SCIENTIFIC ABSTRACT GAPRINDASHVILI, V.N. - GARA, MIKLOS

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000514310013-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 19, 2001
• Sequence Number: 13
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

GAPRINDASHVILI, V.N.
... - - , ".. - - 1 1; @- I- - I
Hydrometallurgical treatment of antimony-arsenic ores. Trudy
Inst. prikl. khim. i elektrakhim. AN Gruz. SSR 2:147-159 161.
(MIRA 16:8)
(Arsenic ores) (Antimony ores)

D.N-; KURDEVANIDZE., M.K.
Problem of the complete treatment of TSnelissk sepentinites.
Trudy Inst.prlkl.khim,i elektrokhim,AN Gruz,SSR 3:73-85 162
(KIR A 16; 1)
(Georgia--Sepentinites)

GAFR;j UDASHV ILI V N - KUDEVAUDZEF M.K.; GUNEPADZE, 1).S.
. ,
Fractional separation of hydroxides of some metals from
solutions obtained in the acid leaching of local serpentinites.
Trudy Inst. prikl. khim. 4. elektrokhim. AN Gruz. SSR 4:45-52 163.
(KIRA 17:1,)

GAIR INDASHIT 11 - V N. - N G i (", i i A 1) Z E , L . K .
@ I
Ultric arid treatment of' ',ecrOari 0 Gruz.
@,SR 3A no.2:295-1101 Vy 165. (MIRA 1.@.q)
1. instittit Prikladnoy khiini-i .1, eloktrokh@a:@,@ ili
@-,;; I Im I 1 1. t "! , , "
" iutlll:@, I @ I "i ,

I
t
KOSHARNyr. i.ya. Exosharnyi, I.IA.1; PIDPRIGaMCM, M.V.;-GAPS==, I.I.;
,MIPNMO K.I.; XASHCHIMU, I.A., red.; MSMMO, V.P., red.;
NIKOL&YMO, V.S., red.; POTAYCHUX, I.M. [Po"talchuk, I.M.1, vidp.
red.; S30MYUK, F.L,red.; YOGT,.V.Ta.. tekhn. red. . .
[Soviet Drogobych Province] Radians'6- Drohobychchym. Drohobych,
Drohobytalke obl. vyd-vo, 1957. 199 p. (KIRA 11:8)
(Drogobych Province)

GA P TIFIVC-1 IT. "C4 A)
ll?ropoli@- Therapy -for Ar-ricultural Animals Suffering From
'Tecrobacillocis." Cand Vet Sci, Kazan' State Veterinary Inst)
Kazan I , 195h -(RzhPiol, No 5, Var 55)
SO: Sirn. No. 670, 20, Sep 5,@::-SUrVe,r of Scient@ific and Technical
Dissertations Defcnded at ITSSR Higher rducational Inntitiftions (1")

-)A,. I I @
".-104,"INA, V.Yll. ; CHUB, Yo .;', . i GAI@TJNINA, -@,.V. ; .7K'Ji ii; , . . '. .
L-', ,,atory ri:),lel-oC a sfowrdng -!n't for c(irronton ferits. Zav. lnb.
30 nc.1:1280-121L 64. (MIRA 18:4)
1. Nauchnc,-i6,itfi~!-.~vatnil.-ikiy institut osnnvnoy khludl.

L.1-
Heating the rolls with exhaust gases. Sbor. rats. predl.
vnedr. v proi7v. no.2-.19-20 161. (IAIRA 14:7)
(Rolling (Metalwork))

GkMNIK1, M.L.; DUDAMV, V.A.; SPIVAK, E.I.
Operation of heating furnaces of a medium sheet mill. Stall
22 no.2:17&178 F 162. (MIRA 15:2)
1. Zavod "Amurstall" i TSentroonergoehemet.
(Rolling mills)
(Furnaces, Heating)

KISETZI, T.; DIORDITSA, A.; TYNURIS, E.; CHOGOVADZE, G.; BEGMATOVA, S.; gA@UJROV,
M.; KAKIIAROV, A.
The entire country participates in foreign trade. Vnesh. torg. 43 no.19r
6-12 163. (MIRA M2) -
1. Predsedatell Soveta Ministrzv Belwwskoy SSR (for Kiselev). 2. Fred-
sedatell Soveta. Ministrov Moldavskoy SSR (for Diorditsa). 3. Zamestitell
Prodsedatelya Soveta Ministrov Estonskoy SSR (for Tyfiuris). 4. Zamesti-
tell Predsedatelya Soveta Ministrov Gruzinskoy SSR (for Chogovadze). 5.
Zamestitell Predsedatelya Soveta Ministrov Kirgizskoy SSR (for Begmpttova).
6. Predsedatell Soveta Ministrov Turkmanskoy SSR (for Gapurov). 7. Pred-
sedatell Soveta Ministrov Tadzhikskoy SSR (for Kakharov).

iy*
In ti.-., Lini of ;urds a,'.d c.,-e.;t.iL:. VOV 1'.
@--edoedatell l'*j0%'cTu
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(f c 1-1 -.v -.::.,@-iradov) . x nl'117 F-. ra zhdario k Oy
or Klycl: ) -. .,., @i, i Er
!@..enoka'yr

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(01-001 of
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hydrogen sulfide as a protection for plants. K. A. Gar.
go r 1. J. Ck@. led. (U. S. S. R.) 16, So. 12,
of J@, Stj,pcn*.jm c4 S obtainul hy the Thyhm jwwrsi are v%- 00
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-OAILXA.),,A SAW lwisdWftd@ ubbm-Wonid IM
J-100.1940.
1941.1
An ovdinalry Mer paper is imvwvwd in a 5 or 10 per cent. potammiurn
&r@@ mobition. dried, mall cut into sirnall stripi, on which an
*Zorn all vull1wr sullibmils in the IkInIvaux Illixturv filmy IM drimfi,if
byspinickh-hpownr4mr. Upint~4*twrt,*nLoffhvc%vliporoulphat .m
PV6dUC*d A IWIPCOPObIll COSOMtiOn In the Wfitgf*@ tOlItil, Old a 1.
nistely the Unw Cer"ilitfation W" found to cause KUrching Of
in the UASM,

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A. Gar. ViwA.-1j,k4mum1. I.a. lVdAene"im i
Imirklotmoijil"J" )'a. 1'.
III; Xhim @r rral Zktir. 1940 No. 5. 1,11, -A review
nI MIMS proiltming La.(A%(),), by oxillizins
-v 44 Cu.
amcnites by air in the present SO.. jwt%tuction tit
jxv,wtl.,NaIlA,(N ivn,trAd A %he tm.ici. Ivi-luctim 0
mv;it? (,Luj(A@00. with -4 A-,(),. dil-I. aith dAy) -00
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aroA irsiloll (Cont appro%. 24@ of A-y). and .00
till CuO). A presm. tit I tic vJtwt 1) lie %4, py-lu-I
a 9 itir xroluA Mth 14 111-it, BAS @1111 th-olefilAt% ". !"
h" 1111n. 11. 1.4y,ulfid- m -k. ot -ii- th,-
Z 2*0
;,,cpn. F--- . no. 4 -c, the Ii-e-i
prelin. ln@tieidr- Can Iw prujwl. in lite focin 4 4 1-te
frout S obtailled by absorbull 11,,s from C.Ar-ovull And coo
00 -3 :11 prolucer zu. A meth(ml for proilucing su@jx u,ions fruin
1116t will] Ujifite LCIlultvC CRIS. at ItAlillizerN, "A, coo
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locicirs"" all"Ishlet lot toskolvilical *uFk with out.
t1asse "" 909PMWGRS Of Insecticides and fungicides
K. A. (W. J- "'"- /Rd- W, N. S. k. 1 111, No Ii.all
hi@h IWIIIIII. %M11,411ml
In thWi-sile slut milains an siflioler it, Ill t&jIL _ t1w,
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DustAbility and hygrOILCOPiCit'y of caldurn attenale
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DMIOPrIcOf Of tho d4ricultural econarnic pofsans
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UW., K. A.
ledicim - ktriculture
nov 4.9
"Deve2opcent of tho Agricultmia IneecUolde Induatr7 In Thirty Yvaxa,n V@ 1.
Cmxl Tech Sei, K. A. Garp,Cama Agr Scis, Ho Ga Gabrlyrvlova, Caml Teich SO-, 3@ Pq.
uKhImtah=kE[7ft i'MMYOU"A6410 140 n. - @ .30-*4
Matorical a=unt of dewlopmnt in the Insecticido Ud-sti-fo Fbrsons Inportant in
chemical rosearmh umrk ir. ftsecUel&3 are linted and c@=nplos are rwDented of
the tochmological progross and dmloTmnt of Imoctlelde pmluctn,,
?A 34T48

USWChendstry - Arewwtax, To3dolty Oct 48
Cheralstry - Insecticides
'?Z%perimental Study of Relation Between Solubility
ard Toxicity of Thermic Arsenates of Calcium,"
en X. A. Gar, Can& Agr Sci, Soi Inst for Fertilizers
and Insectofungicides Imen.1 Prof Ya. V. Samoylov,
7 pp
"Dok v-s Ak Se3Jchoz Nauk" -Tqo 10
Determined relationship betimen solubility of
intestinal fungicides f or various pH and their
toxicity to various type insects. Subject material
d.issolved poorly in alkeli, ancl was less potent in
low 33/49T16
UBSIF@/Chemistry - Arsenates,Toxlcity (Contd) Oct'48
auch =ixtures. Overheating arsenate compound dur-
Ing manufactare, Im-ered its toxicity. PecamendA
that insecticicles containing arsenic be tested
for toxicity on basis of solubility in water and
In solutions with varying pB of 4 10. Submitt4d
31 Jan 48.
33/49T16

ridd.WC&I Tkoqge.6
k4ila u
phoric add. K. A. Itj
d Lad K@-D";SEVVWVIL Ln-,
14 Zhur.
timts
ObiPthef Kkirx. 23
1111FC-3 I id
t
Calandrd Orylias Irtith the follo*ingft ".P Wsp t in 1-1
ii@@ ..rated that mW& aliphatic amnatic esters are I'd tiv Y
-.@j *enkly active and the activity drops with inava3c f the
iAlphatlc radicals or the tAter; hydrox)-alkyl acitoA 1.4
a
tM y TI
iLnd aldehydoalkyl tsteft h9va v@ry low: ac It 16
activity of trialkyl dithiophosphates rises sigalfic2nd en!
L"CN
@41, 11 atom of the alkyl Froup is replaced by as grour
SL
L,r COR. ..'rh4 -following esters am reported (b., d3o. n1j,
";'Conen. in after 3 diys exposure tQ4
trq giylng 50% mortalit
(JtjO)IP3tCl tCIIPh. be.,& 123-M .
ati. emulson):
0.1. di-El ejkr. bs-is 135-7% 1.1444,1.5498,
A; is-,
di-Pr ever.- be., 1.01M, 1.53sit r,
isq,.-Pr ater 4, 121@4*. >1; ds-Vu to
137:16-.@ 1.0800, 1.5=, nontoxic; ;6-howBu
b"4 .117-22*. 1.08W. 1.5301. nontoxic; (BuO)jPSXIIr i
@VHICH,011, beat Q)-5*. 1,0491.1.4&15, over 0.5. (A[tO)r.i
PS@CIrOrtOAC )h 100-2'. IAW 1.6255 4 7- - di-Et *
@. _1.1517,,1.4M, ,.68;
L-q & 115-1
I% N&I, 1*5, nontoxic-, dkja-Pr @ukr, be.t jW;@
imsto, 1@4335, nontoxic; di-Bu-cster, bq;& 100'.
1.1 4858, noutoxi- di-i3@Bss e-Tkr. bo-@ 104*,i 1.0086, 1.4915t
n@ntoxic; Yj;;:firO)iPSiCH%CJItCII0,'b#.ij 74*. 1.1348,
1.6W5. nontoxic; di-Bu esttr. bo-en 754% 1,0756,1.4055.,
notanxic', (FW)oP3jCffXff-CN, bm 1:442* 1.1704-
1.5105, 0.03: di-Pr @ ba 116-20.1hu, IW
0.25: di-iso-Pr crkr, 1.0182, L5M, over 0.25,
di-ft esicr, N-u@ 01-V 10810 1.505.3, 0 36-
122--3*, 1.068h.; i.5016. over 0ii; bhovsi-
(*IIjGIIjCO,Afe. bs 145'. 1.2GIM, 1.5160 over 0.3; di-Ell
unrloC. bt.1 107% 1.1011, 1.6050, 0.084;t.ii-ijo-Pr-anO!-,i,!
124-9% 1.1162 1.4915 0 0.- (AW)sPSICH2CHjfdCC6VI,
*q
Tus uh)-O-, Libid. 1.516.16.15; di-El awkC. bi 5ol"!
11577 1.4995, -over 0.15; di-iso-Pr axakg, bo " .6 .;; I . .1
j.1:1203: lAM5,'n6ntoxIc; &Bu ejkr, bwns'llo 1.1;
1.4918. W hs,a4 115-14*: 159'.
4FJ 14* , ' '
1.4015, noutoxicl (FJO)jpS CIVICAPAPCO 1 1.
bi. I
lawo, I.IS341 nontoxic-, . [NIPS2 10) C NVVI
Are N., 134.8 4, 1.2864, J170, 0.007
-0.013;
CIZ(COEj)
CIIlCOEI, bl.s 160-70', 1.2078.1.4ow, 0)33-
(MeO)sPSsCH(CO#CHMej C113COjCHM*j. boa 113-@J
11.1824 1.4810. 0.003; (AfeO),PSCjr(COCH, j
ClIt6ACHoCII-Vet. be.:a lq7-8*. 1.1493, IAMS, nontoxic,'
I (FJG)3PSiCff(COjA[t)CffjCOlAt#, ba.ou 110-20, 1 M37,
I
1.4070, 0.001".0021; (EIOIIPS
jCJI(COJFJ)CIrj'O;Et bj@
157-62' 1.1742 1.4910.0.021,*.(Fjo)jpsicll(coic"lfrAliz!
. A . .,!:.
MMCHAfit b.-ty,117-21'. 1.1493. 1.481a; 0.0034;
(FjO),PSjCH(I
hCHXHMIOCJfC0,CffCHSf,,,. 'bla.,
12-1-11% WOUS, IAM% noutode: (ppo),pS@CH(
CIrC0,EI, b.:, 1460;4.1706. i.oW,1,01069, (PIIPACII-,@
(LVjCjjM,,,)CffCOCM.V,, bs@ft'l
47
95
nontoxic; (FrO)*PSXII(MjBu)CH,MBu N 'h
34%,
C"'
IM47,.1.4822. about,0.5; (jjd.prO),pSejj(RE,) -
"
COXf. h, 151'. 1.0702.1.51,10. 0.'25. (BuO),PS@Cjj(
EI)CII,MhJ b.. 125-80 1.10778, 1.4861. >0.5; (ijal-
BUO),PSSCH?C6ACfrCO@Ej. b... 117--30', 3.0642,
1.48M. >0,& Q. ANL R0301
A

-W,

:

ol,
I
At& Arlificatlalli of tho 110thoct o the studr_
Tosis into of Fit
rygilattr into
M
"

Ph 4 the Penctra-
'
ul 'td'
.4 it,
orust ttmectie'litct and expetlica
t1ti K. a. I'mr,
n into the Plants.
,
a, alid Cher-
'IV
ftML XM; R. V
" @ 1, 1
D- . @
-
) anti Rt-
ll"N()
ift
CtO)
PS(OC
ll; of (
W
l
.
"A
le
3
'
xit"
,
4
till Whic I were
t
d [
1% d
it
were use
i
'
mI
l
i of th
laij
s
l
i
F
1
f
l
L
A
& -
ellia
t: sitcc
llie
e
C all,
l
I
e
to 111.1
t:
C
14
P
thAn tse
_wqtz
tahlc,. A dimct telatitin wat found tlctwxti the atut. of P
W14ch penrtrateN the Insect botlyarui the degree of poison-
inj@, wit hill crichysp(l. &Toup. 11rathoccumwitit lower level
ot-tTic di-lit dcriv. Iltan inonti.-Vt deriv.. but this 6 cauwd
tiol! by a incre differetwe of diFfui;,qn.,Mnce its dead sp-z6viteris
tltll difftnt" lit pvclwattflity d-,tpjwars twWver fetuttles
anti 111AC-4. 06@utthvmtun plants xvTre allowed to ah-iorb
Ilifaugh tho itsti-i aq. cinuhlons of ilm 411-Ut deriv. (0.03-
0 and t6-:=uctration to the le-ivei was mtudii.,d ridlo..
A, with even 0.2% tilloblon fail'A to
sprAyin
IC coutirol of AuttxcrtAaoz althouglt
iliciallit. of 'he Inwcticitle wlikh 1xinctrated tbe plant iw.sA
"hed 0.0al" cor-
'10 of the greeii irwsi lit rooln temp. Thi:

1
"
20,10 ing./k9. At levver tentit, Wita this value
1,1
In d.1
6
0
Inc. kg. a mighli-table degree of coittrol was lit.
I
tni ded "tI The
mets contained tilt to'12 mgJLjl. of tile ill-
lit deriv. Tile lictictratkull into clitysaritheinum was wb-
s0 rithilly jike*tt foutut lit bLctq. Jimt-ver. ou'cebltare*
@Ctllt@lrL3 no Control wa-t achlev'd by this'lliettloct aplost
B'evicoryne bearfitcre. al lonves WL43 of.).
orhiglw. Intah-
CIDU. hydrolysis of
tlll@ Insocticille took IlLarn kod rkfttr 10 days only tile hy.
'
dral
ysil Products ""Llined, M14 pruct" is acccitimted by
sunl@llt' 1-hiitillir with 170 thtit. oil shaded k6lacy b@-.m4
ShOwM 441% hyil"%%ii aft" 141 day,. lit tnolight Alnwx't all
waihydrolymlin-Idays. Onwbeattli r prm-css pitc-t but 2 ,
il,ky% Thwt, i@rathion ii itot truly a systeltik hismUtle
owhig to Its txw lwanctration and stability lit tbo ptoit@
K"'.whipoll
7-

- - - - - - - - - - - - - -

GARY K. A.
"Research by Means of Radioactive Isotopes Concerning Penetration and Residues of
Phosphoorganic Insecticides in Plants," a paper presented at the Atoms for Peace
Conference, Cieneval Switzerland, 1,055
.2F

A
MW Medicine - Physiology
Oaxd 1/1 Pub. 22 - 46/49
Authors I Gar, K. A. Sazonova, N. A.; and Fadoyev-j Yu. N.
Title I Decomposition and separation of diethyl-4-nitropherWlthiophosphate from
the organism of a rabbit during intravenous introduction
Periodical I Dok. AN 33SR 102/1,, 185!-187, May 1, 1955
Abstract Experiments were conducted on rabbits injected intravenuously with a
toxic phosphor-organic compound (diethyl-4-nitrophenylthiophosphate).
to detemine the rate of decomposition of the toxin and its separation
from the living: organism of the animal. . Results obtained are 31sted.
Five USA references (1950-1953). Graph.
Institution i So. Res. Inst. of Fertil. and Insectofungicides im. Ya. V. Samoylov
Presented by Academician Ye. NcPavlovakiy) December 29p 1954
MOW
D- +-r7 ?a 7.

t4
USW Medicine Physiology
Card, 'A Pub. 22 - 46/46
9 Oars K% A.; Sazonovaj N6 As; and Fadeyev, Yu. N.
awll&
Title. I Penetration of dimethYl-4-nitrophenylthiophosphate into the blood stream
and its effect on the activity of cholinesterase during oral poisoning of
Periodical I rabbits
Dck. AN SSSR 103/li, 173-176s Jul 1, 1955
Abstract i Experiments were conducted on rabbits to determine the degree of penetration
of dimethyl-4-nitropheTWlthiophosphate. (administered orally) into the blood
stream of the animals and to study its effect on the activity of cholinester-
ase during the poisoning of the rabbits. Results are described. Eleven
references: 8 USA and 3 Eng. ('1951-1953). Table; graphs,
Institution Sc. Inst. on Fertil. and Insectofungicides im. Ya. V. Sawylov
Presented by: Academician A. Engellgardt, April 12, 1955

GAR, K. A.
-
Study of factors influencing the effectiveness of various types
of DDT dusts In controlling shield bugs. (Trudy] NIUIF no.156:
36-45 '55. (HLRA 9:10)
(DDT (Insecticide)) (Barygasters)

T J
1!*cndtH1ty and sadfmentation of DDT and hoxi-
&IrAft dasits, K. ft. Car. _rroy. Nargh. last. udokta.
--Y4. V.-Sd@IOVIGM IqS5, No, ISO. 45-
4 liuch fisir 7M.
@hllh 6r,224isperskil is essential to (lie tulkity of
DDT . - an dusts. Adlictonce Increws with
an beraelit'r
"ilk sutfacc S - Wi. but drift is alo Incrt-ised. S@Uk-
`hcivsW showeti.that sedientritatlor. of In= partic" Is
mvift slower tMa c@pcctcd finna Stokes* AwniuLA. This Is
ext@Wued by the vi-tuat viscosity A of tnaving air; A 5.5
atol. whcre a Is ad Index Of the a!r turbulence. and F Is air
vtkcjty, in M./im, When 0 - 1. the Vidual VIWO21ty of
the lilt Is about 350 times the mokeular;. CAN)MO finics when
v - S. But air moverriono am turbident, and there are
moments of @ swiststm, when ilust scallacritatWu follows
Stout W tAw; the - probability of such montents decreates
ft=% 0.5 to 6.06 vititzi wind vtSocity Inemms froin 0 to 2
in./jec. - Real spftt of sedinientatIon S1. in cn./ftc.. Is,
expit3sed.by the tqu@tka:- S' w (219)qPktljg, where
112@
&MIM(ion due- to 0-avitatim-(Q-91 cm./We.). P Is Pro,
bilit of the YL*odmctrk suriftIt Of atus, & is d. of pq-@
=11. g.jp., , I. radls of putkies in =.. and jii 13 niol.
Wty c the air ia V./cui./scc. Speed of sedinir-itation is,
invendy proportle-w1to the deVftAj4!spcrs;Icu, Expo.
in im aerodkn=k tuM confirmed the aboye hwatula.
D61ations Observed with kanfin dusts are explained by the
ReAhneraticim of &jst--p=d&& -.Adda.
of tate to Laolin
(1:1) Inipmesdispertion and alcmsedinmentation. Ficki
1. thimect that the deposition of DDT and hexachloma-
Id
.14@i with hormls mu& better than Of (11-5d With take.
depositim d dusu with kaolim and tak- (1: 1) Is much
P"er than of these with tak alme. This is erplalnW by
=bc!rdkpftAox& a the kW)-t-Ic inixt. and important
5 f tiny kaaa pudetes.hy drift. Tte acrodynarnic
tub@ with autocutle recordea, appeated to be a very usef ul
tMI; the search WoPtIMM Partwe sue of
dusis 2 teference&.:@ yet,-.

GAR, K. A.; CHERHMS07A. V.I.
Stabilit7 in the toxic action of hexachloro-cyclohexane and DDT
dusts tinder various conditions. [Trudy] NIUIF no.156:55-64 '55.
(MLRA 9:10)
OIDT (Insecticide))
(Benzene hexachloride)

GAR, K.A.; MOLCHANOV, A.Y.; BEWBRAZOV, Tu.N.; DUBOVITSKIT, A.M.
Using the ash from Cottrell filters of electric power stations
as filler In preparing dusts. [Trudy'] NIUIF no.156-73-89 155.
(MLBA 9:10)
(Innecticidee) (Ash (Technology))

GAR, Konstantin Arkadl-yevich
N15
632.58
.G2
Kbimicheskiye Preparaty Dlya Zashchity Rasteniy (Chemicals for Plant Protection)
Moskva, Sellkhozgiz, 1956.
1-15 p. illus., tables.
"Literstura"; p. (11-4)

KAMSHILOV, N.A.; ANTONOT, KJ.-; BAEHAREV, A.N.; BLINOV, L.F.; BORISOGLEBSKIY,
A.D.:,P44,I.A.; GARINA, K.P.; GORSHIN, P.F.; GUTIYEV, G.T.;
DELITS INA, A.V.; DUEROVA, P.F.; YEVTUSHENKO, A.F.; YEGOROY, V.I.;
YMEMENKO, L.L.; YRFIROV, V.A.; ZHILITSKIY, Ya.Z.: ZHUCHKOV, N.G.,
pro-.; ZAYBTS, V.K.-, ISKOLODSKAYA, R,B.; KOMNIKOV, V.A.. nrof.-,
KOIJ,'SNIKOV, Ye.V.; KOSTINA, K.F.; KRUGWYA, V.A.; IMONTIYEVA, M.N.;
LESTUK, Ye.A.; MUKRIN. Ye.N.; NAZARYAN, Ye.A.; UNGRUL', A.M., prof.;
ODITSOV, V.A.; OSTAPINIO. V.I.: PSTRUSEVICH, P.S.: PROSTOSURDOV.
N.N., prof.; RUXAVISHNIKOV, B.I.; RTABOV, I.N.; SABUROV, N.V.;
SABL410VA, T.R.; SAVZDARG, V.11.; SAMIN, V.S.; SIMONOVA, M.N.;
SMOLYANINOVA, N.K.; SOBOLEVA. V.P.: TARASENKO. M.T.; YETISOV, G.G;
CHIZHOV, S.T.; CHUGUNIN, Ta.V., prof.; YAZVITSKIY, M.N.;
ROSSOSHCHANSKAYA, V.A., red.; BALUM, A.I., tekhn.red.
(Fruitgrower's dictionar7 and handbook] Slovarl-spravochnik
sadovoda. Moskva, Gos.izd-vo sellkhoz.lit-ry, 1957. 639 D.
(MIRA 11:1)
(Fruit culture--Dictionaries)

4.
USSR General and 3@)ccializcd Zoology. Insecta. Insect and P
Kitc posts.
Abs Jour : Ref 4iur Biol.) No lo, ig.)Qr', *Iro 4,1046
Authors : Gar 1--. .", Gmnia) Ye. F.
Inst -FoeS-VII.,
Titlo The T,@3ting of Now Prcpamtionc for Prooowing Trontraont of
Sugar-Boot &,,,ds.
Orig Pub Zazhchitr- rast. ot vredit. i bolcziic,,, 1957, rio. 1, 46.
Abstract Chlor&inc, haptachlor, aldrin, dieldrin, isodrine and andrino
verc -W-sbaad in e@erimants on small plots. Ethalone - FCC11
(tachnical and enriched with gamrra-izomer to 99-100 parcent).
1ho effictivaness vas detarminod at various periods Nn to 9
days) after sprouts appeared in glass contilners on tho PlOtG
The d,@--d bcQtlcs were counted 1 1/2 and 3 days after addin3
tham to th-, plant containers. P.11 the insceticidas testQd led
Card 1/P-

"Preparations TestedAgsinst Suctorial Cotton Pests," by A. V.
Flyaginaj, Senior Scientific Collaborator at the All-Union
Scientific Research Institute of Cotton Growing, Tashkent,
ZaGhchita Rasteniy ot Vrediteley i Bolezney, Moscow, Vol 2,
NO 1, Jan7Feb--57, 1) 47
Tests were carried out to determine the comparative effectiveness of
organophosphorus insecticides and chlorinated terpene insecticides when
applied for the control of suctorial pests which attack cotton plants.
The tests were conducted at the Station for the Protection of Plants of
the Soyuz Scientific Institute of Fertilizers and Insectofungicides. The
insecticides that were tested were synthesized at the All-Union Scientific
Research Institute of Cotton Growing and included toxaphene, chlorten,
chlorten with DDT, polychlorpinene, polytoxaphene, vofatoks, a 30-percent
emulsion of thiofos, and a mixture of lime-sulfur decoction with anabazine
sulfate. All tests established that the organophosphorus insecticides
were considerably more effective than the chlorinated carbon insecticides,
and the use of the latter is not recommended.
(Comment: Chlorten is obtained by the photochemical chlorination of
a-pinene, and contains no less than 64 percent of chlorine; vofatoks, also
known as metafos, is diamethyl-4-nitrophenylthiophosphate, according to
Xhimicheakiye Preparaty djM Zashchity Rasteniy (chemical Preparations for
the Protection of Plants) by K. A. Gar, Moscow, 1956, p
@p 40 and 28J

BNZOBRAZOV, Yuriy Ilikolayevich; HOLCHANOV. Andrey Yatill'yerich;,GAR,
Koustantin Arkadlyevich; RATRAIISKIY, N.S., red.; SHPAK, Te.G.,
takhn.red.
[Hexachloran, its characteristics, its manufacture, and uses]
Geksakhloran. ego avolstva, poluchenie i primenente. Moskia.
GoB. nauchno-tekhn. izd-vo khim. lit-ry, 1958- 315 P- (MMA 11:5)
(Benzene haxachlorld4

USSR/General and Specialized Zoology - Illsect3 - Har-iful insects P
and Acarids. Chemical Means in the Control of
Harmful Insects und Acarids.
Abs Jour Ref Zhur Biol., No 6, 1950, -54o4
Author Gar, K.A.
Inst
Title Industrial Experiments of 65% Concentration of Chlorthbae-
Orig Pub : V. sb.: Organ. insecto-iLng-5-ts--dy i gerbitsidy. M.,
Goskhiriiz,@,It, 1958, 208-2--0
Abstract : Of all the chlorthene (Ch) preparations obtained by the
photochemical method, the most accept@,ablle w--s the prepa-
ration containing about 64% of Cl. The reduction of Cl
in Ch decreases the toxicity and increases the phytocidic
property of the preparation. An increase of Cl in Ch
from 64% to 6% slightly increases the toxicity, has
little effect on the phytocidic property and sonewhat
increases the atability of the preparution. On the baais
Card 1/2
5
USSR/General and Specialized Zoology - Insects. Harrdul Insects P
and Acarids. Chemical Means in the control of
11an'aful Insects and Acarids.
Abs jour Ref Zhur Biol., no 6, 1959, 254o4
Of experiments carried out in various USSR zones, there
were histod the npeCies Of mites end inject,. and the
effectiveness OP @On@!entrated emulsions of 61% ch prepa-
ration (they accapted for introduction into 'practice)
used for their control. Effective concentrations of Ch
emulsions are not phytoc@dic to plant
.L species. Pests in
the control Of which Ch, is slieltly effective are ijldiCa-
tcd. The treatmtnt Of veu-,et4tble cultures in closed 6xound
with aerosols of a 2% sOlutio-1 of technical Ch in grocil
oil was very effecti-vu '-'!' controllinG mites on
cucumbers, an--other culturt:s 'alustiu and aphids
at an outla-, of 5-20 cm3'
Ach-ianov 10 /r13 Of tile solution. A.P.
Card 2/2
P

USSR/General and Specialized Zoology Insects. linrmful Insects P
and Acarids. Chemical Means in the Control of
Harrd'ul Insect's and Acarids.
Abs Jour Ref Zhur Biol., uo 6, 1959, 25405
concentration against (-;'.ter-;.'1.laru of the apple and Mac
mining moths, on-1 in 0.5 and 11,1. concentrations aqAi:ist the
maple leaf rollc-r. 13oth concentrate e-xalsions were highly
effective in the control of mites, plum aphids and pear
psyllas. When plants were sprayed with emulsions of Ch
and DDT not in one case wc-re there observed scaldings of
the leaves. -- A.P. Adrianov
Card 2/2

IVAIJOV, I.I., Agro no M-e ntono log (Khaybulli nakiy myo u, Bashkirskoy SSR); I
LEVIN, R.I.; GAR, K.A. ,-
Lettore to tho editor. Zashch.rast.ot vred.i bol. 4 m-3:60
my-is 159. (MIRA 13 - 4)
1. Zaveduvusbehiy punktom aluzhby ucheta i progno2ov Irkutakoy
oblauti (for Levin).
(Plants, Protection of)
.4-

1-7 (2)
AUTHORS: Gar, K. A., Yevteyeval N. V.j SOV/20-127-6-41/51
'A'ftdi-67V?W'-Ye. I.
TITLE: On the-Fungicidal Activity of the 6-Isomer and of the Mixtures
of b- and @-Isomers of Hexachlorocyclohexane
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 127, Nr 6, pp 1290 - 1293
(USSR)
ABSTRACT: The outstanding insecticidal properties of the t-isomer of the
compound mentioned in the title facilitated the production of
a number of chemical insecticides for agriculture as well as
for veterinary and sanitary disinfection (insect killing). Com-
mercial hexachlorocyclohexane contains 6 isomers. The content
of S'-,isomer, which is practically the only insecticide, amounts
to 10-1 A,. Many procedures have recently been developed for the
purpose of raising the content of r-isomer. The non-toxic iso-
mers are mostly removed by means of extraction by organic sol-
vents. They may then be further used. Preparations enriched in
this way are not only more active but they also change the
taste of the crops less than commercial hexachlorocyclohexane.
--These enriched preparations are particularly important and
Card 1/3 valuable for seed treatment. In this connection, and in view

On the Fungicidal Activity of the 6-Isomer and of the SOV/20-127-6-41/51
Mixtures of 6- and J'-Isomers of Hexachlorocyclohexane
of the hypothesis on the poisoning of living organisms by
K. A. Gar (Ref 1), the authors carried out a thorough inves-
tigation of the remaining isomers, particularly of their fungi-
and bactericidal activity. The results obtained were not only
interesting but they instigated further investigations of this
problem. It was ascertained that the a- and P-isomers have
practically no activity whereas the J'-, and particularly the
6-isomers possess fungicidal properties, the toxicity of the
latter being very specific for microorganiams. Figure 1 shows
photographs of the Petri dishes in which spores and mycelia of
the fungi Fusarium. and Diplodia were sown upon potato-dextrose-
agar with addition of 0-05; 0.01 and 0.002% - and 6-isomers.
The addition of r-isomer to the nutrient medfum inhibited the
growth of the colonies only in the case of Diplodia zeae
(Schw.) Lev. The 6-isomer, on the other hand; caused either
a complete or an extensive suppression of growth in all species
of fungi investigated (D.zeae, Fusarium. oxysporum, Botrytis sp.@
a species of penicillium, yeast, etc). The strongest inhibi-
tion by medium concentrations is worth mentioning. This parti-
Card 2/3 cular effect of the two isomers suggests the capability of

On the Fungicidal Activity of the 6-Isomer and of the SO'1/20-127-6-41/51
Mixtures of 6- and 4t-Isomers of Hexachlorocyclohexane
forming so-called tong-like complex compounds with some metals
which participate in these or other ferment systems (Ref 3).
On the basis of the results obtained, informative field ex-
periments were carried out at the Dolgoprudnaya agrokhimiche-
skaya stantsiya (Dolgoprudnaya Agrochemical Station) of the
Institute mentioned under "Association" (Tables 1 and 2). The
treatment of the wheat- and linBeeds favored their germinating
power, and greatly reduced the affection by fusariosis, or
fusariosis and polysporosis respectively. Wheat wau fully re-
lieved of wheat smut (Tilletia tritici). The effect was even
better than that of the mercury preparations. Doctor R. Smrzh,
Yu. 11. Bezobrazov, and A. V. Molchanov supplied samples of the
preparations. There are 1 figure, 2 tables, and 3 Soviet ref-
erences.
ASSOCIATION: Nauchnyy institut po udobreniyam i ineektofungicidam (scien-
tific Institute of Fertilizers and Insectofungicides)
PRESENTED: May 5, 1959, by S. I. Vollfkovich, Academician
SUBMITTED: April 29, 1959
Card 3/3

SHOGAM, S.M.; FENIKOVA, Ye.I.; GAR, K.A.; POSLAVSKIY, Yu.K.; GOLUBEVA, Z.Z.
Investigation of fillers and selection of appropriate machinery
for the production of new organic powder insecticides. (Trudy) '
NIUIF no.164:3.-5 '59. (MIRA 15:5)
(Insecticides)

GAR, K.A.; DOBROKHOTOVA, N.M.; YF.VTEYEVA, N.V.
--, __.- - - - -- Studying the processes of penetration and metabolism of some
organic insecticides in insects and plants. (Trudy] NIUIF
no.164:5-6 159. (MIRA 15:5)
(Insecticides) (Succinic dehydrogenase)

GAR, K.A.; GULEWKOVA, L.P.
Selection and evaluaticn of preparations for contirolling the
Colorado beetle. (Trudy] NIUIF no.16416 '59. (MIRA 15:5)
(Insecticides)

MELINIKOV, N.N.; VOLIFSON, L.G.; KUZNETSOVA, K.V.; SAFOZITOV, Yu.N.;
GAR, K.A.; GRANIN, Ye.F.; FARBER, M.S.
--------------
Insecticides baXed on hexachlorocyclopentadiene. (Trudy] NIUIF
no.164:8-11 159. (KRA 15:5)
(CyeloDentadiene)

GAR, K.A.; CHEKALINA, V.I.
Investigation of the toxicity of chlorinated terpenes. (Trudy]
NIUIF no.164:40-41 '59. (MIRA 15:5)
(Terpenes) (Insecticides)

GAR, K.A.
Organization of investigations on insecticides and fungicides
in the Chinese Peoplels Republic. Zashch. rast. ot vred. i
, bol, 5 no.1:45-46 Ja 160. (MIRA 14:6)
(China-Insecticides)
(China--J'ungicides) -

S/020/60/132/02/28/067
BO11/BO02
AUTHORS: Boldyrev, B. G., Gar, K. A., Yevteyeva, N. V.
TITLE; Esters of Thiosulfonic kcids as Now Fungicides@
PERIODICAL% Doklady Akademii nauk SSSR, 196o, voi. 132, No. 2, PP. 346-348
TEXT: Esters (I) of thiosulfonic acids are effective against microorganisms
within a wide range. They also stimulate the development of plants thus increas-
ing harvest. The authors investigated the fungicidal properties of methyl eaters
of alkanethiosulfonic acids (III), and the trichloromethyl eaters (IV) of these
acids. The authors do not agree with the American investigators (Ref. 3) as
regards the assumption that the fungicidal effects of trichloromethyl esters oi-
d i f f e r e n t thiosulfonic acids are the same, regardless of the nature
of the radical (Formula IV). This was disproved by the authors (see below). They
also tested some aryl esters (V) and (VI) of alkane- and arene-thiosulfonic
acids. The fungicidal action of all these esters was tested in the toksikologi-
cheskaya laboratoriya (Toxicological Laboratory) of the Institute imeni Ya. V.
Samovlov (see Association) in the following species of fungit Diplodia zeae,
Alternaria radicina, Verticilium dahliae, Fusarium. vasinfectum and Fusarium
Card 1/3

Esters of Thiosulfonic Acids as New Fungicides SIM16011321021281067
B011/BO02
oxysporum. Certain concentrations of these preparations dissolved in acetone,
were introduced into agar nutritive media, into which the fungi then were sown.
The action of the esters was determined after 5 days. Similar experiments with
equal concentrations of Figon, Kaptan, and Tsineb were conducted for
comparison. Table 1 shows that trichloromethyl esters of alkanothiosulfanic
acids are the most effective among all substancis examined M. During experi-
ments in vitro they had a much better effect than similar esters of arenethio-
sulfonic acids. This action, however, is not due to the trichloromethyl group;
the substitution of chlorine atoms by hydrogen atoms influences the activity of
the compounds under consideration. The special effect of the nature of the acid
radical R becomes evident during transition into the aryl esters of thiosulfonic
acids V) and (VI). While the aryl esters of methane- and ethanethiosulfonic
acids @Table 1, No. 10-13) are still strongly fungicidal and even surpass the
trichloromethyl esters of arenethiosulfonie acids (No,, 7-9) in their action,
aryl esters (VI) are considerably less active than other esters (I). Some of
them, however, are not inferior to fungicides as active as Kaptan. The esters
discussed here, particularly those of alkanethiosulfonic acids are thus highly
active fungicides and are worth further investigation. The action of the
fungicides was investigated in the Institut mikrobiologii AN USSR (Institute of
Card 2/3

Eaters of Thiosulfonic Acids as Now Fungicides
Microbiology of the Acad
references.
5/020/60/132/02/28/067
BO11/BOO2
of Sciences, UkrSSR). There are I table and 2 Soviet
ASSOCIATION: L'Vovskiy politekhnicheskiy institut (L'vov Polytechnical Institute).
Nauchnyy institut po udobreniyam i insektofungitsidam im. Ya. V.
Samoylova (Scientific Institute of Fertilizers and Insecto-fungi-
cides imeni. Ya. V. Samoylov)
PRESENTEDs January 13, 1960, by S. I. Vollfkovich, Academician
SUBMITTED: January 3, 1960
Card 3/3

GAR, K.A.; GUSAKOVA, M.V.; CHEKALINI, V.I.
Investigation of the toxicity wid phytocidal capacity of the
distillates of some chlorinated terpenes. [Trudy] NIUIF
no.171M-80 161. (FJRA 15:7)
(Chlorine organic compounds) (Insecticides--Toxicolo'gy)

POSLLVSKIY, Yu.M.; GOLUBEVA, Z.Z.; GARp K.A.
Jkppl-ication of DDT dust combined with chlorinated terpenes
against cotton*bMworms. [Trudy] NIUIF no.17l18l-83 161.
OffAk 15.- 7)
(Bo3lworm) (DDT (Insecticide)) (Chlorine organic compounds)

,GAR, K.A.
Against plant diseases and pests. Priroda 52 no.4160-.62 163.
(MIFA 16:4)
1. Nauchno-issledovatel'skiy institut po ubodreniyam i
insektofun tsidam im. Ya.V.Samoylova Moskva.
fFungicides) (Insect4ides)

PEY-VE, Ya.V.; PETERBURGSKIY, A.V., doktor sellkhoz. nauk, prof.; GAR,
K.A., kand. sellkhoz. nauk; GOLYSHIN, N.M., kand. biol.
@a-uk; KOROTKIKH, G.I., kand. sellkhoz. nauk; CHESALIT, G.A.,
kand.sellkhoz.nauk; RAKITIN, Yu.V., doktor biol. nauk;
ZEZYULINSKIY, V.M., kand. sellkhoz.nauk; DEVYATKIN, A.I.,
kand. sellkhoz. nauk; VENEDIKTOV, A.M., kand.sellkhoz. nauk;
TARANOV, M.G., kand. biol. nauk; BORISOVA, L.G.; BEREZNIKOV,
V.V., kand. tekhn.mauk; KONLRATENKO, R.V., st. nauchn.sotr.;
BORISOV, F.B., st. nauchn.sotr.
(Chemistry in agriculture] Khimiia v sellskom khoziaistve.
Moskva, Kolos, 1964. 381 P. (MIRA 17:9)
1. Chlen-korrespondent AN SSSR (for Peyve). 2. Nachallnik
laboratorii Nauchno-issledovatel'skogo instituta plastmass
(for Borisova). 3. Ilauchno-issledovateliskiy Institut
plastmass (for Kondratenko, Borisov).

GAR, Konstantin Arkad'yevich; BOBNEEVA, N.P.v red.; ZOTOVA, L.A..v
'-'- -red.-
[Glioinistt7 protocts crops) Kidnilin zashchislichaot u---o-
zhai. Moskva, lzd-vo "Znania," 1964. 27 p. (Novoe v
zbizni, nauke, tekhnike. V Seriiq: Sellskoe kho-.iqistvo,
no.12) (Mi(A 17:7)

'MU'MXC, Gl,iNaO, L.P.1 KILINOUKly, M.S.j GAR. X.A,
Part. 201 L-1.1hy-1 a:3ters of N-tiryislil.fonyl-N-arylcarbamic
a,;Id. I,ur. arg. l(Yljc, I no.li!21-124 Ja 165; (MIRA 18 t 5)
1. Enoprotxttrovskiy gciuaearstvennyy univorsit8t.

WA b -2 RO
ACC NRI AP600039 Scufic-E--C-,O-D-E--:--UR/0348/65/000/010/01)33/0036
@ AA
AUTHOR: Gar# No (Doctor of Agricultural Science)
ORG: VNIIKHSZR
TITLE: Pesticide compatability
SOURCE: Zaabohita restenly ot vrediteley I bolazney, no. lop 1965,
33-36
TOPIC TAGS: plant disease control, peaticidep fungicide, chemical
reaction, organic phosphorus compound, orge-nic sulfur compoundp calcium
compoundp copper compound, Insect contro
114
ABSTRACT: The problem of postioidardompetability-appaars when two or
more chemical compounds wi-5-Ji-rfai-ant properties ore required for
simultaneous treatment of plants. The present paper discusses the
compatability of 27 different pesticides and fungicides In relation to
one another indicating when mixing Is requIredo recommended, not
advisablep or ineffective, Anabasin- or nicotine-sulfates require the
addition of soft soap, limep or alkali to Improve wetting and to break
down the sulfate molecule for higher toxicity, Mixing Is recommended
wben the toxic effect cam be intensified, an in the case of DDT and
Card
Cmd -------

NRI AP6000390
polyohlorpinene against leaf eating bugs, or when several harmful posts
can be destroyed with fewer treatments, as in the ease of sulfur and
copper fungicides aninst mildaw and oldium on grape vines. Mixing of
organic fungicides Oaptan', zineb and dieblone) with mineral oil
preparations is not recommended because this may cause burning of plant
For the same reason, mineral oil preparations should not be combined
with preparations containing sulfur. Also, calcium arsenato which
contains lime cannot be mixed with preparations that break down under
its affect$ such as copper oxyohloride and bexacbloran., In some caseS2
mixing is ineffective baoause the preparations produce similar effects;
and '$ with simultaneous application, the effect is not intensified due
to action mechanism differences, as in the case of anabasin- or nicotin
sulfate preparatiofis mixed with organopboapborud,,preparations or DDT
with calcium arsenate. Combined application of chemical preparations#
particularly herbicides with insecticides or fungicides* should be
approached carefully. Orige art* has: 1 table*
suB coDE.- o6. o2/ suBm DATs: 00/ ORIG REPt 000/ OTH REV: 000

S@632/62/000/000/013/015
D 24/D307
AUTHORSs Gar. P-P., Gundyrev, A.A., Nametkin, N.S.,
PE-n @henkov, G.M. and Topchiyev, A.V.
TITLE: Refractometric investig@tions of some
organosilicon compounds
SOURCEI Issledovaniya v oblasti kremniyorf;aniches-
.kikh soyedineniy; sifitez i fiziko-khimiches-
kiye svoystva. Sbornik statey. Inst. neftek-
him. sint. AN SSSR. Moscow. Izd-vo A14 SSSR,
1962, 228 - 234
TEXT: The refractive indices at 200C for the C and P
lines of hydrogen (for the first time) and for the D line of *
sodium have been measured for 46 compounds of the following classes,
the hexaalkyl derivatives of disilylmethane, disilylethane, and
disilylpropane, and of disiloxane, aryltrialkylsilanes, diaryl-
dialkylsilanes, and linear and cyclic polyethoxysilanes. From the
results, the individual, mean and specific dispersions, and the
Card 1/3

S/632/62/000/000/013/015
Refractometric investigations ... D424/D307
molecular refraction for the 2) line, have been calculated. As
a rule, in any one clasz; of alkylarylsilanes those in which the
alkyl group is ethyl have the highest refractive index. The re-
fractive indices of dialkyldiarylsilanes are about 0-05 units
higher than those of the aryltrialkylsilanes with the same alkyl
and aryl groups. In the case of the phenyltrialkylsilanes, the
introduction of a methyl group into the 4- position of the phenyl
ring and then a second methyl group into the 5- position increases
the refractive index, while the situation is reversed in the case
of the aryltrialkylailanes. The specific dispersions of aryltri-
alkylsilanes are 15 - 20 % lower than those of the corresponding
diaryldialkylsilanes. The refractive indices of the hexaalkyl
derivatives of disilylmethane, disilylethane, and disiloxane
increase with a rise in the molecular weight, those of the di-
siloxanes bein& less than those of the corresponding members of
the other clhsses. On passing from hexamethyldisilylmethane to
the corresponding ethane and propane derivatives, the refractive
index increases by 0.0025 units per CH2 group added, while the
specific dispersion is decreased. The change in the specific
Card 2/3

S/832/62/000/000/013/015
,tefractometric investigations ... D424 D307
dispersion of the hexaalkyldisiloxanes is anomalous, the ethyl
compound having the lowest value. The refractive indices of
pol.,vethylsiloxanes increase by 0.007 per diethylsiloxy group
and are much higher than those of the corresponding polymethyl
conpounds. Dialkylsilanes have much higher refractive indicea
and specific dispersions than the corresponding hydrocarbons.
The molecular refractions of all the compounds investigated
were calculated by Sauer's method (J.imer.Chem.Soc., 66, 691
(1946) ) from established group and bond values and the results
were found to be in good agreement with those calculated from
the experimental data. There are-3 tables.
Card 5/5

S/06 2/v *2/00 0/003 /0 10/014
BI 17,'B- 44
AUTHORS: Mironov, V. F. , Dzhurinskaya, N. 0. , Gar, T. K. , and
Petrov, A. D.
TITLE: Reactions of allyl halogenides and benzy.' chloride with
germanium hidrides
PERIODICAL: Akademiya nauk SSSR. izvestiya. Otdeliniye khimicheskikh
nauk-, no. 3, 1962, 460-465
TEXT: The recently discovered reaction (Izv. AN SSSR Otd. khim. n. 1960,
2066) of trichlorogermaniumhydride with halogenides of the allyl type, in
xhich halo@:en is substituted by the trichlorogermyl group, was studied in
detail. The reactions of allyl iodide and methallyl bromide with
trichlorogermaniur,hydride were found to proceed exclusively as condensa-
tion. Methallyl chloride, similar to allyl chloride, requires, of course,
the presence of other, since essentially without it an addition takcz)
place. In the reactions investigated, high-boiling by-products were
always formed which may also contain products of the addition of the second
HGeC1 3 molecule at alkenylger-.ianiumhalogenides. Besides condensation,
Card 1/a

--/062/62/000/003/010/014
Reactions of allyl haloeenides and ... B110144
y occurs in the presence of H P'Cl,, other r,:actions also take
which onl U
2 0
place durin,- the reaction of trialky1germaniumhydrides -aith allyl
halogenid An experiment to extend the condensation also to saturated
and aromatic halo&enides was 'without success so far. i7ith benzyl chloride
and tertiary butyl chloride, however, this reaction proceeded successfully,
good yields in benzyl tri chlo roe, erm, aniumhydri de and tertiary butyl-
trichlorogermaniumhydride being obtained. Raman spectra of the new
substances whose properties are listed in Table 2 correspond to standards.
It was nointed out finally that no similar reactions exist in the
chemistry of organic compounds of other elements of Croup IV. L.A.Leytes
is thanked for conductin,5 the spectral analyses. There are 2 tables and
7 references: 6 Soviet and i non-Soviet. The reference to the English-
language publication reads as follows: A. J. Vogel, Y". T. Cresswell,
J. Leicester, J. Phys. Chem. @8, 174 (1954).
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Instituto of Organio Chemistry imeni
N. D. Zelinskiy of the Academy of Sciences USSR)
SUBMITTED- October 20, 1961
Card 2/4

MIRONOV) V.F.; GAR, T.K.
Reaction of trichlorogermane with butadiene. Izv.AN SSSR.Otd.
khim.nauk no.3:578 Mr 163. (MIRA 16:4)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR.
(Germanium hydrides) (Butadiene)

s/o6 2/62/ooo/ooe/oo6/oi6
B117/B180
AU@HORS: Mironov V-- F., Gar, T. K., and Leytes, L. A.
TITLE: Synthesis and spectra of organogermanium compounds containirg
cyclopentadienyl, cyclopentenyl and cyclopentyl radicals
PEMIODICAL: Akademiya nauk SSSR. IzveBtiya. Otdeleniye khimichaskikh
nauk, no. 6, 1962, 1367-1392
TZXT: The above compounds have been synthesized for the first time and
their IR spectra studied. Compounds containing cyclopentadionyl radicals
were synthesized as follows:
Go A1,S)a
(X
h1gBr -
C11,
Go-- -Go (Clls)a C21f,
between 500-600 cm-1 the S@ectra*of these three compounds show lines
Card 1/3

S/(62/62/000/006/006/016
Synthesis and spectra of B117/B180
appropriate for the valence fluctuations of the Ge-O bond. Besides -this,
they all showed a series of lines obviously corresponding to vibrations
of the cyclopentadienyl ring bound with the germanijm atom. Analysis of
the spectra, which resemble those of cyclopentadienyl silane, shows that
cyclopentadienyl germanes*have covalent structures and are therefore not
sandwich compounds- Compounds containing cyclopentenyl or-cyclopentyl..
radicals were synthesized by addition of trichloro germane to Icyclo-
pentadiene or cyclopentene. Intense lines in the 370-430 cm- range)
corresponding to the vibrations of the Ge-Cl bonds, were detected in the
spectrum of cyclopentenyl trichloro germane. In the cyclopentyl trimethy!
dermane spectrum, the valence vibrations of the Ge-C bonds appeared as
bright lines in the 550-610 am-1 band. Above 900 cm-1 the two spectra
are similar. Lines typical of the oyolopentane ring were found in the
following bands; 090-910 am 11 1030 arrl (Raman spectrum), 1450_ 1460 cm-'s
2860-2870 cm-14 It was not possible from the spectra to decide whother
the compounds woke
C>--GeR 3 or !O'-GeR 3' There are 7 figures and I table.
Card 2/3

S/06 62/000/008/006/016
Synthesis and spectra of ... Bl I 7YBI 80
ASSOCIATION; Institut organicheskoy khimii im. N. D. Zelinskogo Aademki
nauk SSSR (Institute of Organic Chemistry imeni N. D.
Zelinskiy of the Academy of Sciences USSR)
SUBMITTED: February 19, 1962
f
V
Card.3/3

V.F.;,..G-AR, T.K.
Internction of tl'icil-10rogormane with cOnJugated dienes. fjokl.
SSSR 152 no-5:1111-1114 o 163. (MIRA
I* Institut organtchoskoy khilii im. N.D.Zalinskogo AN SSSR.
AN
l6sl2)

----------------
L 14462-65 ridn W/,07 (c)/Dip W/T Pc-4/Pr-4 Rx
@ACCESSION NR: AP404h706 S/oo62/64/m/oo8/1515/1518
AUTHOR: Mironov, V. F.; Gar, T. K.
TITLE: Reaction of triehlorogermane'lwith acetylene nd its deriva-
tives
SO'URCE- AN SSSR. Izvestiya. Seriya khimicheskaya, no. 8, 1964,
@1515-1518
TOPIC TAGS* trichloregerman
e,
.---I-,-2--b-id-(~~i-Cblorogermyl)et:hylent- _77
ABSTRACT: A,study,of-the 'reaction' '-Of tricblorogermane vith-ac6tyiene
showed that different products are obtained, depending on reaction-
:Conditions:, 1) the bubbling of acetylene through trichlorogermane
yields the addition product 192-bis(trichlorogermyl)ethane; 2) the
.-addition of trichlorogermene to acetylene-vaturated bexane yields
trichlorovinylgermanetin, addition to 1,2-bis(trichlorogermyl).ethane;
3) the &ddition of.tri'@chlorogermane to acetylene-saturated ethyl ether
yields the polymer
C
eeCH CH x
Card 112

Z
1, 11w) 62@65
ACCESSION UR: AFh()447o6
t4) the bubbling of acetylene through trichlogermane etherate yields,
@in addition to this-podymer, 1.2-bis(trichlorogermyl)ethylene. The
reaction of 1,2-b,is(trichlorogermyl)ethylene with methylmagnesium
chloride yields 1,2-bils(trimethylgetmyl)ethylene and the polymer
CH
VCH cH
x
CH
3
@The structure.of the synthesized compounds vas studied by recording
Raman, !R, UV, and NMR spectra and measuring dipole moments. Orig.
art. has: 4 figures.
ASSOCIATION: Institut@organicheskoy khimii 1M. N. D. Zelinskogo
wAkademii nauk SSSR (Inntitute'of Organic Chemistry, AN SSBR)
--SUBMITTFD---a3zi-n-6V ENCL- 00
-SUB-CODE: GC -170 REP 501; 010 OTHER: 000
Card 2/2

MITRONOV@ V.F.; GAR, T.K.
Interaction of trichlorogermane with acetylene and its
derivatives. Izv. AN SSSR. Ser. khim. no.8sl5l5-1518
Ag 164. (MIRA 170)
1. Institut organicheskoy khimii im. N.D. Zelinskogo AN SSSR.

1w
001
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t 19A-65 Fm WAPF ('!..)/FWP W/T Pe-4/Pr-4 AS (mp) _2/AFVL/RAEM (a)/F.SD @gs)/
WD(t)
s/oow /64A58/002/OhOO/OhO3
ACCESSION M-05003148@
T.
AUTHORi Lgtes, L. A*; Oar K i; Mironov, V, F,
io'*1 in the spectra of betfi-alkenylgermanea
TITLE: Appe Prance of signa, pi-tonjugat n ------
as a function of steric factors
SOURCEt AN SSSR. Doklady, v, 1581 no, 2, 196h, 400403
MPIG TAGSf Raman spectrum, germanium compound, pi bonded orgAnom tallic compound..
-,;conjugage bond system, bets spectroscopy
Abstract: *The line lnt!'!nsity in the Raman spectrum of various alkenyl-
germanes'with the Ge atom in.the beta-position with respect to the C=C bond
was studied. Of five such compounds synthesized, three were by a new
condensation reaction.d.Lecovered by the authors: RCI + IlGeCl ether
R-GeC13 + Hcl. It.was :also demonstrated that the addition ol HGeC13 to
cyclopentadiene results@in the formation of a compound with um in the
germani
bet4-poaition to the double bond. The frequencies and line intensities
corresponding to C=C vibration in the Raman spectra.of alkenyl-germanes
indicated that the "beta effect" is not specific for compounds of Si, Ge,
Sn,.but in a particular case of the special properties of allyl and benzyl
systems, i.e., the very'high reactivity of these systems in ionic addition
reactions, their stability in radical-reactions, and the.ability-of allyl
Card 112

L 19604-65
ACCESSION NR: AP5003148
hydrogen to be exchanged-readily for deuteriuw,.explained by sigma-pi
An ana
conjugation of the 1-2 and 374 bonds in the ayitea G=C-C-M. IySiG Of
the Raman spectra of the planar rings of two of the compounds synthesized
indicated tha. the "beta effect" is a particular-case of sigma-pi conjugation
according to Neemeyanovi It was also' found that the induction effect
(replacement of thleelectropositive group (CH3) 2Ge 4 by the electronegative
C12Ge exerts essentially. no influence on ICIMC. Orig, art, -5 formula a.
2 graplis: ard'I tables"
ASSOCUTIONt Institut organichesk9y khimii im. N. D. 'Zelinskogo kkaderdi nauk
SSSR (Institute of Organic Chemist!:j, Aqademy of Sciences, SSS
SUBMIWEDs 08Apr6h ENGLt 00 SUB CODEt OCJ0 OP
NO REF S@Vt 016 OTHER-. 000 JPRS
Card 212,

L 3ffz23=6q ER(M)/EfIF(c-)/kWF(j).'
ACCESSION MR: AP50081%1 SIW,62/6S/000/002/0291/0300
AVrMR.- Mironov, V. F.: Gar,-T. Ko
TITIZ.: Reactions of trichlorog'er'o'anakwith alkyl, alkenyl, and al'
SOURCE AN SSSR. lzvostiya. Sertya,khtmicheskaya, no. 2, 1965, 291-300
TOPICTAGS: hitercorg~mic.compoutid,,o,rganogermanium compound, trichlorogermanel,
alkytIalide, alkenyl hatide,'alkynyl halide, alkylgermane synthesisVinfrarid
spectilvm-
ABSTROLM The condenaii-tion "of. trichloragerviane (HGeCl3) with allyl halides, con.
sisting of the substitiltion of the trichlorogermyl group for the halo
gen.,may
be exl:ended to saturated tertiary halides.: Secondary and normal alkyl,haltdes.do-
not ei:tter into this reaction, its vas ehown.by experiments using a- Iand see-butyl,
chloride. Propargy! chloride andIromide also condense with trichlorogermades
but this reaction to associated with an addition reaction. The preparation of 7-7.
the following compounCe is described-, t-butyltrichloregarmane, t-butyltrimethyl-
germane, triphenyloethyl hlorogermano,od-butenyttrtchloragermane,Pf-butenyitrL-
C
methylgermane, Y-chlorobuty1chlorogernaneg and r-chlorobutyltrimethylgermane, and
F@Ild 1/2

7
L 51863-65-- --]@I@T(my/E-P@(WEWp(J_W- PC-4/Pr-4 C-SIPJA
- 1.1 . V
ACCESSION WR.i AT500212.1;
AUMORIO: Hiron Iovo V*' F.1@- DxhuringkA.yag AtLq j ;'.aar, K.
TITLE,., Anew,reactioh'for synthesizing otlanogermanium compounds
SOURCE: AN SSS -R. Instl.tut neftekhimicheskogo sinteza. Sintez i avoystva mouomerov!
(The synthesisand properties of monomars)o Moiicow, Izd-vo Nauka, 1964" 150-152
TOPIC'TAGS:.. organoger~'ianiuml.brotpAde,-alkyltrichlorogermanium, alkanyl trichloro-
germanium,,trichlor-agei.-manium addition
i ABSTRACT: Following Ali extensive rw4iew of previously published research, the
authors report a new condensation reaction of HGeC13 with the halo-derivativea of 1
hydrocarbons, with-good yield's of alkenyl- or alkyltrichlorogermaniums. 'This
pattern of.Ge-C bond formation is entirely unique, since the hydrides of Si, Sn
and otbPr metals form;Iydrocarbons,(i.e., reduction) under similar conditions.
HGeC13 can be added tc:) any -unsaturated compound at room temperature and without i-
benefit of catalystsei Treatment of organogermanium chloridee with gaseous hydro-
gen bromide provilded itigh yields of the corresponding orga des.
nogetmanium brcmi
Orig.-art. has: 11 fOrmulas.
LCcrd,,,.

'P
PC 1JP(
iCCESSIO' X N11:, 'AP5012458 UR/0062/65/000/004/0755/0758'
661-718.6
AUTHCRSz Mironov,-V.-P. Gart T. K.
i ibromide.--)
TITLE: Synthesis and ponvorsion of german um. tr
SOURCE: Ali SSSR. IzveDtiya..Seriya kbimicheakayat no.*4# 1965, 755-758
TOPIC TAGS: germaniuil bromide, organic.synthesis, unsaturated hydrocarbon, organo
metallic compound
ABSTRACT. When HBr is.passed over metallic Ge, both tetrabromide and tribromide
form, but only little of the latter. rt has been demonstrated that the addition'.of
powdered Cu to Ge som6what improves the yield or the tribromide, butatill the yieU
is no more than -30%, With other the tribromide (UGeBr ) forms butyrous etherate..
3
whichis insoluble inlexcoqu ether. This permits the HGoBr to be separated from
3
GoB since the lattexis readily soluble in other and only partially in the
r4
atharate. It is somewhat more oonvenient-to produce HGeBr by dissolving Ge(CH), in
HDr. The hydroxide mity be prepared (free of GoO by 1Wdrolysia of the trichloride
Card 1/2

L 57075-65
ICCESSION M AF5012450
,etherate. This procedtr,-e 'requires great,quantities of ether. -if HI is used instead
@of HBr, GrI is produceilt and this appears to bo one of the better methods of
2
or GoI21 how-
robtaining this,compound'. The best method or producing either HGeBr3
:ever, is by an exchange' reaction, replacement of C1 by Br or I, during passagelof
BBr or HI through the-triohloridf! or its ethgrato. Distillation of an etheral
solution of HGeBr containing HBr, and even mt)re of HGeBr dissolved in HBr acid,
3 3
.yields yellow c
rystalslof GeBr crystals, which react energetically with allyl
!bromide and butadiene tlo,form allyl germanium bromoform and Ge-1,1-dibromo germanium'
'eyolopentane-3- GeBr !is not obtained by distillation of anhydrous HGeBr Like
3'
:HGeCI RGeEr ombinea@ with unsaturated compounds in an exothermic roaotion without-
31 3
.:catalyst. With acetyline t fo 'lie unsaturated compounds chiefly; with ether it
forms only uneat-lar-a-re-M-mbi4ounds. Orig. art. has: 8 formulas.
ASSOCLUIONt Instituti,organichookoy.khimii im. Nd D. Zolinakogo, Akadeaii nauk.oSSSR.
:(Insti-tute of Organia Oiamistry, Academy of Soiences,SSSR)
:SUBMITTED: 17jul64 ENCL t .00 SU3 CODE3, 'Oct 0c'- -
-F SOT 004
0 RE OTHM 002
N
Card. 2/2
J

L 27783=0 RX.-
ACCESSION NR: AP6016569 UR/0062/65/000/005/0855/0862
.2
Mironov, V. F.
AUTHOR; T. K.;
TITLE: -Synthesis and traitsformations of tribromogermane
jSOURCE: AN SSSR. Izves!dya. Seriya khimicheakaya, no. 5, 1965, 855-862
TOPIC TAGS: germanium compound,- organogermanium compound, germaniumhalide
ABSTRAM, Thefollowl*; reactions were carries out- tribromogermane with allyl bromfde@
to produce CHVCHCH20613%; german1w dibromide with allyl bromide, -to produce
CH2=CHCH2GeBr3; tribroinogermane with cyclohexene, to give cyclohe@ltrlbromogermane
C6H,,GeBr3; tribromogermane with allyl eMoride, to give CICH2CH2CH2GeBr3; tribromol
Cff-CH2,
germane with butadiene, 0 yield CH3CH=CHCH2Ge(CH3)3 and C Ge(CH3)2;
CH- H2
CH-CH2% CH-CH2%
dibromide with butadiene,:: to yield GeBrZ, and after methylation, U 'Ge
CH-CH
2 CH-CH2
(CHS)2; tribromogermane'witb acetylene, to form Br3GeCH=CHGeBr3, and after
clkro: 1/2

L 5778345
ACCESSION NR: AP50156139
methylation, (CH,3).3GeCH=CHGe(CH )3 and (CH3)3GeCH2CH2Ge(CH3)3-, and tribrovio-
germane with ethylene, to from Br3GeCh2Ch2GeBr3. All the procedures employed are
,described in detail. 'Ve i
:Lxpress our, appreciation to P.V. Petrovskiy and LA. Leytes
for recording and interpreting the NMR,, Raman, and M spectra. Orig. art. has. 4
ffgures, and 22 formulas.
ASSOCUTION: InsUtut ofganicheskoy khimii Im. N. D. Z elinskogo AkademU nauk SM
(Intitate of Organlo'.Choodstrys Academy of Sciences, SSSR)
SUBMITTED: O$Sep64 ENCL: 00 SUB CODE: OC

L 31882-66, - .EWT(m)/!@4PCJ_1/T_.__1JP(c) RM
ACC-RT,
MM2531 SOURCE CODE: UR/0062/66/000/003/0482/04-
AUTHOR: Hironov, V. F.,,Gar T. K.
) 7!
V,
ORG: Institute of Organic Chemistry im. N. D. Zelinskogo, A ademy of Sciences_SSSR
@(Institut organichesk
oy khimii Akademii nauk SSSR)
rogermane) with 4;onj ed(I
TITLE: Reaction of trichlo _@S@t dienes
;SOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 3, 1966, 482-489
TOPIC TAGS: organic synthesis, germanium compound, cyclic compound, diene synthesis
:ABSTRACT: While HGeC13 is added exothermally to practically any unsaturated compounds
,along unsaturated bonds in the absence of any catalysts or activators, HSiC13 adds to
ithese compounds only in the presence of catalysts (Pt, H2PtC16) or radical activators,
:frequently also requires elevated temperatures and pressures. It was unexpectedly
ifound that the reaction of butadiene with trichlorogermane leads to formation of a
inarrow fraction which, on the basis of elemental, chromatographic and spectral analy-
sis ,consisted of a mixture of two compounds, one of which present in a predominant
amount contained two atoms of chlorine. After methylation of this mixture gas-liquid
;chromatography still showed the presence of two compounds. The compounds are unsatu-
;rated five-membered rings with GeClZ group in the ring. The formation of the compounds
!results from 1-4 addition of germanium dichloride to diene. On the basis of spectral
UDCz 542.91+661.710.6
1/2

L 31882-66
ACC NR: AP66i-2@-31
data, structure of the two compounds has Peen elucidated. Isoprene also reacts with
@GeC13 producing a heterocyclic compound.'IUnder the same conditions Dropylene produces
jonly linear addition products. The following equilibrium is proposed for trichloro-
germane: IICI + C-02
ICC13 W [GoCI31
The addition Of GeC12 leads to a stable compound only in the case of butadiene,lisince
ifor other unsaturated compounds the unstable three member rings are eir-t Ter polymerized
:as soon as they are formed or they are split by 11C1 which is always present in excess.
I
'On the th retical basis, formation of stable three member rings was predicted only fo
.acetylene7ompounds, but they were not found experimentally when HGeC13 was reacted
iwith acetylene. Orig. art. has: 6 figures.
SUB CODE: 07/ SUBM DATE: OlNov63/ ORIG REF: 019/ OTH REF: 002
Card 2/2

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