SCIENTIFIC ABSTRACT DOROGAYA, Z.I. - DORCGOCHINSKIY,A.Z.
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CIA-RDP86-00513R000411010015-8
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RIF
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S
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100
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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KALKiIIIIIK, I.A., dnktor voterin.ruiuk; IXAJUGAYA, Z.I., vntorllULrW vrach.
Influence of tissue extracts on the reactivity of anitnal organ-
Inme. Voterinartla 36 no.6:57-60 Je 159- 04IRA 12:10)
1. Ilartkovskly vaterinarnyy lastitut.
(Tissue extratte)
XALAMIX, I. A.~ PEREDERAI n. Ya., BOUMV, V. 1. tall DOIA)GAYA) 2,. 1.
11 Conserved blood of animals in the biogen atimulator dwing hog fattening."
VeterInariya Vol. 37, Ho- 3, 196o., p. lo
",u p - Vd- Dr.
K kL,~ ktc, V d- - 55~., f -
KALASHNIK, I.A., doktor veter.nauk; PEREDERA, B.Ya., kand.veter.nauk;
BOZHKO, V.I., kand.veter. nauk; DOROGAYA, Z.I,, veterinarnyy vrach
- f-1_1 - '
Conserved animal blood is a biogenic stimulator in swine fattening.
Veterinariia 37 n(;.3:70-72 Mr 160. (imu 16:b)
1. Kh,trtkovskiy veterinarnyj Institut.
(Blood as food or medicine)
(Swine--Feeding and feeding stuffs)
4-6
V 9
A'j -I-AO-1-JIL-L"Al-as rw- f-1 I 1- 110
fit A-0 if* t-dipfel
RSPVO#Wg 00 RPONAMMID HOP AU1 UPCAYUPUQeN"
"men 0 NOPOOTPawsm y Mae Pm Kar4ulL IIWAM-
lima to Zt1sullom Safi perswis working With Polaw variedird
its rellanj to the immoures to Im, taken for the preventimi of
the Intniduct"t smiat I in our ct'untly I tile Potato wart
viii, 2. lip, b7 -1)), 3 OKA, 1931.
Aftw givissig a very brief defecrilition of tLe niorpholivy slual
I
biology of Hy"CAJOrivIlt aft&6i'dieups 1which i0i stafteil to IV No
far aboang from the Union of Soviet Republics)), the author givea goo
A 0
Of
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1. appecially f.
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00 (kM&My' Isis poinw out that some of tho - resistant'varistito.
so 04-- JU141, Originstillf fMm that country are pwrtkularly.1s row
insamuch sis they I*iu*nUy bear imsil, 1WxWplCUoUqn=".
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StOP4 Should ImUmliately be taken for its complete eradication.
00 including &W thorough MOM-41 frctB the soil of all pa_rU of the
00 14ftaftl ]plant* and their destructhm by Are, the isolation of the
of 1"fretiOn NO with 0 UMWOn not under 2 m. all #^MnJ, tire disin-
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Subject USSR/Engineering
Card 1/1
Author Dorogin, P. Ya.
Title Stock protective barrier for "at type hoiats
Periodical Sbor. mat. o nov. tekh. v stroi., 3, 14-15, 1954
Abstract Movable protective barriers for mast type hoists are
described. They are of two types: one tubular, the
other, a fence of wooden boards. 2 graphs show details.
Institution : None
Submitted : No date
DGRCGIN'411) 11. 1.
ECKCGIVIN, V. I.-. "Hydroeloctric power station aggregAes as L.-enerators
of reactive power." Min Higher -Education USSF.. ~~Oscow
Order or Lenin Power Enginecring Inst iv.eni V. E.
Molotov. Moscow, 1956
(Dissertation for the Degree of Candidate In Technical
Science-s)
So: Knizhnayu Letopiol, 1,-'0, 18, 1956
DOROGI kand. takhno nauk
JIL
Use of the gererators of hydroelectrio power stations as
"nchroncrue c(Openilatord. Elek. sta. 34 no.7143-46 JI 163.
(MIRA 16:8)
rN,
TELEZILLINKO, V.P.; q(IRSHENIN, Yu.V.; DOROGINITSKAYA, L.M.
Dynamic characteristics of seismic recordings in tLe case of wedge-
shaped layeris batied on modeling data. Trudy SMIGODIS no.27:95-121
162* Oju 16:9)
1. Sibirokiy nau..-hno-iseledovatel'skiy institut geologii, geofiziki
i minerallnogo syrIya,
(Wext Siberian Plain-Seismic prospecting)
DOROGINITSKAYA, L.M.1 TELFMHFYKOp V*P.; FROLOVAt L. A.
Experimental study of the reflection coefficient and propagation
velocities of elastic vayes in fluid-caturated porous media.
Trudy SNIXGGIMS no. 3008-110 1 64 (MIRA 19:1)
.) 0 1 .3 *; C) ,,~ t j-, , A . .",
Tne Distribution of tension of an orthotropic plate with a circular openirl~ with
pure :;,iear. "Inzhinernyy --J~bornikl' ;Lcadwy of icience of t~ie U:I~SA
ely
,~er,art.,,-ierit o*-' .-I*ciew;es, Lnstitute of Ilechanics.
].0- "
DOROGOMM.Aoso (Leningrad)
Pure shear-induced stress distribution in an orthotropic plate
with a circular aperture. Inzh.sbor. no.21:113-119 '55.
(Strains and stresses) (HLRA 8:11)
IF7
621 0
Wt=leq,~'RUERTI FS OF CUM ni VF
d )-VIno -K400-fr DUV~Cb1d G.M. KNI, I.E.. -QJ~ !~~C7,
T
1955. (2),*+a-,- ft"Y". Is er ~ ( li
full 4"Calu Imly of tha 4jtfoM;M or bOWIng cLnd mixtre on ;ha cia;Conal (If
mainly ash (Kctorki Ot cm'~ ehwgr4 rMoc-dlmg to Ockc ~,'v AVI,
~F %)At
til'i Prol f Z~;;~co In all nm plwra Is ;rZr.,d. Micro ji,j
tho coal dcio not pass throujM cko boMina sym~am ic la stag"ti-4 ut two
alaula bo alklod III Cormt4n; proporr.1m frm acramto bwgurs.
A ri yy PJ -~j
C, r" 1-0 1 Pj AT
AYCKIN. T.B.; BURTSEV, K.I.; BYSTILOY, S.N.; VIMS, G.B.; VCDNEV, G.G.; VORCYIN.
A.S.; GEVLICH, A,S.; GRYAZNOV, H.S.; GUDIM, A.F.; GUSTATINSKIT, N.A.;
DVCIIIN, B.S.; DrDHHX0, V.Te.; DMIITRrM, N.H.; DCIMZ, N.H.;
G.M.; ZHDANOV. G.1.; ZAGCIRULIKO. A.1.; ZELXWSKIY, A.G.; IVASHCHMO.
a". ..- KAYTAN. S.I.-. IVASHA, A.S.: K=Yff, A.D.; )MISHNVSrIT, G.S.;
KOZYMN, V.P.; KOLOBOV, V.N.; IDAIM, K.I.; INYTHS, V.A.; LWUM, B.Z.;
LOBCDAI H.S.; LUBDWS. I.A.; MARMTKIN, I.I.; MUSTAP0, P.A.; NIMIROVSKIT,
N.Mi.; NM9M, V.A.; 03MOVSKIT, U.M.. P3W-SXV, M.A.; PETROV, I.D.;
PODCROZHANSKIY. H.0,; POPOV, A.P.; RAK, A.I.; REVYAKIN, A.A.; ROZRKov. -
A.P.; ROUNGAtM, D.A.; SAZCKOV, S.A.; SIGALOV, M.B.; STOKAIRIM. Ta.B.;
TARASOV, S.A.; FILn'M, B.S.; PRIDNAN, N.K.; FRISHMG, V.D.; XMIKOV-
SKIT, X.V.; KHOUPTSIff, V.P.; TSARNV. M.N.; TSOGLIN, MON.; CHMIZ, I.I.
CHMOK, V.T.; SHWZCN, A.K.
Samuil Berisovich Bame.Koks i khim.ne.6:64 156. (Km 9:10)
(Bamme, Samidil Bertsevich, 1910-1956)
-b 0 R o I D
Gr. N
.1-8(5) PHASE I BOOK EXPD914TATION SO11/1247
Dostizheniya domenshchikov Magni-'-.--ogorskogo metallurgicheskogo kombinata
(Achievements of Blast Ftu~rsce Operators of the Magnitogorsk
Metallurgical Comb-ine) Moscow, Metallurgizdat, 1957. 279 p.
3,000 copies prtnted.
Ed.: Bannykh, A.I., Professor; Ed of Publishing House: Yablonskaya,
L.V.; Tech. Ed.; Attopovich, M.K.
PURPOSE: This book Is intended for engineers, foundry foremen, and
personnel in research institutes. It may also be useful to students
and othe::-s interested In foundry prantice.
COVERAGE: This book deals with achievements of the foundries of the
Magnitogorsk, Metallurgical Combine. The processes of preparing
the charge, melting and pouring are described. Improvements In
foundry methods and the theory behifid these improvements ate.presented
with numerous graphs and illustrations. ~The book is the combined .
effortr6f the following authors: Foreword: Bann-kh, A.M.. (editor);
Introductlon., parts 1 and 2: Bannykh, A.M.; peirt, 3 by
Card 1/6
-Achievements of Blast Furnace Operators (,;ont.) SCV/1247
Stefanovich, M.A.; Chapter I, part 1 b-ir Dorr cbid G.M.; part 2
Part 3 by Yakobeo- _~ _? pter If, Part 1,
by Shitov, I.S.; 41 . ~h a p ~te r'~
A.F.;
2, and 3 by Galatonov, A,L.; Pam 4 by Banny1ch, A.M. and Nayasov,
A.G.; Chapter Ill., aalatob.-.~v, A.I,. and GolchirtJ V.I.: Chapter
IV, parts 1,2,3,4,5 and 6 by Gala-',onov, A.L.; pat by Stefanovich,
M.A,; Chapter V by Stefanov~.-,!h, M.A.; Chapter VI by Babarykin, N.N.;
Chapter VII by Shastin, V.A.; Chapter VIII by Gorriostayev, V.K.
There are 51 references, of which 43 are Soviet, and 8 are English.
TABLE OF CONTENTS:
Foreword
5
Introduntion. 1. Brief description of a blast" furna(,~e 7
2. Results of technical and economIc ach:evements c-f the
blast furnace shop,, 195(-- to 1955 8
Card 2/6
Achievements of Blast Furnace Operatrrs (cont.) SOV/1247
3. The nature of processes in a blast furnace 16
Ch. I. Preparation of Raw Material and Fuel for Blast Furnace
Operation 36
1. Method of coking 36
2. Blending of ore 68
3. Agglomerate plants and prepara'v',ion of agglomerate 79
Ch. II. Flux.-bearing Agglomerate 87
1. The use of flux-bearing agglomerate in the charge of a
blast furnace 87
2. Quality of highly basic flux-bearing agglomerate 91
3. Resulto of blast furnace performace with flux-bearing
agglome-rate 92
4. Theoretical principles and reasons for using flux-bearing
agglomorate 97
Card 3/6
Achievements o:*.' Blast Furnace Operators (Cont.) SOV/1247
Ch. III. Elimination of Manganese Additives from the Charge
and -the Production of Low Manganese Cast Iron 113
1. Productivity of the blast furnace and coke requirements 115
2. Quality of pig iron 117
3. Economic results 126
Ch. IV. Increased Pressure of Blast Furnace Gas 128
1. Application of increased top pressure 128
2. Plan for a changing over of blast furnaces to increased
top pressure 129
3. Operation of blast furnaces with increased top pressure 134
4. Control and measuring instrinents and their readings .137
5- Special features in the operation of blast furnaces with
increased top pressure 140
6. Changes in the distribution of the charge materials in
the stack 142
7. Theoretical principles of blast furnace operation with
increased top pressure 146
Card 4/6
Achievements of Blast Furnace Operators (Cont.) S011/1247
Ch. V. Application of Blowing With Increased and Controlled
Amounts of Moisture and Increased Heat (Temperatare) 175
1. The role of hydrogen and water vapors in blaet furnaces 175
2. Results of using blowing with variable arnount of moisture 182
3. Direction of changes in moisture content (from normal t6
optimum) 191
4. The importance of high temperature blowing In relation to
changes in the blast furnace prricesses 193
Ch. VI. Controlling Blast Furna,,e Operations From the Top 210
1. Analysio of motion and distribution of charge material3
in the otack 212
2. Characteristics of the basic principles in controlling
blast furnace operatioxs from the top 229
3. The use of principles of controlling the blast furnace from
the top for the elimination of certain troubles In the
functioning of blast furnace 237
Card 5/6
Achievements of Blast Furnace Operators (Cont..) SOV/1247
Ch. VII. Constructional Improvements of Blast; Furnace Shop
Equipme.-,rit 248
1. -Lodd Ing-. arrangement for blaer, furnacas 248
2. Receiving hopper 250
3. Hot air duct equipment 255
4. -Arrangement, for removal of melt products 26l
5- Ovethaul of blast furnaces 261
Ch. VIII. The Role of the-Blast Pirnace Foraynan 266
1.. The Magnitogorsk school for fr4remnr. 266
2. Foreman -- a blast furnace technologist 267
3. Foreman as the organizer of work at a blast furnace 2;74
'4. TTnifom wojiking-vnethods for the various shifts 276
AVAILABLE: Library of Congress
GOlksv
3-10-59
Card 6/6
AUTHORS: Varshavskiyt T.P.,
Shevc1aenkog N.S.
TITLE: Smokeless Charging
koksovykh pechey)
PERIODICAL: Koks i Xhimiya,
"OV/68-59--6-7/25
Dorogobid, G.M., Seppar, A.M. and
of Coke Ovens (Bezdyinnaya, zagruzka
1959, Nr 67 pp 2_~+-31 (USSR)
I
ABSTRACT: In 1955 VUKhIN developed a method of smokeless charging
of coke ovans with two collecting mains. The basic
deficiency of the method was a decrease in the weight of
the charge and an increase in the ash content of tar due
to carry over of the coal dust during steam injection.
In 1957-58 VUKhIN in co-operation with the Magnitogorsk
Metallurgical Combine investigated various methods of
charging ovens in order to improve the technology of
charging. The main attention was directed towards
decreasing the amount of dust carried over into the
collecting mains. The characteristic features of the
methods tested are shown in Table 1 zmdthe dependence of
concentration of dust in the gas in ascension pipes on
the moisture content and the content of particles belov
50 p in the blend in Fig 1. The best results were
Card li2 obtbLint3d when charging was cairled out In two stages;
Smokeless Charging of Coke Ovens SOV168.-59..6-7125
first through two outside holes simultaneously or in turn
charging 12.9 tons (without levelling) and then after
15 - 25 minutes, through the middle ho I a (3-3 t) and
levelling. Under these conditions the carry over of
dust into the collecting mains was the lowest (9.85 - 11.8
kg/oven). The method can be used at; a moisture content
up to 7.5% and with the inje(-tion of steam a(:cording trj
the VUKhIN-MMK scheme (Fig 6). The use of vibrating
filter screens for the removal of susponded matter from
tar was tested with satisfactory results (no details) and
will be incorporated into the operation practice on the
MMK plant. Continuation of the work on the smokeless
Card 2/2 charging of coal blends with a moisture !:!ontent. abo;ra
is recommended.
There are 6 figures, 5 tables
ASSOCIATION: Y-agnitogorsic-ty Meta-llurgiQheskiy Kombinat
(Magnitogorsk Metallurgical C,Dmbine)
Seppar a:--d
% .
DOROGOPID, G.M.
'I
Cokr-. c?,emlcal engineers of Magnitka are strivinF for t,~&nichl pro
roes. I;oks i f~dm. no-9:3-8 161. (VIII(A 3.5;T
1. Magnitogorskly metallurgicherkiy kombinat.
I (Magnitogorsk--Coke induEtry)
KROLI, V.L.; _ROROGOE3ID - PRAZD,,,IKOVA, V.A.
___ -G."
Effe4t of the aJdition of mazut on the quality of coking products.
Xoks i khim. no.9:12-16 161. (MIRA 1.~:I)
1. Magnitogorskiy metallurEicheskiy kombinat.
(Magnitogorsk--Coke industry--By-products) (Mazut)
DOROGOBIO, G.M.; KADUKKVICH, R.V.
New equipment far the coke and coal chemicals production in the
Magnitogorsk Metal-lurgical Combine. Koks i khim. n0.6:53-56 163.
MRA 16:9)
1. Magnitogorski:r metallurgicheakiy kombinat (for Dorogobid).
2. GosudarstyeMry institut po proyektiroywdyu predpriyatiy
I.oksokhimichasko,r promyshlennosti (forr Mordukhovich) -
(MagnitogorSK-4oke ind--ietry-Equipment and supplies)
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5o6o. DavoaNATiom or umaAmATED HrxtocAwNs IN THF, auTAxb;-
BUMM,YRACTION BY ABSORMOM IN BRMIKS WATER. Dorojochinaldij,
A. 2, Iyuter, A. V. and Musnikovap D, M. (Azarbiidshanskoe Neftyanoo
Rhos.: 1947# 21, No.3, 13-181 Chem. Abstr. 1947, Al, 5818).
water is beat
The ahearption of unsaturated hydrocarbons by Br2
when the reagent Is fresh although the results are amlly too
high. If the saturatedi agueous colution of Br is trested with
KBr, the usefulAsso of the reagent Is evtonded. In most oases a
solution sisturated with Br and 30% satunitod with KBv is to be
recommended. The results are vithin 1-1,3S of the truth. Isobutax
does-not affect the results, but 5% of pentanes causes erros of about
5%.
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10,41 0 4119 0 0 0 0 0 0 0 0 0 Is Is 0 0 0 0 0 0 01 0 0 0 0 0 41 0 0 * 0 0 0 0 i 0 a
40 Tdo 1.00 0 0 0 0 0 41 0 0 a *;* 0 0 0 0 0 0 0 * Is 0 00.00.000
DOROGOOHINSKIY, A.Z.; )MLIMEDVA, N.P.; SXUMZADOVA, I.A.
Douterium-bydrogen exchange of song bydroearbons on alumino silicate
oestalysts In cracking. Probl. kin. I kat, 9:162-167 '57.(MIU 1113)
(Catalysts) (Hydrogen-laotopes) (Cracking process)
39-4-5-15/26
AUTHORS - Y)t1okhin, B. Z., Dorogochinskiy, A. Z., Meltnikova, It. P.
TITLE: A Radiometric Method of Control of Interfaces Between
Different Varieties of Petroleum Producte Pumqed Throug~ A Single
Pipeline (Radiometrichookiy metod kontrolya pooletiovateilnykh
perekachek razlichnykh.sortov nefteproduktov po odnomu
magistrallnomu truboprovodu)
PERIODICAL: Atomnaya Energiya, 1958, Vol. 4, Hr 5,
PP. 475 - 477 (USSR)
ABSTRACT: If the oil transport from the fields to the place of ship-
ment is carried out by way of a single pipeline and if, for
example, gasoline, crude oil and diesel oil are sent through
in direct succession it is especi"lly import.1-nt to know the
interfaces between the transported products. If the time of
arrival of one product at the place of shipment is exactly
known a very economic working can be achieved by due regulation
of the brnneh lines to the varicous reservoirs.
In the GrozNII the following method has been
Card 1/2 elaborated:At Ine same time when at the starting point of the
09-4-5-15/26
A Ardiometric Method of Control of Interfaces Between Different Varieties
of Petroleum Products Pumped Through a Single Pipeline
pipeline another oil product is cent throuCh, a radio-active
liquid in added to this oil. At the place of arrival, i.e.
at the pumping stations,it in recorded when the naximum in-
tensity is reached. Thin is then the sign for the due and
economic switching over.
Thin method has been tried at a 086 km lonr,- pipeline and
proved to be very nuccecefull. 124
Triphenylstibine which contains ra,,Iio-active Sb served
as indicator. There are 2 fiCures.
SUBMITTED: August 1, 1957
AVAILADLE; Library of Congrean
1. Radioactive substances-4pplicetions 2. PipolUes-4peration
Card 2/2
5(3)
AUTHORS: Kozorezovq Yu. I., Dorogochinskiy, A. Z. SOV/2o-123-5-24/50
TITLE: Alkylation of Toluene by C 0 Olefines in the Presence of
Sulphurio Acid (Bernokinloinoye alkilirovaniye toluola ole-
finami C 10)
PERIODICAL: Doklady Akademii nauk SSSR, 1958, Vol 123, Nr 5,
pp 857 - 859 (USSR)
ABSTRACT: In the production of the most commonly ufied synthetic detergents-
the alkyl-aryl sulfonates - benzene, as a possible deficient
item, should be replaced ty other aromatic hydrocarbons, in
particular by toluene. No informations has been published on
the effects of various factors on the intensity of the course
of the reaction of the toluene alkylation by C 10 olefines in
the presence of sulfuric acid. Of late it has been proved that
high-molecular olefines (preponderantly C 10) can be obtained
from the polymerization with phosphoric acid of the amylenes
from the C 5 fraction of thermal cracking. Therefore, in the
present paper the reactior, mentioned in the title was studied
Card 1/3 with the polymerization products of the pentane-amylen*
Alkylation of Toluene by C 10 Olefines in -the Presence of SOY/20-123-5-24/50
Sulphuric Acid
fraction. Chemically pure sulfuric acid was used as a cata-
lyst. A description of the laboratory equipment used is given.
Numerous experiments with the fraction of the amylene dimers
(boiling point 125 - 1750) and for the purpose of an ex-
planation of the effect exeited by the following factors were
conducted: a) concentration of the initial acid, b) duration
and temperature of the reaction, a) molar ratio of the olefines
with regard to toluene, and d) relation of the acid to the
hydrocarbons. The resultis are nummarized in table 1. Thus,
the following optimum conditlons could be indicated, which
secure the highest possible yield of alkyl products; cioncentra-
tion of the initial acid 95 -- 97_p7rocent by weight calculated
for monohydrate; temperature 10 5 , duration of the reaction
30 - 40 minutes, molar ratio of olefinee to toluene
1:4 - 1:6, proportion by volume of the acid to the bydrooarbona
0.12. Under these conditions, the yield of the alkyl product
amounts to 140 - 143 per cent by weight calculated for the
initial olefines. The formerly (Refs 5-8) dreaded significant
depolymerization of the initial olefines by acids has turned
Card 2/3 out to be much lower (12-13 per cent by weight). It was proved
Alkylation of Toluene by C 10 Olefines in the Prenence of SOY/I.o-123-5-24/50
Sulphuric Acid
moreover that the yield of the amyl toluene fraction is
affected only by the concentration of the initial acid and by
the temperature of the reaction (Table 1). Figure I shows the
distillation curve of an alkyl product. Constants of tho
products obtained are given. There are i figure, I table,
and 12 references, 1 of which is Soviet.
ASSOCIATION: Groznenskiy neftyanoy naiichno-isalt-dovi~tellsl,:i.-f institut
(Groznyy Scientific Research Institute for Petroleift)
.4 PRESENTED: July 23t 1956, by B. A. Kazanskiy, Academician
SUBMITTED: July 20, 1958
Card 3/3
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Swam, 3$ Oweb &W-
KDZOFjZOV, Tu.I.; DOROGOCHINSKI WP.
Sulfurio aold alkylation of tolmqns by diisobutrlana. Izv. vym,
uchab. zav.; neft' i gaz 2 no.5:49-54 '59. (MIRA 12:8)
l.Crozneuskty ueftyancy Institut I Grozneneskiy nauchno-iseledo-
vatellskiy inatituto
(Alkylation) (Toluene)
KOZORNZOV, Yu.i.; DoRwcHiNsur, A.Z.
Sulfuric acid alkylation of toluene by C12 olefins. Izv. vys. acheb.
zav,; neft' i gas 2 no.6:45-49 '59. (MIRA 12:11)
l.Groznenokiy neftyanoy inatitut; Groinenakiy neftyanoy muchno-
Iseledovatel'ski.y inatitut.
(Toluene) (Alkylation)
DOROGOCHINSKIT 'A.ZA~,,',
-I
Contribution of Groznyl petroleum workars to the development
of the petroleum refining industry. Trudy GrosNII no.4.-5-16
'59. (KIRA 12:9)
(Groznyl--Petroleum--Refining)
DOROGOCHIBSKIT
Vays for the further development of the petrochemicals Industr7
in Groznyi Trudr GrozNII no*4.*203-217 159. (MIRA 12:9)
?Groznyi--Patroleum chemicals)
VOTLOKIIIIN, B.Z., DOROGOCIIIIISKIY, A.Z.; MLIHIKOVA, H.P.
0
Use of radioactive indicators for checking consecutive pumping
over of petroleum products in min pipelines. Trudy GrozNII no.4:
253-265 '59. (MIRA 12:9)
(Petroleum-Pipelines) (Radioactive tracers)
5.11100
AUTHORS: Dorwoc)
trok! A
;
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lve,t )
21all-0i"I 1
TITLE: Sflpal-jt
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ABSTRACT: T~~e
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j e (-j a- or)
of' if, f r,
41
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Practions oC
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e C, a cno
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C,c~.--oti-dary Ovil I
0 n
veoult-.3; devlatlollo did 11(fl, The Cori-
C111"1011 olatC3 that- of
f 1, ~,.l c ~, I o no poi,mito an of the
Content Ot, "ll-Olflatic, 111(1 1111":11
oi, comblned.
V-) L,efei,ctic(2L;, 10 Soviket., 6 Thu, U.S.
vefevencoo are: Molpol.dcv, F., et zil, frid. Enq:.
Chem., 1111.), lo~)2; Ct-Lchile, D., r,~- ~rrjl, It.)
Aria I .Chem. , 'L! ~ ,I G".) ,11) ~) I ;F1, 11.) .,Lt -,,,i 1 :3,1~ .
Weio.,-, F., Anal. C11("In., "- 11'' A.,
Andve-vio, A., Plemilic', if. W., 'Frid. Ciiem. , 'j,
1949; Jonotlon, 11., ApjjleL),,;, 1W., M. ,
Anal . C11--ril, 210, 8o,,,, 1911"3.
ASSOCIATION; Groznyy Petroleum 5clentil'Ic u U~
Sci)ai-Litlon ot, 131-owl
tons 01 pe
~ t r.0
secondavy 01.1g,111
Table 4. Propertim, Gf the fj.pntjOrj
tographle .
method frorL cePlirnt
the
e,i by
`-he chromn-
Gelective oreucel 11atillatr,,
hydrogeratlon. bpfore ar4 aftfr
21,
IAII)L X rol rf V;j r,-Ilr ,F
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J
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S-14 (A 16,3 N 97 034'
'l 2
~
KAZANSKIT, B.A.; J)OROGOCHINSKIT, A.Z.; ROZINGART, M. I.; LTUTER, A.V.;
MITROPAN6V, 'M.G. -
Arormtizatlon of narrow bexane fractions of Groznyi gasoline on
an aaumina-chromic oxide catalyst. Kin.1 kat. I no.2:294-299
JI-Ag 160. (MIRA 13:Et
1. Institut organiobe:koy khimli im. Y.D.Zelinskogo AN SSSR i
Grnznenskiy nauchno-i aledovatellskiy neftyanoy institut.
(Aromatization)
(Hexame)
86-IL6
S/152/60/ooo/Coi./002/003
B023/BO60
AUTHORSt Derogoohinskiv. A.. 7. Nakhape yan, L. A., Lavrenttyev, V,J.,
A. N., Yershov, V, V
TITLE,. Antioxidizing Propertiesilof Some PyrazolineliDerivatives
PERIODICALt Izvestiya vyssh1kh uchAbnykh zavedenly. N,-f" i gaz, 1960,
No. 3, ppi. 69-71
TEXT: In "he authors' opinion, the stability of-mo-tor fuels 11 to oxidation
is a most important problem. They therefore studied the antioxidizing
propertiee of some pyrazoline 4erivatives in their capacity as inhibitors
The authors first obtained numerous pyrazolines having no subs-.ituents 'In
position 1, and then such having different sub3tituents in this position.
The following compounds were synthesized as possible inhibitorst
1-carbamido-3-phenyl pyrazoline 1--phenyl carbamido-5-phenyl-4-ethyl-
pyrazoline, 1-tliiocarl)ir,i,(!o-3,5:5-trimetliyI pyraz'oline, 1--phenyl thlo-
carbamida-3,5,5-trimet'-.~,! pyrazoline, I-phenyl thiccarbam:ido-3-methyl-
5,5-pe-itamethylene pyrazoltrie, 1-phenyl thiocarbamido-3,5-diphenyl
pyrazoline, 1,3,5-triplienyl pyrazoline, 3--amino-l-phenyl -:)yrazoline.
Card 1/3
An~~oxidizing Properties of Some S/11 52/~,C//G1k. i0 0 ? 100 3
Pyrazoline Derlv.,!~iro,- B02 3/Wf~o
Derivatives of phenyl thiocarbamides of variOU3 pyra7oline3 were. obtained
by the action of' phenyl isothiocyanate upon thezip pyraioliiies (Ref. 5).
In a similar manner, the following compounds were obtaint!d from the cor-
responding pyrazolines: 1--carbamido-3-pheny" pyrazoline ivid I-phenyl
carbamido-3-phenyl-4--ethyl pyrazoline (Ref, 2), 3-amino-1-phenyl
pyrazoline was synthesized from acrylonitrile and phenyl hydrazine (Ref,6).
1,3,5-triphenyl pyrazoline was obtained by interaction of benzal aceto-
phenone and phenyl hydrazine (Ref, 7). The efficien-.y of the preparation
examined was estimated by comparing their inhibiting eff.?et with the
effect of para-oxy diphenyl amine, which was taken as a :3tandard, as well
a3 with the effect of 2.6-ditertiary butyl-4-methY1 phenols Two samples
Of motor fuels A and B were taken, the properties of which are given in
Table 1. Sample A was prepared by intermixing equal amounts of fresh
distillate of thermocracking and of the benzene-ligroin fraction.
Sample B was prepared by intermixing the same amounts in a ratio of
30 : 70, Both samples were inhibited by -iariouq additions on the day of
their preparation. The additions were allow-A to disqolve in the motor
fuels by being added as benzene solutions. Benzeno wa3 taken in an amount
of fU0,1% of the fuel Yolume. The effect of stability of' namples A and B
Card 2/3
86146
Antioxidizing Properties of Some S/152/60/000/005/002/003
Pyrazoline Derivatives B023/ '0060
was examined first, For this purpose the authors studied the inhibited
motor fuel for its stability to oxidation by determining the induction
period on the basis of rOCT 4039-48 (GOST 4039-48) within 6 h. The content
of potential resins in the motor fuel was determined next. Results show
that some pyrazoline derivative samples have a considerable Inhibiting
effect. The best results were yielded by the use of 1-phenyl thio-
carbamido-3,5,5-trimethyl pyrazoline. In the sample inhibited with this
substance, the resin formation appeared only after two months, whi.Le
resins in a noninhibited sample increased with uninterrupted intensity
throughout the whole storage time.. There are 3 tables nnd 7 referencess
5 Soviet, 1 US, and 1 German.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet in.. M.. V. Lomonosova
Moscow S&ate University Imeni M. V. Lomcnosov) GrozNII
Groznyy Petroleum Institut2i
~
SUBMITTED: September 3, 1959
Card 3/3
KOZOBBWT, Yu. L;
Alkylation of toluene by Cio olefine In the prasence of
sulfuric acid. Xhim.i tekh.topl.t maael 5 no-5:36-41
my 16o. (MIR& 13:7)
1. Orognenskiy nauchno-ionledovateltakly neftyanoy institut.
(Toluene) (Olefins) (Alkylation)
67171700 68999
AUTHORS: Dorokochinekly. 1. Z.P Lavrentlyev, V. I , 8/020#0/131/02/045/071
N9 P.9 Boll/Boll
Kupriyanoip Ve As
%%
TITLE: Synthesis and Properties of Naphthenic H11rocarbons With a Long
Side Chain
PERIODICAL: Doklady Akademii nauk sssR, 196o, Vol 131, Nr 2, PY 367 - 370
(USSR)
ABSTRACT: The authors wanted to work out a general method and conditions
for the synthesis of technical -fractions of the substances men-
tioned in the titlep an well as the study of the properties of
these fractions. Pr lene, _jXjene
Spy _,Iam:rlens, hexylene, and
'I bu
heptylene were used for the purpose. As a result of the experi-
ments conducted at the authors' instituter a 3-stage scheme of
synthesis was suggested: 1) synthesis of olefine with a given
number of C-atoms, or polymerizationg respectively. A dehydrated
pentane-amylene fraction from thermal cracking, purified from the
sulphur compounds, was utilized. The catalyst was phosphoric acid
on kieselgare Olefins with ramified struoture were obtained in
urred at
oo
this connection. The highest yield of itiodecene
flov-A 11A I
q
170-1800, pressure of 50-60 atm, volume rate 3- h- * Amylenes
:
68998
Synthesis and Properties of Naphthenic Hydrocarbons 3/02o/60/131/02/045/071
With a Long Side Chain B011/BO11
were transformed to 70%. k concentrate boiling between 120 and
1850 was obtained from the polymerizate (yield 85-90%). Table I
shows the resulting (mostly ramified)atructures of isodeconeso
Table 2 shows their physico-ohemical properties (the raw material
was fraction 6 of the thermal oracki-ag and benzene). Isomeriza-
tion and hydro-dehydro polymerization of the olefins were ascer-
tained as side reactions. 2nd stage: alkylation. Aromatic hydro-
carbons (benzene, toluene) were alkylated by means of the iso-
deoense produced (Refs 3-5). The beat conditions were: 97%
92SO 49 reaction time 2 hours, ratio benzencisodeoene a 5:1. Tem-
perature 10-200. The alkylate amounted. to 140% by weight of ole-
fine or 9CP16 of the theoretical yield. A fraction boiling between
1800 and 3500 was obtained from the a:Lkylate as a concentrate of
isodecyl benzenes (85% of the alkylate). It chiefly consisted of
mono-substituted derivatives of benzene (Table 2). On using alu-
minum chloride as catalyst the yield was higher and attained
97-98%. Disproportionation occurred as side reaction. 3rd stage:
hydrogenation. The alkylate concentre.te was hydrogenated on 2
catalysts: a) nickel catalyst. The optimum condition were: pres-
rArd 2/A sure 7 atm, molar ratio hydrogen:alk:rlate - 2.801 1;0-2000a,
68998
Synthesis and Properties of Naphthenic Hydrocarbons 8/020/60/131/02/045/071
With a Long Side' Chain B011/B011
Volume rate 0.2 h'1 I b) nickel-tungsten catalyst* Optimum oondi-
tions: pressure in the reaction zone 200 stmi Imolar ratio hydro-
gen-alkylate - 64:11 30001 volume rate 0-5 h- . To prevent a tem-
perature increase on the latter catalyst# the alkylate was diluted
with gasoline distillate (fraction 80-1200) of the trade-mark
"Zaloshall In. a ratio of 1:2. Destruction was recorded as a side
reaction. 7he desired naphthene fraction was obtained from the
hydrogenation product by rectification, It boils out between 180
0
and 350 , Its yield attained 90% of the aromatic hydrocarbons con-
tained in the alkylate (Table 2). The range of the fluctuation of
properties in dependence on procedure and raw materials is shown
in table 3. Data obtained show that the scheme described here
leads to naphthene hydrocarbons with a long side chain, high den-
sityp high oaloricityp and a low freezing temperature. The follow-
ing names are mentioned: Ye. G. Vollpova, L. A. Potolovskly,
1. F. Blagovidov, L. I. Kostiking Yu. A. Golldshtein,
Yu. I. Kozorezov, A. Z. Dorogochinskly, and K. I. Zimina. There
are 3 tables and 6 Soviet references.
Card 3/4
68997
Synthesis and Propertiev of Haphthenic Hydrocarbons 8/020/60/131/02/045/071
With a Long Side Chain B011/BO11
kSSOCIATION: Groznenakiy neftyanoy nauohno-iseledovatellskiy institut
(Groznyy Saientifio Research Institute of Petroleum)
PRESENTED: November 28# 1959, by B. A. Kazanakiy, Academician
SUBMITTED: November 25p 1959
t4.
Card 4/4
S/081/61/()00/021/060/094
B138/B101
AUTHORSt Gonikbergj M G Dorogochinskiy, A. Z., Mitrofanovp M. G.,
Gavrilova, A: V. K.,
Vovk, L. M.
TITLEs Homogenous demethylation of toluehe. Basic characteristics
of the process at 750 to 7900C
FERIODICALt Referativnyy zhurnal. Khimiya, no. 21 1961p 319, abstract
21L34 (Neftekhimiyal v. 1, no. 1, 1961: 46 - 53)
TEXT: The homogenous demethylation of toluene (I) in a flow system is
studied at temperatures of 750 to 7900C and pressures of < 40 at. Lt a
volumetric feed rate of 5 to 7 br- I the conversion of I Into C6H 6 is as
much as 75 to 80 % in one ran and the 0 6H6 yield is 90 mole%, calculated
from the amount of I which has undergone reaction. By rectifying the
products of the reaction in a column with a theoretical efficiency of 20
Card 1/2
3/081,/61/000,/021/060/094
Homogenous dem'bthylation of toluene ... B138/BIOI
platee,very high purity C6 H6 is produced, and a small quantity of a mixture
of high boiling-point aromatic hydrocarbons containing >_ !iO % diphenyl.
The possibility is discussed, of tieing the bimolecular reaction equation
to provide an approximate description of the kinetic laws governing this
process& EAbstracter's notet Complete translation.]
Card. 2/2
-D,,OROGOCHIMKlY, A.Z.; GONIKBERr., M.G.; MITROFANOVI M.G.; KUFRIYANOVt V.A.;
VOVKI'LOMs'
Homogenous dometby3Attion of toluene. Report No. 2s Experi-
menta with gas cyclirg. Neftekhimiia I no-4001-504
J3.-Ag 161. (MMA 16: 11)
1. Groznenskiy neftympy nauohno-issledovatellsidy institut
i Inotitut organichegkov khWi AN SSSR imeni N..D.
Zelinskogo,
JUMSKIYp B A DOROGOCIIINSKI'Y A.Z.; ROZENGART, M.I.; LTITER, AN.)
Effectk,of the feed ratw on the process of aromatization of h 0
0
over aA.' al=inutn-chrom~xm catalyst. Kin. i kat. 2 no,2:25~~6
Mr-AP 141. (MIR 14 67)
1. Insti ut organicheskoy khimij All SSSR imeni N. D. Zelinskogo
i Gorzneikiy neftyanoy-nauchno-issledovatellskiy Institut.
Otoxane)
(Aroumitization)
8/081/62/C,00/006/099/li7
B162/BIOI
Dor
AUTHORS: ~~ochinskiyp-Ao Z.t Baahilovt Ao Aot Chertoryahokiyt A* V4
Arutyunovaj Oo Los-krechatovat P. I., Shestmk, go P. 10
TITLE: The problem of the ohoice of solvent for polirmerisation of
ethylene into polyethylene at low pressure
PERIODICAL: Referativnyy zhurnal. Xhimiyap no. 6, 1962, 614, abstract
6P35 (Tr. Groznensk. neft. in-t, v- 3, eb. 25, 19619 17-29)
TEXT: An investigation is made of the possibility of using extraction
benzine as a solvent for ethylene when polymerizing it into polyethylene
at low pressure. It is shown that the following are suitable: an extrac-i 2
tion benzine fraction evaporating at 65-900C with an aromatic. hydrocarbon 1
content of 3.0 before do-arQmatization and of 0.70 after do-aromatization
or a fraction evaporating at 75-95()C in the case of which de-aromatization'
is not needed (aromatic hydrocarbozt*ooncentration,0.7$)- It is shown that~
the presenoe of aromatio hydrocarbons has no effect 'on the polymerization
process, 1-~ impairs the regenerabIlity of the solvent, [Atstraoter's
n
ote: Complete translation.]
Card 1/1
S/153/61/004/01)1/007/009
B110/B203
AUTHORSs Kozorezovt Tuslat RoL~gochinskiy, 1.Z.
TITLEj Intensity of the reaction of polyalkylation in the sulfuric
acid alkylation of toluene with high-moleoular olefins
PERIODICALs Izvestiya vysehikh uohebnykh zavedeniy. Xhimiya i khimi-
cheskaya tokhnologiya, v- 49 no. 19 1961, 133 - '137
TEXT# In the alkylation of aromatioa, especially toluene, with low-mole-
cular olefine, undesired polyoubstituted derivatives are formed in part,
the formation of which is reduced by excess toluene. The tendency to po-
lyalkylation decreases with increasing molecular weight. Few publications,
howeverg deal with the intensity of t-cluene polyalkylations with high-mo-
lecular olefins. In the present paper, the authors study polyalkylatione
in sulfuric acid toluene alkylation with isodecenes separated in distilla-
tion from the polymerization products of the pentane amylene fraction of
thermal cracking with phosphoric acid catalyst. The authors utiedi to-
luene w1th bromine number - 0, the isodecene fraction between '25 and
1750C, with molecular weight - 1341 bromine number - 120, and chemically
Card 1/8
3/153J61/004/001/007/009
Intensity of the reaction of ... B110/B203
pure H2SO4 as a catalyst. The method described by the authors (Rafe 6a
Tu*I. X(izorezov, A.Z& Dorogoehinskiyo Dokl. AN. SSSRq inp, 857 (1959))
was used for the production. Table I shove that in the toluene alkylation
with isodecenes yields of more than SC~o of monodecyl toluenes (fraction
220-3000C) are obtained'which only slightly decrease with decr,)asing mo-
lar ratio toluene/oleffile. A decrease in the ratio from 4-7 to 1 increa-
ses the rield of residue boiling above 3000C only from 2-3 to 5,-5~ by
weight. The decreaeo.'In densities and 'refractive Indices shows that the
aromatic fraction does not increase to the same extent. An increase of
the bromine number and the aniline point indicate an increaso in, side re-
actions of olefin polymerizations, A decrease of the molar ratio from 7
to I reduced the fraction of aromatics from 95 to 83 % by weight. Here,
a proper excess of toluene should reduce the undesired olefin polymeriza-
tions to a minimum. The iaodecyl fraction between 220 and 3000C was oxi-
dized in an oscillating steel autoclave with 5% KNO 3at 2000C for 2 hr.
Terephthalic acid, Identified as methyl aster, was formed in a W% yield,
The absence of o-phthalic acid establishaa with reeorcin suggestcd a
p-structure of the original decyl tolueness H 2so4as a catalyst does not
card 2/8
S/1 53/61/004/001,1007/1009
Intensity.of the reaction of ... B110/B203
permit Tormation of m-isomere. Ortholsomerism is sterically impossible
due to the isodecone structure. In tho isodecene fraction obtained with
0
H PO ('120-180 C), compounds with tertiary C at the double bond (RR'CwCH
3 4 2
band RRI - CURIO are prevailing. The aromatic compound adds to ihis
tertiary U in the presence of R so The introduction of the t5rtiary C
4#
atom into the ortho-position of toluene is already difficult in the case
of simple isobutylene. Therefore$ the-alkylation %X p-xylene with Isode-
cone is also difficult; it yields 55% unsaturated olefin polymors and
Only 19,5~* aromatics (after silica gel adsorption'). In the alkylation of
o-xylene, however, a 98% yield of alkyl xylone with aromatic hy&rocarbons
was obtained, corresponding to 161~ by -weight or the initial oltfins. The
alkylation of p-xylene with n-nonene and n-octons produced yields near
those of o-xylene (Table 2). Thuat the o-alkylation is facilitated with
decreasing branching of the olefin molecules and absence of the tertiary
C atom at the double bond. There are 2 tables and 14 reforencest 9 So-
Viet-bloa and 5 non-Soviet-bloo. The reference to the English language
J.
publication reads as followet Ref. 10. B.Priedman et. al. J. Amar. Chem.
Soo. 79, 1465 (1957)
Card 3/8
3/1.53J61/0041001/007/009
Intenoity of the reaction of ... B110/B203
ASSOCIATIONt Groznenskiy neftyarioy-inatitutg Katedra tekhnologft nefti
i gaza (Grozr*,y Petroleum Institutep Departnent of Pe-
troleum and Gas Technology) Grotnenakiy neftyanoy nauchno-
iseledovatellskiy institut Woznyy Petroleum Scientific
Research Institute)
SUBMITTEDi June 1, 1959
A
Cr
at
noHOaro lo % 219 In
'VVOAYOLrHmrt Yoxiq F4 z
00JAU0 vial
Intensity of the reaction of ...
0', to 40
CL Ci R 0.
C4
0
C~
V)
L)
C4
owe
Ck
C-4 C4 C4
- CL Iq CL CL ort
tl
-Ilem) exhOL R 12 !2 12
OV)Iih
IT
o t-
co %k
-r CL
w q
C14
S/153J61/004/001/007/009
BlIgB203
! ( K
nuwe 300 C
d~
no
0,&~18- 1,4796 0.8(06 1,4M
OSfA 1 1,4865
Ors 50
1,4843
0,8686 1,4M 0,Wj 1,4915
0,8716 1.4915 0,9000 1,4930
0,3746 1,4921 0,9010 1,4950
-~~"Card 5/8 0.8746 1,4927 0,9014 1.4970
Intensity of the reaction of
S/153/61/004/001j'007/099
B110/D203
40
Legend to Table Is Sulfuric acid alkylation of toluene with isodecene
(H2so4 concentration 96% by weight, referred to monohydratel temperature
100C, reaction time 60 min; volume ratio acid/hydrocarbons C,12). (1) -:5-o
Test number# (2) molar ratio toluene/oiefinsp (3) alkyl toluene yieldt
% by veight of olefinst (4) alkyl -toluene properties, (5) fraction abovs,
1750C, (6) bromine number, (7) aniline point, (6) fraction composition,
(9) -above 3000c, (10) losses, (li~ fraction 175-2200C, (12) fraction
220_3000c, (13) fraction above 300 C-
Card 6/8
Intensityof the reaction of ...
Table 2
S/153/6i/004/1)01/007/009
B110/B203
CDOACTSS a-m-3KC11.1m
BbI10A $A-
A
see %
HIM Apomantye.
onm- cxmn x0m. :"s u
yrAesoAopoA 0 1
log HOWIT, d04
02e- I 1-Co-
tj
0 m
+mforl PKH & , ;
32,
51 Owa-KCIMOA fluJO-AeU" 81.3 - Omm 1. 4695 38,1 71.8 19,5
53 120,VMO.KCHAOA ~U.10-jletxen 161,0 - OA810 1.5m 1.3 16.6 98.0
78 ftnapa-KCRAOX IN-Ho"CH 14T.1 80.0 0,M1 1,4880 3.4 - 9 j.0
161 finapa-KCHAO.M ~M-OgTeff 162,0 83.0 O,8M2 1.4890 3.2 11.8 96,0
166 aopmo-Kamw fm-HoHeii 162.0 88.0 0,8749 1,4972 0.7 17,8 99.0
Card 7/6
S/153/61/0041/001/007/Oog
Xntensity of the resotion of B110/B203
Legend to Table 2t Sulfuric acid alkylation of xylenes with olefins
(H SO Conoentration - 96A by weight; 10 0C1 60 min; molar ratio xylene/
2 4
/olefins - 71 volume ratio acid/hydrocarbons - 0,12). (1) Test number,
(2) aromatic component, (3) clefint (4) alkyl xylepe yield, ~ by weightp
~5j referred to olefinal (6) of the theory (7) *alkv:L xylene propertiest.
6 bromine -numberg (9)(,anillne pointp (io~ content -)f aromatiost % by
wei tj (11) P-xylene, 2) o-xylenep 0~) isodecene, (14) u-nonene,
(15 n-octene.
DOROGOCHINSKIY# A#Z.j MELINIZOVAt NoP.
I-- --.-
Deuterium exabange of some bydrocarbons of the axomatic and
naphthene series on an aluminooilicate cracking -:atalyst.
Zhur.VKHO 6 no.ltl3.e-n9 161. (MIU 14:3)
1. Groznenskiy nauabno-isoledovateltakiy neftyan-3y institut.
. (Hydrocarbons) (Deuterium)
5/065/61/000/006/ooi/ool
E073/E335
AUTHOR: Dorogochinakiy, A.Z.
TITLE: tWe--'5~eve1Tt-1-efh--BTrthday of Academician
B.A. Kaxanaldy
PERIODICAL: K imiya i tekhnologiya topliv i masel,
1961 6, P*67
TEXT: B.A. Kazanskiy was seventy on April 25, 196l. He
graduated at Moscow State University in 191e and subsequently
worked in the Chair or Organic and Analytical Chemistry. He
has worked for over forty years at Moscow University. He
became Docent in 1930 and in 1935.Professor and Head of the
Laboratory for Catalytic Synthesis of the Institut organicheskoy
khimi Akadewli Nauk SSSR (Institute of Organic Chemistry of
the AS USSA. in 1945, B.A. Kazanskiy becamc Assistant Head
and then H4ad of the Chair for Oil Chemistry at Moscow State
University. In 1943 lie was elected Corresponding Member and
in 1946 Full Member of the AS USSR. In 1954 he became
Director of the Institute of Organic Chemistry of the AS USSR
im. N.D. Zelinskiy. Under his guidance, many investigations
Card 1/3
S/065/61iooo/006/001/001
On the Seventieth Birthday E073/E335
were carried out on a multitude of hydrocarbons and their
catalytic transformations. Kazanskiy was the first to
discover and study the reaction of hydrogenolysis of
quintinary naphthalene hydrocarbons and their transformation
into paraffin hydrocarbons. Jointly with other Soviet
scientists he discovered and studied the dehydracyclisation
reactions of paraffin hydrocarbons and aromatic hydrocarbons.
Under the guidance of Kazanskiy a large number of active
catalysts were developed. During the last twenty years he,
carried out major investigations of catalytic hydration of
mono- and poly- unsaturated hydrncarbons
and of dehydration of paraffins in olefins. Ile and his
team studied the proporties, and developed mettiods of
synthesis of hydrocarbons with three and four chain cycles
and cycles in which the number of carbon atoms exceeds six.
He has written over 300 papers and was the chief editor of
a number of classical publications in chemistry (journals,
etc.). Kazanskiy initiated and participated in numerous
Card 2/3
's/c,65/61/ooo/oWooi/ool
On the Seventieth BIrthday .... E073/E335
chemical congresses and meetings. Ho was awarded the Order
of Lenin,, the Red Banner of Labour, the Stalin Prize and
i:iany others. There is I photograph.
Card 3/3
AUTHORS:
TITLE:
PERIODICAL:
S/08 62/000/001/060/067
B162YBIOI
Saponj M. F.f2nMa2h~~~,
Thermal stability of distillates of' various origins
Referativnyy zhurnal. Xhimiya, no. 1, 1962, 449, abstract
1MI82 (Tr. Groznensk. neft. n.-i. 4.n-t, no. 11, 1961, 38 - 52)
0 0 0 0
TEXT: The 50 C thermal stability of 150-200 C, 200-250 C, 250-300 C and
300-350 0C fractions separated from a non-sulfur Groznyy paraffin-base
petroleum mixture, an Lastern sulfur petroleum mixture and from the mazut
thermal cracking products of these types of pet:-oleum on semi-industrial
GrozN11 apparatuses with columns having 28 theo::-etical plates, was
investigated on an JICA(LSA) apparatus. The thermal stability was evaluated
from the quaniity of reaidue and resin in the f:ractione after oxidation.
The catalytic action of metals (electrolytic co:?per, 124H3A(1Wi.NZ&)stdeland
BPP-24 (VB-24) bronze) on the oxidation process -nas demonstratod. It is
shown that for narrow rectified and cracking fractions of non-sulfur and
sulfur petroleum the principles determining the quantity of residue forming
during oxidation cannot be explained by the content of unsaturated hydro- I
Card 1/2
5/08 62/000/001/060/067
Thermal stability of... B1621YBIOI
carbons, resins or sulfur compounds in the initial fractions. The magnitud6
of the resin content in the oxidized fractions io greatly affected by the
quantity of resinous substances contained in the fractions, the oxidation
temperature and the catalytic action o~ the metals. Sulfur compounds
stimulate resin formation. [Abetraoterts note: Complete translation.]
'50
Card 2/2
3h888
B/061/9,2/000/003/067/090
iO 40/.iji 01
jJj D.oro aoch i n W: iy ,Z. , :."c 11 n i'cov n- c- t, o z --, rov .-i, 0. 1.
T ITLE - Effect of the lc-r,)c of aelacted hjero!7cnntion of unsaturzlt--~!
'q S in 41
ydrocarbon thermocracking distillate on its thermostabili-
Ily
PERICDICAL: Referativny~ zhurnal. Khimiya, no. 3, 15162, -~35, abztract
3Mlr,2 (Tr. Grozncnsk. ncft. n.-i. ir-t no. 11, 1961, 53 - 57)
TEX": The effcct of the group composition of hydrocarbons on the thar%-,al
ot2bility of the iiEtill3te from thermocrackin,-, boilinF wit at -20 - 260 0C
(obtained from the ma7out of Gvoznenrs--i~ paraffin-bast~d mi-,ed pevroleum),
after selective hydrogenation to different de,,-reo3 of tho unsatUr-tc-d
hydrocarbons (ori,.7,inal content in tha diz;tillate: -~as invc&tiF,,ate-1.
It was shown that the decrease of tho fuel thermal staUility deponded on
the nresence of diolofins and aromatic 'hydrocarbons -.,.,ith uns~tur%tcd 3ide
chains. Uld hydrorenation (up to 16ci~.) of thie unsatur,.to-, 'hy,-'rocarbonr.
4- 0
,rom the distillate resulted in a -'ucl with satisf,,.ctcri 1h otability
Card 1/2
0
Effect of the decree ...
:IAbstracters rot:!.- Complete translation.~
0
j/0~11/'?/000/003/067/090
B14c,/BlCil
V411,
C.-rd 2/2
34414
B/C,81/62/000/002/085/107
157 JI? cc B157/B110
AIJTHORS% Dorogochinskiy, L. Z_ Multnikova, N. P,,, Shakhzadova, I. A.9
G~onar_OT _T7'Ya.
TITLEi A study of the reaction of iso'.ope exchange of certain
aromatic and naphthenic hydrocarbons on a deuterated
aluminosilicate cracking catalyst
PERIODICALx Referativnyy zhurnal. Xhimiya, no.. 2, 1962, 489, abstract
2M229 (Tr. Groznensk. neft. n.-i. in-t, no.. 11, 1961, 246
252)
TEXTj The deuterium exchange of aromatic and naphthenic hydrocarbons of
varying structure on an industrial aluminosilicate cracking catalyst has
been investigated in a flo,g-through type plant in -the vapor phase at
1500 - 2000C and atmospheric pressure; volume flow rate 0.10 - 0.15 hr-1.
For comparison, the hydrogen exchange was studied between certain aromatic
hydrocarbons and tritium oxide in the presence of the srme catalyst
specimen. It was shown that the capacity of alkyl derivatives of benzene
to undergo hydrogen exchange on a deuterated catalyst increases with the
length of the aide chain of the hydrocarbon; the presence in the side
Cara 1/2
5/081/62/000/002/085/10't
A study of the reaction of... B157/B110
chain of a tertiary C atom (isopropyl benzene) increases the depth of I
deuterium-,hydrogen exchange. Naphthenic hydrocarbons will undergo
isotopic exchange readily only when a tertiary C atom it) present in the
molecule (methyl cyclohexane, ethyl cyclohexane, isopropyl cyclohexane).
(_~bstracterls notes Complete translation.~
Card 2/2
s/o65/62/000/004/001/00
E075/El3b
AUTHORS Gonikberg, M.G. , On-aachin-JUX
Mitrofanov, M.G., Gavrilova, A.Ye., Uroixin, A.F.t
Kupriyanov, V.A., Makarlyev, S.V., Zamanovj V.V.t
and Vovk, L.M.
TITLE: A process of thermal dealkylation of aromatic
hydrocarbons
MIRIODICAL: )"'.himiya i tekhnologiya topliv i masel,
no.4, 1962, 11-15
TEXT. As a result of investigations carried out in the
years 1953-1960 in IOKh AN SSSR and GrozrIII, a technological
scheme was developed for an industrial process of thermal
dealkylation of monocyclIc aromatics such as toluene and methyl-
naphthalenbs, A pilot plant for the process producing
30 000 tons of benzene per annum consists of a small number of
simple units. it contains a tubular furnace of only
3 mil. cal/hour capacity. The main production indices for the
plant are as follows: reactor pressure 50 atm; maximum
temperature 790 OC; separator temperature 35 OC;
-1 '1/,
A process of thermal dealkylation... vo65/62/000/004,lool/004
E075/E136
pressure in benzene column 0.1-0.3 kg/cm2; temperature in
benzene column, top 87 OC, bottom 130 oC; pressure in the
recycle stock separation column 0.1-0.3 kg/cm2; temperature in
the recycle stock separation column, top 2600, bottom 304t `C;
molar ratio hydrogen/feedstock 4:1; space velocity of' feed
4.0 h-1; consumption of hydrogen 2.10,,o wt of feedstock; yield
of benzene 78.7*,,j wt of toluene. It was calculated that ,iigh
grade benzene produced by the process from petroleum derived
toluene is considerably cheaper than th4t obtained currently in
the coking industry. It was established that thermal
demethylation of methyl naphthalenes (700 OC, 50 atm) gives
naphthalene with a yield of ca-5Q,10' wt of fcedstocli~ after one
cycle. The most suitable raw materials for the process are
aromatic products obtained during reforming, pyrolysis and
catalytic cracking processes. It is expected that the dealkyla-
tion process will constitute an important source of benzene and
naphthalene for the Soviet petro-chemical industry.
There are 1 figure and i table.
Card 2/2
S/204/62/002/004/003/019
E071/E433
AUTHORS: Kazanskiy, B.A., pRr_q&ochinqkiy-,-~z , Sterligov, O.D.,
Lyuter, A.V., Dmitriyevskiy, M.L., Nazarov, P.S'
TITLE; Dehydrogenation of isopentane into isoamylenes on an
alumochromopotas3ium catalyst
PERIODICAL: Neftekhimiya, v.2, no.4, 1962, 448-456
TEXT: A systematic study of the process of dehydrogenation of
isopentane into isoamylenes under condit-Lons of a stationary and
moving layer of granulated catalyst K-544 was carried out on
experimental installations of Groz NII. Tests on the stationary
layer were carried out on a laboratory and.an enlarged
installation. The reactors with a stationary layer of the
catalyst were of the capacity of 40 and,500 cm3 respectively.
Tests in the moving layer were made in a co-current continuous.
pilot plant with a reactor (4 litres) and a regenerator (4-7 litr*s).
The volume of the catalyst - 35 litres, throughput - about
100 litrea/day, the velocity of circulation of the catalyst
up to 16-litres/hour. The analyses of the reaction products were
made by chromatographic and other chemical methods. The influence
of the temperature, volume velocity and rate of recirculation of
Card 1/2
S/204/62/002/004/003/019
Dehydrogenation oflaopentane ... E071/E433
the catalyst on the main parameters of the process an well as the
behaviour of the catalyst were studied. It was found that the
catalyst had a good and stable activity. During an operating
period of 1100 hours in a stationary layer and 400 hours in a
moving layer its activity remained practically unchanged. Under
the optimum condition of the process (temperature - 540*C and
volume velocity - 1 hour-1) the yield of isoamylenes amounted to
30 to 31 wt-96'. calculated on raw material (98.6% of isopentane)
with a total yield of unsaturated hydrocarbons C5 of 34 to
38 wt.%. The catalyst has a satisfactory strength and good
regeneration characteristics. The velocity of burning out of
coke from the most inaccessible layers of catalyst K-544 amounted
to 20 litres/litre of catalyst per hour, in comparison with that
for aluminasilicate catalysts of 13 to 16 litres/litre of
catalyst per hour. There are 6 figures and 5 tables.
ASSOCIATION: Institut organicheakoy khiniii AN SSSR
im. N.D.Zelinzkogo (The Institute of Organic
Chemlstry AS USSR imeni N.D.Zelinakiy) GrozN1I
Card 2/2
KAUMUY9 B.A.; pgMQMMjjX,,_A.Z~; ROZEAGAHTj M.I.; TYUNIKIU,, N.I.;
KUZNETS(IVA, I.M.; MWER, A.V.; NITROFANOV$ M.T.
Aromatization, of mixtures of n. hexane with 2-mothylpentane..
with 3-methylpentane or methyloyclopentane. Izv.AN SWR.Otd.
khim.nauk no.7t1308-1309 Jl 162. OMA 15:7)
1. Inbtitut or anicheskoy kbildi im. N.D.Zelinskogo AN SSSR.
lAromatization) (paraffins)
L1636
3/080/62/035/009/010/014
D204/D307
AUTHORS: Dorogochinskiy# A.Z#, Viktorova, Ye.A., Shuykin, N.I.p
-Bdkkova, Ye.Ps,-hnd Malin, A.G.
TITLE; The effect of cycloalkenyl phenols on the stability
of a fuel containing unsaturated hydrocarbons
PERIODICAL: Zhurnal prikladnoy*khimii, v. 35, n'o. 9# 1962,
2060 - 2064 .1
TEXT: The stabilizing effects of;,A) 3-methyl-4-(cyclopenten-2-yl);
B~ 3-nethyl-(S-(cyclopenten-2-,Yl); C) 4-methyl-2-(cyclopenten-2-yl);
D 2-(cyclohexen-2-yl); and E) 4-(cycloheien-2-yl)-phonols were in-
vestigated, on a fuel containing -,/15 fo' of unsaturated hydrocarbons,
over a period of 5 months, at 50 � 0.50C. Vive samples of fuel.were
Uested with the above additives (50 mg per 100 ml fuel), two addi-
tional samples were respectively treated with 10 g/100 ml of p-hydro-
tydiphenylamine and 50 mg/100 ml of inhibitor ~P4 -16 (FCh-16)7 and
one sample was kept as a blank. Each sample also contained steel
wire (with a surface area of 20 CM2 per liter of fuel) and was open
tQ air via a capillary. Every month the samples viere tested for tar
Card 1/2
The effect of cycloalkenyl ...
content and stability to heat (1
B and C inhibited tar formation,
xydiphenylamine and FCh-16. The
impeded by B and D. The additive
There are 3 tables.
SUBMITTED: May 30, 1961
3/080/62/035/009/010/014
D204/D307
hour at 1500C). It was found that-
similarly to antioxidants hydro-
formation of sediments at 1rOOC was
B thus exhibits a twofold action.
Card 2/2
_D0B=rHTM.qKTY 'I~i3djr Zinovlvevicht LYUTER, Alsksandr Valentinovich;
VOLIFOVA, Yev en a Grigorlyevna; RF.KHVIMHVILI Antonina
Nikolayevna; IOMNIKOV, F.M., red.; KUZIMENKRI, N.T.,
tekhn. red.
[Oil gases in the Chechen-Ingash and oUwr economic regions
ot the Northern Caucasus]Neftimnya'gazy Chocheno-Ingushskogo
i drugikh ekonomiohookikh raionov Severnogo Kavkaza. Groznyi
Chachano-Inguohokoe knizhnos izd-vo, 1960. 259 p.
(MIRA 16:3)
(Caucasus, Northern-Gas, Natural)
Kimsm, B.A., DOROWCHINSM. A.Z., ALIM, T.S., USIM07A, A.P.
Catalytic dalWdrogematiois of IWdsocarboss.
Report presented at the 12th Conforms" on b1gh Solm welot
compounds, devoted to monomerm, 3-7 April, 62
DOROGOCHINSKIY, A.Z.;
Work of the collective of the Grozny Petroleum Scientific
Research Institute in the development of new technological
processes in oil refining and petroleum chemistry. Trudy
GrozNII no. 15:3-15 163. (MIRA 17:5)
MITROFANOV, M.G.; MIRSKIY, Ya.V ,; DOROGOCRINS,KIY. A.Z.; DRONIN, A.P.
MAKARIYEV, S.V.; LUGOVOY17rf-.--"---'-- ..'
Selecting the best arrangement for separating gasoline fractions
in molecular sieves. Trudy GrozNII no. 15:84-92 163.
(MIRA 17:5)
KAZMISKIY., B.A.; DOROGOCHINSKIY -A'-Z*. S,.ERI.lGrV, O.D.; LYUTER, A.V.;
.DMITRIYF,V~M,-M.L.;'NAZAROVA,"M.P*.; R+JASHVILI, A.N.
Studying the dehydrogenation of Isopentane on K-544 and K-5
finely divided catalysts. Trudy GrozNII no. 15:241-253 163,
(MIRA 17:5)
KAZAJISKIY, B.A.; DOROOOCHINSKIY, A.Z.; ROZE71GART, 14.1.; LYUTER, A.V.;
- --.- ------ --
MITROFANOV, M.G.; BRF.SIICIIWKD-, Ye.M.; KALITA, L.A.; GOLIDSHTEYN.,
Yu.A.; AFANASIYEV, A.I.; HAKARIYLV, S.V.; ZAMANOV, V,V.
Dehydrocyclization of normal hexane. Trudy GrozNII ro. 15:
254-264 163. (MIRA +5)
KONOPLEVI V.P.; DOROGOCHINSKIY. A.Z.; HITROFAROV, M.G.
Alkylizing toluene with propylene in the presence of aluminum
chloride and polyalkyl toluenes. Trudy GrozNII no. 15:271-273
,63.
Initiating the oxidation of cymenes in the liquid phase.
Ibid.:274-277 (MIM 1715)
KUPRIYANOV, V.A.; DOROGOCIIINSKlY, A.Z.; MELINIKOVA, N.P.
Studying the hydrogenation of fractions of industrial
isodecyl benzene on a nickel catalyst. Trudy GrozNII no.
15t278-293 163. (MIRA 17:5)
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1 0
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1. Institut organicheskoy khimii AN SSSR im. N.D.Zelinskogo i
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KAZANSKIYO B.A ; DOROGOCHINSKIY, A.Z-j ROUNGART, IA.I.; GITISp K.M.;
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catalyst layer on'the 'aromatization of n,-heptane.
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1. Institut orgwdchaskoy khimii AN SSSR imeni N.D.Zelingkogo i
Groznenskiy neftyanoy nauchno-issledovateltakiy inatitut.
(Heptane) (Aromatization) (Catalyots)
KAZANSKIY, B.A.; DORIOGOCH~IlfS X,-A.Z.; ROZENGART, M.I.; KUMETSOVA, Z.F.;
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n-hexane. KinA kat. 4 no.5068-772 3-0 163. (KIRA 16:12)
1. Institut organichaskoy khimil AN SSSR Imeni N.D.Zelinskogo
i Groznenskly neftyanoy nauchno--issledovatellskiy institut.
ZHAVORONKOV M.N.
I
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of the developmNit by X.V.Kharichkov of the cold method for
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leum refining and petroohemical induatries of the Soviet Union.
Khim i tekh. topLI. i maisel 9 nool-1:19-23 N 164 WIRA 18:1)
PIVOVPJiCJVA, G.A., DOROGOCIIINSKIY, A.Z.
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1. Groznenskiy neftyanoy institut.