SCIENTIFIC ABSTRACT ZUMAN, P. - ZUNA, VL.
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CIA-RDP86-00513R002065620005-5
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RIF
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S
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100
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November 2, 2016
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September 1, 2001
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December 31, 1967
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SCIENTIFIC ABSTRACT
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Proceedings (cont.) CZECH/2433
Arend, H.T. Polarographic Study of Basic Trivalent
Chromium Salt Systems
395
Krivanek, M. Complexes of Iron with Saccharo~e ~599
Dratovsky, M., and M. Ebert. Effect of Gelattti and Thymol
un Cathodic Deposition of Cations at a Droppll ig me
roury
Electrode 404
Russian Translation)
[Germay) Translation]
41o
Kuta, J. Study of Hydrogen Overvoltage W~th a Mercury
Electrode With Controlled Dropping Time,
413
Dvorak, J. Effect of Capillary Constants on the Maximum
of Oxygen 418
[Russian Translation] 421
(German Translation] 423
Vavruch, I. Attempt to Classify Refined Sugars by the
Polarographic Method 427
Card 5/ 14
Proceedings (Cont.) C=H/2433
J.
Spalenka,, M.
Some!Examples of Using Polarograp'hy In
Industrial Laboratories 433
Novak, J.V,A . Determination of Phosphates' 438
Russian Translation] 439
German
[
Translation)
442
Komarek, K. Polarographic Determination of Skill Aisounts
of Thorium 444
Komaiik, K. Polarographic Determination of Babies 455
Koreck;, J., .00
F. Nademlejnskvs and B. Neliba. Experience
~n the Use o f the'Polarographie Method in Steelmaking 461
Mojzis, J. Polarographic Determination of Manganese
a Triethanol amine Medium 464
Linhart, F, Polarographia Determination of Gold 470:
Card 6/ 14
Proceedings (Cont.
CZECH
~2433
Prchlikj J. Polarographi- DeterwInation of OX~
Illuminating Gas ygewin 478
Jelinek, T. Use of Polarographie Methods in Control
Analysis of the Treatment of Metal Surfaces 485
Zabransk~, Z. Determination of Thallium in Biological
Material 490
fRussian Transleition] 493
(qeman Translation) 495
Dookocil, Polarographic Reduction of Hydrogen
Peroxide in the Presence of Catalysts, That is$ Complexes
of Iron' With Catechol, Pyrogallol and Ascorbie,~,Acid 498
Majer, F., B.G. Simekp afid 0. Sebor. Polarogravhia~.
Analysis of Benzoic Acid and Phthaiia. Anhydride 5o4
Capka, 0. Polarography of Coumarin 509
Card 7/14
Proceedings (Cont.)
Trnka, J. Polarographic Study of the Degradation of
Glucose by Alkalies
Russi'an Translation)
German Translation)
[
Zuman, P. Reactions of Carbonyl Compounds With Primary
Aminds
Suchy, K. Polarographie Determination of CyanuricAcid,
Cyamelide, and Rubeanhydride
Pleticha, R. Some Complexes of Amino Acids Wit4 Metals
LRussian Translation]
Laerman Transatl0n]
Roubal, J., and J. Zdrazwil. Polarographic Determination
of Phenol in Water and Urine
Domansky, R. Upe of Polarography for the Determination of
Pentosans in Cellulose
Card 8/14
CZECH/2433
512
516
518
520
530
534
536
539
50
546
Proceedings (Cont.) CZECH/2433
Kalvoda, R., and J. Zyka. Polarometric Deterii-nation
of Derivatives of Barbituric Acid With the Aid of
Mercuric Salts 550
Blazek, A. Polarometria Determination of Some,Unsaturated
Organic Compounds 5
(Russian Translation)
Pleticha, R. Determination of Diacetyl
(Russian Translation]
(German Translation)
Buchnieek, J. Content of Colchicine in the Devielopment of
the Meadow Saffron
Sandholee, B. Use of Polarographe in the Paper and:
Cellulose Industries
Zuman, P. Polarographic Determination of Sulthydryl
Substances in Fruit
Card 9/14
-566
309
572
570
579
58
Proceedings (Cont.) czEcR/2433
Russian Translation 6o1
Engliph
[
Translation]
603
Knobloch, E. Hydrolytic Decomposition of the Oxidation
Product of 2
-methyl-1.4-aminonaphthol (Vitamin X5)" 607
Bitter, B. Polarography of Ascaridole 04
Kleinzeller, A., and Z. Fenal. Muconic Acid,in Bacteria 619
(Rubsian Translation] 62o
[English Translation] 622
Nosek, J.J., 0. Krestynova, and R. Podivinsky.! Polaro-
gr~tphy of Steroids 624
Russian Translation 698
[English Translation] 63o
Santavy, F. Polarography of Cardiac Poisons 4ith FiVe-or
Six-member Lactone Rings 632
Card 10/14
Proceedings (Cont.) CZECH/2433
Santauy, F. Polarography of the Oxidation Products
635
of S ome Morphine Derivatives
Russian Translation) 637
[ German Translation] 638
Simane, J. Polarographic Determination of Oxygen In Blood .640
Doskocil, J. Polaragraphic Study of Some Biological Redox
Indicators 645,
Russian Translation 648
English Translation]
[
649
J. Polarographie Study of Some Peria4datic
Doskocil,
.
Oxidations 651
657
(Russian Translation)
[English Translationj 659
Y
Homolka, J. and V. Krupicka,' Study of BrdickVs Viltrate
Reaction in Ser*-'-'-. 662
Russian Translation] .664
[German Translation] 66~,
Card 11 /14
Proceedings (cont.) CZECH/2433
Svatek, E. Study of Catalytic Reaotione.at wDropping
Mercury Electrode 667,
Koryta,, J. Decomposition Rate of the.Complek of
Nitrilotriacetic Acid With Cadmium
Smutek, M. Slow Electrode Reactions 677
Russian Translation .683
English Translati,n
[
1667
Hanusp V. Polarographic Study of the.Recoubtnation of
Phenylglyoxylic Acid 691
Koutecky, J. Linear Systems of Electrode Regotions in
Which a Chemical Reaction in Solution Takeellaae': 699f
Pliva, J. Contribution to the Theory of Difidsiork Cur~ ,....)
rents 108:
Russian Translation]
[ 712,
English Translation)
717
Card 12/ 14
Proceedings,.(Cont.) CZECH/2433
Tockstein, A. Derivation of the Extended Eq~ation'of
the Polarographic Curve
721
Russian Translation] 725
[German Translation] 727
Vogel, J. A New Apparatus for Osaillographic~,Polar~ogr aphy 731
(Russian Translation]
736
(German Translation] 739
V
Riha
, J. Polarographic Derivative Curves 743
,
(Russian Translation] 746
[German Translation] 748
Neavadba, 0. Artificial
Regulation of the Drop Time 751
Russian Translation
[ 757
English Translation
, 758
K. Vacuum-tube Polarograph
g2~r, 76o
Russian Translation]
, 763
German Translation) 767
Card 13/14
I
CZECHOSLOVAKIA
SUE-YUAN TANG; ZLTh1ANj P.
Polarographic Institute of the Czechoslovak Academy of
Sciences, Prague
Prague, Collection of Czechoslovak Chemicai CoT~municationsf
No 6, 1963, Pp 1524-1533
"A New Type of Maximum on the Limiting Currlent,of the
Reduction Wave of Phenacyl Sulfonium Ions."
z/ow/65/boo/4al-
307319535
,kUTHOR: Zuman, Petr
I --
TITLE: -Ca-,-f-eence on applying correlation equotions in
organic chemistry
PERIODICAL: Vestnilc eeskoslovenak4 alceidemie v61, no.1, 1963,
151-152
TEXT: Miniqterstvo 'S'kolstvi (The MiniAtry of' Education),
Odde'leni chemick~ch v6d Akademie v4d SSSR ~The C-hemical
1,-tences Section of the Acadenty of S--,ienceia USSR) &nd Stgttl,a
Universita v Tartu (State University of Tartu) heldi a conference
on this topic on September 11-16, 19-j2. Tharo ifetire 200 delegates
and 34 papers were read. The main work of tho confarance c;onaiisted
-i4clissions, which were very live'.y, The paperq; road ere of a
standard. Dr. 0. Exner, .)olarografi.cK)1'1 ustav 9.9,A.V
!P..:,a;--,~raphic Instittite, C7(-.choijlov0c AS), pretteintod a papeir on
.:i ant i ta t ive evaluation of the induc 7 ive e ffac t x ri aroillat.1c, systems.
Dr. P. Zuman (Polarographic Instituta, Czechoslov&D: AS) discussed
tn,~ relitions between the structure, the lineeir re).ations governing
-ie free energies and polarography; -)oth authors participated in
Card 1/2 . .....
NIP-, -
Conference on applyling ... z/002/611/nOO/001/001/001
8073/853-5
the discusrAon. The number and "111allty Oir top spe(lialists studying
.-liartitative relations between structure and reactivity in the
is considerably higher than woul.d appaar froin superficial
uf the appropriate scienti"tc literature (Profetisor
S..atr-ns.,,tein, Professor Ginzburg, Pr,)1'essor Efros, Professor
Litvineiiko, Dr. PAlin, Dr. ELntelis, D -. Rudakov) ; the number of
able and wall informed scientLfic workers iiii also remarkable.
'v-inilst in *.~'estern Euroue this type o* rf-s(ttArch doeti; not receive
'ucn attention, in the Soviet Union the number of ~I-Irotjps working
;..-i this fielc' is growing continuouFjINr and if the Okcilities in
Czechos)ova*tia are also taken into c.insidfnration, it can be stated
.siat soon t:-.ese facilities will equal the best American faCilit.LeS,
to relatively recently has enjoyeo a practical rionopoly
t I I I _' LL~1,__ 0, )r
ClIeMiStry. Apart from thEl Soviet Unic~n,
Czk-c_-I~,val~ia is tne only country of the Soviet ElLac which pays
to these prohle'11S. This conference was organizod by
Dr. V. Palai of Tartu University.
ard-2/2
C
MANOUSEK) 0.; ZMAN, F.
Direct polarographic. detatnizAtion *f lrjrid6xnl Ma the preafonce of
pyridwnl-5-phosybate. Co.11 Cz Chem 27 n6,24:486-47 F 162,
1. Central Recoarch Institute for Food indt Intry ~krA Polarogriaphic
Institute,, Czechoslovak Academyol! Sciences~ Prague.
,2- 71.19
gin
vim
T
zum"
?.I CHODKOWSKI., T.; SARTAVr.,
Polarograpbjr of nonbens9nold'aromatic. and r6lated substancev4 U1. A
polarograpbio study of the adid-base properties of tropyliumlion#
Coll Cz chem, 26 no.21380-391 F 161. (EW 3.0 19)
j
1. Polarographic Institute, Oxechoolovak Ac~4emy of Science ;Pre.'
V cue
and Chemical Institute, Medical Faculty, h3:Ac)qf;jj ~,Universit
,yo :
Olomouc (for Zu= and Santa:q) 2. Stftdivit Addrang I Inatititte of
PbyBicochemical Analytical Mathadop Polish Acadw' of Scieno~, Virsavp
Poland(for Gbodkoweld).
(Polarograph and polarograp (Aa-61matid compounds)
(Tropy-lium compoundsT
Z/oo8/66/054/012/003/00,4
E112/E335
AUTHORs Zuman, Petr,
TITLE: '_1TT-eFF of-Substitution on the PoIldrographic Charac
teristics of Organic Compounds. Repoi*t on Research
Work at the Polarographic Institute, eS,AV, Prague
PERIODICAL: Chemicki listy, 196o, Vo34 54, Noo 12,
pp1244 - .1264
TEXTs This paper-was written to commemorate the seventieth'
birthday of Academician J. Heyrovsky'*
The contribution of polsrography~ u organic..chemistry is'',
briefly outlined-, J.- Heyrovsk-f. won the~fiiit tb :demonstrate.the
relationship between the number of conjhgaiied d6uble-bofi~z JUn
a'compound-and its reducibility at the drdjping~:mercury
electrode. Shikata et al introduced-the rule of'electro"
negativity to explain substitution effects~,upon;the half-wav:e
potentials of organic compounds having pol*rogrltphically~
active groups in the side chain. The terms "induction effects"
and"tautomeric effects" (I and T) were later introduced to
polarography in accordance with developments of theoretical
organip chemistry. Induction effects are static and refer to
CarFd Wil
E112/E335
Effect of Substitution on the Po.larograpti.ic,,Characteriatics
of Organic Compounds. Re ort on Research Work at the
Polarographic Institute, 9SAV, Prague
a shift of electrons caused by a substitueni, while tautolmeric
effects are dynamic and produced by an external.field. The
principal group of substituents encountered.in organic chemistry
are listed and- signs of their !'I" or "TOO; effects are
indicated,-relative to hydrogen. The follorwling~conventions
are used.throughout the paper: groups more,negative than
hydrogen (electrophilic) will exert negative effects
(-I, -T), whilat less negative groups (nutleopbilic) will
produce positive effects (1, T). Reductions are nucleophilic
processes, for which the following rules apply:.,
1) groups with -I and -T will move the~half-wave
potentials towards more positive valuesq whilst groups with
positive I and T will produce the opposite effect.
Card 2/11
z,/ooII/6o/o54J012/O03/0O4
E112/E335
Effect of Substitution on the Polarographic~Characteristics of
Organic Compounds. Report on Research Workiat the Polarographic
Institute,'dSAV, Prague
II) Ortho- and pir^derivativesiin the benzene series, with
groups, exerting _T effects will be re4uce4i in the ranges
of more positive potentials than the m-isowirs. ~The opposite'
U
will hold true for compounds with positive ~T flitherto
described methods only permit qualitative interpretationl6f
polarographic processes and are not applicable t,q~aliphatic
compounds. The author summarizes quantitative methods developed
by the Czechoslovak School of Polarography. ~or t~h* study -6f
substitution effects upon the polarographicIbehaviour of 1
organic compounds. The new methods are basod on the assumption
that although electrodic processes are hete~ogeneousq they
can be nevertheless interpreted.as if their~Aiatics were
homogeneous, The paper is divided into four main sectionsi
A - effect of substituents on half-wave potentialm,
B - effect of substituents on limiting currents.
C - analysis of unstable intermediates,
Card 3/11
z/oo8/6o/o,54/012/003/004
E112/E335
Effect of Substitution on the Polarographic' Characteristics of
Organic Compounds, Report on fleas-arch Work at the Polarographic
Institute, CSAV, Prague
D - study of homogeneous kinetics,
ad A: experimental details are discussed. It 18: essent ial
that the electrode mechanL.a of all'the compounds vhich are
being studied and compared should be identical. Transfer
coefficients, as determined from the current/voltage and
halfwave potential/pH curves should be practtrally identical
for all compounds of the series of comparablo derivatives.
According to the work of Taft, describing tho effect of
substituents on the kinetics of homogeneous reactions, three
main factors contribute to the numerical vaUte of the velocity
constant, namely, P (polar), S (steric) anrl M: (mesomeric)v~
as expressed byi
log k P + S M 00'
Card 4/11
Z/008/60/054/019/003/001f
E112/E335
Effect of Substitution on the Po,larographicl,C-haracteristic.3 of
Organic Compounds. Report on Research Work At the Polarograp6ic
Institute, 6SAV, Prague
The Czechoslovak.group of polarographers have developed for half-
wave potentials for irreversible electrode proceases the
equation:
0
E1/2 !!T/anFln 0.87 k f \(t.,/D (2)
0
where k is the velocity constant of the'llectkddic process:
and a Cxpresses the numerical value of the:~ charg Ie-trans.fior
constant. Other symbols in the equation havle thoir conventio nal
meanings. Combining Eqs. (1) and (2) the author~arrives at
the expressions
E1/2 P + S + M (3),
for the change of half-wave potentials produced by polar, :steric
Card 5/11
z/oo8/60/054/PI2/603/004
E112/E335
Effect of Subsitution on the Polarographic Chara4teristica~ofi
organic Compounds. Report on Research Work at the,Polaro raphic
Institute, CSAV, Prague
and mesomeric effects of substituents. A detail*d descrip~ioh
is given of how the above equation is utili~~ed for,' the inter-1,
pretation of substitution effects. Series of compounds are
taken in which it is assumed that only one ei~ffect will be
operative, e.g. polar effects will be studied, wiih Imodel s6b-i
stances where steric effects between reducible groups and -pub
stituents can be excluded. Para-substituted'beniene derivatives
are examples-of compounds where both mesomerlic and polar 4ffects
way be exerted. Steric effects can.be stud i~nd in aliphat i~c
compounds having bulky substituents in the vicinity of polaro"
graphically active groups, such as ailyl bromides, disulphides,
hydroperoxides and 4-amino-N-dialkylani.lines, su6stituted .in
the o-position. Finallya o-substituted beniene derivatives can
be taken as examples of reactions in which all three effects :
are operative. Various qualitative observations on the effect
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z/oo8/60/054/012/003/004
E112/E335
Effect of Substitution on the Polarographic':Characteristi.to
of Organic Compounds. Report on Research,'Wark tit the
Polarographic Institute, 6SAV, Prague
of substItuents are alsoiAcluded, particuiorly.in cases which
cannot be supported by sufficient quantitative data. This!
author summarizes-and assesses critically polar6graphic wprkl
carried out by a Czechoslovak research teani'and'publishe 1d:in,
Czechoslovak publications. Thefollowing studies are inr-JLuded.-
polarographic, reduction of pyridine derivatives~j* ease ofi
reduction increases in the order of the 3,: 1Z and 4 isomers.
It is assumed that the heterocyclic nitrojelh extirts a -T~
effect, producing highest e1ectron density~*n the 3-position4
Eaters of phthalic acid show the interestin'~ phOnomenon that
the mononethyl-phthalate was reduced at PH 9-j8 at more
negative potentials than the dimethyl-tater,;, This is
'Dimethyl-
explained as being due to the effect of COO
terephthalate is reduced at more positive potentials than
the dimethyl-phthalate. The half-wave potentials of some',
sterole derivatives, particularly the cardiac gJycosidea',
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Z/008/60/05.4/012/04)3/004
EL12/E335
Effect of Substitution on tha Polnrogritph,ict!Chatacteriatice
of Organic Compounds. Report on Research Work ait the
Polarographic Institute, dSAV, Prague
are compared and the effects of substituentp in.,rings C and
D on the reducibility oC ring A are notaki.
Naphthoquinones(f4l,4) showed the interesting' behaviour
of substituents*in positions 5-8 having additiv* .characte ristics
while those substituted In 2 or 3'displwyed-cons'iderable,
deviations.
ad B. The polarographic study of limiting currents permits
the determination of equilibrium constants,~.while velocity
constants can be calculated from mensuringllimi~in& kinetic
currents. Examples of equilibrium constants detormined
,polarographically from limiting currents irk 'clud4i :the reaction
products of carbonyl compounds with primary amilles. One'of
the earbonyl compounds studied and for which thoqquilibr:ium
constant was established was pyruvic acid And It was seen that
its reactivity with different amines decreAaed in the following
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A/008/60/054/012/603/004
9112/E335
Effect of Substitution on the Polarographio~Characteristics
of Organic Compounds. Re Drt on Research ifork at the
Polarographic I"titute, NUV Prague
orders met4ylamine, histamine, glycine, histidi,xie, alanine
and ammonia. In a series of reaction products of ketones' with
amines, the stability of the compounds increases, on the.
other hand, in the following order:: methylcycl6hexanone,
-acetone-, cyclohexanone-, cyclopentanoned. Theloffect of
nuclear substitution on the equilibrium constant of the
reaction product of benzaldehyde and glycine wah investigateo,
showing increasing values of the equilibrium constant in the,
order, p-OH, p-OCH o-CH.0 F1#,o-0H.
3'
Velocity constants of fast chemical reactions can be determined
from the measurements of kinetic limiting,e~urrents. The
effects of constitution on the values of these tonstants can
be studied. The problem of adsorption on the a6rcury p
electrode is discussed and particular attention:is paid to
the adsorption of the depolarisator, An attempt is made to
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z/oo8/6o/054/0l~/oo3/P04
E112/E335
Effect of Substitution on the Po:larrigraph.ic,'Chatacterist,ics
of Organic Compounds. Ile ort on Research Work ~t.the
Polarographic Institute, ESAV, Prague
correlate adsorption currents with constitutJon,1 Examples
are, however, restricted to a few sterole dr ivii t ives.
ad C, Detection of unstable intermediates..,;,Pola.rographytmakes
it possible to detect unstable intermedia ets in.reactions~
proceeding by proton transfer. It was poss 'ibleAo establishi
from changes of limiting currents with pH the existence of
certain cations, the existence of.which ha~s~so far boon
unknown. Compounds which were shown polarographically to.be
proton acceptors included Some at P unsaturated*,atones,
acetophenone, phthalic acid, azulenes and others, It was:also
established that it was possible to distinpiish, by means,of
polarography the cis- and trans-forms of di'bonzoytethyleno.
The formation of unstable intermediates in olec~rodic
processes was also demonstrated.polarograph.ically - such as.
for example, the formation or free radicalst, which then may
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Voofl/60/05.4/012/003/0041
E112/E335
Effect of Substitution on the Polarogi-aphic- Characteristics
ofOrganic Compounds Regort on Research Work at,the
Polarographic Instit~te SAVt Prague
undergo dimerisation. The free radicals may also undergo
protonation, as in the case of phthalimide.
ad D. Study of homogeneous kinetics, This work rpfers ' a~aong
others, to the polarographic study of reactioti mechanism and
effect of constutitionypelocity constants of,*~the-d-ecomposIitiob
of dithiocarbamates, of the oxidation of dioles With periodic:
acid and alkaline hydrolysis of Isothiouren-
There are 101 referenceal 48 Czech and 53 ~ion-Czech,
ASSOCIATION! Polarograficki 11siav ESAV, 'r la
(Polarographic Institute, Z?SAAV' Prague)
Card 11/11
ZUMK P. KUIIC#yo
Catalysts of hydrogen separation In proIOnce of oom sulttir
derivatives of Wantoin and pyrimidineftoll Oz chom 25~ .
no.12:3861-3880 159. (RIA1 9:6)
1, Polarographisches Institut, Techoshoolovakische Akademle der
Wissenschaften, ftag. i
(Catalysts) (Hydrogen) (Sulftr)
(Elydantoin) (111rimidine)
COUVITRY : C ZVECH OSL OVAK IL B
CATWORY t Physical Cherdstry. 'Elootroahamistry
ABS. JOM,. i RMim.j No. 1 196o, No. 624
AUTHOR Banyaj, H. ;.,, ~Z=a
IVST.
TME i Polarographic B~ehavior of 44nino-41-MethoXY-
diph-en-ylamine (Variaminblau)
I ORIG, PUB. i Collect. Czechosl. Chern. Communs, A959s 21~,:
He 2, 522-5?5
ABSTRACT In the o;tidation of 4-amino-41-netho;qdiphonyl-'
anine (I), the quinone of p-anisyldlimine it
formed. Tlio polurographic staidy of this rcao-
tion showed that at pII 2-14i oxidation proc6eda
with the participation of two, electrons;
(dFa/dpH) = 0.056 v. The holt;ht of the wave is
proportional to the concentrntion~of I and to
Y-h (h - height of Hr, coluDm'). 91,he oxidation
of I proceeds reversibly,,-- 0, Knesul
CARD:
B749
DIstro:
Van
tk a r Ilk stlu y 4, yo. 0 In it ;i0lowod i,
N-0 till In it mol. to 4e tilt molt riw it K ized.:; it
V
A4,11FARU41410 W I pholyl flitch-.1ji in the )1i 1 1" X a fill Oll I
Vrmsp 14 the Itiom led to v inarktil truni 11 kin cd he
(Ilic d ..; IM(I It mlli
i4offthq cill in Wo to be i to
Am Mat I IR91,161011101 TqWktl(*Atl 1*1 " 16,
I
Ikiow wictil i tsir4wi, tilt; comilso~ owl M11,11 i~ )k
potdmws 011 Ilotil-oub Itu i a-owhyloyd 1( 10. t icio
f :thus miublisheit that t c r1rocti-ou q1teirl 11 Ilia syll 101111
ring 6 four 04 mobilk that Ill 01W w"Cia, k Wompdi ; I
schin Chit b cmd"le "as do w M4. I I
unbul 6*4 1HAU. ( 5 414muo Will it IVESUV M jhLixiMill IN
su gl%v4,a odc-4 :k
-'1'.7"vTfr=by3fusttm4trps -3A uldn-1. ~C.v
'retp, lmiq. 1 *ftorFI01
it Live a (40b" stdoction stq3 at -1 wt Inv 6-Ing 4,1 ~le I., I
tmuq. "Cempulloid Ill it "fil a I to V. t '0
former sup wm stiri
ft and to ir, m I
calloilt dn4 the laminlt = edcuills. Of 4 WT 4
tq* dixivii. muld be oil ju,'ox. 4ttd.
CZECHOSLOV.MaA/Physical Chemistry - Surface n16613ena:'
Adsorption. Chrormtographyb Ion Mchanaa.
Abe Jour :Ref Zhur Khimiya' No 19, 1959o 67393
Author :Zurmi, Pet~,- Cerny, Vadlay
List
Title Polaroaraphy of Ster:oids. III. PolaroCraphic Redv-ction
of Steioids Contaihing the Alde*,6'GrPup in position 18.
Orir,, Pub Chem. listy, 1958, 52) ro 8) 1468-:1473
Abstract The polararraphic bphavior of dehydro-5~&-dih~drot,4:ra-
mothy1holarrhiraine (I), its oxlnei~(II),idehydrotetrh-
methy1holarrhimiae, and dehydrottiianot6y!t.,,olarriiidiiie
(III) was investigated. Theae stiroids4afch contain the
aldehyde group In position 18 cind!~raaclled chain in po-
sition'17 are reducible within th6 pH ranae 7-10.5 to
give a single wave of -1.65 which is independent of
pH. The fact :
, that El. i~ independoht of'pll is explained
by steric hindrance.due to hydration. II is not
Card 1/2
AdsorptIqz=&iC8trv Surface a
. Chromaio4;raphy. on ledorjena:.
Abs jour Ber zhur MIIMIYa, 110 1. 13
91 1959, 67393
reducible* The nitroae
lower the overvoitat.6 onlcontalni,4 ster~'Ids 1,,
reduction w4 R 1,011 V064C'Mted
.2 evolut
hi Ve combines wit,, the c6 # 04d tile
dier concentration. talytic. % steroid
Vhel, OxYcen z: Rolarrhedine, qi ~ wave at
ces investiC.M10-xima are depressed t' ' 18 Much less active
P' tod. plas h4n the~Other subat~,._
.a2) were determl oclatIon cons ntg~ (.pr,., a
stren&th. 1 9. --d In 7 alcohol at r. ndl
75 aild'9-7- ,I ather low Ionic;
rfilmine 75 and 9,5; IT 5 6-deh Otetrawth
and ov 9 -3. 8.4 Y111014r-
and 'te 9
1XX 'v 8 - 3
See Communicat1w, 11 In R
Matousek zhMin -19$3~) SO 231 54749.
Card 2/2
34
-------------- 7-
SUKAY. P.; ZUKANOTA. A.; SOMAK. B.
Fol,^~rographlc determination of carbon bioulfldlo',by "MIOAS rays Lin
German with summary In Russian].' Sbor.ChskhAdAv.r&'b. 18 no.3i632-447
0.'53- (MU ?:6)
l..TSentrallnyy polyarograflohaskiy ine\,itut lAnstitut profeablonsIlAfth
zabolevaniy I trudovoy giglyany. (Carbon bi'slulfida) (Polarogiaphl'and
C, v"',,- 11 . ; ZU"VAN, , P . " 7CU =-.,,
"Polarographic Detemiraticm of C-arbcn Disulfide Witll!Thc 41(r$ of Arc(I'L
Uaves", P. (32, (CCUECTICE CF
Vol. 18, Vo. 5, Cctobcr 1953, Prahn, Czech.)
110: Y-nthly List of East European Accessioxis IX, 76!. 4, '0. 31
March 1955, Uncl.
U-
111-im, r n7l; I
CZECHOSLOVAKIA Physical Chemistry. 1,91eet.rochemistry. B
Abs Jour: ilef Zhur-KIMM176j No lgo1958, 63904
Author Z R; Teisinger J; ZuMan P
Inst f-got give-n
Title The influence of Albumens on theiPolarographic
Behavior of Metals and Their Compounds with
2-3-Dimercaptolpropanol.
Orig Pub: Chem. zvesii, 1957, UP No 517-527
Bi ~Zn) Cd and Pb
Abstract: Waves of Au, Ag) Hg, Cu, Sb~
are reduced in a citric bufter solution (pH 64-3)
with the addition of albumin (I),during which
the dependence i on the I,~concentration is
gr
exponential. Th Be data are explained by the
Card 1/3
OZECH03LOVAKIA Physical Chemistry. leatroohemiatty, P
Abs Jour: Ref Zhur-XhjmiY;a, No 19, 190, 631904
AbBtract: complex formation of metftls~1(14) with (1) vin
It , om
addifton~ the'~Au'p'Ag'j H#-AhdiS d. Plexesigre not
reducible and in the abeendelof I the waved' of
thene M didapo6g~, WM16 Cu,.~~?,Id tihil Pb 0"PloXes
are reduced) and', their waves I are. Toduced w1th 'the
addition of I to.a somewhat 11mited valuej'whieh
is determined by,thd coeffictont!:ot diffusion,of
these complexesoT;ArVaddorptlon ret6r*datioh~of
the process simultAfteously ~Opear;'O-~ which -i Indicate s
the' character'' of 1 the'i-i t depsndei~ce of thellreduced
waves: on' ' them! height Oif Pthoi ~6kervblr ~ US arid the
reduction,,of theiCu. wave only in the limited area
of potentials (trough), With theiaddition~of I
to the solutions of complexe6~of Kwith 2.5-
-dimereaptolpropanol (II), the M waves are also
reduced but only because of the adsorption~
card 2/3
// MY 0 V/1 .41 ~
TBISINGER,vj.; ZUKA.NOVA, R.; ZMTA, L
Effect of calcium salt of ethyldiaminotetri~dtlc Acid on lea&
binding In erythrocytes and blood proteins. ~;Praco-mi lek. 9 no.4v
277-280 Sept 37.
1. Ustav hygieny prace a chorob % povolani 4,11rass, reditel prof.;
MUDr J. Teisinger*,
(MATHAMIL, off,
on lead binding In erythrocytes 6 blood protelzu (00)
(MIYTHROOTM, eff. of drugs on
edathamil on lead binding (0t))
(BLOOD PROTEINS, off. of drugs on
Sams)
ZUMANOVA R.
Effects of proteins on the polarographic behavior ofimetal~ ad their compounds
with 2 -dimer-captoprop-anol.
P. 517 (Chemicke Zvesti. Vol. ll,, no. 9. Sept. 1957., Oratislava, Czechoslovakia)
Monthly Index of East European Accessions OTAI) CL. Vol. 7,j ~io. 2,
February 1958
,41~
'f~ 1 71[l 1-*:~ '!'11-11:
"Polarographic detemination of ciLrbcn disulphidc from itvanc-dic wave." P. 17811
(cm4T-cKE Lim,, vol. 47, 112, Feb. 1953, Czechoslovakia)
ZUMBADZE, D-11-; 114VROTSYAYA. V.S.
Comparability of the results of studios on dry stindq obtalnod
on the basis of difforont criteria. Trudy~OGHI~ no.I9:31-54
159. (Min 13 -.5)
(Vinds)
AKHLIADZE. G. L. DLO
LMAIRM-MAX.-O
Certain surgioal forms of crucallosis. Xhirurglu, Monkft no#12:55-39
Dec 1933, (GIKL 25:5)
1,, Candidate Medical Sciences for Akhalafts. 2. Of lasbapk BAYOU
Hospital (Real G. L. Umbadze),
AKHALADZE, G.L.. kandidat moditsinakikli nauk; ZMADZEj (;.L,
Certain ourgical formo of brucelloois. Xhirvrgila rio.12:55-59
D '53.
1. Iz Kasbegskoy rayonnoy bollnitoy (zaveduyushchly G.L.Zumbaifte).
STMIME, Milda; MISEVICS, V.., kand. ~ekonom. naO... red. I
red.; BITARS, A. p tekhn. red.
(Waya of Improving tboa overhaialing of ivdus4xial 6,quipwnt i~:
the metalworking industry of the Latvian SA R. ]Razos
anas
iekartu kapitalremorita pilaveidoswas iespe~&s Latv*Ls Pqt
metalapstradasanas rupdeciba. Riga., Latvij" PSR Unatnu
akademlJas, i%devnieciba, 1961, 91 P. (111M 15:3)
(Is.tvia-44otalworking machinery-Maintenmee =d repairs)
~ 1
VALDM,VIIS, Andrejs; ZUMBERGA, M.t zed.; PILADM-0 ?4.p tolft. red.
t
~i 4
ZVMRIS, Arvi-' Indrikoviohl kbn~ red.
_~ ~IRCI~LAtj red.1 FARGIM, J.1 to 41
- i ~ - - 0
CIPENS, Gunars; ZUMBERGA, M., red.
I . I
v-w
LChemical foundationo of heredity and mustltlonij ledzim-
tibas "A mainibas kimiskie pamati. Rigap Lat Iviias PSR
Zinatnu akad. izd-ba. IC)til- lnA n- fTh iTjifvih-n
CIPEg Kalmansj GULANS9 P,, kand. ekon. nauk, redq~,JIRZINA,~L.,
kand. jur. nauk; ATUEMI,-T. I red.; LEMIGA, A.' takhn.
p
red.
[Cash paMnt for the labor of collective 4=erdij Kolbos-
nieku darba samaksa nauda, Riga, Latvijas PSR zinatnu
,511, A.[Rasins, A.]. atarshiy nauchnyy sotr.i SAVILIM 'A, J.),
red.; ZUMBMGA, M., red.; BONDILRE, A.., tokhn. rW,
(scientific and tecbnical ta~rminology)Neaphlnaia~i tokbni-
cheskaia terminologiia. Rigd# Izd-vo Aks.4.3hauk Latviiskoi
SSR. lio.3.[Plant protectionlZashchita ra6tmnii. 3.960.
591 P. (link 15.- 10)
1. Latvijas Padomju Socialistiskas RepublIllas Zihatnu Akndamija.~
Latviesu valodan terminologiJas komiaija.'!. Pribaltiyskvqa,
stantsiy" zashchity rasteniy (for Rasinuh).
(Plants.. Protection of-Dictionari6rj)
OZOLSO A., akademik, otv. red.; PETERSONS,, Z.v kahd'4seliAozo
nauk, red.; ROMANOVSKA, O.,Aand. selfkhd'z',,nauk, red.1
SPOLITIS, A., kand, sellkhos. nauk, red.j-."f-qip---m-v
red.; PILADZE, Z.p tekhn, rod.
(Possibilities of im rovingUe winter hardiness and f V
resistance of plants~ Augwziewietiba, ai.~atumizturibaousn
to kapinasanas iespejago Riga, Latvijas PSR Zin4tnu akad.
izdevnieeiix, 1962. 186 p. (MIRA 160)
1. Latvijas PaOomju Socdalistiskas ftepublikas zinatnu Akademijav Biolo-
gijas instituts. 2. Akademiya~ nauk Latviys~oy SSSR (for Owls).
(Plants-Frost resistance)
red. 1 131
GALENIECEp K.; TAUKA,, L.; Z!RjM8qAL_M TARS A. tekhn,
red.
[Guide to Sphagnum moeses In th-9 Latvian: $,S.R,'~;'a brief
survey with tables for the'determination of Sphagnum see-
tiona and species] Latvij%s PSR sfagnu suft notaieeje; iss
parskats ar sfagnu seioiju un 'sup notalkmanas tabulam.
Riga, Latvijas PSRS Zinatnu akad. i%devniecibaPi1962. 109
(MIRK 16 3
(Latvia-Mosses)
red.; EOMNIS,.Al., takhm. red.
MIKELSONE, Ausimjj~~XXA
#,pg beans] grmu pupinas. Riga, LatVIjas PISR Zinatnu
[Sti
Akad. izdavniscibap 1963. 50 po (MIPIA 160).
(Latvia-Beans)
N, -
: I
VIWIANE, M~; ZU14BMGA, M.,, red.
Norclasuses) flarciscoo High.. Latv.ljas N11IZinatva aked.
lzd-ba, 1963. 39 [In Latvian] (MIM 11 7)
JUYJIA, rturp; ZIEDIN3, Indulls; oZ,,,)LM dia;
7WIRERGA, M., red.
. ..........
(New illaterial,, fror'. "10013 wa.3Q') inun-I
atlilkao. Rig., j,ajvj no koksnel
130 p. [in iatvu,,) jan J)qj Mnatntj akild. lzi-I)RO 1901
171
I
1 l~ I
CUDARSj Jazops; ZU14BEROA rod.; TXMIMRGA, A., tlokhn. Tod.
~ -~- -fm -j il.
OAVEL'YEVA,J., red.; ZUH39RGA, H., red4l INKIS, H,,~, toldmo red.
(Scientific and technical terminology) HAuabnaid I tekbnichol-
okaia torminologiiao Riga$ lzd-*io had, zt,&~k La~viiskoi SSRV
No.1 [Technology of metals and machine parts; Natvian-
Russian., Rusolan-Latviaa)] Tekhnologiia xw~allov, i eleme
nty
ahin; [Latviisko-rueskiiO ruasko-latviiskii) 19~~8,,MI20 p
0 a V
Y
Zinat
1. Latvijas Pad=ju Socialistiskas Republi,~Aa ak ~~Ja'l
Teiminologijas komisija.
(Russian languoqe-Dicti~,noxi~s- an),
(Latvian lk%ruage-Dictfo'wie6--RUsOi&UY
VALDMANIS# A.p doktor biol. nnuk, tail.) ZUxOV6UPA;0
takhn. red.
(Methods of vitamin and microelement detOzination] Vitamitu UA
mikroalementu notoWanas matodes. Mp.. Latvijas PS11 Ziluitnu a'ka-
demijas izdevniecibap 1959. 96 p. (In Latvianj~ (HIM 340.~)
1. Latvijas Padomju Socialiotiskas Republikas Zinatnu akadeaIjis
Biologijas inatituts,
(VITAMINS) (TR=~$LEHUTS)
FUKARAK, lAF'R, T.,- MSTRGVI,p S.; KIJEp D.; LWJICEX Z.; & WANX,, D.
v JIG , p p
SEVNIKp F.; ZAGARO B.; MIKLAVZIC, J.; HU, A.; PIPAN, R.1 FUIIY.L, L.;
SVETLIGICP A.;_~Ul R,_L,; KP.110, Ft.
Revoiw of poriodicals; silvicultize. oul,i::c Youg 9 r0.4/5:144-.
145 Ag-o 64.
A, , . -
ZMO ; 91RCA *1 F.
MR, M.; SIRCA, F.
i :
I
SO: Monthly List of East Euroepan Accessions, (EEAL), LO, V4. 5, ';No. 3
t
March, 1956 . j
BUICp 4,3,; Goiac' L.1 PETERMO P.1 SIMR, J,;Z il"M. mi.
~Slovlom dr 9
the CaO Al.,)(~ at lov temperatures, Watt .1
nooV,2t27-32 la;%Te 162,,
1. Laboratorij za anorgansko komijo, Instittit za kemijo
Vniverzo v Ljubljani'p
I
~Jjjt~U-24qm And L"L"L-.Uj"-
-t it
0 ritm9killi 110NIM1.11, "tpi ob "afte"llwo
SIRCA, F.; DOBOVISEK9 Bogomir, docent, dr. inz.; GWENAUER, S.; KOBOVIITC, I.;
HAMRIAI B.; VODOPIVEC, F.; KUSCERp D,; Kfi'RNCp J.; DROBINEF F.;
PAVED, D.; CAZAFURA, K.; TURKp St.; OCM4, Drup, docent, dr.:inz.;
ROSINA, A.; LUMER
.j4q SOVINCr 1.
New books. Rud met zbor 4i431-457 163,.
MER M : 51RCA) F.
ZUM, M ; SIRCA, F.
ZUMKINA, T,14, LUERSKIY, A.P.
Photolonization abnorption In alkali hillidd trysuili In uic 23-196
range. Fiz. tver. tela 7 no.5t1455-1461 1,14 !65. (MIRA 1 11 81 0
1. Loningradskly gosudarAvennyy unIveraltet"
ZUKHAYAp Ye.M.
Case of multiple osteochondropathy of the ~piph~vojs of the phlanges
of the hands. Vest. rent. i rad. 37 no.2:67 Mr-Ap 162,(KM 15'4)
1. Iz rentgenovskogo otdoleniya (zav. Te. Ydnlc~vich) Mediko-sanitarnoy
chasti. Chelyabinskogo traktornago zavoda. (nachal.1nik L.L.Scredinina).
(FINGERS-DISIPA-11
A060^000
AUTHOR: Zumpe, Guenter
TITLE- Introduction of the elementary load funatica,and,the equalizing
Dinction into the solution of problems relating to flexure of'
beams
-PERIODICAL: Referativnyy zhurnal, Matematika, no. 11, 1~62, 7,6,
abstract 1IB316 (Wiss. Z. Techn. Univ. Dr6sd.en, V)61, v. IOP
no. 5, 108c) - 1092, German)
TEXT: The essence of the method proposed by the "thor for flndlng'~the
extremum of a certain Riemann..;Stieltjes integral consist I~ in poplacing the, class
of admi.5sible sufficiently smooth comparlson llne~ by a ~~lass of functions! coli-
taining plecewise constant functions of elementary loadsl~and the concentrated~
load function. The character of the solution of the variational problem obtained
In the manner Indicated Is not Investigated.
L, Ya. Talaf
(Abstracter's note: Complete translation]
Cartl 1/1
S/04YO~/1000/POS/048/M
CIII 03 3
t; 3
AUTHOR:
TITLEt The application of the.matrik,calculus at the deduoiian:
of the extromal values 0U0ontinuoua':beam' cutting Powera
PERIODICAM Referativnyy zhurnalq Matematikel n0$ 8, 1962t 36
it
abstract 8V184-'.(WiRs-i Z. Teohn6 dniv. Dr.eaden"s, ;90
10, not 6p 1339-1,344)
-:TEXT: One d6scusses the reductio]*W of boundary value problems
.for ordinary differential equations toga sequih4e of iroblems iith
initial values; the reduction i's done by aid oflhe Green's fu~citios.
Thereby the matrix calculus is highly used.,t,~
[Abstracter's notes Complete tra'nal'ation*3
'Card 1/1
rMl
8/04 62/000/608/049/073
AUTHORs Zumpeg G.
TITLE; The formation rule of the elements 6f tho transformed
matrices and the leap quantities ofithe reduction me-
thod'and its application
PERIODICALs Referativnyy zh .urnall Matematikap nIo' 8,,1962p 36p,
'('fWiss. Z. Te''ohn. Vnive Dreaden't
abstract SV185- iq6i~~
lop no. 69 1377-1379)
TEM, This is the continuation of the premeding paper of
the author.(see Ref. 8VI84)-
[Abstracterts note: Complete translationl'.
Card 1/1
B1111,116,11,1 1 11 41A d HIMH Moffitl
11 )1 SKA , Parma; all Faraiti
r1logical tund ierologicn.1, Invintiption cX nomi-Onfccl.lont.1
Yo-jpltit'. pailenta in ',!aiiisw In 1%3, I'v2egl, ep-MeirIcL
1. 87 -f,) 216
6~1
-JI
~~~ SPELINA, V.
Treatment and diagnostic use of intrix-arterial oxygen insufflation
in ischemie conditions of the extremities (Pr6liminw report)f Rozhl.
chir. 42 no.1:30-43 Ja 163.
1. 1. chirargicka klinika lekarske fakulty KU:* Pl- ii, Mdnoota doce
dr. J. Spinka.
(OXYGEN) (EXTREMITIES) (VASCULAR DISEASES)
(ANGIOGRAPHY) (DIABETIC ANGIOATHIE3)