SCIENTIFIC ABSTRACT TEREKHOVA, G.M. - TERPILOWSKI, J.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001755420009-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 16, 2001
• Sequence Number: 9
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

MIKHAYLOV, N.V.; STRAS1910VA, T.T.; TERMOVA, G.M.
Method of determining phosphorus in polymers and fibers
based on them. Khim. volok. no.4;66-67 163.
(MIRA 16%8)
1. Veesoy-uznyy nauchno-issledavatellrikiy institut iskuset-
vennogo volokna.

TERPIM, N.I.; AI;GOtSXi.YA, M.A., direlctor.
Hicrosco,'pic stiidy of the dynamics of extraction of alkaloids from the
tiaeues of the belladonne~ plttrt. AT)t.delo no*4.-27-)O JI-Ag 13).
(MLPA
1. Kharlkovekiy nauchno-ionledovatellokiy khimiko-farmutse7ticheskiy ilisti-
tut. (Belladonaa)

TERPIW. 11. 1.
Problem of improving of the processes for extracting medicinal vegetable
rav material. Med.prom. no.2:32-35 Ap-Je 155. (HLRA 9:12)
1, Khortkovskiy nauchno-inaledovatel#ekiy khImiko-farmatsevtIchaskiy
instituts
(BILLLDONU,
extraction of alkaloids)

TXRPILO, 11.i,
Microscopic examination of pruning material from the tea bush.
Apt.delo 6 no.6:26-28 N-b 157- (MERA 10:12)
1, Is Xharikovskogo nouchno-iealedovatellskogo khimiko-farmateevti-
cheskogo institute,
(TEA--ANALYSIS) (GAYYXINS)

TROPP, M.Ya.; TER 11
Purple hellebore. Apt.dalo 7 no.2:60-65 Mr-Ap 158. (MIRA 11:4)
1. Is Khar1kovskogo nauchno-issledovntellskogo khimiko-farmntsevticheakogo
instituta.
(HELLEBORE)

TIRPMO N PROKOPSIMOO A.P.
M M
A~,
Oaltivated carrot ([Daucus ustivus (Raffm.) stoch]) Ig & now
medicinal raw material. Apt.delo 9 U0.1885-91 4-7 160.
(MIRA 13:6)
1. Is KharIkovskogo nattobno-Iseledovatel'skogo lchimiko-farma-
tsevticheekogo instituta.
(CAnM-THMUjPZM IG USA)

TERFILOt N.I.
Microscopic analysis of raw Anabissis in the process of extraction.
Med. prm. 14 no.7:47-50 Je 160. (MIPA 1338)
1. KhArIkovskiy nauohno-issledavatellskiy khimiko-farmatoevtiaheakiy
inotitut.
(AIMMIS)

TERPILO, 4astaslya Ivanog~a kand. biolog. nauk; VISYULINA, Ye.D.,
- -p-CHU-M PAK$ V.D., tekhn. red.
(Anatomic atlas of medicinal plants] AnatomicheBkp- atlas le-
karstvenrjykh rastenii. 2.., perer. i dop. izd. Kievp Gos. mod.
izd-vo USSR, 1961. 361 PO 041RA 15:3)
(BOTANY, MEDICAL)

TIR-PIIO. R.N., inzh.
Rationalization of electric lighting of farms. Svetotekhnflm 5
no.2:24-26 F 159. (KIRA 12:1)
I.Ukrainskly institut makhanizateii i alaktrifikataii sellskogo
khozyaystva.
(Electricity in agriculture)

TERPIL09 N. N.v CAND TECH SO It "4-*#zlrr"" AIND D
VELOPMENT OF A RATIONAL SYSTEM OF ELECTRICAL I:-fQ"4)W -FOi
CATTLE FARMS,#$ Moscowt 196 (JOINT SCI COUNCIL OF I"
ME0J4AtlIZATIO" OF AoRICULTURE
L- N')ON SCI RES lH4T
11VIM11 ELtCTRIFICATION OF AGRICULTURE "VIESKii"),
(KLI 3-61t 220).
270

L 45182-66 Ili)
ACC NR~ APG026460 SOURCE, PO/0038/66/011/002/0163/0176
AUTHOR Terpilowski, Janusz-Terpilov6hi, Ya.
ORG: Depar,nient ofPhysicochewical St,vucLu.-,,al He8carch, PAN Wroclav"
sti-uktui-*'a-'In--y*cfi--kANY----
TITLE: hermody amic properties of liquid metal solutions. The Zn-In-Cd
and In-Cd systems
SOURCE: Archiwuin hutnictwa, v. 11, no. 2, 1966, 163-176
TOPIC TAGS: EN11F, zinc indium cadmium system, indium cadmium system,
liquid solution, liquid slystem, thermodynamic potential
ABSTRACT: Thermodynamic investigations of Zn-In-Cd liquid solutions and
indirectly of In--Cd liquid solutions ~vere carried out by the method of measuring
the electromotive forcus of concentration cells of the following type:
(O'bil LICA + 0,42 Xuj + 0;0~' 7.10A, Zn-In-Cd
rneltell Wt-- liquid %oluUon
Card 1/3

L 45182-66
ACC N" AP6026460
The subject of investigations were 15 liquid solutions of Zn-In-Cd In the temperA~
ture range 430 to 580C. In the reproducible limits of the readings, the values of.~'J
EMF in cells varied linearly with temperature. The compositions of the investi- % r.- 14
gated solutions were expressed as atomic fractions of zinc (Nl), indiurn (N2), and..
cadmium (Nd. The EMF of the cells at 500C as (E500) and their temperature
coefficients (dE/dT) are given in a *table in the original article. The values for
the integrals of equations were determined. The results of the excess molar
thermodynamic functions of mixing for the three-component liquid system
Zn-In-Cd and for the binary one of In-Cd are presented. The author stated that
the activity of zinc in liquid solutions of Zn-In, Zn-Cd, and Zn-In-Cd at
500C has a positive deviation from the Raoult law. The values of the activity
coefficients for zinc are highest for the Zn-In liquid system, intermediate for the
Zn-In-Cd liquid system, and lowest for the Zn-Cd liquid system. The
Zn-In-Cd, Zn-In, Zn-Cd, and In-Cd liquid systems are characterized by
positive values of excess molar thermodynamical potentials and enthalpies7of
mixing for any one concentration of the components. The values of excess Imolar
entropies of mixing are equal -to zero for three-component Zn-In-Cd liquid
solutions with low indium concentration and for binary Zn-Cd liquid solutions. In
Card 2/3

L 45182-66
ACC-NRt AP6026460
the liquid phase of Zn-In-Cd, the maximum for '.,dG- (excess molar thermo-
dynamic potential), 'd~- (excess molar entropy), and I'Aii!- (excess
enthalpy) appears at the 'same ratio of the atom fractions of indiu'' and 'c;%Ldmium
m
N2_IN = 1. The values of molar enthalpies of mixing for the In-Cd liquid system
3 .1 1
obtained in this work and determined by the calorimetric method approach each
other (0. J. Klepa, Acta Metallurgica, 6, 1958, 233; F. E. Witting, E. Muelle.,
Z. Metallkde, 51, 1960, 226). Orig, art. has: 5 figures, 11 formulas, and
5 tables. [Based on author' a abstract] [NT)
'�~DB CODE: 07/ SUBM DATEL 31Dec64/ ORIG REF: 006/ SOV REF: 002/
OTH REF: 015/
AM
ird 3/3

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I
L i5w&-66 E4T(J)/EWT(m)/rWP't)/EW?(b) XJPW JD/JQ
ACC NR: AP6001647 SOURCE COEE: UR/0051/65/019/006/0936/0tiSS
AUTHOR: terpilovskiy, D. V.
ORG: none
TITLE: Afterglow in aqueous solution. of gadolini-.Lm salts
SOURCE: Optika I spektroskopiya, v. 19, no, 6, 1965, 936-939
TOPIC TAGS: gadolinium compotaid, fluorescence, nonradiative transition, f4tvv'edds
I I L) - r)-
ABSTRACT: The auth considers fluOres 6cte In strongly dissociated aqueous solu-
tions of radolinium%=s to determine the time of afterglow. A theoretical model
is proposed for calculating the probability of normadiative transitions. The lan-
thanonion is can-.3idered together with a hydrate stell whose vibrations are modulated
by Brownian motion. Nonradiative transitions am possible due to the interactions
between electron motion of the ion and the vibrations of the water dipoles. A formu-
la is derived fox, luminescence attenuation. Calculation gives a reciprocal for the
afterglow tim of 464.8 cps, which agrees well with the experimentally observed val-
ue of 500 cps. Satisfactory agreement was also observed in the case of temperature
.Card 1/2 UDC: 535.372

L 15oo8-66
~:ACC NR: AP6001647
1~2-
relationship; the experimental ratio of afterglow time at 200C to that at 950C was
-6.06, while the theoretical value tras 5.64. The data indicated that the prcposed
mechanism for nonradiative t 'ransitions in aqueous solutions plays an important part
.for the trivalent gadolinium ion. The author is sincerely gratefu-I to S. A. Al't-
,shuler for guiding the work and to A. M. Leushin for valuable consultation. Orfi-.-
art. has: I figure, 4 formulas.
!SUB CODE: 20/ SUBM DATE: 28Sep64/ ORIG REF: 003/ OTH fEF: 005
~Card 2/2

4T--~lpll,onsny, ]-.F., (;7.nd Tech '.ci -- (dir's) "stildy of th,~,
jp:-~rfoT-.,,,,nce in pneum--tic removnl of roprocessed ndllinj~; pe~~t .I'
;Ansk, 195~,- 15 PP (1~iii of HiL,:her -rducation USSR. Belorur~:7-i.-!n Poly-
tech Inc', i:.. I.V. Stalin) 1'10 copie:-, 109)

~,TZRPILOVSKIY, X.F.
operation of the intake section of the nozzle of a pneumatic Peat
harveg ter. Trud7 ins t. torf. AN :3SSR 8:281-297 159.
(KIRA 13:12)
(Peat-Harventing)

TIRPILOVSKIY, X.F.
Design of the nozzles of pneumatic heat harvesters. Trudr inst.
torf. AN BSSR 8:298-308 159. (HIRA 13:12)
* (Psat-Harvestir4s)

T -!,, -,. F I L ON S KUY, K,~- .
k!~-
Ronlatanco of a nozzle of a piloir.~Itic peat Yarvoa ter lurin : ,IC f lr,-,r
of air and of peat-air mixture. Trudy Inst. torf - A2, :;33., 9:13- '6
160* (Peat machinex-r) ('el,11A 1/,:2)

lato o' t'.,e ovc -i'- o a atic
9: ]_,"'7_' 1
C:1.1A
(F at !.,.ac:.i,.ir-,ryi

PIUNOVSKIY, I.I., kand. tekhn. nauk; ZHIVOTKO, B.I.,, kand. tekhn.
nauk; RUKTESHEL', S.V.., kand. tekhn. nauk; SHTOMPEL',
B.N., kand. tekhn. nauk; BUTVILOVSKIY, F.A.p lnzh.;
KORZIEMSKAYA, R.A.9 inzh.; LDGVINOVICH, I.P.j, inzh.;
UTEVSKkYA, L.I.p kand. tekhn. nauk; RUNTSO, A.A.j kand.
tekhn. nauk; NAGORSKIY, I.S.p kand. tekh-n. nauk;
TERPI;p , 4j.. kand. tekhn. nauk; LOSEV, V.I., kand.
tekhn. nauk; YAROSHEVICH, A.A.p kand. tekhn. nauk;
KATSYGINj V.V., kand. tekhn.nauk,, red.; BOROVNIKOVA, R., red.
(Problems of the technology of mechanized agricultural produc-
tion] Voprosy tekhnologii mekhanizirovannogo sel'skokhoziai-
stvennogo proizvodstva. Minsk,, Izd-vo "Urozhai." Pt.2. 1964.
336 p. (MIRA 17:7)
1. TSentrallrqy nauchno-issledovatellskiy institut mekhani-
zatsii i elektrifikataii sellskogo khozyaystva nechernozemnoy
zorq So.SSR.

KUZNETSOV-FETISOV,,-L.I.; TMILOVSKIY, N.1r,
laborator7 ultrasonic unit for physicochemical Investigantion-s.
WTI no.17:63-68 152 [Publ. '531.
(Ultrasonic testing)

"

111.1%; L.I.
M.:m-ea in proj,ir'lioc j--' i'rill!nr, rud"s subject,~,-' to ullrnsonic
W.Wfs. Trur!-7 MKI-M no.18:100-106 153 ~publ. 154.1. 12:11)
(Oil well drilling fluids)
(Ultrasonic wov3s-InCustrial a,)Plicatlons)

A, P. P
A,
1926 Stud f jlcctrg=sl&lliWQv of mel4ld in on All.
U$ irkand
li Tui 'I il,Inil , I no.
P-%1111198,
Mechanism of the cff~ct of ultrasonic vibratiatu on clec-
trodtposition was studied. Diagr2ms, graphs. 4 ref,

~,
.7~:-
. ".- z~,, A'M

0
A
z'i
I fox
Paz'
A 91111 f
C 1 6
14 IN, Ita
d d

SOV/1 ,,6-'~6-4-43/49
AUTHORS: Kochergin, S. M., Terp,'.Iovskiy, 11. lie, Vyase1e-,rr,, G.
TITLE: The Influence Exerted by the Ultrasonic Field on the Gas
Content During the Eleotrnlysis (Vliyaniyo ulltrazv-akovogo
polya na gazonapolneniye pri elektrol~ze)
PERIODICAL: NauchDyye doklady vyssh-ay ahkoly. Khimiya i khimicheqkaya
tekhn-~Icgiya, 1958, Nr 4, PP 77c,-7161 (USSR)
ABSTRACT: Experimental data were givan the influence exerted I-,y
ultrascnic vib7atilor.3 on the gag ccntent during the electrolysis
and NaCl as wel'. as NaCH in order to obta`n H
)f H 23o4 2 02
and Cl 2* The electrolyaia indicated in tablq 1 was carried out
by means of sperially metnlifa,~tured apparattis. Th-, nod--ficat-Jon
,.f "he eleotrolyt.? ~*esist,ancca factor in dependerze cn the
gas ocritent at the ultra2onic field was nvestigated. The
depondence of the gan ccnteTit ra t-.Ime under influence exerted
by nltrasonico (in thr,, e1tirtrolyte 'Nan i-aventiglited. A
root~vtlori uf -,%ho gtiv -.-jntint jjureuntrigt! taken
in the ultracrn-1n -field due to a cletrease, of the ohnic resistance
during the analysis. 1-.ri the of a extended electrc-
Card 112 lysis -Ln the ullv_rascni:~ field the percen-.age cj' gas content

The influence Exerted by the U-1, --'.-a-7oni ~, F--'--, -1 !",as cc'n-
the Electrolysis
beCOM83 constant. In order 'zo Gbtaf-ri hydr-ogor. and ohl,)ri-ne
by apFlicatitn of iiltras'~n-`-.,~ a ~---a-:~vtause _4 r. el-l"',~rL, P'."Ner
consumption takeF F-lace.
There ar,: 4 figu.-Li and 10 references, 8 -,47 whinh arr! Sovict.
ASSOCIATION: Kafedra khimii Kazanvikogo
kog.-. inst-it.-ata (Clrai-- of Physirp.1 C'r-k.,mit ;-.ry at '.:hr,- K~Z,~nl
SUBMITTED: may 31, 1958
Card 2/2

500)
AUTHORS: Neemelov, V. V., Maminov, 0. V., SOV/153-58-6-19/22
Lebedeva, N. M., Danyushevskaya, R. G.,
Tervi1Q-YakiY,JL-N- -
TITLE: Continuous Oxidation of Paraffin in Foam State in Apparatus
of the Rotor- and Bottom Type (Nepreryvnoye okisleniye
parafina v pennom soetoyanii v apparatakh rotornogo i
polochnogo tipa)
PERIODICAL: Izveatiya.vysshikh uchabnykh zavedeniy. Khimiya i
khimicheakaya tekhnologiya, 1956, Nr 6, PP 108-114 (USSR)
ABSTRACT: The interaction between gases and liquids is very intensive
in foam state (Refs 1,2). In the present paper the results
of the oxidation mentioned in the title with molecular oxygen
are discussed. Thie process belongs to the complex chemical
heterogeneous catalytic processes with a chain mechanism of
the reaction. The best results were obtained when the whole
initial material was transformed in well mobile foam. The
rate of process depends on the height of the foam in the
oxidation column. However, completely satisfactory outputs
of the foam apparatus can only be obtained in the case of a
Card 1/4 continuous process. The authors investigated two methods

Continuous Oxidation of Paraffin in Foam State SOV/153-58-6-19/22
in Apparatus of the Rotor- and Bottom Type
of foam production from paraffin: 1) use of the centrifugal
force in a rotor apparatus; 2) exploitation of the kinetic
energy of the gaseous reagent, i.e. air which is blown
through a perforated bottom and forms a support in order to
maintain the foam on the bottom. The extended laboratories
in the Kazan' neftemaslozavod (Kazan, Petroleum and Oil
Rofinery) were used for the experiment. B. Ya. Konovalov,
Director, and A. S. Moi9eyeva, Head Engineer, collaborated in
the experiment; A. A. Aleksandrovskiy, Assistant of the
Kazan' Institute of Chemical Technology imeni S. 14. Kirov,
M. S. Khaykin, V. V. Levandovskiy, A. V. Matuzova and
V. P. Solov1yeva, assistant chemists, collaborated in the
experimental part. A rotor apparatus worked out by V. S.
Nikolayev, Docent of the Kazan' Institute of Chemical
Technology imeni S. M. Kirov (Fig 1) served for the experi-
ments; paraffin of Groznyy, Drogobych, and Novolmybyshevsk
was used as material. Potassium permanganate and soda were
used as catalysts. The following conclusions were drawn:
1) the following facts are very important: a) The oxidation
Card 2/4 is imperfect if the paraffin is kept longer than 100 seconds

Continuops Oxidation of Paraffin in Poam State 807/153-58-6-19/22
in Apparatus of the Rotor- and Bottom Type
in the apparatus b) The initial temperature of the process
is below 140 , o The variation of the air consumption does
not influence the time during which the paraffin is in the
apparatus. Two processes take place at the same time:
oxidation and distillation. e) An intensive resin- and mud
formation takes place at temperatures above 150 . f) The
optimum paraffin consumption amounts to 10-20 I/hour. g) The
maximum rate of oxidation is reached at 740 rpm. However, a
transparent model shows that an intensive foam formation
takes place only at certain places of the apparatus. The
time t4e paraffin remains in,the apparatus must be at least
five times longer in order to obtain a better oxidation
intensity. This would increase and complicate its structure.
Howev rp the rate of oxidation in foam oxidation apparatus
(Fig ;) with bottoms in after the increase of the acid numbers
B-12 times and after the increase of aliphatic acids (Table 1)
20 times higher than in periodically working apparatus of the
bubbling type. The capacity is 2-3-5 times higher. The
oxidation proceeds mainly under the formation of carboxylic
Card 3/4 acids. Higher temperatures did not deteriorate the quality

Continuouc Oxidation of Paraffin in Foam State SOV/153-56-6-101/2?
in Apparatus of the Rotor- and Bottom Type
of the products, Thus the oxidation may be intensified,.
Rotor apparatus have a lower capacity, are, however, well
nuitable for the formation processes of neutral oxygen-cortain-
ing products. In foam oxidation apparatus heat conditions
are easily regulated. There are 2 figures, 2 tables, and
2 Soviet references.
ASSOCIATION: Kafedra obahchey khimicheskoy tekhnologii, Kazanskiy
khimiko-tekhnologicheakiy institut imeni S. M. Kirova (Chair
of General Chemical Technology, Kazan' Institute of Chemical
Technology imeni S. M. Kirov)
SUBMITTED: November 10, 1957
Card 4/4

50 1 3) 5
AUTHORS: Maoino,,, 0. V., V. V.,
Lebedeva, N. M., Danyu9hovskaya, R. G.
TITLE: Scme Characteristic Features of the 1~ydrodynamics of the Foam
Layer of the Paraffin - Air System (Nekotoryye osobennosti
gidrodinamiki pennof;o sl9ya sistemy parafin-vczdukh)
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Khimiya i khimicheskay
tekhnologiya, 1958!'Nr 5, PP 149-153 (USSR)
ABSTROT: Paraffin oxidation is an exothermal process. The atmospherics
oxygen is absorbed by paraffin by entering certain chemical
reactions with the latter. In this case the mass exchange bet-6-~---
air and paraffin depends to a high degree upon the hydrodyna--ic
working conditions of the apparatus. The mass exchange is to 4
high degree influenced by the degree of turbidity of the gas
and liquid flow (Ref 1). Under certain conditions of the motiez.
in the turbulent range the gas becomes a disperse medium
distributing within the liquid phase. The contact surface is
enlarged and is rapidly renewed. These hydrodynamic conditions
cannot be produced in the usual bubbling columns with periodi.:-
Card 1/4 drive. The capacity of such columns is extremely insufficient.

SOV/153-58-5-25/28
Scme Characterist_~c Pea-ures of the E1ydrcdyna=.1cs of the Foa= Layer of "he
Paraffin Air System
In the foam apparatus as devised by Pozin and his collaborators
(Ref 2) there are, however, very favorable conditions. To u--.---
this apparatus for paraffin oxidation Leveral constructional
modifications were necessary, like, installation of electrica.
heating, cooling coils etc. Experiments have shown that paraf-
fin can be oxidized continuously in a foam layer. The rate of
oxilation increases thereby by the 8-12 fold, since high
lurz)idity is attained. Table 1 (p 151) shows the influence
exerted by different air velocities and different types of raw
materials ipon the foam formation and the degree of oxidation
as well as the losses of paraffin. The oxidation was carried
oiit for 15 minutas at 1600 and in the presence of manganese
dioxide as catalyst. The results tend to show a dependence
between the foam formation and the efficiency of the oxidation
process. The m--re of the liquid is transformed into foam, and
thE "higher the foam layer is the more perfect the oxidation
pxccess takes place. Pure paraffin without additions is very
difficult to transform into foam at temperatures up to 1600,
even at higher air velocities. Above 1700 this takes place
Card 214 O_a1S-_e::, but then again the ouality of the oxidation products

SC;V11
Some Characteristic Features of the Hydrodynamics ol zhp 7c~=
Paraffin Air System
suffers. The addition of regained paraffin or of 2-5% oxidized
paraffin increases the foam formation rapidly. Then the surfac:e
active substances (alcohols) contair,ed therein play a positljv,!~
rolo. High air velocities (higher than 0.2 m/sec.) are un-
favorable for the transformation of the whole paraffin into
foam. The intensity of the oxidation is decreased, a heat 'supp-,
becomes necessary, and finally reaction products are carried
along by air and are removed. The air velocity of Oel mlsec~
optimal. A system in which the catalyst is distributed in the
form of colloidal particles favors the foam formation. Perfo-
rated bottoms with openings of 1-2 mm covering 80-906 of the
total surface are good for the foam formation. There are
I table and 3 Soviet references.
ASSOCIATION: Kazanskiy khimiko-tekhnologicheskiy institut, Kafedra obshchey
kh-imichaskoy tekhnologii (Kazan' Chemo-Technological Institute,
Chair of General Chemical Technology)
Card 3/4

F- kp I V -S K
NESMILOV, T*T,- TIIRPIIoOV�-KUA-",-..KAMINOV, O,T~; LUBEDAYA, N.M,;
DOVihFXWT~A, R.G.
Continuoun oxidation of foaming paraffins by mnlacular oxygen,
Kh1h. naulm i prom. 3 no.1:130 '58. (MM lily)
1, KAzanskly khimiko-tekhnologicheekly institut im. S.M. Kirova.
(Paraffins) (Oxidation)

Ai,
-3 r N
NESMZLOV. V.V/., kand. takhnonauk; IPMZVA. U.K., kand. khin. nmuk:
- G.;~ Itand. tokbn. noult;
MAMINOTj O.T., kond. tekhn. neuk
Continuous oxidation of paraffin in a foamy state. Kael.-zhir. prom.
24 no. 6:20-26 158. (HIIU 11:7)
1. Xavanoldy khimiko-takhnologicbemkiy inatitut Iment, S.M.Kirove.
(paraffins)

MSMELOVO V.V.; WXWOV, O.V.; TERPILOVSKIY, N.N.: ISMUZVA, N.M.;
DAWMHU,-,KAYA, R.G.
Problem of foam formation during the oxidation of paraffin in
bubble coluaw and in a continuous fosm oxidizer. Trudy URTI
no.26:15-18 059. (MIRA 15:5)
(Paraffina) (Wdation)

MSMELOV, V-V-- TEUIWVSKIYI N.N.; LEBEDEVA.. N.M.j DANYILHEVSKAYA, R.G.;
0
MOUNOV.9 -0-.v.-
Study of tho oxidation of Novo-Ufiwk paraffin in the foaming
state in the presence of manganese dioxide. Trudy KKHTI no.26:
19-22 159. (MBA 15 -.5)
(Paraffins) (Oxidation)

NZSlf2WV, V.V., lmrtd.takbn.nauk,- IJBIDIVA, N.M., kand.tnkhn.nauk;
TWIIDVSKrT, N.N., kand.tekhn.rALuk; KAXINDY, O.T., kand.tekhn.
nauk; XUCIV7' kand tekhn.muk; DAMSHITSKATA, R.G.
Oxidation or paraffins in a foaming state, Kael.-shirsprou.
26 no.1:13-18 JA~ 160. (KM 13:4)
1. Kazanskiy khimiko-tekhnologicheskiy Institut imeni S.M.
Kirov&.
(Paraffins) (Oxidation)

BESMELOVI V.V.; RUIINOV, O.V.; TMPILOVSKIY, N.N.; LEWDEXAI N.M.
Alteration of certain physical properties of paraffin in the
process of its oxidation in the foamed condition. Izv. vys.
ucheb. zav.; Ithim. i khim. tekh- 4 no. 2:283-286 161. (MIRP, 14:5)
1. Kazanskiy lldmiko-tekhnologicheskiy institut im. S.M. Kirova.
Kafedra obshchey khimicheskoy tekhnologii.
(Paraffins) (Oxidation)

KOCHERGIN, S.M.j. TERPILOVSKIYp_~~,.j~.; VYASELEVA, G.Ya. (Kazan$)
- I
AAadic dissolution of copper in an ultrasonic field. Zhur.-fiz,
khim. 35 no. 4:917-919 Ap 161, (MIRA 14:5)
le Kazanskiy khimiko-tekhnologicheskiy institut im. S.M. Kirovao
kafedra, fizicheskoy i, kolloidnoy khimii.
(Copper) (Ultrasonic waves)

BURMISTROVA, T.P.; TERPILOVSKIY, N.N.; NESMALOVp V.V.
Influence of certain factors on froth-forming process during the
oxidation of p-xylene. Trudy KKHTI no.30t289-295 162. (MIRA 16slO)

L 413;i9-661) E'.',T(n)/EP--(c)/T Pr-4 DJ
AP3000501 8/0065/63/000/005/0018/0022
AUMOR: Sedachij,_Y~. M., .11comeloy, V. V.; Moyseyeva, A. S.; Lebedav ap W. M.;
-Kuznetx4ti~tL.'1-.-M.; -;~atypo R.-*S1j-.j-1Tjrj~j lava kir, H. N. f
'TITIF,l Oxidation of paraffin In the foam state
SOURCE: Kh1miya i takhmologlys. topliv i maselt nov 5. 196% 18-22
TOPIC TAGS: oynthetic lubrican continuous oxidation, bubble column, paraffin
traction, paraffin oxidation
ABSTRACT: The Kazan' Synthetic Lubricant Plant in cooperation with the Kazan'
Xnztitute of -Cfievd&!'Tcchnologj, has developed a nw process for oxidizin-g &f6iV-
fo,amed par affin up.t6-carboxylic acids. This continuous process van adopted on a
pilot-plant scale in 1961. The new continuous foam process increases the yield
up to 270$ as compared vith the previous; process. The author gives the processing
i data and diagrams of equiymant used, as vell, as a breakdowa of the p"*aff in fracw
tions and their specifications. The lossic operating parameters am: tempersture,
i125 130*Cj air consumption, 1 a-'O/kg of o3ddized paraffin; a,aid number of oxidAta,
150 60 ag oC ME. In order to obtain good air dispersion, the use of screm In
I Card 1/2

L 41352-65
ACCESSIOI( IM: AP30M501
the bubble COIU= is roc=wnW. The final product met& the r*quirwent, placed
M synthetic yetrole%u yrodwtg. Orig. art. hu I tablas and 2 diagram
.ASSOCXATXOgt
;SUBM=Ml 00% MOM 00 BUS 0=1 00, Is
;no MW Sov 000 OTM: 000
COrd 2/2

lia Bodies
L Con,jersiOn '11 So
of Solids pbsse
piziksy No 2.4 195Bt NO 3484
Abs JOUr Ee-f ZLIar
I
or
last
Title
-za
amwwski ja ,nusz teristica Of Ag
Ural Cbarac
Not Give" and. Struct No li, 3-40
T~aer~od~ cl.2 19561
politeabn- wro
orig pub
P,bstract
W&
UMIX.
Ono of 59
Z01' * jnve5tI-6&t' LC Percent
,ts electrochemical 8? 4 stomJ tion
rom 28.4 to .
,,~tli 0, compos,
,uthor reVO 4n9 f tious %fare
M_,Ln ranf alloys -A-a-ZU tiga
so alloys ACI The inveg re-
an& of fl-le liqent Of zinc. temperature
Of zinc) tomic perc Bf 0 of bigh ,
10.8 83-01aUremelat Of the e1 on the basis Of the
meals (liquid-) tYVe * (a) partial
base& On the za calculated.* -potential'
elis of t1le ,owing vere nic alloys
versible c the f0 ftermody"I solid
dat86 obtai'16 he isobaric U ad Zinc
.solution Of Zinc A.
LatiOns Of t f di aissolution of liq ti-jer-
molar v&e- and. entlla'-Py O.Proresa Of I the Isoberic Ol:LCI
eUtrOWY 'I also of tle ~ entbalryp tion of s
Ag.zxly an -za alloys. (b) 'Mt py Of forma (C) PCtivity
Ag and the entrol -
liqad nt 06t
Modynamic Potentials compone 6
Ag-ZA alloys from 601a
1/2
POZ
C!a of 8021 da,
Abe
p
Ottr Rer z,4,
- hase COn','e
PI In
and coeffl., no -" -1958, aoltd Bodt
ajuovs at en t Of P1O 31484
Cheelcea 00C. acttvjt,~, 6
-PeITO., -roz the t 21,e of C
Ag_,, ed. Xt ejVe is omponen
rat, Q~e~ te
4tur, 'a-1`8tew h cottfl., aat ., of the sol't d
ayste a , 2he 4 Ve a Ag.Zn Ag-Za
ent 0 Is CU. ed tht th ch the
dl krobJer4 01"dered ,t., e g and expe Sire t. Vas
"R~ of Sc4a8ed Of Ozde,,l Ctur Zjz*nts "2'e
rozzaa .0a -Phases Of the
ti tartin ng Of e at hI
9 Wit
on of soi fh t a Ph,, ghe-r te
d al., Z
'Y8 e caa e of t 4
,h Pe,
f.po. cUa t, e Ag_,,
soil 0
. d -~ Of th-

POLA14D / Physical Chemistry@ Thermodynamics. Thermochem- B
istrys Physico-Chemioal Analysis* Phase Transition,
Abs Jour: Ref Zhur-Khimiya, No 110 19561 35384
Abstract: following has been determined: 1) the phases P12
Au-Cd,% a Ag-11.1g; Cu-Zn and Y Ag-Cd belong to the
Daltonoid gro'T ;.2) the phases J'Au-Cd; ?3f#.80Z
Cu-Zn; A I P j V Ag-Cd; r.. r~, Bi-Tl; f9 Pb-Tl;
J%Z Ag-Zn belong to the Bertholoid group6 The
Bertholoids have a disordered structure; the vari-
ations of AG, AS and -Z-H within the limits of
these rhagoo are insignificant and gradual. On
the other handp the Daltonoids offer a low degree
of irregularityy the variations of Z-G,, AS and
ZH_ within their limits are considerable and occur
intermittently, forming an inflection point in the
vicinity of the Stoichlometric compositions See
also R Zh-Khimp 1956) 77515; 1957, 50724
Card 2/2
9

rhermodynande Properties of Liquid Metallic 891011.1"&

1
A'
"
W

--
WW'
-the Ht in
4
Th
R
,WlasnoAct termodynaaritcane eteklych ;941wor6w metall. It Wad
bmn-. i~~twurn- Htea*twa (P"), No. 3, Wrrszawa, 1058. pp.
227-237, 4 figs., 5 Wx
In 4his work the H~-In sysWt tA hiAherto unknown thermodyna-
tnicat pt(Vertlvs was Investloted b:r the qo4cd of rneasnrW t4ectro-
motive forces. Dming these Investigatlo", 'ij?,wevsible elenx.nts of the
following type were applied: Injjq. j(0.0 I~ft + 0.4 KBr) + 0.1 InDri
131~ In
Tests were carried out w*, 11 alloys of 5 to 95
ptarrit 4A of Indiurn In the range of 380 lo~W*C. The rtsuits of menum-
ments of the elfvirernrAlve fOr"s In these tYPW Of elments w"e dl-
rectly, recalculated On changes Of Partt&t MOkr therf"dYnarnical va-
lim for indium: POtentkd (WA01.), entmPY (&SW and
.
enthelpy (Alfin) at 00T. sod activities (aiz~ and the coefficient of acti.
vity (fln) for Indhvn In alloys at 430* sod 500T. lAter as in a prevkms
work of thia serfee, the wathor ca)mdAed the cbanges of p*rtJ*l molat
thermodynamical =4ues for hismuth: thermodynam" Potential
(kill), m&*Iv (ASoi) and enthr*y (AH91) at 400'C. and the activitles
(a,j) and the ac*vity voeftkiaAs if 9j) for bismuth in atloyi at 00* and
W*C. The chenges *1 the fcflo*kV tbermodynamiM t-notions %vr*
also calculated: thermodynamical potential (AO), onAropy (AEO and en-'

y (AH) during mfxft of txze liquld,tottals 4nto liquid allnry~ at
i
mp

14000C. The results of measurements and calculailorn are given In ta-
~blm mid presented In, diagrams. The liquid wyotan BI-In Is chsTamcierl-'
~zed by a negative dellmCon from. the Raoult's law, decreasing with in-
s of the efr(halpy uhanges are negaliWe
gmaing temperaUne. The valuie
for the teffwrrAuye 400'C in 4he WWe -60MPOSIHOrk TaMe, and they
attain - 504 cal for the alloy BlO.sTnq.$. The liquid soMfons B14n be-
_NSgj and AS In rela,
hafe as m. i-regular, because Abe courne Of 'NSiA,
tion to the canporttion may be expres" by equatsons.

T& K 7
Distri We
7.
'off P-!phx
qk!~~%e of the s I
7F Wriviam., Ckm
No. 4. SLInintary).-E.m.G., S, of cells
Nlg(~,lid)jL'Cl + KCI tutectic mixt. + JdgCl!jAg-?ilU~
(v4id allay) %Ytrc nic-asurcd (cf. T CA St 1-73-d&) at
Im , i ,
!"(X) -611P. i-lic solid 11"Iny compil If at. 5,C), E at 6W0
(mv.), teirip. c(~eff. dEldT (;iv./d;Cree) were found: 42.0,
205.1, -25; 44.0. 19-1.0. -28; 45.5. 197.9, -30; 47.0,
18,1 Z. 1, -27; 41S.1. 184,5, -21; 49.3, 17,0.9, -6; 50.5,
167-9. +7; M.3, 145.7. +20; A1.7, M53, +.W; MA.
159 S, +32; 54.2, 152.0, +40; 56.7. 144,0, +37; 57A,,
143.6, +3G; 61 1 134A and +33, resp. The partial
'Itiolar heats, colt 11~t.a
.~d_thC1v3odYn=lc potentials of
crit-resixmiding to villoy GyrurAtion front solid components.
Uctivity and activity cot1s., ate caliA. directly. Equa,
C tion.1 fit Wagner and S--twt1ky (C.A. 25, 1131) fitted Iliq
C, curm (if E uml dEldr vs. compn,, if a suitable dcgree (if
,it disotda, (0,03)o was assumed. Thus P-p'rA&c ut Ag-his; qys~
UAu is almost completely ordered. 6teckj_
Aj

Distri: E2 c IV
f and degree of order of the 0-
Thsrm_z;~
bA" systege'l fallml '17C " I I
ph"a 01z" &
110 1 ro(law,
WrMIM 6
--tv-07 I
o. 4, 13-23(1958)(Ungl6j, .nnninary); cf. preceding
abstr.-E.M.fs, E, uf cell 44111 Lict + KCI Cultectic Illixt.
AuAI 1 4 "W3, for
_14 erc nicasure at 4 -5Z
+ZnCl
") jruilta
it R I lit 3W -119" for tile wild one.
Ilquid ZEnE c
_EEKIE!NjP
The following alloy compit. (Zn at VI) R at 500* (mv.),
v'T w~rc found, resp.:
and temp. cotff. dEldl' (,uv.ldcg; e
43.8, 239.3, -96; 45.1, -08; 45-5. 10-113, -90;
40.8. 220.1, -7102; 47.5, 225.4. - 103; 48.7. 218.3, - 100;
49.0, 211.3, -117; 5U.1, 203.3, -1:315; 50.2, 2014, - MIA;
60.8, 103.4. -135; 50.9, 193.2, -136; 51.2. 187.9,
-140; 52.3, 177.7, -146; 52.0, 17-1.9, -147; M.0,
168.0, -148; 54.0, 160.2 -149; '54-8, V18-7, -1 '10; 64.9,
157.8. -150. The tent:; . coeff. dEjdT tot s,,Iid Z11 clCC-
.2, and
trode, was -48, -91, und -05, f-,r -17.5, 51. , /V
Zn alloys. Tile caled. lieut -if hv;ion of Zn 6 1.79 kcal /g.
atom, in agreement with blander (C.A. 27, 4175). The
partW, snolar heali, untroijiff-and thermodynamic poteii.
tials of Zu crrru5lion(M,:i_g to transfer of liquid U tio ~,Iid
alloy,wer~ccalcd.dirtxtly.
differed from th.,;c calcil. theoretically after Olandcr ( C,J.
27, 4473) fur cithcr %litchily ~r completely dii,)rdvrC,l phaw'.
Probably the Rupp-Ncumillin rule ii invalid too, X-ray
diagrams f(,r th(: idbly contg. 50.1 at. % Zn, -is %VC11 its tile
rhangrs of Oval-Ayllmllic flim"tiolli with c(IIIII)II, illdicate
that tile zu- kit ;?-jjh:t,C i-i 11"t a typical "I'lltouide. Con-
biderable dii-micring 6-gin, at maiit; 40". Stecki

POLAND / Physical Chemistry. Thermodynamics. Thermo- B
chemistry Equilibria, Physico-Chomical An-
alysis. Phase Transitions*
Abs Jour: Ref Zhur-Khimiya, No 24, 1958, 80625.
Author Trzebiatowski, W.
Inst :Not given.
Title :Thermodynamic Characteristics of Intermotallic
Phases of the Daltonian and Berthelotian Types.
Orig Pub: Arch. hutn., 1958, 3, No 2, 97-112.
Abstract: Previously published data (Celader A., Z.
phys. Chem., 1933, A 163, 107; A 164, 428;
1934, A 168, 274; A 169s 260) pertaining
to electrochemical measurements for the de-
termination of partial molal thermodynamic
constants (such as the thermodynamic potential
G, enthropy S, enthalp~r,y H) of the
Card 1/3 14

POLAND / Physical Chemistry. Thermodynamics. Thermo- B
chemistry Equilibria, Physico-Chemical An-
alysis, Phase Transitions.
Abs Jour: Ref Zhur-Khimiya, No 24, 1958, 80625.
Abstract: less noble components of intermediate Ihases
of the Ag-Cd, Au-Cd, Cu-Zn, Bi-T1 and M-Tl
systems were utilized. Results of previous
investigations (Ref. Zhur-Khimiya, 1959, 44009,
-90924) indicate that,the order.--of determined
values of . G, ~~ :.:. S and H, in the lim-
Its of existence of .- - an .-phases of the
AujoCd system, and also of -phase of the Ag-Cd
and Cu-Zn systems, are characteristic with Dal-
tonian type of phases. Whereas the order of
determined values of the sAme properties in the
remaining phases, ie.,/ . -" - and - 'of the Ag-
Cd system; of the Au.-Cd system;,., and e:
Card 2/3

POLAND / Physical Chemistry. Thermodynamics. Thermo- B
chemistry Equilibria. Physico-Chemical An-
alysis. Phase Transitions.
Abs Jour: Ruf Zhur-Khimiya, No 24, 80625.
Abstract: of the Cu-Zn system;.-' and... of the Bi-T1
sy:-tem; and .'-phase of the Pb-T1 system are
charac,6~,ristic with the Berthelotian type
phases, It was established that a degree of
deviation in the stoohiometric comi')ositions
constitutes the basic criterion that deter-
mines the direction of behaviours of the in-
termetAllic phase of varying composition and
causes it to act either as Daltonian or as
Berthelotian phase.
Card 3/3 15

)e /I / j- 0 vV
PoLAUP/Ator.dc and Molecular Physics - Heat. D
Abs Jour flef Zhur Fizika, 111.3, 1959, 17632
Author Terpil3vski, Janusz
Inst Institute for Structural Research, Institute of Chemis-
try and Physics, Polish Academy of Sciences, Wroclaw,
Poland
Title Thermod-jamraic Properties :)f Liquid Metallic Solutions.
II. The System Bi-L--..
Ori(; Pub : Arch. hutn., 1958, 3, No 3, 227-237
Abstruat : It study was made of the thermdynanic properties of the
system Bi-L-i containinc; five -- 95 atomic percent of
iadium, Ln the temperature range from 3W to 5200 C,
by a method of measurinC; the emf. The partial molar
thcri:vAynanic fuzictions of indium, and bisrxith are cal-
ctLlated: the thermodyntwtic potential, the entropy aad
Ca rd 1/2

POUM/Atomic nad Molecular Physics - Heat.
Abg Jour Ref Zhur Fizika, No 8, 1959, 17632
the enthalpy at 14001 C of the activity and the coeffi-
cicat of activity for indivii and bisuuth In alloys at
400 and 5000 C. A19D calculated were the chanr'es in
t'ne therti.3dy-a-Ac poteitial, the entropy, and enthalpy
(lurint; Vhe rAxinr;.of pire liquid uetals at 4003 C.
The restilts of the meastixericAa and calculations are
reduced i% tables anid are plotted 3n curves. The liquid
system Bi-In is characterized by a ne~ptive deviation
from the Paul law, diuinishinC; with increasing termperatu-
re. The chanGes in the entropy are ne_mtive over the en-
tire re,-;ion of compositions and reach a magnitude of -594
calories for the alloy Bio-5 Ino-5- It is shown that
liquid solutions Bi-In behave like se-mi-regrular ones,
inasmuch as the changes in their entropy is comiected
with the coefficient P, which characterizes the delia-
tion from the Nehavior of re(s%Llar solutions.
Card 2/2
- 50 -

POLAND/Atomic-)and
Abs Jour
Author
Inst
Title
OriG Pub
M.)lecular Physics - Heat. D
: Ref Zhur Fizika, No 10, 1959, 22414
: TerDilowski, gqpIlsz, Prezezdziecka, Ekilia
: Academy of Metals, Wriclaw, Poland
: TheruDdynamic Properties of Liquid Solutions of Metals.
Part 111. Semi-ReGular Disiary S.:)lutions.
: Arch. hutn., 1.958, 3, No 4, 315-327
Abstract : On the basis of calculations performed in Part I
(Referat Zhur met, 1958, no lo, 2o661) and Part ii
(Referat Zhur Fizika, 1959, No 8, 17633) it is shovil
that liquid solutions Au-Dl, Bi-Cd, Bi-Sn, Cd-Pb, Cd-Sn,
In-Zn, Fb-Sb, Sn-TI, and Sn-Zn behave like seLd-reGalar
ones. The experimeatally determined values of the chan-
Le in the partial wlar entr~)py for the corrponents
ES1, E S 2) and the -.dxinG entrapy (S) in the entire
Card 1/3
- 30 -

POuU-1D/,',t;Dmic and M.-ilecular Physics - Heat. D
fibs Jour Ref Zhur Fizika, No 10, 1959, 22414
reCion of the solution concentration can be expressed
by means if the followinC eq-,,,ations:
zS1 =-Dij In 111; 6-b 2 = -DR In N 2 S A R
(IT, III IT, -I- IT la IT
Where D is a c5effictent that expresses the deviation of
the solution fron ret;ularity (11 and 11, are the concen-
trations of the first and seconi compoilent in the sblu-
tion). Numerical vaiiies are obtained for the coeffi-
cieat D and are tabulated. If one considers the solu-
tion Sn Zn, Cd Pb, AC; Pb as serA-rerular, one ob-
tain3 a better aGreement between the experiTzental and
calculated data, then in the case of assLwain(; these solu-
tions to be reGular. It is shiwn that the local orderiLt;
Lifluen-ces irsit,;iificantly the value if the cL)efficient
D in semi-regular soL-tioas. As can be seen frori the
results obtained, there exiets a connection between the
chanGes in the volume durinrg mixinL and the values Df
Card 2/3

-.- -- . - -POLAND/I~t~~mlicand Molecular Physics - Heat. D
Abs J:)ur : Ref Mur Fizika, ND 10, 1959, 22414
the coefficieiit Di. Althoud, this dependence is not
proportioual one can nevertheless say that chanCes in the
volume play a substantial role in the chanCvs of the
coefficient D.
Card 3/3
- 31 -

POLAND Chemical TechnoloFy. Che..jical Products and H
Their Application. Synthetic and Natural
,~,,Iedicinal Substances. Galenical Proparations
and Mediqinal Forms.
Abs Jourz Ref Zhur-Khimiya, No 9, 1959, 32435.
Author : Terpilowski.-J., Saiyt, K.
Inst %Not,given.
Title An Ap-.)lication of Ionic Substitutes in the
Analysis of Pharmaceutical Preparations.
Orig Pub: Farmac. polska, 1958, 14, No 13, 196-200.
Abstract: A review. Bibliography of 70 titlos.
Card 1/1

COUNTRY Poland
CATEGORY
AD-i. JOUP. 371'hiia., ~.'o. 16 1191591
. k 4,1. -100 560~1
J. and Q:Znyt,
TITLS The Chelatometric Determination of Magnesium in
Certain Prescriptions
OR IG -PUB. Acto Polon Fharmac, 15, .-o 4, 285-292 (1958)
A B r RA ~;T A i3imple, rapid, aad act.,urate chelatorne--r4c
method hac buer. developed for the determination
of Mq in .1, number of widely Veed vubscriptlkl,.Is.
Optiwum conditions for the dissolution of varioun
mixtures have been determined together willn tne
most effecient waye of removing components which
interfere with the determination; the 14tter
purpose was achieved by the use of a colvnn
packed with Amberlite IRA-400 anion exchango
resin and by the use of the hydrolycis reaction
(in trie case Bi salts).
From &athoral summary

"Order-disorder" transfn;r:nntions In -netf,11-ic
WIADR-10SCI C:-7j,'.TICZI[r-,. (Polakin Townrz,.tatwo Chemicme) Wroclnw, PoInn(I. Vr,,l. 13,
no. 1, Jan. 1959.
Monthly List of ast European ;~cccssions (FEAI) LG, Vol. 8, no. 8, August 19,10.
UNCL

- -- I - -.-, - ---- ---' --- - --- L . . , - - - ~ - ~ - I - -
r- C:p " T E_ I I L-Li -~ 5- L. . --j -
j f 1~

BILINSKA, Urszula;jERPnCWSKI, Janusz
Determination of phosphorus in certain copper alloys. Chen anal 5
no.1:17-22 160. (EW 9:11)
1. Katedra Chemii Nieorganicznej Wydzialu Farmaceutycznego Akademii
"cznej, Wroclaw.
(Phosphorus) (Copper)
'49

18.9100
AUTHORSt
TITLEt
It'jIg 11~8 104,5
2330,7~
P/03Y60/005/003/001/002
A076 Al 26
Terpilowski, Janusz, and Przez'dziecka-Mycielska, Emilia
Thermodynamic properties of liquid-metal solutions - Part VI.
The IA-Sn System
PERIODICAL: Arohiwum Hutnictwa, v- 5, no- 3, 1960, 281 - 290
TEXT: In order to investigate the thermodynamic properties of the
liquid In-Sn solutions the results Of Mes,SUrMeAtS of the electromotive
forces - emf - were applied. These forces were measured in reversible con-
centration cells of the typet
In (0.6 LiBr + 0.4 KBr) + 0.1 InBr inxBnl-x
liquid melted salts liquid
I I solution
The authors investigated 10 liquid In-Sn solutions with an In content from
5 to 90 atomic %. The design of the electrolytic cell was the same as in
the previous works of this series (Ref. 5: Terpilowski, J, "Archiwum But-
Card 113

23303
P/038/6o/005/003/001/OC12
Thermodynamic properties of liquid-metal ... A076/A126
nietwall, no. 4, 1959, P- 355). The emf of the oell were measured in a tem-
perature ran e of from 390 to 6100C and the values of the amf were deter-
mined at 4009 0 (E400), 50000 (E 00), and 6000C (E600) 98 the temperature
coefficients of.emffdE in-the aNve range of the temperatures concerned.
tdT)
Based on the results of these measurements and the Gibbs-Duhem equation the
following calculations were performeds a) activities (aln, aSn) and the
activity coefficients (fln, fSn) of the constituents, b) changes of the
partial molal thermodynamic potentials (EUI., k-GSn), ent-r-opy (A-UIn, 3ESn)
and enthalpy (A_ffIn',4ffSn) of indium and-tin, c) changes of the thermodynamic
potential (IJG), entropy (6S) and enthalpy (AH) during the mixing of pure
liquid metals into liquid solutions. It was stated that the enthalpy of
mixing shows negative values in the whole concentration range and attains -
40 cal/gramatom for liquid alloys containing from about 72 to 62 at.% of
indium. The small values of the enthalpy of mixing and the values of the
activity coefficients for indium and tin, which approach unity, prove that
the constituents influence each other very little in the temperature range
of the measurements. The 6G curve has its extremity displaced towards hien-
Card 2/3

23303
P/03 60/005/003/001/002
Thermodynamic properties of liquid-metal ... A076YA126
er concentrations of indium in the liquid solutions likewise the &H curve.
The activity isotherm for tin is distinguished by positive-negative devia-
Oz;nci -Ioroy.,i the Raoult'F, I-aw and Lliai. uf 1,Lu ac~JLviLy t,i, il'L,1111.1 "J~f
(111 J'3 ,It i.9 possible ~juch a ciurse of those LIiLnaudji1zuiic. curve.5
in relation with the appearance of the solid phase P of a variable composi-
tion in the In-Sn system. The values Of ASIn, '6SSn and AS in the tempera-
ture range of measurements are not much higher than those for regular solu-
tions. This results probably from the fact that both of these metals are
close to each other in the periodic system. There are 4 tables, 4 figures
and 20 references: 12 Soviet-bloc and 8 non-Boviet-bloo. The reference to
the most recent English-language publication-reads as follows: Kubaschewski,
0., Catterall, J, A,, Thermochemical Data of Alloys, London - New York,
1956.
ASSOCIAT10111: Katedra Chemii Nicorganicznej, Wydzial Parmaceutyczny Akademia
Medyczna, Wrockaw (Department of InorRanic Chemistry, Pharma-
(,Pi)tA(,FtI Spctinn. Medical Academy, Wroclaw) J
C-ard 5/3

. TERPILOWSKI, J.; TRZEBIATOWSKI, W.
Thermodynamic properties of indium antimnide. Bul chim PAH 8 no.3:
95-98 160. (EEAI 10-.9/10)
1. Department of Structural Research (Wroclaw), Institute of Pbysical
Chemistry, Polish Academy of Sciences. Presented by W. Trzabiatowski.
(Antimony indium alloys)

TERPILOWSKI, - AIII!-~.Zdoc.dr.
On Daltonids and Berthollides among the intermetallic phWes and
their tharmo-dynamic properties. Wiad chem 14 no-3:157-174 Mr 160.
1. Kiarownik Katedry Chemil ~Iieorganicznej, W~vdzial Farmaceutyczny,
Akademia Madyczne, Wroclaw i Zaklad Baden Strukturalnych, Instytut
Chemii Fizycznej, Polska Akademia Nauk, Wroclaw.

346e/,5
5/137/62/000/002/004/1'
AO06/A1Ol
/dp
AUTHORS: Terpilowski, Janusz; Kundys, Emil; Slaby, Henryk
TITLE: Thermodynamical properties of liquid metal solutions. VII. The
Ag-Tl system
PERIODICALi Referativnyy zhurnal, Metallurgiya, no, 2, 1962, 12, abstract 2A57
("Arch. hutn", 1961, vol. 6, no. 2, 137-146, Polish; Russian and
English summaries)
TEXT; The authors measured emf E of reversible concentration elements of
type Tl (liquid)/(0.58 LiCl + o.42 KC1) + 0.05 T1Cl (molten salt)/AgxTll-
(liquid solution)+. Investigations were made of 10 liquid solutions of Af-T)
containing 10 95 at. % Tl. The investigation method was described previously
~MhMet, ig6o, no. 9, 19484) . E values were determined for 950, 1,050 and 1, 15o
K. The emf-of all elements varied linearly with the temperature. For elements
containing solutions with 0.1 and 0.2 atom portions of TlNTI, numerical values
of El 050 were'extrapolated from the linear dependence of emf on temperature.
The re'sults'oPmeasurements and extrapolation were applied for the case of the
Au-Tl systeth to balculate changes in the partial molar thermodynamical potentlals
Card 1/2

S/137/62/000/002/004/144
Thermodynamical properties of liquid metal ... AOG-6/A1O1
of entropy (A ki, A ~Ag) and enthalpy (ART1, A RA ) of Tl and Ag, activities
and activity factors of components, changes in-the fhermodynamical potential,
entropy.(A 9) and enthalpy-(A H) of mixing liquid T1 and supercooled liquid Ag.
Isotherms of activity of the components in the liquid range of the Ag-Tl system
show positive deviations from the Raoult's law only within a UT, range from
about 0.1 to 0.11. The isotherm of Ag activity is characterized by a low negative
deviation.f3~om this law. Mixing-enthalpies are positive over the whole concen-
tration range and show maximum values on the side of liquid solutions enriched
with Tl. These maxima attain 950 cal. g-atom of the solution. A-PT1 P A -'!-A. g
and AH curves have an asymmetrical shape, and a maximum on the A H curve
appears on the side which is opposite to the enormous majority of other liquid
metal. systems with sharply different atomic volumes of components, Values
6-9;rl' A SAf and A S for the liquid Ag-T1 system are higher than for ideal and
regular solu ions. The basic cause of this fact is the great difference between
atomic volumes of Ag and Tl. Liquid Ag-Tl solutions behave like semiregular
solutions with coefficient D - 1.42, Information VI see R7,hMet, ig6i, 3A14.
[Abstracter's note: Complete translation)
Authoig summary
Card 2/2

30577
ISISSO P/038/61/006/003/002/003
E07l/El8O
AUTHORSt Terpilowski, Janusz., and Gregorezyk, Zofia.
TITLEs Thermodynamic properties of liquid metallic solutions
PERIODICAL., Archivum hutnietwa, v.6, noo3t 1961, 197-204
TEXTt Thermodynamic properties of liquid indium-lead alloys
were investigated by measuring the electromotive forces in
reversible concentration cells of the following type3
G QD
In 1(0.6 LiBr + 0.4 KBO + 0.1 InBr InxPbl-x
liquid molten salts I liquid solution
Spectroscopically- pure indium, and lead of 99.99% purity were used
for the experiments. Altogether ton In-Pb alloys, with an atomic
fraction of indium, varying from 0.05 to 0.9, were studied at
temperatures of 4oo, 500 and 6oo Oc. From the resulti obtained,
the following values were calculatedt temperature coefficient of
the electromotive force (dE/dT) within the temperature range
studied; activities (&In, apb) and activity coefficients (fIn,
fpb) of the components; changes of partial thermodynamic molar
Card 1/ 3

30577
Thermodynamic properties of liquid ... P/038/61/oo6/003/002/003
E071/E180
potentials ( &GIn, &GPb), entropies (-SSIn, "ESPb) and enthalpien
AHIn, AHPb) of indium and lead and changes of the thermodynamic
potential (6G), entropy (AS) and enthalpy (&H) for the process
of mixing pure liquid metals into liquid solutions. The
activities of indium and lead indicate that there is a positive
deviation from the Raoult law. These deviations decrease with
increasing temperature. The liquid indium-lead solutions can be
approximately regarded as semi-regular, with the values of
entropies of mixing higher than for ideal solutions. This
increase in the entropy of mixing is probably caused by the
difference in the atomic volumes of indium and lead as well as by
the effect of atomic bonds. The values of -EH-jr,,, tH,~,b and LH
are positive for the whole range of concentrations of liquid
indium-lead solutions. On the basis of investigations by
0. Kubaschewski (Ref.8z Z. Elaktrochem., 59, 1955, 840) it may be
postulated that, during the formation of these solutions, a
loosening of the atomic bonding of indium and lead, associated
with the absorption of energy, occurs. The existence of solid
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30577
Thermodynamic properties of liquid ... P/038/61/006/oo3/002/003
E071/E180
intermetallic phases of variable composition does not appear to
have any influence on the thermodynamic properties of liquid
indium-lead solutions within the range of temperatures studied.
There are 4 figures, 4 tables and 11 references: 7 Soviet-bloc
and 4 non-Soviet-bloc. The English language references read:
Ref.9: 0. Kubaschewski, Trans. Faraday Soc., 45,, 1949, 931.
Ref.10i W.J. Svirbely, S.M. Selis. J. Am. Chem. Soc., 75, 1953,
1532.
Ref.lli R.W. Bohl, V.D. Hildebrandt. J. Am. Chem. Soc., 79, 195-7,
2711.
SUBMITTED: September 1960
Card 3/3

TERPILOWSKI, J.; BARYCKA, I.
Thermodynamical properties of liquid cadmim-a-magnesium solutions.
Bul chim PAN 9 no.41175-178 161.
1. Department of Structural Researchp Wroclaw, Institute of Physical
Chemistry, Polish Academy of Sciences and Department of Inorganic
Chemistry, Technical University, Wroclaw. Presented by W. Traebiatowski.
(cadmium) (Magnesium) (Solutions)

,-TFMILOWSKIt J.'; MANCZYK, RO
Complexonometric determination of zinc in some prescription
mixtures. Apt. delo 10 no. 2:85 Mr-Ap 161. (HIRA 14:4)
i (ZINC-ANALYSIS)

P/038/62/007/001/002/003
E193/L383
AUTHOWS: Kundys', Emil, Terpi-roi-rs-ki,--.-Janusz and Josink, Jerzy
TITLE: Thermodynamic properties of liquid metallic solutions.
IX. The Sb-Tl system
PERIODICAL: Archii-rum-hutnictwa, v- 7, no. 1, 1962, 39 4 6
TEXT: The obj.ect of tile present investigation was to, study
thermodynamic propjerties of liquid Sb-Tl solutions. To this end,
the e.m.f. of revQ'rsible concentr4tion cells of the type:
Z~
Tl '(0-58 LiCl + o.42 KC1) + 0.05 TlCli Sb Tl
x I-x
liquid molten salts liquid sol-Lition
was measured. A linear temperature-dependenco of the e.m.f. was
observed in every case. The other results are reproduced in
Table 1. Changes of partial molar thermodynamic poteiltials
entropy (LIS and enthalpy
('~-6'T i Sb Tl' /-"SSb) (~-%"T I I -L"'S b
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w
ill/o38/62/007/001/002/003
Thermodynamic properties .... E193/r:,383
wore calculated from these data as well as the activities
(a TV aSI) ), activity coafficielits (f, rl,fSb ) for TI and Sb,
and changes of the thermodynamic potential CLG) , entropy S
and enthalpy (!~R) of their solutions. As will be seen from
Fig. 11, where a Sb and a T1 are plotted against T1 concen-
tration (N T1 ) at 650 OC, the activity isotherms for both
metals show a negative deviation from Rault's law. The enthalpy
of the solution is negative for the entire concontr,%tion range,
reaching a valuo of -1190 cal/g.atom nt the TI-rich end. Thn
asymptotic character of curves for the enthalpy of the solution
and for partial molar enthalpy of the components can probably
be attributed to the existence of an intermedi -ate y-phase in the
system studied. As shown in Fig. 2 (-where ~_S TV I-S, 5b ond
(cal/OC) are plottad against 'IN TI - the broken curves
relating to ideal solutions), changes of partial molar entropy
of the components and entropy of the solution for the entire
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P/038/62/007/001/002/0-03
Thermodynamic properties F,193/r!,383
concentration range were found to be higher than those of an
ideal solution. This effect is probably associated with .
relatively large volume changes accompanying the formation of
liquid solutions and with the difference in atomic-evolume of
both components. There are 4 A1,1gures and 11 table3.'
W-
Fig. 2: d $AV-01 rA Fix. 4:

1
1 J1 I
40 1
- _ 1

10

%%
% V
M
0 1~, 41
to

CO

0 4.9 '44 a#
IV4
Card 3/4 Nn

I,/()-,j8/621/007/001/002/003
Thermodynamic properties .... E 193/ E3 8 3
Table 1: Key 1 -.Lp.= No. 2 - Temperatur a range of the
measurement, a C.
Card 4/4
0
I.P.
JVTI

Am mv dE
dT j
w MV11000 Zukres temp
ratur pomia-
r6w w OC
3 4
1 0,050 317,5 -m,a 620-700'
2 0,100 253,1 21,7 590-680
3 0,-.00 .192,2 16,3 550-700
4 0,300 151,1) 12,7 510-690
5 0,400 120,9 9,6 460-600
6 0,500 96,8 7,4 410-4690
7 0,600 71,0 4,9 400-600
8 O'NO 48,6 3,4 400~690
0 0,800 26,'Z 2,1 400-690
10 0,000 12,4 1,0 400-690

P/038/62/007/003/001/002
E193/E383
AUTHORS., Kundys, Emil, Terpilowski. Janusz and*Zaleaka, Ewa
TITLE: Thermodynamic properties of liquid-metal solutions.
X. Pb-T1 system
PM-IODICAL: Archiwum hutnictwa, v. 7, no- 3, 1962, 233-241
TEXT: Measurements of e.m.f. generated at 400 600 'C by
a reversible cell of the type:
Tl (0-58 LiCl +-0.42 KCL) + 0905-TlCl PbXTI X-1
liquidl melted salts liquid solution
were used to determine some thermodynamic properties of liquid
Pb-Tl solutions in a wide concentration range ', Using the
Gibbs-Duhem's equati 8n and the experimental 'values of e.m.f.
at 400, 500 and 6oo C and the temperature coefficient of e.m.f,,
the authors calculated the following properties:
-,-I) -changes in the partial molar thermodynamic potential
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P/038/62/007/003/001/002
Thermodynamic properties .... E193/F.3831
entropy /-"S and enthalpy Lk of both constituents;
2) changes of the thermodynax~ic potential, entropy and enthalpy
of the solutions (calculated per g.a. of each solution);
3) activities a and activity coefficients f for both
components-in liquid solutions* The results, tabulated and
reproduced graphically, were similar to those obtained earlier
for the Bi-T1 and Bi-Pb-solutions. The -validity of the method
employed was confirmed by the fact that the values of enthalpy
of solutions obtained by this method were in good agreement
with those obtained by F.E. Wittig and P. Scheidt (Z. phys.
Chem. NF, 28, 1961, 120) with the aid of the calorimetric method.
In general, the results'6f the present investigation provided
support for the view that metals occupying adjacent positions
in the periodic table form liquid solutions only slightly
deviating from ideal solutions. This is demonstrated in Fig. 2,
where the change in the partial molar enthalpy of both components
UAKT,, Z%9pb) and the~change in the entropy-of the
solutions are plotted against the Tl concentration, the
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P/038/62/007/003/001/002
Thermodynamic properties #*so E193/19383
broken curves relating to ideal solutions.
-There are figures and 5 tables.
SUBMITTED: September 26, 1961
Fij._2:
'65"df Ivrolprop
taLrd 3/3

A

8/137/62/000/012/001/085
AOO6/A1Ol
AUTHORS: Terpilovski, Janusz, Staroficik, Rudolf
TITLE: On the solubility of In2s 3
PERIODICAL: Referativnyy zhurnal, Metallurgiya, no. 12, 1962, 7 - 8,
abstract 12A36 ("Chem. analit", Polska, 1962, V. 7, no. 3,
629 - 633; Polish, summary in English)
0 24
TEXT: The reproduction of In.8 3 solubility at 25 C, equal to 5.8-10-
is determined from thermodynamical data. The concentration of In ions in satu-
rated In2S3- solutions is polarographically determij~ed, depending on the acidity
index. The experimentall reproduction of solubility approaches th calculated val-
ues with higher acidity. This fact confirmed the formation of 104 ions-in the
solution.
V. Vigdorovich
Card 1/1

STAROSCIK, Ru4c.Wt_-NK1LOWSj~;, JanuBs
Calorimetric determination of indiira by pyrocatechol
violet. Chem anal 7 no-4:803-808 162.
1. Departmant, of Inorganic Chemistryq Faculty of Pharmacyy
Academy of Medicinep Wroclaw.

AU7HOR:
S/137/63/000/001/001/019
A0061AI01
TITLEs Thermodynamic properties of liquid solutions
FERIODICALI Referativnyy zhurnal, Metallurgiya, no. 1, 1963, 7, abstract IA29
("Bull. Acad. poloft. sai. Ser. soi. ohim.11, 1962, v. 10, no. 5,
221 - 225, English; summary in Russian)
TEXT: In the binary Mg-Zn system the presence of an MgZn2 phase, and of
three other intermptallides within a narrow range, was observed. The MgZn2-PbDse
has a close-packed lattice and melts congruently at 5900C; the hereditary struc-
ture of the short-range order is supposed to be preserved in the melt which
would affect the thermodynamic properties of the latter.. The thermodynamic pro-
perties of the r4g-Zn system liquid alloys were investigated by measuring the emf
on 12 specimens within a rarge of 0.035 - 0.90 atomic portions of MS. The emf
depends linearily on the temperature. By applying graphical integration, the
author determined changes in the partial molar values (61'Znl IA'gZn- &ITZn) and
of free energy LF, entropy LS and enthalpy ~LH. Activity of Mg and Zn in
Card 1/2

S/137/63/000/001/001/r,19
Thermodynamic properties of liquid solutions A006/A101
solid solutions was calculated from equations ATi RT 1n a,. It is noted that
the thermodynamic properties of alloys Zn-Mg and Cd41S era similar. In both
cases negative deviations,from the Raoult's law are observed. A mini=m on the
concentrational dependence curves of activity corresponds to the MgZn2.phase;
this proves a substantial interatomic interaction of components and the presence
of a definite degree of order in these alloys.
A. Vertman
[Abstracter's note: Complete translation]
Card 2/2

PRZEZDZIECKA-MYCIELSKA, Emilia; TERPIIDWSKI, Janusz; STROZECKA,
Krystyna,
Thermodynamic properties of liquid metallic solutions. Pt.
9. Archiw hutn 8 no. 2: 85-102 163.
1. Katedra Chemii Niaorganicznej, Wydzial Farmacautyczny,
Akademia Medyczna, Wroclaw.

TERPILOWSKI, J.i SLIDI,H.
Thermodynamic properti,~,s of liquid magnesium-thallium solu-
tions. Bul Chim, PAN 11 no.683171-320 163.
1. Department of Ino:rjanic Chwistry, Faculty of Pharmacy,
School of MedicJna, Preserted by W.Trwebiatowski.

JASKIEWICZ, A.; n~ILOWSKI, J.
Anomalous delay effect in polycrystalline BaTiO3. Acta phypica Fol
23 no.3:407-409 Kr 163. 1"
1. Physical Institutey Wroclaw Univ6isity, Wroclaw.

TERPTILWSKI, Janusz; ZALESKA, Ewa
Thermodynamic properties or thallium-tellurium liquid solutions.
Rocz chemii 37 no.2:193-200 163.
1. Department of Inorganic Chemistry, School of Medicine, Wroclaw.

TERPILOWSKI9 J.; RATAJCZAK, E.
Thermodynamic properties of CdSe and CdTe. Bval chim PAN 12 no.6:
355-358 164.
1. Department of Inorganic Chemistry of the Divtalon of Phamacy
of the School of Medicine, Wroclaw. Submitted April 6, 1964.

~Zvlkc-'!
SLABY, It.;
Thermod~nami^ -)roperties of liquid magnesium-gallium solutions.
Bul chim PAN %i.e. 12] no.9:581-585 164.
1. Department of Inorganic Chemistry of the Division of Pharmacy
of the School of Medicine, Wroclaw. Submitted July 6, 1964.

ctncentration