SCIENTIFIC ABSTRACT RUDKOVSKAYA, G.D. - RUDKOVSKIY, D.M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001445920019-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 20, 2000
• Sequence Number: 19
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

24426
S/07 61/031/007/008/008
Synthesis of N-substituted ... D229Yn3O5
filtered and th-,- filtrate distilled in vacuo, Fractions contained
methacrylic acid, MAA and from the fraction, b.p. 750C/1 mm, asmall
amount of MDMIA was separated. Recrystallized from heptane, m.p.
90.5--91-50C. Soluble in common organic solvents: Polymerizeo in bWk-
or in concentrated solution, forming a soluble thermoplastics poly-
mer containing no unsaturation. Preparation from CH 311~112ITC1 e.nel TFAC
by the method of G.M. Chetirkina [Abstractor's note: 1-1,c_~_-Ferenc 4-0
original source not given] is subsequently explained. A 34,8 %
yield of IM11A was given. Jkfter boiling equimolar quantities of CH,
NH HCI -.nd 1,1AC in anhydrouz toluene for -ten hours some CH NH HC1
2 3 2
lto-i- filtr,,tion of the solid. toluene is distilled off
and -"dual oil fractionated in vacuums The fraction b.p. 74-
B2 0C/2 i_ _d n 20 1.4740 and was N-methylmethaerylamide. A small
D 0
amount c--,' .-.-'A also crystallized out, m.p. 88.5-90 C. On carrying
out the rua.--l-ion in benzene and boiling for 16 hours,-N.-methylmetha-
crylamide obtained in 45 % yield. blethaorylic acid anhydride,
Card 2/3

24426
S/07 61/031/007/CGB/008
Synthesis of N-substituted D229YD305
b,p~ 83-84'C/10 mm was ob-tiained from methacrylic acid chloridep me-
Ilo.-crylic acid and pyridii~c in 66 ~ yield. There are 13 references:
3 'loviet-bloc arid 10 non-';oviet-bloc. The references to the 4 most
recent English-language publications read as follows: R. Dunbar, G.
White, J. Org. Chem., 2-3, 915, 1958; A.W. Titherley, J. Chem. Soc,,
79? 391, 411, 1901; 81, 1520, 1902; 85, 1673, 1904; 101, 1871, 1912;
Q.B. Thompson, J. Am.'Cheni. Soc., 73, 5841, 1958; D. Davidson, H.
Skovronek, J. Am. Chem, 80, 376p 1958.
ASSOCIATION: Institul visokomolekulyarnikh soyedineniy Akademii
nauk SSSR (Institute of MacroL.olecular Compounds, Aca.-
demy of Sciences, USSR)
SUBMITTED: July 16, 1960
Card 3/3

L 13294-66 EWT(m)/E'AT(j)/EWA(c) RM
'ACC UR: AP60003213 (A) S(XJRCE' DE: UR/0266/65/006/02110017/0017
JNVENTOR: Sokolova, T. A.; Rudkovskava, G. D.
'ORG: none
oA
,TITLE: A method for producing dimethacrylamides. class 12, Nq_,-jZ525-j_fAwounced
by the Institute of High Molecular CoMounds AN SSSR (Institut vysokomolekulyarnykh
soyedinenity AN SSSR)]
iSOURCE: Byulleten' izobreteniy i tovarnykh znakov, no. 21, 1965, 17
'TOPIC TAGS: methacrylate plastic, polymer
1ABSTRACT: This Author's Certificate introduces'a method for producing dimethacryl-
!amides from monometbacrylamides. The product yield is increased and a wider selec-
:tion of raw materials is provided by treating,the monomethacrylamides in methacryly-
~chloride in,the presence of magnesium bromoethyl in a tetrahydrofurane medium at
C.
SUB CODE: 07/ SUBM DATE:, l2Jun63/ ~ORIG REr: ooo/. OTH REF: 000
jw
1_C rd_1/1 UDC: 547.391.'31398.1.07

RUDKOVSKAYA, N,Te. [Rudkivslka, N.E.)
Effectiveness of tough(saing children under nursory conditions.
Ped., akush. i gin. 23 no-3:30-34 161. (MIRA .15:4)
1. Ukrainskiy nauchno-issledovatellskiy institut okhrany materinstva
i detstva im. Geroya Sovetskogo Soyuza prof. P.M.Buyka (direktor -.
kand.med.nauk O.G.Pap [Pap, O.H.) nauchnyy rukovoditell deystvitelInyy
chlen AWT SSSR A.P~Nikolayev).
(CHILDREN-CAREE AND hYGIENE)

RUDKOVSKAYA, Ye.V.; LOBPIIOV, S.D.
Case of visceral moniliasis. Zdrav. Kazakh. 22:no.8.,69-73162
(MRA 17 z4)
1. Iz kafedry terapil fakullteta usovershenstvovaniya vrachey
(zav. - dotsent- N.A. Tiomo) Kazakbskogo meditsinskogo instituta
i patologoanatomicheskogo otdeleniya klinic-heskoy bollnitsy
No.2 Alma--Atye

L 35831-66 Emrr(i )/-Tn,1T(m)/T/VP(v) IjP(c)
ELI /~Ai
ACC NRI AP6ol5729 SOURCE CODE.- UR/0032/66/032/605/0~68/0570
AUTHOR: Voy tskiyj S. S.; Rudkovskayap Z. S.; Geretovskeyet N. L.
ORG: Scientific Research Institute for tbe--PlliaLg-tigo--InO-p-st.ry-.(i~',Bucbno-
Issledovateltskiy institut rezinovoy promyshlennosti)
TITLE: Determination of the specific adhesion of different adhesives
to fiber type polymers
SOURCE: Zavodskaya laboratoriya, v. 32, no, 5, 19661 568-570
TOPIC TAGS: adhesive bonding, elastomer, chloroprene, cyanatej J'~Wrvtnc-
ABSTRACT: The article presents a simple method for determining the
specific adhesion of various adhesives to fiber type polymers. It,
includes a consideration of the effectof the nature of the elestomeric
adhesive, the introduction of olyisocyansteslinto the adhesive, the
thickness of the layer of adhesive, the duration of vulcanization,O-and
the temperature of the layer of glue. With respect to the effect of the
nature of the adhesive, it was found In a qualitative way that the use
of natural rubber produced bonds with a small resistance to
stratification; it is recommended therefore that use be made of mixtures
c-f* chloro-orene rubber containin vulcanizing agents and polyisocyanates.
Lizard 112 UDC: 6200179-4

ACEC NR: AP6015729
A figure illustrates the effect of these additions of polyisocyanates
into the chloroprene rubber mixture. With an increase in the thickness
of the layer of adhesive substance (163, 385, 585 groms/metor 2) the
adhesion of a chloroprene rubber mixture containing polyisocyanetes
increases (2.1, 2-4, 4,8 kgf/cm). Orig. art. has: 3 figures.
SUB CODE: Il/ SIJBM DATE: none/ ORIG REF: 002

Rudkovski', boris, 0 byznamu uceleneho fenologick eho nozorovani. PLACLva v -1rirode.
(The lii~66-r't-rnce of a comprehensive -henolol-ical-bur stud7 of birds in their nitpr--l
surroundings.) Meteorol6gicke Zpravy, 4(506)tl27-128,1950. In ~:zech. KII-B H-
.The author supZests that the time of arrival -ind departure of Agrating birds,
whichis linked to meteoroloAcal fa-tors, shculd be closely observer -ind that
obs~-rvers should be able to identify birds bt sight a nd hearing and to n,-ty -ittent4
ion to certain Plants which develop .-it Ve same U.-ne -.is com-tin birds arrive.
Dditor Jo3uf brablec nointa out in -t note that for Czechoslov,tkia, with It- varied
~Usatic conditions and torography, it is not nossible to draw ge-ieral ccnclusions
from the behavior of birds tind he mentions a few exaTples to rrove di3cre"AnCie3
between the ex-ect(A And actual arrival of certain srecies. jub.'%:ct i~-.adlngst
1. P~ienoloV~ 2. Bird nlpraticns 3. Czechoslovikia. -G.T-

BORON12 F.; P.Ui~KOVSKIY. A.
ExRmination cf the functional state of the Ilve,r in alimentary
tOXICOInfeCtiOnS. S07. med. 28 no.!O-~29-31 0 165.
(M-114 18 11)
1. Klin-ika 1nfektsionnykJh b,-A-p-may (za-.-.- dotsent doktar meditsiny
P
Boron') Meddtsinskoy akade-jOli v Belontrke, Pollsha.

KAYY,,NICHNYY, losif Solomonovich; KALINOVICH, K.I., inzh., retsenzent;
jUIWaVSKIY"..-Y-q., inzh., retsenzent; CHISTYAKOVA, L.G., inzh.
red.; GORNOS'4"AYPOLISKAYAi M.S., tekhn. red.
[Brief handbook for a heat treatment specialist) Kratkii spra-
vochnik tekhnologa-termista. Moskva, Mashgiz, 1963. 285 p.
OGRA 16:7)
(MetaAs--Hent treatment)
(Metals--4%ndbooks~ manuals, etc.)

Th'FELI
ifl the (14
n i ae j 0 n 7 L j-1 165. k jYh
V06SCI-PJ- 4J

GANIKIN, V.Yu.; KRINKIN, D.P.; RUDKOVSKIY, D.M.; TRIFELI, A.G.
Effect of the temperature of formation of metallic cobalt on its
reaction capacity in the prccess of carbonyl formation. Khilz.
tekh. topl. i masel 10 no.10:11-14 0 165. (MIRA 18%10)
1. Vseioy-uznyy nauchno-issledovatellskiy institut neftekhim-
ichesk-4kh protsessov.

F
It u SA a a U m it a at a so a east
A A. C 0, It 1. 1 U Ill a ONO a 00

T

00 h .00
&"
Ob d1larillated PMucts ft- TIP--P
'
l lfrudeletv
rcaducts of oil. U-%LltAAdhvvskiL Trani. I
-
J .00
.0-lit
colvir. Thrort). Ajapqed cvm. 193.1 2, Ill. 1.
.
~titmS4 mtAl
ti
d
iWi
f
see,
, con
uc
ng rr
ty o
y
(jju5),_Thc poss
and
ressures has bccn druiowttatc-d
t normal
i
1l
0
'31 .
ca
t
y a
p :'
00
ustrial tucthods baed on diftermt (ractions of crackcd
and twarene were worked out. A dewription of
talysts, raw nmter" and prucrsw% is given.
of

0"
go*

so
Of
so
lp
0 ~

O
0 zoo
'00
00
use
wmt,-
ts
: g
N - I L A ACTALLU ICKAL l
llINATURI CLASSIFICATION o
ts
a e*
aid., $M .111. Oak, 00. In T
. W

-a
Tonovi W-0.,-all
$*job') .10 0,11 all
al a
Ojai))
97, U - "1.' 4 -
It it F, or a Is Al I a OW a d 9 1 W 91 5 a . .....................
0, 0 0 0
0 0 0 0 4 0
,
: : : : : : :
0 as a,
st 0 0 0 0 e
e

0 0 0 0 0 0
Y 1 1, Is 31 11 It U U
A
00

0

: of
-PY C
0 11, RU
00 Kkdm.
I*Iluij.
.11aub
the
so j ! "-c' i
Iurluh
~
from I
0: "on I
be f
0 ("1r
.
251
0 frorn I
0000411 00004
"MR -, - I
rr Mir,-Rw
11 Is It F Is It is 0 at U U M a I I I . me 0
-1 -,T- L M 0
00
.00
Un -st&sb at the reaction of formatloW at
do from ethylene maid hydrogen chloride. I 1. -00
skif, A. G. Trifel and A. V. Froii. Ukrain
.
AO. Wilis. Tell V 7-921(liCM) (in Ru-AiAu).-
-00
S. 41( the ".0cliort C.R. + ficl ti Etcl were .00
&in[ 41,vitnifin. of FtCI at 17,11% 3x)*

2') In %p
con%tructed aps), ojluotzt~l I
use
"cro(HiCJ#cmlx1v%Ipptd.unMhxrl. Th,
zoo
" effectill with dry sm.". with and without
Itiluent, (if or it milt- of CIL. C,11. and C,If.). Cis 0
ial lem-lions of the reacting llm-~ %ere caltif.
roe
1!rsISandtheprenuresiniheapp. Thereta.

u
the fl. consts. snit lerrip. is expresw4t I'v
7-
iON
- bid Pn.iP(-,rv.1Pp,.j - 4.1mi
,
0*0
The thermal effect of lilt rrut-lion, ajnl.
0
oil. coasts.. is 13.4 Cal./mol. C. 111.1ne -
-
l
1
I
moo
J; z
=60
0
too 0
A S a I L A .1 TALLURGKAL LITIERAT CLASSIFICATION
too
Al Joe
V An A I; a cm o ne'strusaa 3
U is AV 00 91
10 1 0 o 1 11 1 Us 0 0
0 0 0 0 0 0 0 6 0 0 0 0 0 0 0 11111 0 0
67,40 10 19 0 0 010 0 0 0 0
4 0 0 0 0 0 0 0 0 00 0 ale 0 0 0 0 0 6 0 0 0 0 0 0

~- ~- 11
0 o 0 0 0 0 0 o * 0 0 0 a 0 a 0 0
v is It is u is w it w pt a
A It C 2 L-~-Z -rA--X---I-L-i. X--P. g- I I A.- I#. Y 11.04 11 11 no -1
I cc
oo fit !.ot.s
of -
go A
00
so Ar
0 * t
preparation of butYl chlocides from the CoM
00 buW~ao IfGciiuu of home ciracking gm
06 11,114TAillkil and D. I t'kf
L;. -;. R.) 1, .10-1-40t IllM).-A Yield of 77r'L
00 tA c
'c,,, of I ed accondmary HuCl -s ob in
UTIZut, Dickmno and Rjap-rs J(
Os. J- ga%lno JJCJ tM the VMfk)Fi
00 by. At-tins with
ImltTl,w. in thr P,~
rhr loarlb,11 lot Orvalcts
0 * 'j, J MrA Cl
00
00
* &
'
a
000 0 00 00 000 0
000 a
A It It 31 36 S Is V X IN a at a U u *no
_I _II _, 1. .1, _ , _, . .
A- N -1 -1-
ffata~,

-00

atfated .06
me. A- -00
. led.
MeNCI .00
by the as* 0
A. 22.
it rni2t- =00

vl ~.,n 40*
It L
00
*!,00
0 0
er w
~aoo
i see
04
of S. A OTALLUFLKAL Lfff*ATIRf U aStIFICATION
It
r3l~
0 00 0 0 0 0 0 0 9 0 0 0 0 0 It 6 is 0 0 a 0 6 0; a so 0 0 0 0 0 9 0 0 0 0 0 0 0 40 0:
- ~044`
0 0 0 0 0 o 0 0 0 0 0 0 0 0 0 0 a 0 6 0 4 0 0 0 Cle 0 0 0 0 0 a 0 0 0 0 0 0 0

0 0 0 ej**414` VFWA 410 0 0000*000000000
03 Is Is to If I? to 19 a 1, - V X 20 As 31 9 U Ad a k V m p 40 of a o a L, 0
0 A 2 r _.A~ I r A a L

praparstift of butyl dLktWes from'&@ scamtrawa -00
0 0
butyitn*kacdoneivapw-tba"aack*PM. 11. 1).
so 7 itudkovsO and A. Tfifel. Org, C". led. ((: S..
_
5 00
Os ic S. R
.) 2.203~
(19311); cf. C. A. 30. (MY21.-Nuly lix)%
SlesCCI was obtained h causing sawous HCI to
rt -09

00 a
on a
valsorixed mill. of hICIF- Clit (1) 24-35. normal butyk-mrs
1.00
0 441 NO. bivinyl 12 -18 and Cill, hydrovarlsons 21 .3110 its t It,
6
ne
tw
f HiCl
l
~ ~00
e o
w
. an &9a woo
t
at 5o 4)o
awl is
.Ilntart
time of 3-15 see. At this rate nofmal bulylents aml bi.
.00
I virtyl pratt-tically do not react with 11c1. while I mul Aretv. -00
Imes give nearly IIK)% routtriqlars. Chanuthig jjj~
00 of IICI it) I frosu 1: 1 to 2:1 showed no effect on the yield .00
00 j tit-MraCCI. The ltitesirner of hi vinyl and avet yienc% catt"I =00

00 Impid poipoing of the "tilyst. U-0 of XIAI. w,A4 Alone
wit hoot MCI, F"luced the Vicid .4 %fr.CCI 1,):10-. 400
Y1144. IIIAM'. zoo
00 rote
*0

see
0 .0 0
00
0 0
see, 0
00 t
A to At a WALit.#`~KAL LITINA11,81 CtASSIFICATICh It
66 8 -100
00 t:
-7w--
r i, it uo a., 1, goo

i W tIA
0 We 0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0
0 0 0:0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0
0
0
0
O

1?
0
#
'? ?
T
iT" ,
T
;;a;;;,
u M a
At" Met*
A A.- V-v .1-L-L'" I S
PRAL A -I -I

0 A
:
0

purvisewbis catabtic convwsiion of n-butylenss; .00

into
A. V. FMn,
d lee

Jr
an
AKOVA (Compt. rend. Acad. Sci. -00
U.R.S.S.. low, 4, 373-~-M).-IQiiant. conversion
of x-butyknes into isobut
(l in prese ce of
=

!dx different catalysts In e at about 300*
= 00
and equilUum relatMshfps am determined between
j 263* and 4W. SIO, gel-HPO, promoted the largest
i
Id
f
e
(".3%) o
(I)- F. N. W.
~ 0

ZOO

ta v too
f a S L AW ALLU94XAL LITIN-T"t CLA$MFKATOG~
400

U 5 AV to A
o
!*1C Keg a R t( Of a
1A 'w 0 -j Al a 3
KLO A IIM 0
d"i
0
0 t
0 0 0 0 0~0 0
0 0 40 0 910 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0 4 * 0 0 0 *1* 0 q 0 0 0 0 6 0 0 0 0 0 0 0 4p a 0 0
0 0 0 0 0 * 0 0 0 0 0 f 0 0 6 0 0 a 0 0 0 Oil

0 0 o o 0 0 0 0 o a 0 0 0
I I a is 11 is w 11 14 It 11 m 11 a p a #1 .1 a
L A L a P p 0 0 1 v I f A I I AA N U 9b 91 1

-Ape

,110 lis'lloll "t cg.ck..l too.,
I uft flutil Sh. bulan. 1-11
-00
N. AWkmsmlim owl 1). . kii~.
1 .
.141. ME.'. 11'. Wit$1.11f
1. ImIll'otil.a.0 "O$ All 4 ... I
11-V

lot
0
=9

roe
got
gee
1.i;so

0-1 so
bee
ties

' lr
'i
it x.
.,T
o

DITTO
I a I, a to u IS 14 IS 16 It 0a
A- a L 0 0 4p;-
J, Runion XYMM& 41 Sidi adaze
0,10CRI1,11% AND P1100101"Is 0.0t$
00
lo
09
10

f 1
I
mmim" of isdaytrial US-
-00

I
c
0
I
t
!=
zo

a
0
0 1
I

ou
0vw a am 0f0
64
kk z
o
9 111F
M3
-
-'
R. T.
Zee

a 0
gee

11100
1
300

A Ia. I L A AtTALLUOIGICAL LITERATURE CLASSIFICATIC" Cs 0 0
Ila. 40.01,
INIOV') OLI 0-- Oft billil ow a
r .; tool
'
U9 AV 00 IS
g 4 F II
a aTZA AR 14 Im a It I I It l1aSa as V RA
xKW n114
l
11
1
, w
t U
4
11
11
, 0
11
t
o
00 00 0 0
1~ 0 0 0,000000 0 000 0 0
0
0
e
o
0
O
o
0
0
0 000000 o0
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a 46Af 0 0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0
0

0 9 0 9 0
0 0 0 0 0 0 a 0 0 0 0 0 0 0 0

A L 6 L A a j A L J; f 0 A I I V Y V I I A U of Los 19 W A I
A -f

0
0
Synthesis of ethyl ChWde.

: V. K. Paxhitnov, W V. tvanov,kif
N. At--k-ndrv,
1.00
0 a'- xiiii N. S. (kA(xiJtjn, ()rj, ('Arm. /.J, it'. S. S~ R.1 4.
-00

CC C. it, 30. ~ W. -Contrary I.,
(liKj7j;
00 A
letters. ri at. (C. A. 28, -P):Z*) the traction lvclw44-n drv 0
00 llCl and Ctli.with a cutalysto(anhyd. AICI, mi,livistlett in
00
l F.tCl itioceeds satisfactorily at tritips. aftivr
Oe e The rractitni rate i=ruws with inerrasing Irmp. ( -79: -00
00 to giving in the interval 1wtwtvjj atut - 12 500
00 j 9S% yields, The rtL1 obtained at -!Wp* "asuirst%f
liolysisteri anti at -12' 107v polyiners. The addri- of =0 0
00 a 10 g. At to I g. AICI. iticteased the inotluctivity front 7m.
Of j; WII g. to 504) it, Etcl. Vicidi of 95%, (9117b Ftcl) it-
~ii
00 Id. wish air anti with cracking rai-
%UJIM front CII14
(II.Cit.atif[Ctifo)byworkitiprat -27'and -'W.
so Chas. Diane

00 go 0

o
00
=00
'kill, 10

0
ago

A I a . S L No TALLUPGKAL LIUSIATIAE CLASUPKATICh

b
,
,
I 2.
4
W
u
to to It it a
It 1, or
f
W
8
1 n a
3 9
0 0 0 0 0 OA 0 0 0 * 0 0 0 0 0 0 0 0 0 0 0 a 0 0,0 0 0 4 0 0 0 0 0 0 0 0 0 0 0 0 se

of 00060009906060 0 0 4 a 0 9 0 0 0 9 q 0 a 0 0 0 0 a
0. a all's
A
a 4r L I L_j L 4 1j.f f 1, AA LO U j

i'
'"Pbi6 ITOIII hy&OC&rboD Xases. M -
-
a
il
NO ~11
lk
Kk
0
V
4C ;-so
im,
s
nd A. V. Fro'l.
ily
,
1
.
k
m
l
OM, '.'~~A review covitring the mtxlu~ts of til-t- klll~ "I
Laid. hytirmalixMIS undcr varil"Is C-ludili"Cl" IN,I) Ill. Ill-

I'm V
64 mur and catidyits orpt alkylatwis aud
SJOICIA1 1111VI16PIl II 114id 1-1 lilt Ill,-
Ort
InAtIC Cifill
d
t
as l
$.
p
thICINKI of A9141 Of 1--i, IAIIC. It. R,
.60

=00
00

00 zoo
400
Of a

of
00 z t:0 0
jL. CLaSS106CATICft
40 Its, 9
A Kit '(St trttt It 0( ~Wa n I An i
9 0 fie 0 a 0 a 0 0 0 0 6 0 0 0 6 0 9 a 0 a 0
O's 0 61

Iff -#I I I
_k A A F . Q a I -I W 1 1.
A 2L_ A-"
10 PC 9 ! I I I -nit 141";
i,i. oil 41sonit 1*01'; N, Aod At
Ifigh I.infoarrati.s. -1J.1tvas fair.milystio, it (a.f. - I-h .."0, .4
official way of production of flassiontud ulanne. I. Pylulytic to I,II- I A I I- I as I I. ct.Si
floes
Acracking of matut in The presence of colri4gwkm
I - 4`01114111111 111) to Wt(" Off tile AIIII. Ili 1114sot) -4 thic-
kAaVJAji#_lA-A. K,irali,#vA. and V~ G. trattifin b. bellow 011)"; OIHAI lor hytiforAt
busla we 11141.
1!P#If4 Chem, W.SSR.) 19, IMI-MI(IMMil Rug. under the Conditions, d an 2.5-
00 gitan). -- Crift-rion ill the tIrpth of tile pyrolysis Is the vul. ( a
r-ow P - COWWJI. + Coll.) its the a" produced. in. 4.7: Ili milit pyrolysis, 735'. It 11.7, ft - 1.7, sar,"nAtit-a
00 erratmit Imratly *if If tits- temp. tit) to 1111113". faster above I.W7,. The berizornis: and toluctsic fractions am rrL&tivtl 00
I.saar its uu~tlil. romjxI3. 0.3 anti 4.4". tit tit))
thm trtiql, ; P 1.10 1 5 1% in-fividivi, oil stsiM PYTIslirosis of 00
Site 2 1 1$.:1; 7A And 3.31e. cr~aji., at K.10-33% 1. it. the xylen"
ChAtACIrr; p no 2 corvet,Ixonoth to noritud W 0 0
4 to Xtiolatics; fraet lost rou,sidersably ricki-r (45.0 told at JAW. I
I deril pyrtAyliso with frill. 0_3 an, IX_V-W. r 1.4. ex4ruille id compri. cat Ili
zIjVVIy (4%tfr firromlyn. is( Call, anti Call. Ili favor ol' C.H4 ar.)JIla 14 0
00 lie part (OptiIIIIIIIII 1`0111ditit)[13): C4114 4A. C41I.Nic
I% ChitAA.tefijfr~l toy is - 2-4. Another rfacasture of the 1. (of the majul). Ilyrillylis Its clavil air 00
00 'fricrvP ,( pyr.Ay,i~ I% (he wt. ratio 11 - C4jf,/CIf,Nfc. It, in a tallmlattlially higher yield of airfins (16"
60 01 In the gxsification of cauitov cracking inazut (it. UAN10. 94111
under olitititurn condifialossitY thin ounuttitLative I)yTt4ym'
11. 1 *; So. 3". 270--MM)" 1617., kK)- (11%). 11. Pyrolysis in the presence cot water vapor and 00
lart... Ity
00 At the -*,,n,t. air exci-. a roeff... 0.1. the yield of of oxyliess. D. M. Rudko%,,kil. V. (,. Markovich. anti
0 Coll, rCnimi"J fairly r,,n-f. 0 1 .4-12.5"; ) with the tetup. H. A. Kattralcova. 141. -lk-ttCr yiel.1% all alC-
varying frottl Xzl* 11) INN)' anti tile time of contact r (rosin fin, anti higher concti. in thr fumi gait wre saxight by all.
I.-! to 10 see.; it MH* InarliMly at lower leffill., VO-7W)" I I
I tit. isol' lizOand by use of 0, itt%tewl of air, r"It. Inthr Ne 0
r - I W. In roxilvist to Coll.. the yield of C.114 + pyrolywis of kerartene In porcelain rractori, with a kerowne.
gC.11. (mainly C.H., with nmor x-C.11, anti very little i ~* 0
IN, ~1! Call.) flotilla clistitsorlty with rhing temp. ;&list with loingr1`7' water ratio 1:3. time of contact r the yiellf
lee
optintion con-liti-vi, hy the crit~iorn -4 booth P of Cliffs inctessloed between 80U' anti from 10.5 to
5) 27.0 wt. 170 (of the Ircrowne converted); the aptimusts
anti the total yield to of unutol. hydriwtrbons ( 14-14`~), : 4 Zee
Are fairly Inititti. KIIII-Will'at or Almitit I ~. tie U410'at r iii teMP*. not actually reached, scents if) lie tit absout I Its)';
40 2 V 3 ara,.: it 735'. 1 it 7. As nw- to, [.I (,all, is, ,. Calls + Call# we ab-sut 14", at PAII-SWO)". filling to 9-1e Poo a
all 111654", (14slin"JIM Yield -4 IolAI Otefiffla. 42`;. liets between
to
lie I tile clatreme 7101". 1 0_4 an-l 01111" r 113S. Is fAlla 41.611. 1140 anti ItAW; from ?out to) SON)% CIS, ill'tra,irt, frotil.5.0
if.;
lt'!','in the Sac r- no it-,,nont tit dittititthrd ar.,aiticatit"i.. is, It 7 It, from 0.7 to 2-1. t4ital stows (still. 41.11 tip U0.3;
:2 11 in the 2nd ew-e owing to morra,ifir row,lymerization. Th-
Zl -, _ - - I - - ___ - __ __ "suit's In steel reactors are cl~. Incirmic of r front 0.03
A I. a . s L a NITALLURGICAL 1,111NATIA11 CLASSOKATION to 0.2 saw. ravaltaid [a ouly a slight huyeasse of ratio. froax -~-7
IFIV., 1111.1a". as,
INIC.1 .1. a.. cat a I-OW
S-4 t
,0 UIs AT W_Lt 11A An A 1 41 N 0 -0 0 1 IN 5
iv " "trip wag Nit Itlif RUSS It KKW I 1A 014,
411 VO 0 0 0 0 0 0 0 0 0
!40 i~
000 0 0 0 00 0 0 0 00 0 Ole 0 0 0 r, 0 0 0 0 0 0 to 0 0 0 0 0 91

1
0 0 0 0
0
1
,
t.. o,,,, its 11111 -so 9.11 a o'. 1'. .11 at of :1

1 .11. 1 1 . I I
l too .4 At 1, 1 J
4 I a

1 o
It 1::il .4 to T'lls-1-1
1::-1 ".1 Moo p ll..::i ) i, it taicko Do' to .
Fr,ldt 10 .6 411-1t.1111 Moto.
.4W "I

4 I'l-filt.4 ., 1,,w invICAW all thc 19141 au.t.
it $4 All't (J.I 1 CAIO Ind If jild fit luve a di'linvily more IjWked V11cct

0 .
bso ,-4~ cA tjoi.d 4, fins rnwfjitlx it trul. (43.7-)
"
a %. un
I C
ll
f 'No the y"'111% '" Calls, Calls. most IrArtiCilloolly C4114 (1j.
vinyl). At p - 2 an, 4
ill 1
V.I[
it
1
III
i
S 00
ro
al
at %1,0* 1011 al,,;Mjr imrct~ ..
a
a
s, .
..
1;jojo
.
.
.
,
j, 11.1
5.0 anti 2.x, 5.8
3.0; C
1
1l
1
1
2
4
2
8
d 0
7 00
00 MA I's VA".. .111 nurr.t.. .4 C.11. J- Call. ormching it
w
1 If
l
c
i
Cit .
.
.
a
.
.
mi
.
,
.
, (1-4. 1.0;
Call, to. 1.3. 1-11 anti J. 0. 0.5
lilt, unt .11 lairtin
111
11
00
0 . .411.
(a
te
aso
)mole an
,.
"141_11 ~Ilaootll r 1~ 1. wr
, .
q
.
.
III
A
&2
i
:
is I 3t. ti.ins fast
f.wn-1 I., Ila, 'd is it 0.41
"
.
.
ts
.
ii., L/11M) it Inatin ) 2
,
1
:6) toul ,11
M
:Lt
I

0
0 . #V.1.
with Ow #,into , 1'. W 1-1 Past "ol'i livall
'a
1l b .
.
.
.
.
.
I.i,ht
041 all. II
M
11
14
7
4 00
00 actaA.
1"t. 11.1,11V ."v q, It., I .... it 4hilo, 4 Worly ."N4
$) 1. C .416.1 hydrI.-
4 file If .
-
.
.
.
;
3 1 A ;111,1 L. 1111-Ul. to ith No is bill 09
,
mpofs .4 CO: at IAAJ Witt 11AW
n
i
i
l 1111jil fi,tlurr 4 [if N
nuall
eo n "
a
.
rstrfxxta rr%u
t
at
the amt. it 0.4 and I'S". F-P... cwlm fill. Italy, AS Stat- . 00
41111111 mild by Mmiatatcan, 11,4) Arloa chwily lay lorottecting Wrlin*
00 mrun%l p4mrripali- 1-r kf,jv 115,11.t .... tsbjet-9_1
00
pyrooly.eq Itl.l ..ill it. -1 -4 - wr. r-Olmig
00 I :V ~? -1 1, Ill I Is. .. - to I
00 2 441 till tl,~Jc I 11-16"Itills Call.
0
-1. at -.-9t r tIN 11.3 wr.; muirr tile given t~mrj-
00 ir~, #a.m. tile liligh-1 ywl,l in Call,
00
0 So was he".. Call, 1";. Itivitlyl 3e'. Withfooll ot-.Whing tile
s - 1; tile toptilinalln Slain of
in
i 00
00 mum
a
opt
iolefins lic,t at Jxmit so Tile vill, r4ornpra. ill the upti- 00
040 nitint g-.a. a. (;,It, 24), Call. 5, Calls 2.5. I,ivitlvl 1.5". jut'll
00
00 .4fill. !has,; CH. ~1_1, 11, 1:1. CO 13. Call Lt). Cooke
t
)
d
l
i
(lu
a
"
t
ill, vot. a,( tile loust'"14
;
00
so hor F 1: 1. flit clarttl ItNt lulAill-r With rr,pixt to tilt: b
"U'Wildly" 4--into-cft.1 mmilt (with deduction of lu~ao
so 1XIM411) 1~: Call. 13.5. C.11.5.5, Cill.4.4. biVillY13.3, IOIAI
00 Ascuntlouard with
00
00 00
00
0 0 0 0 0 40 0 0 0 0 0 0 0 0 0 0 0
0 a 0 0 0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

Neparation of milthylene chloride from nirtheno X1. A[
k"-Likh, Uj~"Wjkovsktl. mul 1. F, Siki-vw1t, /4u,.
1'rikhtd. Xhim. Zj. AA-W(II641); J. Iffiied Chem.
V_V'S.R~ 23. 11-111 _4( 1 WA Ix Encl. trall-Litiont; Cf. Cileter
.ind Osse, U.$. 1,57*11.613, C.A. 20. 1213. -The I)rrpn.
M CII,CIt toy 3 thethiuk wu inw,tipted: rhtmitmt~nt
of Clia, of MeCl, and of their mist. Tire mo%t ciiificteirv
i~ vitforiltttiots of cf($ Cunt%. MCC% ~* A4 to give 4 Ct
L'II,,.%fvCI rullo, I O.N-;0.7, .1sen Ow yie1.1 if CII,Cl,
waclies 703,11"-. (oil Cf) and .31'7, tm CU,. Polychbirideq
vinupri.w 10% . The tw%t temp. ntsige L4 3141 4.'sl' and
either liniken gl,'~q or CuCl, tulie filters give uppirox. thr -Liniv
result. Almoo no AfcCl k Jim in the jorm-em. and thi* cAn
lie rveyeltil. CaCit or CuCls do not apj~..r to h4ve any
"Perific catillyfic action over g1j", In all clov"I Millie C
dellimition look place which may have an effivt on the
rrsultq: lhi4 w.it not vitilit4l further. C.. N1, 9~61*4

112 194

ly
~,,-o45577. WDWGERATION OF4=& OBTAINED FM CARMNLATED plESEL OIL
TAR. KetqlaM4 M.M. and RudkoVal 1 1) H. (Khlm.

_,XWN,
8N
AUTHORS:Afanassev, I',D~., Gadaskinal W.D., Remi7. E.K., Rudkovskly,
D_.M. 6~-6- TIS'
TITLE: Complex esters from products of oxosynthesis and other
products of chemical processing of hydrocarbons. (Sloahny-e
efiry iz produktov oksosinteza i drugikh produktov khimi-
cheskoy pererabotki uglevodorodov).
PERIODICAL: "Khimiya i Tekhnologiya Topliva i Masel" (Chemistry and
Tectmology or Yueds anct Lubricants) 1957, No.6, pp.16-25,
(USSR)-.
ABSTRACT: An experimental work on the synthesis of a series of
complex esters and determination of their properties is
described. The following raw materials were -used:
1) Monohydroxy alcohols from oxosynthesis; dihydroxy alco-
hols obtainedin a treatment ofunsaturated gaseous bydro-
carbons; di- and trihydroxy alcohols - condensation products
of propionic and butyric aldehydes with formaldehyde.
2) monocarboxylic fatty acids, obtained by oxidation of
paraffins and by oxidation of aldehydes from oxosyn'thesis;
dicarboxylic acids of fatty and aromatic series'. Technical
mixtures were mainly,used so that technical mixtures of
esters were obtained. Esterification was carried out on
Card 1/4 boiling of mixtures of acid, alcohol, catalyst and oxygen,

Complex esters from products of oxosynthesis and other
products of chemical processing of hydrocarbons. (Cont'.)
the latter being used for the removal of wate'P-ATckl~ie
reaction zone. As catalysts zinc oxide and P-naphthalene-
sulpho acid (prepared as in ref.5, Wittq Ber'.9 v.4-8) p;0751P
1915) were used in a proportion of 0'.3-6.5% of the reaation
mixture. In order to prevent t tie formation of incompletely
substituted esters the monobasic component was usu ally in
excess (125-150%) of the di or tri-basic componant. Esters
of momohydroxy alcohols from oxosynthesis and acids ob-
tained by oxidation of paraffins are given in table f.
Esters of mono-hydroxy alcohols (from C4 to ClO).and acids
from oxosynthesis (C4 - Cq) are given in table 2. As the
esters obtained possess a low solidification temperature
and a relatively flat viscosity curve, they are suitable
as components of lubricating materials. In order to in-
crease their viscosity additions of high molecular polymer
esters can be used. As an example the viscosity of the
isobutyl ester of isobutyric acid with an addition of
polybutylmet2a,arylate (0-20%) is given in table 3'. Esters
of diliydroxy alcohols and acids obtained by oxidation of
paraffins are given in table 4'. Esters of dihydroxy
Card 2/4 ~lcohols and acids obtained by oxosynthesis are given in

Complex esters fromproducts Of oxosyntlaesis and other
products of chemical processing of hydrocarbons. (Cont.)
65-6-3/-A
table 5. Esters of trihydroxy alcohols and normal aRds
(including those obtained by oxidation of paraffins) are
,-iven in table 6. Esters of tribydroxy alcohols and acids
from oxosyntLesis - table 7~. Complex esters of adi ic and
phthalic acids and primary alcohols (from C4 to C183Y
secondaTy hexyl alcohol, mono- and triethylene glycol were
also obtained'. Esters of adipic acids and monohydroxy
alcohols are given in table 8'. The influence of the struc-
ture of the alcoho-1 component on the solidification temper-
ature of adipic acid esters is shown in table 9 . Phthalic
esters of mono-liydro-xy ~-Icohols are given in table 10'. Data
on adipic and phtlialic acid esters of dihydroxy alcohols
are given in the text. The following data are given in
tables: starting components, boiling range of esters, spec-
ific gravity, molecular weight, volatility %, viscosity,
temperatures of turbidity and loss of fluidity, acid on
saponification numbers. For comparison literature data on
molecular weight, viscosity and solidification temperature
of a number of esters are.given in table 11. It is concluded
chat from synthesised products the following are of practical
Card 3/4 interest: esters of butyleneglycol, diethylene- and

Complex esters from products of oxosynthesis and other
products of cLemical processing of hydrocarbons. (Cont.)
65-6-11/13
triethylene glycol and fatty acids (C6 and above)-6f' normall
or branched structure; b) esters of m6~thyl- and
ethylmethylolmethane and fatty acids (C6, and above) of
normal and branched structure; c) esters of adipic acid and
iso alcohols (C6., and above); particularly good results were
obtained with alcohols with the most branched hydrocarbon
chain; and d) esters of pLthalic acid and iso alcohols (C4
and above). It was established that asa starting raw
material for the production of complex esters with one com-
plex ester grouping and possessing a low solidification
temperature, the products of oxo-synthesis can be used.
Certain fractions of fatty acids of normal structure, ob-
tained by oxidation of paraffins as well as acids from oxo-
synthesis can be used for the production of complex esters
of poly-hydroxy alcohols (di and triol). Technical mix-
tures of alcohols 'and acids can be used for the production
of complex esters. The required mean properties of esters
can be obtained by selection of corresponding fractions
from mixtures of complex esters produced. There are 11
Card 4/4 tables and 7 references including 4 Slavic'.
ASSOC; Len NII.
AVAILABLE:

v
Fn - r, j, 4
44 to;ilmilo sub L4 fmm poducts of Me
b tg
cheu&-A trubtfient d alls at taft fim= &W and dbde.
NV D G%d"kins. D M Rudkov*5, and S. Va. Varztern-
Ikay- Zkur P,ikkd Kkgm. M, 14&-64(1957) -Surfac~-
4, tzv--- ~Ubstaz~= c = all -1 schytez-te
,.wide vVit-h-A) ted xz& -~-Ikylzted tech. hcoals
(L) melds. (c rimery aks. of the tM CLH*.+ 104 'M
fm - 1-18. e Intetlid-4 cuOmee ttridoo (st aazl HsOb
~he --atact angle (on parafilu), team fatinaffi=. and toun
Mit'alty )I the ~r,,Iucts were cf~td, The pmducu o( (a)
- t~ g ~d as t v st~dard mm. aidace-~ctfve ~brsunces,
UP : Qr OP-8 kef. C .4 51, 10116a). Thom Gf (b) were
aut f,vin forming and thow of (c) with m between 10 and
~ 4 were Fu!?d !rqt~ng agenti.. _ __ -j.JjtppMjtz

AUMIORS A. G. a:~d Ale K
TITLE: - ~yi r at - ~101 --c' - ~fp' Cp Alr.6h.~1~3 fn~z: rilef-
Fuel, Fraccti'-71~-'. ",7
z "; - ~-" - C-
"y
top f j f! a L.
PERIODICAL- Khj-mlya
pi~ 7
A'Q
STRACT: T-~e
rL- 1.
UjP
Card 1/4
T
4
'. P'~* , 4 - '-
.5
j a:,,H
r,.t
mazal' Nfo~.
t;l~~ ai--~i the
- -
ffiz-e and
ed
B V -a Sfa exna"'Llent
ana 0
In- f- FL a j r
.Ri~..3 !t e Y' 2. r. tnv, p. r E, a na t f C C, a!`a-
8
hy,-`--.3 fl'-Art -L~if ue f ra f cy.3 a r :~: ~z i-i -
L
Qf Ualy-It.
the sivrth.--'-zls
gas, the r-a-.,G Df 2u,L:,ply i~~f ti-A lllqu-~i ma"rlerlal and of
the rate ...f ~-f the. gan, t;n tliq in.,n'i~nyjatlcr~
p nc L ;-= s :5 ;~ Vt ~ r e 17-5 3 t I C.-I 2. T;~-e raw mata-Z-:Lal u.3e.-J. wa~5 the
fractl--ln 1*:~ vl- t ~ i.00 W" cn-, a
re :: t if J.,t~at- d!.ir I T~ag tw,~ q- i-.~ t`;~.'-'Aa tlon:~ cf ~..:Vacke
-L - -A.'i fra-tion
pe Lr ~~ 1crum. L,"nyelcal :f t,
arre it-al."ed as -,,veil -0--.4 C15.. C6 07 h7dt-;:~-

P reparatioz- of
ps
r-a:- ens
by the Oxc-Synthesis
oaz,b,3r,5 in ths raw mat~qrlal !'Table T i
were .,~.-arrled j,
~-"at I
a of the I
Detail p of 12',135L;urats-d
hyd--!,~..cart L-rs a,--e j I.-,, t_a r.. C-1,:alt wa3 uLed as
catalyst. The c-f the of thi-
,~atalys,., )n th:? ralue of -ari.,c.ny'lat-3~,j c~f ulioaturatel
0 C , h,7dr-ccjait.,,--,r,:3 was Im'-estigated at a tt,~,mpe-aturq
5 11 L
of ir-26C, pre3surp-3 -~f 200 aA-.d 300 atns and the r ati,:~
tDf the -Zat,:: ',;f :PAPPI-7 ',I the --aw n, -a t tra5
A~- P.,
TI, e L: o f rit
q-a~B Z, f; :f it
material. cf 1-. e 1 a t a"'
- L, lyst via i a i i d
vv,'- thir- -.e lfmit~s Q.03 0 Resuit3 o-e these exper-1-
ments ar.= and De 4-
tails of lm,-estf-
oat-Ion,3 ~~:7: :.:-,fiuer 'i-3 --f teimre-vat'ure .-'n. t1r.-B --ate of
the &.t f""--)O atms are g-", 7-9r, .,m Table 3 and', P-4g.3.
A,~tl-vatior- energy wai cal--4i late d ancording t- the equation
by Arrhe-.--Aus and wa3 11
, 0 0 0 c a 15 /.ru -1. a a temverature
coeff-4-'-nt of the rate c,--f rea~~:t~Lcu i.q. Experim-ents
on the- t~ff,,.ct .-f p~:eq.3are .~n t'-,-ie process
IvIera ~a,,-r-'e-- at ,,f, 'Tablo 4
Card 2 ard
fr:~ "ut, .11~

c;. "'7_"
Preparation (,f C,3 - C~ Al T 91 Fr,
-a,:, t L-) i
by the Oxo-syritLasirz,
industrial a t a.,vi. :cn, - a 1,
_:-,it t m
of .-he, - 'a taly.3t 0.2%) a change -'n t'Ln~- P 2a '.3 -i I ~' r, -. I " r :,!, I
150 - Y.10 atm:i dces rict affe:,,t t,~e
T -a-c i e f: fri e i C, the cf thi:'~
3 1 t 14: f 1- h e T) r,:, we r#- f~
~'w at
te:.q-;-*,~tfu7P--., Partial p
'^els,.lre5 t' C-0 and
;,aryii:z rat-'-,,z s~ip-.Ily ~-" t`qe mat.-rial. Fvcx, data
f I
az?l F~-"p '-.5- It. c.ar, Fitjer., thal, at lo'""
at-, k
2~ o I o -, - - I
-0) t h c- d -3',- f m, c- r a r. c f u r. -
qaturaL,m,:j Y"-" I-i 1, .1 as' ng i
:j Yj part a
F 3
.1 2i.1 the inffluen.-e
~h raw rful4i~r'-Ill a-il quant-Ity
-r u a t a t
s tn-c '-a prc,-teio. are elven
~ri Table~i ur-il 8. rLI'las.
tha
I u cbmined ffcrr.~ fzfa~~t-'-O-r-E up t,~: 100:"
td. The ~Ll
thia
the f vac, t n b- E, u t'~ 160c"~'C` fjunrea-,.~-ed rar ar~aterlal)'v
t COL-L%:'~!' ---.F bptwea7; 140 - ~Qccl~'
and th-~ -vac '-;_5 steal cf all
Card 3/4 t ,, F,

-56~ -C-- 4/2.3
.Preparation of Ce - C., Alc~!~cic Olefir-Conta-Ininj Fu6l' FrIaCt~orzs
by the Oxo-SynthesI6.
and 5 Refereme-,i: 3 Soviet, 1 Gerriar. ard 1 English,
ASSOCIATION: LenNII
Card 4/4

SOV/136-59-2-20/24
,.mUTHOR: Okolovich, A.
TIT1,E: Organisation of the Flotation-Teagent Section in the
Standing Committee on Synthetic Surface-Active Agents
of the GNKX USSR and the Problems Facing It.
(Organizatsiya sektsii flotatsionnykh reagentov v,
postoyannoy komissii po sintaticheskim poverkhnostno
aktivnym,veshchestvam pri GNTK SSSR i yeye zadachi)
PERIODICAL:Tsvetnyye Metally, 1959, Nr 21 pp 84-85 (USSR)
ABSTRACT: One of the four sections of the surfAce-active a2ents
committee of the GNTK of the Sovet Ministrov SS9-.
(Council-of Ministers of the USSR) is that dealing with
flotation reagents. The following have been confirmed
as members: I.N.Plaksin, corresponding member AN SSSR
(AS USSR) of IGD of the AS USSR (Chairman);
O.S.Bogdaaov, Professorv Mekhanobr Institute;
Ye.S.Alekseyev, Sredneurallskiy luiedeplavil'nyv %-~,-od'
(SredneuraiWy Copper Smelting Works); K.G.Bagatarlyants,
Gosudarstvennyy komitet.(State Committee) of the Council
of Ministers of the USSR; S.I.LGorlovskiyq Mekhanobr
Card 1/# Institute: L.A.Ivanovaq Nauchno_,S sledovatell,skiy

FU
SOV/136-59-2-20/24
,Organisation of the Flotation-Reagent Section in the Standin
Committee on 2ynthetic Surface-ActiveAgents of the GNTK US' and
the Problems Facing It
(Gosplan USSR); M.A.Eygeles, Professor, Vsesoyuznyy
nauchno-issledovatellskiy institut minerallnogo syr1ya
(All-Union Scientific Research Institute for Mineral
Raw Naterials). The author enumerates the tasks of the
section and notes that at a conference on -the
10th December 1958, the programme of work for the section
was adopted. This conference heard the following reports:
S.I.Mitrofanov, Professor, on "Directions and Projects
for Research Work in 1959 in the Field of the Production
and Use of Flotation Reagents"; A.K.Livshits, Candidate
of Technical Sciences on "Xanthate Production Methods";
y, Candidate of Technical Sciences on
__D,!,&dkovski
"Production of-Washing Media from Flotation Reagents".
The conference adopted resolutions aimed at increasing
facilities for research on flotation reagent and
improving its co-ordination. At a conference on the
Card ~/k l4th-17th December 1958 of the standing committee on

AUTHORS: Rudkovskiy, D. M., Trifell, A. G.9 S106AI1,910001081021021
,

!I-eks'eyer&-,--K-. B1 157B
_X 017
i
A
TITLE: Production of Butyric Aldehyde
nd Butyl Alcohols
by Means of the
Method of Oxosynthesisj
PERIODICAL: Khimicheskaya promyshlennost', 1959, Nr 8, pp 652-658 (USSR)
ABSTRACTs In the present paper the production of butyric aldehydes and butyl.
alcohols from a commerical propane - propylene fraotionand from a
carbon monoxide - hydrogen mixture by means of oxosynthesis is des-
cribed, and the technological factors determining this process are
investigated.
The method has been described already earlier (Ref
,
7)~ It consists o f three stages: production of the cobalt-carbonyl
solution (which is used as catalyst, solvents toluene, iso- and
n-butyl alcohol, pentane-hexane fraction from the direct distil-
lation of gasoline), carbonylization and decomposition of the
catalytic complex formed. The apparatus used and the processes
which take place in them are briefly described. Figure I shows the
scheme of the laboratory arrangement, in which & flow system was
used and work was carried out at a temperature of approximately

0
1
50 andat pressures of 150 to 300 atm. The composition of the
Card 1/3 gases used as initial products is also given. The influence exer-

Production of Butyric Aldehydes and Butyl Alcohols S1064 59/000/08/02/021
Ifeans of the Method of Oxosynthesis B017
B115Y5.
cised by the temperatures in the range of from 110 to 1500 on the
rate of carbonylization of propylene is investigaied in a static
system. The following was also investigated: The influence exer-
-cised by the cobalt concentration on the conversion of propylene
at 120, 135 and 1500 and 150 atm (Fig 3), the influence of pressuro
on the carbonylization of propylenel(Table 1), of the propylene
conebatration in the solution on the oarbonylization of propylene
(Table 2), of the gas composition on the rate of pentane carbonyli-
zation (Fig 4)t of propylene (Table 3) at different temperatures,
of the ratio PCO on the constant of reaction rate, (K.102)
(Fig 5), of the p:rthl pressure of carbon monoxide P
02 on the
maximum stability temperature of cobalt carbonyl 9 ), of the
composition of the propane-propylene fraction Fig 7) and of the
volume rate of the liquid raw material (Table 4) on the yield in
propylene transformation products. Carbon dioxide delays the
carbonylization reaction. The maximum stability temperature of
nobalt carbonyl shows~a logarithmic dependence on the partial
pressure of carbon monoxide. The influence exerted by,various
factors on the formation of acetals in the condensation products
Card 2/3 in using butyl alcohols as solvent is given (Table 5)9 and the

Production of Butyric Aldehydes and Butyl Alcohols S1064 59/000/08/02/021
by Means of the Method of Oxosynthesis B115YB017
composition of the hydrogenated product obtained by using a
pentane-hexane fraction as solvent in thecarbonylization of the
propane-propylene fraction is mentioned (Fig 6, Table 6)..The re-,
sults show-that n-butyl alcohol is the main reaction product
(60%). The other produotsiares isobutyl alcohol (22%), alcohols
C8 and eater (6%), 2-eth 1 hexanol (9.5%), and higher condensation
products (higher than Z (4%) .There are 8 figures, 6 tables, and,
11 references, 4 of which are Soviet.
ASSOCIATION: VNIIneftekhim (VNIIneftekhim - All-Union Scientific Research
Institute of Petroleum Chemistry)
Card,3/3

50) SOV/ /79-29-6-31/72
AUTHuRS: Hudkovskiy; 1). M., Ketslakh, M. l!., Zonis, El. S.
TITLE: Common Synthesis of Alcohols and Kutones From Aldehydes of the
Oxo-synthesis and Secondary Alcohols (Sovaie3tnoye polucheniye
:;pirtov i kc-tonov iz alldcgidov oksosinteza i vtorichnykh spirtov)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 6,
pp 1914 - 1920 (U3511)
ABSTIU-CT: In tile present paper a synthesis of the aliphatic alcohols
CI-C and ketones or acetone and uiethyl-ethyl-ketone was de-
0 6
vised. The yields were high and the consumption of aluminum al-
coholates, which were used as activators in the reaction of
the cobalt carbonyls, was low. As initial products for the
reduction hydrogen carbon solutions were used, which were ob-
tained via tile Ioxo-synthesia and contained 26-56~ aldehydes
C6-C8. The reduction was carried out in the presence of iso-
propylate and secondary aluminum butylate in the correspondin,,,r
alcohol solution. It was shown for tile first time that the
cobalt carbonyls activate the reduction process. Their effect
Card 1/2 was more intense when using directly tile aldehydes of the oxo-

Common Synthesis of Alcohols and Ketones From Aldehydes SOV/79-29-6-31/72
of the Oxo-sjnthesis and Secondary Alcohols
synthesis than with an artificially composed mixture. The re.-ular
addition of the aldehydes to the solution of aluminum alcoholates
as well as the continuous distilling-off of the ketones formed
favor the fcr:nation of the alcohols and inhibit the condensation
of the aldehydes. The optimum laboratory conditions for the
reduction of the aldehydes C 6-C8 in the presence of the aluminum
isopropylate were determined on which the yield in alcohols
(C6-C.), with respect to the reacted aldehyde, was 94% and that
_j
in acetone 95~j. The aluminum consumption was there 1.4-3;~', related
to the reacting alcohols and the acetone. The use of the second-
ary aluminum butjlate resulted in likewise high yield in alcoho-
lates and methyl-eth~3_ketone in the case of a solution in second-
ary butyl aleuhol, There art! I figure, 3 tables, and 13 refer-
ences, 4 of which are Soviet,
ASSOCIATION: Lenirigradskiy nauctino-issledovatellskiy institut po pererabotke
nefti i poluchenigu iskusstvennogo zhidkogo topliva (Leningrad
Scientific Research Inrtitute for Petroleum Refining and Pro-
duction of Artificial. Lic;uid Fuels)
8UBMIMED:
Akd 2~2 May 12, 13/58

VT-
I Ell!
Carl
RZ
R
MEN.
9, A
91 ~, i ~. i I i
Iff a
tfl'9jRj.;. I ?
T~
el R
?ZVI.
2 r
IR
Ir
Fin
R air
HE

FROST, Andrey Yladimirovich, prof. [deceasedl Prinimali uchBatiye:
BUSMAKIN. I.N.; TTEDENSKIT, A.A.; GRTAZHOY, Y.M.; DEW311TIYEYA,
M.I.: DINTSES, A.I.; DOBRO11RAVOY, R.K.; MLIRKOYA, Y.R.; ZIUMKO,
A.Y.; IPATIYEV, V.11.; KYTATKOVSKIY, D.A.; KOROBOV, Vj.; MOOR,
T.G.; NEMTSQV, M.S.; RAKOVSKIY, A.T.; REMIZ, Te.K.; RUDKOVSKIY,
.D.M.; RYSAKOV, M.V.; SEREBRTAKOVA, Te.K.; S=XIIOYICH, A.D,-,
STRIGALEVA, N.T.; TATEVSKIT, V.M.; TILICHETEV, M.D.; TRIFELI,
A.G.: FROST, 0.1.; SHILTATEVA, L.T.; SHCHEKIN, Y.T.. DCLGOP0LOT,
N.V., sostavitell; GERASIROY, Ta.I.,.otv.rod.;.SMIRN0VA, I.Y.j red.;
TOPCHITETA, K.Y.; TASTREBOT, Y.Y., rod.; KONDRASHKOVA, S.F., red.
izd-va; LAZAREVA, L.Y., tokim.red.
LtSelected scientific works] Izbrannye nauchaye trudy. Moskva,
Yzd-vo Mosk.univ., 1960. 512 p. (MIRA 13:5)
1. Chlen-korrespondent AN SSSR (for Geresimov).
(Chemistry, Physical nnd theoretical)
777777, 77

;.UDL-V3,"dY, D.,',-,
C, 1 C?~,
of secondar- products
60. (I-IL-A 14:2)

TRIF-11,
Prircipal teellmolo ic
c,,-:, o.-rthesis. Trudy
Vllillfeftollcl im no.2:.2.'7--~'lY (".IRA 14:2)

RUDKOA'SKIY, D.M.; T:J,---.L',
n
r.rcraration.
1, 4:2)
Oxo proces,-.)

.0DKOV3::IY, D-L.; T.JF-L'I A.G*,, ALE:%:3--7--'zJA, K.A.
Uce of coba-It salts of organic ac-do as catalrs'u:-, in t*-.c procc!;~-, 0.1
wr-o 3yrt'L.esis. Tru,-.1y V-.'IITcfLte',.,A--n-. no.2:1172-53
(0,:o r-rocc3s) (Catalysts)

ii,UD, USE. D I! - IUSHI:~'y
Selection of carriers 2or coL:,alt in the proceso of on."'Y"ti,c~-i:3.
liudy UIII'jeftc-:,-hix. no.2:59-~J() tot., MLA 11,:2)
(N. o Process) (Cobalt)

FtUDKOVSKIY, D.M.
0
I

RUDKOVSKIY, D.M.; GANKIN, V.Yu.; N.S.
6 - C8 aldehydes from oxo syntf-,csis products ru
Recovery of C T d
(!"!--A 14:2
VINETTeftekhim. no.2:90-92 160.
(Aldehydes) (Oxo process)

AUTHOR: Gankin, V. Yu.; Rozovskiy,.A. Ya;~Rudk6vskiy, D. M
on..
TITLE, The mechanism of formation of a catalyst for the hydrogormylation reacti
from cobalt salts
SOURCE: Neftekhimiya, v, 51 no, 1i 1965- 58-;61---
TOPIC TAGS: hydroformylation, cobalt carbonyl, hydroformylation. catalyst, -co- :,---I
balt naphthene, carbon monoxide

5
L 34001-65
AC093SION NR: AP5006077
e74_-~77 ~1
Thus, formation of cobalt carbotiyl,,fr6m cobalt naphthenA '4et'eimined in,t
o ene
solution after addition of a small a-m-ount.,of,carbon 1 at.an' initial,total ca o
rb n
Y
monoxide+hydrogen pressure of 400 atm.; this was accomplished by heating the,
ture to 95C for 30 min. in an autoclave, analyzing the liquid and gaseous reaction
products and measuring the decrease of pressure with time. The equilibrium con-
stant for reaction (1), i,e. the reversible formation of cobalt nonacarbonyl from:
octacarbonyl and carbon monoxide, and the rate constant for formation of catalytic
cally active hydrocarbonyl (reaction 2) were derived. A linear relationship be-
tween P /K and P was predicted from the kinetic analysis in agreement with ex-
H2 CO
perimental results, K being a reaction constant which can be calculated from ex-
perimental values and P. and PCO being the partial pressures of hydrogen and car-
bon monoxide, respectivefy. Reaction (1) and the formation of cobalt nonacarbanyl
explains the inhibitory effect of carbon monoxide on the hydroformylation reaction,
Orig. art. has: 3 tables, 2 figures and 9 formulas.
ASSOCIATION- Vsesoyuznyy nauchno-issledcvateliskiy-institut neftekhimicheskikh
protsessov (All-union petrochemical processes scientific research institute)
SUBMITTED: 24Dec63 ENCL: 00 SUB CODE: OC
NO REF SOV: 003 6THER: 003.
Card

l,,UDKOVS.KIY,j)-M.; 13-1,'47:1Z, Ye.K.; MUMP, IT.I.; VIADE-.I~fflhl, I-I-
Cortain reaclGiono of rolionaldehyde and 1,,utN,-aldcl-..,de. Trudy YNIIlefte-
(NI-A 14:2)
(Prol,-ic:-.,, dr.-;'y-uc.) (3tt:nmldeKydc)

iiUDKOVS':UY,, D.*L.'.; I".,YAI,IITO%r li.S.1 CIEU11, V.Yu.
Conversions of hexafluoroprop.Tflene under conditiors of rxo -~nthesis.
Trudy TlIII",e'te':!;im no.2:121-124 160. (,L-A 14:2)
'Dr'Lopene) (Oxo proc--,ss) (Fluorkie or&--nia

KTzTSLA-LT,, 1-1.7T -H9LyKQVSKI-X%
Y.A.
Preparation of tri-.ict*-iylol-)i:-.-jFerc lby t".e conden3atuior- of butyralde-
hyde. Trudy --io.2:154-167 150. A 14:2)
(But'.5-raidel:yd'a) (Fonmllehyde)

UM'
KETSLAKII ---.,OVSKIY, D.:
Syntl,csi3 of di.,:ietliyldirreVzlylol:--,--,thane by the conde-ination of iaobtu~r-
aldc-iiyde with fonrialdel,y,c. Trudy VNIIlTofte!-.h,:Lm no.2;16P,-177 160.
("'DA 34-:2)
(Isobutyraldehyde) (Formalde:-Yde)

B/081/61/000/014/021/030
B117/B203
OTHORS: Ketslakh, M. M., Rudkovskiy, D. M., Eppel', F, A,
TITLE: Production of polyatomic alcohols by condensation of
C3- C4 aldehydes with formaldehyde in a continuous process
PERIODICAL: Referativnyy zhurnal. Khimiyat no. 14, 1961, 416-417t
abstract (14 /L18)- (Tr,. Vaes. n.-i. in-t neftekhim.
protsessov, no. 2, 196o, 178-187)
TEXT: It was shown that me'thyl trimethylol methane (I), ethyl trimethylol
methane (II), and dimethyl dimethylol methane (III) can be obtained by
continuous condensotion of C-C aldehydes with CH 0. The reaction is
3 4 0 2
conducted in an aqueous solution at 20 80 C in the presence of the alka-
line reagent. The contact time is 30 90 min. Excess CH20 is removed by
water at 115 - 1300C and 2 4 atm pressure, and led back into the Drocess.
96-98% C - C aldehydes, a 20-37% CH 0 solution, and a 20-25% NaOH so-
3 4 2
Card 1/2

S/081/61/000/014/021/030
Production of polyatomico.9 B117/B203
lution are continuously introduced into a tubular reaction vessel within
10-30 min. The mixture is stirred at 300C for 50-60 min, and then
neutralized. Optimum conditions are: a) for 8roduction of (I)s molar ratio
CH 0 - CH CH CHO = 3.5 3 1, temperature 30-60 C, contact time 20 min; in(
2 3 2
the presence of NaOH or Ca(OH )21 the yield is 70% (if the molar ratio is
increased up to 109 the yield rises to 77%); b) for production of III)s
molar ratio CH20 CH 3CH2CH2CHO = 10t 1, temperature 30-50 0C, contact
time 10 min. The use of NaOR should be preferred. The yield is 63-66~4;
c) for production of (III)- molar ratio CH 20 - CH 3CH(CH3)CHO - 2.15 S 19
temperature 60-80 C, contact time 5-15 min. In the presence of NaOH or
Ca(OH) 2' the yield is 8CY16. The technologica 1 scheme of the process Js
given. rAbstracter's note: Complete translation.]
Card 2/2

83981
S/080/60/033/009/0 141021
WIN A0031AOOI
AUTHORS: Gadaskina, N.D., Remiz, Ye.K., Rudkovskiy, D.M1.
TITLE: 'Me Condensation Products of Multiatomic Alcohols Wir.h Ethylene
Oxidejand the Esters of Tkiese ProdUCtS
PERIODICAL: Zhurnal prikladnoy khimii, 1960, Vol. 33, No. 9, pp. 2132-21-1;
35
TEXT: The condensation products were synthesized of dimethy1dimethylol-
methane, methyltrimethylolmethane, ethyltrimethylolmethane and pentaerythrite
with various amounts of ethylene oxide. It was shown that the number of alcohol
groups in multiatomic alcohols at an equal amount of ethylene oxide lowers.the
solidification point of the product. The shorter the straight hydrocarbon
chain in the alcohol molecule, the lower is the solidification point. In the
derivatives of methyltrimethylolmethane and pentaerythrite It was shown that
with an increase in the amount of ethylene oxide the solidification points drop.
On attaining a certain minimum value they rise again. An increase in the amount
of ethylene oxide from 12 to 24 modes per mole of condensation product has prac-
tically no effect on the viscosit., \~ With small amounts of ethylene-oxide highly-
Viscous products are obtained at room temperature. The product with 2.1 moles
Card 1/2

83981
S/080/60/033/009/014/021
A0O3/AOO 1 ~
The Condensation Products of Multiatomic Alcohols With- Ethylene Oxide and the
Esterg of Mese Products
ethylene oxide per I mole mi--thyltrimethylolmethane has a viscosity of 2,500
estokee at 200C. Esterificatton with fatty acids yields condensation products
of multiatomic alcohols with ethylene oxide which are insoluble in water but
soluble in alcohol, With an increase in the molecular weight of the aald the
points of fluidity loss drop. The lubrication propertl4were tested on a 1,500
rpm four-ball machine with a ball diameter of 19 mm. The lubrication ability of
the MrPg~ -15.5 (PERE-15-5) was determined as 97 kg, and that of the ester QaP3'
-12.5 (PERE-12-5) as 67 kg. The corresponding value for good industrial lubri-
cants on this machine is 52 kg. The appropriate selection of the muitiatomic
alcohol and the amount of ethylene Ide condensed with alcohol makes it possible
to produce a water-soluble lubricanywilth the properties desired. L.L. Kheyfets
and N.I. Krausp took part In the work. 7here are 2 tables, I figure and 2
references. I Soviet, I English.
SUBMIT=: December 24, 1959
Card 2/2

S106416-11000100110031011
B110/B215
AUTHORS: Rudkovskiy, D. M., Remiz, Ye. K., Katsman, S. V.
TITLE: Synthesis of monomers for.the production of the plastic
"Pentone"
PERIODICAL: Khimicheskaya promyshlennost', no. 1, 1961, 16-18
TEXT: A chlorinated, crystalline polyether of high molecular weight,
"Pentone" is formed by cation polymerization of 3,3-bis (methyl chloride)
oxacyclobutane:
i
CH2C
01H CH2 1
C 0 -OCH2 C- CH 2
ClH --' 'CH 1
2 2 CH2Cl
The methyl chloride group on the neopenthyl carbon, and the abseace,of H
in ~ -position, make the pentone polymer stable up to 120O.C. Absorption
Card 1/ 6'

S/064/61/000/001/003/011
Synthesis of monomers for... 13110/B215.
of water is low. With M 4 vapor saturated with moist HC1 at 80 0C. IThe
preparation of the monomer from pentaerythrite takes place in two stzLgcs.
HOH2C CH2Off HC1, ClH 2C "S, C CH2OH NaOH CiH,C CH 2,
C e 0
HOH2C C Id2Off C1112 CH2Cl ClH 2C/' \CH 2/
The authors developed a tro-stage method of preparing pentone monomers at
atmospheric pressure. In the first stage, pentaerythrite was treated with
HC1 gas in the presence of xylene in organic acia (molecular weight = 102).
The monomer of Pentaerythrite develops first and accumulates HC1. Besides
mortoester, also di- and triesters form. First, HC1 was introduced at
120-1300C, and again after two hr at 180-2000C. In the fractions separated
at 12 mm Hg, the yields of esters of chlorohydrins and trichlorohydrin are,
determined by ascertaining the chlorine content and refractive index.
Optimum yields of trichlorohydrin (approximately 7W~ of the theoretical
determination) were obtained under the following conditions: ratio penta-
erythrite acid 1/1; temperature: 200 to 2200C (Fig. 2), HC1 1 200-,4 of
Card 21V

S/064/61/000/001/003/011
Synthesis of monomers for... B110/B215
the theoretical amount (calculated with respect to trichlorohydrin)y gas
velocity of HCI:. 110 1/kg-hr, time of reaction: 9 hr. A ratio organic
aciO/Pentaerythrite N 1 gives lower yields of trichlorohydrin (Fig.~3)-
Dichlorohydrindiester and monochlorohydrintriester which also formed, can be
converted into trichlorohydrin3ster. The yields of trichlorohydrinester
produced from CH 3COOH, C4H9COOH, C5H11 COOH, C7H15COOH were the same as those
by commercial acids(molecular weight approximately 102). This ester had the
following properties: boiling pointt 160 to 1700C at 12 mm Hg, specific
20 20
gravityi 20 = 1.217 to 1.221; nD . 1.478 to 1.4881, Cl content - 37-5 to.
38.5 percent by weight. Trichlorohydrin which was formed in a ratio of
10:1 as compared to the ester, showed the following properties: melting
point 65 - 660C, Cl content 55.2 to 55.6%. The pentone monomer was obtained
from this mixture by reaction with aqueous sodium hydroxide at 70 - 800C.
The reaction products were distilled at 107-1080C. After drying, the fra---
tion yielded the desired product at 80-810C and 10 to 11 mm Hg. The,optimum,
yield (70 to 73 percent by volume of the theoretical amount) was obtained
with 20% of aqueous NaOH; 105% to 110% of the theoretical amount of alkali
Card 5

3/064/61/000/001/003/1011
Synthesis of monomers for... B110/B215
(Fil. 5) were used for this purpose. In the firsz fractions,impu-rities o-f
2,60dioxaspiroheptane, melting point of 83-860C were found. Absol-ute purity,_2
however, is necessary for the polymerization. On storing, the obtained
monomer oxidizes with atmospheric oxygen, its speciric gravity is increased,
and its freezing point is reduced. Since thereby the properties of poly-
merization are ill-affected, the corresponding inhibitors have to be added
when left standing. These properties were: boiling point = 80 to 810C at
20 20
10 mm. Hg, d20= 1.2993 to 1.2995, nD = 1.4856 to 1.485a, solidification
point = 18.7 to 18.90C, moisture content according to Fischer = 0.03 per-
cent by weight. The pentone polymer thus obtained showed satisfactory
properties. There are 5figures and 16 references: 1 Soviet-bloc and 15
non-Soviet-bloc.
Card 4/

20510
S/064/61/000/003/004/009
2ZD9 B101/3203
AUTHORS: Al'shits, I. M., Shtraykhman, G. A., Rudkovskiy, D. M.
Luchko, R. G., Remiz, Ye. K.
TITLE. Slow-burning polyester resins on the basis of pentaerythrite
dichloro hydrin
PERIODICAL: Khimicheskaya promyshlennost', no- 3, 1961, 26-28
TEXT: Glass-reinforced polyesters are widely used for the production of
large-sized goods (hulls, automobile hoods)i For this purpose, they must
have a reduced combustibility. The physicomechanical. properties of the
resin are deteriorated by the hitherto described methods of reducing the
combustibility: 1) the use of acid chlorides or phosphorus-containing
acids, 2) replacement of styrene by halogen- or phosphorus-containing com-
pounds, 3) addition of organophosphorus or organohalogen compounds to the
resin. Therefore, it was the object of the present study to produce slow-
burning resins on the basis of chlorine-containing alcohols. It was as-
sumed that the chloromethyl-, methyl-, and ethyl side radicals of such
alcohols would improve the heat resistance, compressive strength, and
Card 1/4

20510
S/064/61/000/003/004/009
Slow-burning polyester resins ... B101/B203
other properties of polyester resins and glass-reinforced plastics made of
them, and that their considerable chlorine content would reduce their
combustibility. A procedure for direct hydrochlorination of penta-
erythrite was developed. 136 g of pentaerythrite, 150 g of benzine
(boiling point 150-1800C), and 10 g of organic acid (C 4 -C6 acids or in-
dustrial acids obtained by oxidation of solid paraffin) were heated, and
hydrogen chloride was bubbled through at 160-1650C. The reaction was
carried on until two hydroxyl groups were substituted by Cl., Total
duration of the reaction 6-7 hr. The chlorohydrins were separated from
the benzine, and fractionated at 3-4 mm. Hg. Dichloro hydrin distilled
over at 135-1550C. Its chlorine content was 39-4qa, after recrystalliza-
tion 40-41%, melting point 72-740C, yield 60-68%. The esters.of organic
acids and of dichloro hydrin formed as by-products may be used for the
synthesis of dichloro hydrin instead of fresh acids. The dichloro hydrin.
was used for the synthesis of polymaleinate dichloro-hydrin penta-
erythrite phthalate:
Card 2/4

3106 4/6 1/000/003A-04/; 01--":i
Slow-burning polyester resins ... B101IB203
a I"CI CO
I
21nC11,011-G-C112011m
LO fit ej
CO '\
Clip CO
C14.0 CH.Cl
I I
It oco-a-l=cfi-oco-CI4-c-CH,,-()w-Cii,-co--O-Cl-l,-C-CH, OH+(2in-I)H,O
I
CH'C1
V/
The components were melted at 1200C, the temperature was slowly increased
to 2050C under stirring, and held there for an hour. The total duration
of polymerization was 5.5-6 hr- 3-9 ml of water was separated per 100 g of
mixture. The resin yield was 86%. The resin had the following charac-
teristics- viscosity of the solution in acetone 0.488 cpoise; acid
Card 3/4

20510
S/064/61/000/003/004/009
Slow-burning polyester resins ... B101/B203
number 40-50; saponification number 520-550; degree of esterification
90-7~6; color, lemon-yellow- 3Wo of styrene was added to this vitreous
resin at 700C in the presence of 0.01% of Ilydr:)quinone. The viscosity of
the combined resin determined by means of a D.~-4 (VZ-4) viscosimeter was
8 min 50 see. On addition of Ya of isopropyl benzene hydroperoxide and
2% of 40% styrene solution of cobalt naphthenate, gel formation took place
afer 1.5 hr. The solidified resin had a specific gravity of 1.28; heat
resistance according to Vicat 115; Brinell hardness 18.8 kg/mm2; chlorine
content 18.6%; water adsorption during 24 hr, 0.03& - Exposed to a spirit
alcohol flame for one minute, it was'extinguished after 20 sec, whereas
industrial FIH-1 (PN-1) diethylene glycol maleinate resin was burnt up:
completely. With addition of 1% of,Sb, it was extinguished after 2 sec.
Glass textolite made of this resin and ACTF-6 (ASTT-b) glass fabric
(ratio 1:1) was extinguished after 15 sec after having been exposed to a
Cas flame for two minutes. The loss in weight was 5%. The glass 2
textolite had a specific gravity of 1,65, breaking strength 2750 kg/cM
bending strength 2700 kg/CM2,' compressive strength 1400 kg/CM2, re-
silience 160 kg/cm2, water adsorption within 24 hr, 0.1%. There are
20 references: 2 Soviet-bloc and 18 non-Soviet-bloc.
Card 4/4

ALISHITS, I.M.; SHTFUNYKHMAN, LUCHKOj R.G.; REMIZ9
Ye. K.
In combustible polyester resins based on pentaerythritol dichloro-
hydrin. KhJm.prom. no-3:174~176 Mr 161. (MIRA 14:3)
(Propanediol) (Resin?, Synthetic)

GADASKINA, N.D.; PLAKSA, Kh.LqQiiU
Sodium dodecylbenzenesulfonates based on coal-chemical materials.
Miirn.i tekh. topLi masel 6 no.2:10-16 F 161. (MIRA 14:1)
1. Vsesoyuznyy nauchno-issledovatellskiy institut neftekhimicheskikh
protsessov.
(Benzenesulfonic acid)
(Coke industry-By-products)

(Alcohols)

'ohols of C , oxo synthesis ac raw material for the
0 In -
prrAUCUOn O~Isurface-actilve auents. Khim. prom. 40 no.9:6J,3-
665 S 164. (HIRA 17:11)
Vqe:3oyuznyy nauchnc-issledo-iatellskiy i.n.-itituL neftekhimicheskikh
Pro LSSOOOV.

KLI"4-:';KO, V.L- r-JTKOVS.'-'lY D.M. l'.S*i",T'-L!l- . ly~&'-,.
4, e s en' 3~a--~a a~~.-~
ralyroa e ni~
J_o Vjasoyunyy a okj,,r .I -L5 i.,-J. ut ief Le Ihm* !,h---2k-
P', 7, Z:

GANK. IN, V.Yu. , K*'?,ii-11"I'll, P.
K;-re-,I-c:3 oft
bydrocarbinoi in ti;p 'L:uld s ev 7-
pha U I
2130 r) 06ri a
ej~ItCr 17 1064,
1.

t V
Ill 165.
a ~3 oraz riy3r n a u n,.,,
PP

-7 n- 47 (14 MPW
11, 08794-6 -jjtt~/EWPQ~ IJP(a) WW4R.~j
NRi IkP6030844 IV) S6URCE CODE: UR/0191/66/000/009/0 _0i_1/00_1_
ACC
~AUTHOR: Al'shits, I
M.; Anikina. T. A.; brad, N- M.; !S!jt lakh M. M.; Rudkovskiy, D.
~M.; Tsubina, Kh. V. ------
ORG: none
!
ITITLE: Unsaturated polyester resins based on neopentylglicol.
ISOURCE: Plasticheskiye massy, no. 9, 1966, 11-12
TOPIC TAGS: polyester plastic, copolymer, copolymerization, glass textolite, bonding
material, adhesive, synthetic material
ABSTRACT: An unsaturated polyester resin was synthesized by copolymerizing neopentyl;;,
glicol styrene or with commerical low grade molecular polyester-acrylate resin46
JTGM-3cand). This polyesterification reaction was conducted by stirring a mixture of
the polyester with either styrene or TGM-3 resin at 800C in C02 atmosphere. It is cone
cluded that the unsaturated polyester resins exhibited high thermal stability and that
they can be recommended for use as cements in the production of glass textolites.
Orig. art. has: 2 tables.
SUB CODE:, 07,11/ SUBM DATE: 00/ ORIG REF: 004/ OTH REF: 005
L
I Card I
n8t
UDC:
+A7A
678.6441430-9 : 678;746.'221.06 677.521t
441430-9 : 678,674142128~,41,06 677~521

GANKIN, V.Yu.; ROZOVSKIY, A.Ya.; RUDKOVSKI.X,J..~M-.1
Formation of a hydroformylation catalyst from cobalt salts.
Neftekhlmila 5 no-1:58-61 Ja_F 165. OAMA 18: 5)
1. Vsesoy-dznyy nauchno-issledovatellskiy institut neftekhi-ni-
cheskikh protsessov.

L1615-66 9-dT(M)/ET7(c) V IT(t)/
ACCESSION NR.- AP5021661 ~UR/0080/65/038/008/1670/1677
546. 731262. 3+66. 046
AUTHOR: Krinkin D. P.; Rudkovskiy, P. M.
TITLE: Thermal decompositionAof cobalt * b I ase
-carbony inthe liquid ph
SOURCE: Zhurnal prikladnoy khimii, v. 38, no. 8, 1965, 1670-1677
TOPIC TAGS: thermal decomposition, 'cobalt compound, carbon monoxide, metal
deposition
ABSTRACT: Starting materials were a catalyzate from the oxysynthesis -process
i and solutions of cobalt carbonyls in toluene.and,in different gasoline fractions.
Hydrogen was supplied to the reactor to. decrease the partial pressure of the car-
bon monoxide formed in the process. The process of decobaltization was carried
out at pressures from I to .300 atmospheres (absolute) and temperatures up to
200 C. Experimental results are presentedin tabular form and a diagramatic
scheme of the equipment is shown. The main factor in the thermal decomposition
of cobalt carbonyls is their breaking up on the surface of metallic cobalt. At the
I start of the reaction, nuclei of metallic cobalt form centers for decomposition of
1/3
Card

L 1615-66
ACCESSION NR: AP5021661
the carbonyls, either in the volume, of the liquid or on the surface of the appara-
tus. In the absence of metal-lic cobalt in the thermal decomposition zone, there
can be a long period of induction. At tempera 'tures of 160-200 C and'a partial
1 pressure of about 0. 5 atm (gauge) of carbon monoxide, the residual content of
soluble cobalt, 0. 001-0. 005%, is reached in 10-30 min and then.remains practi-
cally constant. Initial concentration of cobalt over a wide range (0. 1-0. 4%) does
not affect residual cobalt content. An increase in temperature substantially
increases the depth of thermal decobaltization. A partial pressure of carbon mo-
noxide of more than 1 atm (absolute) lowers the rate of thermal decomposition.
Introduction of suspensions of metallic cobalt considerably increases the depth 1
of thermal decomposition. In a column with a ratio of surface to volume of
0. a cm2/cm3 and an external heat supply (surface temperat4fe 10-16 C higher
than the temperature in the volume of the liquid), nV6f cobalt was 35 5016
_devositio
of the cobalt formed in the decomposition process. With turbulence resulting
from intensive mixing, the deposition increased to 85-9516. When the surface of
the apparatus was cooled 10-15C below the temperature of the liquid, the amount.
of deposited cobalt decreased to 5-10%. prig. art. has: 3 forinulasi I figures
Card

K:1 T I N P 1 iF1 0 V I Y I-. m

e in, -,
r
M
r
n 5- ~ i
;
,
.
n-
)
9:641-647 E IE5 M A 1 ;3
,
. .

"i, V. I;,'-' KII
F8 9 k h i -M
no.ll.-2329-233) 1' '(4

KRPIUM, PITKOUYTY', DX,
Efffen- t, of dbf a-. pro --a E,!3. Khiir,, prom,
r,
- C7 3 5 G (k!PA 17;6)
n

BRUNSHTEYNS, Boris Anatollyevich; KLIMENKO, Vladimir Leonidovich;
TS`YRKIN, Yefim Borisovich;,- -,D.M.,,nauchn.red.;
jjq~qV~SKIY,,~
SEGAL') Z.G.) ved.red.;.Eb1IYANENKO, V.-Isj tekhn.rede
[Production of alcohols from petroleum and gas] Proizvod-
stvo spirtov iz neftianogo i gazovogo syrlia. Leningrad,
Izd-vo "Nedra," 1964. 199 P. (MTRA 17:3)
4~

KRINKIIII D.P.1 RUDKOVSUI, D.M.
Formation of cobalt carbonyls frm metallic cobalt (powder)
and carbon konoxide. Khim.prom. no.9t655-660 s 163. (MIRA 16:12)
N~

MIMI
INYANITOV, N.S.; RUDKOVSKIY D.M.
Preparation of iridium carbonyls. Zhur.,obr.khim. 33,no-4:1053-1054
Ap 163. (MIM 16:~.)
1. Vsesoyuznyy nnilchno-issledovatellskiy institut neftekbimicheskikh
protsessov.
(Iridium compounds) (Carbonyls)

IMYPJIITOV, D.M.
Hydrogenation and hydroforar'lation in the presence of cobalt,
rhodium, and iridium carbonyls. Neftekhimiia 3 no.2:198-200
Mr-AP '63. (MA 16:5)
1. Vsesoy-uznyy nauchno-issledovatellskiy institut neftekhimicheskikh
protsessov.
(Carbonyls) (Hydrogenation) (Formylation)

f~U'Q,KOV-9KIY,-,Dtj.; IMfANITOV, N.S.
Reactions o-*:' hydrogenation and hydroforWiEt-ion c-1,
;~O, ene
under conditions of oxo synthesis. amr.priklAhim. 35 no.12:
2719-2724 D 162. (MIRA 1615)
1. Vsesoyuznyf nauchno-issledovatellskly institut neftekhimicheskikh
profsessov.
(styrene) (Oxo process) (Hydrogenation)
.W
"CO

RUDKOVSKIY, D.M.; KLIMENKO, V.L.
Production of propionic.aldehyde and certain syntheses based
on it. Khim.prom. no.7:484-486 Jl '62. (MrRA 15:9)
1. Vsesoyuznyy nauchno-issledovateltskiy institut
neftekhimicheskikh protsessov.
(Propionaldehyde)

RUDKOVSKIY.~ D. M.
Dissertation defended for the degree of Doctor of Chemical Sciences
at the Institute of Hetrochemical Synthesial in 1967:
"Obtaining Ocygen-containing Compounds Using the Oxo-synthesis Method.,
and Development of Several Other P~rocesses for Obtaining Chemical
Products,Based on Crude Petroleum (Compilation of Studies)."
Vest. Akad. Nauk,SSSR. No. 4, Moscow, 1963, Pages 119-145