SCIENTIFIC ABSTRACT SPRINTSYN, M.N. - SPRYSKOV, A.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001652730001-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 25, 2000
• Sequence Number: 1
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

MEDVEDEV, Nikolay Akimovich;,.SPRINTSJN, M.N.V red..; KIMMEL', L.S.,
red. izd-va; BACHURfN_A__,_A-.X.--,_t_eO~. red.
[Forests of the European North and their industrial use]Lesa
Evropeiskogo Severe i ikh promyptLI-ennaia ekspluatataiia. Mo-
skva, Coslesbumizdat, 1962. 124 P. (MIRA 16:2)
(Russia, Northern-Forests and forestry)
(Russia, Northern-Lumbering)

SPRINTSYNY M.N.; AMALITSKIY, V.M.(deceaved]; DENISIYEV) V.I.; ZHUKOV,
T.-F.-;LIKHOVIDOV, N.K.; SHCHEDRIN, B.Ye.; KAFTANOVSKIY, G.M.;
SUKHANOVSKIY, A.I.; TSVETKOV, V.A.[deceased]; MITELIMAN, Ye.L.;
KALASHNIKOV, P.L.; ANDREYEV, I.I., retsenzent; SALTYKOV, M.I.,
otv. red.; SLUTSKER, M.Z., red. izd-va; GRECHISHCHEVA, V.I.,
tekhn. red.
(Handbook for the logging entitprUft economist]Spravochnik eko-
nomista Lespromkhoza. Moskva, Goslesbumizdat, 1962. 291 p.
(MIRA 16:1)
(Lumbering--Handbooks, manuals, etc.)

P, NV
Aavr,
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or *V~1127;-nll
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LIMIA.-
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a_.,, fiva aryinlotb$1 type*

MOKO D.A.; NECHIPOMKO, N.N.; PUSTOVA1OV, V.I.;
SFRISH M KIY, A.I.
Method of insulating suspension devices for galvanizing parts.
Avt.trakt.prom. no-10:29 0 '54. (KTRA 7:10)
1. Kharlkovskiy veloeipednyy zavod.
(Galvanizing)

%11 N&MO, V.I. kr;ndidat khimichnsklkh nauk; TSARIMIN, D.A., kandidat
tokhnichookikh nauk, dotsent; NECHIPORM44KO, N.H., kandidat
tekhnicheskikh nauk, dotsent; PUSTOYAWY, V.I.. inzhener;
SPRISgEVSKIT, -A,
-1., , kandidat tekhnicheskikh nauk.
Insulated hooks for electroplating machine-parts. Vest. mash.
36 no.8:62-63 156. (_qLRA 9:10)
1. Kharlkovskiy velosipednyy savod.
(Electroplating)

25(2)
AUTHORt Sprishevskiy, A. 1., 507/32-25-5-43/53
TITLEt Electronic Automatic Cutout for Machines for the Testing of
Contact Resistance
PERIODICAL: Zavodskaya laboratoriya, 1959, Vol 25, fir 9, PP 1136-1137 (USSR)
ABSTRACT: So far, in contact resistance tests, the fatigue crumbling
of pittings was determined on the basis of the noise change
of the testing machine or by a visual examination 'of thepit-
-t1hg~;.and thdin the electromotor was switched off. An automatic
control of the cutout of the machine at the instant of the
crumbling of the pitting was developed. For this purpose, an
electronic automatic cutout was designed. The basic scheme
of the latter was suggested by the Candidate of Technical
Sciences I. M. Sakhon1ko, while the scheme of the necessary
amplifier was worked out by Engineer V. I. Shchipunov and
D. T--. Pavlov. The-mode of operation of the cutout is based
on the conversion of the mechanical vijyration arising from
the destruction of the pitting into electric signals which
act on an electronic scheme and thus stop the electromotor
Card 1/2 by means of a relay. A piezoelectric transmitter (Fig 1)

PHASE I BOOK EXPLOITATION SOV/5105
Nauchno-tekhnicheskaya konferentsiya po voprosam povysheniya
lznosostoykosti i Broka sluzhby mashin.
Povysheniye iznosostoykosti I sroka Bluzhby mashin. t. 2 (Increas-
ing the Wear Resistance and Extending the Service Life of Ma-
chines. v. 2) Kiyev, Izd-vo AN UkrSSR, 1960. 290 P. 3,000
eoples printed.(Series: Its: Trudy, t. 2)
Sponsoring Agency: Vsesoyuznoye nauchno-tekhnicheskoye obshchestvo
mashinostroitellnoy promyshlennosti. Tsentrallnoye i Kiyevskoye
oblastnoye pravleniya. Institut mekhaniki AN UkrSSR.
Editorial Board: Resp. Ed.: B. D. Grozin; Deputy Resp. Ed.:
D. A. Draygor; M. P. Braun, I. D. Faynerman, I. V. Kragellskiy;
Scientific Secretary: M. L. Barabash; Ed. of v. 2:
Ya. A. Samokhvalov; Tech. Ed.: N. P. Rakhlina.
PURPOSE: This collection of articles is intended for technical
personnel of the machine industry and for workers of scientific
-CArd:~-1_-1tq__

Increasing the Wear-Resistance (Cont.) SOV/5105
research institutes and design and planning organizations.
COVERAGE: The collection contains papers presented at the Third
Scientific Technical Conference held,in Kiyev in September 1957*
on problems of increasing the wear resistance and extending the
service life of machines. The conference was sponsored by the
Institut stroitellnoy mekhaniki AN UkrSSR (Institute of Struc-
tural Mechanics of the Academy of Sciences Ukrainian SSR), and
by the Kiyevskaya oblastnaya organizatsiya, nauchno-tekhnicheskogo,
obshchestva mashinostroltellnoy promyshlennosti (Kiyev Regional
Organization of the Scientific Technical Society of the Machine-
Building Industry). Papers presented at the conference were
published in two volumes. The firstvolume contains papers
presented at the plenary session and at the conference section
on "Wear of Metals and Methods of Investigation". The second
volume contains papers presented at the conference section on
"Methods of Extending the Service Life of Machine Parts". These
pEpersd1scuss mechanical, chemical, and electrolytic methods of
increasing the durability (wear resistance and fatigue strength).
--Ca:rd--2-/-9
Increasing the Wear-Resistance (Cont.) SOV/5105
Of metall1c and nonmetallic machine parts. Only methods which
have found Industrial application are reviewed. In addition to
members of the editorial board the following persons participat-
od In the preparation Of the papers for publication: Professor
M. P. Braun, Professor D. V_ Vaynberg, Candidate of Technical
Sciences I- P. Petrenko, Engineer M. D. Sinyav8kaya, Candidate
of Technical Sciences V. A. Shevchuk) Candidate Of Technical
Sciences V. N. Semirog-Orlik, Engineer V. F. Yankevich, Candidate
of Technical Sciences M. L. Gorb, and others. References (mostly
Soviet) accompany some of the papers.
TABLE OF CONTENTS:
Foreword
5
Balashov, B. Increasing the Fatigue Resistance Of Parts by
Cold Working
Allshits, I. Ya. [Candidate Of Technical Sciences], and 7
L. N. Sushkina. New Bearing Materials and Coatings :L8
Card--a-z-
.;/ 9~

Increasing the Wear-Resistance (Cont.) SOV/5105
Astaflyev, S. S. [Candidate of Technical Sciences).
Electrospark Hardening of Machine Parts 28
-_ ge __.k. (Candidate of Technical Sciences]. The
Sprish vq-kiy,.-A,
-Effect of Manufacturing Accuracy on the Increase of the
Efficiency of Rolling'Bearings 40
Kuz1mIn, M. 1. Work-Hardening and Burnishing of Gear Teeth 47
Formin' G. T. Increasing Wear Resistance and Prolonging the
Service Life of Parts With Large Cross-Section Area by
Surface Hardening After Rapid Heating In Furnaces 57
Panchenko, N. P. [Candidate of Technical Sciences]. Re-
sidual Strain of R:Ings Made of ShKhl5 Steel 70
Shevchenko, P. V. [Candidate of Technical Sciences). In-
vestigation of Damages to the Contact Surface of [Railroad-
Car] Wheels and Measures Taken to Increase Their Strength
and Extend Their Service Life 83

9/123/61/000/015/017/032
A004/A101
AUTHORS: Grozin, B. D., Panchenko, N. P., Semirog-Orlik, V. N., Sprishavskiy,
A. I.
TITLE: The effect of mechanical operations on the state of the outer layers
of antifriction bearings
PERIODICAL: Referativnyy zhurnal, Mashinostroyeniye, no. 15, 1961, 19, abstract,
15BIll (V sb. "Povysheniye iznosostoykosti i sroka sluzhby mashin.
V. if?. Klyev, AN UkrSSR, 1960, 61-76)
TEXT: The authors present the results of comprehensive investigations of
the effect of mechanical working on the physical state of the outer layers of the
antifriction surfaces of antifriction bearing races. Foxt groups.of.specimens of
bearing races were investigated, the manufacturing techhology and processing
conditions of which were different. The specimens were subjected to metallo-
graphic, electronic microscopic, X-ray structure and spectral analyses; their
microhardness was also investigated. During some grinding conditions and other
operations carried out after hardening, high temperatures and local pressures are
arising, the interaction of which causes structural transformations in the surface
Card 1/2

S/123/61/000/015/017/032
The effect of mechanical operations ... A004/AIOI J
layer. The thermal effect during grinding is different in the field of surface
projections and cavities. The projections may undergo a second hardening, while
the cavities mainly experience a tempering. The non-homogenilty of the outer
layer produces structural stress raisers owing to which micro-destructions are
possible in the surface layer. The thermal effect arising during the process of
after-hardening operations contributes to the concentration of chromium and
carbon at the surface. The initial microgeometry and the shape of the surface
being machined affect the temperature gradient of the outer layer. The defective
layer originating during the preceding operations cannot always be eliminated by
technological finishing operations. The investigation shows the way of develop-
ing dependable processing conditions. There are 21 figures.
M. Borts
[Abstracter's note: Complete translation]
Card 2/2

KACHANOV, N.N.; SPRISMSKIY, A.I.; KYASIB, G.A.; BARNSHTEYN, M.L.-
What abould a modern metallograpb1c microscope be like?
Zav.lab. 26 no.6:770-773 16o. (MIRA 13:7)
1. Nauchno-issledovatellskiy i eksperimentallnyy institut
podshipnikovoy promyeblennosti (for Kacbanov and Sprishev-
skiy). 2. TSentrallnaya zavodskaya laboratoriya ZIatoustov-
skogo metallurgicbeskogo zavoda imeni I.Y.Stalina (for
Khasin)- 3- Mosko-7Bkiy institut stali im. I.T.Stalina
(for BernBhteyn).
(Microscope)

SPIUSIEVSKIY7 A,I., lcawi.tekhn-nauk; IMAMV, L-M-P i"h*
Over-a.U mechanization and-automation in the.bearing industry. Mekh.
i avtom. proizv. 15 no. 5:1-7 My 2-61. 1(MIRA J-4: 5)
(Bearing industi7-Technological innovations)
(Automation)

SPRISHEVSKIY, V. I.
Bronze Age site at Chust. Sov.etn. no-3:69-76 154. (MLRA 7:11)
(Ghust--Bronze Age) (Bronze Age--Ghust)

RUBIBSKIY, N.; SPRISKOV. V.
Superior operatiox of a trolley bus service center. Zhil.-kom.
khoz.5 no.6:16-17 155- (MLRA 9:1)
l.Director Vt*rogo trelloybusnoge dope Moskry (for RubizekAy)
2.Glaniyy Inshoner trolloybusnogo dope Noskvy (for Sprtskov).
(Moscow--Trolley buses--Maintenence and repair)

SPRIMIWI -L.M.
-I-,,.--''. 'P-
Devel:)pment o'L the te~.hnolcgy forr a simplifled preparation of,
brandy. TrudyMN7111'-4~11-27 164. (M-.LRA.

KROVITIS, Yen Yanovich [Kronitis, J.1; ZANDER, R., spets. red.; SPRIVULIS,Z.1.
red.; MIRONOV, A., tekhn. red.
[Manual for collective farm foresters] Spravochni kolkhoznogo leso-
voda. Perevod so 2-go izd. Riga, Latviiskoe gos. izd-vo 1959. 446 p.
IKIRA 14:10)
(Collective fqrms) (ForestArs)
I

EGLITIS, Oskars7 SPRIVULIS, Z. red.-, LJDRE V., tekhn. red.
1
(Beekeeping equipment] Blokopibas inventars. Riga, Latvijas
Valsts izdevnieciba, 1962. 179 p. V. (MIRA 16:5)
lBee culture)

1,TU'-,S11KIN,A. [14eieskins,A.], kand. oollkhoz. nauki SPRIVULIS, Z. [tr~mchtorl;
i"ElLAMEYA., red.; ~TZIOPIETE, M., teklin. red.'
[Best varieties of vegetables, potatoes, and fodee--- root crops ] Dar-
zenu, kartupelu un lopbaribas saknaugu labakas skirnes. Otrais par-
stradatais un papildinatais izdemums. Riga, Latvijas Valsts izdev-
nieciba, 1960. 222 p. (In Latvian] (MIRA 14:12)
(Potatoes-Varieties) (Root crops.--Varieties)
(Vegetables-Varieties)

RIHIERS, A; red.; DUNAISKIS, Z., tekhn. red.
[How we prepare for the 22d Congress of the CPSU; achievements
on the "Burtniekill State Farm] FSK-F MI kor-g-resu sagFidot;
padom 'lu saL-miecibas "Burtniekill sasniegtri. Rigal Latvijas
Valsts izdevnieciba, 1961. 57 p. (MIRA 15:3)
(Communist Party of the Soviet Union-Congresses)
(L.-tvla--State farms)

SKRONANIS, A.; SPRIVULIS, Z., red.; AKE, L., tekhn. red.
[DPR-2 milking unit]Slauksanas agregats DPR-2. Rdga, Latvijas
Valsts izdevnieciba, 1961. 88 p. (MIR-" 15:12)
(Latvia-4-filking machines)

SVIKIS, J.; TA l,;LVO%', A.; .11TIVULIS, Z. , red.
[Mechanization of the protection of plantsj Augu aiz-
sardzibas darbu mehanizacija. Riga, Latvijas Valst-s izd-
ba) 1963. 167 P. (In Latvian] (MIRA 17:7)

LABRENTS, V. [Labrencis, V.]; ODIN', Ya.[Odins, J.); UUBLIS
red.; ZHAGARS, A., tekhn. red.
(Tables for the calculation of earthwork with trapezoidal
and trapezoidal-parabolic crbss sections] Tablitay dlia ras-
chats. zemlianykh rabot pri trapetseidallnoi i trapetseidallno-
parabolicheskoi forme poperechnykh sechenii. Riga, Latvii-
skoe gos. izd-vo, 1963. 236 p. (MIRA 16:4)
(Earthwork--Tables, calculations, etc.)

KLAVINS, J.; FRIVULI-':';?_:.~.
[Improve the herd; L-,- ":ollectlve Farm. of -the Valmiera
Agricultural Collective and State Farm. Administration as a
purebred cattle stationj Izkopsim. ganampulku- Vak' ras
kolhozu. un padomju saimniecibu razosanas parvalde. Len-ina
kolhozsskirnes lopu audzetava. Riga, Latvijas Valsts izd-ba,
1964. 21 P. (In Lr-tvianj (MIRA 17:7)

BERZIN F.
UVULIS, Z.,
Lauksali-.!,.it~. inas Fi.a3h-Mu r-gu'Lesaiia un
I - ;,-,
Stt..~ izd-bf.,, I,. l) p.
Latvij,~, 4Z
(Irt

of hvbri~d'
ja s izii ba lq(~,- (~l V..
Ze ~t
jr, LVI an

OZOLS, J.; SPRIVULIS, Z., red.
[mechanization of legume culture] Paksaugu audzesanas
mehanizacija. Riga, Latvijas Valets izd-ba, 1963. 108 p.
[In Latvian) (MIRA 18:3)

GAILIS) J.; SPRIVULIS, Z.) red.
[Forest tree breeding and seed plantations] Meza koku
selekcija un seklu plantacijas. Riga, Latvijas Valsts
izdevnieciba., 1964. 193 P. [In Latvian]
(MIRA 18:7)

VC I.
7 1 51, Cz
Id"'t, r f l"n st (F-'~.`O Lf', Vol.
I li L a u ui? c, o e a n C, C~.
ar ch 10/ 5'-

M,Vitaz6v1avv prof., inz.
WjQV4aX
awmWaw"now,
Termination of the first five-semster course at the Higher
School of Forestry and Woodworking. Drevo 18 no-5:197-198
My 163.
lo Vy5oka skola lesnicka a drevarska.. Zvolep.

LWENFISZ-WOJNAROWSU, T.;SPROCZYMKI. K.
p
Antibiotics in the treatment of diarrheas. Pediat. polska 27 n0.3:287-
296 mar 1952. (GLML 23:2)
1. Of the First Pediatric Clinic (Head-Prof. St. Popowski, N.D.) of LAs
Medical AcaderV.

S/197/61/000/001/002/002
B124/B203
AUTHORS: May, L.,_ Sprogis, Yu.
TITLE: New method of producing methyl triacetoxy silane
PERIODICAL: Izvestiya Akademii nauk Latviyskoy SSR, no. 1 (162), 1961,
71-76
TEXT: All procedures hitherto used to produce methyl triacetoxy silane
can be divided into three steps; 1) acetylation of alkyl chloro silane
by various acetylating agents, 2) distillation of the solvent under
atmospheric pressure, and 3) vacuum distillation of'alkyl acetoxy silane,
possibly with the use of a dephlegmator. B. N. Dolgov, V. P. Davydo'va,
and M. G. Voronkov consider the acetylation of alkyl chloro silanes by
acetic anhydride at room temperature during 18-20 hr, subsequEnt slow
distillation of the acetyl chloride, and fractionation of the residue
under vacuum with the use of a dephlegmator, to be the most suitable
method of producing alkyl acetoxy silanes; the methyl triacetoxy silane
yield attains up to 70% of the theory. K. A. Andrianovt A. A. Zhdanovt
and A. Bogdanova obtained methyl triacetoxy silane from methyl
Card 05-

New method of producing... S/197/61/000/001/002/002
B124/B203
trichloro silane and acetic anhydride by continuous distillation of the
acetyl chloride by a dephlegmator and a descending cooler with a yield
of 78% of the theory. The authorst experiments showed that a yield of
about 70-75% of the theory can be attained with the use of all variants
mentioned for the acetylation of methyl chloro silane. Benzene, toluene,
carbon tetrachloride, 1,2-dichloro etha4e, and ether were studied as
solvents; the acetylation of methyl trichloro silane was most efficient
by means of glacial acetic acid~in benzene, CU or 1,2-dichloro ethane
(70-75% yield of the theory). The dependence of the boiling point of
methyl triacetoxy silane on pressure in vacuum distillation was determin-
ed (Fig. 1). In the distillation (which must be repeated) under vacuum or
atmospheric pressure, 1,3-dimethyl-1,1,3,3-tetraacetoxy siloxane is form-
ed by means of intramol4cUlar condensation, and sometimes polymerizes to
a resinous substance. This also leads to reduced yields. Therefore,
it is more convenient to recrystallize the product from the reaction
mixture, the best solvents being the aliphatic hydrocarbons of petroleum
(petroleum ether, benzine, kerosene) and, among them, benzine. Ace-
tylation is best carried out at 66 - 670C (boiling point of methyl
trichloro silane), which guarantees
Card 2/5

e-,; me thod -, f producing. . . S/197/61/000/'001/002/002
B124/3203
an efficient condensa-cion of vapors. With the use of benzine.as a solvent
in the acetylation of methyl trichloro silane, the reaction mixture forms
tl-,,.,o distinctly separated layers after filtration. Crystallization begins
immediately, and is concluded after 1-6 hr (depending on the volume of the
crystallized fraction and the type of precipitation). Fig. 2 shows a
typical crystallizate from benzine (pure liquid methyl triacetoxy silane)*
The formation of layers in -the filtrate also occurs in kerosene, but yield
:fund purity of the product are lower. Under optimum conditions, the yield
in the procedure described attains 80-86% of the theory; it depends on the
time of heating, the amount of solvent, the conditions of filtration and
ru-,:,asshing, the time of cooling, etc. The degree of purity of the crystal-
line product is 95-98%. Among all known methods, the one described is
the simplest, most economical, and most suitable for appli.cation in the
industry.. There are 3 figures and 23 references: 5 Soviet-bloc and
16 n.on-Soviet-bloc.
!ASSOCIATION: Institut khimii AN Latv. SSR
(institute of Chemistry of the AS Latviyskaya SSR)
SUBL"ITTE'D: July 21, 1960
Gard 3/5

IIIAYP L . (Maijs., L. ]; ,SPROGIS, Yu. [Sprogis, J. ]
Now method for obtaining mathyltriacetoxysilane. Vestis lAtv al-, no.l.-
71-76
1. Institut khimii AN Iatviyskcy SSR.
:~ .-L;--,' ';L:=,:. - . . 1 1- - I
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Ac)r,. Jour
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Author Landau, Ludislav; Marclaka, Kmil; Spronel*
Inst I Lilt 4 -
T i t 1 t Th'- 1'.--la-tionshin bF.-t-.-reen tl,,, a' Pro-
n ---nd.
(1~ lic!
1: 'ILbn io~
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ITO :1. 13
Or 13 Pub. : 195~r/, 4, '41-('64
Abstrant ! ~-rolxo (coif rol' 'hr, star,
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fro-! f ortiliz.30. 72*4 '.7-'1,f,4 M.-d Sr:*4 per-
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.Ueji-~ o:.P -i-itainiri A ~n 1cf 'lc. Iivor of pp-_,j-
Card:

SPRONOV, F.F.
Appearance of helminthophage in soil carnivorous Hyphomycetes in Turk-
menia. Doklady Akad. nauk SSSR 81 no-5:973-976 11 Dec 51. (CIRL 21:5)
1. Presented by Academician K.I. Skr7abin 15 September 1951.
2. Institute of Malaria and Medical Parasitology Nxkmon SSR.

~- F , , J -, _ , - - - - V ,73 .
"Ife,dth Center." p. 3,
(ZDRAV!,'t-J! F4011T., No. 49, Jec. 1954, SofiYa, Bv.!~vlaria)
SO: Vionthly List of East European Accessions, (Ez'"L), LC, Vol. 4
No. 5, May 1955, Uncl.

SPROSTR"07, B.I.
Case of-0. fever. Suvrem. mod., Sofla 8 no.4:93-94 1957.
1. Iz-Okoliislcata bolnitea - gr. Breznik. Terapevtichno otdelenie
(Zavezhdashch:.-B. 'I. Spostranov).'.
FERV , case reports,
(Bul))

6FROb'fRAiIOV, B.I. (Bolgariya)
- -
Elect rocardiograohic changes during the sensitization period and
in anaphylactic shock. Klin.med. 35[i.e.341 no.1 Supplement:12-13
Ja '57. (MIRA 11:2)
1. Iz terapevticheakogo otdelaniya (zav. B.I.Sprostranov)
Okoliyakoy bolinitsy v gOreznik.
(AUSCUINATION)

KWIATKOWSKA, Barbara; SPRUCH, Tadeusz; ZBROJA, Wanda
Diagnostic errors in cases of anomalous positions of the kidney. Fol.
tyg. lek. 17 no.20:792-795 14 My 162.
1. Z I Kliniki Poloznietwa i Chorob Kobiecych AM w Lublinie; kierownik: .
prof. dr med. Stanislaw Liebhart i z I Kliniki Chirurgicznej AM w
Lublinie; kierownik: prof. dr med. Tadeusz Jacyna Onyszkiewicz.
(KIDNEYS abnorm)

rupture th, duAf-r..-,-)n wV
unusual com.-licr-itAors. Fe,-L Vg. lek. IF r1o.52:297,
1, 9 77 2'3 D '63.
1 . 'I I Fil In' ki Chlirl-rg.1 c zne' ",kade-mil M,--dycziej w Lubh~nj~-,
Okicr~v,-;njk- fyror. ~r T. Jacyna-Onys7kieaicz

MOCI-aA, Ihrian; SPRUCH, Tadeusm
Asymptomatic perforation of gastric ulcer. Pol. 'Lyg. lek. 19
no.1:27-29 1 jal64
1. Z Kliniki Ghirurgi-cznej AM w Lublinie; kierownlk., prof. dr.
med. T.Jac,.vna-(hvszkiewic27.
Ile

PMISGKA, Anna; SPRUCH, Tadeusm
Result of the treatment Gf acute pancreatitis with traaylol.
Pol. tyg. lek. 19 no-45:1729-1732 K 9164
1. Z I niniki Chirurg-'emej -Ccademl-i Medycznej w Lublinie
(Kierownika prof. dr. T. Jacyna-Chyszkiewicz).

L 8478-66 E-.-,TT(d)/EWP(V)/EIP(l~~)/W(h)/W(l)
ACC DR: AP5028518 SOURCE CODE: UR10286165100010201009910099
~'AUTHORS:' Gillmant L. N.; Spradep I. W~P,
----------I
.ORG: none
~TITLE: A direct action pressure regulator.. Class 42, No. 175753 jannounoed by
!Central Engineering Bureau of Armature Construction (Tsentrallnoye konstruktors.koyel
byuro armaturostroyeniyay-
SOURCE: Byulleten' izobreteniy i tovarnykh znakovq no. 20t 19659 99
TOPIC TAGS: pressure regulator, mechanical engineering
'ABSTRACT: This Author-Certificate presentsa airect.action pressure regulatoroon-
'taining,a~directing membrane mechanism with-a regulating device, the regm ating
:organ i3i the form of a ball valve, and a regulated throttle with The
;jh
'ILI _rQJUIL is mounted in line between the chamber above the ball an- ehind
7T-ihe regulating organ. To produce a low coefficient, of hydraulic resistance, the
ichamber above the ball is connected to the chanlier of the directing mechanism,
!while the membrane is rigidly connected to the valve of the, throttle.
'SUB CODE% 13, 14/ SM DATE: 2WA-r64
I-Card 1/1 Ms. 621- !~!~553.-
Card 1/2

ACq NR: AP6032525
in the chamber under the ball independent of the regime of medium being r 'egulated,
the chamber is equipped with auxiliiwy valve operated by a type of seryodrive. Orig.
art. has: I figure.*
SUB CODE: 20/ SUBM DATE: 03Apr64/
Card 2/2

L ~ '-4
ACC NRz r~P60113401 (,,J) SOURCE CODE,' UR/0413/66/000/010/0115/0115
INVENTOR: Gilman. L. -M. Sprude, 1. K.
ORG - none
TITLE: Device for the prevention of pressure increase in tanks and pipelines.
Class 47, No. 181931
SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no. 10, 1966,
115
TOPIC TAGS: pressure control, prZ*-_5uv_e valve, pipeline,'tanT
ABSTRACT: An Author Certificate has been issued for a device preventing pressurp
increase in tanks and pipelines. The device includes a main spring-valve and an
auxiliary spring- valve. In order to bicriQase operating reliability and reduce hyqrau--A'1-,'.
resistance, both valves are.spherical and mounted on the elastic walls of, the chambe~r'-"
The main-valve chamber cap has a povt connecting it with the upper chamber of th6-:,,l
valve housing (see Fig. 1), Orig, art, has: 1 figure. [KPI
1/2 UDC: 621. 646. 82

L --4A2 Iff
I
i ACC NR:
I
i
6018001
(D. :
I;
, I
I
i

SPHU11G. Faclor (Zagrib)
-.,----.-I----.------- ------ --
DiboratOT7 O'L 11-iat 11easmirementa, Enel-gija lbr7 12 no,'1/8t
21-7-218 763.
"Nikola Te:31a, pioneer of tho ele-It'riv.-AV era* by Milan
P6-rtot. Re-viewed by Fedor Sprung. 2-56,
4~

0 3 _s_d ETA- la!~-' ar
Vul- no. I

--V S
j~,,-.c lQDL4,
1 st -)f -i',ast ~:-ur-)ean Ztccessions, ii, iVd.
U n.

SPRUNG, Hkoo, dre, Ploce
Kinetones and antihistamintes. Ned, glpn. 8 no.9:309-310 Sept 54.
(MMION SICMSS' ther.
. antihistaminics)
(ANTIHISTAMINICS. ther. use
notion sickness)

SPRUNG, MAkeo, Kapetan dr.
Severe anaphylactic complications following intravenous
administration of penicillin. Voj. san. pregl., Beogr.
13 no.1-2:6o-64 Jan-Fab 56.
(PENICILLIN, inJurious effects,
anaphylaxis (Ser))
~ALLMRGY, etiology and patbogenesis,
penicillin anaphylaxis (Ser))

SPRUSANSKY, Jdzef.,-inz.
------ t-~
"Handbook of water resources management" by S.Hronec and [dr.)
J.Ratica. Reviewed by Jozef Sprusansky. Vodni hosp 12 no.11:
453 N 162.

SPRUSIL, Aiois
-. - -.1-- ~ e~!-;'
Mechanization and automation of the limestone and coke conveying
and batching for the limestone kiln of the Opava beetsugar mill.
Listy cukrovar 80 no-4:86-88 Ap 164.
i. Severomoravske cukrovary National Enterprise, Olomouc.

SPRUSIL, B.
On the evaluation of measurements of small changes in electric
resistance. Chekhosl fiz zhurnal 15 no.4:287-298 165.
1. Faculty of Mathematics and Physics of Charles University,
Pragiie 2, Ke Karlovu 5. Submitted October 15, 1964.

SPRUSIL, Jiri, inz.; DEJMK, Wilfried, Inz.
I
Hydromechanical coal mining in the United States. Uhl-t 7 no.":
104-io6 165.
1. Banske projekty, Ostrava.

SPRYGIN, A.I., inzh.
vlays to reduce the number of accidents in the magnesium industry.
Bezop. truda v prom. 5 no.8:lC-11 Ag '61. (FIRA 14:8)
1. Upravleniye Permskogo okruga Gosrortekhnadzora RSFSR.
(Magnesium industry--Hygienic aspects)

0 1
110 v S n
kha 'I

Kh 01 i CO i EV J, ; S PF4 li Gi
BOY V,
Us e o 'L G; I &cle, LS for partipai aeratior. Gor. zhur. nio.~.
72 S 165. 1, F :9 1
1. Tzishkei:-,u~",'-Ty ."ilitelihnicheskiy instit'ut (for Sprygin).
2. Altyr-Tc~,-.
svl.ntsovc-tsir--tc,.-,-y kombinat (fc-, F-r! ty'n-in:i.
3. inotitiAt (for Boyav).
y k

KOROLYUK, I.K.; STRAKHOV, N.M.; GEKKKR, R.F., redaktor; SPRYGINA, L.I., redaktor;
SHEVCHENKO, G.N., tekhnicheskiy redaktor.
[Limestone hillocks and conditions of their formation in PodoliaJ Podoll-
skie toltry i usloviia ikh obrazovaniia. Moskva, Izd-vo Akad.nauk SSSR, 1952
138 P. (Akademiia nauk SSSR. Institut geologicheskikh nauk. Trudy, no.110).
(MLRA 9:7)
l.Chlen-korrespondent All SSSR (for Strakhov).
(Podolia-Physical geography) (Podolia--Corals, Fossil)

FILATOVA, L.G.; SPRYGRIA.,
Effect of environmental temperature and hormones on the endu-
rance of animals during a fast developing hypoxia. Opyt izuch.
reg. fiziol. funk. 6t73-77 163 (MIRA 17:3)
1. LELboratoriya ekologicheskoy fiziologii ( zar. prof. A.D.
Slonim) Instituta fiziologii imeni I.P.Pavlova AN SSSR i kafedra
zoologii i fiziologii ( zav. - doktor biolog. nauk L.G. Filatova)
Kirgizskogo gosudarstvennogo universiteta.

T -I
ARMAND, David Llvo7ich; DOBRYWIN, Bo~~Ip Fedoro7ich [decx!asP,!': Yuriy
Konstantinovich; ZIMAN, Lev Yakovlevich; MURZAYFV; Sdua-l Makarovich;
SPRYGINA, _J4,udmila. Iv nvma, HESTERGAZI, M.M. [deceased]
MA43iiA, O.S., redaktor; ,SMIRNOVA, H.P., rednktor; N,N,
tekhnicheBkiy radaktor.
(lion-Soviet Asia; its physical geography] Zarubezhuaia Azlia. f4,.i-
cheskain geografiia. Moakva, Goo.ucht~bno.-pede..-og,izO--'7o MinlstarAtva
prosveshchentia RSFSR, 1956. 6C6 p.[Supplemantl PrIIov:neniiA 1956.
13 leaves (fold.maps), OMLRA 9;5)
(Asla~-Phy~iical geoGrzaphy)

R I KHTER It G.D., otv. red.; ORLOV, V.I., red.; SERYAGIVA,-L.I.,
red, izd-va; LADYChTUK, L.P., red.izd-va; DOIDKIIINA,
1.11., tekhn. rea.
[Natural conditions and resources of the U.S.S.R.]
Prirodnye uslovila i estestvenriye resursy SSSH. Mo-
skva, Izd-vo AN SSSR. Vol.6. (Western Siberia] Zapad-
naia Sibirl. 1963. 487 p. 2 maps (MIRA 17:1)
1. Akademiya nauk SSSR. Institut geografii.

3PRYNAROVA, '-J. ; GLIVICKY, V.
Problem of relationship between physical training, physical develorgnent, and
the functional state in young workers. P. 531.
CE3KOZ-LOVINSKA HYGIENA. Praha, Czechoslovakia. Vol. 4, no. 9, Oct. 1959.
Monthly list of East European Accessions (EEAI) LC, Vol. 9, no. 1, January 1960.
Uncl.

SPRYNAROVI, S.;JOACHIMSTHALAR, F.
Blectromyographic atudy of a complex movement habit. Cesk. fysiol.
9 no. 1:57-58 Ja 60.
1. Vyzkamny ustav telovychovuy. Praha.
(NOVMMTS physiol.)
(BMTROMTOGBAPHY)

ZBUZEK, V.;BARTOSOVA, D.;VAGUIA, J.;SFBYNAROVA, S.
Studies on the value of adaptation changes to specific sprint
and stamina training. Cesk. fysiol. 9 no.1:69-70 Ja 60.
1. Vyzkumny ustav telovychovny a fakulta ITVS VSP, Praha.
(PHYSICAL IDUCATION AND TRAINIWY)
(ADAPTATION PHTSIOLOGIGAL)

GLIVIMY, V.; SPRYWOVA.S.-; TINTRU, J.
Comparison of changes of pulmonary ventilation, oxygen requirements
pulse frequenc7 and blood pressure during average load in trained
and untrain6d attidente. Ceskefysiol. 9 no-3:23G-231 My 160.
1. Vyzkumnv ustav telovychovay, Katedra, lekarskych ved ITVS,
fak-iLlte. KU, Praha.
(SPORTS)
(RESPIRAMON PbYsiol)
(PULSE physiol)
(BLOOD FRESSURE phy
.sjol)

SFRYNAROVA, S.
Comparleon of themaximum o2ygen requirements in trained and untrained
students aged from 16 to 17. Cesk.fy9iol. 9 no.3:270-271 My 160.
1. Vyzkumny ustav telovychovny, Praha
(RESPIUTION physiol)
(PHYSICAL JIDUCATION AND TRAINING)

S PPYN AR-OVA, S. ; PE! S~Zl ALI M, R.
Participation of changes in pulmonary ventila-,11--l-i and utilization
of oiUgen from inspired air in the increase in ox-
./gen consump-
tion durixi,r, physical exertion measured repeatedly in boys. Physiol.
Bohemoslov. 14 no.l-.96-106 165
1. Physical Culture Research Institute and Phlocr-i-pological Re-
search Institute, Prague.

of ~the 'UfIC T, tne ~,,~:,re i in the
of Hor ;;jnc- (I'lie 'ii:,.,le o ftiie Geen~-n,vii -ie
"i'~U'lldS)". Cand
7 111L
A 3~--.i, Sanatov J, 5arabov, (II.- U-A,
L,,~,rvev of Oi nd canical
Jisseri-i~dori :,efenrled at Aigher L-2ucatinal institutio:1S.
( 1L),

VUNDER, P.A.; SFRYSHKOVA, N.A.
Iffect of docerebration on intensification of reactions of the
thyroid to methylthiouracil and thyrotropic hormone. Biul. eksp.
biol. i mad. 40 no.11:16-19 N- 155. (NLRA 9:1)
1. Iz kafedry fiziologii z1xivotnykh (zav. - prof. P.A. Vunder)
Saratovskogo gosudaretvannogo universiteta imeni N.G.
Chernyshavskogo.
(BRAIN, physiology,
off. of decerebration on thyroid reactions to methylthiour-
&ail & thyrotropic hormone in chicks)
(TMOID GLAND, pbysiolog7,
off. of decerebration on reactions to mothylthiouracil
& thyrotropic hormone in chicks
(THIOURACIL, derivatives,
mothylthiouracil. off. on tkyroid in decerebrated chicks.)
(PITUITARY GLAND. ANTARICR, hormones,
thyrotropic hormone, eff. on thyroid in decerebrated
chicks)

,
4
-
o
n tit 1
I 1 11 13 14 11 lf to a 711
1
n M110
n 0 JAR
-C 1) L H -A- L 2P1 P9 AA N t tv 0
90
-00
00
0 A
uintojecular amounts of sulfurk acid.
kas Withk e
hth
f
i
a
on o
The sulionat
sap
q
f
pure
A. A. SrRUMKDV. - J. Ckew. Ind. (Moscow) S. No. 2), 41-1,(193 1).-Vapon o
benzine, previously refluxed with HtSO& am pajscd thf-sh the sullmAkdoo mizt-
during reaction to carry Off the Hzo fonutd. From a to 4% unn%cted WS04 should
0 be leit in the njill. ILftel sulfonation. The yield is 97%. 11. M. LHICESTan
-00
t
*0 ZI:
eog
d
00
00 j
00
go
00
go
A 0
00
lop
00
00
0- of - , !
0 1 .,..SLA WILLUPGACAL LITfRATLAt CLAS11FICATIC1-
CZ
U Is if K) -IF INA
"0 nal, nit 01% otart avix n i ~a4
00 000 go ~ 0 0 0 0 0 0g0 .0 1,
00 000 0

a 0 4 ~ smi-&-a 0 a -4 0 G 0 0 4 6 a a
0 416 0 0 0 0 0 0 0
a Ip a 0 Ip 6
0 0 0 0 q
0 a
0 0 0 0 0 0 0 0 a 0 6 a 0 0 0 0 0 0 0-0 0 * 0
I14 1 A , 4 - - 11 ! !, , . !. ., -, 2- t 1, jj 'n A It " . 11 11 11 4 r.
AIL D L 1 6 11 j 1. L 00 '-C t I
'
00
09 -
-r
1
of . ~ .
A r
00 j
(I I/ l

00 SulfOnAtiODOfngphthitleUeinv&CtW. Lya-Gri,hinatidA.A.Skn
Ani-
041 -,krawhnaiu Prom. 2. No. 11, 19-21(1932~. An app. for tMelfff6tiation of C,jj.
iltscirsbc(L 707, of C,.If, is introduced into a sulfonAtor heated to IMP, the-n th,
00 whole (if the 93% HIS04 prebt2ted to 7.0 W'. and the ina%, ti"td for 14) tnin
Th,-
.
00 .-WI is neol, gradually evacuated to f;lxi inm. to reni.,%r the lilt) ff)t7llcd, At,*v us,-
changed C,,Il, licing recovered its a trAls- A further 2W-~ .1 the C,.If. k Own tmut,-d -00
00 !11 the 'alto. AV And finally the remailling no -C~ -f 11,14), ti-I I, '111plowd
.
R.C A, -00
ic~

00 J! 00

00
00
90
40 a 0

o -00

w ;00
.
e --* 0
I-
p 1 z4v 0

El
A S L E T L L IL L' rFRITLSE CLAWFKATIC- 0

-
t

AV "a L&
1 14 4
11 AA A W 0
,l
t, It 0, m: K it R St K if 11 1
0 a 0 * 0 0 0 q 0 * 0 0 6 0 0 40 0 0 0 0 0 0 0 6 0 0 0 0
a 0 0
0000 0 09 99 q 00 0 0 0 0 00 4- 0 .
0 0 0 .0 0 0 * 0 0 a 00 0 0 Go 000 1

0-0 -40 0 a 0 0 a 0
-0 ;- q
*-0-0 0 0 0 a 0 4 a 49 0 0 4 0 0 0 41
:41-0 MIlvMeO ~:
-
6 4 i i ; 704"7
0 a 0 & 4 0
0
0 o
OG is 11 Is 14 U 14 11 Is of 20111 Ij D 39 JS X V 21 'f ; JO 11 9 11 R 0 k V A 0
L I
t
I V 4 0 9X VP tt
9 A J
~
fi
P A) 412 At co
0
00 f .
.
-
.-
A
-
.,

00
0
0 10
.00
09
fe Z A d -"3-" 46M. A.
00 PMO-4-22-7(1904) The i;iV-
method h' b~d ON th
d
i
6z4
RF
M 00
e re
owl
m of H
N
C
I
00
00 (1) to HOcJfs(NH,)ci%m (n) with Na-Ug by pt,,- -
Iteling the -tim Bast. from Alm. 00 with a layer ta .00
00 kemwat. To a own. nj 9.16 g. (0~05 mol.) I it, too cr

*V .
1W Mad the CRACt awl. of KOH or N,.M ,, d,k-d
.00
k1ruSeft And Na-Hg OM 9. HS wA 715 g. Na (excev,
NO*
00 015%))- the WhOk A`G69tirVcdc-MfUU7 without disturbing
00
so Ibc tOP lay- Of kcralleft, the FIX was srpd.. the reaction =
"uxt- WAS Poured into the caled. amt. of Ilel, buikd A roo
000 few Min. With charcoal And fiftervd. The fihmte wa,,,
1
2
10"d to 914841 until U C"d. out, or directly diww.
*
tised at 10
And titbw ime-diattly coliverted i,,,. ;r zoo
Vkm`Md Bbck V or tbepptd. dim compd. was fifteml
ff
Oe u
And dried at about OD to a Postro which can be astely
transported. TU yield of the disso Compd. by wp,.
00 WAS 94.6% and higher without wpa. Timnly-four
oo
00 Chas. Blanc z
'00
00 '00

410;.
00
~
'00

00 f
0 S L

ITALLUP(.KAL LITIM.71,89 CLA$SWICATM~ 00
tt
00 s
0* t 'I-C ji~jv W. 't~
---
-
~W-F Roo
19 W 00 15';

O
l (
4
L S
; p t, 1, Do K K it It 9 K If Zf It 09 MW n 1!14
1 0 0 0 0 0:0 0 a 0 0 0 & 0 & 0 0 0 0 0 0

0 Oi
e
0 0 0 O
OT44:00000:0
M 0 0 a 0 0 0 0 0 4,
000*00*0000**0:00 go 010694 000 000000006000l
i

0 9 9 0 0 0 0 0 0
1"4r* 0011,
0 0 0 4 0 0 4 0 a 0
0 it 0, y It. is, I a m A 16 20 14 is, ItL u P H 6 1) is P W 0, u at W O'C*
L 0 L 1 6 Is A I L a If F 9 A is .1_ An 1. L AA N CC W U I
" ! " I
DrIernlination of Imput tj 4 In com;~. 11.11111". 00
thalens It- P. llv,ts,mv iiiiik A.A. .4jeliov I"Ohn-
IV i'l,tn. if
kturook-av-i I'mm. 4. licl 1-fornir ,,, is,
..ifrr, aioblv and Ill., li~ inipulifir.'. li%- IV,
m - Is-ne - t"locn, al"I n' ti'lial. F.W the left.
..I tit '21) K. a-k';.I[:Ntkt ith '_10 tc. I',,
Na,Cth it 0 Nl' (,,I ~.'O tillit. ill rditw, cosol with 14tiny.. -0 411
0 1111 a i 111t. r fnnn C:Jf:N1 ):, wa%li. aridity the filtrate with #;,7 n-.
00 4 -nvd IICI. tilt. r thrmigh a III&- filter, wa,h. dry and -00
its 1911 I'llf ON 11, Ill "I It' A I -, 1111 :; K -11 k',.II;Ni it fri"ll
00 0- 1'r-Aing ..%In Idi".1 .,1 1-1 "') In :k I*mvl..VAkil app
00 01111 11 t" p, if _`,j I'lo. ..I "'ll ' and -tit Inin. at I) doe
Ilse still. lou, 11" '-s-i';h.A Connecting Filmult-ver
0 11 it, a,th div un.li-I-0 k's,II,N(vr with .1 uc. por.
Owi it uslud it, ls'~ atid itmi,,fi~i init) an Fili-nnwvt-ir ila,k.
111.1 its, [,-it oh, i "iTh a gritile t-mr,tif ,(;.it on, timil,
of ill., ll..k and .1. 1 .411V voillarslinAlloic ('.,If.Ni 1, Is,
, v 'I" "n't C.At. I-V
to ';ir -I dinitionapht fiat, nem, and v.nou~ zoo
0q I'MIN.r. fir -4 fron. (fir I-mvims &m. of "I ze 41
k.~.Il. in a Pa,lo-W app. ith IScv. ;-ctr. ether at 50' a-
0r ~* : .! goo
rval'. [fir Im rthrr alt.1 -vigh. fie-
jue s4 the pr, %-u4 e%tn. -1 C,.Il. and a little zoo
'NO.. thr sellitil Ix-n-entapir of and
00 90
11-1#111411 loAtt'r i, it.m, .1131 I"Wrr; the h".-
00 1 %vr. with life hittoduLed covirection it, negligibly rmaW 00
FmIn Ibe Ill. 11. if 1h,- re0thial file ronfrnli of n.
Omp 1:
.$list me sIVI& su'v"111111% Io the
ihrm"41 , o' V.. Aill of .1- i"11% J."'t,tt "~ 1'. .. !!
Nik, and ....: 111,11o.j pi"'hict,
i-v tit" im-0-1 vs- %Att- %lilt tm 4s,-uv.uv J 1 1 112~:- see
00 1 ~tjoe
.1. it -ft-LL.RQK-
0* ~3 - - free
so ""P tv it to :8 if a it ff ft it of 4 1 ft
: : 0 0 0 0 0 0 0 00
0 0 : a : : :f: : : : : : : : : 0 : 0 0 # 4 0 * 0 0;

IF
A, A
'j 11 1' it
L &, L I P.
J
A L It

~. 43
-
- I
49

A
09 :-ee
-0e

AMAIYSIS Of -00
A. A. SpitusLov. AndiiiekniAxillillityu I*rvm. 4. W-xl 1.
-00
28. 41WI.-The previnus method of acidity the filtrale. filter oil tile ultim-hru'll, 1
anAlysiswa.4tuiptuvril. Fow I he (let It. of at-idity and twitch. dry and weigh. Fix the dan. sA dinitto-
Schot, filter .00
1111puriticit. diss,4ve (1) ii; twilurne i-r zy1cut .
alqrnxs and relinclus Iliatter. u6C I from the previous 400
unit proceed ws usual. Foyr the deta. of 11,0, btAl Z) it. me it from C'.11% by -1L3(K. With Steam for 2 hri.,
~f
I with M) cc. lulticne for I hr. in a d&4 connected with a filter on C16111 coutil. some 1. licat in a por,clAm dish "a
A --09
graduated dL%tn tube Pruvided with a reflux bulb con- the
a water both kv :3 hirs. until all Cwti, is evatid.. unite
: den r. Fiw the detn. Of CIjig, boil :!t) g. I wi
th W) cc
-
"a '. ww:igh;Axwut'2 g. of this. w,,rk

,
I with the main portion, dry
0 nd 3rv.,,f:Y;% Nami fw 2hrs.untwi SWcQ.,Ac.)o
lip in th luvskil app. with 18 cc. fil pelf. ether (b. 70
Pav --Go

! dell"It It [MM-4 clx)l- filter I'll Call. COME. about 3 g,

i
l
l
d
1
h
h
l
l up
at .1w), f~r 30 min., filter. Wil"ll -sth P~tx. ethtr. "pel the
-
t

oe z! wrt. mill w
a s
j
t
ou
e suit. #
ated Sit
and
. weig
grami
5 cc. -1 I(M)", Acoll, eir4cuatir quickly. licat in a jKlilifill jutil wrigh. The la" in -
pirt?, ethl, with air at 4()
ve* dinitrultuplithairn" A1141 tM110144 InAttCr The

z;*~

U ""', 1.112 f,.f 30 litill.. add 40 ce. Iflo and 3 cc. of coned. gi
(cmduc is freed frottl the hill tIA"r- -Of fr-illuil- IliAtirf hV
!

Q 4114til lify C'.114 with 41"Ill (1-2 hrx.), CO'l. filter
[Writing in toluene With pUre allilliAl 01410U1, A141 (Sign
, anti
Weigh. The valuts obtained are uniformly 0.2% -4 - and d.
p. of the t1ricil product ifir vf"ittsits
the sit
I-, Which "lost Ile added to the re3ults of dein, For [be
i
I
i
N
l
h
l
di
i .
Cloff".40, are dctd. according t'? the Pfo)IXM,-,l t)ICImA
i
f
w
&Ol
On
thu
g"t L
th I%
ifetti. of n
tronap
) g.
s, -- ant
A method of Vjcciroph(it(rairtric dirin. o
Curve
j A Water Will a( 7-0 5' for 2 hr%.. cuA. filter oil 1. wAsh, .
N()~ in coned. 1I.S0. .,In,. i, ijc~itlwd. C. H.
C
Jj
d
-
r
,
40 too
00 t.S 0

00 8 A I
Z:4D a
T
boo
U -14-
,An
0 0

0 0
0 4 at 0 tt It it, of R

0 0 0
l
t
00 0
0 0
0 0 0.0 0 0 0 a
4 0 0 0 0 0

0 0
o
0 J

0 a 0 a a 070-6 a** 60-1111i 11111-70 a a W--
see 0000000# 00 as 0&*q:J#0i5M1
#4
6 -1 It 11 11 " it 4 if is if JD I It A is A v a A 111, 11 v 11 it 13 k V So J,
tj L; ti Al a eilli
A 11- -4--a-L 1-k a it P 9 A 1. T_ U T_ cc Do R 4 4
Lx_
A r
A
-so
0 -00
00 r
as
*a
00 a ll
09 Isolners of xylidine by bromide-
DiltmIllnefloll Of
-00
00 bi 1 11 lo 1110 A,
141 M,
"011 no*

a 1 ji~llkl '11
1
e1" 1,P'tm Willi
,4 14 10011-110 -Iti
1
11
11
d

00
111
.
4 1
'
"I
p .kV
I
1

a* O I,
m I
j4 (111,4
i 4111 Kill-KII10o; the rrill

o 0
oe
,P,p mA KHM, I. V.pliv. 1., 3

" 1A mt.l. '.I

aa-
of
,!,so

10 to
so

1
00 1
0
0 ~
Z; 600

0 9
0
9 . 1 "

1 .600
300
11000
ire a
t:00
ti0o

~
so

Ate.%%.A DITALLURMAL LIIJIMATUSIR CLASUFKAT10k, co 0

:00
8 .
woo
00
ilk
An L 0 Old 0 IN '3
u
`
!

o a
to [plot, owbi Kit olm "lift n 1 1
~
100000~00000000*POOO 0000
1800
0 000C60000 0 0 0 0 # 0 * 0 : : : i 00 0009 600009 0 goo 00 11
0 0 V,

03

A a 3 P to It 1) 11 m it m 0 to Pf 11 It 17 a x a m IF a 70 a if V 11m
o A
r It It
I

00 Yr-1- AA 4 it W It it s, 0 j it, L
L"
lit ..1, ,.t. '.0"Ot

0

.00
Color mcdols. ..d or ftot dittomimallon
'!If
is
A
ft
,
.A jbtkov~
11
S
1) J
IM AW1113
l
h
101
Z
-00

0 .
.
,
.
. 111mil
irm.
. (
,
S~ R.) 3, VO 3: 4. 1 -*. A. ", UPOP A pet-Imph-lo-
metric Inetholl bir mill"IYA10 a 111!11~ sit o .411.1 0 nill-
04111 usishifisicne 14 dest-Owd which it Itawd ots the trelot
00 prixtuced by treatment with 93.8170 lit."Ah, The red ct-lot
of the %oln. of lm-nitronsiplithalette in emictf. lfSO. 14cleir
0 away when a little of any org. solvent of the nitro product
1 is added, such as AcIO. ArOll, irtralin. etc. The r4m ZOO
reactions of the Tnant)- and di-nitronaphthatene in stAns.
'31
of coned. HrSO as well as ill the presence of alkali by.
droxide in acetone and pyridine are dciribed. Tech.
spitrimaphthaltne was found to contain I part of the d.
-a coinixt. to 17.87, of the a-is"titer. W. T. IL
*0 4ri

be j

floe

4 ' L A *fIAIlUI(,KA& LITERAIIIIII CIAWFICATIO, C-1 ztV*
we '
t r'
Il
a .111-~ "'.1117 ~ -___ . I .)"
. '- 'T
1 1. f:., -1
- .
L
Z-7470 U Ts &V M3 is ; I I . i -, -
1 1
IF it tit? 2V6( Kit Xg( ttrtLt V04' All
.
e a 1 0
0 41 41 0
0 0 0 a

o-00 0000-0-t -t- A AL-

T TO
: v
- V
i a-
4-
W

0 o 0
e
0 ~44 a ~
MS i
to -
ea 7 1 1 a I S I I f 3 W It F. 1,.
J~ it W 11 m J .1 u r 0
A a r 1
1 V T -A I -L M -14 CL PP U
00
AWN It. 11. fledarow
00

skov. Org. LIM. led. f IT.$ S. R.) 1.
S
and A. A. *
go -
#V-10( I MR1 N.%%olvr 0,3 S. of an arnmack- am ine in 2- 1 h
cc. EtO (;kpmding -ma ibe wAv.1 and add 1 2 cr. ul dry.
00
rictlitild. LAM uttf. with HCI (1t)t!rct. liv-Ap, the "lixt
at
00 .
romi temp. ug at .11) M). un a -alry I-nth, still (try in a
w
*0a drying oyrn at 40 Ml' for 15-D0 litill. I)iu)lvr the -alt
00 in Atit-lit 140 m If,(). intrutliKv 4'. of the requircil anit.
f 0
1
N
V
Oll
i
i
o
.
I
u
ant
A
t
trate hot in thr jur%ence tit pht-notl -
f)hthakin as indicator. Equally xuud rmults werv ob-

00 taintd by the mw of C#114 instead of Et-O as a Avent. see
Unsatisfactory rmits were obtained in the detim of
zoo

*0 03; HOCilVifs (colurrd quivioline, umv. .-aminu-
anthraquinone tlx)or mily. in EtiO) anti Ph.V.Nfe, (low coo
basicity).
Chas, Blanc

00
00

00 , goo
:Zoo
009
XOO
lip
woo
i t:00
-, iq too
ASN~SLA METALLURCKALLITINATURECLASSIFKATICO t.
.13 J.1- goo
!OIGNa -1, a., 'J.( aid ill
use
117'A I S 0 ed 0 ff IN 0 a
d"
F) u St &v No
01 009
0 o o 0 0 'Or 0* 0, 0' 0,4"9090009009000
01
;Z4 : : : : :ie 009000000000000000000* 01
0 ;000000000900

o 0 0 0 0 * 0
.7 -4-i-i7o *~4,v 0 1
7
1 0;0 0 0 0 0 0 0 0 0 0 0 0 6 0 0 0 0 q 0 0 0 0 0 0 0 0 f 0
I : 11 it a w a a Al a 0 4 Q 41 a at#
a it if Is w $6 it bi a it
A-A -L. _~L_ _&___X F. 2 It . 1_1 _11 pzwl Tat .,1 4 k a I A 00
!..go
00 hulle"Utiat of all 1.60. It. V.
STWUL4A)V-(kF- xhl~* 10J. tt'. 3. h. RA 2. 11v1
00 (two); Cf. C. A. 20. 45&).-Kxpts. on the inillunatwu if 0&
es C,JI. and hydrol"t, of C.HrSWI with HjO asul dil. .00
11's0. 5h.. that I larst"Mali'm pfftcss 6 a niorr
g tr,tclhm Mom k con,vived toy Marvitimr-n ntul lotr t C, .1, *0
0 30, 125411~ Mp or.11111. dn-rod. o-.1 -mily ,,, 11', 0
0 -t. .4 atishm.11".1 .4 CAI. 4,4.1 #foe by.11far'i. .4 tit. -0
i ll,k% 0 1 11,01, woo -00
00 al~~ OU the S116te ul equil, 4A ll,~" 1111th it-, IIVIIIAtt,: as*
j 11,8(A + mHO " I1~SO,.%HO. The sitiftmation equil.
t~
so ji- can be abifted tKb a min. t(arn. of d0-2% HSO.. While zoo
00 w of sulfarontion (Gulraot, C. A. 14, AN: Catirtut, I:. A. =0 JI
36. 24,") 6 an bsolIrfinhe value. It ctmillittes that tvno-n.
00 nf 1400.. which RMY1111st"tically AppraerheIi the litult volwl, 000
00 file inlift."ata.61 pr.. tkvfiy ff~.~ do, .00
-4 9 Of VAINUAli-VIII, IS 1011"WIAnt M flit' Cook-IM "I dlllt~. .11
a II.S0oo nqt*nl bw the %ultnall.us ,( wit. tel '00
00 Var-alootow, Jr.. V. A. 24, 44MV). Cha-. HUti, see
Prodeatim of O.naplkthoW. k. K. kilklittian *it([ M.
00 Yoo. I llytilievich. 0q. Ckew. Ind. (LI. S. 4. RA 1. 722 8
1036): cf. C. A. 29. 441S1 ; 30.Wl3".--Thv itwiotite viiii -
01 P-C,JITS(0111 I' frdlKVd 60111 Nl',` 10 IS-25',
I,v I fir rr~r-l p"%cifeltv M in$ rim lewing XA,j. I N.,SO,
f.14" the istilt...i.1i ... I vood."I. 111.10".1, .4 mIL
I '.so
And 40.1.1 44 tf C'.1 1,4 M 4, r diwit.-.1 C W
wto*
46k.Ak LITFIATURt cz- ):So*
i ties
41,
V 11
N> it Aft I I a 11A 0 m I too IN 1 41
0 01; it or a a4 a a to n n it n i
00 ;
0 o o 0 0 0 0 0 0 * :is 0 0 0 0 0 : 0 0 0 0 0 0
0 0 0 0 000 0 0 0 0 * * o6 goo go see 000

* ~99

.1 is opq
t. a L r I L Is
6
,

UsiftirmAstim of Imomwo of xylldlair by birstlWdit-bro
mate MmIlm. it. 11, Frthwov isiul A, C Slav-km
if 0q. (.'Awm. lovd. W. S. 14. R.) 2, I'll likitti. The it,.
provenicint of thr previ,miq 111011'%l (C. if ~ $0, 719741
Illsoliva it Imt-41.1c follet, xylillifir %dl, its 11,0, lit"Imi'l.
thr 11W of all esit-044 nf 4141111prof KIlt-KIIIII. m4a. mial
"k litrollwi wills 0.1 N N*.Vf, Its lisp w~iirsr of KI
.610 Orrh Im,111,

Igoe
o 0 j

coo
0 0 coo

moo
910
100
COO
t

s
t
P

i
5

4
Alm-It' 811ALLOIGKAL LITEPIPATLAC CLASSIFICAVOW too

b u AV so Ail, A
a Imp CP & It FW-1 -I* W a 0 a > It v
10 0 0 00 es o * 9 o 0 0 0 0 0 0 v 0 0 0 0 0 0 00001
V
Io 0 0 0 0 0 0 0 0 so 0 0 0 e 0 0 0 0 0 4 0 4 0 0 0 0 0 0 9 0 0 0

Pt-'s'-4,44 fW *W or OW ow-
I It IJ 14 111 16 1y 14 It JTP It It n .4 j 0 t.
A r, It J- L L a M. 11 1 1 U Y-A- A- I- AA. N OL W M4 7 4;0 o
00 -00
-00
CmPosition of commemial xylidine. H. 1%
and A-A.-_4xyAvv,-Urt. CAk-os. lpid. it . S. S~ R.)
b
-xviidille. Obtaimil frimil I ?ouets NvIi-lic,
m4laitl, the Wanrf%: m-4- NS 6'11', p.
A (amraminat"I with EtC.H.N11.) 33-.%"~C. M-2-2 -J,.; Ild
mud o4- 4-h%.
cha'. IIIAIIV
00 a
00
00 rl
600
00
zoo
00
09
0
.0
-roe
COE ~igg,
=t 'lie
Do
Lill..YURI CLOSIffCATION
$L A tVAILLURGKAL
j.. Is, 00
0 U 11 AV LS It 1POWN slaws[ PC it at a WLO n I !m
0 0 - 0 0 111 0 0 * * 0 0 0 0 0 0 0 0 0 010 0 0 0 0 0 0 0 0 0 0 of
-000 -000 Oil: 0 0 0 00000 0 so 9 0 so 0 0 @1@ 00 0-4 0 0-00 0 a 0 0 4 0 0 0 0 0

W
IItiff t 11
o 11011 11 If W 6 it 114 "Jolla 814111 aIf u Is ill a IF to IF 0 AV u to As at 0
It If L A L.-I r,
Af -4 -A L -L Al. 11'1 1 W Y Y ... I "T -I U, a CC 0 K
$I a-h S.-A-14 IV-1 Itt s oi, 1 -rj

00
GO,
so So tim of iw4- and p-Asylidines from commercial

Sla xyli=, IV. A. A 6% %kov, V. ltou,.Ikin and It. P

Ii
d

Sick r
orov-
rf- C. A. 31, lll 81HI P
-00
00 iqlidive M) unit ~111(01r. '11"I I Qcvtal.
s
-00
~VTV 4kid. anti AW J01C%V1l1r4 itl ill
,
89-110% ptur I is wpd. fimu coin. xyhditw timig
4 .00
;
;2&J% m-xylidiaLs by treating it with N5% of
. see
Acoll and allowing I iwetate to crytiallizll- at 28 N,
in 8 firs. fly this modification of the Linipacit inelli-st =00
000 ;.C*r. pat. 39,W) the yield of I is increasmi by 00

, and its PUrity by 3-6%, obviating the nemsity of wasitirg
00 L3 acetate with AcOll. Front lite Inothrr Iiqu-,t frt,lut 1 =09
460, acetate 34-5% 11 of W-1-4% purity wa.- obtained by Ilion 00
with 11,S0.. COntrAity to I.irojlx,h Vim. cot.) th, p1mi
00, with 1ICI gives faighly tinpurr 11. Approx. '.05 refrtrncr, 0 0
Chu.-. Blatic coo
zoo

-00

Ain-SL& MITALLUPWAL LITINAT1,41 CLASSIFICATION

~81 CII Cal ca C- IV&
u9 AV a -Ii! - . , ;-- -~ --- ;-- Y T 'I IV AM 3 a 0 3 6
;i
.0
*

s

1 It IT .1 M
19 ty 11,11P Will Kit sit(
0 0 0 9 0 0 0 ~ 0 0 0 0
0 0
4 it 1 :14

I
11
0 OLO 0 9 6 0 0 0 0
0
9
4
0

: :A
o 0 e 0 we
a
..
0 e 0 0 9 0 0 a & 0 0 0 0 a 0
.
.
0 4 @is 0 0 6 0 0 0 0 9 0 0 0 41

It A I M a A a in it Ill it It U is k v Is h 1 4; 11 it
A 4, L_ it- 1--j- _r, it I L J. a " Y , a R . - I ~ M I , , . . , W
Iff_"_0
It
I
Isomeric xylidixes: dissotiza d boa of di-
filoolurn compounds and coupli a -00
zoolunt, V. I1. 1'. FvdL,,ov..A_A.,SvryAOv and E. L
SheJudyakOva. J. t;tn. t hens. ~ V. S. S. R.) g, S, I I A i
!,11104); ei. C. J. 32, L!tMll_ The %elocitic- Of tile trav.
tioiFs (A formation anti deconilm. of duLzonium cOsnptI%.
of joilineric xylidines were measurt,ti Ily a coloritnetric
hol. To this end, aliquot part,, of t'hc diato coniN.
"V
1.1111Cd in the traction Or [vuldo-fing Unultelrd during the
'I'voillpit.) In tile reaction 114:11. Acrr conjilrd vinh 21.11. 1 ~:
00 Il0C.JIiChII (Schatfler'si ucid) al drfintiv on,fvA% anti
the color lentn-Lities were coniltated with ilhit ,f standir-I
00 -w)lns, bintilarly urated. The tv,tts were inade -Ailli purv
00 prothicls. fit the following tile INI Of VUVIJ AAA Of 2 ROS.
(times 10 -1) represents the Velocity Cul"t. (if diaz(jtlj!a-
00 tion at 0' and the 2nd no. represents tile velocity consi. of
00
00 decompa. of the diazanitan conipd. of the xylidine 6onwr '200
at 40': m- 4, 21C0. 7.62.; GA. 2.123, 1.3.71l; m-2 inot
100 ~010121
drid.), 375.7: p, 4.043. 419.4. Preliminary rv_kUI(,, Njumw .0 16
that p-0sZNCJ"tCI in itrong IICI soln. at IS' vooples _*6
with m-2- and p-Ilylitline and does not couple with the
and v-4-isotrtm. Chas. IlLtric
11,0
60 t
a - I L a*ETALLURGICAL LITEWATtaf CI-SUPICATIC.
go 81 06
#ALI 11 colt
U -0 is,
got fal lot I P An -,rx 0
It 01 W K It It it W 4 L 1 o AW Is 9 AJ 0 3 WIG;-
*0 n~6,1 .1-`
0 0 9 0 0 9 0 4 0
0 0 0 0

W W 0 0 0 0 4
a 0 a 0 OV 0 0 a 0 0, 0 9 0 4 0 0 0 0 0 6 0 0
$I/ Q"I$
I L m U. 4 If

A.
ILI.
I
I RSA I I I I I
T
T
e'llist. "", I
.1,11 do
-Iml
It ), 1
( I
11
,
Z
14.~A 1, 11 m

WII
and Olill. 1b., I,. .... ..

00 m

,0 1 amt
1"aclum 'tow m"1 li'llix J."g,
O
1
w
11111111tv 4 fit.. '1,'1l
00 11%, ,
410 I,ak
-490
00
Go

400 0
.0

go 09
00 ..d0 0
to
00 It too

.
I, K IT PF K ff rt f m
,.
*
0 a 0 0 a 0 0 0 0 0 0 0 0 0 0 0
0 IN a 0 a 0 0 0 0 0 0 0 0 or*
a
0 OV 0 0 0 6 0 4 0 0 0 0 0 0 * 0 0 0 0 0 0 0 0 0 0 4 6 0 9
0 0 a 0

4 -i- _0 -0 -*-** 0 * 0 * 0 9 0 0 0 0
1 1 4 ~ i I I 1 10 It of 4 It Is M 11
0
2 c a I F r H
00
00
so
0o
0 a
:0 a
00 a
00 1
00 z
09 a
o0 aT!
Ii:
00 a
040 j
00
00 4r
9
X
0 * 0 0 0 0 04-4 0-0 0 00
it U a N a N U M n a 41 a 13 &t
. I
~Wfanaj&w rijetlifa. Lj. - Influenis of time and excom
'F"t an Ila Process of to-*U-.
of the Mronstwe r"
A. A. Spfyskov. J. Gen. Ckm. (U.S.S.R.) 14. KLI-41
(1044)(Ung" summary). el. C.A. 33. &W.-Tht
ludent propobed
previously by S. was confirmed by expt]. data. Increase
ut the excess of the substance heirs sulfunated slows down
the sulfonation rate (if the substance is int)l. in
After 30 hrs. of sutfoctation of CwIIj by an equimol. amt.
of 100% HSO. at 162* a condition is reached which is
qcw eqt!il.: the latter is established when the concn. of
Opent acid reaches 40%. At low tenips.as well -m %ith a
iirse excess of COI, very long periods of titne are needed
Vor attainment of equil. Thus, with 3 mols. Cwlls and
I mol. HSO. equil. was not reached althouxh the spent
acid coacn. dropped to 2.5% in 30 hrs. at 162*. In view
of the dependence of the concti. of the spent acid not only
on the temp. and the substance being sulfonated, but also
Pu the coma. of 1140. beins mied. the excess of substance
being sultanated, =0 the duration, the concept of Cuyot
(C.A. 14. 406) has no significance. The 25% coacn. of
spent acid "ached in the sadfunatim of Calf, in this work
is. appartntly, not the limiting min. coacn.
G. M. Kosdapoff
ZL.'.-'L- a[TALLURGICAL LITERATURE CLASSWKATION
slow
sanoso -j 1 Sa3go') .1, W4. cot
94.1r:~-Z.-3==
U a IV N3 LS ; ; ; ; j, - , ~ , - l; - & - ,, - - ; ;
0 Ce K It Of It Or
00000000000060no:o:o:0r0oo
-~0000010000000000 0 0 0000
110.1 110.1n.
4JILil out a- 01
An I I a ad 0 It 9 1 N a 9
066006400090000060
000000000000000000
0
,00,
-00
*00
'V0
-00
zoo
zoo
see
too
400
loo
too
lof

9 0 0 q 0 0 o 0 o 0 0 0 %~ 0 0 0 0 a 0 a
415of. - . - ~Pf -
41 4 An Al AS
it
j I f f 4 it U I)
Ja IL -- 1--L -9 1-- 'M W-CC-M-Lt
A 1-L_J6-A--ft-F-
.

.4; '
The oWlesudion remedon. M. CommitnAW of I-
00 .4
00 mapirthateme"Nomic ad4 into the 24*omor..._a A
-3maimsm-and N. A. Onymakim (Ivanuvxk Stoic 01M:-

00 Inst.). J. Gm Chem. (U.S.S.k.) 16.
R
42P
A
40
Th
i
f
d
f
C
1
)
, .-
uLUn
.
nair
com-
.
.
1
e f
Actur i
; c
.
vervon of I-CmIltSO.11 (1) into the 2-immmer (11) was
slut tied at 160-2*; the equil. between I anti 11 Is emall-
00
lished under these conditions in 1-1.5 hrs. at the ratio,,(
15:85 of the 2 Isomers. Tbe beating was done In the lire%-
com of lfSO..IW and of other conens. of IIjSOj, down
0 W% 11#50.. It was shown that 57"", 110). lead% to
0 tablishmut of equil. nmm rapidly than dms the 3V,' sci,l
this arian from b JIFS0,11 ~y thel
=Ms of the C
00 is
strongrr ", wit an lion of Coils and IIrSO,. anti the'
latter then swe"tes; ClJ(q In the 16:1145 ImmucT ratia.
M A mvftd d odkeallim d me~emit. A. A.
00 INd. 10OD-41-A new niethod fur the sulfona-
=
2
1611i, was developed which comhts, in the ad,ln.
of I mole 100% I1sSOj to 1.7 molest Coils at W. anti hest-
ing the inixt. 2 firs. to 163". The final mixt. ctintains
51,,V unritsocted 118SO. and 2-2.5% suffou" and tom. The
excess Coffe is recovered by On. of the nm&,t with water
above SD*. The suVonated product contains.46.2e' 11.
,
G. 161. Kosolit
poff-

A I to. I L A.11TALLURGICAL L1194AILINt CLASWKATICW
01, om. dill IVILMO-1 R31131 Go a
too
-00
100
.00
goo
0
see
Cat
too
Sol
ro UO 195 '0', 0- on 0 *fee 0 0 0 0 0 0 41 0 0 V* 0 Is 0 666660 64049 00
O's
- 1 0 0 41, 0 0 0 0 else* 0 0 0 o 0 0 0 0 0 010 0 0 0-0 0.0 * 0 6 We, 00000 00

-'1- 1 co, I, ~Dn of
A
kp.
S, C ournad, o' Generai rjf!:T-,.,:trv -,.urn.-.1 ef h, - ii) lq-46, Volurne !~, i4c.

0 a o-O 0 -04 0 0 -0 0 -#-ee-e
0 0 0 0 0 10 f pw_ 0 0 0 0 0 0 0 0
00
is a or W it 41 it ed 45'r
~A L. f r__j _J, J. 4, lL A I- ll. t- _t jt__A_ f t- .0
-00
*lip
-0
The suffismiltion reaction. Y. 6nditions olriff"erid- oto ilawng Delore qcaling; in Mill cive the mixt. w&% h;"ll.; 90
bilify of the sullonstion reaction. A-A,Sr .1.
Lf.skov (Ivan- geneous within I hr. of heating with const. shaking. All
i ovek Star %led. 1114t.) J. Gem. 0"M. 16, clipts. were conducted at 100,; C.H.Al'so, - 1; 1 .4st 0*
so 2126-31(lid)(in Ruisisn); cf. C.A. 41. 2720U.-Al- concu. - 100%; duration of rLactian 400 lus.. complete
.
00 t tempts were made to teach equil. starting with each of soln. 120 hr%.; appearance 4 solid 2-CqjIyS0sJl
the stillonatioll products. I- atilt 2-naptithalenesulfonic hrs,-, sulforte,; and tar, MR.!" -. disultonic acids III.
Lirates. Samples of 0.3-0-d
adds, In the form of motiohyi .-isomer lkS.4%: 1-isomer 13.61"; residual ff,,;O.
j. were heated in scaled tubes to 1001 and the mists. were 6.8% of original. (Fixur" given below are in ?be al.ire
00 titrated with 0.1 N NaOll. The I-Isomer gave the order): 1. 01, CAM A 240. 11.81, 4.6, 04.41, SA, 4A.
.-ftAlowing results: 6 firs., 13.2% hydrolyeb. final IIIS04 1. 100, 10W, 75, 340, 0.06. M.3, 95-3. 4.7, 2.8-. 1. iloi
00 cancis. 43.2%; 12, 23.7, 60.5; 19. 23.6, 60.3; 24. 21A 1384, -, - (heated to 183' for 4 hm. mass no Imiaer'
5L 57.5; 50, 18.6. 52.8; 75, 17-5. 51.0. The 24somer. melted at 100-), 2.00, U.5, 96.6, 3,-1, 1.0; 1.08, lf)t). I I 11.
It". at 4
00 however. failed to show hydrolysis even alter 130 1. 250. 1.013. 1.8. 97.8, 2.2, 0.5; 1.5, 100, 4M, inu
oo o 100% the same result was obtained after beating the add 22M. 1.5, 12.7. 81.8, 18.2. 6.4: 1.5, 100, ow, .50.
127 lirs. with 0.4 mill. JICI and 2.6 mals. IW. rM tie- 1.32, 2.5. 87.7. 12.3. 4A); 1.5. 104). IM0. 720, 290. 1.61. zoo
00 trease of by frolysis of the 1-isomer after 12 fire. is ob-
-1 11.3,97,5,12-5.3.7;
00 viously flue to revel-tal of the hydrolysis by sulfortation 80.7, 19.3, 15.9; 1, 92.75, 600, 410, do" not appear
with IIS04 of aver 60`,~c conen. which yields both I- and 0.622. 14.8, M.9, Ill. 1. 14.1,. 1,92.7.5. low, 3.10, 290. WI-A.
00 0-isolmers; it is probable that given a sufficient time all of Besides showing the gradual traits-
& material would tie transformed into the 2-isomer, which formation of the originally fornied I-iwmer intn The 2.
is stable to hydrolysis. Furt her, Clef I a was sullonated in isomer, the cipts. show that %ulfonatiou of C16114 at Plu, ie -00
scaled tubes; the 2-i~mier iews detd. by either salting (Alt essentially irrcvtrsible (in the 1.111-fir. expt. only 0.5~ -00
C
(W by the PhNIINJI, inech-1. GencrallY the mixts. were of original lf.'S04 rc"I4in&l unreactM). In sullonsitsolis 400
y heterogcitcouc. slowly ht~otninK homogeneous, involving the forniation of only I isomer there exists a
originall Wow whictitliestilfonicAciiftfnt!4z%ot hydrolyze2nd
t Tit c rapidly when the aint. of disulfonic acids was temp. 200
J 2 c"n%iticrable unit. Ad disulfonation took place the reaction isirreversible.
sawl. I~ -0 0
during the there arc 2 temps. of interest: that below the hytlruly%j~
chirging of the tubes when stirring was rx-
eluded. in I cipt...thc mixt. was stirred immediately of either isomer and that abovc which both isomers call 12:09
bithyttrolyzed. lit the ease of C,.Il, thc5c are approx. 70'
poll 1-00
and 113-15'. G. It. Ko"A
A I I
-tyltLO'~KAL LITEIPATtiFE Uz- II C:00
woo
~11 O~E 20 C -i-a
__T_V-' 5 L
13
U IS AV to is, W it It CF K All ft OF a it a rl It rt- 0 1 11 14 1 13 4 1 1
And

)hL
!:~ -1- of th- '-,!~-Iration
A.
of
12

0
M X
A 1 1' & Is it I A, ~ L is h r Q A I 1 4 V i Ik at Cc. tt 4 1,
." I ~v IW~ "'044 to
Twil 1110111.1116 bo( 11 .1il faimil"all 1.4 filial 1,1100118, 11 "Al
00 vig L,.*, 4ifif A, it
Iffln0linA - /On.1JJ1djRJ Lit
!
go
set
tit 1.5 g. III
Rrtlucli,m nicilt.A. Mlot 0.3 it, M mrTiple

11-li, ~AA a viti%i ~ %4 W slot. ~4 AvOll vind
'111.t I,,
6 list. sitil allacts &it mtr~wwmiolrd cNiviolvispet.
go 9

: I(csoat to a outle bad voitko, Shafting law &_6 "in., M ho

Iasi
luor
f
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HCI
i
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d

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eat to
imWone an Zu.
Cnno and after about I fir
filt
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e
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ur
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Irnedimosinc WA-h with rmseol. IICI and try
00 -1 WN*. If of, little -4 the 1,64..Lerr to 1womwit
thVIS tWftWC fiti.litt
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attlo
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00 ..
y unt
a
n
p airr
wh
c
'Nu"Irfoulkil-113 Air KINril o" 2.5 clitillool", ,,sue ol
fi-,Ivr%. The percentage of 1,15-dinhoistriaphthitiene ILL - I
(,a/c) where a lit the Last. of the ppt. of hyvlrorhl4?rilfr

14 U'l -11.1 lilt III v letinfill Istille solid c Is the "t of a "litiv I'l 1100
'Iltw owm 1,111 (21 S"Ilfitr 1114.111'.1 '!ihoi.lmo (Ile
' 00
1141itd,, it 1. 1 4911. 0W.. 411d 1 -6 MIA.. o 'I
NA I I SO, W I 3"L
"
:
oo
ht.. usla with A Stiffer (A"I 21J0 f.p.111.). &Ald
li
al (,or 1-2 h
t 80"
N
Ii
h
diki
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00
00 v
n. a
.
eutra
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e
.
ot, blauffice
.)In. to plicualphihoakin, coolo, filtrr the rentaininf 1.3-
h
i
Wals
w
t% wolcrt iffy ill W-M .11141
"114th, I Ito 1~ptflliiflv sit# I'h IrA41IFt ill Owmifil, walwiv 4
till Its lit I - 21"k lit I tat a tisitA. r4oittilliti musit I* itialile.

At .14)* ftw I 11r. often 1.4.5-and 1.3.8-trinitrunisplathalen" Too
Irid 1.3 iiiiiarmAphthalcoar causes the trinitromiplithAlroar4.
1.1 got hil'o "4's *114-froas .-Itir 1.3 Ailtitnonss plot Im Icur low,

A I a - 1, L 4SITALLUNGKAL LITERAIMSE CL&SUPWATPON K Z--
low,
it
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00
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it Zbw A.-A-4a
I
i 1 ~. 1=19-- AM GWU'CQM'
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.,
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a a 0 0 0 a IF
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sia.. so-AM.
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0 0 0 0 0 00 *:.**fee** 0 0 0 0 wo 0 a 00 0 0 0-0
0:0, 409
00 0 00 0000 a. 4510 a 0 me-9 6"0,04 ore 0

D-a",5
USSR/Chemistry - Sulfonation YAr 1947
Chemistry - Naphthalene
"Study of the Sulfonation Reaction: VI, The Equilib-
rium Constants of the 'Naphthalene Sulfonation
11
ReactionI A. A. Spryskov, 10 pp
"Zhur Obshch Ehiza" Vol XVII, No 3
Values of the equilibrium constants, and. data on the
equilibrium condition.
1~fflgi

0 o 0 46~0
,I!Ootdoo I. 1~ 1, ;v 00011111000
5 6 tf Ij IA Itt It 13 16 AY A Pr 4w 4 1 A; &I &I ts
'4 0
-00
Sulfonatlou reaction. V11. l9quillbrittru botween l.
x! and Z-visphLbaleattemllionk 0". A. A. Spry,k.,%- 0,,u-
I - : -00
uv-k State Med. Itut.). J. Cell t-Whi ITT,*.';..';.R 1 17.
15t 1917)(iu Ru"lau). cf. ibQ. 17, M; C.A. 42,
1309-
bV4A.-Sulloustion of Coll, by an equlinol. arnt. of lt)r)~r
00 II.S0. in rAlvd tulics At 122' lesiN to rquil. betwero lite 1. -00
00 ind 2-,ulfo kotorts only xlowly RIIII -lily after -111, 1011111
5iltl lit.. J- A real aiwrzli to equil. laki, I'l.wir
go rquil. ratio at 1=0 6 1-2-botorr - 4:941. At I iW the -00
ciltsil. 6 reached fairly rapidly (atiaut 32 lit*.) whrn lite
0 #
abow ratio it V:91; with 1.10 moles of C1.116. the vent. if
00 1 -tolfo i%omer drops to 11.5%. hot with I"q than I owle =00
CIJIG. tile 11%olner itivrex-4-1 to (lite 11hrowitro-1 I,
- y~t mwtplaw,,I). At 163' 4 lit,. mift,, for r.1jol ; ,
It.-fr. if III, residual IWO. cout-11, dl.qm to IT*",. ifir I- coo
00 tillo i,omrr at equil. it only (1.5% of lite intal. when if,.. wee
I GSA). -u-1. drol. wity to thi, i~-cr i~ Gmsul in
00 6. %1. ko-Eimia goo
Are 0
coo
goo
A I L IT-U1-rrK-L LmAOLAI CLASSIFICkTiCk r Z C, 10
woo
E) U is AV W-) IS 16-1
Aft A It a N 0 1 w 0 2
K it it It K It If it, a a
IV I, I, 1, 0.
are 00 4114111411to* 09000 4999 0 0 a 0 er~ 0 0 0 Go 0 0 0 0 4111 0 0 0 6 0 a

~W INV M-W-W-W W %T 'a' W W-
.4 a 0 0
Iff if
I lip 1. 1 A i I I, I , t, 1 14 0 be if ill it A; 4;
6 V ~
-- - _ ! 4 x 1 - k.,,, 4,
A -A _L AL _G,.A J_& L 0 1`,!, 4 A" I L_ _V l. ~ ..V 4 1.~ MM
FUKOWS
CA
00 CU;A ~W.
00 The sadfouation reaction. VL11. H*at effect of ad- 100
s :i foution of amothallecte A A S %k Zhar. Objh-
0 Arl Kkim. (J. Gen. Cls*cin.)'I&"Ai-,-ro~-("Ii,;4,4); Cf. C-T -00
0: 42. 1921c; 43, 471c.--CAlorimetaic %luilyof sultonatiort dircrec of %ulfiviiatioo tif C,jl, was invmtiiptftl uml,, a -00
C,Jl. with 10V; H3S(la at tprodoeul-
of variety of coudition,t. At UW disultomillon i% Irrey,".
"lit (cwtuititiet of 1-iuliurr) ha~ %I"vn the ll,-kt effec ible. whileat IMbit is-versibleand 6 an equil. reaction. -00
00 i is 5.07 kad./mole (calcil. on liquid st.Lrting malt It was found that POlYsillforlatitin is prlssible with relatively Soo
-j! The beat of soln. of the anhyd. I -sulfouic acid in wa weak acid. Thus the following voticn%. of qwnt " were
0
0 8.5' is 0.06 krAl./intile. that of [lie hydrate is 0.30 kcul./ 'found: for diellifonallon of 2-15- 97r% at 11)0- at =00
00 d unile; hence the licat of hydration of the I ~tjlfauic acid is 103" Fill!'; for triinifonation at 1111* 7717;. Sall plel tit
%) 11,71iral./mole. Calcu. of the lival efirct in various stairs Cleft, W e firatril with 11.14,1 li. Jlj:;()j in %raini, lul~rs,
00 of the sulforiallt"I Allesw% that U, the Iniction litticertlil to after WhIlell's the %ulfonic Relds weir tilratnt. with the Ake.
00 MUllittliMl. it 11 at-ciltulkillitif by it Suldlit-t heat Wert suillPtiOn that It, ca" where few than 2 itioles IUSO, had r0 0
(per mole Clefts). IX. A method of preparation of Z- reacted per mole of Cleft,. the Inixt, contained only innno-
oe naphthalentsultonic acid under pressure. Ibid. 740-62; and disulfortic arisis, etc. This is confiern iroe
ed by th
cf. C.A. 41. 27LIV. C,jl, is tre.tritl with UISO..1110 in which a 3-1 niolar ratio gave 95q tit- and 57,5=1:
at MAW and hratnt 4 hr%. at 111:4 * in it cl(*"l rt~,l at 2 lemates- Only in very long cxpts. were insol. products
jarm. prr%surr. Thk proceilturr givm a low contrIll of
1-isomer (61-D and a high utiliiation of lljS04 (unused
W I but 4-1"); the 2-isomer is obtained in 92.2-
OCR 3
04.40/'o yield. Unreacted Civil, ranges front 14.4 to22.7c'
,when 1AXA-LIM inol. Cleft. is used per mole of HoWs.
:1 liThe analytical methtAl itself was described earlier (S., No
C.A. 40. M11). X. PtilyeaVonation of anodiallene.
jrbid.141-7: cf. liubnMovantlZo6n, C.A.42.5te.-The
too
=V11 C900
see
L
a., Get VILA3110-V
JIGAP
se
lit f? it it or 44 x a K it pt cg It it N MW A I
000000 0 00 0,00 0

a
it
0
00
0
so
00
90
00
0 &
90
00
09
Will
00
W W W-W-W a
0 0 0 0 0
Its were obtained with 100%
detaCtOd. Thc(0110wingrem -25
".So.: at 21), 0.19 Malt C1.11 per mole II*SO, in 0
hr. gave S-It"r 1110110- al"' disulft"lic acids; V-1 Mole
C'JI. Per tnole IISO. in 1_5 hr,. gave sil and 141!`v. -P-.
0,17 mole in 11.2 10 hrs. at ,,-25- gave 78 and 22%. feSP-;
e conditio" gave ~*% di-
bile 0.12 Mole untiff the sam its were:
and 2% tirisuljorlic acid,. At Im' the resu
O.W Mole Cj&tI a fK-f mole 112506 in -9) hrs. ta" 90% di-
r,sulfonates. spent acid conen. 118.71- . 010
and 10% t Ai t
mole in 165 b-. gave 90 and 107c. r-P-- 94-8 ." r
mono- and 46 . di-
acid; o.42 mole in 40 hrs. gave 54%
. 0.5 mole in 24 111's. We
s Mt W".
suilonates, 76.9% bile in
7i9; Mono- and 25,v discid, spent add 76.5%.
his pe 43% -- and 571~1, disultunic Wid-
1570 Isrs- t'
with 50% t " co-n At 130' the - I'S were:
5 Sy7o mono- and 2)% disul-
o.5 mole C.. fr. I. I hr. P;W
ww; in 3 hr3. 78% and 22%
jonk sews, 78%. spent .in 6 hr.. 71 % - and
and 727.7% IP-t acid.' t acid; 0.2 MOIC C"H'
en
29,1. disullonatej. 75.3% IP lfMic scids, with spent
in 3 hr3. gave 98-o di- -112% trisu 5%
v cmcn,, while 0.11,.r~ mole in 3 hr&. gave
acid 01
mono- and 95-, liutf-ic acids, with s5.3% spent WW-
. 0 mole clil, per mole IItSO4 in "I"S' ran9kg
At 163 0-1 j,70 tri-and 35% disulfom-
up to 36 hrs. gavT a ma" * of C)' ' Cljts
hs.), with 93.6% %Pcnt ()-20 mole
'i'('"36 t.210hrs-ffall- M... of 29% tri. and 71%
In carts, ~P -5'7c spent cone"';
t olo hr, with 841
disul onat'On n
00 00 00 0 0
4P 0~9 0 0 * 0
0 0 0 0 0 0
0 0 9 0 0 0 0
00
00
with 02 malt Cljf. (up to 210 lus.). 1he:.'W-nr. run pvr
64% mono- and 3o% diiulfort2tiou (02.6c' spent acid)
when 78.3170 HtSOq was used, while the III()% " Pire in
47 hrs. 1% mono- and 09~; disulfonates, with _6"
spent acW conen.. and at 210 Itts. 915% di- and 8-77 tA'
sultonates were obtained (spent ". 77.4%). whell 0.45
Mole C,oH* was used the maj. valuft were at 210 hn.
237c, mono- and 77% disulfortates, with 37.8"Pe spent aciel.
further Increase of the amt. ol Call. lead to the progres-
sively WIter amt3. of monosalfortates. Heating 0.25U g.
2."isultonyl chloride with 0.1321) W. HgO too bee. at
163' pve 12.2% by" Of the my rp lead. by
0 .74
SO$ deta.), while In a =6nhw expt. t1w .74somm save
id.8170 Wrolysis;
this shows that distiffonstion is no
longer revasible at this temp. Sultonatios at I- mad 2-
suffonaphthalevas at 100* with 0.1".4 mole per andir
If&SOd for 15-1 W hr$. showed that 960. 11t50. is capable
of introducing a 3rd soffo group into the mol.; thus. tbe
spent " concu. was 95%. when 0.18 mole I-COUr.
SOJI and I mole 100% IfPSO. were knK at WO' 1117 hri..
resulting in formation of 778% ell- and 22% trisalfonic
acids; with the 2-isomer, using 0.21 mole with W.0%
HtSOo. 15 hri. gave 3.6% mono- and 96.4% disulfortates.
with spent acid concn. of 82.7%. G. M. Kow)lapoff
00
00
00
00
00
00
00
00
00
00
00
& 0 0 0 0 0 0 0 0 0 4P 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0
00000000000000000_00000 0000000000000000--!!o

SPRYSKOV, A. A.
A. A. Spryskov, The study of the reaction of sulfonation. XI. The obtaining of
monosulfo acid during sulfonation of benzene with fuming sulfuric acid. P. 1370.
A method has been worked out for the sulfonation of benzene consisting of
different weight amounts of benzene and 23-27% of fuming sulfuric acid are mixed
in the cold and then heated while stirring in a closed vessel at 162-1630 for nine
hours.
Chair of Organic Chemistry of the
Ivanov State Medical Institute
July 4, 1947-
SO: Journal of General Chemistry (USSR) 18, (80) do- 7 (1948).