SCIENTIFIC ABSTRACT SAVCHENKO, D.K. - SAVCHINKOV, I.L.
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Document Number (FOIA) /ESDN (CREST):
CIA-RDP86-00513R001447310011-9
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RIF
Original Classification:
S
Document Page Count:
100
Document Creation Date:
November 2, 2016
Document Release Date:
July 13, 2001
Sequence Number:
11
Case Number:
Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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SAVC- D.
Fquinnent at- present,used in c-121rider-I c~i t~! rin
-'-1--ation o"' ecuipment and instruments t=r) LI 3h
T he
-Ior kArurc ich-skie appamay i ir-strumen' on t i'
ye I , - ty y kh pr4meneniye
T
I , ~L. -s and Experience in Their '10. 11
SUIRG!'A rk-uipment and Instt-umcnt. use)
nrch L'Ist.
S=cm:, 19,57 A collection of Faners of the Scientific Rese,
for Experimental Surgical rvjuiment and Instruments.
E. D. TIE, i
J~.
LIEIITSI~,AYA~ 14. il.., L. A.
-ulation and its clinicnI w-6 e-xnerinertz-1 .... ItI7,
blocd
Noy-..,re kInArm-ichoskie a,-)paraay 1 instrurnenty i Onty --kh primenemye (Nev.
S17;~?CIICAL Finiij)-ment and Inatru'rients mid FA-pe-ience in Their. Use) 110. 1,
Rese. r h I t.
Miovcolf, 1957 A of Papers of the ScientifIc i a c rs
for Expen-lb,mntal Sur,-ic,'.1 Lquipment and Instmments.
-7. D., T
%*. 3-3
3. GO.--1,30VT T3 K-17,-' ......
L711TICI:-) 11,
0
y--watA3 Cor the conserw~Uon of whole ori.'aris h~- chil-l-ird tvith
c1rcullat-Jon and its. use -i ti crieriments on tr~ivlsid4mll-atlcm of extrarnitias end
of dc'~-3 .... 1
anvzaraay i instrunenty i qpyt ikh
Lencc ir. Tlwir ~Usc
zollip7ont zinC; Instrummts and Cx-eri NO 1
4.
If"17 A me bmem"Ii
collect'on of 'ape,rs c, f c Rcs,:,;~rch In
for E)T)Crimcntal Sur-icall Ecuipment arid Inat-mincNits.
SAVCHENKOP G.,; KRAIT, S.
rRendervt a nlan for the futurelBender-r: vrosvekt. Kluhinev.
A .6
00 A
od PIA
Orr;
Pi
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es
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MITALLOftICAL UNRATM9 CL41SIVICArlow C-1 7V.
ISO., si~sjtv. - No"I"N'
$.Mob* 141040.1p em. V31AII aw a.# 451
-I*,-T* .1 g KT 0 0 9 1 Ir 01 0 AS -4 -5 t
it
'o 000 0 Soso**
**so a * 0 e 0 1.re Wa tZO 0 0 0 *- 0 0 9 0 0
0114?i?# lei
t --- - '
00
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to t
so
go
(J.-A Cbm
of x *ad
of
iAw " MA
all. H so I =00
in thcl= 1w AMP Of &q- NHS
t4p (U) ago
awl of N% M-, W* 'mWrd toltht, 00 40 (u) w1wn'
(M) imfir"m th" pr"w Miss of
w ~ The ?OV-0-41 Of
kno per C.C., ist M.'~
too
atbW CaUgM &W, WA jmsedw.~ AAPO,4" mind 1,04",
004 :be WE-
be, ~mg 000
labod 4011 (UP by C*Dv~
aully
by
us 0 R. T.:
W34 H
t!o
tree
.41ALLUROCAL LITERATURE CL*SSWICATION
01 -ji"Wee
'too
s.6.44 .11 ~' d.t %skill tat axt 391
IT PO IS[-i '-i- --" ' -1 1
Opp 11,11,11,01,11 units Stu n It a 1 14 4 4 0 1 v 0 a 4 3 a
Ole 0 0 0 0 0 0 0 9 0 0 0 0 0 0 0 0'G 6
0 Ole -0 0 0 * 0 0 0 0 0 0 w 0 *0 -0 :1201 801: a 0 0 0 0 0 e'se 0 0 0 0 0 * Al 0
A a- &-* 0 0 0 0.0"o. 0 0 0 0 0 0-0 0
lu, ~A, .41,1006 age popowevy ww -
9 1 K L j -Ay i` -1-o" Iirlall 1211 jaA
oaf 1 1 4 1 1 1 1 It 11 IF I] m is if 11 Is " 'a I - In
4_ y L-1 ~
1~~ COPIES-
004 of
;-Of
1-00
i
00 ;-go
so 1-00
00 so
00 100
Fnwdow detection smid 61bridmatme of it -00
V. Tanammiev m0 0. S. Sugmko d
J. A
Zm
U. S. S. R. 7. z"l(tomr-Im 4-mal. I., F was r.00
lop go OW m todom: To A cc. ad the hot main. &M 00
NsOH -W dkMly al1r. end me anneal of A#No~. Filter,
**a 400
(left WM AgNO~ for campleft ppin.), FaW to the filtrate
00a WM C&(NO#h ftee ficam Cf-. Tbe abwmm of F is sitoern X; =00
V a P0. dams not aPpmr in 1-2 min. To det. the amt.
W F pieve t. titrate the neutral NOW. with AlCh. imius 00
Phenalphth-ld as indkator. A. A. Ek)ebtlinstic
0
'coo
_~ a !zoo
POW
tj~~:j z 290 0
0.
"~:l rl_ 00
~A
Do 0
ASA-ILA METALLURCKAL LIMATE111 CLASSIPWATION -0 .0
--7:
00
AV' is, n3 V, ZZ4k An L S V nd 0 4 0 1 If W 2 0 a 3 a v Ole
19 x I
I" it IF a IF of It it x MI.
0 0 0 0 0 * 0 0.0 0 0 0 0 is 0 0 0 0 0 a 0 0 01410 0 a 0 0 0 0 0 0 0 0 0 0 0
- 01 0 0 -GLO-0-4 _k 0 6000 0 0 0 a 0
0 0 00 0 0 a 0 00 a 000 so 0-0 : 9
a 0 Ole 0 0 0-0
f A is to 11 '1 U 13 tb 11 is if a 11 n n it h 14 it x ?I 1. 1, &; it It 1, 1. 0 ld u 4,
of A s L a --L-J--fo-jt t L AA 06 rX W U 4
.00
00 0
-06
60
scb"] doWssfution W podium ftoodds. 1.
Tile I
00 _"j; A WieJ c
Tansimy and O~ 6. Savrh JD
m.) 7. or, i -i4owny. cf. C. A. ". 1741
Of A. A. It-hiliniA
Zoo
40
Me
t L 1.4 t1l.k It tilto"l-C rL .%%IFK TFC.
00
K It It a at mw n i v.
Of 9
0 a 0 0 0 0 9*009090666NNUOSOf COOSOO900046*60
0 0 a 0 0:0 0 0 0 0 0 0 00,41 00 9 0 10 0 0 0 000 6 0 O's 0 0 ~ 0~9 0 0 C
iA
of
00
A
00
in
#0 it
00 a
00
00 Ar 1;!
06
W
00 .3
04 a
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00
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Ox
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Jl7W -4yWW�i_VJ_
.. ...
BMUMVA 8AVICMMWVA (MM M.). BMrqMXWM
bjol.12 ir, 1, pp. 103-120 10 figs. I diag., 1935. (ROgliah MIGNISMANZY.)
Three groups of bacterial diseases of. &x have, been di&mti&W
S.R. -Flax Institute, visa (1) thm attacking the plant itself.
at the U.8
(2) those reducing seed germination, amd (3) those inducing ph3skok,111*111,
changes in the root system without visibly affecting the tissum
PQru*
The organions comprising group 11) are butyric acid-forming, a
-rmentation of
rods, facultative anacrobea, causing aceton"thylic fv
zoo
carbohydrated and assimilating filtmpri in ruinerall (ammonium slid-
phate) and organic (peptone) (omit. The pathogenicity of the lecteria off
was demonstrated I y a series of laboratory and field experiments
h
f l
i
to
:
aver
es
ons
[a fully tabulated amount of which in gim]. Two typo o sf
been observed, one involving injury to the roota and occurring on A
kinds of soil, &M the odier, manifested by stunting of the root system
and dying-off of the growing-point, whiA is codued to vwipin no&'
Bacteria diminish the yield of straw by 40 per cent. slall of wed by 18
Under faroursible conditiom of plant growth a new root
per oent
tie 0
ARIALLURGOCAL LITIM-TWE CLAbSWKAJ$VJI
ip it 6C a It K Cr of C1 it It It All I I J1 ad a x
a 4 3 0
of 0
0 0 1
06 0
00 0 0.9 0 00 0
-
'
'
system may be formed and the dead "it, re~i.Ctld.
tUdiVidUal
stM
iujK
of bacteria show variations in viruleucc~. and some reduce the yield on
rich, dark-coloured soils an heavily as on poor, eanjIV looms, tjjj)%h
the Reneral tendency 6 for the latter to be Most affoct;41.
Airther xtudira ;r# "niml in tho rofic j)( tho *"I j4jcte6)w*#'
'.U.'.
Iva Of grrmination of '28 pr vent., and also on those toopm.
g
:
le "
'hysiological ohs" in the root kwtem and reducing the
yield by 15 to 20 1wr cent.
00 Iketerial infection offia
pears to be largely controllable by proper
go m
iflago on virgin soil and th use of suitable fortilixerd.
00
00.
00
00
00 *so 0 0 0-66 0-000
0
0 00 0 0 0
6
o 0 0 0 0960
to 13 is " a It 1) A M a, A P i M
M Lt
r 0 1, t-
A
S
* detervilmation of fluorine in atificial
Th cryolite. 6100
00 ;
anatuiev suit G..S,$isxcbeqko. J. APNird Cherk.
(U
S
S
R
742-11(fi
) 9
'Ciiiiiiii74ii)(IWJdf
a .
.
.
.
.
t
.--A proxi.
h
f
mate ruct
od o
analysis Is based an the assumption that
when artificial Nal.Alf's is treated with N&OII and CgCIr,
h
i
Cog
t
e und
vu4vt-d residue will be N&AI(h and CaFt after
mtstrulizins to phent4plithalcin. The F.content can thm
"s -ak-d. after pptg. the unuscd Ca* I in the filtrate a-.
iAiiI-and litratitix the ppt. with KINIaOs. 1I.M.L.
00
[gee
zoo
is
too
.10. 1 -art,-
1.10.4 to C., 48L C.1 a-- Is I
-
-
-
-
-I T
SU RAW 10151' at
V " p tv if OF 49 1 -a-11-77v
0 a I W IN 1 A3 a
&T
~,L $
a
"
WD n
i I 1 11
I
0
0000 0 is **so so* 0 wo
-000 0,0
T:00*000,0 0000 see* 0 0 1, V
0 0 00 9 0 00 *
0 0 ~
s
00-010 0 go 0 0 to q go 40
I A is 1,
It i it a a Z4 A U 1) a a 1. 4 a I, I; ij 4,
4 1 44 U a to It 0
'00
-09
00 j det"Osidon of Alkm In tnisommamm,
steels and cost Vans. 11. G. Karpov and G. S_Sav-.
00 a : -, %_
Oictilso. Zm-likoya L4b, 6. 1051-30MM- C V. u-
0: 11, mcf Or delvi, gif $1 in file juretruce of, Fe lot potim
AIV hr fivaticat of Pe with arm "Ital ark I Then
0 K'sir. call fir lipid. free frIviso KslicK. linvIlctit Irrittilis
wi-fe A stained with ra,t islon still Ulf, Nin. V and othrr MOO
,,teefq. liermsirmpe 1-1.5 jr. of mniple (depending on
aint, id Si I#rt-*rnl) in If)-M) cc. of convd. IINO.. tvap. the ago
of ~olrl. and tranifer It, without filtering front any grarbitc,
is) a )It (11sh. Inlrettfurt, 2 C of CJ),H,. 2-1 g. 11 and
00
filmlly Itat. with KCI (3-7 S. a RX) cc.). After 16 Inin..
so
0 filter off the through a paraffirted funnel and wash
00
0
0
ils-ortnuilIfy, with Iterni-aid. KCI IVAn. Tranider the 4
:0 -r fit sit F
Ill. with The 114 almineyer ftalsk finif 1111talp
0
Y flot, with 0.4 jV Mooll its Phenninlithalr1h. C. It.
0 =~
Z:69
00 f
moo
tie 111
I L A WALLt;PfICAL I.ItIFOATI.Of CLAStIFICATION CSO 0
4. 14P 0
I i~
1:. 11 P I I I I I -. I:- '' .
S a 04 0 m 1 9 so I Al a -3 7-11311;
Is A. .3 is 0 IV IV Cr K K 4t W SE It 91 IT It 13 Is ilut
000000000000000000 00 664606 00000000000 00
~00 0 0 0 0 040 0 6 * 0 0000 a 0 0 0 0 0, 0:0 0 * 41 0 * 9 * 4 40 goo 0 01
H111114114 1116 NXIII04-An 0 0 Ji A 'sit IJU 1411 ima ). it do or a if or a
A A L. F~ 9 A I ~ I-Al., W It 4-1-1 -U.-A A, A k 4t I A lvlf
oil ..Cr_p.R -Ptak$! -oo:ii
A 0
The citiodimetric detumt0stion Of plaunum.
*0 X2,110V atut G. S. Amn. 0offur pbstimr.
-(U-%-,,, R,)l%..
00 ]Nil. (kiln. ton-,
cumparimm 14 th, 111,111,44 for detig. II
00 rowilletricay showi that theY aft, "Ittalk, tic'ettrutt'. but
11C. I't anti flat! 2nd with
so the Ist works b,%t with (J.141.1MIS n
tu-4miS nix. I The eW,)r in the KI nic-th,-I Varies ScIflic
00 0 ~ht with the age of thr m4n, and do,vchw% ""we AI0wIY
than in the SnCh inethud.
00
too
A a LA. -11ALLURGICAL LITIENATU41 CLASIMPKATION 0
via--
Q.c -- -----
AV 00 AS q 4,11til 4.1 a., oil
a K a, III pt a a it of KW it W IN 0 A3 a 3 1 7 411141,
0 00 0 0 0 0 0 0 0 0 0 4p a 0 & 0 OLO 0 0 ce a 0 4 0 0 0 0 0 0 0 0 0 0 000 0
9 0 0 0 0 0 0 0 0 0 0 a 0 0 0
10 0 0 0 *11 'S a 0 0 0 0 0 0.0 4 0 0 0 0 0 0 0
-oalT TTTT7T7TZ!Z%:p!T 0 W. 0. a x lift. voteconst.im further addo. tfilirjit - fr(onithril 1 4p 0
AAL-A--L_j _j_A_j_A_L_jL_A__p_Q_ it t a IF I
W
'
8
- v (in the JIF Cotifelit was rAIWff by ififect 041.6. a 11F. 46)
A.
TU-011r(re -Corti-pounds; of lan
1
1AU= :WJ
I Thropull)%ofifterAlt fiN Men asr* n MI ri'llig III-' enotrill, .r
jblus". 1. G S, TAIIA11-aprit, IIV, Open foll-all-I
'
"
11
l
l
ho;m. IQ, linrl lifisirl"Ill)(111 fill
fil
mitif
, 27
ip. at a
'~
.
IIV;
file
-'ritralutu -11114- in #Ill- lift Will' -Naf)ll
J, fill phase is K,ChfF
Wo l1w In&~%, 4,40 NPAII".
If:OavuIK,CbFrc~xit 00
inethyl torange. anti lurthVI tell as .
afhoot 40_51;
11F
%her.. the latio KF CbF
in .4u
'11.114"alms. (file 1.1~1 ill she I-rcm-lier of Cacti)
;,-$ % I 1 1" Naoll ;..r In,
:I
! ~
.
.
,
-cluing" attrujitly from about a rotm. 2 lot irk asini,
.
;
sis, "
111
-
A2
- fi
i1
ted
l
5
h
l
I
1
k N
Ml
i
fur%. The new solid totpa,,r is KChI:o. synthr.41ftf it,
,
rc,
a
.
I
i.
im-
a
t
tw
.
. w
11
gm,
1y
, Ik- som- say as KTA-., With IIF increasing frmn stmo
rift, %V'tctn
-
f KT
ith i
i
I
h
i
F
i
too .70.07f. the -4y. -of KCbF, I, muLTurat and fidh %ilmlv
ncrra~c.,t s
ncreas
ub*A
t,
ng
at f
.4 o
a
t
l
1.1 t1r;
at lip
at th6 imint
to a max
an,
Iunif--mily. F-K the ),tcm K;rAl-~K,
CbF,-IIF-
,
.
,
KI: 1,111" ill .4n. Ti,cs .11agilly-. the new sifli.j
00 ; 9
I lItO at iN- uru Ta + Cli (4, Taz('; + Chili) in
tPhasr aptcarmlic fr,ml this I.lint On wm shown to be 'win, was dctd. as a function sit IIF. in she jorrst;1`17 14
04111
s -it Ili 3 wayq:
KTAP by artaly-is to( she to-Olict vothr-olit Nosh Ta and Ct) in the m)li,l lihac. The o,"ithine, soly.
se
(,I) TA %a4 Ij-iIvv.I in IlF ~ JINO~. life w)lll, C-111rd.,
,so_s with ncre"5,llg lll~ Ill. to) al )IF :1.75";. e
1-ps-mil Ill, mold..4 Ill omki- life In, N) CAl- Is, IlF,
'
llba%r
i t;jav,; - falls 'I""ll is) a -00
Ill.'. -In, in anams. valrd, 1,
KTAPT:
a1141 I'l't.l. with a K ndn. of at IW 17.111't unit then riles again. )lilt
0
the lips. was oooa4-1 %.fill .011, IlF and dri,fl: Of mnic Olase K,Cbrl + K,TAVT: file "vinfluncil" ply, is Units., 0
0
wish 41,ful,h. the anit. of Kill-.; NL) fly rker"to. w
hat tower thatt the mutut 4 individual mviubiluiri, owing
111 the fir%t firioluct in 41f, Ill:; the 3 loroulucts wurr tq inuttial %alting out: no clict". interaction anti no -Ai,l
aIdentical, KTmFG. Ilrbow i5";~ IlF. file salt decfonmil, .4". are Ollcrio-M. The C'nollitiml, of stability 4 'IAlble,
0
art-orditig to 2KTaI;. + Tal's. Abovr ihat ,,,n
soils. xRP..%tFs (R - alkali metal %I - Tat Cbj
0
th, seolir. ,f KTAF. ill 25' 2. a functi'm of lip is 'it, frPrrwnt"I by a 1)1,-t (if of I - 1, 2,3) 4-lin-t increavvir
i~ "MIgrilellt atilt has a Shall'twolill. ( 15.931, 4-:) at al"Alt 54", (1 IF (to the right of the x,m lifisCil-Q) and irWrr:lsing Rl'
:
h
f
h
f
0
11F. KlCbF, was by dis_,Min, Ch in 111; + , to, t
t o
t
e le
e zero); with increj,,jug Ill
(,feemising
-
Ii
l
RF
f
ll
l
d
0
IIS(),. concg., treating with K' . washing the IlPt- with a
s
Tlrar
l-
-m
), "
Y. i
cr froto left to right bring
0
ale.. at&,] ro-cry,o1g. (fillip 10", IiF; tool healif Is at 110", C'. Ril, K, Na. Nil,; c%3111 I , 2RbF.TaF, is stable at
*
v
the WAR PV(4VC% lift 9"Infillillifilly. 101461111 14 KlCbFj ahjwrr Ili! frourn. I R
1KT-a-
.; 1,
0
10
in dil, Ill, will, Saoll itnellsyl red, ill e1w, prefornre (if ,'Ialdv of It -lightly higher fill than 2Rbl:.TnIj,;
'
0
Ca III ct mones 5 suok. NaOlf jorr pilot. C[jF&. On ral
. call only exist at -,ii,i4crakly higher IIV. NII.P_
,
a'sem"I , the 4 K,CbF1 into raft, only at very high 111.
. (7) All known ('-,fit
-0
00
ill,- soft
V. i.,Ilu-rlll K,CbF,-J[F-
A) and Ill:
I Ilk.Ii Metal 1111'101n MIAtV4 Andl Hilt Willurnbat V% are li,fetl in
.
T
,
was
Iij to .1 ottive,firmed toy inclea-hig '"fly life zimit. -
cluding the fiew KT4F. an-I KCbl:.. (S) Sooty. data h.
.~f
itilh,411 A-1.11"it IM. ulifil fit, et"llpil. Ili, i~e any betirr cnidni fri~ for the witti. of TO And
Ron PrOln
Chilton through Thin,
VIIIIII 0
solo" -IF ORV 04(
--
U Is ill 00
'1' .1
loot ZA --64- Is If a .1 W of I a Cal
, it
If K X If x of K ff is,
4
.1 0 of
0 0 0 0
OT4111, 0 0 0
0 111111 0 of to .0 0 0 1 1: :
00 0 0 0 oil 00 so 0
* 0 0 0 00 go & 0 0 2 0 0 41 0 0 0 0 * 0 0 (0 06 00
rt-44
it )6 JV loll uu )so SIV )61004444J a* Ce
AA---r It, ~ - 4 k i -
: -1 rI_ - 0~ ~,il, 1 -0 *
fildlial't$
00
~ ~'V -fluorfifes of tantalum and of columbium. it
00 -91
!hrnko anti 1. V. Tat),Antcv, 1. .40plitrd Ckepn
k_iPj)(I0j,)(jn Rus%i4n); cf. C A. 41
1, 173M. -(I) The soly. of KgTaftr In 160 In the prelierwe 01
IF Nt 711' flW-1 filerrAllrisly steeply with the eml. of IIF;
fill 11A M.47c flit there I-. file chainjit, In the compfl. of the
V1141 P114W floiji. Of KfiChl's"It Ito' li atirmit 3 limes
10010111041141 VVI fill let Alinot A% lip tile IWAIll P11449 14
K 11.0. lWyntid that pilitit It 14 9tchpil al Ih#
I rionsit ion linint I lip wply is UIA%, (Cli 1114171, 1(1014.114%).
flita it dfll~it Sharply and p-4ist-4 throuSh it 101ti. (Clillif
11.19), Kll(A)1:,,) at 44mit 11111 Ifirvottspil. of the see
go
ji,)~ %111111 PhAW fri"AllUl Cillitt. UP 10 *110"' HP. (2) The See
00 lillemarY jimpitilf, N ali, Pis 10 Were
0o olvemiddi.1 of 911, - ().I lJoIld 1110 Willi"if fill
1. 2. a. anti 11)1;. lit KI, - 1.20,14"$t 111'ainfactj section, it des
tAltidateil and,plotivil no s-Ay. ciirvet tit 9046'rraws flit 601y. Of K4ChFI 10 1/# A4&'01HIWnI 161~14
against Kit. Ilic soly. of KST4Fr i1rctraws with lizereas- for 9,T*Fr. iqots of tile soiy. ratio kojitaki,rap,
ing KF, (Astest at the loweit KF; above V~ KV the soly. Jcjlnst jZF (at const. fill) have a was. it about 5% KF.
rMaitil PrAClk'Aily COnKt.; 111CM.-ting [IF cont:~t Shifts at any Ill? coricn. (3) Frain a weakly acilt (1117) mized
whi. of Taps and Clips. add". of KF up to 2% In soln. Ire 0
t he 901Y. CUt VO UpWAnI1 Wit 111011t ChAllice ill Shape; lc*eKF will ppt. KjTaFr it it Is present at over W).)%; K,CbFr
.1rcreaws tile Soly. of KsTjtFl to Vit Its value, 2% XF to
will lint plit. utiller fliese cuisditions as Ionic as its Concu. it
5"'. Kit. to 1/0; ii-qibly, at this conen., Ki,rapt
I* completely inu)l., the residual soly. ol)%crvrd beloniftig Im-, than :l1,*j,-, If therv is itiort- tit It. KJAPt can still he
ItIltd. pure toy difg, lifewilit.. it vart No pilriti"I Stu] farther
'I,, the Cb salt prewtit in the KiTaFt. The corresponding
rurves for KjCbVP are qualitatively similar to K$TaFr but )y recrysta. from flit. lilt. The K,CbFr obtained by
d quancitAtivOy difterernt- in 1% lip. chanice of KF front cv-dpu. of the filtrate contaltoi alimt. 1;~v K,Taltr; it can
'P -j~4 11 to the soly.of K.ChF,. (,I I/ :too
cf d. lit 2.3. anti
16,70 lip only tit at low cortens. of KI." the 1411 of tically. it iw preficrAble to catfy anti thr septi. at I I IF,
1 - is touch Jower than in flit c&L%c of KsTAFr: thus, Me With th, Cl. ~f.jc. in the- fiffto of V I
0 -SL A ETALLLF'.GICAL LITINATLIVE Ckl$SWICATION
,-FH~ , . _ -- - -- -- -- - --- --_ we 0
"It any 06'
PW 0 W 'k 07 a a 3
it 1; 0t It a It At "a It I ivA
00 0 0 0 a 0 0 0 4111,0 e 0 0 0 0 * * 0 *'616L* * * S 0 0 f .�Lobo 0
~9-116 0 0 0 goo 0 0 * 0 0 0 40 0 0 0 ~g AA ~ 0-0 a 0_9 -C 0 0 0 0 0 411 0 0 0 0 00 oee
0
i~,'
c )
IV
..... I/Reaction61faf Ann filtun 111ti ste th it
cid 11CT 1111
j
%odium aafte-.- F
M. 'kvchrMko.F,
KUM AiR
'Y-C '5tRv1=-Uv3f I am K~rh. Aeliamte -sections in the
wem A - died
systems AIW(Vi~HseMir Its Na salts -wHto u t:
by methods of ccm ductivity. tan.Ci spit"rophotonietry, and
ittry. ~.In sonie cases the d6lation fr6w_ the addl-J.--i i
-tive VWues of pirupertim can - be.',used to det._" COMP11-1
compds.- forifiecf Im wfa~~-, 77he compa; of conapdi. fetvied Iii
AU(CiOA isw'
these systems,depends'en pit.- At low-pH
ut In n UtMI of weaW add tuedia, WAI(C204)
fortned b 0
is stable.
---77777.
r
I'V
SAVCHENKO, G. S.
"A spectrophotometric investigation of the interaction of.dosium
tungstate and molybdate with some organic acids in aqueous solution"P
Khimiya Redkikh,Elementov, No. 2, p 68, 19550
Reactions of sodium tungstate and molybdate with'.oxalic tartaric and
citric acids were-investigated by measurement of the optical density of
solutions in the ultraviolet part of the spectrum. It was found that
sodium molybdate reacts with oxalic acid in two stages with the formation of
a complex salt H2 M003 (C204) * The reaction with'other two acids as well
as the reaction of sodium tungstate with all three acids can be regarded as
exchange reactions or morestrictly as neutralisation reactionsp since sodium
molybdate and tungstate have alkaline reactions (phenolphtlialein).
30; D-413171
c6
alp
ii
V
g v
15.
Vat
Ala
jai
,'IV
7;-t
m
12
5)4 IlOiVEA W
CA
5(4)
A9730150
Tomil'yo.. V. P., larshl#vs. Y, a., 30V/153-58-)-30/30
Ya1.iuLr*ki7, X. A.
1111a1 conference DISOUS8104 0. the Methods of Investigating the
Coup I ram a In solutions
pa moscAam, isuabeaLya koupl.ksoobroaaw"Iya, v rastworakh),
MIQVICAZI lav.*%Lya vysshIkh uohebAykh savedonly. Xhimiy. I
thIalohmakays, tokhaologLva, 1958. Ir 3, py 173 - 174 (9331)
ANSTUCT S YwAS, February 16 %a 21 , 1958 a conference discussion %oak
the town of IV"DTGI Is deal% with the Qbj
:
1 he
At mad 1.4 the SIZI.. It was called a. . d.aL,,..
P!
V11th All-UnLon Conference on the Chemistry of Complex
Formations. Marc than 200 persons attended the conference,
amsood thes, 103 do la&&t*~ frOa TOXIOUS towns Of the U531.
At the conference methods of determining %h* composition of
the
to experimental data and problems concerning the iafluence
of %be solvent upon the processes of complex formation.
0 - ~ . ~- - 2. In the ltatUro by A. - K. 36bko Ad
Pbysiaaj and Chamic.1-7ra-a-17. Usu the
19 11 I-ma,
se 'I',
tha r :ulta
%.~
3 IuSiOA:
#
:
.
.
in &I Q..
to.
of a systematic i4we I sit P
&a sell as In systems by as"s of
the optical method wow dealt with. In the I.atur. by T.. A.
Flalkoy he idea of & ;urther investigation of the coupTox,
formation processes In solutions was developed. 3*.ides tho.
dejerainstAou of She composition and, stability of %h. complexe s
slao the physical and chemical properties, the chemical net,urg
Card 2/ifi and the structure of the complex compounds sun% be Lav.sti.
k -------
1
e
T
a and X. N. Yatsimirskiy in their lecture ~1ove.-t7
m~m#G
4
ga_
rt
%
k
.4 Polymerization UP 14a-Poly laida 14 Solution,.
mQUIL:"d experimental results of be investigation of the
Pairs r'"IiQu In OQXUtIGAI Of Dalybdio said. The authors
Proved that 089401417 the solybdLa &aid within a certain
X"40 of the PH values " the a .... t"tjoas exist* .4 a
ausib... of Compounds that can be sXprosso4 by 4A overall formula
4(g,,ao4)~2 . ZA the lecture by X. Y. Aka&V- a" Y'R.
0-4 4116
5P'T"Ovokir 4Av64.tig411OA results on basic &Its %a 1 14%0
k As,
"count the complex formation 1, ... by ...no of the
,I
P0440atLomatric method were mentioned for Myatt.. with L.
a
06"Law &M Ladius.
IM the sy-lu4tica of their results tb
.
"thOrs "Play" the Method of the table diff.r*aa.. Th.
*&I. ala, Lon of %he GOAD'Outly.. constants was carried but
according 'a She Interpolation formula by S*Wt*A. M. A.
C462212Y~gkiZ. hold a lecture on -PH Me.sure..4t XotKi'd-gr
She 3olutlaus in C, binatioa With tg
o
System at
he
.
f the sys%.a Cu RCI _ 11
Solubility Diagrams . 20 in Inv.stlla-
tLA6 CQXPLdx Copper Cospounds I. Saturated scluttoAg.. I .,
%
Was found that %h f the Liquid 1
!
more basic th=
Z ,,, Lh. increased
acidity of tho soXut1GA from the viewpoint of tho formation
Of hydroxy-ohlora in the clu%jon as explained
1
V- L 1"WAOT opened the discussion with his I.aturej
Lute
po the necessity of utilizing the concept, worked
:us "A 'hs LOT-stigbtIOMN Of the polymerization to organic
hamistry In the obegigtry 91 pqlyn4q,.&r oomyl~x.s. L.
Card 1116 Gr4abore think. ths% tbw no, approach of %he hydrolysis
cost "Ago Discussion an the x4shoda of soy/' 5~-58-3-)0/30
lavem,gatiag the Coo,ploz yorah%loa in 301.%Ioas
taloa%igatina as developed by %b4 54anAtma.Lan school Is of
klgh value. Be also Pointed to she Mov..61ty of studying
the Umolkina of the pol$a#rtzatian proas.o and a 4tana%itativs
determination of the streagsh of the polymers. A. X. Babko
Detailed cut that the study of %h0 polyzer structure was
&X7. 1. P. xom~, M.StLo"d Ix his Idatur. %hot the
4"*
14$4 oldell eTSM-Volysorl get Loa type scoordL.4 to the
:;
taken* -nucleus + chain members- to ne% obtained in .11 ......
The following 6GL.A%L4%G took part At. the dl.....Loas V. X.
901116th-M. A. T. Ablow, 1. S. 1. T. ?".any.v And
9. A. Tataistrakly. - A. K. Racks then discussed In his lecture
-Nothods of Dot.rminlAg %be Disocalstio. Coast"% of %be
Complex groups lit ftlutloas- the sale prlnaipl.s of 4storalal%#
She Instability constants. N, F-Zasar' discussed In his
100SILre "q&.14ulatioa Method* of the Instability Constants of
%be Complex Compounds Accardiag to Zxp.rIa.a%^1 to%.- the
P04.1"ILU.4 of using the known calculation method. of the
instability GCAS%"%S for .&2'ZQUB Osten Of %he GO.p1a. fQvft-
%to& 14 solution. It several .-anual.at, complexes Are fam.4
the displacement sa%hod by Also&& sat Nodl-Ad-r (QQAPL.VsA *7
A. X. Jabko) o"not be recommended far %he calculation of
the, Instability oonw%sas. Th* lwasuror discussed %he 41o.
solaltda sa%hods of the polynomials proposed by D'yorrus,
ladeg. Ronnott, Sk.tchard, 94"lloy And o%hor Authors- Th.
constants calculated in this .07 are 30% very accurst.. it
we* proved that the method Of .".0461vs oppraxt.ationa'a"
1084 to wrong conclusicas as to The whoalcal prove.*** taking
place La She system Th. most probable .1.o
of the physLoal ocastants com be obta4mad by the nothoil of
the loost squares. A. V. Psitsyn, Y*. 1. Takster And L. 1.
Timagra4ava desort4ed the detorainattes, vethad* of %be
inalabillsy constants of she =&lat. oaspLox.s of .&qbSum
arealum And iratt hiob ex. based an the invo.Sigatten of St.
equilibrium displacement of the **.plot formation by silver
L
X.
1. Dol'shakova. 1. V. Taasnay- And Q.-jjL,_gjUL&kA_
sks!
b 14 1. Wri.-OX-121ce Role of sit. Time Y"toe-ra-
:
.
.
,Loa of %be complex roreatlos-. 1. the 44soussioa *A %be
loo%uzoe A. A. Grinb4rg mentioned the% due to the ale.
64 J,aota.at of %he *quillbrt. %us methods discuss.& of
Card 7/16 doteretaing %be Instability constants (palladium And cobalt
-
-
sa
0
ft*a not be employed. X. V. Abler pot mt*4
out the necessity of devising direct "Sheds of pro.Laa the
ONL.Sames of torn. In & stop-is. cowplqx to,
%So&- 9- S. Tatsixtrekty neatlas,.d that the to.t.bility
;W4sWSA%8 Of slowly diasoclatLag ampl.s.. @.a to 401ouLst.1t
PON thAromobealoal data. I- F. Adaso,lob. A. W. G*lu$o
among c%h-rs %ovit par,% in %he &Isausol.a on %he
A. 9. Jahko, requested Inal.olos, in %h. "at soaf*r,nv. 0, %be
tb*sis%r7 Of complex Go-Pou"a . 1.o%- 14 hiah various
GLIOU14tion methods of 'the instability conat&ato shoulit to
discussed by the osampl. of Saw*'. This should Qj.,Jt,
to which d1vorgencles Of the values of to* coast"$* W.
(trtat ritta. of ovoL4%kj., %as, experimental data can load,
X. P- Noner' stressed that 14 %a* determination of the
I&GS-btl&%Y constents all 0.ola.l equilibria should he %.I.%
late "*am% that reader Complex the complex fQM&t1QA process
44 the WQIUSIAA, ONPOGI&III the Adrolrals proodo.s. of she
S*ntr.1 ton ead the addendum. 1. the 1*4t-r- delivered by
Card 1/16 tt
--b"'k0l
P- ZOS-114 'APPIL-46104 of the DISIrlb..
-
: On" '~
L
o
'
,
0atfgatLaa of the St.b&LL%y Case% "t.
"Uoe
C Diezusslou on the Methods at
:%:
I %lasting the Complex Yoraction in Solution.
at Sm. Thorlum Complex Compounds- "suit. obtained from It.
IUu-!.a of thorium,
"Pan"g in %be cycles Y1 ~ .0 - b A*&. - star, and
Z-OX7
1 V 4 hlorafam, motor
*r* give..
;
:
rrom 0.42 S"; . of in th.rius
'
4"pl, WL *h 24$tyI-&4.tQn. a"
Z4
M
1
A
Sed. 1. V. Tczm~oy.v, 0. _Se- ~o end I.. V.
-
-
-
-
'
T
46111h%rov held loaturs, 0. the .;f
Ztf
.
%.f %bo
.
1
sawjTlli~
.OTTOVIA tu. :is MIA.tica of the stability air complex
-pounds In solutions. In tut-'.Zturs al.0 other methods
Of IAVOMtI9&tinq OQaPlmX formation ;rocossos In the solution
discussed ~Pff M.&SUZOM"t, Am"or .... % of %to optical
Mty .4 Wall .0 Of the beat at mixing) J. 3). B.r.sln
hold
% lecture 04 of the ;club I ITEY-YA.-thd
s
In a U4 .a t1'. Phsh cyam..... ..;ZOxa* of Metals'. as
"*ad the, 4at-rained qutatit.-iv. of %be
ro"Iton of the transition of the p1thalanymaides of cob<o
MiCktI, 4appor and zinc. " loll " of the fr.. phth.10-
cranium into the sulfuric "Id solution, far the theoretical
To-aculng, &Ad am " olptrLa.mtol ;roof of the existence of
baad* In the ompl..as Inm-atta-t*l. Th-.. char.aterlation
t
o ser"ed his as a proof of maw ollostron4c, foraulas of ,
phticaloazaclas and It. complex derivatives. In In. 1*0tur
4#11vored by 1. L. Krupstkin an 'The Nathod of Zb* Tan Sol:..t.
MethO4 of ISTOAMiTTIA1 tho jFaxsation and Properties of
"
Co-pl-Kes- It a" prO--4 that this X-Vhod makes it
Or$
possible to determine the number of amplezvo tamed is the
systems their composition and ralatlwo stability. V. 1.
1"notsov, A. X. Ubko, 1. P. Eamme. 1. 3. NumWin and
U. 1. ?='YOA 1001C part In this SIOC'McmiGn.. In %m 1.0%UZO
delivered by A. A. Grinbera &" 3- ?. Elsoleva, on She complex
-
1841adium, compounde-Tri~
.&M. a aceri-L"Sion, number *bate
four It a** proved that in the caaw of . targq chloric. Lad
'aromina ton excess complex** with the coordination number
are formed. Th. Instability comav"to of the.. complexes
estimated. L. a-=.,Ozoct a "a analp"ation
In th: spectraphotomatrIc LAvostlfatlox, of the complex coa-
Pound that can '00 used In systems -ith the faracAlon (or
pr*4OmIn&t1OA) Of One 014410 Q"Flox~ :his method makes It
out 10/ti a.&Iblo to det.ralva, %be Z=PQ4i%I4- "A OCASt-At
complex. In the lootnev dolivarad by X. D. Tatalairskiy,
Karabl~TL the application Of %no theory of crystal.
11
-4 1
line .as ror he determination of ttw composition and
,.
,
structure of the chloride o"Pl.Z.8 of cobalt, n1okol a"
Opper according %a the &bmrpg&ou apactre, Of Shama completes
discussed. It a.. promd, th.t in & bY*rO-h1OriO said
:
concentration above 5 In %b- solution %hero x1*24
an equilibrium btte..n the Z.zrabsdrza &&d antall.#d-ria form
TO. ?. 3"Arsoka pro.od In
at the cobalt ahloro compl
e
him lecture -The Applics tI - &dLOsCTIV* Isotopes LA the
n
:i
I&,,~jj&&tjOA of the Salvation Zq"llbxLUM, in 3OIU%iQA9 Of
Complox: C"Pounds" The poesibilitr of maing d&%& an tug
Lantope, Xghmgs to clarify %to as the, complex and
mechanism of the hydrattoa processes. r. X11- mmat49ft0d
in his lacturs the use or r&"D"tlv InotOPOO in 4t0 *UAY
of 11: " matimany couples#& In A4-44"ous solution$. A. T.
Ablow, V. X. TOLM.cher, V. 9. Kus"I"t and A. X. Golub took
part in the discussion Of the I.C%OX-0- Th* Of
employing the theory or the crysta-Ilina fields In GAVI&IniLa
Card 11/16 %he results obtained from the aboaryti,&A spectra Of' in~ 008-
Coatersam* Vlooastan on the Methods of SDTj1$5-5a-3-)o/3o
lavesussuad the complex Formation LA Solutions
plex compounds was stressed. in the lecture delivered 'by
1. A. ShOk 04 *Th@ 19IT04tigStiG4 Of the C4APIvZ yGraftliOU
by 13.-Xethad or the Dielectric ttrw~abLlity and the Patarlza-
tioaO the prinalpIts of the method. mentioned were proseat.4,
This method was "played for Investigating the coapota44 of
the type of %he -affiliation" prviuoto. Th- loutr. delivered
'my 1. A. Sh.k " re. T!, trim& -taploylad the Id.thad of the
ItIoloosr1a Coastont for IAvsstjC&t%og Complex Coapaurdo of
She Typs of Crystal 301YAtes In 3olUtioms' dealt with the
Investigation of the solvattm of le.nthmaux and cerium chlorides
with ketones, am well am with the owdy of the co.pazda
formed 113 heterogeneous systems with tributyl phosphate and
allria said. V. F. Toro22Y. gave in her lecture -Th. Patera.
gr.phla Method of fA-v-;.tij%%jng the Complex Torva%-.4Z in
Solutions" a survey of the applications of the polarographLo
"%bad LA-the study of the aosplez compounds, &ad illustrated
v
r&1 fluaXazaateriatic feature. of this method. In the
s
Xa Vzo doli red by T. X qjMWka,. -The Cryameopla X.thod
:
:
of AT* Ugating the Campiox formation Reaction.* '~ survey of
POMbIlitim a Of the 4rYOSCOPLO method Was given, aind Its
applIcabilloy in the stwAy at several complex aospou"m of
&"t0 ablarlds with ord"La substances was proved. A, X.
"
I" described the restate of his lovestLgaticas of thia-
:
.
veral a took
Of
A vivid d1a;u0.LQA
:%.1x.
plans %h d. . A. makov &ad u. r.,
.
tj
'L
;
Fliakow o44sidered the oryancopic method of lavostLgatiag
tomplex soupousis %a be of *an.1dorshlo value. C. a.
Totsixtrokly pointed out that the publication of the survave
@a Individual methods of laremilgatiag the complex formation
1*44tioas would be desired; this concern* ampealally, the
pulazographia am%ho4. Th. aryoscapla method should be brought
10 4, level that a-ken the calculation of the equLlibrius
seastants at the processes to be Investigated possible. Th,
biablem of the method of evaluating the ozparia.asel, r.4alls
%team* "to and sort import"%. Many SOL.Atists us. %b*
is )a1ality Gonstanto without taking in$* .400"1 the Way
Is ~Iaob they had bona obtained. The calculation mothad,
employed by A. M. Golub are on. ~toy book, " compered %a
Uas* -splayed &V present. In him I-tuz. 0.
card 1 16 p"mted out Us extremely, great ispars"Go of
eveJuat f the result. obtained. -0 V-11 .0 of the Plo'kii
=4 I
"'..
, K, Babko sugg.sSod selecting an$ or two 4y.%.
that "a "P:t1--0tAIIY well "A %a
%be regal , ,btalawd according to differeat &*shod* so that
It Is POR611at to check "A ... 1,.,, b.m. y.. 1. T~,7,a
took PLC$ to the di.cuaOica. To. AL. 7
Yt-
jkq, diooue4.d As
_
_
his 100%ur* -Tho Xff.ot of the Solvent on tap Couples yorx.%104
Present ONVOIl AN On the State of SquilibrIam, I. the
of
:OPOu-1" 1140 &AfLu*A.. .&tried by the .92veage
l
miles a A u1" state. upon the salvation of %be aye%..
GDOPMA411tGo upon the tabilitation, of the Q"pl.xvo formed
sit the *Yates, uPoA the 8t-p--Ime dissociat
Ion
Gr
%b* agapl"'s
sat upon a number of other The
ju
-
i
a
4
by the dleln*zrla .,notem% upon %as camp I #z
f
r.s. ::
was 414ou ... 4, It was Ocadluded that a direct relation 40.0
"t %bat U -114410&l mature of the **treat just
beI-ke to V. AbIg. and 1. T.
!Awe.. I,---
104SWO On -The $#*a ... AFL -
CIA ... ttso%iga of otakel Cqualt
Card 14/11 "Pyrld'as"S' In TAX40us The Instability 904.1"14
f
h
o
S
e QQmPI#x#0'.0r' determined am, it We. proved shot %k.
couffroaas Discussion an the Methods of SOV/1 5~-58-3-30/30
investigating the complex Formation in solutions
stability of the pyridLast.ol I. ob,&n4.d In day.Adena- an
the 4:1veat. To. 1. 1 his lectux. -The loflu.no.
_LUrLy" In
of Ih solvent Upon -the Composition and. Stability, of Cc-pl-x
IQ a.dio*uoaed the, polwographic Investigation method Of
like chloride and %kLLooy~n&%o complexes of load ia,aqu*ous
othasol solution@ at different content of the AGA-84uscus
solvent ead as a constant Ionic strength. A
ObWwtor of ths Complex forzatIon was found an well as %h4
tastability cometazte of the complex.*. The Influence of
he dielectric comat"t of the solution ask the stability of
b* Investifaled cospl*xos ... prow-d. IQ %he lqctux. by
:
I. F. -TsoLl yew an the -Investigation of Aquo Complex.* in
Milzed Solvents- the main attention was devoted to the &.a.*-
"IF of Ike q"litativ. recording of the dolvation affect.
In Ike Gamplox formation. The applicability of the poloxv.
SrmSh4o method In the determination of the composition "a -
stability of the aqua complexes in mixed solvents as proved
am experimental material an the sh.roodrammia. of the I
dissociation of the o"nLum.a4uo complexes Is &quo*Qa ethanol
Cord 15116 solutions was sontlo"d_ V. S. Tolasch.T. V. 1. gusaot.ow
"d 1. 1. Ton"mWev, stressed in their lectures the necessity
of & &or* complete &ad general investigation of the solvatica
processes. A. 9. labko and A. V. Golub pointed out the
post Import"** of the Investigations of the complex form"
tion equilibria In non-squeoun solutions. &ad made several
GrIlLosa oommionts on the lecture by To. 1. Tur.ya. The
following scientists took part LA this discussion, Z. P.
A44010110h, 0. 1. thoterazovokly, I. P. MOGhMiU and A. 0.
VMA1%1kkh6V. At the rinal meeting of the conference A. A.,
Griaberg# Corresponding Romber, AS USSR, said in Us @poach
that each 4 oooference we. very =Seat. A detailed 4l.c...
also of the deterni"tLon methods of the composition of the
_400916248i 64 well an of the method umed In the study of %be
'queatilottwo ah&r"%.r1mtLo~ of the st.poi.9 complex f.m%-
$&OR was *Xtrosely Useful for .11 no attended this GOAt.V.4d..
CW4
5(2) SOY/78-4-7-15/44
AUTHORS: Savchenko, G. S.,~Goncharov, Ye..V.
TITLE: On the Tartrates of Indium (O.tartratakh indiya)
PERIODICAL: Zhurnal neorganicheskoy.khimii, 1959, Vol 4, lqr 7,-
PP 1558--1567 (USSR)
ABSTRACT: The reaction of indium chloride in. an
aqueous,.solution With,
,
tartaric acid and sodium tartrate was investigated in iso-
molar oeriea of:from O.1.mol/l to~0.5 mol/le The results ob-,
tained by measuring the e.m.f.~, the hydrogen ionco,,,centration7
and the-optical density are shown by figures 1-31and by~ -
tables 1 and 2. The development of hydrogen ion concei.tration
with.a further addition of tartaric acid in&icates a complex
formation in stages. The primary stable complex ion has the
I
ion with
highest stoichiom
etric ratio I : 1, the less stable
'
maximum saturation has the ratio 4 :.1 (tartaric acid : InCl
3)
Figure 4 shows the time-dependent *;-n the, case of
varying tartaric acid concentration, and'figure 5 - the
3+
solubility of the In -ion under the 'same canditionsp.
Indium
Card 1/2 .
tartrate forms a precipitate'in solutions with a ratio
SOV/78-4_7-15/44~
on the Tartrates of Indium
(tartaric acid Incl3 of n 0-7 and a -i I.. The precipitate,
is amorphous and crystallizes only,after several days. At
n > 2 the precipitate -~faraia dissolves. The analysis of the
precipitates is given in.table 3, the molar.ratio.between
C H 02- and In3+1 is 1 1: I.Also the thermograms of the
4 4 6
precipitates obtained at 'n.~-O-Tand n - 2 (Figs 7,8) prove the
same character of the precipitates. Tables'4~_and,5 show the
analyses of precipitates which,were dried above P 0 The OH_
2 5'
content determined by:difference is 0.65 instead of 1, so that
the formation of a dimer with the elimination of water is
assumed* A comparison with.the tartrates of.aluminum and gal-
lium shows that indium differs,from these elements by complex.
formation in stages. A salt of little solubility is formed,
which dissolves in the excess of tartrate. The oxy groups of
the tartrate participate in complex formation. There are
8 Vgures, 5 tables, and 6 references, 4 of which are Soviet.
SUBMITTED: April 8, 1958
Card.2/2
87334
S/078/60/005/011/02,/025/XX.
B004/BO6O
AUTHORS: ZSgavg~h~enko Tananayev, 1. V.
TITLE: Interaction of Aluminam Ions With Ethylene,Diamine
Tetraacetic Acid and Its Salts in Aqueous Solution
PERIODICAL: Zhurnal neorganicheskoyAhimii, 1960, Vol- 5, 110- 1111
pp. 2593 - 2597
TEXT: It is stated that most studies on complex compoundsare concerned
with the determination of the instability c nstants.:By contrast, the
authors examined the interaction between A13+ and ethylene diamine
tetraacetic acid (EDTA) and its sodium salts by the physicochemical
method, with a view to establishing the limits of the existence of indi-
vidual complexes and the conditions of their mutual conversion.' These.,
data are said to be important both for the theory of the complex,problem
and for the practical use of complexons. The study was.conducted with
systems of the general type Me3+ Y4- - H H 20 (the EDTA 'radical being
indicated by Y 4-) The components were AM and EDTA satuTated to dif f erent
3
Card 1/6
Interaction of Aluminum Ions With Ethylene S/078/60/005 11/021/025/Xi
Diamine Tetraacetic Acid and Its Salts in B000060,
Aqueous Solution
degrees; H Y; NaEl Y; Na H Y; Na HYi and Na Y~ Five systems were thus
4 3 2 2 ~3 4
examined by way of isomolar series and series with.a.constant:cation
concentration. Measurements (after 12'- 14 hours of stirring) included
pH, specific conductivity X, optical density.D, in some case13 also the
mixing heat AH. Fig. I shows the change of the H concentration in
0.05 molell isomeric series as a function of the molar ratio
n = Na R Y & AICI for all five systems. While curves 1 - 4 exhibit
x 4--x 3
a maximum near n = 1, two breaks appear on curve 5 (corresponding to the
system with Na Y), which are interpreted as the formation of complex
4
(OH)yf-.~The maximum of the curves
ions LAlY3 and [Al 1 4for n-1
is accompanied by the formation of a precipitate, which was found to be-
H Y. In the reaction of Al 31+ with R Y and their acid salts, the concentra-
4~ + 4 +
tion of H ions rises rapidly at first. Thereupon, however, the H ions
start competing with the A13 ions, and H Y is salted out. This is illus-
4
Card 2/8
87334
interaction of Alurninfim Ions With Ethylene S/078/60/005/011/021/025/XX
Diamine Tetraacetic Acid and Its Salts in B004/Bo6o
Aqueous Solution
trated in Fig. 3 for the process in the system AlCl - Na H Y H 0
3 2 2 2
(for AM 0.01 mole/1).-To n 1 there corres'o'onds a maximum of
3
LHJ andvC. The hatched zone shows the weight of the precipitate. The
latter forms only at n7>1. The decrease of the amount of precipitate, with
a further increase of n is caused by secondary reactions: formation of
[Al(H 4-x y)](3-x) ions. The displacement of Al 3+ ions from.R 2Y2- is thus
reversible. As is shown by Fig. 4, the system AlCl H 0 exhibits
37 Na4y.- 2
two breaks on the curves of pH and AH for n 1 and n = 2. The first break
corresponds to the reaction Na 4Y + AlCl 3 NNaLAlYj + 3NaCl, and after
prolonged standing a conversion takes.place corresponding to
2Na[AIY] + 2H 20 )(A10H) 2Y + Na2 H2Y. The second break displays the
reaction NatAlY] + Na,Y + H 0 --4,Na + Na HY. The acid salt
2 21Al 3
R [AlYj (K -3) i' ely in an -acid medium. By con-
H = 2.10 s formed.quantitati7v
trast, the ion [AlY]- (pK 1.5.7) is formed primarily at a high pH. The
Card 3/8
8733h
S/078 60/005/011/021/0251/XX
B0.04/ 060
legend to Fig. 1. AlCl H Y
4 H 0; 2: klCl NaR Y -~E 0;.
2 3 31 21
3: Alcl
3 Na-H Y
2
2 H0; 4: AlCl
2 NaHY Ya~ Y H
R20; 5: AlCl 20:.
1 1
Lo&end to
F ig.3
1 3; 2:
0 3
'\Iel..10
-3: 4
weight of Hu Y.10
AH; 4:
4
precipita te.
Legend to Fig.
4. 1: PH; 2:
3:
L, H; 4: PH ns of 'Na*Y at
in Solutio
concentra tions corresponding to the n-values of,the systems.
Card :8/8.:
S/089/62/012/005/005/014
Formation of uranium tetrafluoride... BIOI/BIOS
result of the sedimentation of uranium tetrafluoride. (3) Measurement of
the pH confirmed the step-by-step addition of the fluorine anions to
2+
uranium; at n = 2, UF arises, at n72 the poorly soluble monoolinic.
2
2-5H 0 arises. Study of the solubility in the system UP - HF H 0
4 2 4 2
0
at 25 C gave a solubility curve from which the solid phases could be
estimated: UP *2-5H 0 at 0 - 38% HP in the solution; UP (poorly soluble) 45
4 2 4,
at 38 56% HF, and UP *4HF at 56 - 80% 11F. The compound UP -4HP is stable.,
4 4
only in concentrated 11P 55%). There are 11 figures and 2 tables.,
SUBMITTED: October 26, ig6i
Card 2/2
m
ACCESSM im: Ap4oo5833 NU9/63/000/0i2/00~3/004 1::J
-THOR:
avchank -Novokreshchenova pe De
A
L
-ting metal coatings on metal thermal fatigue
!TMM Effe~t Of 10W-MF-.
no 19631 43-44
SOURCE: 'Metalloved.' itexmich* obrab. metallov 12
TOPIC TNGS; therdal fatigue metal coating., alloy coating',
-metal, alloy, steel,
coating
:Bi, ZrL and rOS40 iaLloy coatings
A*BSM, &CT: Th e-authors studjecl the effect of Sr,
the~rmal fatigue Of Ni (IM), bronze., brass,(t62) and, steel (u(h18Nq2 sub-
the
CY ranaa 40cr-130cc-, The thermal fatigue
jected to 1000 cles ia,the temperature
on thebasis off a 9%, 10% on& 20 decrease in sup-
of the specimens was evaluateci
turc strenith and elasticity. The thermal fatigue of the,basic metal was decreas--'
cc -a A
while other, metal coatings Irad
I by more tha -30%b when Ni Inas ~oatcd vith Bi
no effect* Sn and
POS40 alloy coatings stronaiy affect--d the thermal fatigue of
I brasg; zn., that Of steel atv hig~aer tcmYL-ratures. The increase& theraall
bronze anc
pr6;.
fatigUL 1 1
Of Steel with a Zn-coating is explained by the.low thermal I~strainz
produced by active law-
duced by this-,mttal. The decrease in tha=al fatigue
melting coatings is ex -W
Plained by ac Rebinder effect. art.. has: 4 11
Card
ASS
OCTATIONS
-ftidagogi-'~ "I-
ca
r
ZHARIKOVA, G.G.; KOVYAZIN, N.V.,- UJKIN, A.A.j.MITROITOVA, T.N.; SAVCHERKOJ
ACC.NR: AP7002939 SOURCE CODE: UR/0020/66/171 /006 )/'1L1V,3/141;6
AUVOR: Shlyk, A. A.; Stanishovskaya, Ye. X.; ShovChuk, S. N'.;
Gaponenko, V. I.; Gatikh, 0. A.
ORG: laboiratory of Biophysics and Isotopes Academy of Sciences BSSR (laboratoriya
biofiziki. i izotopov Akademii nauk BSSR).
TITIS. Role of phLytochrome in the.chlorophyll metabolism of green plants
SOURCE: AN SSSR. Doklady, v. 171, no. 6, 1966, 043-1446
TOPIC TAGS: chloroplast, chlorophyll.synthesis, light biolomic,affect, tracer study
~ABSTRACT: Effect of phytochrome on chlorophy-Us a and b and on protochl.orophll was,
'investigated in atiolated rye seedlings and rye green leaves under different lighting
,conditions Groups of rye green leaves werg exposed for 15 min to infrared light
,(1.4 mw~cm far infrared light (1.0 mwlcm4), infra red and far infrared light
combined, and white light. -Following exposure the seeds were keptin the dark for 3
hrs before determining chlorophyll levels and for 15 hrs.before determining
;.protochlorophyll levels. In the second experimental series groups of 9 to 10 day old
~seedlings placed on damp filter paper between glass slides were exposed for a 10 to 15
in ~-) and to far infrared 'Light (!
mi period to infrared light (652 mVcor 645 m 737 m,,v-) at!
an intensity of 1.0 to 6-5 mw/cM and a ratio of I or 1-5 between the. duration of the.!--
Card 1/2 UDC:
1
.14p=ag
21M SOY/56-,2;6-4-68/70
AUTHORS: Zaytqe,,r, A. A,, Le6nov, 0, 5,p Zalchmkof 1~ A..,
TITLE: On the Oscillations of Plasma Electrons (0 kolebe.niyakh
elektronov plazmy)
PERIODICAL: Zhurnal eksperimentallnoy i teoreticheskoy fiziki, 1959, V01
367
.
Nr 4, pp 1332-1334 (USSR)
ABSTRACT: The authors of the present "Letter to the Editor" deal with in-
vestigations of electronic oscillations in plasmas of viscous
gases at pressures of from 3.10 -1~ to 5.10-4 torr.'Recording .of
the oscillation was carried out by means,of a heterodyne.circuit
with an independent generator for the decimeter range and an
independent amplifier for the intermediate frequencies. Work was
carried out at a frequency of 30 megacycles on.the 10 megacycle
band. The upper limit at which regular oscillations could still
be observed was found to be independent of the nature of.theLgas.
(He: 2.10 -1 , Ar. 10-2, Xe: 6.10-3 torr). For the purpose of
solving the problem of oscillation excitation it is of great im-..
portance to investigate oscillation dist Iribution along the dis-.
Card 1/3 charge axis; hitherto, such inve stigations have riot been carried
On the Oscillationsof Plasma Electrons, SOV/56-36-4-6,8/70
out without probe influences. The authors endeavored to eliminate
these influences and to investigate the non-influenced oscilla-
tion distribution. For this purpose,they used a cylindrical
tube of 7 cm diameter.and an electrode gap of 2,.2 cm. A figure,
shows the distribution of oscillation intensities at a pressure
for which the free lengths,of path of the primary electrons wer .e
great as against the,electrode,gap;,in the diagram the in-
tenrities in dependence on the distances between~the probe and
the cathode are plotted. It was found that the oscillation dis-
tribution, which is representable by a periodic function, has
amplitudes which increase in the direction towards the anode.
The intensity of oscillations and the coefficient of increase
grow with a decrease-of pressure. Oscillation intensity may,vary-
by more than the thousandfold under these experimentalconditions
along thebeam, At sufficiently high pressures, if electron free
length of path is small with respect to.the electrode gap, tile
oscillations are damped towards the anode, and one maximum only
can be found. Measurements showed that the spatial oscillation
period can be well approximated by the formula 1 = 27yo/ci (v 0
Card 2/3 velocity of electrons in the beam, [CM/sec], and Lj= cyclic
On the Oscillationsof Plasma Electrons SOV/56-36-4-68/79
frequency of the observed oscillations). Ivithin the range of
sufficiently strong oscillations an anomalous scattering of the
primary beam. can be visually observed. This fact is, finally,.
discussed in short. There are 1 figure and 4 references.
ASSOCIATION: Moskovski-y eosudar6tvennyy universitet (laoscoyr State University)
SUBMITTED: February 19, 1959
Card 3/3
21609
S/188/6,1/POO/002/004/010
2-0 141,q 2" /So-z)
B!113/B203~
AUTHORS& Savohenko,__!.,k2_q Zaytaevq A.A9
TITLB'.-~ High-trequency oscillations in a low-pressure discharge
PERIODICALt T!estnik Moskovskogo universitata. Seriya 39 fizika,
astronomiyaq no. 29 !9619 -19 25
TEXTa The authors experimentally studied the effect of pl"ma,boundaries
on the excitation conditions:and intensity distribution of electron oacil-
lations of an argon plasma. They studied oscillations in a low-pressure
discharge in a cylindrical tube of 65 ,mm diameter with an.indirectly heated
oxide cathode of 3 mm diameter. The tube also contained a mobile antics-
thode and a side electrode. The mobile electrode oould be connect ed as
anode or electron reflector;, in the latter casep the discharge started
glowing on a voltage supply between cathode and side electrode. Theos-
cillations were indicated by a cylindrical pr.3bFj 0.08 mm in.diameter, which
only touched the beam to keep the measurements free from interferences
otherwise caused by the probe. The authors observed various pre3sure-de-
pendent forms of discharge. The form shown in Fig. 29a occurs at a
Card 113
2i6og
S/ 85J6110,:)0/009-1004/01 0
High-frequency oscillations in B4121IB201
pressure of 10-2 mm Hg. A pinch Is formed on a decrease in preIssur e,-. At.
.13
a pressure of 700 mm Hg, the pinchbecomes stronger. -Behind. it, there.
is a scatteringg and the intensity of oscillations inereas .eso At -a
ressure of 5--)0-3 mm Hg, a sharp pinch is formed. Behind the pinch, there
is another scattering, and the Intensity of oscillations:coatinues increa-
sing. Finally,. a pressure.4~ 3.1C-3 mm Hg gives uniformly diver Iging beams.
No oscillations were observed,in this case. A certain pe.-riodicity (pro-
bably due to the effect of plasma boundaries) was noticed with respect to
the.distribution of intensity of oscillations with anode-cathode spacings
of less than 26 mm. Considerable oscill-ations were also observed., I
standing wave is probably formed due to electron reflections from the anodep
which enables the oscillations to te amplified. It the mobile electrode
has a negative potential relative to,the cathode, the electrons are reflec-,
ted into the plasma by a retarding field formed aeaz, the.reflector. The
effect of the reflector on the character of.oscillations gradually decreases
while moving away from thecathode, and fina'lly vanishes. When determining
the range of generation of oscillations, the authors found that oscilla-1
tions existed for all. ano,de-cathode spacings if the d1schaTge showed a
Card 213
w
PF (zo -
6~ yApA
?OAu
L~3798-62 EVITUVE
~.11:ff AT
CES
SION NR: AP5013367 UR/020T/65 000 002A 4
/003
AUTHOR: Zaytsev, A. A. (140S.Cow); Savchenko- -1a Ko-, 016scov)
TITLE: Electron oscillations in a
plasma
SOURCE: Zhurnal prikladnoy mekhaniki i tekhnicheskoy fizikij no. 21 'i005, 30-14-
-TAGS:' plasma oscillatib A i t ~p_
n~ intens ty- d
TOPIC istr-ibut o ~y:,
~7.
Tbeam interaction -
-ABSTRACT -Perib iz s~-JnAh p tial' i;tri
Conditions. under-whi-ch-, -Ity
.d
of the intensity of plasma o -'e'- udi-
-Wer :,at e
_ t;, a
it
experimentally. It was found that.period c y occurs in the und
-prese
.:secon 'Wave'..
.-7.1--which.:reflects- primary., or,einits ddryelectrbns~_t orM,A-.-refj:e'Ado-*t
b6
the absence' -of such a undary-s -the-", oscillations a.- - h~qplffted ~ln~ 4cc rddhce- with',
the theory of convective plasma instdbility~ The e46 im&nts --were conducted v4
1 a plasma produced in several types of argon-filled discharge tubes. The role of
the reflected wave in the formation of periodicity was considered first. The
distribution of oscillation intensity along the discharge axis was determined for
two different cases in which a) the reflector plane was perpendicular to the
direction of the primary beam, and b) the reflector formed an angle-or.450 with-
ASSOCIATION: none
suBmi,.r.vB - iojui64
ME
ENCL 61, Mrs. p
NO REF SOV: oo6 OTHM: 007 ATD, PRgSS:
d- 2a
~,1'5 Yl
SAItCIM-NKO, I.A. I I . I ~
__66
L 26612
CC NR: 6609440
thd -fobal'--- ,poin mtra,tor- ith.
contiz~i6us-vflow. caloirimetdr is:.-plac'ed'on t of. the~-conq
c llect f -di ffirdgms'to locate: the beam- alongAhe - focal.*- ima M6 ~zibdii~'
0 ion o al ge 6
Haiti: '~~e*,. ~iottea ~:6 P
0 rived,-N "qA' th e
ea -With! the'dbove
theoietiiial e.
JA .fp'Wid,.to.- e ~Nc~ci, ~,'For:Ah~ ~~dbAdbnti"qrj,
b
CIA
g.
P "-ta't
Card 2 2
SAVCHZNKOV9 I.I..
Roentgenologic endo-suscultation and registration of variations of
movements of the cardiovascular-system at the esophagus, trachea,
stomach, and duodenum.Xhirurgiia no.11:18-27 9 154. (MIBA 8:3)
1. Iz laboratorti rentgano-fonodiagnostiki sefdochno.;sooudistykh
zabolevaniy (zav. I.I.Savchenkov) Instituta terapii,(dir. prof.
A.L.Myasnikov) Akademii meditsinskikh neuk SSSR.
(CARDIOVASCULAR DISBASES, diagnosis,
x-ray a nlo-aus cult at ion technic)
(CARDIAC HURNM AND SOUNDS,
endo-ausculatation. roentgenographic technic)
SAVCHENKOV, Ivan Ivanovich, kandidat meditainakikh nauk: KIPHIS, S-Ye,
redakt.r'; -VI'
.ITRIYEVA, R.Y., tekhnicheskiy redaktor.
[Phonoroantgenolog7 of the heart; based on nSunday Lectures"
material'of the Polytechnical museum] Zvukovaia rentgenologiia
serdtsa; po materialam nVoskresnykh chtenit" politekhnichaskogo
muzeia. Moskva, Izd-vo, "ZnAnie." 1955. 23 P. (Vaesoiuznoe ob-
shchestvo po rasprostranerd,iu- politicheskikh i nauchzWkh znanii.
Ser. 3, no.24) 8.- 9)
(Heart)
VISWIVSKIY ' A.A., professor; GALANKIff. N.K.. kandidat meditsinskikh nauk;
DZEAGARYAN, A.D.,.kandidat meditsinskikh nauk; SAV V, I.I~v
kandidat maditsinakikh nauk,
Surgical treatment of double aortic arch.-Khirurgiia 32 no.4:56-62
Ap 156. (MLRA 9:8)
1. 1z Instituta khirurgii iment, A.,V.Vishnevokogo AJW SSSR (dir.-
chlea-korrespon4ent ANN SSSR prof. A.A.Vishnevskiy-) i Institute,
terapii ANN SSSR (dir. deyetvitell W chlen AMU SSSR prof. A.L.
Myasnikay)
(CARDIOVASCULAR DWXCTS, CONGMITAL,
double aortic arch, surg. (Rua))