SCIENTIFIC ABSTRACT REBANE, L.A. - REBANE, V.N.

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SCIENTIFIC ABSTRACT
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21018 S/O-,-8/61/000/005/026/050 4, J,!p o 38~1 113 7/ 7) AOOl/AlO1 AUTHOR- Reban~!,_-L-A- - TITLE- On conoen'tration quenching in the NaCl-AS phosphor PERIODICAL% Referatlimyy zhurnal. Fizlka, no 5, 1961, 181-182, abstract 5V386 L (it r1'r. . I.n-.a fiz. 1 astron, AN EstSSR!', 196o, no 12, 49-66, Engl. summary) TEXT- The author investigated spectral characteristics and quantum yield Q/ of emission in NaCl-Ag phosphors with different content of activating admixture. He shows that in NaC1_AS phosphors there are centers of two types, which include different number of actlva-.or ions. He shows also that the main part in the ob- served process of concentration quenching in this case plays the competition be- .ween centers of the 1st and 2nd types in absorption of quanta of the excitation light. (Abstracter's noter Complete translation.] Card 1/1 113?1 1137 /35 T) AUTHORs Rebaneq L.A.- 20824 S/OA8/61/025/003/012/047 B104/B20', TITLEt Concentration and temperature extinction of luminescence in some alkali halide phosphors activated with silver PERIODICALg Izvestiya Akademii nauk SSSR. Seriya fizicheskaya, v. 25, no. 3, 1961, 345 - 346 TEXTs This is a reproduction of a lecture delivered at the 9th Conference on Luminescence (Crystal Phosphors), which took place in Kiyev from June 20 to 25, 1960. The author studied the phosphors NaCl-Ag and NaBr-Ag, a characteristic feature of which is the complete solubility of the activa- tor salt in the basis. PhO2phor XCl-Ag in which the limit solubility of AgCl at room temperature does not exceed 0.2 mole% was taken for a compa- rison. As was shown by a study of the absorption coefficient as a func- tion of the activator concentration in the two abovementioned phosphors, the shortwave bands must be assigned to centers containing an Ag + on (centers of the !at kind). The longwave bands must be assigned to centers Card 1/3 20824 S/048/61/025/00x/012/047 Concentration and temperature .... B104/B201 containing two Ag+ ions (centers of the 2nd kind). The centers of the let kind prevail a low activator concentrations. The centers of the 2nd kind grow in number with increasing activator concentration, and the maximum of the band shifts toward the longwave region. As may be seen from ths diagrams in Fig. 1 showing the radiation yield as a function of the acti- vator concentration, this yield is dependent upon A exe and differs for different centers. The competitive behavior of the centers of Ist and 2nd kind are inferred in a discussion of the diagrams shown in Fig. la. The drop of the total radiation yield is explained by the competition with centers in the stage of a temperature extinction. The study of tempera- ture extinction in silver-activated phosphors is rendered more difficult by the strong temperature dependence of absorption, Thusq 0absorption rises to the 3.8-fold at a temperature rise from 20 to 370 C. Moreover, the ratio of absorption in centers of Ist and 2nd kind varies with tempe- rature, which holds true especially at high concentrations. The tempera- ture extinction of the centers of 1st kind follows the Mott formula. In a discussion which followed the lecture under consideration, Z.L. Morgen- shtern stated that the shortwave bands in the phosphors dealt with pro- Card 2/3 20824 S/048/61/025/003/012/047 Concentration and temperature ... B104/3201 bably belonged to the pure lattice, and not, as 'assumed by the author, to centers filled with silver. P.D. Klement and N.N. Vasillyeva are men- tioned. There are 1 figure, 1 table and 5 ref6rences: 3 Soviet-bloc. C. 'Ffa/r. 7. C"-frw 70 Legend to Fig. 1: 1a) radiation yield of N&Cl-Ag phosphor as a function of activator concentration at /\ exc _' 218 mp, 1b) the -same for exc - 228 ML~ (curve 1) and 240 m~((Curve 2) exc Card 3/3 REBANE, L. Ye. Role of bronchoscopy in operations for tuberculosis of the lungs. Xhirurgiia 37 no.1:87-93 Ja 161. (MM-A 14&2) 1. Iz khirurgicheeikogo otdeleniya i otorinolaringologicheakogo kabineta Leningradskogo nauchno-isoledavatellskogo instituta tuberkuleza (dir. - prof. A.D. Semenovp nauchnyy rukovoditell prof. I.S. Kolesnikov i kand.mied.nauk M.Ye. Favle-nko). (TUBERCULOSIS) (BRONCHOSCOPY) ' 14"IC' PROpy kxd 84' THECALMIA! -WtMiiAL~ D QLLCUL El; hWTHOD` 0 V!NG * - fa uss In A ohs ~dlminslonal Ha M'114~~- ~ )Wule In the iise' -aluniform. tmian for tbe~wetbllljc -mic modd of of ~ :eti6 fleld AndAtmni-4strg thv, contln~ity.coiZitlo" atthi fattice-_ a i nctions, derfies,x wd of col~~ttnj th Wool. matt a magnetic propert j7u f irelectrons irvarbrnatic xnolmlesv -The mithod ji sh to lead to'res ob eclilar-torbit inbthod.*-:. to ihoie: er ~M r AUTHOR: Rebane, T. K. TITLE.' On the Calculaticn of the Magnetic Properties of the Molecules by Mear.9 of the Free Electron Model. II (K raschetu magnitny?a svoyatV molekml po metodi, metallicheskoy modell. H). PERIODICAL.' 'QJ Vpqtnik Leningradskogo Universiteta Seriya I ziki i Kaim1lli, 1957, Vol. 22, Pr It, PP. 70-75 (USSR). ABSTRACT: In one of the earlier works, based on investigations, the unidimen- slonal. free electron model (metal model) has been suggested for the calculation of the diamagnetic anisotropy of aromatic organic mole= cules. The present work attempts the realization of the above Men- tioned calculation method and its comparison with the molecular-or- bital theory. As a result an approximate equivalence of both methods at the calculation of the diamagnetic anisotropy of non-excited mo- lecules has been found. A theoretic verification of a formerly sug- gested empirical rule for the determination of the form of the uni- dilriensional potential in conjugated molecules containing hetero atoms is given. There are 8 references, 3 of which are Slavic. Card 1/2 On the Calculation of the Magnetic Propqrties of the Molecules c~4-J~-9/2o by Means of the Free Electron Model. H. SUBMITTED.- February 19 1957. AVAILABLE: Library of Congress. Card 212 ji5RA IVE) 7 -k7 'U THOR REBANE, T.K. Computation of the ALnisotropy of the Diamagnetic Suceptibility of the Aromatic Molecules with the Aid of the Method of the Metallic Model of the Molecule. (Raschet anizotropii diamagnitnoy vospriimehivosti aromaticheakikh molekul po metodu metallicheskoy modeli molekuly-Russian) PERIODICAL Doklady Akademii Wauk SSSR,19579VOl 114,Nr IPPP 7P-72 (U.S.S.R.) ABSTRLCT The paper under review corrects an alleged error contained in the method of computation employed by H.V.Volikenshteyn, L.A.Vorobinakiyq Dokl.Akad.Nauk,Vol 85,Nr 5oPP 9770950gand'suggests the utilization of a now methodflor the computation of the diamagnetic anisotropy of the aromatic molecules in the framework of the metallic model without application of theport*rbatlon theoryoThe auldiaensional Hamiltonian, which describes the behi6ior of the 19-olectrous In the iiagnetio field, had been chosen in the above-2 ti nod pr I iapei,in the follo- 0J 2 :7- 2/ da . (The coordinate s d8 wing forms HW.(1/2)d - ( 0) 12 . was computed along the bond.Purth oreqth* Lit# 6-m-h-1 wore employ- ed).In the computations contained in the above papertonly the thd:rd term in thia Hamiltonian was used an perturbation operatur.The paper under review9on the other handgmaintaine that in the second perturb&- tion-theoretical approximation also the contribution of the second term must be taken into consideration. But the problem of the energy spoo- trum and of the wave func-Lione ofthe x-electrons in the metallic model Card 1/2 of the molecule permits in the case of a homogeneous magnetic field an RE9A~-T., T. T., Cand PhY5-Math Sct -- (dIS5) "Concerning the computation of Oiarnae3netic sqce~tibillty of the 1-electronic shells of aromatic molecules w4gt"he-ass-tstanee of a wodel con- tainin# free electrons." Len, 1958. 9 pp. (Leningr Order of knxkxxx Lenin$ State.Univ Im A. A. Zhdanov), 100 coplos. (KL, 9-5518, 113 10 - 551-4 -3-18/30 Al "'i-TH OR t~ebani~:- -T.K. I L~, Clloilf----~ rf tlo~. In-Ltial Sin-6--le-Elect-l'o --.i I'VI a 7,-e - - 311 r- ct ions for the Sc)ilzti~,)n of 2--'Lel'd Er~uations V.,ith ExchanL,-t~ (0 vybo--a iskhodnylc:r od-ni)o~lektronnykh samosoglaso- --aar ; c, 1,-fu~-jKt s i-1 pri T-e -li~avneni7 Lof,,--) p:-,Iya f, clbueu~:ja -PEI,~IWICAL: SpektroskurjJ- Lya, 1'91-8, Vol,IV, Nr.71, ,)P~398-400 (USSR) ABST!Li~CT i The i:~eth,-,d ,:..f self-3cnsisteut ---'-Le--ld v7-it-l exchange f irst by V.A, F,~k (FGck) in I-q-,)O (Ref".11) makes it possible tt, 'Cind ~he. ~,est fG-- a Multi- electron sycte-, --aith full separaticin of ttle variables of se-oarate, In th-is mp,-!..hc.C,- 1--he groland- state wave-Dj-,nctiof- of An ~.---~)lecturon system is given in i-lie form. of a determinant consistinG of single- elei-.,uron fun,:~ticnq Tj-- Sinre the wp-7re-f-unction and all physioal lir:)pp-rties of an r,.-electron system -ire in-varian- under 'LLnitai-y tral-ls.+ornLationc of the -,:-ave-funclt.-Iions oz o e -ay. S -L r m -I u e "lard 1/2 c-L' the -~D~ as; new 3-18/30 Choice of -L,~.Le Initi-al S4 fo_- the Solu- tior_~ (4, e n ,c hEx.~han- F~i~.dJ Ecpa+-~ons w-' 1f lunsisL T-ric, autho:, derives a oond.it-Im f,-I, "JoiOP, froa all .. - ~(05 - pe z~.sible o7,thogonal of:' ~:3 b in -a ~ -or - r-, ft lie n i t -A r; ir, c-, e - ae ct ron i~, r. -~; t i c, n, _n I .a t-fur_.~;tLon v.-ii--;-,.h iZ the beslu initial a,o roxia.-ati.cn. t, c a, S._)JU4-.jOj of p - - the self-consistent fi(:~Ild equ-atfon innrolveO i, Thraie are 3 reference-S of vihi-b. 2 aiy,, Sc,,,--et and 1 Gelman. Len-inGrad ~at,e Tjni~:-ers-_--t7 (L-_rLir_,--x-adskiy ;6.o s" Id r t~ t -,~elln_ly Un i _11,f3 f - s I t e 1. Elect.-on wa-res-Theor jr 2. Electron waves-Yunctions 3. Transformations Card Ada;.-iov, *,~. N. , veselov, Rebane, T. K. --n__ , TITLE: The Electric aid Ya6r~~iic Properties of Uolecules With Complicated Structure Calculated on the Basis of t-e Free-Electron Model (Raschety elektricheskikh _J -ma,-nitnykh svoystv slozhnykh molekul na osnove modeli svobodnykh elektronov) PMTODIC-'L: Izvestiya Akademii nauk SSSR. Seriya fizicheskaya, 1958, Vol 22, Nr 9, pp 1o15 - 1o18 (USSR) ABSTRACT: The authors succeeded in computing the polarizability and the diamagnetic susceptibility of n-electrons on the basis of the simple model of the free electrons. The polarizability cL of atoms and molecules usually is computed by perturbational methods. For the com- Dutation of the n-electron longitudinal polarizability Card 1/14 of t~ie polyenes C2nH2n+2 the formulae The Electric and LTagnetic Pronerties of Molecules W--t*1 SOV/4a-22-9-1/40 Complicated Structure Calculated on the Basis of the Free-Electron ""odel 4En an (W - p LW4 n (_,)n_,0, P nL sin pnL (_,)n_cos qn + (2) sin qnL CO 2 and n(o) L4 (15 - T12 n2 (3) 121t4n2 were employed. The results, together with the results obtained by Bolton (Ref 1), are listed in table 1. The polarizability of the electrons was also determined for the case of a ring-shaped and a hexaEonal molecule. A simple mathematical scheme was worked out, which allows to determine the aave function and the encrgy spectrum of the R-electrons in the magnetic finld very exactly. If the one-dimensional potential of the conjugate bonds is everywhere equal to zero, the problem Card 2/4 is represented by the determination of the eigenvectors T'-e Electric and Properties of Molecules With SOV/_'8 -22 -9 - 1 /4o Complicated Structure Calculated on the Basis o_4' t-,e Free-Electron ,,~~odel of the Her-itian matrix. The energy spectrum of the g- electrons in the magnetic field ;~,nd their diama.-netic susceptibility are determined according to the secular equation det W = 0. This computation method of the diamagnetic susceptibility can be extended also to the case of a variable one-dimensional potential. The method allows to consider the influence of the intramo- lecular periodic field as well as the deviations from the periodicity. Starting from the matrix-formulation of the i)roblem the connection between the methods of the free electrons and of the molecular orbits was investigated. The agreement of the energy spectra shows by means of t;le results obtained by the semi-empirical method due to Pariser, Parr and Pople (Ref 4)that the depth of the potential well in the place Wnere the atom j is situated is given by the equation 1 V -2 C(2 - q i)I j + qjE il N i0. This equation validates fla_~-d 3/4 the semi-empirical formula suggested by Veselov and I OU T'-e E'lectric and Magnetic Properties of Molecules 7iith SOV148-22-9-1140 co7,.:jlic,qted Structure Calculated on the Basis of the Free-Electron I!Zodel Rekasheva (Ref 5). This formula describes the relation between the shape of the bottom of the potential well in conju.-ate molecules which contain hetero-a-toms, and the potentials of the electron affinit'y and the ionization of sin,~;le atoms. There are 2 tables and 5 references, 2 of which are Soviet. ASSOCIATIN.~: Leningradskiy gos.,universitet im. A. A. Zhdanova (Lenin- .-rad State University imeni A. A. Zhdanov) Card 4/4, SOV/51-6-1-4/30 ALT IU OP Rela:~.*., TA, TITLI klu tho. A'Aorrti-Ion, Spei~tra ;:~r Aliphatil FoIyEiulphides 101~ :!pektr&4 pr,;. iya ai-ifatichaskikh PL- R.L v!j 1 UL Opt-,k& 3psL*.tr-.,aLcpya, -Z,, Vcl IIr I, up 21-27 kUSSRj BS,i ?,tI C. T . ~t!. ~'rt F-b~ ,t2..;i ~-I' ali-Phatic! vc-ly.,~,.-,Iphides are I . t, I t3 r"'e, ats:wi of aulp~-jrar in the polysulphide hE-,- --i as the chair. lanjtham-t thq abrorption spectra are displaced tovmrdy. IcnS,5r wa-reienrths-. The avthoz attempts to find the reason '.Y applying cjuant,=-chemical prirciplas to the C D - e -~trM ~Irlsetra cf ali-hat;c noly-salohides. He shows that this dihpla,-Nnent iz 4-,4e tv zolitting ef the vIp- and 4s--!evols of sulphur at,)mp ir, the poly-Pulphide nhain. quantum-mechanical calculation of the displan--eintint '.y th,3 methcu of inola7:ular orbits produces a satisfactory agreewerA; wiv-, expenimen-b as zhovm in a table on p 27, where col 2 slve,~ vile GxparJuzantal (~'rcm Refs 3.4') and col 3 the theoretical po~itionr- the absorption maxima in aliphatic polysulphides. Card 1/2 SOV/51-6-1-4/30 On mo Ai.)-,c,rntj;.n Z-oe-tra of Aliphatic Polysulphi-I-el, I - .1 la ra z:e;r J s unti rely tnvoroti- a' , The author thanL-z YeAl. Gui~ 7 yan(;*,-&. f c-g, he:: o= , Thers are 1 tablo and 4: English -. S U Bto I T TED -, bia T 'U 1 , ,~..' Card ?1'e AUTHOR. Rebane, T.K. SOV/51-6-2-35/39 THIS 0 Borovinskiy "On Conditbns of Joining of Functions in a Unidimensional Me4allic Model of a Molecule" (Fo povodu stat'X L.A. Borovinskogo "Ob iisloviyakh ilthivaniya flunktsiy v Odnomernoy raetallicheskoy xodeli itolskuly") P&RIODICAL; Optika i Spektroskopiya, 1959, Vol 6, Nr 2, pp 266-267 (USSR) ABS TRACT: Boroviaskiy (Ref 1) has expressed a view that in unidimensional metallic models of molecules it is not necessary to preserve continuity of mave- functions at the branching points. The present author (Rebans) questions Borovinskiy's separation of variables when dealing with a "ring -with a DrOjeCti0n" Model (Fig 2 In Ref 1). The author also criticizea Borovinskiy's method of joining wave-functions, which does not allow for interaction between)t-electrons of various members of b1phanyl and benzene-type molecules. Borovinskly (Ref 1) has discussed the ItrIng with a projection" model, when the projection length approaches zero. A node of the unidimensional wave-funetion is then found at card 1/2 On the Nper by L.A. Borovinskiy "On Conditions of Joining of Functions in a 'Unidimensional Metallic Model of a Kolatrale" the point -where the projection uss formerly attached to the ring. Borovinskiy suggested thail, tAs node Is due to joining of wave-functions at the branch4ng point. The present author (Rebane) ascribes the node to the special conditions (an infinitely high potential barrier) at the outer end of the projection. Thoins is reference. SUBMITTED: May 16, 1958 oard 2/2 PHASE I BOOK EXPLOXTATZON SOV/4186 Abcademays. nauk SM Stroyanlye vashchestva I APektr*BkOPIYA (StructurO Of Matter and Spectroscopy) Moscow, lzd-va AN 5S3H, 1960. 113 P. arrata slip inserted. 2,300 copies printed. 9d.z X. V. Aatakhov. Professor. Tech. Ed.t T. P. Polanova. PMPOW j This collctlo~ of articles In Intended for physicists and chemists interested In spectroscopic methods of research an the structure of molecules and r*Iated problems. COVZR.AGEt The articles contained In this collection were taken from the editorial files of the Zhurnal fizichaskay ~jmtL (Journal of Physical Chemlstry) and are concerned with spas trosoopic methods In research on the structure or a0locul h in Lhydrogen bond, isotopic effects, problems to he stry, the structure of aqueous solutions or olectrolytea, and the chemistry of complex compounds. Refer- ences accomosnY Individual articles. The author thanks the following for having participated In determining the density or deuterocompound3: V. 0. GOICT, P. N. KkOl&je~, V. 1. K=her-f&vyy, Ye. Z. Zhur- avlev, V. I PUMInp and L. S. Zhilkin. He thanks A. 1. Brodskly ro~ his discussion of the results. Ar. zevA A. M., InI M. Z._ALL".haler [Novocharka" kiy ;,)II- tk:=rche_i`oL17 In3t1E'u`T1iovoch~;ikaii1C Polytechnic lnstitut~].. Problem of Change In the 3tracture of Polyethylene at plan*-WI&I Extension 69 _P-Aktb~~~_ Ye __t__1UYjkOva , S. D I Ulch and V. 14. NkjS0_;~j_!v (ii6r.kiy State Univ-ft-N-17ty JL&~ - --Z7 on the Via 0 im..J. X. L. Lobachevi Y . isotopic Effect c dity or I)OUtoroaltobola T3 Icinke and V ps5enko tnveoti- i7ailon or Surface' Tension or Liquid M --t-- e a. ~-3oj~u;Fo-ns. 1. Sar- face Tension of a Lead-Ulver System TB VsjAhftr&__T_-t-- CoOrUMaticn Equilibria of Nickel tons in qO - Pbo - 3102 System Glass" 84 Kole Icy -mii 3ilikatov (institute of Inatitut khi ;n SIlicates)j. Structure or Spojumene GInaJ 93 V. 1. Av4r,yanov is thanked for having plott3d the curves ror a- and p- spodumene and for the crystallization product or spolumene glass. n: teralcal Ya. Karpov). fo~ Phys tco4t Institute Imenl L. -a4-.':udst on of Excess %-Electron Diamagnetic SuaceptibilitY n ~ at' Certain MalectUes C-ntaining the SIX-Yember Carbon Ring With the Aid or the Pre-e ElectronA Model 96 The author thank3 1. N. Kalachivaya and B. Ye. 3amcdudOv ,ror the numerical calculations, and Ye. N. Gurlyanova M. ?(. Ala=v for their auj~g.stlons. 9. Ya.,.. and M. N. ~.I'A31ayl~va ctn3tltuttobB~ct'ey I reorg&nIcFii~ZGY kh-1111 Ili _- 24-__�~.-_ rdrITskava (rns itu'~ ')f General and InirganIc C~;-IsCrY I=enl :1. .3. K~trnakov)). Temperature Depenlinci or C.orllnati~n Nab~rrs of Alkali get" =lcaj,ln ATJ,!Jus Sol'Ition3 102 t"t"'ttir-in n )[2sj_n tnntit4 1 1 5 Klro~ 3urra~c rendlon taotherr.3 AVAILAULS: Lltriy af C~ngreB3 6 10-20-60 S/051/60/008/02/026IJ5(~ AUTHOR.E. baranov, V.1%1 and Rebanel T.K. E201/E3191 rITLE On the SeRLI-empirical Calculation of the Ionization Potential+ f Aliphatic Compound q PERiQDi(_AL: Optika 1 spektroskopiya, 1960, Vol 8, Nr 2, pp 268 -- 270 (USSR) i'~,bSTRA,"~: Using Fok and Hartree's self-consistent field method (Ref 1), Hall suggested a semi-empirical method of calculating the ionization potentials of similar moleculet, (Ref 2)~ The method is simplest when applied to aliphatic molecules. Structure of the latter is assumed to be such that all the carbon atoms lie in one plane. Calculations are greatly simplified if antisymmetry of the ionized molecular orbits with respect to reflection in the molecular plane of symmetry is assumed. Then individual groups of atoms in a molecule (e.g. CH 2 can be represented by parameters calculated from the experimentai ~7alues of the ionization potentials. For normal paraffins, C nH2n+2 ' Hall obtained the following forml_,!-ri for calculation of the first ionization potentials (Re~': C!~~) S/051/6o/oo8/02/026/036 On the Semi-empirical Calculation of theEioonl~EUK,n Potentials of Aliphatic Compounds Wh I(n) = -a - 2b cos W 11 + 1 where "A" is a parameter which describes the CH 2 groups and the end groups CH (CH and CH are assumed 3 2 3 to be equivalent) and "B" is a parameter which describes interacting of neighbouring groups. The parameters flail and "b" were found by Hall from the experimental values of the ionization potentials of normal paraffins. Similar calculations but with different parameters were carried out by Franklin (Ref 4). The present authors used the above equation and various values of "a" and Ilb" to carry out the same calculations. They found it impossible to approximate satisfactorily the ionization potentials of molecules of the whole paraffin series using Eq (1). No improvement was obtained by introd Card2/4 u S/05l/6o/oo8/02/026/o36 On the '~',,;ii-empirical Calculation of fK06100RHation Potentials of Aliphatic- Compounds a correction to the parameter "a" allowing for the non- equivalence of the CH 2 and CH 3 groups. If, however, we assume that for some reason the ionization potentials of methane and ethane cannot be represented by Eq (1), then for the remaining members of the paraffin series we obtain good agreement wi-th experiment (Table 1) for Ila" = -14.o6 eV and "b" = -2.02 eV deduced from the experimental values of the ionization potentials of propane and butane. The present authors calculated also the ionization potentials of free aliphatic radicals (CnH2n+l ). To describe a group with free valence and its interaction with neighbouring groups the authors used two new parameters determined from the mean experimental values: ICH- = 9.96 eV and I C2H = 8.72 eV 5 The results are given in Table 2. They agree quite well Card3/4- 0~) S/051/60/008/02/026/036 On the Semi-empirical Calculation of thle'?100'Mion Potentials of Aliphatic Compounds with those reported by Stevenson (Ref 6). There are 2 tables and 6 references, 5 of which are' English and 1 German. SUBMITTED: July 6, 1959 0 _.J~ /,/4 AUTHOR: Rebane,.T.K. EZOI/3691 TITLE: Calculation of the Polarizability of q2qu&a~~d Molecules, with Alloviance for the Electrostatic Interactions oCfiY-l;ctrons PERIODICAL -.Optilca i spektrookopiya, 1960, Vol 8, Nr 4, pp 458-464 (USSRj ABSTRACT: The author considers the effect of the electrostatic interaction of TL-electrons on the polarizability of moleculea with cpAj~%gatfid .-single and doublp bonds.'~ Perturbation theory formlae are obtained for the self-consistent field method. The theory developed in applied to molecules of ethylene and benzene employing simplifying assumptions which are used in the semi-empirical variant of the salf-consistent molecular orbit method. It is found that the electrostatic interaction of a-electrons lowers considerably the ft-electron polarizability of conjugated molecules. In conclusion the author points out that the polarizability of conjugated molecules may be altered also by inter- actions of JI-electrons with, say, 6-olectrons . The paper is entirely Card 1/1 theoretical. There are 15 references, 6 of which are Soviet and 7 English. S/051/60/008/04/005/032 SUEWTTED. July 20, 1959. REMNE, T.K. Variational principle for the calculation of the correction to the energy, of an electron in a molecule. quadratie with respect to the magnetic field strength. Zhur.eksp.i toor.fis. 38 no.3:963-965 Mr 160. (MIRA 13:7) 1. Fiziko-khimicheakiy institut im. L.Ya.Karpova. (Blectrons) ;F 86036 S/02o'/6o/, -5/003/0!6/039 BO I 9/B077 A Ll 4 0 0 AUTHOR: Rebane, T- K,, TITLE: The Relation Between the Number of 2c Electrons and the Characteristics of the Magnetic Susceptibility of a Type of Aromatic Molecules V, PERIODICAL: Doklady Akademii nauk SSSR, 196o, vol. '35, No, 3. PP~ 568-1-70 J TEXT. Here 'those cond~-tions are examined by which the contribution-XT,- of the interatomic Ir electron currents to the susceptibility of aromatic molecules have a paramagnetic and not, a diamagnetic characteristic. In simple electron approximation X-V = 7 j y (1) an approximation of p P'p k the disturbance theory yields X X(1) +)((2) P lp lp 2 2 2a2 12 ( k pl- q1 pOSOK Y I C* C )S2 2e kJ q 2 2 - k pk P1 Pi pk kl)kl 2 2 h C k,1 h c q+p P q Card 1/2 REBANE., T.K. Effect of the degree of complanarity of a molecule on the signs of conjugation of-jr-electrons. Zhur.fiz.khim. 35 no.8:1681- 1690 Ag 161. (MIRA 14:8) 1. FizLko-khimicheskiy institut, imeni L.A. Karpova. (MolecuIar rotation--Models) (Electrons) ADAMOV, M.r.; REBANE, T.K.; EVARESTOV, R.A. Variational estimation of values computed in the second approxima- tion of the perturbation theory. Teoret. i eksper. khim. 1 no.5t 588-594 S-0 165 (MM 19:1) 1. Fizicheskiy institut Leningradskogo gosudarstvennogo univer- siteta. Submitted June 23, 1965. L 04759-6-7 EWT(m)/_K1T-( 10 ~E_r-T Tj_- jD ACC NRt AP6025967 SOURCE CODE: UR/0051/66/021/001/0118/0120 AUMOR: Rebane, T. K. ORG: none TITLE: New variational principles for dynamic and static polarizability SOURCE: Optika i spektroskopiya, v. 21, no. 1, 1966, 118-120 TOPIC TAGS: electric polarization, dielectric polarization, nonlinear functional rator, variational method, hydrogen ABSTRACT: The application of variational principle for the analysis of the upper li it of dynamic and static polar--zability in systems with an arbitrary number of elec- trons is discussed. In addition, the formulation of variational principles for the lower and upper limits of polarizability in excited states is provided. The dynamic polarizability of an n-state discrete spectrum of the energy operator H is given by in an electric field with the ~;tential w (r, t) - IV (r) cos Cord 1/3 UDC: 539.182 .-L W17~(2767 - ------ ACC NRt AP6025967 0 Operator H, its eigenfunctions ~n and function W(r) are real. The value an(")' where P = tc equals P. (it) W (r) ~. (r) where un(r;p) satisfies (H - En + p) u. (r; 1.) + IV (r)0 and the boundary conditions common for wavefunctions, u can be expanded into the following series V (k I W I n> ~k (r) qn ,,;~j (E. - Ek - p) By applying variational techniques to Un and the functional [(H - E. + p) u + WQ, u[(H-E.+p)t&+2W' dv,- K. (U; 1, 4) L .4 the authorb arTives at the expressions p,(jL)=miaK,(a: ix, A). and P.(jL)-mazK.(a; Card 2/3 - L 0059-:-67 ACC NR: AP6025967 which are in accordance with the variational principle. An example of utilization Of this method for calculation of static polarizability for the la-state of 01 hydrogen atom in a homogeneous field W(r) = z is included. Orig. art. has: 15 formuiii-.~I SUB CODE: 20/ SUBM DATE: 27Dec65/ ORIG REF: 004/ OTH REF: 006 kh Card -3/3 ACC NRt AP6036952 souRcE coDst uR/oj8i/66/oo8/oi1/31 AUTHORt Adamovs, M. N.; Isdovskayaq le. M.; Rebanep T. X. ORG: leningrad State University iM. A. A. Zhdanoy (Laningradakiy gasudarstyennyy universitet) TITLE: Variational calculation of the polarizability of the F-center in alkali halide crystals (point lattice approximation) SOURCE: Fizika tverdogo telap v. 8. no, 11, 1966, 3t73-3i?6 TOPIC TAGS1 F center, alkali halide, variational method, ground state ABSTRACT: In order to calculate atomic shifts and frequencies of local oscillations in.arystals with defects, it is necessary to estimate the static polarizability cL ~of'.ihe defects and ions of the crystal base; this was done both from above and from A variational method of the perturbation theory was used to findo in the poin iA approximation, the narrow interval in which is located the value of the polar !iMibility of the F-center corrresp,onding to the model potential V(r), The following ,--,4wave function was used to describe the groupd state--bf the F-centert Optimum values of parameter y for NaC1 crystals were determined from the requirement 1/2 ACC NR, AP6036952 of minimum energy of the electron described by this function and located in the field of a nonpolarizable point lattice with an anion vacancy. The excitation energy Elp - Els was found to be I 15 T-~ - 15-523 and the estimate from below, ct,< 15-556 The two sets of estimates for various alkali halide crystals are tabulated. It is concluded that the variational calculation gave a precise value of the polarizabi-lity of the ground state of the electron moving in a field with potential V(r). Since, however, the model potential V(r) describes the F-center only approximately, the re- sults of the calculation may differ from the actual value of the polarizability of th F-center, being probably somewhat high. The numerical calculations were performed 'with a BF-914-2 computer, and the program for calculating the optimum value of paramete r was written by B. Ya. Frezinskiy. Authors are grateful to I. V. Abarenkov for dis- cussing the work. Orig. art. hast I table and 11 formulass ' SUB CODE & 20/ SUBM DATE s 08Feb66/ ORM MW 1 0031 OTH RU 1 003 2/2 L 12003-66 EWT(1)/h'V1P(m)/EPF(n)-2 ACC NN AP5022857 SOURCE CODE: uR/oo5i/6.5/ol9/003/0313/03i6--I AUTHOR: Rebane, ORG: none 7 TITIE: Perturbation theory in the Hartree-Fock method SOURCE: Optika i spektroskopiyaj ir. 19, no- 3, 1965~ 313-318 TOPIC TAGS: Hartree Fock method, perturbation theory, wave function, variational method ABSTRACT: The author examines the calculation of higher-order corrections to the energy of a many-electron system,, using the Hartree-Fock method, the applicability of which for calculations of not only unperturbed atom-molecular systems, but also sys- tems that are perturbed by an external electric and magnetic field, has been enhanced by recent progress in computational techniques. A general expression for corrections to the energy of order (2s + 1) and 2s is derived, in terms of corrections to the one- electron self-consistent wave functions of order not higher than s. The uniqueness of the selection of the appropriate single-electron functions is demonstrated. It is also shown that the perturbed self-consistent wave functions possess certain proper- ties that are similar to the properties of perturbed exact wave functions. It is noted in the conclusion that the results.can be extended to apply in the case of a two-electron perturbation operator, which is of interest in connection with investi- gations in which self-consistent functions are constructed in the form of series in Card 1/2 UDC: 539-182 L 12003-66 ACC NR% A-P5022857 terms of Inverse powers of the charge of the nucleus. Author tb&Ww Yu. who pointed out the possibility of applying the variational principle to the pioblem., and M. N. Adamv and Me G. Veselov for a discussion and coments. Orig. art# has: fo-rmuiss.7777- 4 3 SUB CODE: 20/ SUBM DATS: 03ALA/ OTH MW: 006 .4 REBANE, T,K. Variational principles in steady-state perturbation theory. Vest.LGU 20 no.22:20-28 165- (MIRA 18:12) 1 ~, :, I, z - PEBANEry T.K. Go,mr,ent on the approximate formula of Mulliken in the case of interaction between energy equivalent states. Zhur. strukt. khim. 6 no.1:176 Ja-F 165. (MIRA 18:121) 1. YLtefiankly lrutt,111(it Lonint, ,radokolro tro:ntdur-sLvantiof!o universiteta imeni A.A.Zhdanova. Submitted July 6, 1964. T,'I 1 C7 -T. le ctr ost a -ile 4n a moilec, opt. i mc REBAN"' , "'. K. Molecular gyromagnetism. Zhur. eksp. i teor. fiz. 47 no.4:1342-1344 0 164. (P =11'A le: 1) 1. Leningradskiy gosudarstvennyy universitet. RFBANE T K o . - Semiempirical method for determining the electrostatic potential of the electron shell of atomic nuclei in a molecule. Part 2. Opt. i spektr. 17 no.6:825-831 D 164. (MIRA 18-3) REMNE, T.K. Simple model for the rotary magnetic momenz; of a mo],.eccule. Vest. - LGU 20 no-4:30-35 165. OWUPIA. 18MILII L 14 ACCESSION NR: AP500044 ' ASSOCIATION: None. SUBMITTEW~ .300ct63 0 Gp- SIM-CODEi". NP ,NR REV SOV-i~-;~ 004 T1 3'. _j t'. L 1349. IoN NR AP40479011-~ ACCESS a- ev. ObIt and the nuclear motions- in add t, F v-* 45-4135i 3) h QV de bj ch. K. mukhtar MET oloctical, error ma ion,j the. magrietIc . h3.9 -of the.:ejectron c,cofit-ribut 0 analysis f M. 10. or=, ial - f olecule. orig. at :has: o a veto brad 9 Y. nq !ASSOCrAtIONIt LenIin4radskIi' tit rsity)~ Istate unive 'ENCL t 27Feb64 SUj3MiTTEDz- Nit'. 0 1 EK SUB CODE. I Ao, - 4, "n COrd. 2/2 ACCESSION NR: AP4042975 S/0051/64/017/001/0003/0007 AUTHOR: Rebane, T. K. TITLE: Semiempirical method of determining the electrostatic poten- tial of the electron shell of a molecule at the atomic nuclei. 1. Theory of the method for diatomic molecules SOURCE: Optika i spektroskopiya, v. 17, no. 1, 1964, 3-7 TOPIC TAGS: electrostatic field, molecular structure, atomic ion, atomic charge ABSTRA-_T: The author extends his previously proposed method (opt. i spektr. v. 16, 164, 1964) for determining the electrostatic potential of the-electron shell at the nuclei of free atoms to include atomic nuclei in molecules. The method is based on an interpolation of the energies of the iso-electronic ions and on the use of the Hellman-Feynman theorem (H. Hellman, Einfuhrung in die Quantenchemie, 1/2 ACCESSION NR: AP4042975 Edwards Bros., Ann Arbor, 1944; R. P. Feynman, Phys. Rev. v. 56, 340, 1939). The theoretical premises of the method are considered first for the case of isoelectronic diatomic molecules with a fixed sum of the nuclear chArges. This is followed by study of molecules in which the charge of one of the nuclei is fixed, and for Which much less experimental material is available. It is claimed that the accuracy of the semiempirical formula is not iniferior to that of purely theoretical calculations in the first type of molecules, but the results are only approximate for the second type. The applica- tion of the proposed method to concrete molecules wi'll be treated in the second part ofithe article. Orig. art. has: 19 formulas. ASSOCIATION: None SUBMITTED: 150ct63 ENCL: 00 SUB CODE: NP NR REF SOV: 002 OTHER: 005 AoAl-ION I !.'. KA'.G,~Ikl, V, *K,; fL"hz-IE, 111. ?". ll--'culating 3~tark ef--:'oct in the hydrogen aTom. Vest. LZU 19 no.10:3i-39 164. (MIRA 17- 7') 00z551U1N' ~,rt: A?4010232 8/0054/63/600/004/003 5100 8 AINHOR: Rebane,, To X. ,TITLE: On altarnation. effect of carbon-carton bond length on diamagnetic susceptibility c4uned by interatomic Ir-electron ourreabo in the hapta3An*-:-- SOURCEs Laninerad. UtAvarsitet. VestaLk. Strip fjolki I khIp"s vyVe 41 1963a TOPIC TAGS: bond length, diamagnetic swcoptibilitys aitermAtion'Weatp beawne, parampnaticj heptalene molecule, electron awrot 'ABSTMCTs T1,w alterrAtion effoot of oarbon-carbon bond length an X,,, introduced by interatordo 7r -elecizon ourrents in the mostio swoopUbility of hipytalene, has been inveOigated. The hq*alaw structure is given in Fig. I on the aftolow sure. The magnitude of is dste=lned froathe London ralationghip 2 1-2-) M.4 Acassiox xR% a4oio232 Calculation; show that alternatinC bond longt1w in heptalene maintain the "anomalous" Wamagnetto character o;C-?( but.significantly lower its numerical value. The magrAt4des of for heptalane C32~20 WA Asphthaleas Cos yield (0) rupectiv4r, hW*'X (0) magnitudes -;2,.75 -4 (0) *xA 2.185 X In the diamagnetic its ausoeptibility of bensenis and vmx -3~,26 to 4&5,3 x 10-6 =~/=I. "The !author is grateftl to Me.O& Ves*Uv vA 0. X. Dadtrlywa for their haVe" Orip art haa 3 6 formil" and 1 f4wreo aca* SUBICTTMI 04pr63 WS At W" -Emil Ol So CODZI 00 NO RN SM 002 QTMMI 006 77-----' 7- - ----- 4 Acassio,m NR& AP4MO232 ... A. . - Ago I I!, "1 .1 --M INGLosun: m 11 1 I I.- A R! BANE ) T. K ~ Semiempirical method for determining the electrostatic potential generated by electmns around an atomic nucleus. Opt. i spektr. 1.6 no.1.164-167 J& 164. (MIRA 17.3) REBANE, K.; REBANE, T., kand. fiz.-matem. nauk TL-.ory of Raman scattering of light by molecules. Izv. AN Est. SSR..Ser. fiz.--mat. i tekh. nauk 12 no.3:227-237 163. (MIRA 16:11) 1. Institute of Physics and Astronomy of the Academy of Sciences of the Estonian S.S.R. and Leningrad State University. 2. Corresponding Member of the Academy of Sciences of the Estonian S.S.R. (for K. Rebane). REBANE, T.K. Generalization of the concept of alternant conjugate MOle- cules. Vest. LGU 18 no.22:30-34 163. Effect of the alternation of carbon-carbon bond lengths on the diamagnetic susceptibility due to interatomic -elec- tron currents in the heptalene molecule. Ibid.:35-38 (MIRA 17: 1.) REBANE, T.K. Variational method for calculating molecular magnetic susceptibi- lity. Vest. LGU. 18 no.16.-7..Il 10"". (MIRA 16:11) ACCESSION NR- AP4011503 S/0051/64/016/001/0164/0167 AUTHOR: Rebane, T.K. TITLE: Semi-cmpirical method for determining the electrostatic potential produced by the electrons at an atomic nucleus SOURCE: Optika i spektroskopiya, v.16, no.1, 1964, 164-167 TOPIC TAGS: electron potential, electron field, electron electrostatic potential, electron core potential, light atom, light ion, hydrogen, helium, lithium, carbon, beryllium, boron, nitrogen ABSTRACT: Using the nonrelativistic wave function and ground state energy of an N- electron atom with nuclear charge Z, as given by the Schrodinger equation, an ex- pression is derived for v(O), the electrostatic potential produced by the electron shell of the atom at the point of the nucleus. Use is then made of the semi-empiri- cal formulas of other authors to arrive at a method for determination of the values of the electrostatic potential produced by the outer electrons of the nucleus of the atom. The values of the electrostatic potential for light atoms and ions from H through N+, calculated by the proposed method, are tabulated and compared with Card 1/2 ACC.NR: AP4011503 the theoretical values. The results indicate that the accuracy of the semi-empiri- cal method where light atoms are concerned is not inferior to that of the self-con- sistent field method. However, before the semi-empirical method can be extended to heavier atoms there must be constructred the appropriate semi-empirical formulas for the total energy and means found for taking into account relativistic effects. "The author is grateful to M.G.Veselov for valuable suggestions." Orig.art.has: 10 formulas and I table. ASSOCIATION: none SUBMITTED: l3Uay63 DATE ACQ: 14Feb64 ENCL: 00 SU3 CODE.- PH NR REP SOV: 002 07HER: 009 2/2 Card KOZWVY B.A. (MOSIM); RE'D;,NY, 11'.K. (MOSkVU) Calculation of the'Fr -eledtronic diamagnetic susceptibility of heteroatom-containing aromatic molecules using a one-dimensional model. Zhur. fiz. khim. 36 no.1:143-147 Ja 162. (AURA 16:8) 1. Fiziko-khimicheskiy institut im. L.Ya. Karpova. (Heterocyclic compounds) (Diamagnetism) 11, ;,netic susceptibility of a two-dimensional anisotropic harmo--dc oscillator. Vest. LGU 18 no.10:24-26 163. (MIRA 16.3) '1-ant-u-na theory) 4. ( ,_ REBANE, T.K.- __ 'Calculating the effective electron mass in a one-dimensional periodic field. Vest LGU- 16 no.22:21-2.1- '61. ( A 14': 11 ) (Electrons) Wave mechanics) ACC NR: AP7002413 AUTHOR: Rebane, V. N. ORG: none SOURCE CODE: UR/0051/66/021/006/0661/0665 TITLE: Influence of stimulated emission on the Hanle effect SOURCE: Optika i spektroskopiya, v. 21, no. 6, 1966, 661-665 TOPIC TAGS; laser emission) stimulated emission, line width, spectral line, line intensity ABSTRACT: The author proposes a theory which makes it possible to take into account the dependence of the Hanle line shape on the intensity of laser radiation, with particular application to a three-level system (energies Ea > Eb > Ec with moments Ja = 0, Jb = 1, and Jc = 0; laser emission corresponds to transition b - c). The ,-.heory is based on expanding the density matrix in powexsof the Larmor frequency, witt zigorous determination of the dependence of the expansion coefficients on the ampli- tude of the light field in the laser. This yields the dependence of the Hanle line shape on the field intensity in the laser, and also the dependence of the total spontaneous emission (from-the lower laser level) on the magnetic field. It is shown that the Hanle line broadens monotonically with increasing intensity of the spontane- ous emission, and that turning on a weak magnetic field in the presence of a - b stimulated emission leads to an increase of the summary intensity of the b-o c spon- taneous emission. This effect of the magnetic field is a distinguishing feature of 1/2 UDC: 621.375-9: 535-01 ACC NRI AP7002413 the Hanle effect.in the presence of stimulated emission. The author thank M. P. Chayka for suggesting the topic and for continuous interest) and V. I. Perell for valuable remarks. Orig. art. has: 17 formulas. SUB CODE: 2o/ sm nATE: 14mar66/ ORIG REF: 0031 ATD PRESS: 5113 I-L-1444- 94-T(Jrl-~/BD-S ASD ial-;Uzolblu AT300 2200 S/2943./63/001/000/0084/00?4 !AUTHORS: Levshin, V. L.; Rebane. V. N. i7TTLE: On luminescence spectra of benzoic acid d its salts ISOURCEi Optika i spektroskopiye; sbornik statey. v. Is Lyurdnesteentaiya. Moscowt zd-vo, AN SSSR, 1963, 84-94 :TCPIC TMS: luminescence, benzoic acid; absorption, emission i'ABSTRACT: A study has been made of the absor '.7 .ption and emission spectra, the laws of Pecay and relative yield of luminescence, and the effect of heavy atoms in benzoic. ,acid, the Na_, K , Cu , Ph salts of benzoic acid and C1 v Br~- substitutes at 2iquld p1trogen temperatures. The structure of the benzoic acid molecule is givens C1, 11r) .0* 0 off, -LO(H..N.. K, Cu)~ 6 N-rom the spectral analysis it was shown that the spread and intensity of the absorption bands vary uniformly from one salt to another and that the introduction Card -L 8 8.6 ;AC(1 P6 h_:___A_T_3_O__O_2_2_D_0_____ 'of Cl and Br ~iignificantly affects the electronic levelB* The spectra of -lundnes-' Pence duration seems to vary from that of absorption, wi;h emission bonds stroncO 'dependent on polarization media. Furthermorel the spectra of these isalts show individual characters and chpnge only slightly when heavy metallic atoms are Dres6at. 'Orig. art. has: 6 figures, 6 tsbles, and 6 formulas. ASSOCIATION: none SUBKTTTED: 0971ar62 DATE ACQ: 19ray63 'SUB CODEt PH NO REF SO`Vs 004 ACC NR, AF603" SOURCE CODE: UP/00 5 3/66/0211004/040 57Wf2- AUTHOR: Rebane V. Ow: none TITLE: Influence of an impurity gas on the polarization of resonance fluorescence SOURCE: Qytika i spektrookopiya., v. 21,, no. 4, 10, 405-412 ToPle TAGS: fluorescencep collision cross section,, polarized Imminescencep excited state, kinetic equation,,'byperfine structure ABSTRACT: This is r. continuation ok earlier,work (Opt. -is-speAr.. v. 2o,, iB5,, 1966) where the effect exerted by collisions with atoms of an inert-gas impurity on the density matrix of the excited atoms of the investigated substance was.considered. In the preceding paper the substan 'ce was in the state ILP.I. in the present paper these results are generalized to the case of an excited state with arbitrary electronic angular momentum in the adiabatic approximation. Kinetic equations are connidered for the density matrix of the excited state. A solution is obtained for these equa- tions in general formp in an approximation which linear in the pressure. In this ap- proximationp the degrees of polarizations (unlike the Hanle line broadening) d6 not depend on the possible change in the lifetime of the excited state due to the colli- sion. A numerical calculation 'is presented of the degrees of polarization of the res-- onance fluorescence and the Hanle line shape for different polarizations of the ex- citing liglrt,,. in the presence of a byperfine structure. The influence of the colli- Card 3/2 UDC: "5.372 4 ACC NRo 1AP603" sions on the degree of circular polarization is found to be twice as large than their influence on the degree of plane polarization. The Hanle line broadening in circular polarization is 1.6 times larger than the broadening in the plane polarization. The ,relaxation of the density matrix after turning on the exciting light and the attenua-, tion constants characterizing the fluorescence quenching at different polarizations are determined. The theory proposed can be refined by takin into account nonadia- batic collisions and by other approximations, but calls for availability of reliable experimental data on the depolarization of*the resonance fluorescence under the in- fluence of the impurity gas. The author is sincerely grateful to M. P. Chsyka for continuous interest in the work and valuable remarks.- OrIge art* has: 36 formulas. SUB CODE: 2D/ SM UTZ: OM PJ W, 0031 - IW 1 0(*' I Qrd 2/2 ATjTHOP-' Levshin, V.L. and Rebane, VXT. SOV/51-7-2--lV34 TTTLE: A Gamparative Study of Light-Sum Storage and Temperature Quenching in a ZnS-Ag Phosphor Excited -with P-Rayc and Light (Sravnitallnoys izuchaniye zapasaniya svetovylch summ i tsmperaturnogo tusheniya fosfora ZnS-,kg pri vozbuzhdanii 15-luchwni i svetom I FERIODICAL:oDtika i spek-troskopiya, 1959, Vol 7, Nr 2, up 236-240 (USSR) ABSTR~CT: The papar .~rds ~)resented by M.D. Galanin at the Vii-th All-Union Conference o- Luminescence on July 1, 1958, in 'Koscow. The papar reports a study of thermoluminescence and temperature quenching of tha ohosphor ZnS-Ag-MgG12 (10-4 g/g of Ag and 10-2 of MgCI2-. axeited b, .1 h .1 it eans of light and 13-rays. The c os-ohorss vara heated to 8000~; in air b3fora r!1easurements; they ware precared by V.I. Shchayenico. .1 D-~~rcury lamp P-R-K-4 was used in photo -excitati on; the 365 m1i line was seoar-ited out by ine-,.nq of a filtar. Beta-riarticies were from the f ol loving s ources : p32 (maximum #-energy E = 1. 7 !-',sV, mea n energy 0.7 LIeV) , T1204 (F , = 0.783 ileV, 9 = 0.261 MeV) and 335 (E = 0.167 MeV and 43 = 0.055 -11,3V). The phosphor was used in the ronn of a layer 0.25 a,:L thick. It vias excited with light or with 6-rays at the liquid- r,tro/F,en ta:nzerature, tha excitation then ceased and the phosphor vas rd 1capt in dar~zness for 1 ain. Next the ohosohor m~as heated at the rate SOV/51-7-2-14~/34 3ariparative 'Study of Lig- -Sum Storage and Temperature Quenching in a ZnS-A& ht j 0 Phos ohor Exci ted with p -Rays and 'Light of 15 de&/min. The intensity of luminescence of the phosphor was rocorded by means of a photomultiplier FEU-19 and a microammoter M-91. n-io peaks were observed on the th a rmolumines c once curve of the photo- excited phosphor (Fig la); these peaks were at -150 to -1650C and at -75 to -800C. The 19-excited phosphor (Fig 149-Z) exhibited the same peaks. it follows , therefore, that for both types of excitation the same system of local levels vas obtained. Filling of these levels depended on the type of excitation; when photo-excited the shallow levels -were filled to a greater extent than deep levels, and on AM-excitation the reverse was true. Filling of the local levels depands strongly on the intensity and duration of excitation. It was found that -when the photo- excitation intensity was reduced by a factor of 104: (frcm 30 to 0.003 VVlcm2) the rate of filling of the levels was the same on photo- excitation and onp -excl tat'-on from a 5.7 millicurie P32 source (Fig 3). It follons, there ore, tht the peculiarities of .0-excitation are entirely due to the low intensity ofd-rays. Calculations showed that both a 0,003 W1V/cm2 light beam and a 6-beam from a 5.7 millicurie p32 source Card 2/3 deliver energy to the surface layer of the phosphor at the same rate of SOV/51-7-2-14/34 parAtive 3tudy of Li,-,ht--Sum Storage and Temperature O;uenching in a ZnS-Ag Phosph or Exeited with p-RayL, and Light PA013 OV cm-3sec-l. The authors studied also the temperature quenchiu6 on photo- and p-excitation (Fig 4). It was found that at lo%. excitation intensities the temperature quenching beZins at lower temperatures than it does at higher excitation inten4ities. The temperature quenching curve recorded on excitution with p-rays from a 30 millicuria P32 source (dashed curve in Fig 4) is almost identical with the quenching curve obtained on ohoto-excitation at the rate of 0.3 IiTf/cm2. cknowledgment is made to rl~.D. Galanin. for his interest. 'there are 4 figures and 3 references, 1 of vjYdch is Soviet and 2 -~T:B1:ITT"6D: Ze7otember 2, 1958 rd 3/3 TSATSKA, S.M. ;REBAN:,;, Ye.I.;GE.RASIMOV, V.S.;MAKAROYA, G.A. Use of a centrifagal blower and tar extractor of the TsKTI-LPI type for the parification of crude gases. Gidroliz i lesokhim. Dram. 1Z no-7:19-23 '59 (MIRA 13:3) 1. Ieningradskaya lesotekhnicheskaya akademiya (for TSatska, Rebane). 2. Vakhtanskiy kanifollno-ekstraktsionnyy zavod (for" Gerasimov, Makarova). (Wood-using industries-lquipment and supplies) (Gas Durification) REBANE, Yu. [Rebane, J.] In the Estonian sky. Grazhd.av. 16 no.1:4 Ja 159. (YIRA 12:3) 1. Ifachal'nik otdela transporta, dorozhnogo khozyaystva i avyazi Gosplana Estonskoy SSR. (Estonia--Aeronautics, Commercial) REBANES, A. Estonian S.S.R. Avt.transp. 35 no.10:38 0 157. (MIRA 10:10) 1.Ministr avtomobillnogo transports, i shosseynykh dorog Ratonskoy SSR. (Estonia--Transportation, Automotive) jv\,-L. R rl a 8 s CA 4 31 .9 15 at 's .0 a Q uo -01 it 28 Ho di 4 ~vl 12, I to o no. P '5 wi v o i ij .3.1 6e ir ALITGAUZEN, A.Ya.; RKBARBAR, R.Ya. Laryngeal smear in diagnosis no-3:41-43 May-June 1951. of cancer. Vest. otorinolar. 13 (CIAL 20:11) 1. Doctor Medical Sciences A.Ya. (Kharlkov). 2. Of the Clinical Roentgenological. Radiological, (Dire ctor-Do cent Ye.A. Bazlov) Research Institute for Diseases (Director--Prof. L.L. Framin). AlItgauzen and R.Ya. Rebarbar Laboratory of the Ukrainiaa and Oncological Institute and of the Ukrainian Scientific of the Ear, Throat, and Nose IEDANOV, V.V.; REURDIR, V,M,; MOLCHANOV, A.S. continuously operating delay network using RC loops for automatiG -pliver thickness control systems of drawing frames. Izv.v-js*ucheb*zav.; tekh.tekst.prom. no-5:130-137 161. (MIRA 14:11) 1. Moskcvskiy tekstilznyy institut. (Spip.ning machinery) (Autmatic control) r 7,T Vr, tne vat,,erz, i, fI W-a~ tic. izv" Vy- Lek -,iin Era' ~r~ I-D V i 7;' -tU' 1)~;b-,ajp .,.on , RIEBARBAR, Ya.M.; KILMIN, V.P.; VINTER, Yu.M.; ~ULIMAN, Ya.V. Selecting the optimum parameters of the mechanism for automatic jacquard card punching. Izv. vys. ucheb. zav.; tekh. tekst. prom. no.2:121-126 165. (,1 a-FA 18: 5) 1. Maskovskiy tekstilInyy institut, Vsesoyuznyy nauchno-issledo- vatellskiy institut legkogo i tekstillnogo mashinostroyeniya i TSentrallnyy nauchno-issledovateltskiy institut promyshlennosti lubyanykh volokon. REBATINAR) _Ya.M.; GLIVIrER, E.I. Using the theory of image for ',he aut~,matl~.-i pr3- from a fA-tt(,,rn in jacluard weaving. Izv. ,r,1-9. 1-heln. I tek5t. paoir., n:~.r~' zi ~,-2-1--8 1 c"; (MIRA 17-8) ,,. Moskov3kiy tek-iztLI'nvy iii:~ti2. --, R:,i,BARBAR., Ya.,M.; SUSLGV, D.A. Photoelectric head for reading the design pattern in t-,-- automat-ic cutting of jaelmrd punclied cards for looms. Izv.vys.ucheb.zav.; tekh. tekst.prom. no.3:103-M 163. (14IRA 16:9) 1. Moskovskiy tekstilInyy institut i Mentralinyy nauchno-issledo- vatellskiy institut lubyanykh volokon. (Jacquard weaving) (Punched card systems) Illysic!-, Nucloar Tcc!-_n:)lo,.-_-y an-' Fow~_r c-8 Abo J:ur i c: 7,,.u-- - Fizil 11c; 5, 1959, D 1021 j"Uthor llr_-t,~rlin A. Reb-anric M. Strn,,!,l J. In,3 Title ani.c! Transparency of r%Qfl,,~ct-_)rz in One-Dimensi:mIal Twt)-Group Diffusion Thcory Ori,_- I~ub:Rojits. "J. Stei.on" Inst., 1957, 4, 29-42 ;,bstract :Descripti,)n of _- zietha_! of doturrlininc tho scalar ani~ vuctcr (J) neutron flirces at t.c bowriclacrics of r_ulltiply- layere(I reflect.)rs anJ the calculatj-o-in of the critical cau::~'Uion, with the aiC.- of calculations of albee-o and trans- paloncy ~f inCivb~ual layers. For-r.1-LIns are deriv&.- for the elc:~~onts _)f t-1--c albeda, .-:atrix an(~ of th.e trans-Darency T.:atrix f-,r se-,)aratc s-21"criccil, plane, an". cyl-in-c-'rical layers (in t"~~e Calculations Us-- is =10 of tdc ZWO-,:~r-O'Ui) Constants). ~~I~j~roxirxation cquations are usecl, by which the watlhors cal- culatc the matrix clerent of the albedo foi! H20, DOO, ancl C. C ar 1/2 15 YUGO-SLYLVIA/Iluclear viysics - Nuclc~x TechnuloCy _njyj Power C-8 Abs Jour Ref Zhur - Fizika 191-59, 11o 10210 .1 110 5, 1 7me fDllowint.- liraitin6 cases are considcrca: infinitesi-,_-nIly thin and infinitely thick reflect:)rs. T*.-,e arbed.0 and transDarency of a two-layer reflector are exprQsscd in, Icr--s of t-Inc altedo an(I transparency of the im'J idual !,,.yors. .Iv Analc~Znus forrullas are derived for a throe-layer and -,=I- ti- LI 1 Given for -a .Dle-layer reflector. A numerical exa=m, c is two-layer spherical reflector (layers of D20 anO C). T120 calculatea matrices of the albedo anc! trazs-Darei,,cy were used -to dcterLd-ne tIL-,L, relations between -~ (111) an-ft Y(R 2) :~,r ~~ (P,,) ana also between J (R,-. =C, J (R2) '-1r J(R on the', bouriOlaries of the indiviCua layers of t1he re_~ 3 flector anl inside mltiple-layers reflector, obtained frm~ tile bouni.-Iary condlitions, exuressce- in tLe tems of the albedo ." the internal and external reflectors. -- Dd. L,.vin L LI_ 43. o Card 2/2 - -h., IKIJI.~'V",~', I-A., 1 Ti zh. R-IHA-r A.Yu., -WrI2, ..~ 1% CoUtif-MOUS R-3phalt,,,:~oncrete plan t wJ th 50-60 ton per hour C_qpacil.y. AvI. dor. 27 no.8.-8-9 Ag 164~ (MIRA 17il2) - RE,BAVA, Vera- Girls who make speedometers. Rab. i sial..37 no. 5:10-11 My 161. (MIRA 14:4) (Czechoslovakia--Motorcycle industry) REBAnT, Ya. ~k e We are using new methods of building. Zhil.stroi. no.li:14-16 '59. (MIFA 13:4) 1. Glavnyy arkhitektor Rostova-na-Donu. (Rostov-on-Don-Building) 0 -,.t L 24271-66, EWT(1) ACC NR: AP6oo699i SOURCE CODE: UR/0051/66/020/002/0135/0193 AUTHORS: Rebane, V. N.; Rebane, T. K.- ORG: none TITLE: Effect of collision-induced transitions between the sublevels,!-- of the excited state on the depolarization of the resonance fluores- cence of atoms in a magnetic field SOURCE: Optika i spektroskopiya, v. 20, no. 2, 1966, 185-193 -TOPIC TAGS: fluorescence, nuclear energy level, depolarization, collision cross section, excited state, adiabatic approximation, kinetic equation ABSTRACT: The authors evaluate the effect of collisions between E!X- 1 cited atoms in the P state and the atoms of.an added gas on the polarization of the resonance fluorescence. The use of the adiabati approximation leadsTo a simple expression for the effective cross Card UDC: __539 L 24271-66 ACC NR AP6006991 sections of the transitions between the substates of the P states. It is shown in particular that.when the condition for adiabatic col- lision8 is satisfied and the trajectories are assumed to be straight lines, the effective cross section for the transitions between the substates does -not depend onthe detailed form of the interaction forces, on the impact distance, and on the velocity. Solution of tbe~`____' kinefic.equationa.for the.density matrix of the, P state'_ai~d a 1 low-M. Ance.. for.'the selection rules for dipol6.'-~6#iKssion leads~-to 6imp-le orl~t_~ f Ia -tor..tbe dependence re.seenqe--p t Mu of tbe:fluo olarizati on on- be Y: :density, of the added gas. Metbo ds o. el, 'improv.:1 M_ tbe accura( g theory are.-briefly discussed. The authors ihainik'.k. T._~Chayka..'for- Pontinuous,interest and discussions, and. N. -Demicov for valuable:- advice. Orig. art. has: 45 formulas. iSUB CODE: 20/ SUBM DATE: 2lDec64/ ORIGREF:,-~003/ OTH REF: 001 J 2Z2 40- L 24271-66 FWT (1 1?ACC NR: AP6006991 SOURCE CODE: UR/0051/66/020/002/0185/0193. 15 !AUTHORS: Rebane, V. N.; K. Rebane, T. IORG: none 'TITLE: Effect of collision-induced transitions between the sublevels I '!I of the excited state on the depolarization of the resonance fluores-A Icence of atoms in a magnetic field SOURCE: Optika i spektroskopiya, v. 20, no. 2, 1966, 185-193 I ! -- TOPIC TAGS: fluorescence, nuclear energy level, depolarization, .collision cross section, excited state, adiabatic approximation, jkinetic equation IABSTRACT: The authors evaluate the effect of collisions between ex- cited atoms in the P state and the atoms of an added gas on the 1polarization of the resonance fluorescence. The use of the adiabatici. !approximation leads to a simple expresFi-on for the effective cros 9 L Card