SCIENTIFIC ABSTRACT SKOROKHODOV, B.P. - SKOROKHODOV, S.S.

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• Document Creation Date: November 2, 2016
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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

A. N. TAIEN(P'SKly,
SFC),ROKHODO!fp
-hr, Of C-OmPlex
co, +
.1tan -.,n--sses 12--116 '65.
-1. v- - I chern. met.
9 ilx~ "1 7, ys.ucheb.zav.; (MIRA 18--4)d
!. Ural'31:iy polite-khrii2lieskiy institut.

SKOROKHODOV R ; - - _,._ -
Rotary (vans) Yents. Vod. i san. t9kh. no.3:37 Mr 157.
(United States--Water pipes) OCRA 10!6)

SKOROKHODOV, B.
~ --,
Some problems of depreciation and general overhaul of
communal enterprises. Zhil.-kom.khoz. 6 no-8:7-8 '56.
(MLEA 10:2)
(Civil engineering--Batimates and costs)

SKMORHODOV, B.
Magnetic water motor. Zhil.-kom.khoz. 7 no.4:29 '57- (NM 10:7)
(United States--Witter meters)

- SKOROKHODOV, B.P. __ -
FWWWWFIF~
Norms of amortization of public bgths. Gor.khoz.Kosk. 31
no.6.,28-30 Je '57. (M1RA 10:7)
(Amortization) (Moscow--Baths, Public)

SKOROKHODOVI B.F. __-- - ~
Living conditions Of the workers. Gor.khozJbsk. 36 no.lj48-50
A 162. (MM 16:1)
(New fork (City)-Housing)

I,IY,I;(.I,AY, Georgiyevich; ~TAOROKEODOV,- Grigorly !Fedorovich;
DO.,"D11"PKINI, N., red.
[TDward the gonlo of albundancel K -420bl2iia. '.'Olgo-
grad, Volgogradz*oe krizhrioe lzd-vo, 1c)63. 38 p.
(KIRA 2813)

MORDVINTSEVAY AN, kand.takhn.nauk; OLISHANSKIY, N.A., kand.teklin.nauk;
Prinimal, uchastiye: SKOROKHODOV, L.N.,, inzh.
Welding plastics. Izv, vys. ucheb. zav.; mashinostr. no. 3:96-108
!61. (14M 14: 5)
1. Moskovskoye vysshe~s tekhnicheskoye uchilishche imeni Baumana,
(Plastics-Welding)

NEKRASOV, L.I.; SKGROKHODOV, I.I.
The question of existence of higher hydrogen perosides; critical
review of literature. Part 1. Vest.Mosk.un. ~er.mat.,mekh.,
antron.,fiz.,khim.11 no.1:213-219 156. (MIRA 10:12)
1. Xafedra fizicheskoy khimii Moskovskogo univerBitata.
(Hydrogen peroxide)

NNKRASOV. L.I.; SKCROKHODOV. I.I.
1xistence of a higher peroxide hydrogen. Zhur.fis.khim.30 no-5:1189-
1190 My 156. (mm 9:9)
I.Moskovskiy gosudarstv~nW univeraltet imani M.Lamanoseva.
(Hydrogen peroxido)

S-KOROKHODOV
, 1. 1. Ond NMASOVY L) I,
"Concerning the problem in Regard to the Existence of a
Higher Peroxide of Hydrogen -- Part l," by L. i. Nekrasov
and 1. 1. Skorokhodov, Chair of Physical Chemistry, Mos-
cow State University., Vestnik Moskovskogo Universiteta,
Vol 11, No 1, Jan eb 57, pp 213-219
After reviewing USSR and foreign work on the synthesis Of H204 and
results obtained in the investigation of products obtained in attempts
to synthesize higher peroxides of hydrogen, the authors subject to crit-
ical discussion data on the physical and chemical properties of the glass-
like product obtained in the low-temperature condensation of dissociated
water vapor or dissociated H202, as well as in the interaction of atomic
hydrogen with oxygen. They arrive at the following conclusions:
1. When water vapor or hydrogen peroxide vapor has been dissociated
by means of an electric discharge and the product of the dissociation has
been condensed on a cold surface (at a temperature of approximately minus
1800), the radical H02 is formed, which may either be stabilized by freez-
ing or undergo association, forming the hydrogen superoxide H204- In ad-
dition to that, H20 and H20 are formed on the cold surface. The glass-
like product consil Of H2C , H202, and H20-

2. When the temperature Is raised. the glass-like product undergoes
a number of transformations. After being originally in an amorphous state,
it crystallizes at minus 1150 and begins to decompose. At the temperature
of minus 6101 when the rate of decomposition reaches a maximum, the product
melts, becomes poorer in hydrogen superoxide because of the continuous de-
composition of this substance, and-is transformed into a solution of hydro-
gen peroxide in water.
3. The decomposition of the glass-like product, which begins at minus
1150, is due to the reaction
H204 H202 + 02
4. To confirm these conclusions and establish beyond doubt the exist-
ence of the radical HHO~ and Of H204, more thorough investigations will be
necessary.

KOBOZEV, N.I.; SKORO)MODOV, I.I.; NEXR.ASOV, L.I., MAKAROVA, Ye.l.
Phyaical-M=istry of concentrated ozone. Part 2: A study of
the synthesis of the highest peroxide of hydrogen H204 by the
reaction between concentrated ozone with atomic hydrogen [with
summary in English]. Zhur.fiz.khim.31 no.8:1843-1850 Ag 157.
(MIRA 10:12)
1. Mookovskiy gosudarstvennyy universitet im. M.V.Lomonosavn.
(Peroxides) (Hydrogen) (Ozone)

61
AUTHORS: Reznitskiy, L. A., Khomyakov, K. G., 76-1-1V32
Hekrasov, L. I., S)(orokhodov, 1. 1.
TI-111LE: Conc erning the Higher Peroxide of hydrocen, and Frozen Radicals
I. Determination of the Deconposition Temperature of tile
Classy Substances Produced in the Electric DischarL:e From
,'tater Vapour (K voprosu o vysshey vodoroda i
zamorozhennykh radikalov. I. Opredeleniye teploty
razlozheniya steklovidnogo veshchestva, poluchen-noLo iz
parov vody v elektricheskom razryade~
PERIODICAL: Zhurnal Fizicheskoy Khimii, 1958, Vol. 7~2, Nr 1, PP- 87-92
(USSR)
ABSTRACT: The results of the calorimetric determination of heat effects
are given, which ac~3ompany the deCOMPOSiLion of the glassy
substance (obtained from dissociated steam with an electric
discharge). The method of continuous heating on adiabatic
conditions was used. This method makes possible the
determination of heat effects in a relatively quick and
realiable manner. 9 construction of the calorimet-ric in-
ve5tigation of the interaction at low temperature of vapour
dissociated in an electric discharEe vuas worked out. Three
Card 1/4 heat effects were determined thich accompany the heatinC;

76-1-13/32
ConcerninC the Higher Perodixe of Hydroi-er and Frozen Padicals
1. Determination of the Dec3mpo Sit4 on T
emperature of the
Glassy Substances Produced in the Electric Discharge From
Water Vapour
process of the Elassy substance. The authors show that at
-1150C the first exothermic effect begins and that it is
accompanied by a separation of 02'At - 700C the 61assy
substance begins t'-,,;, melt. This goes ~;-n till -55 OC. At this
temperature the endothermic process pa3oes over to an
exothermio Dne. This is accompanied by a turbulent separation.
of 02* It reaches its maximum in a liquid phase at -1r3OC.
This exothermic effect takes place in the meltinE. range of the
eutectic of the H20-H,02 system. in order to take this effect
into account the heat of fusion of the eutectic was determined.
It was 74,5 cal,1g. When determining the real value of the
second exothermic -effect this auantity was taken into account.
The authors stated that wita the first effect, which began
at -1150C and which was accompanied by a separation of Cas
a heat of 78,6 k3al/Mol 0 wa5 separated. The endothermic
2
effect which is connected with the melting of the substance and
Card 2/4 which beLins at -70' is also accompanied by a separation of

76-1--13/32
Concerning the Hieher Perodixe of Hydral---er 9.--d Frozen Pad-4calp,
I. Determination of the Deccmpos~4'-ion Te,7.D~ratu--~~ of the
Classy Substances Produced in the Electriz Dischart-,e From
Water Vapour
j,as. With this effect 100 cal/L if202 ,.,ere recorded. The quantity
of the oecond exothormic effect was 68,0 kcal/fi"ol Of C, 2'
It is accompaniod by a docompo.91tion of if204* The data
?Jven huro Prove till) proce-Do of thu docOmponition of glkway
substances suggested earlier by one of the authora
(Nekrasov) (ref. 6). The endothermic effect stated with this
decomposition has not yet been clearly explained. According
to the opinion of the authors this effect had to be
attributed to a change of the stiate of aLgregation with
Classy substances, which would coincide with the explications
in ref. 11.
The authors were advised by Professor N. I. Kobozev.
There are 2 fipires, 2 tables, and 12 references, 2 of which
are Slavic.
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Concerning the HiCher Perodixe of Hydro,-,3n and Ft-)zen Fad-4cz-15
I. Determination of the Decomposition Temperature of the
Classy Substances Produced in the Electrio Di3charee From,
Water Vapour
76-1-13/32
inien4 71. V. Lomonn-iov
ASSOCIATION: Moscow State Un4%,ej-r-ty
(Iloskovskiy univez-site-t, im. M. V. Lomonosova)
SUBMITTED: Oct.olber 3: '1956
AVAILA3LE: Library of Con---ress
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srommCoov, t. f.: Master Chem S~:i (diss) -- "TrIVest,'vation of m-thods of
pr-aparation and the physi-cochemical properties of roz-,2n peroxide radicals
sYstems (1109--11204-11202-H20)". Moscow,, 1959. 12 pp (Moscour State U im M. V.
Lomonosov), 110 copies (M,, No 12, 1959, 126)

33691
S/076/62/036/002/002/009
B119/B101
Ifekrasov, L. I., Kobozev, if. I., and
~v ~~' I
Yevdokimov, V. B. (Moscow)
TITLE: Problem of higher peroxides of hydrogen and frozen radicals.
VI. Investigation of the magnetic properties of peroxide
radical condensates
PERIODICAL: Zhurnal fizicheskoy khimii, v. 36, no. 2, 1962, 274 - 281
TEXT: The authors studied the magnetic properties of peroxide radical
condensates synthesized both from dissociated water vapors and from
the reaction of atomic hydrogen with liquid 100~- ozone by methods
already described (Zh. fiz. khimii, 31, 1843, 1957; ibid., 12, 87, 1958).
The magnetic susceptibility was determined by the method of comparison
with water as gauge substance (measurement of weight increase in the
magnetic field) between -150 and +200C. Below -1100C, peroxide radical
condensates are weakly diamagnetic; their susceptibility is -0.1 - -0.2-10
cgsm. The paramagnetism of the system increases with the temperature
owing to free oxygen (neither adsorbed nor occluded) forming from
Card0

MAL'TSEV, Yu.A.; SKOROKHODOV, I.I.; NEKRASOV, L.I.
Hydrogen superoxide and frozen radicals. Part 7. Zhur. fiz.
khim. 37 no.12:2740-2745 D 163. (MIRA 17:1)
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova.

ACCESSION NR: AT4028330
S/0000/63/000/000/0041/0045
ADTHOR: Xobozev, N. I.; Nekrasov, L. I.; Skorokhodov, 1. 1.
TITLE; Mechanism of low temperature formation of hydrogen peroxide
SOURCE: Saveshchaniye po khimii perekisnyfth soyedineniy. Second, Moscow, 1961..
Xhimiya perekisny"kh soyedineniy (chemistry of peroxide compounds); Doklady*
soveshchaniy. Moscow, lzd-vo AN SSSR, 1963, 41-45
TOPIC TAGS: hydrogen peroxide, low temperature formation, nascent hydrogen, ozone,-
oxygen, hydrogen, hydroxyl radical, water
ABSTUCT: This paper proposes a scheme for low temperature reactions of atomic
hydrogen with oxygen. The authors explain the research of interaction of nascent
hydrogen with oxygen at low temperatures with the formation of hydrogen peroxide
and water as a final product. The paper claims that, in addition to water and
hydrogen peroxide, the primary products also contain free frozen HO 2 radicals and
0, compound, the higher peroxide of hydrogen. The concentration of 110 radicals
~2 4 2 .
in condensates is small and in the best cases attains only 0.4 wt--d,.. The H02 and
R204 radicals can be maintained only at temperatures of less than -1200C. At higher
temperatures the latter break down into hydrogen peroxide and oxygin. If hydrogen
Card 1/2

ACCESSION NR: AT4028330
peroxide is formed in the heterogeneous mechanism through the HO2radical, then the
formation of water occurs basically in the gaseous phase or through OR radicals or
oxygen atoms. The proposed scheme reflects the basic outlines of the process of
hydrogen peroxide formation at-Jow temperatures.
ASSOCIATION: Moskovskiy gosudarstvenny*y universitet im. M. V. Lomonosova (Moscow
State University)
SURIKETTED: 13Dec63 DATE ACQ: 06Apr64 ENCL: 00
SUB CODE: CH
NO REF SOV: 009
Card
OTHER 017

5( ") SOV/76-53-9-321/37
AUTHORS: Skorokhodov, 1. 1., Nekrasov, L. I., Pezni-k`y, L. .1, Khe)=,Ya-
v , N - I
TITLE;: On the Problem of the Higher Hydrogen Peroxide and Frozen
0
Radicals . II. Some Notes on the Thermochemistry of the Higher
Peroxide H204 and the Radical HO 2
PERIODICAL: Zhurnal fizicheskoy khimii, 1959, Vol 33, Nr 9,
pp 2ogo-2095 (USSR)
ABSTRACT: In a previous paper (Ref 1), calorimetric investigations were
described which dealt with the decomposition of the solid
condensate (C) obtained by freezing out (at -1960) the steam
dissociated in an electric dischar-e (as a so-called vitreous
substance). The two-stage decomapposition took place with two
exothermic reactions: HO 2+EO2 -:~ H202(solid )+02 (1) and
H204(liquid) ---> H202(liouid)+02 (2). Detailed checking of the
decomposition of (C) (obtained as mentioned above/as well as
by a reaction of atomic hydrogen with liquid ozone) indicated
that the resultant data need some correction. Visual observa-
Card 1/4 tions and data obtained by the thermographic method (which

On the Problem of the Hi7her -'ydro-,en Peroxide and Frozen SOV/76-33-9-32/37
Radicals. II. So::-e Notes on the Thermochemistry of the Higher Peroxide
H204 and the Radical HO2
will be presented in a separate article) showed that on the
decomposition of (C) the solid phase vanishes at -70 to -600,
the melting being an endothermic process. Livingstone, Ghorm-
ley, Zeldes (Ref 8), and A. I. Gorbanev, S. D. Kaytmazov,
A. M.Prokhorov, and A. B. Tsentsiper (Ref 9) found that the
concentration of the free HO 2-radicals frozen in the (C) amounts
to 0.3 per cent by weight only. Hence, it results from (1)
that the portion of hydrorren represents only 4,o of the total
amount of the forned hydrogen, and the first exothermic effect
is to be ascribed to the thermal effects of reactions (1) and
(2) as well as to the crystallization heat of the amorphous
portion of the condensate. The authors analyzed experimental
data on the first thermal effect (Table); the crystallization
fteat of the amorphous (C)-portion amounted to
,!~,H = -2.6 kcal/Mol H2021 which is near the melting point of
H202' It is therefore assumed that the devitrification of M
is directly connected with the presence of H O,,Anthe condensate.
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On the Problem of the higher Hydrogen Peroxide and Frozen SOV/76-33-9-32/37
Radicals. II. Some Notes on the Thermochemistry of the Higher Peroxide H 20 4
and the Radical HO 2
The value A H= -39 kcal/mol was obtained for the thermal effect
of H 2 04-decomposition in the liquid phase of 0 2 and H202' Here-
from the authors calculated the formation heat for H 204 (from
the components) and the re-formation heat of the HO 2-radicals
into H 204* The respective values are A H= -6kcal/mol and
&H= -15 kcal/mol H 204' They are in good agreement with other
thermochemical data. The structure H-0-0-0-0-H suggested by A. N.
Bakh (Ref 15) is the most suitable for the data obtained. Cal-
culation of the bond energy shows that the energy of the mean
0-0 bond is found within the range 11-43 kcal if the other bonds
are contained in the H 202 molecules according to the corresponding
bonds. There are 1 table and 17 references, 8 of which are
Soviet.
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On the Problem of the Higher Hydrogen Peroxide and Frozen SOV/76-33-9-32/37
Radicals. II. Some Notes on the Thermochemistry of the Higher Peroxide H204
and the Radical HO2
ASSOCIATION:Gosudarstvennyy universitet im. M. V. Lomonosovs, Moskva (Moscow
State University imeni M. V. Lomonosov)
SUBMITTED: March 28, 1958
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S/189/60/000/004/006/006
B002/BO60
AUTHOR: Skorokhodov, I. I.
TITLE: Lomonosov Lectures at the Department of Chemistry
PERIODICAL: Vestnik Moskovskogo universiteta.. Seriya 2, khimiya, 1960,
No. 4, pp. 77 - 78
TEXTi The scientific conference I'Lomonosovskiye chteniya" (Lomonosov
Lectures) was held at the Department of Chemistry from April 14 to 15,
1960. The conference, convened on the occasion of the 90th birth
anniversary of V. I. Lenin, the founder of the Soviet Union and of the
Kommunisticheskaya partiya Sovetskogo Soyuza (Communist Party of the
Soviet Union), was opened with a lecture by Professor M. I. Shakhparonov:
'IV. I. Lenin and Natural Science". A. A. Balandin spoke on the subject:
"Ways of Development of Catalytic Ilh-emistry" and gave detailed results
obtained from the stepwise decomposition of hydrocarbons by water vapor
over nickel catalysts in a research conducted jointly with
T. A. Slovookhotova. The lecture by M. A. Prokoflyev and Z. A. Shabarova
dealt with.- "Binding Forms of Nucleic Acids With Amino Acids and
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Lomonosov Lectures at the Department of S/189/60/000/004/006/006
Chemistry B002/Bo6o
Polyacid.-//
Proteins". V. I. Spitsyn reported on "Research Into Inorganic
made jointly with T. Kolli, Ye. A. Torchenkova,' G. N. Pirogova,
V. Ya. Kabanov, and others. V. A. Kargin, P., V. Kozlov, and N. F. Bakayev
reported on "Microscopic Structures of Polymers"., Academician
A. N. Nesmeyanox lectured on "Ferrocene, a New Aromatic System".
V. M. Tatevskiy dealt with "The Theory of Connection Between Properties
and Structure of Molecules".
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S1076161103=100310221023
B1211206
AUTHORS: Nekrasov, L. I., Skorokhodov, I. I., and Kobozev, N. I.
TITLE% The nature of the peroxide-radical condensates (Answer to
P. A. Giguere and D. Chin)
PERIODICAL: Zhurnal fizicheskoy khimii, v. 35, no. 3, 1961, 691-693
TEXT: P. A. Giguere anA D. Chin (Ref. 1: J. Chem. Phys., 31, 1685, 1959)
doubt that a higher hydrogen peroxide H 204 is formed during peroxide-radical
condensation. This assumption is, however, confirmed by various physico-
chemical and analytical methods (thermographic, calorimetric, and magnetic
investigations). Especially by magnetic investigations it is shown that the
peroxide-radical condensate is slightly diamagnetic at temperatures below
and that at temperatures above -1100 C the total magnetic susceptibil-
ity increases along with a simultaneous increase of the paramagnetic pro-
perties. The increase of the total magnetic susceptibility shows that the
liberated oxygen is to be regarded as a decomposition product of the unstable
chemical composition H20 4* The process in question is therefore not a simple
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S/076/61/0-"5/003/022/023 XY
The nature of B121/B2o6
desorption of occluded oxygen. The following chain structure.has been as-
signed to the compound H204:
H 11-1011-10,11,0INIO I/H.
The failure of P. A. Giguere to obtain H204 is explained by the application
of solid ozone instead of liquid one. The decomposition of the compound
H204 at a temperature increase proceeds according to the reaction
H204 --;~ H202+ 02. The mechanism of the reaction of the H atoms with the
liquid ozone film is discussed. The radical H02 formed on the surface of
the liquid ozone according to the reaction 03 (liquid) + H ---> H02 + 0 M
diffuses into the ozone film where the reaction HO 2 + H02 __4 H20 4 (4) takes
place. There are 14 references: 8 Soviet-bloc and 6 non-Soviet-bloc. The
four most recent references to English-language publications read as follows:
P. A. Giguareg D. Chin, J. Chem. Phys., 31, 1685, 1959; R. A. Jones, C. A.
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The nature of
5/076/61/035/003/022/023
B121IB206
Winkler, Canad. J. Chem., 29, 1010, 1951; J. S.. Batzold$ C. Luner, C. L.
Winkler, Cariad. J. Chem., 31, 262, 1953; J. D. Me Kinley, D. Garvin; J. Amer.
Chem. Soc., 77, 5802, 1955,
ASSOCIATIONt Moskovskiy gosudarstverinyy universitet im. M. V. bolnonosuva
(Moscow State University imerd M. V. Lomonosov)
SUBMITTED: September 15, 1960
A/
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22005
S/076/61/035/004/013/018
Iq 11ro B106/B201
AUTHORS: Skorokhodov, I. I., Nekrasov, L. I., Kobozev, N. I.,
and Makarova, Ye. I.
TITLEs Problem of a higher hydrogen peroxide and frozen radicals
PERIODICALt Zhurnal fizicheskoy khimii, v. 35, no- 4, ig6i, 905 - 910
TEXTt III. Kinetics of the decomposition of peroxide radical condensate
formed from dissociated water vapors
By peroxide radical condensates the authors designate the products formed
by freezing out water- and hydrogen peroxide vapors after dissociation in
an electric discharge, and also by the reaction of atomic hydrogen with
oxygen or liquid ozone at very low temperatures. Data available in the
literature-concerning the kinetics of decomposition of these peroxide ra-
dical condensates with temperature rise contradict one another as to im-
portant items (Ref. 6: E. Ohara, J. Chem. Soce Japan, 61P 5699 1940;
Ref. 7: L. I. Nekrasov, Dis. MGU, 1951; Ref. 8: R. A. Jonesq C. A*
Winkler, Canad. J. Chem., 29, 1010, 1951). For this reason, the authors
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22005
S/076/61/035/004/013/018
Problem of a higher hydrogen B106/B201
studied the decomposition kinetics of such condensates, which were pre-
pared in an apparatus described earlier (Ref, 5: Zh. fiz. khimii~ 319
1643t 1957; Ref. 11: Zh. fiz. khimii, 32, 87, 1958). The water vapor
entered the discharge tube at a rate of 1.4 g/hour and a pressure of 0.5
mm Hg. The discharge amperage was 0.2 a, the voltage 1000-1200 v. The
cooling trap was cooled with liquid nitrogen. 0.7-0.8 g were the initial
amounts of condensate in all experiments. The condensate composition was
the same in all experiments; the molar ratio between oxygen generating
from decomposition and remaining hydrogen peroxide was always 0-15, the
concentration of H202 in the final solution was 50 percents by weight.
The decomposition of the condensates was studied in an experimental system
that had been likewise described earlier. The decomposition of the per-
oxide radical condensates with slow heating was found to take place
essentially in two stages with different temperature coefficients and dif-
ferent activation energies. The first noticeable separation of oxygen
takes place between -95 and -700C for about 17% of the total oxygen formed.
The solid condensate starts melting at -70 OC; this process comes to an
end at -600C. In this temperature range, and also on a further heating,
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3/076 6210/W35/004/013/018
Problem of a higher hydrogen ... B106~2201
the second more intensive.stage of decomposition,takes place, at.which
the 0chief oxygen amount escapes. The decomposition is completed at -40 to
-30 C. Between -110 and -1000C a hardly noticeable step appears in the
curve-of gas separation, which characterizes a weak decomposition process
in which about 3~ of the total oxygen is generated. This weak dec*ompo-
sition is accompanied by the disappearange of the yollowish color and.by
a modification of the condensate structure: the condensate becomes
opaque-and-begins to melt in places, An analysis of the kinetic curve,
t-ken.under isothermal conditions, showed the two-stage decomposition
reaction in the temperature range -95 to -40 0C to be a reaction of first.
order. The activa+ion energy amounts to.1.2-1.4 kcal for the first stage
of decomposition (with condensate in the solid state), but 8.0-9.0 kcal
for the second stage of decomposition. The results substantiate the ear-
lier assumption of the higher hydrogen peroxide H 204 being contained in
the condensate* The authors reach the conclusion that the assumption put
forth by E. Ohara some tiie ago (Ref. 6) "is still the mott probable ex-
plaftation hccbunting for the results obtained: Accordin'g to this'asbump-
tion, the two-6take asp6ct of the decompobition of the peroxide radical
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Problem of a higher hydrogen
22005
S/076/61/035/004/013/018
B106/B201 i
condensate is due to the decomposition of the H204 compound, which takes
place by different mechanisms in the solid ahd in thb liqUid state. ~
Mentloh 18 made bf Ye. N.'Yerelnin, who'took part in the work of Ref- 7 to-
gether with L. I. Nekrasov and N. 1. Koboiev. There are 3 figures, 1 '
table', and 17 referencess 7 Soviet-bloo and 10 non-SoViet,-bloc. 'The three
most recent references to English language ptiblibatibns read as follows:
M. A, P. Hogg, Je E. Spice, J. Chem* Soc'., Sept.9 ;971, 1957; J. A.
Gormley, J. Amer. Chem. Soc-, 79, 1862, 1957; R, L. Livingston p J. A.
Gormleyq H. Zeldesp J. Chem* Phys,f 24, 4839 1956.
ASSOCIATION% Moskovskiy gosudarstvennyy universitet im. M. V.
Lomonosova (Moscow State.University imeni M. V. Lomonos.ov)
SUBMITTED: July 28t 1959
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22005
S/076/61/035/004/013/018
Problem of a higher hydrogen .. . B106/B201

+.10
140-, -K--
T
k. MULL-1
IR k
t, C
LIO.. -I(-,
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UtIff.-I
k.
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MOTOA pannomepnoro Harpenanna MOTOA HOCTOR11HUX TOMUOPaTyp
-to() 5,78 0 00288 -2,572 -100 5,78 0,M8 -2,056
-96 5,65 0:00337 -2,472 -92 5,53 OjOI52 -1,818
-93 5.56 0,00330 -2,482 -78 5,13 0,0184 -1,735
_91,5 5.50 0,00359 -2,445 -Irwr 4.58 0.0291 -1,530
-80 5,19 0,W390 -2,4U8 -14 4,57 0,0231 -1,636
-67 4.86 O,W470 -2,328 -50 4.45 0,0385 -1,414
-57 4,64 0,oOOSO -2,022 -41 4,31 0,0831 -1,080
-50 4,61 0,0117 -1,932
-48 4,45 0,0110U -1,398
-43 4,35 0,0948 -1,024
Tablet (a) method of uniform heating, (b) method 'of constant
temperatures.
Card 5/5

.1)1

13-20

930
) an d
- z
z C,

n.- 9 1026-1050

R:~i s g i s

: s tud ! d,
I r gE.
-r~ist3 and

r
k
I i
"! T
i
7r

d~ --hprge

1-14020
2~ nc)8
f ilp
Tr a z I' P
rydr
-d
crs r d,
Tre -z rl
r, n: r
t he
d d NH irli 0,~ 5,

'~? Q
3 0, 110'~r'/Oor ;C05/0013
rrv ~ i t i (~ rc Af 1; ~,d -i ~: i n ii d ;~ r i tir, R 2 1
r e f e r r e dt. f) the t n tv I amot, n t Cf NH 3pa-qqPd through the appar-itus. Experi-
mentF, ,~t -190 ar-I -196"IC :;how-d that the rield of N.H. doea not derend on
temp's, I-Iij i) I-p T t is -(nrlud-rl th;- ft.rnifion of hydrazine rr,-,,~eeda
according io the eq,,,at,on 'IF 2+ N112 + lit ---)N 2H4 + 11 (5), where M is a part!olp
-aus;!rn~ -recorrJAratiQn, Disqoci.rition of N H proceeds accordirg, to the
2 4
N H --) N,H A(-- 2NH (6) and IT H 4- H go NH ~ NH (7). Thus,
2 A 2 4 2 2 4 2 3
the .,,,-I.eld of N,F", rleppnd.? )n se-eral factors Wnivh rict toge+her: 1) -n the
C., . I
,--oncentration of TIF ralicals. which 1'. inversely prcr,;rtioral to the
2
dissociaiion of NH 3 ; 2) on concentralion of atorzii- hydrogen, vvhich is
directly propc-rt;LonaL to the dissoc-,ati,-?n of NH J on the time for Nh-11ch
3;
the gns remaina ir. the discharge tube, The shorter thas Period, the less
Is the dissociation of N 2-11 4* A maxivjm degr-?e of NH disso,~iatinn
-orresp
-.onds to a vri-inimum conrentraticn cf NR, radicals and to a maximum
--oncentraticn of Patoml-c hydr.,.gen Th!.~---., the Yield of hydrazi-ne reaches a
Oard 3/6

24020
S//076/W035/005,/003/008
Study of t-e formation -;f h-fdrazine during... B1 01/k 113
minim!im with maxinum di.-,s~-,ciation of NR3 S. S, Vasi.-I 'Yev and Ye . N. YeremLn
are mentioned. There r3re 2 f .gure3 and 14 reforenceg : 3 Soviet-bloo and
11 non-Soviet-bloo. ThP 3 Mo9t ir!-,ortant reforences to En,~Ylish-lqrpuqge
publications read as flllowc- j. 0. Devins, B. Milton, J. A-,er,, Chem, Soc.,
76, 2618, 1954; G., W, Rotinson, M. J. McCarty, J. Chem. Phys, 30, 9?91
191;9; K. Ouchi, J. Ele~.!-rf-'-hem. S--(,,. Japan, 20, 381~ 19,52
~~.SSOCIATTON: Moskovskiv gnoudarstvecnyy universi.tf~t im. M, V. Lomon03OVa
(Mos~,ow Stt;f,e Univerqity imeni M. V.
SIMMITTED - July 3, 1950,
',ard 416

27683
0 S/076/61/035/009/006/015
B106/B110
AUTHORS: Skorokhodov, 1. 1., Nekrasov, L. I., and Kobozev, N. I.
TITLE: The problem of a higher hydrogen peroxide and frozen radicals.
V. Thermographic method for studying the decomposition
process of peroxide radical condensates
PERIODICAL: Zhurnal fizicheskoy khimii, V. 35, no. 9, 1961, 2025 - 2030
TEXTs The decomposition of condensates containing peroxide radicals was
studied thermographiczlly. The systems investigated were obtained from
water vapors dissociated in an electric discharge, and from the reaction
of atomic hydrogen with liquid 100 % ozone at liquid nitrogen temperatures
The system obtained from water vapor contained approximately 15 % (by
weight) H 2 04and considerable amounts of H 202 ; that from hydrogen and
ozone contained up to 60 % H 204 with no H 202. The method of preparation
was described Dreviously (Ref, 2: N~ 1. Kobozev, I. I. Skorokhodov, L. I.
Nekrasov, Ye. I. Makarova, Zh. fiz, khimii, J1, 1845, 1957; Ref. 5: L. A,
Reznitskiy, K. G. Khomyakov. L. I., Nekrasov. I. I. Skorokhodov, Zh. fiz.
Card 1/4

270
S/QJ6/61/035/009/006/015
The problem of a higher hydrogen B106/B110
khimii, L2, 87, 1957). The thermographic investigation method was similar,
in many respects, to the method of differential-thermal rapid analysis
elaborated by G. V, Ravich: G. G. Tsurinov, and V. A. Vollnova (Pef. 3:
Zavodsk. laboratoriya, 21, 602, 1953). Fig. 1 shows the block diagram of
the apparatus used. A photorecording Kurnakov pyrometer of the ~ITK-55
(FPK-55) type was used for recording the heating curves. Heating was
carried out at a constant rate of 150/min. Automatic recording was
switched on at -160 to -1500C. and was continued for about 10 min. The
investigF.tions produced the following results: Independent of the prepa-
ration method, the peroxide radical condensates contain the same compounds
which decompose during temperature increase. The evaluation of thermo-
chemical data (heat effects of 34 - 36 Kcal/mole 0 2 at decomposition
temperatures >--550C) showed that the decomposing compound is the higher
hydrogen peroxide H 204' which agrees with the data in Ref. 8 (1. 1.
Skorokhodov, L. I. Nekrasov, L. A. Reznitakiy, K. G. Khomyakov, N. I.
Kobozev, Zh. fiz. khimiJi, a, 2090, 1959). The differencesin the thermo-
grams of the zwo systems investigated are based on the following fact:
The condensate produced from dissociated water vapor is of disordered
structure, and crystallizes at -110 to -700C. The hydrogen peroxide in
Card 214

2768~
S/076/61/035/009/006/015
The problem of a hi.-her hydrogen B106/B110
the condensate is responsible for crystallization. During heating in the
temperatare range of from -110 to -750C, the heat of crystallization of the
amorphous part of the condensate appears, therefore, besides the chemically
conditioned thermal effects. On the other hand, the condensate from the
reaction of atomic hydrogen with liquid ozone before decomposition contains
no hydroren peroxide, and is of crystalline structure. In this case, no
heat of crystallization, only chemically conditioned thermal effects appear.
The good agreement of values for 6H calcula�ed from thermograms with data
obtained calorimetrically shot-is that the thermogral,hic method may be
successfully applied to the investigation of frozen systems containing
radical and metastable compounds. The authors thank Ye. I. Makarova for
conducLing the chemical analyses. L. G. Berg and V. Ya. Anosov (Ref. 71
Zh. obshch. khimii, 12, 32, 1942) are mentioned. There are 4 figures,
I table, and 10 references: 8 Soviet and 2 non-Soviet-bloc. The reference
to the English-language publication reads as follows: R. A. Jones, C. A.
'Winkler, Canad. J. Chem., 29, 1010, 1951.
ASSOCIATION: 1,.Ioskovskiy gosudarstvennyy universitet im. M. V. Larionosova
(Moscow State University:imeni M. V. Lomonosov)
Card 3/4

3126 '117
S/076' /62/036/"001/007/017
B, ()7//B 1 10
AUTHO"~S Skorokhodav, I, I Golubev, V. B, Nekrasov, L, I,
and Ke-)bozev, N . F.
T IT',,E The hip-her hydroren peroxide in frozen radicals. V~ Electru,i
paramarnetic resonance atudy of peroxide radical condensate
PERIODICAL: Zhurnal fizicheskoy khiiqii, v, 36, no. 1, 1962, 95 - 97
TEXT: The synthesis of the radical HO 2 either from dissociated water
va 'nor or on reaction between Dure ozone and atomic hydrogen at -196 0C has
been studied by the e.p.r. method. The purpose of the investigation was
to check published data (Ref, 1, see below; Ref. 2: A, I. Gorbanev, S.. D_
Kaytmazav, A, M. Prokhorov, A. B. Tsentsiper, Zh. fiz. khimii, 31, 515,
1957; Ref. 3, see beloww, Ref,, 9: S~ D. Kaytmazov, A. M. Prokhorov, Zh,
fiz. khim-ii, 54, 227, 1960) and to establish the maximum HO2 concentration
oossible, The resonance spectra of both peroxide-radical condensates
exhibit asymmetric maxima at 9000 /SEC. irrespective of the method of
synthesis. The asymmetry is due to the anisotrony of the g-factor which
Card 114

32637
S/076/62/036 '/001/007/017
The higher hydrogen peroxide- B107/13110
amounts to 2.009. The line width is about 75 ce, Synthesis from
dissociated water vauor has shown that the ratio of unpaire"', electrons
to the number of H 20 2 molecules remaining after the decomnosLtion of' the
(-,oriden,-,,,t(-- varies from 0 to 0.0()7, ,-Aiich ?. ,-rees with Ref, 1 (0.0065),.
The d-,vergencp from the value ,,,iven in Ref.. 2 (CI-004) is explained as
folic;T- The condensate is se-,)ara ted in the cool-.n- trap in the form. cf
t.-,,;o nne sli,-htly ahove the level a,' liquid ri~troger, which is white
~,nd ~2`,,',- but. M,, -,,iilile otlf,.e-- below the level
and containz7 about 5f;:7, H 0 at,ld the raadi-cal FO . At -JIOoC,
9 2 2
thc rin,- tnrns oarnm,,~-Iune~~(, abiorn.~Ien dir.-.uni.shes.
Frcm flur,,~ r- i ~,-r 5
ha F, - Vi n *, ~,-a t t 11 e rI t i
,j!-2--jrerj C-JeC7ron~ 'o numbe r o t' H 2 0. mol~ac;iles remaining after tne
tic- o-, 'Uir- condensat- Varles -ror, O,ucf, to O~00)~ From th~
.~-iraciaf-netic -Lone it is nj' -c--ssible to deci-je
w-e-her the radical HO e
o r -L ~. .-Iyaroxyi L: T-- r e s. e n-, The presence Cf
T o d rf xy L 110, i
gamma Ice ou i
Car(I 2/4

132637
6
The hi-hor hyd ro-en peroxi~] e -E 1 .3 7'-P 0'
below); the resonance spectrum of' the condensate in queo r-ion rn-s--nl~ i,.-
the Famma spectra of organic comnounds, suzch as Te--Ion. polyethyl-r-i--,
etc., -4hich cont.--:~.in "lie radical C-0-O', as -iell as the snell;!rum of*
notassium peroxid- K-,,)-O*; when the rin- '-ecDnes co1cr'es-, n-t-w-e-i
r, te~i T e
-110 and 00 xY,_, i io s e C a
c~ilculate.l for the the ralica, 0~ to %
1 - 1 - by w e i Fh wihille that for :10 is
2
The pregence of HO _s therefore very p roha le The -max i mum, Ll I
2
Tirere a r,~
asuro -)iint S
,)htained from the me~ -ments amt t o 0 4;,) by weight.
'18 refere-tices 10 Soviet and 8 non-Sovir-it, It" o iA rmrot recent
references to Fnj1ish-l,.irIFuaUe publications e as followg: Ref.
R. L. Livin~-ston. J. A. G'normley, 11. Zelcies, J, Chem. Phys, 2 :7, 1
I )l 56 ; R e f - C , K . Jen, S N. Fon er, E- L_ C oc 11 T- a n , w e
Rev., 112, 1169, 195,~,; i?e' 1A : J.. lt,- Flo,-~rnoy. L. H~ 7_lauiz~, S.
~i. Scollii!-7, The fol.Artn, intornational S- () C free rr.96 ic~, 1!
stabilJ7;,tion, V, 1)~_),5; H, 'N'. Refroad, ""'. G,),d,,, Bull. Amiev.. P~,.,,-, 3i-,~_-_
2oo, iq~-,6.
C,kr,! 5/4.

TI, i e
- -V7

A
L 61080,-65 EPIN,/E.PF (c N, (n),42JEli P
ve
C.
Ft --a
RM
CCESS1014 14R: AP5018253
-LT./0078/65/010/ 00711740/1742
546.33'137'173-31
AUTHOR' Skorokhodov, I. I.- Kurbatov, G. 11.
TITLE:\\Thermal decompositOn of ni t V Iperchlorat-fl
J
SOURCE: Zhurnal neorganiclies,oy khimii, v. 10, no. 7, 1965, 1740-1742
TOPIC TAGS: nitrosyl perchlorate, nitryl perchlorate, thermal degradation-
ABSTRACT: X-ray diffraction studies of the solid phase formed by the partial
decomposition of nitrosyl perchlorateklwere carried out, ta an attempt to deter--::._
mine the mechanism of this process. The compound was decomposed at atmospheriC.'
pressure at 130,150C in.a stream of nitrogen. interplanar dista nces and line
was- --that --the -
intensities I-or the brightest lines were determined. -f Lund
-thermal decomposition-of-nitroisyl ehloride in the solid phase produces nitryl.
I perchlorate, as follows;
N
2
OC104 7--> N02ClO4 4 N02 C101
A monotonic increase in the relative amo.unt.of-nitryl-perchlorate in- the Solid:
Coed

L 5135-65 EXT(m)/UF(c)/ZM/Wp(J) Pc--4/Pr-4/Ps-4 M RM/1rdMT/JAd/JF.4
ACCESSION NR: AP4046080 S/0076/64/038/009/2198/2203
AUTHOR: Skorokhodov, I. I.; Nekrasov, L. I.;
TITLE: Hydrogen superoxide and frozen radicals. 9. reactions of atomic.hydrogen
with ozone and oxygen in the gas phase
SOURCE: Zhurnal fizicheakoy khimii, v. 38, no. 9, 1964, 2198-2203
TOPIC TAGS: hydrogen superoxide, hydrogen peroxide, free peroxide radical,
,hydrogen oxidation, gas phase oxidation, liquid phase oxidation, ozone oxidizer,
oxygen oxidizer
ABSTRACT:- In connection with the search for-an efficient method of synthesizing
hydrogen superoxide, H204, the.gas-phase reactions of atomic hydrogen with ozone
and oxygen have been investigated. The purpose of the study was .to confirm an
earlier assumption concerning the particular role played by the liquid ozone film
in the formation of R204 in the reaction of atomic hydrogen with'100% liquid ozone.
The gas phasr. reactions were carried otit in avacuLn apparatus used previously for liquid-.
,phase reactions, and their products - peroxide-radical condensates ~were collected,
.in a liquid-nitrogen trap. The products of both gas-phase reactions were identical,--,,
containing water, hydrogen peroxide, H204, and H02 free radicals,\'Xthe latter in
.Card 1/2

:;;~PawXtW_ NA
L 15135-65
ACCESSION NR: AP4046080
very small amounts. However, the H204 content was about 27% by weight Inthe pro-
duct of the ozone reaction, against 15% in that of the oxygen reaction. The com-
position of both products contrasted sharply with that of the condensate obtained
previously in the liquid-phase reaction (40% water and 60% H200. This fact was
taken as an indication of the effect of the liquid-ozone film. Haximum yields of.
all reaction products in the gas phase were observed at high 11/03,or H/02 ratios.
As the ratios are lowered, the yield falls to zero. A reaction mechanism based on
experimental data was proposed, according to which H204 (as well as Rj02 and H02
free radicals) is formed on the cold walls iof the reaction trap, whereas only waters'
is the end product of the reactions in the gas phase. Orig. art. has- 2 figuires~
and 11 formulas.
ASSOCIATION: Moskovskiy gosudarstvenny*y tmivergitet im. H. V. Lomonoeova
(Moscow State University)
SUBMITTED: 02Nov63 ENCL: 00 SUB CODE: EP, cc
NO REF SOV: 010 OTHER: 009
Card 2/2

1 63565-65 NdT%(m)/EPF( o VEPRANP J VT Pc-4/Fkr-,h/Ps-4 RPL Md/Rm
1ACCESSION NR: AP5013527 UR/0076/6*5/039/005/1277/1281-.
51fl/. 545
:'AUTHOR: Malltsev, Yu. A.; Nekrasov, L. I.; Sleorokhodov, I. I.; Oks, N. A.
!TITLE: Use of the EM-4 electron diffraction camera for studying products of the
-temperature condensation of dissociated gases and vapors
ilow
ISOURCE: Zhurnal fizicbeskoy khimii, v. 39, no.. 5 965~ 1277-1281
ITOPIC TAGS: electron d iffraction camera, free radical
,ABSTRACT: Free-radicallproducts of the low-temperaiure condensation of vaDors and
~aases pass~_d-IFP-5-5-gff-ah electric discharge were studied by using an E14-4 electron
Idiffraction caimera modified by the addition of a system for cooling the sample And
ia system for protecting it from contamination (by water vapor or vacuum lubricant).
IThe design and operation Of the SySteM3 are fully d,~scribed. The two systems per-,_.,~
)Oc.lTh- protective system permits
imit electron diffraction studies from 0 to -i9(
;experiments at -1900C for 11/2 hours with contamitatin the sample. This was
1 19
~demonstrated by an analysis of ammonium chloride (see fig. 1 of the Enclosure)
I certain change in the interplanar distances shown by these mlcrophotogra~Tnsis ~ue t6l
j
Card 1/3

T.
1ACCESSION MR., AP5013527 ENCLOSURE: 01

ACC NRz AP6034150 SOURCE CODEi UR/0076/66/040/010/2361/2365-
AUTHOR: Nckrasov, L. I.; Skorokhodov, I. I.; Kobozev, N. I.
ORG: Chemistry Department, 'Moscow State University im. M. V. Lomonosov
(Khimicheskiy fakul'tet, Moskovskiy gosudarstvennyy universite t)
TITLE: Physical chemistry of concentrated ozone. Formation of ozone from oxygen
in a glow discharge at low temperatures
SOURCE: Zhurnal fizicheskoy khimii, v. 40, no. 10, 1966, 2361-2365
TOPIC TAGS: ozone concentrated ozone, glow discharge, elemental oxygen,
ozone formation kinetics
ABSTRACT: A study has been made of the formation of ozone from oxygen in a glow
discharge at 0.5 mm Hg and -196C. The generator was described in an earlier study
i (N. I. Kobozev et al. Zh. fiz. khimii, 34, 1843, 1957). The generator was operated
on voltages ranging from 800 to 1200 v and a frequency of 50 cycles with a discharge
current of 0.15 amp, The flow velocity of oxygen varied from 0.1 to 4.0 X/hr. The
experiments were directed toward determining the place of ozone formation, and the
role of the discharge tube, connecting channel, trap, and priesence of elemental
oxygen in the trap. It was shown that ozone is formed in the trap, and only in the
presence in the reaction zone of a cold surface and elemental oxygen. The glow
discharge is only the source of elemental oxygen. In other experiments, the
L(~,~rd 1/4
UDC: 541.14+541.13

ACC NRI AP6034150
1,9",v.'Mollhr'
0
10
0
Soo /Ma 1//r a 590 10#04,
lFig. 1. Dependence of the absolute Fig. 2. Dependence of the degree
yield in ozone on the U/V parameter of oxygen conversion on the U/V
(U, discharge power; V, flow velo- parameter
city)
a - Inert; b - active surface of
a - Inert; b - active surface of the connecting channel.
the connecting channel.
dependencies of the yield in ozone and of the degree of oxygen conversion on the
U/V parameter (U, discharge voltage; V, flow velocitq were studied with the use of
connecting channels with inert or active surface (see Figs. I and 2). The results
of the experiments have indicated the following mechanism of ozone formation:
Card 2/4

ACC INR- AP6034150
1) dissociation of molecular oxygen in the discharge tube
0z + e --).. Oz- + e,
020--1.- 0 + 0.
2) recombination of oxygen atoms in the connecting channel
0 + 0 + M - 02 + (2)
(M,-walls of the channel)..
The reaction l/reaction 2 ratio determines the amount of elemental oxygen reaching
the cold walls of the trap. -This ratio depends on such factors as flow velocity arAd
pressure of oxygen, discharge voltage, and state of the surfaces of the discharge
I
tube and connecting channel; 3) reaction of elemental oxygen with oxygen molecules
absorbed on the cold walls of the trap
(3)
0 + 02-S - 03-S,
-'~a'lls' of the trap).

ACC NI: AP6034150
In the experiments, small amounts of almost 100% liquid ozone have been synthesized.
Orig. art. has: 2 figures.
SUB CODE: 07/ SUBM DATE: 13May65/ ORIG REF: 0081 OTH REF: 011/
F
Card 4/4

SKOROKHODOV, L. N.
Problems in the theory of the welding of plastics by means
of ultrasonic waves. Plast. massY no.11:33-35 162.
(MIRA 16:1)
(Plastics-Welding)
(Ultrasonic waves-Industrial applications)

MOKWINTSEVA, A.V., kand.tekhn.nauk; Prinimali ucha6tlyes- OLISHVISKIY,
N.A., kand.tekhn.nauk; SKOROKIIODOV, L.N., inzh.
Ultrasonic weldina of small-size-po-lyethylene shells. Trudy MVTU
0
no.106:199-207 162. (MIRA 16.-6)
(Ultrasonic welding) (Plastic3-44elding)

" K Ol
"
I ROMODOV, 1- Ya.
"Kratki ocherk. istorii russlr-.o4- meditusiny, Izd. Pral-ticheskaya -Meditusina, Leningrad,
i926, 262 pp.

SKOPOKHODOV, L. YA.
USSR/Medicine Medicine, Military Nov 1947
Medicine Training
"Military Medical Academy imeni S. M. Kirov," Prof D. N. Lukashevich, Maj Gen
(Med); Docent L. Ya. Skorokhodov, Lt Col (Med), 8 pp
"Voyen-Medits Zhurnal" No 11
Briefly describes history and fundtions of Military Medical Academy imeni Kirov,
factor in rapid imrrovement of military medicine. Soviet military medicine parallel-
ed general development of nation in rise from agricultural economy to become one
of great industrial powers of world.
FA 53T75

--I - -- -
- , i.. .,.
f H
- ~ rlaly ; o isiorii. meditSirSkOy !T.ikrobiolo. ii v ciore-,olyut.siolinoy F~Ossjj
(1-5tteriBlv an tL - Ili.-tory of YicrobicloEy 12 Frerevo-lutionary Russi~),
Yedr-iz$ 1c,4;:
1, - I -.

-iRiMedicine LT-J-demioioFy FD-3305
Card 1/1 Pub. 148-21/24
Author Skorokhodov, L. Ya.
Title : The status of e-Didemiology in Russia during the first quarter of the
l9th century
Periodical : Zhur. mikro. epid. i immun. 10, 90-92, Oct 1955
Abstract : A review of work in the field of e-Didemiology in Russia during the
first quarter of the l9th century from 10'sources dating from 1798
to 182.0 is given. The 10 sources are cited.
Institution : --
Submitted - June 24, 1955

SKOROKHODOT. L.Ya.
MI.I.Babukhin, the founder of the Moscow school of histologists and
bacteriologists* by A.I.Me.talkin. I.A.Alov. IA.B.Zesin. Reviewed by
L.Ik. Skorokhodov. Zhur.mikrobiol.epid. i immun. 27 no.11-100-103
N 156. (MLRA 10:1)
(BABUKHIS, AIRIUNDR IVANOVICH, 1835-1891)
(MSTRIZIN, A.I,) ~LOV, I.A.) (KESID. U.N.)

SKOROKE---*,~OV, L.Ya. (Leningrad)
Pavel Gorianinov and his role in the history of Russian medicine.
Trach.delo no.2:213-215 F 157. (KIRA 10:6)
(GORIANINOT. PAVEL FEDOROVICH, 1796-1865)

SKOROKHODOV, L.Ya.
~i-us- sia nmicrobiology in bacteriological control of the
efffictiveness of disinfections; author's abstract. 2~hur.mikrobiol.
epid. i immun. 28 no-8:77-78 Ag '57. (MDU 11:2)
(ANTISEPTICS, effects.
bacteriol. control (Rua))

, I.; -.-II I . 1. p . II/ .11
SKOROKHODOV, L.Ys.
History of the Leningrad Microbiology Society. 7-hur.milcrobiol.epid.
i imun. 28 no.8:156-157 Ag 157. (MIRA 11:2)
(LSNINGRAD--MIGROBIOWGY--SOCIETaS)

SKOROKHODOV, L...Ya.-
"Dictionaz7 of terms for a course in agricultural microbiology"
by A. I. Metelkin, 0. A. Metelkin. Reviewed by L. IA.
Skorokhodov. Zhur. mikrobiol., epid. i immun..32 no.8:11+9
Ag 161. (MIRA 15:7)
(MICROBIOLOGY-DICTIONARIES) (HETELKIN, A. I.)
(METELKINJ 0. A.)

SKOROKHODOV, L.Ya. (LenLina-lad)
W.I.
Rusaian madl~~.Lne in V~e t:~xe of NapolLeouL,- Wareg rAi the 150th
annivensary of tha var of 1812., Sov. zdrar. 21 no.926?40162-
(MMA 17 -, Q

.SKOI(OKIIODOV, Lov Yukovlovich; NEYVAN, red.
[How microbiology developed] Kak razvivalas' mikrobio-
logiia. 1.'.oskva) Meditsina, 1965. 48 p.
(I,',IRA 18:9)

ACC NRs AP6015243 SOURCE C06L /bon
AUTHOR: -Sk-u
-~khodov, L
ORG: TsVIISK im. V. A. Kucherenko (3- i
TITLE: Prevention of crystallization cracks.in arc_spot welded metal
i/J
SOURCE': Avtomaticheskaya svarka, no. 5, 1966, 20-22
TOPIC 'FAGS: steel, arc welding, spot welding, weld defect, metal cryntallization,
welding electrode, welding Lechnology/St.3 steel 4
ABSTMur: The arc spot welding of elements of St.3 steel more than 10 mm thick
results in a~ low resistance of weld metal to crj~-tallization cracks. It is shown
that this may be offset by adjusting the welding conditions and particularly the
electrode fecd rate. The cracks arise at the boundaries of columnar crystallites and
chiefly at the sites of their mutual contact, i.e. they bear a distinct inter-
crystalline character and are affected by the orientation of these crystallites
Thus, during deep fusion welding of this kind (depth of fusion up to 45 mm), the
crystallites contact at their ends if the electrode is stationary during the cavity-
filling stage, i.e. when the diameter-to-depth ratio 0 of the weld pool is 1.25. It
is established that if during this stage the electrode is additionally fed at the
rate of 6 mm/sec, the depth of the weld pool is reduced while its diameter remains I
791,763: 620.191.33

ACC NR: AEF6015Z43
virtually constant, i.e. ip is increased to 1.7. The crystallites are bent in the
direction of the center of the weld pool and the crystallization cracks in the weld
metal are partly suppressed so that they do not emerge to the surface of the weld
spot. The welding is carried out under tighter conditions (current density 40-50
abun2), with the electrode melting rate being higher than during conventional arc
welding. Orig. art. has: 3 figures.
SUB CODE: 11, 13/ SUBM DATE: lOJun65/ ORIG REF: 003
Card 2/2

)i- - I --"' - - -,- - * ~11.
5" , ~. ',"I .'~ LI
Lractors
'T
511-pur,.ose marhine. Sov. -hen. NO. 5, 1952.
9. Monthl List of Russian Accessions, Library of Congress, December 195? ~M' uncl.

KLEMMIYKVA. A.I.; SKOROKHODOV, N.A.i Prinimali uclmstiye: ALEKSANDROV, G.F.;
BABUN, F.Ya.-, BAYBARIN.",P.P.; VAYNSHTEYN, TS.Z.; (RJSZV, L.V.; ZHITVIN,
N.P.: KONTSEVAYA, Te.M.; MINA, K.M.; NOVLTANSKAYA, K.A.1 FOD- i'
VOYSKIY, L.N.; THUR SKV, D.S.; FLEROV, N.G.; CHIMCH", I.A.; TUROV,
Yu.M.; GUDKOVA, N., red.; YEGOHOVA, I., takhn.red.
[Light over the gate] Svet nad zastavoi. Hoskovskii rabochii,
1959. 422 p. WRA 12:4)
(Moscow--Metallurgical plants)

KOVALMIKO, Vladinir Ivzmovich; SjOROKHOPqV,_Mikhail Arkadly~yizh;
., tekhn. red.
TSYGMKOVA, D., red.; YAOXI[k ~A,
[Birth of the new] Rozhdenie novogo. Moskva, Mosk. rabochii,
1961. 141 p 0 (MIRA 15:3)
(110scow region-Agricultural workers)

KOKOVIN, Yevgeniy Stepanovich; SKOROKHODOV, Mikhail Yevggenlyevich,
KOLOMI'YTSZVA, 0.1., red.; GLUBOKOVA, N.A., tekhn.red.
[Under the North Star] Pod Foliarnoi zvezdoi. Moskva, Izd-vo
*Sovetakaia Rossiia." 1960. 157 'P. (MIRA 13:7)
(Nenets National Area--Description and travel)

Xlectric fences for forest and shrubby pastures. Mias. ind. SWE
no-2:33-34 '57. (KIRA 10:5)
1. Starshiy zootekhnik Smolenskoy oblastnoy kontory Roaglavzagot-
skotootkorma.
(Mlectric fences)

SKOROKHODOV, 11.,
With the new curricula. Sov.profsoiuzy 6 no.16:34-35 N '58.
(MIR& 12:2)
1. Direktor flagnitogorskogo gornomatallurgicheskogo instituta
imeni G.I.Nosova.
(Kagnitogorsk--~-Mining engineering--Study and teaching)

1. M. IRS), INOV.
bezon~:tcri,~stl ir liteiirrr nrolzvodntva. ~10-.,-,va, 1947.
7
Ilibliography: 2n5-2o6.
Accident prevention in t"lle f,"indirig, t--IdU-2trf.
DD,': TS21O."161
S 0: %nd Ve-C!i,,talcal Enginecrtng in thc Soviet Uaion, Llicary if
lon~zreuc, 1953.

SKOROKHODOV, N.Ye., kandidat tokhnicheakikh nauk; ZAYVDV. M.A.. kandidat
1 --.1 --- - tei6fAei-Ekh nauk; KOFDLIV, A.S.. inzhener; SKORDKBDDOVA, V.F.,
inzbener.
Measuring the pressures exerted in the cold rolling of thin
sheets. Trudy Sib.met.inst. no-2:5-18 '55. (MLRA 90.12)
(Strains and stresses) (Rolling (Metalwork))

Q91 A Y', kandidat takhnichookikh nauk, dotsent; GOLUBNV, T.M.,
professor. doktor takhnichaskikh nauk; ZATKOV. M.A.. kandidat
tekhnichenkikb nauk; CHMYSHIW. N.A.. kandidat tekhnicbeakikh
nauk, dots6nt; KOROLIV, A.S.. inshener; OSHIN, V.I., inzhener.
Determining acting forces in friction and eccentric presses.
Trudy Sib.met.inst. no.2:19-29 '55. OMLRA 9:12)
(Strains and stresses) (Power presses)

SKOROKHODOV, M.Ye., doteent; KUCHKO, I.I., inzhener; KOR=V, A.S.;
BUKHVOSTGV, I.G.
Investigation of the rolling of experimental raila. Trudy TSNIZ
MPS no.111:25-32 '55. (MLELL 9:5)
(Railroads--Rails)

-SKOROKHODOV, N.Ye., dotsent; CHELYSHEV, N.A., kand.tekhn.nauk;
-ZAY~, XA., dotsent; FROWV, N.P., inzh.; KORDLET, A.S.,
in2h.; KBAVCHMMO, L.Ya., inzh.; SKOROKHODOVA, V.F.. inzh.;
ABAKMV, V.A., dotsent [deceased]; YLFTAWY, Y-P., inzh.
Investigating conditions of rolling plain and shaped
sections on a medium-ohape rolling mill. Trudy NTO
Chern.met. 15:24-55 159. (MIRA 13:7)
(Rolling mills)

SKOHOKFODGV, 14'.Ye., prof. otv. red.; AGAFOV, V.F., prof. po
rabote, dots., red., 30YAPSHBOV, M.I., prof.,
red.; VFOFLOVSKAYA, Ye.S., red.; GAGETI-T-ORN, A.V., red.;
GOLIESHTFYN, N.A., red.; IVANOV, N.I., kand. tekhn. nauk,
4-ts., red.; KORZH, P.D., prof., red.; PETROV, V.M., dots.
kand. tekhn. nauk, red.
[30 years of the Magnitogorsk Mining and Metallurgical
Institute] XXX let M2-il. Magnitogorsk, 1962. 170 p.
(MIRA 170)
1. Magnitogorsk. Gorno-metallurgicheskiy institut.
2. Sekretarl partiynogo byuro Magnitogorskogo gorno-
metallurgicheskogo instituta (for Petrov). 3. Dekan me-
tallurgicheskogo fakulfteta Magnitogorskogo gorno-metal-
lurgicheskogo instituta (for Ivanov). 4. Zaveduyushchiy
kafedroy fiziki Magnitogorskogo gorno-metallurgicheskogo
instituta (for Korzh). 5. Zaveduyushchiy kafedroy obrabotki
metallov davleniye 111agnitogorskogo gorno-r,,.-tallurgicheskogo
instituta (for Boyarshinov).

EWP(k)/EVff (d)/EWT(my/EWP(h)/EWP(I)/Evip(v)/Ewp(t) H?'/JD
ACC NR~ AP6005559 SOURCE CODE: UR/0148/65/000/010/0084/0089
AUTHOR: Skorokhodov, N. Ye; Subbotin, V. A. 11.~
ORO: Magnitogorsk Mining and Metallurgy Institute (Magnitogorskiy gornmetallurgi-
cheskiy institut)
TITLE: Study of the performance of composite rolling-mill rolls
SOURCE: IVUZ. Chernaya metallurgiya, no. 10, 1965, 84-89
TOPIC TAGS: composite roll, rolling will, cold roll-Ing, hot rolling
ABSTRACT: It is shown that the working surface of rolling-mill rolls can be easily
renewed and roll changing eliminated by using rolls of thi-composite type, con-
siating of a fixed central core surrounded by two semi-cylinders that are fitted to-
gether. Rolls of this kind (Fig. 1), have been experimentally used for 10 months in
the cold rolling of lead, aluminum, and copper and in the cold and hot rolling of
low-carbon steel. It was thus established that the fastening of the semi-cylinders
to the steel core of the roll is sufficiently strong and reliable even under condi-
tions of extra-high loading. This new design dispenses with the need for roll
changing, since now the roll core is a permanent part of the rolling stand and only
the semL-cylinder need be replaced. The new design is suitable for both smooth and
grooved rolls. This was also confirmed by laboratory tests on model* of two- and
I

L 2G779-66
ACC NRI AN
Fig. 1, Composite roll with lonthwigg-split
barrel (one seal-cylluder removed)

ACC NR: AP6005559
four-high mills, and by the concomitant analysis of rolling kinograms. on entry into
the area of deformation the gap between the joints of the semi-cylinders decreases
owing to the compacting presoure, thus preventing any flowage of metal into the gap.
iC_ The elimination of roll changing increases the productivity of rolling mills, while
the fact that the roll core is -now a permanent fixture facilitates the entire tech-
nological process and its automation. Orig. art. has: 5 figures.
SUB CODE: 11, 13/ SM DATE: 12Apr65/ ORIG REF: 000/ OrH REF: 000
:41 Card

:-)KO;-"C42!O3OVj P. I.
PA 52~__53
USSR/Medialn; - Grain Oct 1947
Medicine - HybridIty
"Rationalization of the Method and Technique of
Interhybriclization of Grains," P. I. Skorokhodov,
Turkmen State Selection Station, Bayram-Ali, 21 pp
"Dok Akad Nauk SSSR" Vol IVIII, No 1
The Turknen selection station first began hybridiza-
tion on a large scale in 1946. Experimenters faced
a number of difficulties,in the form of unsolved
problems of the biology of blocming under specikic
conditions in the subtropical climate of Turkmeniya-*
Reports a method of pollination, called lUdted free
pollination developed under these conditions. Sub-
mitted by N, A* -f,-"7 Apr 1947.
am Makelmo 52T53

SKOROKIIODOVI Pli.
- - tu -*:7h4 'er
Of the moi- -re of 2-1' ;~- -L I C'n-estnut soils und
the Protection of forest st7ips. no.2:74-79 F 164*
(MURA 17:3)
1 - 1- u
~. Volgogradskaya se-- '---,'-;-.!-,~-.~7yeystverl-rL!=-Lya opytnaya stan'siya.

SKOROKHODOV, P.M., inzh.; KONDAKOV, L.A., inzh.
Phasing at 110 k7. Rnergetik 8 no.1:28-29 Ja 160.
(MIRA 13:5)
(Electric currents)

-.S-KOROKHG-DOII,- P.M. -
Concerning the modernizaluion of the SLP-2 steeloscope. Energetik
10 no.4:32-33 Ap '62. (KRA 15:4)
(Steampipes-Testing)

AUTkR., Skorokhodov. S.A., Foreman SOV-91-58-4-12/29
TITLE,,, Some Problems of Organizing the Electric Assembly Work at
a 220 kv Substation (Nekotcryye voprosy organizatsi-i elektro-
montazhnykh rabot na podstants-ii 220 kv)
PERIODICALg Energetik, 1958, Nr 4, PP 15-18 (USSR)
ABOTRACT, The author suggested and intrcduoed some rationalization
projects improving the quality and speeding up the rate of
electric assembly work. A description of a new design of
the hydrostatic level utilized for checking and displacing
horizontal axles of large-sized construction and equipment
is given. Deficiencies of the former design, (continuous
liquid consumption which stops operation and the breakage
of glass pipes) are eliminated by this new design. The in-
stallation of air circuit-breakers of the "VV-220" type by
means of a 3-ton automatic crane is described, as well as
the assembly and installation of "RLNZ-220" type dic;connec-
tors. These disconnectors are supplied in nonasEembled state
and each pole is assembled and set on the earth befcre being
lifted by an automatic crane. The installation of current
transformers of the "TFND-220" type by means of a 3-ton auto-
Card 1/2 matic crane is also described. These current transformers

SOV-91-58-4-12/29
Some Problems of Organizing the Electric Assembly Work at a 220 kv Sub-
station
are supplied in an assembled state, filled with oil. Their
total weight is 4,400 kg, including 1,500 kg of oil.
There are 4 diagrams and 1 graph.
1. Electric power plants--Substations--Construction
Card 212

SKOROKHODOV, S.A.
[Credit for co=er.::ial enterprises] Kreditovanle torgov-jkh
organizatsii, Yloskva, Gostorgizdat, 1961, 103 P.
(MIRA 15:8)
(Credit)

5KOHOKHODOV, Sergey Alekseyevich; KARFOVA, L.A., red.
(Developing credit to the domestic trade of the U.S.S.R.]
dazvitie kreditovaniia vnutrennei torgovii SSSR. Lenin-
grad, Izd-vo Leningr. univ., 1964. 159 P. (MIRA 17:6)

-ah- ,I -Ila r. - c
i Q I'
cv of ~Ln C)

~c, f4 C'~~L, V!
z z 7.-
'
'
'
-
r
CY.C11 hy
banyl compounds.
&axy
ip
w
la
-
'
L
l
r with 590 4l,90, as alXwe gave 0% J(eBMC((U1)Bx. bt,

1
also obtaiued in 1-o'
4% yield
5192
Q21
V 1
sonien"
ljtctdtides
la
o
!
wetby
LAL444
Q-&IWUIS Into .
,
118-19
, (1:0 I.
, n
,
met4XLSjhCP~.*Of 160 als,
m c 0-oXO 21cohi T, 1. Teal- from the above bronto ketone by hydrolysis with a1c. a
J- , ,
-K; and S. S. Skornkhmlov (Strise ~
NaOlf; the latter procedure gave the carbiffol. N W-8
1
-
I4J-
ht
n
th
i
2
17nitwrud). Zhur. 06
rhckA~~575~95
-me
:
ox;k~
--V
1.6160. t(CAt
ng
y
d. 1.016, M.
o5j;
~a, 120,25b.-The be--t isornerizing catalyst
ethylethylane oxide 30 min. at 60-70* with p"ous plates

f
13;~
i
i
& satd. with ZnCIj Mu. and dried at 110", followed by diitu,
of 7
addu
Wuc
ithout
10
1
b
6%
or
somer
zation of metbyllac:tolldes, Meo
R.CR
), of -
,-
.
res
w
;
gave 9, distillate,
y
OX0 ulci- is ZnCls-, the derivs. of tertiary ovo nics. require drops FttO soln. of ZnCIt to the above oxide nve at i:~:,:-,P,
,nere drastic conditions thnn do the corresponding derivs. of reaction, resulting In formation of PhCH(O?J,,)COL :. ~ ,
secondary alcls. The methYllaclolides of alkaromatic oxo .99.5-9,8*, dm 1.015, n'0 1.5050; Senjitarbazalle. in. IA, ~ I
aleg, &play au absorption band at 017 cin. -1, characteristic 2,4-dinitroPhenYlkydrawnr, rn. 140-l'. To 11.12 g. 2-
of the oxide fing in these CoMIKIS. To20g.PhCOC11J[eD flittlioxy-2-phenyl~3,3-dbitt:tliylethy!ene oxide was added
ill dioxane was sdiled 60 g. dioxane
Br, yielding 81.1170 -

bromo deriv., ba Ill
13% which (52.27 g.) treated with 3 ml. satd. ZuCl, in EttO and alter I hr. at I IV there was
MeOM (from 16 g. Na) suspended in RtjO. gave in 10 hrs. .
formed 872% Afel'AlCAcOMe. b& 89-90% n1j' I.M. -Simi-
03.6 % l-,nakoxy-l-Phenyl-2-tneihjd-1-6leme oxide (1j. hr 75.5- larly 1-niethozy-l-plienyl-2-inetliyl-l-btitt-iie #,xidu 1::tve
v, 1), 101-~2*, di, 0.9%.3, t-1.1 1,4051, absorption ittax. 265, methazy-3-plieftyl-2-penkir:,.)". b, 98-9', dj, IAY-15~
257, -954, 252, and 213 mp. Heating this 4 hr!;. with 5%
90
so
Il
e 58
f
h (atime, in. 08-9'), which with 11160~Cl in 10% KaOlf gave
(
.
l
SEsC(O1lV
-, lo. d"
.
"a A
tav S
J.870 EtBz, identified as the semicatbazone, m.
5
r;1-1 1. ;Q, which has absorption max. 320 and 234 nip.
* Similarly ZlIC12 in EtO added to I-methoxy-l-phenyl-21-
Refluxing PI-iCOCBrMcRt its aq
. tic. NaOl f 21 hrs. gave the tnethyl-I-hctene oxide gave 73.4% 3-methovy-3-phen)4-3-
sanic n1c., Ill 113-13.5*. 2-1le-sanol with PBr& gave 52.5% heptanane, b, 108-0. dzO.1.192, nl.* 1.1003(oxime, Tn. 71-2').
2-brotnobexatic, 6 47-84. which conventionally- yielded To PhINIgBr from 2 g. Alg was added 4 g. PhCIl(OMeY
b4 130-2*; this (1131.3 g-) COEt. yi0ding after 5 h". reflaxing and usual hydrolysi-
y
and 83 K. 93Cri0i ill 484 g. H,O was treated with 62.5 nil. all unstated yiekl of the a-iromer of ElPhC&011
In.
ILSO, and 120 mi. 1120 ant. after I hr. at 70 yielded ,
the fl-isorner was prepd. sindlarly from benzoin Me ether;
821.3% tit, b, d. 0.057, the Product. m. OV. The spectra of thenu comptis. art:
?jV 1.5070. which with dioxane-fir gave 71% 9-brom.)-2-
1 shown.
methvi-I-Phenyl-44exanone, b, 43
1~9*; this treated Ivith
AlCONa'111 Rt,O gAve 58-35'o
1lrxC:1,' oxide, b. 07-81, nU, T;flsheated

/y
USGR / Physical Chemistry, Molecules. Chemical Bond B-4
Abs Jour : Ref Zhur - Khimiya, No 8, 1957, 25788
Luthor : B.S. Skorokhodov
Inst :Lenin9ii&'ffnD1i_eF5ity
Title iInfrared Spectra of C~ -Oxides
Orig Pub iVestn. Leningr. un-ta, No 16, 110-116 -Ip
Abstract Spectra of o4 -methoxy- -phanyl-p-ethylethylene and -me-
thoxy-g -ethylethylene (RZhXhim, 1956, 39530) were obtained
in order to make the data of infrared spectra of -metho-
xyoxides more precise. It follow from the obtained results
and bibliographic data that the frequency of about 900 cm-1
is characteristic ofCk-mothoxyoxides containing phenyl in
thecKposition. Monoreplaced c~-oxides of the aliphatic
series with heavy norm4 radicals (octyl and heavier) ha-
ve a band of about 917 which is missing by prop lene o-
xide, Asymmetric direplaced o~-oxides (ethyl esthers of
Car(i 1 A - 29 -

Yclic acetals of Ve methyt [a.ctolide 0 Pr
ation erties of th f "Oloct.",

I
W
t
--
t T-
ridoon
(o
I Tau
L-urakhod v (Stfzte Vriv- Ijf-qr-i--- -
--
Zhur -Obs I ( I 9W); C L C-A
90, 7725c.-To 20.5.3 g. Ke,CCOCIj*fc-. in dioxane -..is

-
.dded 45 g. Jjox. Brandafter l.5hrs.at7G-SO* thtre
e
--~
' -- - This(421~j
ubtabiedS2.71' CCOCM-Br.4),52-3~ ;.,
e
J., M
8
wu 5 L-Ided over I hr ~ to 5.7 g. Na in '-". ml. L-y M,
14 md
fiftt:r 4 days at r,K)ri temp. thv soln. was -~izd. with CC,.
Filtered rapiMy, and jaimedia-tely fractionated yicjding IOX

put -,live Me& CC(OMf). CAfc..O (1), - h. 77-7ti*~ b - UA-511
7
3
4-mv ~ abson, tiqu
* 0.8916, YM 1.4173,: which dqts~ nct;
Iramis typical of HO and C:O groups and does dispiLty Ln
abi. max. at 8,04) cm.-I typical of the oxide ring; Q6 small
arnt of VeXOCA-feIO.W'e, bn 70-l', nU I 4.21GO. was
A Isulatvd. The ppt. fman the above is'~Iatiou Waiwash'A with
Et:O and distd. yie!ding 7.33 Z. -oxo--ttmol-; Imating the
pi oduct with dil. acki &-ave a further yk!d cf this sublancc.
"Ox~,tenol" (11) had been r-zga~~ as a cyclic compound
but "as shown by its iafrarcd spectrum to I;c Me~CCOC'-
MejOH (cf. CA. 50. 47819)- ShAdng I with dil. IGSOt
kives 71.P% U. m. 49'. G. M. icoselapolff I
"