SCIENTIFIC ABSTRACT IVANOV, K.I. - IVANOV, K.N.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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On some special features of action of inhibitors on the kdne- ties of auto-oxidation of hydrocarbons. (Cont.) 65-4-3/12 features of inhibitors of I, II and III groups, observed under oxidising conditions, as in TOCT '381-52, are independent from the concentration of these substances, of the method of calcul- ating the 4ree of oxidation of the oil (acid number or -the amount of absorbed oxygen) and the presence of metals (iron and copper) in the reaction zone. The influence of 25 organic compounds (containing amine, phenolic groups and sulphide sul- phur) which were known as inhibitors and their classificationg based on the differences in their action on the individual stage of the oxidation p-rocess are given. (Table 3). The res- ults obtained can be used not only for stabilisation of fresh Card 2/2 oils, but also oils already in operation. There are 3 tables, 10 figures and 6 references, including 5 Slavic. ASSOCIATION: Thermo-technical Institute (Teplotekhnicheskiy Institut) AVAILABLE: AUTHORS: Ivanov, K.I. and Mlkhellson, A.Ya. 65-10-7/13 TITLE: The Influence of the Degree of Purification of Power*Oils on Their Ability to Form Water Soluble Acids in the Initial Stages of Ageing (Vliyaniye glutiny ochistki energeticheskikh masel na sposobnost' ikh obrazovyvat' vodorastvorimyW kisloty v nachale stareniya) PERIODICAL: Xhimiya i Tekhnologiya Topliva i Masel, 1957, Vo-10, PP. 34 -~41 (USSR) ABSTRACT: An investigation of the dependence of the ability of transfo rmer and turbine oils to form water soluble acids in the initial stages of ageing on the degree of -their refining with sulphuric acid was carried out. Properties of oils taken from the investigation are given in Table 1. Oils were successively treated with 93-55' sulphuric acid in 3% portions neutralised with 3% NaOH, and washed and dried. Thus from each distillate, samples were obtained of a diferent degree of purification. All samples were tested for stability accor- ding to MCT 981-55 (results: Figs. 1-4, Table 2). It was established that all investigated distillates and oils prepared from them form, in the initial stages of ageing,.volatile and non-volatile water-soluble acids in amounts decreasing with Card 1/2 SOV/65-58-12-10/16 ,Apshteyn, R.A. and Mikhellson, A. Ta. AUTHORS: Ivanov,j~,__j.,,_,,,L TITLE: T~-w-M-'et-hod for Evaluating the Behaviour of Transformer Oil During Normal Operation (Novyy metod otsenki povedeniya transformatornykh masel v ekspluatatsii) PERIODICAL: Khimiya i Tekhnologiya Topliv i Masel, 1958, Nr 12, pp 46-48 (USSR) ABSTRACT: A method has been developed in the VTI Laboratory for determining more reliably the behaviour in operation of transformer oil, i.e. the behaviour after ageing. The method consists in ageing the oil in a specially equipped small power transfoSmer with a tank capacity of 12 litres operating at, 95 C under no-load conditions at a 100% over-voltage, i.e. with a maximum of 100% increase in the field strength with simultaneous blowing of oxygen onto the oil at a rate of 25 ml/iain per 10 kg of oil. During the tests the oil was heated by the losses of the transformer itself and also by an additional 140 W immersion heater and a 1800 W hot-plate placed under the transformer. Due to the fitting of an additional Card 1/3 tank and circulation of the oil in the zone of the field SOV/65-58-12-10/16 New Method for Evaluating the Behaviour of Transformer Oil During Normal Operation at a relatively high test temperature of 95 � 0.5'C and saturation of the oil with oxygen, the ageing process is accelerated and lasts ?50 hours, i.e. the ageing is considerably slower than in various "express" methods. The testing of the oil was effected simult- aneously in two transformers in two stages. The first stage, lasting 100 hours, enables determination of the tendency of the oil to form water soluble acids during the initial stage of ageing; the second stage lasting 650 hours permits evaluating the ability of the oil to resist ageing over long periods. During the first stage, the oxygen is fed in continuously, during the second stage, the oxygen is fed in solely during the time when the transformer is actually in operation, i.e. 7 hours per day. At certain intervals samples are taken and the total acidity, the content of water soluble and volatile acids, the saponification number$ the content of active oxygen and hydrogen, surface t(.,nsioa et-c. are determined Card 2/3 and also the loss factor and tae break-down voltage. At the end of the tests the quantity of precipitate is LI SOV/65-58-12-10/16 New JAethod for Evaluating the Behaviour of Transformer Oil During Normal Operation also determined. Between the individual tests, the transformers are carefully cleaned by heating them twice over a long period,each time with a new portion of fresh oil. The here described method permits evaluating of the behaviour of tran former oils under conditions closely resembling normal operating conditions. During the first 100 test hours, it is possible to evaluate the ability of transformer oils to form low- molecular water soluble acids at the beginning of the ageing process and during a subsequent 650 hours it is possible to determine the behaviour of the oil under conditions of operation over long periods. Test results are given which were obtained for some Soviet oils, one of them containing 0.3% of the anti-oxidant 2,6-di-tert.butyl-4-methylphonol. There are 3 figure5. ASSOCIATION: Vsesoyuznyy teplo-tekhnicheskiy institut (All-Union Thermo-technical Institute) Card 3/3 AUTHORS~ Ivanov, K. I., Vilyanskaya, Ye. D. SOV/'20-121-1-29/55 TITLE: On the Interaction Between the Hydrocarbon lutooxidation Inhibitors and Alkyl- and Peroxide Radicals (0 vzaimodeystvii zamedliteley avtookisleniYa uglevodorodov s alkillnymi i perekisnymi radikalami) PERIODICAL: Doklady Akademii nauk SSSR, 1958, Vol. 121, Nr ')~ pp. 107-110 (USSR) ABSTRACT: The authors proved already earlier that some oxidation in- hibitors of the mineral oil hydrocarbons in the liquid phases by molecular oxygen are able to retard the oxidation only if they are added to the substance to be oxidized (white oil = beloye maslo) before the be,~innirg of the reaction; other inhib- itors, however, cause this effect if they are introduced in different stages of the oxidizing processes. It was assumed that the inhibitors of the first group are able to bind active particles which initiate the chain reaction (mainly the hydro- carbon radicals R); the inhibitors of the second group are, however, assumed to interact with peroxide compounds. These peroxide compounds are formed in the initiating stage (hydro- Card Ilif peroxides ROOH) as well as in the development sta,,re of the re- SOY/20-121-1-29/55 On the Interaction Between the Hydrocarbon Autooxidatirn Inhibitors and Alkyl- and Peroxide Radicals action and yield inactive products (Ref 1). Later a third group of inhibitors was found which retard ai3 well t tie auto- oxidation if they are added before the beginningbut aie in con- trast to the inhibitors of the second group able to stop a developing (not inhibited) process only in its autocatalytic stage. In order to solve all problems connected with this prob- lem the authors introduced alkyl (R')- and peroxide (RO') ra- 2 dicals immediately into the white oil during its oxidation in order to investigate their influence on the activity of the antioxidants of all 3 groups in different-stages of oxidation. The first group was represented by p-oxydiphenylazaine, the second by 4,41-diaminodiphenyldisQlfide, and the third group by 2,6-di-tert.-butyl-4-methyl-phenone (yanol). Acetyl peroxide served as source of the hydrocarbon radicals. The peroxide radicals were obtained from an interaction between cumol hydro- peroxide and cobalt naphthenate (Ref 5). The results of the first series of experiments (Pig 1) show that the introduction of the 'CH 3-radicals in the initiatin.- staSe of the reactien Card 2/4 accelerates to a great extent the oxidation of the not in- S07/20-121-1-29/55 On the Interaction Between the Hydrocarbon Autooxidation Inhibitors and Alkyl- and Peroxide Radicals hibited oil. The induction period of the process is practical- ly eliminated (Curves 1, 2, Fig 1). The inhibitors of the first and third group retard in the presence of the addEd *CH 3- ra- dicals the beginning of the oxidation of the oil, in contrast to the inhibitor of the second group (Curves 4, Fig 1). In the second experimental series the same antioxidants were inventi- gated with peroxide radicals C 6H5C(CH 3)200' From the obtained results (Fig 2) we may conclude that the introduction of these radicals at the beginning of the reaction accelerates as well to a great extent the oxidation process of the oil. The anti- oxidants of the second and third group maintain their retarding effect in the case of the introduction of RO*-radicals before 2 as well as after the beginning of the oxidation, as well as in the case of addition of these inhibitors to the oil which oxidizes under the inflaence of the introduced radicals (Fig 2, B,V). An antioxidant of the first droup does not stop the re- Card 5/4 action in the case of an introduction of RO 2-radicals, neither SOV120-121-1-20155 On the Interaction Bet-,~ieen the Hydrocarbon Autooxidation Inhibitors and Alkyl- and Peroxide Radicals before nor after beginning of the experiment. There are 2 figures and 9 references, 7 of which are Soviet. ASSOCIATION: Vse3oyuznyy toplotelchnicheskiy institut im. F. E. Dzerzhinsko-o (All-UnionThemotechnical Scientific Research Institute, 4-meni F.E. Dzerzhinskiy) PRESENTED: December 27, 1957, by N. N. Semenov, 14ember, Acade:-,y of Sciences, USSR SUBMITTED: December 20, 1957 1. Oxidation inhibitors--Performance 2. C)xjdation inhibitors --Chemical reactions 3. Oxidation inhibitors-Test results 4. Alkyl radicals--Test results 5. Peroxide radicals--Test results 6. Mineral oils--Oxidation Card 4/4 J, Oxij~~~~c%rbons in the I JrA id Phase. Collection of Articles) 140800V,. riki) essr, In-ta khimicli Os fiz izd-vo AN SSM 1959 ~34 _p. __13f~;;~u Denisov-, _Te'.T4 (MZsc~; State Vaiverdity imeni'M. - V. Lowno6ovj. Characteristics of -the Action of Inhibitors on Side-Chain Decomposition Reactions 66 Ivanov.,,K.I,_, and Ye.D. Vilyanskaya [Vaesoyuznyy teplotekhnicheskiy nauch- ~6~fiil:~&;;;~tel I skiy inatitut imeni F. E. Dzerzhinekogo (All-Uhion Heat Engineering Scientific Rqaea=b Institute imeni F. E. Dzerzhinskiyg. Effect of Inhinitors an the Kinetics if the Autoxidation of Hydro- carbons T7 The authors investigate the effect of various inhibitors on the autoxidat:ton of hydrocarbons from petroleua crudes, as well as various stages in the development of the oxidation process. Card 4A8 SOV/96-59-9.-12/22 AJUTHORS: Ivanov,. KJT. (Dr. Chem. Sci.) and! (Cand. Chem. Sci.) TITLE: Fire-zesisting Turbine Oils PERIODICALs Teploene:,getika, 1959$ Nr 0, pp 65-68 (USSR) ABSTRACT: There is iru(,h interest abroad in fire-resist-ing turbine oils and work on this subject; has also been done in the All-Union Thermo-To,',Iinical Institute. Besides secvAng to lubricate and cool the bearings, turIvine oil io used as a hydraulic fluid in the governor gears where it is undai, pressli-re. It is this oil- tinder pressure that conz tl rutes the main fire risk and so sometimes the obje.:;'v I ~3 t:> replace or~_y this part of the mineral lub-1--icating cii. The synthetic oil described in the present artiol,a J.~; interderl to rep_1a,'.e all. the mineral lubricating oil irk tbhs turbine system. A synthetic lubricant was develop6d based on organic phlosphorus compounds. The prin,,;ipal physical propertie3 of this lubricant are compared with those required by the standard specification and with those of mineral turbine oil in Table 1. The synthetic Card 1/3 lubricant has a self-ignition temperature in air cf 74-00c, it is as close to the sDecification as normal turbine oil, Fire-resisting Turbine Oils sov/96-59-9-12/22 is not subject to foaming and is not toxic at low concentrations. A number of tests were made over arid above those called for in the specifications particularly in respect of the effect of the material on insulation. The results which are given in Table 2 show that the now material has much less influence than mineral oil on most of the insulating materials used in alternators. A sample of the fire-resistant lubricant was tested on a special bearing rig illustrated diagrammatically in Fig 1. The test results are given in 'Table 3 together with comparable results for a normal petroleum lubricant7 and it will be seen that the synthetic lubricant has a good resistance to ageing and foaming. Sufficient data is now available to indicate the desirability of making full- scale tests, perhaps first only in a governor system, but preferably in an entire turbine lubrication system. Some small changes will be required in turbine lubrication systems; for example, the lubricant is of higher specific gravity thal.11 water and so different arrangements must be made to drain water from the lubricant tanks. For health Card 2/3 reasons, it is preferable that the synthetic lubricant Fire-resisting Turbine Oils SOV/96-59-9,-12/22 should not be exposed at temperatures above 50 OC~ A four-ton batch of the new lubricant has been made for testing in service. Card 3/3 There are I figure, 3 tables and 9 references, of -which 1i 1 is Sovieti 3 are German and 5 are English. ASSOCIATION: Vsesoyuzn:71.r teplotekhnicheskiy institut (All-Unio,n Thermo-TechnIcal Institute) S/096/60/000/011/002/018 E19VE181+ AUTHORS: Ivanoir K I. (Doctor of Chemical Sciences), vllyanskH~y_a, )~e.D. (Candidate of Chentical Soiiences), and Luzhetski~~L.A.A., (Engineer) TITLE: New Developments in the Theory and Praati(~,e of Using Anti-oxidants in Oils for the Power Industry PERIODICAL: Teploenergetilca, 1 60 No 119 PP 34 39 TEXT: The theory and practice of the use of anti-oxidants -in turbine and transformer oils is reviewed. The authors (,Iassify ant.*.J.-oxi.dants into three groups (see Table 1)., Inhibitors In t-he second group are able to retard oxidation that has already commenced, those of the first group are not, whilst those of the third group can retard the process only in the auto- ca. talytic stage. The tests were made with white oil but were found to be valid also for Baku transformer oil. The behaviour of the d if.-ferent groups of inhibitors depends on their ability to interact differently with the intermediate oxidation products, namely, hYdroperoxides and peroxides . Proposed mechanlsms of inhibitor ar_,tion are given in Table 2,', It is found that the chemical nature of the functional group o(%ourring in the anti-oxidant molecule Card 1/3 S/096/60/000/011/002/01.8 E19VEl& Now Developments in the Theory and Practice of Using Axiti-oxidants in Oils fo.~ the Power Industry does not suffice to relate the anti-oxidant to one or other of the three classes given. i Apparently, the position of the functional group in the inhibitor molecule is most important. Two Lmpo,.,,ta-nt praot-Ical conclusions follow, namely: it is possible to use anti- oxidants in turbine and transformer oils not only when they are new but also aft-~ir they have been in service and are partially oxidised, and -it is also possible to reliably stabilise regenerated oil. ir-- which some traces of oxidation products are usually left: aper.ially selected mixtures of anti-oxidants may 'be used to stabilise oils, Anti-oxidants of the second and also of the third groups should be the most effective in retarding oxidation that, has already commenced, whilst anti-oxidants of the first g:roup arenot suitable for this purpose,, 'Phis conc.1-asAon has been confirmed both by laboratory oxidation tests and in the field 'by tests on turb-ines and t-,-~,nsformers, Theoretical. (,onsiderations are given why the simijIt-aneous application of anti-ox1dants of' the differew" groups (1, and 2), (2 and 3), and (I and 3) can giva .',nc;-reased effeat.'A,-,~3ness,, It is pol.nted. out', triat the pu b L.i s h. works 011: Cal. J. B/096/60/000/011/002/018 E19VE184 New Developments in the Theory and Prac:tico of Using in Oils for the Power Industry British and American authors are not in agreement on this point. However,, the laboratory test results given in Tables 3 and 4 and Figs and field tests show that a suitable mixture of two additives can be highly efficient in turbine and transformer, oils, It was also shown that no enhancement of effect is produced wher. anti-oxidants of the same- rou:p are mixed togeth-or, exrept in the case of anti-oxidant roTt4 9 (VTI-8), which contains. sulphur. The importance of secondary properties of anti-oxidants such as their influenog upon corrosion or electrical properties of the oil and. partacularly their solubility is discussed, Fig 4 shows the neutralization value as function of time for a turbine before and after using inhibited turbine oil containing a mixture of the abo-.re mentioned. additive VTI-8 and p-oxydiphenylamine. This article goe.-- further than most in naming the additives and. their concentrations used in the tests. There are lir figures, 4 tables. and 1*7 references: A Soviet, 6 English and 1 French. ASSOCTATIONa Vsesoyuznyy teplotel~hnicheskiy Institnt (All-Union Thermo-Technical Institute) Card. 3/3 s/oBi/62/rOO/007/027/033 B168/BlG'. AUTHORS: ~14anoulZo 1_v, Lipshteynt R. A., Mikhell-on, A. Ya., Luzhetskiy, A. A. TITLE: A method of evaluating the operational characteristics of inhibited insulating oils PERIODICAL: Referativnyy zhurnai6. Khimiya, no. 7, 1962, 550-551, abstract 7M197 (Sb. "Prisadki k maslam i toplivam". M., Gostoptekhizdat, 1961, 290-297) TEXT: A test-bench method of evaluating the operational characteristics of transformer oils has been devised (a diagram of the apparatus is givens Essentially this method consists of testing the oil for aging over a period of 750 hours in a low-power transformer running without load at twice the maximum field intensity. In order to reduce the time taken by the test the aging process of the transformer oil is speeded tip by using special devices for heating the oil to 950C, for saturatingit with oxygen and for circulating the oil in the field zone. The quality of the transformer oil is determined, while the oil is in use, from changes in a Card 112 S/08 62/000/007/027/033 ,k method of evaluating the ... B168YB101 grouD of characteristics - namely, tendency to form low-molecular water- soluble acids in the initial stages of aging (after 100 hours), general acidity, quantity of sediment, tangent of angle of dielectric losses (tan 6), condition of the solid insulationt corrosive attack on coppery etc. With this method it is possible to make a more objective and broader evaluation of the operational characteristics of a transformer oil than by other, familiar, methods. A number of tests were,carried out by this method on home-produced commercial and experimental oils and also on imported commercial oils. LAbstracter's note: Complete translation .3 Card 2/2 S/065/61/000/007/005/005 E194/E435 AUTHORS: Lipshteyn, R.A., Ivanov, K.I. and Mikhellson, A.Ya. TITLE: Assessment of the service properties of transformer oils PERIODICAL: Khimiya i tekhnologiya topliv i masel, 1961, No-7, pp.63-70 TEXT: Existing laboratory methods of testing transformer oils do not assess them fully. Accordingly, the Laboratoriya nefti (Petroleum Laboratory) of the VTI has developed a method of assessing transformer oil in small transformers. These transformers operate at twice the rated voltage and, to reduce the test time, ageing of the oil is intensified'by heating it to a temperature of 950C, saiiirating it with oxygen and by circulation of the oil. The oil iE ~3sessed by measuring the contents of low and high molecular weight acids, the amount of sludge, the dielectric loss angle, the condition of the solid insulation, corrosivity to copper and other tests. These rig tests give results that are in agreement with YTI experience of the service performance of the oils in question and data obtained by A.A.Luzhetskly. Test results on a considerable number of oils are Card 1/3 S/065/61/000/007/005/005 Assessment of the service ... E194/E435 given, In general, Soviet oils front low sulphur crudes were unsatisfactory usually because of excessive-formation of low molecular weight acids or sludge. Even the best of the Baku oils did not give such good rig test results as imported British and French oils. Oils produced from high sulphur crudes were also generally unsatisfactory. Di-terbutylparacresol (DBPC) effectively improved the oxidation stability of many of the oils. However, the results of rig tests on inhibited oils are,sometimes not so favourable as might be expected from laboratory bench tests. The usual relationship between depth of refining and inhibitor response is reported. With base oil of satisfactory quality, the content of DBPC may be reduced from 0.3 to 0.2%, but further reduction to 0.1% gives poor performance. The All-Union Scientific Research Institute of the Petroleum Industry (VNII NP) and the Novo-Kuybyshev Refinery developed a method of manufacturing hydrofined transformer oil from high sulphur crudes without solvent treatment. Although bench test results are satisfactory, heavy sludge formation was experienced in laboratory transformers and, accordingly, stricter requirements were applied to this oil in Card 2/3 s/o65/61/000/007/005/005 Assessment of the service ... E194/E435 respect of sludge formation in the fourteen hour oxidation test of the standard rOCT 981-55 (GOST 98.1-55). The seconcr production batch of hydrofined oil was also refined by percolation and gave much better rig test results. On the basis of the work, it is recommended that if *ransformer oils are made from new crudes by new refinery processes, or with new additives, they should be admitted to general uoe,only after being subjected to a 750 hour'rig test on experimental transformers using the procedure of the VTI. The existing standard for transformer oils rob'T 982-56 (GOST' 982-~56) should be tightened up in respect of dielectric loss angle-, and for aromatic oils in respect of sludge formation after oxidation. Some tightening up in neutralization value after oxidation is also to be recommended. When further experience has been accumulated the standard should be extended to include such characteristics as colour, interfacial tension, stability of el'ectrical properties on laboratory ageing, copper strip test and gassing properties in hydrogen atmosphere. There are 2 figures, 4 tables and 5 Soviet references. ASSOCIATION: VTI im. Dzerzhinskogo (VTI im.Dzerzhinskiy) Card 3/3 27917 s/oq6/61/OO0/011/oo2/o06 111,9110 E194/E155 AUTHORSz, Ivanov, K.I., Doctor of Chemical Sciences, _7_1EY_an.skaYa,, Ya,D~, Candidate of Chemical Stiencea, Kazanskiy, K.M~, Engineerg Shilankov, B,F,,, Engineer., and Fedorova, J.V., Engineer TITLE! Service test results with fire resistant turbine oil "Ivvioll IA" PERIODICAL, Teploenergetika, no. 11, 196lq 271-29 TEXT~- Work on fire-resistant hydraulic fluids and lubricants for turbines is proceeding in several countries. For example) Pydraul F-9 is suitable as a hydraulic fluid but not as a bearing lubricant. In 195a-59 the Laboratoriya nefti (Petrol-eum Laboratory) of VTI developed a fi-re-resistant aubst:it-ate for turbine oil, grade Ivvioll 1A, intended for us 'e bVI-th $a hydraul-i-- fluid and lubricant, Laboratory test results were published by two of the present &uthore (Ref.38 K.I. Ivanov, Ya.D... Vilyanakaya, Teploenergetika no.9, 1959) and then an experimental batth of the material was made for field tests. The viscosity of the material was 20 centistokes at 50 OC~ the flash point was 218 OCI open cup Card 1/3 27917 Service test results With fire S/096~61/000/01k/002/oo6 K194/E155 and the fire point .4n air 740 OC. The specific gravity at 20 OC is 1.17.' The material meets the requirements of the conventional turbine oil specification in respect of stability and neutrality. Before the charge was put in the turb-i-ne certain changeo were made,~ the cylindrical filters in the oi-I tank were replaced by gauze screens which could be cleaned during operation of the turbinel the design of one of the main glands wao improved. In the earl-y period of operation with Ivvioll IA, -foaming was observed but was cured by the addition of a silic.owe anti-foam agent to the amount of 0,1% by weights After two or three months' service the -brass gauze screens in-the oil tank. were attatked by the fluid, During the entira servite period the vaket-up of firt- resistant fluid was 200 kgo whereas the amount of ril that. had been required in a corresponding-peri*d was 800 kg. 'The difference-is presumably due to the lower volatility of the fire- .r-asistant materl&l. After a perrio-d of servict the ri3tosity and neutrality of the fluid were unchangerd and all parts of the turbine, whi-th were carefully examined, were in good condition. The fluid was on test for 5400 hour93 during which the turbine ran without stopping for 120 days7 at 18 hour3 a day fox- 11-0 day3) Card 2/3 27917 Service test results with fire s/cq6/6l/ooo/oll/002/oo6 E_194/E155 and at 12 hours per day for 45 daya. The water contant of the fluid ranged from 0.02 to 0.2%. Water is easily removed from the fire-resistant fluid be,.ause it accumulates on the surface of the oil tank from which it readily evaporates. The results indicate that the oxidation stability of the synthetic fluid is better than that of the usual mineral oil. The fire-resistant fluid darkened in colour because it attacked the protective paint used-in the system, Ivvioll 1A is toxic if ingestedg but if normal hygienic precautions, typical of those used With similar fluids elsewheres are observed there is no risk on this account. The difficulties with foaming and corrosion of brass can easily be overcocae and it is considered that 1,evioll 1A can replace mineral oil in turbine lubricating and hydraulic systems of the type considered, There are I figure, 2 tablea and 3 referencess 2 Soviet-bloc anti I English, The'English language referents reads as follows., Ref,lg Harris Product Engineering, vol, XX, 1954. ASSOCIATIONs Vzesoyuznyy t eplot~akhnich ask iy institut - Mosenergo (All-Union Heat Engineering Institute and Moaenergo) Card 3/3 88706 S/07 61/035/001/004/022 B004YB060 AUTHORSt Xvanov, K. I. and Vilyanskaya, Ye. D. TITLE: Reversal of the negative catalytic effect of aniline in its action UDon various stages of autoxidation of hydrocarbons PERIODICAL: Zhurnal fizicheskoy khimiit v. 35, no. 11 1961; 50-57 TEXT: In their study of the effect of oxidation inhibitors upon the oxidation of hydrocarbons (Refs. 1,2) the authors found that aniline acts as an oxidation inhibitor if added to the hydrocarbon prior to the begin- ning of oxidation, but that it speeds up oxidation if added after oxidation. Aniline thereby differs from inhibitors of the first group (diphenyl amino, phenyl-fi-naphthyl amine, p-hydroxy diphenyl amine, Methyl aniline, dimethyl aniline, antipyrine), which, while no more acting as inhibitors once oxidation is started, do not have any accelerating effect either; such of the second group (eA-naphthyl amine,o(-naphthol, p-phenylene diamine, diethyl-p-phenylene diamine, p-amino phenol, hydroquinonet 4,4'- diamino diphenyl sulfidep p-tert-butyl phenol, benzidine, o.-tolidine), which inhibit oxidation at all stages, and such of the third group Card 1/4 88706 S/076/61/035/001/004/022 Reversal of the z,----,-ative catalytic B004/BO60 (A-naphthyl amine, a-naphthol, m-phenylene diazine, diphenyl-p-phenylene diamine, phenyl-a(-naphthyl amine, di-o(-naphthyl-p-phenylene diamine, di-A-naphthyl-p-phenylene diamine, o-amino phenol, diethyl-o-amino phenolp resorcinol, 2,6-di-tert-butyl-4-methyl phenol, pyramidon), which inhibit oxidation only prior to and in the autocatalytic stage, but no more once the reaction has attained a constant rate. This difference in the three groups is due to the different position of the functional groups. 0-1 m-, and p-toluidine behaved quite like aniline. The authors of the present article wanted to study this behavior more closely. The experiments were carried out with refined medicinal oil (d20 . 0.8810, V - 32.2 conti- n 50 stokes). The minimum concentration at whi ch aniline has an inhibit:..ng or an accelerating effect upon oxidation (2 wqo) is higher than the con- centration of the other antioxidants (0.1-0.2%). The following experi- ments were madet a) addition of p-hydroxy diDhenyl c-mine (1st group) and aniline to oil, beginning of oxidation test, and, after five hours, addition of further 3clu' aniline; b) addition of 4,41-diamino diphenyl disulfide (2nd group) and aniline, and, after five hours, addition of 3% aniline; c) acceleration of oxidation by the addition of 3% aniline five Card 2/4 V 88706 S/076/61/035/001/004/022 Reversal of the negative catalytic B004/B060 hours after beginning of oxidation, followed by addition of p-hydroxy di- phenyl amine; d) like c)t but addition of 4,41-diamino diphenyl disulfide. Results: the reagent of the 1st group (experiments a and c) had no more an inhibiting effect, while the reagent of the 2nd group b and d) brdught oxidation to a standstill,. Aniline thus behaves in much the same way as the RO radical, which is likewise not pasaivated by the Ist group, while it is by the 2nd group.. it is assumed that aniline enters into interaction with the reaction products in the case of oil'already undergoing oxidation to form a radical which combines with oxygen to form a peroxide-radical. There are 6 figures, I tttible, Pnd 6 references: 4 Soviet-blue and 2 non-Soviet-bloc. ASSOCIATION: Vresoyuznyy teplotekhnicheskiy institut im. F. E. Dzerzhin- skogo (All-Union Institute of Heat Engineering imeni F. E. Dzerzhinskiy) SUBITITT"ED: April 8, 1959 Card 3/4 Reversal of the ri gative catalytic ... Legend to Pic. 1. a) acid number of the oill KO~.-,- b) time, hours. 88706 S/076/61/035/001/004/022 B004/BO60 mg Card 4/4 1 1, 1' , "," !!"I -?, s/o65/62/000/007/002/002 E194/E484 AUTHORS: lvanoK_,__~.I., Zhakhovskaya, V.P. TITLE: I, he nature of water soluble acids formed in the initial stages of ageing of transformer and turbine oils "','RIOI)ICAI,: Khitniya i tekhnologiya topliv i masel, no.7, 1962, 58-62 I'EXT: The authors studied by a chromatographic method the amounts of steaut distilled volatile aliphatic acids occurring during the early'service ageing of transformer and turbine oils, it was first decided to study the saturated mono-basic fatty acids because they can easily be separated by steam distillation from the other acidic compounds which might be present. The choice proved justified for in none of the steam distilled materials did ordinary qualitative tests reveal any unsaturated fatty acids, phenols or cresols. Samples of turbine and transformer oil from service were thoroughly extracted with distilled water. The extract was neutralized with NaOH and concentrated by evaporation, reacidified and steam distilled. The neutralized distillate was evaporated to dryness and after dissolving in a auitable solvent Card 1/2 s/065/62/000/007/002/002 The nature of water soluble ... E194/E484 was put through a chromatographic column. The acids were removed from the column in order of decreasing molecular weight starting with iso-valerianic acid eluted by 0.5'1'0 n-butanol in chloroform. Formic acid was eluted last with 25 to Yr% butanol in chloroform. The experimental results are tabulated. The total acidity of the transformer oil ranged from 0.04 to 0.7 mg KOH/g an.d that of t~e turbine oil from 0.06 to 0.31 mg K011/g. Th~ amount of volatile acids found by the method described rangell from a quarter to a third of the total water soluble acids content, except in the case of transformer oil from eastern crude where the amount.was very much less. The principal volatile acid in the samples tested was formic (56 to 8401;)-. Acetic, pi-opionic arld oleic acids are present in smaller quantities (1-5 to 11.5"U'). The transformer oils tested contained relatively large amounts ('13 to 45") of iso-valerianic acid, There are 1 figure and 2 tables. ASSOCIATION: VT1 Card 2/2 :IVAROV, K.I., doktor khimicheskikh nauk; MIKEELISON, A.Ya., inzh. International method of testing insulating oils for artificial aging. Vest.elektroprom. 33 no.1:5-9'Ja '62. (MIRA 14*12) (Insulating oils--Testing) DZHUVARLY, Chingiz Mekhtiyevich; IYAMV-,jKqn9tm~LttA-InA9)dp-4J JORLIN, Mikhail Vladimirovich; LIPSWEYN, Rafail Aleksandrovich; MUKHAPSKAYA, Leyli Idamovna; LEVINA, Ye.S., ved. red.; YAKOVLEVA, Z.I., tekhn. red. (Insulating oils] Elektroizoliatsionnye masla. [By] Ch.M. Dzhuvarly i dr. Moskva, Gostoptekhizdat, 1963. 274 p. (MIRA 16:4) (Insulating oils) IF Owww"NO'' L 13338-63 __P4174/p?r-4, W/19114' AC(:ESSIQN IIM: AP3002775 S/0204/63,(0031003/0352/0359 AUTHOR- Ivanov, K. I.; Savinova, N. Ko; Zhakhovskaya, V. P. 66' TIIU* Thermal 5t ability of, aj!SL1_ hydroperwdde SOURCE., NeftekhimiYa, v- 30 nb.,,3,* 1963- 352-35Tr __TOPTIG ---TAGS -isomeric d alkyj hydroperwdde d~cOmpositiojfj a. ky r ABSTP.&MI 'The investigated isomeric alk-yl hydroperoxides cl.- b P: according to their increasing stability against thermal dec`~~ifipoq~tion. Undq~~ thE investigated conditions their stability in io-1 NtionT-1_5~_as ws secondary, primary, and tertiary alkyl hydrocarbons. In ar. Diert media 0 chlorobenzene solution under a nitrogen atinosphere and at-110G, the directlon of thermal deCOMP03itiOn is different Por alkyl hydroperoxides of (Ufferent structures. The primary alkyl-hydroperoxides under these condilt~:Ions decompo$es nzrily into hydrogen and acid- with the same number of atoy priL ms. The hydrogen, sk--leton of the secondary pentanehydroperOdde-2 partly breteks- dami -4th -the formattion of meth-ane and butyric acid. The tertiary hydropi_-oxL&! decomposes by a complex radical chain reaction. The composition of tho gaaeous ]chase alid -Card 1/2 L1333-8-63 ACCESSION NR AP)C-J2775 the nature of the solvent show alarge effect on the directioti and .0 some extent, on the rate of the a2kyl hydroperoxide, decomposition#, Ther gitseous oxygen: 13 vigorously absorbed by the solvents of the decomposLig it3or-eric alkyl hydropez-oxides and even takes part in their decomposition in an inert solvent such as chlorobenzene. In the treatment of, autm'dd0don gachwlism of petroleum and of paiaffinic hx*ocarbons espeoially,,, onla must confj!~der not olay the effect of the decomnosition. in the liquid but also in the gaseauD media. Ln addition to this the possibility of direct formation of acide during the decomposition of alkyl hydroperoxides must also be considered. Orig. arto has: 2 tables. ASSOCIATION: Vsesoyuzny*,y teplotekhnicheskiy nauchno-1ss1ed6vateltn!.d*y institut im. P. E. Dzer2vinskogo (All-Union-Scientific Research Institute 6T.Heat Engi rin ENCL:!. .00 SUBMITTED- O3Dec62 DATE ACQ: 23Jul63 SUBCODE: 00 NO MF SOV- 004 010 Card 2/2-- GORBAMTKO, A.D.; ZEGER, K.Ye.; ZERNGVA, T.A.; IVANOV K.I * A-ttl~- LIIISHTEYN; R.A.; LUZHETSKIY) A.A.; POCOTSKIY, L.I. Importance of ash content in boiler fuels for electric power plants. Standartizatsiia 28 no.1%24-25 Ja 164. (MIRA 17:1) : I Ivi 1 1: kand.tekhri.nauk Organ] ze tbo prrdtiction of honvy-duty coro barrol rnok drilln. Gor. 7hur. n,),,4-,43-48 Ap 164. (14110. 17:4) IVANOV, X.L; ANDHEYEV, V.D.j MANZIYENKO, G.G,j IJSIfKGV, R.N. Invostigating the efficiency of using pistons of variow desijm for rook breaking. Gor. thur. no'. 121L.5-47 D 165. (MTRA M12) I PI 'M W-' GL) jr, LWkk w ; I II J FjVAN, / r, M 7CT NR, AT6015194 (P, t4 SOURCE CODEt UR/0000/66/000/000/0046/0049 AUTHOR: AleksplevapMo Ps; Ivenovs Ke Is ORG: none TITLE: Determining the thermal stability of fuels in a rocking aiito-alave SOURCE: Metody otsenki skspluatetsionnykb svo7stv reektivn7kb topliv i smazochnykh materialov (Methods for the performance evalue.tion of jet opellants and lubricants). Moscow, Izd-vo Mosbinostroyenlyeg 1966j 6-49 V TOPIC TAGS: petroleum fuel, fuel thermal stability, fuel corrosiveness,? fuel deposit formation ABSTRACT: The effect of moviment on the values of the beat stability indices of reactive fuels was studied in the laboratory utilizing a rocking autoolave to simulate the motion of fuel in tanks, Tests run 0.13 T-1 and T-5 fuels and on fuels containing cracked products,%bowed tbat7 the tbermo-oxidative processes In motionless and In agitated fuels do not differ too significently--tbere is little effect on deposit and i resin formation and*acidity is just noticeably higher, Orig. arto has., 3 figures and 2 tables. conE2vm?lv 14/ SU13M DATE: 1ODec65/ ORIG REF: 001 Wd IVANOV, K.I. ,%-M'N~-Practically important tasks of the geography of agriculture. Tap. geog. no.41r206-214 157. (MIRA 1NU) (Geography, Economic) (Agriculture) ZVORYKIN. K.V.; IVANOV,_J~.. Tasks of the geographical study of natural and economic con- ditions connected with agriciiltural production. Geog. I khoz. no.1:35-39 '58. (MIR& 12:1) (Agriculture-Rconomic aspects) v IVAITOV. Y. J*_-- -""- - Mnrn attention to goographical studiee In agriculture. Gnog. v shkole 21 no.5:1-5 S-0 158- (milth 11110) (Gnographical rennarch) (Agricultural physica) GEDYMIN, A.V.; ZVORYKIN, K.VaVANOV, K.I. "k-rarian atlas of the German Democratic Republic" [in German] and the system of the qualitative evaluation of agricultural lande in the German Democratic Republics Vopegeogs no.43: 190-205 '58. (MIRA 1215) (Germany, East--Agriculture--Ha ) (Germany, East--Soil surveyT IVANOV, K.I.; LEBEDEV, P.N. Compiling maps of the agricultural use of soil as one of the contacts between teaching geography and life. Geogo v shkole 25 no.2:38-43 mr-Ap '62. (MIRA 15:2) 1 (Agricultural geography) _1VANOV, K.T., rod.; EELOTSERKOVSKIY, M.Yu., red.; BOLYSBEV, red.; GEDYMIN, A.V., red.; GLAZOVSKAYA, M.A., red.; GOLOVENKO, S.V., red.; ZVORYKIN, K.V., red.; IGNATIYEV, G.M., red.; KUZNETSOVj G.A., red.; LEBEDEV, N.P., red.; LEBEDEV, P.N.q,red.; WITPIKOV, A.N., red.; SHEYNIN, L.B., red.1 GREBTSOV, P.P., red.; YEPI~IAKOV, M.S., tekhn. red. [Accounting for and the evaluation of agricultural land) Uchet i otsenka sel'skokhoziaistvennykh zemell. Pod red. K.I. Ivanova. Moskva, Izd-vo Mosk. univ., 1963. 385 p. (MIRA 16:7) (Farm--Valuation) (Soils--Classification) (Cadaaters) IVAN0V,.&j.;,VESK0V, M.I.; KIIOMYLOV., G.S.; MELINIKOV-, SOS" WTAKELI, K.P. Technological layouts for mining coal without men and without timbering. Gor. i bkon. vop. razrab. ugoll. i rud. nest. no.1i 49-66 162. (Coal mines and mining) (Automation) (faRA 16:7) IVAN011, K.I. 1, .... - ~ I~ ~'': ~- '~' ~-7. Territorial (geographical) production plans in agriculture. Vest. Mosk. un. Ser. 5: Geog. 20 no.5:3-10 S-0 165. (MIRA 18:12) 1. Kafedra ekonomicheskoy geografii SSSR Moskovskogo gosudarstvennogo universiteta. Submitted June 10, 1965. Ll I ~ I I V AN,, )~ ., F , 1 , ~ W)LYAN -I , ,-~ 'LANVI, YEN-e!l, jmrrove tille qu;.jll.t.-i (-),' firil.l. att-I , Gor. zhur. no., 144-.4-/ Ap 165. (MIRA ISO) 1 1 il : . I IMAM, Gy. T. Functional prc)l,eftIE!-' of oil. firciuced from "I'lazan, ri,2f-t,4,Hui. no,4:9-11 165. Chi- -kLM-, tu L. ins lit! 1111~ Ile 1. IV4,01V , K. I. 2. USSR (600) "The Basic Features of the Hydrochrmical Balance of the Preestuarial Areas (of the Volga River and of the North- am Casrin Sea.)" T=dv GOIN, Issue 4 (16), 1948 (70-129, 9. Meteor-ologiya i Gidrologiya, No. 3, 1949,1M Report U-2551, 30 Oct. 52. --ncy -m --ri Tel C-0111, 2 1~i' 1): U-303", 1-1 --------------- USM/Geopby~ics Oceanography ll-,J-)ct ~0-- Turbidity*- ~t~fficient of Light Atteauation as a Function of ,q iAi~ Diameters Qf ra-r-ticles Suspen~--d in Water," Ivanov., State Oceanogmphic"Inst, Main Adm Ot..-94-drometeorol Sv ~P, .or Dok Ak Hauk SSSR" Vol LXXIV, No 5, PP 9225-929 Organized, experiments with kaolin and clayey silt d;ild in distd water to clarify dependency between content of suspended substances and coeff of light attenuation. Found coeff of light attenuation for vame lengths above 300 =," increazes, reaches max for USSR/Geopbysics - oceanography 11 Oct 50 (Coutd) particles with diam of 1.5a., then drops sharply and asymptotically approaches axis. Suggests wt conen of suspended substances might be approximated by detg coeff of light attenuation, inasmuch as former quantity is usually difficult to det because concn is negligible, varying 0.2 - 2 mg/:L- in sea vat,=s. Submitted by Acad V. V. ShuleYkin 15 Aug 50. SKOPINTSEV, B.A.; IVAWV, K.I. - Use of photometric measurements in determining ounpencied,particles and colored hunic compounds in s'ea water. Trudy GOIN no.22:113-131 1 52. (141RA 12:1) (Sea water-Analynio) (Pbotometry) IVANOV, K.I. Deposition of sediment in the sea off the mouth of the Kura River. Trudy GOIN no.28:131-136 155. (MMA 9:6) (Kura River--Sedimentation and deposition) kand.tekhn.nauk; GMIMATIKOV, Yu.A., inzY. Investigating the bearing properties of coal pillars in a .9teep seam, Ugoll 40 no-3:30-33 Mr 165. (MIRA 1814.) 1. Institut gornogo dela im. A.A.Skochinskogo. IVANOV, K.1. 14anufa-clu-re of cementleus arbolit blocks at the production center of an interfarm building organization. Stroi. mat. 7 no.7:26-27 J1 161. .(MIRA 2427) (Zvenigorod District-Building materials indust) KHESIN Gennadiy Llvovich; BABENKOV, Igor' Sorgeyovich;-1VA'OV Konstantjn,.-jv,"qyAqh; MELINIKOV, Ye.A., otv. red.; LEDOVSKAYA, V.V.y red.; IVLEVA, I.P., red. r LStress distribution in a boring instrument and in rock; static and dynamic investigation by the photoelastic method] Raspredelenie napriazhenii v burovom instrumente i porode; staticheskie i dinamicheskie issledovaniia raetodom foto- upr"gosti. Moskva, TSentr. nauchno-igal. in-t informataii i tekhniko-ekon. issledovanii ugollnoi prou7shl., 1963o 89 pe (MIRA 17-4) RUSAKOV, G.K., kand. sellkhoz. nauk; MILYAVSKF-, 1.0., kand. sellkhoz. nauk; SHILKO, V.P., kand. sellkhoz. nauk; MARTIVENAS, A.N.; BELIUSKIY, A.I., agr.-ekonom.; KARPUSUNKO, A.I., agr.-ekon. (deceased3; POS-!ITNYY, V.M., ekonom.; PANCIEVO, Ya.I., agr.-ekoncri.; hVAGIIEV, V.M.1 agr.-ekonom.; SOBOLENKO, V.S.; KRAVTSOV, D.S., agronom.; LYSOV, V.F., ekonom.; SHLYAKHTIN, V.I.p kand. ekon. nauk; TSYBULIKO, F.Ye,,; ORIKIIOVSKIY, I.G., agr.- ekonom.; TATUREVICH, N.M., agr.-ekonom.,; GAIVASH, I.I.; NOSACHENKOI V.F., inzh.-ekonom.; MUKHTJSULL111, Sh.M., agr.-ekonom.; ROZENTSVAYG, A.L.p agr.-ekonorn.; BERLIN, M.Z.J, dots.; Jy&2V agr.-ekonom.; SILIN, A.G., .j. K. I* P ekonom.; LIKHOT, I.K.; CH&NOV, G.I., kand. ekon. nauk; MIh'WLOV, M.V., kand. ekon. nauk; GORELIK, L.Ya., red. [Planning and econon&cal operation on collective farms] Planirovanie i rezhim ekonomii v kolkhozakh. Moskva, Ekonomika, 1965. 258 P. (mIRA 18:5) 1. Zavedljyushchiy otdelom ekonomiki i organizatsii kol- khoznogo proizvodstva nauchno-issledovatellskogo insti- tuta ekonomiki sellskogo khozyayst-va Litovskoy SSR (for Martinenas). 2. Zaveduyuohcl-dy otdclom Sttivropallskogo krayevogo komiteta KPSS (for Likhot). MARTYNFNKO, I.A., inzh.; MILYAYFV, I.S,, inzh.; TUGAYEEV, T.S., inzh.; KOTLYARSKIY, I.A., inzh.,* MOREV, A.B., inzh.; WUDRYAK, V.A., inzh.; SUDOPLATOV, A.P., prof.; IVAKOL K J., kand. tekhn. nauk; IGNATIYEV, A.D., kand. tekhn. nauk; KOLYSHKIN. 0.M., kand. tekhn. nauk; YEREWNKO, Ye.I., inzh. Industrial testing of the auger drilling of coal with double spindli. auger,drilling machines. Ugolt 40 no.1:32-37 Ja 165. (MIRA 18:4) 1. Kombinat Ukrzapadugoll (for Martynenko, M:Llyayev, Tugayev). 2. Gorlovskiy mashinostroiteltnyy zavod im. S.M.Kirova (for KotlyarskiyI Morev, Mudryak). 3, Institut gornogo dela im. A.A.Skochinskogo (for Sudoplatov, Ivanov, Ignatlyev, Kolyshkin, Meltnikov, Yeremenko). 11if fir 1 a IT IF IVANOV, K#K* Increase the rate of technological progress in construction of sea and river harbors. Transp, stroi, 12 no,12:1-3 D 162. (MIRA 16:1) 1. Nachallnik tekhnicheskogo otdela Glavnogo upravleniya po stroitellstvu morskikh i rechAykh sooruzheidy Ministerstva transportnogo stroltellstva 9SSR. (Harbors) (Hydraulic engineering) .IVAITOV, K.K.; BOGATYREV, M.F. Fatal outcome after appendectmy. Sov. mad. 25 no.2:110-114 F 162. (IMIRA 15:3) (APPENDECTOMY) (DEATH-CAUSES) 1 1 ~j ~-J! GNUTMIKO, A.A.; ]~_VANOV,--K.K. (Khabarovsk) Disorders of the ear in acute leukemia. Veat,,otorin. 23 no.2: ' 27-32 F t6l. (MIRA 14,-.4) (ISUMIIA) (DRAFNESS) (EAPd--DISWES) hTiFIFET'Sy V.Z., karid.tekhri.nauk; ARSST, G.A., lnzh.; IVAPIOV, Yzh.; SOLODOVNIKOV., V.A... inzh. . . .1.1- .. ...I-- ~'.. .- Devices for the control of undenrater hydraulic ongineerJng operationa. Tranap.stroi. 15 no.10252-53 0 165, . (MIRA 18312) TOROPOVA, Ye.G.; GAVRILINA, G.V.; LIROVA, S.A.; ITANOV, K.X. Formation of antibiotic 6613 in cultures of Actinom7cos daghestanicus. Antibiotiki 4 no,5til-14 S-0 159. (MIRA 13 Q) 1. Institut po isyekaniyu nov7kh antibiotikov AMN SSHR. (AVTIBI(r, ICS) (ACTINOMYCES) T- ----------- - F IVANOV, K.K.; KOVALENKOVA, V.K,,,- IL'ICHEVA,, N.P. -, GABRILIHA~, G.V.; LIROVAS.A. Fermentation concUtionB for organisms producing toy antibiotics in an experimental plant. Antibiotiki 5 novl:,4,?,-47 Ja-F 160. (MICA 13- 8) 1. Institut po izyskaniyu novykh antibiotikov AMN SSSR. (ANTIBIOTICS) (FEWENTATION) IH KOVALENKOVAI, V*K.; DAVYDOVAv T.A,; BORISOVA, V.N, Prinimali ,IYARO :Vq uchar,tiye; 50KOLOVA# L#B.; PROKHOROVA, T.G.1 SHATILOVA, Z*K.; MINEVA, L.I.; SEMENOVA, V.So Obtaining coliwjcin on an enriched medium. Med.prom. 14 no.11:13-16 N 160. 1. Institut po izyskaniu novykh antibiotikov AMN SSSR. (NEOMYCIN) 'I! 1h 111111 . IVANOV,-K.-V., GAIRILINi., G. V., KOVAIYNKOV, V. K., LIROVA, S. A., SOKOLOVA, L. B. (USSR) "Aerobic Ref.,piration of Actino;hycas circulatus, var. monoVeIni, Proactino~Vcas actinoides and other Actinomyeetes In Deep Culture in Fermenters. It Report presented at the 5th International B-lochemIstry Congrez;s. Moscow, 10-16 Aug 1961 .TVANOV K K - UVRILTILk. G.V ; KOVATRIKOVA, V.K.; LEROVA, S,A.q LOVky L.B.; -Prinimali uchastiye- BOY-.'kFf-')KAYA, R.V,p inzh.; 1"I'DICHORMI T.I., Lnzh.; SILATILOVA, Z.L, JnWi. "ration and respiration of actinomycetes and rwoactinomycetes sy tibictics in fermentors in relation to biochemical .nthesizing an v changes in the culture modia. kntibiotiki 6 no.11:984-989 N 161. OURA 15:3) 1. Institut po izyskaniyu novykh antibiotiko- A1.91 SSSR. (ACTINOMYCES) (ATITIBIOTIGS) IVANOV I LIROVA, S.A.; DAVYDOVA, T.A. Determination of the rate of oxygen dissolution and of the intensity of respiration of micro-organisms.by-meant of gas analyzers. -Lab. delo 7 no.7:45-48 Jl t61. (HIRA 14:6) 1. Institut po izyskaniyu novfth antibiotikov A14N SSSR,, (RESPIRATION) (ANTIBIOTICS) IVANOV, K.K.; LOW, V.S.; SOKOLOVA, L.B. Respiration of cu.1tures of Actinomyces circulatus var. mono- mycini. Biosynthesis of monomycin on various culture media. Antibiotiki 8 no.lsl8-27 3063. (MIRA 16%6) 1. Institut p0 isyskaniyu novykh antiblotik-ov AM, SSSIR. (AIITIrwyms) (1101-10MYCIN) (akcTERiOLOGY-CULTURESS AVD CULTURE MEDIA) GAUZE, G.F.; KHORIN, V.A.; ERAZENIKOVA, M.G.; PREOERAZHE21SKAYA, G.P. IVANITSKAYA, L.P.; LAVROVA, M.F.; USPENSKAYA, G.A.; GOLIDEMG, L.Ye.; STANISLAVSKAYAp M.S.; IVANOV K.K.- KOVALENKOVA, V.K. Monomycin , a new antibacterial antibiotic. Nauch. inform. OW. nauch. med. inform. ANN SSSR no.109-40 161 (MIRA'16:1.1) 1. Institut po izyskaniyu novykh antibiotikov (direktor - prof. G.F.Gauze) AMN SSSR, Moskva. UR/0205/'65/005/,-)02/0243/02h.7 !I T~7 At radioresistance of :LrradLated animals SOTJRCE- Radiobiologiyajp Va n TOPTC TAGS: anLmml, rat, mouse# r tim P itartiem, radiatior. 4 sicimass, single radiation dose, bacteriologic cultvre, antigen,, lip"', polysewcharidep doeg-adation reaction P.7 T7 "kT rarz"orr-~-tectiv,~ 4ffect of baoterial antigen aomporento 5379- lfi(' C011 VBJR('-&~r~r idea,, and lipopolysacchaxi:ios) was i. t 1. t h 91) thFkl, ari de t t 01 Ca ;I 7', r, 71iiiii :,I Np 24~hi*a -Imal,% Vith A a nj?j,O l. r Osol on -01 MUR, m m IL i.7 ASSOCIATION- epidemibla-gil rif o p!-v qrA M -i ro bc, PIP I - 'Lo ur sovit, (-Y11 Taof 0, 3/3 1, F, Hill' P, 'IN,; tfi,l Till; 111 Hi IVAINOV K.K.; UVAROVA, R.N.; STEPM1,1011fi, L.K. y Chenical composition of surface antigens of Salmonella paratyphi B. Vop. rBd. khim. 10 no.5:4?4-4'19 S-0 t64. (MIRA 18:11) 1. Otdel radlatsionnoy mikrobiologii i immunologil Instituta epidemiologii i mikrobiologii imeni. Gamalei ~M SSSR, Moskva. VIII MI 1 nRLISHCHEIIA, A.P.; IVANOV~ K.K.; SINILOVA, N.G. Effect" of antigens and the products of their degradation on Lhe radioresistance of irradiated anirals, Radlobiologiie. 5 no.W43-2247 165,, (Min 18:12) 1. Institut epidemiologii i mikroblologil imeni Gamlel AMN SSSR, Moskva. KHASYJiACHTKH, G.D,, kand. telchn. IVANOV, K.Y,, inzh,~ YA,IC'Ft.GOV, I),X inzh. Study of new typea of enclosing structures. Transp. strol. 14 no.lOT4,3-47 0 164, (MIRA IS:3) IVANOV.. K.K. . inzh. Introducing the use of hydraulic units for tensioning the reinforcement of reinforced concrete elenents. T-ansp. stroi. 14 no.12:22-25 D 164. (MIRA 19:1) I-V AN'17, F. m. J on tb3 Baaiv rf a "Raising the rat Content 'n the *Vlj-lk of tht-t EMAt Fri'~Olan Dairy Gattlo Purposeful Bre3ding Effort." Mlin. HIgher Education USSR, Lgrangrad -Agricultural Inst., Leningrad, 1955. (Dissertation for the Vlegree of Candidate in Agricultural S--ences) SO: 'XI)izimaya Letopis' , No. 22, 1955, PP 93-105 CAL'PERIN, M-A-, ka"d-tekhn.nauk; AR NTOV, V.V.; IVAITOV, K.P., inzh.; '1,%H-SFJd'MOVA, Z.1. ....... T!'tj,;,.j---. Studying the effect of prolonged heat treatment on the physico- mechanical properties of deposited austenitic metal. 8varka . 1:73-85 158. (MIR& 12:8) (Hard facing--Testing) (Electrodes-Testing) (Metals at high temperature) GALIPERIN., M.A., kand.tekhn.nauk; ARDEMOV,, V.V.2 kand.tekhn.nauk; IVANOV, K,M., inzh. - -.-I.- -.......- --------- -- -, -_ T,endency toward intercrystallite corrosion in austenitic filler metal depending on temperature and time of aging. SvarIca 2:71-76 159. (M]M 14; 5) (Steel-Corrosion) (Metals, Effect of tenperature on) A~RS: Saychenko, Yu.M., Ivano-,T, K.M. 32-24-6-30/44 TITLE; News in Brief (Kc,_ro_tk-1ye _sodb3hc~~a.) PMODICAL: Zavoas1mya, Laborator~yaq 1958o Vol 24, Hr 6, pp- 757-758 (USSR) ABSTRACT: lu.M.Saychenko. of Kazakh State University imeni SX, Kiroir (Kazakbskky gosudariti~=Vy universitet im. S.M.Ki=m) in co- operation with G*3. Maksimova worked out a method for the reduo- tion of the time of ixposuxe in luminescence spectrograms used for sorting glass. A graph shoym, among other things, that a quartz lamp serwes as a light source and that light paesea through the sample into a "horn" where it is absorbed. A o=parison of the luminescence spectra of various types of glass is said to hw;-e shown that a decrease of the in-tens-ity of the :Luminescence speo- tnm takes place with an inerea4a of the iron mutent- in the samples. K.M. Ivanov of the All-Union Scientific Institute of Coal Research (VeesoYuznYT. naudmo-issladovatellskiy ugollnyy institut) viork-91 out a speo-ural method making 141 possible to determine zinc in electrolyte sollxti=5 of up to 0.005%. A spootrograph 13P-22, a genexator PS-39 7 a mioropbotometer 'YjF -2, as well as an cam 1/2 autotxansformer TM-10 vAdch regLla*ed 4oltaget f=m 0 to 250 V -Neww in Brief 32-24-6-30/44 were used. Bismuth was used as inner standard, the method of three etalons being uBed. A mix-hurt of etalon powder end graphite ma burned, and for analysis the vlootrolyte solution ma steamed, dried, and burned with graphite powder. There is 1 figure. 1~ Light 2. Spectroscopy 3. Electrolytes-11-operties 4. Electrolytes-Analysis Cara 2/2 . . .'4 ": ,,." -; 0 IVU," ~" ;I F - - of the cooling rate on the propertLes of the austenite- metal of the weld, Svar,prolzvs 12:7-9 D 163. (,.jTFLI, 18-9) 1VANOV, K.M.; PWTNUOV, A.M. Device for bonding standard specimens. Plaut.massy no.6:73-74 160. NIRA 13:11) (Plastics) (Adhesion) Iff 01111"11111i 141,1111"4111, ITINIHI IVANOII__ ~.- - GAZI ZOVA, 0. ff. I P--,Nm- Study of the microstructure of pipes made by irindi-fig on avam. Plast.massy no.8:29-31 160. (KIU 13:10) (Pipe, Plaetic-Testing) IVANOV, Kim Rikhaylovich; RYAZHSK1Y, 0., red.; GOLUBKOVA, G., tekhn. [seven~.jear plan in five years] Sam' - v piat'. Moskva, Izd- vo TsKVLKSH "Molodaia gvardiia," 1960. 53 p. (111RA 35:4) 1. Sekretarl Leningradakogo gorodskogo kowiteta Voesoyuno o Lenitskogo Kommunistichaskogo soyuza. molodezhi (for IvanoT (Leningrad-Socialist competition) in~;kiy-,O Fam in 1. 8,--,Y-,)ro--7,apadnyy, inatitat SA-140ogo khozyays-.v-A, I.eainvrads~ay-a jblastl. 2~ rilavWy zoottldm!k. punkts Reaptiblikanskc!y .o3r-" pc, ltoro-4-., 'aborat 4 leningra&lml-a oblasi-2 (Ift.:r Z,)Iotukhin). IVANOV, K.M., master Books for climbing 6 - 10 kv. reinforced concrete poles. Energetik 11 no-7:25 J1 163. (KIRA 16:8) (Electric lines-Poles and towers) ADAMOV, O.V.; ~VANOV, K.N. Length of short threads on pipes of sanitary engineering systens. Vod. i san. tekh. no.11:15-17 11 '59. (MIRA 13:3) (Pipe fitting) 137-58-4-6735 Translation from: R(!ferativnyy zhurnal, Metallurgiya, 1958, Nr 4, p 62 (USSR) AUTHORS. Tageycv. V.M.,-Ivanov, K.N., Bodyagin, D.Ya., Lavrent'yev, B.A. TITLE. Improving the QUillity Of Steel jnBots and the rechnical arld Eco- nomic Level of Their Utilization (Uluchsheniye kachestva stall'- nykh slitkov i tekhniko-ekonornicheskikii pokazateley ikh ispol'- zovaniya) PERIODICAL: V sb. : Metallurgiya. Moscow-Leningrad, AN SSSR, 1957, pp 65-76 ABSTRACT: The re!iults of investigations by Lenitigrad metallurgists in the theory of crystalli2-ation and the mechanism of the origin of various types of inhomogeneities in steel ingots are set forth; new types of ingots for forging and rolling, designed on the basis thereof, are described. Data on the employment of spec- ialized forging ingots with smaller shrinkage headswithout shrinkage head, and with greater taper (10-12%), and on the use of hollow ingots, are presented. Card 1/1 1. Steel ingots--Development 2 Crystallization--'rheory A - Sh. t ft~ikolayevichj SHAKHOVp Mikhail Alekseyevich; ZHWMI- M AM., -iftzkr;-f-re-d-.j--bJIILLING, V.A.9 red. izd-va; GVIRTS, V.L.9 tekbn. red. (New high-strength structural steel 36KbN3YFA with low nickel content] Novaia vysokoprocbnaia konstruktsionnaia stal* 36KbNWA a-nizkim soderzhaniem-nike3iao, Leningradi 1961. 17.,-p-, (Lonimpadskii Don ' nauchno-tekhnicheskoi. propagandy. Obmen peredovym opytom. Seriias Metallovedenie i termicheskais. obrdbotka., no.4) (MIRA 14:7) (Steel, Structural) GUBBA, A.A.; ZAKGEY14, Ye~ N.; ZUSMANOVICH, V.M.; LISITSYN, S*N ; MOZGOV, A.Ya.; PAVLOV, A.S.; PISKORSKIY, B.N.(deceasedj; USHOMIRSKAYA, A.I.; FINKEL I SHTNO, S.M.; CHISTOVSKIY, V.B.; SHER, S.Yu.; ADMIOV, O.V., nauchn. red.; BEYZERMAN, A.N.j nauchn. red.; ZHIVOV, M.S., nauchn. red.; POGORELTY, P.P.j nauchn. red.; STAROVEROV, I.G.y naucIm. red.; STESHENKO, A.L., nauchn. red,; TSEYTLIN, M.N., nauchn, red,; KOKHANENKO, N.A., inzh., red.; VOLNYANSKIY, A.K., glav. red. [Assembling intericir sanitary equipment] Monta-zh vnutren- nikh sanitarno-tekhnichoskikh ustroistv. Mookva, Siroiizdat,, 1964. 725 p. (MIRA 17:8) ,Ik~~.4441 0 a of 10 It 11 U 44 It 14 0 61 tt 211 It 2 a. 4, 0 4 off 0 0 0 0 0 0 0 0 0 iiiiii4l _AAL_V_Q~ R. 1 14 21 16 It A A 111 11 U U M 0 16 U X to tl it il tj j, a At a 'IL-fi, -T V V-L1 I t-' 4-t- k, S t A 9 It ..a .41 Celli-$ I v 00 6 D"mpodfloo of methismial in of the zinc-chrome utsilym. V. A. -00 Pwumov Axt K_ N IvANov f, M." 'I.J. JR.4.) 6. the Wa. :0 thesis of UeGH is mirsible, *W the wait uptive catalymn -00 04 favor M*011 decomM as well as its synthesis. A study is mack of the dm=pg. -00 actim of the c4wywr ZVO~CrA at ordumy atm premum an th2 meoll sibTady :0 9 fmmecL The a". prop"am of zoo to crj(h w" 10: 1. 11te CAWY= was Opbi .00 0 ou Fe-fme asbestos to increase Its surface. "a ppuL sbmW be efromd by XuiC(h POO In= the satm of the nitrates of the metals; when pptg. by Nik the catulyter obtdmtd 0 13 is considerably Jew actim Alta the ppto.. the carbonates an redlu"d by H. Cam --Of most be taken to avoid excessi sise of timp. during the pnW. of the catwywr. Ilie Zoo W ir ;00 40 040 so 0 0 go ho a AS 00 0 u 5 1~410 8 A 11 a -L A at TALLUSGICAL 1.11FRATURE CLASSIFICATIOM I too 9z" Ives It T- u 11 10, ;V . 1 9 x it aft it p tp ty cr 19 of It a0 0 '0 0 0 a 0 o 0 o 0 0 0 0 0 0 0 0 0 Cr 0 0 0 0 0 0 a 0 0 q 0 0 0 0_0 0-0 0 0 is so so o 0 * a 0 0 0 0000 0 0 is 0 0 0 o # o a 0 0o0 o * 0 o at I; a to % a a a a 0 a 4 a a 4 1 a P 0 4 4 Q! 0 9 0 a 0 f 0 0 0 a 0 6 0 0 0 0 0 0 a 0 0 0 0 0 0 a 0 0 9 0 0 0 0 0 0 a $ 0 0 4-0 0 4.0 a * 0 0 0 0 00 to so go so 00 Proportion Of Putt CatAIYWT to asbestos was 1: 1. the totni wt, of Imth being 9.11 C, 96 1 Ap raW.-TheMeOlI (Tom aburctentered a V-shaped gliets tuix, IttAteilita an oil ' r of 1. to ISO t where It evapd. aM Its vapors Imissed into a dixompa. spit. where they 00 were first heated. then filtered through the catalyzrr. "e products chtained were cooled to liquefy aDd wit. the undevocapd. MeOlf, the vol. eJ which was measured in a 00 hutM and the lisses wm cotlecteff In gattomettfi; filled with addifird 110). Inifurner 0 so of imp. and spoW.-Ilhe first bubbles of detompr. as appnr at 2#0-8)1; with in. t their y gradually increases anill becagors particularly noticeable crMW W pup. quantit 00 F at 275-M at XW the decoutpit. is already very intrusive. P. and V. MUM it most So convenient to purrue their investigation at 325', the Mwed of Ixi.Wng in MeOll being I , -IM 1. per min. At a greater rate of speed and at a higher temp., P. 1,. h k l 66 00 . c ange ts et p ace in the character of the dmxnpn. and of the catalyier itself. the - WS' while, non NfeOli decom 5 times faster than at T coaden hl whit 00 - . . u e pg. cs am e gs emitted; then vapors am products of HCHO polynterita", whtrew the eondco-sed 00 product is triazymethylene; the caftlywr blackens and a gray ring of volatilized Zu 00 is formed, Za being reduced at almt Under normal conditiocts of weed and 00 temp. the condensate consists chiefly of MeOlf. whems the gum-s consiot of It, CO go and COl. SlaWity of Like catal -In sarrentent with the findings of Stnith and YW. go Hawk (C. A. 22, 15M) and contrary to the statements of Taylor and lZisdakovskii 00 (C. A. 21, 3FO4) and of P. V. Zimakov (f. Chem. Ind. (Rimia) 3, 1072"(108)). the C(h 0 formed does not act as catslyz" pohm. although it is stiongly absorbed by the cat- 00 00 alyzer. Tile catalym is very stable and after 57 lits. of unintervipted wtck shows no 941 sign of fatigue. HIMMAar, Nw_-iox 00 00 00 00 0 00 00 00 0 6 a 0 0 0 o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 a 0 0 0 0 0 0 0 0 0 9 0 0 -I af ---- 4mb A~~Qj with t 4ft of rttk4 Calm Y, to. hum- if If t"" at Ca ftuot. 1. "ith V-k ":*b a,*) Q14 in of the 8 rrd Place- ~1~ft of c" the Petit d[. Z* 41 3Q. of, 4.qr elf. bl, Cataippi I j;74ttivity Zoo 9 -"vv I lack at the 14 left of th~ awh as tft, 4" Aft With R lb.,k te. tw IA~ 4_9 14 Vt, th ~rsi Colliq cimmilaft - 4dda 42 at ft?Bt. C4141 t4 ft" 016% .doltv, am of M cook. 73%eAtZf V all 3 ts ft. ritt"icia ZM( t 8u 4. beat lvitAl I. Of re4ur mia tival t an P. daa to 0 pe lion Coutal t Iof f", -1 Z;5 Wall to uuiiel~, 14 CC ju "so: le mo_ 1, V J) -C. A. I ~k un,14 4)) , 0 V in a C, rculatinto 1-rem jaw, 4ovi VN fit,, 41 ftlech. 1r With 4 'Ll 47"k-u 4 at hir Z P-tuctic', ure., ~Ocy of "-C'r ialAo"t mew the C', 0 th 41J.&I 0 ~!#) d. fine h . k 4it, 11'actin, C nv"t rif rh SchrKe MCI Fri' Ydroc~ Iter.11 "til. Q)4_ Wk. tak it it. Athij, it ro 04 of fill ofsoof 141"illat. Jou to I'l-1, 401,5 a (tic L 4W and ftqAj"4, 41,11 i*,. Whik 'I 4exi" n G, Cu at 310* 4dfln - "ClIN 240t of 91. theo,, - rill. P"q ppia., Proved fe M*So 4Cj!j a 4 Init'd most In of 4ch t1j"It 211ttl tcmp- v", airtil" r 1, 4A$ fit) th, lot P"_uCt fdy 1:":_rTved It th rurr. ft Cm. __o PrlkV%, r a , 0 0 : Iris 4n e -/zoo "0e 0 coo f lye 0 ham fro,* - . ill ~_m 4? 4.4d ' * 13 t 0-*31.4 t in 44 --#ft. out .-,,qute the yicUl be-,wi im CO reached up to 70% when the condensate contalaect .hout MOA nt MeOll. calf^ BLANC 0* so so so so of 00 so q i 4 i:i~ i M ;~~ :1~,: I 11111011111~ 4W IV, MI.III I V INV!, tff MIA 'I WrtIR F" I P I I IW IPT I IN VMi~ 1II 11 j Ill ~11 - 0 13 a a G a a 0 4 IS 0 0 0 a 0 a 0 00 0 0 0 0 0 0 a 0 e 0 a 0 0 6 fAvAl"41. 1 0 0 a 6 0 0 41 a 0 0 a 0 0 a 0 03 11 #1 11 It M IS 1& 1; a o J2 it a- a ji z M v a it A-- 11 1) U P. 9 11 11 14 19 0 11 U to $0 it i 1 U V CC a Or* a' I r a 4 A. L a a 00 00 A Umt-fok 4 t ..D Paco$ .?It% MA 4 -0 00 00 A , f$ 'r MothalsO cattlyzetil. V. A. PLOT-ov AND K, N. IVANOV. J. Grat, Mal. ago 00 0J. S. S. Rat 921~1931), d. C. A. 26, Mi.-Tlii'%y6th61s*fMc0H (turn COnnd ~00 so rest it, was Stut at to 162 atm., with h*h spred of rvoictins laws throulth the r= d 30% h f 0 t v App. an 3 t e prae, o vuwm catalywo, ell is a weak culldrit WOHM-0 f d ti i b W b d f B -60 0 or ut at poolortm goo ac v o ow mostly hydrn- t , spee gas g - CULIMO Aft FOMcd 10 ift Oll KIM ll th FIA M) + 21f * .00 so t e rt" M: : Pm M , O CH. + M.- The addit. all ZnO to Cu produces no appreciable effect, while the addn. ( l d id df b1 ff C 0111111111 f 't n t"a u ec e aval CrAto e e ect on thccatalyxii of MrOK, I.Jkeztto, i 1 4 - so Cfs()o bKOITO fleSective at 11 411 speed of reacting gaws. and instead ov%rcOH. hydro. . b d Th bi l f C d C d Z O N i l 1 - car ms are pro uce . e com tutt ou o an int an act ft ve 3 u. CO l rA 000 0 a catalyst. S. L. MADORIMI- to 0 so &S 0 go ro* us 0 low Zile L LIUSATURI CLAISINFICATION C-L- ties %$loll .011 0"T lot 811111 a 7 m 9 AT to alt" L I I Od 0 IN Ill 2 413 a 1 W A I SA u I to atlif OrK Stu it e~ Is 0 a 90049000 0 0 0 0 a 0 e 0 0 0 0 0 a 0 0 0 0 0 A 0 0 41 0 0 0 6 0 0.0 : Is 4 q 0 0 0 0 4 a a 0 0 0 0 0 0 0 0 0 0 0 0 0 0