SCIENTIFIC ABSTRACT GRIGOREVA, N.E. - GRIGORYEVA, T.G.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000516820016-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: July 27, 2000
• Sequence Number: 16
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Web m E. Grigar eVai-PPI
abzkch. tm-' 107-111),- T%u ncw pe~ntamrthjn' 'J,i~l
were prepurd, vit chlorOu M I
py,idu'o WE of 2 -dinitr4
I'dr,,chla-idm of p pf--n,-ut r!, i-
In alk111fir aledia lt~' 'h-fij'~Ut t'%
of thc%~ dyes was d~!ccrrnuirfj in ~,]%~ents in ttle - t
NaOH. HCI, HOA, and ff,CO, S~rritnctrt-l ~t~t. I "kn'i
As~Avc in Nfe and Et alriihok , tt,ry di4~ivv fjj~,rr ~fj KIr'. '..
arctic acid and 0&11&0 to reddiiih-violet colours &iruil4r to th-, d
bcnzidiite der.-. hi pft~Ftnco of Rkubol (but differ in thAt b~'
of the solution the colour i1cepens). Max. otrad min
vary rording to strength of solution, &W-aptiou I.j%-cr in acett,
acid L~irkg five timm higher than in alcoholl + HCL Max. abs."ption
of nionokaits U in F-tOH is 465 m0a and in acctono 495 ni~L
am
Thoteric nature is shown by formation L;f ctiloured salts witla acids
a alkalis. Cations acid aniont in alcohol cidubit gamilar colouri
(max. absirption 630 tniA.). Aniows colouri exhibit more statmtlity
thAtI cAtivas- A 1, B

14~mtilllt 5.2 K; ili pymliii~mi) (1)
";it[' -1 14~ !'-Oll! It) nti.-. g:;v- :; d4tk
W141 N11c,CQ Idt b~ldn-t.
lipt . wid, 11 101cr r-iihinlc Avith 1110
tMorid,, dark-ml, tit. 167' (conlaius 0.5 V-011 ), fr Which
fiwt.ry cr-stii. qolvct cauld nct be foimd. 11cating
to*-L~"4'33' in 11(1I1fl1Ttari!m of %uric
Tonoval of t1m. latfrr with III)( Me-(-O plye a litw-vyl r,4111t,
which 00,ki-I 60"o (f-IJCoTf,Nll,)CI (111), Ycilow (Irmn
M )I J_ -A01f;
M10). U1. Whi0i CGMAHC(l 0,46 MCAC 1.
L
Or"'Itc, YCHOW, M. (fr,m EtOlf and IGO). I (I g.)
ruid 1,3 g. 111( CI ,aft litatvill In 5 ml, ELUI I aud 2 ial. pyr-
15 -11hi. (.11 stvain O.-oll gave n Ictl i?Ft. (initially
violtf ). which aftrr wa0iinj wa4 chriffilt(igTA11hf-ji rin Allot
yiddi,g grccri
Nill twl.sll : C1101; ClICH:
in.21.ul'x Eo*,5~,1,4(ift~)11),Fg:l~)(1--tf)tl.flc)),(*.t)if(fl(:(),11),
lt~fluxuj 18ith pYlidine I hr., filtt:tcd an(I evapl. tjjjj ~,jvc
Some diuitruaniline and lit, is(ilatc(I as the ploatc, wa:;1:iujr
'the imidile with ]Is( ) gave rin uuidentiriL-d git:t-n pr-Auct,
Ilcut-ing L with P-Csl(,(NITAc)t I,% I"toll r)51,',j (RI.
(M. It , - P-L.1411.
C4114). vicilct, tit. 147' (tx(,tn Acoll), 'AtLiCII J1CjtC(I t0 itj
ul-p- and treated wit), 11,0 gave In,
"7&-7* (from Ftoll-l~y)); fj(rrj#, ;,cjjnjv, in, I
I rind gave 671J10 vi.,-Iet IV (it, - p.
Afr,NC7,1lj, it, IIII Mom Etolf) 1101 Imited Willi 11,0
Y T

7-7-77 - -
g ?'A~ Qlx~
V m fill., I lQI salt ht aled with Nal. it I
Pvc Ptr-n
decomp, 2-10" x (Clixj)" 41~0 4-du (I't0m.
Mir-)und 1.15 g. III licatud 5 mics, fit EtOIr' (reat(A Ivith I
till. pytidine aud licatui until I Itut reacted (2 Ill-1.) g-Ave
0.0 jr. orange-reA solid, which repptd. (viiii EtOlf with
Me'lZO j"-J%c Pate YLIlow in. 2&r)* (from
EtOll-Etco) (COntnilli 1,25 Illolr:q 11tOll); pirra.e, Ill.
233': 1 f, 23 ;;.) in 1-4011 Imited Willi IS g. m-CJ1 00
0.5 fir. g ive 11) g~ n-rud 11' Oz I - Ill,
) tUilli 2 UPACq IWO11); lXAtCfj W IS2' (0 ill-
ci llmt m it gave'4 Innivit Will which 19:41 pa-:;td over
A, Os In EtOlt and file, effluent roln. tr,-.Ited with EtIO.
yielding a brown !:nI3A, in, 22~18', it compd. of 2 ril"Icl On.
Iwjr 1 Nlf,)CI (VI) mid I tw4c di.-Onior wiih 2 )~tol(,*
file rLitfuat 'suln' trc-mUl With tll11ZC E'lvc ytll~AV
vitvdieg ~,f V1, m, 715" 0,j mc-1z: E1011). I
J.'.) awl I g. in 1`1011 11C.-Itcd 3 mir). kpv~! 0.2
ain;ust black IV i-j1lNCJJ',), m. 160'. If fl.e'
I e, gf:llti w(.--le lliA ill jorl :3 i~' rty., lilld
11f.it(A 21) til~ll. In F(011' tl~~Lrc! f'-tiv"I 0.:1 r. ,nr"-~n
(Olive- c.11'xil (.1(: 61 ('11., OU CH., "'71 ( 1,
22-3, ONI&II lct~lills I'A IfJO); tht-l-111,11 p,;ivv, di-
liltn"Illilille alid a vit, 'llik, b~AIZ11j''Ic &~V' ."I glut.1"s'll-
a)(Ithyde wasdecol."l;f), (cf. Twymr-;,rlal- C.A.49. 102,~~M)
nxid 2A g. ci( the yel (jw jjv-uii(-t vvwi tak-en tit, in hot txiLA.
IICJ; (M COCIiilr fill! R0111. %Vi n1'(ltMIi1C(I lNitli N11,Off,
Ykidiug yellow lit. 307' ~frwn EtOlf),
which has 1 14111, Laoilp uv~iikiblc f~,r dia;r-tmiti-n. lhi3
(0.5 g.) und 0.5 r. I ImattA in Elf) I with 2 jul. pyri-Jine
15 inin. and kept 12 Ins. i-~ivc 517c, IN IV IR' - (P-kC,
11,101, which does not rr.(It. but (Icktimp. na licaling, the
product, C61I.N.Ch. cc;ntains 3 tr-le.,4 FtOll. Thu4 im-
vLb~.tivitul di. alims Can mlvt with quMcmary pyriditlit'sn
salt:i in 1, 1: 1,,uid 1:2 plipotti,mi. G,- M.

C' 'A X I)
Influms of And 211tatiles WiribitaItion qlrcl
ytkUnG 4yel. V. 9, Ortpit'itin. 1. K. lkwl A.
et", state Unlv,, Kharkov). zhftr~ ObAthel Vim.
3(W1 103);, d. CA. 00, 13778b.-AW)rptiou ~Wtm
I a-base dye$ Won txmnid. In 0% EtQif,--
aw SM 'Ith varybig arnts. of NO. L'Or tic AcOf I;
7 tpoctra wcrttxamd.al&oInak.,.&Wna. with varying
un . of NOR- The pytidina d t In Aq. RLOH Undergo
hydmlydi whkh Is more httet= Teases of comp(li. w;th
I any acid added tothe saln. shifts
Ww" basicity of the ~atlion.
the equil. In the direction of the dye salt while alkali shift.
.,tho equil. in th* dirretion (A the but 11 the dye containsi
-40nor 'groupti; with elect mn-acrept of FT(JUP3 the
afti. of alkah ylelfb del-Ply--colomd "losic dyt,3. The
Anilintsime pplilim.- t1v;:_s are dreoloriztcl In concd, 14904
ovylu to salt romiAtion, thc~e to the oflj~lnltf dYN
-6. max. ime noled la M01 I atil
ots d4n. The following at
EtO14 with excess HCI# resp., for the following dyti of type
RN11(CH)11:NHRCl (R thown): Ph, 485 Eng, 495 injA; p- C
MeWlil 495 495; PO&OCJ14 600. &)U; P-HOUlt 105,
805; -1-Cilli, 410, 480, 2-C!,Jl, i~2,
550;
p-OtNCjjH,41U~-b27, Thevarlowtivpermauze
reptoduced.
frotiii excm NaO11 and pyridine-SO.) with"p-
14MIllautoll,inthe rivencerifa. little 11C[gave
Z
JjCj,yjo1tt,m, '4C3-4*,whld%rttainsrtO1f. 4

6t fVtd104 a 01kounit with
a 1. K. Waite &ud N. G.'
swt tw Joy, zim o1). z1of. 6SACM xh~m
IGNI ' ef. Ud#MY* Z4VIA4 Kkof,im C303%.
ic'd. Vah.- so, IAllat wai pudftj
by tstattgent with CUSC44 and With m Kt. of phttal c co
vetk arthrdsides reflIL", a on. Thu Pkire m-At H'11' b.
144*. pictste, to. W. Aals (2.15 tztl,) and 1.5 C. 2,4-di-
13 keobcmzm* (1) heated briefly to forra a sain., thm
~Itd~o With W ML 4!7 r240 And k4rVt I 41AY
yiddi If IM compmeit-1 sr4 hented & hin. it to,, the
$AMC poduct foctmA. 71le Salt, treuOd with 15% Mail,
'the red "V~417 of lot*
". memm HtAttag the t with '.t, I't ntnex In
E
Wit at 5"0* tare an vptp.~ with 9 1IC1 the CmT"Ppad.
8.4 ~~sNHAP Ai show-1:1 A, md-bmwn, m.
blts;~IM, . 130-, ), 493, In the prera. of It
j'%t*TsthtmaWf&me4 viokc 4 3tlhint tile (tunt thero-
611ne'. thip rabnUnre
"on,of 11 W" P tM41: S.27R,
V W
j"'Y'a-042,60,M. 167, (from keoll), cc at. OP.
(tratri MftCO), this pawed over A" give an Upp" 1110W
%=e
to", aW lawtr Yk4et The Latter Outod *itb 36 cjCG
Cave tb4 Pam M
yeseg"
h led ovc, P.O. at 7so I
121 0. deep AoW, ~m~ I
hr. t shve sum I to t. and sayt purt Cjj1W-
04NsC7, a dark &Q). 7ne yellow chronuk(cVaphic zo:ir,

ab~n

tat
1 Y
-T
6
in
o pe"
C=P.

'd

WAII 'i
Ul. lk
Utae courpo"d, lnfu*ib:o omd gpf
I was t!so d%ved tyadtua
A= T. 1, 71 spwtTaly
Morl, U
E and p 44 v,
4-dWtpiila-rvhwy at 130%. 111
W" JJCOH j-ATt I dt4CP tj~~.d flgd
aq trtatraut vrtt!3 4
Meoll Ngalt PYO a Mut Oka Cal.
odftq IV WIA a-
r41T4N:Clfcy(:cl(cl.f;Cfiw:

----------
Distr: hF-hJ/hE3d
"COMIU4 hydr4-tn *103 of N- I substitutO4 Inid i n
!~~-CT M - ;'
R Gjjr-Z;va, A.
ov) f. mjkAel
ry yridinimn dskyr-Wej were lgel-d.
amirding to Vacke MI. 329(1(X)4)) wiOuKa
tiols by boatits pylidin'!
omitirs in FtOH f,)Iuwrd by dign. cA RtOlf and ht-Atinj thr,
millne with 1110 wit the dy-a was
dinitmanifine --I --cmkm~; tt~rti a Om fvltratc~
with EW Anp trtatsurnt wilh C. Nval e, j-'J.
to ykld zfe ck-wircl arylpyTidLaium :111cride. I I y&og 11tv't-
tion ot pyridist &kooSAmnylmtc in MvOll ovct Ft%. gave
M-PAOM piperUine IRT gal, M. 2w'. 'wife-m
Similaarly, Tim &btai"-d:_4 11-C-3 F44, 171A
Hcl
110 sau. W,
a
11 1 GAU coll)d Dm it Vwifiej, f(rdromation, of tht lict
%sit ci
Which dw fKt cr-'at; thih with V40H w0 'V-f"4mfq'*1-!
YiY?j4t4FWU, Ell, I I
G. M. KQwJ&wj

GRIGORIYEVA, N.Ye.
1% -Mmwmw~
Pentatueth=(P~ridins) dyes. Uch. zap. KIIGU 95:207-230 '57.
(MIRA 12:10)
(Pyridine) (Vfes and dyeing)

GRIGORIYIVA, R.Ye.
Catalytic activity of diatomite. Bent. gliny Ukz. no.2:136-140
158. (MIRA 12:12)
1.Kharlkovokly gosudarstvenW univerettet.
(Catalysts) (Diatomite)

AUTHORS: Gri--orlyeva, ff. Yo., Foch!~a, A. A, juv/79-26-6-54/63
TITLE: Morjoanils of Glutaconedialde~$iyde (Monoanily ~:lutakonoyogo
dialldoC;Jda) I. Derivatives of Pri:nary Aromatic Aninos (I.
Proizvo(Inyyo porvichnykh aronatichenkikh aminoy)
PERIODICAL: Zhurnal obnhchey khimii, 1958, Vol. 26, Itr 6,
pp. 1677 - 16C1 (USSR)
ABSTRACT: Of the derivatives of prinary anines only the dinitro-subutituted
ones were known (Rof 1). One of the authors _-..nthetized the
correoponding anilinederivatives anti other primary aromatic amines
(Refs 4,5)- However, the nature of these com;~ounda was not in-
vesti~:ated in detail as their yields were toonmall. In order
to investiEate similar compounds more clocely the authors elabo-
rated a method of synthesis of '%-.he derivatives of aniline and of
other aminee; in some cases they obtained conoi!erable yields,
and the authors could inverti~.:ate their condensability with aro-
matic amines and compounds containin- active methyl 6-roups. The
condensation of the monoanilo with aromatic amines was carried
out under different co,ditions: in acetic acid in the presence
of hydrochloric acid, in acetic --nhydride in t"'e presence of
Card 1/3 hydrogen chloride and in pyridine in the prenence of hydrogen

Monoanilo of Glutnconedialdehyde. 1. Darivativev of JUV/79-26-6-54/63
rri;;,"ry Aromatic Amines
chloride. Only in the lnut mentioned case a color chwire
occurrel, which could bo t~,)-en as an indication as to the nature
of the process of reaction, howevor, no definite reoult could
be achieved, The invozti--.-~tions c.,rriud out of the monoanils
of glutacone uldehydo ahowod in any way that they are of ampho-
teric character. Their conde-aability with comWoundu haying
active Met*1 droupo can nerye as indirect proof of the strlicture
of thqobtained monoanils. Thus the monoanils of glutacone alde-
hyde are investigated as derivatives of aromatic amines. It was
shown that the unsubstituted monoanil and the monoanils of
glutacone aldehyde with nucleophilic substituents in the aro-
matic nuclei do not enter the condensation with aromatic amines.
The condensation of some monoanils with the methiodide of
2-.-.iethylbenzthiazole was carried out, however, the structure of
the initial products could not be determined. There are 2 tables
and 9 references, 3 of which are Soviet.
Card 2/3

Monoanils of Glutaconedialdehyde. 1. Derivatives of 30V/79-26-6-54/63
Primary Aromatic Anines
ASSOCIATION: KharIkovskiy gosudarstyennyy universitet (Kharlkov State
University)
SUBMITTED: May 12, 1957
1. Aniline derivatives--Synthesis
Gard 3/3

AUTHO'AS: GriCorlyevat H. Yo., Gintse, I. K. .30-1/79-28-6-55/63
TITLE: - -ro-h-o-anila of G1_u_taoLm Aldehyde (Monoanily glutakonoyogo dir-11-
dej;ida) II. The Influe~ce of the Mediu~m on tle Color of the De-
rivatives of Primary Aromatic Amines (II. Vliyaniye sredy na
okrauc% proizvodnyl:h pervichnykh aromatiche3kikh aminov)
PERIODICAL: Zhurnal obahchey khimii, 1958, Vol. 28, Hr 6,
pp. 1682 - 1689 (USSR)
ABSTRACT: The problem concerning the influence of tl.e medium on '..'a color
of the organic compounds has interested scientinto already since
long. The unualty intraionoic dyes are especially sensitive to
changes of the nedium. Many hypotheses have already been suegested
for thin problem (Refs 1-5). That by Kiprianov and his colla-
boratorn is widely acknowledt;ed (Ref 6) as are those by other
authors (Ref 7) who deal with the dependence of the color change
of the intraionoic dyes on the polarity of the solvent. According
to this conception the dyes ire divided into three types: Some
deepen the color with the decrease of the dielectric constant
of the solvent (is type), the others increase it on the same
congitions (2nd type), and the rest have an intermediate position
Card 1/3 (3 r type). The monoanils of clutacone aldehyde as derivatives

Alonoanlls of Glutacm 2dehyde. 11. The Influence of .30*f79-28-6-55/63
the Medium on the Color of the Derivatives of Primary Aromatic Annines
of the primary aromatic amines are tautomeric compounds the
structure of which can be represented by the mentioned formulae
of scheme 1. They belong to the intraionoic compounds. Each
of the mentioned formulae can be represented in form of a di-
polar ion. They easily react on changes of the medium by changing
their own color in various "neutral" solvents and in the presence
of acids and alkali liquors. However, different from the earlier
investigated intraionoic compounds (Refs 6,7) no fixed de;erd-
once of the color change on the polarity of the solvent was
noticed. Therefore the authors had to inveotiCate this problem
more in detail: The relatively good solubility of the monoanils
made it possible to determine their absorption spectra in many
organic solvents. Thus eight monoanils of glutacone aldehyde
were investi6ated this way. It was shown that the absorption
change of these monoanilines in various solvents is connected
with the structure of the complexes of the monoanil an well as
with the solvent an such in the case of an equivalent possibility
of conversion. Thus some considerations on the causes of the
color change of the monoanils of glutacone aldehyde in various
Card 2/3 solyentso in the presence of acids and alkali liquors are mentioned.

Mononnile of Glutacmo Aldehyde. II. The Influence of ~;U//79-28-6-55/63
the Medium on the Color of the Derivatives of Primary Aromatic Amines
It is shown that there is no principal difference between
nolvatochromism and halochromism. There are 4 figuresp 3 table
and 13 reforences, 4 of which are Soviet.
ASSOCIATION: Khartkovskiy gosud&rstvennyy uniYersitet (Kharlkoy State Uni-
versity)
SUBMITTED: April 12, 1957
1. Organic compounds--Chemical properties
Card 3/3

5 9 9 - 5 - 2 46
OTHORS: Rrigorfyeva, 11. Ye.j Gintse, 1~ K., Af&naq1.,,ea, Z. 1-1.
TITLE: Pyridine Dyes, Derivatives of the Secondary Azines (Piridiriovy-
ye krasiteli-proizvodnyyP vtorichnykh aninov)
-2_7RIODIC.*,L: Zhurnal obshchey khimii, 1059, Vol 29, Nr 5, pp 8617-8619 (USSR)
A 3 ST R A CT There are only little data available cr. these dyes (Refs 4,2).
As to color and chemical uroperties they are considerably dif-
fering from the corresponding derivatives of the primary
amines. It can be seen from a comparison of the data pre3ented
in table 1 that the unsubstit-ited dye is colored more intensely
than the corresponding IN-alkyl-3ubstitnted dyes and that the
substitution of the phenyl radicals for the hydrogens of the
amino groups is without any effect cri 'he shift of the ab-
sorption maximum. The aniline derivat"ie is readily hydrolyzed;
the acid suppreoses hydrolysi!j; in ricid solution the extl4nation
coefficient increases by more than two times whereas the ab-
sorption intensity of the secondary am;ne derivatives is
hardly changed by the additicn of acid. It could be concluded
from a comparison of the data given in ta~'.~ 1 "hat "he
Card 1/3 derivatives of the secondary amnines are not hydrolyzable.

Pyridine Dyes, Derivatives of the Secondary Amiries
SOV/79-29-3-24/61
Table I illustrates the results of the optical changes of the
freshly prepared solutions; on the determination of the
variation in the color intensity of the dyes in the tame ccurae,
in dependence on the concentration, It can be seen that the
derivatives of the secondary amilnes hydrolyze as well, the
more rapidly the less the basicity of the cation and thil con-
centration of the dye ia. An can further be scon the N-methyl -
substituted dye hydrolyzes letat, considerably, however, the
diphenylamizin derivative. These facts show that the hydrolysis
of derivatives of the secondary arJnes is also related tc the
basicity of the cation the degree of wh4 ,ch is determined not
only by the nature of the r~~dical b,-It ais~ by itu VOIUMO~
Figures 1 and 2 present the abscrpti~n spectra of the dyes cf
the diphenylamine and mothylaniline derivatives In neutral,
alkaline and acidified alkaline medium. Figur.-?3 3 and 4
give the spectra of the corres-.1ondini, mcneanils of the
glutaconic aldehyde. Four pyri'd-ine dy~','s and twc
monoanila of the glutaconic ald,?~~-d,~ werfn synthesized. Fo,.~r
preparations are new. It ~o q3ju-e.i thcit the p, oculiar it', ~ 3 -_n.
Card 2/3 th(! dyeing of the N-alkyl_sub3tit%t---J dy,~s and their ~.'Lea-;aC-

SO 7, '7,2 2 '.
Pyridine Dyes, Derivatives of the Seccndary A::;4.re.9
ASSOCIATION:
SUBMITTED,
Card 7/7~
under the influence of alkali liquor are due to
of the spatial arrangement which is inaicated ly their
-3orption spectra. There aro '# figureo, 3 tnblos, arnd I? ref-
eronce3, 11 of which are Soviet.
Khargkovskly gosudarstv,~nn.,-y uziivursA`tt~t (Khar"kc".. 3tat;~
University)
January 28, 1956

5(3)
AUTHORSs Voynova, V. N. 30V/79-29-5-57/61
and Dukina, L. M.
TITLE: Unsymmetrical Pyridine Dyes Olesimiaetrichnyye
piridinovyye krasiteli)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 5,
PP 935-940, (UOSR)
ABSTRACT: It is known that the color of the unsymmetrical dyes
represents in a certain degree a "molecular mixturell
of the corresponding symmetrical dyes; the color of thc
unsymmetrical dyes has, however, not always an additive
character (Ref 1). The authors completed the chemical
and spectroscopic investigations reported in references
2-5 and analyzed the absorption spectra of 17 pyridine
dyes obtained b;~ them according to Zinke (Ref 6). These
dyes were qynthesized by the condensation of the
N-substituted monoanils of the glataconic aldehyde with
aromatic amines in the areuence of acid according to the
well-known scheme 1. In order to avoid the disagreable
Card 1/3 intensification of the color of the alcohol solutions of

Unsymmetrical Pyridine Dyen
SOV179-23-3-37161
the dyes by hydrolysio hydrochloric icid vias added to
the alcohol solutions in the spectroscopic investigation
of unsymmetrical dyes. Table I gives the data of the
optical determinationi of' the. unaymmetrical and the
corresponding symmetrical pYridine dyes. The maximu-n
values of the symmetric-al does, the 3eccndarj amino
derivatives, are presented in column (I), the primari
amino derivatives in column III), the calculated
Dilt-01). 2y ~i comparison of
additive maximum in cola::in 2
the data Civen in triblo 1 It r!iri b4! t;n,,-tj th:st ther colorcil'
eight dyiii la of additive nature,
that in six dyes (1,4,6,7,11,14) a hypsochromic shift
from the additive maximum is observed and that in three
dyes (9,15,17) the maximu,:, moves in the direction of the
long waves. It is thus seen in most of the CWIC'S that the
change in the color depends on the chang
.,c of the basicity
of the amines which form the molecule of the unsymmetrical
Card 2/3 dye (according to Kipri-inov, A. I. nnd Pil~-ugin, G. T-)-

Unsymmetrical Pyridine Dyes
3()7/79-29-3-37/61
There are 2 tables and 9 references, 6 of which are Soviet.
ASSOCIATIONt Khnrlkovokly gosudarstvennyy univer.,iitet (Khtoekov 3tqte
University)
SUBMINTED: January 28, 1958
Card 3/3

-.3610 7 -5
9
AUTHORS: Cirigorlyeva, 11. Ye., Glrtoe, 1. K., 1,~,ubit,;kaya, T. A.

TITLE Products of lLydrogenlatlon of N-pht--nylpyr1d1n1Lffn
Chlorlde. Condensatlon uf N-pheriylpiperldlnium
Hydrochloride WIth j)-Dimr--tiiylat-,iltiobeiii-,~ildehy(le
PER10DICAL: Zhurnal obstichey Ichlrill, l('60, Vol 30, Nr 3,
PP 1031-1037 (USSR)
ABSTRACTt This is a continuation of pri~~vious work (11. Ye.
Grigorlyeva, A. B. Organeslyan, I. A. My-sh, ZhOKh,
27, 1565, 1957) on hydi,ogen-ation of N-phenylpyridinium
chloride (1) over a platinum catalyst under different
conditions. The method u3ed wa,-, de.,icrlbed previouily
(see above reference). Cozideri:~ation of N-phenyl-
piperidinium hydrochloride (II) with p-dimethyl-
aminobenzaldehyde (11I) wa.-, aljo studied. It was
fovind that an hydrol,,oiiation ol',* (I) over a platinum
catalyst, a mixture of N-phenyl- and 11-cycio-
hexylpiperidinium hydrochlorldet-, I-, Cormpd. The
Card 1/3

Froducts of Hydrogenation of' N-phenylpyridInItim 76305
Chloride sov/79-30-3-59/69
hexylpIperidInfum hydrochlov1de.,3 Is f*or:ried. The
ratio of' the two hydrochloride. In the mixture depends
on the conditions of' hydi,ogenatIon. Condensation
of (II) with (III) in acetic anhydride first form.3
a blue dye. The latter Is unstable and on heating
decomposes with formation of a red dye. The blue
dye was riot Isolated. It- color Is very close to that
of Mlchler-'r, benzhydrol, Etr-,~l 11~, Is t!-,at,
they are atialog,.- Thf! ve(l dy#~~. !--~ -ooluble
In water, more joluble In and d1chlorcethare.
It does not crystallize, and ha.,i the following a~sorp-
t1on maxima: In alcohol ll(-'O, III Witel' 501i, and Iri
dichloroethane 5011 111 It 1,, ~,,tiggeoted that the re-d
dye Is a salt With ti,tictuve 1:
Card 2/3

Products of' Hydrogenation of 11-phvnyl-
pyridinium Chloride
ASSOCIATIONi
SUBMITTED:
Card 3/3
c11,
\N'
sov/79-30-3-59/69
b
There are 2 figures; 2 tables; and refevences,
I U.S., 2 German, 2 Soviet. The U.S. reference Is:
C. F. Winans, H. Adkins, J. Am. Cherti. Soc., 511, 306
(1932).
Kharkov State University (Kharkovskiy gosudarstvennyy
universitet)
September 1, 1958
T_4

GIRIGORIYEVA, N.Ye.; KRUGLYAK, L.P.j SHCHERRAKOVA, L.I.
Absorption opeotra and structure of glutacona2dehyde dianils.
Zhur.ob.khi:-n. 31 no.8:2599-26Q4 Ag 161. (MMA 14:8)
1. Eharlkovskiy goeudaretvennyy universitet.
(Glutaconaldehyde) (Amines--Spectra)

GRIGORIYEVA N.Ye.- SHCHMIJAKOVAP L.I.; GINTSE, I.K.
- 2 --- A
Catalytic hydrogenation of di&xLUo of glutaconaldehyde and their
o1a to (pyridine dyes)* Ukr.khim.zhur. 28 no.7:848-851 162. (MIRA 15:10)
1. Kharikovskiy gooudarstvennyy univeroitet im. A.M.GorIkogo.
(Dyes and dyeing) (Glutaconaldehyde) (Aniline)

GRIGORIYEVA, N.Ye.; RODIONOVA, L.A.; S!:GJZWtKOVA, L.I.; Ty7jPA, D.P.
Certain transformations of glutaconaldehyde dianils. Zhur.
ob.khim. 32 no.2:493-301 F 162. (I-IM 15:2)
1. Kharlkovskiy goeudarotvennyy universitet.
(Glutaconaldohydo)

S/062 63/000/002/UO4/02'0'
B1447BI66
ALITHORSo Mayranovokiyl S. G., Grigor'y-eva-,__t._1m,., Burashkova, H. V.,
and Kucherov, V. F.
TITM Conjugation factors in cyclic eyetems. Communication 6.
Polarographio and potentiometrio study of electron interaction
offeoto in cyolohexadintio-1,2 dioarboxylio acids and their
methyl esters
PERIODICALs Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no. 2, 1963, 240 - 245
TEM Cyclohexene and cyolohexadiene-1,2 dicarboxylic acids and their
dimethyl eaters were studied polarographically and potent tometrically to
clear up the problem of possible interactions between the double bonds of
the rIng. The polarograme of
0 CH CO CH CO CH
2 3 2 3 2 3
02 CH OFC02 CH3 C02CH
3
Card 1/3

3/062j63/000/002/004/020
Conjugation factors in... B144/B1a6
CO2CH3 rNFCO 2CH3 0 2CH3
CO2CH3 1',, /ICO2CH3 02 CH3
(IV) (V) (VI)
were taken at 250C using 0.05 M tetramethyl ammonium iodide solution con-
taining 9.5%, by volume ethanol. The effect of pH and ionic strength was
inve3tigated in borate buffer solutions (P11 7 - 10-5), 0-1 N MaOll, and
potassium chloride solutions. The anode was an Hg electrode, the reference
electrode was a calomel half-oell. The ionization constants were determined
at-j200C and init4al concentratione of 1,,0.001 11. For all compounds except
III the reduction wave was pfl-independent or I, II, V, V1 the ion trans-
ferenco number Is 2, the diffusivity 6.5,;0-9 CM2/sec. The polarographio
curves showed two steps; the difference between their B 1/2 could be altered
neither by incren8ing the depolarizer concentrstion nor by raining the
temperature and ionic strength of the solutionnorby varying the height of
the Hg column. This indicates that the two reduction steps are irreversible
and occur due to hydrogenation of the double bond involving formation of a
relatively stable free radical intermediate. 1%) 1V, the two double bonds

Conjugation factore in... B144/3186
are hydrogetiated successively. Electrochemical reduction was-, ababnowts-118W.
where the double bond is conjugated with neither of the two GO 2OR 3 groups"
All this wan confirmed by the analogoun relation between Ionization con-
atanto and utructures of the corresponding acidn. it was found that the
eater is more easily reduced and the dissociation constant of tho aci4l
increases on conversion of I and V into II and VI respectively. Since the
steric interaction of the &tome does not change# these effects must be
attributed to Fin electron interaction between the isolated double bonds in
11 and VI. There are 3 figures and I table.
ASSOCIATION Inatitut, organicheakoy khimii im. N. D. Zelinskogo kkadsmit
nauk SSSR (Institute of organic Chemistry imeni W. D,. tellaskly
of the Academy of Sciences USSR)
SUBMITTEDt May 10, 1962
Card 3/3
-P,

BELOV) 1,, inzh.; GIUGOXI-=A,_O,, Inzh,
"Topaz-211 and "Start-211 pocket radios. Radio no.9:38-39 S'63.( RA!6:
1. Institut radioveshchatellnogo priyema i akustiki imeni A.S.
Popovas

CRIGWYEVIA, (). A.: ~Jartor Mod Sci (dirs) -- "Clinical obseinmtions in acuto
hepatitis treated with Intravermi (h-op txansnision of t:..lucosell. Lenint~rfvl, 1")"),10
17 PP (joeningrad rodlatwlc Med Inst), 250 copies (fm, NO r, vr),?, 1,1.1)

KIIONHLOV, V.V.; GRIGOR'YEVA, O.A.: RIVLINA, N.Ya.
Accuracy of the spectrum determination of the content of a series
of elements in metallometric samples. Zap. LGI 39 no.2:149-162
161. (MIRA 15:2)
(Ores--Sampling and estimation)

GRIGORIY.EVA# O.A.; KVYATXGVSKIY, Ye.M.
Ifighly sennitive double-are muthod of spectrograltle antily,11--
for the detection cf gold and some disseminated ele-ments.
Zap. LG1 45 no. 2;74-80 163. Okllrul 1-?:5)

L nD72-65 WT(M)1XIT(C)1ZWA(d) EWPW/T Pc-h/I`r44/Pv-4/Pi-4 UL/
AM7TF~ASD(&)-5/ESD(dp) RKM jW/JD
ACCESSION NR: AT4047300 S/3115/64/000/021/0344/0358
(,6)
AUTHOR: -Burovoy, 1. A.; Yemel'yanov, S. V.; Moroiova. K. S.; GrIgorlyeva, 0. A.
TITLE: The use of variable structure feedback systems In the controi of thermo-
chemical terogeneous processes
SOURCE: ~Scow* Gosudarstyenny*y InstItut tsvstny*kh metallov. Sbornlk nouchny*kh
trudov, no. 21, 1964. Matematichesklya modell tekhnologicheskikh prot3essov I
razrabotka sistem avtomaticheskogo regullrovanIY8 5 peremennoy strukturoy (Mathe-
matical models of technological processes and development of variable structure
feedback systems). 344-358
TOPIC TAGS: variable parameter control system, automatic regulation, heterogeneous:
process, thermochemIcal process.
ABSTRACT: The most convenient and effective regimes for thermochemical hetero-
geneous processes cannot be controlled by linear methods because the variables
which must be controlled are described by nonlinear differential equations with
unstable singularitles In the phase plane. The stability of these points depends
largely on Initial conditions, so that In order to accommodate realistic distur-
bances In the system, feedback controls with variable structure must be used.
Using,W method of multi-sheeted phase planes, developed by V. Ve Petrov and
Card

11 UO72-65
ACCESSION NR: AT4G47300
G. M..Ulanov, the authors studied the phase plane topology as a function of the
sign and magnitude of the static gain coefficient K, of the control system. This
Is done by assuming a process with two slngularltla~ only, deriving the expressions
for their phase plane coordinates for processes limited by constant velocity of
he-t face che-mIcal reaction or concentration of the gaseous component, or by
both4,urnd Invastljat_1ngtheba~havlor ~of t-hase ~c-oordI6-aites a-sK. c anges. was
~
discovered that If M crIt;#tboth singularities change pl9cas and lfo~l Kp
crit than does I ln?luenc he coordinates very much. This leads t he
conclusion %tat I fthe system structure (Y Is varied during the transient pro-
cess, the system can be organized in such w3y that It will return to the origtn
from any given Initial point and will have a very wide (sometimes unlimited) stabled
region. OrIg. art. has: 13 equations and 8 figures,
ASSOCIATION: Gosudarstvenny*y Institut tsvetny*kh metallov, Moscow ~$tate
SUBMITTED: 00 ENCU 00
NO REF SOV:.11003 OTHERS. 002
Card 2/2
SUB CODE: le'~W

GRI VA~ O.D. (Ioningrad)
Intravenous drip infusions of glucose in -Boticin's disease. Klin.med.
35 no.8:106-109 Ag 157. (KIRA 10M)
1. Is fakul'tetskoy terapsyticheskoy kliniki (zav. kefedroy -
zasluzhennyy dayatell neuk prof. Y.A.Valldmen) leningradskogo
Pediatrichaskogo meditsinskogo institute.
(HIMITIS, INECTIOUS, ther.
glucose, intravenous drip infusions)
(GLUCOM. ther. use
infect.hepstitim, intravenous drip Infusion)

GIIGORIYEVA, O.D.,, kandomed.nauk
Dynamics of serum protein fractions in acute hepatitis. vor'.
pat. krovi i krovoobr. no.5:69-61 '59. (14I;-.A 15-4)
(HUATITIS9 IWMTIOUS) (BLOOD PROTEMS)
(PAPER ELECTROPHORMIS)

GRIGORIYEVA, O.De, kand.med.nauk
Electrophorotic studies of blood protein fractions and hemo-
sedimentographic observations in rhe=atic fevore Vopepat*
krovi i krovoobore no*6t73-79 t6l. (MIRA 1613
(EfEMTIC nTM) (BU)OD-SEDDMTATION) (EWD PROMNS)
4-~

SMMIOVA, A.M., kand.med.nauk; ~RI O.D., kand.med.nauk
Clinic4l serological parallels in rheumatic fevvr. Vop.pat.krovi
i kravoobr. no.6:8048 161. (MUU 1613)
1e 1z Fakulltetakoy terapevticheskoy kliniki Leningradokogo pedia-
tricheskogo meditsinskogo institute, (zav. - prof. V.A. Valldman)
i Otdela mikrobiologii Instituta eksperimentallnoy meditsiny AHN
SSSR (zav. - chlon-korrespondent AHN prof. V.I. loffe).
(MiEUMATIc nTER) (SEROLOGY)
-.T

r Rrid f- ft I
t 1
ri Ix t I!;,
me. 11 to if; ~Aoilc, r- I I t I tJI dE 14 7 .,j- 3
I j j k

Grii,'01"Yeva, 0. G., ResiuLance of' coa.,it,o iwint I)y L,
n, Tr. Goo.
gidrolog. III-ta (WOrIM of' thu Stitte lVdrological. In.;tItute), p 5-28;
(MiGeofiz 1/60-M)

tl;RlTr!OR'TNA, 0. Ctind GF~q-~r Sei (diss) - - r,,slls'.anc,~ to wavF- acl.!on of
shorelinrs composed of coliesive and semtrock stonp". Inin,-rad, lq,~O. 17 pp
(Lenin-,rad Ord,-,r of Lenln State U Im A. A. Zlhdanov), 225 cop!es ('~---No 15,
1940~132)

GRIGORIYIVA, O.G.
Laboratory determination of the resistance of rocks to
the action of waves* Trudy OGI no.74:71-88 160.
(KIU 13: 7)
(Rocim-lestlog) (Beach erosion)

GRIGORIYEVA, O.G.
Comparing calculated and natural profiles of coastal rhallow!.
Trudy GGI no.8809-76 161. (MIRA 15:2)
(Coasts)

G GOR I
General forecast of cbanges in the banks of the Volgograd
Remervoir. Trudy GGI no.108:68-88 163. (MIRA 16:6)
(Volgograd Roservoir-Shore lines)

Ev, C.
p r f 1
I
of baris TrAy
~."!7-`. 17: 12;

SWIRO, I.I.; AMOV, F.G. Prinimali uchastl": PSGUSHEY, M.Te.;
GRIGORI j STOYA.
POPOTA, L.P.; GONCHAROY, M.Ts.; TOLKI
,T
(XIIIA, G.Ye., tokchn.red.
(General machinery industry tims norms for establishing norms
for milling machine operations; small-lot 3nd piece production]
ObahchemashInostroltellur normatIv7 vremeni dlia tekhnichaskogo
normirovanlia robot no frezernykh stankakh; malkoserilnoo i edi-
nichnoe, proisvodstvo. Moskva. Gos.nauchno-takhn.izd-vo mashino-
stroit.lit-ry, 1960. 142 p. (MIRA 14:4)
1. Moscow. ?Sentrallnoye byuro promyshlonny),.h normativov po
trudu. 2. 7aveduyushchly otdolom mashinostroyeniya TSentrall-
nogo byuro promyshlennykh normativov po t d ri N chno-
isoledovatellskom institute truda (for Sh7piuroK nu
(Metalwork-Production standards)

GRICCRIYEVA 0 P
V.G.Shtofkn an a scientint and teacher. Biul.MDlP.Otd.blol. 67
no-5:150 S-0 162. (MM 15:10)
(SHTEFKO, VLADIMIR GERM&NOVICH, d.1945)

POLUSHRIA, T.V.; RUDIIITSKAYA,
Antishock fluid on the basis of plasma albumin in donor blood.
Probl.-gemat. iperel. krovi 5 no.3s52-55 Mr 160. (MIRA 14'-5)
1. Iz TSentrallpogo ordena Lenina instituta, gematologii i perelivanlya
krovi (dlr. - keystvitelonyy chlen AMN SSSR prof. A.A.Bogdasarov).
(SHOOK) (ALBU14INS-THERAPEUTIC USE)
1.

GRIGOR1M'.,',, O.V. and KFLIZON, 1,.S.
"The Dynamics of Proportional Navigation." Notes of the Leningrad
Higher Engineering Naval Academy im. ndmiral S.O. Wnkarov, Issue
1957- -,.;. ,.') . 11,

LUTHORt A.S. and Grigorlyeva,O.V. SOV/20-121-3-10/47
Kel'zon
,
(Leningrad)
TITLEs The Proportional Wavigation as a Problem of Cybernetics
(Proportsionallnaya navigatsiya kak problema kibernetiki)
PERIODICALs Doklady Akademii nauk SSSR,1958,vol 121,Nr 3,pp 432-435(USSR)
ABSTRACTs Starting from the papers of Fewell LRef 1) and Spitz LRef 2]
who investigated the kinematics of guided missiles, the authors
consider the dynamics of guided missiles under proportional
navigation and the suitable choice of a control of motion which
would guarantee a stable tending of the object to the target.
The consideration of the dynamic equations for the considered
motion admits to explain partially the apparent discre anciea
(the necessity of non-hitting) in the papers of Looks fRef 61
and Adler [Ref 91 .
There are 10 references- 3 of whioh are Soviet, and 7 American.
ASSOCIATIONs Leningradskoye vyssheye inzhenernoye morskoye uchilishche
imeni admirala ?TnkArova (Leningral HiOier School of lqaval
En'l-intering imani Admiral Mlkurcv)
PRESENTEDs 'Y"arch 27, 1958, by V.I. Smirnov, Academician
Card 1/2

4a 0
AUT:4URS G r i & 0 r I Y cYAq- U. V. ,
TITLE: The calculation of
guidance problems
FENIODICAL: Jzvestiy~j vys.-illij,11
Aviatsionnaya tekirlika,
~:/147/61/OOU/004/003/021
E031/E184
and Ke Vzon, ,,. S.
control inert ja it, c(.~rtaijl
jjcjjebljyj~LI I V., '6-t, (It, tj I-y
no.' , 11)61, 2~-'-"q
"' I
-:XT It has been shown that all est ivjttezi (if
manoeuvrability based on the value of the normal acceleration
of the centre of inertia are inadequate. The conditions of
stable missile guidance with consideration of the inertia of
the controllini; airfoil are discustied for tht,, following ca!3es
of .1) with a zero lead angle (pitro purtiuit cotirqe);
2) %,rith a constant lead angle (deviated pursiiit course); and
3) with the'use of the proportional navigation course (approach).
The limit values, in pursuit courses, of the velocity and
acceleration of the control-flap declination in the filial stage
of approach are determined from given formulae for certain
values of It = vs/v (vs speed of the target, v = speed of
missile inertia centre). In the proportional navigation course
Card

Th(_. :,Itions of control inertia. fi/l"17/61/ooo/ot)"i/oo-71/021
*EO31/El8,,i
equatAon '~ of motion are given for the navigat ior,a I I-t ion
A = 2 ; L h o ~-, o 111 t io 11 shot"_', tild, -c la t. I olis I I I p 1, " i .. i, , ~1~ ~i rl~~ Ie of
contro 1-f 11,% 1) tl(~c 1. irwit ion and t if(,- lead 1 4~ . T~,, I , rt~ 1 -! t I onfilli p
ensures that toi- controlled object will t'o I 1mv. the ti "jectury
exa c t ly. The Condition for hitting the t.tr~,:et is 1) >1 (p=1/1,;).
The stability boundaries for guidance of the mi.-;54f Ie ill the
firlal St;AS(' 11-e Ca ICU lated from the turnin,~ rate of the pa t. h
while velocity and acceleration are determined from thQ control-
fla,) declination. The results are plotted in a dlagrat:i f rom
which the effect of the control-f tap inert la can be determined.
$ ince thf~ pursu j t courseLq are part j cu I ar ca.5e.,5 of the. proport iona I
navi.c_iAtion course with A = I , it is conclujed t~j;it. the increatie
of t!1(! llovigatiollill Correction widells the I it y
the -uidalice of a Inissile in Lhe final tit' its
There are 1. figure and 2 tables.
ASSOCIATION: Kafedra teoreticheskoy mek-hArliki, d!ikove
vy!3slieye inzileneriloye morskuy., och i, I 1~-,hchv
(Department of Theoretical J,on~ngvad
C,~trd 2/21 Naval Enginnering 1'1~gh School)
S 1: BY I TT E D january 23, 1961

GRIGORI)~".V.; KELIZON,, A.S.
Considering the inertia of the rudder in some problems of
pinpointing, Izvvyo.uchebozav.; av.tekh. 4 no.4:22-29 161.
(HIM 15t2)
1. Ioeningradskoys vyssheye inzhenernoye morskoye uchilishche.
kafedra teoreticheakoy mekhaniki.
(Bombing', Aerial)

FEDOROVA, L.I.; GRIGORIYEVA, O.V.1 KOZINETS, G.I.
Preparation of plasma by formation of Increased pressure in
flasks. Probl. gemat. i perel. krovi 9 no.3t57-58 Mr 164.
(MIRA 17s10)
1. TSentralInyy ordena IAnina institut gematologii i perelivaniya
krovi (dir.- dotsent A.Ye. Kinelev) Ministerstva Mravookhranenlya
SSSR.

GRIGORITIVA, P.Y4.4jots.
A.F. Koni and his work in the field of Passian forensic medicine,
Trudy LNI 2.,295-300 155 (Nnu 11:8)
1. Kafedra, sudobnoy meditsiny (sav. - prof. A.P. Kurdymov)
Pervogo Laningradskogo seditsinskogo Institute ImenI akadealka
I.P. Pavlove,
(MVI. ANATOLII FREDCROVICH. 194-4-1927)
(MICAL MISPRUDOGS)

DONIGISVICH, M.1.9 kand,med.nauk; GRIGORITIVA, R.I., kand.med.nauk; ZHUCHKOVA,
L.O.; XADOWSMVA. P.P.; SiMINOVA, X.P, (Nor-dovskaya ASSH)
Organization of psychoprophylactic preparations for all p&rturients
in Saransk. Top.okh.mat. I dot. 4 no-5:74-78 S-0 '59.
(SAW SK--CHIUM MrH-PSTCHOWOT) (KIRA 13:1)

SOV/110-59-6-3/24
AUTHORs Sakovich, A.A., Candidate of Technical Sciences;
Grigorlyeval Rol., Engineer; Grigorlyev, V.S., Engineer
and Blonds I*Vol Engineer
TITLEs An Investigation of a Titanium Absorption Pump
(lealedovaniya titanovogo absorbtsionnogo nasona)
PERIODICAL:Ventnik elektropronyahlonnosti, 1959, Nr 6, pp 13-16 (USSR)
ABSTRACT: Existing types of vacuum pump are subject to various
operating difficulties when installed on high-voltage
valves. The pump here described is based on the
principle that titanium does not react with mercury but
can absorb gas when hot. Hot titanium reacts
irreversibly with most gazes and volatile organic
compounds. Theme substances penetrate the crystal
lattice of the t1taniums forming solid solutions. Zxcept
for hydrogen, gases thus absorbed are not released during
subsequent heat-treatment under vacuum. This principle
formed the basis of the model absorption pump which is
illustrated diagrammatically in Fig 1. The absorber in
a block of porous titanium containing a heater. Because
different parts of the block are heated to different
Card 1/5 temperatures different gases are absorbed. The device

SOV/110-59-6-3/24
An Investigation of a Titanium Absorption Pump
was found to be fairly effective at pressures between
0.5 and 0.001 mm Hg. As porous titanium contains a
considerable quantity of occluded gas, prolonged
de-gasification was necessary. The device does not
absorb inert gases and evolution of hydrogen is possible
if the thermal conditions are unsuitable. Titanium
absorbs gases beat when it in condensing on a surface
and attempts have been made to use this principle in the
construction of pumps. However, as pumps of this kind
are complicated and unreliable, improved methods of
atomising titanium were sought. It was accordingly
decided to locate the titanium in the mercury cathode
and atomise it by ionic bombardment in the presence of
a cathode spot. A model absorption pump constructed on
this principle is shown in Fig 2i it in installed in a
high-voltage valve. Authors' certificate Nr 111517 of
Ilth March 1957 has been taken out by three of the above
authors for this device. The titanium electrode in on
the centre line of the valve and is surrounded by an
Card 2/5 auxiliary electrode at a positive potential. When

An Investigation of a Titanium Absorption Pump
SOV/110-59-6-3/24
negative potential is applied to the titanium electrode
an ionic current passes causing atomisation. The
atomised titanium in deposited on a screen and on the
auxiliary electrode, creating an active surface that
effectively absorbs the gas. The screen protects the
internal parts of the valve from contamination with
atomised titanium. Some results of tests on the
absorbing power of atomised titanium obtained with this
model are plotted in Fig 3. It was found that when
pumping air the lower limit of pressure is below
2 x 1o-5 mm Hg. The weight of absorption with a current
of 2.5 mA and a voltage of 2~5 kV for various gases is
tabulated; the figures relate to a volume of 20 litres
with an initial pressure between 60 and 70 microns Hg.
The electrical circuit shown diagrammatically in Fig 4
may be used to supply the electrodes of the device.
Employing this simple circuit, it was possible to make
up a sample titanium absorption pump and instal it in a
mercury rectifier type VR-3M as illustrated
Card 3/5 diagrammatically in Fig 5. The valve was subjected to

An Investigation of a Titanium Absorption Pump
SOV/110-59-6-3/24
-the usual manufacturing cycle of vacuum treatment and
forming. After evacuation by a mercury pump, the valve
was connected to the absorption pump, Tests were then
made on the rectifier on a low-voltage bench and at
high voltage using an equivalent circuit. The electric
strength was checked periodically by static tests. The
valve was maintained for 2000 hours without the mercury
pump in use and operated under load for about 400 hours;
there was no came of pump failures When the valve was
left for a long time without pumping, leakage caused the
internal pressure to rise to some 5 or 10 microns Hg
but when the absorption pump was connected the vacuum was
soon restored. A defect of the pump is that it absorbs
inert gases only very slightlyg hence, if there is an
appreciable ingress of air, atmospheric argon may
accumulate in the valve. The service life of the
absorption pump, though not yet established, is likely
to be considerable and can probably be made of the order
Card 4/5 of 10000 hours. The power required for the pump is about

An Investigation of a Titanium Absorption Pump
sov/ilo-59-6-3/24
100 W, most of which is absorbed by the auxiliary
electrode. By a slight change in construction the
latter could be used as an excitation anode; the power
required to operate the pump would then be considerably
reduced. One of the advantages of the pump is its high
pumping speed at low pressures. A disadvantage in the
presence of a high voltage on the auxiliary electrode
which, amonst other things, limits the upper pressure to
between 200 and 500 microns Hg: beyond this limit
corona occurs and atomisation of the electrode is much
reduced. There are 5 figures, I table and 3 references,
I of which is Soviet, I English and I German.
Card 5/5

liv.)TOMOV. V.K.; ~OLGV. V.b.
Relation between the structure of orpnin compounds nnd their
odor. lienort N,7.4: Synthesis of 3-(41-tort-butyl phoivl)-2-
T-ady VNIISNDV nn.!?:19-'1')1 1514. 0 -,iA V':7)
groixD) (Proplonaldehyde)

I- ---- GRIGOR'731VAO S.
. , -- -, : -1 .
Fr~tt growers frm the Urals. Worov's 2 no.9:26 s '56. (min 9:io)
(URAL NOUICAIN PJIGION--"UXT CULTURI)

GRIGORIYEVA, S.
Vacuum cleaner In the service of science. Zzian.eila 35 n0.1!
6-7 Ja 160. OGRA 13:5)
(Seed industry)

SAMARINA, V.S.; NOVOZHILOVA, Ye.V.; GRIGORIYEVA, S.A.
Formation of the salt composition of underground water in some
regions of Central Asia. Vest. IZU 17 no.12:22-31 '62.
(MIRA 15s7)
(Soviet Central Asia-Water, Underground-Composition)

KUZNZTSOV. I.P.; FOIAK. A.Y.; RRIC~~ITNTA, M.
Rapid construction of petroleum refineries In Bashkivia.
Prom.strole 38 no.6:28-29 160. (m," 13 -, 7)
I* Inatitut B"hN113troy (for Grigorlyaws).
(Ushkiria-4fttrolaux refineries)

GRIGORIYEVA, S.I., inzh.; FEDORTSEV, I.V., Inzh.
lArge.-block assembly of tubestills. Trudy BashNIIStroi no.1-
109-121 162. (KIRA 17:3)

ANTONOV, A.S.; LAYKOVA, N.F.; IVANOVA, P.V.; GRIGORIYEVA, S.P.;
BELDZERSKIYP A.N., akademlk
Changes in the amino acid composition of fibroin of the silkworm
Bombyx mori L. induced by the analogs of the nitrogen bases of
DNA and RNA. Dokl. AN SSSR 155 no. 5:1201-1204 AP 164.
(MIRA 17:5)
1. Mookovskiy gosudarstvennrj univer3itet im. H.V.Lomononova.

7
BELOUSOV, M.S.; POKLADA, I.I., prof.; BEZRUKIKII, P.S.; BARNGCLITS,
S.B.; ZLOBINA, P.P.; GRIGORIYEVA S T - MEDVEDEVA, R.,
!%A~! P
red.; TELEGINA, T., tekhn. red.
[A course in accounting] Kura bukhalterskogo ucheta. 2.,
perer. i dop. izd. Moskva, Gosfinizdat, 1961. 488 p.
(MIRA 16:11)
(Accounting)

KOVAIMIO. N.I.; GRIGOIRITIVA, T.A.
1 -
. , -,
Optical activity, density, and molecular weight of oil fractions of
petroleum from the Saratoy field, Report No-5- Uch.zap. Sar.un. Typ.
fiz. 56:129-138 '57. (MIRA 12:11)
(S&ratov region-Petroleum)

-TffA13TrEVrZ.S., HUKlNA,Ye.A.,KIHB, M. & dilGall Y-,,'J A . A.
--"Fagin-Complex 1"paration for tlw Treatment of Refractorf Infected
~lounds."
SOi Byuls Skaper.Biol* i Mede 1944(g),(Quoted in Referaty 19h5)

GRIGORIEVA, T.A.
"Innervation Of The Internal Organs." (P.134) by T.A. Grigorieva (Moscow)
SO: Progress of Uontemporary Biolo (Usp. Sovrem. Biol.) Vol. DIVIII, lc,49, No. 1 (4)
(Jifly-Aug.)
- -- q~, i~~ _q, I --
- - I -

GRIGOR I TEVA, T. A.
29879
ImWervatslya kapillyarov. doklady akad. nauk SSSR. novaya oyeriya,, t. LXVIII, No. 3"
1949, a 589-92. - Bibliogri 11 aasv.
SO: L S T 0 P I S I NO. 40

GRIGORIYEVA, T. A.
Synapse in region of the capillary bed., Uch. zap. Vt. mosk. med inst. 2, 1951
Capillaries, USSR (600)

GRIGORIYEVA, T.A.
Cause of trophic disorders in regions of the body deprived of
sensitivity. Doklady Akad. naiik SSSR 78 no.2:387-390 11 May
1951.. (CIML 20:9)
1. Second Moscow State Medical Institute Imeni I.V. Stalin.
2. Presentod by Academician A.D. S.peranokiy 26 February 1951.

of t,~.(.
Sin 1~2, 'cron, "orcov --at(, ~.e~-ucnj ir;~t n.
(Dis-ertnti-on for th,~! i)c,lrcp, of Doctorate in
lechrrnnya J,=ar-y-Deccmbcr llfl~2

CRIGOROYIYA, Tatlyana Andreyevna; SHUBIN, A.S., redaktor; SACHITA# A-I-#
u kyl A rc-li ;-00 F-24,r
[Innervation of the blood vessels) Innervatmila krovenoonykh mosudov.
Noekva, Go@* Isd-vo, mode Ilt-ry, 1934. 373 P. (MLRA St3)
(Blood ves"Im-lumervation)

DOIDO-SOBUROV, B.A., professor. radaktor; GIBBILISKIT, N.L., redaktor;
redaktor; YILISEYIIV, T.G., redaktor; ZHDAKOT.
D.A., redaktor; KNOPPI, A.G.. redaktor KUPRITANOV, V.V., radektor-,
NIKHAYWV, T.P.. redaktor; PRIVNSA, N.G., redalctor; STUDIT$Kff. A.S..
redaktor; SHCHILKUNOVA, S.I., redaktor-, KHARASH, G.A., tekhnichs-
okty redaktor
[Problems in the morphology of the nervous system) Probleny morfologii
nemol alatear [Leningrad] Goo. izd-vo mad. lit-rr. Imningradskos
otd-nie. 1956e 179 ps (MIRA 10:2)
Io Chlen-korrespondent Akedemii maditainskikh nauk SSSR (for
Dolgo-Soburoy)
(UnTOUS SYSTM)

USSE/General Division. History. Classics. Personnel. A-2
Abs Jour., Ref . Zhur. Blologiia,, No 4, 1956, 14131.
Author Grigorev&_Z.A.
Inst
Title I.M. Sechenoy and His Thoughts on the Structure of the Nervous
System (On the Fiftieth Anniversary of His Death)
Orig Pub: Arkhiv anatcaii, gistol. i embriologii, 1956, 33, No 2, 7-13
Abstract: The numerous hypotheses of Sechenoy on the structure of the
nervous system, which were confirmed bylster research, are
cited. The under-estimation of Secbenov's hypothesis tbat
the inhibiting fibers are intercentral and end, not in the
skscles, but in the corresponding nerve centers, is pointed
out. Considerations an cited again t the newest propositions
on the interchangeability of nerve elements.
Card 1/1
-7-

GRIGM17EVA. T.A.; LUVICH, G.A. (Moskva)
Meeting of the Moscow Society of Anatomists, Hiotologists,
and Imbryologletso Arkh.anat.glstol enbr. 33 no-3:10D-101
Jl-S '56. (MIRA 12-.11)
(AWATONT--PMODIC&W)

. A- (Moskyap 1-41, 1-ya Neshahanskaya. d. 90/96
90
The structure of unnWelinated nerve fibers; review of foreign literature.
Arkh. anat. gist. i embr. 34 no.1:121-128 Ja-F '57
(KLRA 10:5)
1. Ix kafedry gistologii (zav.-chl.-korr. AN SSSR. zaal. deyat. naukil
prof. G.K. Khrushchov) I! Mookovskogo gosudaretvennogo meditainakogo
instituta im. I.T. Stalina.
(NIMUS, anat. and histol.
unmyelinated fibers structure. review)

XJJORIJ;TA-.Z.A. (Moskvn, 1-41. 1-ya MeahchnnekAya ul.. d.gn/96, ~v.q)
",toixrnn1 of comparative neurology"
1956. Reviewed by T.A.Grigorleva.
no.6:118-124 fi-D '57.
(N-,UROLOGY--MU IODICALS)
Lin Nngllohj, Vols.lo4-lo5.
Akrh.nnnt.gist. i embr. 34
(MIRA 11:1)

GKIGO;QmA-j-TvA.-, prof., red.; ZEIZNINO A.V.p kand, med. naui,.# red.;
SAVICH, G.A.9 1-cand. mod. nauk, red.
lftommtions of the First Conference of Young staff Members of
Morphological LaboratorieB in Moscow] Trudy pervoy konforentsii
molodykh nauchnykh sotrudnikov maskovskikh morfologicheakikh
laboratorii. Pod red. T.A.Grigorlevoi, A.V.Zelenina i G.A.Savich.
Moskva, Vses. ob-vo aratomovp gistologov i embriologov, 1959. 139 P.
OAIRA 15:4)
1. Nonferentaiya molodykh nauchrWkh sotrudnikov moskovskikh mor-
fologicheskikh laboratorJy. lot.
(14orp~ology(An:Lmals))-Congresses))

GRIGORITIU, T.A.t prof,
Kwous w"r no. Zdorovlo 6 se.6t9-10 Jo 160. (MIRA 130)
(Nmms xNalin)

GRIGORIYBVA, T.G.-.-
Results of testing baits to control agr1otes obscaras L. Trudjr
VIZR no.1:157-160 148. (MIRA 11:7)
(Click beetles) (Insect baits and ropollents)

I ~fl
so
dkma
go's it
A I al L L"IMUNI CLAIWKATNP
2#1401 *to diff set
AV so Is 1, -6 a
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elf
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141914ftf O"'Ai W 94.
" i I ?A &s&
is
00900*000000*00410
0 a a1 , A

ussR/Diology - Rexachlorane as an Insec- Dec 52
ticide
"The Effect of Hexachlorane Deposited in the
Ground, on the Fauna of the Soil," T. G. Grigoryeva.
(Submitted by the Section of Plant's Protection,
All Union Acad of Agric Sci. imeni V. I. Lenin)
Dok V-S ord Lenina Akad selkhoz nauk imeni V. I.
Lenina, No 12, pp, 16-20.
Describes the toxic effects of Hexachlorane on the
insect fauna of the soil in selected exptl sections
of the Leningrad Oblast. Observations over a period
of 3 years, revealed the potency of hexachlorar-e
in dwtvvylft haorul plant-40tUo inseci-g-aa-
FrQfttWI*S 1u =d SbOwO ground, Vith little or
.no orfact on rain ww , and. sow beneficial er-
feet on certain plants, resulting in increased
Croper of agricultural plants grovn on soil treated
with hexachlorame.
248T2

GRIGORIYIVA. T.0.; XARMVA, A.I.
7eeding specialization of the frit fly Oscinella pusilla Haig. in the trans-
Volga region. 9001-9hur. 32 no.5:893-902 5-0 153. (HLRA 6:10)
1. Veanoyuxnyy nauchno-iselodovateliskiy institut sashchity rastenly.
(Volga valley--Yrit flies) (Frit flies--Volga valley)

STIRK. V.S.; GRIGORIYEVA, T.G.
In mmory of Georgil gonstantinovich Fistnitskil (1900-1931).
Ant.obos. 33:376-379 153. MIA 7:5)
(Piatnitakil, Georgil Konstantinovich, 1900-1951)

GRIG OR I I-ATA. Tat 'yam Grigor lyevuu.
[~~O-C~two*rm Haden& baellIfnes and its control] Zervcyvye sovki i
bor%a a niml. Moskrap Goo. izd-vo sellcoz. lit-ry, 1958. 56 p.
(Grai&-Diseasos and posts) (Outworms) (MIRA 11:10)

GRIGOR;rEV -' starshly nauchnyy sotrudalki GLEBOV, M.A., startihiy
A I ,,,
nauchnyy notrudnik; FERSIN, S.A., starshiy nauchnyy Botrudnik;
FETRUKHAP 0'1., otarshiy nauohnyy sotrudnik; SLIVA, I.K.
Practices in effective control of the sugar beet weevil.
Zashch. rast. ot vred. I bol. 4 no.5:23-25 S~-O 159. (MIRA 16:1)
1. Vsesoyuznyy institut sashchity rasteniy (for Grigorlyeva,
'Uhbov, Persin). 2. Vsesoyuznyy nauchno-issledovatellskiy
Inatitut sakharnoy svekly (for Petrukha). 3. Glavnyy agronom
inspekisil po sel'skomu khozyayotvu Smelyanskogo rayonei,
Cherknaskoy, oblasti (for Sliva).
(Smela District--Sugar beets--Diseases and pests)
(Smela District-Weevils--Extermination)

GRIGORIYEVA) T.G.,-k&M.ael'skokhoz.nauk
Imediate tasks in the protection of grain crops. Zashch. rest,
ot vred. i bol. 5 no.9:1-3 S 160. (MIRA 15:6)
1. Zaveduyuohohiy 3,aboratoriyey po izucheniyu vrediteley
zernovykh kulltur Vaesoyuznogo instituta zashchity rastoniy.
(Kazakbotan-Wheat-Disoases and posts)

oRXoR, iTvA , 2. ra.
---- ---.---Nw-~-9e,nera1 law governing the formation of agroblocoenosem and
principles underlying the protection of plants on virgin lands.
Zhur. ob.'Ibiol. 23. no.6:411-418 N-D 160o (KIFA 14: 1)
1, Vessoyusnyy nauohno-iseledovatellskiy institut sashohity rasteniyq
Leninarad.
(RECLUMION OF LAND) (AGRICULTMULL PESTS)

GkIGOR'YXVA, T.G.
Factors determining methods used to protect grain crops in the region$
of reclaimed virgin and Idle lands. Aht. oboz. 39 no-3:509-520 160.
(MIRA 13:9)
1. Vnesoyuzwy institut sashchity rasteniy Veemo7uznoy akademii
sel'skokhozyaqstvannyykh nauk 1m. Lenina.
(Kazakhetau-Wheat-Diseases and pests)

GRIGORIYEVA, T.G.; TERSKHRI, E.S.
Diatribution of grain hugs of the genus Aelia, (Homiptera, Pentato-
0
midae) in the trans-Volga region and northern Kazakhstan. Ent.
oboz. 40 no.la19-23 061. (MIRA 14:2)
1. Vsesoyuznyy institut zashchity rasteniy Vaesoyuznoy akademii
sel'skokhozyaystvennykh nauk imani Lenina., Leningradr.
(Starays-Poltavka Distriot--4tinkbugs)
(Karabalykokiy District--Stinkbugs)
(11mat-DiBeases and posts)

-GRIGOR3?~~LAI T-G.
Some results of azxl prospects for studying the grain Fksts and
their control in areas where virGin land is beinf; brought under
'1-1-zhur. 41 no.10-17 Ja 162. 04IRA 15:4)
lo All-Union Institute of Plant Protection, Leningrad.
(Virgin Territory~--Wheat-Diseases and pests)

GRIGORITEVI, T.G.
Investigation of the soil fauna in virgin and cultivated lands of
the trans-Volga region. Vop. skol. 7t4o-41 162. (MIRA 160)
1. Vmooyusnyy institut sashchity rasteniy, Leningrad.
(Volga Valley-Soil fauna)
T'!

GRIGORI)EVAO T.G.
Raw crop farming and the main objectives of agricultural
entomology& Ent. obozr. 41 no.3:485-491 162. (MIRA 15:10)
1. Veesoyunzyy institut zashchity ratieniy Leningrad.
(Insects, Injurious and beneficiall