SCIENTIFIC ABSTRACT GORBANESCU, GHEORGHE - GORBANEVA-TIMOFEYEVA, L.V.

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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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GORBANESOU, Gheorghe
"Comic alectrodynamics* by Dzh. Danzhy (Dungey, J.W.]. Reviewed
by Gheorghe Gorbanescu. Studii fiz tehn Iasi 13 no.2:303-304
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GOEBANEV, A. 1.
Gorbanev, A. I. - "The 25th anniverzary of the Ukrainian
State Institute for Applied Chemistry, of the All-Union
Institute of the Soda Industry W23-191M, Trudy Vsesoyuz.
in-ta sodovoy promsti, Vol.
V, 19,01, P- 5-
SO: U-4'3i, 1" Sept- 53, (Letopis IZhurnal In 24, 101.,q
0 0 y1ch Statay, Nio.

GORBAIR-EV, A. I
Gorbanev, A. 1. and Ginzburv, D. M. - "Direct transfol-riation
of soda into sodii= hydroxiac by the action of water vapor",
Tru V30307uz, in-ta sodovoy prom-si-J, Vol. VP YI;h9, p.
229-12, - Bibliog: 12 items,
SO: U-4631, 16 SePt- 53,,(LetopIs 'Zhurnal Invkh Statey, No. 2h,

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KgSSIJCR, Yu.M.;.GORBAIW A.10
Heat of dilution of the solutlons of alknii metal chlorides In
concentrated hidrogen peroxide. Report No.l. Izv.vost.fil.All
SSSR no.4/5:75-89 157. (MLRA 11j: 9)
1. Institut obahchey I neorganicheekoy khimii iment N.S.Vurnmkovs.
(Heat 4 voluttort) (Alkalit metal chlorides) (Hydrogen peroxide)
(Blectrolysis)

S 1 v
I
MS LER Yn.Iz.,.j--gO: .1.
Heat of dilution of the of alkali metal chlorides in
concentrated h,,TC',,rGPan 1twoort No.2. Izv.vost.fll.AN SSSR
no.6:50-6J 157- (MMA 10:9)~
1 Inntitut obahchey i neorganicheskoy khimii imeni N.S.Kurnakove.
(Heat of O~Jeotralysla/ (Hydrogen peroxide)

AUTHOR: None given
-TINZ: Presidium of the AN USSR. On the Acitivities of 30-8-107
the Dagestan Branch of the Aff USSR (T presidiums Akadexii
nauk.SSSR. 0 deyatellnosti Dagestanskogo Filiala)
PERIODICAL: Vestnik Akaaeudi Nauk SSSR, 1957, Vol. 27, Nr 8, pp. 80-81 (USSR)
ABSTRACT: The president of the academy received a report by Kh.I.Amirkha-
nov, member of the Azerbaydzbon bxwch )f the AN USSR (as well
as a report by A.I.Gorbanev. Doctor of Technical Sciences, which
is connected AIR-Uh-e-Hr-st-mentioned report). The Dagestan
Branch obtained remarkable successes during the last 3 years.
The research results obtained have already been utilized by
various plants of the Azerbaydrhin rePA-1c., Thanks to the work
carried out by the research institute for geology it was pos-
sible to disnover new mineral oil deposits in the autonomous
Checheno-1Wxhs1qa ASSR- 30 that mineral oil production
will be increase-a considerably in this autonomous republic.
In spite of the successes obtained by this branch, there are
still some deficiencies which prevent full development of the
already obtained scientific successes. Measures have been
Card 1/2
Nor-_
AVAILABLE:
Card 2/2
30-8-14/37
On the Activities of the Dagestan Branch of the AN USSR
taken to eliminate these deficiencies.
Library of Congress

Abs Jour Ref Zhur Kilimiya, No 1, 1958, 148
indicates the anisotropy of the r-factor. Consequently,
the absorption may be attributed to the free radical H02,
the presence of vhich has been postulated previously,
or the OH, vhich is less probable, because the latter
could hardly be preserved in a trap even at 770K due to
its high reaction capacity.
Card 2/2

AbTHORS; Kessler, Yu. M., Gorbqney, A. I. 20-3-W/52
Deviations of the Thermodynamical Properties of the
TITLE:
SoXutions of Strong Bleotrolytes from the Limit Law in the
Debye Range of Concentrations (0b otkloneniyakh
termodinamicheskikh avoystv rastvorov sillnykh elektrolitov
ot predellnogo zakona v Debayevskoy oblasti kontsentratsiy).
PERIODICAL: Doklady AN SISR , 1957, Vol. 117, Nr 3, PP- 437-440 (USSR)
ABSTRACT: Pirst, some previous works dealing with the same subject are
discussed. The authors determined the integral solution
beats A'% of Nacl, M, RbC1 and CsCl in H 202 at 00 by means
of an ice calorimeter. The difference between the signs of
the experimental and the theoretical valuesAW and AW D
begins to manifeetitself in the case of H 20 at
much lower concentrations then in the case of H 20. Taking
account of the dependence D - f(c) (where c denotes
concentration in mol/1), of the repeated collisions, of the
eigenvolume of the ions, of the modification of the distance
a of the extreme approximation of ions in the case of a
change of temperature, etc. cannot explain the occurrence
Card 1/3 of the positive solution heats in the Debye (Debaye) range
z

Deviations of the Thermodynaipical Properties of the A.0-3,49/52
Solutions of Strong Electrolytes from the Limit Law in the
Debye Range of Concentrations
of concentrations. '2he only,possible causes are the pro-
Auction of ion pairs and the dependence of the structure
of the solution on concentration. The solution energy A G
connected with:the production of ion pairs can be
determined in the most general form on the basis of the
theory of the "specific interaction" of ions developed by
J. N. BrOnsted (Ref-7), and E. k. Guggenheim (Ref. 8). The
authors consider the specific interaction of ions to be
the result of their approximation to the distance r ij~ ai+a
where a and a are the radii of the solvation
domains of the ions. The course taken by the computation
according to the two above theories is described in short.
The satisfactory agreement between theory and experiment
extends as far as o - 0.025, 1. e. up to the boundary of
the Debye range. In order to carry out such a comparison,
corresponding cociputations were carried out on the basis
of published data for NaCl in ethylene glycol
NaC , NaBr and KaJ in formaldehyde and KC1 in H 20. In
aquious solutions agreement between theoretical and
Card 2/3 experimental values extend Ia from & W to the highest

Deviations of the Thermodynamical Properties of the 20-3-22/52
Solutions of Strong Electrolytes from the Limit Law in the
Debys Range of Concentrations
concentration a >0,1, but in the case of solutions in
H20 a agreement extends along the smallest range. With
a gi,!n"ooncentration the greatest difference between
theoretical and experimental values of A W is found in the
came of solutions in H202' The smallest difference is found
in H20. Ethylene glycol and formic amid take up a middle
position. The modification of the structure of aqueous
solutions with a okange of concentration is probably small
in spherical ions at least up to o - 0.1. There are I
figure, I tablet and 24 references, 9 of which are Slavic.
ASSOCIATION: Institute for General and Ihorganic Chemistry imeni
F. S. Kurnakov AN USSR (Institut obehohey i neorganicheskoy
khimii im. N. S. Xurnakova Akademii nauk SSSR).
PRESENTED: April 27, 19570 by I. I. Chernyayevq loademician
SUBMITTED: April 23p 1957
AVAILABLE: Library of Congress
Card 3/3

GORBOIVS A.I.- TSINTSIPMR, A.B.; ZRITIMMA, P.M.; DOILOVA, K.S,
ReIaction of dissociated vapors of R202 at a temperature of -1960C.
Isvo 3.1b. otdo' All SM no.5t43.-52 058. (MIRA 11t9)
41netitut obahchey I neorganicheskoy khiall in. NA. lurnakova
AN SSSR.
(Hydrogen peroxide) (Ileetric discharges'Ahrough gages)

AUTHORS: Kessler, Yu. M. Go anev, A. 1. SOV/62-58-8-17/22
TITLE: Notes on the Glauberman and Yukhnovskiy Equation (Zamechaniye
k uravneniyu Glaubermana i Yukhnovskogo)
PERIODICAL; Izvestiya Akademii nauk SSSRj Otdeleniye khimicheskikh tauk,
Nr 8, pp. 1010-1011 (USSR)
ABSTRACT: In this short report the.correction of an inaccuracy in the
Glaubermanand Yukhnovskiy equation for the electrostatic part
of the free energy of the electrolyte solution is dealt with.
This equation reads as follows:
2 2 3 2
F (T 2D')r 2 (B 2P X T),
e 0 E
where B is equal to
X C -1)3 + (x 5 (x,-2 )4x
.9 (11 1) + yo (xl-2) +
3
x I + 2PX + 11
P is the parameter of the theory denoting the mean diameter of
the ions, Otherwise the notation is as usual. In employing this
Card 1 /2 equation for deluermining the heat of dilution AW it turned out

SOV/62-58-8-17/22
Notes on the Glauberman and Yukhnovskiy Equation
that&w(,) is equal to -ooa+ X -0. The authors conclude that
the equation.7 -(T/2D -f-oiz2 E 2 (B/2p3 AT) leads to the
e 0
uneertain f-3x-mAW,,) - 0/0 (atX- 0). This indetmAnacy was
investigated by the authors. It was found that,lim,&W 0
at)(-~O. Therefore the equation given by the authors may be
assumed to beloorrect. The equation for AW(,) sufficiently
describes the.experimental data for aqueous 1 1 eleotrolyte
solutions at :2500-and P--;,4A as well as ap/aT-5-10-4 A/degiee.
There is I referencs,.1 of which is Soviet.
ASSOCIATION: Institut.obshchey i neorganioheskoy khimii im..No So Xurnakova
Akademii nauk SSSR (Institute of General and Inorganic Chemistry
imeni No So KurnakovAS USSR)
SUBMITTED:~ March
,79 1958
Card 2/2.

I i ,

5-4600
AUTHORS:
TITLE:
PERIODICAL:
ABSTRACT:
Card 1/3
77064
sov/62-59-12-8/43
'Kessler, Yu. M., Gorbanev..~
A Comment on the Theory of Solutions of Strong
Electrolytes
Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh
nauk., 1959, Nr 12, pp 2116-2118 (USSR)
The authors list all the corrections of the Debye-
Wilckel theory made by various authors (with a list of
literature references). The fact that parameters a
(averap effective ionic diameter) and h (hydration
number) vary.in equations obtained by different at~_thors,
and that equations for AW (heat of dilution) and L 2
,(r*elative partial molar heat capacity), derived by
Wicke and tigen (E. Wicke, M. Eigen, Naturwissenschaften,
38, 453 (1951); 39, 545 (1952); Z. Electrochem., 56
551 (1952):. and Robinson and Stokes (R. A. Robinson,
R. Stoke's, Ann. N. Y. Acad. Sci., 51, 593 (1949)) on
the basis of the Deby'e-HlAckel theory, do not de.scribe

A Corhment on the Theory of Solutions of 7 TC-6 4
Strong Electrolytes sov/62-59-12-8/43
experimental conditions accurately (unless a tempera.-
ture dependence of a and h is assumed), suggest that
additionalcorrections are needed. The assumption
that da >0 and dh >0, that would adjust the
_T'T_
theoretical values of AW and L21 contradicts experi-
mental evidence. The authors conclude that in order
toIexpla.In experimental deviations of the data on
6W and L2 frcmtheDeby'e-Huckel thewcay, it is necessary
to consider the existence 6f ion-pairs and the changes
in the structure of solutions affected by increasing
concentration. There is I table; and 39 references,
Soviet, 12 German, 2 Indianj 2 Japanese, 2 Dutch,
1 French, 1 Canadian, 2 U.K., 12 U.S. The 5 most recent
U.K, and U,S, references are; Do 0. Miller, J. Phys.
Chem., 60., 1296 (19156); E. Glueckauf., Trane. Faraday
Soc., 51, 1235 (1955)4 J. B- Hasted So H, M, EI-Sabeh,
Trans. Faraday Soc., 9, 1003 (1953~; R. A. Robinsor,
R. Stokes, Ann. No Y. Acad. Sai., 51, 593 (1949~,;
Card 2/3 J. B. RaI5ted, Do M, Ritson, C, H, Collie, 'J. Chem.

A Comment on the Theory of Solutions of 77064
Strong Electrolytes SOV/62-59-12-8/43
Phys., 16, 1 (1948).
ASSOCIATION: N. S. Kurnakov Institute of General and Inorganic
Chemistry of the Academy of Sciences, USSR (Institut
obshchey i neorganicheskoy khimii imeni N. S. Kurnakova
Akademii nauk SSSR)
SUBMITTED: April 7, 1958
Card 3/3

5(2) SOY/78-4-9-2/44
AUTHORS: Tsentisiperp A.B., Daniloval M.-S., Kanishcheva, A. S.j
Gorbanevt A. L
TITLE: Data on the Existence of a Higher Hydrogen Peroxide
PERIODICAL: Zhurnal neorganicheekoy khimii, 1959, Vol 4, Nr 9,
pp 1952 1957 (USSR)
ABSTRACT: The glassy substance formed at -196 in the vapors of water
and,hydrogen peroxide dissociated by glow discharge, and by
reaction,of hydrogen atoms with oxy en or with liquid ozone,
has Ve4n described by many authors ~Refs 1 - 11)9 among
,others by ff. I. Kobozevp L. Io Nekrasov and Ye. N. Teremin
(Ref 11). In the present paper the X-ray analysis of this
substance is reported on. The substance was synthesized by
,means of a glow discharge in an H20 - H202 atmosphere in the
apparatus described in reference 17, and by causing atomic
H to react with liquid 0 . The goniometer head of the X-ray
camera is.given in figurg 1, the Dewar vessel in figure 2.
Table,1 gives 'data.obtained from radiographs of the substance
inies'tigated, and table 2 the chemical analyses. The authors
state that the substance is formed in the amorphous state
regardless of the syntheti8 method applied, It begins to
Card 1/2 crystallize slowly at -115 crystallization being completed

SOV/78-4-9-2/44
Now Data on the Existence of a Higher Hydrogen Peroxide
after 5 hours. Grinding of the substance under liquid nitrogen
.also induces crystallization. Only the lines of ice and hydro-
gen peroxide were visible in the radiography as well as the
halo of the amorphous substanoeg for which the composition
H204 was determinedo The sub.stanoe evidently is a higher .hydro-
gen peroxid*4 The authors express their thanks to 0. A. Oollder
for his valuable advicso This investigation was carried out
together with the Fizicheakiy Institut Akademii nauk SSSR
(Institute of Physics of the Academy of Sciences, USSR).
There are 2 figures, 2 tables, and 19 referencesp 6 of which
are Soviet.
SUBMITTED., May--5t 1958
Card 2/2

5 (4)
AUTHORSt Gorbanev, A. L Kesslert.~Li-. M., SOV120-125-6-30161
Sevostlyanovj E6 St
TITLEt Some Re6ul6xities in the Properties of the Solutions of'Strong
Electrolytes (Nekotoryye zakonomernosti svoystv rastvorov
sillnykh,elektrolitov)
PERIODICALs Doklady Akademii nauk SSSR, 19599 Vol 125f Nr
pp 1281-1284 (USSR)
ABSTRACT: The authors state that it Is possible to explain the,
deviation of the properties of electrolytes from the Debye-
HUckel-law only by taking the specific ion interaction into
account. On the basis of assumptions made in an earlier
:of ion interaction is given
paper (Ref 4) the ogntribution f
,
as amounting to 1n f. - Ars.330 - B~
+ r
0 (I). [a - r
-
1
+
0 3
the sum of the crystallographic radii of the cation and,aniong
B - 6.024-10 20 coefficient taking the solvation energy

of the ion pair into account (Formula 2), c concentration]..
The deviaticn Ig f ~ w lg f 1g f (f experimentally

Card 1/4 ezp D c ex
p

some' Regularities In the Properties of the SOV120-125-6-30161
Solutions of Strong Electrolytes
determined.behaviort 7 theoretical behavior according to
D
Debye-Ffilckel) was investigated at 250 and c a 0.01 in
aqueous electrolyte solutions. The following increase of the
deviation was found: LiCl< KCIO 4 UP, NaNO Na
4 3' 01040 Rbel'
Cocl, COBt< Kol< KBr< LiNO 30 N&Cl< KJ < Li Br < NaJ .ffaft4 LiOlO 4<
4KF< Cs?.,1t follows herefrom that there is no agreement
between the deviation and the solvation ability of the ions.
la the energy of electrostatic interaction and quantum-
mechanical energy compensate each other, with an increase of
the ion radiusp the lack of agreement must be due to individual
differences betreen the ion pairs, which manifest themselves
An theirsolvation energy. Thereforeq the values for *1C
were.caloul9ted and the curve of the function BPJO - f(a) for
0
0 and 250 was plotted (Figs 1, 2). An existing conneotion
now becomes noticeable. The considerable straggling of
measured values may be explained by the omission of all other
Card 2/4 interaction factors. Investigation of the dependence between_
177177777 2

Some -Regalarities In . the Properties of the SOV/20-125-6-30/61
Solutions of Strong Electrolytes
Bp,c and b (dipole effe.ot).as well as g (charge interaction)
resulted in no.connection In the case of water. On the basis
of data (Ref 7) for formamide the values *of BPjc in a
formamide solution were calculated and represented as f(a)
and f(b) (Fig 3). The authors, however, emphasize that this
connectionp which now becomes apparent, may be due to a
misapprehension. It happens that the salts for which data
in formamide are availablep show a continuous connection
between a, b and g (Fig 4). Thus, the real argument of the
function B tic can therefore only be one of the variables
a, bp g. In order to clear this up, it is necessary to
determine the values for salts which do not fit in to the.
curve of figure 4. There is no connection between al b ana.g
and the deviation from the law of dilution heat. The dilution
heat is influenced in the same manner by the various effects
of ion interaction.-In this case the entropy terms of the
equation must not be omitted. There are 4 figures and
Card 3/4 7 referenoesp 4 of which are Soviet.

Some ~'Regalarllwdes in- the Properties of the SOV/20-125-6-30/61
Solutions of Strong Electrolytes
ASSOCIATIONs Institut elektrokhimii Akademii nauk S33R (Institute for
Electrochemistry of the Academy of Sciences$ USSR)
PRESENTED: January 14P 19599 by A. N. Frumkinq Academician
SUBMITTED: December 26# 1958
Card 4/4

5
~.4130 7~089
-- e
S01110,~ -6o -.I - 31/37
AUTHORS. Gorbanev, A. I., Kessler, Yu. M.
TITLE-. Brief Communications. Concerning Calculation of Ions
Effect.on the Structure of Water
PERIODICAL. Izvestiya Akademii nauk SSSR, Ot-deleniye khimicheskikh
nauk.,.1960, Nr 1, pp 140-141 (USSR)
ABSTRACT% It was shown by a series of mathematical transformations
that the method for calculating the ion effect on the
structure of water, proposed by I. G. Mikhaylov and
Yu. P. Syrnikov (Vestn. Leningr. univ,, Nr 10, Seriya
fiziki i khimii, vyp. 2, 5, 1958) is quite reasonable
and interesting from the qualitative side, but quanti-
tatively-It is expressed incorrectly. There is I
Soviet referen-,e,
ASSOCIATION., Institute of Electrochemistry, Academy of Sciences USSR
~Institut elektro-khimii Akademli nau~ S-SSF)
SUBMITTED: '
June 23, 1959 Card 1/1

2/076J60/034/009/021/bU
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TrMR. I...... 10901-1959)
MMAIC&LI Zinarmal kniali. 1960. Tel. 34. In. 9.
pp- Is W2153
TM. An ottusry out- So CI,vo to b.nor of the Rest of the kf.dra
Frois.."t. Kbor-kovskoco
institute to. T. 11bml~ of llodutt. of %h.
pAeS,~ '.'~'..Sam Inatituso lawol T. 1. 1 *nlu). professor
A. J. 27ser". she died on J"warr 4. 1960 . FuTio-ing th. otttvary. a
It" of the elsailifle marks P.Wllob*d by hie in St.". to 1926. th.
lefeem.4 fIRIA1104 k16 Atudl-M-at the Kh"'196-.kly tokhoologlah.ski:
imstitut (Khar-lov T.63"nologio-1 ImAtItut*). y"m 1924 to 192,3 be -Ork-d
with fter.stor A. 1. XMb.A.". aft 'Jueetroly.16 with"% U.0tred.j S7
nosom of a Spa" Cap*, " wbitb o0ousten sevoral "p.riaeuto "do by
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pIgm,,,bOw#kty4, a *estrovervy followed. in the anarov of vidah the lattor
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Ca" 2/2

GORBANEV,_A.I.; KESSLER, YU.M.; KRYLOV, V.V.
Effect of the structure of strong electrolyte solutions on thermo-
dynamic Oroperties. Zhur.strukt.khim. 2 no,3:260-267 My-Je '61.
1. Institut elektrokhimii AN SSSR. (MIRA 15:1)
(Electrolyte solutions) (4bemistry, Physical and theoretical)

USELER.. 7U.M*; POVARM., Yu.M.; GORBANEV A.I.
Close interaction of ions in solutions. Zhur.strakt.khim. 3
no.1:9-2--94 JTs,--F 162. (MIU 150)
11 Institut elektrokhi-ii AN WSR.
(F.lectrolyte'solutions)

SEVASTIYANOV B.S.; A.I.;.KESSLER Yu.M.,(Moscow)
Apparatus for'measuring electric.conductivity. Zhur. fiz.
'chi-, .36 no,3.2644-W ..Mr 062. (MIRA 17t8)
1. Institut elektrokbimii AN SSSR.

34824
S/020/62/142/005/015/022
B110/B10-1
'C~ 0
AUTHORS: Alpatova, N M., Gorbanev. A. I,, Kessler, Yu. M., and
Lozhkina, L: G.
TITLE- Physicochemical study of complexes between alkyl (aryl)
chlorosilanes and halides of tetrasubstituted ammonium,
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 142, no~ 5, 1962, 1073-1076
TEXT: The authors studied the complex formation between CH 3SIC13 1)9'
(CH 3)3 Sin (II), C6H5Sicl3 (111), Sicl4 (IV) with NaCl (a), NaF (b),,KF
(c), CsCl (d), CsF (e), NH 4 Cl (f), (CH 3)4 NC1 (g), (C2H5)4 NBr (h),
(C 4H9)4 NCI (i), (C4H9)4 NBr (k), (C4H9)4 NI (1), ethyl pyridine bromide (M)
by chemical analysis (for hydrolyzable Cl, and argentometrically), con-
ductivity measurement, and visual observation of the dissolution. The
synthesis was conducted in Ar atmosphere at 35 - 400C during 3 - 12 hr,
depending on the dispersity of the salt. I, II, III, IV reacted with e,
h, i, k, 1. With halides of tetrasubstituted ammonium salts, complexes
Card 1/4

S/020/62/142/005/015/022
Physicochemical study of complexes B110/B101
are formed if the alkyl radical is long enough. Their ability to form
complexes increases with decreasing anion radius. In I and II, which
behave similarly, i dissolves with formation of two layers. The one has
an organosilicon compoundsIsalt ratio of,3:1 (viscous, at room temperatze
supercooled, colorless, or yellow liquids), the other a ratio of " 4011
(movable, organic compound with some dissolved salt), Dissolution of k
is analogous. 1 yielded no complexes, only slight yellow coloring, and a
slight increase in conductivity of the organosilicon compound. IV behaves
like I and II but forms poorly fusible complexes. i and k dissolve in III
without layer formation to give a yellow solution with 'nigh temperature
coefficient of solubility. The solubility of i in III is much higher
than in I and II, the conductivity x - 2-7'10 -4 for III:i = 5.4 : I
(unsaturated solution); x = 7.4*10- 5 for III:k = 45 1 1 (saturated solu-
tion). In the system II-i the layer composition does practically not de-
pend on time and temperature. This is confirmed by equal conductivities
of the isolated complex and the complex together with the second layer.
The behavior of [(CH 3)3'S'C']3(C4H9 4NC' to solvents proves a stronger,
bond of the one molecule than that of the other two. Si was not separated
Card 2/4

S/020/62/142/005/015/022
Physicochemical study of complexes ... B11O/B1O1
off during electrolysis of the systems I-i; II-i; I-k, and the solutions
of i and k in I at D c = 0.25 - 10 a/dM2. Low-resistance. p-type silicon
was dissolved in the systems I-i; II-i, and the solution of i in III~ In
the [(CH 3)3 Sicil3(C 4H9)4NC1 complex and its benzene solutions (1 mole of
complex : 10 moles of benzene) at D a = 4 a/dm 2 , silicon dissolves with
almost 100 % current yield (referred to Si4+). Complex formation, layer
formation, extraction of two (CH 3) 3SiCl molecules by aliDhatic solvents,
the dependence of the complex formation on anion radii and cation dimen-
sions, the anodic behavior during electrolysis are similar to the behavior
of analogous Al compounds, the cathodic behavior during electrolysis is
different. There are 3 tables and 10 references: 3 Soviet and 7 non-
Soviet.
ASSOCIATION: Inst[tut elektrokhimii Akademii nauk SSSR (Institute of
Electrochemistry of the Academy of Sciences USSR)
PRESENTED: Octobor 7, 1961p by A. 11, Frumkin) Acadomician
Card 3/4

Physicochemical study of complexes ...
SUBMITTED: October 2, 1961
S/020/62/142/005/015/022
B110 13101
ul-K
Card 4i4

ai MOOT YU.N.; 0ORBOW XMIMv TuAl AUMVA, I.V..,,'
Activity'000fficisutf Of 0691= Ohl id in N-mothylfoiamdde,
(KML,-15-2)
le IrAtitut elektrobbluli AN-SM. *W[*Uvlfto ~Wmdmikom
I JJ*umkiqrm4
Astivity omffWmts)

KOSM, Yu.N.; POVAW7# Yu*K*j -A-I-
Problem of the salting-OUt OffeCto ZhUrootruktakh" '4 no-18200-
.102 Ja-V 163. NM 16-#2)
~i. rnotitut slektrdkhlaii AN NJ%
(salting-out)

GOLODSHTEYN, I.P.; KESSLER, Yu.M.; POVAROV, Yu.M.; GORBANIV, A.I.
Dipole moment of N-sethy1foysmaide. Zhur.strukt.khis. 4 no.3s
"5-"6 Yq-je 163. (IaRA 26t6)
1. Institut slektrokhWi AN SSM.
(Parmaide-Dipole moawn~s)
-an

AL.PATOVA, N.M.; KESSLER, Yu.M.;,WRBAM
, _ ,- A.1
Interaction of hydrogen chloride with halides of quaternary
amonium salts. Izv. AN SSSR. Ser. khim. no.8tl369-1372 Ag 164.
(KRA 17t9)
1. Institut elektrokhinii AN SSSR.

GOLIDSHTEYN, I.P.- ALPATOVA, N.M.; KESSIn, Yu.M.; GURIYANOVA, Ye.N.;
QOBAW,V,'A.1.
Interaction of hydrogen chloride, tetra-m-butyl ammoRi= chloride
with trimthylehlorosilass in benzene solutions. Izv. AN SSSR..
Serekh1m, no*9e1683-1685 S 163. (MIRA 160)
1. Institut elektrokhimii AN SSSR.
(Amonium compounds) (Silaine) (Hydrochloric acid)

POVAROV, Yu.M.1 MRSSLER, YU.M.; GORBAN&V, A.I.
Thamodynxmic properties of strong electrolyte solutionB in Bolvents
with high dielectric constants. Elektrokhimiia 1 no.10-13.174-1181 0
165. (MIRP, 18M)
1. Inatitut elektrokhimii, AN SSSR.

t 12898-66 SWT(a)/ZTO(k ZMWAV_rdR( JP04-
ACC NR: AP5027580 SOURCE,CODE: UR/0364/65/001/011 1/13 41/135
f
AUTHOR: Alpatova, No M.1; -Kessler, Yu.__M.-, Gorbanev A.
ORG: Institute of-Electrochemistry, Academy of Sciences SSS _(Institut
elektrokhimiTAkademll, naux,Ub~K) Ak~5
~TITLE: Anodic behavior of.sIlicon in somenonaqueous solvents. JI0,.,
SOURCE: Elektrokhimiya~q ~v 1 no., 11:9. 1965, 1344-1351
TOPICTAGS:~ :silicon, oxidation, organic solvent, electrochemistry.'
organosilicon compound' electroplating
ABSTRACT: This.article.reports.on the~continuation of work reviousl
p 1. 1 y
-reported in Vlektrokhimiya,:11 8441J1965). To determine the nature Of.
the anodic rea.ction of the first, polarization wave during the dissolu-
tion of-Si in chloride,solutions in H-methylformaamide solvent,,polari-
zati,on.studies wer e conducted with stationary and rotating ~Ll_ectrodl~q
Measurements were also made in mothylchlorosilane solutions. p-typel
silicon of 0.045 ohm,cm resistivity and n-type silicon of.0.040:ohm,er.
resistivity were used as anodes. Polarization measurements were made
..with the lower faces of cylinders 1.8-3.0 mm in diameter, pressed into
teflon. The faces of the silicon cylinders were successively electro-
UDC; 541-13
Card 1/2

L 12898-66-
ACC M AP5027580
plated with palladium and copper and copper leads were soldered to them.
The potential of the anode was measured with respect to the aqueous
saturated calomel electrode. Electrode polarization was both galvano-
static and potentiostatic. The anode polarization curve for p-type
silicon in N-methylformaamide solutions has two waves, where the first
wave corresponds to the dissolution of silicon with the participation
of solvent and the second wave corresponds to the oxidation.of the sol-
vent. The reaction is inhibited prior to the second wave, which is ex-
plained on the basis.of adsorption of chloride ions on the electrode
surface. It was shown that the hole's participate in the anodic disso-
lution of silicon just as in the case of aqueous solutions. It is con-
cluded that the results of this work will be useful in the preparation
of silicon'surface relatively free of oxide film, electropolishing of
silicon, and production of new organosilicon compounds .7 The authors
wish to express their gratitude to L. I. Krishtalik for the valuable re-
marks which he made in the course of the discussion of the results.
Orig. art. has; 7 figures...
SUB CODE: -~.07/ SUBM DATE: 30Mar65/ ORIG REP: 006/ OTH RM 004.
L Card

T (m) iiG Nn
0,
~'R A115017958
537."Ll
AMT-MR: AlpatoviLi H&- 'e-s-le-rx --Yu Gor ianev,, A. 1.
e
jT en7_'Pn
._ Elec,:ric&l conductivity of b, _--solutions of hydrogen chloride AM
i-atra-n-butyba nium ehlorida,_~'
SOURCE: AN :3SSR. Izveattya. Seriya khimicheskaya, no. 6, 19650 989-994
TOPIC TACS: quaternary a nium base, hydrogen halide, tetrabutyla nium
chir-ride, benzene solution, conductivity isothem~, electrical conductivity
ABSTRAC-1- The system (n-C09~3[Cl - HCI was studied by measuring the electrical
conductivity of isomolar serieG in benzene at 25, 15, and 10C. The HC1 concen-
~rat,iDn ranged from 85 to 40-30 mole %. The electrical conduct[vit-, isotherms
belong to the irrational type. The inflection poinz 0, x being the
concentration) corresponds to the composition tetra-n-butylamw-aium chloride
FC1 = 1-1, rnd does not shift as the temperature changes, indicating the forms-
tion of a ccmpound of this eon*osition. At the ratio of 1:3, a faint Inflection
is a-loo obacrved, but it is fairly indistinct and the formation of the corres-
Card

4 4
-L 60,049-65
i ACCESSION NR: AP5017958
ponding comp3und cannot be ascertained from these data. In the interdation be-
tween R4h'X and IM at roop temperature, the follawing stage!z are distinguished'.
f!) frrmaticri of soid (crystalline) compounds R n(HK) ; (2) formation of
4 n
R, NX aad TLY in an
iric's of this composition; (3) reaction between
Ineru BoivurL. firnt two stagea are treatEd
Br, and T by means of thermochemical cycles. It is COnClUded tilaL LK'V-~
of F 17X is fucilitated as R increases in length. The theoretical con-
4
re in accord with the formation of the compolL!nd fn-C4H9)4 C1 HC1,
2 fig! ree i7ld 10
thts vork, Ortg. arc, h&a:
4!

ALPATOVA, N.M.; KF,9$LER, Yu.M.,- GORRUST A.L
Interaction between. methylchlorosilaneB with complex compounds
of tetra-substituted ammonium halides and HCI. Zhur. nearg.
khim. 10 no.7tl566-1571 JI 165. (MIRA 18:8)
1. Inst-Itut elek"trokh-indi AN S&911.

ALFATOVA, N,M,j KESSLERp YU.M.;-M-B
AWfp~-A.I,
Anodic belaviar of silicon in owe nomqueoua solutions.
Blektrekhlmiia 1 no.7.-844-850 JI 1659 (MIRA 18:10)
.1, Institut elaktrakhimii AISSSR,

19
L

Goammo KOVALIT, M.L..insh.
Device for adjusting flooring slabse Blul.strol.takh. 22
no-q-.17 S 155. (NIHA 12:1)
I M-4. ~~ I

GORDA - T
am--,
Building.without wood on colloctive farms. Sells strol. 11 no.4:29
.4.56
1. Correspondent "sety "Leninskoye swWa."
(Buildirt)

GORDWiMs To
Dons by members of the'All-Union Volunteer Society for Assistance
to the Army, Air Force, and Navy. Radio uo.3:16 Nr 160.
(MIR& 13:6)
1. Z-amestitoll rodaktors gasety OZavot Illicha."
(Radio)

~,GdRBAMq V.; KMWSOV9 V.
in oral we&. Isebr.1 rMs. no.2:41 7 161. (M3RA 24t2)
1. Mae%W rodkollegli s&Todakay imogotirasbki lZa takbaUb9*ly
progreasup g. Orele
(Ore3,-Leatbor Industry)

KIS FJZV, P., dispatcher; AFONSKIY, P.; I V V.,- SMGANOVSKIY, V.
Sg. Odeosa),-'IONF.SKU, Ion (Rumyna ya Naro`c~ya Respubiika)
The fraternal international relations are growing stronger.
Sovo profsoiu-%.v 17 no.21:32-33 N 161. (MIRA 14:10)
1. Makeyevskiy kobokhimichookiy zavod (for Kiselev). 2. Pred-
sedatell Kharikovskogo oblastnogo komiteta profsoyuza raboahM
mashinostroyeniya (for Afonskiy). 3. Radaktor zavodskoy gazety
"Za tekhnicheskiy progress" Orlovskogo zavoda imeni Medvedeva,
9..Orel (for Gorbimv).
(Trade uni&W)

MEZHRNNIKOVI A., inshe; L17ATOV, Pe,, starshiy inzh. po takhaiaheskoy
0
inforwAtsiii GIB I TSOL~~~s, V.,- KOSTM 9 P.
EmboVe of experiewoo IsabrA rats. nD.5:22 162.
(HIPA 15:5)
Is PMo UMnIcheakoyinformtsii larbyumtornogo savoda..
lOulagrad (for lbabon-4 v). 2. Kombinat OS41rhiLI48, pos. Tetyukbe,
Primorskly kray (for Klmtov). 3. Cblen prealdiumm oblastnogo soveta
Veasoynnogo obahchestya Isobretateley i rateionalizatorov, g,
rrkatak (for Gorasimov). 4. Sekretarl obl&Btnogo soveta Vseooyuznogo
obahchestva isobretateley i ratsionalisatorov (for Kostenko)e
(Techwlogical i=ovatiozo)

inzh,';- OMMAMIN, V.A., kxnd.tekhn.nauk, starshiy nauchnyy
sotrildnik: 0(44Wj~-,Y.P.; TRlUBIN,'V.A., 4avn" red.; SMIN, A.T.,
zam.glavt6go r6a.;.GRIMICH, G.P., rid.; YAPIFAROV, S.F ,red.;
OMMIYEV, I A. --red.`- MICKHLOV, B.A., re*d-.; ZIMIN, P.A., i-ed.;
7PINA, ~ L.A red. J,x&-va; RYAZANOV, F.Ye., tekhn.red.; GMIBERG, T.K.,
-tekhn.red,
Elorthwork operationi under 4inter conditions] Proizvodetvo zemlia-.
nykh robot v zitunikh-usloviiakh-:spravochnoe.poso~ia.', Koskvao Goa.
lzd-vo lit-ry po atrolte-.9.,arkhit. istroit.materialem, 1961.~ 149 p.
(WIR A 14:4)
1. Akademiya stroitel'.et.va iarkhitektury SSSR. Inatitut orgenizatail,
makhanizatsUitekhnichookoy p omoshchi stroitelletva. 2. Rukovo-
ditell laboratorii zemIrnfth rabot.gauchno-issledovatel'skogo insti-
tuts organizateii,-m9khanizateii i tekhnichoskoy pot~6shchi stroi-
telletvu (for Rogovskly). 3. Laboratoriya'zomlyanykh robot Hauchno-
issledovatellskogo inatituto orgenizataii, makhinizataii i teUmi-
dheskoy pomos-hchi stroitel.'stva (for Cherkashin). 4. Starshiy tekhnik
loboratorili semlyanykh robot Nauchno-iseledovatellskogo instituta orgs-
nizatsiii-mekbonizatsii i takhnicheakoy pomoshchi stroitellstvu (for'-
(larthwork-Coldvestber conditions)

GORBAMEV
Experimental PMZ,unit. Stek. i ker. 18 no.10:45-46 0 161.
(MIRA 14:11)
(Conveying machinery) (Glass manufacture)
(Automobiles--Windows and windshields)

WRBAUTp V.00
-20
Autamt1a duction Une for large bottles. Stek. i ker.
(MM 16s6)
PT
3
is 11~~k lyzaviod Imini Ybd"&w.
.(No subject headiW)

GORBANEV, V.S.
-- ~-
Now semiautomatic machine. Stek. i ker. 21 no-10:38 0 164.
(MIRA 18:11)
1. Orlovskiy mashinostroitelinyy zavod imeni Medvedeva.

7-7~
Rim

133-58-4-8/40.
AUTHORS: Raspopov,, I~V.4Doaent and Gorbanev Ya. S. and
Sviridenko,~F. F., Engineers
TIMS: The Use of a High Basicity Sinter for Smelting
Phosphorus Pig Iron (Primeneniye aglomerata v7sokoy
osnovnosti pri peredele fosforistykh chugunov)
PERIODICAL: Stall, 1958, Nr 49 PP 306-311 (USSR)
ABSTRACT: The use of a high basicity sinter for the intensification
of the process of removal of phosphorus during the melting
period was tested in the open hearth melting shop of the
Azovstall.Works when smelting rail steel. Chemical
composition and size distribution of raw materials used
for the production of sinter - Table 1. characteristics
of sinter produced under laboratory conditions - Table 2
and that produced under industrial conditions - Table 3
sinter basicity up to 14-3). Changes in the composition
of metal and slag in the course of heat when using high
phosphorus iron and fluxed sinter are shown in Fig-3,
similar changes when using ore - Fig.l. The comparison
of operating indices of open hearth heats carried out with
the use of sinter and ore are given in Table 4.
Card 1/2 Conclusions: The production of sinter with a v7ide range of

Iron
The Use of a High Basicity Sinter
133-58-4-8/40
for Smelting Phosphorus Pig
fluxting from rich in iron and low-silica materials is
possible. The melting temperature of fluxed sinter is
considerably lower than the unfluxed sinter and in
particular of that of raw ore. The use of highly fluxed
sinter during smelting high phosphorus pig iron decreases
the duration of the heat on average by one hour, 23 mins,
and permits a substantial increase of the concentration
of phosphorus in the slag. The increasq of the cost of
the mineral part of the charge is compensated by the
increasing yield of steel. The productivity of open
hearth furnaces increases by 9%. The following partici-
pated in the work: Professor I. G. Ka'zantsev, and
Engineers: M. T. Bullskiy, P. N. Slepkanev, A. G. AlimOV9
Ye. V. Tretlyakov and a research group of the Ukrainian
Scientific Research Institute of Metals. '
There are 4 tables, 3 figures and 4 references, all of
,which are Soviet.
ASSOCIATIONS: Zhdanovskiy metallurgicheskiy institut
Zhdanov Metallurgical institute) and Zavod "Azovstall"
Card 2/2 Rzovstall Works,)
1. Sintered.iron."Effectiv.ene-as 2. Steel--Manufacture Sliags
--Properties,

SOV/133-58-8-2/30
AUTHORS: , Raspopov, I.V., Dotsent and Gorbanev, Ya-S.,
Gulyga, D.V-, EngineerW
TITILE: The Production and Smelting of Fluxed Sinter from the
Kerchl "W14 Ores (Proizvodstvo i domennaya plavka
aglomerata iz Kerchenskikh rud)
PERIODICAL: Stall, 1958, Vr 8, pp 6?6 - 682 + 1 plate (USSR)
ABSTRACT: The production of fluxed sinter kCaO/SiO0 = 0.6-0.9)
and the results of operation of blast furnaces with 8(Y,6
of sinter in the burden are described. Operating indices,
material, heat and hydrogen balances of the furnace
operation with-sinters of basicities 0.16, 0.6 and 0.9
are given in Tables 4 $ 61 7 and 8, respectively. Main
points: for each ton of limestone withdrawn from the
burden by increasing the sinter basicity from 0.16 to
o.6. asaving in coke of 365 kg was obtained. With
further increase in basicity to 0.9, the amount of coke
saved per 1 000 kg of limestone withdrawn from the
burden de-.reased to 283 kg. Above 40%_of hydrogen intro-
ox"'se' 'o wa'er.
duced into
the furilaue was LU.L U V
to 200115 of As present in the sinter mix is remaed during
sintering. 0~nclusions: 1) on smelting a burden
Cardl/2 oonsisting of 80016 of sinter and 20016 of ore, an increase

30V/133-58-8-2/30
The Production and Smelting of Fluxed from the Kerchensk Ores
In the s-Inter basic!ty from 0.16 to 0.6 increased the
furnace output by 6% and decreased the coke rate by 8%;
the cost of iron was de~:-xeased by 10 roub-les/ton. The
above increase in sinter basikcity was accompanied by a
decrease in the limest-one charged directly te the furnace
by A2%i 2) for further improvement of the furnace
performance, bet-ter szreening of sinter is necessary.
There are 8 tables, 4 figures and 3 Soviet references.
ASSOCIATIODS: Zhdanovskiy metallurgicheskiy institut (Zhdanov'*
Metallurgical Institute) and Zavod "Azovstall"
("Azovs,tall" Works)
Card 2/2 1. Sintered ores--Production 2. Blast furnaces--Operation
3. iron--Production

SOV/133-58-8-3/30
AUTHORS: Lukashev, G.G., G(;.Pbaaev,_Y_%_~Prikhod'ko, L.D. and
Gulyga, D.V., Engineers
TITLE: A Study of the Movement of Materials in a Blast Furnace
Using Radioactive Indicators (Izu-heniye dvizheniya
.materialov v donennoy pechi. s pom~shchlyu radioaktivnykh

PERIODICiLL: Stall
Nr 8
pp, 682 -- 687 (USSR)
1958
,
,
2
ABSTRACT: The above investigation was carried out using radioactive
phosphorus and cobalt which were enclosed in lumps of
limestone, coke and steel shells (Fimire 1) on two furnaces
-,
operating with a 10(Ylo sinter burden (3
0% of fluxed sinter,
CaO/SiO2 .= 0.9). Radioactive specimens were introduced -
into the furnace through a pipe (Figure 2) at the following
distances from the inwall; 110, 460, 860t 1 370, 2 230
and 3 150 mm. The rate of descent was determined either
by the appearance of radioactivity in the iron (samples
were'taken at the beginning,middle and the end of the-
casting):or using counters enclosed in water-cooled probes_-~
,
(Figure 2) which could be introduced at various furnace
levels (Figuxe 3). The experimental results are given
in Tables 2-4 and Figures 5, 6 and 7. It was found that:
Cardl/3

QOV/13-3-58-8-3,/30
A!Studj of the Movement of Baterials J.-a a Blast Furnace using
-Radioactive Indicators
1) under normal operatinG conditions, burden materials
descend at, a mixLisium rate on the periphery and at a
maximum over the zone of combustion of coke in front of
tuyeres. Mean rates of descent of materials in the
furnace cross-section vary. Under certain conditions, the
baximum rate of descent can appear in the central zone;
2) the distribution of'the maximum rate of descent along
the furnace height was as follows: up to 10 m1h in the
top part, in the middle part of the stack up to 4-5 q1h
and in the bottom third of the stack up to 3.5 m/hi
3) deviations of the path of materials from vertiml could
not be determined by the set-up used in the experiments;
4) the actual deviations of the paths of the individual
burden components can take place not only towards widening
of the stack but also towards zones with a maximum rate of
Aescent; .5) the most economical operation of the furnace
was characterised by the following distribution of mean
relative velocities of the descent materials
Oard2/3

SOV/133-58-8-3/30
A Study of the Movement of Materials in a Blast Furnace Usinz
Radioactive Indicators
Distance from
"the inviall of 0-200 400-1 000 1500-2000 centre
the throat,mm
Mean relative
velocity, 80 100 95 85
mp/min
6) the overtaking in time of coke by limestone during
the descent from the stock level to tuyere level is about
10 - 30 min. The maximum overtak-4ng relates to sectors
with -a - minimum rate of descent. . Thert; -are 4 tables and
7 figures.
ASSOCIATION: Zavod "Azovstall" ("kzovstal" Works)
Card 3/3 1. Blast D=naces-Performance 2~. Radioisotopes-Applications

STARSHMOV, B.N., kand.tekhn.nauk; LEBEDEV, A.Ye., kand.tekhn.nank;
LUKASHOV, G.G.J. imb.; SAVELOV, N.I., inzh.; TARASOV, D.A., inzh.;
SU4UN, I.Ye... insh.; TIKHOMMV, Ye.N., inzh.; SINIT$k'.IY,, V.D.,
insh.; GORBANEV., Ya.Se., inzh.; PRIKHOD-KO, L.D., inzh.
Operation of a blastfursace with a capacity of 1513 m3. Biul-
TSIERM no.9sl-6 960. 154)
(Blastfurnaces)

STARMINOT, B.Is# kand,tekhn.umake SAVILOT# N-I-o inzb., TARASOV, DeA.o
Insh., WPM. 10yes, Insh., OORBAM _Ta
jLA, nsh., PLISWOVSKIYP
SeT., lush,
Adopting a blast furnace with a useful capacity of 1719 vi~.
Metallurg 3 no*717-9 J1 160. (NI"13:7)
(Blast furnaces)

r7848
S/133/61/000/008/017/025
A054/A129
AUTHORt Gorbanev, Ya.S.
TIT--'E: News in brief
A
PERIODICAL: Stal , no. 8, 1961, 744
TFXTt In the "Azovstal'" Plant. 1) Tests were carried out to investigate
the endurance of welded. seams and the brittleness of MCT-3 (MSt.3) type steels
with a 0. 15% _ As content and MOT. Wr Nst - 3kp) steels with a 0 - 17 - 0. 19% As con-
tent. Of steels almost idefitical In composition, those containing arsenic dis-
played better mechanical properties than steel melted from Krivoy Rog ores. The
elongation values were identical for both types, the average yield values were
29.2 and 24.'1 kg/mm2, strength limit values 45.3 and 37.0 kg/mm2, respectively.
The notch toughness values of the Aa-containing steel and of steel not.containing
As (of the Yenakiyevo Plant) are the following (numerator - with As content; de-
nominator - without As)t
Test temperature, 0C ................... [phone]
ak, k9m1ce: 11.6 9.o 6.2 -Jt2 0.72
longitudinal samples ............... 12.3 9.4 5-9 0. 0.29
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27848
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News in brief A054/A129
I
transversal samples ..4 ........ .... 6.8 4.8 3.4 1 0.70
7.5 4.1 10.-h 0.28
2) Tests were made to Increase the service life of some parts of metallurgical
equipment. "Sorbitization" is applied for the heavy-duty crane-wheels to a depth
of 20 mm to eliminate aplittingi nitrating is applied for parts subjected to
friction;' long and thin machine parts are cemented with a subsequent straighten-
ing at 300 - 4000C and the same treatment is applied to parts having a higher (up
to 0.4%) carbon contentj high-frequenoy hardening is applied to the wheels of
small-1-cad cranes and the working rolls of the blooming milli a rest is con-
stracied on the lathe to facilitate machining of the hardened parts. 3) The sur-
face hardening of raila along their entire length was tested on 1.5 - 2.0 m long
Pieces Of P-50 (R-50) rails by high frequency hardening In the Mr3-102 (MOZ-102)
test equipment. After hardening the hardness had Increased to 302 - 400 HB, the
strength limit by 10%, the yield limit by 40 - 50%, relative contraction by 20%,
notch toughness by 150% when Ysrdening on air and by 300% when hardening In wa-
ter. Relative elongation decreased by 1.8%. When hardened with pressurized air
the rails containing carbon and manganese do not increase sufficiently in hard-
ness (at the lower limit). When hardened with a water-air mixture their mix com-
position becomes difficult to control. The best results are obtained with warm,
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News in brief A054/A129
softened water (38 400C). The depth of the hardened layer at a 2,500 cps cur-
rent frequency is about 9 - 10 mm with an intermediate zone, while the rate,-of
displacement of the inductor in relation to the rail amounts to 6 mm/sec. 4) The
heat-treatment of crushing mill balls has also been established. The hardening
process for 40, 50, 66, 80, 100 and 125 mm-diameter balls made of M76 (M76) and
Gr.6 (st.6) steels was Investigated. The chops of the standard 10-ton M76-steel
rail ingots Were iner4ased. Based on the tests the hardening equipment for ball
mills was reconstructed. The analysis made in YuGOK shows that rail steel hard-
ened to 300 - 400 HB is the most suitable for 125, 100 and 80 mm-diameter balls,
while for softer balls the St.6 brand can be used. An excessive hardness results
in fracture of the balls and accelerated wear of the crusher lining.
Card 3/3

VOLOSHIN) A.I.; BOGOUVIEIISKIY,, K.A.; AE]ITYRCHENKO,, A.M.; TURIK., I.A#;
ZHIDKO., A.S.; LULYUK, V.S;; GARAY, L.I.; ONOPRIYENKO, V.P.;
STARSHINOV, B.N.; BABIY, A.A.; SAVELOV, N.I.; Prinimali
uchastiye: TORYANIK, E.I.; VASILOYEV, Yu'S.j SHEMELI, T.I.;
SEMTA., V.I.; BONDARENKO, I.P.;*AMSTISIAVSKIY, D.M.;
ANDRIANOV, Ye.G.; SERGEYEV, G.N.1 ZAM&KHOVSKIY) WA.;
IYUKIMSON, M.O.; IVONIN, V.K,; TSIMBAL,, G.I.; SENIKO, G,19.;
KONAREVA, N.V.;.SOMDKIY, Yu.L.; LUKASHOV, G.G*; TAWO'V, D.A.;
GORBAIW Ya.S . SUPRUN., I.Ye.; TIHHOMIROV, Ye.I.; KOHONWI.Q., P.A.;
P ~Kof;i GULIGA D. V. ;' PLISKANOVSKIY . S. T. ; PONO14AUVA K. Ye.
Effect of the length of coking on coke quality and the performance
of blast furnaces. Koks i khim. no.12:26-32 !61.
(MIRA 35~:2)
1. Ukrainskiy uglekhimicheakiy institut (for Voloshin.,
Bogoyavlenskiy, Akhtyrchenko,,.Tu=ik, Zhidko., Lyalyuk., Toryanikp
Vasillyev, Shemell). 2o Zhdanovokiy koksokhlktAheskiy zavod
(for Ubay Senyutd* Bondarenko Amstislavskiy) And i
Tianov,
Sergeyevp Zamakhavskiyp LrAdmsL, Ivonin, TSimbal). 3. Urallskiy
nauchno-iooledovateltakiy institut chernykh metillov (for
Onopriyenko, Starshinov, Babiy',, Sen.lkos Konare,;fa-, Soloclkiy).
4- Zavod "Azovstalin (for Savelor, Lukashov., Tarasov*., Gorbanevs
Suprun,, Tikhomirav,, Kononenko, Prokopov,' Gulyga, Pliskanovskiy.,
Ponomareva), '
Coke)
ast furnaces)
t

GULIGA, D.V., irzh.; GCRBANEV, U.S., inzh.; CHEREPIVSKIY, A.A., inzh.
Studying the flow of charge materials in blast furnaces during
the smelting of Kanyah-Burun sinters. Stall 23 no.8t686-689
Ag 163. (MIRA 160)
1. Metal-lurgicheskiy zavod "Azovstall.11
(Blast furnaces)

KRASOVITSKIYj V.S.j kand.tekhn.nauk; BOLISHAKOV, L.A., kand.tekbn.nauk;
inzh.; YEGNUS, R.M...
TURCHENKOVA, Ye.K., inzh.;
insh.; CHUMAK9 M.A., inah.; KISSEL', N.H., inzh.; SALIMAN, B.Sh.,
insh.
Increasing the stability of ingot molds by an addition of
ferrotitanium. Stall 23 no.&717-M Ag 163. (KM 16:9)
1.,Zhdanovskiy metallurgichaskiy institut, savod "'Asaystall" i
savod im. Illicha.
(Ingot molds)

KAZANTSEV, I.G., prof.; LUKASHOV, G.G., inzh.; GCOAKEV, U.S., inzh.; TARASM&P
L.P.,, inzh.; SAPELKIN, NJ.,, inzh.
Strength df welded jointb In armmpic containixg structural steel pro-
duced at th~ "Azovitall" Plant e, Stall. 23.. no. 31illl2,1ll/*-. D 163.
(MIRA 17,.2)
1. Zhdanovskiy metallurgichemkiy inatitut i installurgichaskiy zpvo4.
"Azovetall".

GERSHGORN, M.A.; SVIRIDENKOp F.F,; KAZARNOVSKIYj D.S.; KW.VTSOVA, I.P.;
POPOVA, A.H.; FRADINAp M.G.; Prinimali uchastiye: LUVSHOV, G.G.;
RUDOLISKIY, N.L.; SLEPKAITEV, N.P.; PIJSKATIOVSKJY, S.T.; jC0RBAf-U!;,V
U.S.; BULISKIY, M.T. (deceased); ARMIANGELISKIY, Yu.N.; SHAROV,
B=..,- VISTOROVSKIYO N.T.; RAKHANSKIY, B.I.; SAPOZHKOVI V.Ye.;
RYABININ, N.G.; KARAKULINA, R.R.; FADEYEVA, A.M.; 7VEREV, D.A.
Improving the production of high-strength rails by alloying
them with granulated ferrochromium in the ladle. Stall 25
no*5:408-411 My 165. (MM 18:6)
1. Ukrainskiy nauchno-issledovatellskiy institut metallov i zavod
"Azovetall".

SO~T/ 137-57-6-9790
Translation from: Referativnyy zhurnal, Metallurgiya, 1957, Nr 6, p 69 (USSR).
AUTHORS- Dukhankina, L.S., Khan, O.A., Gorbaneva, Z.I.
TITLE: The Solubility of Antimony Oxides in Zinc SulfrAte Solutions (Rast-
vorimost' okislov surlmy v rastvorakh sernalcislogo tainka)
PERIODICAI,- Tr. Altaysk. gorno-metallurg. n.-i. in-ta, 1956, Vol 3, pp
132-135
ABSTRACT: An isothermic method is used to study the solubility (S) of Sb
oxides in .chemically pure preparations in neutral ZnSO4-solutions,
there being 18 g H2S0411iter. It is found that the S of Sb?03 with
elevated Zn concentrations of from 20 to 12-0 g/lit-er rises from
0.0718 to 0. 1162 g/liter, the S of Sb2O5 being constant and equal to
- 0. 14 g/liter. As temperature rises from 20 to 80', the S of Sb
oxides in ZnS04 solution rises at Zn concentrations of 1207g/liter,
while in a solution acidified by H?S04 (up to 18 g/liter), the S
curve.'s lie considerably higher. Sb concentration may attain-100
mg/lifer in solutions of nearly commercial composition.
A.Ye.
Card I/ I

GUM&MA-TIMMUU. L.Y.. kajAidat moditsinakikh nank
Oraphio investigation of the reorganization of masticatory functione
foUowing osteoPlastY of the Jwl- Stamatologila no-1151-53 Ja-T
'55- (MM 8:5)
1. Is kafedr7 ortopedicheekoy stomatologli (zav. prof. I.S.Rubinov)
Leningradskogo zeditsluskogo stonstologicheakogo institute, (dir.
prof. R.I.Oairllov).
(JAWS, surgery,
postop. masticatory changes. graphic determ.)
(WTICATION,
graphle determ. of abanges after jam surg.)

0ORBANNA-TI110MINA, L.V.. kandidat meditainskikh nmik
Peculiarities of maklAg prostheses for children with cleft palates
Stomtologlia no.4:48-52 Jl-Ag '55. (MLRA 8:10)
1. Is kafedry ortqmd1chemkoy stonatologii (sav.--prof. I.$.
Aibinov) stovostologIcbeskogo fakallteta Leningradskogo manitarno-
gigly,enicheskogo meditsimakogo Inntituta,
(CTJCJT PATATA. therapy
prosthetic)

G0RBANVJA-TIMOFEYEVAp L.V.
Orthodontic treatment of anomalies of the bite in cleft palate.
Trudy L (RIRA
SGMI 6307-42 160. 15:1)
(GIYYT FAUTE) (TEETH-ABNORMITIES AND DEFCRMITIES) .~ I.

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