SCIENTIFIC ABSTRACT A.YA. FREYDLIN - L.KH. FREYDLIN

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000413620020-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 13, 2000
• Sequence Number: 20
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

MYDLIN, A.Ya., kandidat takhnicheakikh nauk.
Technological productivity of stamping automobile bodies. Avt.i
trakt.prom. no.4:34-39 Ap '57. (M.LRA 10:5)
l.Gorikovskiy avtozavod imeni Molotova.
(Automobileo--Bodies)
(Sheet-metal work)

FREYDLIH, Abram 46u"h j, kand.tokim.nnuk; SVBJWLOV, H.I., kand.
79xM.naujc, red.; XUBNEVA, M#M., tokhn.red.
[Cold forging techniques: stenographic record of a report]
Tekhnika kholodnoi shtompovki. Stenogramma doklada. Lenin-
grad, Leningr.dom nauchno-tekhn.propegandy, 1958. 47 P.
(Knu 12:9)
(Metals--Cold working) (Sheet-metal work)

I.I.; BORISOV, R.I.; YASINOVSKIT, B.S., inzh.; SANNIKOV, Tu.K.. inch.;
SOKOIDV, V.A., inch.; LETCEWO, L.D., inch.; NALOYEV, G.A.. inch.;
CHICHAKOV. K.K., inzh.; BARYKIN, V.I., iuzh.; J~Il,~A.Ta., iuzh.
- SH insh.;
GULTAYEV, A.I., inzh.; STIGNEYEV, TA.F., inch., AGANOTA,
EMIMSKIY, I,Te., itch.; AVROV, A.N., insh.: DIMIDOVA, R.L. inch.;
NIKIYOROVA, Ye.D.. lnzh.; KLIBAHOVA, T.I., inch.; CHIVKUNOV. X.I..
inzh.; STOROZHKO. I.G.. insh.; NOVAKOVSKIT, Te.Ta., inzh.; GOYK=',
A.O.. inch.; TARASOV, A.M., insho; SHISHKO, A.P., inzh.; UVAROV,
P.T., ekonamist; DRAGUNOV, M.V., skonomist; KARANDASHOT, ~.A.,
ekonomist; KONKIN, H.V., ekom:omist; GOREV, K.S., okonomist. Pri-
nimali uchastiye: LAPIN, T.I.; RAMSKIT, Tu.A.; KADINSEIT, B.A.;
SOKOLOV, S.D.; STOROZHKO, I.G.j FOMINMI A.I.. POLTAKOVA. N.,
red.; SUIPSOV, G., tekha.red.
[Organization and improvement of production; practices of the
Gorkiy Automobile Plant] Organizataiia i sovershenstvovanis
proizvodstva; opyt Gorikovskogo avtozavoda. Moskva, Goo. izd-va
Polit. lit-rY, 1958. 332 P. (MIRA 12:2)
1. Direktor Gor1kovskogo Avtomobillnogo zavoda (for Xiselev).
2. Glavnyy inshener Gor1kovokogo avtomobilluago savoda (for Borisov).
3. Gor1kovskiy sytomobilln" zavod (for all except Kiselev, Borisov,
Polyakova, Smirnov).
(Gorkiy--Antomobile industry)

25(l) PHASE I BOOK EXPLOITATION SOV/3123
Freydlin., Abram Yakovlevich, Candidate of Technical Sciences
Tekhnika kholodnoy shtampovki; stenogramma dbklada (Technique of-
Cold Stamping; Transcription of a Report) 'Leningrad, 1958.
48 p. 6,20C copies printed.
Sponsoring Agencies: Obshchestvo po rasprostraneniyu politicheskikh
i nauchnykh znanly RSFSR, Leningradskly dom nauchno-tekhnicheakoy
propagandy; and Nauchno-tekhnicheskoye obshche8tvo priborostroiteltM
promyshlennosti. Sektsiya kuznetsov i shtampovshchikov.
Ed.: M. I. Sverdlov, Candidate of Technical Sciences Tech. Ed.:
M. M. Kubneva.
PURPOSE: The book is intended for foremen and skilled workers In
c0ld-stamping departments.
COVERAGE: This booklet deals with the development of'cold-Btamping
equipment in recent years and problemp connected with the design
Card 1/3
~_2_j

Technique of Cold Stamping (Cont.) SOV/3123
of dies and cold-stamping o-perations. The author describes
t-ypes, designs,~nd op ration of cold-stamping orocesses. No
personalities are mentioned. There are 39 references: 19
Soviet, !4 English, 5 berman, an~ I French.
TABLE OF CONTENTS:
Ch. I. Presses for Cold Stamping 3
Gap-frame presses 3
Two-column high-speed presses and large presses 7
Double-and triple-action presses 11
Embossing machines 12
Hydraulic presses 12
Multiple-operation automatic presses 13
Transfer machines 16
Universal and specialized equipment 17
Clutches for modern presses 18
Mechanization and automation of press operation 19
Individual Improvements in presses 23
Card 2/3

Technique of Cold Stamping (Cont
Ch. II. Cold-stamping Processes
.: Economical layout of material
Ch. III. Dies
Bibliography
AVAILABLE:
Card 3/3
Library of Congress
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A.

V~ ;;7
New Features (Cont.)
0011,0294
Konovalova, I.I. [Engineer, Zavod "Metalloizdeliye; Leningrad
(Leningrad Metal Products Plant)]. Transfer Machines for
Making Safety-razor Blades 206
Fabricating processes and machinery for automatic lines
are described, and information on tool life, heat treat-
ment, grinding, and packing of blades is given.
Lanskoy, Ye.N. (Candidate of Technical Sciences, Docent,
Moscow Machine Tool and Instrument Institute]. Selection
of a Crank Press for Required Force and Work Parameters 217
The author discusses flywheel effect, the meaning of
nominal force (capacity), the magnitude of force at
various angles of the crank, the work delivered by motor
and flywheel,' and the work of deformation. Recommendations
for selecting the proper press for a given stamping
operation are presented.
AVAILABLE: Library of Congress
Card 9/9
GO/ajr
10-21-59

GUUV, H.S.; GUSIV, V.M., kandidat takhnicheakikh nauk, redaktor;
XAPLLN, M.Ya., redaktor; YRIMIN, G.I., Inshener; MIZINA, Te.A.,
tekhaicheekly redaktor.
(Installation of sanitation equipment in residential and civic
construction] Opyt montasha sanitarno-takhnichaskikh ustroisty
v shilishohnom i grathdanskon stroltelletva. Leningrad, Goa. Lzd-
vo lit-ry po stroitelistru I arkhitekture. 1953. 32 p. (MLRL 7:8)
I* Brigadir santakhatkoy Leningradskogo treata. Santakhmontath.
(for Gusev, H.S.)
(Plumbing)

GONCHAROV, F.S., kand.takhn.nauk-, FBZDLIN, G.I., inzh.; SLA.DKOMOOV, II.I.,
inzb.
Asbeatoo-coment sawage stand pipos for inductrinl buildingli
and apartment bouaeo. Nov.tekh.mont.i spots.rab.v stroi. 21
no.9:21-22 S 159. (MIRA 12:11)
1. VoesoyuzWy nauchno-iReledovatellskiy institut gidrotekhni-
cbeskikh i saniturno-telthnicheskikh rabot (for Sladkomed.Dv).
m (pipe , Asbestos-cement)

ALIKSE M , Yo.K., inzh.; IZOUR, R.N., inzh.; LYUXE, Te.P., inzh.; NIXO-
LAYUSKIY, Ys.Ta.. inzh.; PIROGOV, A.H., inzh.; RODIONOYA, R.G.,
inzh.; TOYBIN, V.A. q inzh.; YRNELIK, - G.M. , insh.; UffiTUPIKAO
A.K., inzh,; CHWOT, D.L., inzh.; SYMONAET, L.B., inzh.; 2HM.
H.S., inzh., reteenzent; MOLTUXOT, G.A., inzh., red.; TIKHMV.
A,Ta.9 tekhn.red,
tProduction and installation of -pipe systems; reference manual)
Izgotovlenie i montazh tekhaologicheakikh traboprovodov; spra-
vochnoe posobie. Moskva, Gos.nauchno-takhn.izd-vo mashinostroit.
lit-ry, 1960. 574 p. (MIRA 13:7)
(pipe fitting)

MOSEYEVA Z.K. - FRODLIN G.N.
Chemical.removal of formic acid from-Acetic acid-with potassium
permaagenate and bichromate. Ihim.prom. no-51.306-307 J1-Ag '56.
1. Yerevanskiy zavod "Polivinilateetat.0
(Acetic acid) (Formic acid) (fttinifta salts)
.

IOSEV, I.P.; FEDOTOVA. O.Ya.; FRETDLIN, G.N.
Alcoholysis of polylvinyl acetate in presence of polyacids as
catal7sts. Report No. 1: Stud7 of the rate of reaction. Izv. AN
Arm. SSR ser. khIm. nauk 10 no.6:403-410 '57. (MIRA 11:6)
1.Yerevanski7 zavod "Polivinilatestat.0
(Alcohol.velfie) (Acetic aoid) (Chemical reaction, Rate of)

FREYDLIV, G. V., Cand Tech Sci - (diss) 'Alcoholysis of polyvinyl
lw"410-
acetate in the presence of a emzt" of cation-exchange resins and
sulfo--acids.0 Moe# 1958. 12 pp (Min of Higher Education USSRP
Moe Order of.Lenin Chem-Technol Inst im D. I. Mendeleyev), 100
copies (KL, 15-58, n6)
_ 51-

WSEV, I.P.; FEDOTOVA. O.Ya.; YREYDLIN, G.N.
Preparation,of polrdn3rl alcohol by the alcoholyals of polyvinjrl
acetate in the presence of polyacids as catalysts. Report no.2:
"Idfe span" of catalysts and feasibility of their regeneration.
rzv. AN Arms SSR khim. nauk 11 no.1:31-36 '58. (mrRA 11:6)
l.Yerevanakiy zavod "Polivinilateetat."
(Acetic acid) (Aldoholysim) (Catalvois)

FREOUN', G;N.; MHODAROVA, S.M.; CHUXURO A.P.; FOMINA, N.V.
Vinyl monomers based on dicarboxflic acids. Part It Mongesters
of adiplo' and succinio acids. Zhur.ob.khim. 32 no.3092-794
Mr 162, (MIRA 1513)
(Adipic acid) (Succinic acid)

S/079/62/032/003/003/007
D204/D302
AUTHIUS: 4regillin--G. .1 Zlienodarova, S.M., Foi,iina, N.V. and Chukur,
it. P.
T I ME: Vinyl mononers based on dicarboxylic acids. 11. Vinyl
alkyl eaters of succinic and adipic acids
P'2'iJODICjiL: Zhurnal obshchcy Idiinii, v. 32, no. 3, 1962, 795-798
r.~x r: Preparation and properties of the above esters vvas ,;tudied owing
to the possibility of producing from them internally pla.-iticized polymerj.
Direct vinylation of monoesters in the liquid phase and the I'vinyl ex-
change" methods were tried. Normal butyl, amyl, hexyl, octyl and nonyl
vinyl adipates wer(i synthesised by the catalytic reaction with acetylene
in an autoclave, at 160-180 0C and 20 atri, over Gd acetate, inhibiting poly-
filerizatiort with hydroquitione. Optimum conditions for this reaction shall
be determined in future work. Succinic monoesters were found to be too
unstable to be treated in this manner. Vinyl n-11 esters (H=methyl to do-
cyl inclusive) of succinic and adipic acids were prepared, in 30-70 and
Card 1/2

zi/079/62/032/003/003/007
Vinyl monomers based on D204/0302
30-97% yields respectively, by the action of vinyl acetate on the corre.5-
ponding monoester at either 200C for 5-7 days or 30-40 0C for 30 hrs.
0
Using IIg acetate/conc. II,)SO, as a catalyst and hydroquinone as zui inlkibi-
tor. The yields were reduced at higher temperatures. Lxpcrimental de-
tails are given and physico-chomical properties of the products are tabu-
lated. There are 21 tables and 12 references: 6 Sovict-bloc and 6 non-
Soviet-bloc. The 4 most recent references to the -Inglish-lanGruage pub-
lications read as follows: US Pat. 2,472,434,(1949);US Pat.2,153,987,
(1959); Port in the collection "Industrial Fatty Acids and their
Applications", N.Y.(1959); R. Adelman, J.Org. Chen., 14,1057 (1949).
SUBMITT ED: January 30, 1961
Card 2/2

S/030/62/035/005/0',5/01=*
D247/D307
2'.- i OR S -_2 r e,&jjn,-~. and Davydov, V. N.
Separation of phthalic acid by esteri.-Cioation without
a catalyst
-'-~-'RIODICAL: Zhurna-1 prikladnoy khimii, v. 35, no. 5, 1962,
1150-1153
,-.I-'XT: The authors aimed at devel
(Ijoping a TrIethod of separating iso-
(1) a,,-,1d terephthalic ) acld3, based on selectiveoeste-
fica-uion with ',IeOH under pressure, to Obtain I! from a mixture
c.: -and 1)-xylenes rather than from the expensive pure ,)-xylene.
"-*-.e -elative rates o-P esterification var4ed witi, temper -
~.: - d. . U ature,
'-ieOH:z~.c-id ratio (n) and time. Thus the rate of esterification of I,
sit 170 _ 1800" and 100 - 200 atm, Js 7 ~- 10 tir-es greLater than that
of --I; ra-Asing- (n) increased the rate of reaction of IT at JSOOC
(over 1 hr) but riot of I. Presence of water retarded both processes
,,o same extent. The optimum time was 40 - 80 min. The content
-of I! could be raised from 25 - 60~- to 87 - 96% by esterification
lard 1/2

FREYRLIIL,-"; DAVYDOV, V.N.
Separation of terephthalic and isophthalic acida by extraction with
hot methanol. Zhur.priklAhIms 35 no,n:2520-2526 N 162. (MMA 15:12)
(Terephyhalic acid) (Isophthalic acid) (MOM=01)

FREYDLINq G.N.;__.LITOVGHEIIKO, N,N.
Imparting water repellent properties to polyvinyl alcohol with
beta-naphthalonewilfonle ricid. Kbim.volok. no.2:15-18 163.
(14IRA 16. 5)
1. Lisichanskiy filial Gosudarstvennogo nauchno-issledovatellskogo
i proyaktnogo instituta azotnoy promyshlennosti i produktov
organicheskogo sinteza.
(Vinyl alcohol polymers)
(Naphthalene sulfonic acid)

L 17480-63 r-W(j)/M-T(m)/f0S AISID M.,4 RM
-J CC tz_- !:~~bd4_766_ _S/6 183/6 3/bOO/604/002 4/002 6.-
i A= 11 OM i 7re_ydljn, G. Ns Lttovchenko, N. N.1 Ophovskaya.-G. D
TITLBi Chemical processes occuring in waterproofing with polyvinyl alcohol f
Bota-naphthalene culfonic acid
SOURCE: Xhimicheskiye voloknap no# 4P 1963, 24-26
TOPIC TAGSt polyvinyl alcohol, naphthalene, sulfonic acid, waterproofing.
ABSTRAM Authors investigated the mechanism"of the waterproofing method worked
out by Freyd1in and Litovohenko (Rhims voloknat no* 2, 1963, 15)- It was estab-
lished that the waterproofing is effect d b the formation of B-naphthalene sul-
fonic acid esters of polyvinyl alcoholy(FVA~- Chemical and X-ray studies indic-
ated that the given method does not en so disceinible changes in the c. stal-
ry
linety of the polyvinyl alcohol: "In conclusion we ex-aress thanks to V. A.
NaMT~, and V. A. Xach&Upv (tiQlchanehy filial-GIAP) for help and participatTon
in carrying out X-ray analysis and radiometric measurements". Orig. art* hasj'
I equation$ I table and 1 figure.
FOR
AS.",N.- LISIMM415K EWICH) S'EATE DESIGN A~;D PLA~!'!ING sm. RS13. INST.
NUMCUT I11,1DUSTIff.
!Card

L 1494a-63 W(J)/EPF(c)/EWr(rm)/BDS AM Pc-4/Pr-4 RMIWd
ACCESSIGI NRt A?300370,0 S/0190/63/005AM/1009/1011
AUTHORSvi Frgdlln, 0. N.; Menodarova.- S. M.; romiray ff. Ve; Chukur, A. P.
TITLEt Poly~merization ~f vinylalkyl enters of dicarbo 0 acids
SOTIRCEt Vv*so1,omolek:u2yarr,7*yc, soyedineniya, v. 5p no. 7, 1963, 1008-1011
TOPIC VGSt polymerization, vinylalkyl ester I dicarboxylic acid , benzoyl.
peroxide
ABSTRAM The polymerization process of vinylalk7l eaters'of succinic, glutaric,
and adipic acids was studied. Experiments were conducted in sealed ampules
containing 4T gra of the monotter and 0.1 gm of dissolved benzoyl peroxide in an
ntTospbere of either nitrogen or qr. The ampules were placed in a water bath at
temperatures ranging from 65 to 120C, and the progress of the polynerizatiori '
followed by*broDdne number determination. It ran found that the rate of polymer-
Ization incrensed vith the temperature, thek yield of the viny1mathylsuccinate poly-
mer at 100C being, rore thnn ton times tho yiele at 80C. In a vacuum the polymer-
ization proceeded at a higher rate and at laver temperptures, wbile the presence of
oxygen delsyv~ it. It was also recorded that the e'sters of adiric acid polymerize
SOMMIhat faster an corpared with the esters of succinic and glutaric acid. 8ut it
Card .1/2

L 14948-63
'ACCESSIal TIRs AP3003790
was-also found that the induction period of Telymer forration increases from
viryl.metbylsuccinate to viny1hexylauccitate and prectial3y ceases with the vinyl-
hyptyleuccinate ester. Orig. art. has: 1 chrxt and 4 tables.
A.133SOCTAITCN: lAsichanskiy fil:19,1,gosudarstvernogo nnuebno-issledovatellskogo i
proyektnogo Instituta azotroy prony*shlennostj i r-roductov organicheakogo ainteza
(Lisichnn Branch of tho State Scientific Resee-rch Pnd Production Institute of the
Kifr-67g-en Industry and s)
rroduef's-oT Organic
SUBY-IT-TED: 18Dec6l DATE ACQ: 08Aug~3
SUB COM CH NOW SOVI 004
Card 2/2

63/033/003/005/005
S/07
A066YA126
'AUTHORS% Freyalin# G.N., Zhenodarova, S.M., Chukurp A.P.0 Fominal N,V..
~.TITLEs Vinyl monomers on the basis of dicarboxylic acids. 111. vinyl
alkyl esters of glutario acid. Vinyl cyclohoxyl.and vinyl
benzy], eaters of sucoiniop and adipic acid
;~PERIODIGALs Zhurnal obehohey khimii, v- 33# no- 3, 19631 934 - 938
;TEXTi The authors describe the synthesis of vinyl alkyl eaters of
-1 to decyl alcohol#~
glutaric9acid and of normal aliphatic alcohols from methy
as well as the synthesis of vinyl cyclohex~l and vinyl benzyl eaters of sue-,
cinic, and adipic acid. The purpose of the present work waa to study the
influence exerted by the structure of the substituent in the side chain on
~the properties of-the polymer. The vinyl esters were synthesized as follows$,
acid was transformed into a monoester by partial esterification;
'with suitable 'alcohols. The monaester was subjected to a "vinyl exchange"
reaction with the participation of vinyl acetate. The monoalkyl glutarates
~were found to be very stable, colorless liquids which are able to withstand
vacuum distillation. Furthermore, they boil in vacuo at high temperatures$
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S/079 63/033/003/005/005
:,Vinyl monomers on the basis of too A0613YA126
.-Mo monooyolohexyl and monobenzyl eaters of sucoiniat glutarior and adipio
ac id boil at high tomper6tures and decompose during aistillation, There
axe 4 tables*.
ASSOCIATION!, Lisichanskiy filial Gosudarstvonnogo instituta azotnoy prom
ahlennosti i produltov organiohoskogo sintoza (Lisichansk
Branch of the State Institute for the Nitrogen Industry and fw
Products of Organic Synthesis)
SUBMITTEDt February 27, 1962
Card 2/2

1."." wqF.TDI,-IrI) GON,
f
I
1y' or methyL on ca--,- . - , .
1~14 ~ . I ~ t-, , , ~,. ~~, Z, t! : .,
Miur. pri.el. jhJm, 37,
,~~ .-,.1 11 16'.

MYDI,INI G.N.j SOLOP, M.A.
XinOt1cs of the polymerization of vinyl aster of H,,11-diisobutylgIfItaramide.
Vysokcm. sood. 7 no.6tIO60-1064 Je 165. (MIRA 1819) ..
1. Filial Ocaudarstvannogo instituta. acotnoy promyshlormsti, i ~ -- , ,~ , ;. iI!P7-
Severodonetak,

GOLIDENSHTEYN, 1,.M.j FILUDI.Im, G.N.
Hydrolysis of dientorm of dicarboxylio golds on the KU-2 cation
exahanger. Zhur.priklakbim, 38 no,6aI345-1348 Is 165. (WRA 3.8s 10)

FRUDLIN) G.N.; A.DAMOV`j A.A.; ZAYTBEV$ P*M.
Vinyl monomers on a base of dicarboxylic acids. Part 6s
Direct vinylation of the monoester3 of dicarboxylic acids
with acetylene. Zhur. org..khim. 1 no.4:666-670 Ap 165.
(MIRA 181ll)

r,.N., CHUMIR, A.P.; IMAROKBOXHOVA, L.I.
Vinyl monomers based on dicarboxylic acids. Part 7: Vinyl
alkyl esters of aselaic and asbacic acids. Zhur. orp. kh1m.
I no.8:1367-130 Ag 465. (MIRA 18,11)

GOWDEM'IrMflp L.M.S FWDLIN 0.11.
AWdro2imis of dUators of dicarbm.721c noide an Im
axchuVaou ftwoprM.I&im. 38 no*U&2538-2540 9 965.
Wro2rule of diontere of carbomy3lo acids on the
KU6-2 oatlcm oxcbwWw wxUr 4Mwdo oondiUow.
IWAS 1254w5" (Hipi 18322)
1. Butmitted r4vember 14, 1963.

60 AT("),
04036- 114~lp
Oft. e
e ~d,
0
84ni Ver ,n_
c 0.1) _ Act, SOURc~e-
zotno S nth Onetaki amolv, CIDDE
~- e
Pro Star P Y .8ra A. A.; P (JR/O
MJVB 6 Odu' 11
~8 enno'O~fjc - ~V-A ereh
'2'ze. to St4t
Zo t (S -,--,,e 000165100010
ot
rea * t1i e "kov
Ctton nyl etler A 00100,771
of ,Ono,, Produkto net StItut ( -
SOjj'R V111y, ere 6 v skly f, ? Of th
ko,go CZ" eirch 46ed orgaill 1141 e N,t
ej,`nt-4~ SS 4`18e on cheek ro
080 sudar t en
ez, SIR - Otd tc rbo Stntez 17dust
2'OPxC Ic Ven
(PrObi' , --- Plen, 4 0 in, t and
o-ynth ZACS. Qma -in-Ye ~bahch 4cld&.
et (c a ltut'o
PrOce& Ph4tj c 'Part 5
a c dtc4r SttCf
he
y of the
c?pPerea
, ctj the )CS-C-Ov-oy -11htmt
tin r on 4ctd 3 i
chlo Of 'aynthest, J. ea -tid%v 4- Pr)bl
a ca C4 rid vinyl terj J)2ercu 0
e
e-vch Oif 'V4ukj, fty organ
Qctto a t e4d 24dttt. 44ge '"llyl
ret, I pal %th 650 ches.
tire& Ver YJ-dt ry coj~pound, 4c19 40
12 ti~ert I and Chlo e tested.
Ide
10,48 copper , Pate etate
shoj and 0 boron't, 4cet., the 'foll
rte press A64e rtf,, e& of 0
Oed roe. Of these Oride ovjaj~ r8441
(equirt, Copper C,
libri 4%ell Oub fth
Stan Z 0 zinc.
4ib zler'UrV ces er4te
L to O'f
Cat J'
c4
reached t4ncetmte 413'zed tht ftes
V48
ftojoy 8 rea
than 24 .. ed etton
the
he

L 158go-M
ACC NR: AT6004036
reaction rate was accelerated by a rising toWerature, high yields of*Vi!%Yl *a tore
(vinyl stearate, benzoate, oleato, butyrate, methyladipate) were obtained, and no
by-products or tars were formed. The'vinyl exchange reaction can also be used to
Isynthesize high-boLling vinyl eaters. Orig. art. Me: I figure and I table.
ISUB CODEt 07 SUSK DATH't 24Dec63 ORIG REPt 002 / ON REP: 003

.0 0 * 0 ** 0 0000 004
000*000*0000004:
ti 13 W

00 J1
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oo
0404 ho inform. Digost (American Edition), Y:- 4.
M7. p. 444. Translated and abstracted from
tL
994.1 .VeMonnaVa Knorgetika (U.S.S.R.). v. 3. no. 7.
1046, P. IL
00,0 Describes a ceramic composition, its preparation.
00 plication for reduction of bast losses from
and
Is molds. Ito use resulted In decrease of 20-
U

0 41
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o:
0
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hii-AIDLIN 1 1. 1.
Use of aminazine for treatinent of earlyjox~coses .,.n preff cy.
Vop. okh. mat. i det. 6 no.11:66-68 N 161. 14:12 J
1. Iz akusherskogo otdeleniya (zav. I.A.kaplanskiy) qoslavllskoy
gorodskoy bollnitsy (glavnyy vrach G.S.Matviyevskiy)
(PREGNANCY COMPLICATIONS OF)
(CHLORPROMAZINE1. (TOXEMIA)

FREYMINP L L
Use of aminazine In obstetrics. AkushA gin. no.6-.99-100 161.
(MM 14:12)
1. Iz akusherskogo otdeleniya (zav. LA, Kaplanskiy) Roalavll-
skoy gorodskoy bollnitsy (glavnyy vrach G.S. Matviyevskiy).
(CHIMPRMAZI119) (PRFGl,'AVCYt CMMCATIONS OF)

FREYDIN, I.L.1 MONAKHOVICH, L.S,
Several problems in developing the industr7 and transporta-
tion of the European part af the northern U.S.S.R. Prob.
Sev. no.5tl9-31 163. (MIRA 16:11)
1. TSentralInyy ekonomichaskiy nauchno-iseledovateliskiy
institut Gosplana RSFSH.

YRMLIR, I. S.
Structural chWes in ye,gt cells induced by radioactive phoophome.
Hed.rado 3 no.4:08L89 J1-Ag 158. (MIRA 12:3)
(PHospHoRus-rsompics) (YRAST)

17(2,12)
sov/16-59-6-32/46
AUTHOR. Freydlin, I.S.
TITLE, The Antibacterial Action of Extract From Leukocytes of Rdbbit Peritoneal
Exudate. Author's Summary
PERIODICAL: Zhurnal mikrobiologii, epidemiologii i immunobiologii, 1959, mr 6,
p 125 (USSR)
ABSTRACT: The author studied the antibacterial action of extract from leukocytes
of rabbit peritoneal exudate on Staphylococcus aureus and Sh1gella
flexneri c in vitro, The Staphylococcus aureus strains had marked
hemolytic and plazma-coaggulating properties. The tests showed that
extracts prepared from suapensions below a density of 30,000 leukocytes
per cu mm had no antibacterial action, whereas extracts from suspensions
of 30,000 - 50,000 leukooytes/cu mm had definite antibacterial properties.
Extracts from suspensions of 65,000 - 90,000 leukocytes/cu mm prevented
the growth of colonies on the liquid nutrient medium. Shigella flexneri
were more resistant than Staphylococcus aureus to the leukocyte extract.
In a number of cases Staphylococcus aureus strains lost their pathogenicity
as a result of contact with the extract. The leukocyte extract proved more
Card 1/2 effective at 370 -than at 40C. The extracts were also relatively thermo-

SOV/16-59-6-32/46
The Antibacterial Action of Extract From Leukocytes of Rabbit Peritoneal Exudate.
Author's Summary.
stable, withstanding heating up to 65 0C for 30 minutes. However, they
lost their bactericidal activity after boiling for 10 minutes. Storage
of the extract at 150C for 2 months led to a decrease in its bactericidal
activity of 7-8 times. The results showed that the leukocytes of rabbit
peritoneal exudate contain an active bactericidal agent which can be
liberated from the leukocytes by extraction.
ASSOCIATION: Kafedra mikrobiologii I Leningradskogo meditsinskogo instituta. imeni
Pavlova (Department of Microbiology at the Leningrad No I Medical Institute
imeni Pavlov)
SUBMITTED: June 27, 1958
Card 2/2

FREYD.LIN, 1. S.
"D,K. Zabolotnvi (1866-ig2g)" by IA.G. Gimmellfarb, K.M. Grodskii;
in series "Outstanding figures in Russian Medicine." Reviewed by
I.S. Fraidlin. Sov.zdrav. 18 no.4:57-58 159, (MIRA 12:4)
(ZABOLOWYI. DAIIIIL KIRILLOVICII, 1866-1929)
(GIMKRLIFARB, IA.G.) (GRODSKII, K.M.)

FREYDLIN, I.S., vrach (Leningrad)
"Road to health" by IA..N. TraUtman. Reviewed by I.S.Freidlin.
Zdroavle 6 no-4932 Ap t60. .4; (MIRL 13 -.8)
(HYGIENE) (TPJMTW;o IA -)

MODLIN, I.S.
Change in the phagocyte
reactions of leukocytes
pign during the process
i mod. 52 no.9:80-83 S
activitY and Some
in the peritoneal
of immunization.
161.
cytochemical
exudate of guinea
Biul. eksp. biol.
(MBA 15-6)
1. Iz kafedry mikrobiologii (zav. - prof. V.11. Eosmodamianskiy)
I Loningradakogo moditsinakogo instituts, imeni I.P. Pavlova.
Predstavlona deystvitellnym chlonom A1411 SSSR II.N. Zhukovym-
Verezilnikovym.
(PlIAGOCTYTOSIS) (EXUDATES) (DANONITY)

FRSYDLIN, I.S.
Phagocytic actirlty and some
cocytes in perit 'meal Fiicudate
nization with tetravac,,cine under
turatlon of the body with v-1tamin
.i Imun. 33 no.1091.01-1,05 0162
cytochemieal reactions of leu-
of guinea pigs folloving immu-
conditions of afferent va-
C. Zhur. ialkroblol. opid*
(MIRA 17:4)
1. Iz kafedy-j m1kroblalogli I Lmingradskogo meditsinakogo
instituta. imeni akademika Pavlova.

a a 0
e
a If 4 P U u a a 1: x u
A J- Au ill"rw lot L 111 1 v" is 1-1~ 11- 1- M a CC pa U I A
F,:'

00 A Kjoedw of thermul decomPoWtim of PGtASW- f-t*
3, 1 VivIdJul and 1). N, 16's-kew C),
A. A. Halaulln
*
mjr. 1036. No. IS. 321 45.
ftfp, M,g I,
(1) yjcM2chirt14v KaCLh S11) at 3711-42W asulchwdl,
at 4444,3"; twth reactilms ppwvni
-
vatio-4144 till'
11
41% '11
I
f
-44
W rtu
Im
l
INY o
tammAy at C.
fanner FrKtjon 6 11) tinles that -4 Ow latter - I Iw fall"
th. TOlluct (all, wth-11 1-. (Ilan Z7% ,( %I*- 1~
to the aW thm lists rapallY to a inilli. for SO I
00 awl mLits., at 440'. the ratio is at a min. for 0-8 111
so ThepromssismPir-
acted mA2I-0IICII(OK)CChK(IV) III + 11,; IV
go CIT.O.. CHA) CO + III. H. C. A.
00
I-. I MATALLURGICAL LITERATUIR CLAISIFICA1100
L A
0 NO 0 it tt OP 44 K it 111 4 It It It ft 0 It JAG
j0 a o & 0 0 f o 0 0 Is o o * * * o 0!0 0 9 0 0 0 0 0 0 0 0 0 0 0 0
0 * 0 & 0006 60000 0 iiiii a 0 0 0 0
0
*0
Is
0
Go
1,60
-00
see
000
coo
? goo
goo
!see
Ise
No
bee,

fit I 1
A L
0
A
A
60
010
41 1 1 it 11 It is it Is
a 1-k L Js a x P is Is is I,
4,1 1 U 7 V. 11 r
fit "Pim ONO!"
m
j",tigpit aw *XjI"f is
A.A.BalandinsindL.Kiz.FrOdlin.
It S. S. R.) 6. 1W M1401). -The thermal infetmelkes
or"alkell malts of monethasic aliphatic acitis with caustic
81611111" with the formation of hydroriefliesn't sell% %tied".
NOC(hil and NsOIf in vatious pfcqmwt4mi% were charged
ivAo a ti-cc. ampoule. the top of which was drown to a tie-
tube adins in a capillary mend ccinnimted with a
l;r.;Y4.k.;d gas httret. The ampoule was riet-trwally
ted In a both of an equal mixt, of XN*(h tind N*NO,~
temp. was kept consi. within - O.A' by an vltv~ revu.
The Is""" and solid reaction protlucts were
l;" (cf. J. AppIlied Cheeme. (U. 8. S. R.). in prem).
r
The reaction heitinis at 210"and prome,"dit rapidly at 2511'.
'Me reaction gives pure H and net Co. With Nzoll in
1111111 equiv. tv higher ratio, thesolid reaction product cim.
a of NstCOs. With NaOif in less than equiv. anit. it,
I
*Mo. to Nm,C(h there Is forreird NvrCtO.. incirming with
ilte decreasing raiki td NsOjf ml inctru%ins Irmp. At 17
temps. tirlow almim Vil" no NaCO. is Pained regardles. i
d the amt. of NaOlf added. Na,CO. gist, react% with
Maoll with the fewination o( NsC(h and If. The rear.
tion begins at 2OU" and prorreds, at an unu%tmily high rate
4t *Kl*. The prolabir %chrviie III drcamr,n. ii:
KaC(hH + NnOll - NuXth + 11,; fl!tj)
Note"
NsC,(;. + 11,; 12N Ns.C,().
4---
INsOli - 2.%a.CO. + If.. The diffefencr lwtwrm
schernes 2 and I I% that the reaction ImIcerds in '21 stage,
with the N~Off acting as a catalyst in a and it% it reacting
O."Urtint"t in A. with the NS'C'O' to the intermedistr
teduce. The results oldecompa. of NatCro, with NaO)f
16 - I L AOtIALLURSKAL LIMAN
19hrive ibis xul"Iflon. Chao. slanc
viask-
'.IQ8j 4.9 ,'--_ -
k .Tow --'-T- a.,
1i it As! I rit"_ '11 ir-w- .),Ili dat as.
0 " 0 " to ; K a, It a of a I w of 11 a a
0 We 0 0 0 o 0 '0 0 go 04 no 806
'600
roe
so
is
roe
of
'00
-00
-
'00
'00

9
906*000 ii,ago
A a L r L I Is
of
0 A
00
00
06
*a A Thermal docomptsmilion of load factmate and fortmah: acid
l l
d
049 11 on m*t&
e&
Surface. I K,_I-j%:jkUjilw1uI r, F. Ilulan.
*
l,%A. thal. Uta -. T S.. (
lit I It Ili. walk. slat..
00 Ntf. Skim. 1937. .V- 67~iea High.1% '.W. TIw gmssluct.
00 t a, %ell st, the kuwtiv. of it%,- d-onsim. tit Ills (inmate atut
IIC(x M on 1'1*,Artr liftichni. The theoryofintertnediat I'
I
SO Alt I"Ilitallm 14 malkimmil"I fly 11m. 41111ildilly if( Inothwito
4ditairied finni file decompn. of IICS(X)II lift M and Ills
f-malv, .n llh~ The ratelviie trifect of Ill. .-n the 1e.
90 o -isipts .I lit 4XIII I, Th,- Al.. tit r of %,4 S its-
a
00 0 11,1m.1 .1,111lig III,- -,I Ift,q)(111 list
-114- j 11,41"lls. I.V Ifir 0,11-A1
00 0 life (111AI 1-11.11141, 111-11 file 11110`111M.11414' M11- I IS`
21 11.1ilt 144-fl- 114`91til Al.M.1111K I.. %gliss7bitil' t(Iltati.41 J.*
Ist,l-t-Isf traklimil, giving the c-Surray of bulivalim.
so It, 1,,w ~*.Vs, 111, fa-A., I.F.0114-ti IIC( )i1jPh, drsromplo.
00
=%! tilt
I I Ilml-ii Alli"il Ills, x*Sr,,o, n-tispo. wall
:"
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too
It J A L, A P 'a A I 1 11 V I. A 1 1 4A N M It
9 9 9 as 9 9 0 0 a
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-00
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IM, i-h.mll %R111'.
-
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oacand
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ful. Hawam, When a 6 prmnt in
100
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00 Itte resetioa t-p. - be cmaidela"y reduced and the I
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'
* , ,I
-
Ca"Vonsion of Pittamalu"I anti Onslitim ("Maet,
iiiarmAi
in that lits"Ots of milkieliff A I
I 'I.Attta- J. AtfilIM (Atrim 41, 'v ,,, k ) to, I,k..i 114
-
Litt I-101VII -- 1
he C%I)IN, ~%,Jt CAtitkil "Ut M
avertit-rell ck.C. ("rettice proVille(i with a tritip. icgulai.w.
06 U, IICO'Nm at 210 XW' owl IIC(hK at 220-4141" '11.1 IN't
tinid any oxalitic at all, iniftpirtwicully t4 tIW anti*. #4
0 411stiliuWAI; thi-is, the tmr. Alowr
:0 lh~,r I.W" the hwitutt- We cistalviimlly int"
'-%alatc. anti this ctmvrr~.m vmx~mt% -ithrn A ii-ttit-
00 tvitip. interval (10-:21P). At this zone the lollowme;
00. W1011
reactions art rinnficting: (1) 2 IICO'%t -- %11'C'0.
96 .3 catalyst
Go + 11,; (1-1) IICO.NI + Moll - NIXOi + fit. M
.%IrC,O. + :.'.%1011 - 2.%ICOi + Hs. If the alkiiii concti
00 is low the reaction vviticity bctwctn formate and alkalt
60 ~:7 6 still low cyrn 2( 1% high temp. of the catalytic tone:

00 In this ca%r reaction (1) Im the higheu velocity anti the
alkali is else true catalyst of the traction. If the ALAN
is taken in tit" all 3 rractlims mur equally littAible. anif
the Witiall is a catalyst and coinponent tit the Frictim,
although the final product Im ciarWitaic. Fur thr prvIln
of otutiAte. the use of 11CO'Na as a raw utati rial ii Itt'g.
A 0 P
0*
00
-00
-00
-40
.00
roo
;-;zoo
r
.-Os
.-Oo
7
'; 0 0
0
adyantseivius than HCOX Tcn triervn(vi,
A. A. lo(fx-wtiv 0
00 9
-1t4LLUfGKA1. tiff'64WRIF CLASSIPICATtCk
go ZZ -Z' t.
It kV a It it 91 U VI it rt It or 413 n i III On
0 0 0 0 0 1110 0 0 0 0 OJO 0 410 4 0 0 0 0 9 0 0 0 6 C 4 0 0 0 0 'A 0
0 0 0 9 0 0 a 0 0 0 0 0 0 0 * 0.0 0 9 0 a 0 0 0 0 0 0 6 a 0 0 0 411 a

a To a A, A a A, a aim so, M M g a at A a;~ a Qr 4 z
I, - I a w -;- W;
4 1 s I i I to -I I U U W is it 10 1 N 17 0 N to 11 V U M 1% U io.I am -r, 4.- At &S -A, are
A l- M N M W CE b
0 ilt &-I,
A[
"food a agli'm .1 Shot xalylool..~ flo.1f.;satuf 0
(11,1111ble lotionslys 1,, 0,101*16 kh
00 14floo. t1o. h h. 14.) It. tj,.S hifful i-l"Itkilp"
0 gf. C. A. JI.X9W, 32. Will, 'I hr i,rrv1,,u.lv diwrlfm
awthud was used. The influence 4 oiatslyot, i%ptclid fin I
:0 kettionittatim, drhydruirnatkm &till tundeti-atimi rnirtiont, Ooe
the directiom of the timmipon. W No. K and %it, Its.
Irs was im-rxilgated. Tho. ifthl-titflvl frd
370XV)
1.4
R-11110110 was 11641shm"Vell hit., d "4114,11.1ir ton't .... IV ~,l 1-
kniii sit tioKalistel Ili the Invowniv oil Ifil't, jand immo A**
rhO, all formostoo was franoduluird Int(v vaithmair relt,ail *Go
Itist tott the temp. The limnuitimi oil o%iditi, wA4 Suit
mooted (at=') in the prr4wncv cif 0.21 in,st-of vis ti-v, coo
.3 deted) lier 11.1397 S. tof IfCCNINa, yirldifig 1104AP;. id as a
Mi 2% All V&ttkMStC, Ifill 1`11111111" 111trina- d~( 11110 ittlif
Cdcalalyst doocreaved the Yield ,if ,tjd4(r And itwo. ~4
of carbounair. An eximially owlive oraialvo lite Oo, I-w.
Ikoin tol ortalate was N&NII.. its lite lorrwii- 4 2 4-j. .4 lot
wbkb FA)%f of IICOX vrise franotfornortl loot., -14ir .1
2W'; IficMuse. N&NII, was as active as alkali uiciAls but
'"Itarly safe to handle. In the P"mn" of alkali niciabi, 'See
..0"If, yieltied besides IICONHl. alto 6% of toxvilatio.
Ilialit htffattoore and 4 patent rrferencrio. A. A. 1'.
0 to
I a I L a
I U AT to 9%
AffAtIoURCKAL LOTIRAIT CLAIDIFICATtato
I- . . .1 ~ .
.90 1- d.t .
rA , , to
0 6 11-111 -IF I V 111 AM A I
Too J T, n Of n I As
0"
0 0
fjob 0
.11- we 0
a old 0 to il I Is so 5' 4 IN

00 Of 0 9 0 0 0 00 00 0:
*131ftfmor Off I 4.tw I T'.0,1vot t, I is w M a M LY a 2; 0
A A L a -1 AL a r a a I t - y T A-k 2 4 0
044( * so
*Opi

(d 90dam"s with saw of 10MILO
AQW. L If. FamDujq &W A. 1. LnebovA (c4inipt,
MCI ANd. ON. 19. 701-7W).--
Nalls saislyw dw resetion 21LOOX . X 0',
li
(X PO U
NY
CsZG
Ou
i
l
WNj)
MQr* act
ve
.
.
t
*
,
y

0 thanKOH. As the amount o(N&NH. bwresaw the 00
Y144 of O&OLMO Agar"M and e reaTon "is
pnK
*
r
act-vnibw to the ustAm I CO,X + t &NIT,
c
tN
I
W
N
OII
1
00 4-
&
21, The re4eflons are ant
+
tb!;;'Ja wW pmxxwd imaw"tely on &MtJon of the
-free
N&NU, to the molten formate. P. .1. 11.
go

00

1,09
]-so
U00

t I a I V .1
AA I

OMEN"
!09000900000*00000000
4.0000000000000000000o
V if U U M " 16 IF 11 w a
A
4
00
04 C
V
00
00
00
66
06
1w
roo*#*6000000000:0
oil 933 14111611 16114141 AJOU *A
V-2 1. -.1. 1 a -A---
0460C111CS I",

"go tomato
Kim#" W
g
94
, =
a
1:

h. Is"emki. Itabod
-
o
1
Pro*- iw- -%"*a 2, 146-67 00

00
Xoforw. Zjjw. ISO, No. 10, 5: cf, C. A.
t
f IIC(X)N
d
i .
a
te
wmpo~ o
.-Th# kholks W l
1061
SqW- W 54 P64W
and uu*r wriest pressure In also ve-I& The solid
products at 11W rtat Jw (akift place In 2 ditectioas .00
2HC(JON% - Ni%CA + 0 4W 2MCOUNs - Na#C(h t .00
HI + CO) well anowlysed. Wearly e"Iv. stnts. at cubott-
ate wW *"(* tot *bWwd at M-O'. On increase 600
of the temp. to 4UU* Uw ykidoloxalate first increased. then
decrea". The curves at dw Nummory Process wtre a(&
b
d b
i
i
l
h
w
oo
c
e expresor
y a s
aracter a
CWMXA
mp
ies c
comp
kinsticoquation.
t
wasobservedtfurio4therowks. Repostedexpwintbe
ddn
(
d
TJ
f
l
dift 4
o 0
?
. o
w a
groun
root nsa
t#.
some vesse
juve
d th
t
f the re
tio
Th
l
h
S
W t
e w
n.
e
ass
=ease
ac
c
y o
t S
ts
t e
di
I
CO
N
t
lid X
CA
moo
. no
xcee
II ain
ng a
v or
adda. a
so
k
%
.
definite lindt. tocreastal the wWty of the rrocAlon in 2too
definite staps. It is cooducled that the reaction il Ft-
-0
Wed to the beten3sestems 400 the waus of the vewl
d
b
O
l
a
=
011
:
on-
atr an
car
za
ter.
cbein
and that it Is of
ate an fornsed sitnult"~owwly and the ttactions are
t
f
d 11
400
the
the pro
ucts a
rristed to the outowalytic effect o
fraction, W R. Henn
'00
ASO-ILA MIALL&INGICAL UTERAT401 CLAIWICATICIff
143050 w4t OiV 0119 ......
U Al NO Af~
S j 0'
I.& j j j j 9
0 0 0 4 0 9 0 #'0 0 0 0 0 010 0 0
too
OK 0.1 M
91 0 0
0 00
0 0 0 0 0 0 0 0 0 0

410 0 0 0 0 0 0 0 0 a
0,3 11 1 f I # a 1)
Aa A -L-1 p
Of A
it,
100
0
0
:
Oi E
.3,
01
ip on rCV---#7*--4-Vf7FTq . -44 0 6 -6 ve 6 0 0
0-0-0 # 0 0 0 is a 4 0 a * 4 : : : : - 0

I 27 z? it h 14 V If M X it U It k At
A is if JS it (I it do0
V A 00 CC W tf
I L
610 4~(' koot-i
1., tiff 140 1.11f.1 'i

Itogictift of sodium &tWd* with aromatic ictonali in .00
11tridlitt find T. K 11uhawya.
the Owes aftlo.
.
AnAlugut's -414
to the between NaNll, (1) and *all% of tug.
adds the "Untatic ketones with I in the multrin state
WWtM dcQVW Of the Co group to give NsHCNe (11).
Ule cOnspoOdWS kdrombusas and jxoWIly NA111, ac-
bl
id
C
d
&I
e
era
a.. cons
Kaoll + RH + RH. In siti
well Ej small anato. at JIM, NaCM, dicyanodumidir sful
Nils we fos , pirobably due to secondary rffloc,"-~-
i 0*
n
The reaction, strouglY exothermic, Proceeds viVwWI1Y =
all cases at temps. below 150* and (or the dikcton" isI
!o1rnt. Beaxopbenone, bewil and benzimn
Often vcry
110.
with at give CA, H and Nils. Mijorrmitir
g
and phertantlirtnequinoste give Ph, in addri, to othcr
P' Anthraq imam! With I giVCS A I)VOWn. dfFItW-
"
investi.,rd. John Livak
po,
of
10 Cal Uuw.j A -5
LIMIA TWE CV11FIC&TIC0
-74W,~ -T --M.,
U 'R AT to Is An A 11
(p t1 of K tv .1 tt 1C It
0 0 0 0 4 0 0 0 9 0
0 0,0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0:0 0 0 0
Zoo
Age
U SSR
"VIP
Coda I a 0. 1) s
Ana
0 0 0 0 0 0 0
0 0 0 0 # 0 * 0 0 0 0 0!~

ease* mis goof or 0 a 0 A 0 a Fa 9 -1 9 0 9 e 4 OF 0
oo 06909090*00&-o e 0 00 6 0 a 0 a a a 0 0 0 o- 0
1) It J4 A it 0 m It is 1; 11. a X 1, m
00 A 11 C ~11 1-1- 0 it P AA N rA 0 U&I I s I
A .00
00
00
-00
7b# latteraction of seeldetailde w1th thel Wtv of argank
00 adds. L. Kh. Frtfdlin and A. 1. LCO-dervit. J. Gex. -00
09 Chtm. s.-R.) 9. qw-1mr-mm); cf. C, A. J2,
immP.-NaNil, reacts with fortmat", S,vtzlel AM -00
*a textelietre mereardinet to the arteeml tiuation 21 RCO,.%l -00
so 2 NaNfl, - NaHCNv + MeCOs + Itoil Rif, while
00 with propionates, succinates and hen/oAles, the PIM-IKT --o
of N, eead Nil. in the protlucts of reacticra was iZscrveil.
*0 14 which was explained by the wcondAry Irciaction: 3 %'A-
The formation of It
IICV, - 3 NaCN + No + Nile,
ad sit the irtale, of tile reaction stmove 3fW waorwi-m-I tjY .0 a
she orriendary trartioni NaNif, 4. 1,14aC-N - NAXN. s,
If$. 24 11frrature and 19 patent IrICUMV4. 40Vkfoal tile -*a
peikd M52-19-14. A A. 11tolsomy ko
as 31;
so
00
00
00
&,a 0
'00
%a*
~-9 0
9 Ul
Ate-ILA MITILLuNwAt LIT14AT1,111 CLA1,J)PICATICIP
woo
Ire It
IT -SAT -0
An L I I
1111, PPIPIPIP OW49 xx RK Kan is OF KW n I SA
i
0 0 4 0 0 1111 a 00 0 0 0 0 0 0 0 0 0 0 0 glia, 0 0 6 0 0 0 0 0 C 0 0 0 0 0 0 gi.-A
0 a 0 0 ;V 000 000000000 0 00009"0o of a 0 0 0 q 4 0 0 0 0 49 a 0 0 di
To --- -- - ,

111 0 a Via w v - -
0-0
1"0
&
0
0
.
.
***so so* too
0
lit a tit It A M 11a 11 SZ 0 It 4 V V
it to cc go dilL It
T L AA

06

00
a it, t I 'o,
1 I
0 ,
it., w0
the fittenkcsion of whiamide with ItAttaintyl Compounds
i'v'.111 vq^.tv, 'I,, 'mwo
0-0
p
11t.t. it
iscillial4tol fitobjeflost L. Kh. 11111.1411, A 1, tj . .....
I -
;tulN. A K.111111-W4 J 4~411- " 11-~ -1`1 ""
I. t. .4.33. %
"
It. 0
.
the iturtwum NANI
Ij Anil 1WhI1%VIK! 4itIll 441,1 1,11
k 11 k',11-
4
ketutir. 1f$ I he .4l,w1o v 44 it ~.Ivvqt k. v.)ot hitle-I with higim-F liq I A Ih, I-olow
ketwe.-I of thl, sallph-atic. movwtiv nd 1,,11wor vrw~. ~
,op oll"filk-I 1110

00 .
I NJ, Ic 7 1.
3 Again (lit teutsiot imiltni tit the CKintati-m of NAIlCN:. I:t; a, J 01 1
.
"fc1podding livilsoi-mbuns itnit It. rht It4awn with O'Dtivill %%Ih Ill, all-
the "upds. in which the CU group i4 linked with .1 IneW phan"Ill: hy )"ji.111411 if, C. 1. 24, 7-
Fir(CO), atI4 wic0l.) &"d with N (COiN111), .",I Ci ills 1,11,01 M 1~.'W [jil", to gj%, till
,,,I a, is, pli" %I :.,I:, at :A-
Awl owl4l, '411, 41"] 1
'
'
latep. I
lor 11IN'b'11111111 .4 1hr Oro. fivis, 1,
NAICN. Ati-I willi
nit Ill Ill. Xwo"ol 4,441.w. jpkvii tit p,p". I It, It" (IJOWIV lit ,.I I
34. Ill, I I tv) I~ 1w ~A.il 1. V~ I I, I ji--1 \ It.. Al"I I Vh\ 11 It 'I 'Al
v%0" %~ ....... 1.,.I* 4--ol.L.1
; SIR

('I) an if,, lWo.g.
oil 14 'bAi,(
4, 11-111 thi. 11
Ir
.
tAll,

OvItIrAlTboir CLA'"APKA11101. *to
of
al 1.
4.1
loot F0 ,
w am it a
o 0 0 s
0 0000 0 4 0 0 0 o o 0 0 0 is 4 o 00 0 000 . 0 0 00 0

~
~
~
0 0 0 0 0 0 0
O 1
O
*
6
0
0
0
O
0 9 0 0 0 0 0 0 4 0 0 6 0 00006000060
o
o
~
04 At Al Al 11 w v jw a b It a a 0 #1 AW u

b
1
-
-
..
-
-
-
-
l`
6
k
!lAJ
UA
A
Imxw
0
4 0-00
~
00 -4-- L-
A j - 11 .
1
1
-j
-
_
. j
- -
k
I.-P.P80010 t. .-V #1- .4,000
lm
0
so, 1MVIII, -AW lff"T!li-ml~l
S
0
A
-00
r - 00
! -00
: lk 111,0"N"m d Owbu IMMA& I. C~ FkTw-
- -00
'00 = W W4 A. 1
ki
19
T &C
. 1,4bodm JOvU, Acail-
nutkm
Th
966
0
M -00

0 -
),-
s
o
oi. C
Cl.
w.
.
iii-iftifi,tio, I A + j0.+ jk4mpi of .0 m +
.1 0
I
+
'O
*00

-
is" oaa~(Mj ji~ br fbhw no*
too
P. ;eh by d _t, (Pt
vbC12~fttlui cataly, bWk. Own-, see

ambietas). (Walate so pftdaced uii&f any covAtIm.
'to v
ll
f
i
13"W
N
cmn.
as
o
reacts w
th
&NUst tr or C4ko at
+ + me'.
t M,
?
V

00
H + Cl
tb. 1.10. &.0 + it-* + %, :
,L
T.
a*
g:
S. A V o S L a StIALLUROKAL U MOM CLAISWKATICP
00 '110., S~l fill. - - - w
Ificed wit a" 04f
0 a ; m n I
0 's '690 of
0 00 010
0*0009400006004096040
coo
800
'00
rz ?see
lld~. too
400
i~'& a a owl
I IT "
n
0
00060000660400 01
Vo
40000000000000000,

ie- T -a,64-4,4
, t~ sj ~11 I az A so Is AL a 4 As U u A a 16 if a 11, G 0
oil
flip V14-Arl-13; .016
uill =4y ~
X.111=6, 1. Catelyos 64UTIty, Pu and tMir
de"dvatim. L. Ah.. A. A. Babindin, A. 1.
e0 : - I'll .00
lobcdeva, and T A. FaMili".. (Inst. of Org. Chem,
00 Aced. Sci. BuM. ". ui. U.N.S-Y., CkIss -o*
sci. ckint. 1945, 53-W(in Hughils, GOA); d. C.A. 39,
a
47v2l.-The activity of SiOs Sels to the vapor-plixtt by.
to a drolysis of MCI was I PbCI and water term
00 AZI I Introduced from two ztttuy regulated Balathhu .00
burtis Into an evaporator, *ad ffwn thttv into a rtwikm
tube p4w*d in art tkv. oven (variation in (trup. ~ 1 -4119
The temp. *as measured by a thennocouple placed lns2.
the catalyst. The temp. and the sjumc velwiy are the
mint lnjlxjrtant factors affeclins the direction owl i he rate
td the reaction. Wt. ratio If#()/IniCl. it it is neA lower
than 0.7-1, Is k%s important, It *a% found that SiOt
gris arv deactivated at temps. almyr NO 4M' (Okatov's
Si(h gel). and oomo of them are diactivatul even at as see
w
low a temp. " 440* (Geftoan 80h pill. The ykkt of
00 to the presence of Okatuv. gel ii simad 71 at 060
4 1?.@' at AM'. and reachles Z1.9% .1 it. t1wor,licol
Z
at 542 , i9th span vvkw~ljr 309. The regeneration of
SiOs gels (which have been heated to 6N) by the Irral.
mcni of ok dors not relidabliol: 11svit original activity.
When Okatov's Sel was ww4 at 430% its actM%y remained A 0
at the same kwl for many tus. (ykki of phenol 7-87t) go*
A did not ch&W after the treatment with ok. The
preguation of SA Scl with 3-81,9' K4, IfsM4. cow-
:
ttxu phosphate or NH4 phosphomolybdate completely use
deactivates the former. The Imprx-guation of Sich rl woo
with HoM deactivates It (or the vapor-phase hydrolys"i
441tof MI. but malm It 24 times as active than unpoisoned 0
AlAALA SIVALLUNGICAL Liff
is dehydnislon of &k. G. L.,
t "Ze a4-- I
L
u If &IF so &C 4 a I F I
I 18A *9 )of ?w ; an I a 3 SO
1 X4
000 0 0 60 0 0 0 0 e 0
00 000 0 0 00 00 0 *so 9 0 000 a

64900 90*09* 0 ***goo*
o ji ,
4 t I ~ W it U I t' ti so ty 11
AL -4 _". A AL _jt__
LL-IL
:01 14 dho 7
00 A Osixtmi,
00 .4 if, C4** 1"IVANNot of bakliplijill by hyd(OXY1 In 6*
ofirks. U. Activaim of sib" pi. L. Kill
A. A. Balandin, G. A. I'Mman, and 'A. I
l
x Itrit. Organic Chem, Aced. Set.
00 bwfi. 1"4. j4j. U.R.S-S.. "slit its. thin. 1945. 37&-K3
(Exigh.1% sumnsary), cf. pricinfin4 "r.-Im the g&A.
*0 pha- vm-banr rvactim tmtwwn cilmbraft"r And water
tuhstis in 11w forutatium, t9 tilits"A and 110. it
0 2 haft I"u vistiotsaly clAftiont (list alk. earth mitt may un-
60 R kamv the 'Activity 14 file %ilk-* p1 catalyst. Tluwmxll
00 .1 CIP11,111mly CA the Tvaction, ImOmn 4m, arml G(1V
i1 tbi. "miclusinis to lm Irmir"cl, Tbr gfftpr ii #A-
011111 j 111jed to file usir 44 041" fid cStalystlof " low -iivily.
00 0 Wilh highly bclivv SM calSlysts, treatC4 with IIN(h
M.J cartiully wathed Slid ikirdl. in quartz of Pyf" re-
*0 4 &CtiUll IUI'ft WZ) UUM. joing. VOIA Of Catalyst Y) nd.'
Ifirlilp. mmit. within - 1'. "Wat luorg. sg,_. wm Wulily
uund to knm the catalytic activity of.SM g%I with regard
0 0 V totheywitfulpliciuml, Itiotseratialtorict.OwylleNtof
0 0 Z both plictiol mA IICI, as a suintantilat yield of HCI
jil cmp6l with a Mur yiki q plies" inificales prepouder-
0 0 11! a iiwe rrlwtkms, cotaweratitm of the yield of 110
H: aucc (
'1i sk-4w bas in the paxt led to moucous comicit"lious. A
wt" of nins wrre made with SA Irl bnptcg"tw with
vatiinawdui. tbing a total wtit. of afmt 13-17 g. CJI.CI
in each full And Varyinganits. of Itio, (rum IIVUjC*II&C1 -i
all: uA to 04. Between runs, the catalyst was reantrated
by livatins in a strewn of air at &xj* for 6 his. With
CICI, in the rat al"t ON activity it low -I td in tbe
Igoo" Sivieliv.
VMS 0 0- C a- til-
***. 66 '00: 00:9 0.0
I
1 it A' A12PA31.1011 911 ids 16m WIN 0
7_1460
fro"p. range 4&)' &1io'; At mu" the ykbi.4 I'lle"al
C.~Mpariml with the withmi wt.
Ammounil
n Moly[Xl&te (S"L;) k&Vtg the SetiVily Ad the
40' 9cI catalyst Practically unchanged. At 4.jlj*. liga
(S"O kmers the activity -atidersibly; the Cdect 4iiiiii-
=6 at U111" And Abuse. due . dub4 to vDiatilisatmm
HAQ At hiallser tcmp, lo the pretrom Ad 1.0.1
(5'~)- no l'b"001 VFMA (Cetskil cirta Attire 4 lics.; the yield
in JICI w" 6,41"No of the theory; the ustairst resngiustd
while- lUtlicallud total inactivity. 1,4witring of catalytic
activity (from 10-1 to 9% rkld in pbastil) *as Alto
Otoctv"I with 41ttl mgRat"tw at ZIX)l
the clil&IY%t SWAn to tm entirely Inactive wilk regard to
hirma6un of phrool, although it ttmalm simucellat active
witb ltvixect to IICI. A highly Active SKh grl catalyst
(phcoul yield at tuX)* up to 44.67j, of the tbm7) became
-Wilcrably I- activx uh- hulicegm . ftCla,
.~ted with
w"Clso Of IlISC4 (10%; at OW within about 2 fire.,
fill 10,; II&CIr, C4CIj, or Mil", Y*J& of plietisol wittv,
festi., 21%, 8.111%. 144'". as couipated with 441.6%
without &&1t. The only ca~ of pos. smration by sdju.
Of %4t in CUC4; With 270 CuC4# the yield of phrnol At-
taincil 73~ir of the thoory; Tishcheakil'i tetuary catalyst
"DT" canig. 2% CuClt and 10% MgCJ, gave a yield of
77.5~v. The jumawd activity is entirely dw to the
)I CUC4; the adau. of Ug" resulted in a slight
C717.1"V9101 the 31imifWily of the c"y%t * C&W is
rendcred iwtctivr b
ititirg. salts can be It.11y rftt=4
untirrenaiiiin with CuCI,.
9 1,' W340 -0 1 1.
-Y
US At 90 LS;
?
::::::i0 0 o so* 0 as** 0 0 0 0100,0 0
VALIA) z4 a- Ali
)AL t4 two SO A119449aa a it
000*000000000000*0
0
~00
.60
-00
.00
.00
4P 0
200
440
4:441111
LID 0
so 0
9111110
be 0

4 4 1 A F A A of 0 it u m is 16 it I$ It a i 0
*47A AlLi
'A
00 4
o 0 * o 0
Nil 1111 1-4 11117111*4 41 mumazeas
A 4y-- The fsairdvily of pMfyl 11111141119 IN CAWYOC ""f-ablills
u
as hydrolysis, 1,, Kb, kyr
- ItIllis, A. A. Italattilln. slid
;.
tv
C1
Scod, Mj, U. 1 S.
lima AvaiL W, U, 8 H. It
S. (71010 MCC (kX1 MIS OM
,
Ituatish, W4).-Ilbci alki I'llur of, mt;1y1k*l1
i
K
t
hyditilyted ta 14%011 twhen POL-I -F $401
Tim *W of pholl from Visor b always re." twban
steam
.
front I'liel, but rVacties 9.11% at &W. InslWes"t6m of
the Hit). with CuCle Incirfame thr hydrolysis of 1"h
40"Istmils, [gut r4lerflally tit 11hilt. Phi 6 hydinlywil only
Yield ill 141011 at 401' ul 41%
a moss
htl
ivin
mi
.
.
g
g
y, g
'I 1
041KV the plirwiltv fit NLh LW
u in AMA Lstal
lk
ll
so
W tivu
y
,
14iP Is only
does mA Inmam the yleld
Cl
d C
Sio
00 f!i .
. an
u
.
Aietill hydrolysied. Tbw tulm. yimlM of 1111,011 Is 4.2%
at AM at OW this bamilMsedl.0.6%, SiOldoes
l
1
l
0
le
19 yalia
19 rmi
4lity in
lint Catalysts IW trwills". 7
:0 W with Mcmi balldvis Is pfulattly dim to the avid itaturr of
6
h
d
I
I
di
h
A
4 s
ntrinse
nte
t
t
iou
14(h. uhkb catalym the
yb
y
fur"Imillists and hydrulyals orms I'll "Irr.

IV
.77.,
As, 4-1 - F- -V. j-T--t-W
00 0 0.0 0 0 0 0 4
0.0 6 0 0 * 0 ill * o 4
-00
.00
*0 0
of
11114111
.0
goo
=00
000
066
see
gee
MOO
tie
too
has
tool

A
4 -1-1 -M Is CC pp ~Ub

A
*
Mechanlim of mor-Phass CAtAly tic
lubsidution by
00
hydroxyl of halogen &"&Cbl I
~ In &"I group" -eo
(
k -A, -im, -
Mrs. A lisdan A Fit,hiowt. 4.1d
.
T'vd- NIL #,-Id ,a 1'.R.%.% ,-.4, 1
Im fifills I IIS11,11. 1101 % Ih- %.I I J.,

: k1 I.hAw by 04 &"d it, the V*I.n 1,114- Ily Sit h Ir

0 vmmmd.

:0

0
: .00

0 =00
01

'O0

-A, 0
too
C IALLUO&KAL LOTREATL-01 CLASSIOKATION

U kv 00 0
t;t
.001110 sit ot a ,R " An L I I nd0 66 0 di a
a I A

1 . 0 0 0 0
0 0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 41 0
40 ois 40 0 0 40 0 0 0 0 0 0 0 0 * a 0
0 0 0 4~

0 V 9 W-0 41 #--" 0
F111*0641100000 0 sees 0-00-0- 0*0000096909
*Gj 5 A I a 1 10
A 11 a ZI ZI n M 21 A Is 11 32 LI 14 a IL L? a P a 41 A; 43 a a f:*
00 ': - t . g--,-_L _,&_. 4 _L _
00 PlEffet'is
00 Hydfolp" W dilatobsuse" by water vapor in *0 -09
00 pressm of dU= gol Cdallft, L. Kb. Freldlin. A. A.
Halandin, G. A. Priduan, and A. I.- Xkimmi- ^00
69 tAwiksya Prost. 190, No. 12, 9-11; cf. C. A. 39. 47V2':
40, 46769. AIMM-Ttis is a summary of the nwmr 00
00 innxwtant of pftvious expts. and some new data. In the 0 111,
IT. hydrolysis of PhCI with SiCh PI as Catalyst any mineral
00 a sdmixts. except CIA and its salts d"wess the activity of
the catalyst and promote side reactiom, Craj lowrrs
00 A F the activity at the catalyst considerably, but don not
0 * z 41 affert its Selectivity and facilitates its regrarration. .00
00 j A mixed catalyst of 810~ V1, OCIj, and CuCIj has the
activity of Wo pl-CuCII, Is more stable thermally, and 04011114111
is rtsdify regemrsted with sit at 450*. Fe cfxnpds.. zoo
so al he they adde4 or derivnI from the app., poi.,mi the Coo
catalyst. Washift the MOj Be[ with IINO& inerewo its
catalytic efficiency (d. D. Tishchenko, of &L. C.A. 30. 0
:0 4MV). VAthaudzWCKA"contg.CrCla5andCuCh
0.2%stSW*dw* vepracticallynosiderractionsand
&I OW side reactions amotinted to 15% d the reacting fee
MCI. With time the effectivvnea of the catalyst de-
, ~41 41
clines, but dw regeneration the original efficien
'joo
somewhat surpassed. The increase of CIA in the ca'71Y.Its 400
beyond a ctrtidA win. does not miss the effiLiency of the 40 0
catalyst. The temp. range of the catalytic activity of the
catalyst Is 40(HW*. PhCI hydrolyzes eawr than
j"o
Mr. Phl hydrolywo very slowly and the rraction 11 110
ca"xed by silics gel. Phil did not hydrolyse even
ot
n
7o
at 620% M. Ibwh 1-00
,A Arl -At! VAGICAL WrRATOI CL- ASSWIC .AITION 9-2- too
.11
j7- sic- 411
T
o 11011ast fault Kurt It 1.4 0 w ~V~Wb 0
0( (1 1
010 0 0 0 0 0 It 1P_ o'. 0

Willa 90*04bialli -W 0
EWAN
IS, 1, nil 1333 Six uv,so*tl 943
A. A -a - A-# A -1 a.. X-A a a -L-L--t
If ~P
001 -/`,~- . . .
0 if a
0 0 the MeChaniam of the vaptir-Pballe cAwytic subiditu. 1**
tion of hydroxyl (or aryl haingan. _1_ A - h. A.

1W
DAU din
e
u ?haT,
A
1
Lebetleva
a
d 0
A
F
lee

09 .
.
n
.
.
.
M
.
m.
(
of U.S.S.R.. Mouvw). Ads PAyokochim. V,,R,S,s, al.
-Ttle
WHOW16)
t
k
I1110,

so a .
pregen
wor
an the vapur.phs"
ftwilloct of myl hatides with 11
0 In the tem
f
.
p. nuw o
400*-OW* Is mntmwtd with past work. partkulaily in the
caw al c1lilluirctiscusem (1)
Th
k
l

00 .
e un
itze ro
e of SA ;,I
(U) " a cistai Im On irpleemmuent of aryl halogen by
Oil Is pointed out. as well as the fact that only CIA awl its lee
will% promme the Victim of It. whereas other smilts 4ecrease lee
it. A thcvry of the promm based an the funtiation id
00 %plains the
internsediste silkate estere Is propotted whkh c too
pr,VjWS lagu as wen as the other observed phenonvenilk
agmed. with the vapor-plim hy"ysh of I to phenol.
P. 1. Flyinir
ASS .11, L A idl&LLL%VSWAL ILFTNRAI It" CLAUVKATON
4414,
400
too
*0
too
""IRV
To"
slow 11"491" taldito icit dmv da, itillaimill aiiiAl dW Inv Lit
, I I a 11 V~IAI tv two
U Is AV w001#001 NXwx login it I
in I - of 0 4 : " : : :
11110*0000,11116000006 0*0400 0 000000
It - 0 0 0 0 a 0 0 0 a 0 0 0 0
01 Sol a 0 0 0 0 0 0 a 0 0 - - - - W

0~9 a of 0 9 0 0 0 0 0 t~COAT - t-# 0&6e00040006000
~ .- -,D,0 0 0 * 0 0 o 0 0 0 0
s A I 'i -i ,, '1 11 LA is !I to to X n 24 J. 1, m " X J1 1z tj to 13 U V IS P 4: of
A _1_11. L__L ALA 1. J. - U 24 IX-1111-1t.t- b~ 1, 4. 6.t- I

can-version of asylFbalWei'And allminafloti-O r-CFmitk-,
ra
Illy bound halogen by water vapor, L. Kh, Frodlist,

A. A. 114131111in, A. 1. Leloordeva. %nil Is. _- Pridiii:111.
A
Invil..4 kad..Va wit S~S.S. M.. Ohlel. K Aim. Namok 1%6, 439-
46--A new directimi tit the rrActitian of ArX with strani

so a ita% f4sund; IN-, tv%ultst in clituittatkut of the halvoirris

a "VIIIACC113tilt by 11) and i,, catalyzed by CuCls deloctihird
n oxides of T1 or Sa. 04ily PhOll is formed,

a Whik- the gas tiffiWilt COUtahIll JICI. Coo Coo; Cl. 0. SMI
It art- al'Vitt, It 6 befirv,,il that the Initial reactic"t is
0o I -tit 1121dailml: 11110 4. 111101 - ilct + fico + sit.; CO
0 0
t ii thirls midierd by 1100 it) COf while 11 reacts with I'licl
i mid give. IICI aml Coll.. CI I- thinlitaird mare teAddy
00 IhAti 11r. while dichhortibenictics give a striswise Tractiml
'
'j
YiVidiliff Coll, 411141 PIICL PASSAIV Of OJI S. I'hCI Aild
!
13.8-114 S. Ilso over Tith conts. 61% C
.Clo In [40" with
0 %twice VrI.."Ily Of 134-INI Save 1.11-2.7% I'lloll and
ill, I I ICI;* ~iltdlar calidr.1 Isamed t'll Nit), gave 0.7-
Ltj':~ 1,11011 1411.1 IICI. hithrr Tith. SnOl. of
0011 Cu alisite are lxxwly active. The yirlds of brittene rasise CI,Cjf# mond 11t0 over rith-Cucit at iow with a slmcv

0 Z
0 molsout &V; at Sm". with not imAble dross at lower tenslo., velocity .1117-367 gAve A2- l(Cl, Anil the 11toducts cim-
c
ming the comblimthm catalysts (nit detailed yield. of tAined MCI an't Coll. in . 6A r2ti- at AN)
0 2] C411s are given). The catalyst al,awly losses its activity 44 X1.8 g. PhO jiid 3.5 1. 11 its 11.5 min. 1,jmtr vrl,%Ity
Alid 111tilt lie tVKCHrFAtrd toy Air bliwhig at NOV moist simn.
"
" 20) ovirf IICI; Nimilor
with CuClo. The
clititination
mictisiol begin$ At UbUUt
401"
h
bi
t
d
l
A TiO
C
Cl
l 11%-KV 44 I'hCI 1111%1d 1011th 1.3 11ttil Its() %A.- only
-
-
l
I
i
J
l
f
l
C
l
k
fi
d

O an t
e cum
ca
ne
a
ysts.
, cata
u
r
yst
used at 5W-50' with PhBr ano I.C1,111CI gave similar t.
v. 11 il
prist v%, s
it
i
wvr'
cuti
ie t
in y i
i
r mc
I
i
l; I
showing this If filit-rated ljy catalv,ti 6 cairable cif corn.
P~ results: very little Roll forms, while Phlir reacts some Plicating the 11,11.41 Arvi '.41AVOIC liv,11.4wit'.
'_W', leu thAn I'hCJ tonder emialmrable camilitions; I- ilhvimi,ly. r.a.0%,ti list, -,hmtn41it41*' re,
C1.111CI gim, almt 401'~. tnAlict yields than are OWAiRVII 1411i4ill Air 011-11"i'Allic I'# OW "InVItIP"I 14
Ithell"I'.
A S 6 . St. 4 AtIALLOrrICAL LITFRAIVAC CLASSIPICA1106. I U. Z
k ja~. 1 1; K I , V.
of
47 Q Itil', IF AO I
0 to " " ; J ".1
plan it atsuan 1!X4
0 0 94 o 0 o 0 0 o o * 0 0 * 0 0 a g * * is 0 0 0
0 0 G~e * * 0 * 00 0: 0 0 0 0000000410 0 0
AF it m a Vill
A A 1--A
I I N 0 -.0
444
_60
j, .00
.00
.00
"Joe
COO
000
-0 0
0
:600
200
-:0 0
no*
We*
00
0 * 0 0 0 0 0 111 0 6 0 0 0 0 0
0 0 a 0 0 * 0 as 0004 goo

fill"!
.L A
0
0
09 A I
00
at
00 -3
Go 0
00 3
0 9
00
k
a P a if I a IL a he U a of 41 4& a ice
-
A
I A
is I

"" .-
_
far ce;'Pi , -A.
01110CA11111 soo "QVj4!!s'1 ;.Dog
Catalytic exchange of halogen for hydroxyl in the
A
ti
i
LU
A
L
.
roma
c ser
es.
.
ctivat
ng effect of ompiser. L.
-Kh
11
F
A
A
d
l
1 * 0
1:
.
sai
.
4
ritfil
its,
.
in. A. 1. Lebedeva. and G. A.
TFrIthuman. Bull. licad. ui. V.R.S.S.. Mile its. ikisaa.
- 4110
I
1947. 815-22(la Russian); d. C.A. 40, 4.5771; 39. ~611111
47141; 40, W271.-Tht catalytic activity of silica gri in

the Im-phaft cubversiun of PhC1 intst PhOll by list) vatxar .00
is stro4lir Increases] by Cu. The catalyin is prvpd. by im. lee
prrsnalim of millita gel with 0.2% CuLls anti uJaniki. .4
Inelsillic Cu (01~) to mlipenatate flar has q4 Cu Ifirmsh
*
-
Z
l lee
e
l Is notla
tawo above 4(Xl
Pkild 11181W
4tsoVV4&1s'W. With nietsult Cu mided, 1 tic 4clivil y '4
the catalyst is fully preserved tip to W' but Itills oil
somewhat on beating above that lentp.; lmrt- silica gri
Suffers thetinal deactivation In &txvut the %anic tecup.

1. lot. of la~21) 1111n, dialli". V'4. a.( coo
Cattlysit &) ml., with 10.0 ff. I'hCJ anti Miami

01
F H
5W'
5W'
ass
at 450'
0
d In
ach
n
d
k

)
e
ru
e
1
,
t
. an
.
p
.
,
.
I
4G-&) miss, the yields of PhOll were apploss. twice t how -
4.
Ire
obtained with the sassaw catalyst without Cu. Complete
rritenetation Is achieved by beating In an air stmant 0 tars.
*
g
&I I%OU
. yields (A Pholl Altailivi. werrover the 6o
11110 patwd, Catalysts ("Aumml lly It IPOp. 161#01, .4 q0 0
CICI. call he alln-lat complelely le.i'm "'I by illittli'94141041
with C
b
t C
0
i
i
h
h
ff
00
u
u
s w
u
t
out e
ect 4-11 t
etimillyd'seti.
,
valed catalysts. Thus, twarstineut wills Cu salts cats tic j
used in dittinjuish between sever sible anti itTevet,ible ile -
activalkla. Activation wills CUSA). lai rilually effra-livc. we 0
cucto bring fix sued in the Wour.0 of I he trawl I'm. k'"Ahme
does not catalyst the elichsinge. I'l. Ttkm
--- ~ -~ I-- --. t Ito
1
L A 64TALLUSOKAL LITROATME CLASAMPKAllusis 1 V- - - r I boo

.

lailos') 017 04V ~00
0" it is t$ W
it
Ire 0
0
6 0 0 0 0 0 t 0 0 0 0 0 0 0
OT018
a WON* we 9#00 go 6-4-40,
a 2 1 VWA
0 IS 4111; 0 41 0 0 0 0 0 0 a 0 0 0 0 0 0
-0000000*000*090

NSYMARK, I.I.; MYDLIN, L.Kh.; FRIMAN, G.A.; SHRYNPAYN, R.Yu.
Structural changes of a silica-gel oatalyst during its poisoning.
Dop.AH URSR no.5:27-32 149. (xw 9:9)
l.Inatitut fisichnoi khtmil Iment L.V.Plearshavalkogo AN LWR i
Institut organichnoi khimii AN URSR. Predstaviv diyenty chlen AN
URSR O.I.Brodalkiy.
Oatalyst%) (Silica)

..... of the other bond In phenol 11114M 11. C414-
"U' I
.110. d .. mpos don of anisitile and phiffietole. L, X10
'i . A. 1141.610in. And N:. M. SalArova. lzwrl.
-Ifiad, SaiikS.A.S.K.. (11,14. Nkint. Namil 1949, 1911-2fil;
0. C.A. 43. 57--Oks- , [is uncal,alyzed low-trinta. PYTOIY%i'
oil PhONI.- -111d PhOlil (In the Iflull. range Of 41KI-701"
And it!) fill, . trap.). III xl;144 file primary %tell,
mit it( Illo ill # It, (Illivil. It: 1. art Ilkvlwellr Imilif-A,
C folf"'alard fly R: + 1111011-
4,01111tini'd he .4 'ide r.-Amoal of tile Evarratipluarlit (YIW..
IlhO.NI.- - IlliC11,011. the hitteir giving. am further dc-
Thr m4s. *144 (if 1111011, (forn
11111 ;4nd CO.
PhOSIC And 1,1101-1. Art 51.7 inj At 040" and at
- 1*11ey fill with further r6ing ternip. Thc~-
74 ft,[,
Y14:1114 CJII I.. UI~tAjjtiAlly unproved only it the reactiolli
.are Votilluctt d it lower temps. tit the presence of catalYlts-
phOl I %,t, otgAiije,l horn I,hO%tc at 443' Ott %it-xa get
thV AI).-1ILV ad H-O' With en"t"" "hoNle IllO
fit S. 1. fill- yields uvire:14 and 18(".. rr~jp.
\~r(?IAIVe tit the PhOll p..sjcd) i.e. of the ajine orexr A, in
r,(A,s to[.,. And 24', Lit o47'; in both cu%m 1120 only
lifullintr% thr pyroly.i.. taut doesnot re-Act,ii,evitivnctil by
Ihe Allm-licV tit product% Ill hydrolysis (Nicoll). tit coll-
fr&%j to KlAs~ And 19) AISCA get, artivr itilkat" catalyze tile
pyrolym, c(licit-tifly. With I'lloNlar (without 11.0). at it
1PACe VVIOCItY ~31011 f[./l. cittalyit/hr.. In 40-inin. runs.
M =, 346. Ito, 44:1, and 482", the yields of PhOll were'
17 M. 53.7, -,:,.2 Onax.), CA1.4. and Deconifin.
I.jains almaut 2,'4)' lorr Owl in the uncatalymi rtaiction.
And ii mis. At 410'. whrreA, without catalyst there 6 no
tc-Al-tiam yet it 44;1 '. lit the Pretence of a catalyst, Ito gas
is evolved a- 44:1% Andlitily 44M) fill, gas Is evolml from
9.(W it. Pholte at Ot" (CII., CO, land Ill, no unsatti.).
The cawlywc contains PhOlf load cresols. but no BxH and
no PhCII,011; consequently, the Iwinctillation reaction
*Ilk-b I lit, .4- " 14, at ~4. 111"ll Ill lon,i(Aftf"I pvlofv~
~11111111-~441 It (I V.11.4 of 11111 Ill,
At -Ilit
'it 11:1'- )P I: PhOMP 41-6- 1. PhOll -
Al"; - Tim tirg. of fill) I- A~ W"I to .,r-.i,ijt 4
actia". , riller.. 21141 Iii'll'.61r, "lowfler l,[ .1 hydrolvtkr r-C.
ikin iiettern ma).%. 161 nie -act a vit Y o(I Ill, ,.a I -
ialv%t calt lw ful1v t-torc-I IlV Irt-mment willa tat At ,:ol -
75'. The Yield ,f Hit it I from 1,111 jFt I, .,I
And i, M1.2", , At 314- 'rhe amt. of 1A, evolved 2,
I,-,- th.al a.% 1,111 of Contmil. Mfw"
L"41, IM V, a :1,%) 11,1,10 -fit 1"~
111'r Y', fd-,of I'M Of I

replaesawl of hi log to by hydrawyl in the
SZOMIlds: rhit, IV. VWrIkests bydralyda of o- and p-
c1dorophenots and ti. and L, Kb,
Ilreldlul-4wd G. A. PrIsItuan (Acud, Sri.,
14*11. Abad. Nalik S.S.S.R., Oidel. Khios. Sauk 19C).
317-23. cf. C.A. 39, 47921; 40. 4376% 41, 2211d.
OQ4J.-Ilydrolysis of p-aC411#011 at 519)* over porccLain
Ibips gave no IICI or hydroquinout; over silicu gel a con-
ver-iou of I(M., w-.%s reached. and 4.6% hydroquiuane t-
14ted; * bydru.
J:ilira gel promoted by CuCIt gave
at 43o' "it 12" at W', based on Abe aint. of
CIC%11,0[t introdu"d; the Utter figure corTeponds to
:Irl~ coavitnion; the yield of IICI alwayv exctedcd that u(
hydroquinant; ty.&L" of inmcinol (up to 1.2`0 %t-ir
AL,as detected. 'rhe hixb yidd of JICI is caux4f by thr
dchydruhalogenative -iction of the Cu promoter. ;is, oini-
Pkin of Hit) at 6M, gave 1111011. O-ClC#l1,()N over
vilic.s promoted by CuCls gave u mAx. Yield sit JICI (331,'C)
at UP (16,87a at 4&) but the pyTocatechol yield seat
low: , 113.4% at Ms. o.CJI.Cls ovet
~Ilwj act jave 1-2% pyrocatechol and 0-1.7'7" a-CiCs.
11.01latrAW. AtWo,thevuluessire
"tute at two' they ace 0.7 and 5.417,; bete again IICJ
evulution is well ahead of bydrolysis; pnxnotion by CuClr
due* not affect the pyroctiteclsol yields but increases the
CIC.11,011 Vichl-% by 300-Mr~. with a 2W-3(11)1~, J11-
MAW of IICI evolution. O-CJI#Cls over Oics promotcd
by CuCl, gave a mAst. yield of 4 6% bydroquinone at M)*;
the CIC.11.011 yield A1.0 r" wIth temp. and reaches
All" of couverard product at WO*; total couvef9o",
j.dicil by IICI evolution, ia mag. (30.9%) at W)*, Ile
p-defirs. are hydroly" more reAdily than o-derivs.
G. M, Koocitapoff
Vi-

F ',WWW-WWWOV6099090001we
OM ii is J9 11,44 I.Vb N r1li till 'M It 16 J? a A, 0 A' Q I., Ad ago
_I JA MS. IX
ji- f _ ;L
'&ATGCG Of the Qth*i HAk In 9LIMPIS and Dzil. the rAtio of PbOll to C.11, w" 13' 1 the IT-
law-temponature decompWtion 4 nisole lifte. ips wuA free #4 C,11. and cuntsined CO, Cit.. and M./
e i
to[* In "&I*d tubes. L. Kh. Freldlin. A. A. n, Addn.of %trAin tolbef"d it-11-1.2 rAlio? Lit A01-574, gave
:
Isar IoWVF )i4`11111 Of 1`11011 At hiiihrl II)ACC velocities,
and N, hl. Nazatova. but)a -%0%. the I,)% -pace veloesty 0431. -00
09d. Kilim. Sask 1949. No. 1. tirl-9,-Thersual de- till I
of PhOMe anti MOM PM-MIS Pri-AIT With Pht t 1- -1V%AkUlI%I -11 I,-%cf le"'Ps. .41t11 A14-Ift-i-14s' frM-
compa.
s 01 kyl tionloctAU, At 410' Ah" MUM; tile IlCat Yk-61 Ififl.2', i
!.i formation of PhOl I. with probable furmatitin of free at occurs at 57 4 , &% *t,,%ce Veit wit Y'_='. Throff-s"cuntAins
00 a"i mdkals. SiMullutne(PUSIT tbeftherS undergo a "cublaw- but 10% CsII, (the rest is All givell jtxjvr); the irmucat
to -1 type" rearfrAngement Into "kyl files. The free radicals contains alkylpheniAs (not oolitoi Our chArActerued).
front the Ist reuction lead to formatirlis of alkylphellols, Cliff, and unrrwied MhOlit; no Ph%le or 1411 *As found.
%rater vapor ill" not aittr the pfrodurts of the reaction but G. M. K,wAApod
v decreuses the reaction rate. Vapors of PWR were.
ji,stsed thrOligh a PIMA tub-, Psektd with flaw
0 0 0 ami heatfti to 432- 117, 1 for PhOW or 44D-M'for PhOlit,
PbOll was estd, in the cilluent brumametricallro while the
fother proslucts were "ted by fractionation. PbOhft
equ yields W, pholl ;it 321, At stkace velocity 312 In an
empty tube; the packed tube gave the fullowle
.a _I results
(10 the Above onler): 11-2s7' M-S WT'. 22.8'70- 621
z 2M; 4.5.1'.1, 574% 20; 51.7~~', M 257- 45 We; 707%
2Vs. The off-IlAs ranged front 0,7 to ~1 It.
AMC). parAliel with the PhOll riellils; the remaining
material on distn. yielded Calls. Ph.Me. ustreacted PhOhle.
F'
'I F*51;11
*-ILA bITALLURGICAL,LITINAVURE CLAISIMATION
tofu*.) ZIF elo., 114"
U AIV 10 LI W so P no Cost son %W Kira HK
A I a nd 0 1 IV 9 a 2 3 1 V
-00
-00
.00
11411111
=00
1:0 0
too
as*
see
roe
so*
goo
*0
04,

audit$ yll
G. A Pridutan. R, yu, Nh,j1,'j I- N1111,111k.
Ors. Aead. sa. P I. Khdiwi (Jual
.8-H.R., Mosellow).
N'aak v -*.y X 11goola. A belf:
(,,dl Kki. Vella 1950, 521_M_Ihe
oliluf-Phaft hydrolysis o( MI hHdqs is cat
Ic I allynd
11 hydillhilic catalyst allic, 0 lot
he lkctiv*tkmi brali too the If,(); a typkul aclival owes that
hatuj~. (11, of lot sty)
t! I 41-W4 n"i valodyse thr frarliull,
hVII1111941 %ilkla Sol is arlite: j,un"Oully0aly fl-onsir
fill active
'rntvfslwdl tilt Oil SloulAul thrailk-d grl. litmayrr'llit,
catalytic Activity Of & milks Sri I" governed not only fly the
.1. of thew centers but by the vol. of the rulcrupores. which
dets. the op. surface at", and the mut. of Intermediate pot"
for
nalce" the transport of reactant* ami products.
PbO I still ul IICI, 110111 JIM and 1110 listow In
approx., equal woots., at -W) S.A. catolyst/hr., in 3 W.
min.(I I. PbCP mas at incivusing ternils. from 464) to W,
with sk-alrol"m rtgroorfation lot h2b' Wiesen runs we"
detti. for a types of $ilk-* Sit rabilyme with the ""Ing
charm-torWirs (cogal pooss Vol.. ink-toporto Vol. (mi./a.).
vol. of absorbed lieluki C4JIj at Ill. main. Pleasure. Vol. of
intermediate pages (nd./if ) Smusuer-Romwit-Tou
outface arm In sq. tn.z'u. 41) U do 0.113 0.00. 0 , 3I%:
(H) 11. 441, 0.2111. 11.418, 41, 9. h (ffil 0.0'P.&I, 0.46,11,14,'
W; (IV) 1.23 0.96 1 .19 11-W 490; (VI O.W. 0.21, 11.9A,
0.72. 424); tvl~ 11-W, UAW. (5W. 0.76.328. Curves of the
vichl of Pill III (in ) against the temp. are of 3 lyp,*:
calAlysts 1. IV . anti havil a distinct max. at about tvWi
ill# subwegurni fail of the rate is due to loonveirsible th"nut
JIVewtIvalhool. ,his is "nut Inglithest with catilligai 1 which
IWO ill* SMAII0111i vul, -11 Intermediate pool . Tbol 21*4 t
tarepremitedbylliandUl. Catal"tUll"ahmaord
PFG,M Ically indepentlent at the Irtup. bwtwm 460 and
III has a activity lorgover" al and flolol.
owed by a &U. Absence of - Increaw, of be .,i,lt
IOU
with the temp. in the case of n Is, attributed to be inguth.
elflicy of Intemediale pores. I.e. to in"ttloste diffusion,
1y vim Trov
"his "Me fill-1104' I$ FeSP01111ble fUr he relaiive
high Activilv of III, deloplie its vvfv high
lYfW. ("Weagullsol low catalyst Vt. charkIrtnisohi b,
he.
s small rull-r-tipoic and a lal4v 1nlgfouc4l1atv-p,v# v,4.. is au
tWooxped curve with the y1ekil ifleadily Increasing with temp.
up to tW*. The selectivity of the catalysts, characterfj~j
by the yield ratio 1ICI/Pb0H. is difforent for the 3 types-
it is lowest with Wks gets 11 and 111. with the 11CIjilhOll
ykki ralki inct"Ang Very sitmilly with the temp., fivin
mlotmit MW and OW" on, resp, With the gris 1. IV. lowl V,
ilk# ratio begiall to Increaff with the temp. (goal 01111, uu.
with Vt, It regruidna way newly temp. indefortutent, - 1.
The thergual st'stoully..expors"d by the ratio .4 the IlhOl I
violds at fAX) amd 6W . derfesson In the order Vt (0-14), V
1 1). IV (1.4), 1 wall Ul (9.4). I.e. the treat tuirruploosous
Vi is the noust thtfloostalligg. catalysts I and 111. having tht
smallest Vol. ef intermediate pom. are the West Kahk
Catalyst 11 is vot Included in this ev4luatkm 00 account of
the 11111dondriagot rrvle of Inhitolted diffusik"t. Ali Imp.,ri"I
%Wes gtl. found to be Ywy highly scilvit at 4.V)*. butalmml
voulplefely Inactivated of Wo. was filulki to Ill, very bigibiv
ink-topolorms. and. by the reversibility of Its MrOll-v.t-r
ddwwptkm curre. almost completely devoid of iatrfoomlutl~
="which owcounts for Its exceptionally poor thrium,
N. Tb-
d
,Pjr/

CA
P--tift 41 akkel .Wyw by 6 d
I'Veldlin and N. 1. Ziminovs,
Okw- a"". A "Kk3j-S-R--
KU01. NaNk 1950. d3"J.--*tWU' at
)Ure dfliassed films of
N;J As Catalyst
Ito naltil, CA. 36. 32w) I WM COntimsed
.11 . L-hint of AhNI. 2 bra. at
106 WitlINS01,11. followed by washing with H.O. RtOH. an
toluene gave 1h d
After gatu. with t basic cutalvst conic. 2.33 ff. %;i per mi.
11 for 10 Min - - residual 11 was displaced
with
N atal tke uniatil. ctwntld. was liaortalswett; thud bj~kcWroa-
tiMQ WMA CAUWd At 113C V%9WUW MIT Of 11 retained by the
catalyst. Aliti sAAblus with II&MIC 11W OMAIMIS West
repeated. PhWt, Cill:01011u, etc., were ownt satio~
fwwy for the removal of The retained (julsorball If from
the catalyst. Removal of as much as 210 mi. a&%wbed If
it= 2.33 g. NJ still leavee certain activity (hydrogenating)
In The catalya, and the latter is pymilsork. but rr"Wal of
-hr- contact of the unsaid. rompd.) com-
2234 ml. It (24
pletely buictivates the catalyst. which In then noopyro.
phoric. The removid of If 11 speeded by higher temp.. anti
at 00' the num. amt. of It removable from 2M L,. NJ is
about 224 mi.. and only with removal of the fast 3-1 mi.
does the actisity vanish. Thm, %kcietal Ni is a catalyst
that I* promoted by adsmbed 11; pos%bly other forms of
NJ catalyst are similarly promoted. lxww sub-tances (un.
described) as hydrogenafkAi over NJ lead to com te poi.
Poulng of the gattilyst "hich illuntrrtes a caw of ttpov~s
bring either if* ~61 substance itself or an intermedlAte
that reacts wij'Jh the promoter. G. 161. KOWA&POrl
OIL,

A. .1
NS
to . . t~ .
VA
tT
24r
Aul*tantw wt., wh It 6 uwltwtuiy Wymml Ily n-ft, if

Differential" out-ting of likkol, T" WM 49 Wsd'
)Son in a 4gWyet- I.. Kh. IrrWilis and N, I.
I& jollw"OT;-Psibld AW.
We 01 ha Okcafl' tit'i, U.3 S"
zu"'. dr.
Notsk 74. jel"
the 11, adoorlKI tat motif the Uf slimasiVild in II.-asid, Ni wall
radires). anti the nmequivairtict: Of the 2 IMM, of its was
joy espis. a, hydrosenntiow of org- otisapd,
demoolitIT21fil
with the Ill, CMtainivi in NI.
.'jrVCcM 1441, is, . %, a I nu. % It It ~Mtsa ,is Cit h%. tor"I"O Mhy'
PvkV to the citill. The itiv.,oftesolni ICU inin 3
toy Nikliki'to litifine. with-
r Content.
a "life fractio's of its fit
lot I (A -$%-w ml, It$. on lat~A-
Uktn, "it). Nt. Xat ml. d Nt takes UP -ctlY the
same anit. of Its its gfvm up In the bydrullermtka, and the
prurstait can 14 StIrMAIM fris4"I"Ify, with the *into. of U$
lve" lip anti fAim) UJISSAlso rVuMblins The antio. M1111.
M
ost, Its is ovistiontly the *dwittw4l I(,. With ant"tioncetof
timup 11. repmeentrel toy styrene. rhondink- wvNt. t# its fattis.
the 2.M X. of KI gives up %1144W ud, fit. and.,iii soubsequo,oit
"Compl. of gnup 1, it win give up only tbove 10-21 Fill
Con"imily, compois. of group U withdraw from the %I. in
adda. (is the advartictl Ill. " pan of the 6saulveil Ill, with
A Clouctoonfunt partUl drartiva I kin at the 4doomptive ej pwit y
of the Ni. I.e. paitial destroc" of its sot,tive centers
Subptessce* of cft*p Ill. e.g. IhN(h wid vinvi butyl wth",
withilraw UiettoUlatnt. %of Imoth the Sh4th..
"Ved In the M; the tionts. withdrawn frsxn 2-11 S. So toy
dii[Crmt cognIsts. of 11"I gmp were Y"T Clone. :IV =$.
TAP-M, and 7X1-724 ml Tbi* I* 4isto Its- I-AA1 nit -4 fit
that cute tin ovithLItAwn f"n 2.Xi of 4 Nt hr tit.t (f-.tvq it
with a compd, of Stiouls 1 4nd Own, Afirr ajoliont'; IIth
toluent, by a substance of grwp 111. Misr rmw-
the It the NI bectsmes Inacti,,e Ittr the hydrgrnatiom ed
ccenj2s. of smp L The 11, adissitied m the osorl.ceo it.i.
dently forms no pan of the active centers, IntiscNinquiph,
istivatotignted, The ratio H 1&JPWb*d);I1GIi.AW.vf) Xi -
2:7: 19. i.e. the wimple conuhis I atom 44 tits,,tol'"I 19 per
2.7 atoms NL This coitiridess with the rAtio II:Ni - I ~3
artived at by l1avisawand Oernief (C.A. 21,340 byrict-Inm
diftnictiou. Them. ofH Niisalvotot:1 ', '
times Out nu, of 11 atoms adspriml. I.e., Ow so". al putcu.
tinily pow" active centers is 3.5 times the bw Isl rIujI
centem The no. of the bitter Is roughly 1/n, the no. ul Ni
atoms. N. Thm

A 11
dim
0
*0
elb IV
so
It Un Aix 1,11FAID1111,1140"
A ji- 1
81.136 Aervirroda" of Catmilytic Activity of Siltre GA
Diff"va, porosity. (in Russian.) L Kh, Ficidim, I. r Nvilli-
A, G. A. Fridman, and H. Vu. Shrinfilin. 1--ticilipa Akademi
N41A SSSn (11111114ill of tho Acadviny of Sciences of the USSIU.
Of (:11onlik-jil jAo._Fth. JUJI, P. .44.1
Prvilroul 1"11115 Of a tolill"114tive Invvii(Iji,iltioll lit the 4ANI)II,
fqpCftj" Of litliVAINI 11.1 11011. LIVIlMitt-d tell JI)t4t$111,114 (if
ifivrent Imyrosity In the hy,"Iysim of chhulivillew. Influrike of
N
I
110(crevil fim-Imp, stwil a% type Of arlivaltir, dr1mv of Ix-ftil).
ch... 4111 41divill, of g.,1 ralal)m* ~,,, .1mil.4
dw illifili'lli-v of the 11,1,1wir Artivotow .31A lit'l Ilmlimit 'd lit, 11
DMA #[#4f 01.1ft"I.
761
USS
4s I L s NITALLUV4KAL LIIIIANott
t U7
'ZI
U AlF Ali - V. 7-1-t
n, :7 it :7 of Of 4 6t I
Aa
0 0 0 0 0 4
*0 0
0
too
Iwo
go*
to
too

CA
Tb* ad[vit sirwhirs of ibit Wasi-hrilrollos towyal
L. Kit. Freldlis and N. 1. Zholoov4 (Acad. Sci. U.S.S.R.:
"'= -~ '11itist. All". Namb S.S.S.K.. Wel. x1lins.
N ILI 14&4.-1n a skeleton N1 catalyst, prepil. by
kw*IM 4 60VI-Al alloy at 106'. the atom Mdo Hd.:
Abiteripts sits sM dist fo-
lf*4.: was oil - 1 A11.9 (w
Imins to adporbed and dissolved H. F"p,, detil. by the
reviossily J~C.A. 43. 1113M) described inethod of selective
ydrogma of org. compds,). it. gives the weissure
of tboodive orattra prwat at the surf4we. That this jl~
directly relisted to the West. of ilso structutod Ito. is slkiw.
CalriAmestally by I sg - ve removal of Ila. with tho
of Locreaslar suatc of I-methyl-l-cyclopistise (1). In
the absewit of five Hs. For compk4e removal Of the I Id',- b
corTespostillas to the gives amt. of 1, OD min, k tuoush.
The anit. of Ill adsorbed by a gives sample of The N1 cala-
lyst (2.33 s., civats. 47.4 oil. If.& and 177 mi. flog.) prov-
to be a Knew futictift of the Moahling 16.. [Aliewite.
the catalytic activity In hydrogmatiots W allyl &1c. is a linear
function of Ha- and both of Jis and caulytic
activitY fall to we wbm an the-24-ttlmols rctuavett by a suffi-
cient amt. of L The same behavior was obseried with tbc
un of CJTS:CIIOBu (U) as 114emovir; allyl &k. bad biez
Atow to remove oaM.". but am lljio, Tbt
s=tret I= itpi flog the c se of adsiorption and of
cls yde wdvky. PA a twictim at the remaining I bave
UK Now slow; in other wol , UK ratio irtmains
coast., anif. in lite gives lWance. Is - 0.77. Roth I and
U act cotamned in equizool. ansts.. equir. to the anit. of
I" removed. X-ndisfrarris
entity of (Fe radiation, 30 kv., 10
ma.) %bow complete tity of Amt lattion of active Ni
N, T'lu'a ~
Iltd. w" 1". and of Nj Inactivated by depromotion witb
oil - C4W,

P, of dw skim-0 catalyst by loor nk linflai *a
, p
_r6 Ii
Nrimark F1 R.
R
.asullortlooreedusts. 1.F.. , L
Va. SbaWda, and G. A. Ffkfamn (L. V. & v it Ina
Ph Cloven. Aciod- Bel. Ukr. S.S.R., Klev). low .044.
311 to-PoiNjo-
ins of a maple of ones. 000 gel with I ig I ICO.U causedi .
.dK"mwaidnwAmopomyol.immOJltaU.limi./a.,mI
of the op. -- to, am trout M to 101 9q. in./j. I a another
moopliv. the own adda. caused a decaaw of the total puts
Vol. froto 0.46 to 0.40 tall./g., of the onleropo" Vol,Itutn 0.20
to 0.19 vol.1c.. and of the op. suslace one frout 41A) to 3UV
fnq;0=6/1. In a 3rd maple, the total pore Vol. decreased
AS to OA3. and the anicropore Vol. from OM to 0.18
val./S. The vol.of latcrivediale pore underwent noch"se.
AlwS wM tbose clarim of mictopoi Vol. and op. surface
.ares. tionto Is AW a dwran 0( the Catalytic Activity In the
PhCl + H&O - PhOH + lICI, as illus-
WS data of yW& of PhOtl and HCI. at
rated V
t=
F` - ' SIOS W Ispace Velocity 38H Jr. PhCl/1-
catalletAr.) 10.7 and I 13%; polooned with 167p_ HCOtLi
v 1y 336) 02 and U.5; pobmfd with 17, (AcO)r
it -(space velocity 372) 0.3 and 0.7. The ;=I Is re-
verome; with an looporw (German) Si(h go. impregnated
with Ca". the sp. values and the catalytic activity were
Increased upou cludou of the Co". Adsorption of 11,0
=.w an the S% gele tow not detectal at either 3001 or
. At 4604. PhCI was adsorbed without decimpa.. but
Mr. stood to an even higher degree, Fbl, underwent de-
covol:. At XO'. where there was no decompa., adsorp.
Uois PhBr was 3 thes". and that of Phi 7 titnts as great
sathatolPliCl. Tbevwyuuwhstroo;aadsorWionalPhRr
and Plol se compared with Pba is taken to amount for the
elecreme of the hydrolytic cawy6c actirltr of SKN get. un-
,pratnolsol sor protected witis CuClt, from PhCl to PhBr
and Pbl, owing to stronger adsorptive poisoning b the
latter reactants. ,;. 19'~

n1 L. Kh.
Kin-tici of dehydration il(10t Ir4i Ph01;PhFk!AC JWA-
il
IyO5 and on p V Mid
ilia and
IUVA gAr
Sl ~Y.. 5D,
'i-1 M., c
,3o: cf. Zhur. 01ishchrl Khiioi~ (J. Gen. Client.) 21, 1255
(1051).-Flow expils. %vere made at n ferd rate or 0.10 till.
IICOJI (92 or I00%)/min., oil 20 int. (wt, 9 -11 F,..
length of colunin 0 cm.), with ri of tile gas far CO.
Tbe exr)tl. data (tenip., 1111-gn't evolvcfl pEr till. licoill"
dr.,Tcc of decompa. In 70) are, on Ca(HIP06)j. with $23717
IICOjff: 167*, 39.2, 8.4; 192', 82.0. 17.7; MSO, IMJ),
11.7; 201% 18-1.0, 40.0; 210*, 242A, 52.2; 218*.
1
73.8~--O; oil with 92% IICO,II: 1721~ 20.0, 4.1;
ID5 49.5, 10.7; 20n*, 0.1.7 13.7; 220', 121.0, 2n.1;
2111 U0.0, 40.9; 2,18'. 12160.11: 50.1; 2W .10-1 0, le'-
0 2
oil Caj(PO4)j, with 100% IICO~lf, 172" , 3b:4.'(j'h; '70:
0.00 pai cN,nlvrtl in oil citics, in 1001/
10 /0. Vitt CO.
E, (kcal.~aiolc) and lirri, N, Policat I'll
~he arfivation ellergi
factors ka are (%vith 82(,f,, ITC0111), nil Ca(II2I'0.)j, 17.6 and
.1.8 X 101, and oil CaAROA)i, 15.2 wid 5.2 X 1W. Three
iC.1fillyst.3 -ire, conseriarlitly, 111,glity 50crtivc ill file Sense of
dchydrution of IICOjII it,.; rigaitist dehydrogrnalioti, rind
hig,fily Petive. At a feed rate of 0.22 vil./inift., nit M*.
vol mt. pure CO were evolved for I nil. IICOIII, w; nigningi
G3 R7 .1.8% C
0 'I'Compril with only 9 0 lit tile gnq, riblillned
i) 'i"rae')
v -, I q and ~tyflpr ~C.A. 29, 62n8l) on hiq best catalyst,
ThO, oil silica gel at 2W) . 'rite phosphate-i retain undirtila-
Hici:f activity after 20 bri. servirc. The (fain for Cos.
(POO, fired 6 hirs. at 800* (with 82% IIC('hll) are: 201*
31A 0,7; 246'9'135, '. "; 2B.1', 157.0, 3.1,11; 278-:
203.2 63 2170, CO ciordem In gaA V ~ 111.2,
'-, ~ ~.5 'Y 160. For Ci(IIJ100i livilcil I 1jr. at k4).300.:
1W, 25.8, 5,0: 157*, 60.0 10 H- 170' I(A.0, 22.4; 178',
168.1, 30.30/?0': CO In gas it;O%*, 'ii.7, k. 3.2 X 101-,
The firing results (it a decrease of the rate by one Wf, with I
1
, 1111cl!auged B. Preliminary heating to 2CO-300* increases
tile rate very con.9iderably, despite some InctraNie of E.
Tile rictivily of Alto, Is both lower and le" selective than
!s. Hipti, data with Alto, (concia. t
at4
""it of tile ell 1)110*11'
of HCoW , Till. gas tvolvtd/mI. 11COJI, degree Of
-'r I IC0111 lit %, CO content It, gas in %) art:
jeconilia.
If)0(1;: 2W. If2-I, 18.8, 94; 310's 40-1.0, &3.2, 1 7 2
"M4. 70A. '10.j, -; .110 02.0, 92.3, -; 5 a 20
62 2-10 3101, )00.0, 1)8.2, -; 39%: 261 42-5.
21 2, 82; 310 187.5. 04.2, 80. Treatment of AIxOj by
I illipreganCon with KO lowers the selectivity Fitill further;
witil 'I % KjO. at 203', the activity was ticcirea-sed by UU%
nad tile atilt. of CO lit the gas from 93 to 721%. Firing of
A110 6 firs. at 800* lowers Its activity byabOut One half.
N. Thon

USSR/Cbemlistry - Catalysts Nov/Dee ~l
"Determination of the Relative Adsorption Coeffi-
cients of Water and Formic Acid on Silica Gel,"
L. Kh. Preydlin, A. M. Levit, Inst Org Chem, Acad
Sci USSR
"Iz Ak Nauk SSSIR, Qtdel Ekim Nauk" No 6, pp 799-
605
In view of the fact that dehydrated SiO gel ex-
hibits sharply lowered catalytic activ!?y in de-
hydration of MOOR, vapor phase hydrolysis of ar-
amatic Hal derivs, etc., a study of relative ad-
sorption of water and HCOOR seemed advisable.
197T15
USSR/Chemistry Catalysts (Coutd) Nov/Dee 51
This stud was carried out on untreated (1), cal-
cined (I, and promoted ~III) SiO2 catalyst from
the Vosla-esensk Chem Combine. Below 3000, MOOR
on I is adsorbed less strongly than water. With
III, the relative adsorbability of MOOR drops
still lower. It rises sbarp]ly on silica gel pro-
moted vith K~CO The coeff of relative adsorp-
ve
tion varies witR*temp. At low temps, the relati
adsorbability of water rises.

Effect dvery high presmes on the catalytic propettes of
filuininum oxide. L, F. Vereshchasin, L. Kit. Frehilia.-
A. M. RollinOlICITI: A1141 1. U. Ntlinallov Onst. Orit. Cheiii..
Avail. Sci. U.S.81C, Stim-owl. Isted. AW. Nisisil
S.S.S. R., Of-ki. Kh1m. Naull lost. NOPI Dehr1ration
Fl,n*uf 1:10if it, C'11. writ ItI.S.10 ill a flu% system oil 12 IRI.
lit "tjly;l i tube diwn. 15 intil.) ill I lit lejuji. range 2AI 1:h)'.
"I a fmf rate of 0.16 1111,111011. (Sp2re va'Kity 0.96 1A.
CACAIVIlt). The C,11. content in the tat was at least 97%.
throughout. Stability of the Catalysts -as leoAd by the
Constancy of the rate of the W evolution. r (ml. STP/mI.
EjOIJ); the nomisary ngentratkin, wag done with air. 2 firs.
At 5-11. Frnh AIA flipt.l. frrmn AI(NO.), with N11,011
waitted, aim] dri"I At IM' (catalyst 1) Outwed a low init6i
..,*tivjty. aclivalmin merity E = 92.5 kcal., male. after 2 hrj~
setmition with air. Z hr.. at thc activity r--. P.
f4IImK fit 16.0. After run%. without regencratioll. E r,.c
to atul. After 3 d4y3 stay with the re4ctim pru,jucts.

7V h's -' i ~ d j;, 6j 6 t A
tj-'tW&E---
ins
93 El
'Zi
' - -:,! i
b
112i
U3
fg:
--31-54 i
- p -!
is-of 1": 1 Ali .1 1
9 SP.11A
E.1
t
I OHN. i NI!, ~-2 1

USSR/Chemistry - Catalysts Jul,51
IfInvestigation of the Ki'netics of Dehydration of
Formic Acid on Silica Gel," L. Kh. Freydlin, A.
M. Levit
"Zhur Obshch Khim!' Vol XXI, No 7, pp 1255-1264
Investigated kinetics of dehydration of HCOOH at
200-300 C on differently treated silica gel
specimens, whose apparent activation energies
vere in the ordor: thermally deactivated ;;,ac-
tive.->promotcd -orith inorg admixts. Gas product
vas 98-99~ CO. Reached conclusions as to uni-
formity, location of active centers,
191T23
USSR/Chemistry - Catalysts (Coutd) Jul 51
effectiveness of different inorg admixts. Calcd
umber of active centers per I g silica,gel,
found it to be 10 times as great for 1 mol HCOOR
as for I mol Et0H.
191M3

Potentiating of le eltict-deb7ilir"Mitleft cellialyou
in the 11011 of the re.0wry -.1 thelf "Ure scredwit. I.. Kh.
Ffirldlus and
N. V Z11111-vok MO. Ort. Cherts. Aciss), M.
34C. 1611far"). PAWY Ali", Ndak S.SAR. To,
an enunifer,stecl why polacadog of a
great variety of hydrogemetion-clehydrogensetion. catalys(%
(I'd, Pt. NJ, Co) with a gmt variety of catalyst -pobeessial,
(0, S. 1w. Tr. 11, A,i. %b. M. Cis. life, Is, &nit their Mesepels.)
diers not. no 1% cimininstly and generally issitIlIllej, Mqkj Ill
1441-)r tl%-f "M Ill " it adive celairts, but It fluel to to.
of thwiolved
Z lift (Zt Is act tiefeent1ti pristuater of the
IcAtalystx. The polacens listed fire &HIfighly mactlest towards
111. This poisoning effect of this gmt vaflcty of polsonts
content lic dus to a resection with the metal. especially as to,
Which does not fVACI With H-FMII Intfidje at all, Is a Catalyst
Poison even at room temp. -nud, In all tbm Instances. the
-Po6ooizur- consists simply in "deprossootiocit" through
removal of 11, is furthcr corroborated by the irreversible
nature of that pokining, and the necessity of mifewed hydro-
gestation to remost the ratalletle sidivity. Furth"
is proViifed by the stoichiometric p"Vortion bef:xg
"xi-Aimplioit of the junw"i and the sent. of dissolved 11,
osed the simple telAtion becercess the and. of poison intro-
duced and the lowning of line activity. The %,is -411111ft
poisoning effect of HOS can be explained by a chin rrartisio
afthetypoll's + If -if, + 118; .1118, -11, + :.N; S f- 11
-- 118, etc.. owing to whkh twit fool of lfi can lising I.K,l
tberemoviklot4gfftt?W,OfllatL'tll$. RrIfentritionhys
screens of fit has rsorullselly the rflivt of "it she ratsivat
isnew with It. Tile obors-vatkin tif Mulkin, flat, WA 41.
4437s) that deactivates the PVC
catalyst very rapidly, can be readily explAin"t by a con-
surseption of the dissolved If, In agreement with the r-any
wo~wdw hydraggroatkin of cycloptriftne at routo temp
uudtf twillittetry pmsule~ this hydrojettotifect IAki-q pUrr riffn
In the absence of fit. M) fly at the rips-niie of the d4solfinj
11, and results Inc ornplele polson Ing of the cAtAl yst. Inthe
blidnitfenstion of 10 in]. of an MAX17c suln. of 1-inethyl-1.
cyclopfintene (1) In 10,11s, on 2ZI g. M, the initi4f r.,tr of
alififfliellon 14 He was 2 alert Me inin., th.st rAIP
fell to 0.5 Ird./faill.. and. afirr iowth't, IN) no" , In if 2
Ud./mi". The I content of the "It. felt. at the" siAzes,.
to 6 and to 1.1%. resp. Superficially ud,swtwd It in only
loosely bound and. being consumed -fint. ptotects miive
centers against depromotion. its long as 11, is supplied
from without. Conditions favoring removal of the dissolved
H, such as high temp., vacieurn, or a strestess of f1tranews
gas, deproonoto the catalyst. fly practical ex * in
dehydrogenation wed hydrogenation reactiomi. tnstrr-ngth
of the bond betwets the dissolved-If promoter and The
catalyst decreases In the order Pt > ,'I > Pd. Arcrplors of
dissolved It have a de,promoting urtiou. The prarthv of
ouvyinS out dehydrniscruition In a stream of 11, is deed by
the advisability of keeping up a coffee. supply of Ow two
effacer. Tbiffl
1141

USSR/Chemistr-y - Catalysts Noy 51
"Kinetics of Removal of the Promotor trom a
Skeleton Nickel Catalyst and the Relative Rate
of Activation of Hydrogen," L. Kh. Freydlin
K. G. Rudneva, Inst Org Chem, Acad Sci USSR
"Dok Ak Rauk SSSR11 Vol J=I, No 1) PP 59-62
In empts the hydrogenation of benzoaulnone,
estab
lished -that hydrogen is present on the cat.-
,alyst in 2 forms, dissolved hydrogen (I)- two
adsorbed hydrogen (II). I acts as catalyst
promotir: When due to rapid rate of supplying
benzoqvinone, slow rate of supplying %, or
198T5
USSR/Cbemistry - Catalysts flov 51
(Contd)
Insufficient quantity of catalyst, I is used up, the
catalyst is deactivated. The limiting factor is not
dIffusion of hydrogen, but its activation: The vel-
ocity of the reaction of adsorbed hydrogen with Lben-
zoquinone is much greater than the rate of acti'M-
tii6fi 6f hydrogen.-by adsorption. The energy of act-
ivation of the'reaction seems to be the same vith
either I or II.
198T5

x0etwo CA the dehyditatiott of almlsAft in the presmCe 0i
mambobtut*4 itakium pbosoatt L Kh, I-r.1,11in w-
m Levit - lt-c 4 hx ch~, k ,! S., I
lot"s Alt"l, Xakk ~, ~ ~ R.. tAM. xhlw AGut
Qu. I 1';- 7, 11n t1uw citle, awl-~ A 11~rvl r~f, M ml
tan J, -1. f9 a. F- th~ rt~ultt .11h ")I.
144." 0 V;_ ACtiVMIOU -~CT E - 4416 kcal tn,4,
!,.-q-_rzcv Net,.4 k. - 4 T'he K44 is Vx 1.0";
,:Ill.. the -1mis, of thr -r rcr"zltq undinuui,h~l fm
hai- Th, -!~!a law P,Oil ='. 24.5. S.2; X15". 47, 5,
i~5 347'.A~ 6. 31141; 3:w~ ;- 1. U; A. - 3h 6. #. -
A I,)*. AfECt ttMttM~l 4 -r~ CA!.IV't ith KOJI 5', .
tbc d~gTerol c~,urcr%im At 4~11 ta:i". asAx,.%itt~t 47'. fur
the untrr.!cd mtAy,t :w, for arc:
I- . 6 1: :>A'. .31) 6, 1- 4, Z72'. 3S L. 13.11; 2M'. Pft S.
,17 1, I_-S 1. 4:1 4; -'.-4 141 9. 4,14.4; 297'. I.,aL 2.
-b. k. - 4 licastint,,fthecutAl" 4
hr, At 4,%C.-rl %!,. at 2W from oil 4 19
1 7' . umlrr %b, %~mc the actwrv ,f
.r., Am, -At,lyst in of HCWl w-A, k-rcl
-~v by a t~ior of 2. 11% z,_, 11-011. 319% 14.4, 6 t,; A32
41 6, 17 2. 34,1% WA ip, +'.- 'p; 341 '. 155-2. W 1; ~~Xi
-" -.r, . F. - 35 ~~ a, - 3 X 1011. RAi,mg cd the
!,MP fAal. t" F.Iiw tht ~tmwcrsgom above slr;~ With
-tis, III L'S.7. '. ; '- 31S'. 47.0, 19A. 3Z3'. -00,
5; 'SZ7 *, 141 t. 4A-~. .~W. IWA. E - 68m.
Ilf". Tlw of cam-wsion Carin-t he raiiol
With Awi,~,".t ignited I hr. at tivi-7,W. the
.t~u f(w EvAl rre; -*J;"*. 39. 10.1; 41V. !Is,, 26.11;
t.51 -. I Q. 4 Z. 1, 4- 14 ~ L Z' : . 60 ~0t;. E - 36.0. k, - .5 X
]--a'. (ans tht ~im ~u;ws, she rate of dehydrAum of
ht:(1;,V-ed tulwt..~
,,%,A 11-1 rAte io-7. A!~4 .Riif nil., min.. resp ; for EtjO,
:~4.-`i, it, k 1 0 (X73-ZP,451. rates ITj-l.Ao M1.
ml
LIX), cun~crwja 4j~-43_07,t and for Etuff, E
The rdhit ti, taut an injetmediAte proluct w
,h, .;C. C%1 ST6. gel. -ltbrlroion Of
F-,Al i~ CA -1 lCleVine th.m ou C.Ae?( Th.
At,:
:1 )e 1,01. The
CA* t.,* -Otuvt~ "l-WIq C,11.. The We f the 1`40-
gri 4zAl% %I t, %h,w~c- *-W S bt*. heAturg at NA,~ 1,,wersa it,
by a Thon

FRF.YDLIN. L.Kh.; LEWIT, A.M.
Kinetics of the dehydration of alcohols in the presence of trisubstituted
calcium phosphato. Bull. Acad. Sci. U.S.S.R., Div. Chem. Sci. '52, 177-
84 [Engl. translation].
(CA 47 no.19:9920 '53)

PIGODC&M of 40hydrileamislad A k -k
M" #Ad K. G. Rudarva (last, fX1. Cbein. Aeid.'Scl.
-SAJL. uvocomi). Dawy Aimd. vitak S.S.S.M. 93,
f6011419M), d. C.A. 43. 0=4 40 1104C.-Tbe Ni
C'StSIP4. prrlxf. by 2 bra. lesehing of a ")% M-Al allivy
Z In was dellydrugensited by Jbr. levallue"t with a 2%
a "'no"quit"m at W under No# and than again
Mid. with lit. At W. the lithYdrogroalvil cAtairt W"
able to take up an al"t. Of If# up to about "% of t c amt.
pleme it in Me original catalyst prior to its debysirog7nall"An.
At a still higher jellip.. M% Ili, am
L of Its takeir up rt.
WAJAKd about [be asume. only the time Reccomary for it was
iiiiame. The rehydragenated catalyst reducell lit.
am t 4 tly the I I token up is active. The activity
of t~:= rVal"I 6tairs%3 was tested in hydrogenation. at
20'. of vinyl pbrayl other (in sk. solm.). eugenal (in ale-
ads.), and cisjoptioquincric (in Cqlts Wa.). With The lot-
lowering of the activity is observed after one
ter. a distinct
ball Of the equiv. amt. of H (relative to the amt. of The
quinem) has been spent; this. evidently, corresponds to
begisialne hydrogenation of Ili* -,Ind CO srmp. The lot
au" of the react kill follows a ~~nd-unlrr law. laminciams.
tin activity of tlw entmarat regenerated at 60* is low* than
that at the adomal. noodchydroccoated catalyst. In voust
elpts.. with vinyl phenyl ether. tbe activity of the regenct~
I ated catalyst rentainii fairly coast, over the course of the
hydrogenation. and draws close to thilt of the original catit-
lylit. This sho"s that, although the catalyst beconses tit-
"= to the course of the reAction. it is On reactivated,
The ydrogers in the reacting mitt, is not tiorrely a fre"ant.
-but It also plays the rule of prormotor wbkh miteverates the
entsfyst fit the very course of the reaction. N. Than

UM/Chemistry - Rydrocarbons Xan/Feb 52
"The Kinetics of the Dehydration of Alcohols in the
Presence of Three-Substituted Calcium Phosphate,"
L. Kh. Freydlin, A. M. Lev-it, last of Org Chem,
Acad Sci USSR
"1z Ak Nauk, Otdel Xhim. Nauk" No 1, PP 163-171
Debydxation of ales In presence of 3-substituted
calcium phosphate proceeds highly selectively, with
the gas contg 98-99% unsatd compdo. Secondary alc
are most easily dehydrated by this method, iso-alc:
less easily, and normal ales least. The rate of
2 OBT14
USM/Chbmistry - Hydrocarbons Jan/Feb 52
(Coutd)
debydration of normal ales decreases with increasing
mol wt. Calcination of the phosphate cats,3,yot de-'
creases its activity. On substitution of the
bydxogen at theCKandJ3 carbon atoms of ethanol, the
&ctiva,tion energy is reduced, as was found also with
the use of other catalysts. K2C031 which acts as
prompter for phosphate catalyst it dehydration of
MOM, poisons this catalyst in the dehydration of
ales.
2DOT14

Effect of pre silo z on the c1 macter of porailtir, vitalylle
Properties, Aild Olvitr of !iiWa nel,
V1. Sj
[in U,; ~iu),t afaln. 130J. Acad.
Ull'v*'l cht m. Sch 1953, tramt4tion).-Sce
c I. ~ c 14
C.A.. 48,4929f.. L. 14.

lu s SIR
%AtablHty d skeletal.nitkpl jAtd,jj gLelavAted t ma
and K. 0, HUdneva. DIV, in:
6.m. Sci 1933, 997-Munst. tntu3.i
lAtiou).-SLe C.A. 48, 6217d. L. !1,~

i" and Allljrflva
T7 i~.
lae;~rs. W"cli, 11*111-15:1 Cl. CA 46,
1854C.-Iltermal dcactivation of skekul (Raney) ;I in N
atni. and in r-ccuo was "amd. In 11 attn. ia ab~cnc-, a(
org. matter the cutalyst has high staNlity. ~nd its activity is
not lowemA by 2 hts. at 3M'; only at 460' ar higl~ dms'
its acti~i*ty dcclim,. fleated in rrcw,, the catalyst oc , It,
activity mom r:,.pi(Uv than it does in Naorn. Thus t -.~ tnain
reason for decliqc of Ni activity untler usual hvdmgenmion
conditiong is appamitly not mcry~tn. but 65tructio I of lht~
active sutface owing to chcm. dehydogunation aii( bt,xk-
ing. Kmolrioff

Reactlati of iteld aithydridea widt, ktmati
Y Acatir anhydride, L, Kh. Fv+llia,

A
Ma
14e
LoklianovaTT".
~In
1liv
.
,
a
fl S
MS1
R
Sti
Acatt
.
.
.
.
Mtn., Mad. Muk of
'
.
CO "Jild tlle
EMU react with I nifACACIO YI(:IJiUK JVOI .
Ming inetal avvtatts.' The catimi of the built
rotfesim
aff-tets thr., derompit, 'f`ht reaction Pru~:Ailfldj In tile cold;
with tilt TI salt, it i- Coval'I"ne at 60" with that Na Nalt

are Incouiple tell- decompA. (Zit salt) or klo ilot rk~act at ail.,
(Ca salt). The reaction ka"McratM by org. bAwi with It
IrTfiary Natoul, as NvOlas byaui(15 like AcOll. Strychaille
cffj~ctivt catalyst thuu AcOH. Addix. tit 6ucll
ysts %%at oil Y zke!et Clate!) the Itket.1,11% Not may q(te'-'t
OIL IWA(10a of tho Nactivity uf the: salt tit tile Auve list;
~at cularly .,u eptibla In tli;;i zespcct !3 the Li imit, The
-im-tic curve3 of thv reaction villow Ina% -, W111A arr charac-
AtxEtic o! awwitalytic rtactloo,i. It 6 "Agzelted t1lat tho
proce-4cls throulh. "ll initl4l vorwat"llytic OwRO,
hi
ofter w ell the MOR forialni cataly~~A,_i tile pro~L'~3. Cf,
Whitford, CA, 20, 3fV1. IL Effect of the Ilataro of the
:anhyclrlde. Ibid. a5(", .-Tile icacticri of V and Nla forms
atts dwribcd in preceding abAr. Ii gQn,,xA for all Aphatic
anhYdrides, The TI salt re-art3 zven. at room temp. mid
~W3 re4ction inasr be craployed for qual. detectica of tilt!
anhydrides. AnhydMcs of dibasle a;Ad3 require !levated
temp. (cc reaction, while 4nhydrides of umatd. diba,~ic
acids do not react, uordo couatarin. phthalimide, or IftetAe.
It was showli that, Linder the conditions des
cribed by
Tankolotog (C.A. 4, 2304), it is Impwnible to I-vilate the
product of ad4n. of HCOjlq& &r-4 AcO; thi cryst. prodilct
l
ta apparent
y AcClNaAcOH. And 6 com Ittely Irre C4
l
f
Nf
Kw
G.
avo
L,
AM 9
__0

FRMLIN. L. Kh., A. A. Balandin and E. A. Lekhanova
Interaction of Acid Anhydrides with Formates. II. Effect of the Nature of the
Anbydride, page 350
Sbordk statey po obahchey khimii (Collection of Papers on General Chemistry),
Vol I, Koscow-Leningrad 1953, pages 762-'166
Inst of Organic Chemistry, Acad, Sci USSR

L- YD L / 1Y, L.- 1