SCIENTIFIC ABSTRACT FARKAS, ISTVAN - FARKAS, JOZSEF

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SCIENTIFIC ABSTRACT
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FARKAS, Istvan, dr.; DUBECZ, Sandorp dr.; KANTOR, Elemer, dr. Neurinoma in the otomach. Magy. onkol. 7 no. 2:102-106 Js 163. 1. Budapeati Orvostudomanyi Egyetem, IL oz. Sebeszeti Klinika. (STOMACH NEOPLASMS) (NEURILEMOKA) DUBECZ, Sandor, Dr,-ELRXA.';- Istan, Dr, KESZOLY, Istvan, Dr; Medicall University of Budapest, III. -Surgical Clinic (Budaposti Orvostudomanyi Egyetem, III. sz. Sebaszeti Klinika), (department chairman% STEFANICS, Janos, Dr, docent). "Insufficiency of the Anal Sphincter and the Problems of Surgical Correction." Budapest, MaMr Sebeszet, Vol XVI, No 3, June 1963, pages 152-156. Abstract: [Authors' German summary]In the evaluation of the surgical procedures for the correction of incontinence of the sphincter, lite- rature data and the authors' experiences are presented. The surgical problems and future expectations are analyzed. Based on the evaluation of the 13 cases reported by the authors, it is concluded that many cases of incontinence of the sphincter could be avoided if the White- head operation would be replaced by the more timely fistula operation. 4 Eastern European, 27 Western references. Li/l 12 FAMW, Istvan; GEMCSER,, Ferenc, IWZp Mihaly Intestino-intestinal reflex ard micromotility of the intestinese Kiserlo orvoetuds 16 nools62-64 :064, 1. BUdapesti Orvostudonamyi F4gyetem 111. es 11. oz. Sebes2mti Klinikaja es a Magyar Wephadvereg Zgesmsegugyi Smolgalata. 4' -astri 492b(a 4M. Pottle, J , C0140141144 of slowricelly !044W 11"f*4 or 6lto4-fW51*T~ I Me J Irrorls orroarmost an HungadAax Author nasuries elastic rival resistaxwo, p"Pational to dit. placement. DeformulLoo plus# I.; djs:.S%dfL U.4.d Is based on cletalminwoo Mcow rotado of IlInr istead of the cus- r tomaxy center of OvIty oFdW close sections. AdvsAt&114 Is of most, serwir 108494 4yor, This to Illus- tvated by s"dial O"Iss. Pmcvdm Is iqually Appile6lo if t1yet, ate 44c att ~t the sam size..' A TAPM:7, J.; ALA,-,7CS, A. Condensate droin tap based on heat expansion. n.765 ENI,RGTA. ES ATIO,",:TECqITIrYA. (Energiarizdalkodasi Tudonaryos ---Uycsujet) Budapr:st, 111in,vary Vol. 11, ro.1.1/12, Nov./Dec. 1958 Ecnthly List of East European Accessions (-EZAI) L,'.. Vol. 8, no.7, Jjly 1959 Urcl. =JKA.L, J.; FAIMS, J. Institute of Orgarde Chemistry wid Biochemistiy, Czechoslovak Acadcrq of Science; Praguo (for both) Prague,, Collection of Czechoslovak Chemical Convunications, No 2, 1963, pp 404-409 "Anomalous Courso of Elimination Reactions in the Series of Phenocyclopropane Derivatives" Country : HMIGARY Category : Cultivated Plants. Potatoes. Vegetables. Melons. M Abs Jour 9 FzhBioloo No 69 1959, No 24903 Author i _E!Lkas 9 J. Inst i, - Title :Growing Carrots on Irrigated Soils* Orig Pub : Kerteszet es szoleszetq 19589 7, No. 6. 10 Abstract : No abstract. Card S 1/1 CZLCHOJLOVAKIA Filipp jj FARW~ j IsInstitute for Reseerft Proftotion wA utinsation or Re"Olsotop" - (ror 0& 2e institute or orpae Chamdetry and Bloebodstr v Osechoslov*k A"dft7 or selen"s,, Pmem 'm (for if Prag". Cal I matink AL 9580019 Oak Q=q 2agammudc. MUM& NO 16 JOINUT 19679 VP 462-4t0 'Inualele "Id to and tbelp emlemmeso Fart PrepamtIon or aminamethyl- urson hydmMovideeo FARMAS j, J,Al~;) FIAU 0 E. FARKASO J. ; MCA# E. Preventing the turbidity of wine caused by iron and other metals. P. 157 Vol 2 no 7 July 1956 IiWNr'FRUAr;I TECHNOUGY Praha, CzechoslovWda So: East European Acceasion Vole 6p no, 2,, 1957 CZEi:HOSLOVAX1A/ChemJ-,a1 Tenlmology, Cheinical Products and H-27 Their Aprllcationp Part 3- - Fermentation Wuntry. Abe Jourt. Referat, Zhurml MA&Iyap No 10p 1958P 34157* Author .1 Jim ftr%J. Inst I TOR-g-W-W.- Title *. Doportance of A Now NeVzod, of Adding Gaseous S02 to Wine. Oria Pub.- Kva 3 p 0 No 7* 155-158- aw nwalo 1957, 3* Abstract: The inportanee of S02,in viniculture., the doles of $02 for the vine and not sulfitization (15 mg per liter) if very sweet) 30 x9p It sweet) 50 mgp if medium., 75 Mgt If drYp and 100 M If - vem dry) =d the sulfi - tization methods (with & sulfur fue.- with 802 801u- tionp and with pmeous 80 from cylinders and anpoules) an discussed, A device for measuring doses Of 602 Card : 1/2 Card : 2/2 CZECHOSLOVAKIA/Chemical Technology - Chemical Products and H-26 Their Application, Part 3. - Fermentation Industry. Abs Jour Ref Zhur - Khimiya, No 7, 1958, 23003 Author Jan Farkas Inst Title Influence of Grapes Treatment Conditions on Wine Qjality. Orig Pub Vinarstvi, 1957, 50, No 10, 146-147 Abstract No abstract. Card 1/1 /q/? Ktq S CZECHOSLOVAKIA/Chemical Tochnology. Chemical H Products and Their Applications. Fermentation Industry. Abs Jour : Rof Zhur-Khimiyal No 6, 1959, 21224 Author i Farkas$ Jan inst Title 'Use of Ion Exchange for Stabilization of Wine Oris Pub Kvasny prumysll 1953, 49 No 79 156-160 Abstract A method for tho use of a cation exchanger (CE) for treatment of wine is dGScribed. With passage of the wine through a CE, ca- tions of Fe, K, Ca, Mg and part of the ni- trogen-containing substances are removed from the wine, The necessity for treatiaent Card 1 1/2 H -1i FAIRYA3. J. Applicstion of complexbn III in wine making. p- 323. PRLq4YSL POTUVIN. (Ministersto potrAvinarskeho prumyslu) Pravat Czechoslovakiaq Vol. 10, no. 6. June 1959. Monthly list of East European Accessions (EEAI) LC, Vol. 8. No. 11, November 1959. uncl. FARKASs J. Use of cation exchangers in wine making, P. 949. Technicka Fracas (Rada Yedeckych technickych spolocnosti pri Slovenskej akadernii vied) Bratislava,, Czechoslovakia, Vol* llp no. 11, Novo 1959s Monthly Ust of East European Accessions (EEAI),, LC Vol. 9, no. 2,, Feb. 1960 Uncl. FARKAS, Janos, adjunktus Newer method for correcting the profile of the racking hobbing cutters with positive face angle. Gep 14 no.2:47-50 F 162. 1. Budapeati Mussaki Egyetem Gopg7artastechnologiai Tanazek. FARKAS, Jan -. Curing of wines affected by mousy smell. Prum potravin 14 no. 12:649-652 D 163. (9 1. Vinarske zavody, n.p., Vyskumne pracovisko, Modra. FARKAS, J.; KISS, I. Observations m biochemical changes In irradiated spores of Bacillus oereus, Acts. mikrobiol. acad. sci. Hung. 12 no.lt 15-^8 165. 1. Gentral Food Research Institute (Directors G. Torok), JMdapeat. MMAS, J&i.AN Uperiences with the treatment of rosacoa with riboflavin. Cook. dorm. 28 no. 2:57-64 lob 1953. (CLKL 24:2) 1, Of the Dermatological Clinic of Slovak University, Bratislava. HNGTI, Xugon; FARKM. Jan Problems of occupational dormatomes from viewpoint of the work of the ambulMorium for Industri&l dormMoses, Cook, dorm. 24 no.5:27&283 Oct 54. 1. Z poradne MMZ pro kouns aborobv z povolanta v bratislave (SKII. dtim"se ocave, prev. & control. role of ambulatorium for Induste dermatossis) (OCCUPATIONAVDIMMS dormatoses, prev. & control, role of ambulatorium for indust. donatoses) FARKAS. Jan, HUDr., noistent kliniky Cutaneous forms of perlarteritis nodoem, Cook. darn* 30 no,6: 352-357 Doc 55. 1e Z Dermato-verAroloilckoj katedry LIM v Bratialnve. (POURMITIS NaDOGA, skin) (S9rNq blood supply, porlafteritle nodose) FARM, J.,--A," Dermatological aspect of periarteritis nodoma. Pratisle lek. liety 35 no#2:86-93 31 -Tan 55. 1. A dermto-vererole katedry LYM v Bratislave; Yeduct Wedry doe* dr, L.Chmel. (PARTARMITIS KMA, anifestations skin) (SKIN, In various diseases perlarteritle nodosa) FARKAS, Janosq adjun%tus Calculation of the co-ordinates of bore systems by means of vectors. Gep 14 no.12s475-1+79 D 162. 1. Budapesti Muszaki Fgyetem Gepgyartastechnologiai Tanazek. FARM., Jangap adjunktus nate &Uowancefe Gep sow never method for determiniug CcOrdi 15 no.49137-139 Ap 963- Apgysrtastecbnoloea!L Tawzske. 10 *"Pefti Mussaki Fgrtsm r FApjW., Janos ---- . changes during saw processes in the spice paprika induatrye V storing epic$ paprIM mi3jing products c9nditioned to various dogreoe of meimtwe contents Xm.rr ~.po. no.4:127-330 n-Ag 162. i.. - 1. Sng~a FaF.,k&fo3.dojgOsO V&13,a,&, loratorima FARKAS, Janos, egyetemi adjunktus SystematizatioIn problems of science.. Magy tud 72 no.1:1-11 Ja 165. 1. chemical Industry University, Veszprem. L 13517-66 iT ACC NRt A OM2 SOURCE CODE: HV/0036/65/072/001/0001/0011 AUTHOR:. Farkas. dAaa&-_Farka&#_XAs PRG: University of the Chemical Lndustr7 z r~em (Vegyipari Egyetem) ---------- . L_~ Y TITLE: Problems of t~e.sYstematization of science SOURCE:. Magyar tudomany,- Ve 729 no. 1, 1965P:1-11 TOPIC TAGS: -scientific PrOgraM.9 scientific information, scientific policy ABSTRACT: The article presents new possibilities of systematization and defines the concept of science. The principles which can be used as starting points of systematization are described and reference is made to various trends In philosophy on the subject. 1he problems of documentation are also presented briefly. The proposals made by Kedrov, Strumilin., 'the-Auger report, the works of Uyomovj Szalai and Bukavoskiy are described and evaluated in some detail. [JPRS1 SUB CODE: 05 SUBM DATE: none ORIG REF: 005 OTH REN 002 SOV Ra: 003. r- I Card r,-,, In 't nc ti u SICHIM, J.; FAMAS, J.; SON. F. Studies in the chlorampheAlcol series. Part 4. Birathosis of 1-(p-nitro- phanyl)-2-hydrozymetbyl-2-dichlaro-acetoddo-1,3-propiLidlol and a correctics, Lin Inglish with summary in Russian]. Sbor.Ckwkh.khlu.r*b. 18 no.1:102- 105 If '53. (MLIA 7: 6) 1. Chostral Chadcal Research Institute, Prague. (Chloratophsaicol) mms.l, J-. Siam, J. "Studies in the Chloramphefiicol'Series. V. Side-chain Chlorinated Analogmes and Oxazolines. In English. " P. 469 (COLI;-,-CTIOrl OF CZECHOSLOVAK CIUIICAL CCIMUCATIM-U. SBORMIK ClIEKHOSLOVATI-ml-.11 KHMICHESKIKII RABOT. Vol 18) no. 4, Aue. 1953; Praha., Czech. ) So: Monthly List of East European Accessions, (EEAL), IL., Vol. 4, no. 4, April 1955, Uncl-- 71 r g4atftl. V.' MWOr IGO" (in= VtOH), also ob"id froni P- 'C oroinphenkol If FWhl_m TA), in no in the stdo chok and oiuoffnes. oQq , _kjLZffkd -Ith KOH! Ift _pa with U wbw the takt. was decompd, % ic er t-AW rifigue, CAM- fn MOM (dwooapa. with aq. KOH gave thred-2-dichivro-1 ': er Y 2-omol me I Y A-47,69M.~,~ynthesesaro mdky;4_j *gr*,j4ss3j*xy6exsyj). j ). The cots ,p desaibed of all-4 mood-Cl Alcrivs. from replacing the OR C03arw (Vb), al. 1881, (1 ntom), was. ,ol by C1, o( the thre& &nil try0m, tiffted =y heati.A CSILCH grour trthloramphen1c - i ~=Iq 84M ]ChK CrYfkfo-,'~~N L.!~ -C dedvs.j- and of 3 of the 4 potslble wnblines famed by (OH%CH(NHC, R v d i d asa E ) 11.36 g.), in 4 tu~ Cj1r In 10H mln.-ontheste4u~'- .filtrarnol, cycllatlon RCOR wM 4 941. 6% KOH ClI(O1I)Cfl(NHCOCHCI*)CHsOH (1a) (32.3 ff.) and OR 9. bath and dIIg. with- 100 ml. RsO- It was also obtained' PbaCCI in 200'ud-'C4W beated 1 hr.-od'the steaus bata Yield) by J.'U otlizatio. W1Vb and (45 yield)' 7 yielded 31S.~ k-,, (W%) Jksv*NOtCqff4CH OH)CH(NH- aeatine 2 min. at 110' OM I. 11401H. C H - COCHCls)CHiOC1%, M), m. 182-2.5' (M RtOH). A H)CH(NI11=10H with 0.85 V0E*NH.HCI Benzoylatfou:bf M in: QH&N gave 607C lhrca-#-Ot~ 6 mi. Cj4t4. Via, heated w th HCI In dio=ne,- gave, CH(OBz)CH NH(-'OCHCIjr)CHaOCphs UMMUR), M. 3 S%Vb.m.l3r. Vb similarly yielded Vlb, m. 133*1--,-' (from C")4%!eery(hro-isomw (Mb) of m.210*(fwm. t(from BtOH). Short boiling of Va and Vb with ccacd.- ,AcOEt),was~r~o.aii~lyin47.5%ykM. MA(4.6tc -aq. HCj pve I& and 1b; rap., which. by benzoylation In; g.)heate420mIn.at 1W* with 1.46g. PCI&In 15ml.xykne, QMN, yielded 08.4 and 54;2t)0sNC#M4CM(0H)CR-1 nddUd.with50mI.pctr. ether pve2.15 Iss (VIU ), -sh. 11U.8* and 1760 a 70~) throo-r! (NHrocHch)ckho17 , _I ONCJhCH(OBz,'CH(NHCOCHC4)CU%Cl.(iV*~ . tu. 1.1 0, f (from Won )" Mp. v ars"Ara-P-OINCACH(M)CH... (M), m. 1728 WtId U.9%)6s JgNIHCOC ~~6132 m. 164* (from MOR), WUA' I'M(1.82 g.) in-10 ml; RtOH treated 4hrs- at 0* with 100; tad as a by net. V11a and VUb gave with ml. Q.1N ;QOH, Ii-MOH gave, after neutralization with, cw same cryfAf&-p-0jN'4'HC11Cl- uc HCI, dis6.'of the XtOH,'and diln. with 10 rul RIO 0 tA).. CH(NH cis Bs (U), m. 147.5' (from EtOH)t! 919. In mi. MCSCO with 250 tal 0 IN*". BA i ting 8 (46%) :ik~o*DsNQHCII(OH)CII.If.EiERCh~. O'S N. Ifl. M'4U -q- with 0.1 -MeOHP, !iYdiollyzed (W%'* A'COJI) La .4.I% VIA, tn. 138 SOCL . ill N HCI in I H,O Zil"I 2111) ffaxs-O#NC Cgr I d"ne widi I& and 1b gave 42 2% , and 4M -t-- 0,NC4111. '~.C~l(II.Odil&C".HitCl,)~N-CHCI(30HIk~!m. 28* (frm -CHASO.O.M.C111111COCIIElt flAll., Crythro. hydrolyzed (HC1 in EtOH) to U- Trtatment of 1.52 g. iM,1S9.5*(fromRtOIl)j, Vt. Steeccoursc.itheredur- with 16 mi. dioxant said. with JICI pvt 0.33 If. I (19AW! don of dehydrochlorimphenicul and related compounds, ,i,yi,ire-p-02N[Cji,clfclcl[(NllcocHC6",Ou (Xis ]ill $!Cher. JjjUxLLjY-S lildi, jq~gd in. 131.,5* (from Collij), also obtained tr*tn Va with PCI, ill Rudinger, and WAIMA I orni 16U. bWf4-.::RQuctlOa r - XYl(:11c after hydrolysis; the 0.79 g. 31.5%) VA Ulu Y~, eiilcof~t;;~e comptli. by the Meer-ein- o ~ c Oly rodilommpki tavicil 4ave Ub Oil btnzoybtion A~0.61 g.) with 0-40 Potindorl methixt u stermPecific. 'rhove- wnipds. which .5 r 6 g. PC.]. in 5 MI. C#If I gave ) Ikeat NCeII4*, 7. -Os have a free primary Oil give thica-complis., those in which i 0.27 g.~ 3L MICICII(NI . -- 135 (from -ICOCIICI,)CI12CI the OH group is esterified, t(herilled, or replacLA by C1 or If,, I At .I~toll). .111milarreuctionwith AP1C2q,6%x1U,-. giveerythe"ompdo. P-0~NC4114COCil,"TlfBzCjfgQif(4.71, LI-i" 0130 obtained in 47% yicld from X1b with PCIs. g.) reduced with 4.0 g. (Lso-PrOMI (1) In 150 Oil. Iso-PrOll; Thu cycliz"tion of XUh with KOI1 In EtOH gave 48.8% gave 1.33 g. (28%) threo-p-03NCJ14CH(OLI)CII(NFIBz)-I threo~r-o~NCJ14CIlCICII.N:C(ClICh).O-CHS (XUU), CILOH, in. 152-V (from EtOR). P-O.NC4IfjCOCIf-, I -- -- I (XIIS)CII1011.11cl (24.6 C.) in OW mi. tee and water was I 129' (from EtOlf), also preild, in 10% yW frota Vb with treated simultaneously with a solil. of NaOkc (50 g. in 60. ! : mi. 11,0) and 08 g. PhC1ltOCOC1 (11) with coaling. the; illilded 5-10% XIIIb, ill. 02-.5* (from CCIjorCjHs). Boiling XUT& 5 mill. 'oil which stpd - crystd. on standing and gave. id ter recrystu. ill 601/~o AcOll ja ve 44.7% RIA, in. 109'. CYCHMU011 Of I from CgH4 and then from (ho-PthO-par. Wirr 211 1., ]alb with a1c. K011 gave 60% 1ra*S-P-0iNCJf,CH.O.C- ~(61.3%) i~.~NC4ff,COCH(NUC06CffPh)Clf.O'if (111). k I ~ in, 03-50. M J17.2 g.) tn 200 ml. Iso-PrOll addvil zr..ki- (ctic CH.C1 (XIV), M. 08.5, (from EtORL, uallytol6.3g. In 100 mi. ls(~Ps OIL whilc the TiltsCO and. Ise -PrOlf distd. oil, gavt, after tLewupu. with lag. tart%ricj acid in 200 ml. 1120. 5 g. (34%) ihreP*0jNCi14CH(0fI)- C!l(XHC0X1f.l`h)CH,0ff (IV), in. 113-18". - As by-, 'CJI,C0CH(.NIIM- products iAere Isolated 0.73 g. p-03*s CiltPhAle, in. 142-3* (frottl EtOll), and It compid.. C.111.- in. 276-7* (from ELM). IV tins also obtained In yield by treating (prepti, Irmn 2.48 g. of the corresponding. ifCkalt U11d A 9, NaJIC0j tit 8 ml, 1110) with 1.9 mt, It Ini 25 inL MetCO, evapg. at room temp., difg. with 11,0, fift-ring, and washing with dil. IICL P-(MCjff,C0CIf- (NI-lC0Cl1CIj)Cl1,01I (V) (14.5 X.) heated with 25 AKOUluh hi 120 mi. C4Hja0H 3.5 hrs. at 9"0 under L I vavu, ofter decorn i HI 2- t biric acid fit IW ml. 5,k ar 1 IA 4.11 g, (2& o , _t0 , C41liCtl(OlOCK(NHCO' C11CII)C111011 IV 9), in. 1 9-501, and a small amt. of the erythro-fortis (M), in. 172-3*. p-0sNCiH4CQCH(,NlI- C0CHC1i)CIl;i0Ac YU) (8.16 WA In 300 MI. Colts reduced with 15.35 jr. I 11 9 mi. Cells (000, 7 hrs.) gave 3.7 (20 25"), 'rythro OINC#ff,cl-l(oll)CH~NHCOCliCl,f' ( __ . - - it*_(frorn C4H, and from HCls). SOO` ga-,e er,-thro-P-0sqC.IIACH(011)CU(NHs)CH&OH, M. 210- i 121 . Reduction of VIt with I In iso,-PrOH and decompri, with tartaric acid gave VIb. V (120 g.) and 114 g. PhsCCI in 170 ml. C,11,9 heated 20 min. on the steam Wh, after diln, with 1120 112.2 S. (60j)fP-%NCH,Cra: (VIU), in. 2 - a*. Reduction of 1 In 60 mi. CJIs gave, after relaxing 5,65 S. h, 3.5 g. (61 erythro- ONCO I firs. C I I (0j. i)CI I (.'q I CQP If _C_h)CI1qqLCA.. ty, fft~&x 150 g. V anO 150 ml. SIX1, in SOU ml. dioune 23~ min. gave 97.5 (58.4%),6-0,%'Cslf,COCII(NIICOCHCh)-: CHCI (IX), in. 141* (from MIA and a smallamt. of 2-di.. in. 115-10'. Re-i duction of 50,8 fe. IX trith (if -1 g. I In5W itil. ho-PrOll gave - 'in file uftfal Ala$' 15.6 g~ (55.6%) e,y1APo~p-0,NC.H,CH-! (0H)CfI(,VIfC0CJlCh)CIf:CI, tit. 1,T)* (from HtOftl 116ting 8 g. BzCII(Nllt1hle.1-lCL dtied azeritropically Ir C11T., with 10 g. CIICIjCQCI in 200 mi. Clif 1 14 lin. under reflux ajid, eva the soln., gave 8 g. (76%) StCH NH-' M, the reduction Of widch With I a I".; COUICIANIC ( % PrOU 9,tvc 907, trythro-illiCH(01[)Cfl(NHCGCIICJI)ue XI), tit. UG-7' fir-Orn C4110; It was also prepti. In 92-g.; 722%) )ield by refluxing 7 g. noiephedrine (X11) 3 his. with,, _9.5 g, Clichcollft fit 30 MI. MOIL &-,pon. of XI with 10% 11C1 o firs. ave )OUIC1, tit. IIW2*. VII. Side re-' Iketlour in the raluttlon of dehydrochloralilphenicol. JIH .11pher, Mirriqla, SIOW., Jill Parka.4, aiiii Frant3ek gumi. Ibid. 1819-30; Calledion Curhoslov. Chem. Commus". 19" 3 17-29(1954) (fit Enali-ji)-The reduction of the P-01 NCGH4-, COCTI(MICOCHC4)CHzOH(T)b)rthtl~-teer%ieln-Poiiiidorf _qutthod was studied. Tit uddn. to the redue 14~n o1Ahq]55j Ou dehydration occurred Yielifins P-W;C#H,C0qNI1- &MCIO.' Cl 1, (11) which tomled cry,t. 2 JVJUarvme.1Ay1-4- 'mdhyi-$-(p-nilrophenyi)oxi,se7le (111)a 11(l was responsible for ilymericby-products. 1(m.12.'I-I")(100g.)InIOOml.isof r j rOH was dropped during 5 firs. iiitva 5olu. of 120 C. (ISO.; '.k0)!A1J1j.259 MI. lso4p lf,and t t. was hea at vW; tamrr~flw Af o 6W all. 20% tartaric: was added to the residue,: to 40 *pd. Clystals the Isa-PrOll d6ld. off fit 450, and the i ejad. witu C4H. and crystd. filtrin HO to give 61.6 S. (61 .5%Y Evapti.oftbeC,;Hitzt.andebroma- togratphy yielded 1.6 g. III (11griiiiiie far"tion) (an. in Compt" C,Ilf,NOICI (IV). in. 117-18* (C%H& fritcliOllb, caampd., Ciall,4114104 (V). wt. 109-200' (111011 fradt! fian). III wasahoohwhied bY the Mterwtill-POARdOd fl!" ductfull of H mider hinjilar conditions as described above. Chromatography y1diltif 11.5% 111 and compals, IV and V. Iloiling, IV ill aq. EtOH gave V. III was also prepd. by -mixing 0.5 g. ii zCll.%IeNHCOC1ICh ivith 2.5 nit. AeO und 21.5 Jill, 11,S0, ove 0.37 Q79.5%) 2-dkMoraniethyl-1- m4hyl-5-phenylexazole, fit. 71 _3 (froan pets. eth"), which, (214) ing.) Y'kided, fly nit"duts at -300 svith 0.25 uIL 11440, (d. I.-15) and 0-25 nil. ILSOo, Ill. Reflasing -lUU mg, 1, witls'270 Jag. (tow-1hiollAt in 6 till. Irri-BUOR 3 [Its. pve, after rjystra., 710 flag. 11, in. ljr)-101. Uwasalsolib-' tallied by latatilln- to the boiling point an "a. 913,11. of cii:cilj 1fOS0AC,ffj&fe~pj -, in. 14"V Urom McCOHO. pytyll. by tu~!xijng 58g. I with 3.3 g. P-McC.ILSOXI (VI) 1113 an 14. C. 'I Y eld 870). Sitaili treatment of 5.08 9. P- 0`2N'CJ14COCfI1N1fDZCIIi&OlI (VII) with 3.4 C. VI In 30 11111. Imitilig tile lisixt..1 fir, oil the stcalm bath, C:l,,9K,(74.i,7,,%0zN(4 iB' -CII V N1 ifv ~a'i 1~" at,,! ifying at labir'lit . - ) hi'll --7* (from Ftt)jl , 4 to MtOj~ in. 1!jW) ouj~ VI IZ b,. to IX by ht-iting a few min. ja~ 150-70'. Heating VII -,villa AclOgjvc Vlfl and IX 111,111cre"j, the reaction of VII with Ac,,C) in Ill! :old ~ieldtd jf-1,10l-i C.If,COCHNHIlzCI-fOAc. Buffing 2 z g. VM with 3 C.' 050-PrO).Al ln,50 m[. iso-PrOll 3.5 firs. gave,4ifttaresimcif; the mitt"Jus material with figroille, 1.5% 2-PAeXY1*WC(A1 II-S.; (pti1,,,P1tea%,W,)oeqwk, in. 103--l" (from Isia,-Prvil). I caj., flag 7 Ill,;. at WO'80 g, I in 4W fall. 1-ICI and 320 ml. HxO pvt~~ '39.1 g. (60.0%) P-O,xC,lILCOCH(CHsOH)XHjJlCI M. m. 180-l", and 5.3 g. P-0ji`;Cjl-f,COAc (XI), in. 87--Q* (br, The o-CA(Mit),fikaris' of XI, in. 13P. X (12,3 g.) in AcOlf treated, with 10.2 g. P-NOIC.H.Coel lit JEW and with a win. of 8,4 g. XaO.Atc pve 110 g. (00-85P p-04NC4lI4COCfl(CiH,- N-OrP)Cfl%Olt Oal). ill. 191--6' (froin AmOll). livating 5 17 t, X11 ssith 3,3 g. VI in M) Jill. C611IN 90 min, an tile stearn bath gave p-0j.~;ctff,coc(C.Hi'vG,-p):Cllt. an. 16(li Mi` (fruits dioxane). Adding 25 ital. lfS04 to 4 soln. of 6 1., I in 25 tast. Ac,O at 50-60" and dilg. the assixt. with 3W Ill.' If j0 3-lelded 3.8 .. (70") 9-dirlitarappidAyl- t-aceliaxporthi-1-5., lit. 112-131 (I'min iso-li ( 11). Boiling I X. Kill 1% ith ',1J till. 1 5% S"Ill. of Al(ClEth, and treMingtheredd lm~ troll pn 1A ',;) ml '1% Urtaric acid F;VC JIM ng, (V.L",`O) j", lit. 11!i-3G'(frOjeJCHi). Val. Urs.- AA-, Oic" 11H Park#A, ond dM reduction of :C RMICOMIch)CHO (3-03 g.) with 15U ml. bo-PrOH and. 0.1 11, (bo-PrO),Al~ I*CIOCII10111. -M. 14 rom aq, MOM. This jeompil. 400 mg.) treated In 10 ml. dioxane with RCI gaW 11 )t-%NC4I1jCHjCOCH%OCOCI1CIj (1), in. 83- ;G, (from ON I). The ame pMuct (1,1.) wu obtained by heaking 0.4 c. p-0WCeH4CHsCOCH j at 601 with I m1-CWHCQjHinIOmI.CsHv Erykro-2-dich1oro?xdky1-5-! (200 mt.) boiled with I ml. sym, collidine 1'.5 lirs. gave 40% Irdw-2-d4chlorem.-Ayl- I ?)-Z-orudixj,ni.02-3'. The; e, throv-deriv. did not reut un er the same conditions. if cat- ing- 250 mg. er-Whra,-tOjNCtUtCHCICH(NHCOC[tch)' ;CHtCI 30 min. nt 131). with I ml. collidine gave 200 ing. I trans -2-d0dorompth>4 - 4-c7dorvmrtkyi-5- (p-nilropken y.1) oxissolins, m. W. Trenting 2.2 X, (a 0.0 mi. C,14N with r~--2 to ml, AIIIN below 15' 10 min. za% e M mg. in- 178*1 (from C6R,), which yieWed I on heating 6 win. on the steant - :bath with 6 ml. WW1 and 0.1 us.L.Hpl.. M*..HndIickf,-.: 3ICHER, J.; SYOBODA. M.; FARKAS, J.; BORK, 7. Studies in the chloramphoulcol series. Part 7. The side reactions in the reduction of dohydrochloramphenlcol Lin Inglish with susmsary In Russian]. Bbor.Chskh.khin.rab. 19 no.2:317-329 Ap 154. (MIRA 7:6) 1. Department of Organic Synthesis. Institute of Organic Cheaistry, Czechoslovak Akadeur of Science, Prague. (Chloromycatin) Aj j 115tudies on the Chloramphenicol Series. VIII. jome UnBaturated Jerivatives. In EngAsh." P. 545o (COLLECTION OF CZECHOSLOVAK CfDlMiL CGOWNICATION3. SBUX41K CMKHQSL0VATziKIKH KHDUCHESKIKH RABOT, Vol. 19, No. 3, June 1954, Praha, Czechoslovakia) 50; Honthly List of East European Accessions,, (EEAW, LC, Vol. No. 5, Mikv 1955, Uncl. ' ' ? hi i hi t 4 lj us n t C orainplienito ~-Cfllln set wl I !1 J iK iwA I i;,*i I; . fwxx OCIAS. Gwrr-'aw M, ia!- C Iwio 090Z-~), c'. C.A. 41. ?1 jCd flo, ImIN3 d pharniatill. (&-sS d file rhl,~ro mid ~"elcupto alin1c;fi A4 chitzamplienk-cil ifiveii. Aditing A,:S! I (4.0~tg,) In a Old. U 12JU s;- COC I100:421ft (M) in 21) tilt. C.11,. filiviing (he ervsf;iP;. vid Cry-o", ft'nil C.11. rave 1-3~*V; "Al'. (IV), in. MV In C411f). Sillifltrly, 1.21 X. Ill Ili 2 ml, dioxm.c trr;il,il A01. I) it g. Uii-~fj i't !4;' 4X-,tVC 14 U. P_ONCjjf,COCf(_ Spv. ry), M. MV (from flioxanc). In it, -mme imulti,r wi'os javpd. P-OjN"tf.C(JCJf(NffA6- ia, 144-1' toan )EtOlf~, In 72% yield. ffi~tg. n0st. (4 "L79 g. V. 70 int, is)-PrOll, 41111 4AS X, A) 16ti-II(Ob 3 hr-,. (trilk-t Uh, d-yrurg. (lie rt-Odur. wiqi IflO ith Ut,(j, d6lit. off th, wiveat, aflo (min HOIJ yidd,d 2.03 -. (134%) The ki-im enintlit. mw okliti(A In 19% 5 Hit hv (tic i rd tic tinti of V, ;t! I l W 1 52 XI (5 T IJ d 2 1 M L r W . 1111 1111 g, . . WN 2 brs.. dilK. the mixt. with 51 ml. VW, filtzrinK off tilt salt, tir-Alig. flij: sulitrits, anti adding ;Z. ether to the . resMue pvc 0.56 er st. * f rn. 138 ront M011). ' ( Nptsag V with X1 P. Al 0--ty-Pro), '-' tim. with 4,141 nit. Cilia, d"Colulog, tile IA-ii4lue -tftrr dL-;tl;. off tilt 'Ellipilt a iola.,44f? g. tartaricaril in, IM tilt. J10. he'.1ting th,-- Inilt 11) inin. nt ho" Alip. 'Ville '!!Xt ifil. 11"t), clig %Ville *M~ It loll I [it- A% (414 g iyv 114A I! J-. pom:~I wit(o) ucm m Men W13"Cl 1,411A ifvfl)~ flt~ 'J)7' (from HIM). U,ipig Irr-lo fiflitfil Al(ko-hl`O)~ 'ercaol tilt- ~-ivlil to 40%'. V1 ( j.Ij gj it 1111-fill 15 'Itill. wifil .19) till. 1017,, ArOl I % O&A 134 g, ( 13,0 L. afti r crs-sta. 1110) 11, In. M11-7 (11`011L Hit is'). IT it. - - f,-CYdlr(A Ill lky tic.-Illits 1% lih in i-AIT01 I "'t I Ing vAl till Itic'). if 11.3 1, 91 lispilv"I be Z) fill. I't-OM 111i.l. at lr~'v , 1 (1-1 ' ". it L .CL 11 ( CA. 43, 00 1 Jc (VIII) ( J.A;l g.) lit 6 till. 41imatic AIMEA to pf'o %till. %vitil 1113ir lit '111 Ir eliffl. 1111cor t. filla. we 5 all. Acole. Ow wa,111A Arith lloteco()-ml. fortionq seful tv.,pd. vlvhl, d g. 1',';FCfJCJ1(_:,)ClltlIr (W. ill. 1411" Or'll" Af)?*, 1`1011). 'IT, f aritiq -I of R75 g, IX in 11) fill. Me'CO mrith.4 v4jl~ cmitil. DA11 A. lltsl< ill 11) "fl. MtzCO 11.21 COCI(Cls)(IN911t, tit. lq4* (firmt. PAOM AwyLtlimi ill IX will& AcvO untl guve 87% eri,,,ap 4,).*,;6lf,Cjlo._ '0010,M1,11ir (X). ill. I ;S 0 ' (frotit HIN110. AcCII(NUL Rellittillix 11 g. X ill Cjltq 3P) I'll. Whit 4.5 g. Ill. 3 litt. gilvo, alivir Ollomalogr3libir v Jhr,w-p- M), lit. froolti M011). W1111%ilir xf 1, Its 1111. P1011 %-14 lAsidtle vville A led. It) juill- at $91'. "IT III,- It t, .w1 vyt 7 ll~p r..-l 0:1, With Ft .0 yi'Y''I o 4 t'd I.- v U -:J Alciv) s.cIlx (X11), ni- 1:31 (Ift-ol X11. 10 fill, A,011, C4111). jlc..1tjjjg tilt: juilt. of qT14 18 Tint, 1110 ~1,j min. on the sitcant hath untler 'Iilv- the,oln, with :p 1111. 1140~ fiftLrjug the forbid solo. With C, and cvupg. dl',~ ift :,nelm J;,fvc 0M)"4 g. 1, la flentica 0,36 9, X1 5 luin. at M)* it, 15 'Tit. 114)',6 11170,11 aud t1119. the filiXt. with IGO ptvt 0.25 9, (0.1t; A. -ifter crystn.) - SH, M. I.S., R K. V11 ivith 1-6 (Train C6114). rafficing R,f? the SOCI~ in wean, ond ml. %ocri LA furs., &1(g. off 1: the frt~illtlc front Cjj, pive 541 rr~ 114cf ClCff(NlfCOCI1CI,)CfISflz, (Xifi, ), tit, VIV. Itt. flujinj 6.35 g.XUj witli .50 fill. 1fuf)1 14 br%. awl diiftr - oil "M BU011 YkIded 1.25 K. fh,e,,, .1vilocil. (1411COCHOS)CUTSFIZ, M. IGI kfrout EtOll). W- fluxing 4.45 It. rtytA,a.p-0,NCti,CI(CICII(NIICOCIICI,)- C11.011t (XIV) Nf) miff. j,t 21) mt. dIrv ccliklluc (1711') an.1 filtiaritig TTIT. tilt colliflinc hytirmliloride dejinnitol Atcr file U114111. of Uffo yiehled 2.9 g. (CUCId: N.ClICI 1,,OSz. fit. 122 .1' (train E1011). Re- it E R W2:VR--M_-:J I - Ub MW Ca~ k's ~Et 11 ~Wq :14 " MO I TOM . 1~:_ i~ s rip -PAI 1111-0. ;n hr, yitl, 2..-,' ravv I!. N,CfJ- ClIsON (XV), in. 1.~! I' Orturt HiOllj, Pvfluvitig 2.79 XV willt 4!12 PuOlf 3 lim. diog, ON 1111011 io -mvif", th-rompl, t1w fr4i(bw W001 1110, cxtK. the OW1111. with Illf). .110 CIVS~11;t, the -1VI-111 gavc. 1.12 C. ' 131 (Iturn "'i " it% '24) fill ~ 1. MOM. cl(ClIcM 4 I;iiCjlC(jXll,. m. 178--W ml., ?,Ie,Co gavo OA4 g, (fw PhM fl 0 (f R b T rom e). e ax V (1 ig ,49 g.) with 1% 111C. ITO 14 ('~ 0 n13 7 Itro. under Cof r-,vr 3.41 g. colivI4. C,IIIF- CONfio"i (XVI), tit. 143, (flom It(Oll). f1w whictioll of Which Yitl(lcfl C-07V of a rompff. c"FIXIN"'o's. XVI MOW 14 NO, P). 1~ f.. M. fluff1kv Parkas,, J. OProgress in organic synthesis. IM p. 698 (Chemle, Vol. 99 no. 59 Now. 1957) Monthly IndAx of East European Accessions (MI) 1,,CvVol. 7, No. 6, june 1958 Gountr;v- :CZECHOSLOVAKIA G .0 0'.:~'/ :Organic Chemisty-1. Synthetic Organic Chemistry Ai)r,. Jour : Ref aur - KWA., No 5, 1959, No - l 53 35 Au -'U- hr !Komrsova, It.; Parkas, J4Ax- .Titlc! :Anomalous Reactions of Di-p-Chlorophonylacet- I amide and Di-p-Ghlorophenylacetonitrile with Lithium Aluminohydride Ori,,~ :chem. listY, 1958, 52, No 3, 454-457; Collect czechosl. chem. commun ', 1958, 23, Wo 6, 1121 Abbtrarli .It was established that di-p-ohlorophanylacet- amide (I) and di-p-chlorophenylacetonitrile (II) do not produce reduction of the proposed di-2,2-p-ohlorophenylethylamine under usual I conditions. The latter was obtained only in the pre3ence of AM or even better, in that of BF3- 1, m-P. UO (from alcohol),was obtained with a yield of 95% from the corres- * 1125 Country j'.;'1r Fef UAW KUM., 110 5, 2-959t No. 15335 .W Title OriF- Pub. ln:bstract :ponding chloranhydride and ammonia in CHC'31 contid. as well as with a yield of 60% from acid and urea. By the action of POC1 on I, Il was syn- 0 3 thesized, M.P. 89 (from alcohol). Reduction of I and 11 waa affected through boiling for six hours with 1o5 mole of LiAlk in tetra- hydrofuran. Prom 1 9. of 1, 0.3 9. of 11, 0.1 g. of di-p-ohlorobanzophonone (III), m._ -- 0.1 g. of tetra2hlorophenylauccinic acid ni- trile, M.P. i86u, and 0.4 g. of di-p-chloro- Cexd: 2A CCU.1try C: .70. "Y Abs. Jour AU, '-ho' Or Pub. Ref Zhur - Miz., Ito 5, 1959, no. 15335 0 Abutrant -phenyloarbinol, m.p. 92-93 . were obtalned. cont'd. From 1 g. of II, only 0.3 9. of regenerated II and 0.1 g. of III were successfully Isolated. The products were separated by means of ohro- matography on A1201. DI-2,2-p-chlorophenyl- ethylamine., b.p. 1600/0.15 mm., was synthe- :Ized by two methods: A. by four-hour boiling f 11 (0.01 mole) with a solution of 0.01 mole of LiAlH and 0.01 mole of AlCl in ether, yield 3~W (with decrease in duration of heatingt Country G J,~jir Bef Zhur Fbim., No 5, 1959., NO- 15335 thar Inst i:.'ut. mtia fir ic, ?Ub. 1113ntract :the yield strongly decreases, and with an in- cont'd. crease it does not rise). B. by boiling for three hours 7.6 mM of 11 with a solution of 8.3 MM of LiAlH4 in tetrahydrofuran and 8.3 M of an ether solution of BF3, yield 98% (without heating, yield _V4%); ohlorhydrate, m.p. 2290 (from water); plorate, x.p. 224-2250 (from alcohol); ethyl urethane, m.p. 92-930 (from petroleum ether).-- J. Kovar 'v zA. r d. 4/4 CZECHOSLOVIXIA/Chonical Technology. Chomical H-18 Products and Their Applications. Pesticides. Abs Jour : Rof Zhur-KhiniYaq No 79 1959, 24569 Author i Par XOurin, P., Sorn, F. Inst :-EaEk~-T~ 31 Title :The Relationship between Choraical Structure and Insecticidal Activity of Pyrothroid Com- pounds. 17. Analogues of Chrysanthemic 14id Containing Atoms of Chlorine in the Side Chain. Orig Pub t Cheri, listy, 1958, 529 No 4, 688-694 Abstract t For the purpose of investigating the rola- tionship between the insecticidal act' ity and structureq cis-(Ia) and trans_2-( V~ Card : 1/9 90 CZECHOSLOVAKIA/Chemica~ Technology. Chemical Products and Their Applications. Pesticides. Abs Zour : Ref Zhur-Khimiya, No 71 1959, 24569 H-18 dichlorvinyl)-3 3-dimethylcyclopropane carbonic acids ?Ib), and also ester of rb and 2-allYl-3-mithA-4-oxy-2-cyclopen- tenone (allylretrolon) (II) were synthe- sized. By the addition of CC14 to 3-methyl- butane-1 in the presence of benzoyl pero- xide (23 hours in an autoclave at 90-950) a 38 percent yield of 191 1 3-tetrachlor- 4 methylpentane (III) of' ~kRO/10 mm boiling point and 1.4860 n was obtai- ned. In the dehydrochlorination of alco- hol solution of III with 1 mol of KOH (48 hours at 06)9 1,1,1-trichlor-4-methyl- Card t 2/9 CZECHOSLOVAKIA/Chemical Technology. Chemical H-18 Products and Their Applications. Pesticidese Abs Jour Ref Zhur-Khimlya, No 79 1959, 24569 pentene-2 (IV) of 78-830/30 mm and of 1.4800 nZOD is being formed. In the pre- sence of 2 mols of EDH (48 hours at 200) III yields a mixture containing 90 percent of IV (or also 1,193-trichlor-4-methylpen- tene-1) and 10 percent of 1 1-dichlor-3- ethoxy-4-methylpentene-1. 1he acetylation of 11111-trichlor-2-oxy-4-methylpentene 3 (Ref Zhur-Khimiya, 195?, 37259) while hea- ting with acetic anhydride in CqHgN (3 hours up to 1W) results in thb 6 per- cent yield of 1 1 1-trichlor-2 acetoxy-4- -methylpenteneA.i IV) of 980/10 mm boiling Card 1 3/9 CZECHOSLOVAKIA/Chemical Technology. Chemical H-18 Products dnd Their Applications. Pesticides* Abs Jour t Ref Zhur-kh1kniya, No 7, 1~599 24569 point and 1 4795 n2OD. Analogicallyq from a mixture 01 1,1,1-trichlor-2-oxy-4-methyl- pentene-3 and -piwtene-49 obtained through condensation of chloral and iso-butylene in accordance with-Callonge and Perro (Ref Zhur-Khimlya, 19559 26089;-19579 54285) forms a mixture of V and 111 1-trichlor-2- -acetoxy-4-methylpentene-4 (~I) with 89 per- cent yield. By introducing an ether solu- tion of V drop by drop (in the course of 3 hours) to the suspension of Zn dust In the boiling mixture of-ether and CH COCH 76 percent yield of ljl-dichlor-4Xevthy1penta- Card s 4/9 CZECHOSLOVAKWChemical Technology. Chemical H-18 Products and Their Applications. Imbicides. Abs Jour i Hof Zhur-lhimlya$ No 7t 1959t 24569 diene-1 3 (VII) of 165-1700/720 mm boi- ling poj~t, 105199 n2()Dj 1g- of 4.87 at 2Z mA is derived. Analollfally, by conducting the reduction of a mixture of V and VI, 62 percent yield of a mixture contai"!~g V11 and its unconjugated isomer (of 145 500/720 mm boiling point of a mix- ture 1*4798 n2OD) is obtainedq whichl iso- merized by heating for 1 hour with n-4olu- ene sulfohle acid up to 15009 results in 81 percent yie4d of vir. When mixture of 093 mols of V11 and 0,2 mols of diazoace- tic ester are added drop by drop In the Card 8 519 h -9A CZECHOSI.OVAKIA/Chemical Technology. Chemical H-18 Products and Their Applications. Pesticides. Abs Jour Ref Zhur-Khimiya, No 79 19599 24569 course of 4 hours to 0*5 g of Cu-dust hea- ted to 3.100, followed by filtering-9J the catalyst and subjecting the filtrate to fractional distillationg 17*52 g of a mix- ture containing ethyl esters of I& and Ib acids is obtainedl having 1~9-1200/15 mm boiling point and 1.4883 n , Purest sample of the mixture [with 130-1350/15 mm boiling point (bath temperature) and 1.4907 n2OD] is obtained after hydrolysis and esterification of the Ia and Ib mixtures (La Forge, F- Be Berthl, We F.9 J. org. Chem., 194.79 127 19~)- The purified mixture of esters (15.16 g) is Card 3 6/9 CZECHOSLOVAKIA/Chemical Technology. Chemical H-18 Products and Their Applications. Pesticides. Abs Jour s Ref Zhur-Khimiyaq No 79 19599 24569 heated for 4 hours at 1000 in 80 ml CRC00H and 15 ml of 20 percent HC1 (acid), f2lowed by pouring Into water extraction with petro- leum otherg fractionahon6 yielding 10.5 g of viscous oil that has 1 0-1100 /0o2 boiling point, which after mixing with 10 ml of n- hexane produces 7.46 g of Ia and Ib mixture of 60-650 malting point. By agitating 2.8 g of the preceeding mixture in 20 ml of he- xane 0.85 g of Ib having 95-96,50 melting Pali (from hexane) are obtained. From mo- ther liquors obtained after the separation of Ib, upon extended standing at -300, 0115 9 Card 8 1/9 czECHOSLOVAKIA/Chemical Tedhnology. Chemical H-18 Products and Their Applications* Pesticides Abs Jour i Ref Zhur-Xhimiyap No 7, 19599 24569 of Ia having 68-890 melting point (from Hexane) are derived. By heating 0,277 9 Ib with 1 ml SOC12,in 3 ml of n-hexane (I hour on a steam bath)v followed b dissolving of raw chloranhydride in K mi C R addition of Oe2 g Hy and 12 hours sMAing of the mixture 0 2 9 of a com- plex ester of Ib acid withli are obtai- ned with the boiling point of 140-150/092 mm and n2OD of 1,5274. In conducting com- parison tests of insecticidal activities of Ib ester and II as against that of al- letrine (on ordinary house flies), it has been established that substitution of mbthyl Card 1 8/9 CZECHOSLOvAKiA/chemical Technology. Chemical H-18 Products and Their Applications. Pesticides. Abs Jour Ref Zhur-Xhimiyal No 79 1959, 24569 groups in the side chain of the chrysanthe- Mic acid with chlorine atoms does not lead to changes in the insecticidal activity of a compound. Card 9/9 CZECHOSLOVAKIA/Chomical Technology. Chemical H-18 Products and Their Applications. Pesticideso Abs Jour i Ref Zhur-Khimiyaq No 7s 1959, 24570 Author :Farkast J*9 Kourim, P., Sorm, F. Inst :- Title :The Relationship between Chemical Structure and Industrial Activity of the Pyrethroid Compounds. 11. Analogues of Chrysanthemic Acid Containing Aryl Group. Orig Pub :Chem. listy, 19589 52, No 4, 695-706 Abstract :By the condensation of diazoacetic ester with the substituted derivation of styrol, 2-aryleyelopropane carbonic acids and the asters with alletrolon M are obtained. Card s1/12 CZECHOSLOVAKIA/Chemical Technology. Chemical H-18 Products and Their Applications. Pesticides. Abs Jour z Ref Zhur-Xhjmjya9 No 79 1959, 24570 In tho comparison of insecticidal activi- ties of these esters with those of alle- trenel it was established that the substi- tution of Iso-butylene in the chrysanthe- mic acid (11) for a phenyl group does not lead-to the lowering of its activity,, How- ever, its activity is lowered when the phe. nyl group Is being substituted. The presence of hemin CH -groups in the cyclopropane ring of II is G;iential from the standpoint of insecticidal activity, The most effective of all the esters obtained are (�)-trans-2-phe- nyl-33-dimethyloyclopropanecarbonic acid Card 1 2/12 CZECHOSLOVAKIA,/Chomioal Ttchnology. Chemical H-18 Products and Their Applications. Pesticides. Abs Jour t Rof Zhur-Xhimiyal No 7, 19599 24570 ester (trans-III) or its pravoratory anti- podes (trans- W -III) with I. The abso- lute configuration of trans-III has been proved* The following aromatic carbinols R R R 9 COH are obtained (using usual MIWOM from an aldehyde, ketone or com- pound ester and aryl or alkyl-MgArl or the corresponding Mg8l derivatives. Presen- ted ares R R2 R boiling point in 00/mm~ n2()D, yiell'in pe;Nnt* They arc: H, 005, C6H6 (rv) no/15 1 5262 9 66.; - CH3 I CH 9 benz7h 0/8, 1.669; 74; 02H5 C2H91 ~Gn- ZY1, 1 51159 1,5-165, 64; CH39 &'~' -Xylyl; Card 1 3/12 CZECHOSIDVAKIA/Chemical Technology. Chemical H-18 Products and Their Applications. Pesticides. Abs Jour Ref Zhur-KhImiyaq No 7Y 19591 24570 113/8 -1 5186 71- CH CH m-xylyl. 119/20, 1 e 53.4, ~,; 64 & 3n"Iy'l 1 IV f02/8 (melting polnP~~JA [sic] 19h29 73 b5-dinitrobenzoate-Wj molIg point of 1 3-1340)- CH3 CH n-chlorbenzyl (V-), 129/11 (340 meltinni'point)p -9 73 (30- 0).- -dinitrobenzoate V melting point 126-127 CH CH 2 4-dicilorobenzyl 135/101 1.5451, 7PI35Ainitrobenzoate, melting poiht 1160). The following derivatives of styrol RA - C6H4 e CH = C(R2)(R3) were obtained in thoj hours of boiling of the corresponding alcohol with 36 percent excess of acetic anhydride and 1 Card 1 4/12 CZBOHOSLOVAKIA/Chomic&3. Technology, Chomical H-18 Products 'aad Their Applications. Pesticides, Abs Jour : Ref Zhur-Xhimiyaq No 79 1959, 29570 percent H2804 (Method X)q or from the correspondinj alcohol in tho contact with Al 0 at 300-3200 (Method B)o Presented bZK4 are Rl, R 9 R boiling point in OC/ /Mm n2OD syntReBW method i 1d in-per- cent* Theyp ares H, Hp CH CA (h5 e71/15- - 165485, A. 5a-.H CH3 7016, 13387o Ai 82; Hj 1, lv.TB,l L/15 1.5189t "2"5&1 87/10' A 86. 8,- 1. �83 i A 84 - miCrIA k 4/3-7- 1.53129 Al 81; UH39 ~319 R941 W22 13332, A 88 (B 66); h-Cl CH3' CH3 162111 -A ~4; 214-4%21 123/15, 1.5593'9 is 99. Card 8 5/12 CZECHOSLOVAKIA/Chomical Technology, Chemical H-18 Products and Their Applications. Pesticides. Abs Jour : Rof Zhur-KhWyag No 7, 19599 24570 VI (n2OD = 1.5490) also obtained with 80 percent yield from allylbonzeno by hoating it with 1 p9rcent tort-butylate K up to 1 00 but V33 (n2VD = 1,5314) with 55 percent yiCIA by heating (1 hour) 1-methyl-3-mothallylben- zone with 1 purcont n-toluonosulfonic acid at 1600 temperature. 2-ar'loyclopropanecarbonic acids RlC6H4CHO(R2)(R 5CLHCOOH wore synthosi- zed when a mixturo o;10,2-0,3 mols of corre- sponding styrol derivative and Oel mols of diazoacetic estor wore added drop by drop to Oal mols of styrol derivative and 1 dust in the course of 6 hours at 120-MOCu Card 6/12 CZECHOSLOVAKWChomical Technology. Chemical H-18 Products and Thoir Applications. Postieldes. Abs Jour Ref Zhur-4himlyav No 79 19599 24570 with the subsequent heating for l/ hour at 15004 The mixture of corrospondi4 ethyl osters, .' Isolated by vacuum distillation is saponMed by boiling for 3 hours with 26 percent water-alcohol solution of NDH (50 percent excess). From the mixture of stereo- isomeric acids, after the addition of potro- loum, other, Thb corresponding cis-acid in crystalline form (notations of cis- and trans- refer to corresponding positions of R, ; C6H4 and COOH groups) is usually separated, he non-crystallizing mixtures are converted (by means of 3 hour heating with SOC12) into C06 Card j 7/12 CZECHOSLOVAKIA/Chomical Technology. Chemical H-18 Products and Their Applications. Posticides. Abs Jour Ref Zhur-Khimiya, No 79 1959y 24570 with the corre W nding chloranhydridos, or else by the interaction of those chloran-- hydrides with M solution in CHC13 at 009 into the corresRnding amides. All the cis- acids were recrystallized from C H6 + petro- leum other all the trans-acids from petrole- um ether. he following arylcyclopropano acids were obtained (given beloi,,i are R1, R'%21 yield in percent of the isomeric aciass, e - ting point in 00 of trans- and cis-isomers? boiling point in OC/mm of chloranhydrides of - cis- and trans- acids): H9 H, H VIII9 59 104, 92, (melting points of amides cis"hii Card 1 8/12 ,q- CZECHOSLOVILKIA/Chomical Technology. Chemical H-18 Products and Their Applications. Pesticides. Abs Jour : Rof Zhur-Khimiya, No 79 1959, 24570 and trans-VIII are 88-890 and 1890 molting point of-toluldido cis-VIII is 1746);-H H9 CH (IK) 50 114 77 59 H CHI, &3 (RI)o 8, 1J4, 162, !, 1;0 Uolt n9 points of amidos cis- and-trans-III are 98- 990-and 1410)- 2.!& -CH CH (X) 40 - 1267 -9 144/1?1' 3 ' ~A? Nb 92 ! -toi- ling ZU '2 122/~ (me'lting pointpoofinttoll3u5i'd/iodgeltragnsaI is-1.45-1470); 9 CH CH (XII) 62 142t 134~ irR~4; ~:41 3 M13 6A (1111) 46, 140-141- - 110/0.1; P.4-Clp. &1~7 M1 46t I 1 9 'H 174 (1)' 99 Eq C 2 5 ?iiv), Card 8 9/12 CZECHOSLOVAKU/Chomical Tcchnology. Chemical H-18 Products and Their Applications. Pesticides, Abs Jour : Rof Zhur-Khimiyal No 79 19597 24570 58, -1 96 -9 -0 When a mixture of solu- tions of ~ 5 g of trans-III in 50 ml of other and ~*2 g (-) ephedrin in 10 ml-of other are kept at 00 for 3 hours 5o85 (-)-ephodrin salt of trans.(+)-III of &0 meltinkgoint (from othy sodtate)9 C(X, ]2 of +00 (with 3,139 in C.,.,Ht;OH) are deri- ved* From mother liquors artor addition of 4.9 g (-)-ephedrin and after keeping at 00 for 5 hours (-)-ophedrin salt of trans- (-)-III of 130-1310 melting point (from ethylacetate)9 CC< ]20D - 38.80 (with 2.64 in C2H50H) is obtained. And from the decom- Card a 10/12 CZECHOSLOV,'LKLVChomical Technology. Chemical H-18 Product.s and Their Applications, Post1cides. Abs Jour : Rof Zhur-Khimiya, No 79 19599 24570 osition of salts vith 4 percent HM 'i acid) -were obtained free trans-W-III F of 84:950 melting. pointv C (-y_ ]20D + 31.90 (with 4 93 in C2H,;OH) and trans-(-)-III of ,~. ]20D ~- 32'20 84-85051 melting Point, [C (with 4 *85 in CAP). Esters of the pro- ceeding acids anti I are obtained with yields of approximately 50 percent in a mixture of C6H6 + C05N from I and chloranhydrido of corresponding acid when keeping a mixture for I hour at 00 and 12 hours at approxima- tely 200. After the usual treatment of a solutdion in C6H69 the raw ester is purified Card t 11/12 CZECHOSLOVILKIA/Chomical Technology. Chemical H-18 Products and Their Applications. Pesticides, Abs Jour i Ref Zhur-Khimiyaq No 79 19599 24570 with A120 and volatile fractions are re- moved by Reating to 780/0/1 mm for 8 hours, or by fractionation at 180-3.900/0/1 mme The following esters were synthesized (given be- low are initial acid and n2OD-of ester)s trans- -VIII 1 5517; trans-IX 105450- trans-III - 1,5381; ;rans-(+)-III L5371virans-C-)-11I 195378; cis-III - Xq- 1-.5369- XI 1 5392-2 trans-XII 1,53,95. X11I 1.5452; X!~, 1.5i55. For Part 1. aeo pr2ecoodLg abstract. Card t 12/12 FARKAS' J. Sulfate lignin. III. Elementary composition of functional group-S. P. 464. CM1ICKE ZVESTI. (Journal on applied chemistry issued by the Slovak Acadeqr of Sciences and the Slovak Chemical Society. Month1j). Bratislava, Czechoslovakia, Vol., 13, No. 7/8, July/Aug., 1959. Monthly List of East European Accessions, (ELAI), W, Vol. 8, No. 12, Dec. 1959. Uncl. SMEJKAL., J.; JONAS,, J.1 FARKAS, J. Dissociation constants of stersoisomere of c7clopropanebydrw7lic- acid pairs. Con Ca Chem 25 no.7:1746-1750 JI 160. (Ew 10: 9) 1. Abteilung far organische Syntbesen, Chemisebes Institut, Tsobecho- alowakinebe Akademie der Wiseensobaften, Prag. (Dissociation) (Cyclopropansearbozylie acid) --1%44S,- J. I_AOVAK, J. J. IK. Relation between the chemical otructure and inaecticidal activity in pyrethrold compounds. III.Analogue of allethrin vith the modified acid portion of the molecule. Coll CS Chem 25 no.7:1815-1823 J1 160. (MI lOt9) 1. Abteilung fur orgaulache Syntheses, Chemisehes Institatp Tschedbo- slowakisebe Akademis der Viessmachaften, Prag. (Pyrotbroide) (Allgtbrin) FARKAS, J.) KOMOVA, H.j KRUPICKA, J.; NOVAK, J.J.K. Relation between the chemical structure and insecticidal actiTity in pyrethrold compounds. IV.Iffect of the subetituent of the elft chain In the process of the laforge cyclization. Coll Cz Chem 25- xo.~31824,4836 JI 160. (IM 10:9) 1. Ibtailung fur organische Synthesen, Chesisches Inatitut, Tschecho- slowakische Akad*aio der Vieseamahaften, Prag. A A, (Pyrethroids) (Ring closure) NOVAK, J.J.K.; FARKAS, J.; SCRM, F. Relationship between chemical structure and insecticidal action in the series of pyrethroide substances. Part 5: A synthesis of trans-2p 2-dichloio-3-phenylcyclorpropaw-carboxylic acid and its allylrethronyl'eater. Coll Cz Chem 26 no.8:2090-2092 161. 1. Inatitut of Organic Chemistry and Biochemistry., Czechoslovak Academy of Sciences, Prague. FAWW I Jo;3ef; KISS, Istvan r-- Technical and economic aspects of food preseriation by radiation. Elalm ipar 16 no.l.-I-8 Ja 162. 1. Kozponti 1~lelmiszeripari Kutato Intezet. CZECHOSLOVAKIA SjwTEJKALt J; FARKASp J. Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Science, Prague (for all) Prague I Collection of Czechoslovak Chemical Communications, No 5, 19639 pp 1345-177- "Derivatives of 1-desoxy-D-Psicose.11 CZECHOSLOVAKIA HORAK , M; SMEJKAL) J; ZAMS L J. Institute of Organic Chemistry and Biochemistry of the Czechoslovak Academy of Sciences, Prague (for all) Prague, Collection of Czechoslovak Chemical Communications, No 9, 1963) pp 2280--2292 "Infrared Spectra of Compounds Containing a Cyclopropane it Ring. ja rT of ths and ca-7 A -WAY X,3. of 70 ;j,. .0 -1 b ,~z 0 xv, Silbatituted C-clopro-paW 44 SWJKa, J.;. FARKASp J. AIIMMI course of elimination reactions in the series of pkipayloyclopropene derivatives* Coll Cz Chem 28 no.2:404P-410 F'. 1630 1. Institute_of Organic Chemistry and Biochemistry, Czechoslovak Adademy of Sciences, Prague. SWUL, J.; FIRKAS, J. Stereoisomeric traWornatiow of 2-oubatituted oyclopropanneerbazy3la acidso Coll Cz Chwa 28 no.2:481-486 F 163. lo Institute of Organic Chemistry and Biochemistry, Gsechoslovak Acadwq of Sciences. FARKA5, J; �ORM, F. Czechoslovakia Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Science -- Prague - (for all) Prague, Collection of 2zechoslovak Chemical Communications, 4;. 4 No 4t 1963, pp bu-bub "Nucleic Acid Components and Their Analogues* XXX. The Synthesis of Poicofuranine," SIERAL, J.; FARKASP J. Hydrogenolytic cleavage of cyclopropane ring-Aw-Ahe series of substituted oyclopropane carboxylic acids. Coll Cz Chem 28 no.6tl557-1568 Jo 163. 1. Institute of Organic Chemistry and Biochemistry, Czechoslavak Academy of Sciencesp Prague. SMEJKAL, J.; FARKAS, J. - ~ - ---'~% v- - Derivativeo of 1-desoxy-D-pisicons. Coll Cz Chem 28 no. 5: 1345-1347 MY 163. 1. Institut fur organische Chemie und Biochemie, Tachechoslowa- kische kkademis do Wissenschaften, Prag. FARKAS,, J.; SORM, F. Synthesis of 5-bis-(Vehlorethy.1) eminomathyluridine. Col-1 Cz Chem 28 no.61l620-1622 Je 163. 1. Institute of Organic Uhamistry and Biochemistry, Czechoslovak Academ.v of Sciences, Prague. 11ORAK, M.1 SMEJKAL, J.; FARKAS, J. Infrared spectra of compounds contalhing a cyclopropane rinig. Coll Cz Chou 28 no.9z2280-2294 S 163. 1. Institute of Organic Cheniary and Biochemistry, Czecboslo- vae Academy of Saineces. Prague. PRYSTAS,M.; FARKAS,J.; SCRMsF. Synthesis of the arlomeric uracil and thymine 2-deoxyribosyl derivatives by the Hilbert-Johnson method. Coll Cz Cbem 28 no.110140-3143 V263. 1. Institute of Organic Chemistry and Biochemistry, Czecho- slovak Academy of Sciences, Prague. TQIA'~~ J.) j. The HaTmett 6 QnvtarAi for the cyn.loi:ropY2 group; I,- ar,,I benzoic acids. Coll Cz Cherr. 29 no.12:2950-2955 1) 16 49 1. Institute of Organic Che,iinty-y awli cf the rze'-~:oqlovak Academy of Sciences, Prague.. 2. Board Yember, of Cz6chasI(wak Cheadc&l Comw,mlra'lons" (Z"or Jora,0. TtM t V Ri -N FWKNSJ.-3. NSKU" Jf moommiefts, Comm*"" AM&W at ftift~~Do ftMPW - OW 411) twooloo ad ik.-.-16 SKIMMUSO 1b 1* inow W 30640Y md "m& OWASONW. rwo T44 use st CZSCHOSLOVAKIA FARM& Jj 30HN9 F Instltut* of OrgaMo OmIstry and Dloabu~a stryo Gseahoslov*k Aosdamy of Solenessm Pngu* - (for both) PMUOO 28118011211 a g8$Gk2-'Mk L"WIll 292ML- ASUAM 30 3o Maraft IL966a VP J-415-1414 "Nualole aeld 0 mid their amdoomeso Part 7% Synthesis of ahloroo2*-f]Luar4odiethylamdzmwtVI) uracn,u GUMOILOVAUA BUM& XI FARK" 30RM# P Inst1tas of 0 cbes"try ma BI Cxoabofa*Vak A or selon"s. Fftem all) =a*" vp OCIal"tiew of hexuleamle sold Pdoomleartazome to 5woubstitut" "sauman derivativ",* FARKAS, J. Investigations into the radiation resistance (if Tribolium confusum (Duval) and Tyrophagus dimidiatus (Hermann). Acta biol. acad. sci. Hung. 16 no-3:207-215 166. The effect of hydrature in foodstuffs on the reproduction of some pests and mites damaging stared products. Ibid.-217-225 1. Central Food Research Institutep Budapest (Head: G. Torok). Submitted February 23, 1965. FARKAS, Industrial uso of oaxpeo, Blot tad 16 oo.49:.1548-3.551 3 D 161, 0 a FARKAS,,Jozef, inz..,C.Sc. Time and temperature in sulfate cooking. Sbor eel pap 6:177-196 161 -n FARKAS, Jozef, inz., CSC. Sulfate process for production of high-yield pulr. Papir a calulosa 18 no,7:137-140 JI 163. 1. Vyskumny ustav papieru a ce:Lulozyj, Bratislava. FARKAS, Jozef, inz., CSc. Rreimprepation of vood shipa as a acmponent of the high- yield sulfate pulping process. Papir a celulosa 18 no.8tl56- 160 Agt63. 1. Vyzkumny ustav papleru a celulozy, Bratislava. 0 XM-1W,7rx.6G3548O SOURCE CODE: HU/0028/66/013/oul/OU35/ A12ZFAC T ---- P and AMMM, Central Food Research in Budapest (Directorl original-language version not give 1-TIMOK, 0 "Reduction of Beat and Radiation Res Latance of Bacillus Cereus~spores by Initiating qermination" Budapest, is; p4ptirm.Hunpospp, Vol 13,, AcAa McW~JRIoSiga Acgoem 7 No .1, 2 iun~'1966; AbsrraSt: (English article) The effect and practical applicability of known g'a-r--m7fdation-initiating aigenta,,such as d-glucosep 1-alanine,. adenosine,, com-! .binations of these., and wild beating, to reduce the resistance of BacWux Ce I _f rVA spores to heat and radiation has been investigated.-Best resA i VeRle' abbiaved if the additive and beating (30%) vere employed in conjunc- !tion. The technique causes relatively little damage to foodstuffs, The spores that-were induced to germinate become less resistant even when they 8 figures, 2 formulas and 1 t ai-e pre senCin high counts Or1j'.- art. has:- able., 1JPRS: 36p8j4] TOPIC TAGSi radiatIion biologic effeetp food technology,, heat biologic effe STJ13CODE:"06 SUBKDATE: 270ot65 MIGREF: CTH REF: 033 r 005 Cord r,,, S Hungary/Analytical Chemistry Analysis of Inorganic Substances, G-2 Abst Journal: Referat Zhur Khimiya, No 19, 1956, U871 Author: Farkas, Joszqf Institution: None Title: Rapid Analysis Method for Limestone and Dolomite Original Periodicalt Meszko es dolomit gyorselemzese. kohasz. lapok, 1956, 11, No 1, 11-13; Hungarian; German resumif Abstract: CaO and MgO content of limestones and dolomites is determined by titration vith Complexon III. Iron is determined by photometry of the salicylate at pH 2-5- Card 1/1 F. T FOCZE, L. Research on ranid detemination of the basicity of ;.*:-,.rt-n slag in an aqueous slar, susi-.ension. p. 254 (Fohaszati Lapok. Bud;;pest Vol.. 11, nzo. 6, Iune 1056 Kohas-zati Larok. Vol. 9 (i.e. 11) no. 6) SO - l,,onthl-,, Lj.st of East European Acce9sions (FEAL) LC. , Vol. ~, no. 7, JUIY 1957 T!ncl. FIRKASp Jozsefo adjunktus A new method for determining the fatigue limit of welded jointse Gap 12 no.1:35-36 A 160. 1. Nahesipari NuwWd Egyetem Ssallitoberandevemok Trans sakep Miskolc. FARKAS, Jozoef Camplexcmetric determination of copper and zinc. Koh lap 93 no.9: 427-429 S 160. 1. Air-A Vasmu Kosponti Laboratorium. FABIM, Jozefj, inze Elastic and plastic loading ~ imi t of a welded joint under general load. I-va~ abor 10 no,2:229-234 861, le Odborny asiatents Vysoka skola tazkebo priemyslu., Miskolc. PIRISI, Ferenc; FAELKAS, Tozs,!.^ Maintenance of norms at the enterprises of the Csepel Iron and Metal Works. Munka szeralp. 6 no.12:1.3-11? D 162. ()()0/004/00 0 -roo velaed A 142 T It lopIll. e joT t U69 SeT j e PIMPW -rxjc e ~106 , %,ects ell 0% la JUL ti ylo a 4 & Yj"1-4e.,.dvj st.;,01150 ~acto.rl 0a -re -lees r 1,0 . -rec e c c by aLesc tT tvio CO -t CTS t Of to IaLed c ble vie e 0v I CO' rlte. ,re -Da De Ole ,,,Se(I CeS D. If e Owto utes tellaLi:1% 0,, 6106e 0 06-fd vie tto cof~' Tyje~ eY. dl)l e G %86teT 96'r t3 0 t1IT e TIbe ~ lao 0~ of e t11 e -,,.peT' e e e e4 &eT mile us'IT st-rNIC tea bj ,3%l, eT .1160 Ty~e %e Oae ~o Guild olde 00 C se OT Tr~e aw 01 ~.011 .0 s e r,.ag,9 te & is S WIG te'O 'rel 0 e -re tyle tyke 9 0-4 C e vie 01, 6 ud -re-40a 0 4 e 0 -bled 10 tjNe 9 Ided. t 6 S%al- t G -r e Ile t of .',d re .0%,906. eTLtIG tjje -to .01je% ,YL06 I ~:a6 , esi-611 colIG 9110 OXIS OTS, -fle'q' itIOLS, ,se -t'lr,e to 0 OUS elr~ lute tA,10 bo ttova HIOI116210001004AO21002 Novel welded vertical cylindrical ... D249/D301 ments. These movements occurred frequently due to changes of tem- perature and pressure of the li:quid, In the new desion a flat steel raesh (80 mm x 8 mm) is laid on a concrete base plate. Sheet plates (6 m x 3 n) are welded to the mesh. Construction of the sides is identical In the old and new designs. Due to the danger of corro- sion, roof plates of 4 mm thickness were used. As a result of the roof design these plates take a considerable part in carrying the load. The design and construction of the roof, and experiences in the production are described. The boundary tension cr, = 1950 kp./cm2, safety factor for the load of snow and earth, n = 1.1. The value taken for the load of snow is 80 kp/m2o Apart from the load symmetrical to the axis# an asymmetric load of snow was consideredf with a peak value of 100 kp/m2. The considered value for the Ind of earthp assumine damp loose sand was 15 cm. 1.7 jjp/m3 = 225 kp/m . Tensions on the roof construction were calculated only by the use of approximations. The nominal volumVs of the containers designed' are 100, 200, 3009 500, 1000, 2000 m2. There are 7 figures, 1 table and 6 references: I Soviet-bloc-and 5 non-Soviet-bloc. Card 2/3 z