SCIENTIFIC ABSTRACT SOSIN, S.L. - SOSINA, YE.I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001652520014-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

27570
S /1 00/61/003/009/005/016
1
Synthesis of new types ... Bf 0/3101
(m) of 10,000-900,000P depending on the molar ratio.
2.18-10-3 0.328.
M The following reactions take place:
(C~ 3)3 COOC(CH3) 3 ----> 2(CH 3)3C0. (R-); (CII 03 CO* -> (CH 3)2CO + CH3(R-). Th e
radicals react with the hydrocarbons:-.
R'
(Calla)2 G112 + R - - (1). 1 1-I
(C4116)2 - if IC ted,14211 H'- lic (Calls), (QUISMCll,)2 it
.ebe resultant polydiphenyl methylene (PDP,','L) (I) does not decompose to free
radicals in the presence of diphenyl picryl hydrazine, and is stable to
oxidants (111103), since the structure of tetraphenyl ethane (TRE) which is
probably formed initially does not permit the formation of stable radicals.
Rearrangements might take place according to
C C C u
Card-2/7.

S/196/61/003/009/005/016
Synthesio.of new types ...
Bi 1 Q/B1 01
and

He (Q51161.1 CH (C4116)1 T~ 11C (C#114)1~ (P41164 7

HC (C,Hs),C (Clis) (C6116)$ AHOI CC111 + (C4115), C11j;
(CO115),C C111 C A dah- C11S. C (C$11j)1- C112 -

The'repeating unit in I and II is: d H- in III- C When
-
H
12
0
f 14
13
compgring the IR spectra of the polymers from DPM, TPE, tetraphenyl
StiC
ethylene, and 1,1-diphenyl ethylene, the absorption maximum characteri'
7

0f-1
-1) wasjound to be absent in PDPM.
,4-s.ubstituted benzene (833-940 cm
.
-Structure Il is therefore not possible, III was also excluded since the
maximum (760.
cm-1) characteristic of,the 0 H a-CH configuration was
.6 5- 2
absent as well. The PDPM structure according to I is thus confirmed. The
dependence of the yield on the molar ratio of PO 'to hydrocarbon indicated
an almost complete consumption of the first peroxide mole for the
dimerization (A). of the total DPM,to TPE (90~Vyield). At a ratio of
2 ; 1 the polymer yield (B) is constant (50%).- This accounts for the
C rd 3/_7 . .... .. ------
a
Ij-

27570

S/190 61/003/009/005/016
Synthesis of new types 0-1 Bi I 01bi 01
change in viscosity. In A, TPE is formed (melting point,209-2110C, i.e.0
higher than the reaction temperat~ie),-and' viscosity Considerably
increases. In,B, however, it,decreases since.the-low-,molecular-polymers
melt already at 180-1900C. The reaction of TPE 2which is firstaocelera'ted~
is then retarded by the formation of high-molecular pol*ymers (melting
0

educed toward the end of the read-
point 200 0). The viscosity will be r
'Peroxide
tion by adding a DPM-PO mixture -to IiPM; thb'yield increase.e.
admixture of > 2 moles/mole of DPM g;,aphically results in a steep ascent
of the molecular weight which asymptotically approaches the ordinate.
er), the
Assuming that'ihe'ahain grows by doubling (dimer, tetramer, octam
following holds: if - 2 - 2/n, where*N' '= number of free radicals/moles
R R
n - polymerization coefficient. I mole of free radicals is formed on
decomposition of TBPO. Maximum M is-thus obtained for a PO consumption of
2 moles/Mole of hydrocarbon. 0.68 mole tert-butoxyl radicals result from
I mole PC (in the form of tert-butyl alcohol). 1.32 mole of radicals
decomposes to give 1.32,mole acetone and 0.66 mole methane, as' follows:
0
1 90-2000C
kCH CO*
(CH 34 CO* 140 C 3)2C0 + CHj, and (B) (CH 3 3 0, (CH 3)2C0
(A)
.
+ CH -0-C-(CH According to Yu. A. Aleksandrova, Huan YU-1i, A. P.
3 3 3

d
C
ar 4/ V

27570
S/190/61/003/009/005/016
Synthesis of new types ... B140/B101
Pravednikov, S. B. Medvedev (DQkl. AN BSBRo 1231 1029, 1958)j'no methyl
(j radicals are formed in (B) which takes place at higher temperatures.
Isobutylene oxide reEults on initiation of. the peroxide decomposition Th't;
51-5300: isobutyl-methyl ether and
authors separated the fraction
isobutylene oxide. In the name way, they obtained polymers which dissolve
in benzene. When using ditolyl methane instead of DPM a olymer
(melting point 180-2400 ith cross-:
insoluble in benzene and p-oresol C w
linked structure is obtained in addition to linear polymers (melting
point = 150-1800C, molecular weight = 2500). The elemental- organic
polymers obtained from diisopropyl ferrocene, ferrocene, and triphenyl_,t'ik
N-isopropyl borazol (TPNI) by means of polyrecombination showed IR
absorption maxima at 820, 1000, and 1100 cm-1 , and, accordingly, structV
(A
CF Fe
are dark-red powders soluble in benzerie (softening..
M 1000-7000; they
point /v300oC) (line wid.
The electron paramagnetic resonance signs,
U
Card 5/7
's "~6

27`70
S/1.90/61/003/009/005/016
synthesis of new types ... B1 I 01B1 01
120 oe, 2000) confirmed the existence of unpaired electr.ons (concenttati.o"'n.4''.-"'~p;~,*
21/g
10 polymer). Treatment of TPXI with TBPO yielded only a soluble-f*
low-molecular polymer.. Polyrecombination gives also. polymers with.
aromatic rings in.side and principal.ohains. A soluble copolymer was
obtained by treating a mixture of DPM (0.1 mole) and DIPB (0-1 mole)
0.25 mole TBPO; DIPB alone gave a nearly insolizble polymer. 26-dichloro-41
P-xylene gives a chlorinated analog of poly-p-xylene soluble in benzene..,-.,.
Cl in ortho-position to the CH3 groups blocks them and prevents their
participation in the formation of linear chains. Polyre combination thus_....Ii:~~-%'~'.~',~:.
results in carbon chain polymers with aromatic rings in the principal
chain, whose production is difficult. Gas chromatography of DPM was made
on the X -2 (Kh-2) apparatus. There are 4 figures, 1 table, and 18 refer'-
ences: 6 Soviet and 12 non-Soviet. The three most recent references to'
English-language publications read as follows: Ref. 7; G. A. Russel,
J. Amer. Chem. Soc., 74, 1047, 1,056; Ref. 9: J. H.. Brook, Trans. Faraday
Soo., 52, 327t 1957; Ref. 10: K. M. Johnston, G,'H. Williams, Chem.and
Chem. Ins. 1958, No- 11, 328.
ASSOCIATION: Institut elementoorganicheskikh Boyedineniy AN SSSR
(Institute of Elemental Organic Compounds AS USSR)
Card 6/7

2-2-0c) 1 2400j, III L e 080
S/1 9016110031009110 15/016
16-.8 Doc) B 12 4/B 101
AUTHORSt Korshak, V. V., Sosin, S. L., Chou Jun-p'ei
TITLE: Production of polymers by thermal dehydropolymerization of
hydrocarbons
PERIODICALi Vysokomolekulyarnyye soyedineniya, v. 3, no. 9, 19061, 1427
TEXT: Heat-treated hydrocarbons are cracked and dehydrogenated, and
yield, besides low-molecular decomposition products, resins which are
low-molecular condensation products with a complex structure which greatly
differs from that of the initial products. Such resins are formed both
by gaseOUB-phase pyrolysis and liquid-phase cracking. High-molecular
polymers cannot form under these conditions due to the inevitable 4ecom-
position in the high-temperature zone, High polymers may be also ~jtained,
however, when the hydrocarbons are thermally dehydrogenated under con-
ditions preventing thermal degradation of the polymer. The method devel-
oped by the authors is based on the liquid-phase dehydropolymerization
in a flow of nitrogen on a platinum or tungsten coil electrically heated
to 650 - 7000C and immersed in the liquid hydrocarbon. The hydrocarbon
Card 1/3

27~80
S/190/61/003/009/015/016
Production of polymers- B120101
is dehydrogenated on the coil, and simultaneously forms polymer products
which are immediately carried along from the heated surface by the liquid
hydrocarbon. The condensation products obtained are led from the high-
temperature zone to a heated container where the drops of the condensation
products are collected, and the unreacted hydrocarbon is distilled off and
-recycled to the reactor (see Fig.). A number of alkyl and hydroaromatic
hydrocarbons was treated in this way. Tetralin is converted to naphthalene
.jR4~X..th4,9dAdLtjQns described, whereas polymers are recovered from p
-xylene,
..cumene, ethyl benzene, and p-diisopropyl benzene; the molecular weight of
thelpo'I rs*o1Aained from p-diisopropyl benzene is about 10,000. The
yield in polymer is 10 - 15% related to the hydrocarbon used, and 70 - 80%
related to the reacted hydrocarbon. There is 1 figure. ibstracterts
note: Essentially complete translation
SUBMITTED: January 12, 1961
Card 2/3

SOSINY S.L,P kand.khim.nauk
Gaa-liquid chromatography. Friroda 50 no.7:101-104 Jl 161.
(MML 14:6)
1. Institut elementoorganicheskikh soyedizkeniy AN SSSR, Moskva.
.(Chromatographic analysis)

5102 eiftIO0610131020
B1030YB217
AUTHORS: Nesmeyanov, A. 17., Academician, Korshak, V. V.,Corresponding
Member AS USSRp Voyevodakiy, V. V., Corresponding Member .1
AS USSR, Kochatkovaj-.11, B., Soein, S. L., Mate;ik.v., R. B.,
Bolotnikovat T. N., ChiTriki_n,-7.-9--_,&nd Bazhin, Y. 9.
TITLE: Synthesis and some optical-magnetic properti*u of poly-
forrocenes
PERIODICAL: Doklady Akademii nauk SSSR, v. 137, no. 6, 1361, 1370-1373
TEXT: The authors studied the magnetic properties of ferrocene derivativees-/
1) of the polyferrocanylones (Table 1, nos. 1-6). 2) the polydiisopropyl-
ferrocene (Table 1, nos. 7-6), 3) the polymethano- and 4) the polyethano-
polyferrocenes (Table 1, nos. 9-13). They were synthetized by. A) Poly-
recombination- To 1), and 2). 1 ipole ferrocene (or of its diisopropyl
homolog) was treated with 1 mole tertiary butyl peroxide In nitrogen
atmosphere at 20OPC.111) and 2) are assumed to be formed as follows; the
Butoxyl and methyl radicals formed during peroxide decomposition separate
the hydrogen from ferroaene (or the cc-hydrogen). The radicals thus formed
Cari 1/6.5-
0.

f
S/0201jOP/-,J?37/006/P13/020
Synthesis and some ... B103/B217
recombine and form linear 1) or 2), easily soluble in benzene. An in-
soluble polymer (Table 1, nos- 5-6) with a two- or tridimensional network
structure is formed simultaneously. The conversion of ferrocene to high-
molecular products amounted to 25~- Nos. 1-3 have a softening temperature
of 290-3000C and are a dark-red powderp whereas nos. 5-6 had their softening
temperature at about 4000C and were light-yellow. B) Polyalkylenation of
ferrocene by methylene chloride and tt2-dichloroethane in the presence of
anhydrous aluminum chloride. Aluminum chloride solution in 50 ml of di-
halogen alkane was added gradually to 40 gferrocene dissolved in 250 ml dry
dihalogen alkane. The mixture was stirred for 6 hr at the boiling tempera-
ture of the solvent. The next day, 10 g aluminum chloride in 25 ml dihalo-
gen alkane were added and treated "or 6 hr as above. The mixture-was
decomposed by ice and EICI and treated with sodium sulfite. The obtained 3)
and 4) were well soluble In benzene, differed, however, by their solubility
in other. Table I shows the molecular weights, the always equal g-factor
and the magnetic characteristics of all substances produced. The decomposi-
tion temperature of 9-13 was 115-12000. All substances are amorphous
powders, nos. 9 and 10 light-yellow, no. 11 grey-brown. Nos. 10 and 11 are
of a chemical composition similar to that of no. 9 (pentaethanodifferrocons).
Card 2/-(,,s--
------------

6
2385h
8/020J61/13'1/006/013/020
Synthesis and some ... B103/D217
They consist possibly of 2 and 4 molecules similar to the latter, connected
by ethane bridges. 4-5 methylensa in the molecule of nos. 12 and 13 belong
to 2 ferrocene radicals. They do'not contain halogen. The infrared spectra
of nos. 9-13 have frequencies within the range 1000-t100 cm-1. To 1).
Derivatives 1) having a n-conjugation between the ferrocena links give a
signal the electron paramagnetic resonance (e-p-r), similarly to the poly-
aromatic hydrocarbons. This cannot be explained by the presence of a
rresponding quantity of the oxidized form of the ferricinium*cation.
cc
Table I shows that also polymers in which the ferrocene links are separated
by the -CH2-GE27 group give an a. p4 r. signal. It is known that the
delocalization of the unpaired electrons between the two phenyl ringa'is not
prevented by this group. In the substances described here, which give an
e. p. r. signal, this signal is the smaller, the smaller the number of
ferrocene links is. This signal vanishes in 2). Polymers with a low
.molecular weight give no e. p. r. signal in the solution (benzene), but in
solid state. This is explained by the fact that the Intramolecular
interactions cause in solid state a conjugation of the adjacent polymer
molecules. This causes for its part an s. p. r. signal. All polymers
Card 3/i,5-

23"54
S/02 61/137/co6/013/020
B1 03Y3217
Synthesis and some
a neutral-901vent (n-octane), j. e. under conditions
t~ that of ferrocene in the authors point out.
under which the charge i3 not transferred. Finally,
-spectra apparentlr confirm the
that their results concerning.the UV
of the polYnucleotides and of the polyaromatiC
"pseudoferromagnetism" nd 8). There are 1 figure, 1 table, and 8 references:
h drocarbons (Refs. 5 a erence to _~ngljajj-language
y t-bloc. The only ref
7 Soviet-bloc and 1 non-SOvif! - 7: Trans. Farad. Soc-t
n reads as follows: J- C. D. Brand, Ref
publicatiO
53, 894, 1957.
'icheskikh soyedineniY Akademii nauk SSSR
ASSOCIATION': Institut elementoorgan do of the Academy of
(Institute or zlemental-organic Compoun
scl6nceo, USSR)
SUB1,1ITTED'. December 20j 1960
ene
1-4) linear polyfarrocenyln t
Legend to Table-1. I) current number r
rrocenylene, 7) ~olydiisopropylferrocenej li aa Y
)luble polyfe ucts of ferrocene with Di-1 2-
5-6) iftsc )Juble,19-11) condensation prod
li;,e 7, ino( -ide, 14) ferricinium cation
ith methylene chlox r's
chloroeth-, 19-13) tor, V Vi) line widih, oe
8, IIIII'mdecular weighto Iv) g-fac
11) Substaw
Card 5/(k!;-
/062/62/000/009/00 .8/009
B1 19/B1,16-
aT'O'v 1
r
ic
from itriles of al Ye
of ()tdejelli
Iq
rjtae5jS .ZreStiYa'
C
- , , & a&lpll
1650 all Oc J'-a
T IT US SSSR 1644 -le 20
.k1K1,,,,je1ajLV' 1962, tri to ,.aa.erVerlt,
TIO. lojac dAill *. heating.
11 & by . Jg O:IymerS
,RIODI 0 ter (1), Tas. combille t e
es ,lyre res'cLItl arA eldea
ti, 1,jetlly r tlaeRl .(je Tjje -1 1 St'adL3.e 1 13-
0 *ere t,,inecl - Br
O~Yflnoace e ELCII ero-j~l ectra 50 Ob ,,oleGjal
L. Vere 6. S P -ae-ta
e (-III) 'rtiary bUtYl 9 -je .'aaV1119 f telling
0 r0l 'JUEJ
(linitr1l Of t -Le3.r I'a ,all tj Ui&e 7 t ut'ea) so
,5ej,,(,.e 3.S. Tj ,,OtteCl e thy" '01 amoull
tt,e Pre aylalys sclaeMe Was t .rl (13.M r 0 -'~r
tarj tio lxiblO 1 tyle 9e -&e
elemell re~Lc 11 olymer so nding OrL OlEtr "tjo perOY-1
,OrobeLb e %id e r _P 00 (&epe t ELM
8, ~: 00 00 - 13
blac 0 jiell
vjelgh~ t of 4 000 C "
ratIlre
temi)e C'rielne
re klotioll
Ge.rd 1/4

S/062/62/000/009/008/009
Synthesis of polymers from B119/B186
CN CN CN CN
I I
R1 C R1 C
CN CN R It L; R
C R, R2
(CH -C- C R C R C
1 2 4 1 -, I i I, 1 1 2
GN (CH
2 'C C C
C~~N C
LCN 31n
n = 104; R1 = (CH 2) 3CN;R2 CH I. OC'(CH33] CH .2-)2N
III too ga.'Ve a black powder soluble in dimethyl formamide; molecular.
weight 5500 (maximum 6200 after.fractionation); softening temperature
5000c; 75 ~, yield.at a molar ratio peroxide -- III = 0-4 -' 1; reaction
scheme CIT CN CN CN
I "R I
CH CH (CH3)3CO4 CIH HCIOC(CH
2 1 2 ji ] 4 1 2 1 3 3
C'1.1 C n
Card 3/4

KORSHAK, V.V.; SOSIN. S.L., kand.khim.nauk
New method of the synthesis of polymers. Priroda 51 no.4:98-101
Ap 62. (MIRA 15:4)
1. Institut elementoorganicheskikh soyedineniy, Moskva.
2. Chlan-korrespondent AN SSSR (for Korshak).
(Polymerization)

KORSAK, V.V., VTNOGRAWVA, S.V., SOSIN, S.L., SIADMV, A.M.
Synthesis and electrophysical proportion of the polymers with the
conjugated system of bonds and the polycoordination po2ywrs.
Report submitted for the International Symposium of Macromolecular chemistry
Paris -3.-6 juV 63

L 11Q82-6 Envzwp(j)/EPF(c)/W(I-)/W(m)/BDS-,!ASD/PJ~-3--Ps-4/
S/0190/63/0051005/0663/0669
AdCESSION NR:. AP3000691
AUTHOR: Korshak, V.; Sosing S. L.; A_Iekseyeva V. P.; Morozova, Y6. H.
TITLE: Investigation of the structure ofla Polymer prepared by,the polyrec=..::.
bination of benzy!
-trifluorciaditate
ulyarnyye so dineniyet' v-. 5, 1963i 663-669,
SOURCE: Vysokomolek
yo
J1
TOPIC TAGS.-. polyrecombination,'polymer, b4nzyl,tiifluoroace~ate' electron
paramagnetic resonance
ABSTRAM The structure properties of a polymer prepared by the polyrecombination.,
Tn s t i t noelemental.
of benzyl tr4fluoroacetate have been studied:at the ute of Orga
Compounds, M SSSR by IR and EPR spectroscopyand.by'the method of the=o- .
mechanical curves. The polymer was--synthesized..at 170C in:the presence of tert-
butyl peroxide by a previously discribed-method.(V. T. Korshak S. L..Sosin,
M. V.'Chistyakov, Uspekhi Lkhimii L tekhno'logii polimerov, Goskhimizdat, 1960
P. 45), and theLreaction.products were isolated and ainalqzed. Study of the
S L
thermomechanical curves indicate that the polymer exhibits elastic.propertie
at 220 to 550C. As the peroxide/monomer ratio1s varied from-2.15 to 3.05/1, the
polymer yield varies from 7.05 to 31.47. on.the reacted monomer, the.mol. wt. from~~
1020 to 22,000, and the softening.point from lWt6 580C. LThe,EPR.spe trum of:
C
.1/3

VASEEV, V.A.; SOSIII, S.L.; KORSIIAK, V.V.
Study of the reaction of fatty and aromatic acid nitri-les with
tertiary butyl peroxide. Izv. AN SSSR. Ser.khim. no.7*.1312-
1319 JI 163. (MIRA 16:9)
1. Institut elamentoor anicheskikh soyedineniy AN SSSR.
(Intriles5 (Butyl peroxide)

VALIKOVSKIY, D.G.; SOSIN, S.L.; KUHSHAK, V.V.
Study of tart-butyl. peroxide decomposition and the reactions of rad-
icals formed in the synthesis of polydiphanylmethylene. Izv. All S,')O-*R.
Ser.khim. ho.?.-1319-1327 JI 163. 0,11RA 16:9)
1. Institut elementearganicheskikh soyedineniy Al, SSSR.
(butyl peroxide) (Polymers) (Radicals (Chemistry))

VASNEV, V.A.;.SOSIN, S.L.; KORSHAK, V.V.
Syntre-sl`sof-Vo-lymers from diphenylmethane derivatives by means
of polyrecombination reaction. Izv.AN SSSR.Ser.khim. no.8:
1487-1496 Ag 163. . (MIRA 16:9)
1. Institut, elementoorganicheskikh soyedineniy AN SSSR.
(Pplymers) (MBthane)

3/190/63/005/004/004/00
MI/B220
AUTHORS. Sosin, S. L., Korshaks V.-V.
TITLE: Polybenzylidene- benzoate and,polybenzy-l.idenealcohol
PERIODICAL: Vysokomolekulyar'nyye soyedinehiya, v- 5, no -499-505::
4,' 1963,,
TEXT-. Previously (Dokle AN-SSSRO 132P;360t 1960) polybenzylidene benzoatd,"
COO-C-C was.obtained by bringing benzyl benzoate into reaction
IC6H5- I 6H51n
with tert-butyl peroxide. In ~tms paper the. conditions of tlie synthesis
were studied mor thoroughly- and the 'polymer was converted to polybenzy3jidew
alcohol.. The dependence of~.yield and molecular weight on the initiator/
monomer ratio was determined:-and a-maximum m.w, of o a
5409000 was bt ined
with 2.35 pole peroxide per mole-benzyl benzoate.. Compounds~obtainedfrom~
the low-molecular reaction,products by treatment.with acetic.acid-and pre-,~_-.
cipitation with methanol: diphenyl ethylene - glycol.. dibenzoate W. , ah is An
in-termediary.polymerization produotv,.a:low-molecular polymer fraction
(Mew. 6oo - 8oo), and a mixture of methyl-phenyl carbinol benzoate and
a-methyl hydro benzoin dibenzoate. Therefrom it is concluded that a small
number of side reactions also occur,with the methyigroups formed on:de-
Card 1/4

5/190/63/005/064/004/020
Polybenzylidene benzoate and BIOI/B220
QlfI
-L -
L
-0
o,
o

H

OH:.

C., CH .4

0
ff OH
~
c,41 CSHCOCGIC
H

Card 3/4

KORSIIAK, V.V.; SOSIN, S.L.; ALEKSEYEVA.. V.P.; MOROZOVA.. Ye.M.
Structure of the polymer obtained by polyrecombination. of beazyl
trifluoroacetate. Vysokom.soed. 5 no.5:663-669 My '63-(MIRA 17:3)
1. Institut elementoorganicheski-kh soyedinep-iy AN SSSR.

--OOSIN, S.L.; KORSHAK, V.V.; ALEKSEYEVA, V.P.
Polymers and copolymers of derivatives of ferrocene obtained by
the polyrecombination method. Dokl. AN SSSR 149 no.2:327-329
Mr 163. (KRA 16:3)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.
2, Chlen-korrespondent AN SSSR (for Korshak). -
(Ferrocene) (Polymerization)

KORSHAK, S.L.; VA.SNEV, V.A.
Synthesis of polymers from the nitriles of aromatic and fatty
acids by polyrecombination reaction* Dokl. AN SSSR 152 no.4t
872-874 0 163. (MIRA 16:11)
1. Instl~ut elementoorganicheskikh soyedineniy AN SSSR.
2. Chlen-korrespondent AN SSSR (for Korshak)j -

AGGMION NR: APL005~163 S/0190/6h/006/001/0180/0181
AUTHORSs Korshaks V..V.; Sosins S. L.~
TITU: Production of high-molecular polymer by p-di-isopropylbenzene reaction with
tret.,butyl peroxide [retter to the editor]
SOURCE: Vy*sokoiwleku1yarnMe Boyedinenlya, ve 6, no. 1,, 1964$ 180-181 and.
lower half of insert following page 86
TOPIC TACS: polymers cr73tal3ine structures quinoids isomer, chromatography,
oligomer, isopropylbenzene
ABSTRACT: It has been shown that chromatographically pure' p-di-isopropylbenzone
.4solecular weight polymer
reacts with trot,butyl eroxide it 200C to form a hieh
rX
> - 5.1
in.
(mol wt 4-10 1 ) of cr7stalline structure. This is apparently due to CM
-izetion of the diradicals in the quinoid forms given by
polymer
CHI ell, CHI CHO CHI Cue
C-1
2H 4.-H-
Card 1/2

AccEssioN NR: Ap4oo9l63
The m-isamer gives ca3y the olUcmar under the some cagoms, "The authors are
grateful to V. B. Bondarev and S. V. Vitt for the gas-liquid chromatography
analysis." -Orig, art. has: 2 figures and 2 formulas.
ASSOCINrION:- none
eb64 ECL: 00-
sumarrED: losep63 DATE AGQs 3.0F
SUB CODE: PH NO REF SOVI 001 QTHER: 003
Card 2/2

ACCESSION NR: AP4019011 8/0062/64/000/002/0347"/1)353
AUTHOR: Sosin, So Vo; Korshak, V. V.
TITLE: Synthesis of polymers from phenole and their caters by polyrecombLustion.
SOURCE: AN SSSR. Izv, SerLya khtaLcheskaya, no. 2, 1964, 347-353
TOPIC TAGS: phenol polyrecombinatLon,.cresol, phenol, hidroquinone, cross
recombination
ABSTRACT: As a development from their previous work, the authors investigated
the'polyrecombination reactions of p-cresol, phenol, hydroquLnone, dimechyl
ether and hydroquinonedLacetateo Polymers with mol, weights ranging from 7000
to 10000 were prepared by.treating them with di-tert,brutyl peroxide at a temper&-
ture.of 200C. Their properties were investigated. The authors propose a
probable formation mechanism of such polymer, taking Into account, In the case of
phenols with free hydroxy groups, a preliminary cross-recombinatiou of phenoxy
radicals with the active free radicals# The polymer of hydroquinone has a chain
of alternating hydroquinons and benzoquinone rinp and shows superior thermal
C.rd 1/2

ACCESSION Y.R: A24019012 S/0062/64/000/002/0354/0357
AUTHORS: .Sosin. S.L.; Korshak, V.V.
TITiLE: Polymer synthesis from aromatic amines by polyreoombination
SOURCE: All SSSR. Izv. Seriya khimioheskaya, no.2, 1964, 354-351'
TOPIC TAGS: polymer semiconductor, aromatic amine polyrecombination,
amine, aromatic amine, polymer,*semiconductor
ABSTRACT: High melting points and possible application of these poly-
mers as semiconductors prompted this work. This is a continuation of
o-'cher work by the authors showing that polymers with regularly repeat-
ed azo-group in the chain (i.e., polyazobenzenes and their analojues)
can be readily prepared by polyrecombination of aromatic amines (p-
phenylenediamine, benzidine) when treated with tertiary butyl peroxide
at 2000. ADDarently, polymers are formed by recombination, active bu.-
toxyl and methyl radicgls formed in the decomposition of the peroxide
tear off hydrogen atoms from the amino-groups while the radicals which
are formed recombine with the unpaired hydrogen at the nitrogen atom.
.1 further growth of the chain on behalf of the amino end-groups Is
Card 1/2

ACCESSION NR: AP4019012
apparently accompanied by the eous dehydrogenation of the see-
ondary amino-groupp resulting Znimuo+~yaxa'zobenzene. Along with the graw1h
ol" the chain, ther6 is the possibility of an attack of the benzene
rings by active radicals and conden�ations as a result of homolytio
substitution of hy4rog'n atoms. To'prove these preases, the authors
heated initial comp"oun.s; benzidinep p-phenylenediamine and a mixture
of the latter wlth*:hyd~oquinone in q nitrogen atmosphere until they
melted (but below 200C)' and introduped into the melt tertiary butyl
peroxide dropwise until the mixture chickened. The reaction product
was leached with methanol or dimethylformamide and the solid residue
was analyzed and its characteristics determined and described. The
molecular weight of the polymers amounted to 7000.
11SSOCIATION; institut elementoorganicheskikh soyedineniy AN SSSR
(Institute Of Organoelemental Oompounds, AN SSSR)
SUBMITTED: 22Aug62 DATE ACQ: -.27Mar64 EXCL: 00
SUB CODE: CH WR REP SOV: ;006 OTHER: 005
Cord 2/2

~ACCESSION NRi AP4032577 S/0190/64/006/004/0745/070
AUTHORSt Korshak,, V. V.; Alekseyeva, V. P.
TI'17,E: A study of the possibility of synthesizing high molecular coupounds from
idiplianyisilane under conditions of the polyrecombination reaction
iSOURCE: Vy*solcomolelc, soyedin., v. 6.. no. 4. 1964) 745-750
'TOPIC TAGS: organosilicon compound, diphenylsilane, triphonylsilane,, tetraphorql-
isilane, phenylsilane polyrecombination) phonylsilane, heter-ochain polymer.,
1'etraphenylsi-lane polymer, diphenylsilane disproportionation, UR 3.0 spectroscopep
,iTrub Tauber spectrometer
i
'ABSTRACT: The polyrecombination of diphenylsilane was conducted in the presence
'of tort.butyl peroxide in a special apparatus at 170 and 2000. The reaction
~products were treated with benzene, and the soluble polymer was precipitated with
imathanol. The obtained compounds were fractionated, analyzed chemically,, and
.examined by i-nfrared spectroscopy on a UR-10 apparatus and on a nuclear magnetic
oresonance TAb Tauber spectrometer. The main polymer isolated by the authors

:'ACCESSION NR: AP4032577
is ascribed the formula
r
C113 -4116-
ilts formation may have proceeded through the intermediate product tatraphenyl-
silane, which has been isolated from the reaction' products together with
triphonylsilane and hydrosil icon. Since at a 1:U.1 molar ratio of the issuing
diphenylsilane and peroxide only 4% of diphenylsilane could be recovered, it is
lassumod that a disproportionation reaction takes place in which some of the
1products become involved in the building of the polymer chain. This assumption
11s supported by the fact that increased concentrations of the peroxide result in
la higher yield of tetraplionylsilane. Heating of the obtained polydiphenylsilane
!of molecular weight 1530 to 9000 in a quartz tube yielded a polymer with a*molecu~-
ilar weight of 810. The benzene-insoluble fraction of the diphenylailane'poly-
1rocombination reaction products yielded a polymer of 190 500 molecular weight.
iOrig* arte hass 5 formulas and I charte

;AGCF,SSION NR: AP4032577
ASSOCLITION: Institut alementoorganicheskilch soyedineniy AN SSSR (Institute of
;Oreanoelemental Compounds/AN SM)
SUB121"TED: OlJun63 DATE ACQ3 1L%iay64 EWI,: 00
'SUB CODE; CH NO REF SOV: 005
OTIMR 1 009
13/3

AGCMSIdN NR: AP4037279 S/0190/64/006/005/0827/0831
ATYMORS: Sosin) S. L.; Korshak, V. V.; Alekseyeva, Ve P.
TITLE: A study of the possibility of obtaining high molecular compounds from
4iphenylgermanium under conditions of the polyrecombination reaction
SOURCE: Vy*sokomolakuly;,3rny*ye sdyedinaniya, v. 6, no. 5, 1964, 827-831
TOPIC TAGS: diphonylgermanium pol'Yrecombination,, diphenylgermanium high molecular
compound, dipherkylgermanium disproportionation reaction, diphenylgermanium dispro-,
portionation nroduct, tatraphenylgermanium) diphenylgermanium, germanium hydride
ABSTRACT: The polyrecombination of diphenylgermanium was conducted at 200C (in them
presence of tert.butyl peroxide) by a technique described by the authors in an
earlier publication (Vy*sokomolek. soyed. 3., 1332., 1961), The reaction product was
treated with benzene,, and the soluble fraction was precipitated with mothariolt It
was found that the disproportionation of diphenylgermanium produced 50% of apoipw
Card 1/2

ACCESSION Nit: AP4037279
(with a maximum molecular wei ht of 1840) and also tetraphenylgermaniums tripherwi
germaniumo and germanium hydNde., the presence of~which was confirmed by infrared
spectroscopy. The thermai Wiproportionation of diphenylgermanium also took place
without tert.butyl peroxide it 200C and at i4OC. :~A copolymer of diphenylgermanium
-with diphenylmethane in equimolar ratio was synthbsized in the presence of teks-
butyl peroxide, yielding an amorphous brown product with a molecular weight of WO
Prig. art. has:. 4 formulase
,ASSOCIATION: Institut elementoorganicheskikh soyedineniy AN SSSR (Institute of..
Compounds, AN SSSR)
'Organoelemental
'SUBMITTED: OlJun63 DATE AOQs 09Jun64 WCLI. 00
SUB CODEt MT NO RZFSOVs. 004
OTHER$ 008,il
C,,d 2/2

kCCESSION NRt AP4037282 S/0190/641096/005/0843/0549~1
AUTHOR: Vasnov,',V, A.; Somin,- S. L.1 Korehak, V. V.
TITLE: Preparation of polymer@ by r'ee*WubLnation from aromatic,'
and aliphatic nitriles
J.,
SOURCE: Vy*sokom~lekulyarny*ye 96yedinaniyat ve 6, no. 5j 1964,
843-849
TOPIC TAGS: organic semiconductor, semiconducting polymer,
polynitrile, recombination, nLtriles aromatic nitrLle, aliphatic
nitrile
ABSTRACT: A study has been made of 1) the polyrecombination of
an aromatic nitrLle having no substituents such as methyl or athy'''.1
lene, and 2) the syntheaLs of aliphatic nitr1le copolymers showing:-,,."'
both high thermal stability and solubility in organic solvents
and softening without decomprooLtiona. In case 10 banxonitrLIG was..
V.
113

ACCESSION NRs AP4037282
i treated with tert-butyl peroxide to form a polymers
CN. CN 1.CN CIN
7J
OR
+ R
H `H
F1
The above polymer structure was confirmed by IR and elemental
analysis. In case 2, a mixture of two nitriles was treated with
tert-butyl peroxide:, malonitrile and adiponitrile, a-tolunitrile."..-11-
or diphenylmethane; methyl 2-cyanoacetate and a-tolunitrile or
malonitrile. All the copolymers produced contained a system
of conjugated C-N bonds in the backbone, gave an EPR signal, and
I had high decomposition temperatures (300-600C)g- but showed
no elasticity* As a rule# they were soluble in dimethylfornamide
and croool only, and exhLb-Lted semic nd cting propertiamo The
0 U V
temperature dependence of. conductivity obe ad an exponential law.
JCard 2/3

-ACCESSION NRs AP4037282
Conductivity measured in vacuum (about 10-3 mm Hg) at 293K
ranged from 3.354~10-22 to 9.33 010-17 ohm-1 cm-1, but at
225-300C it reache
d 10-l'ohm cm-1. This research was done at t
Institute of Organoelenental Compounds of the Academy of Sciences.
-...USSR. Orig. art. has: 2 figures, 3 tables, and 6 formulas,
,ASSOCIATION: InstitU
t a!gmentoorganichaskikh soya dLneniy AN
'SSSR (Institute of*.Organ elemental.3 Compounds,AX SSSR)
i tUBMITTED: 05Jun63 .-DATE ACQt, 09jun64'.., ZNCLt 00
SUB CODE: xz NO REIF SOVs. .0017 OTHER s
109
Cad 3 3

SOSINI S. L.; KORSHAK, V. V.; VALIKOVSKIY, D. G.
Reactivity of hydrocarbons and their derivatives in the polyre-
combination reaction. Dokl. AN SSSR 155 no. 2:376-378 Mr 164.
(MIRA 17:5)
1. Chlen-korrespondent AN SAR (for Korshak).

SOSINY S.L.; KORSHAK, V.V.; VASNEV, V.A.
Effect of polar factors in the polyrecombination reaction.
Dokl. AN SSSR 156 no. 5:1124-1126 Je 164. (min 17-6)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.
2. Chlen-korrespondent AN SSSR (for Korshak).

L 19798-65
ACCESSION NR:
AP59030.0
ASSOCIATION :.Institut eleme,htoorg haq)cikh --ao-' liiiifl* W SASSR ~lUstitute'
Heteroorganic Compounds, AN "SWR)

-.SUBMITTED:
i0_ EML: ~~00,-_~,-; -SUB CODE:
194TU~
::..
,GC
OC
, ,
.-NO REF SOV: 008

d
,ev

;Card 2/2

tertLar - bikt. p.
y aromide a the'source- of 79ree radMis.~ A, ioi
a Vow was
:Card

47

V~ I

if

'TIM'-
a
fa rati I

se:,. macr.omo ocu ar..:,packL
id, .. Ither'nicue chanical,-. curve:,-'--'-,,,-,'.,'.---,,

7A CCES~ - 1;

10
AP404 7 2 1 5
71

showing th a
1
cry$ ta IIivL an d h L Sh-c I a aiid do f 0 jVAa t i ojr,.'
absenc.6

ri g art .
3,f 'I
u r1i t ab a
has 1 4- 1 LIS 8 1 1 1& fl drou A s

S~O CAT t
OR -4heekik -

h -'soyed poul* AN
't I
stitut- is otmen oprSakpi

S S
(Instltuts-~ Orsinoslolkestal: OMPOUS 8-i--AW-AsSIO
Of .

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'
0
SUBHITTEDt: 3119
0 1 RIO 8 t

UB,- CODEt,-
0.~ RAF,_ OTIIII R l
SOV j, 00 a
0 6
0 a4

r

I. Z~;
cot"

KF)l 3 , V. _V. ; SOS III, S. L.
--,,
S5-nthesis of polymers from 1,2-ditolylethane and p-diisopro-
pylbenzene. Vysokom. soed. i no.2:232-238 F 165.
(MIRA 18:3)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.

ACC NR: AP6Oi5615 SOURCE CODEt UR/0020/66/168/002/0357/0359
AUTHORt Sosin, S. L.; Chikishevp Yu. G.
Offirt Institute of Organometallic Compounds.AcaderW of Sciencesq SSSR (Ihstitut 010-
mentoorganicheskikh soyedineniy Akademii nauk SSSR)
phanyleyelosilanes
TITLES Synthesis and study of polymers frorij
SOURCEt AN SSSR. Dokladyp v. 168, noi 2, 1966, 357-359
TOPIC TAGS1 radiation polymerization, organosilicon compoundl polymer,"dogradations
silane
ABSTRACD In a synthesis of the high molecular polydiphenylsilYlone ((C6H5)2si)nt
which had not yet been described, the monomers used were four- and five-membered cy-
closilanes obtained from diphanylchlorosilane by reaction with sodium or lithium in
tetrahydrofuran. The cyclosilanes w9re octaphenyloyclotetrasilane (A), decaphenyl-
cyclopentasilaii-3 (B)j, and an amorphous vitreous modification of octapheryleyelotetra-I
silane (C). Polymers of substantial molecular weights were obtained by irradiating I
melts of these monomers with fast 1 MeV electrons in evacuated ampoules* AsAndicate4
by IR spectra, the polymer formation is apparently due to the opening of rings of the
initial compounds under the influence of irradiation, follorwed by the formation of
polydiphenylsilylene. Judging from the molecular 'weights, the number of silicon atoms,
UDCS 2333

SOSIN, V.V., mayor moditsinskoy sluzhby
Clinical manifestations of pressure injuries of the lungs. Voen.-
med.zhur. no.8:46-48 Ag 159. (MIRA 12:12)
(LUNG DISFASES)
(I)ECO)eRISSION SIMESS)

MKSIMOV., A.V.t kapitan meditsinskoy sluzhbp SOSIN, V.V., mayor meditsin-
okoy sluzhby
Provision of submarines with sterile surgical linen and material
during cruises without contaot with shore bases. Voen.-med. zhur.
no.3:38-39 Mr 160. (MIRA 14: 1)
(SU34ARIM MEDICINE)
(SURGICAL INSTRUMENTS AND APPARATUS)

SOSIN, V.V., mayor med. sluzhby
Special training of physicians and instructiors - chemist -
sanitary personnel of submarines. Vben.--md.zhur. no,10:76-
78 0 f61. (MIRA 15:5)
(SUMYMNE MEDICINE)
41~

-Zult-"fe. le.
Dlst)ortatiom "Aii Nvostigation of the Efficiency of High-Spead Machining of Metals an
Universal Lathes." Cand Tech Sci, Moscow Engineering Economics Inst imeni Sergo Ordzho-
nikidze, IS Jun 54. (Vachernyaya Moskval Moscow, 9 Jun 54)
SO: SMI 318, 23 Dee 1954

I , -
~Z:5 / it --y I I i. i-I
SOSIN, Ye.Ye., kand.tekhn.nauk
Wear of cutting tools caused by cutting conditions. Trudy MIZI
no.7:36-46 157. (MIRA 10:12)
(Cutting tools) (Mechanical wear)

LIVOIT, Dmitriy Semenovich- SOSIN Yeremey Yefimovich THUS S.A., kand.
tekhn. nauk, retsenzent; RUZIN, V.A., inzh., retsenzent; SALYAN-
SKIY, A.A., red. izd-va; DOBRITSYNA, R.I., tekhn. red.
[Technological fundamentals and economic calculations of the mechani-
zation and automation of small-lot manufacture of machinery) Tekbnolo-
gicheskie osnovy i ekonordcheskie raschety mekhanizatsii i avtomatiza-
tsii melkoseriinogo mashinostroeniia. Moskva, Gos.nauchno-tekhn.izd-
vo mashinostroit.lit-r-y, 1961. 21+6 p. (MIRA 14:11)
(Automation) (Industrial management)

7

144

z
-
'
-
min mot-ts'-
V Photocolon
metric deterad"flotC
a, a
Ute ~A
~-
n in c
f td
r Awifid
d otli
i
i
t
1411
Sg!
n
e
i
m
ryo
a
6
rq-
Ow
ng
s 0
O
solin
N
nst.
4
o
y
g
_Chem- G 11,-
aw) 19, atIO,--
w
e
, N
13(1957)(English and Russian summanes).-~~A phot4kolort-
*
'
metric method is given for detk.
sm"A
arnts. of St (frouz 0.02
6u&as,N&r
to 1 0% Siol) in fluorides slightly Sol. In HIO,
C
A. 50,8383i; -
-
_
i
-
ji, -W-
d Craig, CA.' 48~40M'I- -Bra
S. an
liso
4i j C T: 42;~~
5707e - Shell C.A
'
The uorlde-
il by ~ ton, In an alk.
"Oies-can-be
oissolied fus
.
mcdium~ For AlV,j'freshlj,pptd.'-ordrIe&&t
n
fusion may be replaced by dissolving the issdaple i
-
*
pptd. or dzied iLt- 200
e of 'NH4F- Oi:NaF- CaPs
pr=
is Ived W IIN% without adding NE4P be N&F. - T
AIF3~ only alk. fasion*. possible.--- This fnetlzod Is simplifi.
'

Iiaeifid
exact~thau vimetric.ones.-
and more The dni~
VM
to dissolve samples in HNO~ was about 30 suln
the time of fusion was 14to 2,0 hro.7 -The,
'
-
-
'
tolling pro.~
mat
In
Ued
2 to 12%. The raethodc0a
bc
App

b . ..... ....

-- SOSTH) -- Z.I; ZAREMB-1, J.; ALCUSTYU, W.
Analysis of fluorine compounds. p. 871.
CHEMIA ANALITYCZNA. (Komisja Analityczma Polskiej Akademii Nauk i Naczelna
Organizacja Techniczna) Vlarszawa3 Poland, Vol. 3Y No- 5/6, 1958
Montay List of East European Accessions (BFAI) LC,, Vol. 8, No. 8, August 1959
UNCL.

SOSIN, Z.; ZARIWA, J.
Methods of analyzing potassium salts. p. 883.
CHEMIA ANALITYCZNA. (Komisja Analityczma Polskiej Akademii Nauk J Naczelna
Organizacja Techniczna) Warszawa, Poland. Vol. 3, No- 516, 1958
Monthly List of East European Accessions (EEAI) LC, Vol. 8,, No. 8,, August 1959
UNCL.

05//V
0

Determination of calclum, hyrosence of magnesium and
atninonluin salts by jh-eihs o versehaW(BDTA).
Nlearga
q Zaklad Anal. Inst. Chcmll iqW.-GlIWICC.
L
'
'Chint
A nal. 3
1013-IS(IM ZlInglish sum-
Oi
.
.
,
Friary).-Make alk. with KOH a sample contg. Ca and boil
for 10-15 min. Acidify the solo. with HCl, cool, neutralize
with 4 ml. 4N KOJI for each 50 ml. of solm, and titrate with
'
versen ate in presence of tnurexide.
the method was proved
by detg. Ca and Mg In siderites. The results were repro-
thicible and in agreement with those obtained by the gmvi-
f
i
Ca w
metric method. Dem. o
thout removal of N
1
salts: to a soln. contg. Ca and Ift add 4N KOH to pH 1-
.
then add 2 mt. in excess and titrate the soln' with versenate.
-
The method was proved by detg. Ca and
iig in standard

con tg. vrariable anits. of NH4Ct and in minerals
0.05M sollis
f8 standard solos. were prcpd, contg. Ca. Mg. Fe, and At
in ratios approaching those in siderites and clays, namely j
CaO 2-W. NIgO 2.5-10, Fej0j 14-57, and Alt0s Z-15%).'
Z.

,
dT&
2 A", 4'r
7
t ~

CHETKOWSKAJ, Maria; SOSIN, ZoLi ~-,STRZESZEWSKA, Ir
Complexometric determination of zinc in analytical control of zinc
compounds. Application of complexometric methods for zino ash analysis.
Determination of lead, iron aluminum and zinc. Chem anal 6 no-3:309-
316 161.
1. Analytical Department, Institute of Inorganic Chemistry, G2iwice.

CHETKOWSKA, Maria; SOSIN, Zofia; STRZESZLWKA, Irena
Simultaneous determination of zinc and magnesium by complexometric
titration. Chem anal 6 no.3:317-322 161.
1. Analytical Department, Institute of Inorganic Chemistr7, Gliwice.

sosilih, A.M. lumd.med.nauk
i
~.,
Clinical and radiographic data on kyPerplasia of the thyrms
gland. Zdrav.Belor- 5 no.7:14-15 JI '59. (MIRA 12:9)
1. Iz Instituta okhrany materinstva i detstva BSSR (direktor
A.L.Rapoport, nauchnyy rakovoditell - prof. G.L.Dozortseva).
(THMS GLAND7-DISFASES)

SOSINA, A.M.; LAZTUX, I.I.
Itcomplete osteogenesis. Z.drav. Belor. 6 no.3r59-60 Nr 160.
(MIRA 13:5)
1. Iz Belorueskogo nauchno-iseledovatellskogo instituta okhrany
materinetva i detstva.
(OSTEOPSATHYROSIS) (PJWMNIA)

PAM$ A.I.; SIILYBLK, M.I.; LOSIILAI__A,11-
Subcutaneous emphysema in pneumonia. 7drav. Bel. 9 no.l:
86 J163. (14IRA 16o8)
(EMPHYSEMA, PUUIONARY) (MUMONIA)

SOSIIqA, Docent B. M.
Sosina, Docent B. M. and 3. M. Mayzel' "X-Ray Treatment of Xenapause,' Akasuer. i
Ginekol., No. 3, 1949. Xbr., Belorussian Sci. Res. Inst. Physical Methods Treatment,
-clg4g-. Mbr., X-Ray Dept., Ed., .3rd Clinical Hosp., -c1949-.

!30SINA, D. Z.1.
IIX-Ray TreatmFnt of 'Venopeause" Akusher. i Ginekol., No. 3, 1949. Belorussian
Sci. Res. Inst. of P':Iysical Methods of Treatment~ -rl949-. 11-r., X-Ray Dept.
3d Clinical flosp., -c1949.-

SCSINA. B.M.
Motor evacuation of the humian stomach from the viewpoint of
Pavlovian theory; roentgenologic investigation. Klin. med.,
Koskva 29 no.9:64-70 Sept 1951. (CLKL 21:2)
1. Doctor Medical Sciences. 2. Of the Roentgenological Division
(Scientific Supervisor -- B. M. Sosina), Third Glinical Hospital
and of the laboratory of General Physiology (Read -- Prof. A. A.
Znbiov), Institute of Theoretical Medicine-of the Academy of-Sbiencee
Belorussian SSA.

SOSINA, B.M., professor (Minsk))
__a~
Roentgenodiagaosin of benign tumors of the esophagus. Klin.med. 34
no.3:54-56 Mr 156* (MLRA 10:1)
1. It kafedry rentganologii (zav. - prof. B.N.Sosina) Belornsakogo
institute usovershoustvoyantya vrachey (dir. - prof. M.N.Zhukova)
(EBOPHAGUS. neoplasms,
diag., x-ray of benign tumors (Run))

over
,he P, EXCERPTA MEDICA SeC 9/vol 13/5 SURGMY MaY 59 an
halv( .9)
25113. '011-l' 1111013LrM 0V HOENTCEN DIAGNOSIS OF 13RONCIIIAL CYSTS
(Hu3sian text) - Soo ina 0. M,-, Soafna A. M. and Volodko M. F.
ZDRAVOOKHR. BELOR. 1957. 4 (42-47)
It is admissible to designate as pulmonary cyst any thin-walled cavity filled with
air. fluid or both simultaneously. Uncomplicated bronchial cysts do not present a
well defined clinical picture. Roentgenological findings depend on the patency of
the bronchus. The clinico- roentgenological manifestations associated with com-
plicated bronchial cysts depend on the character of the complications. In order to
prevent the occurrence of severe complications bronchial cysts should be removed
Dy operation, '(S)

J
SOSIRA, B.M., prof
Development of roentgenolog7 and radiology in White Russia under the
Soviet regime. Vest.rent. i rad. 32 no.5:9-13 S-0 '57- (MIRA 11:2)
(RADIOLOGY
in Byelorussia (Rus))

CHL'MSOVA, ]~.S.; SOSIa. B.M..,R]IMPMUR, Y.G.
Metabolism of labile phosphorus compounds in brain tissue in connection
with radiation sickness. Dokl. AN 3SSR 3 no.1:26-2� -Ta '59.
(MIRA 12:3)
l.Predstavlons akeAemikom AN BSSR T.N. Godnovym.
(PHOSPHORCS) (BRAIN) (RADIATIOif SICKHRSS)

SOSIN&, B.M., prof.; PROKHOROVA, Te.P.
Clinical and radiological diagnosis of an --ortic arch located on
the right side. Zdrav. Belor. 5 no.1:6u JEL 159. (KIRA 12:7)
1. Iz kafedry rpntgenologii Belorusskogo instituta usavershenstvovanlyn
vrachey na baze oblastnoy bollnitsy (glavnyy vrach G.i. TSgoyev) i
ResTniblikanskoy bolinitsy lechsampravleniya (glavrjyy vrach V.I.
Khimnkova).
(AORTA--ABITORMITIES 1 ~-,,D DEFOMAITUS)

SOSINAO B.M., prof.; GORUICHIK, K.I.
of hernias of the esophageal hi~Ltus of the diaphragm.
7-drav. Bel. 7 no.30-14 Mr '6i,L.- (MIRA 14:3)
1. Iz kafedry rentgonologii - radi4logii (zaveduyushchiy - prof.
B.M.Sosina) Beloruiskogo inatituta usavershonstvovaniya:vrachey
(direktor - dobpent N.Ye.SoLvchenko).
(U.RM)

SOSIVA, B.M., professor; REZIM, A.Ya., dotsent
Causes for a late diagnosis of palmonary cancer. Mrav.Bel.
no.3:20-25 162. (MM111 15:5)
1. Iz kafedry rentgenologii (zaveduyushchiy kafedroy - professor
B.M. Sosina) i kafedry terapii (zaveduyushchiy kafedroy - profesoor
A.D. Adenskiy) Beloru;skogo instituta.
(LUNGS-CANCER)

SOSI-NA) M._ T.; YELTISEILVA,-V. K.
Geology, Strati-graphic - Permian; Paleontology - Permian
New data on the upper Permian period of the*Sikhote Alin chain. Dokl. AN SSSR
82 no. 6, 1952. Vsesoyuznyy Nauchno-Issledovatellskiy Geologicheskiy Institut
rcd. 27 July 1951
Monthly A-.tst of "ussian Accessions, Library of Congress, July 1952. UNCLASSIFIED.

SIMINA, K.I.; POLYAKOVA, A.A.; SOSINA, H.S.
--Q I ~- - - ~;~ - ~--
Analysis of hydrocarbon systems from their mass spectra. Zhur.
neorg.khim.1 no.6:1264-1270 Je 156. (MLIA 9:10)
I.Vassoyuznyy nnuchno-issledovatellskiy inatitut neftyanDy
promynhlennosti (VWInW). -
(Hydroonrbons-Spectra)

L ~5~615,65

LIIISHIEYN, R.A., kand.tekhn.nauk; MIKMISON. A.Ya, inzh.j ZTMINA. K.I., kand.
tekhn.nauk; SOSIUA N.S. inzh.
p
Possibility for regenerating oils inhibited by an additive, Elek.
sta. 36 no.110:34-36 0 165, (MRA 18a*110)

M so q 11 it It Ij to 111 11 11 to 41 W III a is 41 to 41 44
11 11 I-W
It & A. 11, 4
A
o.b jtI. ~Vtoj
Awhdww lad" I" too
anatojins. I. G. 1.
00 Rakhmanckik. S-zRuAbfiV,=,' -114#01=1AIj-
00.1 f-Ick. (U. S. S. R.) 1041, No. 1. 19-20(in German. W-7).
ji -Expts.-mme mude to det. whether scids can be used for
Slon :~ I mod conclu. of taxi= and austaxins. to
040 A ZPII*.I=t Litatole acids for this gourpose oW to det.
optimum conditions for purifying the toxins and snattoxins
004
with a max. preservation of their antigenic ProPetties.
of lie). AcOH and CCi.CWH were used. Vnderproduction
SIX oil conditkins IICI produced togothatain results. The optimum 2 see I
purification and I'- doo of antipuic Properties 4e-
:0 Pend on the PH value mW there Is a defirtite PH vabse for
a I!z vach acid. With HCI the optimum PH is 3.8 both for a
puri6cation and for !!=of the antiagnic propff- coo,
prevema
'g, ties for both toxin -ad With CCUCOOH the
W
0 optimum for toxin is PH 3.5 and for anatoxin P"..S. Soo
-a Toxins and WMECIIIIIS were freed hom inactive prvtcinv~tto-
the extent of 95,4% and PI-6% of the antixenic Power .6
S
was preserved. W. R. Ifenn 60
moo
Noe
ts it-L A AFTALLURCKAL LITINATUIRE CLASSIFICATION
410 ONV adc 431131 did Ov $%I
U It AV 00 It I ; I TA 1A I 1 8 ad 0 0 R.I.W a 2 A 0 2 a V
, ; UP
It to it OP K It a Z161, Villa
0
0 0 0 0 a 0 0 0 a 111 0 0 0 0 0 0 0 0 0 0 0 0 0
00 0 0 0 0 0 0 0 0 0 0 0 0 0 0-0 0 a 0 0 0 0 0 a 0 0 *-& * ft,

I Of I Ow I 1 .01 9. ?1 0, nA U, a
I Y Z -AA M
of 7
;WIXI-lits AMC' -0400-1-11.9
00
00
of
*0
60
b
"Ic
00
dZi -..0
P~
Ae
globulin ems L~- tt~l ii~ mi addid. Int.c,lure salu7r the
altitir ~mt, to give An uddlil. W-5% prul~ill telliuval.
G. N1
AALI
mil !:.!I ^S..5L. *ITALLLPRGICAL LITIMIAIUME CLASSIF)CA710M
go,
1. ad.. .11 ORE 41413
T I I I --V
u if 0 is; 11 EV IkIWOOM Kit KU K U It
it= n I
41 0 0 0 e 0 0 0
Z.
.1111
;W A f a w a -1 .1 w Im 0 Al a 3 a r
10*
'00
see
Oro 0
t:se
to*
0 0 a
466 0-0-0 ww ;w
31 32 $3 U 35 It V It X 1; 11 4 -1 A- 43
t-L - I A k -.T f. 0--t- -L'
lee
I**,

SOBINA. S.M.-.CHAIMKA. D.K.; LYSUKHA, L.K.;KRASOUSKAYA, A.A.
. q .
Local cold-resistant vmria"'ee ofyeasts for making fruit and berry
wine in White Russia. Vestsi AN BSSR Ser.biial.nav.no.2:101-113
156r, (KIRA 10:1)
(White Russia--Yeast) (Fruit wines)

USSR/Chemical Technology Chemical Products and Their 1-12
Application. Fermentation Industry.
Abs Jour : Ref Zhiz-, - Xhimiya, No 1, 19,58, 2830
Author : Sosina, S.M., Lysukho, L.N.m Krasovskaya, A.A.
Inst : Belorussian Scientific Research Institute of the Food
Indus-try.
Title : Preparation of Fungus Malt on a Barley Medium for the
Brewing Industry.
Orig Pub : Tr. Belorussk. n.-i. in-ta pishch. prom-sti, 1957, No 1,
67-73
Abstract : The production technology has been worked out for a fungus
malt with the use of barley: crushed barley is stirred
with an equal volume of water, and sterilized in an auto-
clave at a pressure of 1 atmosphere for I hour. The steri-
le slurry is mixed with a well sporulated culture of
Card 1/3
was 11)rTT__1 =7~_
ation from Aspergd1lus ovyzae
lei, of en,,:,Tbatic prepar e finist-ned beer Fe-vealed
strain P~1, De3ustation of th-
j
'USSR/Chemical ~~echnolo a. - Chemical Products and Their 1-12
Application. FermentatLon Industry.
Abs Jour Ref Zhur - Khimiya-, IN) 1, 1958, 2830
that. the beer prepared iirith the enzymatic preparation
Lroduced with a barley medium, has better 6astatory
~'_naracterlstics; being free from extraneous bitterness
s,nd oJ" milder flavor. It, is noted that both specirlierls
of beer shov poor frothing and lo,,r froth stability,

SOSINA, S.M.
W-
...... -11', ~ .
Growing mold fungi on waste mterials from starch manufacture.
Spirt. prom. 24 no.1:11-13 '58. (MIRA 11:3)
(Aepergillus oryzae)

SOSINA, S.M.
Method for a comparative determination of the assimilability of
proteins in canned vegetables. KonsA ov.prom. 15 no.8:38-39 Ag
16o. (MI-RA 13:8)
1. Belorrusk-i7 nauchno-iosledovateliskiy institut pishchevoy promy-
shlennoeti.
(Food, Canned) Mrothins)

SOSINA) S.M.; ?ASHYOVSKAYA, M.T.,- Prinimall uchastiyet SUPRA11OVICH, V.A.,
mladshiy nauch. so-,.rudnik; NOVIK, V.G,, mladfkiy nauch. sotrudnik;
TSYGla,AQVA,, R.I., tekhnik-tekhnolog -
Methods for the disinfectibn of mclasses for the production of baker's
yeaut. Trudy BNIlPPT no-41113-126 161. (MIRA 172.10)
I

SOSINAY S.M.
Campar'Lson method for determining the digestibility of proteins in
canned vegetables. Trudy BNIIPFT no.4:127-128 161. (MIRA 17:10)

V. V.; T. N.
i-111--,:~~Tlc)f'-~,:o,.~o-)"-.o~~;-)"-,.,-)~-il..-; Co.-Cm"Dund Alkylamiides of
~ci7-i*!-Lio,,,oorz;;io,-),-.oo-),-ii-n~-c acids
r. 36, n-o
o27z~iic cc,;;~:Dound, orran-Lc nhosp.'-..o--=
f "r.; ",-Oro- are 6 lly
des 0 di
Y~u
On Or 0 - Z~
sulb~;-~z-,nccz th,a~~ bond hydro,~-Or,
fluoride or Good yiolds of the f_nal productw5 -,.are
"iccep'C'Or. Re-ardloss
o--' oricinal rori~ma-. only -,onoamLides -,.ere formed; di
Y L
.=.d t-l:,.3T.,a, 6cs CZ~U." 00 Isolated. Sever, sy-nthrisized and c*,-.a-.ac-
L,~d T *,-, 3aliv-Lami-ide of acid added bromLine
c.z, ~,no doublo bond, tuln.o 2,3-dilbromaopropylamnido of nothylturifluoro-
al.4-
haL;: 1 t able .
lJP2,5: 38,9701
.--UD.C: 547.2"!_

905INA, Ye. I.
V- -acteristics and Regional Dis4,.ri-
SOSINA, Ye. I. -- "Agrobiological Cha"
10
bution of Types of Grapes in Kirgizia.'? Min Higher Educetion USSR.
Kazakh State Agricultural Inst. Frunze, 1955. (Dissertation for the
Degree of Candidate of AgriculLural Sciences.)
SO: Knlzhnava letoots', No. 4, Moscow, 1956