SCIENTIFIC ABSTRACT TURYAN, YA.I. - TURYAN, YA.I.

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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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USSR/ Analytical Chemistry - Analysis of Inorganic Substanckas G-2
Abs Jour : Reforat Zhur - Khindya, No 4, 1957, 120M
Author : ._Llx!Zn Ya.I., Toper G.E., Redchenko L.F.
Inst : Comission on Anal3tical ChQmistry of the Acadomy of
Sciences USSR
Title : Polarographic DotorminatAon of Nickel- and Cobalt-lon3
in Absolute Ethanol
Orig Pub : Tr. Komis. oo analit. khimij. AN SSSH, 1956, 7(10),
162-169
Abstract : In 0.1 M solution of WH4110~ in absolute C2H50H it was
not Dossible to obs,::-.cvL:d n6rml polarographic waves of
Ni and Co. In 0-5 M solution of GaCl,, elongated waves
were obtained !~or NL whi.ch are unsuitAble for quantita-
tive doLcrmi.nations. Thu Co wave is be~ttor defined. A
direct Droportionalit:- was rioLod between diffusion cur-
rent ana coacentration of Co. In 1 M solution of
NHj,SCN th,~ Co in contradistinction to Ni produces no
,Y_161-01/~_
Card 1/2 IV

USSR/ Analytical Chemistry - Analysis of Inorganic Substances G-2
Abs Jour Referat Zhur - Khimiya, No 4, 1957, 12o88
polarographic wave, Ni wave is very wcll defined. A di-
rect proportionality was notcd between diffusion current
and Ni concontrati:;n. Th;~ pi-ocess of electric rQduction
of the thiocyanate coiaplo;c of III is irreversible. With
a pyridine backgrotuid. waves of' Ni and Co are, very well
defined. In both instancos thcre is a direct proportio-
nality bQtwe,.~n di,ffusion currunt and conet2ntrations of the
,metals, Pro~:%Isscv of clQctric reduction of pyridine com-
plexes of Ni and Co are rcvcrsible. Half-wave potQntial
of Co is lower by 0.22-1 than that of Ni, which makes it
possible to obs-_--rvc distinct waves. Addition of pyridin,~-
to a solution Of CaCJ-2 in C If OH results in a convcrsion
of the chloridc compl_,xcG oi ?4i and Co to pyridine coin-
ple;.es. In all of thQ investigated solutions, exce-pt for
0.1 M NH4NO3' the polaroG-f=n of Ni and Co showed no ma-
xima although no substnnces that eliminate the maxim
wQre added.
Card 2/2

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Once more on the polarographic determ ation of the composition
and stability of complez ions In a sol. ;Jon dta4ng stepwins
complexing. Shur.ob.Wu. 26 no-7:M4-2W ii ;56.
(KM 9:10)
1. Kishanevskiy gosugarstvemVy universitat.
(Pblarography) (Compounds. Complex)

IM h,
USSR/Physical Chemistry - Electroc*stry, B-12
Abst Jov--nal: Beferat Zhur - Khimiya, No 19, 1956, 61170
Author: Turlyan, Ya. I., Grfdshteym, 1. S.
Institution: None
Title: Oxygen Overvoltage of a Nickel Electrode N, High Current Densities
Original
Periodical: Zh. prikl. khimii, 1956, 29, No 3, 379-384
Abstract: As a continuation of previous work (Fiseyokiy, V. N., Turlyan,
Ya. I., Zh. fiz. kbimii, 1950, 24, 567) investigated was the
ovex-ioltage (7Z)02 at Ni-anode in 7.5 N KOH at 1 0.04-10 a/cM2
and temperatures of 00-850. Measurement of potentials stabilized
in time with the given i was carried out on rotating electrode.
Comparison of the derived curves (I., lgi) fcr different temperatures
with data of previous work (see reference above) permits to reach
the conc~uslon 4f the presence upon the ft;ves within the region
of i i0-11 - 10 ii./CM2, of 4 d,,fferent sections. The linear sections
within the reg-'jn of high 1~ the length of which decreases with rise
Card V2

#MR/Physical Chemistry - Electrochemistry, B-12
Abst Journal: Referat Zhur - Khimiya, No 19, 1956, 61170
Abstract: of temperature, have an inclination coefficient close to the
theoretical value 2.3 RT/bcF (with cc a 0.45) corresponding to
the slowed down discharge of OH- ions. Sharp increase of I be-
yond the linear sections of (~, lgi) curves in the region of
high i is correlated by the authors with the beginning of the
formation of a higher ox14e of Wi, In comparison with NiO2,
which determines the lower limits of the linear sections.
Card 2/2

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AUTROAS: Tarlyan, Yd. J., and Seroval G.F'. 568
TIT~E: Polarographic Investigation of the Composition and Stability
of Complex Ions at Low Concentrations of the Complex-Forming
Substance, Halide and Thioeyfinate Complex Compounds of
Cadmium-. (Polyarograficheskoe Issledovanie Sostave i
Ustoychivosti Komplesknykh Ionov pri Maloy Kontsentratsii
hchevo Veshestva. Galogenidnye i Rodanid-
KompleksDobrazu
T
nye Kompleksnye oedineniya Kadmiya).
PMTODICAL: "Zhtiimal Neorgani,cheskoy Khimii" (Journal of Inorganic Chemistry
WO.E.111 Vo-;ef PP..33b-342.. ku.97S.R.)
ABSTRACT: The equation of Yatsimirsk, 4, relating the half-wave potential
ly
of a complex ion to that of the simple ion, to the concentra-
tion of the complex-forming substance and to the complex-ion
instability and dissociation constants should be especially
useful at low concentrations. In the investigation described
a visual polarographic-installation with potentiometric sett-
ing of the drum and a normal calomel reference electrode was
used to study the behaviour at 25 + 0.300C of cadmium at low
concentrations (0.001-0.1 mol) of 33mplex forming substances
(KCIP KI and KCNS). Oxygen was removed by passing hydrogen.
The range in which only two types of ions were dominant:
CdF and one of the following [CdCll*, d1j+ and ECdCNi-+
-,
4EC
)
H=.
For these conditions the Yatsimirskiy and-De Ford- -
9quations gave identical results, but the simplicity of the

568
Polarographic Investigation of the Composition and Stability
of Complex Ions at Low Concentrations of the Complex-Forming
Substance. Halide and Thiocyanate Complex Compounds of
Cadmium. (Cont.)
former makes it preferable. From an analysis of the Yatsim-
irskiy4 equation it was shown that when simple M and complex
NX ions are dominant the half-wave potential corresponding to
the concentration of any addendum is numerically equal to the
instability constant of the NX iong more negative than that
of the simple ion by RT ln 2 volts.
Ry
This rule was found to apply to the complex ions [CdC1 +
[CdaUS]+ and [Cd3l' . Using Yatsimirskiyls4 method the -
stability constants for the complex ions [CdI09 LUI
formed at KI1 oncentrations >0.03 mol. In cantrast io-
A-Jd. Golub's i polarographic results7 the instability-
constant values found agree well with those in the literaturey
including Golub1sll potentiometric ones.
Card 2/3

568
Polarographic Investigation of the Composition zind Stability
of Complex Ions at Low Concentrations of the Complex-Forming
Substance, Halide and Thiocyanate Complex Compounds of
Cadmium. (Cont.)
There are 15 references, 9 of them Russian.
Ref'.4 is K- .. Xhimii, 1,193, (1953).
.,,B.. Yatsimirskiyj ZhuTnal Ob
Ref.5 ip D.D.De Ford and D.N'.Hame, J.Amer.Ch6tm.8-oc'.73,5321,
(1951).
Ref 11 is A.M.Golub-. Ns:ukovi Zapiski Kievskogo gos.Un-Ta. XIV,
4; 619 (1955).
5 Figures, 2 Tables.
Kishinevskiy University. Received 28 Sept.
1956.
Card 3/3

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USSR/Fhysical Chemistry - Electrochemistry.
Abs Jour: Referat. Zhurnal Khimiya, No 3., 1958, 7320-
Author :
Inst : Kishinev University.
Title :Polarographic Characteristics of Thallium, Cadmium and Zinc
in Aqueous-Oxane Solvent.
Orig Pub: Uch. zap. Kishinevsk. un-ta, 1957, 27, 149-157.
B-12
Abstract: The polarographic reduction of T1+, Cd2+ and Zn2+ in dioxane
(I) - %0 mixtures (from 15 to 75% by volume of 1) on the back-
ground of 0.01 M of LiCl is reversible. A linear dependence
between id and the concentration is observed at concentrations
from 0.191 to 0.905 . 1o-3 M. FI-s shift to the positive side
with the rise of I concentration 2and the constants of the dif-
fusion current decrease. See also RZh-Khim, 1956, 6505-
---I' I+ - --DL .
Card 1/1-- - ; -- -17-

TUOTAN, Ya.I.; SEROVA. G.F.
Polarization in the polarography of the pyridine complexes of
nickel and cobalt Lwith summary In Xnglishj. Zhur.fiz.khim. 31
no.9:1976-1982 S 157. DIM 11:1)
l.Kishinevskly gosudaretveaM universitet.
(Nickel compounds) (Polarography) (Cobalt compound)

774tf~ _z-
76-10-5/3,1
AUTHORS; Turlyam, Ya.I., Serova, G.F.

TITLE 1 Inve.--,ti-%ti,)n ~J the Coiripooition and the Instabi-
A Polaro~;ra
lity Con.,tunts of Pyridin,~ of (Polyur,~grafiches-
koye i isled ovzaniyo oc-1;ta,;-:-_ nestoy.-,oti piridinovykh
komplektjov n1kQ1ly.L)
PERIODICAL: Zhurnal Fizichp:jkoy Kiii::iii, Vol, ~1, 1~r 10, pp. 2200-2205
(USSR)
ABSTRAM The results of the former paper of the authors in Zhurnal Fizi-
cheokoy Xhinii, 1Q~16, 31 , Pr,. 1976, or, the basis of 0,1 and
m YNO without gulatina are exploited here for tae detez-mination
of th~ composition md the instability const;,nts of t~e pyrAdine
complexes of nickel. 'The zuo;-tsurin- temperature was 25 � 0,3 C.
The here found relation tetween the potential of 'the half-wave
~pi/20) and the lac-'aritht.-i o f tho complexformer (pyridine) con-
contration io a ourvc., .1 f!LCt V/LiCh PrOV08 the -nimultaneous elec-
tro-recon;itruction of tVjpeo of thtj nomplex ion as well as
of the simple (hj,Jra11i,r)n) niclk,~!! ions;. F(,,r thit determination of
the composition of' complec ion-i and of the correoponding inAtabi-
Card 1/2 lity constants two metficidj were -applied here, one of Deford and

76-10-5/34
A Polarographic Investigation of the Composition ind the Initabaity Conatants
of Pyridine Complexes of Nickel
Hume (Journ. Amer. Chem. Soc., 73, 5321, 1951) -and the other of
K.B. Yatsimirskiy (Sb. StUtOy PO obahchey khimii, 1, 193, 1953).
It is show-n that in the pyridine concentration region of 0,01 -
I
- 0,5 M (c 4r"s 0,2 1,101/litre Pyr~dine cpmple~e of h
Ni so a _+ ,,;Yn
ckel of the it c 01.1po 3 i t i o: 6ipy +) t L"'PY; and 3
,with the corre innt~.,.'hility constants K -'~7
.3pondinf,
K2 - 1,1 . 10', and X_ 10-4 (0,1 M KR are formed. The
instability conQtzinto Obtained -ac
cor ing to both meth-
ods aeree accord-an.- to orc-er of _-1_-s~nitude. A certain development
of Yatsimirsskiy admitted "o carry out the computation of the
instability const%n'Q7, wi tl,,(~.~,,'t ujir~_ the potential of the half-
wave of the simple ion. Ilhii J s very impcrtant especiall.,r in the
casq of the irrever:;iblc,~ of simple ions
(jlj~+' C02+' -.,nd %i .,ri) . "here are 6 fi-ure:3, 3 tables,
4 Slavic references-
ASSOr'!ATION: Kishinev St-t_,tc Univcrsi.~.';"
SUBMITTED: -,lay 17, 1956
AVAILABLE: 'library of Con,oress
"Ki,.3oAncvs'--1iv ;,.D3udurjt,rennyy universitet)
Card 2/2

talp -'~ bw 0
U A
AUTHOR: Tux-Oyan, Ya.l. (Kishinev) 76--11-6135
TITLE.- Investigation of Polarization in the Polarography of Thiocyanate
Complexes of Nickel (Issledovaniya polyarizatsii pri polyarogra-
firovanii roaanistykh kompleksov nikelya)
FMODICAL: Zhurnal Fizichaskoy Xhimii, 1957, Vol- 31 , N r I I t pp. 2J~23-2427
(USSR)
ABSTRACT: Polarization in the polarography of thiooyanate complexes of nickel
was investigated in dependence on potassium, thiocyanate concentration.
It wan ahown that, in the case of smaller thiocyanate concentrations
(0.002-0.02 M) three nickel waves are formed: The first two (in the
case of more positive potentials) correspond to a resteratica of
nickel thiocyanate complexes, the third - to the eleatro-restoration
of simple (hydrated) nickel ions. With the increase of oKajS the first
wave bece larger, the second and third beca smaller. At oAMS>,-O-1 X
only one (the first) polarographic nickel wave was observed. The
reason for the occurrence of three waves in the o&ae or a low thio-
oyanate concentration is the deceleration of the procesis in which the
nickel thiocyanate complexes fom on the surface of tho electrode.
Cam 1/2 The YI/2 - OKMI S curve passes through a minimum. ( Y'V2 - potential

76-11-6/35
Investigation of Polarization in the Polarography of Thiocyanate Complexes of
Nickel
of the half wave). A shifting of r,/2 towards the positive side
with an increase of cy=S is explaitied by the decrease of electrode
polarization which is sometimes connected with the deceleration of
the process of nickel thiocyanate complexes. The shifting of Yi/.
towards the negative side with the increase of q4WS is charao-
teristio of reversible processes, although in this case the process
is still, in a certain sense, irreversible. By means of extrapola-
tion of the right branch of the K1/2 - c
CNCNS g curve f or the value
-~ 0 the reversible potentia amountq the half wave of the
simple nickel ion, and herefrom the normal nickel potential was found.
The amount of the latter is approximately the value mentioned in
publications. There are 3 figures, I table, and 6 referenoe:s, 3 of
which are Slavic.
ASSOCIATION: State University of Kishinev (Kishinevskiy gosudarstvannyy universitst)
SUBMITTED: May 3, 1956
AVAILABLEs Library of Congress
Card 2,/2

AUTHOR .-TUROYAN, Ya.I., PA - D64
TITLE The Polarization Mechanism in the Pollarography of Simple Ions
of Nickel and Kobalt
(Mekhanizmpolyarizats;L nri p olyarograf irovani i pros t7kh iarxv nfkelya
i kobal'ta, - aussian)
PERIODICAL Doklady Akademii Nauk9$SSR, 1957, Vol 113,Nr 3, pp 631-634,
(U,S.S,R.)
Received 6/1957 Revieved 8/1957
ABSTRACT In order to subject the theory of retarded discharge to a fur-
ther examination the influence of nature and of thia ooncentra-
tioA of the basis was investigated. Investigations were carried
out on a visual plant with a normal calomal-comparisou-slootrode.
In the case of nickel the obtained results make it possible to
explain the inconvertibility of the polarographic wave N12+ by
the retardation of ion-disahar a The equations established by
F-munkin A,.N*(Zs. phya;9Ch3m*(A1 ;64, 121, 1933 and "Kimitics of
electrode-procosses", 52 are confirmed by the experimental re-
sults. A a'eries of facts prove the applicability of the theory
of retardod-discharge and explains the inconvertibility of the
polarographio wave of simple oobalt-ions. There exista,howsrer,-
a small differnese b tw:la the polarographic behavior of 0'02+~
and that of Nj2+& th: 0 + wave in not aymmetriual on the nitra-
Card 1/2 te- and perchlorate basis. On the wholeg the Co2+ -wave is more

PA. - 3164
The Polarization Mechanism in the Polarography of Simple Ions
of Nickel and Cotait.
inolined than the N12-+ ^wave.
(2 illustrations92 tables and 5 citations from Slavic publi-
cations)
Association State University of Kischizew. (Kishinevskiy gosud&rBtvannyy universi
Presented by Prumkin,L,X,,, Member of the koademyg 15o9*1956
Submitted 7.1a.1956
Avaail ble
D
Card 2~2

~j,
AUTHORSt Turlyan, Ya. I., Gorodetskiy, Yu. S. 2o..4-,,1/52
TITLEs The Oscillographic Investigation of Oxides Which are Formed
on a Nickel Anode With the Electrochemical Separation of
Oxygen (Ostaillograficheskoye issledovaniye okislov,
obj~mquBbM" na nikelevom anode pri elektrokhimicheskom
vydelenii kisloroda).
PERIODICAL: Doklady AN SSSR, 1957, Vol. 117, Nr 4, pp. 655-657 OSSR)
ABSTRACTt In order to discover the mechanism of an overvoltage caused
by oxygen, both the nature and concentration of those oxides
which are formed on a smooth nickel anode in a basic solution,
must be known. First, several previous works dealing with this
subject are mentioned. The authors developed methods for the
osaillographic investigation of a smooth nickel anode. This
made the determination of the quantity of stable oxide and
also of the quantity of unstable oxide, possible. The essential
feature of this methodicB is explained here by means of a
graph. The elaborate investigation was c -arried out here with
an oacillograph of the type MITO-2 with 8 loops and photo-
graphic recording. A spectrnscopically pure nickel anode was
investigated. The approximate course of the "complete" curves
Card 1/3 of discharge (of the first one and of the one following up

The Oscillographio Investigation of Oxides Which are Formed 2-11-_3V52
on a Nickel Anode With the Electrochemical Separation of Oxygen.
to the complete reduction of the oxides) is shown in a dia-
gram. The upper horizontal part section on the first curve
corresponds to the polarizing current still switched on. The
point of current-decrease is obtained at the moment of switch"
ing off the polarizing current, then the middle horizontal
section follows and subsequently the current intensity de-
creases down to the lower horizontal sectional part. The lower
part-section corresponds to the presence of NiO on the sur-
face. The middle horizontal part-section part C03-responds to
the reduction of NiO and N12O3 . The decrease of the amperage
from the middle to & lower horizontal part-section part
takes place comparatively slowly. The quantity of electricity
corresponding to the "complete" curve of discharge depended
only very little on the intensity of the polarization current,
but increased with increasing duration of polarization. The
"incomplete" curve of discharge reproduced in a further dia-
gram, had no upper horizontal part-section, because the polar-
izing current was switched out prior to the swit,-.hing on of
the vibrator. The surface of the "incomplete" owrve of
discharge was smaller than the surface of the "complete" curve
Card 2/3 of discharge. After a very brief period of "recovery" (some

,The Oscillographic Investigation of Oxides Which are Formed 20-4-31/52
on a Nickel Anode With the Electrochemical Separation of Oxygen.
seconds) this reduction of the surface increased with de-
creasing duration of the "recovery". A quantity of - 3NiO2-
-layers resulted from this reduction of surface. This confirms
the complete covering of the surface of the nickel anode by
the highest oxide within the range of great current densities*
After a polarization lasting 5 minutes, there exist. already
-17 layers of N1203 and after a hour polarization of one hour
there are already-,30 layers. There are 3 figures and 11
references, 5 of which are Slavic.
ASSOCIATIONz Kishinev State University (KiBhinevskiy gosudarstvenrqy
universitet).
PRESENTED: May 21, 1957, by A. N. Frumkin, Academician.
SUBMITTED: April 20, 1957
AVAILABLEt Library,of Congress
Card 3/3

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twe:118stlas the Couplax Formation Ia Salusicas
jetwestigatias, to developed by 'the 34"Ata.,tam. mahool is of
blak val". Is 41*0 pointed to the necessity of at"fias
Us kinetics of the polymorisation process and a quamiltative
determination of %be alrengsla of the polymer$. A. K. D"ke
poiated, out *bal the study of the polymer structure was
samuseemy. S. P. 1"ar' in his Amours that the
ronaor utlolj Sys-ST-9,01'7marLauLium %YR. according to the
salsomae nualeno + chain ambers" to Act obtained In all
no followLme scientists took par% to th. di.oua.l.A4 1.
volaaah". A. V. Ablev. 1. 3. Numtfis. 1. V. Or And
1. 2. Tats4aLrokly. A. 9. babko than ALsoussod La his lectn,.
Methods of DetermlAind the PLAGOGINSLOA Coastam% of the
Complex Groups to Solutl*W the main Principle& of dateraLmIu4
the Instability ocast&Ass. N. P_Xmar' discussed in bit
149SURA 'C4,10"atioa Methods of the Instability Conat"%* of
the Complex Compzuado AsoordiAg to tzparlsental Data- %be
poBsLbL1l%l*s of using the known aalo.latloa methods of the
Instability oonstants for vwioua a&4.& of the ocapl.8 fare-
%Loa in solution. Lt &.octal Anowsolear catvlax.. at* farmat
the dimplasessat method by Abe" met Bodleader (campLe4ed by
A. K. Nakka) cannot be resome.Aded far the 0.10.1411c& or
the Instability sonat"t. Tom lecturer dlecusmed the Ale.
solation &.%boas of The polyftoalals proposed by B,Y.rr-.
Laden. leanest. Sketabard. FAmalloy "A other authors. The
sonstasts 4610.16%44 Is %his may Are, so% Very %ozrat.. It
a" proved that the method of successive approximallous am
Is" to wrong somelusions am so the Chemical press@-. tkLms
place 1. U. system I..4stigaset. The most probable maims
of Me W.10&1 Goastanto Goa to .1ttaind. by the method of
the least squares. 1. V. PSI%Ayn' To. X. ?.later -4 L. 1.
TimAtradova described %he determination methods of the
lastakility of the exalate complexes of aLobl",
~"i~ "A Iran Which mr. lose.d. 0. The In-Sticau" of the
equillbrlm displao"*4% of the complex f-sioa 11y &11"r
loss. N. 9. Dol'shme-., 1. V. Tan"ay- And 0. 3. 3.,oh.ako
hold a locturi-a-F-Th. Sol. of the Time Yma%or In th_._Ta-~o.sig._
Use of the Complex In the clan..tian, Am %be
lecterns A. A. 0:141a.re mentioned that do. t, the *Ia.
adjustment of the quilthria the ..thd. discuss-* of
Card 7/16 determining the last.billty constants (Palldium mad 604.1%
amplases) s- often sat be "Played. I. T. Able, vwxlst
Am% the "messily of 4*vLstag direct method. of P".ID4 the
mlateame of Intermedics. forms La . 6S.P-16. a-PA.. to-,-
tlm~ X. J. Tatsimirskly mentioned that the Instability
owasseats or slo.ly 4184.616ILL.4 a-plar-s a.. be A1Q.lG1.d
f2va' abo~ob..Ioal data. L. P. Adamoviah, A. 31. Golub
eased othows task part in the disou.stoa *a the lectures.
A. 9. UhAs V".ootod loolusla. La %h. "At co.f.re.a. as the
6-16%X7 of GAmPIoS ooapounA8 a lecture LA which serious
se,lodlatlas methods of the testability donot&nts shavad so
"assumed, by the ozampl. of Actual a ... a. Tbj. houI4 .1-try
$0 which divorgonal*a of the values of the constants Alf.
fs"at a-ShOd- of %Us experimental data a- lo.A.
5. P. Kamer, that In the 4.t.rcl.att.. of %h.
".Losilits .... tons. It chemical .4.1111-tia about& be take.
IMA* "count that router complex %be couples formation pr**.&,
in the solution, especially the hydroly.18 prac4some of to*
;.al..l Loa a" %he a4d.nd- In the loctur* d*liver*4 t,

c
1
d 6 And A. P. Z-!'7a -A;FtL..t.-A -.! tta :Istria.-
-
`
l
ar
6
/ t
es %.%ad to %be jA,.
.Tri
ast.. or the stability Co..%Aaas

Conference Discussion an the Method& Of 30T/153-58-3--30/30
larestigatiag the Complex Formation In 3.1stiome
of So" fharju& Complex CospowAs- result. obtained fr" the
ex"rim.atal lavootLgatlo. of it. di.tributioa of SLrtua
o4sposads In the systems, somitylax.toos bases&* - star, WA
aSzy-1.4.--phthoquinams - clacrefora motor we"
From the** data the s.stants at the inarium,
samplazes with aQ*xyl-&s.1oam and 2-oxy-1.4-sapbih4quitmea.
"recalculated. 1. 1. T-suarew. 0. 3. 3-!!-k.rka -4 U. V.
Go"barev hold a Leasure on sm. oppilasti7c-A of the aelubMty
nWTMW'1a the determination of Sba stability of O"PL"
o"Posmas to Solutions, In "is lecture &log other cathode
of LJMQOIL U *a& I x formation, proassese In the solution
g:od'fpl MIssoat. ew.muzon-t of the optimal
w~ Also"
density. a. Wall as or the be.% or mixing). 3. D. S.-Sin
so U a 16 atur. an the -Appli-t1a= of the Solubifffy-No%bod
U 3 the rhthalacy-las C"Flexe. of Ji.t.W. Be
vact the determined of %be
tion of the transition of %be pbtbalocymldea of cobalt,
2
=1. copper "d also. a .*.I " of %he fr.. phtnalo.
out 9116 QF"Ime into the sulfuric 6414 solution for the SbAo"Sloal
"causing. and &4 as exporimea%&I proof of %be 0XIA14449 of
K-boads In tb* compl.zo. investigated. These ah&rmater1otj.s
&I a served him as a proof of now electronic foralae of
0=047"Loo sad Its complex derivatives. 1. the I.clur.
d*llvor-d by 1. L. X-palkin a. -The Method of the Too Sol ... to
" Nstbad of laved-FrIMAg the Formallon ead Propqr1les of
orgamle Complax.o. Is Was proved shot this method makes It
"Lible 'AD deswraL.. the author of complexes formed 1. She
.:tale. their Gamposition and relative stability. V. 1.
L'"Ews"v. A. 9. Sbko. 1. P. gas", , 1. 8. JNGS&fia and
Tm~ 1. TUX'ym took part in %ht* dlacuselan. In the I.Otur.
-Wil!"C-W-I. A. Griab rg .4 S. P. Zi..Iev. a& tbA Complex
palladium @capon" WL S
h . oordLaut on number above
few It gas proved that in she came of a large ablarlac end
Urealue Loft &Ease@ complexes with the coordination awabor 5
arm toro-4. ?h. instability o.ws%"1m of she** eamplo.as
Wro estimated. I ZAl".,Lcb U..tionod a Ace, aa4pulaslon
I& She spootrophatome trio investigation of the amplat am.
pounds that a" be sed I& qot.a. vith the fw..tt.. (or
Pradoalmatioa) of a.& sindl. c.ploz. This method s.A.m I I
Card 10116 possible to detersim. the Composition a" testability owes.
Is the 1.0turs doll-Grod by 9- 3. yatel"rexty
of the
sad T. D. Carbless, %be application Of %he thear7 of crystal.
It" rielzrTir-Us d.termi.stios at %b4 -spamittaft and
Straatur* of the Chloride Gooploxce of Cobalt, ticket A"
oep"r socarding So the absorption spectra of theme ac=PIOA*e
a" discussed. It was Frowad she% I& a hydrochlarla "14
4Wb0QbLtr.tiw& base 5 col./lizar I. thp solution there exist.
ao, equillbrims ketw"A the lotrahetrla sat oGt&h*tri4 to"
or the cobalt ahloro a-ple X.smK.abo proved Is
a 0:; isotopes 1. the
ILL leetere, -The ApplIG&t1o. A-. -Trv.
investig.tioa of she 3.1y.tio. Squillbrium I- 1-4lutLa- Of
examples Campounde- the PGOBM-11%,r Of using data 04 us
Isotope "*bongo to clarify the tr~tur. of the "A
seeb-al" of the hydxatloA Prooo4ses. V. X11mov metAlowel
of radioactive 1::.% op
if hilt: Sao ga-aq V.
Ablov. V. 3. T.Lamghwl, V. 1. 9-40ten' sad I- V- 001" took
part in the di-soi.. of the Th. 4M.f.la-a of
*-7103'IRS tht %h-7 Of the CrLYst---'t0- t'l-14- t- 'ZV'-""Ad
Card 11/16 she results obtaLned fr~a the absorption speo%ra Of the a"-

Comitareass SLaousslam on the Method. of
InVestigatiag the Complex romation In 3olutions
plas seap#u"s was *%rose.&. In %be lac%ure by
1. A. Ask an -?be In,ea%Lgmt1.a of the complex Yor,mallas
by IN-Method of the Dielectric Permeability Ad %he ?*1mZtzs-
%Los- The PVLRSIPIOS of the method. mentioned "" P".Oat*d.
this a*%hQ4 so$ soplay.4 for Investigating the ocapounds at
%b6 typo of the -aftilistion. products. The lecture deliver"
br 1. A. shok and To. Y2,Xr1as -ImployLad the ROAX04 of the
DLQI*Gtrio Constant for In,eatitatizg Complex Comp.umda of
the Typo of Crystal 3olvat.0 in 501.110a.. deals ith the
Lawestilattan of the Golves.0 of lenthanum And G*rl= chlorides
with k0oves, as wall so .1th the study of the compounds
formed In h"Grog.atous systems wish %ribatyl phosphate And
aitrLo said. V. IN Toro a'. Savo In her I*ctur. "7h- Pslaza-
graphic Method of iftvsmating she complex Formation. in
soluslose. a survey of the appli.4tio.8 of the polart4r.phia
matbad In the study of the complex Compounds. and Illustrated
several ties, characteristic features of this metbod. la Us
I"Sure &.Uvered by T. 1. jj!~ko.& -Th* Cr7a.copxc Method
of laveatiestLag the Complex formation Basationow a survey of
.-,.CWd 14114 the possibilities of the aryamoopla method --m gives. And &%a
applicability In %be study of several Complex Gompameds, at
O&AAAm Obl*Vldw wish Orl"io suba%ama.m ." proved. A. M.
Was described the results of his Investigations of %&Is-
glass%* somplAxom of so,.r&l metal.. A w1vtd dLeduselal 1*.k
plea* me, the lectures hold. To. A. Yl&lkov aSS4 Tn. Te~
FLAX]Sov ommaidered %bs oryo.oapto Agthu& of
empl" ocapou". to be of 40ASid.r.bl. value. X. J.
TASSImAtAkly pointed out that the publication of the euj~Ays
60 L"iViduffil methods of investigating the complex famallan
"solLons, would be d.m$redl this mascara. especially 16be
pol&rograpbla method. The cz7oseapto method should be broadkS
t0 A, IOT*l that all*& the calculation of the eq.111brims
assistants Of the processed to be investigated possible. The
problem Of the Method of evaluating She ezparisentel. results
b""** MW* &D4 *or* Important. ALLAY 4GLAR21814 Us. the
LASI&ILISty scas%"te without tsking Into acacuat the .07
Is which they had been oblelawd. TIL* calculation "theds
employed by A. K. Golub Are ca. step book. As compax.4 %*
%bess, employed 0 present. In his lost-. 11. Z. A-Ar,
__P*iAt44 cut tn* Ogtrsa-IY gross import"** of the _*Zthamatleal
"el"UsA Of the results obtained, Am -11 se of the P.,01tim,
Of war-96- A- 9- 2046 suggested *.jectim, ca. a, 1.0
"&% Arm exportzmAtally -All investigated. A" to ... luat.
"a results Obtained --cardig to different ..%hado me, %he%
It Is PG-&Lbl- 10 shook And %has. To I T
took part in &be JjAQu.AjOn;h*y&. &. ?I.
f 3.1
1LIS 1.0%,art, Th. Iff.0% a West .4 the Complex Pers.11,
Process Lovell as a. %be St-%* of Zq.IlLbri- in the 3,1.91=
Of Complex CONP*u"s' IbO Lnflu4-o- Alerted by the
arms the molecular BSAB'. upon %L. sol"Alon. of tn. &yet-
64"ALOAto, upon the stshilts.slo. of the oampl...s to-.4
In the system, upo. the st.p..J.. 41".atatioa of the
4" %Pon a aumb.r of other p"o.do.s. The lAflu .... ... .
by the dlol*otrLe coast"% ~V.a the co.;jwz jo,malta. p,.4.4.
was dle-use.A. it ... G.aclud.d that a 4,",t I...
' exiet. =1 tL. h_AQ.1 me, tur. of the ..I ... t ."I
he Sake- IVA- G4w,"A$. A. T. Ablo, -4 L. I. held
& lessur. a, .Th. aps.troo-aFt-c-1 .... tie.%LQA of Sick.L Cobalt
Ca" t4114 py,i4l.mi.s. to Varlo.6 -.be 1AwS&b&1L1y cast-%*
-9 the --r- determined -4 it at ;",$d be, Zzo

ca"Grasso Dissuasion am the X*tbodo of say/153-50-3-50/30
Investigating the Complex Yormatioa in Solaticas
stability of %be IpyrLdluatoo- In ahame" In depsods"o a.
"a solvent. To. t. Pc*r- In his loesuzo 'Th. Ingluo".
of Illbe SolvearTfoalho Composition "A stability of Complex
ZOW dLeasseal the pol."graphlo lavo.ti4j.tiou .-%hod of
%be 41tlerlda eat Wouysanst emplexas of lead in aqueous
otbanol solutions at different aaalea% of the ano-aqueous
Ivest 6" at a constant lanic, st"Reth. A St.p..160
=
"%or of the o0splex formation was found as well me the
instability 40461"In of the complexes. The Wluoac. of
the tloloe%ris coastaa% of the solution on the ot&bIlI%y of
$be LAIMOSUfated acuplex.0 ." proved. In %be le.tux. by
1. P. 1&&L1 YOT an %b# -Investigation of AqUO C=pl.XQO In
RIxe& Solveatoo the &&I& Attention Was devoted to the &*@as-
"IW of the qualitall.. rewording of U3. dol.4tion Offsets
Is Us samples formation. TILS &ppliO&bIlItr of the polare-
craws method In the doterinatica of %he Gooposillon nod
obabUily of the oquo oomplesse is mixed solvesto was proved
a" oaparimestal U.SeriaL ca the thasmodXa."Go of the
dissociation of the osdalwo-aquo **&planes in aqueous otbanol
card log &Giulioma Was mentlomad. T. A. Toloacb... T. 1. russ.184,
a" l- T- V&aO&*Yfv GIV04-64 in thOIT lectures ths &606soLty
0t a so" sompl-le and general Laasugastom of the salvation.
P"wO44OO. A. K. Sabha &A4 A. M. Golub pointed 0.1 M.
6206% SAVOrfAMAGO of the Invoot1gatioso of the ocaplax form&-
Slon, equ.111brIt, in too-squaous solutions. sad undo several
*rl""I O~sftts as the lool~ by To- 1. 1
-IV-:Zfa. The
following seleatials %Oak post In th same. 0.1 L. P.
Adonavlab. 0. 1. Xboloyanowsk1jr. A. P. X9 a and A. 0.
R"tmkb*v- At the final MOOStAg of the comfore"O A. A.
GlisbGre. COVz~opomdlag Imb.r. A3 MR. amid In him p*..a
%b&% wash a **stores** was very nZa"t. A detalled discus.
OISIL at %1141 d-SOVUL"ALOa methods of the ampositiom of the
somplares. am well am of %be method used in the study Of %be
qu"US&II" "68`64terISILOG of the stepwiss complex rare&-
Uss WaS szt34mGll useful for 8,11 who attested tht- eant.r.&O..

5(4)
AUTHOR: Turlyan, Ya. I. SOV/153-2-2-29/31
TITLE: Once More on the question of the Dissociation of the Aquo-
complexes (Yeshche raz k voprosu o disootsiatsli akvokom-
pleksov)
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Khimiya i khimiches-
kaya tekhnologiya, 1959,, Vol 2, Nr 2, pp 299-300 (USSR)
ABSTRACT: The author argues against the paper by V. P. Vasillyev (Ref 1)
wherein the attempt is made to determine the composition and
stability of the aquo-complexes of Cd2+, Pb2+, and Tl+ in
water-ethanol-Bolutions by means of the polarographic charac-
teristics by the author (Ref 2). The potentials of the half-
wave of these and some other ions in water-methanol- and
A
water-acetone-solutions were shifted in a positive direction
in absence of the complex-forming agentat when the concentra-
tion of the non-aqueous solvents increased (up to 65 %)-
This result must be interpreted in a general way as an
energetic effect of at least four factors. When discussing
his results (Refs 2-4), the author considered from these
four factors only the roduction of the dielectric constant,
Card 1/3 neglecting the remaining three as unimportant. Vasillyev has

Once More on the Question of the Dissociation of BOV/153-2-2-29/31
the Aquo-complexes
interpreted these results in a different way (Ref 1). of the
mentioned four factors he only considers the dehydration
process of the aquo-ions in the state of polarography during
the concentration-increase of the non-aquedus solvents. The
author is of the opinion that on no account shouId it be
assumed that the dehydration takes place also without the
superimposition of the persolvation-processi viz if one
assumes that the formation of coordinatively untiatarated ions
takes place. In ouch a case it remains to ba clarified
whether the influence of the change of the dieloctric
constant of the solution may be neglected. The author is of
the opinion that all his results allow anything else
rather than neglecting the last-mentioned chango of the
constant. There are 7 Soviet references.
ASSOCIATION: Lisichanskiy filial gosudarstvennogo nauchhb-issledovatell-
skogo i proyektnogo institute, azotnoy promyshlennosti i
produktov organicheskogo Binteza (Lisichansk Bremch of the
State Scientific " Research- and Mxnhing Institute for the
Card 2/3 Nitrogen-industry and for Products of urganic Synthesis)

5M
AUTHORS: Turlyan, Chebotarl, N. G. 3011/78-4-3-19/34
TITLE: Polarographical Investigation of the Lead Chlorine Complexes
in Aqueous, Methanol- and Ethanol-aqueous Solutions (Polyaro-
graficheskoye issledovaniye khloristykh konpleksov svintsa v
vodnom, vodnometanollnykh i vodnoetanollnykh rastvorakh)
PERIODICALt Zhurnal noorganichookoy khimii, 1959, Vol 4, Nr 3,
PP 599-605 (USSR)
ABSTRACT: Composition and stability of the lead chlorine complex in
aqueous, methanol- and ethanol-aqueous solution were
investigated by,the polarographical method at various
concentrations of the organic solvents and at an ionic
strength = 2. With increased concentration of the solvent
apart from the complexes [PbC]]', [PbCl ],[PbCll - also
2 ~b
d
n
2-
off/30 -3' C
the complex [PbC1
H
1 forms (at 30 and 60 ~fo CH
off),
2
4
3
5
The composition of the complexes in 80 ~~ CH
OH and 6o and 80 It
3
C 2H5OH corresponds to that in aqueous solution. In 100 -fa
Card 1/3 CH 30H exist only the complexes [PbCll+ and 1PbC1 2i,

Polarographical Investigation of the Lead Chlorine SOV/78-4-3-19/34
Complexes in Aqueous, Methanol- and Ethanol-aqueous Solutions
In the formation of the complexes two factors nct at the same
time: by reduction of the dielectricity constants in the
solution an increase in the affinity between central atom
and addenda occurs; thus the simple complexes are stabilized.
On the other hand, the impact strength among the addenda in
the complex increases, which results in the destruction of
the stabilized simple complexes. Thus, it is explained that
in 100 ~4 CH3OH no negatively charged lead COMDlex 1PbC1 412-
exists in spite of a sufficient concentration of addenda.
Tables 4 and 5 give the stoichiometric stability constant
and the composition of the lead chlorine complexes in aqueous,
methanol- and ethanol-aqueous solutions. With increasing
concentration of the organic solvent the constants are
reduced. The dominatin- influence of the variation of the
dielectricity constants of the solvent upon the stability
constant of the complex is shown. A linear dependence exists
between the logarithms of the stoichiometric stability
Card 2/3 constants (K,, K2' K3 ) and the reciprocal values of the

Polarographical Investigation of the Lead Chlorine SOV/78-4-3-19/34
Complexes in Aqueous, 1'4ethanol- ani Eltv-hanol-aqueoua Solut-i!-ris
dielectricity constants of the mixed solvent. The stoichio-
metric stability constant of IPbNO31_ was determined in
aqueous, methanol- and ethanol-aqueous solution. There are
2 figures, 6 tables, and 14 references, 5 of which are Soviet.
ASSOCIATION: Kishinevskly gosudarstvennyy universitet (Kishinev State
University)
SUBMITTED: December 26, 1957
Card 3/3

5(2) SOV/178-4-4-16/44
AUTHORS: gurlyan., Ya- Sh-.ipel Iman, R. Ya.
TITLE: Polarcgraphic Investigatim of the Lpad Thiocyanat;j Complexes
j
.Ln Aqueous, Aqueous Methanolic, and Aqueous Ethanolic 'Solution
(Pol-yarograficheskoye issledovaniye rodanistykh kompieksc--.-
- 1, 41
s 14-'sa q vodnom, vadnometanclInykh i vodnoetar.;ziln,~kh rastvorakh)
PERIODICAL: Zhurnal neorganicheskoy khimii, 1959, Vol 4, Nr 4, pp 808-812
(USSR)
ABSTRACT: Th' polarogra~hic method was used to investigate the compositior
and stability of the lead thiocyanate complexes in aqueous,
aqueous methanolic, and aqueous ethanolic solutions with a
constant ionic strength of 2 and at 250. The results are given
in tables I and 2. The reversibility of the electrode pro(~ess
and the'diffusion character of the limit current cermit a
determination of the composition and the stability constants of
the lead thiocyanate complexes to ,be made. The compositions of
the complexes and the stoichiometric stability constants in
aqueous methanolic and aqueous athanolic solutions of varying
composition are summarized in;tables 4 and 5- It is apparent
Card '/3 that the amount of the thiocyanate complex passes through c-

SOV/78-4-4-16/44
Pol.arographic Investigation of the Lead Thiocyanate Complexes in Aqueous,
Apeous Methanolic, and Aqueous Ethanolic Solut-ior,
maximum ir relation to the methanal concentration. In 1100~cjl'OH
the maximum :coordination number is lower than in aqueous solu-
tion. In aqueous ethanolic solutions the formation of the thio-
cyanate complex increases with an increase in the ethanol con-
centration to 30 and 60'70" C2H5OH. The stability constants of
the complexes decrease with an increa8e in the rion-aqueous
solvent. For corresponding complexes in aqueous-ethanolic and
aqueLua me-.hancilio aolution have 'the straight !~.ne PK
(S.-dielectric constant) in common. This fact shows the dominat-
ing effect ofC upon the stabilit constant K. The stoichiumetric
stability constants of FPb(NO were determined in aqueous
methanolie and aqueous ethanolio solutions at an ion strength
of 2 (Table 6). The constant likewise decreases with an increase,
in the concentration of the non-aqueous solvent, but in lesser
amount than the constant KI of the complex [Pb(CNS)]'. Tab-.Ie
gives the relationship between the limit current uf the plead
ions and the height of the mercury reservoir in aqueous methan -
Card 2/3 olic and aqueous ethanolic solutions. There are 2 figures,

SOV/78-4-4-'6/44
Polarographic Investigation of the Lead Thiocyanate Complexes in A'Juec*-'s,
Aqueous Methanolic, and Aqueous Ethanolic Solution
6 tables, and 2 Soviet references.
ASSOCIATION: Kishinevskiy gosudarstvennyy universitet (Kishinev State
University)
SUBMITTED: December 26, 1957
Card 3/3

5(4) SOV/78-4-4-17/44
Ar-THOR: Turlyan; Yae I.
TITLE: The Dependenc. 0i'the Instabil-1-cy
Upon the Diele,.;tric Conottali. u.L
konsta-nt nestoykosti komplekarLylch
postoyannoy rastvoritelya)
PERIODICAL: Zhurn's.4 neorganichesko~`khimii,
(USSR).L
;onstants of Ccm;~--~x '1-.ns
the Solvent
i.onov ot dielektricheskoy
1959, Vol 4, Nr 4, PP 813--617
ABSTRACT: The electrostatic theory of-solvation was used to explain the
dependence-of the.',logarithm of the thermodynami-c and stoichic-
metric'stability o6natants at higher ion.strengths upon the
recLprocal-Gf the-value of.the,dielectric constant of
ooinp*ound solvents. The"similarity in the sizes of the effe-.ti7re
ionic ra-di-i rCd~' ZPb , r.1. rBrl r., r..., rCdCil rPbC- ' "PbB-r'
and rPb(CNS) was ncted. The linear relationship between pK and
Z- is explaiLned on one side by the electrostatic theory and
the other side by the linear relationship between log f and
(f -. activity coefficient). There are 12 references, 1.0 f
Card 112 which are Soviet.

SOV/78-4 -4 -.7/4".
The Dependenc of the lnstabilit;yr,onF3tarts of Complex Ions Upor, the
Constant of thu oc-vujo,
ASSOCIATION: Kishinevskiy_ :;osudarstvennyy universitet (Kishinev State
University)
SUBMITTED: January 11, 1958
Card 2/2

15W SOV/78-4-5-21/416
AUTHORS: T_ I n Ya. 1-p Bondarenkov N. I.
TITLE: The Polarographical Investigation of the Thiocyanate Complex
of Cadmium in Aqueous and Aqueous-methanolic Solutions (Polyaro-
graficheskoye isoledovaniye rodanistykh kompleksov kadmiya
v vodnom i vodno-retanol'nykh raatvorakh)
PERIODICAL: Zhurnal neorganicheskoy khimii, 1959, Vol 4, Nr 59
PP 1070-1076 (USSR)
ABSTRACT: The composition and the atoichiometric stability constants
of the thiocyanate complexes of cadmium in aqueous and aqueous-
methanolic solutions were investigated by the polaroeraphic
method at various CH OH-concentrations and an ionic strength 2.
3 10
The polarogrAphical character of cadmium in aqueous and aqueous-
methanolic solutions with 2 molar NU 4 NO3+NH4CTIS is shown in
table 1. In an aqueous solution the followi4g four cadmium-
thiocyanate complexes were fowid, [Cd(CNS)] .,[Cd(CNS )21"
[Cd(CNS)3]- and [~d (CNS)4]2- . The stability constants of these
complexes agree well with the data of reference 8. Table 2
Card 113 shows the angle coefficient of the straight lina lon" ii-i
d

SOV'B -4-5-21/46
The Polarographical Investigation of the Thiocyanato Complex of Cadmium in
Aqueous and Aqueous...nethanolic Solutions
in an aqueous and aqueouz--methanolic solution in 2-molar ITH 4NO3+
+ NH4 CNS. The dependence of the diffusion cuTrent of cadmium
upon the level of the mer,~-ury reservoir in 2--moler NH MIS was
investigated, and the results are given by table 2. Tile de-
pendence of the potential of the cadmium.-semiwave on the lo-
garithm of the concentration of addenda in an aqueous and
aqueous --methanolic solution is shown by fiUvre 1. It was shown
that with an increase of the m9thanol concentration the stability
of the complex ions increases. The dependence pK - "1 of the
complex Cd(CNS), Cd(CITS) 2 and Cd(CTIS) 3 ia indicai;edrby a line,
the inclination of whi~~h increases with an increase of the co-
ordination number. The dependence of the logarithm of the
stoichiometric siability constantd in the cadmium-thiocyanate
complexea C14(cNS), Cd(cirs) 2 and Cd(CIIS)3 upon tho reciprocal
value of the dielectric constant of the aquaouQ-tnethanolic
solut-ion is given by figura 2. The composition and the stability
constants of the thiocyanate e.,omplexag of cadmitmi in an
Card 2/3 aqueous and aqueous --met har.,,;!:Lc ai-)lution wWi an Ionic strength

SOV/78-4-5-21/46
The Polarographical Investigation of the Thiocyanate Complex of Cadmium in
Aqueous and Aqueous-methanolic Solutions
2 are shown by table 2. The composition of the cadmium-thio-
cyanate complexes in an aqueous solution is given by table 5-
There are 2 figurest 5 tables, and 17 references, 10 of
which are Soviet.
ASSOCIATION: Kiehinevskiy gosudarstvennyy universitet
(Kishinev State University).
Kishinevskiy sellskokhozyaystvennyy institut
(Kishinev Agricultural Institute)
SUBMITTED: February 15, 1958
Card 313

5(2) BOV/78-4-8-23/43
AUTHORS: Migall, P. K., Grinberg, N. Kh., Turlyan, Ya. 1*
TITLE: The Polarographic Investigation of the Composition and the
Stability of the Cadmium Thiosulphate Complexes in Aqueous
Solution (Polyarograficheskoye issledovanlye sostava i ustoy-
chivosti tiosullfatnykh kompleksov kadmiya v vodnom rastvore)
PERIODICAL: Zhurnal neorganicheakoy khimii, 1959, Vol 4, Nr 3, PP 1844-1848
(IJSSR)
ABSTRACT: The solutions Cd(NO 3)2 + WaClO4 + Na2S203 are investigated at
different ionic concentrations which were kept constant in
the individual experiments. In order to suppress the maximum
0.01% gelatin was added to the polarographically investigated
solutions. Oxygen was removed by the passage of hydrogen. A
calomel standard electrode served as comparison cathode. The
polarographic measuring results are shown by table 1. The
dependence of the potential of the semiwave on the logarithm
of the concentration of the thiosulphate ion is shown by
figure 1. A Btep-wise complex formation was observed which the
other research workers (Refs 2 '4) had neglected. With 2i ow ionic
Card 1/2 strength only the complexes [Cd(S203)] and [Cd (S203)2I are

SOY/78-4-8-23/43
The Polarographic Investigation of the Composition and the Stabtlity of the
Cadmium Thiosulphate Complexes in Aqueous Solution
formed. In the case of high ionic strength the complex
[Cd(S203)31 4- is observed. The stoichiometric inatability con-
stant was computed according to various methods (Refs 6,7)
and showed good agreement. The instability constant of Cd(S20 3)
increases with increasing ionic strength. The constants for
[Cd(S203f and ~d( S203 )314- pass a maximum atk- 1. The
thermodynamical instability constant (Table 3) is In agreement
with the values found according to the solubility method
(Ref 3). There are 2 figures, 3 tables, and 10 references,
5 of which are Soviet.
ASSOCIATION: Kishinevskiy gosudarstvennyy universitat (Kishineir State
University)
SUBMITTED: April 30, 1958
Card 2/2

5(4) SOV76-33-4-30/32
AUT-HOR: Turlyant Ya. I.
TITLE: Oxygen Overvoltage on the Nickel Anode (Xislorodnoye perena-
pryazheniye na nikelevom anode)
PERIODICAL: Zhurnal fizicheskoy khimii, 1959, Vol 33, Nr 4, PP 948-952(VSSR)
ABSTRACT: The theory of oxygen overvoltage cannot be further developed
without first submitting to criticism the various investiga-
tion results on the nickel anode, since some papers contain
most dubious assumptions. In his previous papers (Refs 1-4)
the author had obtaPed an exact polarization curve (Figure
of the curve for 25 ) that can be divided into four segments.
Two of the segments are straight lines and may be represented
by equations (1) and (2). Proceeding from these data the Liechan-
ism of the oxygen overioltage was explained (Refs 1-4), which
in the present case is likewise carried out on the basia of
the above mentioned curve. Next, the investigatiori results
(Refs 7-10) concerning the curve section I are explained and
it is further stated that the retardation process (7) men-
tioned in references 7-10 is inacourate and the. limiting stage
(3) or (4) suggested in references 1-4 is right, which is
also confirmed by the calculation rebulta in :reference 12.
Card 1/2 The authors (Ref 13) committed an error in the consideration

Oxygjn Overvoltage on the Nickel Anode SOV/76-33-4-30/32
of the kinetics of oxygen separation on an unoompletely charged
nickel oxide electrode in the derivation of the equation for
the limiting stage (Refs 11-13). The authors (Rof 5) arrive
at a wrong kinetic equation (15) instead of the right one (16)
while reference 14 derived a kinetic equation (18) which does
not agree with the experiment. The fact is pointed out that
a number of authors do not consider the dependence of the
process on time when studying the oxygen overvoltage on
nickel anodes, so that wrong values are given (table of the
values from reference 20) as compared to those from referen-
ces 21 and 1, 2. There are 1 figurep 1 table, and 22 referen-
ces, 14 of which are Soviet.
ASSOCIATION: Kishinevskiy gosudarstvennyy universitet
(Kishinev State University)
SUBMITTED: June 28, 1957
Card 2/2

5
A UTH 0 "a. I., '-ir-rova, 9. F. 2::1--z-1,'."
TITLE: Polarographic Kinetic Currents Caused by the Rct,:tr,~e-4.
Formation of Rhodanic Complexes of Niclrel
kinatichoskiye tokif obusiovlonnyye -,z,.-.~ I onn,~--
rodanist.vkh kompleksov nikelya
PERIODICAL: Doklady Akadernii nauk 3 '32, 1 (~139, Vol 12'j, :!r
Pi) 595~-59B (USSR)
6-ASTHAC11': In order to find out the nature of 'the three -f.E.vIes of the
rhodanic complexes of nickel (which was investigated in previGus
research - - Ref 1) the anthors inve3tig-tel,' the
IoDendence of the height of 'he waves v.t C,.2+ = const
(0.110 mol/1) on the conccntration of KC:-,r" (It= 1:KCNIS + KNO.,,)
-nd also on the concentrntion of nickel -it C,_,,- = const
(12.6 mmol/1). Thr capillary tube hns thq ciaracteristic
2/3,1/6 2/3 -1/2
8 1 mg sec (t - 2, n and J
u
Card 1/A ftenote the kinetic currents, and i 11 the -,!iffusion current.

PoliLrographic Kinetic Currents Cauoed by thrl- 25_7
Retarded Formation of Rhodanic Complexes of -ickel
The following fact results from a prcvious D*.!?c- (Ref 2 in
U hoJanic
,rhich the constants of the instabilily of r
complexes of nickel were determined, In the r:inqe of
concentration of UNS under invcstiarttion, only the ions Ni 2+
,-n~ [7iC!ISJ' take part, in essential, in the ',AffuGion to "he
electrode. The 2uthors asaume the follo-ving scY-?Tc3 of the
elect-rode rjrocoszt~s which determine tl-ie !naxiiu-i current.
first vava:1,12+
Vj 2+
+ Clis - k
'~;~Eaclist +c-.,S
EN i C I:: Sj diff
first + socond wave: C
Mi 2 + d iff
+Cus-
.1 C'T 3r,)duction
I T
rnclisl + k
Card 2/4 1~ 0

Polnrographic Kinetic Currents Cr~used b-, the Rata--:--2A-
Formation of Rnod,,mic Coz,-irlrxcn of 77ickal
first + second + third wave:
2+ di ff 2+ red u c t-3
Ni k I? ~~ i >
3
ff reduction
[:f i C i,.sj + Eu i c" I Sj +
The total height i of che rfave must be determin(-,~ by the
diffUsion velocit,,x which was observed also experimentally. 7hn
eqi:zations which describe the dependc!nce of the kinetic
currents i and F-ii, on Cc-.--- -,tre found according, to t~ie
k J 3
approximate thec(ry of R. Brdi6ka and Y. (-Iof V,.
constant of the rate of adJition of C"IS- to c i3'
considerably higher than the constant of the t':Ac of
t 2+. - -
of the ion to he ion Ni A formula is thm.
0. --;,:~n- o-
as a function of C:.I Accor6in- to the coi!,-t~-1
present paper, the kinetic ctirrent -!.!I(, U ;.ct-
Card. 3 /14

Polpro-ranhic Kinetic Darrents Causei by the
,rForrpr,',3.on of '.?hod,,3.nic Complexes of 'lickel
M
which wa3 observed also experl~ ontall:,. 7hc
!:lso the more exact equations of V
varions diffusion coefficients. Thin or
"hin caze arree with the experimentVil rocj!tF:, i.e.
th~. more (,xrct. thpory confirmoll. th~,
-f~,nar;.,.tion of the second kinetic
1 tr~bla, and 10 referoncco, 9 of whic"
A.-j'50 C I A"i I 1~1.,;hinovslkly gosuearstvonnyy unive-raill'ot
Univcr:-,ity)
PR Decenbor 101, 195a, by A. A. Grinbcr~7, Acadc;Acian
S U 13 1 D(,ce:.ibcr ', 195.3

S/064/60/qoo/01/13/024
B022/BO08
AUTHORS: Aurlyang Ya. 1.9 Candidate of Technical Sciences,
-ff-
Anikina, . S.
TITILE: A Method for the Automatic Control of the Absorption Process
of Nitrogen Oxides by Means of Basic Solutions &t the Pro-
duction of Weak Nitric Acid
PERIODICAL: Khimicheskaya promyshlennostig 19609 go. 1, PP. 59 - 61
TEXT: The absorption process of nitrogen oxides with a soda solution re-
quires continuous control of the soda concentrationj a soda concentration
of approximately 10 g/1 must be maintained especially towards the end of
the process. The control of the soda concentration by means of titration
is extremely difficult and excludes a continuous control. An automatic
control method which is based on the continuous measuring of the pH with
an antimony electrode was worked out for this reason. A saturated calomel
electrode was used as reference electrode. The emf of the electrode cell
was measured with an electronic potentiometer of the type M-32. The
potentiometric titration curve of a 0.1 ff Sa 2CO3solution with Ocl N
Card 1/3

A Method for the-Automatic Control of the 8/064/60/000/01/13/024
Absorption Process of Nitrogen Oxides by B022/BO08
Means of Basic Solutions at the Production of Weak Nitric Acid
sulfurio aoidp using an antimony electrode (Fig. 1), ahows that the elec-
trode mentioned reacts very sensitively to pH variations an& aakes a
separate determination of Na 2 CO3 and NaHCO3 possible. The dependence of
the potential of the antimony electrode on the concentration ratio
NaNO2 : NaNO, (Table 1) and Na 2CO3 : NaHCO3(Table 2) is given. An in-
dustrial model of a pickup electrode, the scheme of which is given
(Fig. 2), was designed for the automatic control under production condi-
tions. The pickup is placed between the circulation pump and the con-
tainers for the soda solution (Fig. 3). The variation of the yotential of
the antimony eleotrod4 at the industrial absorption of nitrogen oxides
with a soda solution is graphically represented (Fig, 4). The calibration
curve of the antimony electrode by means of a hydrogen electrode (Fig. 5)
showed the linear dependence of the pH on the potential, and the stability
of this characteristic before and after the industrial test of' the anti-
mony electrode. A. V. Pushkova took part in designing the pickup electrode.
There are 5 figures and 2 tables.
Card 2/3

A Method for the Automatic Control of the B/064/60/000/01/13/024
Absorption Process of Nitrogen Oxides by BO22/BOO8
Means of Basic Solutions at the Production of Weak Nitric Acid
ASSOCIATION: Lisichanakiy filial Instituta avtomatiki Gosplana USSR
(Lisichanak Branch of the Institute of Automation of
the Goeglan UkrSSR) -
Card 3/3

TURITAN, Ta.I., kand.tekhn.nauk; SNEKAWVA. T.T.; KHARLANOTA, T.M.
Developing the automatic control of the liquor vapor content In the
production of am nium nitrate. Xhim.prom. no.d,.679-681 D 1606
(MMA 13:12)
1. Lisiebanakiy filial Instituta avtomatiki Gosplana, UMR*
(Ammonium nitrate)

TURI ~;_ZHMAJAY, B.P.
Polarographic study of chloride complexes of cadmium In aqueous,
water-methanol, methanol, and water-ethanol solutions. Zhur.
neorg. khIm. 5 n0-831748-1755 Ag 160# (MMA 13: 9)
1. Lisichaukly filial goBudarstvennogo nauchno-iseledovateliskogo
I proyektnogo instituta azotuo7 prozWehlennOBti I produktoy orga-
nicheekogo sinteza. lishinevskiy gosudaretvenW universitet.
(Cadmium compounds)

TURtYAII, Ya.I,; MILYAVSKIT, Tu.S.
Polarographic stud7 of iodide complexes of cadmium in aqueous, water -
methanol, and water - ethanol solutions. Zhur. neorg. Idlim. 5 no.10:
2242-2250 0 160. (HIRA 13-10)
1. Ashinevski7 gosudaretvennyy universitet Lisichanski3r filial gosudar-
stvennogo instituta azotnoy promyshlennosti i produktov organicheakogo
sinteza.
(Cadmium compounds)

TURIYAH, Ya.I.
Reply to V.P. Vasillev's comments on the paper "Instability
constants of complex ions as a function of the dielectric
constant of the solvent." Zhur. neorg. kh1m. 5 no. 12:2852-
2853 D 160. (MlaA 13:12)
1. Lisichanakiy filial goeudaratvannogo natichno-issledovatell-
skogo i proyektnogo instituta azotnoy promyehlennosti i pro-
duktov organiehaskoeo siateza.
(Vasillev; V.P.) .' (complex ions)

reduced at the ele~r,:Gde in tbte fn-"-'c
Zhur. flz. khim. R. no.9g2109-27105
j.. Ynroslavskiy nl3tli mor. o r. iwrc, v

TURIYAH. U.I. TTURIN, Yu.K., ZA7TSBV. p.M., KA3AVAYBVA, Ye.A.
Palarographic anal7siN of nitrOc7clobexane. Zav.lab. 26 no.?:
810-813 160. (MIRA 13:7)
1. Listchanskiy filial Gosudaretvannogo nauchno-iseledovatell-
11 kogo i pro7ektruogo instituta azotnoy promyshlonnosti i
produktoT organicheskogo sinteza.
(Cyclohexane) (Polarography)

B/076/60/034/05/11/036
BO1O/BOO2
AUTHORS: Turlyan, Ya. I., Serova, G. F.
TITLE: Polarographic Investigation of t~e Kinetics of the Formation
of Thiocyanate Complex Compounds'of Hickel in Aqueous
Solution T
PERIODICAL: Zhurnal fizicheekoy khimiij 19609 Vol* 34P No- 59
PP- 1009-1017
TEXT. The authors investigated the dependence of the three steps of the
polarogram of nickel - thiooyanate complex compounds (of. Ref. 1) on the
concentration of thiocyanate (at 00 2+ - 0onst - 0-140 millimole/l.)
Ni
(Table 1) and nickel (at 0 const - 12.6 millimole/1) (Table 2). The
C1qS
results obtained are analyzed on the basis of the theory of kinetic polaro-
graphic currents. The experiments were performed at 25 0C and with four
different heights of the mercury reservoir. Table 3 represents the depend--
ence of the limiting current on the height of the mercury reservoir. On
the basis of data published by S. Fronaeus (Ref. 3) on the instability
Card 1/3

Polarographic Investigation of the Kinetics 5/076/60/034/05/11/038
of the Formation of Thiocyanate Complex B010/BO02
Compounds bf Nickel in Aqueous Solution
constants of N12+ , [NiCNS]" [Ni(CNS) 21 , and [Ni(CNS) 31- the authors
calculated the content of each ion in the various solutions as dependent
on the concentration of thiooyanate (Table 4). Three schemes of the elec-
trodic , processes show that the first step of the polarogram is related
to the retarded formation of ffi(CNS)2 (first scheme)9 whereas the second,
larger step is related to the retarded formation of [NiCNSj'+ (aecond schemc,)9
and the third (a diffusion step) is related to the electrical. reduction
of Ni 2+ and [IqiCNSI+. With the help of the Brdi6ka-Wiesner appzoximation
theory the authoracalculated the rate constants k I and kY k I was also
calculated according to the more exact theory by Koutecky+* It was taken
into account that besides the N12+ ions also the [NiCNS] iorts participat-
ed in diffusion, and that the diffusion cooffici(nts of these ions differ
considerably. It is shown that the reaction rate constant of F .iCNSj+ , CNS"
LN
is considerably higher than that of N12+ + CNS'-. The 1~iCNSJ"- ion is
reduced at the potentials of the second polarogram step, which are more
Card 2/3

Polarographic Investigation of the Kinetiog S/076/60/034/05/111/038
of the Formation of Thiocyanate Complex B010/BO02
Compounds of Nickel in Aqueous Solution
positive than the potentials of the reduction of simple nickel. ionag
whereas at still more positive potentials o'f the first step a larger
complex ion is reduced. In accordance with A. N. Frumkin and 0. M. Flo--
rianovich (Ref 16) it is probably a complex of the anionic tyre.
Budevskiy is also mentioned in the present paper. There are 5 figures,
5 tables, and 16 references: 5 Soviet, 6 Czech, I German, and I Swedish.
ASSOCIATION: Kishinevskiy gosudarstvennyy univeraitet
(Kishinev State University)
SUBMITTED: June 28, 1958
Card 3/3

0 0 S/076 6P~~J/06/12/040
L37 B01 5YBo6i
. ~400
AUTHORSx Turlyan Ya. I. Milyavskiy, Yu. S., Zhantalay, B. P.
jili ~ro o~nes
TITLE: Polarographic Determination of the Activity Coefficients
of the Cadmium Ion
PERIODICALs Zhurnal fizicheskoy khimii, 1960, Vol. 34, No. 6,
pp. 1234-1237
TEXT: Polarographic determinations of the activity coefficient f Cd 2+
of the cadmium ion, with the use of the following galvanic chains were
ca ied o ts
,gTr u
H92C12 0-1 M NaCl 0 WaClO4
n+
I M NaClO4 c Me Indicator electrode (I/
x y
Card 1/3

Polarographic Determination of the Activit,-, SIO, 3 4 /0 6 /12 /0
7
ficients of the Cadmium Ion BOIRBO!Vio
and Egi H92C'2 0.1 M LiCl eX UNO 3
1 M UNO c Me n+ Indicator electrode
3 y
2+ x y
Whilst only simple Cd ions are present in the NaCIO 4 solutions, a
complex formation j.Cd(NO 3W is possible in the UNO 3 solution. The
calculations of the value f Od 2+ at different ion strengthsA were carried
out with the use of the Heyrovskiy-Ilkovid equation (for the NaClO 4
solutions), and the De Ford - Hume equation (Ref. 4) (for tho LiNO 3
solutions) (Table). The potential of the cadmium half-stage (corrected
with reference to the change in the diffusion current) changes linearly
with f,&_c to "- 0-05-0-1, which is ascribed to the change of f Cd 2+
according to the Debye law. The dependence curves of the val-ae f Cd 2+
on 1.b passes through a minimum atA - 0.3-0.6 to approach unity at
/-t ' 3, and with a greater rise of/k to reach a value well above 1.
Card 2/3

Polarographic Determination of the Activity
Coefficients of the Cadmium Ion
8j50
S10761601034,1061121040
B015/ '0061
The values for f Cd 2+ in LiNOV calculated without and with respect to
the complex formation, practically agree at C No- - 0.1 P1 to 1 M
3
a correction with respect to the complex formation leads to the same
values for f Cd 2+ as in NaC104 solutions. There are 2 figures, 1 table
and 10 referencess 1 Soviet, 5 American, I Italian, I German, I Frenc
and 1 British.
ASSOCIATION; Kishinevskiy gosudarstvennyy universitet (Kishinev State
University)
SUBMITTED- July 21, 1958
Card 3/3

GIRSHKOVICH, I.A.; TER'TAN, YA.I. (Severodonetak)
Oxygen overvoltage on the cobalt anode. Zhur. fiz. khim. 34 no.12:
2654-2660 D 160. (MIRA 14:1)
1. Lisichanakiy filial Instituta "otnoy Ibromyshlennosti i produktov
organicheakogo sinteza i Kishinevskiy gosudarotvenny7 universitet.
(Overvoitage) (Oxygen) (Cobalt)

81415
3/020/60/132/06/40/068
B004/BO05
AUTHORx Turlyans, Ya. I.
TITLEs The Mechanism of the Variation With Time of Oxygen Over-
voltagelon the Nickel Anode at Constant Current Density
PERIODICALs Doklady Akademii nauk SSSR9 19609 Vol. 132, No. 6,
PP. 1368 - 1371
TEXT: In previous papers (Refs. 1, 2) the author had assumed that the
increase in oxygen overvoltage qj on the nickel anode occurring after
expiration of time t is caused by the fact that the concentration of
NY 4 on the anode inoreaseag and IN, 204> 1N120 30 The present paper deals
with the quantitative checking of this assumption. On the basis of the
reactions N1203 + 20H ) N1204 + E20 (2) and N12O 4 )N120 3 + 0 Wo
equation (4) is written down for dS/dt (dS is the portion of -the anode
surface occupied by N12O 4); this equation contains the constants Ki and
K2 (K1 = Kl'[OHj2, K1, - rate constant of reaction (2)9 K2 - rate constant
Card 113

81415
The Mechanism of the Variation With Time of 8/020/60/132/06/40/068
Oxygen Overvoltage on the Nickel Anode at B004/BOO5
Constant Current Density
of reaction (3)). Hence, equation (6) is derived for 1 Fig. 1 shows that
this equation well reproduces the experimental data. Rble I liste the
values of the constants in dependence on current intensity and temperatura.
Equation (8) is written down for jt.O. This equation also corresponds to
the experimental values (Fig. 2). Furthet, equation (12) is given for the
oxygen overvoltage 'qstab which is stabilized after expiration of time t;
this equation corresponds to the complete covering of the anode with
N120 49 and also agrees with the experimental data (Fig. 2). The value for
K, decreasing with rising temperature is explained by decreasing concen-
tration of the OH radicals on the anode surface due to a quicker progress
of reaction (2), i.e. an increasing value for K;o There are 2 figures#
I tableg and 12 referencesi 9 Soviet, 1 British, 1 German, and
I Japanese.
Card 2/3

The Mechanism of the Variation With Time of 6/020/60/132/06/40/068
Oxygen Overvoltage on the Nickel Anode at B004/BOO5
Constant Current Donsity
ASSOCIATIONs Lialohanskiy filial Gosudarstvennogo inatituta azotnoy V~-
promyshlennooti i produktov organioheskogo sinteza
(Lisichansk Branch of the State Institute of the Nitrogen
Industry and Producte of Oraanic Synthesis)
PRESENTEDs January 28, 1960p by A. N. Frumkin, Academician
SUBMITTEDs January 28, 1960
Card 3/3

S/02O/6o/134/oo4/o16/023
Bo*/Bo6o
AUTHORS1 Turlyan, Ya. I., Tyurin, Yu. M., and Zaytsev,-F. M,
TITLE- Polarographic Study of Nitro-aci Tautomerism of Ni-.ro-
cyclohexane 1
PERIODICAL; Doklady Akademii nauk SSSR, 1960, Vol. 134, No. 4,
pp. 850 - 852
TEXT: The polarographic method devised by the authors (Ref. 1) for analyz-
ing nitro-cyclohexane (NCH) has made it possible to study the kinetics and
the equilibrium of the nitro-aci-tautomeric transformation of NCR. The
nitro-form of NCH constitutes a distinct wave in a wide pH range; the aci-
.-form cannot be reduced on a mercury-dropping electrode. The authors dis-
solved NCH (ev 0.01 M) in water or alkali, depending on the direction in
which the reaction was considered. Citric 4Lcid phosphate- as well as bo
alkali buffer mixtures served as background. The concentration of the
nitro-form of NCH was recorded on the electron polarograph n)-31A PE-312).
The nitro-aci-(N--.-*A) transformation was studied in the ranj*4-b-e1`WFen pH 8
and 12, while the reverse reaction was studied at pH 3-9.5. The experiment
Card 113

Polarographic Study of Nitro-aci Tautomerism S/020/60/134/004/016/023
of Nitro-cyclohexane B016/BO60
was performed at 25, 32, 4o, and 500C- Fig. 1 illustrates the dependence of
the ratio C,,,,/C0on the PH value at 250C. where C 0 is the initial concentra.-
tion of NCH in the nitro- or aci-form and C, the concentration of the NCH
nitro-form after the reaction is over. As may be seen, the nitro-form is
completely transformed into the aci-form at PH> 9.5. At PH 4.5 - 7-0, a
complete transformation of the aci-form into the nitro.-form is possible.
The equil:Uorium appearing at PH 7.0 - 9.5 can be attained from both sides.
Table 1 gives the values of K N (experimental rate constant of reaction
N--:~A at PH = const) and of KA (the same for reaction A--~N), The function
log YN = f(PH) is linear (Fig- 3), while log K A = f(pH) at PH=5 passes
through a maximum (Fig. 4). A reaction scheme (3) is given for the acid-
.-alkaline catalysis of the nitro-aci-tautomeric transformation (Ref. 6).
This reaction mechanism permits the derivation of kinetic equationa which
fit those obtained in the experimental way (1) and (2) at the following
values of1constants (25'C)-, Ko 50 (mole/!)'- 1~ min' 1. KI ~ 2.8 - 10
1 "7 o - 4
(mole/l)-' min" 0 KII z 0.11 min"' , K, :7 4,3 - 10 ,and K 2 ~ 2-3 ' 10
Card 2/3

Polarographic Study of Nitro-aci Tautomerism S/020/60/134/004/016/023
of Nitro-cyclohexane B016/BO60
ExperimentaAl data are compared with calculated ones in Fig,, 4. The protoni-
zed compleO 1C6H1O :NOH]H appears in the limiting stage of the Nef
reaction (at pH< 4.5). Since at pH,>9.? the isomerization reaction of NCH
is catalyzed by hydroxyl ions, and at pH '/7 this is done by hydrogen ions,
the equilibrium constant cannot be calculated from the ratio K /K.
0 0
Instead, this constant was calculated by means of an equation shown here.
Table 2 shows good agreement for K equation when establishing the equilibri -
um from both sides. Activation energies are finally calculated. There are
4 figures, 2 tables, and 7 references: 4 Soviet, 2 US, and 1 French.
ASSOCIATION: Lisichanskiy filial Gosudarstvennogo instituta azotnoy
promyshlennosti i produktov organicheskogo sinteza
(Lisichansk Branch of the State Institute of the Nitrogen
Industry and of Products of Organic Synthesis)
PRESENTED: may 16, 196o, by A. N. Frumkin, Academician
SU'IITTED- March 12, 1960
Card 3/3

TURIYANV Y-4J,,;- ROMANOV, V.F.
graphic method for determining potasdium in the catal7st of
obutyl alcohol synthesis. Khim.Prom. no.lt68 J& 161.
t re 1 09 (KMA 14 s 1)
chwiskiy filial Gosudarotvonnogo nauchno-looledovatellskogo
i pro7ektnogo*instituta azotnoy promyohlennosti i produkotv organiche-
Okogo ainteza.
(Isobutyl 41cobol) (Potassium-Analysis)
(catalysts)

TDRIYAN, Ya.I,_--
Composition and instability con3tants oif lead iodide complm.:es in
aqueous 3olutiona ac pravided b..,r nolubility data. ZYMr. reorg.
6 no.1:162-168 161. (1-1.1-A 11,-W
1. Lizichanskiy filial Gozudarstvem-.o;,-o iia,-.chno-is.1clovittellsko"o
i proyek'vno-o instituta azotnoy promysilennosti i pro~t~v~ov or,m~,,,'Ir-
0 .. -
oko,,,,o ainteza. (Lead compounds)

TURMN, Ya. I.; TYURINP Yu.M.; ZRANTAIAY, B.P.
Polarographio determination of caprolactam and amino acids,
the intermediate products of synthetic fibers. Zhur.anal.
khim. 16 no.3:352-358 My-Je 161. . (Y-MA 14:6)
1. State Scientific Research and Designing Institute of Hitrogen
Industry, Lisichansk Branch.
(Azepinone)
AmJr,o acids)
Polarography)
~

TURIYAN., Yaj; MURENKOV, A.M.
Use of polarography for the continuous automatic control of
laboratory and industrial processes (survey). Zav.lab. 27
no.5:507-517 161. (MDU A: 5)
(Polarography)

TURIYAN, Ya. I.; ZHANTALAY, B.P.
POlarographic determination of caprolactem in procegs solvtions.
Zav.lab. 27 no.10:1221-1214 161, (MIPA 14:10)
lo Lisichanskiy filial Instituta azotnoy promyshlennosti.
(Azopinone)
(Polarography)

TUR I Y&N I la. I. ; ZAYTSEV , P. M.
Polarographic determination of 'nitrocyclohexane in the production
of caprolactam. Zav..Iab. 27 no.11:1329-1331 161. (WRA 14:10)
1. LisiclAwkiy filial gosuderstvennogo instituta azotnoy pronrjohlennosti.
(Cyclohw=e) (Polarography)

20365
S/020 61/136/005/029/032
B YBIO
C;26,
AUTHORSs Turlyan, Ya. I* and Tsinman, A. I.
TITLEs The effect of concentration and type of alkali on the oxygen
overtension at the nickel anode
PERIODICALs Doklady Akademii nauk SSSR,.v. 136, no- 5, 1961, 1154-1157
TEXT: The authors. state that the data published on the effect of the [ORY'
concentration on the oxygen overtension q of a smooth nickel anode are
contradictory and comprehend only low current densitles i. Experiments
were therefore conducted with the participation of L.F. Gushchinal the con-
ditions of which were similar to those described in Refe 4, However, no
rotating electrode was used, and the resistance drop was measured by means
of several electrolytic switches at various distances from the electrode
(galvanic nickel on platinum wire). Linear dependence of the potential
on the distance was found for i = const. The experiments were made at
250C with purified KOH9 NaOHq and UOH. The results obtained for
q - f(log i) are'shown in Figs. 1 to 3. Three sections appears section I,
flatly rising, with the limiting phase Ni 203 + 20H ads --iPMO2(Ki204) + H20
Card 1/7

SZ0201611136100510291032
The effect of concentration BJO.VB106
41'
(1) for const + (RT/2F)ln 1 (2). Then, the steeply rising section IT
follows and, finally, section III with OR- - e --^ OH ads (3) as limiting
phase and j - const + (RT/4P)ln i - r~ (RT/F) 1n [OH] - - fi 0 -W)AL (4)
The course of the curve depends on the nature of the alkali. In the range
E0H]- = (2 - 7-5)M, -r1increases in the order K+ < Na+ < Li+, while for
lower CPH3-, the course is reverse. For -this behavior of.the nickel
electrode, a change of the catalytic properties of its surfaca is asmi-ed
owing to incorporation of alkali ions into the lattice of the oxides.
Concentration and nature of the alkali cation manifest themselves by the
length of section III (corresponding to complete covering with NiO 2) in-
creasing in the order Na+< K+ < Li+. The slow increase of'rLspeaks in
favor of this assumption as soon as some UOH is added to the KOH solution
at i = const. Compared with NaOH and KOH, the increase of *q,in MOH is
already considerable in the range 10-3 < i < 10-2 - 10 -1 a/cM2. It is
concluded therefrom that during charging of an alkali,lbiftterj with
2 b'.' 'I
i > 10-1 a/cm , the battery oapaoity is only slight liv,~ffe a ted by addition
Card 2/7

2OW
s/620/61/1',,')6/005/029/032,
The effect of concentration BlOh/Bk6
of UOH. The dependence of-- on. [CRY is studi~ao In order to exclude
side reactions, the alkali was quickly diluted with water at i - const
without switching off the current. It was found that for NaC1H the over-
tension 11 in sections I and III is independent of [0Hj_. In KOH, the
function-,I - f(log [OHI-) takes a linear course in sections I and III.
The same is valid for LiOH in section III. The-ooefficients of the in-
clination of the function I = f(log i) in section 1 (0-032 - 0-047 at
7.5 - 0.6 M KOH; O-rO30 - 0.031 at 9.5 - 0*4 M NaOH) and the fact that7l
is independent of ',0HY- proved the limiting effect of reaction (1). The
coefficfent of inclination in section 111 (0-090 - 0-130) corresponds to the
limiting phase (3)~ in order to explain the 'faot that q is independent of
[OHJ-, it is assumed that,3 "" const - (RT/F)lnr
T 1 ... PHI- ~N. The validity
of,equatiQn (4).was also confirmed for the chairged Inidkel oxide electrode,
but.on the condi.tion that li- 0. There is thereforiq a difference in the
behavior of the nicke' axide electrode and the smooth electrode studled by
the bLutho're.' There are 3-figures and 1'6 refereneesi 14 Soviet-bloc and
2--noh_Soviet~;bloc.
Car.cT 3/7

20365
S/020/61 1--56/005/029/032
The effeat of concentration B 10 V13
ASSOCIATION3 Lisiohanskiy filial Gosudarstvennogo nauchno-issledovatelf-
skogo i pro.yektnogo instituta asotnoy promyshlennosti i
pr~oduktov organicheekogo sinteza (Lisichansk Bxanch of the
State Scientific Research and Planning Institute of Nitrogen
Industry and Products of Organic Synthesis)
PRESENTEDa Beptember 19, 1960p by A. X. Frijmkin. Academician,
SUBMITTEDg September 16, 1960
Card 4/7

The effec t of concentration

Lebrond to -1 fq - f (log i) in KOH.
Fig
1 7
5 ~1; after 48 hr;
2 M; 2
) dto.
0
;
~
3 :
3 7 M; .
4~ 2:2
M; 51-3 M;
;
5
) dto. after 1~ hr; 5").dto. after 48 hr;
6
; o.6 m

Card.5/7
20365
S/026 61/13~/005/0*29/032
BIOI%B206
Fig. 1

20365
S/()2oj6l/136/005/029/032
The effect of concentration ... BI O,I/B206
Legend to Fig. 2. IQ- f(log i) in NaOH.
1~ 9:5 M; 2~ 7:5 M; 3~ 5-0 M;
4 2 5 M; 5 1 0 M; 6 0-4 M
Q4
Fig. 2

The effect of cencentration ...
Legend to Pig. 3- f(lok i in UOH,
KOHt and NaOH. 1) 5 M MOH; 2 2.5 X LiOH;..
3) 0-5 11 LiOH; 4) 5 M KOH; 5) 5 M NaOH
C
Car'cl 7/7
20365
S/020/6 629/032
1113610051
Blo.lJB2p6
Fig- 3

TUR'YAN, Ya.l.
Polarographic study of 'Ehe mechani-sm involved. in the electroreduction
of simple and cr)mplex nickel iins. bok]. All SSSR 240 no.2:416-418
S 161. (VJAA 34:9)
1. Lisichanskiy filial Gosudar5tvennogo nauchno-issledovatel.'5kogo
i proyektnogo instituta azotnoy promyshlennosti i produktov
organichesRogo sinteza. Predstavleno akademikom.A'4',.Frumkinym.
.1,
(Nickel) (Reduction, Electrolytic)47,'

RUSAKOVAO M.,%.; TUR.'YAXt,,.Xaj.j USTAVSHCHIKGV,, B.F.
-
Polarography of nitric acid esters. Mechanism of electroreduction.
Elektrokhimiia 1 no.7:854457 Jl 165. (MIRA 18:10)
1. Yaroalavakiy tekhnologicheskiy institut i Yaroslavskiy
muchno-isoledovatellskiy institut, monamerov.

FETRAKOVICH, V.Ye.; PODUROVSKAYA, O.M.; TURIYAN, YA.I.
Comparison of platinum oxide and glass indicator electrcd,~s
in acid-base titration. Effect of nonaqueow solvents, the
nature of the titrant., and various additions. Zhur. anal.
khim. 20 no.8:785-789 165. (MIRA 18:10)
1. Nauchno-issledovatel'skiy i proyektnyy institut azotuoy
promphlennosti, Moskva, i Yaroslavskiy nauchno-issledovatellskiy
institut monomerov.

WR t YAY, Ya. 1.
Catalytic PlarOfsraphic current. fjf arme nickel
Zhur. fiz. khisa. 39 no. lt257-258 Ja P65 WIT---A 19 t1)
1. Yaroslavskiy institut monoierov. Sulw-Utted March 19,
1964.

VAKHRUSHEV, Yu.A.; TURIYAN, Ya.I.
Polarographic study of the recombination kinetics of anions
and dissociation of molecules of terephthalic acid. Zhur.
fiz. khim. 39 no.4:979-982 Ap 165. (14IRA 19:1)
1. Nauchno-issledovatellskiy institut monomerov, Yaroslavl'.
Submitted Dec. 19, 1963.

T UR I iLN
-------- I~i~~~
Solubility products and compositf'on of precipitates of
silver and mercury acetylides. Zhur. neorg. khim. 1C
no.2:549-551 F 165. (YDA 19:11)
1. Yaroslavskiy nauchnc-issledovatellskiy institut mcnomerov.
Submitted June 25, 1964.

TURIYAN, Ya.l.; SMIRNGVA, G.A.; TOLSTIKOVA, O.A.
Polarographic kinetic currents of nicotinic acid. Elektrckhimiia ,
no.8:922-927 Ag 165. (M:'JZ-k 18-M
1. Institut monomerav dlya uInLeticheskogo kauchuka.

ZHAITrALAY,
Pclarourp-,.?.i~-- s-147
Of
-1 - -A
165.
j~r im nt en..
y
nost,

.- ~7.1.!;YATINSKAYA, L.N,; TURIYAN, Ya.l.
9
P-3termination of the degree of pi
L -wity of stymnA b7 the inlirac~
potbntioywjl.rlc method In an arhydrona m9dium. Plast. Massy no.21
52-53 t65. (1141RA 180)

TURIYAN, Ya.l.
"i~*,~~~~,~,."Z"!-~--,--~,,,~~"t~,~.- .
Mechanism of the polarographic kinetic currents of g2yox121c
acid.* Elektrokhimiia 1 no.4:491-494 Ap 165.
(MIRA 18:6)
1. Nauchno-issledovatellskiy institut monomerov ulya sinteti-
cheskogo kauchuka.

TURIYALI, Ya.l.
of --,n. a
--m
and trans-solvation equilibrium. fi;,- khil-. 32
1695 Je 164. (~',~LfLk 18:31",
1. Yaroslavskiy nauchno-i3sledovatellskiy institut monomierov,