SCIENTIFIC ABSTRACT SHAMTOV, V.T. - SHMAYEVSKIY, V.YE.

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• Collection: Scientific Abstracts
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• Release Decision: RIF
• Original Classification: S
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• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

SO V/ 12'G-6 -2 - _2 6 / ~4
Thermodynamical Derivation of Dynanic Suscept-ibill-i".,
equilibriwia, usinE, the lineal, approxii,,iation and accordini
-to (2)
T ~~ 4- (a - a (T - T ) + a) (A - A (3)
T 0 )A 0 ( TA rp 0
wl-_,~ere the z~,_iuilibriwr, values of the derivatives are
found from, -jhe equation of state for the subsystem and
IcT L (Za)Tj J_s the time of isotherm-ic internal
relaxation. In this approximation
4 = cx(T - TO) (4)
vihere a is the coefficient of thermal conductivity
between the subsystem and the thermostat, and Q is the
heat driven by the subsystem to the thermostat. UsinE
well knovin ther-,nodvnamic relations and the linear
Card 3/5 anr-roxi-ma-tion we find that

SOV/126-6-2-26/34
Thermodynamical Derivation of Dynamic Susceptibility
T0 (1A
+ (T - T _6T (5)
11a 0 Ca )a
where C a is the thermal capacity of the system and
= C (6)
a a
is the time of external relaxation at constant a.
For A = const both external and internal relaxation
takes place in the subsystem. The time of external
relaxation at constant A can only be usefully
introduced when the internal relaxation can be neglected.
In the case of adiabatic isolation of the subsystem (a -~ 0),
eliminating T-T from (5) and (3) we find that the
adiabatic relaxRtion time for internal relaxation is
Ts = T - Ca
T CA
Card 4/5 When A-Ao varies periodically with frequency w we find

SOV/126-6-2-26/34
Theruodynamical Derivation of Dynamic Susceptibility
using (3) and (5) that the dynamic "susceptibility" is
Eiven by:
+ 'wTa
A 1 + iw(T T+yTa)-w2Ta IrT
There are Soviet references.
(110-TE- This is a complete translation)
ASPIOTATION: Urallskiy politek-hnicheskiy institutjUrallskiy
filial AN SSSR (Ural Polytechnical Institute)Ural Branch
of the Ac.Sc. USSR)
SUBLIITTED: April 169 1956
Card 5/5 1. Thermodynamics-Mathematical analysis

kj ~rn,
AUTHOR: S I i,), D v , 50V/126-6-~3-29/32
TITLE: ~31 TTi _0 -2 al.11*c -)f 'R--, ProcP_.1-.z__'Cs in
A ti 1
U
v L.;isLo::ia_'z_1., s dopolnit-
FERIODI~'A_'.: Fi7.i'.:a tall ov J_ 1`5L~) Vol G, Nr 3,
PP 570-571 (U;3:]R)
AB.3TRACT: Co-onside-_,, a system -c.-Kii-c-'a is characterised
by t1ae te--.:iTleratare T~~eneralised force A a-d a
co-ordinate a con~u,~L*al-e Uo it, and -_ is described by -he
U
equation of stuate, A AM a), as well as a certain addit-
ional internal -~~a=detar 71 , --ah-ich in the equilibrium
state of the syotem, is a function Df a and t , i.e.,
Tj = -q(a, t). 'We shall assume that the additional p-crameter
Tj characterises a definite internal proDertuy of the system,
for exam-ole, t1le den-ree of long- and short- range order,
spontaneous ma=etisation or electrical polarisation, anti-
lerroma--notic order, etuc. When the state of -he system
chan:res ~%,ith bime the Dar--metuer Tj assumes a no-i-equilib-
riu-..q value 71 / 71(a, T) as a result of which the syste-ir,
as a -a1-i-,)le 3ill Da.,;s through non-equilibrilra states. We
Card 1/9 shall ass~:lme t1iat, in a non--eauilibriurm state, the free

SOV/126-6-3-2Q,/32
On the Thermodynia.~-.ic S,-E=y of Rclaxation Pi-ocesses in Systems witull
Ad"'itional P.3--ameters
eiier~~y of the system is F - F(T, a, 71) ahere
F71 (T, a, -.0 / 0 (the subscript denotes differentiation with
res~.-)oc-u to t1de corres-)ondins parameter). It follows that
C.1
in a non- e (1ui librium 5tate of the sy~stem:
A = -F a(T, a, TO (1)
In an equilibriiii-i state:
71 (T, -q) Till (2)
According tuo(Ref.1) the change in the entropy for a non-
7
eq-ailibriu.--L stuate of the system. is given by:
TdS = dU + Ada - F 71 dTi
Card 2/9

SOV/126-6-3-29/32
-t---~cesses in
On the T'--aory .-Df' .3yste--2is wi-th
Additional Paramete~os
17'riere U(T, a, rj) is the internal ar-er- Tae last item in
Gy
Eq.(3) describes t~ie nor;--equilibriLua part of t-',ie entropy
cjllanr~e. From the e--z---aressior. for the increase of entropy,
0 -
ilich is a direct of Eq.(3), i.e.:
w
T&~ T1
a-ave in t-:-ie of the ther-,iriodynamics of
irreversible -;r--)cesses (Ref.2):
Ij = -LF (T, a, 11) 1 (4)
who-re the kine tic coe f f icient L > () since A~ >0 Eq.(4)
holds for s:7,all deviations of the parameter Tj from its
equilibriLL-a value and, in special cases, coincides with those
used in (Ref.3). If one expands F T) into a series about
ti-le position Of e(L-Uilibriucii and retains only linear ter-,s,
one oblva-ins from Eqs.(4) and (2) an expression allich describes
Card 3/9 ti-Le, -variutuion of Tj vii-th time:

sov/126-6-3-29/32
On the Thermod,-;-namic Theory of Relaxation Processes in Syote-ms
Addition--I Parar-aleters
aT
+
6a i(j,11)l (5)
T aA2
1
where TaT = (IF T1 is zhe relaxatiDn
ional parameter at const.-ant a and
Uo sho-w7 starting .~iituh Eqs.k-1) and (2)
condition, that with another choice of
will hve the fo_~m:
XY, *
11 + ATI =I-q)y AX + 617
(1-6-X (!yn)X
time of the addit-
T It is nossible
and the adiabatic
the variables, Ec,,,.(5)
(6)
where x and y are two arbitrary variables involvin.- T,
a , A and the entropy S and 'rx-Y is the relaxatuion
Card LI-IC)

SOV1126---3-29/32
,Cory 0l
tb,, Tvncl~ci,10~1-7-fl T Tite
on n,3 t r. r F,
i-i onal Par--:1i .1 - ant -,,c and Y
t co ovlin,-,
_kdd u .-L u -L L>
ra-;a~cter q C the f o1'
ti-me of the pa nrlected by
,,I,-:-,ation tuir-les are co
T
f r6 ka T
,Tk73r-ATr( ~-Idw I
aT kT k -
T T T) a a
(rT 31
a/ T
c A.S
aS -k
La, T - ju T
IT
a - 1 -1 -,,a
T TS qbk~ a' rp
T- Ur-T)--77t(
T TT
o- the sYs-~,O`ll
,-Oecific heav --
vihere c and A, re the he SIYD- SYS-.-37'a at
a are "Lie heats D:C t
card 5/9 ~C' ~q and ~c ki u

SG'1/126-6-3-29/32
U
On the Thermodynamic Theory of Relaxation Processes in Systeas
Additional Para-met-)rs
c o ris 'U a n 'U a and A The latter t-,;io s-lecific hea-Us are
associated wiil-h those de-rees of freedora ~Trhich are responsi-Ible
0
for the anijearance of properties characterised by the para-
:,I~~ b-,~r il T'I'le quantities:
[(LA IA - the contribution to:
eaid determine
)aj
,"'A due to these degrees of freedo::,i.
\7
.ca T T, a
VIhen the system is periodically disturbed at a frequency w
vie iiave 'on calculating the dynamical derivatives, using
I CD
Eqs.(l), (2), (5) and (7) and the adiabatic condition:
1 + iWTYZ (8)
(~Y) Z, W Z, 1 + iWT -Z
where :-I, y, z are three arbitrary variables involving T,
Card 6/9

SOV/126-6-3-29/32
On the Ther:,jaynamic Theory of R-,.~laxaU"--'I,-,--- Processes in Systerms with
Additional Para:.-,eters
a A mid 3 '.Tear the Curie point, using the -Uher--o-
dynamic theory of transitions of U~he second kind, we
have, accordin.- to L"hr-, above:
,r-yz 1
T~Kz ay
T-C ) z
where a. is the jump in
(3yz~)z Oft: ) Z
A generalization of the
of -,arameters leads to
bx )Z, C) =- (~xz
n=-1
at the Curie 7Doint.
above results to an arbitrary number
the followin.-, result:
1 +- iW-C YZ
n
(10)
+ iWTxz
n
Card ?/9

SOV/126-6-3-29/32
On the Thermod,-fnamic Theory of Relaxation Proces:3cs in Sy-Ste:,,S ',-rituli
Additional Parameters
No,u the variation of 1 with -time cat-inot be characteriscd
by a sinr':le rolaxation time, as .-;as the case with a sinr7-lo
parameter, since the approach of -the 71n to their equili-
brituin values, nn at constant x and y will be described
by the follo-viing expression:
t
0 Xz Txz
Tin = 71n 4_~ A~je k n =~ 11 21 ... I NI
k=l
X xz
where A;~,- are functions of T and the initial
Card 8/9

SOV/126-6-3-29/32
On the Thermodynamic Theory of Relaxation Processes in 3jf3te.-P.3 -,,-;ith
Additional Parameters
conditions. There are no fi,:~:-urcs, and 3 Soviet references.
3
ASSOCIATION: Institut fizi1ci met--liov Ural'sko-o filiala AN SSSR
U
(Institute of PhYsics of Metuals of the Ural# Branch of the
Academy of Sciences, USSR)
SUBMITTED: A-pril 16, 19-57.
1. ThermQdynamics--Theory 2. Thermodynamics--Mathematical analysis
3. Equa~dons of state--Applications 4. Phase transitions
Card 9/9

AUTHOR: Shmatov- V. T~
SOV/126-6-6-3/25
TITLE. Internal Friction and Absorption of Sound in Systems with
Auxiliary Internal Parameters (-Tnutrenneye treniye i
pog.loshcheniye zvuka v sistemakh s dopolnitelInymi vnuturenn-
imi parametrami)
1".EIRIODICAL: Fizi-ka metallov i metallovedeniye, 1958, Vol 6, 11Tr G_
pp 984-993 (USSR)
ABSTRACT, By an auxiliary internal parameter the author understands
a quantity which describes an internal property of a system
and is a function of state under eauilibrium conditions,
When the system is perturbed the return of the aux-iliary in-
Uernal parameter -q to its equilibrium value produces a lag,
which appears as an inelastic effect: internal friction and
absorption of sound. Internal friction may occur in systems
where 71 is the degree of lonc--rancre order (Refs.1-5), in
1'
substitutional (Ref.3) and interstitial (Ref.6) solid solut-
ions, where -q is the degree of the predominant, distribution
of atoms -produced by deformation, Internal friction may occu
also in antiferromagnetics where i1 is the degree of anti-
Card 1/4

SOV/126-6-6-3/?
Internal Friction and Absorption of Sound in Systems with Aw.,i?iary
.Internal Parameters
ferromagnetic order. Internal friction can be er-pected also
LD
in ferroma-neties, ferrites, ferroelectrics and piezo-elect-
rics, in which -q is, respectively, the spontaneous magnet-
ization, sDontaneous and forced electric polarization. In
internal friction occurs in systems with an auxil-
iary parameter whose change is accompanied by perturbation
of the system and in which perturbation of the system alters
the value of the auxiliary parameter. On propagation of
sound in a system with an auxiliary internal parameter, local
variations in the state of the system will produce relaxat-
-ional absorption of sound,since the system as a whole will
pass through non-equilibrium states. Such absorption of
sound occurs in liquids and in multiatomic gases. The author
calls acoustic absor-otion in solids - internal friction, and
acoustic absorption in gases and liquids - absorption o~ sound.
The paper gives a thermodynamic theory of internal friction
and relaxational absorption of sound in systems with auxilia-
ry internal parameters, Formulae are given for the magnitude
of internal friction and values of the velocity and the co-
efficient of absorption of sound in such systems. Near the
Card 2/4 point where a II-type phase transition occurs (if the latter

SOV/126-6-6-3/25
Internal Friction and Absorption of Sound in Systems with Auxiliary
Internal Parameters
is due to the existence of an auxiliary internal parameter)
a relationship is found between discontinuities of elastic
,rioduli and the value of internal friction, as well as a re-
lationship between discontinuities of the square of sound
velocity and the value of the coefficient of absorption of
sound, It was found that internal friction and absorntion
of sound reach their maximum values near the Curie point.
The results obtained for internal friction and absorption
of sound are of a rxeneral character and do not depend on the
C)
Card 3/4

SOV/126-6-6-3/25
Sorpt4on
Lr
interr -al Friction and Ab of Sound in Systems with Auxiliary
Intjernal Parameters
nature of the
This paper is
6 of which are
ASSOCIATION: Institut
(Institute of
USSR)
auxiliary internal parameters of the system.
entirely theoretical, There are 13 references,
Soviet, 2 German and 5 English.
fiziki metallov Ural'sko-o fi liala. AN SSSR
0
Metal Physics, Ural Branch. Academy of Sciences
SUBMITTED: June 18, 1957.
Ca2d 4/4

SWIVITOV, V.
SOV-3-58-9-25/36
AUTHOR: Piguzov, Yu,V,, Candidate of Technical Sciences, Moscow In-
stitute of Steel imeni I.V. S'Lalin
TITLE: Relaxation Phenomena in Pure Metals and Alloys (Relaksatsion-
nyye yavleniya v chistykh metallakh i splavakh)
PERIODICAL: Vestnik vysshey shkoly, 1958, Nr 9, PP 72-73 (USSR)
ABSTRACT: From 2-4 April 1958, an Intervuz Conference on the'Relaxation
Phenomena of Pure Metals and Alloys" took place at the
Moskovskiy institut stali (Moscow Institute of Steel). The
conference was attended by 196 representatives of 24 higher
educational institutions and 31 scientific-research institu-
tes (including 8 institutes of the USSR AS),,from 13 cities
of the Soviet Union. Doctor K. Mishek of the Prague In-
stitute of Technical Physics and Den Ge Sen of the Pyongyang
State University were also present. S.I. Filippov, Deputy
Director of the Institute of Steel,,opened the conference.
A reviewing report was delivered by B.N.Finqkelishteyn [Fftia-l in
*smw lretitube~ of Stee2). V.T. Shmatov (Institute of Physics of
the USSR AS in Sverdl~vsk) and N.S. Fastov (~Tsentrallnyy
nauchno-issledovatellskiy institut chdrnoy metallurgii (TsNIIChM)
.GAxdga*- Central Scientific-Research Institute of Ferrous Metallurgy)
reported on "Application of the Thermodynamics of An-Balenced Conditions."

AUTHORS: Skrotskiy, G. B., Shmatov, V. T. SOV/5~-34-3-32/55
TITLE: On the Thermodynamical Theory of Resonance z7aid Relaxation
Phenomena in Ferromagnetics
(K termodinamicheskoy teorii rezonan5nykh i relaksatsionnykh
yavleniy v ferromagnetikakh)
PERIODICAL: Zhurnal Eksperimentallnoy i Teoreticheskoy Fiziki,
1956, Vol. 34, Nr 3, Pp. 740-745 (USSR)
ABSTRACT: The present work shows the following: Using the thermo-
dynamical method of irreve-.'sible processes equations for
the time change of the magnetization taking into account
the spin-spin relaxation and the spin-lattice relaxation
can be obtained on very general and simple conditions .
Furthermore the influence of the spin-lattice relaxation
on the phenomena of ferromagnetic resonance are discussed.
The system of spin-moments responsible for the magnetic
properties of the ferromagnetic substances can, from the
thermodynamical point of view of be separated into on own
sub-system with the temperature T(spin-system). The
Card 1/4 residual degrees of freedom of the complete system are

On the Thermodynamical Theory of Resonance and Relaxation -,%V/56-34-3-32/55
Phenomena in Ferromagnetics
here considerad analogously to the thermodynamic theory
of paramagnetic relaxation (K~ Gorter, Ref 4) as a
thermostat the temperature T0 of which is in this work
regarded as constant. It can be shown that the last
mentioned condition will only slightly become manifest
in later given conclusions, and one can also easily free
oneself of this condition. The processes of the spin-spin
relaxation and of the spin-lattice relaxation in general
take place commonly, and they are also connected with each
other. In the case of a sufficiently fast change of the
field strength f? the sub-system of the spin moments will
be in e non-equilibrium state. The temperature T of the
sub-system and the magnetization M do not satisfy the
equation of state. In order to take into account the
internal relaxation the author puts down an expression
for the change of the entropy of the non-equilibrium state
of the subsystem:
TdS - dU-9d1T + (H H dM
Card 2/4

On the Thermodynamical Theory of Resonance and Relaxation
Phenomena in Ferromaonetics SOV/56-31;-~-.~2!55
U denoting the internal energy of the subsystem. For the
change of the enerey in the subsystem
it /dt
T d 6 S/dt = (H--' - dM
is found. An equation describes the time modification of
magnetization which is dependent on the gyroscopic
properties of the magnetic moment and the process of the
spin-spin relaxation. The characteristic feature of the
isothermal and adiabatic changes of state are shortly
shown. Then an expression for the amount of heat do,
is put down which is transferred from the spin system to
the lattice during the time dt. The specific heat of the
spin system is so great that a radiofrequency field with
small amplitude cannot noticeably raise its temperature.
Therefore the spin-lattice relaxation has only an un-
important effect and practically escapes observation. The
spin-lattic relaxation is neglected in the further con-
siderations. At temperatures far from the Curie point
Card 3/4 (T < 0 ) the external f4 eld 10 does practically not change

on the Thermodynamical Theory of Resonance and Relaxation
Phenomena in Ferromagnetics SOV56-34-3-32/55
ASSOCIATION:
SUBMI-TEMi
he amount of the vector of spontaneous magnetization
= its, but only its direction. The ferromagnetic
i
resonance is in weak fields very insensitive to the detailed
form of the equations used for its description. The one or
other form of the equations must only then be preferred
ahen non-linear effects are observed.
There are 11 references, 7 of -..hich are Slavic.
Urallskiy politekhnicheskiy institut
(Ural Polyteciinical Institute)
October 18, 1957
Curd 4/4

SHWOVY V. T., Candidate Phys-Mth sci (diss) -- "Cn the theinodyw-mic tj--eory
of rolaxation phenomena in SYstems vith Supplementary parameters". Sverdlafsk,
1959. 8 pp (Min Higher Educ URSP, LTral State U im A. M. Gor'kiy), 120 copies
(KL, No 22, 1959, 109)

/?. J? A 0 0 66606
AUTHOR: Shmatov V.T. SOV/139-59-3-28/29
TITLE: On the Papers of V.S. Postnikov on the Theory of Internal
Friction in Metals at High Temperatures
PERIODICAL: Izvestiya vysshikh uchebnykh zavedenly, Fizika,
1959, Nr 37 PP 174-175 (USSR)
ABSTRACT: Postnikov (Refs 1, 2) proposes a theory of internal
friction in metals at high temperatures. According to
Postnikov internal friction is due to directed migration
of vacancies in a field of stresses produced by extension
and torsional vibrations of the sample. The present
author criticizes in detail Postnikov's formulae, for the
following reasons. (1) Postnikov assumes that a uniform
elastic stress a in a sample (due to the weight of the
system producing torsional vibrations) both lowers and
increases the energy of formation of vacancies Ull which
is impossible since in this case only one effect may occurg
either an increase or a decrease of Ul (cri is a,scalar
component of a tensor). In addition to this erroneous
assumption, Postnikov takes the equilibrium number of
vacancies n t- be given by
Card 1/4

66606
SOV/139-59-3-28/29
On the Papers of V.S. Postnikov on the Theory of Internal Friction
in Metals at High Temperatures
The mechanism suggested by Postnikov for internal friction
due to motion of vacancies is physically inconsistent.
It is known that directed motion of vacancies in a field
of elastic stresses is possible only when that field has a
gradient, For the above two reasons, Postnikov's formula
for the amount of energy scattered by elastic vibrations
in a sample, given by Eq (1), and his formula for internal
friction, given by Eq (13), are both in error. The
physical meaning of the coefficient of proportionality a
which is very important in internal friction, is not given
at all. (3) kt the end of his second paper (Ref 2)
Postnikov discusses relationship between the rate of
diffusion creep and internal friction. Here again the
same error is committed: forced diffusion of atoms is
considered "in the direction of action of Ci stresses"
and such diffusion does not in fact occur. It is known
that forced diffusion of atoms in that sensa can be
produced only by a gradient of elastic stresses and not by
Card an elastic-stress field itself. It follows that
3/4 re
Postnikov's results on creep and internal friction a ,~

66606
SOV/13 9 -59-3-428/2Q/
On the Papers of V.S. Postnikov on the Theory of Internal Friction
in Metals at High Temperatures
also untenable. It is quite likely that internal
friction in metals at high temperatures is related to
vacancies but an interpretation different from that of
Card Postnikoir is required to explain the facts.
4/4 There are 2 Soviet references-
This is a slightly-abridged translation.
ASSOCIATION: Institut fiziki metallov AN SSSR
(Metal Physics Institute, Ac. Se. USSR) LIK
SUBMITTED: March 31, 1959

67708

-1UTHOA. ~,hmatov, V.M-. ~-10V/126-7-3-1/44
2

in Substitutional
On the The ory of Internal Fri ct
ia
and Interstitial Solid Solutio s lli~
Fizika metallov i metallovedeniye, 1959, Vol 7, Nr 3,
PP 321-330'(USSR)
In Ref 1 the present author has derived formulae for the
in-1U-e:aia1 friclion for systemc; .-iith additional parameters
on the basis of general thermodynamic ideas. In the
special caZe of a sin,-,;le additional parameter the
inte.raal frict-ion in an isoth-xrmal -Dre~ess is given by
;~q (1), where w is the frequency, r is the
relaxation time of the additional parameter at constmt'

U
'4cfoi~mation (e) and tef-'werature (T). The degree of
-
i-elaxation of the isotherm, 1 elastic modulus A ma-v be
redUCed ~.o the form Given by Eq (2), where El is the
non-relaxin6 part of the modulus (Ref 1) and (1/E)" is
the addition to the value o-F' Mrie reciprocal modulus
due to degrees of freedom associated with the existence
of an additional parameter. In solid substitutional
solutions and alloys -~,iith long--ra-nn,e order these
X
Card 1 /4 additional -Parameters are the de~,ree of -oreferred
0 - LI

67708
'30V/126-7-3-1/44
on the Theor-j of Internal 2riction in ~_.'ubstitutiortal and
Inter.,~titiul -,,'olid 3olutions
diuuribut_~on of thc: substituted atoms and the degree cif
loni,-ranSe order respectively. if (TV0,ij) is the
non-equilibrium thermodynamic DotentialT, then in
e cuilibrium:
~) _q (T~ 0 (3)
and hen,~e one can obtain the additional parameter -n
as a function of a and T (Eq 4). If Eq (5) is
differentiated_~;wice with respect to 0 one obtains
Eq (6), where MMO is the eQuilibrium thermodynamic
potential and 1/E'. A comparison of Eqs (3) and
II~q M-and it then follows from Eq (6) that
is given by Eq (8). If the identity given by
-L!Ici (5) is differentiated twice with respect to
temperature, then using Eq (7) one obtains the expression
for t-he specific heat due to degrees of freedom associated
0
Card 2/4 'ith the existence of the additicaal -oarameter which is
given by Eq (9). A combination of Eqs (8) and (9) gives

67708
S OVA, 2C-)-?--3--L'/44
On -chlo. Theor
y of Internal FriQtioa Jn Substijutional and
Interstitial Solid Solutions
correct. Instead,the relaxation time given by Eq
of the present paper should be used. U -
f2here are 1 figure and. 25 references, 11 of which
..~)oviet, 8 English, .3 German and 3 Inte-Pnational.
A.860CIATION: Institut fiziki metaliov AN SSSR
Physics of i-..,,eta1s,Ac.Sc., USSR)
April 25; 1958
(29)
are
(Insti-uute of
Card 4/4

_~ Q
;?-j 00 67751
19 60 sov/!26-8-5-3/29
AUTHOR; Shmatov, V.T. I
TITLE: Relaxational Absorption of Ultrasonic Waves in
Ferromagn_qLi.qsjk
PERIODICAL: Fizika metallov i metallovedeniye, Vol 81 1959, Nr 5,
pp 667-670 (USSR)
ABSTRACT: Using the thermodynamic -theory of relaxation phenomena
(Refs 1, 2), formulae are obtained for the absorption
coefficient and the dispersion of ultrasonic waves in
ferromagnetics. For longitudinal vibrations, the
com lex velocity of sound of frequency t,,~ is given by
Eq M (Refs 2, 8), where Co is the usual Laplace
velocity of sound, .)raS and -reS are the relaxation
times for the degree of ferromagnetic order y at
constant stress a, deformation 6) and entropy S.
Using this expression, it can be shown (Refs 1, 3) that
the velocity of sound and the absorption coefficient
are given by Eqs (2) and (3). The degree of relaxation
of the adiabatic Young's modulus can be written in the
Card form given by Eq.(4), where ET is the isothermal
115 Young's modulus) E'T is the non-relaxing part of
Young's modulus, i.e. that part of the modulus which

67751
SOV/126-8-5-3/29
Relaxational Absorption of Ultrasonic Waves in Ferromagnetics
does not include the contribution due to ferromagnetic
order, ca and k,-, are the specific heats, and cla
and cl, are the specific heats not including the
effect of ferromagnetic order. Since the ratios of
the moduli and the specific heats are close to unity,
Eq (4-) may be replaced by Eq (5), where WET)" is
the contribution of the ferromagnetle order to the
magnitude of the reciprocal of the isothermal Young's
modplus. The second term in Eq (5) is of the order of
.10-4 and hence the degree of relaxation will be
determined by the first term only. It is clear from
Eq (3) that -when W-tcS = 11 the absorption of sound will
have a resonance character. The degree of relaxation of
the isothermal Young's modulus can be expressed in terms
of the degree of ferromagnetic order using Eq (6) which
was obtained by the present author in Ref 10, where c"a
is the additional specific heat due to the existence
Card of ferromagnetic order. Using the Weiss theory (Ref 3)~
2/5 one has Eq ( 7) , and hence Eq (8) , where G) is the Curie
temperature, k is Boltzmann's constant7-and N is the
number of uncompensated spin moments per unit volume . L4/

67751
SOV/2-26-8-5-3/29
Relaxational Absorption of' Ultrasoni-- Waves in Ferromagnetics
As can be seen from Eq (8), the degree of relaxation,
and hence the absorption of sound at frequencies given
by #,WES1 increases with increasing temperature and
reaches a maximum at the Curie point at which Eq (9)
holds. If the ferromagnet is placed in an external
magnetic field H, then instead of Eq (7) one has
Eq (10) (Ref 3), where & is the Bohr magneton.
Hence, using Eq (6) one finds that in this case the
degree of relaxation is again given by Eq (8) but now
the degree of ferromagneti,3 order is a function of the
external field7 and hence the degree of relaxation is
determined not by the spontaneous magnetization but by
the true magnetization. However, the increase in the
magnetization due to the external field is small and
does not play an important part in a wide range of fields
and temperatures. The effect of the external field
need only be taken into account near the Curie point.
The shortcoming of the Weiss theory is the fact that it
Card neglects ferromagnetic order at short distances. if
3/5 this approximation is removed,, one obtains (Refs 3, LO
instead of Eq (7) the expressions given by Eqs (11) and

67751
3OV/126-8-5-3/29
Relaxational Absorption of Ultrasonic Waves in Ferromagnetics
ASSOCIATION: Institut fiziki metallov AN SSSR
(Institute of Physics of Metals, Aca4_qmy._of-
6ciences USSR)
SUal'ITTED: January 19, 1959. e
This is an abridged translation.
Card 5/5

311M&TOV, Y.T.; GRINI, A.V.
Mechanism of the occurrence of internal friction imvurities
peak. Fiz.met.i metalloved. 8 no.6:829-833 D 159.
(MIRL 13: 6)
1. Institut fiziki metallov AN SSSR.
(Internal friction) (Alloys-Metallograpby)

67657
SOV/126-8-6-4/24
AUTHORS: ShS~~~ ~ and Grin', A.V.
TITLE: The Mechanism of Formation of an Impurity Peak of
Internal Friction P
PERIODICAL:Fizika metallov i metallovedeniye, 1959, Vol 8, Nr 6,
pp 829-833 (USSR)
ABSTRACT: In polycrystalline pure metals only one internal friction peak
is observed at high temperatures. Since such a peak is
absent in monocrystals of pure metals, its appea a
ascribed to relaxation at the grain boundaries.1v hen
impurities are introduced into pure metals, an additional
internal friction peak appears; it is known as an
impurity peak. From the systematic investigations of this
impurity peak, carried out by several workers (Ref 1 to 5),
the authors draw the following general conclusions:
(1) Even small amounts of impurity (0-03 atomic %. Ref 3)
may produce an impurity peak of internal friction.
(2) On increase of the impurity concentration the impurity-
peak height generally rises but in certain alloys it
reaches a maximum and then falls or even disappears
completely (Ref 6) at higher impurity concentrations.
Card 1/3 (3) The activation energy of relaxation processes

67657
SOV/126-8-6-4/24
The Mechanism of Formation of an Impurity Peak of Internal Friction
responsible for the impurity peak is close to the
activation energy of diffusion of atoms, provided the
impurity concentration is sufficiently great.
(4) With increase of the impurity concentration the
internal friction peak due to relaxation at the grain
boundaries (observed in pure polycrystals) is depressed
and may disappear altogether (Ref 1 to 3, 6).
(5) The impurity peak is found only in polycrystals and not
in monocrystals and consequently, just like the peak
observed in pure polycrystals, it is due to processes
occurring at the grain boundaries.
(6) The magnitude of the impurity peak is only slightly
affected by the change in the mean grain dimensions (it
falls gradually with increase of these dimensions; Ref 3
and 6). In contrast, the relaxation time related to the
impurity peak depends strongly on the mean grain dimensions,
rising rapidly with increase of the latter. The
experimental observations summarized in the above six
points can be explained as follows. Impurities are
concentrated predominantly at the grain boundaries becaus
Card 2/3 the energy of distortion by an impurity atom is lower at IV

67657
SOV/126-8-6-4/24
The Mechanism of Formation of an Impurity Peak of Internal Friction
the grain boundary than inside the grain. Elastic
deformation which alters this distortion energy would
either favour or obstruct accumulation of impurity atoms
at the grain boundaries. Consequently if such
deformation is varied periodically the impurity atom
concentration at the grain boundaries will also vary
periodically. If elastic deformation alternates
sufficiently rapidly the changes of the impurity
concentration will not manage to follow elastic
deformation and this will, of course, lead to dissipation
of elastic energy, ie to an impurity peak at appropriate
frequencies. The authors discuss this mechanism
mathematically and show that it explains satisfactorily
the experimental data summarized in the points (1) to (6)
above. The paper is entirely theoretical. There are
10 references, 4 of which are Soviet, 4 English and
2 international,
ASSOCIATION: Institut fiziki metallov AN SSSR (Metal Physics
Institute,AS USSR)
SUBMITTED: April 15, 1959
Card 3/3

/'q TO V V. T.
PHASE I BOOK EXPLOITATION SOV/5305
Moscow. Institut stali
Relaksatsionnyye yavleniya v metallaldh i splavakh; trudy Me.zhvuzovskogo
soveshchaniya (Relaxation Phenomena in Me!tals and Alloys; Transactions of the
Inter-Inst.i.tute Conference) Moscow., Metallurgizdat, 1960- 326 p.
Sponsoring Agency: Ministerstvo vysshego i srednego spetsiallnogo obrazovaniya
RSFSR and Moskovskiy institut stali imeni I.V. Stalina.
Ed. (Title page): B.N. Finkellshteyn; Ed, of Publishing House: Ye.I. Levit; Tech.
Ed..- A.I. Karasev.
PLJRPOSE -: T~iis collection of articles is intended for personnel in scientific insti-
tutions and schools of higher education and for physical metallurgists and
physicists specializing in metals. It may also be useful to students of these
fields.
COVERAGE: The collection contains results of experimental and theoretical inves-
tigations carried out by schools of higher education and scientific research

705
Relaxation Phenomena In Metals (Cont.) SUV/5'
institutions in the field of the relaicatidn ~ phenomena in metals and alloys.
Several articles are devoted to the investigation-by the Internal-friction
method-.-.Ait uti, t -,~i
7
IA

"nc
-ctra and lialochromism of Di-(2-dimethylamino- S/079/60/ 030/04/7 0/060
;'YI-._d,,I) thane BOOl/BO1 1
d,.c:_.qvative on the methane bond, and 2) by oxidation of this compozind
into the corresponding carbinol and subsequent salt formation re_actioxi~ In
order to establish the true cause giving rise to the formation of the co-10-r-
ation, the authors made a spectrophotometric investigation of this phencrien,-n.
The determination of the absorption spectra of alcoholic and sulfuric acid
oolations of 2 -dime thy lamino-5 -pyridyl carbinol; of di-(2-direthylami;n')-r-
pyrid~l)-carbinol and di--(2-diriethylaraino -pyridyl)-methane revealed that th=
-5
absorption spectrum of the acid solution of the first COLI-OtInd (Flua I) ~Iif__
fers little from the one of its alcoholic solution, whereas for the sec,--;nd
compound (r.ig, 2) there is a considerable difference between the curves, of
the acid and the alcoholic solution, There is a considerable difference R-1-so
beti,een the curves of heterocyclic methane derivative (Fie. 3), Thusi the
,:)ccurrence of a red coloration on the dissolution of the above methane in h.:A
sulf'tiric acid is to be explained by the formLtion of a dipyridyl carbor.-Jum
sa-l-', (1;~st scheme). There are z, fig"re.s ,--nd lit references, & of which ar;~
Soviet.
ASSOCIATION:
KharIkovskiy t-asudarstvennyy univeraitet (Kh_ar`ko-v State
University)
Card 2/3

MAMONTOVSKIY, Ivan Aleksandrovich; Sf 'I~WEVKA, Semen Matveyevich;.
KLOKOV, B.K., nauchn. red.; SOROKINA, M.I., red.;
NEa',YSLOVA, L.M., tekhn. red.
[Mechanization of winding, insulating~ and stamping
operations in the manufacture of asynchronous motors]
Mekhanizatsiia obmotochno-izoliatsionrqkh i shtampo-
vochnykh rabot pri proizvodstve asinkhronrjykh elektro-
dvigatelei. Moskva, Proftekhizdat, 1963. 109 p.
(MIRA 17:1)

Category USSR/Optics Physical optics
Abs Jour Ref Zhur - Fizika, No 1, 1957,No 24oo
Author Klimovskaya, K.L., Vishnevskiy, V.N., Sbana evskiy, V.Ye.
Title On the Glow of Hydrazide of Tti-aminophthalic Acid
Orig Bib Izv. AN SSSR, ser. fiz. 1954, 18, No 6, 694-695
Abstract No abstract
K-5

KLIMOVSKAYA, L.K.; S124AYLTSKIY, V.Ye.
I -
Investigation of chemiluminsacefide. Dop. ta pov. Llviv. un. no.5.
pt.2:78-79 '55- (VT.RA 9:10)
(Luminescence)

SM4AYEVSKIY, V.Ye.
. . - -DliYii9l-fru8tuations of Ca/Cb in wheat. Dop. ta pov. Llviv.un.
nji;6 pt 2:67-68 155. (MIRA 10:3)
(wheat) (Chloropby-ll)

Sfh!AYEVSKIY, V-Yo.~ YASIPISKAYA, A~A.,
Using the direct current bridge for measuring the electric
conductivity of ore minerals on the site, I-Iiln.sbor. no.14:
371-373 760. (JAJRA 15.2)
1. Gosudar6tvenn-yy universitet imeni Ivana Franko., Lvov.
(14inerals-Electric properties)

.-)O-IQ
~ ~ -L,
1/ 0 11/002/0 22/0 25
~/_3 3 9 S-/ // .9 3 E'O _7 3/ E 3 - 5
AUTHU1,16 G.L J.'k e 1,a V~ Ye, and Vadets, D. 1.
'PIT LE, - oi tiie Iseudobinary Section ZnSb-CdSb
by thp. Debye Method
I'L1116L)ICAL J-'i-6jka iwitallov i m(italiovedeniyej 1961, Vol. 11,
No. '21, jqj~ 311 - '~13
TEXT . Tilic p~icudobinary section bets%reen the two semiconductor
co%i1jounds ZnSb and CdSb contains a number of semiconductor
alloys (Refs. 1. 2)~ Only the extreme compounds of this section
have been investigated by X-ray structural analysis, namely,
tkie compounds ZnSb and CdSb (K.E., Almin, Acta chem.scand~g
1946, 2, 400 - Rel, 3)~ The work described in this paper is a
fXrSt attempt to apply X-ray btructural analysis for investi-
gatin-, the entire -3ection under coiisideration- As starting
materials 99-()()9 ana: 99,99~u Sb .,.rere used,, According to spectrum
ailaiysis the Cd iias the following: admixtureslb thousandths 5o;
Cu tenths '5.-. Ag hundredths 5o and Ca tenths '/a, The materials
Were 'treighed with an accura.-.y of I mg and mixed in the ratios
enumerated Ln Table I ktile Second and t1ii-rd columns give the
Card 1/7

!-,/126/61/011/002/022/025
lavestigation of E073/E335
composition III III(Ac!CtIlar totix Eli and fifth columns in
weight ~J Fu.4Lon wa:i carried otit in porcelain crucibles in
an electric nitifile f'urn-tce under a flu-: consi tin o mixture
S g f a
of KC1 and NaCi. The inelt was intensively mixed with a graphite
rod and then Leemed in an iron mould, Liotuogenisation was
effected in sealed pyrex ajiipules (,these were first evacuated
to lo to 10 Mill 11g.) and following that for 100 hours at
2110-~~70 0C~ Fr(-,::: the horiogen-ised alloys powder was produced 0
wha.c~i was tempered in evacuated sealed glass ampules at 200 C
for ~O hokir.~i, whLch were then allowed to cool down with the
furnace, From the thus-produced powder. 0.9 mw dia. cylindrical
specimens were produced, The investigation was by means of
j;: (URS-70) apparatu6I 11hins copper radiation without a
filters A -,/olta-ge of 35 kv~ 11 curretiL intensity of 12 mA
were applied to the tube, the exposure time being 7 hours.
The chamber diaincter was 66 inin, Under equal conditions, X-ray
patterns oi the starting components were produced. The
distance between idenLical lines of the diffraction patterns
Card 2/7

Il,'073/E335
ij..'.restigilt loll Of . . . .

ct~,*
Tall
(;OCT"!u 06paMa, nec.
,JO.ICK. Vu
o6pa=ll
Z119b CdSb
Z.,Sb CdSh_ ZnSb' CdSb
IGO 12,2
Io
20
7612 2 3 's

'
80 14 9
~
4 70
35
6
59.7 U,3
5
6 40,
~~ 5-1.5
4
49
45
-,5 -
0 ,
44,4 515.6
3
-
55 39,5
'
9 -1.
) 2
65
40
G5 69,9
I 1 35 70
30 25,5 74,5
3
83
12 so
20 16,7 ,
s
91
,3
14 10 go 8,2 '
No
15. Iro
C;ird 3/7

s/126/61/011/002/022/025

Table 2:
Tadnitan 2
3tin citito nocionimbix PCWQTKI(, KX

o~:P=a
1 6,145 7,715 7,805 370,085
2 6,170 7,750 7,695 377,470,
3 .6 190 7,785
1 7,945 383,060'
4 6: 23 0 7,840 7,965 389,235
5 6.245 7,865 7.99b .392,915
6 6.250 7,910 8.0,15 397,79b
7 6,290 7,970 8,070 404.690
8 6,295 7,975 8,075 405,460
9 6,310 8,005 8,110 409,660
10 6,310 7, 985 8,100 40S,045
I 1 5,330 5,053 8,135 414,620
12 6
~.Io
8, 065
8,155
417,035
3 6 375
: 8,125 8,195 424,3c)5
4 G,.-.CO 8,175 8,240 431.090
15 5,415 8, 200 8,255 434,210
C, I rd "1/7

20219
s/i2t,)/61/011/002/022/025
Investigatiult of E073/E335
was mea-surcd with an accuracy up to G~ I nim. The relative
iiitensitv (--)f Ulir, iiijes was Gleterinined visually by means of
a lo-unit scale, i'ecordiiig (identilication) of the X-ray diff-
raction patterns oj_ ZnSb azid CdSIj was by the method of selection.
Ttle Obtai'lled 11 It III ILlklice~~ did not cwradict tile conditions
of extinctiorl ior the space group D, h -1.) bca No Cd, Zn
and Sb Linf!s were detected oil tile X-ray diffraction patterns.
Comparison of tjit~ X-ray diffraction patterns of ZnSb and CdSb
with those of iMerii,,ediate alloys ha-s- shown 'hat throughout
the entir(! SeCLIon tile structure of triese alloys does not
change artt-I the saTac applies to the space group, This fact
enabled choosing indices for the diffraction patterns of the
alloys of Eli,.! critire ZnSb-CdSh section on the basis of the
ratio of' the ixiterisitie~s ui the lines and the interplane
distances.. The lattice constants a, b. c were calculated
by the wethod of* least squares on the basis of general
indices for all tile alloys starting from C-,. = 25* . The
calculated lattice consLazits and the determined volume of the
elenientary ceil for all the alloys are entered in Table 2
Card 5/7

6/126/61/011/002/022/025
Inve s t:L gra t i o a o I E073/E335
( la t t i r- e C C, 11 S La 11 t. kx) I'lle, accuracv of the determinations
was, 0,005 kX., TIJQ obtaiiLed 3:-e-sulls, presented in plots as
functions oi tilie lattice parameter ; Fig. l,and of the
elementary volume . Fig. 2 , on the CdSb concentration (molec%),
are curves witn , hardiy noticeable bend for a concentration
of about j(-: Zn.,~b- Tlt-t5 leads to the assumption of
a proce-9-9 of orticring of the so-Lid solution,
'rherc- are. 2 t igures , ~2 tables and i references
2 Soviet aiiti I ixon -6ovie t ,
ASSOCIATJuN~ L N-ov-ikiy gosudarstvennyy universitet
ini Iv. Franko (1-:vov State University
iin- Iv- Franko)
6UBI,JTTED~ June 27. i960
Card b/7

S/165/62/007/003/006/015
,.e_-.moeIect-.JLc and electrical ... D299/D301
decreased with increasing temperature; 6 first decreased and then
s-,rted to increase. The effect of the heat treatment on the properties
cf srecimens, is shown in graphs. From the temperature dependence
3f t~-.e srecimens it is i)ossible to determine tile dependence of .--.-and ~-k on
ation of t*,
c ~"C e 11-1. r ne components at various temperatures. With ;0
Cd"b, %,
-.1 . orderinC; of the solid solution takes place a' temperatures
uve of the temDera'ure-dependence curves, obtained
it COMPLIXISOr.
autillorsy with those obtained by other investigators, shows that
I.e Drocedure used in the present investigation yields a higher degree
0 order-Jrg. This is also confirmed by the sharper extrema of the curves
~as compared to those 'in the references). There are 4 figures, 1 table
arka 5 references: 4 Soviet-bloc and 1 non-Soviet-bloc. The reference to
-1.,e En~,114s'n-lan6-uage publication reads as follows: K. Toman, j.Phys, and
Cne.-.. Solids, 1 1 , no. 3-4, 2, 1959 -
.1SSOC-_.,TIOII: LIvivs1kyy derzhuniversytet im. Ivana Franka (LIviv State-
University im. Ivan Franko)
August 206, 1961
Card 2/12

ACCESSION NRs Ap4oo9393
S/0126/63/016/006/0941/0943
AUTHORSt Shmayevskiyj V. Yes; Mikolaychuk., A. G.
TITLEt Electrical conductivity and structure of thin ZnSb-CdSb film
SOURCEt Fizika metallov J metallovedeniye, v. 16, no. 6. 1963) 941-943
TOPIC TAGS: thin film,, film, metal fi-Im, ZnSb CdSb thin film, thin film structure,,
thin film electrical conductivity, electron diffraction photograph,, film electron
diffraction pattern., ZnSb CdSb electron diffraction pattern, MM 4 megohm meter,,
MVU 49 bridge
ABSTRACT: This work was carried out in order to study the structure of ZnSb-CdSb
films and the relation of electrical conductivity to temperature in this material.
I
These thin films were vacuum-precipitated on a series of cold glass, chemically
cleaned plates. The electrical conductivity of the precipitated metal layers
was measured in air with the use of a MVU-49 bridge and a M14-4 megohm-meter. The
results obtained are presented in Fig. 1 and Fig. 2 of the Snelosure. It was
established thatt 1) the relation of electrical conductivity of films to metal
concentration was similar to that of massive polycr7stalline samples; 2) in all
1/1';-
_70-71 - 7

ACOMSION NR: AP4009393
the varieties of metal concentration studied here., electrical conductivity in-
creased with the increase in temperature; 3) high conductivity observed in the
1,.,-samples rich in CdSb was explained by a partial decomposition of this compound
(during the precipitation process) into the components Cd and 5b; 4) the electron
diffusion patterns obtained immediately after the metal precipitation had diffused
lines-
this was explained by a certain degree of structural disorderliness (the
lines became well defined again after the samples were heated at 120-150C for 30
min); 5) the structure of thin films was of the type ZnSb. The lattice parameters
decreased with the increase in ZnSb concentration; 6) the structure of CdSb was
studied in order to check the possibility of its decomposition (into Cd and 5b)
during precipitation. No lines corresponding to Cd or Sb were observed. Orig. art.
hast 2 figures.
ASSOCIATION: Llvovskiy ordena Lenina gosuniversitet im. I. Franko (L'vov State
University)
SUB!-aTTED t 23Feb63 DATE ACQt 03Feb64 EINGLt 01
SUB GODSt ML NO REF SOVs 013 OTHERs 005
Card

i r