SCIENTIFIC ABSTRACT GREZESIUK, S. - GRIB, V.N.

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SCIENTIFIC ABSTRACT
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GILTAROV, M.S. Symposium on Insect ontogerV. Zool.zhur. 39 no.1:156-157 Ja 160. (MIRA 13:5) 1. Inetitut morfologli NblyotmVkh Akademii naiAcc SSSR, Moskva. (Insecto--Development--Congresses) GILYAROV, H.S. Scientific conference on the protection of plants hold In Budapest and the zoological institutions of Budapest. Zool. zhur. 39 no.12: :L899-1goo 16o. (HIM 14: 1) (Pltviits, Arotection of-Congresses) (H=gary-Zoological research) GILYAROV, M.S. (Moskva) Certain general Usp. soov,. brates. problems in -the evolutionary morphology of inverte- biol. 49 no.2:215~-224..Mr-4 160. (MIRA 130 (MOREHOLOGY AXD%TS)) (INVERTEBRATES) L Pill;. L P.. 02 A 63- gn I 15- if L,' g;u v 19 '4, 2 4' 4, ti P~ ~j R ii vtl . . 1, " , ar i a ~F[R .1 1 '~ '4 p t- R o r~I j 21 . 1 1.- IN 10 41 TL XIPENVARLITS, Aleksandra Fedorovna, kand. biol. nauk; GUY V,, AHO M.S., prof., red.; KOVALENKO, A.G., red.; YERMIWV, V.M., Te-khn. red. (Change in the soil fauna in lowland bogs under the effect of drainageand use in agriculture] Izmenenie pochvennoi fauny nizinnykh bolot pod vliianiem melioratsii i sellskokho*i1stvan- nogo osvoeniia. Pod red. ~.S.Giliarova. ''Minsk, Sellkhozgiz BSSR, 1961. 196 p. (MIRA 16:6) (White Russia--Soil fauna) (White Russia-4wamps) . _.ql~YAtj~~A~.~f,,4.4-SUKHORUKUVp K~T. Anniversary conference on the protection of plants in Hungary. I Izv. AN SSSR. Ser. biol. no.2:314-.316 Mr-Ap 161. (MDA 14:3) (HUNGARY-PUNTS, PROTECTION OF-CONGRESSES) GILYAROV, M.S. Symposium on soil fauna held in Vienna. Pochvovedonie no.3;120-121 mr 161. (~aRA 14:3) (Soil fauna) GILYAHOV, M.S. Elevonbh Intornational Entomological ConlTeno. Izv. All SSSR Ser. biol.-no.3t/+83-485 MY-Je 161. (MIU 14: 5) (ENTOMOLOGY-CONGRIMES) GILYAROV, H.S. K-V. kriaolldils SiXtieth birthday,, Ushch. Mot. ot vred, i bol. 6 no.4:27 kp 161. - (MIRA 15:6) (Arnolldi, Kcustantin Vladimirovich, 1901-) GILYAHOV, M.S. Crop protection against pests and biological research. Zhur. ob. bial. 22 go.5:345-353 S-0 161. (MIFA 14:9) (AGRICULTURAL PESTS) GII!j~&S.,-doktor btolojr.nauk - 1~' Ninth Congress of German Entomolovists. Vest. ldl S-5SR 31 no.10:118 0 '61. (MIRA 14:9) (Entomolory--Conrresses) SUSHCHINSKIY, M.M., doktor fiz.-matem.nauk; OBTJKHOV, A.M.; GILYPROV, JJ.S., doktor biolog.nauk; TAFT, V.A., doktor tekhn.naik; GLIZIBOTSKIY, V.G.g1doktor tekhn.nauk; OLOFINSYIY, N.F., kand.** tokhn.na$k Scientific contacts with foreign countries. Vest. AN SSSR 31 --no.12:101-105 D'161. (MIRA 14:12) sm ' - hi s= 1. Chlen-korresp9ndent AN (Science-Congresse's) F~r GILYAROV, M. S International Symposium on Soil Fauna. Zool. zhur. 40 no. 2:302-303 F 161. (I-ORA 14:2) (Soil fauna-Congresses) (Arthropoda) GILYAROV, M.S. "Thecamoebap of soils" [in French] 1~y Louis Bonnet, Raymond Thomas. Reviewed by M.S.Giliarov. Zool. zhur. 40 no.9:1430-1431 b 161. (MIRA 14:8) (Pyrenees-Orientales-Amoeba) (Soil fauna) (Bonnet, Louis) (Thomas, Raymond) GILYAROVI M.S. Anniversary congress of German entomologists and some ziological institutions of the German Democratic Republic. Zool. zhur. 40 n0-11:1753-1755 N 161. (MIRA 14.11) (Entomology--Congresses) (Germany, East--Voological research) MAMAYEV, BQrjs Mikhaylovich;,QILYAROV, M.S., doktor biol. nauk, otv. red.-' MESSNER) O.M., red. iz&__va,- MAKOGONOVA, I.A. t ekhn.red. 0 [Gal.1 midges, their biology and economic significance]Gallitsy, ikh biologiia i khoziaistvennoe znanhenie. Moskva., Izd-vo Akad. nauk SSSR, 1962. 71 p. - (MIRA 15:12) (Gall gnats) NARZIKULOV, 4chamedkul Narzikulovich; QTLYAROV,-M.S., retsenzent; SMIRNOV, Ye.s., retsenzent; SHAFOSHNIKOV, G.lQi., retsenzent; LUPPOVA, Ye.P.J otv.red.; VINOGRADSKAYA, S.N., red.izd-va; GELLER, S.P., tekhn.red. [Fauna of the TaJik S.S.R. Vol. 9, no.l. Plant lice (Homoptera, Aphididae) of Tajikistan and adjacent republics of Central Asia. Tli (Homoptera, Aphididae) Tadzhikistana i sopredelInykh respub- lik Srednei Azii. Dushanbe, 1962. 271 p. (Akademiia nauk Tadzhiks- koi SSR. Institut zoologii i parazitologii. TrUdy, vol.25. Fauna Tadzhikskoi SSR., vol.9, no.1)4 (MIRA 17t2) GILYAROV., M.S. Tanks in the field of controlled reorganization of soil fauna. Vop. ekol. 4s21-22 162. (MIRA 15111) 1. Institut morfologii zhivotiiykh imeni A.N.Severtsova, Moskva. (Soil fauna) GILYAROVI M.S. Changes in the composition of the soil fauna of the steppe under the influence of afforestation as an indicator of changes in the hydrother- mal conditions of soils. Probl. bot. 6:346-353 162. (MI-A 16:5) (Belovodsk District--Soil fauna) (Forest influences) OILYAF,OV, M.S. Symposium on soil fauna in Kiev. Pochvovedenie no.9:116 S 162. . (MIRA 16:1) (Soil fauna-Congresses) GILYARGV2 M.S.,, doktor biologicheakdkh nauk In the Laboratory of Soil Fauna. Zashch. rast. ot vred. i bol. 7 no.1:58-59 162. (MMA 15:6) 1. Zaveduyushchiy laboratoriyey pochvennoy zoologii Instituta morfologii zhivotnykh im. A.N. Severtsovs, AN SSSR, g. Moskva. (Soil fauna) GILYAROV, M*S.p doktor biolog.nauk., prof. Role of raw crop aultivation in lowering the number of virevorms. Zaaboh.rast.ot vred.i. bol. 7 no.6t25-26 Je 162. (MIRA 15,12) (Noocav Province.-Virevorms) GILYAROV, M.S. Plant poptpotion prp~aems at thq, First. Conference of Pedag6gic Institute& ~pf the R.S.R.S.R. Zaahoho bo.l. 7 no.11851 N 1620"'.. of thb,Zdt)logists rast. v'red. i 1617) GHILEUtOV, M.S. (Gilyaro . M.8.) A comparative and philogenetic analyvis of the authodu for the insemination of arthropoda. Analele biol 16 no.5142-77 5-1) 162. GILYAROVj H.S., prof. Conference of zoologists in Vilnius. Vest.AN SSSR 32 no.8:77 Ag 162. (Zoology-Congresses) (14IRL 15:8) GILYAROV, M.S. Fourteenth General Assembly of the International Association of Biological Sciences. Zool. zhur. 41 no.2011-312 F 162. (MIRA l5s4) (Biological research--Congresses) --qI-LY-WffJ!- -S. - Larva of Dilar turcicus Rag. and the position of the family Dilaridae in the system of neWopterans (Planipennia). gnt. oboz. Al no.2:402-416 162. (MIRA 15;11) 1. Laboratoriya pochvennoy zoologii Instituta morfologii zhivotnykh AR SSSR, Moskva. (Caucasus, Northern-Dilaridae) GILYAROVI M.S. y" by E.N. avlovskii. ItGeneral problems of parasitology and zoolog P Reviewed by M.S.Giliarov. Zool. zhur. 41 ho.3:468-471 Mr '62. (MIRA 15:3) (Parasitology) (Zoology) (Pavlovskii, E. N.) GILYAROV, M.S. Toward the coming l6th International Zoological Congress. Zool. zhur. 41 no.7:1120 Jl 162. (MIRA 15i11) (Zoology-Congresses) GILYAROV M.S. Second Zoological Confpreme of the Lithuanian S.S.R. Zool. zhur. 41 *o,10:1590,.1598 0 162. (MIRA 15:12) (Litliuania.-Zoology-Congresses) SEMENOVA, L.M., GILYAROV, Merkurly So - ------ The evolution of arthropod cuticla. Haport to be mrubmitted for the l6th International Zoology ~;ongress Washington., D.,C., 20-27 Aug 63 IL'INSKMA, Mariya Ivanovna; QIVAROV, M.S., otv. red.; MAMAYEV, B.M., red.izd-va; SIMKINA, G.S., tekhn. red. (Pests of greenhouse plants] Vrediteli oranzhereinykh rastenii. Mos1cvaj Izd-vo AN SSSR, 1963. 131 p. (MIRA 17:1) GILYAROV, M.S., prof. Studying plant protection in Finland. Zashch. rast. ot vred. i bol. 8 no.9:48-49 S 163. (MIR& 16:10) 1. Predsedatell Moskovskogo otdeleniya Vaesoyusmogo entomologicheskogo obshchestva. GILYAROV, M.S.; MAMAYEVp B.M, Soil-inhabiting insects in irrigated areas of Uzbekistan. Zashch. rast.'ot vred. i bol. 8 no,1101-22 N '63. (MIRA 17:3) 1. Institut morfologii zhivotnykh imeni A.N.Severtsova. GILYAROV, M.S., prof. A symposium on the soil producing mites oribatoidea held at Moscow. Vest.AN SSSR 33 no.4sLU Ap 163. (MIRA 16:4) (Soil microorganisms) GILYAROV., M.S. Zoological problems at the Second All-Union Congress of Soil Scientists. Zool. zhur. 42 no.2:jI8 163. (Mli(A 1613) (Soil-biology-.-Congresses) GILYAROV, M-S- trends of controlled transformation of soil 'Tasks and futvxe 1630 (miRA 16-.7) fauna. Zool. Shur. 42 no-4-'481-1,99 11 institute of Animal MOrPhOlogyp AcadeibY of Sciences Of the U.S.S.Rop Modcow. (Soil fauna) GILYAROV, M.S. ,_ -- . I .-,- I--- T.- , Brief ne;,.is and information. Zool. zhur. 42 no.5:793-798 163. - (MIRA 16'7) 1. Institut morfologii zhivotnykh Akademii nauk SSSR Moskva. (Finland-Zoological research~ i. GILYAROV, M.,S. Soil fauna as an indicator of the distribution of Brown soils in Kodry Moldavia. Zool. zhur. 42 no.8:1135-1146 63. (MIRA 16:9) 1. Laboratory of Soil Zoology, Institute of Animal Morphology, Academy of Sciences of the U.S.S.R., Moscow. (Kodry-Soil-" fauna) (Kodry-Soils) GILYA,ROV, I'll.s., pn~f. At the Saction for General. Zritorncl.~)Igy. Zasii--b-1. ot wed. I " i bol. 9 no.2:58-59 164. ~MIIV, 17:6) 1. Pred-sedatell sektsii obshchey ellit,-).rl-;~ogi; entomologicheskogo - GILYAROV, I-I.S., prof. Breaking dcwn of poisonou:3 chemicals in the soil. Zashch. rast. ot vred. i bol. 9 no. 4:54-55 164. (14IRA 17:5) 1. Institut morfologii zh:Lvotnykh im. Severtsova, Moskva. GILYAROV) MeS.j prof. 12th International Congress of Entomology in Lmdcr-,. Vest. Aff SSSR 34 no.12:72 D 164 (1 U ILk . 1) GILYAROV, M.S. Basic trends in the adaptation of insects to life in a desert. Zool. zhur. 43 no. 3:U.3-454 164. (MIRA 17:5) 1. Institute of Animal Morphology, icidemy of Sciences of U.S.S.R..9 Moscow. ARVOLIDI, L.V.; GlMkROV, M.S., otv. red. (Guide to the larvae of soil Insects] Opredelitell obi- taiushchikh v pochve lichinok nasekouWkh. Moskva, Nauka, 1964. 918 p. (MIRA 17:12) 1. Akadeirdya, nauk SSSR. Institut morfologii zhivotnykh. GILYAR j M.S.; SHARM,, I.M. -- -- - - w - Soil fauna in the fir forests of the Pavlovskaya Sloboda region as an indi(sator of soil and forest oonditions. Uch. zap. MPI no.227:383-397 164. (MIM 18:U) MAVAYEV, Boris MJ.khaylovjrh; IRTVOSHEINA, Nina Favlovna; GILYAROV, M,S.,-doktor biolo nauk prof., otv,red, [Larvae of gall gnats (Diptera, Cecidomyiidae); comjrnr&+ive morphology, biology, taxonomic tables] Lichinki gallits (Diptera, CecidomyiidfLe); sravnitelInaia niorfologiia, bio- logiia, opredelitelInye tablitq. Moskva) Naukaf 1965. 276 p. (KIRA 18:3) -l-, ~l k-v ~-- , GlLYA.ROV, M.I.; SEIMMA, I-J). ki EvoluLion of the cuti;,I~ In Usp. -sm-, biol. 56 no.2-. 208-227 5-0 163. (MIR, 1- -1 5) i GILYAROV, M.S. ( I - - - - ~ - - ~ - 1. i?. Modern concepts ,64. - of homology. Usp. sovr. biol. 57 no-2:300-316 Mr-Ap (MIRA 17:4) C- geyevich in soil. diagrnostics] Zoologicheskil metod diagnostiki pochv. Moskva, Naukay 1.965. 273 P.. (MIRA 18:5) MISHUSTINO Ye.N.; GIL'I'AROV, M.S. Problems of soil biology at the 8th International Congress of Soil Scientists. Pochvovedenie no.5:85-88 My 165s (MIRA 1815) rl I - 'r ~- . - - * ~;- '- ~ a - ': . ; f - ' I v" - "I k. a '- ,19. arju .;.n,.. rn~- It' ')% th~,- - -- I * - n - ~ , -,. :~ ht. - " 11) M.' 35 n~:-,.7-.68, Yj', ( M 7 RA 2.8 -.8) AxWo,OVSKIYO N*No; GILYAROV9 M,S~ Brief news and inforvAtions Zo6lo Shur# 44 no#931437-144D 165. (minA 18110) GILYAROV, M,.S.; NEGROBOV, V.P. Brief news and information. Zool.zhur. 1+4 no.10:1589-1592 165. (MA 18:11) --GILTARUV. -N-.-P. Use of airodynamic models in the bydraulic investigation of rivers. !?rudy LINT no.20*27-43 1 53. (14IRA 12sl) (Hydraulic models) GILYAROV, N. P. "Utilization of Rigid Aerodynamic Models in the Investigation of Rivers." min River Fleet USSR, Leningrad Inst of Engineers of Water Transport, Leningrad, 1955. (Dissertation for the Degree of Candidate of Technical Sciences) SO: M-9723% 20 Feb 56 SOV/124-58-4-4143 Translation from: Referativnyy zhurnal, Mekhanika, 1958, Nr 4, p65 (USSR) AUTHOR: Gi~ya_r_ov,_,N_P,--_ TITLE: Certain Questions of Principle in Connection With the Use of Aerodynamic Models of Rivers (Nekotorvye prints ipiall nyye voprosy ispoll zovaniya aerodinamicheskikh modeley rek) PERIODICAL: Tr. Leningr. in-ta inzh. vodn. transp. , 1957, Nr 24, pp 31-41 ABSTRACT: In order to eliminate the distortion of the vertical distribu- tion of velocities which results from the friction of the air flow in aerodynamic models against the glass which represent!; the iree surface of the flow, the author suggests raising the glass in the model by a height of AH at which the velocity maxi- mum along the vertical on the full-scale configuration and those in the model have the same numerical value and the same dis- tance in relation to the bottom of the model bed. Thus the suggested method of model testing is based upon the acceptance for the purpose of the model test of only that depthwise part of the air flow lying between the bottom of the model bed and Card 1/2 the vertical location of the velocity maximum. The upper part SOV/1 24-58--4-4143 Certain Questions of Principle (cont. ) of the stream under the glass participates in die working of the model, but is not taken into consideration for the purpose of calctilat.iOrl. For the deter- mination of the relative coordinate T) of the maximum velocity on the ver- ~icall velocity-distribution diagram the author present,,: a graph of 9 as a t,unction of the ratio of the coefficient of roughness of the glass and the bottom oi the model. Formulae are submitted for the conditions of kinematic simili- tude of a proposed stream in a model accordiog to V. M. Makkaveyev . also for scale ratios for slopes, depths, and velocities. At the evd of the article the author gives a series of his arguments against the work of A.G. Averkiyev (Izv. Vses. n. -i. in-ta gidrotekhn. , 1954, Vol 52), which contains a criticism ot the author' s method, and discusses A. G. Averkilyev' s statements in detail, A. M. Latvshenkov I. in_Lan~l llater-.ray rrodels--Effectiveness 2. in.-Land -.,;aterway 'D inode1s-' erforrrance Card 2/2 Y/Y/~O v /V. PEW I BOOK MWMATION SOV/4130 Leningrad. Arkticheskiy i Antarkticheskiy nauclino-issledovatellskiy institut Problemy Arktiki i Antarktiki; sbomik statey., vyp. 2 (Problems of the Arctic and Antarctic; Collection of Articles, No. 2) Leningrad,, Izd-vo *Morslwy transport.," 1960. Errata slip inserted. 500 copies printed. Additional Sponsoring Agency: USSR. Ministerstvo morskogo flota. Glavnoye upravleniye Severnogo Morskogo puti. Resp. Ed.: V.V. Frolov; Editorial Board: L.L. Balakshin., A.A. Girs,, P.A. Gordiyenko (Deputy Resp. Ed.)., I.M. Dolgin., L.G. Kaplinskayn, A.A. Kirillov., Ye.S. Korotkevich, V.V. Lavrov, I.V. Maksimv,, A.I. 011, 1.1. Pbznyak, and B.V. Fellsov; Tech. Ed.: L.P. Drozhzhina. PURPOSEi The publication is intended for geographers., oceanographers.. and readers interested in the Arctic and Antarctic regions. Card 115 Problems of the Arctic and Antarctic (Cont.) SOVA130 COVERAGE: This collection of 19 articles published by the Arctic and Antarctic Scientific Research Institate deals with ice conditions in the Arctic seas., -*-.-- atmospheric circulation and anticyclones., aurora phenomena, and methods of oceanographic observation.. References follow the articles. TANS OF C Maksimv,, I.V. Some Problem in the Study of Long-Peariod Fluctuations of Total Ice Coverage in the Arctic Seas 5 Gordiyen1w, P.A. Role of Icebergs in the ice and Thermal Balance of Antarctic Coastal Waters 17 Khrozteava., M.S. Forecast of Ice-Edge Location in the Barents See 23 Gilyarovp N.P.,p and V.V. Xvanov. Modeling the Estuaries of Arctic Rivers 35 Girs., A.A. Typical Characteristics of Main Patterns of Atmospheric Circulation in the Wam Season 43 Card 2/5 GILYAROV, N.P., kand.tbkhn.nauk Z-- Use of mAels in studying a larpe water Nnction on Vre Lena River. Trudy LDY',Tno.26:Y~-62 '59. (MIRA 14:9) (Lena River) OydrauIic models) GILYAROV,-,..N.P., kand.tekhn.nauk; MOROZOVA, O.F., inzh. Resistances in the lower boundary of a self-simulating area during work with air models. Trudy LIVT no-7:17-22 '60. (MIRA 15:2) (Aerodynamic models) (Hydrodynamics) CHEKRENEV, A.I., doktor tekhn. nnuk, prof.; ILINSKIY, V.A., dots. [deceased]; GRISHANIN, K.V., kand. tekhn. nauk, dots.; SELEZNEV, V.M., kand. tekhn.nauk; GILYAROV, N.P., dots., kand. tekhn. nauk; KOSTENKO, N.M., inzh.; Prinimali uchastiye: GRIGORIYEV, S.N., inzh.; TEREKHOV, I.B., inzh.; KHIZHOV, B.M., inzh., red.; VOLCHOK, K.M., tekhn. red. (Practical manual on channel improvement operations in inland waterwaya]Prakticheskoe posobie po proizvodstvu vypravitellnykh rabot na vnutrennikh vodnykh putiakh. Leningrad, Izd-va *Rech- noi transport," 1961. 275 P. (" 16:2) 1. Russia (1917- R.S.F.S.R.)Glavnoye upravleniye vodnykh puteY i gidrotekhnicheskikh sooruzheniy. (Rivers--Regulation) GRISHANINP Kirill. Vladimirovich; TUMANOV, V.V., retsenzent; GILYAROV, N.P., red.; VOLCHOK, K.M., tekhn. red. [Hydraulics]Gidravlika. Izd.2., perer. Leningrad, Izd-vo "Rechnoi transport," 1962. 268 p. (MIRA 16:3) 1 (Hydraulics) GILYAPVW, N.?., Icand. d-.Aierit Structure )f u ractangular in an area of unLIEtterml, aitreaellntdq roaatu). Tru6y LIr, no.46tlL-21 "61 !:,, ! I? ,, : - ,.- ~i GILYAROV., N.P.; IVANOV, V.V. Model study of the regime of the levels and currents of river mouths in the zone of sea influence. Trudy AANII 254:155-162 163. (MIRA 17:11) GILYAROV# N.P,, kand.tekhn.naukv dotsent Structure of an open stream in the section of a unilateral streamlined bank projection in a cbannel of trapezoidal Bection. Trudy LIVT no#61t20-35 164. (MIRA 18:11) ANTONOV, V.S.; GILYAROV, N.P.; IVANOV, V.V. Experimental studisa of the water regime of the ObI Delta. Probl. Arkt. i Antark. no*20:23-30 165. (MIRA 18:10) 'rVid I OV , V . V . ; A.i I! YA 1(07, N.1 I. - . L ~ I - I Reg,4~wie of thE iOWor Yt'-IrJ ;;-y t I tv a' f:. " in i no -one of sea influence. Trudy AANil 262:78-111 1 ~, 5 . -'S:3,1 GILYARCV, N., kand. tekhn. nauk Exploring the lower reanhes and e5tnarles of the nomhern and S'Lbe r4 an rivers. Rech. transp. 24 no.114-50-51-1 165. (MIRA 18:9) KOCHETKOVA, A.P.,- TRONEV, V.G.; GILYAROV, O.N. Compounds of Pallium with glycine. Zhur. neorg. khim. 6 no.7:1582-1585 Jl 161. (MIRA 14:7) (Callium compounds) (Glycine) 8/02 0/62 /i 4 7/00 5/018/03 2 B1 17/B1 86 AUTHORS: Kochetkova, A. P., Tronev, V.G., Gilyarov, O,N. TITLE: Complex indium compounds of lowest valencies. Synthesis and study of the properties of the ammoniates of indium monohalides PERIODICAL: Akademiya nauk SSSR.* Doklady, V-'147, no. 5, 1962, 1086-1089 The reaction of 'indium monohalides with ammonia was studied in TEXT: under. a pressu three states of aggregation: The reaction with gaseous NH re 3 of 3 - 4 atm (t --OoC) yields adducts of the composition InM-2NH,, where M = I, Br. At 2 - 2-5 atm, one NH 3 molecufe adds to the monohalides. The resu.1ting %onoammonjt~es and diadmoniates-are bl7a:ek substances which in solid form are inso ble in water, nitric and hydrochloric acids. They disproportionate int. metallic In and In II'~ under the action of water, and dissociate into InM and NH under the action of acids. Heating of 3 Card 1/3 fl I S/02 0/6 2 /14 7/00 5 /018/03 2 Complex indium compounds of lo%eat ... BI-1 7/B1 86 InI-NH3 to 120 - 1500C and of'InBr-NH 3 to 1450C 'ca"uses their simultaneous dissociation into InM and Nft 3 and disproportionation into 21n met and the '5NH Ex' Eirved at 60 - 700C and corresponding.InM O't~ermic effects obs : 40 - 500C indicated transitton into the more stabl-e crystalline form of the compounds studied, since the composition andiproperties remained unchanged. When the pressure is increased to 6-8 atm, or if liquid NH 3 is used, disporportionation yields grayish black .InM-2NH, products. InM 'NH were synthesized under the same conditi is and studied thermo- 3 3 .1 ?rk , graphically to prove the composition of these products. Thus, trihalides yield Inhi -6NH . Thermograms showed the decomposition of these products 3, 3 down to Intl 3' NH,, and fusion of metallic In. The presence of In met in this reaction was also proved by X-ray analysis. The reaction of In met with NH set,s in at the melting point of indium and shifts to the right 3 1 in the therm Iogram a.t higher temperatures. -The last exothermic effects at Card 2/3 3/020/'62/147/P05/018/032 Complex indium compounds of lowest ... B117/BI86 345 and 2700C.correspond to thel,fusion of mon6halides containing small amounts of In and ammoniates of'In III, which do not take part in the reaction. Conclusion: The reaction of InM with NH 3 causes either addition or disproportionation, according to the conditions. The only products are monoammoniates and diammoniateB. Compounds containing a larger number of NH, molecules were not obtained. owing to disproportiona- tion of In I into nmet and In III at higher ammonia pressures'. There are 2 figures and 1 table. ASSOCIATION: Institut obshchey i neorganicheskoy khimii im. N.S. Kurnakova Akademii nauk SSSR (Institute of General and Inorganic Chemistry imeni N.S. Kurnakov of the Academy of Sciences USSR) PRESENTED: July 16, 1962, by I.I. Chernyayev, Academician SUBMITTED,., July 4, 1962' Card 3/3 b45hl S/020 62/147/006/022/034 B144%101 AUTHORS: Kochetkova, A. P. , Tronev, V. G. , GilY_a=_V_t__Q_-N- TITLE: Complex low-valency indium compounds. Synthesis and study of the properties of indium dihalide ammines PERIODICAL; Akademiya nau~ SSSR. Doklady, v- 147, no. 6, 1962, 1373-1375 TEXT: Complex compounds having 6 NH molecules (room temperature) and 3 0 8 NH molecules (slightly below 0 C) are formed from In I and In Br 3 2 4 2 4 molecules with gaseous NH at a pressure-'of 3-4 atm by a synthesis 3 method described earlier (DAN, 147, no-5 (1962)). These compounds disproportionate already when synthes'izing:,In 2Hal 4* 6NHA + 2NH3 InHal-2NH 3 + InHal3 or when heated to 60 8,50C in an inert atmos- .6NH39 -phere with the separation of 2 NH molecules from the complex compound 3 .having 8 NH molecules, andwith formation of In Hal_-6NH Further 3 2 4 3 Card 1/3 Complex low-valency indium compounds ... S/020 62/147/006/022/034 B140101 conversion in different in iodides and bromides. In 214. Wi5 - InI + InI 5NH + NH with an exothermic effect At 120OC; 3 3 3 0. In2Br 4* 6Nff3InBr-NH3 + InBr 3-51M3 with an exothermic effect at 85 C. Ammine compounds of trivalent In decompose and react with InHal yielding dihalides as final products. Under exposure to air or water, metallic indium is formed. Complex compounds containing 6 and 8 NH 3 molecules are stable in an inert medium. These results, justify assuming a dimer structure with a metal - metal bond, in which In is tetravalent. On disproportionation the binding electron pair is shifted toward an In atom. The kind of smine determines the bond strength and thus also the tendency to disproportionate. This will make it possible to determine the valency of indium in complex compounds with the formal valency of 2. There are 1 figure and 1 table. ASSOCIATION: institut obshchey i. neorganicheskoy khimii im. N.S. Kurnakava (Instituie of General and Inorganic Chemistry imeni N.S. Kurnakov) Card 2/3 19/020/62/147/006/022/034 Complex low-valency indium compounde B144/B101 PRESENTED: July 16, 1962, by I. I. Chernyayev, Aaademician SUBMITTED: July 4, 1962 Card 3/3 45461 S/078/63/008/003/019/020 B117/B186 AUTTIORS: Kochetkova, A. P., Tronev, V. G., Gilyarov, 0. N. TITLE: Compounds of indium with glycine PERIODICAL, Zhurnal neorganicheskoy khimii, v. 8, no- 3, 1963, 772-774 TEXT: Glycine compounds of indium with the formula In(GlH) 3-n G1nCI 3-n (n = 0,1,2,3) and of the compositions In(GlH In(GlH)2G 'C12 t and )3C13' InGI 3 were synthesized by the method described for gallium (Zh.neorgan. khimii, 6, 1583 (1961)) and investigated. Their structure is similar to that of the corresponding gallium compounds and their heat resistance also increases analogously due to ring formation. Decompogition of 1 0 In(GlH) 3 Cl3 starts below the melting point of glycine (255 C) at 160 C. Decomposition of In(GlH )2G 1Cl2 occurs at 255-2650C, and that of InGl 3 only at 285 OC. Indium-nitrogen bonds are unstable in triglycinate and triglycino chlorides subjected to the action of gaseous ammonia under Card 1/2 S/078/63/008/003/019/020 Compounds of indium with glyoine B117/B186 pressure. In this respect, they differ from the corresponding gallium compounds. There is I figure. SUBLUTTED: August 16, 1962 Card 2/2 GILYAROV, V. A. "Dialkyl Anilide Phosphites, Their Properties and Tautomerism." Cand Chem Sci, Inst of Organic Chemistry imeni N. D. Zelinskiy, Acad Sci USSR, 21 Dec 54. 1., 9 Dec 54) Survey of Scientific and Technical Disgortations Defended at USSI. Higher Educational Institutions (12) SO: Sum. No. 556, 24 Jun 55 V*' A*.~ USSR/Chemistr7 Card Authors I Kabachnik, M. 1. Mem.b. Corresp. of Acad. of Sc. USIM, and-Gilyarov, V.A. Title : Theory of tautomeric equilibrium. Structure and propertlen of dialkyl- anilidophosphites Periodical : Dokl. AN S55R, 96, FA. 5, 991 - 994, June 1954 Abstract : Theoretical investAut-ion of the problem regardinp. the dual reativIty of tautomaric sub3tances with stronEly displaced equilibrium. The 3alt formation-reaction and the salt alkylatton-rf-action take place -Ath regrouping which can be definei as the tr~insition of tfic reaction center. Dialkyl an-111dophosphite-i have all the nrol~nrttes of trivalent ph03- phorus derivatives and as such are capable of an Arbuzov type regrouping. Dialkylantlilophospi-lides are cra,)le of rormim,-, sodium salts during the reaction of sodium in an eiter or benzene solution. The constants of all substances obtained from such reaction are shovm in table. Nine rcfercnce3. Table. Institution Acad. of Sc. USSR, Institute of Comroundq S'ubmitted 11arch 13, 1951, A "Tmides of !7hasrhoru.,:3 r at, Nn Pi v Doc :X): B-1,084,841 if t ~, .?~-i "! KABACHBIK, H.I.; GI OV - V.A. Imidoe of alh7lphosphsric acids. Trialkyl- K-phonylimidephosphates; IsY.AN SSSR Otd.khin.nauk no-7:790-797 ji 156. (KMA 9:10 1.1natitut slementoorganichookikh soyedinenty Akademii %auk SSSR. (Pho a ph ate s ) ri aft.; _i ftnd V. A. C,~~ Ff" 4ppll' 11 ~ I'-~ K, ~,,j U. P KABACHNIN, M.I.; GILYAROV. V.A. - - " " Imides of alkylphomphosic acids. Trialk7lphosphate azines. Dokl. AN SSSR 106 no-3:473-475 J& 156. (mm 9: 6) l.Ch.lon-korrespondent AN SSM (for Kabachulk). 2.Inatitut elemenjo- organichookikh noyedineniy Akademii nank SSSR. (Azines) AUTHORS: Kabachnik, M. I., Corresponding Member of the 20- 1!4-4-26/63 Academy, Gilyarov, V. A. TITLE: On Imides of Phosphorus Acids (Ob imidakh kislot). The Di- alkylphosphoryl-N-Phenyltriazenes and Their Salts (Dialkil- fosforil-N-faniltriazeny i ikh soli) PERIODICAL: Doklady Akademii Nauk SSSR, 1957, Vol. 114, Nr 4, PP-.781-784 (USSR) ABSTRACT: In previous papers the authors had shown that -the fullethers of the acids of 3-valent phosphorus enter into reaction with phenylazide and form imidophosphates. This reactio-, was pro- posed as characteristic of the derivatives of the said acids. It was of interest to study these reactions with the salts of the dialkylphosphites. According to several publications the phosphorus in them is 3-valent. The authors found that the free dialkyls do not react with phenylazide. Their salts how- ever (triethylammonium and sodium salts) enter into reaction and form salts of the dialkyl-N-phenylphosphoryltriazenes. From these free dialkylphohphoryl-N-phenyltriazenes may be isolated, which are representatives of a new clasa of phosphor- Card 1/3 nitrogen compounds. The formation of these salts may serve as On Imides of Phosphorus Acids. The Dialkylphosphoryl-N- 20 114-4-28/63 Phenyltriazenes and Their Salts a confirmation of the previously expressed statement that the triazenes-III occur as an intermediate product in the reaction of the trialkylphosphites with phenylazide. The reaction with phenylazide takes place in the unaeparated phosphoru3-eleotron pair; in this respect it is analogous to the reaction with sulphur. However in the case of phenylazide the sodium salts react considerably faster than the ethylammonium salts. This difference was not observe& in the case of sulphur. The physical properties, methods of isolation, yields, and results of analyses of the substances obtained are given. Apparently dialkylphosphoryl-N-phenyltriazenes are stronger acids than dialkylphosphites. This may be concluded from the fact that the reaction of the diethylphosphite with phenylazide does not take place in the presence of catalytic amounts of alcoholates. The experimental part gives a detailed description of the methods of producing several compounds of the group concerned. There are 2 tables and 6 references, 5 of which are Soviet. ASSOCIATION: Institut elementoorganicheskikh soyedineniy Akademii nauk SSSR Card 2/3 - (Institute for Elementary Organic Compounds of the AS USSR) On Imides of Phosphorus Acids. The Dialkylphosphoryl-N- 20 114-4-28/63 Phenyltriazenes and Their Salts . SUBMITTED: February 28, 1957 Card 3/3 GILYAROV, V. A. (Iast. Eleme-n-tary- Organic Compou-ids AS USSR) "Imides of Acids of Phosphorus" (Imidy kislot fosfora) Chemistry and Uses of organaphosphorous Compounds i enly), Wdmtya i primeneniye fosfororganicheskikh noyedn Trudy of First Conference, 8-10 December 1955, Kazan, pp. Published by Kazan Affil. AS USSR, 1957 .2 7o7- 1,f) 10~ 5-3630 77069 SOV/62-59-12-13/111 AUTHORS: Kabachnilc, M. I., Gilyarov, V. A., Tsvetkov, Ye. N. TITLE: Concerning Imides of Phosphorus Acids. Infrarod ".b- sorption Spectra of Inildophosphates and Imidophoo- phonates PERIODICAL: Izvestiya Akademli nauk SSSR. Otdeleniye khimicheskikh nau.1c, 1959, Nr 12, PP 2135-2141 (USSR) ABSTRACT: The IR absorption spectra of triallcyl N-phenylimido- phosphates (A) which were obtained previoucly by reac- tion of trialicylphosphites (M. I. Kabachnik, V. A. Gilyarov, Izv. AN SISSR. Otd. Ichim. n. 1956, 790) and diallcyl N-phenylinildoallcyl-(and -aryl) phosph6nates (B) with phenyl azide, were investigated: no A. 110-P =z INC4115: (1) It = C,Iifi; (11) It ~. c,III; (III) It i-C3117; (IV) It ~' C4112, Ito Card 1/12 (no),11 + C8113N3 - (110)3p = NC016 + N- Concerning Imides of Phosphorus Acids. 770679 Infrared Absorption Spectra of Imido- sov/62-59-12-ln/43 phosphates and Imidophosphonates R\ (V) 11 C113: It' - i-C3117 R,O -P INCOIS (V 1) 11 (, I 13: 11' = C, I 10 1110/ (VII) 11 C!H3; 11' = C,117 (VIN) R - C-114; R, = C,119; (IX) 11 = C3111: R'= C,11,; (X) R - C1119; R, = C4111, (XI) R = Cslls: R'- Gills; (XII) 11 = CGlis; R'= C3117, t, t, Most of the above compounds were synthesized for 'he present investic-ation by the reaction between dialkyl alkyl-(and arylT-phosphona"tes and"phenyl azide: RP (01111 + C,113NN - 11 (R'0)2P = NC,Hs IR spectra of the above commounds have a strong absorp- C) - 0-1385 cm which indicates the tion band at 1-0.5,, Card 2/12 presence of the j7P = N-group. The IR spectra of Concerning Imidez; of Pho3phoruo Acid.,3. '("(069 Infrared Absorption Spectra of Tinido- sov/62-59-12-13/43 phosphates and Itnidophosphonates Card 3/12 triethyl N-acetylimidophos hate (XIII) and trialkyl N-methylimidophosphates (C~ were studied. Ito it. IM 11~~NCIIJ (XIN) It (XN) It A:3117; (""') 11 .110 The above compounds were obtained by reaction of m.ethyl azide with trialkyl phosphites. (110)'v + (113Nj -- (110)31'~z 'NCII3 + N., In the IR spectrum of compound XIII, a strong absorp- tion band at 1350 and 1"185 cm-1 was observed Comoound XIX also shows strong absorption a' 1325 cm- On exposure to air, its intensity decreases and the Concerning Imides of Phosphorus Acids. 77069 Infrared Absorption Spectra of Imido- sov/62-59-12-13/43 phosphates and Imidophosphonates intensity of the band at 1250 cm-1 characteristic of P = 0 bond increases, thus indicating that the above compound is easily hydrolyzed. EEF 0] Card 4/12 . 1.)0,.f16,,-~ -~q -1 r!- 1 ~, /I ~ 3 T(059, LT 71 jkr LT ty Card 5/'12 Card 6/12 77o69, sov/62-59-12-13/43 ov 15 u U. F -FT Fl Ol Z, DIIIAOS Of PhO!;j)',lOrU,3 ACidj Infrared Absorption .,Specilra of Imido- phosphates and Irni.dol)l-ioL;Iil-iciiiLite:l1 Card 7/12 ci v"16,C2 - 5 9 - 130 13 \ tj A (0 ,YL7s Ju u Ira - LT 77069 SO-V/6-2-59-12-13/43 IR spectra were taken on a double beam Dianov-Klokov spectrometer based on a IK-Spectrometer VIKS-MZ-N 11. The yields of obtained products are given below: 2-0 IAI CI 0, INC.11, 66,7 t07,5-108(0,5) 1,~()w 1,0000 C,11,0,PIINC.11, 5.1.0 t02 (t) 1,5088 1,0185 C.11,0/ \C,11, C.11.0 IINC.1f. )p 60,3 117-118 (t) 1,50115 0,0965 C,11.0 Card 8/12 Concerning I~ides of Phosphorus Acids. 77069 sorption Spectra of Imido- sov/62-59-12-13/4,2 Infrared Ab phosphates and Imidophosphonates rv,eM14 4 :LO C'11.0\P IINC.11, 61.5 123-1211 (1) 1,5010 0,9907 C.11.0/ \C.11, C O\P//Nr.ll, 71,5 131-132 (1.5) 1,4990 0.9sog 85,0 148(0,5) 1,5090 1,0150 C.11.0/ \C,11. (yeko C.11.0\ /,NC.11, / rK 54 125 (t) 1,5708 1,10S3 C111,O C.11, ' C OX NC If. :' / ; : 72,0 127-120 (1) 1,5573 1,0770 o , I C'l , Card 9/12 c Concerning Imides of Phosphorus Acids. 77069 Infrared Absorption Spectra of Imido- sov/62-59-12-i3/43 phosphates and Imidophosphonates I. Kabachnik, E. N. Tsvetkov, Dokl. AN SSSR, 117, k i~1(1957)]; yield 87.2%; bP 77-780; 1 mm pressure; nD20 1.11595; dj~20 0.9284. Trialkyl N-methylimido- phosphates are new compounds. The synthesis of tripro- pyl N-methylimidophosphate is given. Methyl azide wa3 added to tripropyl phosphite dropwiue in benzene. The evolution of N was observed. The reaction mixture 2 0 was cooled to 13-17 On the next day, benzene was removed by distillation, and the residue was distilled twice under vacuum. Tripropyl N-methylimidophosphate was obtained in 50.8% yield. The yields oil the obtained products (similarly prepared) are given below: y1Zw F/-;,-- 66 A JC,11,0)3P=NC113 50.0 ~70.5-71.5 (7,5)1 IJAM 1"'.258 jC'1 1 70)3p~ INC.11 3,)0,8 82-85 (3) Card 10/12 1 (cl I I 90)SP= NG113155,0 9,2.5-94 (1) 0, 04,87 1 , U80