SCIENTIFIC ABSTRACT ISAYEV, N. - ISAYEV, P.

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SCIENTIFIC ABSTRACT
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18 (7) 05727' AUTHORS: Tomashov, N..D.., Andreyev, L. A.9 6OV/32-25-1o-16/6,,.1 TITLE: Coki%n"hslve~zlhvestigation of dtr6da-C6krds1*n.: CraaklW -Prom sisou PERIODICAL: Zavodskaya laboratoriya, 1959, Vol 25, Nrl 10, Dp 1200 1203 .(USSR) ABSTRACT: A device and a suitable method for simultaneous microscopic and electrochemical investigation of ~vtreas-~c:6ri*osion dracking''1w-*6-cY-';* eases were developed. The device includes a te.naile.-testing machine with a Yisual and measuring recording system. Axial tensile loads up to 250 kg can be applied; the total e-'edtrode potential.of the metal, and the potentials inAhe result:Lng cracks, are automatically recorded, and visual observation of the propagation kinetics-of cracks is possible. The~tests are . carried out in a corroding medium which is constantly renewed.. The loading (stretching) takes place on the tensile-testing machine (Pig-1) by means of a metal spring, and is adjusted-by a set wheel. Visual observation-of the sample (of cracks) is done by a microscope of type MIS-11. The tensile-testing,nia- chine was adjusted by a dynamometer of type DS-1. Immediately Card 1/3. before the test loading, the corroding liquid,was put owthe 05727 -~~.-,--Cdt*ihR~tlaive!,Lx,~estigation of Strees-Coi*ro61,Od'Cziktking S1OV/32-25-1 o-1 6/63 Processes- sample by a glass tube. The changes in the electrochemical Do- tential in the cracks were measured by means of appropriate capillaries, an electron amplifier (Fig 2, Diagram), and:a loop oscillograph of type MPO-2. The corrosion of alloy MA 2~was- tested in a solution of Na Cro (20 g/1) and Nacl (35 g1l). The 2 4 oscillogram (Fig 3) of the potential changes on the sample sur- face on stretching shows that, by the destruction of the oxide film, an intense formation of anode segments occurs producing a maximum in the oscillogram. New microc~ells (oxide-film loores) formed at the same time effect a retardation of anodic poilar,iza- .tion on the whole metal surfacei The appearance of cracks causes the formation of a steadily incre6sing.anodic segment. From a visual point of viewp the propagation of.cracks cart be divided into 3 periods: (1) The incubation period (from the be- ginning of loading until the formation of cracks); (2)'the period of uniform propagation of cracks (formation of hydrogen bubbles), and (3) the period of accelerated crack development (apparently of purely mechanical character). An increase in' Card 2/3 load,shortens the first and second perio .de, and slightly ao- 05727 Comprehensive Investigation of stress-corrosion Cracking SC)V/32-25-10-16/63 Processes celerates the third one. The results obtained confirm the as~- sumption of a film-electrochemical mechanism of stress corro- sion- cracking.There are 3 figures and 2 references, I of which is Soviet. ASSOCIATION: Institut fizicheskoy khimii,Akademii nauk SSSR (inatitute,of, Physical Chemistry of the Academy of Sciences, USSR) Card 3/3 5U) AUTHMt Tozashovv No, Do 0 Imyev# N,,- 14". SOV/20_126-3-45/69~~ TITUCt The ftability of the Passive of Nbohonical Stresses in gofftojaniya makhanichaski metals (Ustoyobivostl- passivn6p napryazhennogo metaI la) PERLODICALs Do)aMy Akademii.naik SSSR, 1959#.vol 126g Nr 3, pp 619-622,(USSRI, ABSMCTt It - ia,:wdd in-the introduction to the present paper, that the Influenoe. of, mechanical stresses, upon the electrode Pot .ential IL" hardlylinvestigated ;ad that it may be seen from such publications as are available that mechanio.al stresses-shift the electrode potential. in the negative . "otIon. it is looked upon.as obvious that the variation of the cathode potential'is caused by,a v6riati.on of the.internal eneFgy,of the metal;-a a given- Wi '(1). r the as" in corresponding.equation. I i th foxmul-ii Fo which- the, thermal.'effeot of -detorimation is.low compared to.the meahanioal work of -defoxmationt, iormtda. (2). Is given 'for thi 3 variation of the.cathode potential.-The.variations of the .cathode potential are described.as being very oz~*Al on the baois~ of, these formulas, even in. the case of strong defoxU&tion,, and the~k never-exceed,3 - 5 mv. As.,experimental measuring values-are Card-1/3 higher,- the destrudtion of the oxide film is donsidered to be a SOV/20-126-3-45/69 The Stability of the Passive State of Mechanical Stresses in Retails further.cause of the? variation of the oathode,potential in the case of further-stresses. It is:then ad d that'the~state of"ths oxide film determines tbe,sotive or passive state of the metalt* and tbat.it is.thus possible.. to, investigate'the influenoe exeroised'by.,:msohanioal*stresses upon,.thetpassive statii*of tas metal.,,The experiments were carried out on wire hamples~-ahdl the alloys'and their mechanical properties are given; As a corr oding medium,., &,.solution of,NaNC~ and KAGrO~ is, given. The. results bbiained diagraits. I Ar-st~ diWam' (Pig 1) Aboilfs :_" ., Orn thW-Va-AzLtrO1i-.wiifi r'sopeot to-time of. the potential 6;tA of capacity ijilthe primaj~~ passilvation of carbon steell.and the second diagram (Pig 2)~ shows the same for stainless steel. It. ww foui4that,-in..the case of the carbon steel investigat4d,. the potential goes'over into the active state'if the short-timi4 stress oauses a plastic deformation-of the meW. In the case of the stainless steel investigated, only very sUght sa'tivation is' oansed even in the case of meohanioal. stress being very'higbf "mally, it is shom that at the moment at'ibiab the stress :Lis Card 2/3 applied two faotors-booome active in the metal. The one is' Mie-Stability of,the Passive State.of Uechsnical Stresses MY/W-126-3-45/69 in metals machanidal. stress whiob has. an activating effect# the other it; the!oxidizing,agenti which counteracts activation. After the, decrease of the deformation of the oxide film, passivation by the solution predominates. There are,3 figures and 10 referencest 6 of which axe Soviet. ASSOCIM099 lustiitut fizicheslwyAhimii Akademii-n=k-:3WR (Institute of. Phyttgal Chemistry of the.-Adademy.of Sciences,,USSR) PREMMEM February-ll,-1959 by.P~z A. Rebiiider, Academdoian. SURaTTED& 29s 1959 M;d 3/3 ISLXEV~ N.I. Production capacity of continuous vacuum filters. Izv4 vys. ucbeb.' -zav.;pishch. tekh. no.3:96-99*160. (MMA 14:8) 1. Leningradskly takhnologicheakiy institut pishcbevoy promysh- lennosti, Kafedra oborudo-(aniya piqhchevy~h.predpriyatiy. (Filtats and ftitration) (Wire rope-Corrosion) 0 5/020160/132/02/4,6/C,67 B060007 Ap. JDJ 0 0 AUTHORSt Tomashov, N. D., Isaye I. TITLEt Investigation of Anodic. ocesses in the Crack Forkation in iet&~S~ Caused by Corrosion 7r PERIODICALs Doklady Akademii nauk SSSRI 1960p Vol. 132, :No. 2ti4p-, 409-41~271 TEXTs The authors investigated the electrical ,J factors of,ckaek,formation n metals caused by corrosion in the alloy ML2--YM(4-5% Al, 1 1.1% Zn, 0.6% Mn,~ rest Mg). The samples were subjected to a stress of 15 kg/mm2 and coiriodeUin:a. solution of 20 g1l K2CrO 4 + 35 9/1 N&Cl, An impulse polarization wa's carriiiad out with an electric current of rectangular amplitude (0-0-5 ma/cm 2) and 'the potential was measured by means of a loop oscilloscope. The potential in the crack formed was measured by means of a glass capillary with an internal diameter of 3-5 tz- Fig. 1 shows that the anodic polarization of the alloy (with continuous variation of amperage) amounts to 5800 '~OOM2/9 in non-stregsed state, whereas it attains only 450-500 v-cM2/a in atrIessed state. Already:hore- from it may be concluded that the development of the corrosiontrack is due to Card 113 GN.190 Investigation of Anodic Processes in the Crack S/020/60/132/02/46/067 Formation in Metals Caused by Corrosion B004/BOO7. the reduction of anodic polarizability. Concerning impulse~polarization an equation is derived for the potential drop 6E. after switching off of the polarization current io. Fig. 2 shows that the discharge curve can be reproduced by the equation for the discharge of Ia capacitor, which ie,shunted by means of a resistor. Fig- 3 shows the change of anodic polarizabilit; in the course of y development of the corrosion crack. By means of a microscope a.vigorous separation of hydrogen was observed at the deepest point of the*crack, whereas on the sides of the crack no hydrogen was formed. On the.basis of experim 191ntal data, the authors arrive at the conclusion that the rapid development of'thi? corrosion crack was caused by the sudden intensive decrease of anodic.poliriza- tion (up to six orders of magnitude) in the zone of crack formation. Here,~'aot the entire crack, but a limited region in its deepest point served as anode. The authors refer to papers by A. V. RyOchenkov et al. (Refs- 3,,4) and P. A-~ Rebinder et al. (Refs. 5, 6). There are 3 figures and 8 references, 6 of which are Soviet. ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR (Institute of Physical Chemistry of the Academy of Sciences, USSR) Card 2/3 me wmu=~ ~V(b) Pr-4/Pa-4/PU-4 IJP(r,) WtV/JD/EEA ACCESSION NR; AP5010177 UR/0125/65/000/004/00~4/0037 MiTHOR: TI.-nofeyev, V. NJE-ngiriaar, Leningrad); Isayev# '(Xn~dftaer' Leri-'ngrad) - - - ---- TITLE: Buil-iing up a Steel OUrface with copper alloys SOURCE; A-4-tomaticheskaya avarka, no. 4, 1965, 34-37 TOPIC TAGS: ateel, co er loyi cop-per alloy acing ABSTRACT: Eight copper alloys were deposited under identical conditions an "-'arbon (MSt -~)~'~nd love-allay (AK)Peels by the arg=7 hielded arc process. Tho face-metal per~etrat;on into the st-~~). and mechan-ii-c-al characteristics of the boild were -.nvestigated. Theste findingfi are reported: J1) The depth of penetration depends on t1he composition of both metallo, duration of contact of the molten fac( -TieF-zal the titeel base, and stresses that arioe during the, facing process; W th am A M t 9 3 - 2bronze facing. the penetration up to 0. 5 mm has practicad y ao On :be Static stren 1h; the penetration to Z-Z. 5 mrn imto AK ~,teel 4. F Card 1/2 - 45t~68-65 ACCESSION NR: AP5010177 reduces the static strength; (3) The penetration of the above bironze! into MSt 3 W341 !-0KhS-ND stef!lg doeR not affe.-t their fatigize strengthi however, it does reducip tka f~,' jZuc strencth of AK-25 Ateel by 50-70%; (4) In parts functioning umder both .,-)ads. above bronze may be deposited dire(:tl), or. MSt 3 of the &bove bronme ()il -15GI'17Y~i.3 C L L 5'U-B CODK: ?-AM 0 0 Card ZI KOKUSFKIN, D.P.; FREYDENZON, Ye.Z.; KOMPANIYETS, I.A.; SHMNIN, G.M.; LFBEDSVP A.A.; ZATULOVSKAYA, Ye.Z.; Prinimali uchastlyej DUBROV, N.F.; PASTUKHOV, A.I.; j,9AYFV4_Nj1~; STAROSELETSKIY, M.I.; AKSELIROD, L.M. Improving the quality of a faceted ingot by changing the shape of Its side surfaces. Stall 25 no.7t6lo-612 Jl 165. (KRA 18:7) 1. Urallskiy nauchno-issledovatellskiy institut, chernykh metallov i Nizhne-Tajft-#skiy metallurgicheskiy kombinat. -ISA-YEV, N.I..; SHAPOSHNIK, V.A. Method for determining the electroconductivity of ion-exchanger meAranes. Zav.lab. 31 no.lOs-1213-1216 165. (MIRA 19: 1) 1, Volonezhskiy tekhnologicheskly institut. AUTHORs Is= Zolotareval H. 1. ORGi Voronezh Technological lnstitut~ (Voroneshakly tokhnologichookiy inatitut) TITLS$ Polarization of Ion exchange membranes SOURCS1 ..Zhurnal fizichookoy khimdig v. 40, no. 6i 19669 11207-1212 TOPIC TAGS1 ion exchange membranep electric polarization ABSTRACTI The variation of the membrane potential during passage of electric enirrent through an electrodialyz r wit an ion exchange membrane was studied on cation-ex-, ,3;9 change membranes (brandAK, ase'd on KU-2) and anion-exchange membranes based on RDE-10P). Curves re~a.: i re senting the change of the raiibrans potential with time -were plotted in order to determine-the kinetic*s and degree of concentration polarizar tion of the membranes. Under conditions where a limiting current: flown through the membranes a substantial part of the current compriseis the migrati6 componentq so that on the aegaerat of the limiting current on the polarization curve has:& slope which in- creases with increasing transference n-dMber of the i6n in the free solution and vith the absolute value of the limiting current. The limiting current densities were do- termined, for DIA-0 and 19-4 membranes in solutions of potassium chloride in the. 0-005-0-1 N concentration range. A linear character of the dependence of ilim on:co can be observed in dilute solutions.;i As the concentratic-.. ofthe electrolyte.- _C rd 1/2 UDCt 34t.13 ISLYIff, N.X., inshener.- WAWP~ Reinforced concrete rail foundations. Pat' i put. khos. -no,5:6-8 Ybr '57. -(KEM 100) (IMIroade"Balls) ISLYEV, II.M. Wing tracks on reinforced concrete blocks. Tranep.stroi. 9 no.5:36-38 W 159. (NTHA 72:12) 1. Olavrqy Inshe,,nor proyekta Gipropromtrausstroya, (Railroads-track) S/8W/61/000/oo4/601/om A66i/A126" AUTHORS: Denishchuk, B.V.P Isayev, N.M. Engineers TITLE: A remote-control system for the BP -5 (BR-5) air-fractionatlng~ap- paratus of VNIIKIMASh SOURCE: Vsesoyuznyy nauchno-isbledovatellskiy instituti'kislorodnogo mashino- stroyeniya. Trudy. No. 4. Moscow, 1061. Apparat,y i mashiny kiIs - lorodnykh ustanovok..87 - 100 TEXT: The fixtures of the BR-5 air-fractionating apparatus, which is in operation at Chelyabinsk and Krivoy Rog, are regulated by six types of push7but- ton-controlled 314M (EIK) servo-mechanisms. The-latter consist of an electric motor, a reducing gear, a coupling between reducer shaft and armature shaft; further, of additional fixtures such as position indicator and limit switches. The remote-controlled fixtures differ from earlier hand-conirolled types only by a spindle which has been modified for linkage with the servo-mechanism shaft. The electric motors of the servo-mechanisms are push-button-controlled from a desk stand using reversing switches. Thermal relays prevent overloads. There are 13, figures and 3 tables. Card 1/1 IVANOV, G.S., kand.tekhn.riauk; BALASHOV, A.A., inzli.; 11SAYEVY N.M. irizb.; KARMY-SHEV, I.A., inzh.; LIVANOV, V.F., inzh. Increase the production and improve the qv- lity of reinforced concrete crossties. Tra nsp. stroi. 14 no.8:2,4-25 Ag 164. (MIRA 18:1) PEASS I BOOK ZXYL401TATIOR SOV/5078 > Akadwslya nauk URSM. Urge. Instytut *Iektrozvaryuyannya --C' Vnedronlis no a oboy svarkl v promyshlonnott'; abornIk stator. (=p a v7p. uc tion of gas Welding Rethoda In Industryl Cal lection of Articles, v . 3) Kirov, Goa, izd-wo takhn. lit-r3r UVva3R. 1960. 207 p. 5,000 copies printed. Sponsoring Agencys Ordena, Trudovogo Krannago ZrAmeni Institut e2oktroevarici Imeni akad emika To. 0. Patons, Akadeall nauk Ukr&Lnskoy SSR. Zd.s M. Floarenko; Tech. Id.; S., Natunevich. PURPOSE: This collection of articles Is intended for personnel In the welding industry. COVZRAOX: The articles deal with the combined experiences of the In titut loktroovarki imenl To. 0. Piat-ona (Electric Welding 1n:tItute*Im*n1 To. 0. Paton) and several industrial enterprises in solvIngsclentIfic and engineering problems In welding technology. Problems in Can application of now methods of me- isod welding and olectroalag wqldIag In Industry are 41 2 is he third collection of articles published under th;-U.:::'- I t = title. The Foreword wag written by B. Ye. Paton. Academician of the Academy of Science* Ukr&LnIAn SSE and Lanin pries winner. rwre are no references. ?ANA OF CONTIMS Lsqhk&ELCh-R..-L-jC:Ddid:te of Technical clences], L randalterg- C ndId to or Technical sciences, glee atitutolizeni To. 0. Paton), z h 1CAndIdat* or Technical Sciences_ In nauchnO-Igalodovatel-akly trubnyy institut (Ukrainian Scientific Research Institute for the Pipe Industry)j, andA-A-Znkke [Chief Inginear, Chelys- binskly trubaprokatnyy zavod- (Chelyabinsk Pipe Kill) Novo tracess for Producing Large-Dismater 3tralghz-Weld Pipes for 012 and-Gas Lines 140 Itenkoz-2-L-Ift Ineor), D X RabkLo (Candidate of beer, Electric We i . To. Paton139 7 A Verchanko (Engineer of the Trust 'Prodmon tarh'. JT;~st* for Installs- tIon of Food Industry latablishmenta)l, and Ir d- !jWrarmorly Chief Engineer of the Sol 18h.I.AH-M-0- Isporlonce In the Successful Welding of Aluminum and Its More 154 L Engineer IWO ~rzl Engineer# ZIec-r1c Welding u E . a 0. a On Bat;-vgv (Chief Xachanic, 3019crOdekly tsemant.yY z'Lvod tBelgorod Conant Pimat)1- I-Z-Zft2=- (Chief Of the Welding Incineering 06partmen . 2M ... yK skly z4voA 'Sjbt7az:,oA3h. MrlanOYArlk ~Dl;esprurstl avy XAchIn*rY Plant)), and :f PrOCOBS Engineer Syzr. M-9 heath" 3 a n.'ki, .. 0. T vy vAch'n;ry Plant$), 11tetroola 3 Ingwolding or 5L Stool. 1*-Rings for Cement Xi 176 badv [COM did arm of Tech n1caj Sciences, Electric 9 IA*t tUt* 1monL To. 0. Paton), A,_L_jLL&kz",Z 4t VvQl~rmI'kQnAtruktsIYa (Ural 1.bFjjmt.d-3t.o-j 21.11.01-and S. TU. 801013vich I Treat -Dnaprostal kOO8tru1Ct41y8CDn*pL1 Fabricated -31tool Trust)j. Experience 'a the M~ch&nzxstlOn Of Welding [Operational in ti. zrj. 4r K*L&lllc Structures POP a BlAst-Purnmes r2ant 194 and so C 00 Jill **a 6=*N Chem 4 , ff'r mr.1, Zhpr. , 414 cgw% 4 I"Mc - l I i 1~ te II l t v( Woo k pq4 ki . Anti Ito), jiltimiti",Uy SA), and by O'Lith"t "I N- hNofe W401 il~- 64.1 L A IATALLW64CAL LITIERATURIE CLAWK&TWO u AV No as* see* 2*9 IM 0 a a 9 0; 9 do 4 ,# 0 0, *, 0 0 o 0 0 .......... HOSAK. Y.G., kandidat tekhaicheskikh nauk; ISAYIV. U.S., kandidat meditsinskikh nauk Problem of dust control in Moscow Basin mines. Bor'bas oil. 2*." 199-201 155- OM 9:5) 1. Mookovskiy oblastuoy nauchno-issledovatel'okly Winitarno- gigi.vanicheskiy institut (for Isayev) (YMCOW BASIN--DUST--PUVMION) ~V, U.S.; SKSLYAHSKIY. Z.B.; KHOTSTANOV, L.K.; KHUKHRINA, Ye.Vo* On the project for now sanitary standards to be observed in the planning of induatrial interprises (substituting standard 1101-64) Gig'Oturds i profeseb. no*4:3-11 Jl-Ag '57. (MIRA 10:11) lo Institut giglyany truds I profsabolevanly AKK SSSRI kmfedrp gigiyerw truds Mentrallnogo institute us overs bons tvova,niya vrachey (IOftTRIAL HYGUU-STANUM) KHOTSILUOV, L.K.; VATSAK, V.G.; DITFMKHS, D.D.; ~I -SAV, N.S.; SMUITSKIY. K.Ya., lmnd.med.nauk "Hygienle principles of industrial ventilation and its operation" by L.K.Khotolanov and others. Gig.1 san. 24 no.8:86-87 Ag '59. (KIM 12: 11) (VIOTIZATIOM) (KHOTSIANOT, L.K.) VADKOVSKAYAq Yu.V.v ~rof.,; ISAYE;Vj N.S.j SHIBANUVt N.M, All-Union.Conference on,Therml Clothing and Fbcbmar~ Gig. i san, 25 no. 6:101-102 Je 1606 (MIM 14:2) ~CLOTIIINGv GOLP WEATM) (BQDTS AIND SPOES) ffi~ ISAYEX, N.S.1 BEWVA, Ye.I.; KUKARKINA, M.N.; OZHIGA140VA, Z.I.; ~SHERDIETZVSKAYA, T.A.; YURINI B.A., red.; KOROBOVA, N.D.., tekbn. red. [Documents of proletarian solidarity; collected documents on the cooperation of Soviet Union workers witb the workers of Asia.: , Africa and Latin America in 1918-1961]Dokimenty proletarskoi so- lidernosti; sbornik dokumentov o sodruzbostve~trudiashchikhsia Sovetskogo Soiuza s trudiashebimisia stran Azii,, Afriki i Latin- Bkoi Ameriki v 1918-1961 godakh. Moskva,, Profizdat., 1962. 207 p. WMA 15:12) (Trade unions) ISAYEV, N.S., inzh. Frost resistance of soft limestones. Avt. dor. 27 no.9:21-22 (MMA 17: 11) 67148 0 0 SOV/31-59-9-8/21 AUTHORS: Vulis, L~Ao, Isayev, N.U., and Luklyanov,.A.T. TITLE: Static Analog Devices PERIODICAL: Vestnik Akademii nauk KazSSR, 1959, Nr 99 PP 53-58 (USSR) ABSTRACT: The article deals with an entirely newtype of~analogs, the static electrointegrators (SEI)..'Having been un- der development at the Problemnaya teplofiziche,skaya laboratoriya Kazakhskogo universiteta (Laboratory for Thermal and.Physical Problems ofthe Kazakh Uni Iversitv) since 1957,,they greatly simplify. them -computing methods and at the same time widen the scope o;f,problem,s to be investigated. The static electrdintegrators have al- ready been used for computing diffusion of neutrons as well as for solving nonlinear problems pertainiA t the theories of heat conductivity and hydrodynamics Figure 2). The article also mentions two additonal SEI mode Card 1/2 67148 -SOV/31-59-9-8/21 Static Analog Devices the first being practically An electric analog.'of D. V. Budrin's hydrostatic integrator and1the second,an with an ohmic-type,.moving c.omputor devic6l(Figures 3 and 4). The latter has a,f,*rea.*t advantage as make calculations by dividing -the space-time component. into as many elements as desired:. In addition to this, the SEI with an ohmic-type moving computor device~has small dimensions, its only bad.point being the neces- sity to-make intermediateentries. The article. also, mentions the Problemnaya laboratoriya'kafedry'obshchey fiziki Kazakhskogo universiteta,(Problem Laboratory of the General Physics Faculty of'the Kazakh University). There is 1 graph, 1 set of graphs, I set of hookups, 1 photograph, and 12 references, of which 2 are I-mdrican. and 10 Soviet. Card 212 ------------- ISAYEV, N. U., Cand Phys-Math Sci (diss) "Towards the solution of problems in the diffusion theory of the transport of neutrons,'by means of electrical modeling." Alma-Ata, 1960. 16 pp; with charts; (Committee of Higher and Secondary Specialist Education under the Council of Ministers Kazakh SSRI Kazakhstan State Univ im S. M. Kirov, Physics Faculty); 200 copies; price not given; (KL, 1?-60, 139)~ ISAYBV,,,N.U.: WKITANOV, A.T. Bxperiment of simulating the critical state of mclear reactors by means of static eleatrointegratorse Izv* AN Wasakh.SSR Ser.energe nf)9I1-:1Z?-'LZq 160* (MIDA 13:7) (Maclear reactorB-31ectromecbanical analogies) /V PHASE I BOOK MLOITATICH SOV/5179 Alaso-Ataip Kazakhstan. Universitet. Inaledovanlye protsessov perenosa. Voprosy teorli otnosits,11nostl (study or Trans- for Processes. Problems in the Theory of Relativity) Abw-Ata, 1959. 236 p. Errata slip inserted. 1,000 copies printed* (Series: Its TrAdy) Sponsoring Agency: Ministerstvo vyashego obrazovaniya SWR and X"akhokly gosudarstyennyy univereltat in* SoNo Kirov Editorial Board: V.P. Kashkarov, N.D. Kosov, and N.M. Petrov Reap. Ed.: L.A. Vulls; Tech. Ed.: L.D. Kashkarow. POPOSE: TUS collection of articles Is Intended ror research physicists and 4ngi- neers. It can also be used by instructors and students at universities. COVERAGE: The articles of this collection contain the results of 19 studies In transport problms and the geaeral, theory of.relativity made fr= 1956 to 1958 by the staff of the kafedra obahchey fizlid I teoretichaskoy fIz1kI MumMiskogo universitete ime S'Sx. KIrown, (Department of General Physics. and Theoretical Caq-T1,15- Study of Transfer-Processes (Cont.) SOV/51T9 Physics of the S.M. Kirov Kazaidi State University). The articles are arranged in two groups. Group one contains 16 articles concerning the research activity of the toplafizicheaWa labormtorlys, pri weare obahchey risw (Host Physics Laboratory of the Department of General Physics) in the investigation ar:trws- port processes of matter, impulse and energy; group two:ccutains three articles .reporting an studies ct the Department of Theoretical Physics an prdblems of the theory of relativity. Article one or the collection is an Introduction and re- vieve the problems of treapport processes and given a fairly detailed bib]Aog- raphy or contributions of ambers or physics department or Kazakh State.Unl- versity. No personalities am mentioned. References accompany each article. TABLI OF C From the Witor I.. INVMWMOK Or TRANSPONT PROMOM Vulls, L*A. Contribution to the Investigation of Transport Processes T Study of Transfer Processes (Coat.) SOV/5179 Vulis,, L.A. Critical Regime of a System With Sources 16 Vulls, L.A*., and A*A* Kbetritsa. Problems of Similarity and of Simulating Transport Pr ones In Nue)Aar Reactors 28 Iswev N,U. Blectric Simulating at Neutron Transport Process and of the at a Nuclear Reactor 43 vulls p L.A. 9 and A.T. . Luk Iyanow. Blectrostatie Integrator 65 Klinger,, V.G.,,. and V.V. Ropshin. Simulation or Light Produced by Gamms Radiation From a Cyclindrical, Source 89 Dubaw1k,,1.1.., and V.0. Painger. Light ftchagge Between Mirror and Diffuse 84rfteen 9T Kosov, N.D# Application or the Normal- Thermal Regime Method In the Determination of the Coefficient. or Diffusion of Liquids 101 r GLOVII.IbIM, Ya.G., inzh., red. N inzh., red . Ldeceased]; BOLIMERG, N.Ye.., N.Ye., inziri., red-.-, [Construction specifications and regulations) Stroitell- riye normy i pravila. Moskva., Stz*oiizdat. Pt-3., sec.G.0 ch.10.3(Pumps; regulations for performing and accepting repair work] Nasosy; pravila proizvodstva i priemki mon- tazbnykh rab6t (SNiP III-G. 10.3-62). 1964. 21 p. (MIRA 17-.9) 1. Russia (1923- U.S.S.R.) Gosudarstvanryy komitet po delam. -stroitelistva. 2. Gosstroy SSSR (fo~ Gljvinski7). 3.Mezh- duvedomstvennaya komissiya po peresmotru Stroitelvriykh norm i pravil (for Isr-ev). 4. TSentrallnoye proyektno-konstruk- torskoye otdeleriiye Gosudarstvennogo proizvodstvennogo ko- miteta po montazhnym i spetsialInym stroitel'rWm rabotam SSSR (for Bollberg). ANIPINA. T.V.; ISAYEV, O.Y. Catalytic activity of aluminum silicates treated with alkali. Xart 2 [with summary in English]. Zhur. fis.khim. 31 no-99* 2078-2o84 3 157. (ifiA 11:1) l.Moskoveldy gosudarstvenn" universitet is. M.V. Lomonosova. (Aluminum silicates) (Catalysts) _T C- q V. 76-10-11/34 'AUTHORSt Antipina, T.V., Isayevq O*V, TITLEe The Effect of the Composition of the Alumosilicate Catalysts on the Hydration of Diethyl Ether and Dehydration of Ethyl Al- cohol (Vliyaniye sostava, alyumosilikatnykh katalizatorovih*.re- aktsii gidratatsii dietilovogo efira I degidratatsii etildVogo spitta) PBRIODICALt Zhurnal Fizicheskoy Khimii.9' 1957, Vol. 31, Nr 10, pp.2245-2252 (USSR) ABSTRACTs The dependence of the r*aotion velooiti6s In the case of the hydration of the diethyl other and of the dehydration,of the ethyl alcohol on the concentration of OH-groups at the surface of an alumooilicate catalyst and on aluminum oxide was investi- gated here. The kinetics of the hydration of ether and of'the dehydration of ethyl alcohol at alumodlicates of different com- position and at types treated with lye solution was investi- gated at 4000C. It is shown that the degree of the transformation from ether into ethylene is lower In the case of the ether-hyd- ration-reaction by " 1/3 than that of the transformation of Card 1/2 alcohol into ethylene in the dehydration of the alcohol. It was 76-10-11/34 The Effect of the Composition of the Alumoeilicate Catalysts on the Hydration of Diethyl Ether and Dehydration of Ethyl Alcohol found that in the hydration of ether the ethylene separation does not increase considerably with the reduction of the alu- minum oxide percentage, whereas it decreases linearly in the dehydration of alcohol. There are 13 figures, 2 tables, 7 Slavic references. ASSOCUTIONt Moscow State University imeni N.V* Lomoncsov (Moslcovskiy gosudaretvennyy universitet imeni N.V. Lozonosova) SUBM.I.TTEDs July 11, 1956 .,-AVAILABLZs Library of Congress Card 2/2 20-119-1-28/32 AUTHORSt Isayev, 0. V., Kushnerev, M. Ya, Margolis, L. Ya. TITLEs On a Copper Catalyst for the Oxidation of Propylene to Acro- lein (0 mednom katalizatore okialeniya propilena v akrole.-Ln) PERIODICALt Doklady Akademii Nauk SSSR,1958,vol.119,Nr I,PP.104-106(USSR) A,BSTRACTt First a short report is given on previous papers dealing with the same subject. Several patents recommended the application of cupric oxide which has to be applied to different carrier materials. The following problems remained unsettled:What is the phase composition of the copper contacts ? 'What happens to the catalyst during the reaction and which oxide is cata- lytically active ? For settling these problems 3 series of experiments were carried out, the following catalysts being usedz 1) CuO; 2) Cu~O; 3) metallic copper applied to pumice stone. The phase composition of the catalysts before and after the experiment was roentgenographically investigated. The roentgenographs were taken by a Debye (Debaye)-chamber of a diameter of 57,3 mm with the K,,-radlation of iron. The catalysts were tested for 40 minutes in a dynamic de- Card 113 vice under atmospheric pressure in a mixture of propylene 20-1110-1-26152 On a Copper Catalyst for the Oxidation of Propylene to Acrolein and air (10 - 12 4, propylene and about 20 % oxygen) in a temperature interval between 300 and 400 0C. A figuire shows the results of the identification o4j.' the roentgenographs of 3 catalysts. The appligation of cupric oxide in an air- -propylene-mixture at 300 C does not modify the phase com- position of the catalyst. RaWing the temperature to 4000C. leads to a reduction of the oupric oxide to protoxide and also to metal. Originally existing ouprous oxide was reduced to copper under these conditions. Whe swebpinz of the copper by an air-propylene-mixture at 300 C leads to its partial oxidation to Cu 20'. The additional electronographic investi- gation of these catalvats showed that after-its application in a propylene-air-mixture the surface of all investigated samples was covered with'a layer of cuprous oxide. Thus~ the cupric oxide in the Iresence of a propyle'ne-air-mixturi is reduced to the system Cu 0 + Cu and metallic copper is oxi- dized to cuprous oxide. iropylene in the presence of cuprous oxide is oxidized to acrolein and in the gases developing in this process almost no oxygen is contained. Consequently the catalyst during the reduction has an effect in a re- ducing medium and therefore a transition Cu 20 b Cu is pos- Card 2/3 sible. By changing the relation propylene t oxygen in the 20-119-1-28/52 On a Copper Catalyst fox the Oxidation of Propylene to Acrolein reaction mixture the reduction of the cuprous oxide can either be suppressed or intensified. The composition of the oata- lyst is automatically regulated by the existence of the re- versible process of the reduction of Cu20 to Cu and the oxidation of Cu to CU20 . There are 2 figures and 8 references, 3 of which are Soviet. ASSOCIATIONs Institut fizicheskoy khimii Akademii nauk SSSR (Institute for Physical Chemistry AS USSR) PRBJSNTEDs August 69 19579 by V. N. Kondratlyev, Member, Academy of Sciences, USSR SUMITTEDt July 25, 1957 5W AUTHORS: Isayev, 0. V., Margolia,.L. Ya., SOV/79-29-5-26/75 -MwEary-95. Z. TITLE. Catalytic Oxidation of Propylens in Acrolein. I (Kataliticheskoye okisleniye propilena v akrolein. -1) PERIODICAL: Zhurnal obshchey kbiaii, 1959, Vol 29, Nr 59 pp 1522-1527 (USSR) ABSTRACT: In the present paper the properties of Us cuprons oxide catalyst which was used in the catalytic 6xidationi of propylene in, icrolein were investigated. Further its activitrwas compared with.-6ther oxidizing contacts. In order to clarify the part"ac*taldebide ilays in the oxidation of propylene the method of the marked atois was used. The oxidation of the propylene mixture with oxygent 'nk with acetaldshyde marked with radioactive carbon (I t 2 t 0.5) or, cuprous oxide at 350P permitted the definition.of the genetic compounds of t1wee reaction produots. The results of a typical experiment are illustrated in figure 1,;As can be seen, tbo cirbon dioxide is mainly not formed from acet4dehyde brat independently via other intermediates. The data devised according to the kinetic method of M. B. Neymw (Ref 5) are given in figure 2. By Vis use of Card 1/3 radioactive carbon it could be proved that in:the" proce .assei at the Catalytic Oxidation of Propyltne in Acrolein. 'I SOV/79-29-5-26/75 same time and independently of one another several:parallel reactions take place, in which connection unstable intermediates of the peroxide type are formed. Purther some experizetts werecarried out in which the effect of the contact time upon the oxidatimi process of propylene was investigated (Fig 3). The acrolein'y%eld first increases on prolonged contact -time but later remains constant whereas the yield of carbon dioxide continuously increases.~Daring the oxidation of propylene on the copper catalyst the acrolein is not completely destroyed. Probably at the same time and independently two reactions take place: The formation of acrolein and its oxidation up to the carbon dioxide; P The rate ratio of this process is*deterained by the composition of the~gas mixture* In order to clarify the dependence of the acrolein yield on the concentration of the catalyst on the carrier, several samples of the catalyst on pumice and carborundum were investigated (Figs 4-7). Tfie investigation indicated that the selectivity of the process can be obtained by shortening of the contact time, byAncrease ofthe linear velocity of current as well as by a decrease of the copper concentration on the carrier which determines -the course of them process in the kinetic range. Under certain conditions the length Card 2/3 of the catalyst layer can be of decisive importancet Further the Gatalytic Oxidation of Propylene in Aorolein. I SOV/79-29-5-26/75 oxidation of propylene on other,oaWyats was investigatedt V I moo I WO , Gr P CdTep CUSS? CUTSO Cuks. Selenide, telluride, 2-05 3 3 ~ 2.03 arsenide and cuprous oxide-were found to have the highest selectivity with respect to the formation of aorolein. On the ' formation of the mixture of saturated aldehydes and aorolein, oxides. of transition metals (M003' V205 etc.) are' especially active. There are 7 figures and 6 references, 5 of which are Soviet. issaCIATIM: Institut fizicheskoy khimil Akademii nauk 353R (Institute of Physical Chemistry of the Academy of Sciences, 'USSR) SU M TTED: April 22, 1958 Card 3/3 MIN -RUM I WMMOL A 5W SOV/2o-124-4-36/67 AUTHORS: - Isayev, 0. V., Kushnerovp Ma Yas ----------------- TITLE: The Investigation of the Phase-Composition of theCopper Catalyst for the Oxidation of Propylene,to AcrPlein ft,zucheniye, fazovogo sostava mednogo katalizatora okisleniya propilleza v akrolein) PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 124, TTr 4, PP 858-360 (USSR) ABSTRACT: The phase transformations were continu ously controlled by. means of radiographic recordings in the course of the reac- tion itself. These picturea were takon by means of a special- ly constructed.cameral the constructional principles of which are described in form of a schematical drawing. The tempera- a thermocouple ture of the catalyst was recorded by M04Lns of 0 and was kept constant with an accuracy of + 1 . The Xrray beam dispersed by the sample was recorded in a plane film. For the catalyst investigated, good resolution and a PatiB- factory intensity of reflections was attained by using,:an X-ray tube of the type BSV-4-Cu without filter. Like in a~ Card 1/4 previous paper, copper oxide, cuprous oxide, and metallic SOV/20--124-4-36/67 The. Investigation of the Phase-Composition of the Copper Catalyst for the Oxidation of Propylene to Acrolein Card 2/4 copper were investigated. The copperoxide was produced by, the oxidation of Cu and Cu 20 by atmospheric oxygen. The cuprous oxide was produced according to a method developed by D. N. Finkel'steyn (Ref 2). All experiments were carxied out at atmospheric pressure in a gas mixture of the following composition: propylene 15~6, oxygen 15%, and nitrogen M~- The results obtained by identificaiion:of the X-ray pictures of the catalysts are shown by two diagrams..In the oxidation of propylene over copper oxide at 310 the C:atalyst Was reduc- ed, and after operation of 210 minutes cuprous oxidel:wa3 radiographic8lly determined. An increase oftemperature (343 and 370 ) increases the rate of reduction,considerably. Besides the formation of cuprous oxidst a motallic phaino could in both cases be observed, which occurs all the more~rapidly the higher the experimental temperature. It, however, the propylene is oxidized for 135 Minutes Over CuO (370OL only one phase, namely only metallic copper, is:observed. The same results are obtained by the oiidation.,of propylene over cuprous oxide. Details are given. By oxidation of propylene SOV/20-124-4-36/67 The Investigation of the Phase-Composition of the Copper Catalyst for the Oxidation of Propylene to Acrolein on a copper oxide catalyst a highly reaptive.compound is obtained, viz. acrolein, is obtained, which pay -enter into an oxidation- and polymerization reaction in thevolume phase and also on the surface of the catalyst at temperatures of 400-450 . It was therefore of interest to investigate the influence exercised by acrolein upon the phase conversions of the copper oxide. The passing of a mixture of aorolein vapors (0-5%) with nitrogen leads to the reduction of cop- per oxide to Cu 0 + Cu. The addition of oxygen to the gaa 2 mixture sharply slows down the reduction of the catalyst, and a polymer film is formed. B* treating a copper film by a mixture of acrolein (Q-5-5-07-9 oxygen (15~),.and nitro- gen at 4000 for 2-3 hours the copper is oxidized to copper oxide, and at the same time a polymer film is produced on the surface of the catalyst. There are 3 figures and 2 Soviet references. Card 3/4 SOV/20-124-4-36/67 The-Investigation of the Phase-Composition of the Copper Catalyst for the Oxidation of Propylene to Acrolein ASSOCIATION: Institut fizicheskoy khimii Akademii natak SS.SR (Institute.for Physical Chemistry of the Academy of Sciences, USSR) PRESENTED: October 6, 19589 by V. 1. Spit.synp Academician SUBMITTED; October 32 1958 Card 4/4, 66492 37J300M) -54 4 1 1 1 SOV/20-129-1-39/~4~ AUTHORS: Isayev, 0. V., Margolis, Ya., Sazonova, 1. S. TITLE: The Mechanism of Fropylene Oxidation to Acrolein on a Cuprous .Oxide Catalyst PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol..129, Nr 1, pp 141-144 (USSR) ABSTRACT: On the basis of kinetic measurements the authors::gave~a sch6ne.: for the oxidation of propylene to acrolein (Ref 2)~ jn.:th~ r'' sent investigation this scheme is revised by me"i of.:tagged, atoms. Propylene tagged with radioactive carbon was prepared by 0 ; dehydrogenating isopropyl alcohol at 400 over Al 0 After 2 mixing with acrolein and oxygen the propylene thus pro pared.was Oxidized on oatalyets at atmospheric pressure. The catalysts contained 0. 1 And 1% oopper, respectively.. Carboruridus wa& Used as as carrier. The acrolein content in the reaction.product w . determined by the bromid6-bromate method, and the propylen e o6n- ' tent and CO by means of the gas analyzer type VTI. The radio- 2 ig the activities of CO and acrolein were deterained.:by measuriz Card 1/2 l 2 66492 SOV/20-1219-1-39/64' The Mechanism of Propylene Oxidation to korolein on a Cuprous Oxide Catallet activitiee of the barium carbonate and the aorolein 214-dinitro- phenylhydrazone precipitates, respectively. The experimental results are represented graphically in the figures:1-3 (Cc &ad 2 acrolein concentrations as functions of the time~of contacts the catalyst, and composition of the initial gas mixture). Table 1 gives the data obtained and the oxidation rate calcuilat- ed for the transformation of propylene to acrolein. An organic film of acrolein was'found to form on the Catalyst. The stabili- ty of this film was greater in the case of the Catalyst Contain.- ing less copper. The parallel-consecutive reaction scheme sug- eated in reference 2 was confirmed by the experiments. There 9 are 4 figures, I table, and 5 Soviet references.- ASSOCIATION: InstitUt.L'fizicheskoYL-khimii Akademii nauk SSSR (Institute of Physical Chemistry of the Academy of Sciences, USSR) 'PRESENTED Lp b June 19 Rebinder Academician A 1959 : . . , , y , ISUBMITTED: June 15, 1959 Card 2/2 S/195/60/001/002/004/016 B004/BO67 -0,. V., Margolis, L. Ya. AUTHORSt 1"ev, TITLE: Kinetics of the Oxidation of Propylene to Acrolein on a Copper Catalyst PERIODICAL: Kinetika i kataliz, 1960, Vol. if No. 2, Pp. 237 241 TEXT: The authors attempted to determine the rules governing the oxidation of propylene to acrolein and CO. on a copper catalyst. The experiments were made in a continuous apparatus under atmospheric pressure. Temperature was kept constant by means of a photoelectric thermor-agulator in which a portable TTTT(PP) -potentiometer was used. The gases ware analyzed for CO and CO on the b--sis of their infrared 2 absorption spectra and by means of PKTr 5 (GTP-5) gas analyzers. CuO produced by impregnating sillite or pumice with Cu(NO 3)2 and.by heating to 6oo - 700 0C served as catalyst. Experimental data are given in Table is Card 1/3 1. KinetiCB of the Oxidation ~of Propylene to S/195/60/001/002/004/010 Acrolein on a CoDDer Catalyst B004/Bo67 Change of -propylene- b_~a.nge-Of 02 cOn- o concentration centration First-order con- %CU c Initial Result Initial Result, % sec- stants mixture mixture , %C3H 6 02 2 %C02 ~crolein %02 C3 HI N 2 C02 crolein k k c0 aer 0-5 373 15 1 5 1.2 0.26 3.C 30 67 0-55 0-077 o.62 0-052 20 1 C 1.25 0.30 5-C 3o 65 0.85 0-13 0.58 0-053 30 10 G IA 0.31 10.( 3o 6M .8 0.27 6.61 0.054 40 10 C 1.2 0.36 15-C 30 5 2-7 1 0.39 o.61 0.052 6o 1C 3( 1.2 0.25 - - - mean O~605 0-053 1.0 362 15 10 7T -8 - 3-C 30 67 0-50 0,056 0.56 0.036 20 10 ?( 1. 0 .30 5-C 3o 6g .1 O.75 0-11 0.50 0.045 3o io 6c l-55 0.26 im 3o 6M .6 0.22 0.57 0-044 40 10 ~q l-6 0.29 15-C 30 55 2-4 0.32 0.57 O-OA2 6o 0.30 - - - mean 0-54_~ 0 M 11 Summing ups 1) The rate of propylene oxidation is independent of the propylene concentration, and is proportional to the oxygen.concentra- tion. 2) The constants of the reaction rate. linearly increase with Card 2/ /3 Kinetics of the Oxidation of Propylene to S/195/60/001/002/004/010 Acrolein on a Copper Catalyst B004/BO67 increasing copper concentration in the catalyst. 3) The activation energy for the formation of C02 on a copper - sillite catalyst was 28 - 30 kcal/mole, and on a copper - pumice catalyst, 23 -125 kcal/mole. 4) The major part of C02 was.formed by oxidation of acrolein. Therefore, the kinetics of acrolein oxidation was compared with that of propylene,, and the following was found: a) The oxidation rate is proportional to the oxygen concentration and independent of the acrolein concentration; b) them activation energy for the formation of CO is 22 - 24.kcal/mole, and for' 2 the formation of CO, 38 kcal/mole; o) the presence of propylene inhibits- the oxidation of acrolein. The authors intend to perform experiments with tagged atoms to study this effect more thoroughly. The results wil 1* be published in the next paper. There'are 6 figures, 2 tables, and 4 Soviet references. ASSOCIKTIONt Institut fizicheskoy khimii AN SSSR (Institute of Physical Chemistry of the AS USSR) SUBMITTED: December 19, 1959 Card 3/3 S/195/60/001/003/010/013 B013/BO58 A.UTHORS: Yenikeyev, E. Kh sayevq V., Margolisq L, Ya. TITLE: Modifying Catalysts for the Oxidation of~,Hvdrocarbons PERIODICAL: Kinetika i kataliz, 1960, Vol. 1, No. 3, PP- 431 439 TEXT: In this paper the authors studied ithe oxidation Of Dropylene:on cuprous oxide (Cu 20) and of ethylene on"Silver. The oxidation of propylens to acrolein on CU 20 proceeds according toatparalle1euccessive scheme..A step-by-step scheme is presumed; (I)! On the basis of the.change of the work function of the electron during adsorption of reaction components on Cu20, the sign of their charges could beestablished: Like most organic substances, propylene and acrolein are the donors and-oxygen is the accep- tor. The water reduces the work function only slightly and is also a.don= It was shown that the oxidation rate of propylene to acrolein and carbm dioxide is proportional to the oxygen concentration in the gas phase(Ref, 6). This is also valid for modified catalysts. It was established that Card Modifying Catalysts fo� the Oxidation S/19 6.0/0011/003/010/013 of 'Hydrocarbons B01 3YB058 the activation energyand k' (factor of the e4tponential functions for the reactions of the formation Of acrolein and C02 ) depend on the work func-. tion. For greater values of the work function, the activation energy of the formation of acrolein is reduced and that of CO increased. From.the- 2 dependence of the isotopic exchange on the work function JP., the rate of which increases for smaller values of V, the controlling effect of the work function on the surface concentration of 0 2 may be inferred. The selectivity of the acrolein synthesis is increased through the introduc- 2- in tion of acceptor additions (SO 4 , Cl CuO and reduced by that of donors (Cr, Fe, Li). The oxidation of ethylene to ethylene o#de is a typical process proceeding according to a parallel schemel(Ref. 10). The following signs of the charges of the components of the studied reaction were ascertained: ethylene and ethylene oxide are donors, oxygen and C02 are acceptorsiPis only slightly reduced by water. The step-by-step oxidation scheme proposed in Ref- 4 could be explained on the basis of Card 2 Modifying Catalysts for the Oxidation S/195/60/001/003/010/013 of Hydrocarbons B013/BO58 the signs of chargesdetermined: (II). Data with regard to the kinetics of the oxidation process, available from publications and often paradox,.can probably be traced back to the dependence of the partial surface concentra- tions of 0 and C H on the change of the work function., The activation 2 2 4 energy of the oxidation of ethylene to ethylene oxide ought to change only little in the modification of silver, since the surface concentration.of , donor molecules is increased through an' increase of 'f,,. These in turn -1~w-el the change offunder the effect of metalloid additions. It was shown that an increase of the work function reducei the activity of silver and raises the selectivity of the process. Conclusively, the studies showed the' following: There is an interrelation between the work function of the: electron and the activity of the catalysts and the selectivity of the oxidation processes of unsaturated hydrocarbons. The oxidation of hydro.- carbons proceeds over a number of parallel and successive stages and, according to the reaction mechanism, is differentially cont rolled by the work function of the electron. The inhibition of a total oxidation with an increase of the work function is characteristic of the reactions stu(bed. Card 3 Modifying Catalystsfor the Oxidation S/19 6o/ool/003/010/013 of Hydrocarbons B013YB058 This can be explained by the similarity of the reaction mechanism. To alli appearance chain reactions also play an important role in the formation of CO 2' S. M. Vilenkina, Laboratory Assistant, participated in the work. S. Z. Roginskiy, Zelldovich, M. I. Temkin, P. V. Zimakov, and G. D. Lyubarskiy are mentioned. There are 5 figures, 1 table, and 23 references: 19 Soviet, 4 US, I British, and 1 Canadian. ASSOCIATION Institut fizicheskoy khimii AN SSSR (Institute of Physi cal Chemistry AS USSR) SUBMITTED: April 6, ig6o Card 4/f," MARGOLIS, L.Ya.; YKNIKEYEV, E.Kh.; ISAYKV,_q~.~V ; KRYLOVA, A.V.; KU&MROV:' M.Ya.; Prinimala uchastiye: VILENKINA, S.M., laborant Modification of hydrocarbon oxidation.ca~aljsts. Kin.i kat. 3 no.2tl8l-188 Mr-Ap 162. (MEU 15:U) 1. Institut khimicheskay fisiki AN WS. (Hydrocarbone) (O)ddation) (Catalysts) r ,oloviu, O.A.. Radioactive tracer technique in investipting 'U'le zxachanl~s= 3-, oAdation of propyle". to acrolein on a cuprous o_T4 de catalyst. Dokl. AN SSSR 142 no.3-.619-622 Ja 162. (MIRA 15: 1.) 1. Institut khimicheskoy fizikl AN SSSR. Predstavleno akademikom V.N.Kondrat'yevym. (Propene) (Acrolein) (Oddation) ""'HAY',-)J, N.Vi Catalyt-~c cxidatie~m cl-f rir-~71an,~ rcleir, In a 'Ill'urvou f I uirlized be. d. K I', J In. Pr=. 4no.6., '*'1 72 OMIRA 113h. 8) ACC NR AP6017103 (A) SOURCE COME: UR/0226/66/000/001/0046,/0049 51~1 AUTHORS: Dubrovskiy,, A. P. (Moscow); Isayevt P. A. (Moscow) ORG none Tri'LE: Investigation of eas-pormeability of porous miaterials- SOURCE: Poroshkovaya, metaUurgiya, no. 1. 1966# 46-49 TOPIC TAGS: metal pq~~qor, powder alloy, DaNdar=z0bal iyifteviM,,~ porous metal 11111144-~11~j "~, ~~~ Y-J-~f .14 !ABSTRACT. 'The effect of porosity and the particle size and shape of sintAme monel metal and bronze on the gas-permeability of the sinters was investigated. The par- ticle s:~zo varied from 50 to 400//- and the porosity from,12 to 3311-L'. The J~Ortel metal specimens were sintored at 1200C, And the bronze specimens at 750C. Tito gas- permeability was determined by measuring the resistance offered by the specinens to the passage of compressed air. The experimental results were treated after.the method of Yu. L. Illin (Izv. vyssh. uch. zav. MVO SSSR, No. I Aviatsionnaya-tekhnika, 1959)3 'A Ba + BIG, (P1-P2)(P1+Pj-.-- where AS Be, and B, are given by ~A .2RThG -?N~7~T; 'B' Here P, and P2 are the pressures in front and behind the porous specimen,' h is the thickness of specimen, R, T, and I-,- are the gas constant, temperature, and viscosity :ard 112 ~-C_40 COG** 00 a felil O&e t 6 10 03! 1 A f r 111241MISLa tits a m list va-ma-15-11 A4- C -A A_J._&_JL_4 "_ r - ~ a.- 4 0 - 00 -Pip !!P-f- r,4RI., ..s. At. rwi $I ------ - - T.,09 00 At ".00 00 00 64 c Tbe add-a" 19mimbrilm at W*wn (gown !.00 00A Psm*m). P. L. lowy. 11oprdsy hwitiyls 41, No. a. w_6(1w7);=Tw Pallid) PtMWM 4 0 Ill The ikif "'I 008 at high altitudes femits In a shift n( the acid-alkAi iL . ~00 towwd Wkinvia. A. Kar 00 '00 see 00 Soo 008 goo see 400 goo S L "TALLUNWAL L"INATWH CLAIMPIC11,11016 too 00 u a AV -0 ar a It 1-1 'a at is 0 * 0 a o 4d 01 a a I wa 0 do a 3 0 If - no - 1 . L. 0 01 0 0 0 0 0 1 0 0 0 0 -0 00 :__09 010 0 0 0 0 0 0 0 0 0 0 0. 0 0 4 1- 0016 0-0 0 91 & ev.0 -0 0 41 0 0 6 ~4 014 0 0 4 0:0 0 0.4~1,0414:04 0:04 ~ ISAYN, P. L. Distotic therapy in peptic ulcer* Foldsher almoh. no.6:42- 46 June 19519 (CLKL 21-.1) 1. Candld&to YAWdCSI Balance@* ISAYEV, P. L. Treatment of peptic ulcer complications. Foldsher akush no,7:24-29 Julv 1951o (CIML 21:1) 1. Candidate Kedical Sciences. T,S ~ ME , P. lechebn'oe pitqnie pri iazvennoi bolezni fTheripeutic diet for ulcers -7. Moskva, Meigiz, 1952. so. of Russ,i*n, Ace'es'sions, Vol. 6,No. 2, May 1953 lechebnoye I.Altundlyc r-l-i yazve,-;-!!u,,, bol- ezni. lblissi, Gruntedleiz, Ir,454 'I.Cs. 20sm (E-ka san. pros ve shchenlya ) . 3.C00 ekz. 45k-na gtuz, yaz. (55-482) 616.33-002.44-01-13.2 -616.-11,2-.002 id.-083.2-613.24 SO: Ki-dzhnaya Letopis', vol. 1, 1955 ISAYIV.P.L. (Therapeutic diet fnr diseases of stomach and intestihes] lechobnoe pitanie pri. bolesniakh sheludita 1, k1shechnika. Hoskin, Medgis. 1955. 54 p. (NLRA 8-.12) (DIET 3 DISZASN) (DIGNSTIVI ORGANS--DISRASM) SONDLOVSKry, T.P. Graerepeatic ftet In Vwtvalatestima diss"s I.L. Ismv. RwIewod ty T.P. SokolavWdl. Top.pit.14 (Din IN'DISMSI) (NLRA 8:10) (ALIMI&M CAWAT.-MSIM) (IUW, P.L.) ISAYEV, Pinkhus Lazorevich, kandidat mod tainakikh nauk. VAYNTSVEYG,G.Te.. ~P~Fpl~ 6i D INOVA.Z.N., takhnicheskiy redRhor [Nutrition during liver diseases; advice* to the sick] Pitante pri bolesniakh pechent; sovoty bollnomu, Moskva, Oos. Isd-vo so&. lit-w ry. 195~. 26 p. (MLAA 9:2) (DIN 19 DISRASS) (LIM-DISIAM) US&Rjllediciae - tuutrition M-3300 Card 1/1 Pub. 141 - 15/19 Author Isayev, P. L. (reviewed by Sokolovskiy, V. P.) Title Therapeutic nutrition for diseases of the stomeh and small intestite Periodical : Vop. pit., 45-46, -Tul/Aug 1955 Abstract : Gives favorable review of above book which is Intended for physiciaas!and laymen as well. Criticizes some errors, but nevertheless endorsesthe book as a valuable aid. No references. ISAYEV, P.L., kand.med.nauk Do incompatible products exist? ZdorovIe 8 no.9:12-13 S 162. (MIRA 151g)-, (FOOD) PRUE I mm ITITA SOV/3751 46 smadv*10h lmyevs, ~avvi %Uvvich an k2ey Alak Obrabotka -metallov mudyea;'reSSAIP astalliv: I*dM&hddy Inst.""at't DIA& mhj~Ahehj~e' itiu~ (fttma cutting; cutting of mteaAl ft"Ing 100UP =d -*t"-Cutting Iftchim Toole) Mosemp Moransisp 1959. 657 y. ImIft alit inaekttd. i6,,ow copies prinw. wileiv*v"At N.- Kamtygln., amnUdata of IbcbnI'am3 Scleamso, Dooestj Id.s TS' N. -.8memb4t, Ind r; Nd. of PablIshing House: F. G. T&jM~U^; SchfILt V. 1. fteshkim; MnagWg Zd.: A. I. Sokalayp Ingimer. taftnU iL.6 be PUMI*: Mda textbook is'la, -f"A 'Okhnjk~. It:a" &J"! r po, Im '"0 MACUM ladu~U7. COVHRACZ-. the boo'k-deals with the,tboary or watal cutting. ~Taoi vorking iia. reatums and meWp Of the Prj=U* tnv -8 of mIm+ALI-.wttUgo machl-tools-&re discussed. A description of 6100r)" chmdW and ultrasonic-matal-machining wthods Is premaUd. Cbap*rs I to I EMS- FWI IYZMCHIKGVA, Telexa, Kenstaxttacyna; DANInMYAN, A.M., doktor tokhak-' chookikh mank, professor. retsesseat; ISAYBV, P.P., kandidat tokbL&'L- alteskikh nauk, detsest, redaktor; bIjVdW!IjhA.0':re4fttter; GLADXMR, N.N.-, takhmichaskiy rodaktor. Cffi&spead silling of grooves by slab sills] Gkorostsme frosorowasic pasaw diskovyst frosami. Moskva, Gos.izd-ve ober.promyshl. 1955.140p. (Millinguachines) (an 9:,,5) us S R 3394 Tbe e(IWII%iuzn of P 5- ISAEV. ;.h. jklFer leor Fl... -1i, No- 1. Tim mulibmin dstribution of sbowci photons in iu li for !ho enom mugo 4 ~-!W IvitV, aik)-himm bcmu mac v w.- I wify rat ntdiaum dampir:4 iu0 -wj preducti,,n. )ul thm fv( mll~ 4n; clv.-Z rmn "hc nmAA3 of lumm allJ lkwilkis Phyj it-MR) 1, IN jl9.W)L T'he ObtaAMAI I ~otvltllllx.~,j rott, th-il ~-Il-lltalc~l by ~ikji4ij 621 (!,)4q)', lba ;4 ihv JS 'q VE 0, P. USSR/.Iquclear- Physic a--- Photon-showers---- ---FD -1659- Card 1/1 Pub. 146-19/25 Author Isayev, P. S. V'E librium'I energy spectrum of shower photons Title qui Periodical Zhur. eksp. i teor. fiz. 28, 374-376, March 1955- "stract The author calculates the so-caUed equilibriumspectrum of photons which are formed in cascade electromagnetic processes taking into account not only radiative damping and pair production, but also ionization losses'and the Compton effect. He tbank S. Z. Belen'kiy, who guided this work, and L. Ya. Zhilltsova, who did the principal computation. Institution: Physics Institute im. P. N. Lebedev, Academy of Sciences USSR Submitted : July 24, 1954 4,; T r9lis. T~~ry a t6c AV-pirdile. S. luinv '29 ' No Zk , 44jer 1~oi (7): Ri MAKKov A N . . - . , , . . . 11-14 (1955i In ltus~fan: Ims o( equat ons is comi red of which, tba. lokmiteigmstatedcwtibes the pcotoik*. firstixcfted~ 11 ~:Stah~ the AVdrEkk.' -77' :7777 --- :01, -Ns~,-V S~ I)-AYEV, P3. SUBJECT USSR / PHYSICS CARD 1 / 2 PA - 1737 AUTHOR ISAEV,P.S., MUZIN,V.S. TITLE On a Rule observed'on the Occasion of the Decay of Unstable Particles. PERIODICAL furn.eksp.i teor.fiet Llt faso-4, 715-715 (1956) Issued: I / 1957 At present the following values of the masses of stable ana unstable par- ticles (the existence of which has been rigorously proved) are unanimounly recognized (in electron masses): m. M M r a 01 me a 11 me - 2071 m. 270 966 + 3; mp W 1836; MA a 2161 + 11 a - 2327 + 31 mr--, - 2585 15. Z T I-- Among the;e partioles,,^ , x, X, A and L-j are unstable. The values of decay energies which can be experimentally observed or are computed on the basis of known masses of partioles by means of the decay scheme are given be- Decay process: n Deca y process: n no -1, 2 135 3,8 K 7 -389 11,0 e + 2r 1o6 3t0 K + x + V, -246 "r, 0 + 34,5 Igo 0 p + 37POtItO 1,0 3w 75tO+l,5 211 n + it 111,0+3 3,1 K 27t 214 ; 5 6,0 -d~ Ao + 66 6 Zurn.eksp.i teor.fis,~1, fasc.4, 715-715 (1956) CARD 2 / 2 PA - 1737 For the quantity mentioned in the third line it applies that n - Q/q with q = 35,5 h1eV = 69t5 me' All values of n are very near whole numbers, with the exception of some cases in which decay furnishes~only stable particles (e.g. neutron, no). Thus, the energy liberated on the occasion of unstable particles is a multiple of 35,5 MeV. A drawing shows the experimentally observable scheme of the energy levels of hyperons. If the statements made here are correct, and if new unstable particles exist, they must be found among those mass numbers M which satisfy thexelation M - (m. p+M1 njq (in the ease of particles which are heavier than a proton), or M - n in n,q (for'mesons which are heavier than a pion). In these fo,rmulae n and n1 are whole numbers. It is interesting to note that the w2mb*r of electron masses contained in q is very near the value 1/2a - 68,5- This is a nearly verbal translation of this short report. INSTITUTION: gleatro-Physical Laboratory of the Academy of Science in the USSR. Moscow State University AUTHORS: Blank, V. Z.(Deceased), Isayev, P. S. 20-117-5L15/54 TITLEs Approximate Dispersion Relations for the SeatterinE of lNucleons on Nucleons (Priblizhennyye dispersionnyye sootnosheniya dlya ra~;stqaniya nuklonov na nuklonakh). PERIODICAL: Doklady All SSSR, 1957, Vol- 117, Nr 5, PP. 785 - 787 (USSE) ABSTHACTt Here the scattering of nucleons on nucleons is discussed in the absence of antinucleons, in which case the authors startfrom a dispersion relation determined in the usual way, which is given here. The amplitudes of the scattering of a nucleon on a nucleon are here linearly expressed by the amplitudes of the scattering of an antinucleon on a nucleon with positive energy. By this means the abovementioned dispersion relation links the amplitude of the nucleon-nucleon scattering and of the antinual6on scattering. This dispersion relation is then given in the approximation con- sidered here, This approximation is satisfactory in that energy range, where the amount of the integral is essentially deter- mined by the behaviour of the funotion within the integral, aign of the approximation relation. In the case of the nucleon-nuale6n scattering the identity of the particles must be taken into con- sideration. Besides, it is not sufficient to consider the ampli- tude f (0) of the scattering through a certain angle ~Q , biit~ Card 1/2 a linear combination of the type f (9) f 0 denoting the 20-117-5-15/54 Approximate Dispersion Relations for the Scattering of Nucleons On WdClWOO scattering angle in the center of mass system. Subsequently a dispersion relation is deduced and given, taking into considers- tion a further possible approximation. Th e experimental verifi- cation of just this relation is of great experimental interes't. The experimental data available at present on the total section a(k) and on the angular distribution permit to compute the inte- gral from the total cross section, and the value of D(k) obtained in this way can then be compared with the value measured~experi- mentally. This verificytion will solve the problem of the limits of applicability of the last mentioned dispersion relation. In the range_of very small energy (up to 6 LieV), where the scattering is satisfictorily described by a S-wave, the expansion k otg 6 a - -(l/a) + (1/2) rk2 may be used to verify the last mentioned dis- persion relation. The degree of accordance is given here. ASSOCIVIIONs United Institute for Nuclear Research (Obl'yedinennyy institut ya- dernykh issledovaniy) PRESENTEDs July 159 1957, by N.N. Bogolyubov, Academician SUBMITTED& June 28, 1957 Card 2/2 214.01 24(5) ipun z mot xazorrAwou 3or/3369 Too"yanowtys, mosbvusovskays konfer*ntalys Do kvIntovoy to*VL1 palsy I toorLI slo~tanykh chastits. Uzhgorod, 1958 Problow sovitowminol toortl alowentarn7kh chastitS. go. 21 Trudy Q-- kgotarMtsill... (Problems in the Mod*rn Theory or Sloventary PartLelso. Sr. 2: Transactions of the A21-Unlon Inter-Was Conference an the Quantum Field Theory and the Theory of, Wimsentary Partlc2oa) Uzhgorod, Zakarpatzkoye oblastuoye 1zd-vc, 1959. 214 9. 5,000 copies printed. Mccouts Vsob. W.1 A. Bolous. a Intended PWRYMI This book 1 far physicists, particularly tho4a soneerood with problems .in tile field of elementary p&rUclos And ths, quantum theory. OCTMOR; This book contains articles an elementary pLrtLolos GrIgInally read at the All-Valon Znter-V;Lz Conference hO1d at _1104 State University an Octooor 26, 1958. Among the topics dliiimi"d iroi-- fusion ~tb~scjy, ---- L' Zdr6ftt9 contractions. parity studies, nuO140n-nucZeca scattering, 7 *to. onglish abstracts Accoapany each article. References 329M each artlal*._ 9L-T. A.S. Polarization or Quanta-MaLttoil by A M�2M1Mt=x M amebank", V.S. , Optio&L AnaLysis of the Xntorectlaw Between .-Y"t Nucleons! and P1048 Particle~ ftth Joualooi3s and Nucleus 142 jbA4*zv, O.P. The Sad-ftenon*WlcgLc&l Th~cr7 or Nuclear 149 and 3-or-au- Partial wave Analysis of Mo 157 -Umeration -of Partioles ZUM&g,-&.G_ and amot of the Porm-Pastor as tbo ?"Go"Of *bA=hZ1'" Generation of FaLro am frotome 165 nunwaa- V 4. On the Interaction notweenA -partial" a" Melon" in UM Xrpor.n1!!lo1 IT5 IdmIdge, Tktx. The I-s-tion or the 182 ZOM"2g. ju.n.. V..Z. sewl ki I The of 5"ttorInt Jr-M& Roglons, 295 Probles Kr1vsk17' Loor"so, Tu.x.. '-To. Mmlcn. L' B.S. V MILt. $4-?.rtrbtL.M KOtfiR to the eft Lon cr"TzA-%'Zrf1 Interpretation of the Su*1von-Rucloon Scatterings 912 .'r AUTHORS: Zlatev, I., Isayev, P. S. SOV/56-35-1-58,/59 The Bremsstrahlun~ TITLE: g an ~e FaiF Production on Protons Taking Ipto Accovmt the Form Factor (Tormoznoye izlucheni3-e i rozhdeniye par na protonakh a uchetom form-faktora) PERIODICAL: Zhurnal eksoerimentallnoy i teoreticheskoy fiziki, 1958V Vol-35, NT 1s PP. 309 - 310 (USSR) ABSTRACT: Prom a modern point of view, a nucleon is a "nucleus" which is surrounded by a cloud of virtual mesons. The distributions of the electric charges and of the magnetic moment of the nucleons rere investigated thoroughly in Hofstadter's (Khof3htadter) experimentq on the scatter'i-ng of electrons on protons and neutrons. It is therefore interesting, to investigate the influence of the form factor on processes like bremsstrahlung or pair production on nucleons. The aulhors calculated these processes for the special case of protons in the lowest approximation of the perturbation theory (in the third order with respect to e). The graphs taken into account are shown in a figure. Also the "meson fur" will give an additional contribution Card 1/3 to the cross section of these processes. But taking The Bremsstrahlung and the Pair Production on Protons SOV1156-35-1-58/55 in Consideration of the Form Factor account of this contribution is rather complicated and therefore only some comments on it are given in this paper. The exact formulae are rather complicated and -therefore are, not given in this paper. When the proton mass tends to infinity, these formulae are changed to the correspnnding formulae of Bethe (Bete)-Heitler (Gaytler) for the brems- strahlung and pair production. Deviations from these for- mulae will be observed only in t~.e region of large scattering angles or in the region of e.xtremely high energies of the incident electron (1~500 MeV). This leads to the following' conclusion: A difference between the Bethe (Bete)-Heitler (Gaytler) formula will be an argument in favor of the in- fluence of the recoil and of the form factor on the cross section of the investigated process, and also in favor of the possible existence of an additional cont:ribution of the "meson fur" of the nucleon on the cross section. In order to illustrate these -ionsiderations, numerical results are given in a table. The above mentioned differenct, has noticeable values (,j 15 0146) even for relatively small Card 2/3 angles (300) and this fact is an argument in favor of a Ji#N The Bremsstrahlung and the Pair Production on Protons SOV/56-35-1-58/519 ih Consideration of the Form Factor noticeable contribution of the "meson fur" to the cross section of the bremsstrahlung. Further calculations will solve this problem in a more definite way.' The authors thank A.A.Logunov and A.N.Takhvelidze for useful discussions of these results.. There are 1-figure, 1 table, and 4 references, I of which is Soviet. ASSOCIATION: Obl'yedinennyy inatitut yadernykh issledoyaniy (United In- stitute for Nuclear Research) SUBMITTED: April 23, 1958 Card 3/3 AUTHORS: Zlatev, I. S., Isayev, P. S- SOV/56-37-3-21/62 -Q TITLE: Dispersion Relations for the Virtual Compton Effect PERIODICAL: Zhurnal eksperime t reticheskoy fi?,iki, n allnoy i teo 19591 Vol 37* Nr 3(9), PP 728-734 (USSR) ABSTRACT- In the present paper the dispersion relations for the vi.rtual Compton effect in the lowest approximation with respect .,tole, are derived by the method of N. It. Bogolyubov. V. So Vladimi- he rov and A. A. Logunov (Ref 3) furnished a proof for t:'-. bremastrahlung and for the pair formation, and for this reason the authors concentrated on the definition of dispersion relations which are suited for practical use. The authorB demonstrate that the cross sections of the processes in-gingle- nucleon approximation agree with.those cross,sections which were-computed in the lowest approximation of-the perturbation theory. In this case the method of dispersionrelations per- mits the.strict introduction of the formfactor (of them 11of- stadter type) into the nucleon vertices of the Peynma~n.' diagrams which are in connection with the virtual Photo n : line. This is one of the essential advantages which have, Card 113 dispersion relations over the perturbation theory. The re sultant, Dispersion Relations for the Virtual Compton Effect SOV/56-37-3-2116'4! dispersion relations are suited at least for'.the estimation of the conti7ibut3.on of the single-pion state to the proc .eases investigated. By taking into account the single-pion state an important extension of the energy range in the examination.' of quantum electrodynamics at small distances may be attained. The quantum electrodynamics for bremsstrahlung at an energy of --550 Mev of the incident electron and an energy of *,,,2'60 h1ev of the emitted photon may be examined up to distances of', 3.10-,4 cm. The individual parts of the present paperAe.U with the following; dispersion relations for the amplitud,a of the virtual Compton effect, structure of the amplitude,6f bremsstrahlung, dispersion relations for the Lorentz.inv~axia'nt coefficient, dispersion relations for the phy .sical amplitudes in the center-of-mass system. By means of.the d1spersion relations, form factors depending rigorously on a varia~blo may be introduced into the process of bremsstrahlung ands pair formation. These form factors have lalready been deduced by R. Hofstadter for the negative values of the argument (Ref 11). There are 2 figures and 14 references, 8 of whic;h Card 2/3 are Soviet.