SCIENTIFIC ABSTRACT STADELNINKAS, A. - STADNICHUK, M.D.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001652810008-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 25, 2000
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

SM)ELIFIMUS, A.,, inz.
Light over Lithuania; progress in engineering and preparation of
cadres of speciali-Ists in the Lithuanian Soviet Socialist Republic.
Przegl techn no.45:4-6 11 N 162.
1. Panstwowy Komitet NauloDwo-Techniczny Rady Ministrow Litew3kiej
Socialostycznej Republiki Itadzieckiej. -

--- ------------------
YUGOSLAVIA
Magisters Aurel STADLER and Stjepan DJURIC rAffiliation not given.]
"Pharmacies in the City of Subotica in the Second Half of the
Nineteenth Century.ft
Belgrade, Arhiv za Farmaciju, Vol 13, No 1,.1963; pp 68-74.
Abstract : An account of the financial, political and economic
problems of pharmacists in Subotica and the lobbying necessary to do
anything from the opening of the first pharmacy in 1780 till the
fourth in 1873. Eighteen local archival references.

GOTH, $ndre. dr.; Nadasdi Miklos azigorlo orvos es Stadler, Egon, dr.;
Majsay, Aglaja technikai segedletevel.
Role of amino acids in the initiation of hormonal secretion; II.
Effects of amino icids on compensatory hypertropby and ascorbic
acid content of the adrenal glands. 'Sffects of amino acid consumption
on corticosteroid excretion. Magy. belorv. arch. 9 no-3:85-90
June 56.
1. A Budapeatt III. ker. Tanacs Margit korha2a belosztalyanak
(foorvos: Goth. Sndre Kandidatua) kozl.
(ADRENAL CORTEX, physiol.
eff. of amino acids on hormonal secretion. vitamin C
content & conpensatory hypertrophy after unilateral
adronalectomy in rate (Hun))
(AMINO ACIDS, eff.
on hormonal secretisn, vitamin C content & compensatory
hypertropby of adrenals after unilateral adrenalectomy
in rate (Hun))

(WTH, Nndre; GOM, Margit; STAM@, FRAY, Jozsef; MAJSAY, Aglaja
___*96@5-APW.
Function of the pituitary - adrenal system in diabetes. II. Relation
of the plasma corticoid level to the degree of blood sugar fluctuation.
Magy. belorv. arch. 10 no-5-6:i86-igi Oct-Dee 57.
1, A Budapesti Margit Korhaz Belosztrlyanak (foorvos: Goth, ladre) es
a Budapesti VIII Szanto Kovacs u. Rendelointezet laboratoriumanak
(foorvos: Zimandy Aranka) kozlemenye.
(ADRML CORT3X HORNDNO, in blood
in diabetes wellitus, relation to blood sugar fluctuation(HMU)
(DUBRM MLLiTM, blood in
aarenal cortex hormone level. relation to blood sugar fluc-
tuation Okn))

GOTH, Endra; STADLER, 3gon
Therapeutic experiment with methionine in the treatment of chronic
joint dineases. Orv. hatil. 99 no-36:1247-1248 7 Sept 58.
1. A Budapesti III. keruleti Tanacs Margit EDrhaza (igazgato-foorvoo:
Goth Endre dr. kandidatus) Beloaztalyanak kozlemenye.
(.TOINTS,* die.
qhr6nic, ther. , methionine (HLm))
(MICTHIONIM, ther. use
joint dis., chronic (Ikn))

h UNGAR I
M., and S,VADLER E., of the National Institute of Sports
Hygieno, Budapest [Original version not givenj.
"Axiaptation to Miiscle Activity of Circulation Contro.0
Budapest, Acta Physiologicalcademiae ScientiariLm Hungaricae., Supplement
'co Vol 22, 196-3; p 17.
Abstract CAuthors' a-,@-lish su=ary]: The increase or heart frequency in
response to graded muscular work and the time required for restitution
denend on tho ability to physical performance. In trained sportsmen
a negative phase of the heart rate, that of trophotropic excitation,
manifests itself in the second or third minute after performance and
may depress the heart rate by as much as ton minutes below resting
value. The results seem to indicate that the dominance of the negative
phase lasting one or two minutes longer in the pulse rato response to
physical effort may be interpreted as a sign o:t adaptation favorable
from tha point of view of performance.

L 14867-66
ACC NR: AT6007402 SOURCE CODE: HU/2505/65/026/00X/0O24/bm5
AUTHCR:
GRG: Central Institute of Sports Medicine. Budapest (Kozponti Sportegesz,segg
Intezet
T1TLE: Spiroergometria demonstration of the autonomic regulation related to
muscle activity [This paper was presented at the 29th Meeting of the Hungarian'
Physiological Societv held in Szeged from 2 to 4 July,,19641
SOURCE: Academia scientiarum.hungaricae. Acta physiologica, v. 26, S-uppi-tuentp
1965., ?4-25
TOPIC TAGS:* medical conference, circulatory system, human physiologyp biologA67@
respiration, muscle physiology.
At the 1963 me'eting of- tW77-
ABSTRACT:
card!Lac frequency de-I..,
.8obietY it'has'bderi fep6rte7dAF1it a nbe&tilb phase in
"Veloped following controlled Physical activity, This counter-regulatory
jphenomenon was ascribed to tropbotropic dominance and was dorrelated with
@hq degr@e of physical fitness. in further investiaations us spir0_
Card -1/2

L 14867-66
ACC NR: AT6007402
jergometry it was demonWErAET(f ihA, upon performance of a certain type of
were followed by a counter-s@
Physical work, the rogulatory phenomena mentioned
)ry phase/which manifested itself in changes in consumption and
revulatc 02
02 productionAn analysis of the autonomic reactions during the individual.'
phases of work (state of readiness, running activity, ergostasis, restitu-
tion) revealed that the trophotropic dominance In restitution was marked in
'subjects showing an economical regulation,while it was slight..or absent
'in the other subjects. The counter-regulatory phenomenon may thus be looked
1upon as an overcompensation, creating in the organism conditions more favor-@
Able from the standpoint of performance than those pre-Ta4ipg_@@fore muscle-
work. [JFRS1
SUB CODE: 06 SUBM DATE: -none
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STADM, F.
"Telecommunication Engineering in the Develap7eirt of the Reconomy", F. h,
(TECHNICKE NOVINY, Vol.1, No. 17/18, Dec. 15@53, Praha, Czechoslovakia)
SO: Monthly List of East European Accessions, (EHAL), LC, Vol. 3, No. 12,
Dec- 1954, Unal.

--,. 7.
':' - -j -
Characteri.-tics of t@lecomunications traffic. n.. 2.
Vol. lb, no. 1, Jan. 1953
SL@,@FROUDY 0B.-L"OR
Praha, Czechoslovakia
So; @astern European Acce3sicn Vol-5 'No. 4 April 1,056

621.365.663
1133. UN THE THEORY OF TELEPHONE TRUNK-CALL:
FEES. 1.8tadler.
Slaboprou -or-, Vol. 16, No. 9. 449-56 (ID55). In C2ech.
The proposed method of determining trunk-call fees Is
based an two factors. (1) capital costs cad (2) the value of a
given call. The cost factor per unit call (3 min) is estimated
for polygonal and star-type telephone networks; In the former
the exchanges are connected In tandem, while In the lattcr they
are subdivided Into several ranks, an exchange of a lower
rank being connected to only onc. higher rank exchange. Pric-
Inc the call on the basis of its value is based on its relative
importance to the national economy and on the requested re-
duction of the walling fline during the busy hour. Practical
examples of determining the charges in both tandem and star-
type networks are given. R.S.Sidorowicz

z/o,;@ /6nI/cq-3/C) 12/0,04/004
.MY1 I ic) it: Stailler. Fraotj-;el@. Evivineer Doctor
TITLE: Some wmar-1c.9 o- the theory or trunks
PERIODIt-AL: Slaboproudy obzor, v. 23. no. 12, 698 - 7U5
!---XT The principal methods of CnIculating the number of ij-un%@5,
i.e. CaIcIlla"i.011 on t!t(. ka!li,s C)f tile pel-vd..'sible losses uld Oil the
ba-sis of' thv waitj-n.,.,, time, are reviewco. The fundamental formulne
of' Hernwilli., Poisson nwl Erlittis, are analyzed in o 'rder "o determine
lheir-Nnli(lii-y 11TIO :1- atielm both the methods on
)t is made to base
the Premises. Tt, is Found t',at as regards the ap?,roach based
on t-fic perruit7.@ihl- lo!zses, it is of little importance whe"her tile
riumbi@r of t-unks is dotormincO on the hasis of the Bernaitlli,
llois:3on or ErIang fot-mulae. tiowever, *.9ince, in general, the
vol.unm, of telef-how, traffic is -L;teadily increasing and it iss V,ere-
Core necessary to provido ade,Itzte quality of service Under these
condi.tions, it is revorm:,ended that the Bernoulli and Poismon
foriiiulac I)p itsed for systems m) to six trunlis and Ihe Erlilng
formula for larger Calculotion of the number of trunl-@s
on the b,%.-;i.-; of tb- probal@le waitinf@ time is not recomwencle(i since
Card 1/2

2 /012/004/0011
Some repwrks on th, th, )r", F-1(t2/F782
thi -5 met hod i -, 11,it I i Cj OrIt !Y jll:st if i ed 1!!,% 1 flet"la I. -I C-'. I. I t i s
no t n cce.s.,ia ry t n @ e, Co, n :i pecia I met 11(,)d fo r ci c i, 'i-, i 11 the
number of trur,: C-.- t i nc-time systems t b e w e 1-. oil o f P ernij -i s -
b I P .1. e s i probable maximum uaiting tii:ie cm
be evaltiatec' il y ;% simple formula:
v
where D .,1- 1 maxi imim wa i t ing I i me j n hours y
-2
traffic in er-1 nn@7!@ perjuis:iih] P losses rel @it i ve to the t. ra f 'I j c
y and v i @- I @i i- wzm,be- o f I ines whi ch , for a @,i ven loss chirin@,
the bui@:y liour , ;, r-r. capp-hl e of carryi ng the tra f fic ; v is
froi;i a suitab] ( tabli- or diagram. @\s regards the probability Iliat
thf- waitin,- ti.rile i@@. lon@rj.j- or shorter tban a prescribed tigne inter-
Val, it is .Ieces@@-,iry to find ihe (1-1stribittion of the number of
calls a!.i a function of their duration. The resvilt is strongly
der-ndont oit ihis disirilmtion furiction. There are 6 figures.
AS SOC1 -i'l I OIN ---z I . alm -i t i o.
" !,mim iistav spojuo, Fir. (Tel ecouwainic, -is
l?"s (" "I" Tristitutc, PrnFue)
-S U W411-1,11.1) '111riv P'. 1C,62
Cr,r'%.*, 2/2

STADIER, Frantisekq inz.c, dr.
Bronze or steel conductor6? Slaboproudy obsor 23 no.9:523-526 S 1629
1. V7zktmny ustav spoju, Praha.

STADLER, Frantisekv inz. dr.
Overloading"of teleco=unication networks. (@3 i3poje 9 no, 2;
3-6 Ap t64.
1. Research Institute of Telecommunication.

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STADLER, Frantisek, dr, inz.
On the S.Hrbek review of my article "Overload of telecommunication
lines." Cs spoje 10 no.2:32 Ap 165.

ISTADUR) I .
From the producticn of synthetic alloys, p. 164.
STROJNISKI VE-STNIK (Fakulteta za eletroehniko in strojnistvo Univerze v
Ljubjani In@titut za turbostroje v Ljiibljana Drustov strojnih inzenirjev in
tehnikov LR Slovenije in Storjna industrija Slovenije) Ljubljana, Yugoslavia.
Vol. 3, no. 6, Dec. 1957.
Monthly List of East EuropeRn Accession EEAI LC, Vol. 8, no. o, June 1959.
Uncla.

STADLER.. Ivan, inz.
Impressions from some visits to American foundries. Livar vest
10 no.1:12-14 163. , -
1. *Litostroj", Ljubljema.

STADLER, Ivan, inz.
Electric furnace, modern foundry aggregate. Livar vest 10
no. 2/3:47-59 163.
1
-L. "Litostroj", Ljubljana.

STADLER, Ivan., inz.
Opt removal and ventilation in foundries. Li-vikrstvo 10 :,@:,,
nb. 51/52; 2-17 163. 1 ,w
1. "Lito.9troj", bjubljana.

STADLLR, Ivan, inz.
Conference on the cleaning of casts with water in Gliwicex
Poland. Livar vest 11 no. 2: 41-48 164.

STADLER. J.
"Assuring an effective construction system in mining." p. 118.
UHLI. (Ministerstvo paliv). Praha, Czechoslovakia, Vol. 1, No. 4,
Apr. 1959.
Monthly list of East European Accessions (EEAI), LC, Vol. 8, No. 8,
August 1959.
Uncla.

C7ECHOSLOWdUL/Choi@ical Toohnology. Choi-ical ProJucts H
an,! Thoir Uses. lart III, Fooa Industry.
1,bs Jour : Ref Zhur-Khimiya, No 15, 1958@ 51893
Jwthor s Knoz VO Idasek, J., Vedlich, M.,
S

tad J@.
--J=
Inst
Title : Construction of a 11mt for the Production
of High Quality FQrnonts for 1,pplication
in thk3 Milk In(@ustry.
Orig Pub : Prumysl potravin, 1957, 71 No 71 310-313
1,bstract % The quality of feri-ionts Copencls not only
on the qunlity of the nilk used, but also
on th@@ purity of the bacterial cultures.
Ono riust sterilize nilk at 90-950 for 30
minutes while stirring, prior to the cul-
ture inoculation. Subsequently, the sterl-
Carc! 1112

STADLER, Lasslo
On ware damages occurring in railroad transportation due to the
negligence of shipping duties. Kozleked.kozl 18 no.4:33-56 Ja 162.

STADISR, Laszlo
The packaging of goods transported by railroads. Kozleked
kozl 18 no-15:246-249 15 AP 162.

STADLER., Laszlo
Liability for damages suffered in railroad transportation.
Vasut 14 no.11:30-31 If 164-

AUTHORS: Fiala, A. I Ing. and Sta'aler, V. CZECH/34-59-5-17/19
TITLE: Analytical Determination of Combined Sulphur in Steel
(Analytickg ur6enl vazby s1fry v oceli)
PERIODICAL: Hutnicke' Listy, 1959, Nr 5, pp 462-464 (Czechoslovakia)
ABSTRACT: A working method is described for determining the sulphur
which is combined with iron and manganese in various
types of steels,which yields acceptable results. The
method is based on micro-analytical determination of
the sulphur in the isolated substance obtained by
electrolytic dissolution of steel specimens in a
neutral electrolyte. In addition to enabling
evaluation of the chemical composition, this method
also permits determining the total quantity of sulphides
in steel sDecimens taken during smelting and casting of
the steel. Fig 2 shows a sketch of the instrument used.
Some of the results obtained are entered in Tables 1 and
2, p 463. There are 2 figures, 2 tables and 2 references,
1 of which is Czech, 1 German.
ASSOCIATION: Z6vody V. I. Lenina, PlzefL (V. I. Lenin Works, Pilsen)
Card 1/1

STADLEROVA, M.
Kunovice in the Valachia region, Eastern Moravia. P. 30. SBORNIK.
Praha. (Journal Issued by the Czechoslovak Geographical Society; with English
and Russian summaries. Quarterly) Vol. 60, no. 1, 1955
SOURCE: East European Accessions List (EEAL), Library of Congress
Vol.'4, No. 12, December 1955

,D"P *@DLEROVA,
Situation and tasks of Soviet geographor in the contemporary period of
its develop!!.ent; I. GeraSirrWls repo@t at the ad Congress of the
Geographic Society of the USSR. Tr. from the Russian. p. 28,
Ceskoslovenska spoleemost aemepisan.. 80BORNIK. Praha. vol. 61, no. 1,
1956.
SOURCE: East European Accessions List. (EFKAL) Library of Congress.
Vol. 5, No. 8, August 1956.

w
':'PT.'tDL!-R0VA, 1".
Basic principles of the distribution of socialist prodicti3n and the
tasks of ecomomic geography. V. Vas-Intin's report at the 2d Congress
of the Geographic Society of the USSR. Tr. From the Russian, P. 31.
Ceskoslovenska spolecm03t aemepisan. SOBOIRNIK. PrILha. vol. 61, No. 1.
1956.
SOURCE: East European Accessions List. (EEAL) Library of Congress.
Vol. 5, No. 8, August 1956.

STADLEROVA, M.
Professor Bohuslav Horak, swrenty-five years old; a biographic sketch.
p. 3-14. Ceskoslovenska spolecnost zemepisrra, SBORNIK. Praha.
Vol. 61, no. 2, 1956.
SOURCE: East European Accessions List, (EEAL), Library of Congress
Vol. @, No'.@ 12, December, 1956.

STADLEROVA, M.
Bohuslav Horak and Dusan Travnicek's study on the Description of Comunities Iforth
of the Danube (the so called Bavarian Geographer); a review. p. 228.
(Sbornik, . 61, no. 3, 1956, Praha, echoslovakia)
SO: Monthly List of East European Accessions (EEAL) LC, Vol. 6, no. 6, June 1957, Uncl.

1;:v rl@-- r-y
Periodicals: Vol. 63, No. 4, 1953.
ST -iMf 11, The most important endeavors to establish an orographic division
of the Czech Lands during the 19ti, century before the divisi-in
wt@s made by K. Koristka. p. 303.
%'onthly List of" East Europeran Accessions (EEFAI) LC Vol. 8, 'No. 4, 1959 April.
Unclass.

3TADLMANN, Alrred, inz.
Ceramic ceiling assembled without using building machinery,
Poz stavby 13 no.2:70-72 165.
1. Study and Typificatimi Institute, Prague, Worksite for
House Construction, Bratislava.

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STADIDINKO, N. M-
Concerning the level of comprehension by younger pupula of pictures
with a plot. lauk. zap. lauk.-doal. inst. psykhol. 11:36-38 '59-
(KIRA 13:11)
1. Institut paikhologii, Uyev.
(Comprehension)

STADITICHEITKO, A... starshiy nauchnyy sotrudnik
J. 11
Japanese merchant I-Leet and shipping problems. Mor. flot
21 no.12-4.2-"/ D 161. (1= 14--12)
1. In3titut narodov Azii AN SSSR.
(Japan--44erchant marine)

STADNICHMIKO, A.I., [e-mail] (stanteiya Zagoryanskeya, Yaroalnvakava
slinlemmyn dorogel.
Do you know about this? Zdorovle 4 no,6:12 Je '58 (KIR.A 11!6)
(SMOKnIG)

; KOSTIN, N.P., goknvy Inzhener; GUSAROV, M.I., gornvy inzhener; ALV&SMY31VSKIY,
N.A., gornyy inzhener; @t4PPPH] 0 - !,P., gorm7 inshener.
, - A
Drift mining at a speed of 302 meters per month. Gor.zhur uo.9:12-15
S '56. iMIM: 9: 10)
I I.Severourallskiya bokoltov37@ radniki.
(Ural Mountain region--Bauxite) (Mining engineering)

STADNICHMO, A IP., inzh.
Results of work in Northern-Ural bauxite mines in 1957. Blul,
TSIIN tevet. met. no.9:9 1580 (MIRA 11:6)
(Ural Mountain region-Bauxite)

KOZLOVSKIY, Nikolay Fedorovich(Kozlovslkyi, M.F. 1; S_TADNjQ4ENKO,_G.S.___., .
(Stadnychenko. H.S.b red.; KONTAR, X.F., tekhn. red.
[Japan seen through the lens; news photographer's notes]V obl-
iektyvi IAponiia; zapysky fotokorespondenta. Kyiv, Derzh.vyd-
vo obrazotvorchoho mystetstva i muzychnoi lit-ry, URSR, 1962. 69 p.
(MIRA 16:2)
(Japan-Views)

STADINT It" MAE p7l'w() , N - V - , E, I S, .
Co,-,l Ildnes @,nd lf-1.111-Ig
Continuous wo-lk schedulle is +.I-e basis for the fu2l utilization of idning
toclu-iology. Mekh. trud. rab. 6 No. :3, !952
`@' U ons 1
4 Tonta T-i s-'- of Russinn Accessi , Ubrary of Congress, December 1952. TMASSIFIED.

STADNIOMTKO, N.V., inzh.
Greater attOntio:q to mining operations. Ugoll 34 no.2:22-28 P '59.
(MIRA 12:4)
(Coal mines and mining)
1"01.,

STADNIC021KO, N.V., dots; NIZAROV, V.T., gornyy inzh.
Most advantageous borehole diameter. Ugoll 34 no.10:20-22 0 '59.
OGU 13:2)
l.Novocherkasekiy politekhnicheakiy institut (for Stadnichenko).
2.11achallnik strottellstva shakhty No.1 "GukovskBya" (for Hazarov).
(Blasting) (Boring)

STADNICMKO, N.V.; RA@&@V, V-T-
Advantageous borehole diameters. Ugoll 35 no-11:51-52 X 060.
(KIRA 13:12)
(Boring) (Blasting)

STADNICHENKOV N. V., CAND TECH SC:Is "INVESTIGATION OF
BLAST-DRILLING OPERATION3 IN W444-" HORIZONTAL -SXCA"- I-
A@@ ROCK." NOVOCHERKABSK, 1961 . (Miti OF
HIGHER AND 6EC SPEC Eo UKSSR9 KHARIKOV MINING INST).
(KLq 3-619 220).
263

STADNICHENKO, N.V.
Role of the time factor in the efficiency of capital inveatments.
Trudy NPI 139:3-14 162., (Capital investments) (MIRA 16:6)

N.V.: STA DN 1 111: '11KC) C,
@conom-c effec-Lfvene5s c' -a-p-17,a
50-54 11163.
1. Novocherkasskiy politekhnicheskiy inst-itut (for N.V. Stadni-
u
chenko). 2. Rostovskiy finansovo-ekonorziic@ieskiy in3titUt (for
P.G. Stadnichenko).

I
8111ADN I C.I IFNIKO P N.V.; STA DNI CHIMO '0 .
Economic effectiveness of capital investments. Ugol' 38 no.11:
50-54 N163. (mm 1?:g)
1. Novocherkasskiy politekbnicheskiy ins".4tut (for N.V. Stadrd-
chenko). 2. Rosto-skiy finansovo-ekonomicheskiy insti-tut (for
P.G. Stadnichenko).

@-) . ,i.. - 21- - ,
--- @or the -h
.77 geometrr of brci:-h tee- . Mashinostreenie
- - '.1 @@, 404. (MERA 1?@10)
. . , - 'i, I

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inf-'arm. 18 no-5z3O--33 my t, (MITA 18.0

STADNICfWKO, V.G.
, -
Soils of the Veliko-Anadoll Forest. Neuk.zaD.Dnipr.un. 48:53-63 '55.
(MIRA 10:11)
(OlIginka District--Forest soils)

DOMBROVSKIY, A.V.; STADNIGHUK, M.D.
Interaction of the complex salt off-nitrophenrldiazonium and
ferric chloride with alcohols. Zhur.ob.khim-25 no*9:1737-1739
S '55. (NLRA 9:2)
l.Chernovitakiy gosudarstvenrqy universitet.
(Diazonium compounds) (Alcohols)

85611
i
If F3.
.91 cob
S/079/60/030/007/031/039/XX
BOO1/BO66
AUTHORS: Petrov, A. A., Kormer, V. A.,_and Stadnichuk, M. D.
TITLE: Investigations in the Field of Conjugate Systems. CXXI.
Addition of Lithium Alkyls to Trialkylvinyl Acetylenyl
Silane I I
PERIODICAL: Zhurnal obshchey khimii, 1960, Vol. 30, No. 7, pp. 2243-22Aa
TEXT: The authors continued their investigation of the reaction of lithium
alkyls with compounds having a double and a triple bond, and studied, taking
into account the papers of Refs. 39 4, the addition of lithium ethyl, pro.-
pyl, isopropyl, butyl, and tertiary butyl to trimethylvinyl acetylenyl
silane. By treating the reaction product with water they obtained the
addition products of the expected composition: (CH 3)3Si - C4H4 - R. Accord-
ing to the mode of addition of lithium alkyls, structures (I) to (VI) were
possible. In the infrared spectra of all adducts, frequencies of the streth-
ing vibrations of a triple and allene bond system were found. In the
spectral region which is characteristic of the stretching vibrations
of the double bondg, rag cl.,)serrvable (Diapram 1). These
Card 1/3

85611
Investigations in the Field of Conjugate S/079/60/030/007/031/039/XX
Systems. CXXI. Addition of Lithium Alkyls BOO1/Bo66
to Trialkylvinyl Acetylenyl Silane
data show that the adducts are mixtures of acetylene and allene compounds,
and that formulas (IV) and (VI) are negligible. Oxi hydrogenation of the
silicon hydrocarbons obtained from the adducts with lithiumethyl and li-
thium butyl by means of PdCaCO 9 trimethylhexyl and trimethyloctyl silanes
were obtained accordingly. -Thei@ structure was confirmed by comparing
their infrared spectra with those of authentic samples of silicon hydro-
carbons (Diagram 2). Thus all formulas@ except (I) and (II), may be exclud-
ed. The ratio between the acetylene and allene isomers was found from
their hydrolysis. The hydrolytic cleavage of two silicon hydrocarbons,
with R = C2 H5and C 4H9, gave hexamethyl disiloxane and mixtures of
acetylene-allene hydrocarbons, C H and C H according to the scheme
. 6 10 8 14)
(I) --+ HC =_C@-CH 2- CH 2-R + (CH 3)3 Si-O-Si(CH 3)3
(11) -4 CH 2=C=CH-CH 2@_R + (CH 3)3 Si-.O-Si(CH 3)3
Since hydrolysis took place at 65 -70 0, allene-acetylene isomerization
was impossible in this case. The acetylene isomer content in the mixture
was determined analytically (Ref. 5). Also the difference between the
Card 2/3

Investigations in the Field of Conjugate S/079/60/050/007/031/039/XX
Systems. CXXI. Addition of Lithium Alkyls B001/B066
to TrialLylvinyl Acetylenyl Silane
molecular refraction of (I) and (II) permits to estimate the probable
composition of the adduct mixtures of (I) and (II). It was thus shown
that lithium alkyls add to trimethylvinyl acetylenyl silane and give a
mixture of acetylene and allene compounds. They add in another way as to
the vinyl alkyl acetylenes. The course of the curve (Diagram 4) showing
the hydrogenation rate of the mixtures of adducts (I) and (II) is re-
markable. The authors mention A. D. Petrov, S. I. Sadykhzade, and Yu. P.
Yegorov. They express their gratitude to 'T. V. Yakovleva for examining
the infrared spectra. There are 4 figures, I table, and 7 references:
6 Soviet and 1 US.
ASSOCIATION: Leningradskiy tekhnologicheskiy institut'imeni Lensoveta
(Leningrad Technological Institute imeni Lensovet)
SUBMITTEDi July 16, 1959
Card 3/3

32o45
s/o5j-/61/011/005/005/018
E202/E192 "I'-
AUTHORSt Yakovleva, T.V., Petrov, A.A., and StaAAnix-b@,-M.D-
TITLE& Vibrational spectra and structure of the enyne type
silicon hydrocarbons
PERIODICAL,. Optika i spektroskopiya, v.11, no-5, 1961, 588-593
TEXT., Vibrational spectra of the following were studiedg
1-trimethylsilylbutene-3-yne-l-, 1-tr4-methylsilYl-3-methylbutene-
3-yne-, 1-trimethylsilyl-pentene-3-yne-l@ and 1-trimethylsilyl-
2-cyclohexene-1-y.1-ethyne.. These were contrasted with the
available data on the corresponding enyne type hydrocarbons,
Full data of the Raman and IR vibrational spectra are given for
all the above compounds. It is concluded that the substitution
of C with Si-, at the triple bond causes a sharp lowering of the
frequency in both spectra at ca. 75 cm-l' and increases the
corresponding intensity of the band in the IR spectrum. The
frequency of the double bond remains substantially unchanged.
Two additional bands identified as the cis and trans isomers were
found in the first compound. The degree of depolarisation of the
lines of valency vibrations C @- C; C = Ct; and Si - Cj with
Card 1/2

32045
Vibrational spe,:Ara and structure S/051/61/011/005/005/018
E202/E192
reference to the ellipsoid of polarisation was also -investigated,
It was shown that with the elongation of the C- chain of the
silicon hydrorarbon, the ellipsoid is stretched, while when the
branching occurs it shrinks. Cyclisation, on the other hand, has
similar effect as the elongation of the straight chain.
Finally, the authors conclude that the above mentioned frequenc@y
fall in the triple bond spectrum is due not only to the change
of the mass of the nearest atom, but also due to the increased
coefficient of elasticity,
There are 1 figure, 3 tables and 7 references: all Soviet-bloc.
SUBMITTED. December 26, 1960
Card 2/2

89510
S/679161/031/002/003/019
B118[B208
AUTHORS: Stadnichuk't,.,M,_D.,^@nd Petrov, A. A.
TITLE: Studies in the field of conjugated systems. CXXVIII. Mode of
bromine addition to rill.con-conts-ininp Anine compounag
PERIODICAL: Zhurnal obshchey khimii , v. @1 , no. 2, 1961 , 411-418
TEXT: Following Ref. 1 concerning the mode of bromine addition to enines,
the authors studied tha effect of the substitution of a trialkyl or triaryl
silyl group for one of the hydrogen atoms on the reactivity of the enine
system with respect to bromine. A. D. Petrov and S. I. Sadykh-zade et al.
(Refs. 2, 3) found that 1-triethyl silyl buten-3-ine-1 adds the first bro-
mine molecule to the triple bond. The authors studied this problem thor-
oughly, and brominated silicon-containing enines with different substituents
in the enine system and at the silicon atom. The following silicon-con-
taining enine systems were first selected as initial products: 1-trimethyl
silyl buten-3-ine-I (I), 1-trimethyl silyl penten-3-ine-I (II), 1-trimethyl
silYl-3-methyl buten-3-ine-1 (III), and 1-trimethyl silyl ethinyl cyclo-
hexene-1 (IV). In the second group, the following compounds were studied:
Card I 1@

89510
S/07 61/031/002/003/019
Studies in the field ... B118YB208
1-triethyl silyl and 1-triphenyl silyl buten-3-ines-1 (V) and (VI). The
results obtained were compared with those of compound (I). (II) and (IV)
have so far not been described. The following threetypes caMbeexpected when,
adding bromine to these enines:
R2Si C a C - CR'Br CHR"Br(A),R3Si - CBr - CBr - CRI - CHRII(B),
R Si CBr - C - CRI CHR"Br(C) (Ref. 1). This bromination was carried
oat inchloroform at -10-150C. In most cases, the dibromides could beeasily
separated by vacuum distillation from excess initial products, and from
tetrabromides and other high-boiling products formed inlow quantities. The
structure of the dibromides was confirmed by their infrared spectra (Dia-
gram), and by chemical means. In all cases, bromine added to the 1, 4-Po-
sition and to the ethylene bond. The highest yield in allene-1, 4-adduct
is obtained from 1-trimethyl silyl buten-3-ine-1, the lowest one from 1-
trimethyl silYl-3;-methyl buten-3-ine-1. Dibromides of 1-trimethyl silyl
buten-3-ine-1 were shown to be capable of : 1) isomerization on heating,
giving 1, 3-diene dibromide, 2) splitting off vi.nyl bromo acetylene under
the action of alcoholic alkali:
Card 2/

S/07 61/031/002/003/019
Studies in the field B1 1 8YB208
(CH Si CBr C CH CH Br (CH ) 94 - OLT CH3r C CH CH 3r
3 3 2 3 37 2
CH3@3si 0 BrC @aa C CH dH
12 2
The changes in the addition' direction of bromine, according to the-position.:@@
of methyl groups in the-enine ohain,.are- explain*ed by electron displacemerl;@
There are I figure, 12 tables, and 12 references: 10 Soviet-bloc and 2 non..
Soviet-bloc.
ASSOCIATION: Leningradskiy tekhnologicheskiy institut imeni Lensoveta
(Lenincrad Technological Institute imeni Lensovet)
SUBLIMED: February 29, 1960
Legend to the figure: Infrared absorption spectra of dibromides (layer
thickness about 304).l: 1-trimethyl silyl buten-3-ine-1; 2: 1-triiiethyl
silyl buten-3-ine-1 (Experiment b); 3: 1-trimethyl sil 'yl Denten-34ine-1;
4: 1-trimethyl silYl-3-taethyl buten-3-ine-1; 5: 1-trimethyl silyl ethinyl
Card 3

20947
1219 S/07 611031100AI0011006
bo 2 2 0 9 )16ql B1 18YB208
AUTHORSe Petrovy A.A., Kormer, V.A., and Stadnichuk, M.D.
TITLEs Studies in the field of conjugate systems. CXXXIII.
Addition of lithium dialkyl amides to trialkyl-allyl-
buten-3-ynes (Enyne compounds. LII)
PERIODICALs Zhurnal obshchey khimii, v- 319 no- 49 1961p 1135 - 1139
TEXTg As was previously shown, lithium dialkyl amides readily add to vinyl.
acetylene hydrocarbons to form acetylene or allene amines, depending on the
structure of vinyl acetylene hydrocarbons. Considering the considerable
dependency of the reaction direction on the structure it was of interest
to study more thoroughly the reactions of lithium dialkyl amides with
enyne compounds. The present paper describes the reactions of lithium
diethyl amide and lithium piperidide with 1-trimethyl-silyl-buten-3-Yne-l-
The latter adis lithium dialkyl amides even in the cold, but the adduct is
more or less cleft when treated with waterp forming the amine and hexa-
methyl siloxane owing to the weak hydrolytic stability of the 0 - Si-
bond inoL-position to the multiple bond. Reaction of I-trimethyl-silyl-
Card 1/t

20947
S/079J61/031/00-1/001/006
Studies in the field of ... B118/B208
-buten-3-yne-1 with lithium diethyl amide gives a mixture of 8ilicon-con-
taining acetylene amine (1) and silicon-containing allene amino (II)g
(CH3) 3S'-O@E-- C-CE27CH2N'CA.) 2 (1)
k
(CH 3)3 si-c-@c -CH==CH 2--F
(OR 3)3 Si -CH-O=CH-CH2N(C2H 5)2
The infrared spectrum of this mixture shows a very intense frequency of
stretching vibrations of the acetylene bond(2171 cm-I)and an intense band
of stretching vibrations of the allene grouping (1937 cm-I). In the range
1600 cm-1 no absorption was observed which indicated the absence of an
isomer with a conjugate system of double bonds. The presence of silicon is
confirmed by the characteristic frequencies 1208 and 1256 cm-1, that of the
-1
(CH 3)3 Si grouping by the frequencies 843 and 762 cm . Heating with 10%
KOH solution in methanol results in a cleavage of the mixture to form hexa-
Card 2 11A
13

20947
B/079161/031/004/001/006
Studies in the field of B118/B208
methyl siloxane and a mixture of acetylene and allene-amine-S. The struc-
ture of the amines present in the Lxture was confirmed spectroscopically
and chemically. Reaction of trimethyl-silyl-butenyne with lithium piperi-
dide gave a mixture of silicon-free amines with silicon-containing amines.
The former product consisted of nearly pure I-piperidino-butyne-3. Ana-
lysis gave 90% of a compound with an acetylene group in end position whose
infrared spectrum rather corresponded to that of 1-piperidino-butyne-5.
The second product is an adduct of piperidine to-trimethyl-ailyl-buten-3-
-yne-1 and, with respqQt to structure, also an acetylene compound. It was
ihus confirmed that, contrary'to.v;nyl acetylenes.p the' iTtrimethyle-silyl.
-buten-3-yne-1 tends to form acetylene compounds in reactions with lithium
n '@nds on.Ahe nature of the amine,
dialkyl amidesk The mode of additio dep
The formation of silicon-free compounds seems to be due to the instability
of the G- Si to'base-s. The tw'o,''resuitant s1licon-containing amines
are coIlorless oils completely soluble in dilute hydrochloric acid. If
they are separated from this 80lutionj they areq howevery partially clef-.'
at the 0 - Si- bond. There are 1 figure and 6 referencese 5 Sovilet-bloo
and 1-non-Soviet-bloc. The reference to the English language-publication
rea,de 4s followsr. E.Lo Warriskg ;.Am.Chem..Soc.q 68,.2455, (1946).
Card

22203
-)/'079/61/031/006/004/005
D223/D305
AUTHORS: Stadnichuk, Petrov, A.A.
TITLE: Hydrogenewation of enin silicon-hydrocarbons
PERIODICAL: Zhurnal obshchey khimii, v.31, no.6,1961, 1855-1861
TEXT: In the present work the hydrogeneration of silicon
containing enins at ordinary temperatures in the solution of metha-
nol and presence of Pd/CaCO was carried out. The hy@rogeneration
of.compounds was carried ou@ with differently placed methyl groups,. I
in an enin system ( 1-trimethyls*iliconebutene-3-in-1, 1-trimethyl-.f',.'
siliconepeutene-l-in-1, 1-trimethylsilicone-3-methylbutene-3-in-1
and also 1-trimethysiliconetriethylene-cyclohexone-1) and with d_Jf_;
ferently positiotLed silicon atom (1-triethylsilicone-and 1-triphe-',
nylsiliconebuten@-3-in-l). The reaction either interupted after J,'
addition of 1 moie of hydrogen per-1 mole of initial material or it
terminated. Theiplot of exhau@stion rate@ of hydrogeneration in al@
investigated cas s show clearly two maxima,(Figure 1), correspondink
to the binding ot 0.8 and 1.4-moles of hydro6en. The binding of thb
Card 1/7

2220-3
Hydrogeneration
IbV
140
Zt? zoo
Ct
160 -
Card 2/7
S/079/61/031/006/004/005
D223/D305
enin silicon-hydrocarbons Fig. 1 hydrogenera-
tion rate curves.
1) 1-trimethylsili
conebutene-3-in-1
of
2) 1-trimethylsili-
conepeutene-3-in-1
3) 1-trimethylsili-
cone-3-methylbutene-
-in-l. 4) 1-trimetb-.
3
y1siliconeethylene
cyclohexone-1. -
pur_ t. Rpnowe CHOPOGTa r"APPOnanun.
zo 30 40
_pe
Tit.,TcitmLz-3-xeTstjxoyTeit-3~.uit;.I', i - I-TpitmeTitnciLziumTlUtiLiLiumiorexceit-t.

22203
S'79/61/031/006/004/005
D223/D305
Hydrogeneration of enin silicon-hydrocarbons
third mole of hydrogen proceeds very slowly. The initial hydroge-
neration rate is slightly decreased by substitution into the enin
system. The pronounced character of the curves of hydrogeneration
rates point out the preferential ways of the hydrogeneration pro-
cess, while on the other hand the experiments on hydrogeneration
using teacting components ratio 1 : 1 showed no signs of preferenti-
ations. Based on the results of experiments of additions of 1
mole of hydrogen to enins, the formation of the following three
types of siliconhydrocarbons could be deduced;
R3S-4 - CH = CH - C = CH - Rif R3Si - C = C - CH - CH 2 -Rif
I I
R3Si - CH = C = C - CH2 - Rif
I
The structure of the products of hydrogeneration were found by
Card 3/7

22203
S/07 61/031/006/004/005
D223YD305
Hydrogeneration of enin silicon-hydrocarbons
infra-red spectrum and by chemical methods. The comparison of the
infra-red spectrums of the hydrogeneration products and initial
sil-conehydrocarbons showed that in all results of hydrogeneration
new double substituted acetyelenes wer-@formed. The acetylene bond
in silicon containing enins is revealed by the characteristic bond
@ntensity at about 2150 cm-1. The acetylene siliconehydrocarvons
formed by hydrogeneration showed absorption at about 2170 cm--.
These acetylene bond absorption bonds appear intensive which indi-
ca-les the appreciable acetyelene content of the hydrogeneration
products. The infra-red spectrums of hydrogeneration products
showed the appearance of a new bond in the region _'940 cm-1 of me-
dium and weak intensity. The absorption in this region indicates
the formation of small quantities of allenes, i.e. of partial ad-
dition of hydrogen into 1.4-position, but this was not detected in
the case of siliconehydrocarbons -not containing vinyl group ( 1-tri-
methylsiliconepeutene-3-in-1 and 1-trimethylsiliconeethylenecyclo-
hexene-1). The chemical methods of establishing the structure of
the hydrogeneration products were based on ability to add hydrogen
Ca-,:-d 4/7

22203
S/079/031/006/004/005
D223/D305
Hydrogeneration of enin silicon-hydrocarbons
across the double bond, The gaseous hydrocarbons obtained by the
hydrolytic separation rf tl,.,'@ h-,,JroE@encrfation products of 1-trimet4:-
isiliconebutene-3-in-1, 601,',, of which were removed, contained about
95% of acetylene and about 2% of dienea. Unreacted part of initial.
material, judged by the infra-red spectrum does not differ in
composition from the latter. The ozonation of hydrogeneration
products gave propionic, acetic and oxalic acids. Formation of
ace-11-ic acid confirms the partial binding of hydrogen to the 1.4
position, while the formation of propionic acid ( main product of
oxtdation) confirms the acetylene structure of the main hydrogene-
ration product. Comparison of the constants'of hydrogeneration pro-
ducts and some trialyylsiliconealkyldienes-1.3 also indicates the
formation of acetylene bonds and not diene bonding of hydrogenera-
tion. These later ones possess a high refractive index as for
instance 1-trimethyloiliconbutadiene-.1.3 , n3O = 1.4478 ( Ref 9:
A.D. Petrov, S.I. Sadykhzade, Izv. AN SSSR, OEhN, 1956, 513 and
Ref 10., 3.,1, Sadykhzade, I.V. Avgushevich and A.D. Petrov, DAN
Card 5/7

22203
S/079/031/006/004/005
D223/D305
Hydrogeneration of enin silicon-hydrocarbons
SSSR, 112, 662, (1957)), and a product of hydrogeneration of 1-tri-
methylsiliconbutene-3-in-1 which could have contained diene, had
refractive index n.,20 = 1.4310. It was, thus, established that
enin siliconhydroctlrbons would hydrogenerate on the palladium in
a1i three directions but preferably across the double bond. This
postulate is exampled in the case of 3-ethylsilicone and 3-phenylsi-
liconebuterj-3-in-l which possess bulky substitutes in position 1*
Following tnis the catalytic hydrogeneration of silicon hydrocarb-
on.s is similar to the enin hydrocarbons, the difference between the
two groups is probably connected with the influence of space factcrs
which bring about absorption across the triple bond and then abso-
rption and hence hydrogeneration tollow the course of double bond.
Since ethylene bond hydrogenerates easier than acetylene (Ref 112
G.C. Bond, Quart. Rev. 8, 279, 1954) then correspondingly the ad-
d4-tion rate of the first and second mole of hydrogen in the case
of enin siliconhydrocarbons is the same as in siM41arly structured
hydrocarbons. The-increase in apace difficulties brings about an
Card 6/7

22203
S/79/61/0-1/006/004/005
D223/IY305
Hydrogeneration of enin silicon-hydrocarbons
appreciable decrease in the hydrogeneration rate of 1-trimethylsili--
conethylenecyclohexene when compared with 1-trimethylsiliconebutene
-3,-in-1 and others.. Especially the slow hydrogeneration rate of
1-triphenylsiliconbi.itene-3-in-1 could be a result of polarization
which decreases the electron density of the double bond, resulting'
in absorption on palladium and consequently slower hydrogeneration.
There are three tables, 2 figures and 16 referenc-:T,@ 14 Soviet-
bloc and 2 non-Soviet-bloc. The references io the English-langua&e
Dublications read as follows: G.C. Bond, Quart. Rev. 8 " 279,(1954);
@.C. Whitmore, L,H. Sommer et al., J. Am.Chem.Soc., 68, 475,(1946).
ASSOCIATIONg Lenin radskiy tekhnologicheskiy institut imeni Lenso-
veta @ Leningrad Technological Institute imeni Lenso-
vet)
SUBMITTED g June 29, 1960
Card 7/7

@02 2 R D305
11 - A . At I Il P. a I
, . a K
T ITLE The d i po I e womeu ts m r ka - e to rew- cm a pti t V
snui,@ v@-u I a hyl r-) r a rbo n and s I I i cohv(l-)f.-ar(-,@ons
PERIODICAL-, zhu ru'll Obsll@hpv k1timi i 3 Ito,, 11 9 6 1 -3 5 2 1 3
TEXT - Th Au t.bc) rs flowpfo e Lh@ di f)o le wotn@@a ts of four Pain hyd i
-a -bija@ w i t1i I - r t o bu t y I ats 4 f--i lib.-r YA r ad i @@ at %n4l f I v @- a a j@; 1 ) 1
with a ,--)pl- bondsd, grnllpiUg In 0, J@r
f h b "? t P,
rs? n - '@ in khc- refi('tiolz. '@@J'Prlr
0')F-k in Ibis t!fild has beon ilow@ t@v A- k. P@- n2-, S. Mtriv@t`
tn (R"f, 4, 1),)kl , &,'4 SSSH, @.. Z
ind 13, S 6 2 9 55;"-@ R - f
kh; a, i i '19, -3Z32: 1959) r.4 ottir-, cn tus t p v--v
T bvd(ocu,l)orw.@ -clre fj-epar,-@.J in thf;
1 1) rr p@ n ji --- r; v c;'I'@- tl.v lhj@ rlielhIll )f T.
@f t Z It h b - 3

Sro;q '61 -(Vi
Tb@ djp!@I- 42 D3 0
a f a I i11 Z': IIN 1 -2 t 1 o n -D p(-tp-nv1 t, r z r,
ficl t - o@
o fo
t1)h - q @;l - jt@ 1@
b
LiT.
t()7! J' L
I na !111 1@1- i- I ;I
Z'z iz
i'j

The dipole moments..,
S.1079 '1/6.1 /031 /011 /002 /015
D228,/D305
ser-qe.l in the s il i cohydro carbons, although such compounds tend t-D ha-s-
smaller dipole moments, which may be due to the displacement of fr-@
electron pairs of the fialoirrens o@ oxygen to the side of the Si atom,
whose 4-shefl is unfilled@ However, the orientation of the dipole moment
in the molecules of the silicohydrocarbons doeR not appeac to differ from
that in the molecules of the corresponding hydrocarbons, There are 2
Cables and 9 referen,7:es@ 7 Sovjet@-bloc and 2 non-.Soltiet- bloc, T(v? r.4er'.
eacee to tbe English-language publications read as follows- W. H@
Carother@.? G, J. Berebet, J. Am, Chem@ Soc.., 55., 1095 (1933)f C, Eabo-n.,
Silycoorgo comp-., London-, 1960-
AS 30 C TAT I G NLqningradskiy teklinologicheskiy institut im. Lenso-eta
(Leningrad Technological Institut,& im, ten_,ovat)
SUM I TTLI D November 30, 1.960
Card 3/3

00
2726o
S/020/6!/139/005/013/021
B';03JB217
AUTHORS: Petrov, A@ A., Stadnichuk, M. D., and Kheruze, Yu. I.
TITLE: Addition of triphenyl methyl radicals to enyne hydrocarbons
and silicon hydrocarbons
PERIODICAL: Akademiya nauk SSSR@ Doklady, v. 139, no. 5, 1961, 1124-1127
TEXT: The authors found that isopropenyl acetylene is not the only compound
that adds triphenyl-methyl radi@als -In 1#4-position according to A. F.
Thompson '; Jr., D. M. Surgenor, (Ref. 1: J. Am. Chem. Soc-, 65, 486 (1943)).
When triphenyl chlorc methane and metallic mercury reacted with vinyl methyl
acetylene (I), they obtained a crystalline adduct C 43H36. The latter had, in
its infrared spectrum, a rather intensive band of the allene group at about
i
1960 cm-' (Fig. 1,4), whereas the bands characteristic of acetylene and
vinyl groups were @acking. Therefore, the structure
(C6H 5)3 C-C-C@CH-CH2-C(C 6H 5)3 was ascribed to this adduct. A 1,4-adduct is
6H 3
-V,@;rmed analogously on addition of triphenyl methyl radicals to vinyl-tert-
Card I

2726o
S/020/61/139/005/013/021
Addition of triphenyl methyl B103/B217
butyl acetylene (II) which, however, could not be separated in pure state.
Its infrared spectrum is given in Fig. 1)2. Triphenyl methyl radicals are
added to silicon-containing enyxies in different order according to structure,
in oontrast to vinyl acetylene hydrocarbons. Thus, vinyl trimethyl silyl
acetylene (1-trimethy'L silyl butene-3-ine-1) (III) mainly adds to the double
bond. An intensive band 2!68 am-, of the triple bond exists in the infrared
spectrum of the adduct, and a weak band in the range of 1945 cm-1 where the
absorption of allene compounds usually takes place (Fig. 1,3). The adduct
structure was also chemically confirmed. A hydrocarbon with an acetylene
end group was obtained (97-5-98%) according to the scheme
(CH ) Si-C=-C-CH-CH H ) -
3 3 2-C(C 6 5 3 HC=C-CH-CH 2'- C(C6H5 3
1 1
C(C6 H5)3 C(C 6 H5)3
due to hydrolytic cleavage of this substance. The structure of the hydro-
carbon was proved by means of argentometric titration and by the infrared
spectrum; the intensive frequency 3315 cm-1 of the acetylene end group
(Fig@ 1,5) was detected. This hydrocarbon is, according to its structure,
an isomer of the 1,4-adduct of the triphenyl methyl radicals to vinyl
acetylene, and differs from this isomer only by a higher melting point.
Card 2/ @

2726o
S/020/61/139/005/013//021
Addition of triphenyl methyl B103/B217
Isopropenyl trimethyl silyl acetylene (1-trimethyl silyl-3-methyl butene-3-
ine-1.) (IV) adds triphenyl methyl radicals in 1A-Position, i.e., in the
same direction as enyne hydrocarbons. Triphenyl methane is formed in this
case as by-.product (17% for IV, 6% for V). An intensive band (1930 cm-1) Of
the allene group exists in the infrared spectrum of the adduct, whereas the
bands of the acetylene bond is lacking (Fig. 1,4)@ An allene hydrocarbon
described in the literature (Ref, 1) is formed by hydrolytic cleavage. The
structure of the adduct of tripnenyl methyl radicals to propenyl trimethyl
silyl acetylene (1-trimethyl silyl pentene-3-ine-1) (V) has hitherto not
been reliably determined. It is assumed to have a l-,3-diene structure, since
neither an allene nor an acetylene group exists in its infrared spectrum.
The authors explain the difference in the order of addition of triphenyl
methyl radicals to hydrocarbon (II) and silicon hydrocarbon (III) Of
analogous structure by increasing steric hindrances for the acetylene bond
in transItion from quaternary hydrocarbon to quaternary silicon. Steric
hindrances also oc--ur at the double bond of silicon hydrocarbons IV and V.
Therefore, the 1,4-addition is more favorable. Addition is now retarded,
which is proved by a lover yield of adducts and by fcrmation of triphenyl
methane. The authors! exDerimen'@s were conducted with a mixture of tri-
Card 3/Y

27260
S/020/61/139/005/013/021
Addition of triphenyl [e-mail] B103/B217
phenyl chloro methane (melting point 1108-1120C) with an excess of enyne
compound, benzene, and metallic mercury (10--fold excess). The mixture was
shaken for several days in a hermetically sealed glass in protective gas
atmosphere. Then, the excess of er-yne and solvent was distilled off, the
residue extracted with ether. The ether was distilled off, the residual oil,
when standing, crystallized more or.less quickly. The adducts were
recrystallized from petroleum ather or from acetone. All adducts (constants
and data see Table 1) are weakly soluble ir ether, 'petroleum ether, acetone,
Ccl 41 and practically unsoluble in alcohol. The adduct of silicon hydro-
carbons (.V) -is a'most unsoluble. Hydrolysis of the adducts of (III) and
(IV) was raalize(, by boiling with aL-Dholic KOH solution (25--fold excess)
for 35 hr. I. A, Tgare4-ina assisted in synthesis. There are 1 figure,
table, and 4 riferelices: 3 Soviet-bloc and I non-Soviet-bloc.
ASSOCIATION: liiingradskiy tekhnolog4cheskiy insti"@ut im. Lensoveta
4ningrad Technolcc
)gical Inst1tute imeni Lensovet)
Card 4//Y

8/079/62/03?/008/001/006
D204/D307
AUTHORS3 Stadnichuk, M.D. and Petrov, A.A.
TITLEt Investigations of conjugated systems. CLVIII.
The addition of Li alkyls to trimetbylailyl-
iao-propenyl- (A) and to trimethylailyl-pro-
j7e;@l-acetylene (B)
PERIODICALt Zhurnal obahchey khimii, v- 32, no. 6, 1962,
249o - 2494
TEXT: The reactions of LiBu and LiPr with A and B
were studied to determine the structural influences of the enyne
ing on the direction of addition. The addi tion of A to LiBu
group
gave a product, C, which after treatment with water and hydrolysis
with ale. KOH gave a mixture of hydrocarbons containing , 24 % of
compounds possessing a terminal triple bond. Infrared spectroscopy
revealed that G use a mixture of allcuic and acetylene compounds,
the-most important product being (CH 3)3S.ICH C CH2 - C H
4 9*
CH
Card 1/2, -3

S/079/62/032/008/001/006
Investigations of conjugated D204/D307
Analogous results were found for the addition of LiPr and A. The
addition of B to LiBu gave aproduct, D , which on hydrolysis yielded
hydrocarbons containing @j4l % of substituted'acetylenes. The allenic
part of D was mainly (CH 3,3SiCH - C - qH - C4H9- These differences
CH3
are explained by the different electron displacements in the case of
A and B (resulting in unequal polarization of the 1,4 positions) and
by the steric effect of _CH3 in A, The differences between the addi
tion products of Li alkyls and (a) vinyl alkyl acetylene, and (b
silicon containing enynes, (i.e. the formation of a greater proportion
of acetylenes in the latter case), are ascribed to' the steric effect
of the Si (CHI)3 group and to a partial transfer of the3celectrons
from th; triple bond into the d-orbit of silicon. There are 3 figures.-:
ASSOCIATION&
SUBMITTEDt
Card 2/2
Leningradakiy tekhnologicheakiy institut imeni Lensoveta
(Leningrad Techndlogical Institute ime3d Lensovet)
July12, 1961

8/079 62/032/Oli/002/012
D204YD307
AUTHORS: Stadnichuk, M.D., and Petrov# A.A.
TITLE: Investigations of conjugated systems. CLXI. The addi-
tion of silicon hydrides to 1-trimethylbuten-3-yrie-1
(A)
PERIODICAL: Zhurnal obahchey khimii, V. 32, no. 11, 1962'V 3514-3521
TEXT: The additions of MeSiHC121 EtSiHC121 SiHC1 3' Isle3SiH and Et3
SiH to A were studied, in. the presence of H ptel
. 2 61 investigating
the addition products by ir spectroscopyv.nuclear magnetic resonan-
ce, and by chemical methods. Addition of MeSiHC12 to A, initially
at 8500 (self-heating) and then for 8 hre. at 10000, followed by me-
thylation of the productp gave (CH 3)3 Si-SH C - CH = CH20 In the
;Si(CH 3)3
absence of prolonged heating during the addi,tion reaction a,certain
amount of
C Card 1/2

8/079/62/032/011/003/012
D204/D307
AUTHORS: Stadnichukv M.D., and Petrovt A.A.
TITLE: Investigations of conjugated systems CLXII- The nature
of the additions of bromine and hydrogen to vinyl@- (A)
and allyl - (B) dimethylvinyla'cetylenylsilanes
PERIODICAL: Zhurnal obshchey khimJit v. 32, no. 11, 1962'
3522 3527
TEXT: Compound A was synthesized by the mixing of cold vinyltri-
chlorosilane with magnesium bromovinylacetylene, allowing the mix-
ture to stand for 14 hrs.9 heating at 10000 for 2.5 hrs. I cooling
to -50Ct heating with BrMgCH3 and heating:for 3 hrso. at 1000C.' Com-
pound B was prepared by the addition of allyldimethylehlorosilane
to cooled Mg bromovinylacetylenep boiling for 2 hre., allowing to
stand for 3 hrs. and cooling with wateroReaction of A with Br20 in
CHC1 solution, at -10 to -120C# over 4 hrs.p gave rise to a pro-
3
duct which in spectroscopy and chemical tests showed*to be CH2Br_
Card 1/2

S/020/62/145/004/019/024
B110/B144
U '0 11 O'i S Pedorova, A..V., Stadnichuk, M. D., and Petrov, A. A.
Z n o@' :,-.e4-hyl dichlorosilane to allene hydrocarbons
: A d _4 i t' + 6,-
P --,'R 10 D T CL'kademiya nauk SSSR. Doklady, v. .145, no. 4, 1962, 837 - 840
'2:@X'I- :The addition.of methyl dichlorosilarie to propyl and butyl allenes
@@3 .-,ell.as to methyl propyl and methyl amyl allenes in the presence of
-@'@Cl, was investi- .'ed. The monoadducts. ivere subjected to jR-szectral
0 au
and ozonolytical anal,rSiS and to hydration. The effect of adding -.Iethyl
w
-@c.'-Iorosilane to olefins depends evidently on a nucleophilic mechanism
firstly, the hydride ion attaches itself.to the central atom of
t'-.-e allene system. Since the direction of addition is determined
@;-;ericaily, a 1,2-additior. takes place in the case of monosubstituted
a`---enes, but addition on the small radical in the case of disubstituted
..'-'enas. The properties of all monoadducts are listed (Table 2). There
1 f4CUre and 2 tables.
Lenin'gradskiy tekhnologichesk-iy institut im. Lensoveta
(Leningrad Technological Institute imeni Lensovet)

@,AccEssi6iiNR:' AP3001481
S/0079/63/933/005/1421/1424'
..AUTHOR: Stadnichuk, M. DP
:TITLE: Hydrogenation and bromination of 1 -tr4met ylsftyl-3-ter iary butyl
h t
-"butene-3-ine-1
@SOURCE:' Zhurnal obahchey khtmii, v. 33,.no. 5, 1963, 1421-1424
WPM TAGS: hydrogenation, bro'mination, 1-trirniathylsilyl-3 -tertiary butylw
'butene-3-ine-1
1ABSTRACT: 'Hydrogenation andbromination of 1-trimethylsilyl-3-tert. butyl-
@butene-3-ine-l indicated reactiona were different from those with the analogous
11 -trim ethylailyl- 3 -methyl-butene - 3 - ine - 1. Bromination yielded a mixture of ace-1
tylenic and of 1, 3-diene dibromide silyl *hydrocarbon ia6mers. Hydrogenation
;yielded the corresponding acetyldnidr.and the allene sityl hydrocarbons. Identify-
jing IR spectra and physical and chemical data are give
n. Orig. art. has: I
@.@'*gure and 9 form'ulas.
!card 1/2

YAKOVLEVA, T.V.I__@'PADNICHUK, M.D.; PETROV, A.A.
11@--
Vibrational spectra and the structure of organic ccmpounds.
Part 9. Opt. i spektr. 16 nom 4:573-576 Ap 164. (MIPUA 17:5)

GANUSHCHAK, II.I.; YUKH%ENKO, M.M.; STARIICHUK, M.D.; DOMBROVSKIY, A.V.
Haloarylation of unsaturated compounds with arolatic diazo
compounds. Part 18:Chloroarylation of diisopropenyle Zhur, obe
khim. 34 no.7:2238-22U Jl 164 OIRA 17:8)
1. Chemovitskiy gosudarstvannyy universitet i Leningradskiy
tekhnologicheskiy institut imeni Lensoveta.

L 166f.6-65 ET;JT(m)1EFF(c)1FwTTP(j)@r Pc-4/.Pr-4 FI-1
ACCESSION NR: AP4044195 S/0079/64/034/008/2625/2630
AUTHOR: Shakhovskoy, B. G. Stadnichuk- M. D. Petrov, A. A.
TITLE: Investigations in the area of unsaturated organosilicon compounds, XIV.
Synthesis and hydrogenation of certain c2RIpgated di e silicon hydrocarbons
q
SOURCE: Zhurnal obshchey khimii, v. 34, no, S. 1964, 2525-2630
TOPIC TAGS: unsaturated organosilicon compound, conjugated diyne silicon hy-.
drocarbon, diacetylenic silicon hydrocarbon, alkadiyne magnesium bromide, te-
traalkylsilane, hydrogenation, catalytic hydrogenation
ABSTRACT: Diacetylenic silicon hydrocarbons with the silicon atom at the triple
bond were synthesized, then hydrogenated in the presence of Pdf CaC03. 1-Tri-
methylsilylpentadiine-1,3, 1-trimethylsilylhexadiine-1,3, 1-trimethylsilylhep-
tadiine- 1, 3 were obtained by reacti ng the suitable alkadiine magnesium bromide
with trimethylchlorosilane in a nitrogen atmosphere. Upon reduction of these
compounds, the first mole of hydrogen added rapidly to the triple bond not linked
@Card 1/2

ACCESSION NR: AP4044195
to the Si (aL to the Si atom) and subsequent hydrogenation to the tetraalkylsilane
proceeded much more slowly. IR spectra for the diacetylenic compounds nd the
reduction products were obtained and discussed in detail. Orig. art.. has: 3
figures and 1 table
ASSOCIATION- Leningradskiy tekhnologicheskiy institut imeni Lensoveta
(LeninLyrad Technological Institute)
SUBMITTED: 13Jun63 ENCL: 00
SUB CODE: 00- NO REF SOV: 008 OTHER: 004
C.rd 2/2
J

-) @ ! - jP. ; ; i - .." ;
@ - . . j " , 1 ; . i " .
Uns a -lad or z an csiiicon com-pounds . P a --@ 15 -. Add ition of --On
hydrides to cyclic enyne hydrocarbons. Zhur. ob. kh-Lm- 34 no.9:
2931-2934 S 164. (MIFA 17:1-1)
i. Leningradskiy tekhnologicheskiy institut imen-i Lensoveta.

STADNICHUK, M.D.; HINGAILVA, K.S.; FE'.',ROl, A.A.
Dipole moments and the structure of k,3-diene silicon hydrocarbons.
Zhur. ob. khim. 34 no.10:3289-3291 0 164.
(MIRA 17:11)
1. Leningradskiy tekhnologicheskiy institut imehi Lensoveta.

L 4242o-61 EWT (m) E OF(
P 1@
NR: APS008836 S/0019/65/035/003/0451/0456
AUTHOR: Stadnichuk, M. D.; Petrov, A. A.
TITLE: Synthesis and some physical and chemical properties of enyne type germani
'containirg hydr2carbons
SOURCE: Zhurnal obsbchey khimii, v. 35, no. 3, 1965,.451-456
.TOPIC TAGS: gernanium organic compound, spectrum, nuclear magnetic resonances
hydrogenation
ABSTRACT:: Only a few reprbsentatives of germanium, organic compounds are known.
:which have a triple bond in the -, 0- and y-positions with respect to germaniuns.
!This article presents data on the synthesis, physical properties and some chemical
@transformations of-three enyne germanium-containing hydrocarbons: 1-triethylger-
imanium-3--butene-1-yne (1), 1-triethylgermanium-3-methyl-3-.;butene-1-yne (11) and
il-trieth:ylgermanitL,n-3-pentene-1-yne (III). The purity of these compounds was deter-_
,mined by liquid-gas phase chromatography. Their structure was verified by infrared
and nuclear magnetic resonance. spectre. In the 1R spectra of the obtained compoun&
the 2147 cm-1 band corresponding to the triple bond in the'a-position with respect
to germanium does not differ from silicon analogs. Dipole moments were measured
,.Card,

STADNICHH, M.D.; PETROV, A.A.
Study of unsaturated organogermani-am compounds. Part 2: Course
of the bromination of 1,3-enyne germanium hydrocarbons. Zhur.
ob. khim. 35 no-4:700-704 Ap 165.
(MIRA 18: 5)
1. Leningradskiy tekhnologichesk4-y institut iriteni Lensoveta.

KPMELINITISF, 111, R,A,; I@OLYAKOVA, A@A- PFIMOV, A,A.; PEADVEDI-11J, F@A.-
Mass spectra ard structure of organic compounds. Part. 1-1i Mfas5
spectra of l,j%..-?nyne germanium hydrocarj)ons. Zhur. ob. khim.
35 no.5:7711-776 My 165. (MIRA 18-6)
1. Vsesoyuznyy nauchnc--'~!3!3'~edova-;.-ellskiy institut po pererabotke
nefti i gaza i Leningradskiy tekhaolog-icheskiy institut i'men!
Lensoveta.

I it F I joV 'W',, f P. AD,'-f I --li I I K , IM Pi,-MOV, A.A.
Un:!attirated organo.-:1 licon nompczuids. Par' 174
bromination of some conjugated d-4yne silicon
Zhur. ob. kh@-m. 0 '05.
Leningradsk-y tekhnologicheskly institut :Lmen'- Lenc3oqeta.
L

L 06504-67 EW P.(-i) IVIT (m RM
ACC NRi AP7000488 SOURCE CODE: UR/00'19/66/036/006/i@56/11@i
AUTHOR: Ganushchak, N. I.; Yukhomenko, M. M.; Stadnichuk, M. D.; Shevchuk, M. 1.
ORG: Chernovitskiy State University (Chernovitskiy gosudarstvennyy universitet);
Lenin-g-ra-4-7echnological Institute im. Lensovet (Leningradskiy tekhnologicheskiy
institut)
TITLE: SvnthesiA- of certain phosphonium. S'" 3q
the basis of chloroarylbutenes _@@a@lts d 1,5-diphenylpentadiene I on
SOURCE: Zhurnal obshchey khimil,, V- 36, no. 6, 1966, 1150-1153
TOPIC TAGS: organic phosphorus compound, organic salt, organic synthetic process
ABSTRACT: The reaction of a number of.chloroarylbutenes with triphenylphos-
phine yielded new triphenyl-(l-arylalkenyl-2)-phosphoniiim chlorides
.[Ai7CH2C(R)+C(RI)CH2P(C6H5~]Cl-. The phosphonium salts were converted to the
corresponding 1,5-diphenylpentadienes-1,3 by reaction with sodium ethylate and
benzaldehyde. The infrared and nuclear magnetic resonance spectra of the pro-
@ducts were studied. The diphenylpentadienes are oily, yellowish liquids,
'which are readily soluble in the usual.organic solvents,, decolorize bromine
water and permanganate solution. They do not take part in diene syntheeis re-
,actions, even_i
.rjt h genop4les as maleic anhydride with heating.
lorig. art. has: 2 figures and I table. -LJPRS: 37,0231
SUB CODE: 07 SUBM DATE: -03Jun65 / ORIG REF: 010
Card 1/1 P,@ UDC: