SCIENTIFIC ABSTRACT TSERKASOV, I.D. - TSERKOVNITSKAYA, I.A.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001757010010-9
• Release Decision: RIF
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• Document Creation Date: November 2, 2016
• Document Release Date: March 14, 2001
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

TSERKASOV I D (Murmansk, oblastnoi, Glavpochtamt, SSSR.)
-- --------- -- 1 -*--0-
Famnple of the homogeneous diffusion process in the space and time.
Cas pro pas tiat 86 no.3:367-371 161.

I - - , , t - ;-, - -, I ~L
, 1 ~4 . . ~ , I

ZEI-gjYANSKIY, 1T.I; PRIB, 0., student IV k-ursa; SHARYPKIKA, M., student IT
kursa; KOSTENKO, A., student III Icursa-, GLUSHKO, A., student III Itursa;
KOZHIOVNIKOVA, 0., student III kurea; KRASIIOVSKAYA, T., student III
Icursa; SMUM, N., student III kursa; PINTOVA, H., student III kursa;
TSERKEVICH, G., student III kursa; SffAPKA, V., student III kursa
Condensation of aromatic hydrocarbons with halogen derivatives of
aldehydes. Nauk. zap. Lviv. un. 13:129-135 149.
(MIRA 12:10)
l.Kafedra organicheskoy khimii Llvovskogo gosudarstvennogo universiteta
im. I. Franko.
(H7drocarbons) (Aldehydes)

TSERKOVER, E.
Thought,,experiment, plan, and factory. Nauka i zhizn' 28
no*12:74-76 D 161. (MIRA 15:2)
(Polymers)

USPENSKIY, Ye.A.; TSERKOVICH, L.T.
Pathamorp#ological diagnosis of congenital toxoplasmosis.- Zhur.
nevr. i psikh. 60 no.3:315-318 t6O. (MIRA 14:5)
1. Kafedra patologicheskoy anatomii (zav. - prof. Ye.A.Uspenskiy)
Odesskogo meditsinskogo instituta imeni N.I.Pirogova.
(TOXOPLASMOSIS)

TSERKOVICII, L.T.- SAFRONOVA O.N.
.9 1
Pathological anatomy and pathogenesis of Cooley's anemia. Vrach.
delo no.9:329-134 S 161. OUFA 14:12)
1. Kafedra patologicheskoy anatomii (zav. - prof. Ye.A.Uspenskiy)
i klinika detskikh bolezney (zav. - prof. V.P.Cheinyuk) Odesskogo
meditsinskogo instituta imeni N.I.Pirogova.
(AM-IIA)

TSIMVITSUTAI I.A.; XUSTOVA, N.A.
Amperometric determination of V44" and V34- when they are present simul-
taneounlr. Vast. WU 15 vo.16:148 160. (MIRA 13:8)
(Vanadium-Analysis)

TSERKOVNAYA, L. N.
TSERKOVNAYA, L. W.: "The state of the--cardicmascular ststem in chronic
pneumonia of children." First Moscow Order of
Lenin Medical IRst imeni 1. M. Sechenove Moscow,
1956. (DISSERTATION FOR THE DEGREE OF CANDIDATE
IN 14EDICAL SCIENCE).
fttzhnaya letopis'
NO- jj, 1956. Moscow.

TSERKOVNAYA, L. N. Cand Med Sci --(diss) "Condition of the cardiovascular
system during chronic pneumonia in children." Mos, 1958. 12 pp (Ist 1.1os
Order of Lenin Med Inst im I. lit. Sechenov), 200 copies (KL, 14-58, 118)
-122-

T3zj"'-T"- Y.r r. SH-'
, rvvAA A, i- . ) _2 .1, , 1. F.
R~eixmatis.m
Prognostic significance of rheumatic nodules in children. Pediatriia No. It, 19'2.
9. Monthl List of Russian Accessions, Library of Congress, December 1952 IWI Uncl.

TSMOVINAYA. L. N., SHMIUDIETA, I. F.,
Fheuma-tism.
Prognostic significance of rheumatic nodules in chIldren. Pe(hatrLia no. 4, 1952.
0
9. Monthl List of Russian Accessions, Library of Congress, December - 195y? U.C1.

TSERKOWAYA, L.. N., 33HIMUDINVIA, I. F.
RheLL-atlc Heart Disease
Prognostic significance of rheumatism nodules in children. Pe,liatriia no. 4, 1952.
9. Monthl List of Russian Accessions, Library of Congress, December 195A Uncl.

TSMMOTIYA, L. 'ff., SHKAUDIEVli, 1. F.
Rheumatic Heart Disease
Prognostic significance of rheumatism nodules in children. Pediatriia No. 4. 1952.
ffl, Uncl.
9. Monthl List of Russian Accessions, Library of Congress, December 19~2 ~

--------- -- ---
.TO'ER'K,^-VNAYA L. N., 31FRUDNEWA, L F.
Children - Diseases.
Prognostic significance of rheumatic nodules in children. Pediatriia
0 . No. 4. !~,152.
g. Monthl List of Russian Accessions, Library of Congress, December -195Y? Uncl.
~a

N.
TSERKOMYA, L.N.
Condition of the cardiovascular system in chronic pneumonia in
children [with summary in Nnglishl. Pedistriia 36 no.1:55-59 A 158.
(MIRA 11:2)
1. Iz kliniki detskikh bolezney (zav. kafedroy - d~ystvitellnyy
chlen AMN SSSR prof. Yu.Y.Dombrovskaya) I Koskovskoj~ ordens Unina
meditsinskogo institute imeni I.M.Sechanovs.
(CARDIOVASCULAR SYSTEM) (PNEUMONIA)

-TS 3 TTLI 71 TA Y AL1S lnl U-DIUVIA, 1. F.
r,hildren - Diseases
Prognostic significance of rheumatic modules in children. ilediaLriia, No. 4, 1952.
9. Monthl List of Russian Accessions, Library of Congress, December 1952 i9YJ, Uncl.

BEREZIN, M.; KILL'MAITSON, G., ekonomist;,~~~~OnomlBt-
Some simplifications in the journal-voucher form of bookkMing
Bukhg.uchet 15 no.10:38-47 0 '56. (MLRA 9:11
1. Rukovoditell gruppy rataionalizataii i mekhanizatail uchata
Ministerstva tsvetnoy metallurgii SSSR (for Berezin).
(Accounting)

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- e a: '.1 -V - I- . , .. - - - I .
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A-C-7 '7~
AUniOR: Tserkovuirskaya, 1. A.; Kam~)Lava, N. C.
o- m ,, 1
TID-F: A_m,-jer etric determL-~atLon of tantal= And t'tzniL=
SOURCE: Leningrad. Universitet. Hetody kolichestvennago opredeleniya elementov
(Methods ?-nr the qimntitative determination of elements). Leningrad, Izd-vo
Lenin-r. univ., 1964, 77-83
0
TOPIC TAGS: riobi,,u-q determination, tantalm, determination, titaniLn determina-
tion, pyrocatechol, amperometric titration, polarographic o-xidation, loparite
analysis
ABSTRACT: A method was developed for amperometric titration of niobiLn, tantalum
vitk "i, -),~!_aroarar)hic oy-idation
card

L 36247-65
ACCESSION NR: AT5007818
error, while 12.8-51.0 pg Nb and 22.8-114 Pg Ta were determined at pH 7.5-8 and
pH 2.5-2.7, respectively, with maxirnum relative errors of approximately 37..
~anta.'.Lu and niobtim in mixturres titat--i-ir. Litrated at p11 -7.7 an
respectively, after complex-irig of tttaniLn. vith Trtlon B. The uethod was used
for deteruzining Ti, 11b and Ta in loparite, and rhe results were found to be in
good agreement with values obtained by determinatiun of Hb 4, Ta with tannic acid
and h-; gra%,Lmetric dater-,.Jna,A(~n :,C T'.. haF: 11 Uibles and I fnrmula.
ASSOCIATION, none
S',M?-1aTrED: 28Sep64 SUB CODE: IC CW
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ACCESSION MR: AT5007823 X).) 0 .6
1. V
AUMOR: Tserkavnitskaya 1. 'a.; B~+.hovtseva, T. T.
IT-ME: Extractive separatiou of uranium vith macromclecular amines
SOURCE: Leningrad. Universitet. Metody kolichest-vennogo opredeleniya elementcrv
(Meth.ods for the qtLantitative deternaifrvittnT-, --f elt~mentq). Leningrad, -izd-%!o
L4-aningr, univ., 1964, 101-106
TOPIC TAGS: uranium separation, macromolecular amine, uranium determination,
volumetric analysis, photometric analysisq luminescence analysis, diethyl-
dithiocarbamate complex, Arsenazo complex
ABSTRACT: The separatio ti of uraniLm frm accornpanying elements by extractton
vi th C. g olu t ions ~7' f is n cc tv I b e n7-v lani t -,.e trL-ri-octvlauine in herizene nr
.ns ~Jran-.`L ite
anr' r i_.! Fs; - wat.:
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ACCESSIGN NR: A15007823
ri-pr.,ld-,icible and accurate results with mixtures containing Fe, Al, TI, V,
Th, Zr, Mn, Ou, L;-., antii,:,i: :1. IT"- L- reamtract the amine extracts
V(VI) -Ith the reagent Arsenazo 111,
M tri-n-actylami-ne lit n f ~~, f r
wilth ~ om the
"J~7isi- oc the Arse-Laz,- rxip ..ffc--rs -3f accompanying ulemunts _~,ere
I un, e 1 ;i Id t ton _~,7 1 f i~' AIL, Fe34) Ti, V, li,,24 C,3+,
!;1- 71 C1 2 F prevent ext,ac~i:17
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A X

T5ERKO~WjMj,__ Yt~. _A., Cand or Phys-Math Sci -- (diss) "Theory of micro-
scopic stability of systems linked with far-acting forces." Moscow, jy!)-f,
5 PP (Mathematics Institute Im V. A. 5teklov, AS USSR), 110 copies
(KL, 30-57, 108)

AUTHOR: Tserkovnikov, Yu.A. (Tserkovrrykov, Yu.O,) 21-5-9/26
TITLE: on the Stability of a Plasma (Ob ustoychivosti plazmy)
PERIODICAL: Dopovidi Akademii Nauk Ukrainalkoi RSR, 1957, Nr 5, PP. 461-
465 (USSR)
ABSTRACT: The author investigated the stability of a plasma with re-
spect to initial fluctuational disturbances in the stationary
distribution functions f.~ (_fl) of the electric field E and
magnetic field H in the case of high frequencies. Linearized
Boltzmann equations without collision terms are used for the
variations of the distribution function bfi (where index i
denotes plasma components). It is assumed that the intensity
of the magnetic field H is high and the free path of part-
icles composing the plasma is by far longer than the Larmor
radius. The functionts sought for f (*50 by expansion by in-
versed powers of the magnetic field H. The method proposed
is demonstrated by an example of a system with an inter-
mediate curvature of the magnetic field. The article con-
Card 1/2 tains 2 figures and 3 non-Slavic references.

On the Stability of a Plasma 21-5-9/26
ASS6CIkTIONt institute of Mathematics of the AN Ukrainian SSR (Instytut
maiewtyky AN SRSR)
PRESENTEDs By N.N. Bogolyubov. (xx9.,B6hcIyVbov)p Acadwdoian
SUBMITTEDs 23 October 1956
AVAILABLEt Library of Congress
Card 2/2

F_- R KO VIA I K0 V)
AUTHOR GERKOVNIKOV, JU.A.- PA - 2060
TITIS Stability of Plasma in a Strong Magnetic Field (Ustojcivost' plasmY
v sillnom magnitnom pole).
PERIODICAL Zhurnal Eksperimentallnoi i Teoret. Fiziki, 1957, Vol 32, Nr.1,
pp 6'-?4 (U.S.S.R.)
Received 3/1957 Reviewed 4/1957
ABSTRACT BRUCKNER and WATSON, Phys.Rev. 102, 19 (1956) investigated some types of
instability for the case that the density of plasma is low and that col-
lisions can be neglected. Boltzmann's equations linearized on this occasion
are used for the perturbations of the distribution functions without
taking collisions into account. Such equations are also used by the author
in this work, for he assumes that the processes leading to instability oc-
cur durin- a time that is essentially shorter than the time of the free
length of path of the particles. Furthermore the author assumes that the
initial perturbations occupy only a small volume compared to the dimensions
of the system and occur at a sufficient distance from the boundaries of the
plasma. Also no boundary-conditions need then be considered. Thus the
author restricts himself to the investigation of a local instability which
might occur in consequence of the directed velocities existing in the
plasma and in consequence of inhomogenities of density, temperature and
the magnetic field.
The distribution function of the steudy state. In order riot, to complicate
the rather extensive formulae the auEhor resFicts himself to the Investi-
gation of the steadiness of a cylindrically-symmetrical plasma. By using
Maxwell's equations the following connectioi~ between the magnetic field H
Card 1/2

PA. - 2060
Stability of Plasma in a Strong Magnetic Field.
and the pressur e p - 2nT id founds (1/r)a(rH)/ar = -(4n/H)ap/ar
H, n, and T are cosidered here as asumed functions of r and as parameters
on which the steadiness of the plasma depends. The small perturbations
af3.,, ZZ' and aA of the steady quantities fl, E~*, and IC" are described by
a system consisting of Maxwell-equations and linearized Boltzmann-equations.
In order to simplify further calculations d time dependence in the form
e")t is sought. Next, the determination of the dispersion equation is
discussed and the so found dispersion equation is written dovm explicitly
is much greater than the Debye-radius
for the case that the wave -laifft.ti,~Z
and the Larmor-radius. In conefuslon the dispersion-equation for follomring
specLal cases is discussed. A) small curvature of the magnetic field, B)
average curvature of the magnetic field. The formulai corresponding to
these cases are written down, explicitly.
.v I
ASSOCIATION
PRESENTED BY
SUBMITTED
AVAILABLE
Mathematical Institute of the Academy of Sciences of the USSR.
Library of Congress
Card 2/2

AUTHORS: Bogolyabov, N.N., Academician, Zabarev, D.N., 20-U7-5-101
Tserkovnikov. Yu. A.
TTTLr,* On the Theory of Phase Transition (K teorii fazovogo. perekhoda).
PERIODICALs DOkladY AN USSR) 195T.- Vol - 117, Nr 5, PP - 788-791 (USSR)
ABSTRACT: The theory of supracondactivity may be conveniently developed by
starting frou~*aodel -Hamiltonian function (gamilltonian) of . thel
form H - H + H Ho " 2: (E(k) -A)at a
0 int k,s + K's kpa'
H (J/V) a+ a a a The summing
int " - (~kl ) -k.-1/2 k,1/2 k1,1/2 -k,-1/2
up process in Hint is extended only to the momenta, k,kI, belong-
ing to the energy level E -&3< I(k)-' 9 v - VIN - const can be computed with an
asymptotic accuracy for a model Hamiltonian. of the form
H - E (k) b+ b irk -k~ b*b b+b ~ -k"kl b f b'~ b b
o k' k k k k k k* 2 k -k _k k;
Zi7 k k-4k
E0 2 ', 0) N(N-111)
b denotes the Bose-, (Boze) operators,&~,the chemical po-.ential,
k
,,/(k) the Fourier component of the interaction energy. The
relation E(k) - k 2/2m -&-holds. This Hamiltonian differs from
the complete Hamiltonian by the fact that only terms marked by
Card 1/3 two indices were kep%t. The operators are transformed

SOY/20--120--5-17/67
On the Theory of Phase Transitions in a Non-Ideal-Bose-Gas
oanonically, which was suggested by N. N. Bogolyubay in 1947
in the theory of 6uperliiqudidity:
+ 2 2
bk k 0 k t-" k P _k ~bk k0k+e,-'k0-,k"'.k _/'~k -I, k
where P and P+ denote the new Bose operators. The inter-
k k
action is assumed to be sufficiently weak. The Hamiltonian
resulting from this -transformation is written down expli4oitly.
Formulae for the thermodynamical potential and for the energy
of elementary excitation are deduced. An expression is also
written down for the spectrum of the elementary excitationav
according to which the Bose gas transform at _; ::lc ri t i c a!
from the non-superfluid state into the superfluid state.
Finally the thermodynamical properties of a Bose gas axe d4S__
cussed. The authors acknowledge Yaluable suggestions giver. by
N. N. Bogolyubov. There are 4 referencesp 3 of which are
So-ri et.
Card 2/3

SOV/20-,120-5-17/67
On the Theory of Phase Transitions in a Noa-ldeal Bose-Gas
ASSOCIATION: Matematicheskiy institut im. V. A. StekloTa Akademii nauk
SSSR (Mathematical Institute imeni V. A. Steklo-r AS USSR)
PRESENTED: January 29, 1958, by N. N. Bogolyubov, Member2 Academy of
Sciences, USSR
SUBMITTED: January 21) 1958
1. Gases-ThermodyPenic properties 2. Operators (Mathematics)
3. Transformations (Mathematics) 4. Phase transitions-M-athamatical
analysis
Card 3/3

24(8) SOV/20-122-6-12/49
AUTHORS: Zubarev, D. IT., Tserkovnikov, Yu. A.
TITLE: The Ther-modynamics of Superconductors (Termodinamika sverkh-
provodnikov)
PERIODICAL: Doklady Akademii nauk SSSR, 1958, Vol 122, Nr 6,, pp 999-loo2
(USSR)
ABSTRACT: The present paper investigates the thermodynamics of super-
conductors by means of Fr8likh's hamiltonian, in which
electron-phonon interaction is explicitly taken into account.
The thermodynamical perturbation theory is used for this pur-
pose. Also the electron-phonon interaction constant is re-
normalized according to the method developed by N. If. Bogolyubov,
whereby it is possible to improve development convergence.
In this way the same advantagesare obtained as in the case of
zero temperatures. The initial hamiltonian is first written
down explicitly. The cBnonical operator transformations are
carried out like In the latporn by N. 11. Bogolyixbov. Noxt, the
hamiltonian is written down by using the now operators (ob-
tained by transformation). The thirmodynamic potential Q is
Card 1/3 calculated according to the thermodynamic perturbation theory,

The Thermodynamics of Superconductors SOV/2o-122-6-12/49
in which connection the ansatz + < R ) is used. Ex-
pressions for 9 0 and < R> c and (in second approximation)
a rather voluminous expression for 9 are derived. The energy
of the elementary excitations of fermions and bosons are de-
termined by the exclusion of certain graphs, which are given.
The equations given here, together with the expressions for
elementary excitations and with the condition for determining
the chemical potential fully determine the coefficients of the
initially given canonical transformations. As usual, these
equations have a "normal" and a non-trivial solution for the
superconductive state of the system. Finally, the thermo-
dynamic functions are calculated. The authors thank N. N.
Bogolyubov, Academician, for his useful advice, and V. A.
Moskalenko for discussing this paper; they further express
their gratitude to C. Bloch (K. Blokh) for placing the first
printed copy of one of his papers at their disposal. There
are 1 figure and 6 references, 4 of which are Soviet.
ASSOCIATION: Matematicheskiy institut iLV. A . Steklova Akademii nauk SSSR
(Mathematics Institute imeni V. A. Steklov of the Academy of
Card 2/3 SciencesIUSSR)

S/155/59/000/02/025/036
AUTHORS: Zubarev, D.N., Tserkovnikov, Yu.A.
TITLEt On the Theory of the Phase Transi on in Fermi Systems
PERIODICAL: Nauchnyye doklady vysshey shkoly. Fiziko-matematicheskiye nauki,
1959, N N 2, pp-133-140
TEXT: The authors consider a system of Fermi particle ith direct inter-
s
action. For the fundamental magnitudes characterizing the system the authors
obtain equations, as they occur in the theory of superconductivity under use
of the quaternary hamiltonian in which the interaction of the electrons
through the phonons of the grid is replaced by their direct interaction, or
in the investigation of the nuclear material with the aid of the quaternary
hamiltonian.-In (Ref. 1) and (Ref. 5) there were solved similar equations
under the assumption that the matrix element of the interaction is constant
and.only different from zero in a close neighborhood of the Fermi surface.
In the present paper the authors show that by application of solution methods
for non-linear integral equations with branching it is possible to determine
the.solution of these equations under more general assumptions on the kernels
of the equations. - There are 11 references, 9 Soviet and 2 American.
ASSOCIATION: Matematicheskiy institut imeni V.A. Steklova AN SSSR
(Mathematical Institute imeni V.A. Stekloy AS USSR)
SUBMITTED: March 18, 1959 (0
Card 1/1

24(0) Sol/ 30-59-2-42/60
AUTROIX. M., Do.t-r or 1-hy.iz.i -4 z4z..c .. -4
TITLZ. riet.r. FXY.L.. pa
Investigation. of L-t-- Ll
flaike ni.kikh t~MpQrAt"
r

FMODICALa V.sLaik &k.d.oli nak 35111, 1959. Xr 2, Vp 96-100 (V332)
T!,
ADMACT. The 5th All-Union Conforwooe on this problem took place Is
0*0b.r 2T to 1. 1958. It ... attended by
fra
'bIII
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Phy.1 I %' _7 "o*oo*. L-Ingrad, Tbilisi.
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a rdlo,.", mal 111Y.T. 4 field. of law-teaperatare physics ware
di com.od. op.ritiluldity of liq.id hoillus 11.
ast2farromagn.tto.. sngxwt-r..1.%t- ffaot. The following
reports =4 GO"wications earn boards A. A 'Abr",v,,. L. P
jgrjkax reported a. the ~f the praprzln- af
_
supracozaduative allays..A. A. Lbrteio.ov, L. P. rlor-kvv,;~~

ke of properties of *upracoadactorm I= the high-
h
tic field. 11. V. 5hirk.r and Cos.' Ck&AL-_X^x'
4
and Chsho. si-shlo' two yo---s-CS!_.... scientists earLUS at
.T.-f-
a.. a. varsity, described invwmzlg~sttaos for detomineetlon
ex. raised by the Cca2mb (Kalm) lawruction
f the influ
nce
Card 1/4 o u conductivity. T. 1. the
:
pr
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_L~L A. Toorkovaikov
Syp in eupraconiuctor.. D. I. Zalixti.
spoke of the th.roodynastic. of opr ... - ~~.
V__Z_jXXjO of the tho-.1 o..4-tzaa of mpru-

Z,Azz1mAM*r report*! cot vs.
In. I.-StAzz1a, T.
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a11 ..Praco doctor&. 19.1.
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of the or % of th . -isotropy of thermal aadoatl.tty is
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th a- rmaduall, Is. In a sort** of ra;arts probIlwas of
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V. . P hkov spoke of the affect of the f-11.. of %be
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. ...... .be It- Go"
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the .....Il.d J-p 1. of I- It, Llf,b4ts'
Ph ...... 4.
tro.g wagratic I old for a tit. I th open r.-L .-f-. .
. To. Aleksay4v*tiy. Ta. P. Gaydokov exparisentally lareati-
I. the
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AUTROX: Cbents", 1.
TZTLVz Th. FLfth &11.Unjaa conference an the Physics of Los
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2 11-11 "1*
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ParaDICALS Usp.khi fIsi.h..kikh A..k. 1259, Tol 61. Wr 4. pp 743-750
(USSR)
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by tb* 01dv2*oiy.
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G/017/60/008/009/002/002
BO11/BO59
V
AUUJOR~ 7�41kovnikov, 14J., A,,
TITLE: The ConvectionalInstability of a Rarefied Plasma
PERIODICAL: F,~rtschritte der Physik, 196o, Vcl, 8. No. 9,
pp. 528 - 548
TEXT: The present article Is a translation from the Russian by F,.Bartels.
The author studied the convectional instatilities of a plasma which are
f 4
due to local inhomogeneities of density. pressu-re, magnetic geld, and
other zarameters. The calculations are approximative assuming the
pertuAations to oc--ur in a vclume that is small as compared to the
dimensions of the whole system;, In the first section of the article a
conductive fluid, (the model of a plasma) in a straight magnetic f-.eld
Is discussed from the viewpoint of magneto-,hydrodyriamics,. In ths case,
instability is due to gravity, Instabilities of a conductive fluid in a
curved magnetic field have been studied in detail by Kadomtsev (RP-f.- 5),
nevertheless, the author derived the stability condition for this case as
Card 1/2

The Convectionpl. Instability of a Rarefied G/0171/0'0/008/009/002/002
Plasma BO11/'BO59
well,, In the following a plasma is described by the hydrodynamics of a
two-component system which consists of positive and negative ions. In the
adiabatic case, neglecting friction between the components and aasuming
isotropic pressure with only electromagnetic forces acting upon the
particles, fluctuations of density, pressure, and the magnetic field do
not lead to an instability.. Next, the influence of heat flow upon
convectional processes in the above two-component plasma is investigated,
The heat flow is found by solving the Boltzmann equation by expansion into
powers of !/H. Maxwellian distribution for the particles is assumed in
zeroth approximation, The collision terms in the Boltzmann equation are
neglected, Last, the rarefied plasma is described by the kinetic equations
with the distribution being different from the Maxwellian. In conclusiGri,
the author thanks Academician N N. Bogo1jubov for his interest ~n the
investigation., There are 2 figures and 11"; references: 9 Soviet, ' German
4 US, and I British,,
ASSOCIATIONi Akad. Nauk SSSR, V.-A -.Steklov Tnst ffir Mathematik, Abt
(AS-
Theor. Phys1k, T-~, USSR, V, J1, 6tok1cL, lns~;tute
of Mathematics, Department of Theoretical Phyai,,al T 2.14oscow)
Card 2/2

Yt
AUTHORS;
3/056/60/039/01/18/029
B006/BO63
Bogolyubov, N. N., Zubarev, D. N., Tserkovnikov, Yu. A.
TITLE: An Asymptotically Exact Solution of the Model Hamiltonian
of the Theory of Superconductivity 10
PERIODICAL: Zhurnal eksperimentallnoy i teoreticheskoy fiziki,
1960, Vol. 39, No. 1(7)~ PP- 120-129
TEXT: Using the model Hamiltonian by Bardeen, Cooper, and Schrieffer the
authors have shown in a preceding paper (Ref. 1) that the thermodynamic
functions of a superconducting system of the volume V are asymptotically
exact if V --* oo and NIV - const (N - number of particles). This was ex-
plained by the fact that each term of the perturbation-theoretical expan-
eion, by means of which the correction to the solution was calculated, be-
comes asymptotically small when V --w co. The present paper shows that an
asymptotically exact solution as the one given in Refs. I and 2 is obtained
even if perturbation theory is not employed. It is further shown that the
solution resulting for V - oD 9 which corresponds to the non-supercondue-
tive state (trivial solution), is not applicable at temperatures, 9, below
Card 1/2

An Asymptotically Exact Solution of the Model S1056160103910111181029
Hamiltonian of the Theory of Superconductivity B0061BO63
that of the phase transition, 0 0 , as it does not satisfy the conditions
required for exact Green functions. It has already been said (Refs. 4 and
5) that there is no trivial solution for 9 < 0 0 . The authors first give
and discuss the model and approximative Hamiltonians of the theory of super-
conductivity. The second part of the present paper shows that the whole
chain'of equations constructed for Green functions on the basis of the
model Hamiltonian can be satisfied asymptotically. The last part shows that
the trivial solution cannot be used below the critical temperature as it
does not satisfy the conditions required for exact Green functions. A sum-
mary of the results of this work is given in conclusion. L. N. Gor1kov is
also mentioned. There are 11 references: 7 Soviet and 2 US.
ASSOCIATION: Matematicheskiy institut Akademii nauk SSSR
_tInstitute of Mathematics of the Academy of Sciences, USSR)
SUBMITTED: February 13, 1960
Card 2/2

/0..2 000rAJ
11" SOV/20 -130-2-14 /69
AUTHOR: Tserkovnikov, Yu. A._
TITLE. On the Problem of the Convective Instability of a Plasmall
PERIODICAL: Doklady Akademii nauk SSSR, 1960, Vol 130, Nr 21
pp 295 - 298 (USSR)
ABSTRACT: In a previous paper (Ref 1) the author investigated the con-
vective instability of a plasma (caused by the spatial in-
homogeneity of its parameters) on the basis of the kinetic
equations without considering particle collisions. The pre-
sent article deals with the same problem on the basis of
simpler hydrodynamic equations. The author confines himself
to an investigation of weak disturbances without considering
boundary conditions, which fact is justified in atudying con-
vective instability. First, he uses an infinite-conducting
fluid described by the equations of magnetohydrodynamics
u _.?
+ (u 9(p + 112 + 2L + (U_~'7 ) P + 9 div _U"" -
~tt , gy
8r
0, + (_1\_/)p + 1p div 0, UH . curl
Card 1/4 Dt ?t

6 7 ~' 6 Ll
On the Problem of the Convective Instability of a Plasma SOV/20-130-2-14/69
(u\7)H - H div u. The fluid is assumed to be homogeneous
along the magnetic field. Furthermore, iN_ it holds (where _9P
denotes gravitational acceleration), and the magnetic field
is assumed not to be curved. The stability is investigated
in linear approximation, and the disturbances are assumed to
be small compared with the steady values of the respective
quantities. Next, equations for the disturbance are written
down. The gradients of the steady quantities are proportional
to a small parameter/t. The condition
in Yo/a in (p + H2/8n) _ (p + H 2/8n)/ Y (p + H2 /0vt > 0
0 0 0 0 0 0
As the condition of convective stability for a system
that may be described by the above-mentioned equations. The
convection is caused by gravitation; howeverp if the latter
is ignored, the equilibrium condition assumes the form
V(P + H 2/8n) - 0. Following this the author studies the com.-
0 0
plicated case of a binary system in adiabatic approximation
(without considering heat flows). With the help of the afore-
mentioned method it is shown that such a system is instable
Card 2/4 even in the absence of gravitation, Equations for the

67560
On the Problem of the Convective Instability of a Plasma SOV120-130-2-14169
disturbances are written down, and are solved by expansion
into the small parameter /L.After carrying Out several oper-
ations, equations are obtained that describe two types of
motions. The system described by these equations is im-wtable
if a current TO - -en 0V0 is present only in the steady case.
Finally, the effect upon convection processes due to heat
flows is taken into account. In this case it is possible to
linearize the equations and to expand them into a small para-
meter. Owing to the drift-like heat flows, heat instability
is possible in this case, which was lacking in the afore.-
mentioned case. The condition of stability has the form
ln T
0
1~ 1 + where Q + y~ ln To/c) In p.
In p 2 y
holds. The method described has a certain disadvantage in
the case of strongly dilute plasmas, i.e., the Maxwellian
distribution was employed as zeroth approximation with Te-
spect to 1/H. A -more exact investigation is pointed out.
The author thanks N. N. Bogolyubov for his interest in the
Card 3/4 present paper. There are 7 references, 4 of which are Soviet
q~~

675660
On the Problem of the.Convective Instability of a Plasma SOV/20-130-2-14/69
PRESENTED: July 16, 1959, by N. N. Bogolyubov, Academician 141
SUBMITTEDt June 22, 1959
Card 4/4

S/04 61/013/002/004/007
25176 B1 12XB229
AUTHOR: Tserkovnikov, Yu. A.
TITLE: Convectional instability of a rarefied plasma
PERIODICAL: Ukrainskiy matematicheskiy zhiirn'al, v. 13, no. 2, 1.9619
190 - 209
TEXT: The author studies the convectional instability of various plashia
models caused by a local-inhomogeneity of density, pressure, ma"2etic
field, and other parameters. The author proceeds from the assumption a
the region of disturbance is small as compared with the whole plasma.
Parts 1 and 2 of the present work have a plasma model which is based, on a
conductive fluid in a rectilinear, or curvilinear magnetic field, respecti-
vely. The magnetohydrodynamic equations: (1'-1) (1-4)
+ ('UV) U) VQ + , [r'ot 'H,+
Tic
aQ
E + (uV) Q + Q div u = 0. (1.2)
Card 1/5

25i76 S/041/61/013/002/004/007
Convectional instability of... B112/B229
OP
jj + (UV) p + yp div U0,
OH (1.4)
T, rot [uH],
Satisfy this model; their solutions have the approximate form3
exp i (S + L.3 t) (u t)
The conditions of stability are:
H 2
+ -2
n ~ 0 PO 81r -
H2 H2
0
in p + 0
0 8 rL- 1,-(Po + 4
Card 2/5
-10
5 0

D/oAl/61/013/002/004/007
Convectional instability of.. 25276 Bll~/B229
and. 2
H
1 0
?ln H 4
'R-rpo i
0 <
)1n r 2
H
+ 0
4zf-Po
respectively. The plasma model of parts 3 and 4 of this work is a two-
component fluid in the adiabatic and nondiabatic case, respectively.
The basic equations are:
mjn, + (u',V) 'uj) rpi + e1n, (E-* + -Llu,Hl (3.1)
at C.
Ohl -i-
T, +(ulv) nj +ni div ul (3.2)
apt
Tt + (ul 17) pj+Vpj div uj 0, (3.3)
Card 3/5

_71-7
25176 S/04 61/013/002/004/007
Y
Convectional,instability of... B1 12
I12.29
41t
rot H = - e (njuj n,u,) +
(3-4)
C c TI
AN E = 41te (n, - n,),
-crotE. (3.6)

where the indices i and e are associated with the ions and electrons of the:
plasma. These equationii -have unstable solutions with a frequency of propa-,
gation of the interferen ce approximately equal to
m 2 The cond
(10 v ition of stability*in the nonadiabatic is as
0
2
H
)ln T
follows: 0 1 1
< +
,?1n H 4rpo
Card 4/5

ty of ?~176
Convectional instabili
S/041/61/013/002/004/007
B112[B229
The determinations Of stability of Part 5 are based on kinetic equations of
the form:
+ + (, + .1 D, 'I ) V -. S . 0
v E v H
d *, M c v
where f(r, v, t) is the distribution function of the particles. The con-
H2
aln T 0
dition of stability obtained is. Oln H 0. < 8xSO . The author compares
the stability criteria obtained flor various plasma models. He thanks
Academician N. N. Bogolyubov for his interest in this work. There are
15 references: 10 Soviet-bloc and 5 non-Soviet-bloc.
SUBMITTEDs February 10, 1960
Card 5/5

eW S/020/62/143/004/014/027
B104/B102
AUTHORt Tderkovnikov, Yu. A.
n
TITLEs The theory of a n6nideal Bose gas at non-zero temperatures
PERIODICA: Akademiya nauk SSSR. Doklady, v. 143, no. 4, 1962, 632 - 835
TEXT; N. N. Bogolyubov has developed the theory of a nonideal Bose gas
at zero temperature (Izv. AN SSSR, ser. fiz., 11, 67 (1947)). By-means
of two-time temperature functions a method is given to investigate a non-
ideal Bose gas at non-zero temperatures. Green's functions are derived by
calculating matrix elements by means of perturbation theory. The matrix
elements satisfy the condition that no forbidden bands should be in the
spectrum of elementary excitations. Thanks are due to Academician N. N,
Bogolyubcv, D. N. Zubarev and S. V. Tyablikov for discussions.
ASSOCIATION: Matematicheskiy institut im. V. A. Steklova Akademii nauk
SSSR (Institute-of Mathematics imeni V. A. Steklov of the
Academy of Sciences USSR)
C

ACCESSION NRt APS001984 S/0020/64/159/006/1264/'1267
Second sound in a weakly-ideal Bose gas
SOURCE: AN SSSR. Doklady, v. 159, no. 6, 1964, 1264-1267
TOPIC TAGS: Bose gas, ideal gas, second sound, Green function,
elementary particle collision, plasma theory
A3, S TRA C T'nle problem considered 'here is the same as treated by
(prepr_n!~, J()~ n~~ Tj-~S- ~!7-e
of Nuclear Rese-arc~~,
who Lli
1 T" C-v
s

ACCESS ION L',IR AP 50019 "--14
S 1 ow 7~~e ~-n~orac-,;-on is assumed smal-'
v ':.e of
G r ee s -,:)eccr-.es eq--ilvallent !~c-
t -unction as
0 LC oelia-,)-Or of Lhe -Green I s the ~iwe increases without
1
1-itrit is obtained, making the results applicable to plasma calcula-
av-hor '-hanks N. N. S, V. Tvablivov,
N
1 7,:-! es j< i
0 va
S !ML~ 1, T.- 2 T 6 4
SUB CODE: NP, G-P NR REF SOV: 005 OTHER: 000

I _04203n~7 __EW1W__1JPW-
AC~: W 0300 6 SOURCE CODE: UR/0020/66/169/005/1064/1067
Tserkovnikov Yu. A.
ORG: Mathematics Institute im. V. A. Steklov, Academy of Sciences SSSR (Hatematiches-
kiy institut, Akademii nauk SSSR)
ITITLE: Concerning second sound in a non-ideal bose gas
ISOURCE: AN SSSR. Doklady, v. 169, no. 5, 1966, 1064-1067
ITOPIC TAGS: boson, Green function, approximation method
ABSTRACT: An approximation procedure is presented in which the speeds C, and C2 of
"ordinary sound" and "second sound" are computed for the case of a condensed system of
I
ibosons. The Green function approach is used throughout. It is found that in this ap-
iproximation, one loses the attenuation of the second sound and also the correction to
!the effective mass of the particles. This ineans -that the interactions between the bo-
~sons must be regardba as weak, and that the particle density is high. The final
I ex-
'pressions for the speed C1 of ordinary sound and -the speed C2 of second sound have the
1properties that (a) C1 is independent of the temperature in this approximation, (b) C2.
falls to zero, as it must in order to agre-e with experiment, when the number of PU-ti-
,cles in the condensed phase goes to zero, (c) the ratio of C, to C2 comes out wrong ail,
,this approximation; to obtain a correct value for C21CI one must use either the hydro-
UDC: 536.758
L.Card 1/2

)5~~C NR% AP6030016
~dynamic approximation of Bogolyubov, or else lie must carry out a calculation based on
Ithe kinetic equations. The author thanks N. N-t qov for his discussion of the
_~ol~ -
work. Presented by Academician H. N. Bog,;,_~Yov on 3 i~gust 1965. Orig. art. has:
ilS formulas.
SUB CODE., 20,121 SUBM DATE: 27Ju165/ ORIG REF: -004/ OTH REF: 001
-Card 2/2-2-161,

TSERKOVNIKOV., YU.A.
-i-Appead fi-ft're~--of chaotio phases in the theory of nonideal Boas
gas, . Dd_kl..&'SSSR 159 n6.5tlO23-1026 D 164 (MIRA 180-1)
1. Matematicheskiy institut im. V.A. Stsklova AN SM. Pred-
starleno akademikom N.N. Bogolyubovym.

TSFMOVNIKOV, Yu.A.
Second sound in a slightly nonideal Bose gas. DokI. All SISSR
no.6-.1264-1267 D 164 (MIR.A. 18:1)
1. Matematicheskiy institut im. V.A. Steklova M; SSSR. 'Oved-
stavleno akademikom N.N. Bogolyubovym.

TSERKOVNIKOV, Yu.A. ..
Theory of a nonideal Bose-gas at nonzero temperatures. Dokl.
AN SSSSR 143 no.4:832-835 Ap 162. (KRA 15:3)
1. Matematicheakiy inztitut im. V.A.Steklova AN SSSR. Predstavleno
akademikom N.N.Bogolyubovym.
(Quantum theory) (Gas dynamics)

GOLIDSHTEYN, M.N., prof.; ZHEREBTSOV, I.V.; TOLISKAYA, S.Ye.; FRISHMAN, M.A.;
LEVANKOV, I.S.; ROZENBERG, A.M.; BELASHOV, D.A.; -T5nKQVNITSKAYA,_-A.I.;
LAPIDUS, L.S.; YAKOVLEV, B.V.; GUBENKO, Ye.N.; VICHEREVIN, A.Ye., red.
[Preventing the deformation of tracks and structures overlaying
mine workings.] Preduprezhdenie deformatsii puti i sooruzhen-ii nad
shakhtnymi podrabotkami. Moskva. Transport, 1964. 65p. (Voprosy
geotekhniki, no.8) (MIRA 18:2)

TSERKOVNITSKAYA, I.A.; BOROVAYA, N.S.
Determination of small amounts of zirconium in native materials.
Vast. LGU 17 no.16:248-150 162o (MIRA 15:9)
(Zirconium) (Rocks-Analysis)

? IINU~ ~

137-58-3-6293
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 3, p Z65 (USSR)
AUTHORS: Morachevskiy, Yu.V., Tserkovnitskaya, I.A.
. ...........................................-
TITLE: Separation of Small Amounts of Uranium (41) in the Presencd of
Niobiurn and Tantalum by Means of a Phosphate Method (Vydele-
niye malykh kolichestv urana (4) fosfatnyrn metodom, v prisutstvii
niobiya i tantala)
PERIODICAL: Vestn. Leningr. un-ta, 1957, Nr 10, pp 152-154
ABSTRACT: A method has been developed whereby small amounts of U can
be deposited in the presence of Nb and Ta. Precipitation is car-
ried out in tartaric acid solutions containing Nb.05 )Ta.05, and
UOzC1 2* The U is first reduced by an amalgam of Zn, a collectcr
is added to it [ I cc of 2 percent solution of Zr (N03)41 and both U
and the collector are precipitated by a 10 percent solution of
(NH4) , HPO 4' After dissolving the precipitate in a 10 N solution
of H25,64 . the U is titrated with an 0.01 N solution of NH4VO3
with phenyltranyl acid. Final separation is achieved when the con-
centration of the tartaric acid is 0.5 g or less for every 100 cc of
Card 1/1 the solution. P.K.

MORAGHIKVSKIY. Yu.T.; T-SICH OVIIITSKAYA, I.A.
Separating uranium from aluminum, chromium, nickel, cobalt, and
vanadium by means of inner electrolysis [with summary in English].
Vbst. TOU 12 no.16.1127-130 157. (MIRA 10tll)
(uranium) (Electrolysis)

AUTHORS: Morachevskiy, Yu, V., Tserkovnitska a 75-13-3-15/27
TITLE: Amperometric Titration of Tetravalent Uranium With Ammonium
Vanadate (Amperometricheakoye titrovaniye chetyrekhvalertnogo
urana vanadatom. ammoniya)
PERIODICAL: Zhurnal analiticheskoy Ichimii, 1958, Vol 13, Nr 3,
PP 337-339 (USSR)
ABSTRACT: The problem of the amperometric titration of uranium has not
been satisfactorily solved. The polarographic char4cteristics
of elements which can be used as oxidizing agents for the ti-
tration of tetravalent uranium were traced out. A method for
the amperometric titration of uranium with trivalent iron was
also described in publications (Ref 1). The authors of the
present paper used ammonium metavanadate as oxidizing agent
in the titration of tetravalent uranium. Vanadium is on this
occasion reduced to the tetravalent stage at a dropping-mer-
cury electrode at a potential of - 001V. Syrokomskiy (Ref 2)
suggested a visual method of the vanadometric titration of te-
tid.valent uranium with phenylanthranilic acid. This method is
very sensitive, but it can only be employed in 5n - 13,5n
Card 1/3 sulfurio, acid solutions; besides visual methods are unsuitable

Amperometric Titration of Tetravalenz Uraujum _Jith Ammonium 75--13-3-15/27
Vanadate
for the titration of colored solutions. It became evident that
for ammonium metavanadate in In H 2s0 4' 1n HC1 and In RC104 the
limit current for vanadium is distkutly marked. When using
these acids as medium, uranium can beamperometrically deter-
mined in a potential domain of 0 to -0,16 V.. Before the titra-
tion a hydrogen current was for 30 minutes sent through the so-
lution for removing the oxygen. A change of acidity of 4.1- -o-
lution in a aomain of 0 in to In (sulfuric acid, hydrochloric
acid or perchlorio acids practically exerts no influence upon
the results of titration. Thus uranium in concentrations below
255 7/ml can be determined with satisfactory accuracy by am-
perometric titratija with a 0,005n solution of ammonium meta-
vanadate, The relative error on the averare amounts to 1-'~%~
In titration with a more diluted solution of ammonium meta-
vanadate the titration curve takes a much steeper courne,which
leads to higher errors in the determination of the end point.
The Dresence of electrolytes (KC1, K2SO4, 1M4C1) does not in-
fluence the determination of uranium id 0 .1n sulfuric acid so-
Card 2/3 lution. The disturbing influence of iron can be removeP, b.-, or.-

Amperometric Titration of Tetravalent Uranium With 75-13-3-15/27
Ammonium Vanadate
thophenantroline. This binds ions of bivalent iron to a stable
bright-red complex which is not oxidized by pentavalent vana-
dium. Iron, prior to its masking, is reduced by liquid zinc
amalgam in a sulfuric acid solution. The mean error of the am-
perometric determination of uranium in the presence of com-
plexly bound iron is 3-6%. For binding lead, bismuth, chromium
and nickel, which elements may disturb the determination by hy-
drolysis or the formation of sulfates, difficult to solve, com-
plexon III is added to the solution. This keeps these elements
complexly in solution and does not influence the results of the
amperometric determination of uranium. There are 2 figrarea, 6
tables, and 2 references, 2 of which are Soviet.
ASSOCIATION: Loningradakiy gosudarstvenn3rj nniversitet im. A.A. Zhdanova
(Leningrad state University imeni A.A. Zhdanov)
SUBMITTED: February 8, 1957
Card 3/3 1. Uranium--Determiration

5(2)15(3)
AUTHORS: Morachevskiy, Yu. V., Tserkovnitsk~~ya,I. A. SOV/75-14-1-10/32
TITLE: Gravimetric and Fhobor~ctric Determination of the Thorium
Content iz,. Uraninitesid1the Aid of' Anthranilic Acid
(Vasovoye i ZutomcLricheskuye oprodeleniye soderzhaniya toriya
v uraninitakh pri pomoshchi antranilovoy kisloty)
PERIODICAL; Zhurnal analiticheskoy khimiij 1959, Vol 14, Nr 11 PP 55-59
(USSR)
AIIS:L'RACT: Natural uraninites contain relatively small quantities of
thorium. The authors employed anthranilic acid for the
separation and determination of thorium. It was found that
under certain conditions thorium can be precipitated
quantitatively with anthranilic acid. An excess amount of
reagent does not disturb the separation. The optimum Pic value
for the separation of small quantities of thorium in the
presence of uranium is 4.2 - 4.4)uranium being maintained in
complex state in the solution by the aid of hydrochloride of
hydroxyl amine. In this way also rare earths up to a ratio of
C602 : ThO 2 = 8 - 1 and lead are fully maintained in the
Card 1/3 solution. Thorium can be precipitated quantitatively, if its

Gravimetric and Photometric Deterv-'ion of SOY/75-14-1-10/32
the Thorium Content Uraninites i1th the Aid of Anthranilic Acid
conceri+r"sion is not smaller than 0.2 mg/50 ml. To determine
thsrium af ter its Lion as anthranilate, the amino group
of anthranilate is diazotized and coupled with ~_naphthol, in
which connection an orange-hued dye is formed.(Ref 8). In this
way, -the application range of this method can be considerably
widened. The colorin-- of the solutions is determined photo-
metrically. The determination of the ThO 2 content is carried
out on the basis of a calibration curve. The error of this
method is sensitivity is very high, and permits the
determination of 0-04rTh/ml. This -D." Qorium separation
and determination was tested on natur~-.l urkninitea,.
A comparison of the results with those the
determination of thorium by the aid of phenyl acetic acid
showed a good agreement. The calibration curve for the photo-
metric determination of thorium is illustrated. The procedure
followed in the determination is described in all details.
Card 2/3

Gravimetric and -!ittPrr,i,.-Von of SDV/75-14-1-10/-/!?
the Thorium Content i.-.Uraninitesi4ffitbek.(j of Anthranilic Acid
The determination of thurium after separation as arithranilato
may also be effected gravimetrically after annealing the
precipitate. There are 1 figure, 7 tables, and 8 references,
2 of which are Soviet.
ASSOCIATIO14: Leningradskiy gosudarstvennyy universitet im. A. A. Zhdanova
(Lenine,rad State Univeroity imeni A. A. Zhdanov)
SUBMITTED: September 1, 1957
Card 3/3

5(2) SOY/79-29-5-1/75
AUTHORS: Morachevskiy, Yu. V., Tserkovnitskaya, I. A., Golubtsova, Z. G.
TITLE- Precipitation of Palladium With Dimethyl Glyoxime in the Presence
of Ferric Oxide Salts (Osazhdeniye palladiya. dimetilglioksimom
v prisutstvii soley okisi zheleza)
PERIODICAL: Zhurnal obshchey khimii. 1959, Vol 29, Nr 5,
PP 1405 - 1408 (USSR)*
ABSTRACT: In the present paper the authors investigated the influence of
iron upon the precipitation of palladium from hydrochloric, sul-
furic, nitric and chloric acid solutions of different concentra-
tion. It was first determined how far the acid concentration may
be varied without decroasing the yield in palladium. The experi-
ments indicated that the precipitation of palladium with d.-methyl
-
glyoxime is still almost complate in 1.5 normal chloric acidq
nitric acid and hydrochloric aci,! solutions. In sulfuric acid
solution a 100%. precip-ibation of palladium still takes place
from the 2-n solution. The increase "in acidity of the solution
influences the yield in pallad-Jum most in chloric acid and least
in sulfuric acid solutiont3. The reoults obtained in the precipita-
Card 1/2 tion of palladium with eiinot!iyl glyorilme in the presence of

Precipitation of Palladium With Dimethy! Glyoxime in the SOV/79-29-5-1/75
Presence of Ferric Oxide Salts
FeCl, Ln hydrochloric acid medium are summarized in table 1.
Table 2 presents the results of the precipitation in the presence
of Fe2(SO4)3 in sulfuric acid medium, table 3 the resulta in the
presence of Fe(NO 3 in nitric acid medium and table 4 the re-
sults in the presence of trivalont iron in chloric acId nedium.
The results obtained permit the assumption that there is an
interaction between dimethyl glyoxime, iron (III) and p:~.lladium
in acid solutions in which conriection a complex compound is
formed. The nature of this compound is not yet clarified. At
present the authors are carrying out the spectroscopic investiga-
tion of the system palladium-iron-dimethyl glyoxime. There are
4 tables and 2 references, of which is Soviet.
ASSOCIATION: Leningradskiy gosudarstvennyy universitet (Leningrad State Uni-
versity)
3UBMITTED: April 22, 1958
Card 2/2

In, 1/000/1
AUTHORS: ,ikha,r1o1.r, V. !t.T v i na F
U- U e~e-entp, by
TITLE: Extrac'--on o~ n 41rale[3 oj^ tile-
means of tributyl 4n tlo Trilon 3
no..6, i961, 14157-11,,,65
PERIODICAL: Zhurnal- neorj;anici
TEXT: Complex--~formi.ng sub,,;1;.-ancoo~ often 'hevn used for the chromiato-
graphi.c separation of -raxe-earth. ell c.:-iento ~,;-'Z-E) -, I-On e e I I e cZ, o 1 z n e c omp j. ex-
orming sub st Line r., i n te an ue otif..- :~hll Olf-I On .11f, seDaration of t*,..e 7117E, in
(TT',!"!-'3 mole oplution 1e
the system: tributy! Dao,,pha .0
3
L U-
Trilon B has been studied. The followinc holds for the distribution
of an REE nitrate present in one phase, to two phases of equal volume:
~j ~ S I- r4 'bution coeFicie-.q' in 'he
E = c /C (1),* where F, is je a-.IF
0 r U U
presence of Trilon 3; c t', eequilillritim concentratiqn of the element
or,
the organic .~iase *. cthe equilibrium concentrationlof tile element in
A
1i the aqueous phadb. In the aoueous phase, 'the follo,,-;ir~ ions are in
V~ Card 1/ 9
7,

,'07 e. '6 1 6 /3
Extraction of nitrates of -rare-earth 31 1 3206
3+1 3
equilibrium: Me - e Y anr~ TI-erefore, E c /6 1
3 j Org
?,To- + :L!e7- holds, where are the full stability.
3-. 3-i
consL-nts of the nitrate complexes of the type '..Ie(,,To )
3 n the cuotient-
rom Trilon concentration in aqLzeous ,)hase and inill"I'al REil~ concentration
11 :.c : n + ~-:;) + (1-3/c, (12), where Z can be considered
tr/cin)
an emoirical constant. The foilo-.,;in~3 s Tvritten for t'~e distribution
Coeffic., and :7d(,70 -
.ent of t-.-.o nit-ratcs ; )3
J
Pr
hr I Kpry- [NO., 11
(.
where the degree of 8 'he S(,-
t 4 on
effectiveness -;,rithout Tri-Ion. c~ Tne holds for
0 1)
0
Card 1/ .1

Ex I V;i
rm
r.:, n ra F
7~ e1 ft

9
a" w ay na
n C a c., in
b -, gge 3
-1 0 r
r V.) 1r,
4
.
e r
' --l -3
f ~tl-mlne "
x
a
-t
.
r -I of the ~,r:W ex
n. ra * s i;
tild F. 7 1
7 'r -
I ril
111P
r
.
,
y
Ined
,
I
B P wa '
1 rl 3 C. - i I n '

, 0
"
N9 1 we7,t, ~nrl
0
.ar
e cl 1~ I U~,Tl V. 8-c,

Tr*
.
n
r -t, I
rv bv :n
1z F,
'b r '
7
. -c,' E E,
~t a p
a - di 9

x t t I r
V, C, r t 1 1 ~.j .j r I 1-t
4 SF-- 4 L Pl I C."', Y.!h v
n t~f T'l j~
11 lp, All !I ny (I rc d e
r, m -i n va n rl- m r --i nc--) T r n B, fl-r,.-: r
f e x t 1)
P, 0 o. n c 7? n tra i c n H v-i X .3 Inc an.-I Nu 01-ir,
racil, tum p-
arA hc~llu!-,-.im~ A. K~ and F C'
(Ref Ra-i-.ckldmlyq. I t) r--E., :;':,:wi 7 11 (j
TB? ~-xtrac.~icn frQir, Ei~-' ic,ns- wi -
.1 r, t~e :r-rcen"rVion ~- -in -a e a- -n ~ d a b ~!,rl e 1j
under thq same condi"lon3 in ~e Tres-3n,~e c~ T r i I P Th e 11 va" ue
(~ f
dTC'Tped f r~,rr 1-4. hre~.lli~n E!x u c t,-1 e. * ed
be-ween 91 and 1001/7, F i P, ? 9 h,: w s ~ he d s . r -~ I. -..i n
- C, e f f -I r~ I e n - s -- a 1 -o, a,~ Z'd 'nlv ~3 ~~ -f B rA?aIri-I
Eq, (I ;~ The inrrea~z;~ ,.f -Itii- pE '.,-iad~- -eluc-.,~r. ct' Iie
!Jrr
Card 4/9

S/078/61/006/006/01)9/013
Extraction of nitrates of th& rare-earth ... 3110/~n200`
to the right. The comparison of S and F 0in Table 8 shows that Trilon B
does not facilitate the separation of the IRLE of the,cerium gr oup, but
facilitates that of La-11d considerably. The separation of the IREE' of the
yttrium group is also facilitated. In the series Ho - Yb Trilon 3 raises
the distribution coefficient by 2-5 to 3 'imes- S amounts thereby to
3 - 3-5-for a few neighboring elements. The authors thank V.K. Valltsev
for his collaboration. There are 4 figures., 8 tabies, and 1/1 references:
4,Soviet-blpc and-5-non-Soviet-bloc. The references to the English-
language publications read as follows: Ref. 3: D. Scargill et al.: J.Inorg.
and 1,ucl. Chem., 4, 304 (1957). Ref. 6: C. V. Banks et al. Analyt. Chem.,
30, 1792 (1956). ~ef..9: E. J. Wheelwright- J. Amer. Chem. Soc., 75,
4196 (1953)-
ASSOCIATION: In'stitut neo~ganicheskoy khirdi_-~ibirskoye otdeleniy'e
Akademii nauk SSSR (institute of 'Inorganic Chemistry,
Siberian Branch AS.USSR)
SUB11,1ITTED,.-
Card 5/9
lil 9, 1960

24394

S/186/60/002/002/013/022 5
0 -0 E071/E433

AUTHORS: Tserkovnitqkaya, I,A. ajid Charykov., A.K.
TITLE: A study of' the extraction separation, of thorium from
some elements using the z:iethod of marked atoms.11-
I. The extraction of thorium phenylacetate with
diethyl ether, A compound of uranyl ion with
phenylacetic acid, The separation of thorium from
uranium
PERIODICAL: Radiokhimiya, 1960, Vol.", No.2, pp.222-230
TEXT: The object of the u-ork ;.ras the development of a method of
separation of thorium from some other elements (particularly
Uranium and rare earth elements) suitable fo*r the e;,ftraction of 77

thorium fro
m its natural raw materials. The method' was based on J

the precipi
extraction -acid and the
tation of thorium with phenylacetic
of the'precipitate by organic solvents. Solutions of
thorium nit rate, a 2% aqueous solution of phenylacetic acid (AR)
and diethyl ether were used as reagents. The distribution-of
thor'ium was controlled u.,3ing radioactive thorium isotope UX1
(Th2341 T -- - 24.5 days) All. experiments were done at a constant
ionic force equal 2, producod by ammonium chloride, The
Card 1/3

209h
86766/002/002/013/022
S/I
A study of the extractinn ... E071/E433
precipitation was from hot solution-s. The.extraction was done at
j about 200C. optimun, extraction conditions! the v6lum6'df'ether
should equal 'the volume of the aqueous phase, the concentration
of thorluni should be of the order of 1 mg per 20 ml of the
solution. It 'was found that the precipitated thorium
phenylacet-ate possesses specific properties, namely it is
extracted by some organic solvents without changing its structure,
i.e. without dissolving in the organic phase. A complete
extraction of thorium phenylacetate with diethyl ether takes place
in the pH range of 3 - 5. From the organic phase thorium can be
quantitatively re-extrncted with dilute (1:10) mineral acids. The
dissociation constant of phenylacetic acid and its distribution
constant be-~ween diethyl ether and water at an ionic force of the
solution'equal 2 and a temperature of 200C were found to.be
(8. 1 -+' o. 4) x 1 o- 5
and 311 + 2 respectively. On studying the
possibility of the separation of thorium from uranium, it was
established that from a solution containing 0.1 M of phenylacetic
acid, 2M of atwitonium chloride and it concentrntion of uranyl ion of
about 5 M9/M1-, a procipiLitto J.M fox-mod beginning from a p1l of 2.6
and above. The composition of the precipitate corresponds to the
Card'2/3'

A study of the extraction ...
24394
s/186/60/002/002/013/022
E071/E433
fOrmulA U02(C6H5CHOO)2'C61'5CH2CGONH4- It is a fine, light yellow
melts'at OQC with a
-crystalline powdier, stable in air. It '22
noticeable decomposition. It is soluble in water without a
noticeable hydrolysis.. The solubility at 900C is about 2.8 g/1.
It is Practically insoluble in diethyl ether. The'above property 4i
was used for the separation of thorium from considerably lar-ge-r
quantities of uranium. It was found that in order to obtain a,
~1_complete precipitation and extraction of thorium, the pH"of th
~'4 solution should be above 3.
However, if uranium is present in
~i, larger quantities, the extraction of thorium is difficult,
therefore the method of direct separation of uranium and- thorium by'
,1~~extraction of thorium phenylacetate with ether is'-limited to
similar concentrations of thorium and uranium. 'At higher
concentrations of uranium a satisfactory separa7tion can be obtained'
in the presence of hydroxylamine (for.combining uranium into a
:~.,complex)-at a~pH of about 4-5, There are-2 figures, 3 tables and*
2 referenceers I Soviet-bloc ancr I non-Soviet-bloc.
SUBMITTEDt 'June 17 1959;-,
Card' 3/3
'77

TSERKMITSKAYO I.A.; CHARYKOV, A.K.
Tracer study of the possibility of seperating thorium from certain
elements by extraction. Part 1: Extraction of thorilm phenylacetate
vith ethyl ether. Compound formed by the uranyl ion with pheny-
lacetic acid. Separation of thorium from uranium. Radiokhimiia 2
no.6;222-230 160. (MIRA 14:4)
(Thorium)
(Uranyl compounds)
(Uranium)

TSMMOVNIT5WAU,j;A., ; BOROVATA, M- S-
%-WO-NNM - I .
Behavior of zirconium during the extraction of uranium and nio-
biu~ dietbVldithiocarbamates. Uch. zap. LGU no.297:96-96 l6o.
(MJA 13:11)
(Zirconium) (Carbamic acid)

TSFJMOVHITSKAYA, I.A.; CHARYKOV, A*K.
--
Development of a scheme for the analysis of uraninite. Uch. zap.
LOU no.297t.109-118 160. (MIRA 13:11)
(Uraninite)

MORACHEVXSXIY, Yu.V.-. TMKOVNITSKAYA, I-A.; GRIGOR'YEVA, M-F-
New variant of the cupferron method for extracting uranium. Uch.
zap. = no.297:119-124 160. (MIRA 13:11)
(Uranium) (Oapf erron)

TSEMVNITSK&YA, I.A.. KALININ, A.I., MORAGEMKIY, Yu.V.
Amperometric titration of gallium with a cupferron
solution. Zav.lab. 26 no.7:797 160. (XIRA 13:'~)
1. Ieningradskiy gosudaratvennyy universitet im. A.A.
Zhdanova.
(Gall ium-Analys is)

MORACHSVSKIYp TusV& [doceased]l TSEMCVNITSKAYAl I.A.
Photmetrio datemirAtion of tatravalont vanadi= with acid
chrom blue X, Zhx=~ anal, kbime 16 no* W06-107 J&-P 161..
(MIRA 14Q)
L A.A. Zhdanov Ianingrad State Univenityo
(Vanadium-Analypif) (Acid chrome blue IC)

TSERKOVNITSKAYA, I.A.; PRUDNIKOV, Ye.D*j KUSTOVA. N.A.
Effect of organic complexing agents on the oxidation-reduction
potential of the v4+ /v3+ system. Vest.IZU 16 no#10:133-130 161.
(NIRA 14:5)
(Vanadium compounds) (Oxidation-reduction reaction)
(complex iona)

1-1,9o
s/186/62/004/002/Oo6/olo
E075/E-136
t1
AUTHORS: Tserkovnitskaya, I.A., and Charykov, A.K.
TITLE: Study of the possibility of extractive separation
of thorium from some other elements by the method
of radioactive tracers
PERIODICAL: Radiokhimiya, vA, no.2, 1962, 184-188
TEXT. The authors aimed to develop a method giving a more
complete separation of Th and the rare earth elements than that
described previously by them (Ref.l: Hadiolchimiya, V.2, no.2,
1960, 222) by considering the possibility of preventing
coprecipitation during the extraction. It was found that Th can
be quantitatively separated from La by extracting thorium
phenylacetate with ethyl ether in the PH range of 3 to 4.5.
The separation of Th from large amounts of Ce can be achieved
successfully by extraction in the presence of hydroxylamine.
Correct PH for the extraction depends on the ratio ofCe to Th
and tends towards the lower (acid) values when the ratio
increases. Many cations including K, Nal Hg?-'. Pb2+ and some
Card 1/2

0
Study of the possibility of ... s/l86/62/oo4/oo2/oo6/olo
E075/E136
others do not affect the extraction. Certain cations such as
A13+ and pe3+, even in negligible quantities', make the
extraction more difficult especially at higher than 4 values of
pl-1. It is therefore necessary to remove both Al and Fe from
the mixture before the extraction. The new method is suitable
for a rapid and complete separation of small quantities of Th
(of the order of 2 mg) and gives a possibility of carrying out
a volumetric finish. The authors intend to apply the method
for the determination of small amounts of Th in various mixtures
containing U, and the rare earth elements.
There are 7 tables.
SUBMITTED; June 17, 1959
Card 2/2

decetj~3ed
vitallyevich khJUL-
~rjdj.-c,.vria; KIII -yu.17
Irina AleksO - V. A,., rc-d.
nauk3 otv. re6.; ~OZLTIS'~"'V" ].;~ j of the rare
,)f t1lo analytical e I.F,-
)Ies kilindi redkAkh
j r
0sno,r, analit Luliv - 3
e I evielat Lenl-ngr.
1r. -tov .Lern rq, vid)
'en

AMB-SlOl' WRI AP5()l--%63:L -o-, ~,i 64/ooVoo4/054-4 /o550
1, A.: A. K.
7 - 7 'c"Me' pr-)Pertiee 0~ o Sa.1 ta of
507R~CE: :Viz. Khimifa i v, ', no. 14, ji,~4, ry44-55()
TV I - -
thorium, organic aa-It
of -,Rlts of thorium with organic acidn of various
-ari-~Tvqtlc acids, Tarious substituted
,q~3 a jn-~on the
'he rreclplLaL~~-
r Lra a-'-,: Etaa3 1
--~-qtlon in -rg--nic sol-ents.
ra I-aj< I

AL 56568 -65
I ACC-MSION NR: AP5018631 z ,
i v
SUBMT"L'M- 21,3ep62 ENCM 1 00 SUB CODEt GC
IK V., F S C, V " C~) " ! .0 12 JPRS
I
I'i
r-m- I - v -

K011-1f.)LOVA, PIT.G.; TSERFUMITI-ITSKAYA,
Am,-,eronetric 1--trat-ion c; nicb.1,ud vith Zav. lab.
I
I
30 no.11:1329-1330 164' (11"IfUl !a-.!)
1. L-eni.ngradskiy gQsudarstvcnny-,r universitet.

TSERKOVNITSKAYA, LA.; YEPDIAMOV, V.I.
Determination of Gp-, Se. and Sn in cemiconductor materials
by oscillographic polarograpby. Zav.lab. 31 no.10:1178~
1179 165. Oga 19:1)
1. laningradskly gosudarstvennyy universitet,

L 04492-67 EWT(m)/EWP(j)/T DS/RM
ACC NR, 0 SOURCE CODE; U1q/O6W67/0GO/G6jk10'1/0106
AF5017112
kX110?,: Tserkovnitskaya, I. As; Yepimak~ov, V. 11.
om: none
TITIZ: High-frequoncy alkalinetric titration of po ~ienolGermanium acidsl
I SOURC3: Leningrad. Univorsitet. Vestnik. Seriya ftziki i khimA, no- 3, 1965.
101-106
TOPIC TAGS: organogermanium compound, amperornotric titration, polarographic analjlisl
Based on polarographic, data, It was fjoun'd that complex~
compounds of germanium with polyphenols are reduced in a acidic
medium on a mercury drop electroae.'] -,!-,e hlShest --taximum cur..:-ent
was observed in a hundredfold excess Gf organic reagent wit', re-
speot to germanium. The composition of the cou~plexes investl,~ated
w'as established by amperometric. titratlon In an alkcaline medium
i with respect to the reduction current of germanium. The germavilum;
polyphenol ratio In the complex was 1:3. it was of Interest to
-compare results on a scudy of complexes usil 'he polarographic
method. with those obtained from high-fr.equency noncontact t!Lra-
t';.on, since In this case there are no electrochemical processes
at'. the interfaces (electrode
pr~c~eesses), and the eleol"rochemical
~-.241
UDC: 546 2_qq
1/3

L 04492-67
ACC NR: P6ol7li2
properties of the entire chemical system enclosed between $the
electrodes become manifest. Measurements were made with an Instlru-
meni ot the Pungor system. The capacity of the titrimeter---t-Oi(ither-
.with the mixer motor was 48 watts; the working frequency was up-
,wards of 100 megacycles. The experimental condit-ions were as
follows: 10 ml of 1-10-2
I X GeO2 solution was poured Into a cell,
and then solutions of pyrocateehin or pyrosallol were added until
~ditferent ratios of germanium to polyphenol concentration were
attained, from 1:1 to 1:200. The volume in the beaker was brought
tb 70 ml in order that the level of the solution would be above
the upper edge of the electrode. This was necessary to eliminate
the effect of variation in solution volume on microammeter read-
ings. The resulting mixtures were titrated with 0.1 N NaOH solu-
tion. Another series of experiments were conducted In parallel,
using the potentiometric titration of germanium compounds with
polyphenols, employing a glass electrode. Measurement of solution'
solution PH values were made on the LP-58 pH-meter, calibrated
,,wit4respect to a saturated solution of Potassium carbonate with
PH = 3.59
As a result of the titration using sodium hydroxide, curves were
tobtained which had.sharp points of Inflection. Beginning with a