SCIENTIFIC ABSTRACT GRIGORYEVA, N.I. - GRIGORYEVA, N.E.

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• Collection: Scientific Abstracts
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• Document Creation Date: January 3, 2017
• Document Release Date: July 27, 2000
• Sequence Number: 15
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

GRIGORITIVA, N.I.
nicotinic said In the treatwnt of atrophy of the optic
nerve and of certain diseases of the fundus oculi, Test. oft., Moskva
32 no.4:23-25 July-Aug 1953. (GIML 25:1)
1, Candidate Medical Saleme*. 2. Of thi ]Ve Clinio (Acting Head -
Docent G. F. lushlaskly), Owerdlovsk Medical Institute.

USSR/Medicine - Veterinary,, Poot-and- Sep 53
P Mouth Disease
"Course of the ~oot-and.-Mouth Disease on a SuLux~)an
Farm," A,.pirant~~'N. I. Grigor'yevd~~'Chair of Anin-A
Byr,iene and Vet Medicine, Moscov Acad Agr Sci im.
K. A. Timiryazev
Veterinariya, Vol 30, 17o 9, pp 27-28
A total from 150 to 500 units of penicillin in a
0.25% --o1 of novocain administered intr==,-cularly,
in the vicinity of the cup-ncr area of each animal,
at the rate Of 5-10 cc per day for 2-3 successive
270T70,
days, proved effective in the trev-tncnt of foot-ani-
mouth di3ense. The weiGht, aae, ana conditton off
each rni:tal nust be tr-kcn into cons *.~Icr.-tion in
calculatin,7 the total =ount of penicillin to be
administcred. Rinsinz the oMl --nd msal ca%rities
proved beneficirl: I!p-2wp
vith the following solns p
solution c-' aluv, O-Z solution of ncetv-midc, r-n2
1:1,000 soln of potnssium perwnCrrnLte. Streptocid=
albun ointment proved very effectivo in the treat-
ment o~ th~~ teats.
270T79

"The Effect of ChanFlnv, the I-arameters of' a Thr, c-Cycle Mil~lnr M11chine on the
Condition of the Udder and the Health of the Cow." Cand Agr Sci, Moscow Order of
Lenin Acad of Agriculture imeni K. A. Timiryazev, Moscow, 1954. (K*,, No 1, Jan 55)
Survey of Scientific and Technical issertations Defended at USSR Higher Educational
Institutions (13)
S0j Sum. No. 598, 29 Jul 55

ZNAMNMKIY, A.A., dotsent; GRIGORIYKVA. H.1.. kand. eel lakokhoz. nauk
Stmly of the use of six-row cow she4u. Yotorinarila 36 noo7:
59-67 JI 159. (AIRL 12:10)
1. Voronozhakly sooveterinar Y institut.
(Dairy barns

Ly
lnvwdpdow 4f myvtsm with c6ncentrated hydrogea
C, ~toWs. IV. $4kW nu of tht feraitry systwn
S. Z. hts,
kam arA N. K. SmIC Acad. Sri, U.S.S.R..
Div. Mw. Sci. 1*94, t"Ritsi, C A
HA.

f3pitotto contAlmAe, rit-ci,tit"ted
%~ The thormal cbract~fjstics ,I t~~ !-IiA j+ lh~
a systent cAlcium hvJsox;.I,! hpirclcii S
Z. Mak..rrev m,1 -.N;. i~ Gi ij-r'v,v i P i,:i. I. -V
I q54 I I i j1 1, 1 L, -
1)". Ck,
.t v C :1 49, ili-.~,A.

GRi&oR Y6VAj N K
USM/Chemistry Peroxide Compounds
Card
Autbors Ma.karov, S. Z., and Grigoryova, N. K.
Nwe M '1-M
Title Investigation of concentrated hydrogen peri"ide systeru. Part 4. -
Solubility isotherms of a ternary CakOH)? - H202 - 1120 system
Periodical : I7.v. AN ScZS11, OW. Kh1m. Hauk., 31 385 - 3~1; May - June 1954
Abstract t The solubility isotherm of a tornary Ca(C11)2-H2&2-1120 System
characterizod by two solid.phases were. ostablished at-21 and -100,j by
studying the reaction between aqueous calcium hydroxide solutions ancl
concentrated 11202. Tha solubility isotherm at 00 is characterizc-J by
the presence of three solid phaves of described composition. The
effect of increased 11202 concentration on the establishment of the
equilibrium of the system, is explained. The effect of temperature,
at which the H202 solution solidifies, on the existence of CaO2-2H202
is also explained. Nineteen refervonces: 7 USSR, 4 French since
1818-1900, 1 German, 5 USA. Tables, graphs.
Institution : Acad. of Sc. USSR. Laboratory of ?croxide Compcunds
Submitted : July 2.9 1953

U=/CbenUtZ7 Peroxide oompounds
Card 1/1 PO, 40 - 3/27
Autbo" Makarovo S. Z. 0 and Origoryeva., No K.
Title I Investigation of system containing concentrated H202. Part 5.;
Thermal characteristics of solid phases of Ca(OH)2 - H202 - H2
optem
Periodical iIsT, AN WAM, Otd, kbim. nauk 4, 598 - 603, July - Aupst 1.954
Abstract tThe thermal characteristics of the three solid-phases of the Ca(CH)2
H202 -. H20 Mt8m., vere determined by the isothermal curve of the
system, It was established that octobydrate CaO2 a 8H2O and dihydrats
CaO2 a 2H20 of CaO2 deb7drogenate easily and convert into anbydrous
C&021 which remain stable up to 3WO. It was also found that the
thermal decomposition of this system in exceptionally rapid and
followed by a large Liberation of beat. Complete decomposition of
Ca02 was noticed at a temperature slightly Opp 3000, Four referencest
1 USSRj 2 USA and 1 Iftwh (1900 - 1954), Tablesj graphs.
T.astitution t Aoad, of So,. USSR,, Laboratory of Peroxide Compounds
Submitted i August 8,9 1953

YE- V
elm 'With coadoe" VII. I
at 9- of me ~Yst7#,m infadw-nRaIU-nir
Z~ 0. fl.
Afsksmv and N. 9; Qerm,eva. BmU. de-J It 'I,
Zi.&, Ijiv. ..Na. 1933,10,-17. C.A. w. 129M.
It. L. TL~~

160
USER/Chemistry Analysis methods
Cam 1A Pub. 40 - 3/27
Authors I Xakaroyj S. Z.j and Grigoryevap N. K.
Title I Study of systems with concentrated HP2, Part 7. The 0* isotherm of a
ternary NaOH 4202420 system
Periodical I Inv, AN 88M. Otd. khim. nauk lp 17-20p Jan-Feb 1955
Abstract I Uploying the solubility method the authors analyzed the 00 isothwn for
.the ternary system consisting of N&OH-H ra -H 0 in liquid phase* The
presence of three solid phases of a - K i;eoifio composition was
established. The derivation of perfectly stable sodium peroxide octohy-
drates (Na202# 8V in the form of lamin&ted crystals is described. De-
hydration of the octohydrates results in conversion into anh7drou:,N&202'
Six referencest 1 Russian, 1 USA and 4 German (1862-1912). Tabl. O&Pho
Institution t Acad. of Sa., USM, Tho N. S. Kurnakov Inst. of Gen. and Inorg.
Submitted t April 27s 1954

k" C Ole ~ T, k"'H/ /"\I" - (-~'
US,,Q.R/ Chemistry - Inorganic chemistry
Card 1/1 Pub. 40 - 3/26
Authors I 14akarov, S. Z., and Grigoryeva, N. X.
Title I Investigation of systems containing concentrated H202, Part 9. Tlierml
characteristic and stability of solid phases of the NaOH-HA-H20 system
Periodical I Izv. AN SSSR. Otd. khim. nauk 2, 208 - 215j Mar-Apr 1955
Abstract I The solid phases of a ternary (NaOll-H202-H20) system were Investigated to
determine the thermal stability and dehydration properties of the system.
:T:.e synthesis of sodium hydrogen peroxide NaOOH or NaZ02.H202 according
to the Tafel method is described. The system Na202.8H20 was found to be
a hydrate form of sodium peroxide. This was also confirmed by the Dresenco
of an endothermal dehydration effect. The properties,of sodium hydrogen
peroxide are analyzed. Six references: 4 German, 1 French and 1 USISR (187&
1955). Tables; graphs.
Institution t Acad. of Soop USSR, The N. S. Kurnakov Inst. of Gen. and Inorgan, Chem,
Submitted April 27, 1954
N

USSR/Inor&Lnic Chemirltry. Complex Compounds C
Abs Jour : Mfcrat. '.,hurnat Khimf.ya, rlej 6. 19571, 18W8
.'.uthor : 8 Z. R-tkarov. N.K. Gri3orlyeva
Ins t : -
T-Itle : On The Problems Concerning Product-on of Calcium
Superporoxyde C,.01,.
Ori j3 Pub : Zh. Neort:n. XhLmii, 1950', 1, No 7j, 1607 - 1612
Abstract : Bvsinz cn the results of exiDeriments ctrrLed olit with
a vtow to test the analytic methclz of the detormina-
tion of "molecular" and "active" oxysen conrents L"11
superoxid.,s o.'L* alkali aud. alkali-earth metale, as well
as of vxperimento Of Ca04 production by the methods
described in tile bibILo,,,rvpIX*, the authors ,trri-,e At
thQ conclusion that the biLlio,,Iraphic data re.-lardJiv,
tho existonce or C"04 taro not sufficicotly Gubatniiti-
ted.
Card 1/1

5(2),5(4)
AUTHORS: Makarov, S.Z., G i SOV/62-58-11--/26
TITLE: Investigation of Systems Containing Concentrated Hydrogen
Peroxide (Izucheniye sistem s kontsentrirovannoy perekislyu
vodoroda) 0
Communication XV. Isotherm of the Solubility at 10 of the
Ternary System Ca(OH),-H 20 2-H20 and Complementary Characterize-
ti8n of Solid Phases (Soobshcheniye 15. Izoterma rastvorimosti
10 troynoy sistemy Ca(OH),-H 202 -H20 i dopolnitellnaya kharak-
teristika tverdykh fez)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1958, Nr 11, PP 1269 - 1295 (USSR)
ABSTRACTs The Ca(OH) 2-H202-H20 ternary system has been investigated already
earlier (Ref 1) acc8rding to the method of solubility at-tempera-
tures from 0 to -20 . The thermal analysis (Ref 2) confirmed the
fact that actually all solid phases are individual calcium peroxide
compounds. It also made possible the determination of the limits
of stability of these phases. The isothermal lines of the solu-
Card 1/3 bility (Ref 1) have shown the ranges where these phases exist as

Investigation of Systems Containing Concentrated 30'1/62-58-11-3/26
Hydrogen Peroxide. Communication XV. Isotherm of the
Solubility at 100 of the Ternary System Ca(OH) 2-H 202-H20 and Complementary
Characterization of Oulid Phaoez
wall as their conditions of formation according to temperature
and the concentration of hydrogen peroxide in solli!.ion. In the
present paper the authors set up a polythermal diagram of the
ternary system Cs(OH) 2-H202-H20 with the solid phases CaO 2* 8H20,
CaO2 .2H20 and CaO 2* 2H202accordin6 to the data of the ijothermal
0
lines of the soluuility from -21 to 10 . Crystals of' hydratej
and perhydrates of calcium peroxide belong to a lower syngony
than the cubic ones. X-ray investigaticns of CaO 2 and'CaO 2' 8H20
powders confirmed the data mentioned in publications on the be-
longing of the crystals to the tetra6onal syngot,y. Tt;e penetra-
tion of 2 water molecules into the crystal lattice of CaO 2
slightly deforms the fundamental lattice. It seems that the
water molecules fill intermolecular vacancies. Roentgenograms of
Ca02' 2H202 powders considerably differ from those of the other
Card 213 calcium compounds. This confirms the individual character of the

'Investigation of Systems Containing Concentrated 30/6,e-58-11-3/26
Hydrogen Peroxid8. Communication XV. Isotherm of the
Solubility at 10 of the Ternary System Ca(OH )2-H202-H20 and Complementary
Characterization of Solid Phases
compound concerned.There are 6 figures, 2 tables)and 6 re~,erences,
4 of which are Soviet.
ASSOCIATIONt Institut obshchey i neorganichaskoy khimii im. N.S.Kurnakova
Ikademii nauk SSSR (In.3titute of General and Inorganic Chemiatry
imeni N.S. KurnakovAcademy of Sciences USSR/
SUB,1dITTEDt May 17, 1957
Card 3/3
7

5(2)
AUTHORS: Makarov, S. Z., Grigorlyeva, 11. K.
TITLE: Study of Systema Contnining Concentrated Hydrogen Peroxide
(Izucheniye sintem s kontsentrirovanno.,, porekis',yu vod.-ro.la)
Communication XVII. Isothermal Lines of the Solubility anti
Solid Phases of the Ternary System Ba (011)2-H202- H20
(Soobahcheniye 17. Izotermy rnstvorimosti i tvcrdyye fazi,
troynoy sistemy Ba (OH)2- H202-H20)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, fir 1 , pp 9 - 16 (USF)II)
ABS'!'RACT: Among alkali earth metals only barium peroxide can be obtained
directly from oxide and oxy,~en at hi,:.~,h temperature and in
the presence of humidity. In the intt-raction of barium hydro-
xide or barium salts with aquponv solutions of hydrogen per-
oxide hydrates or perhydrates of barium pproxile are formed
which can be transformed into barium peroxide by dehydration.
The numerous data to be found in publications on hydrates

Card 1/ 11 and perhydrates of barium peroxide Pro contradictory. The
preparative methods applied do nPith-r explatin the actuil

Study of Systems Containing Concentraterl lfydro-i~n 2OV/62-59-1-2/7e
Peroxide. Communication XVII. Isothermal Limi-~s of the Solubility and Solid
#hases of the Ternary System Ba (0H)2- H202- H20
composition of the conpourdn for.-ned nor conditions of their
existence and formation. A systematic invest i ~-ation of t'.e
interaction of anueons noIntionn of lh-irium, hydroxide with
oxygen peroxide ~ecms to be most effective by -cans of
phynico-chemical analysis. It permits to dotermire both t h
compooition and nature of the barium peroxile compounrIs
-e de-
formed as well as the li7its of their exi~,terre n d th
pendence on temperature and concentration. Thi- %i-,thors
thoroughly invecti,-~Acd the tr~rniry system Pa(O!!) 2- 11~)O 2- L"O
at -10, 0, 20,and 50 0 by the method of solubility unler
isothermal conditionr. The system tyns invcsti!-_tA -;ithin
a wide range of H 0 concentrations, ~,thereby the conpo-ition
2 2
of solid phases was determined by the method of resilies. The
octohydrate of barium peroxide without carbonate and hy1ro-
gen peroxide of lifferent concentration3, which had been
freed from stabilizers by fractional distillation, were used
as initial products. The drita obtaine~l in the -study of the
Card 2/3 isothermal lines of solubility at -10,0,20, and 500 are given

Study of Sjntems Containing Concentrr~ted Hydroien SOV162-r9- 1 -2/3
y
Peroxide. Communication XVII. Isothermal Lines of the Solubility and 'Jolij
Phases of the Ternary System Ba (OH)2- H202- H20
in (Tablas 1-4) and plotted in (Pigs 1-4). According to the
isothermal data (Table 5) a polythermil diagram of the
crystallization range of solid phases is :shown (FiC 5). It
is characterized by the presence of 3 rnnpes. Solid phases
of the system Ba (OH)2- H202- H20 were separated and inves-
tigated by thermal analysis. In addition, their stability
under different conditions was investicated. Experimental
data made it further possible to device a rip-thod of synthe-
sizing barium peroxide. There are 1~1 M,~ures, 15 tables, and
24 references, 3 of which are Soviet.
ASSOCIATION: Institut obshchey i neor-anicheskoy khinii im. 11. S. KurnR-
u
kova Akademii nauk SSSR (Inutitute of General anki Innr~-qnic
Chemistry imeni N. S. Kurnakov of the Acvle-iy of Sciencec,
USSR)
SUBMITTED: May 28, 1957
Card 3/3

.1 (2)
AUTFORS- Mrdcarov, S. Z. , Grigorlyeva, 11. K. ~,011/612-59-7-3/36
TITLE: Investigation of Systems With Voncentrated Ifidrogen Peroxide
(Izucheniye sistem s kontsentrirovannoy perekislyu vodoroda).
Communication 19. Studies of the Properties of Barium Peroxide
Compounds (Soobshcheniye 19. Izucheniye svoystv perekianykh
soyedineniy bariya)
PERIODICAL: Izvestiya Akademii nauk SS~311. Otdeleniye khimicheskildi nauk,
1959, Nr 7, pp 1163-1168 (USSR)
ABSTRACT: The system Ba(011)2-H20 - H20 was investigated. The solid phases
-em. The dehydrated barium peroxide
were separated out of this syst
was subjected furthermore to a thermal analysis and its stability
was investigated under different conditionc. Some samples were
also subjected to a qualitative X-ray analysis and microphotos
taken of them. The thermal analysis was carried out by plotting
the differential h6ating curve by means of the photorecording
pyrometer of Kurnakov. The octahydrate of the barium peroxide
Ba02,8H2O (heating curve in figure 1) was the component of the
solid phase. On heating a stepwise dehydration eccurs as fa:,.- as
Card 1/3 the semihydrate (0.5 U,O) with two endothermal effects at

_7/78
Investigation of Systems With Concentrated 11jdrogen :;OV/62-59-7 11 /
Peroxide. Communication 19. Studies of the Prcperties of Bari=! Peroxide
Compounds
55 and 1000; furthermore the diporhydrate of the barium peroxide
BaO 2- 2H20.. Two characteristic fundamantal effects are to be
noticed at 65 0 and 1000 (Piu- 2) corresnondinc to the
denomposition of the H20 2 and at 150" a vicak effect - the
separation of the remainine water. The decomposition of
BaO.2H202 takes place differently under different ccnditions.
To find out the reasons of these differences the stability of
the compound was investigated under differ,~nt- influences. In
vacuum, on heating under isothermal conditions up to 500,
stepwise heating up to 900 and at temperaturef; Gf about -5 to
08 and over sulphuric acid at room temperature. Two po3sibilities
of decomposition resulted: Ba02'H2o2'H,)O and !?a02*H20. The
alteration of the composition on decompcoinj the diperYydrato
of the barium peroxide in given in figure 3 ~ae:ond case). in
table 1 the composition on heating up to 900 is given. The
decomposition curves plotte4 from the separation of the active
Card 2/3 oxygen are represented in figures 4, 5- respective data are

Investigation of Systems With Concentrated FydroScn 'j V/62-59-7-3/38
X
Peroxide. Communication 19. Studies of the Pro.perties of Bariun Peroxide
Compounds
given in table 2. The following was discovered furthermore in
the mentioned system: BaO 2*H202- This is formed either by
reaction of BaO and H202 at 300 or by the mentioned decomposition
(II). It is easily decomposed to BaO 2- The peroxide last
mentioned has a crystalline structure (Fig 6) and decomposes
quickly over 5000 (description in Fig 7). There are 8 figures,
2 tables, and 9 references, 3 of which are Soviot.
ASSOCIATION: Institut obshchey i neurganicheskoy khimii im. 117. S. Kurnakova
Akadenii nauk SSSR (Institute of General and Inorgan ic Chemistry
imeni It. S. Furnakov of tho AcadeLly of Sciencez, U33.11)
SUBMITTED: October 18, 1957
Card 3/3

5.2000 75660
SOV/80-32-10-9/51
AUTHORS: Malcarov, S. Z., Grigorlyeva, N. K.
TITLE: Concerning the Preparation of High-Grade Calcium and
Barium Peroxides
PERIODICAL: Zhurnal prikladnoy kh1mI1, 1959, Vul '32
Nr 10
pp
,
,
2184-2189 (USSR)
ABSTRACT: This Is a study of the synthesis by way of Ca and Ba
peroxide hydrates, of' anhydrous CaO
and BaO,-
, which
,
2
are not formed by the direct vc-Letlon (X Ca -,An,] Ba
hydroxides and salts with 11 202* 1. Anhydrouz CaO
- (1)
2
Preparation of CaO
' 8H
0. The veactlon uf CaCl
~%lLh
2
P
2
(j I
H202 In an ammonia solution to form Cao 0120 Is
described In Figs. 1, 2, and 3, whusu study veveals the
following optimum preparative condittono 1'or CaO 2 *
Card 1/6 8H 0: 2.5% H 0 in solution; CaCl 'Ii, 0,, = 1/4; temperature
2 2 2

Concevning the Preparation of Ifigh-Grade Calcl-.im
and Barium Peroxides
0
S'OV,"~O-32-10-91c'-11
Fig. 1. Effect of CaCl 2/H202 ratio c~n CaO 2 '8if20
yield: (A) yield (B) H 0 used/If 0- stoichlometric.
2 2
Card 2/6

Concerning the Preparatlon of' fligh-Grade
and BarlUm Peroxides
A
7 -,,66 0
DOV/80-32-10-9/51
flu
so -
rood
49
Ile, I
143 llu ill:
4
Fig.2. Effect of H2 02 concentratluri un CaO2 hydrate
formatlon at +2 to +40 C: (A) yluld (B) H 202
concentration In solution'W.
Card 3/6

ConcernIng the PreParation of High-Grade Calclum
and Barium Peroxides
'(.~66o
.'2'()V /80 - 32 -10 -9 /51
IGO 40
L61
40
_'P0
10
tIr 01 Rl
ISO . . . . . . . . . .
4 j 1 0 M D
Card 4/6
Fig.3. Effect of reaction mixture temperature on CaO 2
hydrate formation: (A) reactJve 0, content, (1)
(B) Yleld, (2) (%); (C) reactIve 0-) content,
(D) temperature (OC).

Concerning the Preparation of filgh-Grade Calcllum 75660
and Barium Peroxides SOV/bO-32-10-9/151
00 to +110; 2% NH 3' It to Imptrative thrit the 20% CUM 2
solution be added to the cold H 2 0-H202- NH3mixture, Pre-
paration of anhydrous CaO 2 by forming a mixture of '
Cao 2 * 8H20 and CaO 2 ' 2H20 Io not i-,)ore effective since
the mixture has a very fine ct-1,-,tallIne structure dif-
ficult to filter and wash. (21 Conversion of CaO 2 '
8H 20 to CaO 2 *2H 20 by heating In water to a tempera-
tuve just higher than that requIred te detach six H 20
molecules. (3) Vacuum drying of CaO 2 ' 2H20 to 93-94%
anhydrous CaO 2* The procedure by way of steps (2) and
(3) avoids CaO 2 decomposition whose extent during direct
drying of the hydrate Increases with degref~ of hydra-
tion. 11. Preparation of anydvous BaO 2' In contrast to
Card 5/6 Ca 02 hydrates, the temperature- and It 2 02concentvation-

~)6, o
Concerning the Preparation of' High-Gride Calcium U)
arid Barium Peroxides sov/80-32-10-9/51
range of stability for BaO 811 0 1.-' riarrow, and that
2 2
of BaO 2 - 2H 20 is wide, so that the d1hydrate was se-
lected as the Intermediate. Preparation cundltlons:
(1) BaO 211 0: 3.5 to 4% H 01 Ba /PH 0 = 1/2.25 ov
2 j
2 2 2 - _2
1/2-5, room temperature; (2) drying at 110 to 1150, at
I atm. Yield 80 to 85% on Ba basis. Both prt-_~paritive
methods I and II were tested under Industrial condi-
tions at the "Krasnyy kh1mik" ("Red Chemist") plant of'
the Ministerstvo khimlehesko promyshlennosti (MinIs-
try of the Chemical Industry~ at Leningrad, and adopted
for production. There ave 3 figUres; and 8 references,
6 Soviet, 2 German.
ASSOCIATION: Institute of General and Inorganic Chemistry ol' the AS,
USSR (Inst1tut obshchey I neorganichookuy kiiiii-iii A14
SSSR)

GRIGORIYEVA, N.K.; SELEVIEVA, K.I.; DUGAtfOVA, V.M.
Niobium pqrox1da, compounds. Izv.AN SSSR.Otd.khim.naul- n0.6:
937-943 62. (MIRA 15s8)
1. Institut obahchey I neorganicheskoy khImii im. N.S.Kurnakova
AN SSSR.
(Niobium oxide)
V~

GRIGORIYEVA, N.K.;'DERGACHEVA, K.N.
Sodium and potassium pervanadOes. IZV,AN 35SR.0-td.khim.nauk
no.6:943-948 162. (KRA 15:8)
1. Institut obahchey i noorganicheakoy khimil im. N.S.Kurnakova
AN SSSR.
(Sodium vanadate) (Potassium vanadate)

GRIGORIYEVA,, N.K.; SMZNEVA, X.I.
Synthesis and properties of aodium and potassium peroxyorthoniobates
a.nd peroxyorthotanLalates and metaperoxy acids of niobium. and
tantalume Izv*AN SM.Otd,khim.nauk no.7:1137-114o n 162.
MU 15:7)
1, Institut obshchey i neorganicheskoy khimli im. N.S.Ku=akova
Akademii nauk =R.
(Alkali natal niobates) 41kali metal tantalates) (Peroxy acids)

ACCESSION NR.* AT4028337 S/0000/63/000/000/0177/0184
AUTHOR: Makarov, S. Z. (dece&sed);_qri&qy',yev,&,,N. K.; Selezneva, K. I.
TITLE;. Per-oxide compounds of niobium and tantalum
SOURCE: Soveshchaniye po khimii parekisny*kh soyadineniy.' Second, Moscow, 1961.
Xhimiya porakiany*kh soyedineniy (chemistry of peroxida compounds); Doklady*
soveshchaniy. Moscow, Izd-vo AN SSSR, 1963, 177-184
TOPIC TAGS; peroxide compound, niobium, tantalum, metasalt, sodium hydroxide,
potassium hydroxide, hydrogen peroxide, endothermal effect
ABSTRACT: Since 1958, the authori have been studying the reaction of niobium and
tantalum metasalts with hydrogen peroxide for the purpose of producing the compounds
and investigating their properties. The investigation was made within a wide range
of concentrations and temperatures. The peroxometa-acids of niobium and tantalum:
HNb(Ta)04 nH20 were separated in a solid state; some of their properties were
studied. In the case of HNb0 *H 0 the corresponding peroxometaniobates Na(K)NbO4-
2;~e
nH20(N=1.5-3.5) were separate corresponding salts for HTa04 OnH20 were-not
20 were obtained from the peroxortho
obtained. However, these as well as HNbO -nH
salts. The peroxide compounds NaNbO 4 4 Na Ta2Ol2.nH2O
nHX Na(K)NbO -nH20-mH2O2, 4
Cord 1/2

ACCESSION NR: AT4028337
were synthesized first. Some prop erties of the now obtained compounds were studied'
(thermal and chemical stability,,,solubility in 1120 and 11202 and others). Supple-
mentary data on the properties of the sodium and potassium peroxortho salts of
niobium and tantalum were obtained (thermal, chemical stability, solubility in 1120)
as well as x-rays of the powders. So far the experiments in separating niobium and
tantalum on the basis of peroxide compounds have not confirmed the possibility of
such separation. Orig. art. has: 13 figures
ASSOCIATION: Institut obshchey I neorganicheskoy khimii im. NS Xurnakova AN SSSR
(Institute of General and Inorganic Chemistry AN S&9F)
SUBMITTED: 13Dec63 DATE ACQ: 06Apr64 ENCL: 00
SUB CODE: CH NO REF SOV: 001 OTHER: 003
C.,d 2/2

Acc N'R! 'U'16112il,52 CODF: --uii/o4l~/66/00~/oil/0075/0075'
INVEN j*0R. llstinov, V. V.i Ctrigorlyeva, N. M.; Grit3hin, A. A.; Belov, L. V.; Bru-
siLovskiy, A. A.; Sinalayev, 0. P.
ORG: None
TITLE: A method for measuring the thickness and rate of application of films. Class
42, No. 182339
SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no. 1.1, 1966, 75
TOPIC TAGS: surface film, resonator, quality control, industrial automation
'idISTRACT: This Author's Certificate introduces a method for using two piezoelectric
rcsonators to measure the thickness and rate of deposition of a film on a base. The
procedure is designed for a wide range of thicknesses and for obtaining information
M a discrete form which is convenient for automation of the process. The monitored
r; portion of the flow of material being applied to produce the film is switched from
one.resonator to the other and back again after the required thickness has been
rcriched in the given section. Film thickness Is determined from the number of re-
verGals while the rate of application in determined from the reversal frequency.
SUB CODE: 11, 13/ SUBM DATE: 03Apr65
L Card UDC; 531.7;621.9,08;531.717.1;53l..767

GRIGOWMAj N6114
- 31*1~-
Diseases In city population In Udsurtsk ASSR In 1950. Sovet. sdravookhr.
11 no.2:39-41 Mar-Apr 1952. (CIML 22:1)
1. Of the Department of Public Health Organization (Bead -- Doosat M. N.
Vilenskly). Ishevsk Medical Institute.

GRIGORIYWA, N.N. (Moskva)
Vore attention to preserving the health of nothers and children.
Top.okh.mat. i dot. I no.1:3-9 J&-1 156- (NLRA 9:9)
1, Zamestitell stalstra zdravookhranonlye
(PUBLIC HULTH)
rl

GRIGCMIYEVA, N.N.; STANTSO, Ye.I.
All-Union conference on the further
preparation of pregnant women for
I no.2:88-90 Mr-Ap 156,
(OBSTXTRICS--COMORW)SIS)
(GHIIDBIRTH--PSTGHOLOGT)
use of psychoprophylactic
childbirth. Vop.okh.mat. i det.
(MLRA 9:9)

GRIGCRI YJAVA, N.N. (Moskva)
On the convocation of a meeting and conference of pediatrists.
V'op.okh.mt.1 dot. 1 no.6;3-6 N-D 156, (HLRA 10:1)
1. Umestitell zinistre sdravookhrenaniya RSFSR.
(MIATRICS)

Forty years of mother and child care in the R.S.Y.S.R. Zdrav.Ros.
reder. 1 no.11:24-31 14 157. (KIRA 10:12)
1. Zemestitell minintre zdravookhraneniya RSFSR.
(IIATXRUAL AND INFANT WRLYARX)

~4~ I a C - /~ , Y/ ti, /I , ~L/, Al,
GRIG 'YXVA, N.N.
14
Yorty years of motlier and c-~ild care
mat i dot. 2 no.5:5-14 S-0 157.
in tne A.S.Y.S.R. Yop.okh.
(MIRA 10:12)
1. Zamestitell minlatra zdrevookhranontya RSFSR.
(KATIONAL AND IIWANT WSLYARS)

GRIGORITEVA, II.N.-
-------------
Some problems In further Improvement in enre for mothers and
children. T Okh.mat. I det. 3 no~6r)--q N-D 158 (MIRA lls12)
QICAL CAM)

BUIRIOVA, M.N.. prof., otv.red. (Moskva); WIOORI MA,,N.N., otv.red. (Moskva);
LIBOT, A.L., prof*, otvareds (Lenin SKORKYAKOVA, L.K., otvo
0
red. (Moskva); TUR9 A.Y., profep otv.red. (Leningrad); LYUIDKOVSKAU,
N.I., takhn.red.
[Transactions of the All-Nmenian Conference of Pediatricians on
Problems in Ofteumonia and Antibiotics*] Tnidy Vaerosaiiskoi nauchnoi
konforontsii detskikh Yrachei po problemam VnevmoniiaO i Untibio-
tiki". Otv.red.N.M.Bubnova i dr. Moskva, Gos.lsd-vo med.lit-ry
1959. 215 p. (MIRA 14:15
1. Vaerossiyakaya nauchnays konferontsiya detskikh vrachey po proble-
mom wPnevmonlyag i Untlblotiki.* Koacow, 1957. 2. Doyetvitellnyy
chlen Akademil meditainek1kh nauk SM (for Tur).
(MIATRICr#--CONMlSSZS) (PNIUMMIA) (ANTIBIOTICS)

BUBIIOVA, M.M.; GRIGORI)D-VAt ~3.
Objectives outlined by the All-RuBsian Coneress of Pediatricians.
Vop., okh. mat. i dot. 5 no. 2:7-13 Mr-A 160 (MIRA 13:10)
(PEDIATRICS-COIIGRESSES~

GRIGORIYEVA N N., otv* red.; BUBNOVA, M.M.,, prof., red.(Yoskva); VLASOV,
ro e SKORKYAKOVA, L.K., red. TUR A.F.,zaal.
f *, r do (Moskva) P
deyatell nauki, prof.,red.iLenlngrad); RCMMICVA, Z.A., tekhn. red,
(Transactions of the First A-U-Russian Cong:.*ees of Pediatricians]
Trudl Pervogo Vserosslinkogo s"zda detskikh vrachei. Otv.red.W.N.
Grigorleva. Red.koll.: M.M.Bubnova i dr. Moskva, Goo.izd-vo med.
lit-ry, 1961. 508 p. (MIRA 14-12)
1. Voerossiyakiy 9"yezd detskikh -frachey, Ist, Moscow, 1959. 2. Zm-
meatitell ministra zdravookhranenlya RSFSR (for Grigorlyeva).3. Na-
challnik Upravleniya lacliebno-profilakticheako pomoshchi mater7am
detyam Ministoterstva zdravookhraneniya RSFSR Tfor Skornyakova).
4. Deystvitellnyy chlen Akademii meditsinskikh nauk SSSR (for Tur).
(PEDIATRICS-CONGRESSES)

GRIGORIYEVA. N.N.
Grand program in the campaign for communism. Vop.okh. mat. i dot.
6 no. 10: 3-7 0 161. (MIRA 14:3,1)
1. Zamestiteil ministra zdravookhranoni HSFSR
(WOMM-HEALTH AND HYGIENE
(CHILMUft-GARE AM HYGIENEr
'U~ 1 ~i.

- GRIGOR I YEVA ' Nt-*N,----
Plea for steady improvement in children's health. Sov.zdrav. 20
no.5:3-9 161. (MIRA .14:5)
1. Zamestitell ministra zdravookhraneniya HSFSR.
(FEDIATRIGS)

01
GRIGORIYEVA
Tasks of the organs and Institutions of the public health afetem
in protecting childrenin health in the light of the decisions
of the 22nd CPSU Congress. Zdrav. Ros. Feder. 6 no.6:3-8
Je 162. (MIRA 15:7)
1. 7ameatitell nini8tra zdravookhrananiyn RSFSR.
(PEDIATRICS)

GRIGORIYEVA, N. P. and ROZENIYER, L. A.
GRIGORIYEVA, -N- -P- and ROZINOYER, L. A. "Some characteristics of the course of relapse
typhoid in 1945-1946". Trudy Kishinevsk. gos. med. in-ta, Vol. 1, 1949, p. 94-100.
SO: U-3261, 10 April 53 (Letopis ~6 Zhurnal Inykh Statey No. 11, 1949)

r,7~ I r
F. "on the ctsulstics of foreign bcdic:-, in the rhary-mcel arr-a", T1.uf4y
Yishinevrk. gos. red. In-ta, Vol. 1, 1949, P. 359-61.
SO: U-32611 10 ArrIl 53 (Lctopir, - Zhurnal Inykh Statcy 1:0. 11,
77

TSVAYNER. Ya.P.; GRIGORIYEVA, N.P.
* ~
Abberant mawmary gland on labium majus. Akush. i gig. 33 no.2:
89-90 Mr-Ap 156. (MLRA 9:7)
1, Is ginakologichookogo otdolaniya Sorikskoy gorodskoy bollnitay
(glavnyy vmch Y.P.Zatvornitakly) i reepublikanskogo onkologich*-
skogo dispansera (glaynyy vrach G.B.Zhouslidie)
(T=A) (MLMKARY GIANDS)

_GAIGQ4~TtSITA N.P.; IJRNXR, 1.0.
Foreign bodies in the stomch. Nov. khir. arkh. no.2:133-134 Mr-Ap
'59. (MIRA 12:7)
1. Reamblikunakly onkologicheekly diapanser Kishineva 1, 2-ya
gcrodakaya bolluitsa.

IZWER, 1.0.; GRIGORIYEVA, N.P.
Riedel's strums. Zdravookhranonia 4 no. 2:54-55 MY-Ap 161.
(MIRA 14:4)
1. Iz 2-y gorodskoy bolinitsy g. Kiohineva (glavnyy vrach L.Kh.
Pinskiy) i Reopublikan kogo onkodinparwora (glavnyy vrach G.B.
Khonelidze),
(GOITER)
~F

FEDOROVA, V.N.p starshiy nauchnyy sotr.; IffSH17AYEVA, II.A.,, mlad.
"-IIr.hnyy sotr CdUGOR'YEVA*-RPj mlad. nauchnyy cotr.; KI-
VOTOVP S.A.0 zas ~.uc~iiei shkoly RSM; SHADRDIA) M.S.p
red.; NGVOSELOVA, V.V., .-,.n. red.
[Tie between teaching botany and the work of students in
plant growing]Sviazl obucheniia botgniko s trudom ucha-
shchikhsia po rastenievodstvu. Pod red. V.N.Fedorovoi. Mo-
skva, Izd-vo Akad. podagog.nauk RSFSR, 1962. 146 p.
(MIRA 15:9)
1. Akademiya pedagogichoskikh nauk RSFSK, Moscow. Institut
obshchego i politokhnicheskogo obrazovaniya.
(Botany-Study and teaching)
J,

GRIGOROYEVA, N.P. ; ZISM, I.F.
Sarcoma of the scrotum. Zdravookhranenie 6 no.3:60-61 HY-J~163
(MDU 16M)
1. Iz Moldavskogo naucbno-losledovatellskoge institute cnko-
logii (dlr. G.B.Khonelidze).

~eol-ln ~~I,
,;0: 3,LL-. 1,32, Z9 '.'-r 55

DANA, J&nes Dwight; GRIGORIYBT.D.P., rodaktor; qRIG"jJkVAj,P-L trans-
Utorj; ZIAMMUTA. F.C. redairtor; SHANTALOV. V.1., i~khnicheskly
rodaktor.
LThe system of mineralea. Translated from the MMlisbj Sistem at-
nersilogil. ftrevod a anellskogo. Vol. 2. Pt. 2. Lsolobates AM
tollurates, selealtes and tellurltes, chromate*, pboophates, aresma-
too and vanadates. antimnates; antinoultes and &result@*, vanadium
oxy9alts, solybdatoo and tungetates, organto compoundej Solonaty I
tolluraty, soloulty i tollurity, khromsty. foofaty.orsonaty i van&-
daty, antinonaty; antimoulty I arsonity, okolooll vanadlia. nolibdo-
ty I vollframsty, organicheakto sotdinenita. Pod red. D.P.Grigorls-
va. Koskva, Ivd-vo laostrannot lit-ry. 1954. 589 p. tMEA 7:10)
(Mineraloa)

~;IJG'021Y.-[A,
I

GRIOORITLPIA X
Effect of a remote electrode In the combined configuration
method. Razv*d.1 okh.m9dr 20 no-1:36-41 Ja-F 154. (NMA 9:12)
(Prospecting--Geophysical methods)

i
GRIGORIYEVA. N.P., referent
Problems 4elative to the clasnification of mineral reserves.
Razved. i oich. nedr 26 no. D60 Ja 160. (MIRA 13:12)
1.
(Mines and mineral resources--Classification)
Ik
F,
I P

GRIGORIYEVA, N.P.
Determination of the electric resistance of minerals. Min. abor.
no.16:399-403 162. (KERA 16:10)
1. Vaesoyuznyy Institut metodiki I tekliniki razvedki, Leningral.
(Minerals-Electric properties)

2. USSR, - (6C0)
4. Botan'. Study and Teaching.
7. Study of the subject "Basic groups of plents. " Est. v s'.-I--)Ie I;o. 6, 10"ro.
9. Monthly List of Russian Accessions, Library of Congress, February -1953. Unclassified.

GRIGORIYVA, N.P.
Method of condacting laboratory studies and demonatrations for botany lessons.
Ibt.v shkols no.5356-61 3-0 053. (NIM 6:8)
1. Institut wtodov obuchenlys. Akmdenii podagogicheskikh nauk FAISIL
(Botany--Study and teaching)

V 11
GRIGORIYNVA, H.P.
Imanons in studying the formation of organic substances In green
leaves. Biol. Y shkole no.6.#25-3Z N-D 157. (MM 10:12)
1. Institut ustodoy obuchenlya APW RSM.
(Photosynthesle-Study and teaching)

UMER, 1.0.; GRIGORIYEVA, N.V.
Case of papillary cystadenoma of the thyrTid gland. Kbirurgiia, 35
no. 11:217 N 159@ (MIRA 14:1)
(THYROID GLAND-TUMORS)

WILIFERIN, N.I., Prof.1 ARTJNIY317, V.I.; GURWHI, A.Ta.; GRIGORIVIVA, B.S.
Continuous nitration in the production of amber musk. Zhur. Y=
5 no.4:438-442 060. (KEM 13:12)
(111tration) (musk)

KCTELINIK(TI, A.A,, insh.; GRIGMYEVA, N.V., inzii.-eknnomist; CiiiGIN, V.F.,
inzh, ----
Use of excavating machinery in the construction of the Irtysh-
Karaganda Canal. Gidr. I Mel. 17 n0.3-37-4", Pfr 165. (MIRA 1814)
- I, - ", ~ -, ---, ~-
, ,o~, . -:,V,; a.,.. . :,..' " --
- 1- !;,!~-.--:--~,`,,~', .~ , --

o, furs I)y
63,
J: `t~-

SAVGHENKOF YO.D.; GRIGORIYEVA, N.V.
Pathomorphological changes following gamma-ray telettierapy of
neglected cancer of the urinary bladder. Med. rad. 9 no.2:
44-52 F 164. (MIRA 17-.9)
1. Patomorfologichaskiy otdel (zav.- dotsent Ye.l,. Savchenko)
Nauchno-iseledovatellskogo rentgeno-radiologicheskogo institute
(dir.- prof. I.G. Lagunova) Ministerstva zdravookhranenlya SSSR
i radiologicheskoye otdelenlye (nauchnyy rukovoditell- dotsent
I.A. Perealegin) Moskovskoy gorodskoy bollnitsy No-57 (glavnyy
vrach S.B. Vollfson).

Dry beffitir widimis, N,
Pr~. W. 2,40. 10. thice Are -
a
zlialacifory lar camnlim of slaw
IfIMN We 1. to give PH al 4j: (2) OM 6:11,141. .-1
7AAM. N6111M.1216OP" I. to $ITT oil "IAA; (3)AIN',
A. X4.11M.1211A) pw A. togiW9 pit do.a.

5(2).(3) PMz I BOOK 5XPL`OrTA?ION SOV/2554
Akadenlys nauk SSR. Otdolenlym khtalch*sklkh n&uk- 9011INSLYS PO
Iftromatograftl
'
ftoY I oesdochnoy
Xeslodavantya v ablestl ionoobw*mnoy. r4sqred0llt*l
kroaatografil. (3tudles In the Field of Ion R1ch&n6Q, Dtatribu-
"on and Precipitation Chronato4raphy) Moscow, Izd-vo AN SSSR.
19". 150 p. Irrata slip ineart*d. 3s5OO copies print ad.
Ed. of Publishing lauset N.G. TeSorov. ?*ch. 14.: I.N. Ouseva.
11d1toriLl Boardi K.V. Cb,2utov, Correspandins Member, U33R Acadtay
or sciences (Reap. Ed.); P.M. Shwxy-~-, Professor. X.R. 01-sn~ava,
Professor; X.M. 3&ld&dz*o Docent, and N.Y. Tunitaklyp Professor.
PMEPOSMI ?Us book to Intended for choulate and challcal engineers.
COVERAON: The book discusses studios to lon~xchLnte, dletributlen
;
and precipitation chromatography. Various problems of the the.
;
of chromatography and Its pplicaZion are also considered. This
12 the 4th Collection or :tic!@* publishod by the Co=Litteq an
curo"t0graPhY. The first collection was published in 1952 und*r
Was tit 4z *Isal*dovanlya v oblastL W%ramatografit . (3tudles
th
ti
id
r ch
t
h
th
d
bli
h
d i
I
)
m
e secon
n
e
o
roma
was pu
s
e
n
ograp
;
y
1955 under tbw title OTearlya I praktiks primanenlys I*noobwmykh
watertalevo (fteory and Practice or the use or xon~xchance ma-
tarwa); and the third was published In IQ5T under the title *Is
sledowanlya v oblasti tonoohmenmoy, khromat;Crafita (Studies in th;
fteld of Ion-azehange Chromatograph* No personalities are &an.
tlowd. Rerwrences are given after most of the article*.
Devy;do4-'A.T. And--d.N. ri-so-VIN-W. study a., fto Sorption Value and
the MWAbkAg* ameri-y-or-c-atlia-oa warattte WLth Relation to T"-
21
Perot%"
y-w- ratory or the stattonary Front or Dynamic 3orp-
an 24
-2&1"dto, K.N.. and tt. j_pZda=j&a_ Zffect of the Ionlte
Stpu~~-W-tbv Ion Lxshkn4p Process 39
~s&idadz* 9 M and -Kinetics or cation luchange
Cattonit.. 48
ftXt_4_a,. and pjL_Sbam"kjn. purtricatton or 3jato With the
1W of GA Ion~xiftmgs Counterflow InstaZIAtIon 55
P-O"--"A xA . And TA--Z--Che=tv&. Study of
CEO-zinetics or-Com. ~.C.V.&xChar4e an 3u.Ifonated Resins 63
A. B. Pashkov, S.R. barabanov. and N.M. Tunit-
thk-unwarivN7 or-MZEcy JLcldtc Ronorunctlona
C&tL=lt*s In Rotation to trio concentration or Sulfa Oroups and
lAtorchAtn Bonds In cattonites TO
and X.N. T~nltekly. Study or
ib-,jUlfruslon of Ions ThrouiM a Cxttonito mmbrane 7b
SheagrakIn. P.M. Organic Reagents Used in A4sorptlm and Distrl.
button Chromatography, Their Classification* and Trends of Inveatl-
gattm
M1t"12wskIy.-JLA- and &M"hewaldn- Some New Pheno~n&
Iftfik Accompany the Process of glactroalgration of Organic
Substafteas 90
Study of Thermal De~lr*natton or Sulto.
pho;alrormaldabydo Resin KU-1 95
JQVy1AM!A--V-V-' and 9- "-I!Ah&aQVR- Pre4lottation Chronato-
grapft7 105
_Ropr"ru-T.D.. an4'KJ[-Qj-tah&ncv&. Secondary Phenomena In
Precipitation Chre"tography 113
-QI'aftA=xL-X.2- and X-M-Aar"eva. Dat#rstnation or calcium
by the Precipitation Chromatography Method WLtn the IndIcator
Murlmide --124
a S1!A%P-a*v&P S.M., and ZqA. Folookova. Ion-eacnange Paper
in Quxll"V
Grlmmr!Zna,~Chromatographle Method or Qualitative &ruaysin
-rs; PUP Dyestuffs 134
2&L4Adz*~JLX-:~&.X~Q11ahwqv4, and Z,Z,-Zvrmova. Sorption or
Mineral &aide Wn-&-or Their Salts an Cattonites 138
-09L,beel".8 X A.. 4ndJLX. 3alda4t*. Absorption or compi.x zinc
Antand on intw%ttes Van virferont 94altity 143

CHARUKHRIA, Z,11., kand.tekhn.nauk; KIVSHITS, Ye.A., mladshiy nauchnyy sotr-"-dnik;
GRITGORIYEVA, N.V., otarshiy nauchnyy sotrudnik; ZABMDINA, I.P-,
laborant
Determining the concentration of solutions used in fur nanufacture
by their electric conductivity. Nauch.-issl.trudy NIIMP PO-9:56-
70 159. (MIRA 14.5)
(Fur-Dressing and dyeing)
(Solution(Chemistry)-Electric properties)

GRIGORIYEVA, N.V., inzh.; PCHELIN, V.A., prof... doktor khim.nauk
Mechanism of the tanning prooeasi Izv.vys,ucheb.zav.; t kh 1e prom.
no.2:13-21 161. (MiTiZM
1. Ilauchno-isoledovatellskiy institut mekhavoy promyshlonnosti.
Rekomendovana kafedroy tekhnologii kowhy Kiyevokogo tekhnologiche-
skogo instituta legkoy promyshlennosti.
(Tanning)

GRIGORIYWA, N-.V.p inzh,; PAVLOV, S.A., doktdr takhn.nauk,, prof.
Structural and mechanical properties of the leather tissues Izv*TYBO
ucheb.zav.; tekh.legeprom. no*3t65-72 161, (MIRA 14:7)
1. Rekomendoyam kafedroy tekhnologil, kozhi Kiyevskogo tekhnologi-
cheokogo instituta legkoy pronyahlennosti. 2. Nauchno-isoledovateltakiy
institut mkhovoy promphlonnosti (for Grigorlyeva). 3. Itakovskiy
tekhnologicheskly inatitut legkoy provqahlenwsti (for Pavlov).
(leatber)

GRIGORIYEVAP N.V.; PCHELIN, V.A.; REMINDER, P.A.; akademik
Effect of tanning agents on the structure of gelatin solutions.
Dokl, AN SSSR 139 no~6:1403-3-404 Ag 161* (MBA 14:8)
1. Nauchno-isoledovatellskiy institut makhovoy promyWe=osti,
pri Veerossiyakom Sovete Narodnogo Khozyaystya lu,&R i
Mookovskiy goaudaretvennyy universitat im. M.V. Umonoaava.
(Tanning) (Gelatin)

GRIGORIYEVA, N.V.; PCHELIN, V.A.; REBINDER, P.A., akademik
Structural and mechanical properties or protein fibers. DAL
AN SSSR 137 no.4:889-092 Ap 161. (MIFLA 14:3)
1. Nauchno-issledovatellakiy institut mekhovoy promyshlemtdAi
i Moskovskiy gosudarstvennyy universitetim, M. V.Lomonosova.
(Proteins)

PCHELINP V.A.; GRIGOR'IEVA, N.V.; IZMAYDDVA, V.N.
Effect of the fixation of polypeptide chains in two conformations.
Dokl. AN SSSR 151 no.ltl34-135 Jl 163. (KIRA 160)
1. Mookovskiy gosudarstvennyy universitet im. M.V.Lomonosova i
Nouchno-issledovatellskiy institut mekhovoy promyshlennosti.
Predstavleno akademikom P.A.Rebinderom.
(Peptides) (Polymers)

SHMELE'VA, T.A.; GRIGOR'YE-VA, N.V.; FAVLOV, S.A.; LFVINA, V.I.
Use Of polyaCrylAtCS for the strengthening of the skin of
sheep pelts. Kozh.-obuv. prom. 7 no.9i33-35 5 165,
(MIRA 18:9)

2
T.S. Te ln~
Mk
kar.1 -1--uk A M.

GRIGOROYE7A,.N.V...
Gama teletherapy in cancer of the urinary bladder. Urologiia. 29
no.2s4O-43 Me-Ap 164. (MIRA 1817)
1. Radiologicheakoys otdolonlya (zav. N.V.Grigorlyeva) i urologi-
cheskoys otdolonlys (zav. doktor mod. nauk I.S.Temkin) 14oskovskoy
gorodskoy bollnitay Wo.57.

CRIOCRIYEEVA, N. Ya.
V. F. Kucherov and X. Ya. Grigorlyeva,, "Application of the Principles of
Conformational Analysis for Proving the Confif-uration of Isomers of 3-AcetWW
Cyclohexane-lp2,-dicarbo.Vlic Acids."
report presented at the Symposium on Concepts of Conformation in Organic
Chemistry which took place in Moscow at the IOD AN SSSR (Institute of Organic
Chemistryj AS USSR) from September 30 to October 2, 1958.
Izvestiya Akademii nauk SSR, Otdf-leniye khtmicheskikh nauk., 1959., No. 3,, 561-56h.

I Kuchorov, V. F. , Y.1
T Fi, L
j ;I 0l C.NCli
Tnv,~ntlt~rAlow,, in the Fiol,' -If ljj~, Y C,
Collnollyi'll ta r oo-- h i i,,~ i i
s i 'K ~!31.c o oy i n -) n i y,~. Co--r-unic--itJon 21. Dirmc
Cr,nP!n!-,ittow3 of 1.0,v~rido Pr.1
Ll!wthyl. Firrilte, qnA Ccnf~r*iir~_,ticn Pr..- Cbt.,iinpfl
24.
T.1sleinov,--i anl-Vrllom 1 i ~.onf-guratsiya

J. C', I L Aka-lomii rnvik 'jSSR. Ct~],:-liniye khi-ai,~he3kilkh nauk.
5, pp 0 T- Z;
1A r", In this viork thu diene con4onsation of 1-acetoxybutadiene with

~vi 1 c e config-arn-tion
,, ic anhydride Pnl dimeth-1 fti.-,.arate and th
,
nn.,! cpatial transformation of the products formoi were given

A.
,t thorough investij;~itisn. I -Acc tylbutail one 3 synth-Isized
necording- to the Flail; mothoi. condenslition 7-.:?lntc
nnhydride !jhoviod 3patial selectivity with formaticn of the
cio-cis-proluct (II). The confignirnticn was prov;d by
",y1rcgenation an,l lactonizrticn. *#Vit,,) cond~in3ption of

Invpf7'i-,t.ionr; in th, Field of the '3trrnochcni:ltr-j
SOV/ 2-59-5-1~ -0
of Co-iplunds. Communic-r-%ion 2-,!. Diene Conlennationn of 1-Acetcx
'nA Dj-~etv.,l and Confi,-uration :)f
,J~ 'vl no,
1 ioo-.erl
obt,-.itiecl. tr-inc--trr~rt:7 -n,- ('17 nnd
Uit c
onfi.:rirnticn of whic) -.,ri -.,row)d b-.- tlh~-,-r catnlytic
i,,-~Irorrcn-ition, saponification, nntl th(~ observation of
.~I,r models. The derivativeo. of Vic cis-cir, order and
I.rr-ris-cis order 7it'l rin nxif-tl arrsr
,7(,:i,int; of the ncotoxy
have a lovi stability. Thny ~~,:wirr!te ~.cetic acil -~,-Ith
car.p.1vtIc h ... Ire
Tenktion, lkRl-*n,,, ;-, -,nif in.-il~ ion, '!nd heatin!~
variou.9 cyclohexantr.-1,2--lic~ ncidc nre folmod.
The isomeric coripounds of the trr.:v-tvanel crder t7ith the
.-~qwtorip.lly arranged acetoxyl --.e s-ifficiently otable
t-ot .3o.-v, of thc.,r deriv-ti-.-,-.7: 1):~- z~btndri-:?d. Three
,'cit t o f four theo re ti cal ly T,c 1,1 i.'~ c ..'t'r 0 c oul d be
synthonized' it.-, nean3 of dLenc In, c!itrilytic
0. ogr.-v;tion thorov.-I.1 f io.i of thi chenicel
cj,- "--Iic-rloo-~~-" ic ncid
f t i,~ n 3-,nc c to:,
I- L
iaom~rlc ~nF-l
CRrd 2/3 Tfr-,ro t;r,) r,:~ferencpqit "I of 'JoviA.
q

Invontil-atiow, i?, the Pi old of' t"lo Storcoc;ie-i,; r- 14/10
r
i j
of Cyclic Co~~,Pmmln. Com-mni cat ion 24.
' ', i th 'r,,) 1,? 1 -id') and
t"d i OW Of
tho Cbt,,incd
A3"O C,!,*.', 1,, Tn;!*U'~ut
SUI-13,1IT), ..:D;

543 SOV/79-29-3-12/61
A H
~Rs: Xucherov, V. F., QEL,:oz".ya,,,a,11. 'If,. , Nazarov, 1. K. (Deceased)
TITLE: Investigation in the Field of the Stereochecistry if the
Cyclic Compounds (Issledovaniye v oblasti stereokhimii taikli-
cheskikh soyedineniy). XXVIII. Condensation of 1-Acetoxy-
butadiene With Citraconic Anhydride and Stereospecific Trans-
formations of the Forming Isomeric Adducta (XXVIII. Konden-
satsiya I-atsetoksibutadiyena a tsitrakonovyn angidridom i
stereospetsificheakiye prov-rashcheniya obrazuyushchikhoya
isomernykh adduktov)
I
PERIODICAL: Zhurnal obshchey khimii, 1959t Vol 29, Nr 3, PP 793-803 (USSR)
ABSTRACT: The authors investigated the condensation of 1--acetoxybuta-
diene with the citraconic anhydride, whj'Q!i is important in
the problems concerning the atructural direction of dieno
synthesis and in the stereochemic-try of the adduc*13. In this
connection it was shown that owing to the unsymnetrical char-
acter of the two reacting components a mixture forma with a
certain ease, consisting of ab~,it equal amounts of two pos-
sible ortho- and meta-addurta 1) and (II), which pass o,~rer
to the isomeric acids (III) and (IV) by saponification with
Card 112 water (Scheme 1)# Both isomeric adducts hava a cis-cis con-

SOV179-29-3-12161
Investigation in the Field of the Stereochemistry of the Cyclic Compounds.
XXVIII. Condensation of 1-Acetoxybutadiene With Citraconic Anhydride and
Stereospecific Transformations of the Forming Isomeric Adducts
figuration# The formation of a preponderant large quantity of
metaisomer on the condensation of 1-acatoxybutadiene with
citraconic anhydride shows at the same time that the electro-
static influence of the acetoxy group upon the structuz-al
direction of the dieno synthesis is nore marked than the
influence exerted by the factors of spatial arrangement, which
depend on the volume of the aubstituent's. Both the structure
and configuration of the isomeric ortho- and meta-adducts
were thus proven by cleavage and lactonization reactions.
There ars 6 references, 5 of which are Soviet.
ASSOCIATION: Institut organicheakoy khimii Akademii nauk SSSR
(Institute of Organic Chemistry of the Academy of ScienjesgUSSR)
SUBMITTED: January 21, 1958
Card 2/2

5M SOV/20-128-3-31/58
AUTHORS: Kucherovp V. F.p
TITLE: Laws of Double-bond Isomerization in Cyclohexadione-1,2-di-
carboxylio Acids
PERIODICAL: Doklady Akademii nauk SSS , 195 , Vol 128, Nr 3,pp 147-150(USSR)
l
3
ABSTRACT: s in the acids ment one id
e bon
The displacements of doub
the title have boon poorly investigated up to date. The authors
have decided to undertake a systematic investigation of the
character and the laws mentioned in the title in the
'1,4_cyolohexadione-1,2-dicarboxylic acids. For this purposey
A
they investigated the transformations of the homologa of dl-
hydrophthalic acid with mothyl groups in various positions
on the ring. At first, they obtained the anhydride of 3-methyl-
61,4_cyolohexadiene-1,2-dicarboxylic acid (I) and its diester
II . It was found that in the saponification of this diester
of the double bond takes plac fro i-
M alisplacement
~
908
~
T
,
,
tion into poni ion d6. This yields the 3-met
yl -qclo-
hozadione-1,2-dicarboxylic acid (III). An alkaline saponifica-
proceeds with the displace-
tion of the acid anhydride (I) also
6
ment of the double bond into the A -position. In this case,
however, more complicated rja rangements of the double bonds
g
take place. Now, 3-methyl_ &-I9
-cyclohexadiene-1,2-dicarboxylic
Card 1/3 acid (IV), with a system of nonconjugated double bonds, appears

SOV/20-128-3-31/58
Laws of Double-bond Isomerization in Cyclohexadione-1,2-dicarboxylic Acids
as the main product. It became evident that the system of iso-
lated double bonds in the acid (IV) is rather stable, and
suffers no noticeable changes by boiling with alkali. Under
sufficiently hand saponification conditions, howaverp the non-
conjugated A!P -grouping, which is stable in the acid-anhydride
ring, is isonorized. Here, the double bond is displaced from
he interearboxylic position into the nonsubstituted position
At the same time, the A4-bond may be displac 0d int? the
P
63-position. Its further isomerization Into position A is
inhibited by the methyl group in position 3. Thi 19 inhTjory
effect was also confirmed by the example of 4-methyl-A "4-cyclo-
hexadisne-1,2-1i~arboxylic acid (T). The same law applies to
3,4-dimethyl-,& I -cyclohexadiene-1,2-dicarboxylic acid OX).
Also here, the second double bondlon which there is a methyl
group standing, is not isomerized. The ultraviolet spectra
recorded by T. M. Fadeyeva for all acids obtained by the authors,
containing a conjugated system of double bonds and substituted
in the same way, are in agreement with each other. The intro-
duction of a now methyl group on the carbon atom of the con-
jugated system shifts the absorption maximum by about 10 mv
into the range of long waves (Ref 7) (See Table 1). The data
Card 2/3 of table 2 show,that the absorption character is greatly

SOr/20-128-3-51/58
Laws of Double-bond Isomerization in Cyclohexadione-1,2-dicarboxylic Acids
changed by the intr?duction of a 2nd isolated double bond into
the anhydride of A -cyclohexene-lp2-dicarboxylic scide Such
an anomalous absorption suggests that in these acid anhydrides
there seems to be an electronic interaction of two formally
isolated double bondefor which a homoallyl canjvveUmm (Ref 8)
becomes possible due to the existence of a rigid system of the
five-member9d acid-anhydti-d* rings There are 1 figure, 2 tables,
and 8 references, 2 of which are Soviet.
ASSOCIATION: Institut organicheskoy khimii im. ff. D. Zelinskago Akademii
nauk SSSR
(Institute of Organic Chemistry imeni N. D. Zelinskiy of the
Academy of Sciences, USSR)
PRESENTED: June 2, 1959, by B. A. Kazanakly, Ac3demician
SUBMITTED: May 25, 1959
Card 3/3

GRIGOAWA, N. Ya., Cand Chem Scit-- ~diss) "Synthesis, stiraochemis-
-ace o-A -cyclohexene- and Ad 9 -dicyclo-
try, and transformations of 3
hexadien-2-carboxylic acids." Moscow, Z-Academy of Sciences USSR Press7
1960. 21 pp; (Academy of Sciences USSR, Inst of Organic Chemistry im
N. D. Zelinskiy); 175 copies; free; (KL, 17-60, 141)
'IJ

KUCHKROV# V.F.j. GRIGORIYEVA, N.Ya.
Conjugation factors in cyclic systems. Part 1: Character of
the inomerization of the double bonds in monosubatituted
cyclohexadiene-lp2-dicarbo4lic acids. Zhur. ob. khim. 31
no* 2s447-457 F 161. (MIRA 14:2)
I, Institut, organicheakoy 1rhivnii AN SSSR.
(Cycloboxadienedicarboxylie acid) (Chemical bonds)
I

KUCHSROVp V.p.; gRIGORIUVA, N.Ya.; ZEMSKOVAy I.I.
Conjugation factore in cycl ic4systew- Part 21 loomerization of
dobule bonds in dimethyl- .6 ' -oyclohexadiene-lt2-dicarbo3cylic
acids. Zhur. ob. khime 31 no* 2s457-469 F 161a (MIRA 14:2)
I* Institut organicheskoy khimii AN SSSRe
(Cycloboxadionedicarboxylic acid) (Chemical bonds)

KUCHEROV, V.F.; GRlGOH'YEVA, N-Ya.; FADEYEVA, T.M.
Con,jugation factors in cyclic systems. Part 3: Some spectral
refularities in the series of isomeric cyclobexadiene-1,2-dicarboxylic
acids and their derivatives. Zhur.ob.khIm. 31 no.9:2894-2898
S 161. (MIRA 14:9)
1. Institut or anicheskoy khimii imeni N.D.Zelinskogo.
fCyclobexadienedicarboxylic acid--Spectra)

GRIGORITIVA., N. ra. I KUCMOVt V. F.
Conjugation factors In cyclic qatemB. Report No. 42 Regularl-
ties in alkaline invowrization of double bonds in Al. q -eyclO-
h4nmdione-1.2- and 3co(,,6-dibydroit4an-4,5-dicarboryUc acids.
Izv. AN SSSR Otd. khIm. nauk no.12:2196.-2204 D 162.
(MIRA 16%1)
1. Inetitut organichemkoy khinii im. N. D. Zelinskogo AN SSSR.
CyclobsimdIenedicarboxylIc acid)
Indandioarboxylic acid)
Iscmrization)
~

GRIGORIYEVA, N.Ya.; KUCHEROV, V.F.
Stereochemistry and mechanism of dehydration of cyclohexane
derivatives. Usp.khiik. 31 no.1:39-72 Ja 162. (MIRA 15:3)
1. Institut organicheakoy khimii AN SSSR imeni Zelinskogo.
(Cyclohexane) (Dehydration)

KUCHHROV, V. F.IjWGOIIYEVA, N. Ta.; FADMVA, T. M.; KOGAN) G. A.
Conjugation factors in cyclic systems. Report No. 51 Mutual
transformations and the kinetics of isamerisation of hexalin-l,.
2-dicartMlic acids under the influence of alkalies, Isy.
AN SSSR. Otd. Min. nauk no-1:137-145 163. (MUM 16: 3.)
1, Institut organteheekoy kh1aft Is. N. D. Zelinskogo AN SSSR.
Cyclahexanedicarboxylic acid)
Isomerization)
Conjugation(Chomistry))
i

MATMOVSKIY, S.G.; qRIq9W-YEVA2_N.Ya.; BARASHKOVA, N.V.; XUCHEROV, V.F.
Conjugation factors in cyclic systems. Report Ho.41o Use of
polarographic and potentiomentric methods for studying electron
interchange effects in cyclohexadione-1,2.4icarboxylic acids
and their methyl esters. Izv.AN SSSR.Otd.khim.nauk no.23240-
245 F 163. (MIRA 16:4)
1. Institut, organicheakoy khimil im. N.D.Z IJ--I-OgO AN SSSR.
(Cyolohexadienedicarboxylic acid)
(Polarograpby) (Potentiometric analysis)

G.RlOj.-tj--'.A, N. .".
"Sur la synthese do benzthiazol at ses derives -Alkalbubstitutes". Kiprijanow, A. I.,
Ssltnik. Z. P. at Griltorjowa. U. F- (p. 2'2)
SO.' Joumal of General Chemi!La_(Zhurnal Obshchei Khimii) 1936, Vol. 6, No. 2

IN
In@ salts with negative substituents In thr- nfornalic mirleva.i,
Lryl-pynQuxmsu Wis.
him. /Aimr., 1952.18.8 -'L In. k.' I
rical dy" of the genora I P,trnu U U-N I I, (CI I :C If), -CI II I it I;(, I
are obtained by condeming 2 : 4
with o- and P-aminoberizoic acid, I-.t vil-
phassilic acid Q. The dye3 with It ~-- It' - p-mil ,- ("It, -C()'I I
and p IS-CO,Et, respectively have. rtup, nI 1:1,14, 149. mid 1,0%
and th~1-"AlAijq)tlon max. In neiltfAl I"tOll are 5418, 5.~J. An'l ';15
MIA. ,and it, alkaltive MOIL 543, 54.5, ami 5033 vn~L. ~-,ep&tatrun (-f tli,s
symmettle from the umsymmetric dyes (which nut I) is
in all c4se3 difficult. and was not satmiactory in thi mi~htre ~ p
from reaction of I with U. I lie corre:;Ikiwling N-aryl-stif,int,ited
pyTidinturn Wts me obtaissed by hydmty~ii ~,t the dym

0 IT-'-l3,TTra`cw
WSPImr]
amt" ODS141
11411al.-Cleavare
eva, I. K. GlAse end t, ~1
4- P-liff state I in sbz.-N=s
Asi". a. 1 48.
at a late
~1,1 by p-O%NCsH,NH, In - WOR in the pcesence of pyricline
3~ isot-5-ylidme rtM*, vioW, m. 140-1 6. ~(from
retaining some EftOlf); green, m. 188-M (Imm
-reaction mist., In AcOlf-HCI mitt.). Use of P-OINC4114-
'WHs In the above reattlan gave I
M-ftsdadisps-S W8m*rk1Orik(Ujsftdsm,I4Z-3% theuse
~of on-OWC&I-filaillgilvelbe
'Orange, Ut. 1304'. Pyrhirlwl "isr Orophomykk which
does not m. up to aOO*, is obtained lions I and p4).NCOj,-
Nff# In hot MOIL It tonns a salt with IffiCh, m. M-4.5*
(from HsO). It 6sted,with MeOH and concd. RCI 0.5
br- gave #4NC*114NHO. tPAt H1
Phipykit, lWated as mb wkh HgfflV*mr72`s*;4ft"m&tmet:t -
with JGS irmve the free, fmahravy mU, m. 1301, red p"nler.

4(~/~ YEV
w th
AT-11LIV 214
Zt4ki -;r ey. TIC.". 50, lWry
No. I I
No. v5~U.-Dyvs
Nil 01SC1.1 l,N'll(Cll: ClI)-.(: I I: N 11C.1 I,FA:)jN1l-lR ICI (1),
11 1, 11 111).
ttliss
lis :d bY the mctkm of mvidinium 2.4--dinitroptival.
i
Ylate (V) on ',n1f-111ihA1nWL (VI), !MNlitaxidop~tidine (VII),
or su1farii1atuidotWm)1;! (Vflf) [11 the in-en,'e -,f p)r;.
dhie. v (I K. VT. r, Ill). Mv'CO' it) ~ ril. li~rldine
Welt, lwaled Is tnin. at, 11,10" m. MI.
(froill NUOH-CLIC1.), I"ATrom x (maji)
600 Ulm, V (0.7 9.) in 2 sul. o'Tidine and I g. Vill it, :3
Fl-,h1ejCO was, hesited (cr 5--7 min. tit 100', poured iiito
acidified Watet, and the J~Pt. washed With 'Aarin Water and
14"C0 to 'Lild 7o IV, lit. 240'. X (11COM) 1,05 sup. V
-i-iJitic, v1113 zil. Me'CO Ivere heated
(1)
15 -0 tilia. at 100% Ybel"fing 761,~o ITT, us. 210', ), (IICWI)
615mia. Acidic and b-asic salmi. of the dyes decompd. upon
heating, forinhig RNIIO.ZC,114NIfj and
CI (X - pyT1diU1Lun*klx). V (I S.), 1.2 K. VT. 5 tal. Mr,
CO, (Lild 2 1111, tlY'rklille WAS t."Ated 2 1U3. t') ~1(11PICtt!. 'I,:-
COmpri. of U, atid the mixt. lKoured him -Amer, yO,ling
.:j7'w'-' Ix (it - u), OW01 did riot mcit up Vp J(W.
g(jusly, ffillu IV WiVq ijllt~lhldll IX (R - 21 t1li-LZO1Y1) of W1,31,11
the &WAc .alt with 11F.Cli :it. 17&*, tilt! pivrati.. ul. Wl'.
Sifflilotlyllf vi"IdedDC(A - ftidoWj'c r~fltwifh
ligC11 in. 201', Me plaaw in. ZZ04. Ni. llo,,,~h

Cr o E Y191 CF.
U6,13R/Che.mistry - Dyes
Mird 1/1 Pub. 151 - )1/36
Authors I Grigoryeva, N. E., and Gintse, I. K.
Title IPyridine .dyea.derivatives of diphenyl
Periodical IZhur, ob. khim. 24/1, 169-174, Jan 1954
Abstract iThe synthesis of three hitherto unknown rrfridine dyes 1,5-bis-(4-amino
dipheriTl)-pentadiene-1,3-ylidene-5;chloride; 1,5-bis-(4-nitro-41-aminodi-
phenyl)-pentadiene-193-ylidene-5 chloride and 1,5-bis-(p-andnochlorodiphany-
late pvridine)-pentadiene-1,3-ylidene-5 chloride is announced. It is sho%m
that the beating of dyes of benzidine and 4-aminodiphenyl derivatives is fol-
lowed by an isowric conversion of the molecule without cleavage of the wzdino.
The derivation of four hitherto unknown quaternary pyridine salts is describ-
ed. Three references: l-USSR and 2-German (1904-1952). Table.
Institution : The A. M. Gorkiy State University, Kharkov
Submitted : July 6, 1953
~77'71'77