SCIENTIFIC ABSTRACT SHMONIN, L.I. - SHMOTOV, A.P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001549810006-7
• Release Decision: RIF
• Original Classification: S
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• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Z 0.

SHMONIN, L.I.; CHMDYNTS-Ti, Y.T.. TANN' ME A, G.G.: XASHKAROV, L.L.
Deteraining the isot-apic composition of uranium from the stone
meteorite Staroye Paslyanoye. 'BiiilgKomepo opr,abs.vozr.-geol.form.
no.1:64-66 155. (MIRA 9:10)
1. Kazakhakiy gosudarstvenritvy univ"raitet j Fiziko-takhnicheakiy
inatitut AN TazSSR.
(Uranimm) (Mnteorites)

15-195 7-10-14194
Translation from: Referativnyy zhurnal, Geologiya, 1957, Nr 10,
p 133 (USSR)
AUTHORS: Cherdyntsev, V. V., Shmonin, L. I., Strashnikov, N. S.,
Asanova, 0. L.
TITLE: Investigation of the Actinium-Radium Ratio in Minerals
(Issledovaniye aktiniy-radiyevogo otnosheniya v uffneralakh)
PERIODICAL: Byul. Komis. po opredeleniya absolyutn. vozrasta geol.
formatsiy. AN SSSR, 1957, Wr 2, pp 41-65
ABSTRACT: Tests were made or. the constancy of the ratio of activ-
ity between the uranium and the actinium series in a
large number of minerals. Data were also obtained on
the ability of some products of the actinium series to
migrate under natural conditions. In the test for Ac/Ra
in the primary minerals--various oxides, aluminum sili-
cates, titanates, zirconates, niobate-tantalates, phos-
phates, tungstates, and asphaltites--it was shown ttiat
the ratio in these minerals is normul. In secondary
Card 1/3 minerals,, Ac/Ra may deviate markedly from the normal.
a ~Y_ ~~ ~~ I,,

15-1957-10-14194
Investigation of the Actinium-Radium Ratio in Uinerals '
This deviation is explained by the complex processes of migra-
tion of the radioactive elements. For the majority of secondary
minerals, it was observed that Ac/Ra 1. It is possible that
this value is, in many cases, due to the accumulation of the
radioactive elements of the parent rocks. In many secondary
minerals in the zone of oxidation, Ac/Ra is controlled by the
migration of Ac and Ra. In some cases fic/Ra 1. This relation-
ship may occur only if the decay products of U migrate. Spring
deposits show a very large fluctuation of Ac/Ra (0.03-17). In
some primary minerals Ac/Ra 1, although the age of the minerals
is known to be older than needed to establish equilibrium in the
uranium series and between uranium and actinium. Such minerals
are said to be anomalous. The majority of the anomalous miner-
als studied are oniy weakly active, their content of radioactive
elements being below the average for the earth's crust. An
anomalously high Ac/Ra occurs in many primary minerals, chiefly
of hydrothermal origin. The largest anomalies ratio is found in
minerals which, to the eye, are well preserved, and it is also
found in many minerals that are stable in the zone of oxidation.
Card 2/3

80310
1_47115~0 0 SOV/81-59-7-23070
Translation from: Referativnyy zhurnal. Khimiya, 1959, Nr 7, PP 144 - 145
(USSR)
AUTHORS: Shmonin, Ll.,Tv. Cherglutsev, V V., T4rtakovskiy, D.I.
TITLE; The Determination of Boron Content by Means of rradiation With
Slow Neutrons
PERIODICAL. Uch. zap. Kazakhsk. un-ta 1957, Vol 30. PP 7
ABSTRACT: A method was described for determination of 13 based on its raised
ability (in comparison with other elements by a factor of some
hundred) to absorb slow neutrons with the emission of M -particle
and L17 nuclei according to the reaction: B10 + n m He4 + L17, S
the quantity of which is practically proportional to the B content
in the analyzed sample. A layer (3 - 5 mg/cm2) of the finely-
ground material to be analyzed is irradiated by neutrons from a
Ra-Be-source ( '-- 0.15 Curie) moderated in a block of paraffin
7 cm thick, and the number of M -particles and L17 nuclei which
are emitted by the sample in a time unit, Is measured by means of
Card 1/2 a counter installation with a pulse ionization chamber. The content

SOVI/7-59-2-2/14
Investigation of the Neutron Flux of the Earth's Crust
Results are listed in tables 1 and 2: besides geological
formation, location, and genesis, the activity (inpr/h)
and flux of slow and fast neutrons (in n/cm2/h) are given.
Gamma activity and the intensity of the neutron flux are
usually proportional. In the Aktyuz deposit the intensity
increases to 32.4 fast neutrons/CM2/h and 28.2 slow neutrons/
CM2/h. & dependence-of the intensity on humidity was observed
in the Vostochnyy Kou-nrad mine. There are 2 tables and
7 referenceB, 2 of wbicb are Soviet.
ASSOCIATION: Kazak-hskiy gosuda-rstvennyy un-i-ve-relt-at im. S. M. Kirova
(Kazakh State University imeni S. M. Kirov)
SUBMITTED - June 10, 195a
Card 212

-QA 5816210G.01GO21U, I lGrD 1,
A058/j',!(,l
AUT'iORS: Cherdlyntsev. V. V., Shmonin, L;. I. Ostapenko, V. F.
TITLE: Determination of minor traces of thorium by means of neutron irradt-
tion
PERIODICAL- Referativnyy zi-vurnal, Fizika, no. 2, 1962, 19, abstract 2B141 (t'Sb.
nauchn. rabot Kafedrj optiki i Kafedry eksperim. fiz. Kazak,?lsk.
I
un-t", Y100, no. 2, 13-16)
TE,','T: There is described a method for measuring minor traces of Th 232 in
extracts of some minerals by means of recording the fission fragments of Th
nuclei incident to their irradiation by neutrons from a 100-mcurie Ra - Be
source. In the present aork the thorium was separated from specimens together
with cerium, which had been added to the specimens beforehand as the thorium
carrier. If the investigated solution contains U, which also undergoes fission
under the action of neutrons, the Th and U are separated by irradiating first
with fast neutrons and then with thermal neutrons.
rAbstracter's note: Complete translation]
L
Card 1/1

S/081/62/000/011/017/057
E032/,Ell4-
AUTHORS: Cherdyntsev, V.V., -Sh-oin", L.I., and
Ostaperd,-o, V.F.
TITLE: Determination of small quantities of thorium with the
aid of neutron irradiation
PERIODICAL: 2eferativnyy zhurnal, Khimiya, no.11, 1962,142,
abstract 11 D97. (In the Collection: Nauchn. rabot
K.afedry optiki i Kafedry eksper4M. fiz. 1~azakhsk. un-t,
no.2, 196o, 13-1G).
TEXT: To determine small quantities of thorium (down to 10-4g)
in extracts of some minerals, use was made of a method based on
the recording of fragments from the fission of thorium nuclei
during irradiation by neutrons from a Ra-Be source. Thorium is
removed from solution by co-precipitation with cerium oxalate and
t.-le precipitate is placed in an ionization chamber. It is 'then
irradiated with a beam of fast neutrons and a number of fission
events is recorded. In the presence of U measurements are made
of the number of fission events produced by fast and partly
slowed-down neutrons.
Card 1/1 FAbstractor's note: Complete translation.1

CHERDYNTSEV., V.V.; SMIONIN,___~.I.; OSTAPENKO, V.F.; KHALDEYLV, O.D.;
r.-L --
KASHKAROV,
Neu4rbn radiation of the earth. Geokhimiia no.3:261-267 16o.
(14IRA 14: 5)
1. Kazakhskiy gosudarstvennyy universitet imeni. S. M. Kirava,
Alma-Ata.
(Neutrons)
(Nuclear geophysics)

C~ERDYNTISEV, V.V.; ASYLBAYEIV, U.Kh.; ORLOV, D.P.; SH-IONIN, L.I.; ISABAYEV,
Ye.A.; KADYHOV, N.B.
Uranium isotopes in nature. 1.Actimn~-radio ratio of minerals.
Geokhinl-ia no.8:650-655 161. OJIPA 17:3)
1. Geologicheskiy institut AN SSSR, Moskva i Kazakhskiv gosuda--st-
vennyy universitet, Alma-Ata.

ARTAMOITOV, D--titriy Samonovich; LUPICHEV, Nikolai Pavlovich, redaktor;
SILVOITIN L,L ro-tsenzent;SVIRIDOVA, A.A., retsenzent;
~ AA 6
A, 1_14., redaktor, KRASNATA, A.K., takhaicheakiy
rndaktor.
[Manual for oil barge skippers] Posobis shkipnru neft6nalivnoi
barzhi. Izd. 2-oe, parer. i dop. Moskva, Izd-vo "Rachnoi
transport," 1955. 182 p. [Microfilm] O-ILRA 9:1)
(Tank vmssals) (Petroleum--Transportation)

SHMONEN, M~~-,.
I
Maximum ru-nof--:' in small drainage basIns. Sbor.rab..Kursk. gidromet.
obzerv. no.2:w1l6-I.-'1 '64. (147-iA I?ig',

HIKOLIff, A.V.; BELOY, A.P., kapitan-nastavnik; VART.AMOV, I.S., kapitai.-
nastavnik; KOSMACHKT, I.K., kapitan-nastavnik; SARATOV, V.F.,
kapitan-nastavnik; SHMONIJ..", kapitan-nastavnik; BEKMAN, A.A.,
kapitan; DHITZHINIH, A.V., kapitan; IVANINA, B.F., kapitan; PUN-
TAYEV, L.A., kapitan; VESHCHILOV, K.A.; VTKHODTSU. P.K.; SMOLDY-
RU, A.Ye.; VEMSHCHAGIN, Ya.A.; SUTYRIN, M.A.; SAVOSTIN, N.D.;
FILYASOV, K.A.; GCLOVUSHKIN, M.P.; IVANOV, A.I.; FILYASOV, K.A.,
otv.za vypusk; ALSKSONT, V.I.0 red.izd-va; YEMIAKOVA, T.T.,
tekhn.red.
[1hales of navigation on R.S.F.S.R. inland waterways] Pravila
plavaniia po vnutrennim vodnym putiam RSFSa. Vvedeny v deistvie
a 1 marta 1959 g. prika2OM ministra rechnogo flota no.28 ot 11
fevralia 1959 g. Moskva, Izd-vo "Rechnoi transport," 1959. 124 p.
(MIRA 13:6)
1. Russia (1917- R.S.F.S.R.) Ministerstvo rechnogo flota. 2. Glav-
nyy revizor po bezopasnosti sudokhodstva (for Hikolin). 3. Nachall-
niki basseynovykh sudokhodnykh inspektsiy (for Veshchilov, Vykhodtsev,
Smoldyrev). 4. Rabotniki Upravleniya glavnogo revizora po bezopas-
nosti sudokhodstva (for Vereshchagin, Sutyrin, Savostin, Filyasov).
5. Glavnoye uprAvleniye vodnykh putey i gidrotekhnichaskikh soorm-
zheniy (for Golovashkin).
(Inland navigation--laws and regulations)

SHRONIH, M-1.
Effective use of a traffic 'interval" for track work on heavy traffic
lines. Zhel.dor.tranBp. 42 no.12:30-34 D 160. (MIRA 13:10
1. Zamestitell nachallnika Omkoy dorogi, g. QTnek.
(Railroade-Maintenance and repair)

SHMONIN ,,P..,- -
Don't lose time. Prof.-tekb. obr. 13 no-7:29 J1 '56.
(MLRA 9: 10)
1. Zamestitell direktora tekhnicheskogo uchilishchs, No. 13,
Sverdlovskaya obIRSt'.
(Sverdlovsk Province--Technical education)

- . I - -'. I.-, .. - - , . - . - . - ", ... ~ ~ -1 - --- _-i ~ _-
KO',NTA'ITf--I'P--? SHMOININ, M.A.
t)C-,.., developments in research. Stall 25 n0.3:231 Mr 165.
(MIRA 18:4)

SMOININA3 L. T.
USSR/Chemistry Acetylene
Chemistry Androstane
Jul/Aug 49
"Acetylene Derivatives, No 94, Synthesis of Polycyclic Compounds Related to Steriods: III,
Complete Synthesis of Compounds With Androstane Skeletons and Their Structural Isomers
With Methylcyclopentane Rings B,,11 I. N. Nazarov, L. D Fergellson, L. I. Shmonina, L. N.
TerekhovaY Inst of CTg Chem, Acad Sci USSR, 4pp
111z Ak Nauk SSSR, Otdel Khim Nauk1t No 4
Reviews results of 5 years of experiments in subject field in tabular and formulary detail.
Submitted 20 Max 48.
PA 63/497,

Acetylene deitiratives, CX. Synthesis of polycychc
compounds related to sterols. 7. Total syntheals or an
Smear of 15-inethylandrostenone with a methylcydo-
pentitnes A ring. 1. S. Nazarov and L. 1. Shnicarlima
Acad. SO. U.S.S.R- Nf~ow). Zhur. OWA4T-Khlier.
(I. Gcn.Chens.) 20, 87.6 87(195ol; rf. C..4.44,8014J.-
Ittrating 111.5 K. 2.44s.0h - loptillern-I -one (1), b.
fill V. AV LJOAS(I Q'IfII'l 6). CyclitAtion of allyl Iso-
plel,rilyl larl-0. -ilh 11~. ,. III III,
"t !I X. In a N Alan. 11A tits. tit 11.15 in A
,tainle-teel autoclave ca%-e 347 g. unreactc4l ketone anif
17 5 C. bs r-5',
~~ !m) 2'. V I AKS, d%* fewhrar&i.,we, in. -'I-.
18' (dcmnpn.; from FjOH); hydrogenation over lit
in Moll galive tile fe"rp,roding Ak-sah l4reirida"orre. I.,
oil? 1.47:17. 1-- 0 ixl2f, (jewiniaNm-pir. th-Voillp.
-114 -15' (front Ftoll)). Tile tetrahytiro voltip.j. t-..!
9.) in 1-50 tnt. rtA) was ttmtef with Call? for 35 mile. At
70* and, with continum if.. of lit, Call,. tberr ,A,
AddItIl UYTT I hr. at -70' A atlixt. If :.Ile) Sir]. Al,,l
im-BUOK (from 35 K And Wil g~ ROSS); furthcr
teratmelit with Call. L 7 1IF4., (ollownt fly itAlidilif IL.
b.. at - 70% pas,,a::c -f Call, fur 3.5 hr,- at rtx)in fertile.,
treatment with 1110, exiii. with I-.t,O, ticuitAlizativii of
,be arg. layer with AcOll. rated dimn . gave '-It It.
be 104 JAV. rill
1.51M, d:' 1.0114 SIMI Ovt-t I'S xavv III,- V
an,21.1jr. tea 4LI .3*). O'litt"Iled hydro.
gettAtion over lad iii Vtoll g.&%-c
AI-kirahydrea-1-St"dart.1, N., 78-80',nU
This (8 g,) heated with 3.5 g. powd. Kll-~;04 to IMAM-
At 10-100 Mtn., dical alisid. at 14) mile.. scave :1.5 r.
(111. to. 73 1'. 'it.'
I.5W I d" 0.917. Heating I with malvic ;In hydruic lie
C4H, at' 100' gave
fluterrestralicarboxylic anhwiride. Ill. M-(')* Iff'"n Sx-tr.
ethcr). which, larlileal wiih 11,0 2 tits., gave tilefret I, ad.
Ilm-Alulp. 161 A' (ft.)IT1 1~tr. dwI): licattlit; the-millvd(l.k.
ith NIPOU 2 hm K;ivr Oir Pat ...... lie eIl-, lit 127 s'-
litolil McOll). L .., III, cl.--
ith K in but Irv C'~ alld NIVI. Untl
disin. at At 5 team. g-avc po,,xcr Vidd, of It th.it,
were obtained with Kil-SO.. aild the PRAluct wis cvn-
lantinated by S cotn;%Is. Heating 5 g . 11 wit IS -50.) x. 1 4
in the presence of p)rowallul it tits. At 19A :.NX)* 94VC 5:1 9.
untrActed kctone And 2.6 g. Wrwplu ketont (111) 1%
162-V. x1f -1,- 1 W-1, tile :.4-jiNilF"phe-rY1-
I polyflaor0lic U'lld Cly'll), from NIC011 $"Va.-
11=11*1y"Prolucts "I. UbovC :101), Ile-
IOMP. 224-5'. and lec-ottip. 124 5'. thc aualyws of tile
dcrivs. were Poorly rclurutfucible Steel 1- it, N. lly'll-

M, M..

Me NIC
kjW (IV,
XI It M,

Me

C
IVI)
IctlAttOn 'If 2.2 S. Ill O%Cr I't in ttiOXAtte (addu. of 21 111
Irive mit 1 1.0,13 1:.4-dsxsl,o-
PACXYli soise, dcconip. (front MC0101. IV
1.9 g.) in M nll. Proll with 5 g. '.\a riv. 1.5 g. ak. I V),
Itraling 5 S. 3.S-dimr1Avl-j-.y%-1uprntcnc-
tn~ W-4' (front the tniteliout: kith &.00.
~itb %X1 g. 1,3-bula,ficinc in diumanc 6 Ills. at 15S 62,
gave 2.3 g.
Ic 31
M. )!~~fi% ITIfiCh r%ItS in tAUtOn)Cfi tAt -v viol I
color with Fecla anti yielding a :,4-dixitrOpmY1A';1r4SOnCe,
decomp. 225--6* (from EtOll). Hydrogenation in EttO
over Pt.VAVC tll~
114 -4,5* ifloill pelf. rth1l); 2.4 jml" A
d'vollip. About 2W' (Irulu 'f~
LtUll). cplacculcut J
butAdictic by I in a reaction cooductLd for 6 hirs. at )fill'
tit dr3 Cit. yiekled the dikc(cum (VI), In, Uri 7' itmut
'LUII. HO, ind Zn-IIg a
F Reduction tiv .,u. 11
#171. ill, I krto drTiv
P."l-Aing Ill, I't-Inet 1 :1 it 1 .1111 5 It, In, to 'li't
ZU I' g;- ; . ...... .1.1" '1'1e ~.-t .4 ' .." I*,( It,, b I:rl-
-, '. I". W. S'. I. I N%U. .1:, 11 -~: I I . ..... s ~ ...... It Aml .4
ems,
k"Al. CXI Rearrangement of polyene 6 t 6
Allylic and trienic isormerization of 1.6-hepta en -r-s-
-heptittiten
o1. 1,3.6 -5-ol, and 1,34-Octatri N.
Nazatov It Fi-lwt- 1hjJ- 1107, 1301WO).-
Addli, .4 'A, X, ill NI %ill, 1;1,(l ill thr Gt
reagmif houl V xl'z. 130 g lilllr, atilt fill j. 11
1L'IlCXII ill Vl'il.ll 16, g.%" Aivir uniting tismilight.
b 1,6 1.5140,
4).-- 0114154. Mlich Cm iw ilm"i i%lill .1 trakir of pyrogall'.1
Ilytittigmati,ni in Ftolt o,vr N gave 6m.'y1eeAy1c,tr6m4,
h. 1"12 -1'. '1'1" 1.4,2115. ou'lized by CrO, to Bm-
EX0, 11. 1$5-11' fit. lfil~-7'). The
me"t.l. lite. (6 KA OlAcit 6 hr" ..f or, 70' ~jth 6) nil.
lp\r oil dimn. in i N atm. :1.3 g.
J-ym-7-4. h, 75 W, m if .1.1* 11.9513, hich vrll-
anti 1.4lenwrize, en man-ling and m hythortrnati,mi yirM,i
ih,plyl ak_ 1,,, 78 V'. nk.* 1 12-11) ij-he"ll1wrihapt. in. *ill
110"). Stirring M g. I ill 7.1, ml. Fill) ilh ~'l g %:It-
It,() 12hmat;ul
.,1 21 11. Cu-Zn and further Nfuring for 1'21 firs., fullowvl
by 4 ri-Ilefition% (Solal I I 6L&v~l gave.'Y) g. 1.3,6-Atelwarsen-
b,, &11-741', O.R450, Inch
Ill a 1:0 in it, I..%, lml ."I 11VAT"C'mal-, lij- MICH

N .lo. I.J. .4.
A...... p'll ell"O, to
M.-C11:01CHO ill the al.,%r
1., 07 .4', J~ I fll"11~ ..... . I d, C-L JS. 424S.).
-littlitutill vAith /n-Cu ill if,0-F[.0for a totalof 140hr-t.
113 days) gave, frot'. INI X Oiemol, 11 C. Mjftirne (Crob.
.11,1y . b.. 1;., 7', J' LA:U41. d.' U.N1.5.
.Ill, 11 gt%- ...... .... over Ili. and 144) S.
1,1.ri o,iji,of. 1 .4, l". I "fKJO , 1 0 4111:1
oha 1, 1.~ , 1.ol 1-11 oa ... fills all-I 1. liv.11"Kellate'i
olrer ill to b, Ili 7% It. 14L.' 3'. mil'
I 1 11 lit, I:. ii.,41MI. *1 hr ill, n.5 0 '11.1kcit with 1% 11's0,
I tit if froq. NV;.
Sir to)'. 0 jKlIMP. a, I%Cll .4. a 4111.111 Unit. of
-.1b.wl-- 1'. Jill 1.111' 'Clic in-luct (Ilickru'la little la.
~Jorajlc for I %,,it I .111.1tils clear; its hy, rogenatit"I
N gl'-- -th-NAC.1 ,ska,bimol, Ill 72-3% mV 1.420).
0
.8180, -hich Y111d, oil oxidation Me kexyl ketone,
1, 49-60% It. 170-24, .!,* 1.4152. d:* 0.8171; jemicar-
~1,941nl, in. V. SILIkilIg 1.3.5-,vtatricu-7-ol 45 hirs.
tit N atilt. with 3r~ 11:.14 ). gavc tinich undi-itillable tuattff
.%fill utitno:tni a1C. J., N% Of 4-1 MUAII atilt. Of :,4,16-Oft-drien-
1 -4 (,-tude, Ill -NS in. (front petr. cther).
.hich ycllo- on st-l-ling ind on hydrogenation givins
-IA1101. CXIL 7. SvIlthesis and Iscaterization of
styryl(irinylethynyl ~carl "nol.
'I styrylbutallicaylearithrol,
fury I (winyle thyny 1) cA r binol. and furylbutadlenylearbinal
1~4 1111 24 Alilwugh PhCII(4 ill iCif: CIICILCII,
iumneriir3 isito Ific ptiw,tv thenol irreversibly under Ow
action of Ill ill,- iliphatic attalogs undergir a rr-
11"1 1... .-1. if b. 01 1-iff 11'.
.,T,-I 1.111-111.1k loulvigo oilly Ill.- All,.
'hill. nor 'h.rt W.hl of 'At 9 VhClI -
1~41 I,- Ow ( , .,; ...... I -.Clot I ...... ,.) ,
cil'.clic.c1l, 15 8. Mg. an't 1,41 S. 1-'Ctlr at Wl't
'tit"111clo%ern.0t to a N atilt. If-' "q X. C
CH ('11: ( HPA. 1), 140 1 IAV5. I:. 1.M91.
the pro,llwt 11111,1 he ill h Ill-K. 14,1tiona Ill N 4,
of larger le.ol, to e%r..,Ity J,. ".Pn Ilvdio
li"I'Mott lo"t I't K-1le -7 PA I 'Ate144"01. Ill t3l% S '. "V
.4040. d... 0 111 W, ol,1411"t to If. PA.-M.-shvl ka"Mr. I.,
1:* 0 W%11 (:,f-dtn
NO 2 '). 11'.11ing the ollil .0, 3 It.1
I I
eq. itioitalle cotilit. 3'" 12 ht% at I!;
l-iIIt pylopil"I jav~ 3 g
th 139 41 . mi: I 1.40.1il.11 'vdiodc"'It"d 1'. ph,ft
he.t31carbin,4. br 133 6'. ,J, L!OY21, which "ill) CIO,
AcOH gives Pk hexyl letome. N 12V-31 *. m V 1 .5". d88
O.9W5 (stimicarbasone, tri. 118- 19': 244ixilrophrxylh I-
tons. ut. 137-9') (the authentic ketone was pre~fty
oxidation of the corresponding carbinol, th 135-7', ml?
I M-10 dl* 0.0.186. obtained front Bill anti Cjl,,NfgBr).
i~fie st;;yl a1c. stirr"I with Cu-7n in 11,0 for a total of 151?
days gave a nioderate yield of 7-p"y1-J,J.6-kepWritx--
5-ol. b, 130-1% PiV 1.5970, d.** 1.0210. along with some
31riene; upe of 35-40' give% largetv the latter.
1=1
(P Y) th IM-1111, gj,-
IRMO. "llk+ (141-11 un-W-10 "Y-fal, liquefying on ex.
tx1sure it) air. I lydrogrnatiun of (he tricnol over N gave
the above 7-plicnY145-hept.incil. while the phenylhct)tA.

triene g,tvc I-ektivyMephs'Arr, N*91il-100% nit 1.4970, d:*
0,85M. Heating the triencil with 70% aq. dioutle and
lc~ 11,SO, In a N atilt. I hr. to 4("' pvc sortie 50% 7-
P41" .1.3.5-hr Irien-7-ol, th 142-5% which mild not be
, "It. . 1~411" 'j r4pid oxidation by kit; iinfurdiate by-
l4tion pvc 1" 1311" If I.Al4r'.
-AcOll -phrxvl I.
it" SX11j), which tilt 00, Skirt I
ittcarboxylk acid. isolated as the Al joll. l4ra"ll",
at -110' of 90 g. f Ural in Etto with tile Glis".1 re-
agent front I(X) S. Cll&:CIICiCti and UthigUr gave &I g.
2-INry4(mx*IAyxyi)rarN*oI. th 84-P. nit I-P-MA) fll*
which tudy"ferites within 2 numidis to a L'Ikl:
it. by'llogrilmd'"I liver I't give. 1" -
(W 0 . kit 1.4708. 11110.111918 (Ql."'bt4inVtI (Sol., U0611LIL'I
mild furfural). Stirring tile U11.1til. cattlinol %ith CIA-Zil
gild lljO at itno tenip. to 10-2' for a total of 12 41AVS SAVC
2-fmrvi(buj~jdiexyi)tarbinoI, bs &1-4*, xjP IAWAI, it:*
1.0770, which slowlF polymerizes even with hyrfroquirione,
and on hydrogenation over Pt yields the above bntyl-2-
fury1catbinol. lisimcrizAtions with dil. lljS04 failed as
them ales. reiinified and decoinpd. too resuhly. G.M.K.

I\i
SW01JNA1 L.I.
USSR/Chemistry - Acetylene Derivatives
Apr 52
"Acetylene Derivatives 135. Regrouping of the Allyl System. V. Exchange Reaction of
8,8-dimethylallychloride With Amines, Potassium Cyanide., and Salts of Organic
Acids," I. N. Nazarov, V. N. Rakecheyeva, L. I. Shmolina, Inst of Org Chem, Acad Sci
USSR
"Zhur Obshch Khim" Vol XXII, No 4, pp 611-617
In the Action of 8'8 -dimethyl allyl chloride with diethyl anine and peperidenes an
approx 70% yield of the corresponding teryiary arAnes contg the 8,8-dimethyl
allyl radical is forned. This exchange reaction proceeds nornally and is not accom-
panied by allyl regroupings. The reaction of the above with KCN and HCOONa is analogous,
22LT37

't_W1V"qW#k -".Tow

t4pthesfs'of POIYC.YCUC Compounds TCM44-16 4to,"i
3
,
XXI., condengadon
saturate cy
aton s w(th:
9~of Merold k
hydrocenAte akeletavA.
cyclapentanophergan a, and Ch elsO.'
-B
L.
.14. Set., 1953, 131191. ,ft
Oh
XX Stemocheinishy of
polycycllc comnomounds. 2. ~ Seinlest of cis- andlraffs-t-
methylcyclobexane- and -4-cyctahexcut~~1.2-dks--b4.titte
aci4s, and theirlianiformittloas. LN-Na=ro~aud-V.F.
Ruchttov.- 'Ibid. 1954.~ ?A&lk,~..

XMIT. _:Synthtsht of. sulfur mmatogs of MeWdsl'ca do
RIPW
by d(enecoudenvation
eydic dienes.. 1. N. rqttzarav - 1. A. -Gurvkh,.mTcl A I
Kazattsova..'Ibid. 1953, 0116~76."&e C.A. 49,
XXIV. concleasatlea..of
Ik Nalades. VN..
-hydioladene with ax-miati"ted c#
Nazarov.-Und V. S. Burmistrova. , Ibid.,
-19S4, -46~~
See C.A. 49,'2457f. Synthei~-. of I clk comp"ads
*
xV
. re-.
related to sterolds. TAV. Synthe
Compounds
lated to ~ estrone by the rmeth6d of diene wude~%446

otlytrevskil., Ibid. -1953"977.4tS
N. Nazarw and 1. L. K
&5,C.A. ~91245M. Ut-

MIN
11,10NOWN

cor"Pouncis re te to steroids. 1""%W; w iii~ Ai~i Y solidifi;a and in OW27P. At~'~iXl
'
Condensation of I-vinyt-9-mothyl-Al-s-helitbydiOa uct wai probably a mist. of 2 stercoisomors wbfc
~ differ, in",

;
hibah-na with a,&-tmsawated cycil,11c
k; ~taness;. Syn. '
ve
t
t
id k
t
ith
h
d
Pon Hydrogenation of the ethynyl-Ic. over.
~e

tero
s
s a
e
ones w
i
rogens Clans of
y C Ira
0 1
pd
Y gave
cyclopeatartaphenanthrene and chryu -1- 1101, b, 91-3'. n1j; 1.5215; thi%!M g.) beated w4th-23-g.

,
L. 1. Shrrionina and T li: o~,A
14-,P4
h -
! -
r
N powd. KHS04 0.5 hr. at 120-40 /100 mm., then disid-ir:
.
1
ej
1.
r
-
auk SJ,S.R..,
-
!A *acuo, gave 75%
im.
n
uk 103, 1074-90; cf. C.A. 40, 1082d.- b, ",4-4.,5*, nV 1.62ZOI which, warmed with matele an..
Heating stcroidal k9cones rriO- HCi or treatment with Pt In, hydrWe in C*Ua 3 firs. In a sealed tube at IOU' gave
AcOH serves to shift the double bond from the !9,11- to the'
8,9-position. Heating 5829 g. 1-methyt-1pclohexcn41-oUe* citrucankitnhydrifleina
with 75 g. (CH: CRxN and 2.5 g. EtjNPh a an atitoclave 2 shifflar condensation (24 tirs. at room temp. nnd 7 his.-iit
bra. at 245-W' ve 543 g. 1L:ncbxiVd ketane and -20-5 g.
45 100*) gave 30%-xitixod anhydrides, in, 133-46', front v-1tich
% - WftS iSQ1AtCd the Mom [LbUndatit fCnn,
bi, 83-4*. tt~,, t.6060 docomp. 2251 (rf, auhydride, in.
1
Nudenberg and Butz, CA. 37, 53991% hydrogenated over 1
(from hexane); the other isomer, presumably the L4
Pt in EtOH to Ale analog, u-Ps not puri4ed, if the coutleusatiun is ittil 2
lij 84--0*, YjV 1.4950 (2.4-dixisrofheisy1hydrazon', In.' Mg.- days at, room temp.. an utm-Aved mixt. of Isomers IS'
60*). 1 (115 g.) in Etjo was ch Had to -70o . satd. with
nver I hr
CM
then treated with
sus
en
ion
f th f - med. ffydrolysis of the ini) ed anhydii-46% (in 13440)
'
-s
,
..
e rcae-
a
o
p
350 ml. BuCNI.!.OH
tlmi--mt~ct. ofj~A-
I L ELQ~
!~!n by 50% AcOH. finally at 105% gave the free acid,
in ~ 1.59-'
Heating-
-
_
_
whil6 the C,112 stream was iii-ainia~ined 13 bra. at -70' after th6 ac!d mixt. with Raney Ni in C4HI 17 lirs. at SCO- 80% 3
the adda. wai complete, aud. after an overnight interim, 8 firs; at 380-400', and 3.3 tus. tit 00-101 gave a low yktd Qf-
hrs. %t"- 6*; after treatment with IIA the org. layer gave in. 120-V; picratc, in. 132q. -co&

bi., 08-9% l
densationof the vinyl cmpd. (10 4.) Ath -00 g. I-methy14-
-
1.1 c . Caddis and D.. C.A. 41, 1-629b), al,,o formed cyclopcnteit~.
~nrre-(), hrq. at 150* tit an ampul gavd w,o -
86% yij;hl (b: 97-D', I.A24.5) when C,H.- wa' Priss&'l Mixed isonters of. tetiacyclk ketont:4, 10.14-dhnetxW~2,9.

into a olii of .18 g. No in I I. liquid N11. 5i(1Mlt;111cOu31Y
d
4
i e j~r 5-jr
Cardost rad 11-1 te, ni - M-0 and 163-4', hydrageruited,
-
ucT.Over
wit
k 1.13 g. 1. Hydrogenation uf die Pro
tredtb Over VA to the c"Wre-Spoudiuk dihydrr "alogs, tn. 114~15
I't gave &'-V. (111) and 12&-0' (M. tesD.. In which the 0,11;double bard

7,
pfi~

relliMiltAl. Furtlux hydr
ogenation in AcOlL over PtO, of ye1cpen ten-B-one- -finder; C I LIV-_
Oj- 10 firs at- U- 111-all an-lp
the imitner, in. 114-mli',gave C1111v.0. tkt~satd, analug, which gave a imixt, of i5oillers xvillch yiemicti 1 3 g.
Wah t1w Ist instalic" of hydrogenation of the 9, 1 Wink fit tbis.' (m. 1,13-4') and I X lo-inchink isome ('. --() ("n., l-!2-:.r)
group. Rulluxing III with AcClll-~oncd. IICI in; NIC11h -10 Aitichiai!-d to
Airs. gave Eta komcr, in, 52-0, which ivas hkintilied as V, yieli cartionyl durivs. -Hydrophation at " bF., lligh-';klting
which had been de-Alied utrli~r ( CA. 49. 1086c). V could form over NO, in RAM gave the dihydiv duiu_~, at, 122-3%.
not be hydrogenated furtlici Muting IV with AcOll.11CI with,rejidual 8,9-dwuble bosid, dt-wribed carlier (CaL 49,
us abode gave its Loiller (Vl;, It, 92-3'. which ~%Ils'lkptle` 10F.3i); tilt: latter' wits not Isunieflud by boMuz with Ac-
scribcd carlicr (cf, lot. cit.). Sbakilli; IV ~Iitlt 11101 lintler 011-11121, llor totild thia kftone,bc
),firopitatioll .01 V11 Save the cotrtr~,liondfjig
In'r. 0 Una 0j, in. 1201-8,; which doer. tv)r Watiterize -with 7~:
AcOH nor hydrogenate furtheir. ~Ho%vever,trt--itnit.~iti~fVll.-~
with Iodine In sq. -,NfcOH in the pmscllce of 90H, pvt a-'_
~O 0=0, dilioda, deriv4 in.- 12&-'J*i *hHe KWiatr re'llictioll, Of NIX
...with N,Hj.HjtD in 0(CIfiC1iio0H)j gave 81% hydrcx~irbda
Me (VIU),.bs L5&P,'dehydrbgeuated under
C~Htg in t' be, prLmence of Td'~C in 6 firs. at 3T-01
Diels A~4roc4rboa (m), m. 119-219 (Cfr,(.VO.3)
146-4"), which ivas isoNted-aftcr chrornatographi purifica-,
(VI) tiononAli%. :ThusYi71hzLsthe'!itwiv '6 'gurationcif,
nii
tu
11 in AcOH gav c 50% yield V1. neating 6 if. vinylinelbyle the cyclopentape ring relative to tht in nucl S. - Heating-
hexabydronaphthalcrie (above). with, 2 hilethyl-1- vin-~lineth~lbexahydronaphthilen6 10~g. with D

"V
10 hrs. at 170' under C0,1pive mation. of it keto-eniol.form; -this 6ccuirs
at room - t th
1,43% mixed isomeric ketones (X), front which were isalat-d Pg'--- Of Pipeittilste very readily In the
.118-10*,and M",
2 g. KA, mi. MG-30.5% 0.0 g. isomer (XB), m 1 1314", gives a violet color with KL ad L assigmed-the
0.4 g. isomer (KC), In. 133--3.5% the stroctures of )W and XC struCture XIV: the.odginal dion't does not give this color .
,have riot been established. However, hydrogenation over: tCst- XM. Steraocb)~nistiyofpoycyclicc7,jmpoards. ~-Z.':.
Pt0j gave the dihydro derivs., tit. 119-21M M), 114-15*.-
and 132-3'. resp. X1 refluxed with AcOll-RCI In Meph- Ate
gave XD, in. 137-8% described earlier (C.A. 49, 1085e);
the same isomerization took place in AcOlf in contact*
*with PtO2 and If. XB heated with HCI-AcOlf as above
gave an isomer, in. 121-1.V, whose structure -was n Iot Me Me
detd.; XC failed to isomerize under these c Witi-af.i
mi
Treatment of XI with MeMgBr. finally in bo Ing CIli,,
gave the t0racyclic alc~ (XII), im. 158-0* (from MeOH),
dehydrated Over KtIS04 in xylene to a crude product, which
H
after chromatographic treatment gave a low yield of chry$- - if.
ene, m. 243-0*; normally the produet expected in this (VIU). (XA) %
cast would have Incen.4-thethyleltrysene. Heating the vinyl-
methy1hexahydronapistbalene (-.I S.)with lffg.2-methyl-2- me
cyclohexenotie, 10 his. at 170* under CO. gave 1.7 Z. mixed off
isoine)ic ketones, CIjIfu0 (XM), Liam 137-9% iM I.M20;
sent icarbazone, in. 237-7.5*. XM could not be crystd. or
1e
sepd. into individual stereoisomers. Similar reaction Wit Is 11
p-benzoquinaue gave after 3 hrs- tit 66' 3015 10-methyl-
0, cf Nto
in. !)'-'1 9' ( ude),
in. 108-18" (front hICOU), with evidence of change of the oil
Ivy
substance on inelting; the compil. failed to yield a seml-
_.carbazone or dinitroplieny1hydrazone. (cf. Gaddis and Butz,
C_4 41, 4789d). Similar cordensation with 1.3-dirnethyl- (XII) XV)
I firs. at 100* under
1-cyclopentene-4,5-dione in dioxane L -Semi,ster of Cis- and and -4-
a olkyl-2,9-widdster4dicu-15 16-
Me& ve 30% e dith"etic-1kilietubor
W (from MOM, ifte wide ticids guid tbi. sform
dion in. I(X) in. risaii; Is Nazarov iuW V. F. lZuelies-,tv. ibid. 19!41.1
caused by ready L"sterizatior.sit elevated temp. with for- 63-70. cf. CA 48, 510ge','Bachmatut, of al., C.A. as

-z-
43,551i 38, OT; 46, 10189.--:-Refluxing 25 C. cix-l-rnethyl-4. r xylic acid (Iva), J
j4a;`60MA4~yClaheiiUii 44'60 m-
1
1;
~1
cyclobuxene-1.2-dicarboxylic anhydride (1) 6 hrs. In .75 mi. (from petr. ether), which also formed onlydrolenai~
0
6
5
abq. MeOll gave after evapti. and treatment with petr. ether tionoftlie4-cyclcbexeiteanalog~ Tolog.llw"addedM
'
12.2 g. (addid. 1.3 g. obtained by chilling the mother liquor) so
mi. (COCI),. and the mixt. allowed to stand 1 hr.-, heated 0
Ci 1-ni,,Ihyl-2-carboi?zehoxy-4-cycloh=ene-l-carboxylk acid hr. to 40-~r'% evapd., and distd.. gave 10.6 g. cis-;1--qtdh
,d
(11), in. The liquid reaction product faild to 2-carbometho:CY-4-CYilOhexrxe-l-ccrboxyi chkride (V). , b1,
crystallize (7,V 1.4875) and on attempted d!3tn. gove 1;
r
,i
i
h
1
N
OH
i
h
l
ld
i 99-9,5*, gy 1.4905. .9imilarly 6.7 9 Ul gave 5.7 g. cs';-Z-
1- hk
VI
4
s-1-met
oly.,;
s v.
t
a
c.
a
gave- c
-4-cyc
xen
hyd. C-
b
y
8*
lic acid
2-dicarbox
1
m
167
The latter (4
) re- 6
1h -1
)
me Y1 -'ca ire
(
Si
il
l
. -
.
yl
-g.
,
,
-
fluxed 2 firs. in 100 ml. Qbs. MeOll with 2.6 ml. coned- ar
m
y
bss
rbortdkvx>~'- *IhUxcise-2-carbexvfic~ &vM- gave -13.3
ed
IIISOg, evapd. it; vaeuo to 25 mi., treated with HxOiextd.
' correspondIng,aM-chkri&'(VU), bj~j QEV-7%~~S~" I.4W5.
with UtI0 and the ext. evapd.
ve a partly cryst. product
n
t1r,
lt
t r
et tie
t
ith
t
olid (2
4
id
ti
l
) IVa simHarly gave the correspoWing cc 141 ckjoride (VIU). bi
0
:ab
HGO was
l
i
10 j
2
V
a
inci
w
.
.
oil
rt
s
was
en
ca
pe
r;
g. .
s.
u
n,
,
g.)
12.5% nY 1.4760.
11_
(
with II, while the liquid residue gave an distil. L2 9. di- added with cooling to 2.1 g, CHjNj in EW, allowed to!
I
i
i
k
Are b, 104-~B% en
dt
e, ta
apd. and :the res
stand 24 hirs., the solvent e%,
00 1,4723. 1 (5 g.) refluxed I hr. with 1.35 g. Na in 40 mi.
u up in 45 ml.-cold abs. MeOH, treated with 0 F;nh
li
..b
I
:;. Mk;QIj g;tyQ after evapu.. soln, InNAIartilacidificati.00, I17asb
Ag,O and,refluxed 6,hrs.' filtered, the filtrate
with YICI, followed by extn. with Et:O, 5.2 jr. cis-j-tndhyj. NfeOH coacd-in racuo Lit the residite-refluxed:4 i~s.;
1-carboj,t,ii'ioxv-[-c>,clohrxere-2-carboxylic acia, a viscous oil,, 44th 7 mL40% KOH LiLnd 5 mi. TvIeDE11 yielded after;
'
.01 LTS*~O; Ilk was also fortned in 1.8-g. yield when 2 g.
"
! extti. with 134-0. WW1, 9. cis-l-fffelhYI-2-i
acidification and
;
- t-ttictliyl-4-cyclohexetic-1,2-dicarboxylate was re-
Me C;
di carbdxy4-cycIoAIexrnc-1-acdic acid, m. 141.-3* (from Me&CO-
III x ri :1 lirs. with 0.56 g. KOH, 10 nil. H,0, and 30 ml.1
I " petr.ether). Similarly 2.tg..Vl gave CM.g. cis-I-Melhyl-
it: there %vaq also forined'O.03 g. III. which was sefid.-
MCC)
- 2-CarboxYgdoheiant-1-acelic acid, m. 174-5* which wash
ane over Pt gave
by freeLing. livilrogenation. 6f 11 ill diox also obtained by hydrogenation of the maltd. arialog over,.
acid (111), Fd In MPOH.- Similarly 5 9. VU gaVe 607~
In. 09-70' (front pctr. ether), Rcfluxing 3 g. cis-I-mdhyl- Car6oxy4-cyclokezene-1-acelik- acid, m. 162-6 (even after
ml. abs.
cyclohexane-1,2-carboxylic anhydride (IV) in 20 repeated Mstn- from various solvent h d of
2
.
NlcOH5hrs.gava0,8g. UI. Toawarm,;,cL1n.of1g.Na 1 -2-car
the product over lid in MeOR gave . -2-
'
:
f
d
in 2.5 mi. abs. McOll was added 3.5 g. LV and the tnixt.

6
i
1
e
a o
, an
,g.lohexanc -acclic creid, in. 164-5
c
.aj~'jl -7*; since the original add chloride
175
-
j-
9% c
..refluxed 3 hrs., gave, after usual treatment, 1 1 . ! . I - - -

Wl" mull in,
-1.1~~N,11141111 1111p% miftul
Etj0, followLA by 0.5 fir., ut 0* - gavc 0,0 C. car duijg It
t
-andide rvattd with
VII guvc tile aav the
aN0
104-5'~ To GA q. 11 lit Ht,0 wag ailded 0.0 a. powd.-Pelli
5i (f
tilt! Inixt. Ivil'i livatv(I until -will, took -wits thm
place mid
oxy
treated %vith -1 9. PhNlli, then roliaxed 0.5 lair , after diln'.
%viiii If.,O aml supli. of tile org. layer, there 'was obtaitiard to -3 It I It 11 RMIV reh),1:11141 6A hi, i, dild,
0.35 g. I - mr1hyl - I --yclahexena - 1,? -dicarboxylic acid N- with 10 sul, It frecil of iv0f1 in vacua, and acidified to
phenylitaide, tit. 103-1 (fram M-0-pa:tr. ether); the zaine give 770/a sidd. analog of X11, m. 91-3', idimlical with the
product formed from ris-l-nietliyl-l-c;trboiiiethoxy-4-cyclo-. above desceilu.,I]i specimen; refluxiog 9 '4 g. dl-Nft~ lram-l-
lwxci)e-2-e,trIjo%:YIic acid after tile sitaiLtr tarr-itinLin; the Inethyleyelollexil"e-l.2-dic;irbox~taic 10 hirs-yith 2.8 g.
gaittv prokitta furnied from V or VII oil trimatinent with ML lit 42 iral. A 1:0 and . 115 tail. WOR gave after u%ual -
PhNI12 iii Ei:0. "'I'm the anilide X was refluxed ill Lt.o treatme-at M% same product. lit. !j2-3.,)*. - Neflaxing 4 g.
wit It 110cl, I 11r. aud that arg. layer was sepal., washed with X1 with 15 Ild, NfeOli 4 lirs. gave, after evalin,and :scaln. lit
10",I) Na.,M, m:1 smapd.. tile %-ame pheuvIlmide wns agaiii petr- 0111ar followed- by Aariding for ti(tveral ~Jays, 01 g.'
obtaiiied; tit, Lam- :ako formed oil similar treatment of the XII, 111--73-0', und 1.2 g. imneric lrCnj-1-mdAy14-catbum
tufflide Of ~'H. TrCatillent of 1 8. 111 with 1,5 g". PCIS, acid (XIV), in,* 50-8'; the:
fuilowed by Ilemilloilt Ivith PIINHJ, gave 0.95 g. I-nle1hyl. latter. Utter tile usual. tmAtrimit gave the ciarrespandhig
cyetolim) ae- I,!-dicarboxylif acid N-phenyUmide, Ili. 109-20a at-lit"de. in. 112-1-Pi while hydragenatiaa~ of XIV. over Pat
(fr~m Eta.() ether), (lie -,title product being u1so ub~ gave the liquid said. unalug which yiddpd~ after the usual
azy-
inm~ Similar la-Catillent of IVa, or from reaction of treattrient, the corresponding ifans-k ittillyt-2-4atrbalnth
VIINII~ kith V1 or VIII. Refluxiiig 3.5 g, tralls-1-l1lellityl-4- 6yclalic,vane- 1--carboxylic acid~allilidc (XV). In.-08-9, (from
atillYtiridt! (XI) Ivith I g. %,a Et-.0-par. ether). XII treated lit WIG' IvIth (600)~, kt;i)t
ill :10 ml. all.,. MeOll I hr. gaveaftermilm., dilta. with 11.0. 1 l1r.at room temp. tual 0.5 hr.at .10'i hnivi: ti
and GOC/a "lag acid chloride (XVI), Ili 101-56, W.' 1.498i).~ which with'
11'.id (X11), tit. 7.1-5' (froiat petr. PIINU[a lit Ft.~O gave tile andide. lit. 133-4'. Shnikir
1411cr). This (0.5, is,,) ill 1-'t..O ~Vas treatt-d %vith 0.75 g. treatmesit of OIL: tatd. aindut, of-XII Mill (COCI)i gave tile

corresponding acid chloride CXM), b,., OG-7 OR 1.477
which with PhNIM gave the anilide, ra~ 104-6', Identical 170-1 .-Simim wtitia -e
hydroindene- and Z8 K. Infier 4,15 firs. at 170 gave M g.
.with the above described specimen. XV1_ treated with mixed isom6ic product, which was rApd. into the low-'
C113j\T, as described above gave 85.5% melting VI, M. 1%-9", hnd the high-melting isorrser, - m.
ei-rboxy-4--cyclolsexene-i-ize,olic acid. tn. 205-6* (from MeCO). 172-3' (from MOH). - 1 (1.5 z.) and 13 C. 2-methyl-M-1.
Similarly, XV11 gave trans-2-ineiltyl-2-carboxycwlok=ge-l-- thiapymu-4-oiie 1,1-dioxide, similarly heated 6 hrs,- at
acetic: cic"c" tit. 175-7' (GOL70 yield); pure product, m. 176-7*1 143-5% gave 2 g. crude- product, m. about 2DD*, which
(train Me.CO-petr. ether), is idso obtained by hydrogena- after chromatography on A1:01 gave 1.7 g. VU-4i., 215-

tion of the unsatd. analog over Pd inMeOll, Inthisscries 4,
164"1 which. Is unaffected by refluxing 0.25 hr_~vrith,McOH
the trans lsomcrs give stable atillides and enter the Arndt- Coats. 0. 1 % Na, but which fornts a tar after 2 hirs. relluxing.
Eistert reaction more readily than do the cis anallop. Heating 1.2 g. -1-irinyl-6-methoxy-3,"ihydronaptithgtfene"
I
=11. Synthesis of sulfur analogs of steroidal compounds -with I z
. 11 simiWly Ck hrs. at 170-5' gave about I g. lirod-
by diene condensation of c7cUe -r-keto sulfories with bl- uct. which was seN. W4 0.2 g. starting materW a-d.
cyclic dieneg. 1. N. Namrov, 1. A. Gurvich, and A. 1,. about 0.8 g. VIII, rn. 221-'1.5* (from Cille).- -The low--
Knznet5ova. Ibid. 1953, 1091-9-Heating 4.8 g. I-vinyl- melting isomer of HI hydrogenated in dioxane over Pd-.
(1) and 4.3 - g. CaCO$ gave the 2,34hydro dcriv. (IX) of W, m.- 240-l',
2,5-(Iiinciltyl-411-1-thiap)-mu-4-on4~ 1,1-dioxide (11) in di-~
- which could not bithydrogettated.- further;; sitnilar'hydro- -
then 7
.xane with 0.1,15 g. pyrogillol under N 6 brs. at 170*, _
6
iatioti-of-the highwatelting M gave the otherficimer of
lies. at 170' oit the next day, gave 6.6 g. crude tetracyclic IX
m. 2.11-2' (from EtOH). Hydrogenation of VII gave
,
dikcto sulfone, which after fractional crystn. from MeOH the "',3-dihydro dcrIv..(X), m. 216-16.50 (fron MCOH),
form
a"'i rhroriutography on AI%03 gave 3 g. low-melting
which was unchaned oa short boiling with a dil. soln. of
(111). Ill. 212-13*, atid high-mciting isomer, m. 2254*. Na in Nft:OH- Wt which. formed a tar after 2 firs. reflux.
Shni -htr rcacticiti of I g. 1-viliyl-g-mctllyl-A',#-Iiex:tli)-drry- The hydrogenation could be nitti,either in hfeCO or diox-
naphth"IC110 and 0.99 g. IT gave 1.2 g. mixed lsomers, &UPd. ane (the latter at 60 atm. At 100-~20*), The low-melting
by treatment with RtOll into coutfid. IV, ni. Isomer of VI was hydrogenated in dioxatie over I'd to the
ficatingO.75S. 2,3,7,8-tt:trahydro deriv. (XI), tn. 159-60* (from EtOH).
I -v lit y 141.8-d hiv: t hy 1-W-lic-ahyd ro-5-indenotic and 0.75 g. X hydrogenatcd in AcOll over PtO. and H,P
tell; then chro-
'
11 Si lit the 'prcsence oi pyTogallol lit dioxatic 0 tits.
-1y XII, -in. 245-6* (front,- Uf4),
matogripliccl on Ali0i, gave
at NO i-,. gt,ve aLout 0.25 g. high-inelting V. m. 235-6* coatg. 0.5 mole C4114, along with. Its diaretate. -,Heating
(from EtOll and Ntc.-CO), and the low-meltin i3omer, tn. XII with AcCI-AcOH 1.5hrsat 110* yielded the diacetate in

~'. , - P li !I'll" ~~ -:~
~-W,t
~

Al, ly,#"zk NAOd I/
,Into 9.2 S. Na In 350 nil. liquid Nif, viras passed'Cift, 3:1
furs. at 20 I./hr. and the mixt. was then treatedi witW 'MeNPh 10 firs-at 170* Ove 24 C. Iserriers of
continued passage of CHv. with 33 g. 3,Mfinethyl-41- i triff tot 41- B- a #rcn'r &x krys a-l" k r, 15-ar. e j1-4, is 1 147~-504,~
tetrahydroindan-1-oue In 7b nil. Et&O, after which the mfxt. I *IN t.5415, dts 1.056. which on standing deposited OM g.;*'
was treated with Czffl I hr. longer end kept In the cold sdM isatner, M. 139--42*. Hydrogenation C4 the mixed,
overmight; the NHs w2s; evapd. and the residue was treated., isomers over Pt in diorane gave mixed iscm--: d 7 1 L_'
lrjffrdj~t
with 100 ml. EtO. 35 g. NHACI, and 150 mi. -HrO, the rug. '6-- =n
ilayer yielded 87.4% 1.5m. , -,ffd_=7g .. g. _1w1i1b18'g, C'~raoNuc
anhydride in 1 4 0 days at room temp. ge-;e 3.6 g-;
dan-l-ol, b, 88-W*, 0A I.W70, which was P-rfl-lly hydro-
genated to the pre-kyusly described I-vinyl analog (bs.s Mixed isomers 11 and M, ba.oa 144--5'. n9 1.53 10, A:3 1.137;
-hydrolysis of this pimduct: with a1c, NaOH and 11,017c, AcOF.
88-00% ag 1.6045; d. CA. 46, 2Mf). This (3 g.) and
_b
.1.5 g. powd. KH504 heated 10 min. to 120* at 96 mm., gave an uncrystai , Ic mixf. of acids. Keeping 2 k' - 2
and I Up-besizoquinene in 20 mi, d1ozane in sealed tulie
cooled and extd. with EtsO gave 2.2 g. 3.8-dimdkyl;1-; under 24 hirs. at rom temp., followed bk 3 hrs.'at eo~
vinyl-al-Lkirahydroindeu (1), bi.s 60-2% nV 1.5070
Heating 5 g. I with 10 g. 1-cyclopentetione in sealed ntnpui ;save 1.8 it. yellowish
under CO, 13 bra. at 130' gave 3 S. mixed isomeric 7 10- irsen-15,Va-dio?w, m. 166-4.5* (from AreOH';
di=lhyl-B-notcardasura-2-44ien-16-offes, viscous oil, j~ W Ph4sylAYdr=one, M. 213-16% This hYdrogenatrAv fr. df-'
132-40, d:* 1.048, nV 1.5400;- 2 g. of this product hydrG- oxazit' over Pt gave 7,10-ditridhyi-B-morcardochrysan-l-,.d
ce of Pt, absorbed Va-t(ime, in, 140.5-41* (from Etro). XXV. Sysithesii
g nated in dioxane in the presen 210 nd.
hr . -dimdhy(-B-
Mn 4 and gave 1.5 g. mixed isomas of 7.10 hie H
norcardoster-9-cri,15-one, bo.a 123-6% a9 1.52,88, du 1.043.
0
Heating4 g. I with4,8g. 1-methyl-t-cyclopenten-5-meuii4er' 0 -C
- in ampul 10 hrs. at 170* gave 1.5 g. mixed I \
CO. isomers of .0 1
7,10,1"fimdhyl-B-norcafdostera-2,9-dk?i~-16-ont, ba'Ce 133- Afe 1 ;0:
8'. ni? I.M. d9s LOU, whic! hydrogenated in dioxane. -CO
cover Pt catalyst to mixed isomers of 7,10,Z44rimdAy1-B_' me
norcardorter-9-en-15-one, bem 140-2% nV L5280, dze 1,019.
Heating 5 g. I with 50 g. I-cyclohexcunnc.as above 10 hirs. -
_I&ditndA_ -X~
at 170* gave 3 g. isomers of 7, W- cardKhrysa. e H Me
29-die;i-15-oxe, bom nV 1.5375i dto
which hydrogenated in dioxane over Pt to mixed isomers of
7,10-dimelkyl-B-noreardochrysan-9-es-15-one; N..,j 132-4.5* of compounds. related to Utrone by the method of diene
t%VIMI5,dir*I.0433. Heating 4 g. I with 45 g. 2-methyl- condensation, I. N. Nazarov and 1. L. Kotlyarevskil.
2-cydohexen-I.-bnt in sealed ampul in, t.bC presence of 0.5 a. 1W. J953. 1100,-JO.-To 14o g. 2-methozy-619#7,8-tetra.
_7

AF
z
I ydronaphthah tion of 2-CIIIIJOH) ja 900
ml. AcOH was added over 6 brs. at 3' 140 g. CrOx in 400~ml.! in an ampid-jaw-e, about 30 o condensation prodi Let bat
AcOH and 60 mi. H20. the Mass. coned. in cacuo the follow-, 210-W. hich rielded 15 g. (frcim-. 3 g. U) *cam Pd."
(M). m. 142* Id. ad Ed,,. C.A. 33, M01,
ing day at 40-50*, and the residue dild. with 500 mi, HO ctake), and 0.8 c. 1 __
fand left overnight, yielding 90 g. 6-mdAoxy-j,2,3,j.4eta-' whO give a wrong stru IV, bo, 910- o-
1 hydro-1-ozonaphAakne (1); the Et%O ext. of the solo. gave: Hydrogeaaflock of III im MeOH ever Pd 30 brS. a~60' gave 2
V, m. .160--60.3'.=d _17*. ,r - W~
15 g. starting material and 20 g. mcce 1, for a total yield of CU 116 reaziri .
70.5% Omed on reacted starting material); pure I b, 130-50, with MeMgI and heating the isolated product, after t1m;
m.78-9*. A.oln. of EtNfgBr (from 95 g. EtBr) in 200 mi, usual aq. HCA treatment, to, 180-90' i,xh KHSO, gave un-~'..
Et..O was satd. wM oil, B. 190-202-JO.t X 10-1 turn., on. 88' (after rub
h 20 1. Cill, at 2.5 atm. and -70", them this beated-with,SeA hrs. at 300' 1bing);.'..
gave a low yielt of Vt:,
heated to 10%atinigl I hr., cooled to -70*.and_tbP__HCI_.
t
-wLittscf.theautocl,,ivctrcitedu Ura -twaddsid,1-1,1264%- IV
ChfgBr which pptcl. on thr I NO 1"a; WX treatt&~--
-50' with 20 g. I In dry IstePh, the mixt, stirred 0,25-hr.' a - tedvitfi KHSO t:
at -70% warmed to 10', and stirred I hr., then 0,5 hr. at ,sabovew! Met(glandtfieproihict-hea
in Vacgo at 170' gave am-bit, b~,, IBL~-W* which, hcateA
201-
~,2- VIi Her ctu~amatogra yoriAlMijeductiomot.-
zation (cf. Bachmann an ernerda A. 42
_1 - '- - the eluted product with Na-EtOe, and licating-with
Hydrogenation of a frish sample over Pd-CaC(I~ V~ an 11 W-1- 0-95 1 .
I gave 75% 1 hr' 'at 180" 9a c a' 18 ' which, heatedi~ith'
--30% gave. P_ low -yield of a solid prcd~d
bl., 118-24 , n~l 1.58651 makic acid adduct. in. Be 7 hrs. at 320..
CIIHItO, m. -136-6.5*. Hydrogenation of VI over ~ Pt
It heatf-A with 2-cyclopenten-l-one 17 hrs. at 170* ROM "V. 1111VIA itAMIlt nt MIM.A If. 1401 (UTTI- 1`~

X&ZAROV, I.N.; ZAVYALOV, S.I.; BURMISTROVA, M.S.; GURVICH. 1.A.;
SHMONINA, L.1.
Synthesis of steroid compounds and related substances. Part 34.
9-methyl-1,6-diketo-IN6 -octahdronaphthalene. Zhur.ob.khim. 26
no.2:441-444 F '56. (MLEA 9:8)
1. Institut organIcheskoy khimit Akademii nauk SSSR.
(Naphthalene)

-
a
tidi
t
d c0
apo urtais and
XXW
them
t4d
1; A.-OurvieWan(I iW IS.-Clinmouloa-

13947c CA
.

S~WNINA, L. I.
Stmonina, L. I., Cherdyntsev, V. V., Koshkarova, L, L., Ostanenko, V. F. -
T-he Examination of the Neutron Flow of the Earth's Crust.
The Sixth Session of the Committee for Deterzaining the Absolute Age of
Geologic Formations at the Department of Geologic-Geographical Sciences
(OGGN) of the USSR Academy of Sciences at Sverdlovsk in May 1957
T

-P-7 :1
A K 10 :3

TITLE: T'n t; v c. s t i.! a t -i o i Io i.* c -i c.---. 1 Ad d ition ',.--ec~,ani,-:~i of idy-
halides Jompounds to Vinyl Acctate(Issledovaniye radika--'Ino.~ro
khaniz.-.ria prisoyedineniya poligaloidnykh soyedineniy k vinilatso-
tatu)
PEHIODICAL: Izvestiy,, A': SSSFGtde1eniye Nauk, 1958,
lir 1 67 ~U5Ljd)
A 13 STRA C T Up to now t-',,e inter~.cticn bet.cei- polyhalo-id-i-e-thane and tri-
chlorosilane and various 01~~-,-,~:lis and si.2ple vinyl esters was in-
Ves-L--.'::.teu --ost precisely. 'This was done to a smaller extent,
however, w t;, th~ r.--..uctio-,i of the interaction of tile atrove
:.ientioned corc,)oands ,-kith vinyl estern. There exists only
one Americ m -)atc.-It (1,1)46, rcfercnce 7) ii-4~ihich the interaction
bet-.~eea -,ie carbon t-, . .chloride and vir.Y1 acetate is describe(~.
The polarizaticn prodacts of theeneral formula, CC13 (CH2CHOCOC.13~
C1, were obtained as re3ult, where n = 1 .... 3. In the Dresent
paper the -authors report on the invefA.'.-ition of the iiiteraction
~etweeil Ol C11C13, SiC14, S"'C13 and %j2H5Si!1C12 and viryl
er the inflaence cf beri-iolieroxid.e. It was 'ound
acetate und
tiiat the of the e,;ui:.io1eca1ar acdition coa;)oand of GC1z,
Card 1/2 to vinlul acetate is incre--sed cor-es-,)ondin.-,! to tile greater quan-

The invusti;,ation of the Hadical Addition o.-L' Polyhalides 62-1-11/2~-,
CoLipounds to Vinyl Acetate
tity Of CC14. The yield of' the product -,.,as iLij)roved and its
constants were defined exactly. For the first time equiiaolecular
addition com,,jounds were obtained of SiIIC13 and C2H5SiHC12
to the vinyl acetate. Hcre SiCl, does not enter interaction
Unce of benzoi). peroxide). After
with vinyl acetate (in the prcs~!
the interaction between CHCl and vinyl acetate has taken place
a i.,,ix,,.ure of th,~products of iow-;:,,olecular polymerizat"ion is for-
saed. There are 2 tables, 7 1-cferences, 3 of which are ~;lavic.
ASSOC IATIO N: Institute of Or,~anic Che..-,istry iLicni 1i. D. Zelinskiy, AS JSSP
(In-~itut or_-,nicheskoy klii:!!ii i..,. 11. Zelinsko-o Akade:.iii
nau:, 6:3z,10
Sdii",ITTED: July 1), 1-156
AVAILA.ILL'. Librdri 0; cor1rress
1. Halides-Chenj-cal reactions 2. Vinyl acetete-Chemical reactions
Card 2,12

AUTHOIRS: Shostakovskiy, F. , Sh--OL~4_na. L. 1. 0'2-1-23/29
T IT L-"' Or., the -.question of thc Production )f
(K voll!'OSU o _,oluehenii 1-,~~-Isakhlorbatadiyena)
PzRIODICAL: I7vestiya AMI Otdeleniye "hilaic;heskikh 1lauk, 1958
11'r 1, pp. 109 - I'll
A 3 S'Ll it A CIE 11exachlorobuta-ciene belon,,s to the best solvents for many
organic substances. There are many papers in literature des-
cribing the various kinds of the synthesis of hexachlorobutadi-
ene. There is also a series of patents. It was, however, inter-
esting to find also other ways of synthesis, starting from the
available raw material. lit the previous report of the labora-
4.ory of the authors it Yas proved that it is oossible to obtain
hexachlorobutadiene on the basis of diazetylone. Furthermore
the authors were interested to detect ahether it is possible
~o obtain a substance startin- from butindiole (formulae (1)
to (4)). These reaction were -up to now only partly realized.
The autiiors obtained 1,4 -dichlorbutine according to the known
method of(johnson, ref. 4 ) with a yield of Elo~u'. It turned out
that 1,,,-dichlorobutine does not combine at all with chlorine
under the -iven conditions. The realization of this reaction
Card 1/2 succeeded (with a yield of, 986-3) by chlorination in a solution

i1! ! IL I
7,
AUTHORS: Shostakovskiy, M. F., Shapirc, E. S., 20-1-32/58
TITLE,' Chlorination of Diacetylene (Khlorirovaniye diatsetilena).
The Synthesis of Haxachlorobutadiene-LO (Sintez geksakhlorbutadiyena
-143).
PERIODICAL: Doklady AN SSSR, 1958, voi-. 118, Nr I.. pp. M-116 (USSR).
ABSTRACT: The haloidation-reaction of diacetylene is well investigated in the
example of the bromine-addition (reference 1.). But there are no data
on the chlorination. For this purpose the authors worked out a method:
the reaction takes place in the medium of carbon tetra-chloride at
-30 - 2500. Liquid and crystalline 1,1_,2,3,4A_hexach1orobutene_ 2
forms. Its geometrical isomers were isolated and are known (reference
2). They are supposed not to react with chlorine and bromine. The
authors, however., succeeded in performing a further chlorination of
the hexachlorobuteneo- with liquid chlorine under pressure and ultra-
violet illumination. In the case of large chlorine excess (4-8 and
more Mfol) they did not notice any chlorinolysis and obtained octachl-o=
robutane with a quantitative yield. A subsequent dehydrochlorination
of the latter led to the synthesis of hexachlorobutadiene 1,3. This
is a substance valuable in many commercial respects. Regarding this
Card V2 production (references 3,4) there exist patent applications (although

85659
5- z 2-0 gj~ 12 66 510791601030100910!610221XX
BOO1/BO66
AUTHORS: Shostakovskiy, M. F., Guseynov, I. I., Shmonina, L- I_
Vasillyev, G. S.? and Lopatin, B., V,
TITLE: Synthesis of Compounds of the Type of 1-Alkoxy-2-
oxy-chloropliosphine-3-chlorobutadienes-1,3I
PERIODICAL: Zhurnal obshchey khimii, 1960, Vol. 30, No, 9.,
pp. 2836 - 2838
TEXT: The present paper deals with the reaction of ethinyl-vinyl
alkyl ethers1with PC1 (a reaction that has not been described as
yet), They suggest th~ following scheme:
ROCH~CH - C ~ CH + 2PCl5 [ROCHCl - CHPCl 4- C -==CH I PC 1
TROCH - CPCl 4- CCI===:-CH2PC15] + 2802---)ROCH~CPOC12
- ccl ~ CH 2+ 2SOC12+ POCI3
Card 1/3

Synthesis of Compounds of the Type of S/079/60/0301/009/016/022/XX
i-Alkoxy-2-oxy-chlorophosphine-3-chloro- BOOI/BO66
butadienes-1,3
Such a reaction was described by them in Ref,. 3. When studying the
reaction of ethinyl-vinyl-alkyl ethers with PC1, 9 they devised a
method of synthesizing I-alkoxy-2-oxy-ohlorophosphine-3-rhloro-
butadienes-1,3 (Ref. 4). The resultant compounds are viscous liquids
which readily turn yellow, have a sharp odor, and are stable at low
temperatures in seAled ampoules through which nitrogen had been blown
previously., The authors made supplementary experiments to check the
structure of the compounds synthesized. On the basis of the infrared
spectrum the butadiene structure may be regarded as proven (Ref. 5)
The splitting of the absorption band of the double carbon bond for
the present compounds may be interpreted in different ways, but the
opinion that the band is split into various components by rotational
forms of the cis- and trans-configurations (Ref. 6) is supported by
the fact that the components have different intensities which are
almost independent of the alkyl substituent., and that a shift oocurs
only in one direction. Mention is made of A- N. Nesmeyanov. There are
2 tables and 8 references: 7 Soviet and 1 British
Card 2/3

r)f Coamounds of the T ., , -I 1~ 10 7 90/0 0 /0 0 9 /0 16/(' 2 2/ 7,(
B001
~/B066
A S S 0 C 1". T i ON Institut or-anichesko- khim~i Akademii nauk SSSR
u .1
(Institute of Or427a-nl~ Chem--zllr,-,- of the Academy of
Sciences USSR)
SITB`l a
"TITTED 1-ust

BATUYLT, M.I.; SHMONINA, L.I.; MANEYDIA, A.D.j SHOSTAKOVSKIYy M.F.
Optical study of the structure of some 1. 2, 3--substituted 1, 3-
butadienes. Izv.AN SSSR otd.khim.nauk no.3,513-516 mr !61.
(MIRA 1,1+:4)
1. Institut goryuchikh iskopayemykh AN SSSR i Institut organicheskoy
khimii imeni N,D.Zel:Lnskogo AN SSSR.
(Butadiene)

21082
2 210 5 S/079/61/031/003/002/013
B118/B207
AUTHORS: Shostakovskiy, M. F., Shmonina, L. I., and Guseynov. I. I.
TITLE. Synthesis of 1-alkoxy-2-oxy-dialkoxy- and 1-alkoxy-2-oxy-bis-
dialkyl aminophosphine-3-chlorobutadiene-1,3
PERIODICAL: Zhurnal obshchey khimii, v. 31, no. 3, 1961,,734 -736
TEXT: The new class of 1,2,3-substituted butadienes (I) previously described
by the authors (Ref. 1: ZhOKh, 30, 2836 (196o)), which was obtained by react-
ing vinyl-ethinyl alkyl ether with PC1,t contains active chlorine atoms in
its group of oxychloro phosphines:
ROCH~CH-C~CH + 2PC1 5 [ROCHCl-CHPCl 4- CM CH - PC1 51 so2
ROCH- CPOCl 2- CC1= CH 2'
(I) The reaction of butadienes (I) with compounds
containing a mobile hydrogen atom (alcohols, amines, mercaptanes) may play a
Card 1/3

Synthesis of
21082
5/079j61/031/003/002/013
B118/B207
considerable role in the synthesis of valuable polymers, if the halogen
atoms of the phosphine group are substituted by different radicals. In the
reaction of compounds (I) with alcohols, e. g.,the chlorine atoms of the
phosphine group are easily substituted by alkoxy groups under the formation
of 1-alkoxy~2-oxy-dialkoxy phosphine-~-37chlorobutadiene-1,3 (II)l
ROCH= CFOC1 2- Ccl~ CH2+ 2R'OH !fCrCH' CPO(OR')2- CC'~ CH2 (It). This reac-
tion proceeds easily already at 30-35 0C in anhydrous benzene, in the presence
of pyridine. The yellowish liquids obtained have a weak odor and are more
stable than the initial butadienes (I) and may be preserved in seaied am-
poules. Compounds (I) react with dialkyl amines in the same way. In this
0
case, the reaction proceeds in anhydrous petroleum ether at _3 C, in the
presence of excess dialkyl amine. In analogy to the compounds (I) and (II),
the resulting 1-alkoxy-2-oxy-bis-dialkyl aminophosphine-3-chlorobutadienes-
1,3 are assigned the structure ROCH~CPO(NR' 2)2- CC1= CH 2 (111). They are
dense, yellowish liquids, which become darker when exposed to air. To con-
firm the previously assumed structure of 1,2,3-substituted butadienes M,
their Raman spectra were examined. The oscillation frequency of the
C-Cl bond in the grouping - C01= CH2 was found to conform to formula M,
Card 2/3

21082
Synthesis of
S/079/61/031/003/002/013
B118/B207
and the compounds studied revealed a rotational isomerism at the single
0- 0 and C- P bonds, as well as a geometrical isomerism at the C= C double
'bond which follows the C-P bond. The infrared spectra of some compounds
(I!) showed an absorption band 1408- 1400 cm-1 which corresponds to a vinyl
group (= CH2) in final position, which fact is also in agreement with the
structure of 1,2,3-substituted butadienes of these compounds and spectro-
scopic data presented in Ref. 1. There are 4 Soviet-bloc references.
ASSOCIATION: Institut organicheskoy khimii Akademii nauk SSSR (Institute
of Organic Chemistry of the Academy of Sciences USSR)
SUBMITTED: April 21, 1960
Card 3/3

SHOSTAKOVSKIY, M.F.; SHMONINA, L.I.; TIMOMIROVA, I.M.
Reactivity of -halo vinyl alkyl ethers. Izv. AN SS-S-R.
Ser. khim. no.12:2193-2196 D 163. (MIRA 17:1)
1. Institut organicheskoy khimii im. N.D. Zelinskogo AN SSSR.

PROSVIROV, Te.S.; SKORNYAKOV, V.I.; BATALIYANTS, K.Ya. Prinimali
uchastiye: VOLYA, G.S.; PHNTYUKHOV, V.I.; SM40,11INA. I.V.
FASHCHINSKAYA, G., red.izd-va; HIKOLAYEVA, T.. takhn.red.
[Commercial and some noncommercial fishes of the western
coast of Africa (from the Levrier Bay to the Gulf of Guinea);
te-dbook for fishery workers] Fromyslovye i nekotorye nepro-
myslovve ryby zapadnogo poberezhlia Afriki (ot bukhty Levrie
do Gvineiskogo zaliva); posobie dlia promyslovikov. Kalinin-
grad, 1961. 175 P. (MIRA 15:2)
1. Konigsberg. Baltiyskiy nauchno-issladovatells3kiy institut
morskogo rybnogo khozyaystva i okeanografii. 2. Baltiyskiy
nauchno-issleduratellskiy institut morskogo rybnogo khozyaystva
i okeanografii (for Prosvirov, Skornyakov, Batallyants).
(Atlantic Ocean--Fishes)

Cil IYEAT
t)n
11'r a s
ca ~tllyt, c q m. j inas.,iy nc.P:3-6
A 41-

USSR/Chemistry - Aniline 1 Jun 51
"Catalytic Red u*ction of Nitrobenzene," D. V..So-
kol ' skiy, V. P., Shmonina., Kazakh State Tj imwil-
S. M. Kirov,
"Dok Ak Nauk SSSR" Vol LXXVIII, ~O 4 ~- PP 721-72h
Examd reduction of nitrobenzene with H2 in liquid
phase over ske;Leton Ni catalyst promoted or not
promoted with Rh in 0.1 N soln of NaOH or neutral
500 a1c. Measured potential of catalyst during
reaction. Alkali poisons nonpromoted catalyst
and increases rate of r 'eduction in presenize of
Rh. In alkali on nonpromoted catalyst
184T12
USSR/Chemistry - Aniline (Contd) 1 Jun 51
nitrosobenzene (I) and phenylhydroxylamine (II) are
reduced at rates approaching max rate of reduction
of nitrobenzene (III). EMF of ' reduction of I and
II is higher by 150-180 v than that of reduction of
III. III in reduction passes over 1 as intermediate
stage, As long as III is present, I is not reduced
further. When III has been completely converted
into I., I in alkali is reduced directly to aniline
without passing over-II. In absence of alkali, III
is reduced directly to II without formation of L,
II on forming is reduced further to aniline.
18LT12

kill C1 IVA 'N N
U S S R
'~4he catalytic reduction of "a 4nd. Its' ;4-
fives on a skeleton nickel iaT2Y-sr-:r_-'WV
zuk wate tijox. P. , a4w o
and V. P~Slimoniqa Mg.
. . . . . . . . . .
t=cdWt~; am #_11
is bed on ~'no in
cre,431
'I Acimp. reduces.the amH d VAWW
as,
famars a(horption af I at th
*e!d, bow-'
-adsorbed in the presenre of al!mU is more fim
rl~r, since at 500, In tim" soln.,*,redilctoia dq"lvqot War
wherer.% in zoju. It gots sl6wly
Kinadcs of reductioi of nitrobenzene Q;L;:CAI Ak
P. MiThomina
-ornoted by chrAum. N. A~dl
slal. 4hid. 2195-12(il-Rh tl,~pot~Zti~d on dti- Ui;4w*7&t-v'_;',-~77.
VMa Y PrOH1GtW reduction uf Pit NO,,
Tke'?Wew
..creasediii thit i-r--ictice-of,walkali. -Dired4
Ph
Myin'the preswt of. alkiiH is Lhwl po~06,'
4--
10
~tlux ~he limiting factor ixtheanit. of Adso acLf-

-11; - - , ;,, - i, -
SMOITIA, V. P. and SnKOLISKIY, 1). V.
Catalytic Reductiin of Nitrobenzene and Some of its Derivatives on "Skeleton"
Nickel Cataly3t. N. Kinetics of Ylitrobenzene Redliction on "Skeleton" Nickel with
Rhodiiim Promoter, -oage 1195, Sbornik Statey -po o'bahchey !dAmli (Collection of
Papers on General Chemistry), Vol II, Moscow-Leningrad, 1053, pages 1680-!686.
Yazakh State U

matle 0 C
izakh--
-kovskil jKt
dal imonma and
Istartrol.,unle s
azakh~ S.S.R., Trudy Konf.
Okisknie, Akad. Nauk 1955, yfa
100-20.-Hydrogenation of PhN(h was examd. over' Ni
catalyst, promoted by_RL_pr Z~Land over 2Lcatalyst,
The reactions ivere run itt 50% EtOH with and without
-addn, of NaOff. The~mechanlsjn vari6 with the coudi-
tions used. If the proportion of active H is'relatively high;
the reaction is'nonselcctive and the intermediates are at-'
Wked before desorption; in such case PhNffl is the final
and only product., This occurs over Raney_Nj at 5 with
or without promoter; the same occurs wit 0
promoted
or Pt at all temps, With deficiency of active H on: the sur-
face the a&umulatiori of PhNO is demonstrated best in alk.
medium at all temps. and in neutral soln. at 25-4Q*. The
reaction rate is retarded by substituents in this order:-
PhNO~, P-O'N-CdH4I",. P-O,NcjH4OIII P-0-INC4114-
C0,11. At 401 on Raney Ni in neutral soln. the substitu-
ents that limit H activation actually accelerate- the reac-
tion and tht~ asczudinj order is: PbNO~, P-OINCdlIMH,
IE p-0,NICJT4NMI, p-0,NClIl,OH. On,-Ni the rate of hy-
w3 from PhNO2 to m-02NCjfj\rffj, p4gomer
drogenition ri.,
anO o4somer. over Pt the order bjeversed.-C-1.1-K-

/* P
USSR/Kinetics - Combustion. Fxplosions. Topochemastry, Catalysis. B_Q
Ab s Jour Ref erat Zhur - K-himiya, No 6, 1957, 18638
Author V.P. Stmenine, D.V. Sokollskly.
Title ~Ca`t_a_1Y_ti c__'_~_educ t ion of Aroratic Nitrocompounds. V1.
Influence of Some Functional Groups on Kinetics of
Nit-oa_x(-_-p Reduction on Skeleton Nickel.
orig Pifo Zh. obsic-a. I-Eii-xiii, 11056, 26, No 6, 1759-1765
Abstract The reduct'-on of nitrobenzene (I), nitrobenzoic acid
(11 n-nitrophenol (III) and n-nitroaniline (IV) in
aejv?ous-,-,.1coho-L and alcohol-alkaline solutions on a
skc:1 ton Pli catalyst was studied a' 5, 2'55 and 400.
The reductUon sr2ed in aqueous-alcohol solutions at 250
wa-~ !I

85429
3/081/60/000/016 100310, 12
5-A OL,, 9 Z 05 A006/AW I
Translatton from,- Raferatlvnyy zhurnal, nimiya, 1960. No., 16, 1:- 7_3, # 64650
AUTHORS, -Shmonina, V.P., Vlas~:va, K.M., Sok--d'Skly,, D.V.
TIT'LE
In I
Cal-alyt,i Red-ac'.1on of ArDma-~Ic NIT_-rccirpc'.zrdZ,~ I f~_,rmw-ion rX
The Effecs of Ethyl Group or Reductim Kins-.ic~_ of the N~*_,=Wrcup
in Ske'LE-on Nickel and Platinum
PERIODICAL, Tr. In-ta khlm. nauk. AN KazSSP, 1959, Vol, 5~~ PP. 72-80
TEXT 4 Tne effect of the ethyl radical Inf.r.-duced in,,c, the ~~,Lmpositi= of

dej~enis on a ser.'_;~s of
a nitr-comou-nd, r'n T--.,P-, redu.-ion rate of the nitr~~grC%jr
fir
factc,rZ st. of all on 4-e catalyst, nature, Vnen ccndw_:fng the rrsces:s on ske-
,
letcm Ni, -h e in--.rod;.I~tI-_n c-f an e~~,Yl radload en-,alls an az~.,elsrt~d reaction.
T
IhE ethyl gr
.:;up -speeds uP -.he reactirsn mcre Iz !-.he than. in the para-
This is explained by t'me fa,-!% ttiat 4..-qe cf t-he ethyl group
oauses a red used aiscrztlon of the nitr,-,Comround, 1~hus incr=asInjz -t~hp hydr..)gen
a~~-cess ra-~alyst s-urface, TI-is rediStr'_~,_I-,ion cf' the cataiysti_~jrfae
limit-Ing the reaction by h~.rdr-_,Sem a-_tivatim-, haz a fav,~ra'-;Ie effect
Card !12

85429
S/,2 !/6C/OOO/G 16/00_.~/C 12
A006/A001
Catalytic Reduc -lion of Arcmatic NitroocmpoundS,. lnf .--rmat lon D(. The Ef f ec ~. of
admi Et,hvl Group on Reductl_- Kine+i-_ --f the Ni7~rcar:up in _Okele,~-.n Nlcke-~ and
P! a ~ in--Lm
or. -,n=- pr-.Dcess rate. A sitah' redurtlc~ of tre ad.zi:rp'.'_cn of a n_ltrj::CCMr.31_,nd on
x
Pt, occuring during the intrcductim of .tic A -up in 'he rara-state, -zcms-
-thy! zr- - -
wnat. ao.~elerate_c whe_-eas a fur-~har de~:-=_P_Se cf
by ~'re '~i:n of -a -~he
ln-fcrnla4-ion IT! see R ZI-Y,2ii!i% 1957, Nc. !5; # 186,38~
r_~ie, Thi~ i~ --c- f,.All of ~te crigi-ned, Rus_=*_E_~n
Card 2/2

i _S_LL_IYL IN
5H
fl -tig 6-4 J
_I as
a
i 13,
, " " - -1 , 11. 11 11
s'PIP.411

S/07 Y 61/031/003/003/013
B118,3207
AUTHORS: Shmonina, V. P., Temnikova, G. P., and Sokol'skiy, D. V.
TITLE; Catalytic reduction of aromatic nitro compounds. X. Effect
of phenol hydroxyl upon the reduction kinetics of the nitro
group in nitrobenzbne derivatives
PERIODICALt Zhurnal obahchey khimiiq V. 31, no. 3, 1961, 743-749
TEXTt The present paper describes the effect exerted by the presence and
position of phenol hydroxyl upon the reduction kinetics of the nitro group
in isomeric nitrophenols in the presence of a nickel or platinum catalyst,
i. e., in neutral or alkaline-aqueous alcoholic media. The phenol hydroxyl
and ONa groups that were introduced into the nitro-compound molecule reduce
its adsorption on both catalysts more intensively in ortho-position than in
para-position where the reduction is greater than in meta-position. When
the reaction is carried out on the skeleton nickel catalyst in an alkaline
medium, the ONa group in the molecule of the nitro compound accelerates the
reduction. Thus, the compounds studied may, with respect to the increase of
reaction rate, be classified as followst nitrobenzene, m-nitrophenolate,
Card 1/2

Catalytic reduction ...
S/079/61/031/0031/003/013
B118/B207
p-nitrophenolate, o-nitrophenolate. On the platinum catalyst, however, the
ONa group retards the reduction of the nitro compound, and the order of
compounds is inverse with respect to the increase of reaction rate. In a
neutral medium, the bond between hydrogen and platinum is less stable so
that the position of phenol hydroxyl in the molecule exerts no essential in-
fluence upon the reaction rate. There are 6 figures, 4 tables, and 8 Soviet-
bloc references.
ASSOCIATION: Kazakhskiy gosudarstvennyy universitet (Kazakh State
University)
SUBMITTED: January 28, 1960
Card 2/2

5/079/61/031/003/004/013
B118/B207
AUTHORSt Shmonina. V. P,, Detinenko, A. I., and Sokol?skiy, D. V.
TITLE: Catalytic reduction of aromatic nitro compouaids. XI. Effect
of the carboxyl group upon the reduction kinetics of nitro-
benzene derivatives
PERIODICAL: Zhurnal obshchey khimii, V. 31, no. .3, 1961, 749-754
TEXT: The authors studied the effect of the presence and position of the
carboxyl group the catalytic reduction of the nitro group in isomeric nitro-
benzoic acids on skeleton nickel and platinum catalysts in neutral and
aqueous-alkaline, alcoholic media. Although the introduction of the carboxyl
group into the molecule reduces its reactivity, the effect of the carboxyl
group in a heterogeneously catalytic conversion is not limited thereto. The
course of reaction in heterogeneous catalysis is in close relation to the
ad5orption of the reacting products on the catalyst; the influence of the
sulstituent is therefore closely linked with a change of the qualitative
ratio of the reacting components on the catalyst surface which, under certain
conditions, exerts an important effect upon the reaction rate. The influence
Card 1/3

S/079/61/031/003/004/013
Catalytic reduction B119/B207
of the mutual position of the substituting groups upon the adsorption of
nitrobenzoic acids was studied by N. F. Yermolenko and V. R. Skorokhod (Ref.
21 Uch. zap. Belorussk. gos. univ., no. 20, 165 (1954)) who found that the
adsorption of o-nitrobenzoic acid from aqueous solutions on activated carbon
is much lower than the adsorption of the respective m- and p-derivatives;
this is explained by the fact that two polar groups are in the immediate
neighborhood of o-nitrobenzoic acid, which entails a stronger solvation of
the molecule in the polar solvent and a reduction of adsorption. The COOH
and COONa groups which are introducedl. into the molecule,"'of the nitro compound,
reduce its reactivity and change its adsorbability. WiTh respect to the
increase of the adsorptive power on both catalysts, the compounds studied may
be classified as follows: o-nitrobenzoic acid sodium (nitrobenzene - m-nitro.-
benzoic acid sodium o-nitrobenzoic
acid = p-nitrobenzoic acid. To interprete t~e' observed dependence of the
rate of catalytic reaction on the mutual distribution of substituting groups,
it is necessary to consider the effect of the substituent upon the reactivity
and adsorption of the molecule. There are 6 figures, 2 tables, and 7 Soviet-
bloc references.
ASSOCIATION: Kazakhskiy gosudarstvennyy universitet (Kazakh State Universi-
ty)
SUBMITTED: January 28, 19060
Card 3/3

SHMONINA, V.P.; SOKOLISKIY, D.V.
Mechanism of the catalytic reduction of nitrobenzene and some
of its derivatives. Trudy last.kbim.nauk AN Kazakh.SSR 7:38-53
161. (I-MiA 15.8)
(Nitrobenzene) (Reduction) (Catalysis)

~IWNIXA,._V.P.; TARASOVA, D.V.; ALEKSEYEVA, G.K.; SERAZETDINOVA, V.A.
Catalytic reduction of-arumtia nitro compounds. Report No.12:
Polarographic study of the mechanism underlying the reduction
of nitrobenzene on skeletal nickel. Trudy Inst.khim.nauk AN
Kazakh.SSR 8:64-72 162.- (KERA 15:12)
(Nitrobenzene) (Reduction,, Chemical)
(Nickel catalysts)

SOKOLISKIY, D.V.; SHICNINA V.P.- TANFYEVA, G.V.
I
Polarographis determination of acetic and crotonic aldehydes
in a mixture. Zav. lab. 30 no.7:793-794 164'. (MIRfi 18-3)
1. Kazakhskiy gosudarstvennyy universitet imeni Kirova.

11 1 A , VPB 0'? -.*, K1114 A. VA I H ~ 'R .
,~,a2~.tic reduction of aror-ratic n-J, -o comnfo nds. Part 13:
"at itz
(
KJnetics and m=chan-*s,-n of n4trobenzene red-ction on palladium.
L
~hur. cb. khim. 34 no. 3-tF69-8715- Rr 164. (MIU 17:6)
gosuda-r.9-cier yy univer --
FA za. si 'et.

~~c;n cf mtro co:-,Loun~s ~ax t,
-in of ril,--,:.beniene -Dn platinum blacv.
ob.
Z, 4 ;~j - , ." -'.
I'm 1-,4
e

i-J :;r

f 711 f Lr.
7!j

AUTHORS: Kolesnik, Z. A.) and Shrronova, N. I. 2o-6-49/48
TITLE- On the Study of Petroleum Transformations Under
Anaerobic Conditions, Effected by the Influence of
Bacteria of the Genus Pseudomonas (K izuchoniyu izmeneniya
refti v anuerobnykh usloviyakh pod vliyaniyam bakteriy iz
roda Pseudomonas).
P-IRIODICkL: Doklady ;al SSSR, 19,57, Vol. '115, Nr 6, PP. 1197-1199
(USSR)
ABSTR,,%.CT: It is one of the tagks of the microbiology of petrolcura
to study bacteria in Pure culturen isDiat--l from t!n~~
'Imicrobiocanosis" of stiam-w.-ater,.): it shall help to cli~,ar
up the problem concerninE the part played by them in the
transformation of mineral oil. According to Biorstecaar
(Birshtekher) a number of aerobic micrcb-ae e-xist ithich
utilize -,etroleiim ai a f3surce of carb,--n. There ar-:~, .1-io-r--
ever, n~ work4 . 01. th tha chnr,~:.ctz~r of the trans-
formation cf Petroleum if~:ll und'---r
- 'f
'-L2 1-1 `31101e iAS 12r,00r the
of any ih,-/siolotjcal e-r-jup of bacteri---t. Ther~-fcr~~ tl-,~
pri~sent xork was c-:Lrri,)-i out. FlutorescirtE. ~ucttri,
CARD 1/5 color the culture-.~----dium ,'J;-!~n Y,',cre di3covZrod in

20-6-39/48
On the Study of Petroleur, Transformations Uncler An~-a-rnbic
Conditions, Effected by the Influenc~~ of Bacteria &f t1le
Genus Pseudomonas
oeam-water of the 1~ore-holi,, nc. 120 of thi IXth .--i-:am
in the distrio~t T~i-lhkai,~. (No-rth- k pure cultural
of isclated "-,actaria of thig t~p,-- asGigred then to the
L;enus Pseudomonas. Diff.-'L-3ulti*-~-s aro~:,z, ho-;aver, in the
d;~termination of the species. Th-= bacterium was, there-
fore, eliminated by the authors as Ps. fluorescens
.denitrificans. In order to clear up the relation existin--
between the bacterium and petroleum, mineral culture-
mediums were prepared which contained the fcllrj,,-ii-1--
substances as the only source of carbon: a) Asphaltenes,
b) oils (together with petrol-ether-resins), c) non-
refined fractims boilin& out at 21~0-3000C, d) hard
paraffin and e) petroleum. It was experimentally found
that the above-'nentioned bacterium is riot capable of
assimiliting ca~rbon from tae substances mentioned in a)
and c), but tha.t it propagates in the jubstance d) and
in oils. The petroleum culture-med-Jum ~4as visually much
CARD 2/5 changed. It qeea.ed to be interesting to determine the

20-6-39/48
On the Study of Petroleum Transformations Under Anaerobic
Conditions, Effected b.y the Influence of Bacteria of the
"enus Pseudomonas
character of transformation of the petroleum as well
under the influence of Ps. fluorescens alone as together
with sulfate-reducine bacteria. To these latter an important
part in the transformation of patroltum is ascribed. In
their expt~riments the authors inve~ti,,-ated cultures of both
bacteria in the ratio 1: 1 or injividually. The paraffin-
containing petroleum was previously dehydrated. For creating
anaerobic conditions, the air was removed from the test
tubes by nitrogen which had previously been purified from
traces of oxygen at 30-32oC. In the individual experimenta,
after 1 week, a light thin film developed below the
petroleum and a precipitation of oulphorous iron at the
bottom of the vessel. After 3 wee- a looje brown mass
of bacteria (1-1,5 am thick) was to be seen under the
petroleum. In the second test the 1 1-bottle after 20 days
filled w*th a similar mass of bacteria films dow-n to the
bottom. The fluorescing stopped. The petroleum-trans-
formations and the other products are chemically chardcterized.
The tests performed under anaerobic conditions indicate
CARD 3/-

th- of Petroleum Tniasforiiqtions U!ider An,-r--)',lic 20-6-39/48
Conditicns, Effected by tK~~ influence of Bact"c-ria olf' the
f-
-,-~nus Pseudomponas
.--,-j,3 0 C I A TI OIL I :All-Union Petroleum Institute for Scientific Research
and Geological ProWeting k is ,-aoyuz.,-.yy Flef tyn,-(,y
geologora~.-vedochnyy institut)
PRESENTED: V. N. 31iaposhnikov, AcaderAicir~.n, May 27, 1957
May 27. IIQ57
AT~ILABLE: Lil,--rary of ConE~,ress
Cz-.RD 15/5

SIE;miow, N. I., GORSKAYA, A. I., SDJAKOVA, T. L., KOLESNT-K, Z. A., BOLOTSKAYA, 0. P.
and STRIGALE-VA, N. V.
'Vhe Nature of Oil Chm*es in Anaerobic Conditions under the Ufluence of
Biogenic Factors.," P- 315-360 Voprosy obrazovaniya wdtip abornik statey,
(Problems of the Origin of Petroleum., Collection of Articles) Leningrad..
Gostoptekhizdatp 1958.- 389 p. Trudy,, vyp. 128,,
This book, containing four articles vritten by 11 speciali ts, reports
on the results of studies made on the origin of oil depoflits In the Northeastern
Caucasus. The program vas organized In 1950-55 by VIqMRI (A114mion Petroleum
Sci.Reo. last. for Geological Svrvey)

Ql_lmolllve V/9
365-37
S/081/62/000/006/067/117
B149/B108
AUTHORSt Simakova, T. L., Strigaleva, N. V., Kolesnik, Z. A., Voronova,
I. K,
TITLE: Tho'role of bacteria in the transformation of hydrocarbons
and asphalto-bituminoue components of paraffin-base petroleum
under anaerobic conditions
PERIODICAL: Referati-.nyy zhurnal', Khimiya, no. 6, 1962, 527, abstract
61:130 (Tr. VseB. neft. n.-i. geologo-razved. in-tal no. 174,
1961, 77 - 97)
TEM The results of experiments with three different communities of
bacteria taken from the water below the petroleum layer in the wells of
TaGhkal, the Staro-Croznenskiy oil field and the Emba region are described.
It is shoom that under the biological action of bacteria certain chamees
occur in the structure of methane hydrocarbons soparatod from the fraction
250 - 3000C of Tashkai petroleum by fo=ing complexes with urea. The
methane hydrocarbons in the analogous fractions of Wakhachkala petroleum
were not affected by bacteria. The structural composition of.aromatic
Card 1/2

S/081/62/000/006/067/117
The role of bacteria in the ... B149JBIOB
lVdrocarbons in the kerosene and oil fractions was changed, the aromatic
rings showing a decrease and the paraffin chains an increase. It is
concluded that the change in composition of the hydrocarbons and of the
asphalt-bituminous part of.patroleum depends both on their chemical
Somposition and on the species-composition of the bacterial community.
LAbstracter's note; Complete trdnslationoj
Card 2/2

SIMAKOVA, T.L.; KOI-ESHIK, Z.A.; STRIGALEVA, N.V.; VORONOVA, I.K.;
SHMONOVA, P.I.; GFRASYUTO, Z.S.; AHI)REYEVA, L.G.
Bacteriological change of petroleums and their components
under anaerobic conditions. Trudy Inst.mikrobiol. no.9:81-85
161. (MIRA 15:5)
j, Vsesoyuznyy nauchno-issledovateliskiy geologorazvedochnyy
nstitut, Leningrad.
I
(Petroleum-4ficrobiology)

V,'.SFIIKO, Yt- N.; GI~TALA , Ye.Ye.; ZAKU'I'SK-kYA , M.P.; 1-1-1AYI-UROW , V.F.;
0.%7.
Vapor pressure and boiling point of a ternary mixture of acetic
anhydride, acetic acid, and water. Dokl. LPI 5 no. 1/2:161-
164 163. (MIRA 17:6)

yl.
j3 'V L
Y,f y 11 C"I t
equilibrium in the ternar.,, jy;iL,-m acetic anhyLlrint-
c a c- I -
a"* d ac----taldz,,hyde~ l,ok'l ~ 1-P no. 1/2:172-175 163.
T

SPMIONOVA, N.I.
Role of the b~Lcgenlc factcr of t-he asphFdtization process I-
ypes of petrolawns. T udy TIJIGRT nr,.27 Craokhim~Bbrr
dJfferent t I I- ,
no.9.-)6i,,-70 ~64- (MIR-A

SHMORGUN, 6.31".
Vascular reflexes in affections of the liver and biliaq tract in
children [with summary in English]. Viziol.zhur. CUkr-J 3 no.6:
45-47 D '57. (MIRA 11:2)
(RKFT,k S) (BILaRY TRACT--DI=SNS)
(LIM--DISEASNS)

'T'
STIMG-jI, S.S., Gr-.n- Veri -ci -- (diss) "Change in
certain f.inctions of L~,e cardir-vascular system in
Potkin's disea-e in ebildren." Yiev, 19~8, 1L,
(Kiev ilrder of Labor Red kanner ..ed Inst, im
AcadAmiclan Fogomolel~s) 200 c-clies (FL, 2?-z--lb, 138)
- 137 -
OF,

SHMORGUN, S.S.
Periphernl blood circulntion in Botkin's disease in children. Top.
okh.mPt. i det. 3 no-3:47-51 My-Je 158. (MIRA 11:5)
1. Iz kafedry pediatril (zav.-dotsent D.L. Signlov) Kiyevskogo
instituta usovershenstvovAniya vrachey (dir.-prof. I.1. Kallchenko)
i fiziologicheskoy laboratorii Ukrainskogo instituta okhrany
materinstva i detstva (zav. Ye.S. Stnl'nenko).
(HEPATITIS, INFECTIOUS) (BLOOD--CIRCULATION)

ANDRYUSIMIENY.0, P.E.; Offi-MIOVA, V.V.; GONCHARCYA, Ye.I.;-SHMORGUN, V-1.
Effect of the pff and buffer concentration on the stability of
sodium hydrosulfite in solutions. Ukr. kbim. zhur. 27
no-4-536-539 '61. (MIRA 14:7)
1. Nauclino-issledovatellskiy institut osnovnoy khimii, Khar'kov.
(Sodium dithinite) (Hydrogen-ion concentrati:,)n)

TTIMOSH-FNIKIC, Ght.lb~: ) V. T. I OGV i NOV, IN. G. ; p--i,,p,.,yKnV Jj
Aur-sat-ic,rj (,-- tacnnol,~%giraj proCe.,,~SeE in ny~~raulic min-lpg. Ugf)l I
39 no.9:37-4.2' S '64. (Mlflk 17.10)
Donetskijy pol-itek-hniAesk-ly inst-itut (for Tlrimshenkc., Gruba,
L;-,F-,,,-,nov). 2. Ukrbins~.;'.y nauchno-iesleclovatel Iskiy institut gidro-
dctychj u,r,-'.ya (fcv Ferrnyak--n). 3. Gosuda-z-,vermyy proyektno-kem-
str-uk~crsld-y 4nstl~.ut alit--tuaLizatsil rabot v ugollnoy promyEhlei-
nosti (for S".avu!,skiy). 4. Vsesoyuzriyy nau,.lhno-is.9ledovatel.',qkiy
i proyektri(~--konit.ru~t,.~rsr,-Iy institut dobychi. uglya gidravlichesvirli
sposoboyn (fcr Shiriirin).

ANDRYUSHCHENKO, F~K~; OREKERNA, V,V,; GOMHAROVA, Yej.;
SHKORGUNS 7.1.
Effect of pH and bufTer concentration or, the stability of
sodium hydrcsulfite in solutions. Report 2, Ukr. khim~ zhur.
29_no,42~125-12,7 163. (MIRA 16.-0/)
1. Nauchric-issledavatel'sk1y institut osnovnoy khimii, Khax"kov.
(Sodium dithlonitell
(f~,drogen-ion concentration)

GVOZDEVICII, Alokuandr Makarovich-, ZAYGEROV, losif Borisovich;
KOROLEV, Vitaliy Arkndlyevich; SHMORGUN, Yakov_~h4y-evich;-
KASUFANOV, F., red.; DQIOVSKAYA,--G-.; tekhn. red.
[Mechanization of conveying operations in machinery plants;
enerience of the Minsk Tractor Factory) Mekhanizatsiia tran-
sportnylch operatsii v rzshinostroenii; iz opyta. raboty Min-
skogo traktornogo zavoda. Minsk., Gos.izd-vo BSSR. Red. pro-
izvodstvennoi lit-ry, 1961. 710 p. (MIRA 15:2)
(Minsk-Conveying machinery)

ZAYGBROY, Iosif Borisovich; prinimali uchastiye: GVOZBEYICH, A.M.,
,z~MORGUN. Ya.Sh., inzh.; TIMOFEM, T.S., inzh.; ARAT, R.I.,
inzh., X1WSH'5TA-,A.I.. inzh.; GOROITNTSKIY, G.Ye.. inzh.;
SOSIBNKO, M.N., inzh. retsenzent; SIROTIN, A.I.. red.;
EL'KIND,V.D.. tekhn. red.
[Reclamation of used sand mixtures; design of pneumatic reclaimers]
Regenerataiia otrabotannykh amessi v liteinom. proizvodstve; kon-
struktaiin i raschet pnevmaticheskikh regeneratorov. Moskva, Gos.
nauchno-tekhn. izd-vo mashinostroit. lit-ry, 1961. 181 p.
(MM 14:5)
1. Nachallnik otdela mekhanizatsii 14oskovskogo transformativnogo
zavoda (for Gvozdevich, Shmorgun, Timofeyev, Arav, Kuleshove,
Gorodetakiy)
(Sand, Foimdry) (Pneumatic machinery)

GOROKHOV, F.K., kand.t6i-m. na-U4-~ kand. tekhn. nauk,,
PAVLOV~ L,I-~, kandi teklnn~ SEPGEYEV, N-P.~ TLAREM,
B.M.. doktor taknn. riza.-:1-, p:. fi- 1-5..~ V'URBP-TOVA, N-S.
kand. teklm, na,.j'r-., pr:,f, reci "'HESKIS, ';,Bz~ red,
(French-Russian ele,~t.rill.a.",. eng"nearing dictionam7y] Frantsuzskc--
russkii sl-.trarl. Pod red, N.S.Kurbatovoi
i B,14,Tareeva,. Mosk-.,.a,, S'.,vEt,t3kaaa entsik-Lopedilla, 1965. 720 p.
(~CRA .18.12)

UGORITS, I.I.; GLAZUROV, A.A.; SYROMYATNIXOV, I.A.; KASHUNIN, I.S.; POSTNIKOV,
N.A.; RADTSIG, V.A.; ULIYANOV, S.A.; qRUDIIISKIY, P.G.; VASILIYEV, A.A.;
KUVSHINSKIY, U.N.; BAPTIDANOV, L.N.; TARASOV, V.I.; KRIKUNCHIK, A.B.;
SHAPIRO, A.B.; BIBIKOV, V.V.; DVOSHIN, L.I.; XLINGOF, I.D.; KARPOV,
M.M.; USPENSKIY, B.S.; CHALIDZE, I.M.; BWCH, Ya.A.; SalOTKIN, I.S.
Iosif IAkovlevich Gumin; obituary. Blek.sta.26 no.12:58 D 155.
(Gumin, Iosif IAkovlevich, 1890-1955) (mmA 9:4)

KUZNETSOV, Serafim Petrovich,; YEGORCHENKOV. Anatoliy Ivanovich; S
~
A
'iedaktor; KAYDALOVA, A.D., tekimicheskiv reda-ktor.
[Reclamation of new lands in Khabarovsk Territory] Osvoenie novykh
zemell v Khabarovskom krae. [Khabarovsk] Khabarovskoe knizhnoe izd-vo
1955. 51 P. [Microfilm] (MLRA 10:5)
(Khabarovsk Territory~-Reclamation of land)

AUTHOR: Shmo,tov, SOV/20-122-4-42/57
TITLE: The Mutual Relations of Greisens and Skarns
(Y, voprosu o vzaimootnoshenii greyzenov i skarnov)
PERIODICAL: Doklady Akademii nauk SSSR 1958, Vol. 122, Nr 4, pp 687-690
(USSR)
ABSTRACT: In the Dzhidinskiy ore region numerous intrusions of
Kimmeridgian granite are known in which intensive exo - and
endogenic contact zones are developed: hornstone, skarns,
calc - silicate rocks (with pyroxene and scapolite) as well as
molybdenite - bearing greisen. In the area of the ore bearing
rocks the principal rock type is a Lower Cambrian limestone -
sandstone suite. The ores are usually associated with younger
leucocratic granites which intrude the sediments in the cores
of anticlines and form small northwest - elongated stocks
(smaller than 1 km2). The metamorphism is clearly expressed in
the resulting contact metamorphic facies (Ref 4). The highest
grade of the metamorphism is biotite - hornstone facies; the
rocks of this facies lie adjacent to and surround the granite
in an observable zone 90 to 150 m broad. In this zone the
Card '/3 limestone and sandstone have been completely transforms& into