe-
KHcell B 3(1)Hpax H BOAbl meToAom 043Huiepa, pacumcppoisanbi ToproBbie mapKH psiaa pacTao-
pwreneri.
KaK SHAH? H3 0630pa, moHorpacimst coAepacHT ormcaHHe crioAcTa paciaopHTena?Knacca
COeAHHeHHA, 0,IeHb Ba)KHOTO KaK AIM crraenbHbIX orpacneff IIPOMbIWJleHHOCTH, TaK H A.1151.na6o-
paTopHoA IlpaKTHKH npH peweHHH Bortpocoa onpeneneunsi H pa3aeneinia 9/1eMeHTOB.
B. Iletuicooa.
9HIANKJ1011EA1151XHMHqECKOcI TEXH041.014114. TOM 12 N 13 ?
ENCYCLOPEDIA OF CHEMICAL TECHNOLOGY
Ed. by R. E. Kirk and D. F.-Othmer
Vol. 12?Sabadine to Stilbestrol
Vol. 13?Stilbite to thermochemistry
New York, The interscience encyclopedia, 1954, Vol. 12-955 p. Vol. 13-952 p.,
PeueH3Hpyemax 3HuHKnoneami, abixonawaa no peAaKumeti KlipKa H Ocmepa, HBJIHeTCH
eAHHCTBeHHbIM cospemeHHum 3apy6eambim CTI.PaBOTIHHKOM no XHMHtleCK014 TeXHOJIOTHH1).
HO CyLlIeCTBy oHa ripencTaHnaeT co6oil c6opHHK He6onbumx moHorpacimil (no 70 a 6onee
crpaHnu Kaacaaa) no pa3JIHMHbIM orpacaHm XHMIPleCKOR TeXHOJIOTHH HJIH CMe/KlIbIX C HCII ANC-
aHIIJIHH ?npoueccam H annapaTam XHMIltleCKHX Hp0H3BOACTB, KOHTp0/113110-H3MepHTeJlb140A
TeXHHKe, maTepHanoae,ReHmo XkIMIIIIeCKHX riponyKToa HJIH npoAywroa, noaHepratoumxca
B ripouecce npoH3BoAcTaa XHMIlileCKOR o6pa6oTxe (HanpHmep, orxonam XHMH,IeCKOA
np0M1a1111J1OHHOCTH (HallpHMeP, CTO,MbIe BO)bl) H MHOTHM A pynim.
ABTOpbI H36eratoT KpaTKHX oflHCaHHl, OTC131.11aH YHTaTe/I51 K 60.11bllIHM CTaTbHM: Hanpm-
mep, ?TayTomepH51?cm. H3oMepHa a.n a CynbcpaHH.namHA?cm. CyabcpamHAHue cpapmaues-
TinecKne npenapaTbiy. 063opHbie CTaTbH, TIOCBSIIIkeHHble rpyrinam XHMIPleCKHX He1IecT3,
Hanpiimep ?Granby. (cTp. 793-843), 6CH/IHKaTbl* (cTp. 268-360). ?Coe,rumeHHK Ha-THAI
(CTP. 599-613), ((GOA HKOHbl) (CTP. 360-413), ?OniponbHble CMOJIbl) (119-117), fAHT14-
5HOTHKH cTpeirrommieToay (cTp. 271-285), cTeprieHbly (cTp. 706-711), aPacraopkiTenHt
(cTp. 655-686) ripeAcTaansnoT co6oil KpaTKHe moHorpapHH, paCCMHTBHHiale Ha HOATOTOBJlen-
Horo MHTaTeJIH. flepeAKO B CTaTbSIX BewecTaa 0613eJAHHHIOTCH B rpyriribi no ripH3HaKy OAHHa-
KOBOTO HCII0.11,30BaHHH, a He noKJIaCCy aewecTa 11.7111 COCTaBy, Hanprimep B CTaTbSIX C110BepX-
HOCTHO-aKTHBHble sewecusay, cTOKCTILTIblible. BO/IOKHa), 4PacTnopirre.r11Th, ?,r11.1MbID 11 T. A .
1) PeneH3Hio Ha 11 TOM 4011a14KJIOTICAHH XHMIPleCKOR TeXHO/10THH CM. CHosie KHHTH
3a py6eiKom*, N9 9 (78), 1954.?17pum. pea.
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
208 KAPITHKA FL HI4H.TimOrPA01,151
CTaTb14 113.7101140Hbl Ha Bb1COKOM HayTIHOM ypowie. 4HTaTeJlb 3HaK0MHTCA He TO.TIIIKO.
C cyutecTsom Honpoca, HO H C 110C.Tle,71HHMH AOCTIMeHHSIMI4, Hmeionomm npaHTHtieckoe sHane-
rule, npHnem maTepHaa vepnaeTcH He T0JIbK0 143 HosetimHx Haynbix cTaTeA, opHrHHa.nbHbtx
/11111 0630pHblX, HO 14 143 IlaTeHTOB. HanpHmep, B cTaTbe gX11M111111011BbD) (T. 12, cTp. 614-633)
coo6ukaeTcH 0 HaweAmllx C HeAamiero HpemeHH npHmeHeHHe C1IHTeTH.4eCKHX HewecTsax, KOH-
Amitioamppoutax nonHy (?KpHnHym?), H 0614X BJIHRHH11 Ha 110,1BeHHbIl1 KOMI1J1eKC.
143 CTaTbH IXPaCTB0pHTeJIHX. (T. 12, cTp. 654-685) LIVITaTeJlb y3HaeT o Tpe6oHaHHHx, npeAl-
HBAHeMbIX K 9THM HeatecTsam, a 113 Ta6J1H11,b1-0 CBOfiCTBaX cospemeHHbix pacTsopuTe.neri,
B TOM MI4CJIe H HeflasHo BO1HJUllHX B npaxTHHy.
CTaTbH 3TOTO THIIa xopomo H.11.1110CTpHp0BaHb1 AHarpammamm, cxemamil npoH3HoncTsa
H ApytHMH PHCyHKaMH. HMeeTCS1 MHOTO Ta6aHu, Hecbma yAamHo COCTaBJ1e1111b1X. HaKOHe11,.
OaeHb xopowo HocnpoH3HeAeHb1 XHMHMeCKHe cpopmyabi, B TOM tiac.rie cTpyHTypHbie (HanpHmep,
B cTaTbe (Yr.neHoAbt?), H pHCyHKH cTepeoxllmfinecimx mo,Henell.
HaH6oHee Hambim Hemecnsam TIOCBMIllseHbI OTANIbHble CTaTbH, HanpHmep B 13 Tome
?CepHain HHcaoTa? (cTp. 458-501), ?Ce.neH?, ?TaHTaa?, ?Te.n.nyp?, ?Kpaxmaz?, ?Cepe6po?,
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HcerAa npHERNAHTcH onHcaHHH C1100060B Hp0143BOACTBa. Ho npH 3TOM HepeAKO aBTOpb1 Orpa-
1111MHBalOTCH it)opmaabHum onHcaHHem H He IlplIBOASIT Heo6xQaHmbix AJI51 yfICHeHHH Honpoca
pilcyHHos. HanpHmep, B cTaTbe ?CepHaH KHCJI0Ta)) plICyFIKH H.TIH cxembl nee il (Hpome negH
ii 11b1J1eB1L1HOPO Cb1P141) OTCyTCTB)TIOT, a oruicaHHe He ,HaeT HcHoro npeAcTameHHH 0 npHme-
HHemok annapaType. B aToR cTaTbe aBTOpb1 OCTaH3BJIHBalOTCS1 Ha ycTapemnem HamepHom
cnoco6e I1p0H3BOACTBa cepHoik KHC.TIOTbI, a 3HatIHTeTIBH0.6o.nee Ba/K1ibIti 6ameHmuil cnoco6
OIIHCb1BaIOT 6erno H HeTOMHO. IlpH paccmoTpeHHH pa3J1H9HbIX 11p0113BOACTBeHHMX npou,eccoH
aBTOpbI y,He.nsnoT Aa.neHo He BcerAa AOCTaT0,1H0e BHHMaHHe CPH3HKO-XHMHtleCKHM HJIH KOJIJI0H-
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Xl4M1451
1. Charlot G. et Bezier D. Methodes electrochimiques d'analyse.
Paris, Masson, 1954, 96 p.
2. Chemical engineering instruments and control methods. (Chemical and engineering ser.)
Ed. by E. Molloy and E. Carr.
London, Names 1954, 182 p.
3. Glaser H. u a. Chemische Technologie des Holzes.
M?nchen, Hanser, 1954, 156 S.
4. Hopkins D. W. Physical chemistry and metal extraction.
London, Miller, 1954, 232 p.
5. L u x H. Anorganisch-chemische experimentierkunst.
Leipzig, Barth, 1954, 651 S.
6. Martin J. H. and Morgans W. M. Guide to pigments and to varnish lasquer
constituents.
London, Hill, 1954, 127 p.
7. Modern aspects of electrochemistry. Ed. by 0. M. Bockri s.
London, Butterworth, 1954, 344 p.
8. Quolitative Schnellanalyse. Zusammengestellt nach den Arbeiten von G. Chariot u. a.
Berlin, Gruyter, 1954, 82 S.
9. Sicherheit im Chemiebetrieb. Ein Handbuch der Betriebsgefahren in der chemischen
Industrie und ihre Verhiitung. Hrsg. von Gugge r.
Dusseldorf, Econ. Verlag, 1954, 507 S.
10. Sp ea km an J. C. An introduction to elektronic theory of valency.
London, Arnold, 1955, 180 p.
11. Standard methods for the analysis of oils and fats. Methodes unifiees pour l'analyse des
matieres grasses.
Paris, Ed. enseignement superieur, 1954, 117 p.
12. Staudinger H. Ober die makromolekulare Chemie. 2-te verb. Aufl.
Freiburg, Schulz, 1954, 32 S.
13. Wa Ilan d H. Einfiihrung in die quantitativen textilchemischen Untersuchungen. Ein
Lehr- und Hilfsbuch filr textiltechnische Lehranstalten und ffir die Praxis. 2. v011ig neu
beard. und erw. Aufl.
Stuttgart, Kohlhammer, 1953, 336 S.
14. Wolf L. Theoretische Chemie. Eine Einfiihrung vom Standpunkt einer gestalthaften
Atomlehre. 3-te umgearb. Aufl.
Leipzig, Barth, 1954,742 S.
14 XHI41151, M.
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A. 14. ,Ltatniaos H B. 10. Op.nort.
No 7
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
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Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
(433) 49
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(439) 55
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App-roved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
12. C. H. B a te s, L. D.,M a r t 1n, Agriculture, 19, 231 (1935);
D. II. Findla y, E. T. Syke s, Agriculture, 244, 546
(1937); K. V. F er no w, 0. Smi t h, Ext. Bull. Cor-
ml Agric. Exp. Sta., N12 653 (1944); G. S a mue 1, Agri-
culture, 5, 277 (1941).
13. M. G. II a y ma n, Am. Potato J., 21, 110 (1947).
14. A. R. W i Is o n, A. E. W. B o y d, Agriculture, 54, 201
(1917).
IS. A. M. Bi nk le y, Am. Potato J., 25. 371 (1948). F. Mc
? o 1 (1 r i c k, 0. Smi t h, Proc. Am. Soc. Hort. Sci.,
51, 401 (1948); A. E. R i c h, Am. Potato J., 27, 87 (1950).
1(1. A. E. W. B o y d, Scot. Agric., 1952, 204.
17. C.E.Cunni gham,P.N.Eastman,M.Goven,
Am. Potato J., 20, 8 (1952).
18. C. R. Sk o gle v, Am. Potato J., 90, 140 (1953).
19. F. fl o I me s, Power Farmer, 9, Ms 2, 73 (1952).
20. G. S. Co op e r, \V. G. Co r n s, Scientific Agric., 32, 281
(1952).
91. W. G. Co r n s, G. S. Coo p e r, Scientific Agric., 31,
269 (1951).
22. W. G. Co r n s, Univ. Alberta Dept. of Extension Press
? .1\119 1 (1952).
23. Tidsskr. Plan tenvl , 511, 1\112 1, 147 (1952); Tidsskr. Fravl,
20, N1) 21, 374 (1952); V. P ou Is e n, Dansk Fray!, 34,
.1\fr2 2, 15 (1951).
21. D. F le min g, What is new in crops and soils, 5, Ns 7, 23
(1952).
25. H. Velds tr a, Annual Rev. of Plant Physiol., 4, 151-
198 (1953).
26. P. W. Zimmerman, W. Crocker, A. E. Hitch-
c o c k. Con trib. Boyce Thomps Inst., 5, 195 (1935).
27. P. \V. Zimmerman. A.E.Ilitchcock,W.Cro-
c k e r, Contrib. Boyce Thumps. Inst., '', 459-81 (1931).
28. C. L. Wor le y, R. C. Gr o ga ii, J. Tenn. Acad. Sci.,
16, 326(1941); H. \V. Hruschka, J. Kaufman,
Proc. Am. Soc. Hort. Sci., 54, 438 (1919); C. D. La R u e,
Proc. Nat. Acad. Sci., 99, 254 (1936).
29. A. M. S. Pr id 11 a m, Northeast States We:d Control Conf.,
1953, 341.
30. J. Mi 1 h r a (Ii. H. H a r tma n, Science. 92, 401 (1940);
C. R. M. AI me id a, Olearia, 3, 21 (1919).
31. W. C. St e war t. W. Ehelin g, Bot. Gaz., 108, 286.
32. W. C. Fl a 11, Southern Seedruan, ,N9 6, 42 (1954).
33.R. L. Weintraub, J. W. Brown. Nickerson,
Tavlo r. Bot Gaz., 119, 348 (1952).
'34.A. Whiting, Geraldine, Murry, Amari,
But. Gaz , 109, 447 (194').
'35. J.Overbeck, R. Blondeau,V. Horne, Am.J.
But., '')3, 789 (1951).
' 36 J. Alric. Fool Chem., 9, Nr9 6, 293 (1954).
37. W. C. 11 a 1 1. G. B. Tr a c h el u t. U. C. L a u e, Texas
? Exnl. Bull., N's 759. '3-24 (1953).
.38. G. L iv i n gs to n, Plant Physiol., 95, 711 (1950).
F39. (-1 a w a d i, G. A v er v, Am. J. But.. 97, 172 (1950).
40. W. C. H a 11, But. Gaz., 119, 340 (1952).
41. W. C. H a 1 1. Plant Physiol., 9g, V. 4 (1952).
42. ANI. nar. 2368274, C. A., 39, 4428 (1945).
r43. A. CI i f for d, C. A. H a mp e 1, Chem. Eng.
News, 97, 94211 (1949).
44. Am. nar. 2368275, C. A., 39, 4428 (1945).
45. L. C. B r o w n. Proc. 8-th Cotton Defoliation Conf., 1954,
37: W. c. H a 1 I, S. P. Joh nso n, Proc. 8-th Cotton
Defoliation Conf., 1954. 45.
46. Sc he I 9 1. Deutsche 7. Cies. gericht. Med., 40, 134 (1051).
47. N. Pe ter s. Nachricht f. deutsch. Pflanzenschutzdienst,
'19, 16 (1952).
48. P. NI nch ber g, Naturwiss. Rundschau, 7, Na 10, 423
(1951).
49. J. D. Stone, L. M. Smith, Agr. Chemicals, 9, Na 5,
50, (954).
50. R.O.Thomas,W.F.Buchell,J.M.Jackson,
Ark Ar. Exp. Rept. Ser. Ma 27, 3-21 (1951); C. A., 46,
11559 (1052).
51. Comm. Feriil ? 1953, 87. 1\19 2, 58.
52. Agr. Chemicals, 6, Na 8, 59 (1951).
53. Him naT. 48566, Pell). >K. XIIMIAB, ,N9 12, 31180 (1954)
E4. A crpaa. nar. 158285 (1954)
55. A. G. As h, E. H. C a r r, Agr. Chemicals, 8, N9 7, 42, 107
(1953).
56. J. Agric. Food Chem., 2, .7\12 11, 538 (1954).
57. A. W4ch te r, J. prakt Chem., .0, 325 (11113).
58. E.R.De Ong,H.Knight,J.C.('hamberlin,
Hilgar ia, 2, 351--384 (1927); N. S. S te w a r 4,
W. E b el i n g, Bot. Gaz., .08, 286-294 (1916).
59. Am. nar. 2599827, Chem. Z., 121, 9608 (1953).
60. A. M. S. Pr id h m, R. II s u, Proc. Northeast M evil
Control. Coif., 221 (1954); C. A., 8, 11087 (1954).
61. E.Ii. Fischer, A. J. Ricker,T.0 Allen,
Phyto-
path., 26, 504-523 (1946).
62. J. Skoo k, Bot. Gaz.,. 01 486 (1945).
63. AM. nar. 2416259, C. A., ;2, 3902 (1948)
64. Agr. Chemicals, 8, Ms 9, 93 (1953).
65. 3an.-re-m. nal-. 888701, Chem. Z., 1953, 9635.
66. L. B. Sing h, J. Hort. Science, 24, 159 (1918).
67. Fert I. Feedingstuff, 37, 310 (1951).
68. Agr. Chemicals, 9, M2 7, 52 (1954).
69. D. C. McLachlan, L. T. R fel) a rds() 11, Am. Po-
tato J., 28, 687 (1951).
70. P. Poi gn a n t, Compt. rend., 2:19, 822 (1954).
71. P. Po ignan t, Compt. rend., 2 9, 1408 (1954).
72. Am. nar. 2649364, C. A., 47, 12746 (1953).
73. Am. nar. 2649365, C. A., 47, 12746 (1953).
74.P. W. Zi mmer ma n, A. E. Hitchcock. Proc.
Northeast Weed Control. Conf., 1951, 231.
75. J. Agric. Food. Chem., 3, N9 1, 75 (1955).
76.J. Overbeck, R. Blondeau, W. hone,
J. Bot., 32, Ma 3, 205 (1955).
77. F. Go 1 ds tei n, Federation Proc., 11, ,N9 1, 1, 349 (1951).
78. S. E. Srense k, \V. D. II ark nes s, G. Woodar
Federation Proc., 11, .N12 1, 1, 302 (1952).
79. Agr. Chem1cals, 7, .1\79 7, 6 (1952).
80. J. L. P o 1 a n d, Mimeo Report Niagara Chem. Div. Food
Machinery and Chem. Corp. Middeport N. Y., 1951.
81.N. Tischler, G. P. Quimba, W.M. Bejuk
Proc. Northeast Weed Control Conf., 1951, 35-14.
83. H. C. L a n e, W. C. H a 11, Science, 1'6, 427 (1952).
83. Am. nal'. 2637642, C. A., 47, 7730 (1953).
84. A. M. S. Prid h a m, R. H s u, Proc. Northeast Weed Con-
trol Conf , 1954, 219.
85. Am. nar. 2576080 (1951).
86. 0. Dtel s, S. 0 ls e n, J. prakt. Chem., (2), 156, 285
(1940).
87. 0. Di el s, K. Alde r, Ber., 62, 554 (1929).
88. Am. nal. 2550494 '195(0
89. A. Illnapu, FIeppu, 11013epXHOCTIMaKTI1BHble
BentecTaa, H. II., M., 1953.
90. Am. nar. 2654667, C.A., 18, 1621 (1954).
91. ANT. nar. 2664442, C. A., 48, 3384 (1954).
99. Am. nal-. 2634201, C. A., 47, 7152 (1953).
93. Am. nal.. 2637646, C. A., 47, 77 6 (1953).
94. Am. nal'. 2637647, C. A., 47, 7726 (1953).
95. Am. nar. '368601, C. A., :19, 5392 (1945).
96. Am. nar. 2678826, C. A., 48, 2314 (1954); Kauazt. nar. 504102
97. E. H of ma n n, A. A mb er ger, A. Suss, Naturwiss
11, 481 (1954).
98. H. D. K u n z, Pflanzenpath. und Pflanzenschutz, 61, No Ill.
481 (1954).
99. A. Per ret, Kr a wez insk i, Helv. Chim. Acta, :5.
1009 (1932).
100. K. S a k uz a w a, M. Hand a, R. H a r a, J. Soc. Chern
Ind. Japan, 37, 701B (1934).
101. G. Grub e, G. M a t z, Z. phys. Chem., 118, 145 (1926)
102. J one s, Science, 120, 499 (1954).
103. Am. nar. 2668758, C. A., 48, 6642 (1954).
104. Am. nal-. 2687348, C. A., 49, 2668 (1955).
105. Am. nar. 2657988, C. A., 44, 2313 (1954).
106. Am. nar. 2670282, C. A., 44, 6642 (1954).
107. L. C. Bmown, H. A. H ye r, Agron. J., 46, 580 (1954)
Approved For Release 2007/11/05: CIA-RDP83-00418R004500120001-7
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