SCIENTIFIC ABSTRACT GLUSHKOVA, M.I - GLUSHKOVA, V.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000515430001-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 24, 2001
• Sequence Number: 1
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

GLUSHKOVA, 6ED'E'R, M.A.
Interaction between vanadyl SLL!faie and sodium ferz-ocyrimide.
Zhur.neorg.khim. 8 no.l:;247-2/,9 Ja 163., (MIR11 16-5)
(Vanadium sulfate) (Sodi-Lun fervDcyanide)

MA I i KO V v . ~' .~, d f, ~~ o I I ~: rd I ;G L,tl,,i I i KO 11 , ,M . A . ;Y! h.,)'HoVA ,M . M .
n o ' Tmf~:- ' - T,.-,iture o" Fimrrmnfu.-n .1 ~ 11 imi r.-' ilm de.
Zhii r- . noo rg . k I 1 1, r1, 1) fic) . -) 11 1146 ~V 1 W, . ( M I RA ' . 7 - 9 ,
i. obshchey i- necr~,anicheskoy ?him'-'4- imeni
E~=,akova AN S"SH.

546Af1i
Buslayev, Yu. A.-. Sinitsyna S. 8.14 tl4llkov~
AUTHOR:
Polikarpova, H. A.
TITLE: Riobium-base inorganic polymers
N
I SOURCE, AN SSSR. Izvestiya. eorgani or iy,~ matorialy, vi
?TOPIC TAGS: niobift nitry]. ch lori-de V 6 ylkit, W(-
spectroscopy.' polymer chain
d
!ABSTRACT: The authors attetVte prepare 6jobium n-
I WhClot and NM%C1 in nitxvbe.nzeue'~ ;Tht~ di~~i i fori6las; f of, It6,

C~jd 1/3

ASSOCIATION, 'Institut obabdiq I., n6o 6 '0~ i'llo.
nauk SSSR (Institute of
SG
S
RY

T T111 4
1,62927~4
W t ON) i!
ACCENidt 9 R- AP 5020504 fit' 09/06jq, iibidb i: ihwl:
6463.105,
J:
Glushkova, M. A.1 Ye i_ "i Mit:B e4 ~;iu W.;;o I
"a'.. AUTHORv 1 jj
ItI
SyntheSia of-phosphoni lp:~vh n It, f
Pe
4.0 i.,491iryl
SOURCE- Zhurnal neorganicheskoy khlmi,~
''TOPIC TAGS:- phosphonitrile, nitrobdazitnej ~c~loi-tdvj i!Pot1r"4j I" t 1;.
I T7
f P6,`I,
'ABSTRACT: Phosphonitrile chloride irasisynthesjz6d in
ifif 4r_l (1- V-. The reaction was earried bout, a~~ lilbi..j qjjoc~i~ 4~t d
w as 70% form6d~"may,be* r~~r~son ioi 6
The composition of the p
i'1..:.;_1 PNC124 -The crystalline niass formed ap0a6ontjy_eP16s#t 0t a t,
pire ii
and tet er'of 01 the:; rmb rAkel 6ijbst 14M~Tbi
ram phosph iitrile cfilo~
el
a miitLm of:phosphonitrile chlor16~ Wth aihijhei,.,0~&e0 of. I'Vmeol,
-bon'in the rubberlike~ "pound, 4, teat
presence of car I 61~ii;11~
e
anges the synthesis, and thot~ltfi6 ptod~cis oz~its, d pbsi~ ra#1 "q
41, flail
hined 41th phosphonitrilt- chloride.: ~The 661iibillAy 41~m~y!! 1:. lot
Wes -in nittiobertzOne makes it sblbie~ ~-o I ti U0-::P1 hos; le dd,f
PO By
cc
rd i/2

GIUUSHKOVA, M.A.; YERSHOVA, M.M.; BUSLAYEV, Yu.A.
-Synthesis of phosphonitrile chloride in nitrobvnzene.
Zhur.neorg.khim. 10 no.8rl943-1945 Ag t65.
(MII~A 19:1)
1. Institut obclichey i neorganiche,,ikov hirdi -meni N.S.Kurriakova
AN SSSR. Submitted November 13, 1964,

BCRIUS"YA, B.D., doktor meclitsinskikh nauk; GLUSWOVA, M.A.; MM0IYNIji,M,I-
Some factora indicatins, rou-d fiirictton brd ~hlcri(ie metabolism
durirM, sytitematin intFike of lir,,,o-lzhmvtik mirierxil iflitar. Urn-lol'its
22 no.6:5o-~4 i-li Ir,,(,. OIUR~ 11:2)
1. Iz p rope davt ic hes koy terapowtit-Imskoy kliniki (rev. - orof, A.Y-9.,
Guber-rits) Izllevskogo meditsin,,,kogo instituta.
(KIDNEY FUNCTION eff . of dru,vsi On
mineral wit.er from N,,v(dzhmvok)
(CHLORIDES, alfit-cil).
eff. or Novotz),.(qvi3k mln,-rol wntmi,)
(HIMUL WATER, off.
llovotzhevsk mineral wat,~r, on renal funct. Fir
on chlortan m,,ittib.)

GRIGORENKO, P.G.; GLTJbHKOVA, M.I.
Geomorphological characterlsties of the cotton zone of vouthern
Xirghizia. Trudy Inst.geol.Ail Kir.SSR no.6.-179-187 '55.
,raphy) OGIRIL 10: 2)
,hizistan--Physical geog
(Kire

GLTJSHKOVA, M.I.; GRIGORFJfKO, P.G.
Tha Osh Karaffu Oasis; outlino on phynics-goagraphIcal conditions.
Izv.Al Kir.SSR ne.2:101-111 '56. (W.,RA 9:9)
(Osh Kara3u Oasis-Phy-sical geography)

GLUSAOU, It.
'b'.11of aTjl :ionfj agric,iltiiral chAracterintic.,3 of th~ foothille
i-~gion o,' Osh Province, Kirghiz 3.S.H. Tinid,
Otd-.0-og.1 2ian.
fiz.
Kir.SSR no.1:117-1`7
(Osh Pro-vinne-Phy3iral geo~7~L!))V) (09n

GLUSHKOVA, M-I.
Main features of the orograp, and --eomorp~,olo,-.Lcal di7i9ion of
i 1y - -
the 3outhern Kirghizistan. Iz-,. AN Kir. SSR. Sez. est. i tekh.
nauk 1 no.2:21-33 '59. OURA 13:9)
(Fergana Vtdley--Physical. reo,7--tphy)

GLUS,'IKGVA, M. I. ; GRIGORMO, P. (6
Natural conditions of the Batken deoression and prospecto for the
utilization of its underground viaterg. Izv. AN Kir. SSR. Ser. est.
i tekh. nauk 1 no.2:53-62 159- (MULL 13:9)
(Batken Districts-Georraphy)
(Batken District-Water, Underground)

GLUSHKOVA, M.I.; DANILINA, A.P.
Main features of the relief of the southwestern i3lopaii of
the Fergana Rvmpe. Izv. AN K-Jr. SI-R. Ser. es-t. I te)(h.
nauk 2 no.10:1,9-60 160. 17: 3)

'ljLU',;HK0VA I ~,!. I . ,C A f i D G 1: 0 0 '--, C I p"H AT U 3 AL Cori 1) IT 10 .14 5 OF
THE PIEDMONIDI'S OF THE SOUTHERN PART OF CjSH".KrY, LIBLAST,Itl
CONNECTION WITH THE DEVELOPMENT OF COTTON GROWING." t,103-
Covil l9Cl.(A(,AO SGI INST OF GEOGRAPHY). ( KL- F)V ,
11-611, 212).
-55-

GRIGORENKO, P.G.; OTORBAYEV, K.O.
Natural conditions, hydrageological characteristics, and ways
for the economic util-itation of the Kug&rt Valley. Izv. AN Kir.
SSR. Ser. est. i tekh. naak 4 no.3:83-100 162. (MIRA 15:11)
(Kugart Valley--Geology)
(Kugart Valley--Economic conditions)

K -J r g.,

I; , ! , . : ly. ;I " ~-
DERENITSKAYA, V.V.; GJJJSIIKOVA, 11.11.
Dit)hwiie me,-d,woi!n(-eiphnlitii In Monrow Provirt(le.
i immin. 2) -,10.2:10-44 F ' -)q. (MIRA 11:4)
1. 1z Moslrovqkoy oblnstnoy i-initnrno-m)idebmiolo.,ric,ir!31,-oy qt-ltoli.
(I-MINGOUNCEPKALITIS, epidmmiolopy,
diphnsic, in Russin (Run)

c t,t~ :1, ri
!"I u s C,
k (D

.............
mi i i
Tj

c, L u.s H K ov ~,, ~~. A,
/p~whlte-muscIodlwam*lnc#l9-m A.P,Oneg6v,Ti.F~' I
AtInIkov, ind M A. Glwhkovi (Agr. In Elroy). -J-
-- vacri-r~ya 33, ix"Iled while.
muscle disease in mws, calves, itntl pip Is anzatic, and Lt
connected with deficitucles in CO, Ca. Mn and 1; tlb* vitl.
: ~ min A, B, ,and C dcatiency is a contributory factor,
I . G, M. KCmI3J!aty -

.OrTle"'i
c
L'.-.c) r
I-t ; !~irav
r7i tj~-
[~Ce 0'
in
-3 f '00 -1~' I i(-,n with.
fr,'o'-alt, oT-er ~in~i. Icline) or, a f
I-lood and iroductivity of
Crj,~~ 7-,,. , 1. ~, , ;-I ,
s t ni c t s -, c o n (I r c, uo f
tion to tlie U ;.i!~
~-Jvell dailv per 3 of' 7111c),,` le
a I, cl a f c 0 p r t p
(60 -.a~-, given :)I' in

Ca,d 2/9

A
0
T'On7420 WURCZ CODE: UiZ/3213/66/000/003/0129/0139
,%;J""::0R Glunhkova, 11'. 1.
A method for forecasting hail and torrential rain
~;O'U;=: LonirCrad. Vycokogornyy goof iM.cherkjy institut. Trudy, no. 3(5), 1966.
zm obra.-.ovvnIIya i vypadeniya grada (1-fechnnism of tho fo.rination ant) proci-
pitation of hail), 129-139
T
MPIC TAGS: hail, rain, cloud physics \A C IA
A 5 ST RACT :VG1, throuFh a careful study of t,-Ie procesc;pr, of prec-.ipitation form. atioP,
ln,ac developed a new method of influencing convective cloud,-, in order to prevent
hail precipitation. The conditions necesnary for hail formation are listed, and
wore used to construct graphs which tire the basic, for determinin,.: the type of pre-
cipitatior, to be expected for the particular condition prevailino. A mass of aero-
,ynoptic material for days with hail and torrential rainfall in the northern
Caucasus, the tranG-CaucaGua, the Ukrainian SSR and Moscow Oblast' was assembled
and analyzed in order to verify the correctness of the conditiona established for
the graphical construction. The resulto of the analysis are charted. The high order
of vindication of the method confirmed the correctniss of the physical prerequisites
Card

09307-,~)'7
ACC- NRiAT6027420
which are the basis for the method, and, accordingly, the correctneas of the ideas
on the mechanism involved in the formation of torrential downpours and hail de-
veloped by the VGI. Orig. art. has: 12 formulas, 6 fig,-lres and 3 tablos.
SIM CODE: o4 / SUBM DATZ: none / ORIG REF: 007 / Cfrd RF2: OW

USPENSKAYA, L.N.; GJITSHKOVA, II.P.; BNOW, A.G.
Reciprocal solubility of salts in the system of ba-rium and calcium
chlorides and nitrates at temperatures from complebo freezing to
+ 00. Zhur.ob.khim. 25 nc.9:165&-1673 S 155. (KULA 9:2)
l.Rostovskiy-na-Danu gosudarstvanny7 universitat.
(Barium salts) (Calcium salts)

GLUSHKOW, N.I.; LUCH&VA, v-,-,
Forecasting showers and hail forming in air-rzasz: cuvii-ilus rongestus
cluds. Trudy Vysokogor. geofiz. inst. Ali SSSR 2:191-198 161,
l,-':1-2)
(Precipitation O'etecrology))

YA-KOVLEVA, 011ga Sergeyevnaj GLUSHROVA, R.V.) red., aIDTIOVA, M.Ly
tekhn. red.
(School experiments and laboratory work for the cow-ne in hwron
anatomy and physiology] ShkolInye opyty i laboratornye zaniatiia
po kursu anator-ii i fiziologii cheloveka; posollbie dlia pil)poda-
vatelei biologii srednei shkoly. 2. izd. Flosk-va, Gos. uche'Mo-
pedagog. izd-vo M-va pr03V. BRSFSH, 1961. 167 p.
OVILU 15:5)
(Anatomy, Human-Study and teaching)
(Physiology--Study and teachings

Chemistry. Synthetic OrGanic Chemistry. E-2
A~, J-rur: Rcf Zhur-111iraiya, !!o 6, 1957, 19254
Author Dolgov B. IT., Golodnilov G. V., Glushkova !I. Yc.
Dist ~ , "~ ~ fil "I -' L
Titl-] Convc~rslon of Te'vraothylsilane over a Cbror-lium C'--.tulyst.
Orig ilub: a. obs*.ich. hhimiyl, 1950', 26, i!o 6, 16138-i6gi
Abstract: A---, tot r-i:~i.-hyl s i lane (I) over a chrc,mium catalyst
11,;) i!3 dQc,-)Lmoscd intc
C) enjimeo ~iith
~u 6~0 ~J3 a Cucr hyd-,3,
"w
n.'p-11011 of' UA and Si. Dehyftatiori of I to triathyl-
vinylsi'.-ne is riot observed.
Card : 1/1

J
go'l E N Khari o no 7 -2 1
A i 0.,S Do I i
';I ushkova, 11. Ye. , Xhudobi n, Yu. I .
TI PLE: Cat aly t i c De hy dro C orid r,sa t i on (:1 th t-- 1' 1- 4Li
Wi 'h Al co ho 1 .9 i n the Pre se nc e o f 1.1le ~~ 1 CKlo ri d E~
- K-1 a I V
Ka tal i t j che skay a A---gi i rok.o nde nc a t s ya f 1~4 j ' ~ j So
~3p-irtami v prisul~3tvii k h I i i o
PEHIODICAL; Zhurnal obshchey khimii, Vol 2~~, :.'r vp 7 10, - 27 1
USS.R)
ABSIP~-I'ACT: 'ie -authors continued their i
1:aper on the catalytic dehydro cond,--nsatton of Ili- atiovt-
mentioned silanes with oxy, oxo and
Eariier they used alkali alcohollates as for ~il-4 s
condensation of R alcohols (,yiel,-.s
3S'H W'tl" In -,ne
present paper moreover come small additions- oC v&ricTj3 m,
chlorides are used, of' which ZnC12 and 1:rov-~d to b- the
~,e 10 C 4 ty o Ij S W
most active. The reaction - h alcohols
depends on the nature an-,4 the quantity of '"he
1 d
increase of the amcunt of ch-lorides
~o t-e increase of 'h~, -eaction v-, i - i- t f'-I h r

Catalytic Dehydro Conden2ation of 'r'rlalkyl, Sllanfi-i
With Alcohols in thi, Pr(-.enco of
triethyl. silane at a ratio of 2,. 1
increase in length of the alk~:l raJ_':~at- rom to r,-~'I;il
I - - easp a:; ~. 4~ (v
in alcohols ol normal s'iucture decrt the rc )n
('.Pable 2, -Experiments 1-3, 5). The Ji-f,'ic--itiez in the spat-_-11
arrari,i,-ement in the of th,? radica*..,~
structure consi&:. L! 1~?cri?aao tho
rfh-~ stvucture of t: i a I ky I !; i I i It o o x-r ta 11 it r:1 p c1 It
influenct, on the _- actIon
alkox o '~vhich are n; w,
y silanes, 7
ph,vsical propertieg (:,- -,ho newl- synt'hosi::ed
-mil,ines ar;~ Fiven in ta'ole r-_
character for th,-_o F.]'Koxylali(~n the Si-JI hond, %nill
rossibl.-, '0 obt~i_irl th.,, trialkylalkov.%, -Sil,:~-.~,.-- ii,. pur-
11D Side prodU2,-s al- !"')-m-d. are tl.~!!,~'.I-i
2 of -,vhich are Soviet-
AS3GC1A7_IO:;: ~nst4tut ',himii sili`,~tnv Akademi4 n_-_,l S:5 E'
(Inst_;tuto ut' th., (,h~!mi +h,-
Sciences, ',SS;wl)
Card 2/,-,

Catalytic Dehydro ",ondensation c-f the Trialkyl "I'lanes I', -' -11, ~11~
With Alcohols in the Presence of Metal Chlor~~des
I
i
SUILIMIT" ED: July 29, 19/57
Card "," "

AUTHORS
TITLE:
1/012
DoliLoy. B, N, , 61usai~ova, N Y,? Mlarit'ol~:1-1' N1)
Some FroFerties ot p-TrimeU,.yl-sil 1-berizal-johyde
PERIODiCAL: Izvestiya Akademii nauk SSSIR nauk-
1960, No c', pp,
TEXT~ r, - t rime thyl - silyl .-be nzaldeny de Cives rea,,:t_jns sje,:.if_Lc for the
Carbonyl group (silver mirror reaction, rea,~raozri witn Schifrls reagent)
and addition compounds with sodium lbisulfite, 2,4.-dir-.1t,-o-p,,enyI
nydrazine, semicarbav~i_ie, hydroxylamine, afr,:-,ionaa. and a::onia-'.ic amines.
In their experiments the authors obtaine.-i tne b,-sulfate com.7~)Cllnd' the
semicarbazone; an~.i the oxime of the
tr'~--(P-Lriir,etnyl-si-l,yl)benzal,4i,..ir.in,~ --it-id the p trimett;yl
aililine, Metiiod of preparation and zh,~! ,.oi-,:1,~urids art.
described The autnors believe ti~at. tne preFararlion
~of ~Cle' triphenyl -metnane 6uries -ii~ 1 1 Le Tnere ar---
t ~.ining d'12s
roferences ~ I Soviet, 1~wd -5 1!. -Ari i
Card 1/1~-

Ij 00
liwtitu,'~ I-iiim L .)i
fit, ti 11 Ct2
S Uicatt~ t'. '11r o o L r, e
SUEMITTED~ -July 2, 1959
Ca,~d 212

I

25~)L3
Con -I ens a ti or. of rir e t.h:,,l
Yu F I ,, t nk (? I f or nill
There are 6) references: 5 Soviet-bloc anl n,l-,i-S,-~-vL-"t-blol,. "he two
references I an - i e -11C 1, -1 C:lt)"'0 NS
T. 1-1,1,9 1 F~ T
J'2 ' I - . *t
R. C. S~vers;-'n, F-. 1 R~) s
Soc- 1'95 , 514 2 e t I mer.
Chef.-.. S-Dc.
A S) 'I" OC T!, T T 7tI
Ch,~mi!!'f: ol
Carl

GLUSHKOVA, N.Ye.i KIIARITONmr,
Interaction betwee?. and
compounds. Izv.AN Sf)')R. Sor.khim. Jrl
1. Institut khimii silikatov im. I.V.Greben3hchikovq
organomagnesium
1 ~,4.
OURA 17-4)
AN SSSR.

a ,
GLUSHKO111%, IT. ye .;KHARITONOV, N.P.
Heact.~cr. of p-tri.-qethylsilyllf-,,n?,alfir-i~-rde acids
deriwitivec. Izv. Pd: SSSR Ser. khirl. no.11:20'74-'l-'C'7(` ~: 164
u!:1)
1. ILE:t4tUt 1141~ato,,r jjr, P,' 'ISSR.
- I ~ , -J,. - - - - .

L 31803-66 Z,,7 ( m ) /ET "' ( fE*--ii,jA fe!/DS
ACC 11R: AP6012535 (A) SOURCE CODE: UR/0062/66fOOO/OO3/0564/0566
AUTHOR: ~iushkova, 14. Ye. Kharitonov, 11. P.
0 RG: Institute o Chemi.,-,ti7 of Silicate.,.; im. I.. V, Leny- 0 f.
j.jzY,.,A
Sciences SssR-Onstitut khimii siLikatov Akademii nauk SSSR)
TITLE: Reaction of benzaldehyde with alkyL (,iryll chloi,051ilanes
......... . .......
SOURCE: All SSSR. 1zvk_-stiya. ,'eriya khimichesk_iy~i, no. 3, 196b, 564-566
TOPIC TAGS: organic synthesis, silane, silicon compound, UV irradiat-lon
ABSTRACT: The present r-pro(luces the prolimin,-ivy results obtained during the rcac-
tion of benzaldehyde with phenyl trich lor-is i lane and tnettiviplieii~,ldic,iloi,osilane and
studies the effect of temperature, ultraviolf't light an(! NiC12 on triese reactlons.
During the addition of excess benzaldehytie and irradiaticnl~with ultrav_:olet lig'r,t
Zor 12 hrs, the main reaction products were or,iT;iriochlorodi~il-D):,l-ies. was foimd
that during ordinary heating of the reaction mixt-:re for 20 hr!, the li~action pro-
ceeds to the extent of 5-7%. The addition of catalytic amounts of NiC.12 increased
formation of organochlorodisiloxanes (under the same conditions) to the extent of
Card 1/2 UDC:_ 5L~2.91 + 546.2B7

L 31883-66
ACC NR: AP601253'j
9-14%. Whon SnC12 and, in particular, ZnC), ire ti!;ed a-; catalp~ts, tile reaction
mixture turns to tar. Ultraviolet irradi'll-ion al-";o helps the rmction of tile forma-
tion of organachlorodisiluxanes. In all cases CGHOiC13 -Ls nvn~ reactive with
benzaldehyde than (CH3)(C6t15)"Cl2. During the reaction Of P-RH3)CC#7,Hl,CH0 with
C6H,SiC13 and (C113)(COO'~iC12 in the Pl'esl~'nce of NiCl-) (undpr conditions simiilzir to
the reaction of benzaldehyde), the yield for both chlorides was higher. As a result
of the conducted reactions two oi,~l,iinoclil.:)i,o(lisilox,iiies wore iGolatod an(I character-
ized: 1,3-diplienyl-1,1,3,3-tetrictilorodii,.i.loxzine and 1,3-dim(~tliyl-l.,3-(Iii)lieiiyl-1,3-
dichiorosiloxane. Orig. art. has: 2 ta~)Ies.
SUB CODE: 07/ SUBM DATE: 23Jul65/ ORIG REF: 003/ 0111 REF: 005
Card 2/2~`~

KAZITSYNA) L.A.; LOKSHIN, B.V.; GLUSHKOVA, O.A.
Determination of the nitrile group from infrpred spectra.
Aminonitrile hydrochlorides. Zhw-,ob.khbr,. 32 -no.5:1)91-13`15
Yq 162. ('MIRA 15:5)
(Nitriles--Spectra)

OKUNTSOV, M. M.; GOLID, V. M.; GLUSHKOVA, It. 1.
Participation of xanthophylls (violaxanthin and bl-te-in) in the
process of photosynthesis. Nauch. dokl. vjs. shkoly; biol,, nauki
no.3:129-132 162. (MIRA 15-7)
1. Rekomendovana kafedroy fiziologii i biokhimi-i M'stenly I
laboratoriyey fotosinteza Toms1cogo gosudarstvem--ogo universiteta
im. V. V. Kuybysheva.
(PHOTOSYNTHESIS) (XADITHOPIIYLL)

L i6lA~-65 NTMA-UP(e)/E PA(s)-2/
~7CPTCJ/1-1;8-D(dp)/ESD(gs)/ESD(t)/,',SD(a)-5~ 4S
onpl- I fi) :'GG a
ACCESSION NR: AP5000290. 0/00.7o/04 .05 ?),006 01 64/0~69
AUTHORS-. Z L 14
M~bov V~. q.; FJrsova,: 14.;.
1u ov N,X.:
,~Lkq
.Rl c
TITLE: Kinetics of the variation.of~the:*di e tric! ib'nst Of
quartz under the influence ofa:constant L*14-116tri~c I)d
SOURCE-. Kristallograftya, v. 9~ no. ,6, 196,4' 13~4-60i
ctric:'. cons
t~TOPXC TAGS: quartz, diele t&nt~ toloperat6rilf: vai.,4,1~
impurity content
ABSTRACT: This is a continuation of:an earlier~ i4v,"ei gf~ji i n bk thd
authors (Kristallografiya v. :8.1 No. 1.,, 112'4-114i~r 14 6! otijt e in.
eratur~e variation ~'of the ~d 10 t
lous behavior of the temp ect![ q, onst% t
10 1 tjj~
f quartz. The present study,: is: devote :-~'ito':!' t iriei-j 9,;
633 o..
ndi 0 Li Me ro~ 1 ~k6s)
variation of the dielectric donlstant:~at If re4ue ill,
when a constant electric field Is applied.j The' teis 14: we i.
300--700C, and the setup empl ed is iliustrated Ji~' 6i;!Lg. I !,of the:..
0Y
Card
1/4.

L 1638,
U63
ACCESSION NR: AP5000290
enclosure. the res ed ~i; hithe
ults have disclos rio kjW1&sejvj1q
p enote, q
amely that the dielectkicl! con'stani~
non, n
following the application of tb~ :coni trid f `4!ld~' Pisses,
e E~Y'lt 6iec
a
through a.maximum, after which t: de#~~Ls'~4!iloi4l~,, a, coral's A
responding to the dielectr cdnstant, a room tern hj-.ur0!j
ic
mpern-4-!
Value, form, and time of reacbi~ngpthe m~xirol'u~'t
tric field !6poii6d.!~,
ture and gn the elcc ir10ndo]6-,'-
troversial interpretation of :all'the~ dbi~br~e voqtii~ gjcitl~'
o* fA.~ F.: So0b ZVI' JP01:rc;
:.made,only by using the theory . . . . . . . .
It
politekhn. in-ta XXIV, 1915, p~., 62-126.), !whereby ~e, j,, pj r y, 3-on
which.,are.always present in ~h,6 quartz, ~:~ eni6r~ c4i ki'l
structure of the crystal. These diss nt~
mobility to-participate in all the e eo rip, prOceOs od ring J. n I
the crystal when the electric field is, -appl ;ed#':~
figures.
osuftratvenny,', y
ASSOCIATION: Moskovskiy 9
~'N
Card 2/4
7'i

-77"~7
L 16583-65

ACCESSION NR: APS000290

L0monpsova scow State tlrnive*qit~)

~SUBMITTED: 17Mar64 i E~

~SUB CODE:
SS EM sov.
NRW

4 0
064fi
U!

Card 3/4

its pro-i-ndvs, and eit-
o mriIi-, yz~ ,I'll
- 41ilj
T,
f'y t1"'r I' CIO, ,1 -;;:9-
vier 'n ()o pt, ~m~ of 201 ;'tm.. jj:'~ a t'!trlig~:al
~ I c - lit '. of tile elealvilvilly
..It I till'. .111'I III, ~~ nj
, - -) -" ~ kra .. .1.3~ 1- ~~: 11.15 A. (C"'I
"he V, ;I colit'li!1~ I:mIll.i lm't 8Wltolw.
i4 Nrrom:'gllcti~z lit!) .' I. Vw.~" 4 113", VaIllef 0 the
Jljov,! Lit(: (:title U.11111). 5110Y CULI
tile Coll . 1. ;s ;- tru.. am no" Il nlixeLl Olide (k rx)
croo. 'ne etitii on. lor oii~ iormation (if po~ ii mi).4
ch
...... .. . ... ------

ARIYA, SM.- SHCHUKdEV. S.,%..- GWS,iKOVi,. V,B,
SubliwAtion anthal,) of rhrmnIc tund an.'a"dr-jel!, Zh~lr.
y . -
ob.khl-m,2) no,12:2o6).-n?)6 D 15), OITR-k 7.;))
1, Lenin-,radBkiy Gosudarntvennvy ordena lo-3rina univareltit im.
A.A.Zhdanova. (Entlialoy) (.inhydrides)

Category: USSR / Physical Chemistry - Kinetica. Combustion.
Explosives. Topochemistry. Catalyais. B-9
Abs Jour: Referat Zhur-Khimiya, No 9, 1957, 30039
Author Keler E. K., Glushkova V. B.
Inst not given
Title Conditions of Formation of Barium Silicates
Orig Pub: Zh. neorgan. khimii, 1956, 1, 11o 10, PP83-2293
Abstract: By means of thermal, chemical, x-ray diffraction emd microscopic
methods of Rnalysis, it was ascertained that on heatin4g of mixtures
of different composition, of the system BaCo, (I) - SIO.._ (II),
regardless of the composition of the initial mixtup?, the inter-
action between I and II begins only at 700 0, with formition of bar-
ium metasilicat~ (III). At temperatures of 8000 and above,"jarium
orthosilicate (TV) is formed. In mixturec4 containing mucli I
, at
about 10000, is formed, in addition to IV, also tribarium ailicate.
In mixtures containing much II, formation of III is observed only
Card 1/2 -13-

Category: USSR / Physical Chemistry - Kinetics. Combustion.
Fxplosives. To,3ocherdstry. Catalysis. B-9
Abs Jour: Referat Zhur-Khimiya, No 9, 1957, 30039
above 11000 - Forma7dor of Ba-Si, 0-, and BaSi,-O,.-y by rt!actions
in the solid phase, does not occur.' It was found thal; decrease
in volume of samples of I, whic-h is noted at 600-8000, is due to
decrease in porosity as a result of collective cl-ictallizatiom,
and not to a polymorphous transfoination. Increase in vol-'une of
samples of I and II at 1000-1200 0, is due to increase in rorozity
of the samples, as a result of "swelling" of emitted CO.~ in the
presence of liquid phase, and due to the fact that the reaction
products have a larger molecular volume than the initial substan-
ces.
Card 2/ P

IF
t4.o

A,JT H 0 IR o n c. v en
f L IE Diss,!rtat i ons
l3ranc'- o-, Ciit~
r,au',-
D a
1
`2
e 1. t,-.L t, s i.;
-'ci,~nces (Otde~ien-.ye
P EA 101) 1 CA L Vestni~l
A t f E t
d
-0- L'If- d 1, 0 e -a C -a, i i i d a t e o f i ~3 c i c! c e o
V B Glus n io n o th-:~ I rit. :!r,.ct ions In
--S (, I-l' h as .3 -, t, w u (? n S _i 1 i c a n. Di c) x i d 0 a n d
Ox i d L; , A s V; e 11 k o, C n r b c T i f i t e -; a f C - --, 1 c i '. 1m, ,
C.,, i t i u ia a r. d ~] --I. ri u i.-i . ( I z i i c !,. i~ i i y e v:: a i.-.i o
~; t y ri v t v .! rdlyl~; 11 l'-i a !~ i i . 1 - (I. u ~.v a W.- j, z =
okis'ai:,.-, ;Lftri) )natau.ii
t r o n t a r a
Card 1/4 ;1

J., I
o1' a ll'art 'ic- r
I
N al, - R 1) F - 13 1 t:~ Awl-'(Wy 10
A
v ",:,e a idzi t e c) f echn i cal Sc it--nces
A Kiyler lnv,-L3t-J,--uticr, of the Ccnfi,uration and
',,~.'stallization of Ash-Cciitainin.- .3late
A:3 i 0 11:-, (Issledowajjj~,e 1;rotscTqov o IDrazovan,.ya
- yk
1 1~ r i s t a a t., i i i !3 '- a n ts (! z o i n - .-a s p I a v o,,
A t t lie Ins t i tut c. Chi-mical i ~1-j i cs !: Ins t i-tut k',1 i=
.:i i ch. es, k 0 y f t 1, e f o 110 'N i rl d~-,;Ser-'ati-,lis were
def'Landed:
for the dc---r~~e ol a
Doctor of Technical Sci t nces
A N, Voiriov - Investi(,atioil of the 1)(itonation 2nd of tln--
Spontaneous Ignition Jnd(!r of -a
(Ia,;ledovaniye -'etonatsii
v U~l 0 v i v i -a I a
Card 214 1 t. " l.: o,,-- o t 0 1 i v a

Diss ---rtations Jranc~j r - -r ' U i f., -..,; I -, - ';P, -, - , ~ /~~ t;
jul~--December `~57
h ) for ;~Iht2 of a Candidate of Gheiiiical scienc-:k
V, 1 7 e d e,-, of the ilrea~" of Comi~,~'-,ncs
--ind T~i,~ir Utili~:rltl"')n
in cllci.-~ical Linetics.
sv-,,17ey v
h ig::ol. I zova., i.Y(! V
V') Cor tht~ dei-'ro(:' Of 11 C.-I I I (I i (1, L tC 1: t
"al "c italic us -
Ye L Frankf--vif,~i - 'L::v~:-.it:,' - ra
of Ele-,lentary Ionic--',o.-Lc-.I-!ar
Processes in the ~as ?IhaSe- (Mass.
,g pektrame trichuskoye ~L:le(tovaniyp-
protsessov v -azovoy faz-~-)
7) At the Hadium institute J-meni V, :; KI -, I c~ 'p i -I ai~dE, iy
illstitut it G ,K1110pi 1111 h, e f o I I ': V; '!j
t L' t i 0 nS fO V tI " d, L, I" I, e ~, o I,a C a ni d a + e of cc.
Card V.' si~lf`ncf?s "Nerc, C. I

Dissortations Br a nch of Clip i-ical Sc 4-1 encos 2
July -Dec 1 )D- 7
K , Y~. ',.romov - Conv~2rs i a n E I ectrons of Lut etium. a nd
Thulium Istitopes Deficient in llt~utron--.
(KonvE!r,910:111yYe neytronodofiT=
,iltziykh izotopov 1, iitetsiya i
Y
x k3 a
0., V. Parzticloz) in 11, c1 . I-
~3ions Caused by Protons nith an !-Ai;-Ir,~,i ct'
5oo-6oo -'IeV. (14no-ozrirkls:.dnyy~~ chastit~3y
.I yadL~rny.~h
,)rotona~.-- s ener,iYeY 3cio-U'o---)
1. Chemistry-BiblioGraphy 2. Bibli o f,raphy---P,'_-eiai s try
Card 4/;1

'- GLUSHKOVA, V.B., KEMR, E.K.
Condition8 of the preparation and rateo of forr.,gLtion of barium
silicates. Zhur. neorg. Ichim. 5 no.4:882-890 Ap 160.
041RA 13:7)
1. Institut khimii silikatov Akudemil nauk S3611.
(Barium silicate)

I.J -It.
Li
liz 100 A 0:~: 7d /A
AUTHORS: Sergeyeva, V.I., Glushkova, V,B,., Keler, E
TITLEs Physical and Technical Propertleo, of Bariu!:i urvi St.r:)ntium Si_-Lcatec~
PERIODICAL: Zhurnal Prikladnoy Khimii, 1961, Vol, 5~11, No, 1, pr', 2'2-214
TEXT: Synthesis and sintering of single barium and s-.rc-ntium. silicates with
1-1 'Alyll
mineralization admixtures were invest;gated, and tick -cal and -echnical
properties of the sintered samples were dete:,mined, C,)ncr~~tes containing
these silicates have a greater resistance to sea water, they are heat-resi!:t-
ant and have X- and gamma-ray shielding properties, 3esidttC-, these silicates
are used for special ceramics and -ohosphors, Neverthelt,s!, they are insuf-
ficiently studied. Hadley et al. [Ref,2: J,Applie,~ Physic-1,27 11,1384 (191,6)1
briefly reported on some physical propertieg of barium orthosil;cate~ The
present authors determined in previous investigations Eia~ T' 3 , Z h1TKh , I , 10 , 2_28 3
(1956), Ref . 4: ZhPKh, 30, 4, 517 (1957)] formati on condi tions of 'Lari~am- arid
strontium-silicates. In the present work the silicates wer,~ syrith,~sized f-om
dry silicic acid and barium- as well as strontium-carbonate in silite over--._3
Card 1116

22532
S /o eu/6 1 /0 1/")! -t "'oln
A 0 5: 7 /',, 12) ~"
Physical and Technical Properties of Barium -nd Strontium 311.1cateoz
at 1,2000-1,4000C. The 3intered material was milled by 'batches aft,er cach 4
hrs of sintering, briquetted (at 200 atm pressure) and sinti--red again to a,~-
celerate synthesis of the componentq, Duration of th-~ qint,~:711ng pro-
cess was 32-56 hrs. The synthesized silicattjj: Were OICIV, ,I i'-n d ;7,:- t I c I es we 7e
pressed at 1100 atm adding 7-10~o of kerosene by wetght to iocreaii(- 1~i:iiinatl~n
of the material. The articles were fired at different 'oemp,~r'lture::--, and ti'le
physical and mechanical properties were determined, In to o--,)tan 3amp-
les of small porosity, mineralizers M12CO3, BaC12, :]r.0, Fr('l-), MIg-T,~, B-)O~,
and A120 3) in amounts of 1-1.5% of weight were mixed with the~syr.th;size~d~,~i-
licates. The strongest influence have A1203 and B'203 admixtures latter
on Ba2SiO4). They form a liquid phase at 1,3500 _ Iii1000C by neltin,~ of the
eutectic in this ternary system. According to these result;. Al-
)C)3 and B207
admixtures were used to prepare sintered samples, Physic;ll and te,-,hnical
properties of the investigated Samples demonstrate (see Table) tliat, additiOnS
of A120 3and B20~ in the amount of 1-1~5~ by weight decrei--9,:! porosity, in-
crease mechanical strength (except Ba2S'04 4 1~"~ B~O~) and th-~ n )Julijs ofelastic-
itY and bending. A1203 admixtures practicl.111Y !,)' not, th,:
Card 2/6

p
!10,~ 0
A 0571 /'A 12)
Physical and Technical Properties of Barium and Strontium Silicates
3istance of the material. The dielectric constant increw3es -1,,ith B_a0- and
SrO-content in the silicate. Barium silicates have a lovior tempe~rature co-
~ ttiori demonstrated$,
efficient of dielectric constant. The pregent invesi~-,
that improvement and in6rease in mechonical properties of bariu-1- and stron-
tium-silicates were effected by sinterin(; rith admixtureo of raineralizers.
There are 1 table and 4 referenceq: 2 Sovi(,~-bloc,, 2 non-Soviet-bloc.
ASSOC T,%TION: InstitLt khiriii silikatov AN.SSSI Tnst-itute for Silicate
Chemistry of the AS USSR)
SUB11ITTED: "lay 10, 1960
Card 3/6

I I
1-1 I'll' EY Ell k., 1~rof., dok,(lr tekhn. r-uk, otv. riA.; BUDNEKT
P.P., -kadeirik, red.; WiDFO' , N.A., rf~d.; GLlJ.'i'HXOVA.,
V.J., kanti. khim. nauk, red.; ZU"'INA, V.F., nallcKyl. red.
SllicatL,_~. and oxides in the hili'll
Silil:,ny i O'Ki"71y v kh4-r-..ii vyoolllkh In-
Y~63. 3&- r.
,,la
" ;,, 1 .1
de-iyrt rauk Ukr.SL~: (i*or
k
Ll" USSR (~,_ir Toroyov).

BI 17/D I 8b:
AUTHORS: Toropov, N. A., Corresponding Member &S 511, ~-',lashkova
S W.
V. B., Candidate of Chemical Sciences
TITLE. Silicates and oxides in high-temperature ohemistry
(Conference in Leningrad)
PERIODICAL: Akademiya nauk SSSR, Vestnik, no. 3, 196 p 134-135
TEXT: From November 21 to 24, 1962 a oonference took ~1)1.aco in Leningrad
on the -Ludy of the behavior of substances at hij~h ti.m:j)ora1;%tr(.,s and on
pertinent oxperimental methods. The conference had beon convened by the !i
T i3titut khimii siUcatov im. I. V. Grobanslichi kova Aki0emii n;flttk SSSR
(Astitute of Silicate Chemistry imani 1. V. GreljonshoM Ito it ol' the
Academy of Sciences USSR) and was attended by repri.,iientatilrj~S Of 82
scientific research institutions, universities and, industria'). enterprisc~
from more than 20 towns of the US.';R. The director of Wic Inslitute,
Corresponding Y,ember If. A. Toropovf gave a survey on t~.,w pres-ent state
of the investigations into the physical and chemical p.roperties of
ceramic substances in the USSR. N. V. Belovi spoke about the tr.Vstallo--:
Card 1/4

Silicates Lind oxides in high-...
s105016,3100010o,:1,10131014
B1 17/F318k
chemical explanation of sonic characteristic features :Ili the behavior .01
oxides at high toniperatures. S. 11". kriya and P, IiNirozova dealt with
the rules j.-overning, the chapUrs in phase composition In systwis
I'transition metal - oxygen" with tonporatuz~,-, ina:,easc, Tho oynthesi;3 lind
the properties of compounds of rare and rarc-carth elin-iiento and. the
effect of the t~iseoua: medium oil reactions in solid pliase ill systems with
oxides of different valencies vav; dealt with by A~ 1. N. A.
Godina, I. A. 13ondarl, V, A. Bron, N. V. Somikina, '(a. 1'. Sirial!jna. The
+2 +2
effect of D''L Ca and Be ill quantities of 0.1 - 0.5 A011", the
kinctics of mullite formation in alum:)silice-to mix~ure!j j:)intly
precipitat~-,d viere reported by F. P. Badinikov, T. N. A. V.
Volkova. 12hi-, --tudy of silicates of t~i-j alk-alini, ea-Pth was
6escribed b,,,- G. Grebenshchikov, L. Ya. A. i~. 11,01-jakov,
YU. P. !~-OV. Studies of Ule th-ormodynamic pz'o ,pertios of oxides
IL vid I 6.,i, thc eloctrochemical mothol at; 80o wore reported
i,'e:;1-C~hina, V. A. 1'evitski'v, A. 11. C,61ubonkv. Tht: difflision Of
'~nll iron into various materials ivas treatel by A. 1.
izvokov and N, !~, Go:-bunolr.
So was ":ie Analysis of
:Aculation., of reactions in solict pIl'U.'& at Ili,-h

s/030/63/000/003/01 VO 14
Silicates and oxides in high-,.$ B117/11186
temperatures by V. B. Clushkova. Probl ons in the bree(ling of mono-
crjstals of' different silicate substances viore dealt with at a Special
meeting by 3 * G* Tre-vyatskiy, A. D. 11,1edoseyev, b. (;. GriC;orlyeva, T. J,.
P4akarova, 1). P. Griairlyev. Al'-0, Ya. V. Klyuclaarev t;-.poka about the
f~tudico of pharo trapformations and .-iroportlor, of hi,;;h,-WZ1j)vratUre
compoundo; G. V. Kukolev, M. T. Mcllni.k, N. U. !)hnf)cjvo.lova a4out; tIV
K. 'arl -it, tikuye,
properties of low-ba!jic calcium aluminates; A. 11 K, t I
L. A. Kosheleva, B. A. Polonskiy on the sintering and the cryntallization;
of molten quartv. in hot pressing. Lecturet3 on apparatus: Ni.. 11.
Golubtsov "Some instruments for utudying vacuum
,Rumyants,~!v "Application of the hii-h-tomporlLture microscope for studying
Silicates". Lectures on methods: B. ~:. Keler. on tho application of
com2lex thermography for studding high-temperaturo p-racesjon; V. V.
Fesenko, A. S. Bolgar: on the investigration of physival and Physico-
che.iical properties of low-melting compounds at 3)('0() 1,; T,. 'i,. Shpilmam.
A. Ye. Sheyndlin, N. V. Boyko, V# Ya, Ckiekhovokoy, V. A. Petrov, on the
determination of the thermal conducLivity at 1500 Du and T-,ome thermo-
physical properties uP to 2500 0C; S. F. PalIguyev, A. D. Meuymin spoke
Card 3/4

~')/6,'/000/00 3/013/014
Sili6aten and oxides in high-... B117/Bla(,
about tho, investil-111tion of tho mituro of conductlanco and conductivity
of' hi:,hly ref'T'ZLCtory oxides. In this conference a large contribution
was made to the coordination of the work of Gcientifie,,. reonal-c-11
institutions, universiLic,3, and induotrial enterprismil in tho field of
nilicatoo and oxides in high-temperature chemistry.
card 4/4

rMUSHKOVA, KETI-ER, E - K
,I; -n T I AN 53.'] S it I L.
s
R
AN ;,)S.'
WCr

ACCESSION AIR: A~4039617 S10076161VO3810051112611134
AUT'HORS: Glushkova, V.13. (Leningrad); Sokolov, Yu~G. 0~eningrad);
Kolar, E.K. (leningrad)
TITLE; Oxidation of metallic neodymium and the rate of the 0 -.1-L
polymorphlo transformation of Nd sub 2 0 60) 3
SOURCE: Zhurnal fizicheskoy khimil, V. 38, no. 5, 1964, 1126-1134
TOPIC TAGS: neodymium oxidation,neodymium oxidation rate, n eodynium
-sequioxide, neodymium sequloxide A, neodymium sequioxide 0, n,Bo--
dymium. oxide C-A transformation, neodymiun oxide crystal lattice,
noodymium sequioxide stable form, anion vacancy, cation vacancy
ABSTRACT: The oxidation rate of powdered Nd was studied in the a'~r
and In thoroughly dried oxygen. The equipment, w1ilch lo describad
and figured, was set up so as to provide for coatinuouo weighing of,
the 0.1 - 043 S sample at 1.10-1 to 760 mm fig pressuree and 20-1500C
temperatures. In preliminary tests with oxygen It was found that at
an oxygen pressure of over 1.0 mm Hg the oxidation rate does not
;depend upon further pressure changes. Thus teatii were -then conducted
1~~t ~00 mm Pressure. The results are tabulated and grephed. At 240-
(or-d 11-112 .. - - - -

:ACCESSION UR: AP4039617
I
13000 temperatures the oxidation rate showed linear dependency; this
:decreased as the oxide layer increased so as to become a parabollo
IcUrve. In Ary oxygen the constant of the oxidation rate was found:
0 ., 6. 10. lW1mIn-J- and the activation energy E . 38 - 93 J., 0.05 kcal.
Ta A-form was produced upon oxidation in dry ox-ygen az 250 - 5000
(X-ray determination) and was the only stable fona of'tho sesquioxide
iuP to 12000. In another series of tests Investigation the change
C-A Nd 0 at various temperatures the cubic
I form was usod as
2
!starter m2terial. The change was shown 'to occur at 800-100C and
did not reverse upon subsequent cooling. The rate of transformation
0 -A depended upon the degree of parfectio7a ot the crystal lattice
of the metastable 0-form. Lesser perfection resulted in transforma-
tion at lower temperatures. The activation energy of the 99.9,1-f
pure specimen was 2 - 100.26 - 0.04 kcal and the oonstimt 0 = 1.03-10i:
min. -1
Orig. art. Has: 6 tables, 6 figures and 4 fon2ulas.
'ASSOOIATION: Institut khimij silikatov im. 1.V. Grebeachshikova AN SSR
(Institute of Silicate Chemistry, Ali SSSU)
PUBMITTED: 26Apr63 ENGLI " 00
_~R R~P 'OV*_ 0"' OTHER: Oll
2/2
d

f 6rd
q
77
_L-1 -65 MID Q
9592 iii
W/
~ASDM-3/F
.3D(t) - JD/JO
ACCESSION NR: AP404510 4 .154
0 S1020 1156 1:0011011 1
AUTHOR: Glushkova, V. B.; Keldr,E. K.;~.Sokolov,, Yq. 66v, N.: k
q
TITLE: Reaction of Nd 03 with water
2
SOURCE: AN SSSR. Doklady*,'v... 168, no. 1, 1964,151-1 4
4
TOPIC'TAGS: Reod ium xide water system, neodylmm 6xicw~~ dr, stitbilV,
ty, 6tructure
ABSTRACT: The Nd e i
203-wat r sykem was studied- hoodYmi um i 1~
were obtained by hydrothermal s ra 0.4d! is'. wii*ir'-e;r ih
ynthesis; heodyiniu i re~cted'wi
water at different temperatures: and under different z~61atiW lunal. -!",l andj te ;1
stability and structure of the hydrated neodymium oxWes WO-e doldn ed..B)th, I!
the All and C- modification of Nd.,o were fdrmed:in.4:M~1ali've ri~04 t: a osp qre.t
3
25-95%. At 3 5 C the A- form was stable t ~',water vapoi~),! hile 01ei
of 0 Q- rm
hy 0 (1). 1, W*a'W also fdrme6 by the d,!N' ~"M 1~ rard;,
drated to 3Nd 0
2 3' 2H2
less of humidity, while the A-form formed the trihydi,ate NW1,)Oj.;'3%O. th!~
P
100-400C range the C-form gained weight (with acco :
mpallyl, igy a,1 lattic6. [is;- i
Ccrdl / 2

Ll 6418r-,;.65 EWT*i)/EW1Pk' t )/YA*P1'b) fjp(c)~ 16/
Zpo
i'ACCESSION.NR.- AP5019775
313
)?,/om /Ci5gibl/0071 I Wil
:AUTHOR: Glushkova, V. B.; Boganov,,,A (I
iTITLE: Polymorphism of rare earth se6quiloxidns:
;SOURCE:.
All SSSR. Izvestiya. Seriya Wniichnski p, no, 71 19i~!; 1.131 -'j. )w
q
!TOPIC TAGS: rare earth oxide, polymorpKism
IL'~ fo lolli~
:ABSTRACT: The polymorphism of rare earth sesqujbxidem wi~" 'Ity LeA ii,
Ith or th'~ :iitides: -i~ their ph,,,~e~
ree aspects: (1) effect of conditi~ins of prekiration V
state and determination of the lowest7temperatUres whic
t h 11- pure, 10X~V a*, can b4t
~obtained from various compounds; (2) ctudy of the prescn~1-2 i3f reL%I'hbjj~!~ bpiym
r 0i ol~phl.
itransformations in the sesquioxides; (3) study 64f irreversible 10" oly-m6pila,
D. 1"a'11,11 -,d: tbel
transformations. High-temperature X-ray, and thOmal analyvs:4.;
~sence-of polymorpbic transformations jn~the:50-1.5006 ranv 0 #i~! f 6~).e~ W'ing; oxidel~i,'
2 EU203, Gd2og :Dy2O3,: pi d U2, a.::
Y 03, ha203, Hd2O3
SM203)
A-ray diffraction analysis confirmed the presence of irre verb fl~jli, triiii~Ttionn in
Sm2O3, Eu203, Gd203, and theirlabsence at,100-15000 Ini
103, 4Pa, H020i
Er203, Tb2O3, and TTn203- It was ShOW11 that the: Ic".-v-temp .~of lan-t an, ~n
h
Card 1/2

Raw
L 64185-65
'ACCESSION NR: APS019775
'oxide cannot be obtained by decomposing oxygen salts or the k1l vxiM: 0 1 i le: heatir g..
in air:at pressure from 1 to 760 mm lig, The C-ftm of neodyni a'oxj.!I~ fa' obtain(d
qkalat , and hydr 4de 1~9
:by, decomposing neodymium nitrate, carbonate, e!
re:associatetl it -J! cow 1~ e 'nil 1 4:
Ible t ansitions C + A Nd203 and C - B:Sm203 a
z
a low-61--v -4 ratirve
.1ution of gas (1.5-2 wt. %). It is pt~stulat~ed th t the
ormo of!
:oxides of neodymium, samarium, gadolinium, and europitua a I;ve oet .tI-.:;tab*t :n~dificati -nd
rangj~ qex p~to !0 0 1)
which are theniodynamically stable initheir temperature r j 1. nly 1)
.4
~cauvve of the presence of foreign ions in the o~Kide att. i 00
resi 4 tables.
~-igu
I. V. Gr b v-1if"o aile nii nilu)( iss sil
.ASSOCIATION- Institut khimii silikatov lm. a enal ri M
enc s SSSR)
1(1nst;'-,ute of Silicate Chemistr cb e
_y, Acadea of
IINC&: 00 S oil Dm: IC.
iSUBMITTED: lOJur.63
F SOV: 004 0
Card 212
71

004 (4~'
L-5870~-w65
f-TMEW-Pm-4 - LJP.(c.) JJD/JM
ACCESSION NR- APS016590
IM1036 651 1107.01
1.35:$
:j
Davtyan, 1. A.; Glushkova, V.~- B Ko
AMOR:
TITLE: A study of the s odymij- triOlciaq idrcoatw~ I iNidel-"! -0g 66
d
rich In zirconium dioxide
SOURCE: AN SSSR. Izvestiya. Neok~"icheskiye 'materlialy, Vi 11, ~no. .1
-750
743
TOPIC TAGS: neodymium oxide, zirconi oxide, mi*ed; oxide Is ~ui ~ture.i:
L~n
diagram
r mixtu
poWde res of ZrO2 and V201containidiN
ABSTRACT: Pressed
0'.ericIffs, of time;i
tions of the two components were fired at~ 600-17~OOC 6r varLI$61
Y, popriiiii-mit J
some mixtures were prepared by decompoising mixed nLtrates.oi~b aLng
the hydroxides. in the latter two.cases the, ruactioll, was coiiolb'rabl;~ :as;tI
erj:
and its course was sometimes different'. X-ray atialyijis reveil el that I ians':1
ia,
j trans-
of Nd2O3 lower the temperature of themonodlinid t6tragonm:~ ;P1 ymc
formation of ZrO2. The unit cell-pdrameie'rs of'zrft.and itsi'~a!A-d soju:ions'
e stability (if ?t 01 VA id
were calculated for various temperatures. Th 00 !
' t~
ay difffaction patterns of t ef~d; 113W
solutions was studied, and x-r h ;jIdlut'L
Vdiumil clinthe, e tand
annealed from 1600C were taken. The c.hanges in the

L 1558-66
JUW/V7jG/RM
ACCESSION NR: AP5022266 UR/0363/65/001/OC17/114311151.
AUTHOR: Glushkova, V. B.; Isupova, Ye. N.
TITlY.: Thermod,inamic calculations of solid phase reactions betropeen oxides of
elements of groups II and IV of the periodic table
f
SOURCE: AN SSSR. Izvestiya. Neorganicheskiye materialy, v. 1, no. 7, 1965,
I
1143-1151
0
TOPIC TAGS: thermodynamic calculation, titanate, silicate, zirconate, heat
capacity, enthalpy, entropy, beryllium compound, titanium nxide, thermochemiatry
ABSTRACT: Ark analysis of the thermodynamic calculations ft."r solid--phase prccessea.~
occurring at high temperatures was carried out in which the foll(rving formulas
were employed:
r
A1101n + T-Aj -Fir
AGT AIIT TASr; AGT' ab /a/
Methods of calculation of the temperature dependence of the heat capacity C are L.-
i
analyzed for the case of titanates, silicates, and zirconates of elements or-
group II, and the values obtained are compared. A compariijon between the methods
,,Card .1/2

L 1 8-66
AC SSION NR: AP5022266
of calculating the enthalpies of formation is also made. The methods de scribed
account for the instability of oxides of elements in groups 11 and IV; for
example, it is shown that from the thermochemicall standpoint, no compounds
can form in the BeO-TiO2 system. Tlkie-thermodynami~ instabIlity of beryllium
orthosilicate in the absence of mineralizers is also substantfated, Orig. art,
has: 2 figures, 4 tables, and 7 formulas.
ASSOCIATION: Institut khimii silikatov im. 1. V. GrebenshchLIcova Akademii nauk
SSSR (Institute of Silicate Chemistry, Academy of Sciences,L~~',.~R)
SUBMITTED: OlFeb65 ENCL: 00 SvB CODE: .350 TD
NO REF SOV: 018 OTHER: 012
ILq.,d -2~

kCC NRt AP5028727 SOURCE CODE: UR/1)")63/65/0011011/195511964-
AUTHOR: Glushkova. V. B. ; D415yan, 1. A.; -K~le~r, E. K.
ORG: Institute of Silicate Chemistry im. 1. V. Grebenshchikov, Academy of Sciences
SSSR :Institut khimii silikatov Ak~Ce;Ti _nauk-~rSR)_'_'____._...._Z_
TITLE: The Nd203-ZrO2 system. Study of regions rich in Aeodgymium mide
SOURCE: AN SSSR. Izvestiya. Neorganicheskiye materialy, v. L, no. 11, 1965,
1955-1964
TOPIC TAGS: neodymiu;T ccm conlun ccmpot
I pound, zir Lnd, Solid solutjoll metal phave
6 StIm pfiase diagram,
st:t,jbgi,a~ anaig8is x ray anal a gaoe trapsition
Cal,
Rem I y, p ase c mpogition, cryffst At cz~ qxx e
ue, ingg -d
ABSTRACT: Chemical and x-ray phase anal -tu y Nd203-ZrO2 System,
_Vses were use to ~
and a diagrarn of phase transitions was plot d for a reagion ;rich in Kd203. The sta-
bility of the cubic solid solution based 7_Vd2 0,14as detplmined and the solution
was shown to be stable only above 15000C. A-WiFfound that the pritnary phane con-
sists of cubic solid solutions when the mixturms am prepared by coTfrecipitatitig in
the amorphous state followed by crystallization at 400-80000 or by decomposirg a Mix-
ture of nitrates. As the composition of these metastable solid solutiobs changes
monotonically, them is continuous change in their crystal atructurNi from the IM20-1-
type--characteristic of the low-teinperature C-fimn of Rd,-,03 -via the pyrochlore typql--
to the fluorite type in which the low-temperature fOm Of Z11-02 cV5*talliZ6s- 'rho
Card 1/2 ODC: 546,07 + 5116,831

L 11003-66
ACC NRt AP5028727
effect of the addition Of Zr02 an the C-A transition of Nd203 was studied and it was
shown that small amounts Of Zr02 hinder the transition of the cubic solid solution*
(C-form) to the hexagonal (A). Where there is a high ZrO2. content (10-20%) in the
cubic solid solution, the intermediate product formed is a solid solution which crys;-
tallizes in a lcw symmetry (B-type). On heating to 1350-140011C, 'the latter converto
into an equilibrim mixture of solid solutions w-Ith hexaganal. and pyrochlore struc-
ture. Orig. art. has: 5 figures, 3 tables.
SUB CODE: 07/ SUBM DATE: 24Apr65/ ORIG REF: 0(15/ OrH REF: 012

L 11028-66 EWTW1E1'-'N t)/EV;P(b) IJP(c) JDIJG
AZT'T4W, AP50-28728 SOURCE COD~,. UR/67i-6*iT~5-~001103-1/1965/1977
AUTHOR: Sazonova, t. V.; Davtyan, 1. A.; G
ORG: Institute of Silicate Chemistry im. I. V. Grebenshchikov, Aca6arfiy of Science&-
tuf-Ti-I.. -H filk-at -ov ......... .
n
s imil em
TITLE: Study of the Nd203-ZrO2 system and effect of the method of preparation on
the properties of the product obtained
SOURCE: AN SSSR. Izvestiya. Neorganicheskiye materialy, v. 1, no. 11, 1965,
1965-1977
TOPIC TAGS: neodymium rompound, zirconium ccnipaund, powder Tnatal sint(!rinr Powder
ptaltmixing, phase equiliUrium, chemical composition, metal Imalysis, cry6&1
s ruc ure
ABSTRACT: Thermal, x-ray phase, mole cular-spe ctroscopi c and chemical methods of
analysis ,were tech tq,study the products obtained from sintering pressed powder mix-
tures of"ZrO2~ d1jCd203 (in the ratios 90%:10%, 66.7%:33.3%, and 10%:90%). The mix-
tures were prepared by combining solutions of the salts and evaporating, coprecipi-
tating in the amorphous state, mechanical mixing of the hydroxides and mcchanical
mixing of the oxides. Thermograms of the mixtures, curves of therrial decomposition,
infrared spectra, and x-:,-ay diffraction patterns of the products are given. The me-
chanism of formation of equilibrium phases is interpreted. it is showm that the com-
position and crystal structure of the products formed are appreciably affected by the
method of preparation of the initial mixture. Orig. art. has: 7 figures, 3 tables.
SUB CODE: 07, l1/ SUBM LATE: 24Apr65/ ORIG REF: 005/ OTH REF: 006
UDC: 546.657 + 546.831.
Card 1/1

ma lic
*~ti ti;T, kn j mi i ~3 1' k! i t ov 1-noni- I.V. kova AN

Lha Ocl
(,n
'T.-Po"
C) r
%
41

MWMM~~=~_
L 30-,50-66 (m)ZT ;P(,,- )/EtV(Q ET1 I JP(,-- 'A'ji IJD,'JG
ACC NRt AP6015073
SOURCE CODE:
(A)
iAUTHOR:. Davtyan, I. A.; Glushkova V. D.; Keler, E. K.
ORG
ISSSR
TITLE:
Institute of Silicate Chemistry im. I. V. Grebenshchikov. Academ)r of Sciences
(Institut khimil silikatov Alademii nauk SSSR)
Effect of europiin oxide admixtures on the polymorphism of zirconium dioxide
SOURCE: All SSSR. Izvestiya. Neorganicheskiye materialy, v. 2, no. 5, 1966, 890-895
TOPIC TAGS: europium compound, zirconium compound, solid solution, phase transitionj
(XV\CLk)'Z%5 , X (,CL\) CL~\oLNJ'Ai'>
ABSTRACY: The Zr'02-EU203 system was studied by using thernal and x-ray analysis. Ad-:!
dition(of EU203 was found to lower the temperature of the monoclinic-tetragonal tran-
sition%f Zr02 considerably. Crystallization of mixtures of tu;!03 and Zr02, copreci -
pitated in the amorphous state, foms metastable cubic solid solutions of europium
oxide and zirconium dioxide. The crystallization tenperature and lattice parameter ofl
the cubic solid solution increase with rising EU203 content. The decomposition of thel
metastable solid solution into stable phases was investigated. It was found that the
minimum addition of europium oxide required for the complete stabiliuition of ZrO2 is
7 mol % EU203- It was shown that the addition of only 2% EU203 eliminates the crack-
ing Of Zr02 during heatiig. A phase diagram was plotted for the phase transitions in
the Zr02-E'J2OJ system for the region rich in zirconium dioxide (see fig. 1). Orip.
art. has: 5 figures, 3 tables.
Car3 1/2 UDC: 546.831.0546.661
r c, cl 2 1'2
C 10-
a in

ACC NR:
AR)036791 SOUI~tcz CODE';
AU-I'lUt: a-xvtyan, I. A. ; Kalor, E. K. ; Gli-is*hkova, V. D.
UG: Institute 0.' Silicate Chemistry An. 1. V. Grob G nsh ch ikuv, i',N (Institut
silikatov AN SSSR)
TIT112: '-Effoct of additions of gormaniuri dioxido iind yttrium and n 0 0 C y', 4 UM gormanates
or, the polymorphism of zirconium dioxide
S 0 UR 0 E' :AN SSSR. Izvostiya. ilia organ i1cho s kiyo materialy, v. 2, no. 11, 1966,
1998-2002
~TOPIC TAGS: zircon-'Mn compound, germanium compound, yttrium cca,-ipaund, neodymium
COMPOU-nd, phaso transition
OS7
RACT: -ha articla considers tho questJons: 1' tho of Solid
ooliitions ha5od on ZrO,) with additi=; of GuO2; 2) tho stability of tht-L;o solid
solluticn:; and the vola-lity of GoO2
from th6m; and, 3) the offect of amount of the
;addit'ons of -err--nilwa dioxide in a solid solution at tho tenpc-.-a-L.-L~.ra of
monoc ni-IOL--onal transition o~' Z~-O,, and the -z-ossbi-Ifty of th~, --otragonai form of
Zr32' 3-oli'd solutions of zirconium vit.'I additions of 2, 5, 1.0, 15, ar.4 20 :7o--o G,302
wera pru7-ared loy the method of coprocip~ Was C:~Se-,VOCL
!-.I all tho
,an oxo"'.-.urmic affect of crystallization, and at the same tLirm the crystallization
Cold 1/2 ULIC: 946.831.44,541-7

AC~NR:
AF6036,79i
temperature of the product increased with an increase in the anoi.,nt o: additive.
rIv 11-alys's of the products indicated that additions of GeO2 stlbil-fzo t'A-'e
tetra-onal- f o,-,,, of Zr02 only up to a temparature of 12000C. 'Fharofora , 17-arthel-
2 Plus oxide5 ol' rare oarth elomo
ex-periments were undertaken with additions of GeO nts I
(since oxides of the rare earth elements stabilize ZrO, at hii;h tcmporatures). Ternar;'
,mixtures of the followin- composition were praparod (w~.~'I)) j
zro-,-~ 96 90 90 90 90',7 91,7
GeDZ, 2 5 2 5 2 5
Y 01~ 2 5
%T~
0 - - 2 5 3.3
"c12 3
it was found that stabilization of zirconium. dioxide vith gar'-'Lanates makes it
ipossible to increase the stability of the solid solutions at high temperatures. Orig.
art. has: 5 figures,
SUB CODE:0-1,10/ SUBM DATE; 07Jar,66/ QIli REF.- 001

ACC NR: AF7N620') SOURCE COM: UR/o'6-~/67/03/001/0119/012'
AUTHORt Glushkova, V. B.; Davtyan, 1. A.; Folor, E. K.
0.~G: Institute of Silicate Chomist-y in. 1. V. Gi-obanshchil-ov, of Scioncij';'
SSSR (Institut, 'Xhimii nilikatov Akademii nauk SSSi)
TITLE: Proparation and proDortios of yttrium and noodymiun gont~inatoa
11 , A
SOUR, CE: LN SSSR. Izvostlya. Noorganichnskiyo matorialy, v. 3, no. 1, 1~x"), I I) - 12"j
TOPIC TAG3: yttri= compound, noodynium ccmDound, gar-manato
A-55TRACT: Ytt:-iiLm and neod,,rmiura rorm.. anatos w,-,re pronarad by both coorocin--.-ation and
j.)
mochanical mixing of the oxides, and the syst(,.-,1s obtainad
-.:oro sub`:,~ted to differential thermal and x-rzy diffraction ~nr.*!'yso~". I . 0 f 0 -n-' on
of equilibritir, crystalline productus was found to be comDloto at 12CO'C in all ca:;Os.
Both systems contained cormounds of the corno~;itions LnZO3 :GoO,, = 1:2, :1 :'-, and 2. 1.
Aho intorolan_-r distances were calculated for thoso comnound3. Tho bQ-av-or of
_zo=7~anatoz; at hirhi tcimnoraturos was studied by sLb.'jactin,, tlic~m to pro"
firin'.- an--' t"-Ion to x-ray ana-lysJ3. Yttriu.-~-, got-mana"os waro found to be r,-,.)re ct:.ble
'han noodymi,,in. go-mazates at high tom,orat-cirao. Grig. art. has, 6 figvrr,,,. ;.nd 6
tables.
SUB COLE, G?/ SU:_~M DAT-': 29DOC65/ OP10 REF: 00/ QIF, C01
1/1
Card uxt 5i,~6.64v?,89

GLUSHKOVA, V. P.
e.` t! v-s
"X-Ra ,v (C.'.:"s t~i Is r t~. 1 1:) fl v t 'I r 1,
Berif"Pl.
yp.
zil-ar Fiz X:A~,-., 2t.-" 125~,,_i26.5
~4n(i (lptJ -,f tIz- frj'
.~e _zr) 0! t
trc),.)Or!zelo,; r~~ n 1 2- n;, 10'.-
cf
11 '10- i:-:o
di-ri- i n f ~.,14 T)12ner.

J- A L-
C o' n-
nr,. -1
9. Monthly List of Russian Accessions, Library of Congress, 'iY 19,53, Unclassified.

11i0tibi4ilsol iind illo-PhIlIpPy' A moltifutAr, cr
l
y
C.M.

-
-
-
nl
-T
1777'
r~ A,, Ito
.,~!ofjj "Jill "j,
r': it, 2 It, ',till t
,
v!ir
i,f the 7tt
1J.'s ;,.
:1,, Can I'll: c!) o
VjIlliv
fit.,

GLUSIfKCJVA,V.P. ; KOCIfESHKOV,K.A.
Renction of the synthesis of thallium aromatic and haterocyclic
series. Dokl. AN SSSR 103 no.4-615-618 Agl$5. (KLRA B:11)
1. Chlon-korrespondent Akadenii nnuk SSSR (for Kochauhkov) ?. Fi-
ziko-khimichesk-ly Institut Imeni L.Yn.Knrl)ovn
(Thnllium orgAnic compoiinds)

GLUTSFMOVA, V.P.; KOCHESHKOV, K.A.
Intaraction bptween diar'rl mercury and sal.ts or trivabmt thallium
as a mothod for thO Synthoulk3 of ArT112 co-TO1111(113. Itv. Ali SSSR Old.
k1ii m. nauk no. 10: 119' -1198 01 -57- (MIRA 11:3)
.3
1.Fiziko-khimicheskiy institut im. L.Ya. F-arpova,
(Mercury compounds) (Thallium orgmnic compounds)

AUTEORS: ;_1 s Kr, va 7. 2.. " 1612 :1
TITLE: Introducti(,n of Thallium Into TaLlir--vaniye
diberizefurar,L) .
PERIODICAL: Izv,--sti.,,,L, 11N 363H, Otdeleni-~ Nauk, 1957,
Nr 11 1 ',"1 -1 1 C.~-,
A33TRACT: The introduction of' thaliium into tile mi.isol and ~.iophen
by the aid of salts of organic acids of the trivalent
thallium was carried out 'c, and
y the authors (reference 1)
it was shown that t1tis leads towards thalliumo--ganic
ccmpourids of the clao-jArM
and not - aa raintained by
2
t~,e American authors (referen--e 2) - towards compound of
the class Ar 2TJX. Here the behaviour of the dibenzofuran
with reCard to the salts of organic acids iras compared
with that with regard to tile halo-en-salts of the trivalent
thailium. It was shown that the irtroduction o--F' thallium
as ~-.Iqo in previcuo cuoas leilds to the class ArTJX
*
2
Furti.ermore it is 8%oarn that the intrcduc-.i1-.n of thallium
witli regard to oxygen does not lead to the vara-position
Card 1/2 but to the orthoposition. Tlhere are 7, references, 2 of

Introduction of Thallium Into Dibe-rizofuran. 62-11-16/2c.,
wnich are ilavic.
AS60CIATIGli; Physico-Chemical Institute iLmeni L. Ya. Karpov (Fiziko-
khimicheskiy institut im. L. Ya. KaxpuvsL).
SUDMITEEDt JUlY 5, 19~57.
AVAIL;~BLE: Library c" Con6-reL3s
Card 2/2