SCIENTIFIC ABSTRACT -

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000618620018-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 10, 2001
• Sequence Number: 18
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

MM/Chemiatry - Hydrocarbon oxidation
CaVd 1/1 t Pub. 147 - 4/21
Authors t loffe 1. 1.- Levin, Ya.' S- Sbkpl, qva Zo Vqi:ruront~.bij. 1. G.; 04d
Title C Study of the kin.'etics, aiA michknia of vapiar-4phasOl thewoletf~
oxidation of benzene 'Yxith mold on
Oular oxyg
Zhur. fiz. khim, 8~ 1384-wlj%v: Auk' 1954,
Abstract The kinetics of benzeTI4:,:ioiadaii4~-i4thlmoi,06 nslitre`14,ga
at high hydr n~entra~ipi'-and ~~ IA
pearbon cc 4 rM 4i
and pressures. It was found that thG klneitiO: of ~A"~ion "Mictlon
corresponds to the kinstlos,'ofi a degenerated oxplo~lom. The roUtion
between the rate of reaction, benzene:o.Vgen ratio anA partiikl 0-
pressure, was established. - The inhibiting efNct of the qmistz s~r-
face on the volmetric, reae'UoO ot benzeneoMidatlodif is dis;*ssed.
Six references: 2-USSR and 4-Fri?,lish (19294950).; Tables; #apha
drawings.
Institution The K. E. Voroshilov 54'entific Re s2earcih trt~ tut~4 Or,an
Products and Dyes
.Submitted t July 3, 1953

- -- - -I - --.

ussa/chamiitry Oxidation
Card 1/1 j
'Author Iofre, I.- I.
Title Chain. oxidation of phenol,:
Periodical, Zhur Fiz..Khim., 28, Edi:5,.772 7,74, ~!ay.1954
--Abstract.- ~The reaction of vartior-i-Ohase. ihermal oxidation of..- ien9. Wad Invest tic d
r.0 .,,,a I-
at~-610,-63 0--an" -GthnO q-Gf-
jt.P4-.0 4-a
sta The A~.ektloni -J~
-7 Its
3 ales qr
spbnds to the equation of V. ~N 3 6h' n iiila .~Ion'I
:Jemonov: rii 0
proa if
the quartz surface, whieh.inhibits the 'Volt -metric qhaij. a. eatalyt la' q'ur-
hail
face reaction leading to ccflii'lete '6xidation is ~Iai:t T re atmf nt f
-ice wiUi I
th6 surfa iydrogen fluoridt- ~ve u 5 .11 t s1 ling, a r the
Ho
lyticaDy active surface 'centers, And
the rate of reaction is chanred. Five referfmc~i~n
3 n
t -1906, L-nO-orm-4n
t-A tm n since mf. .Tab1e,,L-ra-hs.! U7
:.Institution The K, E. Voroihilov. Instituto of C ~r pa n i c
-~ubmibted Aj>r11 10, 11953-

. i
I
- jh!- : .~ 4!..- .. - -, ..4 .. '.. - 4 ..
. .1 1: . I

w,

4. 1 ;,1,: q1 hf-t",C-nw-Alfl -zillatinn or E .41 1
z - ... -:.. ~ , ~ W J,

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. - I . 1. 1 .,
. . I I
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I - -V
N.- Tj IK C.
USSM/Chemistry Oxidation
Card 1/1 TO, 147 3/27,
~-Authors -:-Tof f6 1. 1$

Title lets rIzene
-The. mechanism.of. incompL oxidation 0 be

-Perlocac,41
Zhur.~fiz* kiAm. .29/9 5456ii seo 1954
155!
:Abstract .of ~t,~~6na
The mchanism Of ia'por--ph&-se";,dx1da~,idn
,
of phenol and found W be based,on the chain chair
cess participated by the.p1mrjv1:ar4 . pa ai
r
=
maernitude of'the activation energy .nee
r
oe
peroxide radical was established, ;The 'mechanism'
:
sion during the process or vapor-phA:se 6xidatloa
.
Equations e---pressing the rate of ph
6nol and diphe
of phenol donversion are included.~ Six refeirenoe
is
jHuo-~im-z-t
jn4 Dyesp!
Ition
1046i i pro
1C the,
I
cm+er-
iqtib4d.
11 the Irate
rUshland
~k

USSR/Chamistry,_ Physical -chJudstr7
6rd Pub 147 -3/27

A~thors -9~ .1of& ~X nj 'Y
p LO and Sherma 'ize

Title t _Stu4y_of -the-kinetics, and 'me6hanismi. 0 r' - ~81 'ox1 ion:of a0
104
,
alati
o. -
Of ~rl ver a
0
)**"-arbon9,il -Part, 5. Kinetics of~~ ion:; j:ddl
vanadium catalyst
Periodical Zhur-* fir.. khim. 26/22
269~~
#
,
'
Abstract t The Otut of , rAphthaUn'.o4d&t1612_'~i4i~toq Ath r I
lk
s
~
potassium-sulftte catai*st; wa's (vonducte'd with I i .
ro h1i6&3jqiO1
resultant reaction producte
4 a ial 180thermou iieth d:deivelopd4
ped a t1
bri lo
this
l,1
. ~ I i
I
investigation is described. Formula determining t 4 rai 6 ~:of' reaetW
.
'
ir4 oi
l
naphthalin oxidation is
included.. It was establis
d th ii. A100 Wi ' the
reaction.is shifted into the internal-diff0ion:1
ture limit of this transition increases with
t6i or 9 Wthe I sic !
,
concentration of the raphthalin.. The rate or: ion; the MW
'
~
1
1
:
of the catalyst,, whieb isrege rat
ng rda?.% on t h Marlhtfi
ne ad duri i
~
4
1 .
1
;
'
insider t
molecules, and the desorption of reaction prodw 't il ar VAO
-determinant factors of the oxidation process. Firt refO;r~nr-*ed:j 31 0SR ;and' -
2 tISA-(1935-1952). Tables; graphs; Arawingsol
Institutions The Ko Be Vorcehilov Scientific Researc*h' InAitut f ftaw~
"0 a~ l UA

Submitted t December 11
1953

OP
I
9c
. " - - - -,; -, I ~ . ~ :. I'l--, , - !I
-t'. mqi " - . I A ~:j I.il; -1 -
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, - 1: .1 .. t I :! I I : ~j . , . I . I

AUTHORSt Malyshevt A. I.t Ioffej I. 1. 75-13-3.-25/21
,TITLE: Potentiometrio Titration of Benzoquinone in a italeic Acid
Solution
(Potentsiometricheakoye titrovaniye,benzokhinons v rastvore
maleinovoy kisloty)
PERIODICALs Zhurnal analiticheskoy khimii, 195001! Vol 13t Nr '3'
pp, 374-375 (USSR)
ABSTRACTs In the catalytic oxidation of benzene with vanadium,cata-
lysts benzoquinone (Reference 1), the, qua:utitative'deter-
mination of which in of interest fortheJ10ontrol of1he'
production of maleic acid, also forms beside maleio.'aoid,
I
'
the chief product of the reaction.
R':zymkow
ski (Rzhimkovs'kiy)
(Reference 2) had worked out a metho4~for;the deteriination
of benzoquinone by which the authors of the present papirp
however, did not obtain any positiveresuits. For i!~he po-
tentiometrio titration of the dark-dolore
a solutioiw for-
,
ming in the oxidation the authors employed the usual io6i -
metric method for the determination of bepzoquinono~(Re~-
Card 1/3 ference 3). Benzoquinone reacts with'potassium. iodide itt

Potentiometric Titration of Benzoquinone in a Maloic 75-13-345/21
Acid Solution
Card 2/3
arf acid solution under formation of~free'iodine and1ydko-
quinone. The liberated iodine was potentiometrically titra-
ted with thiosulfate# a diatinctly.marked potential4rop
occurring on this occasion. The results ihow a good4gree-
ment. The whole determination only..iants,several minutesp
As a compensation scheme in the yotentiom~otrio titra'tion
possesses a higher reliability (Refe':;enoe~4), a poii4nti6-
meter of tYP8 LP-5 was used. The,redox potential iWas
measured by a platinum electrode wl~6, reference toga satu-..
0 i~e in
rated calomel electrode At a content of benzoquin(s.
the order of magnitude,of OtOO05 mdl:the '*:~ror of this
determination does not exceed 3% r6iiativoly).,The~d,etei-
minations were performed at 20-50~0-~i Mfof a 011it thio-
sulfate solution corresponds to 0,0054 g;benzoquin6he. ~
Formaldehyde exerts no influence upola the!: determinei't'lon,
of benzoquinone. I direct potentiom6tric iitr'ation~o .f
benzoquinone with thiosulfate is not'to be recom:mezId:,ed
in the case under review.
There are 1 figure, I tab15 and 6 references, 6 of which
are Soviet.

Potentiometric Titration of Benzoquinone in a Maleic', 75-13-3-2-5/27
Acid Solution
ISSOCIATIONi Nauchno - iesledovatelvakiy inetitut organicheskWi polu.-
,produktov i krasiteley im. X. Ye.joroshilovat gDekva;
(Moscow Scientific Research Institute for OrganioJnt4r-
mediate Products and Dyes imeni K'.: Ye.,Voroshilov~)
SUBMITTED: April 9, 1957
Benzoquinone-Determination 2. Mdleic~ a,cid-ChenxLeal
analysis
Card 3/3

2d-1-6-4-34/61
AUTHORS: Ioffe, 1. 1.9 Vollkenshteyng F. F.
TITLE: The Trend of Contact Oxydation Reacti 0-n8 on
Semiconducting Catalysts (Benzene Oxydation Serving as
an Example)
(K voprosu o napravienii reaktaii kontaktnoga' okisleniya
na polu rovodnikovykh katalizatorakh (na. primers okisteniya
benzola
PERIODICAL: Doklady Akademii Nauk SSSR, 1958, Vol. 118,,Br 4,
pp. 747-750 (USSR)
ABSTRACT: The authors here examine the phenomens''Mentioned in the
title, from the aspect of the theory of catalysis, which
was developed by r. F. Vollkenshteyn (Tefer4nce 5,6,7).
Convenient objects for the investigation of the mechanism
of the process are the simplest aromatic compounds
(benzene, naphtalene), because at them sharply marked
trends in the heterogeneous-catalytic and homogeneous
reactions are observed. The authors suppose that it is
possible to make various assumptions on the possible
Card 1A mechanism of the oxydation of benzene.on electron-

The Trend of Contact Oxydation Reactions on Semicondacting 20-118-4-34/61
Catalysts (Benzene Oxydation Serving as an Example)
Card 2/4
semiconductors and Hole-semioonductors (e.g..Yanadium
pentoxide and ouprio oxide, or ouprous, oxide). Uere, thii
authors proceed from the assumption thAt in case of th,e
adsorption of benzene one of the bindings in ihe,ben:,ene
molecule is ruptured and that the valence which has beooms
free in this way is saturated by the free valence of the
catalyst. Here are two and only two possibilities: In*oas~
of the adsorption of the benzene molecule either a
C-H-binding or a C-C-binding can be ruptured. As adsorber
here a crystal of the type M R is examined (M denoting
m r
a metal and R a metalloid)t which is regarded to be 'built
up of the ions M+P and R-q (pm - rq)-~Most of the semicon-
ductors used as catalyst*-(oxides, sulfides) may hayB':a
lattice of this type. First the adsorptionAs investigated
here, in the case of which a C-H-bindtng is ruptured,~In
this case the adsorption leads to the,dissociation o:f:the
benzene molecule into 2 ions, as is illustrated here
schematically. This mechanism is possible in case of~ electron-
semiconductors and also of hole-semiconductors. The

The Trend of Contact Oxydation Reactions on Semiconducting 20_11$444/0
Catalysts (Benzene Oxydqtion Serving as an Example)
difference between these types of semiconductors becomes
noticeable in case of the interaction of the compounds
which form on the surface, with the vagrant(bluzhdatl~
free valences of the catalyst. Th-as the electrically
neutral radical which is located on the surface, forms
on the hole semiconductors, whereas it,practioalli cannot
form on electron semiconductors. Then the adsorption of a
benzene molecule with the rupture of a C-C-binding is in-
vestigated. Also here the process of adsorption leads to
the production of a positive and of a negative valence on
the surface of the catalystp whereon the netative valence
(hole) remains free and the positive valence (electron)
combines with the benzene molecule, retains it on the
surface, and transforms it into an eleatrically charge 'd
radical. Such an ion radical, which is located on the
surface, practically forms only on electron semiconductors,
but on hole semiconductors. The here examined hypothetical
mechanism is very much achematized, it only:shows the way*
to the understanding of the action of semiconducting
Card 3/4 catalysts in the oxydation benzene.

The Trend of Contact Oxydation Reactions on Semiconducting 20-116-4-34/61
Catalysts (Benzene Oxydation Serving as an Example)
There are 7 figures, and 15 references, 11 of which area
Soviet
ASSOCIATION: Nauchno-issledovatel'skiy institut organioheskikh
oluproduktov i krasiteley im. Voroehilova
cientific Research Institute for Organic SemiproductB
N
and byes imeni Voroshilov)
Institut fizicheskoy khimii Akademii nauk SSSR
(Institute for Physical Chemistry of the kS'USSR)
PRESENTED: July 8, 1957, by P. A. Rebinder, Member, Academy of
Sciences USSR
SUBMITTED: April 24, 1957
AVAILABLE: Library of Congress
Card 4/4

10(2)95(4)
AUTHORSz -_IoffeL I. I.1 Grigorov, A. P. SOV/64-59-3-13/24
TITLEs On the Theory of the Reaction Rate in a Pseuido-liquid~Catalyet
Layer (K teorii skorostey reaktsiy v ps'evdoqzhizhennom'81o-e
katalizatora)
PERIODICAL: Xhimicheskaya promyshlennostf, 1959, Nr 3f ~p 57-64 (USSR),
ABSTRACT: Although the application of.paeudo-liquid catalyst IaVOrs
offers advantages, it may on the other.1hand cause a reduction
of the catalyst (C) capacity e reduce the reactioWrat6 or

change the selectivity of (C~ I tiols of proc6ss6s:with
Investiga n
(PCI)iefs 1-4, 12, 22) which took place recently, mainly dealt
with particular questions. Some general properties therefore
are examined in the present paper, The~suppqsition that:the
application of a (PC) eliminates the influence of the diffusion,
is often found in publications 9 but it :is wrong. An inhibiUon
of the reaction by means of an outside diffiision is oax~sed:by
the fact that the diffusion in the (PC) is vegulatedby the
proportion of the gas permeating the layer in the f orb of little
"bubbles", by the linear dimensions of'these bubbles and by the
diffusion conditions of the gas in the bubbles. An ex4mple of
Card1/3 the contact oxidation of naphlbalene into pbtlialic acid by, means

On the Theory of the Reaction Rate in a SOV/64-59-3-;13/24
Pseudo-liquid Catalyst Layer
of the air served for constructing a diagram.on the influence
of the di Spereity of (C) on.the reaction(A. 1. Tiahcheinko
collaborated)(Fig 1). Two equations (3)~~and (4) are derIved
which explain the course of the reaction in the POI as well
as some forecasts regarding the reaction rate (RR.). Them
application of a "compressed" (PC), i.e. of a, net on the. (PC),
proved useful in the naphtbELlene oxidation mentioned above
(Fig 2). An increase in the density of the o4talyst pst:r,ticles
accelerates the reaction taking place in the:diffusion area.
One of the linear dimensions (the height) of the gas Ilubbles
mentioned above, is proportional to the distance of the.
distribution grid, so that an approximate valuation can be
carried out with regard to the influence of the height of the
(C) layer on the RR. An example shows that an increasobf the
height of the (C) layer reduces not only it&activityj~ buts
also the selectivity of the (C). In accordance with piLblication
data (Ref 21) it was found that a mechanica1mixture of the gas
Card 2/3

Qn the Theory of the Reaction Rate in a BOV/64-59-3-1.3/24
Pseudo-liquid Catalyst Layer
with the moving (0) partioles plays a much smaller r8le~than.
the sorption-deeorption mechanism. Two bd~rdep~.-Jine caseil'of
the adsorption-desorption mixture are explain6dt and I
considerations are given on the activity~,of th;e M. Thore are
2 figuresp 1 table, and 35 references, 13,of ir.bich are 36viet.
ASSOCIATION: Nauchno-isoledova.tellskiy institut organicheskikh poluproduktov
i krasiteley, HIOPiK (scientific Research Institute for'
Organic Semiproduots and Dyestuffs, NIOPiX)

5.3400 77289
SOV/63-4-6-23/37
AUTHORS: loffe, I. I., Klimova, N. V., Brodskiy., M. S.

TITLEt . ............,
Brief Communications. The Catalytic Oxidation Of
Acetophenone Into Benzoic Acid
PERIODICAL: Khimicheskaya nauka i promyshlennost', 1959, Vol 4,1Nr 61
PP 799-800 (USSR)
ABSTRACT: The solid acetophenone from phenol-acetone plants is,:now;
used as fuel, in the form of phenolic tar. For the
preparation of benzoic acid, the above acetophenone wasi
catalytically oxidized both in vapor and in liquid phases.
In the vapor phase, oxidation was carried out with air I
oxygen over a mixture of Va and Mo oxides, tin vanadate,-
supported on siliga gel and chamotte; molar ratio of~
acetophenone-air :30, 1:60, between 200 and 3000.
Benzoic acid .(32%~, maleic acid, and C02 were identified.
'
ied out with air
In the liquid phase, oxidation was carr
and with pure oxygen, at normal pressure, over Mn, Co,
Card 1/2 Cu resinates and striarates. The best reuits were

Brief Communications. The Catalytic
Oxidation of Acetophenone Into
Benzoic Acid
77289
SOV/63-4-6-23/37
obtained by using Mn resinate as catalyst. The optimal
conditions were: 1569, rate of oxygen 5.1/min, the rat 'io
catalyst-acetophenone 2 g:1 g/mole. Tho conversion was
60-65% and the yield 70-75%. Benzoic acid, formic
acid, formaldehyde, maleic acid, and CO' were identified.
2
Purified acetophenone was used in both cases (98.5-99%'
pure). Technical aeptophenone inhibited the oxfdation~
The method of separation of benzoic acid.from the rea.'
tion products was a preliminary distillation:of recovered,
acetophenone, follaw~d by extraction of benzoic acid
with hot water. After recrystallization, the' benzoic
acid has mp 1220 and 99.5% concentration. The yield by
the above process was 8396. There are 4 figures; and 3
references, 2 Soviet, 1 U.S. The U.S. reference is:
H. AigRiley, A. B. Gray, Org. Synthesis,,15, Nr 9,
67 35).
ASSOCIATION: Voroshilov Scientific-Research Institute of ajes and Inter;-
mediates (Naurhno-issiedovatellskiy institut poluprodt&tov'
i krasiteley imeni K. Ye. Voroshilova)
SUBMITTED: April 29, 1959 Card 2/2

5(4) SOV176-33-4-18132
AUTHORd: Ioffe, I. I., Levin, Ya. S. Kronicb, 1. G..
TITLE: Investigations n the Field of the Kine0ce and the Mechanism of
the Vapor Phase Oxidation.of Aromatic 'Pydr6carbons (10;01640-
vaniya v oblasti kinetiki i mekhanizma arof Iaznogo okisleniya
aromaticheskikh uglevodorodov). VII. The Effect of Witter Vapor
on the Thermal Oxidation of Benzene '*41- Molecular Ox.1rgen
(VII. Vliyaniye vodyanogo para na termicheakoye okisloiye
benzola molakulyarnym kislorodom)
PERIODICAL: Zhurnal fizicheakoy khimii01959t Vol 33p TTr*4,PP 863-16a (035R)
ABSTRACT: The investigations of benzene oxidation'with an oxygeft~wat
pr
.
vapor mixture were carried out in. an apparalum and accbrdi,~ig
to the method of the work reported in:reference 2. The watar
vapor (WV) was introduced into the qna:vtz reaotor (Volu~me 'of
50 or 100 ml) by an automatical3yoperating porti Ioner. In order
to examine the specific influence exerained:by Nv) ;arallel
investigations were carried out with oxygen~nitrogen m ixtures
(Table 1). It was found that in the mix'turoB vith (WT);(u~der
the same conditions) a phenol (I) yield whi6h is by 26.4, high-
er is obtained. With rising tomperatura the yield in (1) is
reduced (with and without,(WV), Table 2). 4 ";n increase~of the
Card 1/2 reactor volume gives the same yield of (1) at the same dej;ree

SOT/76-33--4-18/32
Investigations in the Field of the Kinetics and thelgechaniiim of the,Vapor
Phase Oxidation of Aromatic Hydrocarbons. VIZ. The Effect ol' Water Vapor,
on the Thermal Oxidation of Benzene Ifo.lecular Ovigen
of conversion of benzene at a simultaneous temperature decrease,
and a prolonged reaction time (Table 3)o The reduction of the
ratio benzene/oxygen in the reaction mixture:leads to an~ GX-
tension of the process of complete combustion (Table 4) *An
increase of the relative amount of the (WV) added leadsto
the eneral conversion of benzene ang imarea3es the yield in
(I) ~Table 5 for experiments at 725 in a 50 uil reactor).
The positive influence exercised by ('37V) on tho yield ini (1)
is explained from a point of view already described by way
of benzene oxidation (Ref 4). There are 1 figure, 5 tablesp
and 4 references, 3 of which are Soviet.
ASSOCIATION: Institut organicheskikh poluproduktov iikrasiteley im. K. Ye.
Voroshilova (Institute of Organic Semi-Products and Dyes
imeni K. Yeo Voroshilov)
SUBMITTED: September 25, 1957
Card 2/2

4 r.
It , 1, ~ ! - I I r
lap
0: it IF
PHN
.1
fL~ xF
r
H . I V; --, I fi
it 111 n
1 1; 11 ; I Ir
14 it 14
all
a Eli
IOU

IOM,__ ~--, MIKOLLUT, Yu. T-, BRODSKIY, M- S-
Liquid-ph4ae contact-catalytiC oxidation of organict c.oppounds
on noble meWs. Part 1: Oad4atlon of phenovithanol into
phenoVacet iC acid Kin. .1 kat. 1 no. 1: 125-126 XT40 .160.
WRL 1310)
1. Ilauchno-Insledovatel'skly inatitut organic~ssklkh polupro-
duktov i kraniteley in. X-Ye. Vorpshilova, MoAva.
(Platinum) (Acetic acid) (ithawl)

B/064/60/000./004/0'10/021/XX
BO13/Bo69
AUTHORS: Ioffe' I. I.V Pialmen, L. M.
NORM
TITLE., Statistical Analytical Method of the Maorokinetics of
Processes in the Pseudoliquid Layer of a Catalyst
PERIODICAL: Xhimicheskaya promyshlennost 1, 1960, No- 4, pp. 23-29
TEXT: A statistical method of analyzing the processes taking place in
the pseudoliquid layer of a catalyst is described here. The method is
based upon a study of the distribution function of the time the gas
stays in the layer. The authors wanted to clarify the'causies of the
specific inhibition of the reaction in the pseudoliqu,Ld layer, and to.
identify the quantitative characteristics of the process t 'aking place
therein. A two-phase model, similar to that of Refs-3 andA, and
consisting of a gaseous and a pseudoliquid phase, was chosen, for the
analysis of the pseudoliquid layer. The generalized hydrodynamic
characteristics of the system - the distribution function of the time of
stay in the layer - which Is of decisive importance for the investigation
Card 1/4

Statistical Analytical Method of the
Macrokinetics of Processes in the
Paeudoliquid Layer of a Catalyst
9/064/60/000/004/010/021/XX
B013/Bo69
of the paeudoliquid layers can be expressed by the parametera h and 0
h denotes the rate constant of mass exchange between the pha'ses; OJ is ~the
fraction of gas bubbling through. These parameters can be calculated
on the basis of experimental data from formulas (24), (25), and (28):
-1
ol (t IA t . S exp (- hV/ &j v) (24) ; 01 (t2) A5 exp [- hT[/(I_W)Vj :(25);
CIO
1 S (t)dt = SO/S (28). o - concentration'; index 1 - croIas
section of ou~t!let; S - area under the outlet ourvel t - chart time;
v - volume rate of the current; V - volume of the layerl d - diameter
of the apparatus; S' - area bounded by curves SZ (t) a~nd ol(t). The
method concerned was tested with the system shown in Fig. 2. The
concentration of the passing gas was measured on its iaBcapO: -from the
system by means of radioionization. Helium was used for the purpose. The
air consumption was measured with a coupled diaphragm, Tho'circuit of
the system was worked out in a way as to ensure the synchronization of
the pulse emission with the taking of the oscillogram. The distribution
Card 2/4

Statistical Analytical Method of the 8/064 60/000/004/010/021/XX~
Maorokinetice of Processes in the 3013, BOW
Pseudoliquid Layer of a Catalyst
0
functions for an empty volume, for an Ammobiles and a poi eudoliquid layer
were determined with an average particle size of 190g. Tho distribution
functions were estimated from the "degree of Qomp~otness 1"..Experimentall..
data allowed the following conolusionsi 1) As ixpeated 1~ the immobile';
layer approache,s the conditions of an ideal displacement; 2) turbulent
washing in an empty volume is considerable; 3) gas!mixing in a short
pseudoliquid layer ai low linear velocities is lose appreciable 'th~wi in
an immobile layer; 4) the "degree pf compactness" of the distribution!
function drops sharply with an,increaso of the suspended layer. This ~aotll
cannot be explained by a single-phase model. h and.w are calculated for
the pseudoliquid layerat a height-to-diameter,ratio 02:304. The
theoretical conclusions and the correctness of the.chooon. model were
confirmed. Prooeeding from a two-phase model, the prooe,be:oan be
calculated from ordinary differential equations of the niaterial bal:ance,
vhich are written for every individual phase. Using h andW it is
possible.to set up a dimensionless criterion which embracas the
hydrodynamic and kinetic factors, and oharaoterizea the:porformano'* of
3/4.
Card

'Statistical'Analytical Method o;f the S1064 6016001004101010~11XX:
Macrokinetics of Processes in the B013YB0691~
Pseudoliquid Layer of a Catalyst
the system as well as the range of the reaction owirse:*
CP - h(l Q cal- rfatel-
)/kId W.11 denotes the rate constant of the chemi su
reaction'; cr is the specific surface.of the catalyst. There are 7 figu.;es,
1 table, and 8 references: 4 Soviet and 3 US.
Legend to Fig. 2: 1: oil separat#j,
!2-. receiveri 3: courxte:~; 4; coupliad
diaphragm; 5: mercury pressure ga,ugel
'17 1/4 6: regulatorl 7:, column;: 8:, ioniz61t.ion
chamberl 9: rotam1plerl.10:-cocki
11: volume; 12: motor
A7 vithreduot~ion
e gaug,~ j.
gearl 13: diaphragm pressur
14: gas,'container~
Card 4/4

I.I.; PISIM, L.H.
Statistical method for anQrxlng the morokinatice of
processes &rising in the fluidised bect of a Catalyst*
Xhim.prom" no.4:287-293 is 160. (Kft 1318)
Oatalyois)' (nuidization)

IOFFE,-LI4- DOBROVOL ISKIYj S.V. I LEVIN) Ya*S,; GRIM RX;
KAMBULOVAP V.A.; KRONICH, I.G.1 SbKOLOVA, Ye.V.
Similarltr of reactions. catalyzed by liquid and aolid 6c4p.,
Probl. ki~.-'i kat. 10:294-297 160. NML 1415)
1, Nauchno-issledovatel'okiy institut orgunicheakikh pqlu~roduktorv
krasiteleyo
(Acido) (Napht"hylamize) (KAPM01),

IOFF EVIN, Ya * S.
Manufacturing phenols by the direct oxidation of benzeme. Org.:
poluprod. i kras. no.2:88-117 61. (MIRA 14: 11)
(Phenols) (Benzene)

I.I.; GRIGOROV, A.F.; RUb[LWSFV, R.P.; IVANOVA, E.T.
Effect of macrokinatic factors on the oxidation rate of naphthalene
In a fluidized cata4pt bed. XbIm* Pro=- n0-,41258-24 Ap 161,
(KM 34:4)
tNaphthalene)

Ill.; NIKOLAYEV., Yu.T.
Liquid phase cattact-catalytic o;ddation of organic:compounds on
noble metals. On, i kate 2 no*2:245-246 Mr4p 161, :(MIRA 14:6)
Hauchno-isoledovatellakiy institut organicbmakikh poluproduktov
i krasiteley imeni K Ye, Voroohilova.
?Acetic acid) (Ethers)
(Oxidation)

M.V.) GILLER.
Kinetics of the vapor-phase contract, oxidation of furfurolo,
I
Kin* i kat. 2 no&2:25Z-257 Mr-AP 161. (MIU 14:6)
1. Institut organicheskogo sinteza AN Iatviyekoy SSR, Riga i
Nauchno-ionledovatellskiy institut organicheBkikh poluproduktov
i kraoiteley imeni Ka Yea Voroshilova.
(Furaldehyde) (Oxidation)

M. L.M.;~_IOFFE, --I.. I.-
Reaction kinetics of flow systems. Kin,i kat. 2 noo.4:606-621
Jl-Ag 161. OaU 14 10)
I., Nauchno-iaoledovatellskiy institut organicheskM poluproduktoy
i krasiteley imeni K.Ye.Voroobilova.
(Hydrodynamice) (SpU= (Chemistry))

---KAMSKIY, V.BG-; KOVA, Z.I.; LYUBARSKIY, A.G.; VOYL-VODSKIY, V.V.;
IOFFB I I
Electron paramagnetic resonance study of the structure of
~6%862-866
vanadium-molybden= oxide catalysts, Kin.i.kat,,2 noi
N-D 161. (MIRA 34:12)
1. Institut khimicheoXoy Miki AN SSSR i Instit-ut orguniobeskM
poluproduktov i krasiteley imeni I.Ye. Voroshilova*
(Catalysts--Spectra)

2821
J/
S/076/6 035/010/012/015,
B106/BVO
AUTHORSt Ioffe, 1. 1., Yezhkova, Z. I., Lyubarskiy, A. Go (Moscow)
TITLE: Catalytic activity of mixed vanadium oxide catalysts in
vapor phase oxidation of organic compounds
PERIODICALt Zhurnal fizicheskoy khimii, v. 35, no. ;io, 1961, 2348 2351
TEXTt The authors studied the catalytic activity otvanadium oxide,
molybdenum oxide, and vanadium oxide - chromium oxide catalysts in the
vapor phase oxidation of benzene and that of vanadium oxide, molybdenum
oxide, titanium oxidev phosphorus oxide catalysts in the vapor phase,
oxidation of furfural to maleic anhydride. The authors tempted to clarify
the mechanism of the activating effect of oxide additions,of other e,le-.
ments on the catalytic activity of vanadium pentoxide. The catalyst's for
furfural oxidation were produced by aspirant V. A. Slavinskaya (In-t
organicheskogo sinteza AN Latv. SSR (Institute of Organic~Synthesis of the
Academy of Sciences Latviyskaya SSR)). The catalysts wers analyzed by
X-ray diffraction, moreover, catalytic activity and selectivity of the
catalysts were determined in continuously circulating and in continuous
Card 1/4

28293
S/076/61/035/010/012/015~
Catalytic activity of ... B106/B110
flow plants. The authors thank V. V. Voyevodskiy and V.~.B. Kazanskiy for
taking the epr spectra for part.of the catalysts. The X- *ray diffraction
phase analyses were carried out in cameras of type WA (RKD) with OrKa?-
radiation. The specimens were produced by evaporation of a mixture.of
solutions of coimsponding oxalates and ammonium sa n
dfb with subseque ~t
heating to 4000C. Figs. 1 and 2 show the change of catalytic activity of
the examined catalysts with the composition in the oxidation of benzene to
maleic anhydride. A comparison of the determined phase compositions and
the epr spectra with the activity of studied catalysts show that the in-
crease of catalytic activity of mixed vanadium oxide catalysts is due to
the increase of concentration of defects in the V20 5 lattice. These
defects are caused by molybdenum, chromium or titanium atoms penetrating
into the V205 lattice in the formation of solid solutions. When the tested
V 20 5-Moo3catalyst is annealed at high temperatures, a cansiderable de-:
activation occurs, since the oversaturated solid MoO 3 solution existing,
prior to annealing changes over into state of equilibrium, then having less
m003 and thus also fewer lattice defects. It is, therefore, probable that
Card 2/4

28293 s/o76/61/035/010/012/01 5
Catalytic activity of... B1061ijilo
pure,V 0 can be successfully used as catalyst hen the a lia
W a pound to be
2 5
oxidized itself, e. g. naphthalene) causes a cons iderable :concentration of
defects in the V20 5 lattice (by forming.a non-stoiohiometric excess of
vanadium). In other cases, however) oxides of other,elements which form'i
solid,solutions with V 205 must be added to vanadium,pento~iide in order to'
create the required concentration of defects. Concentration and chaiact6r
of defects and thus also catalytic activity and sele(itivi,ty of the catalyst
itity and ki
can be varied within wide limits by,variation of quat nd o~
additions. In order to substantiate the mentioned rules, further pap(irs!
will study connections between.activity and selectivity of vanadium oxide
catalysts, on the one hand, and concentration of lattice defects, on the'
ot her hand. Also the crystallographic characteristics of,oxides to be
added to V 205 will be det ermined. There are 2 figures, 1,table, andj
referencess 4 Soviet and 3 non-Soviet. The referenoe to Ue English-
language publication reads as followas K. Tarainat S~. Teranishi,
T. Vasui, J. Chem. Soc. Japan. Industr. Chem. Seat., ~_01 1222, 1957.
Gard 3/4

1-5193 S/076/61/035/010/012/6!5
catalytic activity of...
B106/tllo
ASSOCIAVIONs Institut organicheskikh poluproduktov i krasiteley (Instft'uie
of Organic Semifinished Products and Dyes)

SUBMITTED: March 4, 1960
' Alteration of activit
el
Pi
nd
ti
it
f
di
bd
i
l
s
ec
v
t-~mo
u
e
vaina
y a
y o
g
y
catal sts as dependent on the MOO content
3
Legendt (1).Total conversion of 0 (2) conversion of C into C
6H
~6 4 3
Alteration of
Fig. 2. v an selectivity of vanadium-chromium
'
catalysts as dependent
Fig,
Fig. I % Fig. 2
YLg 2
on-the Or 0 1content
2 3.
Legends. (1)'Total con- V - Ave

version of a 6H 6#
(2)

conversion of 0 H into,
6 6
C H
4 2Q3'
.....
IZV% V AWW
C
rd 4/4
a

~11mulugol

PIS IEE14, L.M.; ICM, I.I.
Dynamic progra=dng method for calculating optitua conditions
-for chemical readt=. Reactors of ideal mixiug. lihim.prom.
no.5:352-359 My 162. WIRA 15:7)
(Chemical reactors)

IOFFE, I.I.- KLIYDVA, N.V.; MAKEYEVI A.G.
Liquid phase catalytic oxidation of organic compounds on noble
metals. Part 3: Oxidation of ethylene glycol to glyoxal Kin.i
kat. 3 no.1:107-110 '62. iMM 1~0)
1. Nauchno-issledovatel'skiy in stitut organicheskikh Produktovi
krasiteley imeni K.Ye.Vorosbi-lova.
(Ethylene glycol) (Glyoxal) (Catalysts)

S/195/62/003/1002/001/00'3
B075/E436
AUTHOR: loffe I.I.
TITLE: All-Union onference on the heterogeneous catalytic
oxidation of organic compounds
PERIODICAL: Kinetika i kataliz, v.3, no.2, 1962i 171-174
TEXT: A meeting,was convened in Riga to present and discuss,
papers on heterogeneous caisAytic oxidation of organic compounds
derived1from petroleum. The papers presented dealt.with four
main groups of subjects: 1) mechanism of action of heterogeneous
catalyst; 2) kinetics of the catalytic oxidation;
3) synthesis with the use of catalytic oxidation; dev lopent
of technological processes for the catalytic oxidation of organic,
compounds. In the first group of papers, 1.1.1offe dealt with
the significance of the place of primary attack of An organic
molecule with molecular oxygen, relationshipo'betwea'n'the speeds:
of the reactidn and desorption'stages of the catalytic proceAs,'~:
electron-donor or acceptor characteristics-of the catalysts and:
reagents and kinetics of phase transitions of catalysts.
S.Z.Roginakiy discussed the speed'of electronic-transitions In the-
Card 1A

S/195/62/003/002/001/003
All-Union Conference E075/E436
system catalyst -reagents. A series of.papers by L~Ya.Margol,ia,.'
E.Kh.Yenikeyev, SoS*]3abkov, Yu,A.Kozlova, M.I.Temkin,
V.Ye.Ostrovskiy, N.I.Popova and others was devoted to.m6dification
of the heterogeneous oxidation catalysts leading to an increase ih
their selectivity. I.I.Ioffe and V.V.Voyevodskiy and co-authors
reported on their investigation of the mechanism of Action of;'
mixed catalysts with the application of X-ray atid EPR analysi4*
The second group of papers came from the Fiziko-khimicheskiy
institut im. L.Ya.Karpova (Physicochemical Institut6 imeni
L.Ya.Karpov), Institut fizicheakoy khimii AN UkrSSR Unstitute of
Physical Chemistry AS UkrSSR), Institut organiches~~go sinteza~
AN LatvSSR (Institute of Organic Synthesis AS Latvian SSR).
G.K.Boreskova and co-authors'reported on the preparation of
catalyst and kinetics of the oxidation of ethyjene.~
N.I.Popova, Ye.Ye.Vermell and F.A'.Millman described~the oxidatioil
of isobutylene, piperylene and isoprene to aldehydes on a copper
catalyst. Most of the papers in the third group dealt with the
oxidation of propylene to acrolein. A-beneficial influence'of.
water vapour and selenium on the process was mentioned in the
Card 2A

S/195/62/003/002/001/003
All-Union Conference E075/E436
papers by N.I.Popovaand co-authorst A.M.Garnish and co-authors,
B.D.Kruzhalov, A.G'.Polkovnikova. and'co-authors, S.S. 'Bobkov,
A.I.Kirlyan and co-authors. N.D.Ruslyanova and*co.-authors
described,the ways of increasing the yields of phthalic anhydride
and- anthraquirione prepared from the anthracene fraction of coal tar.
B V.'Suvorov reported on a direct synthesis of benzo- and .I
phthalo-nitrites. Yu.T.Nikolayeva and I.I.Ioffe described a new
method for the synthesis of aryloxyacetic acids~ V.L.Plakidina
and co-authors gave more precise conditions of oxidation of
dibenzatronil to dioxyviol~ntrop. R.M.Flid and A.Ye.Krasotkin''
demonstrated the superiority of the process of combined oxidation
and dehydration of alcohols for the production of ketones and'
aldehydes over that of normdl oxidation processes. , I.I.Ioffe
and R.M.Flid and co-authors presented:data on the selective
preparation of glyoxal by the oxidation of ethyleneiglycol.
Yu.D.Kernos, B.L.Moldavskly and S.S.Bobkov"desic'ribed new
synthcaes of maleic anhydricre.and acrylonitrile from olefines,&,
In the fourth group of papers, L.I.Oks veported on the production
of phthalic anhydride with'the application of boiling film or
Card'3/4

S/195/62/003/002/001/003
All-Union Conference E075/E436
catalyst. A.F.Grigorov and R.P.Rumyantsev described a process
for the oxidation of o-xylol to phthalic anhydride. A.A.Avot,
S.A.Giller and M.V.Shimanskaya reported on the production of maleic
anhydride from furfurol by the method of NIOPiK. VM.Dobkin
dealt with the question of automatic.direction ahd regulation of
exothermic processes of heterogeneous catalytic oxidation of
organic compounds. Some other papers, previously published,
were also read.
Card 4/4

IOFFE I.I.; YEZHKOVA, Z.I.; LTUBARSKIY, A.G.
Phase composition of mixed vanadium catalyots,for the oxidation
of aromatic hydrocarbons. Kin.i kat. 3 no.2.-194-200 Mr-Ap .
162. 15:11)
1. Nauchw-iosledovatellskiy institut orgaaLcheakikh poluproduktov
i krasiteley imeni Voroshilova.
(Hydrocarbons) (Wdation) '(Vanadlum oxides):

I WEI
i0m, I.I.;--LYUBARSKIY,, A.G.
Kinetics of the catalytic oxidation of benzene to maleic an]Vdride.
Kin.i kILt. 3 no.2&261-271 Mr-Ap 162. (MMA 15 S.U)
1. Nauchno--iseledovatellskiy institut organicheiUkh poluproduktov
i kruiteley imeni X.Ye'voroshilova.
(Benzene) (Nkleic aWvdr:Lde) (Utalyslo)

- - - --------
SLAVINSKAYA, V.A.; GULSVSKIYq NJ.; SHIMANSKAYA, X.V.; GILLER., SA.;
Mnstige of furfurole catalytic oxidation,' KinA kat. 3
no.2t276-281 Mr-Ap 162. (MIRA 15ull)
1. Institut organichaskogo sintesa AN LaWyekoy Ssaj, Riga i
Nauchno-iseledovateltakiy institut orgunfi~eskikh poluproduktov
i krasitelay imni K-Ye.Voroshilova, Moskva.
(1N=a1dehyde) (Naleic anhydride) (Catalysts)

FISMZN,9 LA (Flolmen, L.M.1; IOFFEV I.I.
Kinetics of the reaction in the flowing systems,, Analele chLmis
17 no.2s85-103 AP-Je 162. ,

Optiml process in at sequence of adiabatic reactors with ideal
displacement. Dokl.AN SSSR I" no-3s6O9-612 Itr ~62*
(KWA 15.,5)
lo Nauchno-isoledowatel'skLy inotitut organicheo'kiWpoluproduktov
i krasiteley, Predstalleno akedemikom I.A.BelandiMi.
(Chemical reactors)

FISIMM9 L.M.; IOM, I.I.
Amount of informtion required for designing:reactorn by the
dynamie programing method. JKinJ kat. 3 ~ no.4,493~-561 n-Ag
162. OURA 1.518)
1. Naudhno-Looledovatellskiy inatitut organicheakikb poluprocluktoy
i kraBiteley.
(Chemical reactors)

PISIM, L.IL;-LOTI ~,-I-
Optimal process in a sequevqo of reactors with ideal mixing,
DOkI*AN SSSR I" noe4sS53454 Jo 162* (XMI 150)
1, Nauchno-imelodovatol'skiy inetitut organicheskikh poluproduktow
i krasiteley. Predstavlono, skademikm A A.Balandinp.
(Chenical reactors)

IOFFE I.I.; LYUBARSKIY,, A.G.
Kinatice of beterogenous catalytic oxidation of-maloic
anhydride. Kini kate 4 no.2:294-298 Mr-Ap 163. (KMA .16 5)
.1. Nauchno-issledovatellekiy institut organiaheakikh poluproduktav
i krasitslay imeni K.Ye. Voroohilova.
(Maleic anhydride) (Diddation) (Cat"il)

- - - --- -- - - - - - --- ~L - -- - -- -- -- ---- - -- -__- ~ - __-_ -- -- -- --- - -- - - -- - --- -- ~ .1 -
IOFFE.. I. I.; MARGOLIS,, L. Ya. -- - -- - - -- -1 - - --

IOFFE, I.I.; KLIMOVA, U.V.
Liquid-phase oxidation of hydrocarbons on solid semiconducting
catalysts. Kinj kat. 4 no.5:779-782 S-0 163. (MIRA l6tl2)
1. Nauchno-issledovatellskiy institut organichoskikli Poluproduktov
i krasiteley.

11ILMMUIPH
DOSOVIT,5KIY, Ye.l.,- IqFF?
j 1j.
Kinetics of oxidative decarboxylation of copper benzoate. Kin.i
kat. 5 noo6slIO4,-1107 N-D 164s (WRA l8t3)
Is Nauchno-iWsdovatellskiy institut organichos,kikh poluproduktoy
i krasiteley.

L. M. (PisImen, L.
PIS214EN
Calculation of the optimum operation of chemical reactors.
Magy kem lap 19 no-. 2: 93-99 F 164.
1-0 Szerves KozbenBo Tormakek as Stinezeksk Tudom.anyom'Mitato
Intezete, Moszkva.

- -------- ----------
ACCESSION NRz AP4012976 3/0020/04/JL54/004/0903/090':
AUTHORS: Ioffsp I.I.; Yeshkova Z.I.j Lyubarsklys.A.G.
TITLEt Concerning the nechwim of oqgmda compounds oxidation
over solid nonmetallic."talysts
SOURC1h AN SSSR. D61d&dy*,, y. 154, no. 4L, l9b4# 903-90b
TOPIC TAG3z solid nonmetallic oatalyit, ox1dat1on:oat*lyst,, pi
catalyst, sigma catalyst
ABSTRACT: The present work in a discussion and derivation of 1
Me
based on the experimental work by A.G. Lyubarski (dandidate theids
Moscow, 19b3) and constitutes, therefore, the conclusions of the:
,.thesis. Oxidation of organic compounds consists of the following
stages: 1. electron transition from reagent to catalyst (chem-
option), 2. XLeatron transmission from donor (re"ent) to acceptor
oxygen), 3. Incormratlon of eleatronB by the.oxygen xlolsoule
61-forming O-Ion, and 4. Interaction of organia
ion with the O-Ion and the formation of the oxidation product. 'The''
1/2
i Card

ACCESSION M AP40129T6
first stage is a complex formation with fillUA ofid-orbits of
cations. The capacity of catalysts to form IT -coogexe* on their'
surface in oontact with hydrocarbons having double~and triple bonds
depends on the acceptor capacity of the catalyst. Stage 2 Is
achieved by straight interaction of electrons with Oxygen# re-
charging of Ions and zonal oonduotIV3.ty, (inlr-aot:L-4i%rod~~0atalysts).
Stages3 and 4 are not discussed in the trtiole# which concludes with'
some recommendations on how to synthesize selective o--activating
catalysts which do not destroy the double CvC bon4 during oxidation.
Orig. art. has: 2 figures#.l formula# no tables.
ASSOCIATION: Nauchno, iseledovatellakly Institut o-MAniebeekikh
poluproduktov I krasiteley (Solent1fla Research ImUtuts of Intai--
i mediates and Dyes)
SUBMITTEDt OlAug63,-'. DhTZ AOQ: -96F064 MCLS, 00
SUB CODEs CH NO R1W SMs 006 0 00.4
2/2
Card
... ... ......

GOLOVANFlIKO, B.I.; SHAMPOV, A.Mi.; TOFFE' III.; F.G.
---- L~~ lt~
Obtaining phthalic anhydride by conjugated vapo:r., 1~-a~t. oxidatian
of hydrocarbons on vanadium catalysts. Neftekhlmla 4 no.4:591-5~2
JI-Ag 164. (1-11 RA 117: 10)
1. Nauchno-issledovateliskiy institut nefteklilmir-heskikh proizvodstv,
Ufa.

SHARIFOVP A.Kh.; GOLOVANENKOt B.Iq T I.I,; BORSHCHEWD,, V.P.;
FATKTLLINA, N.S.
Obtaining phthalic anhydride by oxidizing a petroleum naphthaline;
fraction. Nefteper. i neftekhim. no.8s22-23 164. (MMA M10)
1. Vsesoyuznyy nauchno-isaledovateltakiy institut neftekhimicheskikh
protsessov, Leningrad, i Nauchno-iseledovateltakiy institut nefte-
khimicheskikh proizvodstv,, Ufa.

-~-L' 19372-66
M 22A62'
ACCESM Nm AP5015461 UR10310/4 W/M 3!
AU MH Rt,Qaripam At Khot
FatkuUinal
MITUs Preparation of phthalio amby6irtJ bV axldauodof lAhe mm 7ftacum
of crude oils
MR03s, ftf teperaraboft I nef takhImbAs 2
TOPIC TAM oruxle votrolaum naphthOmeal vxicimotio;rillk
Abstracts Noti6g that.-Ln the*03A.t1i Swou"t 'it 't6~-iii itaphttial4lRi JL~Mlvosk
as larte as that produced f kba coke, ;the::4ki th4cll ~ 4#ic ifi'iheir st%~Aes 9
ithe vapor-phase catalutLe oxidation of arii~tto~
6yielding phthelic anhydride. They ahou tlwt mloi t'~ *'b* 11 pltj~h~*Wn6
;conterrt, the phtholic-anhydride yield way re;q " oratic4l. 1
h 941
Howeve lhla i~a a 1~ t~t Aw
d at ttmkqj;4o.*t: of 4 catslyllt~ LVU
h 2
OA
F
ASSMAMNs VNIln0ft2MIM, -UpAn"PA 1111nort
BJMIIT=s 00 t, too 00.1~'~
an a*
NO P" MV1 002 OTMS 002 . i I . 1: 1: I ~.
Saw-1A

IOFFEP I.L.9 Prof.
Modification of dermatomic tecbnice KbirurgilA 35 no. 5:236-137
MY. 159. (MIRA 13:10),
1, Iz kafedry operativnoy kbirurgil (Zav. - proT. I.L. loffe)
Saratovskogo maditsinakogo instituts (diro - datoent B,A. Nikit:Lu)*
(suRaimasTumns AND APPARATus)

KRUGLIKOVA, G.N.; IOM, I.L.
Use of plastios in the Gorkiy Economic Regiono AwUnootroitevl
no. 5 -.7-8 VV 162. (KaiA 3,5 s5)
(Clorkiy Province-FLOti*B)

I&IF E, 1. L.
Ioffe, I. L. "The surrical anatomy of the r~.ot of the tril'acial nerve", Voprosy
neyrokhirurgii, 19419j No. 1) p. 56-6)~) - Biblioe-. p. 63-,(~t-,
SO: U 3042, 11 ~Iarch 53, (Letopis 'Zhurp-al lnykh Statey, No. .7ji 19-149).

10FRE, I, L. O-jr./t prinencidya orplAchoul'oLo otold'a dlya is"'rotc,"IrmLly".
Icorroziormyl,h preparaucFv. Vracheb. dulo, 1949, j.:0. V, 257-3. 747-46.
SO: Letopis, No. 32, 1949.

lays, I. L.
Technic of radicootoeW of the trigominal nerve br ocoioital apprtwh.
Yopr.neirokhir. no.2:43-31 Kr-Ap 1~0. (CM 190 i
1. Of the Departuent of Operative Surgery (Head Prof. N.A.Qrsa'411),~
First Zeningrad Medical Institute Iment Academician I.P.Tavlov).

1. L., Prof.
Tendons
AnatoTicosurcical survey of rational mmethods of surgical t~-orap,;- 1:1' !deli Ix-ra-.1ali 'is of
0 - 4
diaital flexors in the wrist, Khirurgi ia No. 12, 1952.
9. Monthly List of Russian Accessions, Library of Congress, H&Y 1953. Unclassified.*

2. USSR (600)
Tendons
7. Anatomicosurgical survey of rational methods of surgical,,therao of
tendovaginitis of digital flexors in the wrist. Khirurgiya Fo. 12, 1953..
9. Month List of Russian Accessions, Library of Congress? May -IS153, Mc 1.

-4

USSR/Human and Animal M6rphology - General Problems Q-1
Abs Jour Referat Zhur - Biologii, No 16, 1957, 70223
Author Ioffe, I.L
Title Of Surgical Anatomy of the Palm Skin Creasers..
Orig Pub Tr..Twkm. med. in-ta 19551 5-6, 92-94
Abstract By the method of layer preparation and X-ray-40 bjlnds
of adults of both sexes were studied..' If ~ou diiride the
distal crease (rascetta) in four equal,parti by three
points, then the radial artery goes to the,rh'diaLpoint,
the middle nerve to the middle point - an&the elbow
nerve and artery go to the elbow point., The last one
runs parallel to the proxizal~phlm crease) (liinea~vlta-
i
ing t4e,.sur-
lis), at the middle it turns laterally~ form
face palm arch. The proximal part of lines. vitali,s - cor-
responds to the medial edge of the.middle.aerve. ''If-the
two ends of the crease are connected by a stiaight~line
and the latter is devided in three parts by two points
Card V2 45
USSR/Human and Animal Morphology General Problema
Abs Jour Referat Zhur Biologii, No 16, 1957, 70221
then to the proximal one is directed the mutcular branch
of the third nerve, the damage of which luavios the -thumb
incapable of resistance. "The closed to the knif.r. 4zone
forms here a quadrangle with a side approxoil,5 cz long.
If the radial end of the proximal palm creas''..e and.:the'
elbow end of the distal crease (linea mensalis) are con-
nected by a straight line than it will pass on the level
of the distal parts of the metacarpal boaes,~and the pro-
ximal parts sinovial cELvities of the tendons of :Uexors
II-LV, and sometimes V fingers, and may serve as a pro-
Ximal.limit for the incision to unsheath the~volvulus of
the sinovial cavity.
Card 2/2 46
Zy (Norriel rnO Ertthololdr-ftl) 11orvous
usSR/Hunan vnd Aninrl 11orpholo,
Systor.,
Abs Jour t Rof Zhur - Biel., No 7# 1958t No 31242
Author t loffo LL*
Inst of the Pelmaris DMIch of the Modirl
Title i On the Surgief-I tnttony
Norva.
Orig Fub : Tr. TurL-3. r-'Od. In-tnq 1955, 5-6t 95-98
Abstroct : No rbstract
Cord
32

Modification of the technic of oseo plastic log amputation, Ortopo,
trevooprotess 19 nosl:59-61 Jm-F 158o (MIRA 11:4)
1. Is kmfedry operativnoy khtrargit (sav. - pro f. I*L.loffe)
Serstowskoge mailitsinskogo instituts dir. - dots. B.A.Vildtin)
(ANPUTATICK
log. modification of bons plastLo technic (Rua))

Some problema of apPendectoiW technic. Gov. mod. 22 no.12:47-53 1) 158.
(KIRA 12: 1)
1. Ix Wedry operstlynoy khirurgli (mv. - prof. 1. L. Joffe) SjMtov-
skoge meditainakogo institata (dir.' - dots. B,,A. NIkItin),
(APPREMICKY
tochak, problem (Ike))

IOM. I.Les prof. (Shratov)
ONsthods In examining surgical Patt onto* by I.$. Widenbaum. Reviewed
by I*L* loffs. 111n.mod. 37 U0,11:150-152 W"59. (MMA 13'"63)
(MMOUT)

ANT0111-OV, A.M., prof.,, red.; VOLIFKOVICHp M.P.p prof., rad.;
ZAKHAROVA, G.N., dots., red.; IVANOV, N.R.p dots.0 red,j
prof., red.; POY, A.M., prof., red.;
SHAMARB, P.L., prof.p red.; SHERISHORINA, SoLp profotreds
(Transactions of the First City Conference or:Yoling Sci-
entistap Medical Section] Trudy Pervoy gorodskoy kouferentaii
molodykh nauchnykh rabotnikov. Meditsinskala sektaiU. SaratoTj~
Saratovskii meditsinskii in-t.. .1963. 295 P. (MIAI 18-5)
1, aorodskaya konferentelya molodykh nauchWkh rabotnikov. Me-
ditsinskaya sektsiya, Istp Saratov,

IOM)'I.L., Prof.
Device for external determination of internal~sizes of the
blood vessels. Nkrurgiia no,1:136-137 f63,, (KMA 1735).
1. Iz kafedry operativnoy khirurgii (zav. -prof. I.L. loffe)
Saratovkkogo maditsinakogo instituta.

-----CHUYKO, N,M., doktor tekhn.nauk; RUTKOUKIY, V.B., inzh.; DANIGHM, R.Ye.,
inah.; PEREVYAZKO, A.T., inzh.; BORODULIU, G.M., inzh.;
TIEGUBENKO, A.F., inzh.; SUMILI, Yu.F.., insh.; FRAMOV, V.P.,,
inzh.; VOLOVICH, V.G., inzh.,# Prinimall uchastiyet ;OFFEE, I.M.0,
inzh.; LAVRENTIYEV, M.I., inzh.,- PARKHOMMO, G'P., inzh.,--~'
DEMIDENKO, V.I., inzh.; RYSIN, re.M., inzh.; VOROBIYEVA, T.H., inzh.
Inert gas blowing of metal in the ladle invacuum. Stall 22
no.9t8O9-811 S 162.
(vacuum metallurgy) (Protective atmosoores)

U.JJMKIY, V.M., kand. takhn. nauk; RUKMAN, G.L., inzh.; FELIDWH, G.B., inzh.;
DENISEMOx S.A.9 inzh.; SMOLINA, Z,K.p inzhol KOSTOGRTZ, F.L., Inzh.;
IOFFEp I.M.1, tekhnik
Experience in introducing remote control of pumps
at. the S.MAirov mine, Shakhts strol, 9 no,10t27-28 0 165, (MIM 1M)
1. Vaesoyuznyy nauchao-isaledovatel'skiy institut organizataii I
makhanizatsii shakhtnoge stroitalletya (for Zalineklyp Rukman,
Felldman). 2. Inatitut Aytonatuglarudprom zavoda *Krannyy metal-
list" (for Denisenko, Smolina, Kontogryz) 3. Yakovlevokoye stroltellno-
montazhnoye upravleniya tresta Soyuzshakhtoo3uaIteniya (for Ieffe).

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