SCIENTIFIC ABSTRACT SHAKHPARONOV, M.I. - SHAKHPARONOV, M.I.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001548410004-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Critical Phenomena and Fluctuations Sov/5469
High-Pressure (Studies], GIAPJ. Kinetics of Heterogeneous
Processes In the Critical Region 54
Krichevskiy, I. R., N. Ye. Khazanova, and L. R. Linshits (Lab-
oratory of High Pressure [Studies], GIAPI. Liquid-Vapor
Equilibrium in the Critical Region of Liquid-System Strati-
fication 61
Lomova, N. N, and M I. ShaKhp4,r_qqoy [Labor4tory of the
Physical Chemistry of-8~6_luitions, Chemistry Division, Moscow
State University imeni M. V. Lornonosov]. Permittivity and
Molecular Structure of Solutions 73
Lanshina, L. V., and M. I. Shakhparonov (Laboratory of the
ao___6h_enff6-try Division, Moscow
Physical Chemistry of lutions,
State University imeni M. V. Lomonosov]. Thin Structure of
the Line of Rayleigh Light Scattering in Solutions 77
Mokhov, N. V., and Ya. M. Labkovskiy (Kafedra dcsperimentallnoy
fiziki Dnepropetrovskiy gosudarstvenrWy universitet -- Depart-
Card 5/9

Critical Phenomena and Fluctuations- , SOV/5469
Roshchina, G. P. [Laboratoriya molekulyarnoy fiziki, Fizi-
cheskiy fakul'tet, Kiyevskiy gosudarstvennyy universitet im.
T. G. Shevchenko -- ' Laboratory of Molecular Physics, Divi-
sion of Physics, Kiyev State University imeni T. G. Shevchenko]
Investigation of Fluctuations in Solutions by the Method of
Light Scattering log
Skripov, V. P. [Laboratorlya molekulyarnoy fizikilUrallskiy
politekhnicheskiy institut im. S. M. Kirova -- Laboratury of
Molecular Physics, Ural Polytechnic Institute imeni S. M.
Kirov]. Special Structural Features of Matter in the Vicin-
ity of the Critical Point and Transfer Phenomena 117
Skripov, V. P., and Yu. D. KolDakov [Laboratory of Molecular
Physics, Ural Polytechnic Institute imeni S. M. Kirov, and
the Laboratorlya teploflzikiUrallskiy filial AN SSSR --
Thermophysics Laboratory, Ural Branch, AS USSR]. Light Scat-
tering in Carbon Dioxide along Pre- and Post-Critical Isotherms 126
Smirnov B. A. (Institut neflvekhimicheskogo sinteza AN SSSR --
Card 7/9

Critical Pher-cmena and Fluctuations S CV/546 9
Shimanskaya, Ye. T., Yu. I. Shimanskiy, and A. Z. Golik [Lab-
oratory of Molecular Physics, Division of Physics, Kiyev
State University imeni T. G. Shevchenkol. Investigation of
the Critical State of Pure Sub3tance-s by Tepler's M_atfhod 171
Re2clution of the Confer_-nce on Critl.,~al Phenomena and Flul~-
tuations In Solutions _389
AVAILABLE: Library of Congress (QD545.S73)
10-28-61
Card 9/9

3/!89/60/000/003/006/013/XX
B004/Bo67
AUTHORS-. Lomova, N, N, Shakhparonov,--IA,. I.,
I ____
TITLE: Dielectric Constant and Molecular Structure of the
Solutions of Nitrobenzene Iin Hexane and Cyclohexane
PERIODICAL: Vestnik Moskovskogo universiteta. Seriya 2., khimiya, 1960,
No 3, pp,. 11-17
TEXT: In an earlier paper (Ref. 1) Shakhparonov showed that in the case
of strong deviations of the solutions from the ideality, their
experimentally determined macroscopic dielectric constant must be smaller
than the local dielectric constant measured in a smaller unit volume of
the solution. The present paper deals with the examination of this con-
cept in nitrobenzene solutions in nonpolar solvents (n-hexane, cyclo-
hexane). The dielectric constant E was measured at approximately 700 ko/sec
by means of a "VIE11-1 (IIYeV-1) apparatus Furthermore. the authors
determined the density t and the refractive index n The experimentally
N D-
found negative deviation of F, from the addLtivity was caused by the con-
Card 114

Dielectric Constant and Molecular Structure s/i eg/'6o /oo' loi VXY
of the Solutions of Nitrobenzene in Hexane B004/Bo67
and Cyclohexane
cencration fluctuations- In the region of the separation of the solution
into two layers with a volume portion Y of nitro0enzene of 0,26 to O~45
(in n-hexane) no maximuir of ~- was founA in contrast to the observations
made by other scientists (Ref. 3) The curve L= f(t) is almost linear
and changes its direction only near the disintegration temperature- In
Fig, 4 C-10- - the intensity I of the Rayleigh scattering at A = 5780 A,
c k
and the fluctuation (Ap)2 of the concentration are represented as a
function of the nitrobenzene content in n-hexane at 400C- E- --f- and
loc
(~j p)2 are only little temperature-dependent. For the different position
of the maxima of Ik and (L ~) the following explanation is given: while
Ik is mainly due to fluctuations whose linear dimensions are more than
1/20 of the wavelength of light, i.e., at least 20-30 A, ')2 depends
(A f
on the fluctuations which are not -reater than twice or three7times-the
diameter of a molecule A calculation of the function Ce572 f(y) on
the basis of the statistical theory of the fluctuation c6nfirmed this
conclusion. The data for nitrobenzene in cyclohexane led to the same
Card 2/4

Dielectric Constant and '.1olecul-ar 'XY
of the Solultiors of Nitrobenzene in Hexane B004/3067
and "yelahex6ne
conclusions. There are 1, --Figures, 3 tables, and 5 references- 4 Soviet and
I Us.
ASSOCIATION: 1NIos'r-.ov3k-iY gosudarstvennyy universitet im. M-V. Lomonosova
I 110scow State University imeni
kafedra fizicheskoy khiwii (7,
1-1. V. Lomonosov, Chair of Physical Chemis-try)
SUBI~j!TTED: August 28, 1959
LeEend to Fig. 4: 1 and ~)2
loc k as function of the concentration
of nitrobenzene in n-hexane at 400C.
Card 3/1
A

S/189/6o/ooo,/o,~,/'-)"4-/013/X -X . I
B004/3067
C.41-
CAR I
5
0
C,H.
f'-*-
N'. 4. '
, IC

S/030/60/000/05/38JO56
B011,51BOOS
AUTHORS: Kriohevakiy, 1. R., Doctor of Chemical Soiences,
Doctor of Chemical Sciences
Shakhparonovy
TITLE, Critical Phenomena and Fluctuations in Solutions
PERIODICAL- Vestnik-Akadem'"i nauk SSSR, 96o, No. 55; pp. 96-99
TEXT. A Cbnference*on the above mentioned problems,, which was convened by
the Otdeleniye khimichesk:!JLAII nauk Akademii nalok SSSF (Department of Chemical
Sciences of the Academy of Sciences USSR) and the khimioheskiy fakulltet
Moskovskogo universitets. (Chemical Department of M-.sccw Universit ), was
held from JarTaary 26 to 28j 1960, 1z was attenaea by approximately 150
physicists and physicochemists from vario el s cities of t-he SovietUnion.
The reports dealt with the thermodyramics~~of critical phenomena, the
statistical theory of the s(~Iufl`cns ii _i5E4 critical range, the thermo-
dynamics of irreversible processes in the critical range, the fluctuations
in solutions, and other problems,. A. Z. Golik, Yu~ 1, Shimar-F-kiyj and
Ye. T. Shimanakaya (Kiyev) reported an in-v-e-stigations of the critical
state of pure materials and scluttjons according to Teplers method.
Card 1/4

Critical Phenomena and Fluctuations in 3/030J60/000/05/38/056
Solutions B015/B008
1. R. Krichevskiy, H. Ye. Khazanova, and L. R. Linshit5 investigated the
dependence of the chemical potentials of t5e compone of binary and
ternary systems of compound and temperature. V. P. Skripov and Yu. D.
Kolpakov (Sverdlovsk) reported on the investigation results-of light
dispersT-on in the supercritical region of carbon dioxide. I.R. Krichevskiy
and N. Ye. Khazanova referred to problems of the diffusion-lin liquid and
gas solutions near the critical point. L. A. Rott FMi-ng-kTreported on
the theory of diffusion near the critical point of separation into layers.
V. P. Skripov explained the course of viscosity near the critical point
on the basis of a "Colloid Model". I. R. Krichevskiy and Yu.V. Tsekhanskqya
reported on the investigation of convective diffusion. D. K. Beridze
described the investigation results of light dispersion in the range of
the critical point of the separation into layers of the solutions nitro-
benzene - hexane, nitrobenzene - heptane and methyl alcohol - cyclohexane.
V. F. Nozdrev reported on investigations with ultrasonics in liquidsnear
the critical point. After a discussion on the critical state, the Con-
ference came to the conclusion that there is no reason at present to
reject the classic thermodynamic theory of the critical phenomena, developed
by Gibbs, A. G. Stoletov, and other authors. M. I. ShakhDaronov reported
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Critical Phenomena and Fluctuations in S/030~60/000/05/38/056
Solutions B015/ ~008
on the main results of his investigations in the field of the theory of
fine-structure fluctuations with a small particle content. N. N. Lomova.
M. I. Shakhparonov, R. M. KasimoV9 and Ya. Yu. Akhadov reported on the
results of experimental investigations of dielectric properties of solu-
tions. L. V. Lanshina mentioned measurement results of the fine structure
of light dispersion in acetone - water- and water - metbyl alcohol
solutions. X. F. Vuka and L. 1. Lisnyanskiy (Leningrad) cond ted investi-
gations of fluctuation phenomena in the solutions of ridine and
a-picoline in water, as well as of pyridine in alcohols. G. P. Roshchina
(Kiyev) mentioned data of experimental investigations of light dispersion
in solutions, as well as of the conclusions on the dependence of fluctua-
tions on composition, temperature and type of the molecules of the solu-
tion components.'L. P. Zatsepina reported on the light dispersion in
individual liquids and solutions with photoelectric measurements, and
established in this connection the conformance with the theory by Einstein-
Smolukhovskiy. N. V. Mokhov, Ya. M. Labkovskiv, and I. V. Kirsh
(Dnepropetrovsk~_reported on' 'I~e_irinvestigations of fluctuations of
density in ether and benzene, as well as of fluctuations of concentration
in carbon bisulfide - methyl alcohol solutions. The Conference confirmed /
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Critical Phenomena and Fluctuations in 51030V6010001051381056
Solutions B015/ '. 008
the importance of the theoretical and experimental inveetigation of the
molecular structure of the material in the range of the critical point.
Organizational measures were decided upon for the further development
of the scientific studies in the field of critical phenomena and tluctua-
tions in solutions, as well as for their application to scientific-
economic problems. It was decided further to conduct periodic seminars
in Moscow on problems of the theory of the liquid state and the theory of
solutions. The 2nd All-Union Conference on the Theory of Solutions is
to be convened in 1962.
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S/058/61/000/010/0567100
AOO1/A1Ol
AUTHORS. Berldze, D.K., Shakhparonov, M.1.
1r._-MEz Rayleigh scattering of light in nitrobenzene-hexane solutions
L-,-.
PERIODICAL, Referativnyy zhurnal. Fizika, no. 10, 1961, 180,-abstract 10037
("Uch. zap. Mosk...-obl. ped. in-ta!', 1960, v. 92, 49 - 71)
TEXT. The authors describe the equipment and results of measuring relative
intersity and depolarizatlon degree of individual liquids (nitrobenzene, hexane
-and their solutions at various mutual concentrations). The values of scatter-
ing radiation components Ips Is. and Ik are calculated. The relationships ar4
5t,Aled between each component and depolarization degree on one hand and solu-
tion "emperature on the other hand, including the temperature of the critical
zolnt,. at fixed concentrations. It was discovered that intensity of scattered
radiation passes..through a thin maximum near the demixing point; in this case
deviation from the Rayleigh law of light scattering and an increase of depolari-
za,t;,.on degree are observed.
N. Voyshvillo
[Abstracter's note, Complete translation]
Card L/-1

ZATSITINA, L.P.; SIUMLPARONOV, R.I.
Investigating ",-he degree of depolarization and intensit7 of P.6yleigh
scattering'in methyl alcohol - benzene and methy-1 alcohol - o--Vlene
solutions. Vest.~losk.un.Ser-3:Fiz.,astron. 15 no.4:9-17 Jl-Ag 160.
(MIRA 13:9)
1. Kafedra fizicheskoy khimii Moskovskogo universiteta.
(Organic compounds--Optical properties)
(Light-Scattering)

S, 6,~;'0,33.- -0 1, /024
D 2' 0 D'1-5
AUTHORS.- Sh ~akh n,.- rJ, Ir L~:l An S. L, _. Ko r nhemskaya. L 1,111.
a a - e~ -a t ~ t r n a a! a d V r o n I n a , R z D
I
TITLE-m I I g a 1 i c n f -.j- f e a., do v a o 3 r d n s - t v i r 1
na 1;
Y_ . d LaCl~_ zrlmethylchloro-
S__ Lane ana s,- -_hloroform benzene
PERIODICAL; Z h, n -a 1 p :- I k I r k ln I M I
ou,
C)
--- r- a-r a~jjs 7quia
TEXT, T -n e a. y Of I
Sy-- ~ms H H r. Orfier. ~3 ob-
t a n d a -. a, n e 3 rel
_r a- e na i o n r
a a 1 k y 1, s a nl~.' _M~
2 1' r" S V., E? I r, r~ (I Q n an appara.-
US ':'es Z' e ZlIF'Kh 5 '960).
T'nr -D gh. i:- vas :: on-,:- o
Lea v 1:1 a ..I - 2 r. iw~ s= of a pycn:--,-
y 'o~ in-aivl',ci'ua.
C a. _- ~ d 1 " -,

S 2/007 024
I n c, S I 6a 1,-,
q u d -s v; i 11 'lie-Zh7 C-~f traporz was calcua-
11 0 T ..;I xpe -imen
I P -Ised in e 1 ZS
we..- obTa.-.ne,1J ty 1 t~. T I, a I or, EZ 1 Or, - The :-- on--
s t an t S .,, f Ar,'L U al~ S e!~! -1 1 n P and -.he val,,~ezi of
e n -,I. a I i) y an a - 11 p a - F P~7 ir- ~n Lab,-Iazed i"orm,
y A
Vapoz- __a rl-~01 S L -,:.muonen-.s r2ay be
-g, gives
c a I e d r -h I c
p~*-E._~'s,,-_res agains-~, 7
the rela--_on r)-f a ,,i -lie _- om-.
p o s i ~ i c; t-. i_, 7 V d t,'- I-an e soluiions
- _110 and ";-
at and pa.,,.ial., pressures
and conceti-ra,~.L(--L~~ b~nzerie a-~ _3,0:_C is also
presented Ttt~E E!-aP!- -4--,,C CH _R
2
CH'~ S-,C- slight dEviati-Ons from
the 4dea` C.-H_ -- S-,'iC'L- sz)-Luzion at ~;0'3C s-Lm--"-ar de-
via-ions from Rao~-,!-, s lav.,, a,- -3c-zerved- The au-,hors calculated
concentra-.-onS c.f -.n, -.,~,cors In ec'JI11--brium wlth the 11-
C a r d 92 / -I

T-VeSt4i;at~on, OF rreS,-~Ure ...
U.;_ U~
IS/080/60/033/012/007/024
D209/1)305
quid phase at 760 mm Hg and tIlle results are given in tabulated
form. There are 6 tables, 3 -figures and 1 Soviet-Ioloc reference.
SUBMITTED: October 26,1959
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25 6 ~- 4 .0
D2 0 9 ;' D) 3 0 15
AUTHORS; Korchemskava. K,-li.T_. Shakhpa-rcnov~ Lel~-huki S~L~,
Martynova. [~'.Ye- Baburina,---7-,T-,---aTI-X-Voroni-na, R.D%
TITLE: InveS Tiga--ing p.-ssillre and %rapor dens---y b:nary
solu-~ions cl' sillane chlol,---der'--~a-,,l~,7es
PERIODICAL; Zhurnal p-r---kladnoy kh--lm,.i.. v- 33, no, 12, 1960,
270"~
TEXT: In 7he presenT work ., carried ouT, -co Dbz-a:.n -Lhe nec~essary da-
,a for determir '-ng --cnd-J-T:-lons for -1he re:;ii-LL2ation of haloalkyllo-
silanes .. the ---ubn-,-., -fie resuits o~ inves,lgaTl-ons conl,ern-
ing pressure and -jap-r den:~i~y under pressures o-f '30 - 800 mm Hg,
The measurements v7ere ::nc=-rn.=-d wl-Th de-exm.ning pressure P, den-
-y f, and the raole~:ular vie4ghl- of satiraTed vapor pressure of in_~
lutions. The va-ues of An-aan-s eauation
dividual and s,-- - i -
-onsta-yi-ts and the en-.h:-alpy and en-cropy values for -Jqu.d valsoriz-a-
'on a~ '76., mm a-~~ o-:-,7en in 'rabulated I'c-m. GraphIcally, -,.he au-
Ll
Card

2 4
S"080;,~ 60,-)33.- 012,'O,.8~/024
Inves 1. 1~La t ing pre ss)., ana D 2 0 9; D-.1 0
*,h.3-rs give t-h e 4z-_,tberms oz to-ca: and p_~r-tiai vapor pressules, of
1-iquids al-- 30. 4C-_ cO and !,~)-~alpress~.zres were cal;~u-ated
Irom -he vap,-;r : omRo s 1 T -i o ndaia obtained ".'rom Y, values derived
from the equa~i,,~n M x-- M.. The average mole.-ular weight 0.r sa-
,,-_ira,~-ed va.LoroMuzed f 1 vapor pres5ures deierminations
or
were chosen su-b that the dev-;.a-t-lons fr3m Raou-.,-,.-s law c rresponded
~10
to the Glbbs Duhem equar'L,-n, In all :ases- values of M used in
calcula7ions differed by no- more -1han I - iL5 % from the experl-,
mend, va.lues, In -thls the values of parti-a'2. vapor pressures
and vapor %-er-e by -the cond-_,-t_~ons of thermo-
dynamics and the experiman-121 data., wiLh aocura~:-y.
Other tables repTecent -1he ~_Dnten-.s of vazo.- components in equili-
brium wi-~h liquld phase at 760 mm Hg and the ac-.,-Lv_,ty coefficients
of the components of various zemperatures~ The results submitted
show that the solutions of methyidlChlo-1---sillane .- tetrachlorosila-
ne are characterized by only S-11-ght posi-live deviations from the
idea-, solutlion, and-In many cases may be cons-ldered as such. Solu-
Card 2/,'~

256' )4
S/080 "60/033/012/008/024
Investigating pressure and D2097D305
0
tions of chlorosilane solutions at 40, 50 and 56 0C. There are 3
figures, 7 tables and 2 Soviet.-bloc references,
SUBMITTED: October 26, 1959
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S/076/60/034/007/017/042/XX
BOO0068
AUTHOR: Shakhparonov, M. 1.
TITLE: Theory of Solutions. X. Effect of Fluctuations on the
Dielectric Constant of Homogeneous Isotropic Systems
PERIODICAL: Zhurnal fizicheskoy khimii, 1960, Vol. 34, No- 7,
pp. 1478-1487
TEXT: The aim of this work was to establish the reasons for the deviation
of the experimental values found for the diele Ctr4C constant from those
calculated from Onsager's'theory. Possible causes are: a) change of the
state of the molecules in the solution as a result of interaction of the
components (e.g., hydrogen-bond formation); b) fluctuation of the dielectric
constant as a result of variations of concentration, orientation, density,
etc; c) change of the short-range order when the composition of the solu-
tion is varied.In this paper, only the effect of fluctuations on the
average macroscopic value of E of the solution is investigated. The 'erage
value of the local dielectric constant F_1 is calculated on the basis of
Onsager's theory. The starting point is the function cloc(X?y)z) as the
Card 1/3

Theory of Solutions. X. Effect of Fluctuations S/076/60/074/007/017/042/XX
on the Dielectric Constant of Homogeneous B004/BO68
Isotropic Systems
thermodynamic function of a volume element dV on the assumption of Gauss,
probability distribution of the fluctuations: dWk = n kdVk/V (11), with
dWkbeing the probability of.the value F_k , and nk the number of volume
elements in which the local dielectric constant equals 6 k*
2 2
E IE /3 E C 1 - (661) /3(E) (36) is found for the re-
lation between the macroscopic value E of the dielectric constant and the
mean local dielectric constant El. The fluctuation of El is due to the
variation of concentration c, temperature T, density Q, and orientlation:
hi
= (8 -cf/ac )'&c + (a El/aT)AT+(a E1/aQ)8Q+(&,E,) (41). For the
j=2 j j or
statistical mean square of fluctuation, the relation ',8 E =XldV (43)
k 00)2
is obtained, where X is a function of concentration, temperature, density,
and orientation. In a two-component solution and at a great distance from
the critical temperature, however, only the effect of concentration has to
be considered:
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Theory of Solutions. X. Effect of Fluctuations S/07 0/60/034/007/017/042/XX
on the Dielectric Constant of Homogeneous B004/BO68
Isotropic Systems
2 2 2 2
(A,C- , )=(a El/ac) (Ac) (47). Thus, (,&El) is a function of the mean local
'dielectric constant. There are 11 references: 3 Soviet, 5 US, 1 British,
1 Dutch, and 3 German.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova
(-Moscow State University imeni M. V. Lomonosov)
SUBMITTED: November 11, 1953
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S/076/60/034/008/007/014
B015/BO54
AUTHORS: 5hakhparonov,,jA, .... I. Balamutova, E. A.9 Lellchuk, S. L.j
"Mikheyev, Ye. P. I' uFova, L. V., diushkova, L. F. and
Martynova, M. Ye. (Moscow)
TITLE: Investigation of Pressure and Density of the Vapor in
Systems Containing OrRanosilicon Compounds. I. The System
Benzene - Methyl-dichlorosilane Methyl-phenyl
Dichlorosifane
PERIODICAL: Zhurnal fizicheskoy khimii, 1960, Vol. 34, No. 8,
pp. 1734-1740
TEXT: The authors determined pressure and density of the vapor of a
number of halogen alkyl silanes\Nand -aryl silanes since these substances
readily react with water vapor or metals, dissolve in lubricants, and
easily polymerize. In the present paperg they report on the system
benzene - methyl-dichlorosilane - methyl-phenyl dichlorosilane. The
experimental arrangement (Fig. 1) described in Ref. 2 is based on the
Card 113

Investigation of Pressure and Density of the S/076/60/034/008/007/014
Vapor in Systems Containing Organosilicon B015/BO54
Compounds. I. The System Benzene - Methyl-
dAchlorosilane - Methyl-phenyl Dichlorosilane
principle of hydrostatic weighing, and is thoroughly explained. The
apparatus includes a quartz balance which is installed in a glass
balloon in a thermostat. In another thermostat there is the evaporator
connected with an Hg manometer. Balloon and evaporator are joined by a
thermally insulated, heated pipe. A quartz ball is suspended from the
quartz spiral of the balance; as the vapcr of the substance investigated
enters the balloon, the quartz ball loses in weight, and the vapor
density can be determined from the decrease in length of the spilral.. The
method of operation, the calibration of the instrument, and an estimation
of the errors of measurement are indicated. The latter are about 1% in
the pressure-, and abo-fat � 2.5% in the density determination. The
molecular weight of the liquid vapors was calculated by the Mendeleye-
Clapeyron equation, and compared with data of publications (Table 1);
press-are and density values of methyl-dichlorosilane and mezhyl-phenyl
dichlorosilane, as well as their solutionag are given in Table ?. The
results show that the vapors represent associate complexe-z. The Trouton
Card 2/3

Investigation of Pressure and Density of the S/076/60/034"/008/007/014
Vapor in Systems Containing Organosilicon B015/BO54
Compounds. I. The System Benzene - Yfethyl-
dichlorosilane - Methyl-phenyl Dichlorosilane
constant for the vapors was calculated, and given in Tables 2 and 3 Tt
is found that at 400 - 1000C the vapor composition of the solutions
benzene - methyl-dichlorosilane - methyl-phenyl dichlorosilane is
practically equal to the vapor of the corresponding binary mixture
benzene - methyl-dichlorosilane. The heats of vaporiza t. ion~nd the
entropies were calculated. There are 5 figures, 3 tabl e d 4
Soviet and 1 US.
references: 3
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M. V.
Lomonosova (Moscow State University imeni M. V. Lomenosov.)
SUBMITTED: October 30, 1958
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84245
//1 21 S1076160103410091003/022
0
EO!91/BO56
r! MOP 5 Balamutc-,,,a, 1". A., Shakhriaronov, M. I,., Lellchul-, S. T.,
" , -1,1 Ye , ni
Lomo,~-. A.~ L., Mal i kovrl , Ij
Glushkova. L, F,
TITLE; invesiigatlen of the Pressure and Density -~f IIaDcr in
Systems Containing Organosil-iccr Compounds\ II. The Systems:
Meth.y.11dichlorcsilanel- Methyltrichlorosilane - Meth.71-
phenyldi-,hlorosilane, and Methylpheny-Lidichlorosilane -
?,!ethyichlorophenyldichlorosilane - Methyld-Lchlorcphenyl-
dic.hlorosilane
PERIODICAL: Zhurnal f-47-icheskoy khimii, !960: vol. 34, Nc. 9~,
pp~ -!916~1919
TEXT: The working method anI the
+i'ons mentioned in the title have
parer (Ref. 1). The pressure and
n-ver the systems ment4loned in the
and temperature range.
measuring technique of the investi.-a-
already been described in a previous
Jensity of the saturated vapor phase
title were measured --n a broad --on-
The constants of the AntGine equations,
Card

842115
Investigation of the Pressure and Density S/0116./60/054/009/003j/022
cf Vapor in Systems Conta 4 ning Organosiliccn B01cz/B056
Compounds. II_ The Systems: Methyldichlorosi-
Lane - IMe thy! trichlorcs ilone .. !i'lethvi.
pheny1dichlorosilane, and Methylphenyldiohloro-
z;.ilune MetliylchlorophenyldichlorosiliriE,
Iiilethyld~.chlorophenyidichlorosilan~-
as weil as the values of the evaporation heats and evaporation entropies
for the individual components (Table 1), and the two- and three-.component
solutions at normal boiling temperature were calculated (Table 2). The
valueGobta.ined show that the vapors of methyltrichlorosilane and Methyl-
cii1orcLheny1dichlorosilaria- contain associated molecules, whereas the vaFers
cf inetliyidic~ilorophenyidichloi-esilane do not aEsociate. At 1,00 0C and about
900 tcrr, Lhe varor (in equilibrium) ouer a solution of 50 mole%
CH3SiEcl 2 + 50 molle% CHzSiC'_ consists nearly entirely of methyl-
ri::hlcrosilane. All temneratares from 40- tc 100 C; the vapor composition
f - S!C,
~he three-component solutions CH SiHcl CH HSi-I
CH C I
2 3 6 2
SiHCI CH Sic,
:s sli&tly different frcm that of the b'nary sysrem CH 3 2 5 .13
a,~ the same molar ratio c~f the latter -cmronent-s. Calculations carried
Cara 2/1"

8 14 -2 45
Invest igation of ti,e Pre~_1.-- -r, De-, ity 3/376/60/0'4/00~/ GO ~/O;~ 2
of Vapor :-n Systems Containing
Ccmpounds, Il. The Systems: Methylli-chlorosi-
lane - ".ethyltr4chlorosilane - iMethyl
M
plie.,i,,--Id:cl-,IorOS4-1----ne, anJ 7,!ethylz)heny_1dichlcr,--
silane - ",P-thylchloronhenyldi-chicrosilane -
,~ie-ch~,'.di-chl~oror)hen,-,"Idichlorcsilane
out on the basis of the Antoine equation show that above 100 C ne Change
in the CH C H Sicl ccntent in t.ne vapor phase takes place, i.e., the
3 6
content remains low with the exception Of solutions in which the molar
ratic of CH C,H,SiCl is near unity. There are 2 figures, 2 tab' d
2 6 2 les, an
2 referen3e~: 1 Soviet and 1 US~
ASSOCI-'.TION: Iloskovskily gosudarstuennyy uriversitet im. M. V, Lomoncsora
State University imen-l' M, V. Lomonozcv)
~IUB',",ITTED: Oc-tober 3C: '958
Card .11/3

S/'076/60/0'A,4/()10/001/q22
BO15/BO064
AUTHORS: Balamutova, E. A , Shakhlw-ronov 1A -I Lel ' chuk, S L
Lomov, A, L_ Mikheyev, Ye, P., Martynova, M,- Ye.,
and Glushkova, 1j, F-
TITLE: Investigation of the Vapor Pressure and Density in
Systems Containing Organo-silicon Compou~dsl III, The
Systems DimethyldiChlorosilane - Methylchloromethyl-
dichlorosilane and Trimethylchlorosilane - Dimethyl-
chloromethylchlorosilane - Dimethyl Dichloromethyl-
chlorosilane
PERIODICAL: Zhurnal f-izicheskoy khimii, 19060, Vol. 34; No, 10,
pp, 2156-2;59
TEXT: Pressure and density of the saturated vapor of the
systems (CH 3 2SiCl 2 - CH 3CH 2ClSiC12 ' CH3CHCJ 2Sic'-2 and (CH 3)3 Sicl
(CH 3)2 CH ?ClSiCl - (CH 3)2 CHCl2SiCl were investigated in the wide range
Card 1/6

Investigation of the Vapor Pressure and S/07t)/r',O/O-,'4/'010/00'./022
Density in Systems Containing Organo - B015/B064
- silicon Compounds. III- The Systems
Di-methyldichlorosila-ne - Methylchlcro-
methyldichlorosilane and Trimethyl-chlorosilane - Dimethylchloromethyl-
chlorosilane - Dimethyl Dichloromethylchlorosilane
of concentration and for temperatures of from O'~' to ')OOC The same
method of measurement was used as in a previous paper (Ref, 1), and
pressure and density of the individual components were determined. The
.--urves obtained on the temperature dependence o-," pressure and density
show that pressure and density of the systems investigated rise exponen-
tially with temperature, Table 1 gives the values of the refractive
indices, the density, the boiling points of the components at 760 mm Hg
the molecular weight of vapor at this pressure ', the values of the con-
stants of the Antoine equation as well as the values of the evaporation
heat and evaporation entropy at the normal boil-ing po--'nt-
Card 2/6

S/076/60/034/010/001/022
B015/BO64
--4ble I L

131~tuecno
-2D,

4I
T
P Jif na pa
11 It
P
I
TCOP A
"I I
B
c

'll

S
..
760 AM
7
60

((:[13)ssicls 1,4052 1,0715 70,1 129,0 129.0 9,572 3t10 345 7450 21,7
UHXH,ClgiCI2 1,4494 1 2832 119,5 t7l,O 163,6 6,930 1265 194 9150 22.6
CHaCHCIsSiCis 1,4690 J:4107 149,0 t98,2 198,0 6,306 123,0 203 7940 18,8
)Ssicl
(CH 1,38M 0,&581 57,7 H2,3 108,65 7,0098 IM 229 7560 22,8
(CH ),CtIXISICI
: 1,4372 1,0844 114,9 152 143, t 9,035 2635 314 8460 21,8
Card 3/6

S/076/6o/o'34/o1o/oO1/022
B015/BO64
.--Tabib 2 T it (,.-: it iia 2
solution
PaCTHOP

D
'i 20
4
a
A
B
C
AH
-AS A
500j, py, Sicl,+500,; C113CI12CISiC[l 1,4309 1,1842 5,826 732 M 6960 19,2 89,4
500,10 (C[13)2 SiCI,+500,' C113CHC12SiCI, 1,4450 1,252 6,535 1130 216 7250 19,8 93,5
500,, CIIXHXISiC12~~
+ -500,"1 CIISCIIC12SiC12 1,11619 1,344 7,054 1435 124 10800 26.8 130.9
330,6(cfl3),SiCil+33~6CIlaCI13CISiCls+ -
+ 31% CII'.ICIIC12SiCI2 1,4469 1,2679 - 9500 25,2 103.0
5006 (C[13)3 SiGI + 500,6 (CIIa)3 X
~61,,Clsici 4, 4158 0, GO 197 14, 163 tO550 810 7540 21,4 78,8
500N, (Ctf,,)s sicl+50% (GIIS)3 X
X CHC13SiCl 1,4304
I 1,05121 6,923 1426 264 830 18,9 88,5
1
1
OQ,6 , C11GISICI + 50% (CHN)s x
MC
9
C
1
1cl
x
.
~ - i.t585 - - - 5480 13.8 124,0
3% CHC12 (CIIm)3 SICI + 34% (CH*)sX l .1 1.
X SiCI + 33% CHCHCISICI t,4321 t,0670, - 7600 16.9 i
3
iOS,O

Table 2 (continued)
S/07-'/U'fO/034/010/001/022
B0157BO64
T i 6a ii ix a2 (npoDoxwenue)
Solution

P.ir.TBOP
M
U x

+
J

x
500" (CIIO-SiC12+500; C113CII-CISMI, t 42,3 0,68 0.32
500,10 CfI3),siCJ2+500'0 CfJ3GIICI2SiGI-j
U 139,7 0,845 -
,sCHzCISiCI2-~
50%
+50%CII3CIICI,siCI, 180,0 -
I 0,605
33% CliB)2S'Cl2-F33%CI13CI13CISiCI2+
N
10,01 cli'mm'sicl, 14,2,5 0,70 0, t8
50%(CH3)ISiCI+50%(CH3)2x
xCfI:CIsiC1 113,0 - - 0,90 0
10
50% (CI13)3SiCI+500,f (CH3)2X ,
XCHC12sicl
50%(CI13j2CH2CIS'C1 + 500160 P13)2)e
xCHC SiGI M71 -
0
860
330,; GIIGIj(CHj)2SiGI + 340,6 (Cjja)3X ,
XSiCI+33 CHsCI1,CISiCj 135, 6 - -0
- 855 -z:0. 132
Card 5/6

S/07Y0'O/O34/01 0/00 1 /022
B015 B064
Legend to Tables 1, 2: In Table 1, 1 denotes the substance, 2 = boiling
0
oint at 760 mm Hg, 3= molecular weight M at 760 mm Hg, 3 = 11 theoretical.
1 'boiling p9int in OC in Table 2. There are 4 figures, 2 tables and
2 Soviet references..
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova
(Moscow State University imeni M..V. Lomonosov)'
SUBMITTED: October 30, 1959
Card 6/6

BERIDZE, D.K.; SHAKITARONOV, M.I.
Rayleigh scattering of lig~.t in nitrobPnzene - hexane solutions.
UC .1.I.zap. VIOPI 92:49-71 '60, (MIRA 34:9)
(LiFht--Scattering) ('Jilro~-,Pn7ene--Optical properties)
(HIxIiIIP-OpLical properties)

85524
S/020/60/133/003/029/c3l/xx
eOO6 (3-2,0/, /01.~ BOOVBo64
AUTHORS, Lanshina, L. V- and ShakhParonov M. I.
I- - - -------- 91
TITLE- The Fine Structure of the Rayleigh Dispersion of Light in
Solutions and the Dispersion of Hyperacoustic Vibrations
A
PERIODICAL.~ Doklady Akademii nauk SSSR, 1960, Vol. 133, No. 3, pp~ 624 -
626 V/
TEXT, The apparatus used by the authors to photograph the fine structure of
the Rayleigh line of dispersed light has already been described in Ref. 1.
The authors investigated mixtures of acetone and water at 250C with a molar
ratio of acetone of 0.0; 0.06; 0.2; 0.4; 0.7, or 1.0, and mixtures of water
and methanol with a molar ratio of the latter amounting to 0.15; O~36; OA;
or 1.0. Measurements were made by means of the Hg line A = 4358 A, and for
pure water also with A = 4046 A. The photographs were photometrically
treated with an P4-4 (MF-4) microphotometer.-~ Fig~ 1 shows the pro~oagation
velocity of hyperacoustic vibrations in acetone - water (L)-o.6-io sec-"'.
A-22-10- 6cm) and methanol .., water mixtures (w,-'::~6.5-10 10 sec- 1
Card 1/3

85524
The Fine Structure of the Rayleigh Dispersion S/020/60/133/003/029/031/XX
of Light in Solutions and the Dispersion of BOOVB064
Hyperacoustic Vibrations
A,-'-22.0-10-6 cm) as computed from the equation AVIV = 2n(v/c)sin(0/2). The
data of Refs. 4, 5 on the propagation velocity of ultra-acoustic vibrations
(w(-~:L56. 1o-5 sec" 1, A---.24 * i o'_ 3cm) are added for comparison. A considerable
negative dispersion of hyperacoustic vibrations was found to existi 4W-0
reached about 5%, while the root mean square of deviation was only about
1.4%. The negative dispersion vanishes with falling water concentration x 1
i.e., for acetone - water at x 1 = 0.65 and for methanol - water at x 1 = 0.5.
This negative dispersion is explained by the structural relaxation of water,
and corresponds to the well-known anomalies of water. Moreover, the integral
intensity I_ of the central component and the intensity I tr of the
translational component by Mandel'shtam and Brillouin were compareds and the
refractive index nX was represented as a functioa of concentration (Fig. 2).
Considerable positive deviations from the Raoult law were observed in the
acetol-e -- water mixture, The fluctuations of concentration attain their
Card 213

84707
S/020/60/133/06/o15/016
_r.%41 OU B004/Bo64
AUTHORS: Shakhparonov, M. I., Lellchuk, S. L., and Korchemskaya,K-Yi.
TITLE: The Thermodynami ies f the Solutions of Chlorine
a_EZ2jerties 0
Derivatives of Silane'l
PERIODICAL- Doklady Akademii nauk SSSR, 1960, Vol. 133, No. 6,
pp. 1388-1390
TEXT: The authors report on measurements of the pressure F and density
,r of the saturated vapor of the following systems! CH 3 SiRcl 2 -sicl 4;
SiHCl 3 -C6H 6; CH3Sicl 3 - Sicl4; (CH 3)3 SiCl - CH3 SiHCl 2; (OH 3)3 Sicl
- CH3 Sicl 3Y as well as solutions of CH 3SiHCl2 and CH3Sicl 3 in the X
azeotropic mixture of 45.93 mole% (CH 3)3 SiCl and 54.07 mole% SiCl 4'
Ref. 1 describes the methods of P and tmeasurement. Table 1 gives the
values of the constants A,B,C of the intoine equation log P - A - B(C+T)
for the systems investigated, as calculated from the experimental data of
P. The molecular weight of the saturated vapor was calculated from the
Card 1/2

84707
The Thermodynamic Properties of the Solutions S/020/60/133/006/015/'016
of Chlorine Derivatives of Silane B004/Bo64
equation 7 RT/P, and its composition from the equation 1-1 Yixf.
3. 1
Fig. 1 shows the total and partial pressures in the system SiHC1 3 - C6H6
at 300C as a function of the composition. The isothermal lines P and P i
of the system CH 3SiHC1 2 - Sicl4 at 400C, and of the system CH 3Sici 3 - Sic~
at 500C are given in Fig. 2. The systems mentioned show little positive
deviations from the ideal case. The systems (CH 3)3 sici - CH3 sici 3;
CH3SiHC1 2 - (CH 3)3 SiCl; azeotropic mixture - CH3Sici 3; and azeotropic
mixture - CH 3 SiHC12follow the Raoult law. The isobaric lines of these
systems at P = 760 torr are shown in Fig. 3. There are 3 figures, 1
table, and 1 Soviet reference.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M.V. Lomonosova
(Moscow state University imeni M. V. Lomonosov)
PRESENTED: April 4, 1960, by V. I. Spitsyn, Academician
SUBMITTED: April 2, 1960
Card 2/2

0 ilju~)
6 0 0 c/'/,P 2-J
c/02O/6O/134/OC13/019/O2O
;004/B067
AUTHORS-, Lomova, N. N., an(~-Shakhparonov. M. I
TITLE,-. The Dielectric Con~ the Molecular Structure of
Soluilons Bavin-g--a--67-iTical Dissociation Rans-,~
PERIODICAL: Doklady Akademii nauk SISSR, 1960, Vol.. 134, No. 3,
pp. 632-635
TEXTi In an earlier paper (Ref. 1) M. T, ShakhDaronov obtained the
following resultst For solutions whose thermoaynamical properties show
large positive deviations from ideality, i.e., large fluctuations of
concentration, the experimentally measurable dielectric constantsis
smaller than the average local dielectric constant -C 100 Cloc J/
- )2-
2]/ [ 2 , (97 1oc/')Y'/NE/?Y)1E (1)- To study the
-7-
2
influence exerted by the fluctuation (6~q of concentration on the
authors measured t, the density t, and the refractive index n of solu-
f4 D
tions of nitrobenzene (NB) in cyclohexane, n-hexane-, n-heptane, and
Card 1/4

839o5
The Dielectric Constant and the Molecular /0-
Structure of Solutions Having a Critical BO04/BO067
Dissociation Range
.L
n-octane. The critical dissodation temperature of these solutions was
found at 400C for 48-0 mole`i!,' ITB in cyclohexane; at 20,0'C for 43-15 m018%
NB in n-C6H 14 ; at 19-30C for 47.5 molecj,' NB in n-C 7H,,; and at 19.10C for
5'-.0 mole"' IIB in n-C H On the stren.c-th of experimental data the iso-
a 18,
thermal lines for ~_ were drawn (Fig. 1), and the isothermal lines for
E, were calculated by Onsager's method (Ref. .1 ~.On the basia of data
100 2
obtained for loc loc and ~ F-19y(,6T) was calculazed~ The
dependence of 6*.q)2 on t and tj was analogous in all four systems, The
values depended l'ittle on the type of hydrocarbon used,
2
Fig, 2-, dependence of F- 10C ,q- IA , and (,A ?) P
on -.he concentration of nitrobenzene in the
T2
0
syFtem -nitrobenzene - n-hexane at 40 C
Card 2/

839o5
The Dielectric Constant and the I",:olecular S1020V6O1I,341CjC3/01(91020
Structure of Solutions Raving a Critical B004/Bo67
Dissociation Range
Fig, 2 sho-vs the course of loc L Y)2 and of the intensity I k
of the Rayleigh scattering for I = 5760 A in the system nitrobenzene -
n-hexane, The authors discuss the result on the basis of the statistical
theory of fluctuations and of the interaction of neighborin.- molecules.
By dIfferentiatinE equation (1) they obtain equation (5) for (Q~ IWIq 7
and thev conclude tha' th --1--e of (9E /9t4 is reduced -ear the critical
pofnt. this was confirmed by measurements 3f E in the system ritrobenzene
.-heptane and nitroberzere n-octane near the point of disscoiation
F J_ '5) z -
12-4- F_ = f(t) near the critical point o-
dissociation, 1 - solutior of nitro~e-rzene
in ri-heptane, x = 0.4610; 2 - sclu-
C H NO
-6 5' 2
2
tion of nitrobenzene in n-cctans,
x 11a, 2a before dissocia-
No 0,514,
C6H5
tion, I, 2b after dissociatior
Card 3/4

839o5
The Dielectric Constant and the Molecular S/0201601'. 34/00 31019,1020
Structure of Solutions Having a Critical B004/BO67
Dissociation Range
These results are contradictory tc the data of Ref- 5 according to which
0
has maxilma in the critical ranZe, The authors refer to Gibbs (Ref. 6)
2 2
accord ng to which relations of the form (qX 0,i)Xj ~ 'i (9 xj/lx.)Xi= 0
are 'thermodynamically not generally and exactly valid in the critical
ran-ne. He-nee, the validity of such relations must be experimentally or
theoretically prcved for each case by means of a molecule model. There
are 3 figures and 6 references: c Soviet and 1 USI
ASSOCIATIOI'~ Moskovskiy gosudars'.vennyy universitet im. M.V. Lomonosova
2.1,oscow State University imeni M. V. Lomonosov)
PRESENTE-D% April 4, !960j by V. I. Spitsyn~ Academician
SUP'I'ITTED, April 2, 1960
Card 4/4

SHAIUIP.AMNOV,,-- M.I. (Moskva)
Some aspects of the theory of metal alloys. Iz-... 417. SSSP. Otd.
tekhw nauk. Plet. i topl. no.3:118-120 My-Je 161. (MIRA 14:7)
. (Liquid metals) (Alloys)

.,-.,Ii-.'ov, Ya.Yu.
Influence of fluctuations on the dielectric properties of
solutions in ultrahigh frequer-cy eloctrorwgretic fields.
Zhur. sti-Wt. Ichim. 2 no. 1:13-19 ja-r- 161. (.-':M~- 14:2)
Nosh.ovsh-iy gosudarstvennyy univers-1tet im. M.V. Lomonosovv-.
(Dielectric constants) (Electromagnetic wuves)

KASIMOV, P, M~7,SHAKRPARQNQV)--M~ I. -
Dielectric properties of nitrobenzene - hexane solutions in a
millimeter range of radio waves. Azerb.khim.zhur, no.4;101-
108 161. (MIRA W11)
(Nitrobenzene--Electric properties)
(Hexane--Electric properties)

K)R~HNSKnY,~t, ?,
1) Lr-"L'CHUY.,,';.I,.; i,'IPaTYN,-')Vik, E.Ye~;
BABUiNik, I.D.
Fressurc- and density of vapDrs from solutions of chlorine deriva-
tiver- of silane. Fart 4. Izv.vys.ucheb.zav.;khim.i khim.'Lekh,
4 no.4: 584-,r-8,7 '61. ( IM IIU- 1 ': 1 )
1. Vioskovskiy gosudarstvennyy universitet imeni Lomonosova, kafe-dra
fizicheskoy k~imli.
(Silane) (Vapor pressure)

BERIDZEV D.K.; ~~A?LONOVJI MOIO
Rayleigh light scattering by solutions of nitrobenzene in hexane.
Opt. i spektr. 10 no.2:240-248 F 161. (MIU 14: 2)
(Benzene) (Hexaae) (Light-Scattering)

BERIDZE, D.K.; SHAKHPARONOV, M.I.
Remarks on Krishnan's phenomenon. Opt. i spektr. 11 no.2:282-
284 Ag 161. (Light-Scattering) (14IRA 14:8)
(PhOtOmetx7)

3/058/62/ooo/o 12/030/0 4 8
16r
J/A101
AUTHORS: Shakhparonov, M. I., Tunin, M. S.
TITLE: The hyperacoustic properties of liquids and the structure of
molecules
PERIODICAL: Referativnyy zhurnal, Fizika, no. 12, 1962, 13, abstract 12D96
(In collection: "Primeneniye ul'traakust. k issled. veshchestva".
M., no. 15, 1961, 19 - 28)
TEW.: To investigate the hyperacoustic properties of liquids, a study was
carried out of the fine structure of Rayleigh's soattering lines in liquid pyri-
dine, thiophene, furan, quinoline, naphthalene, and also in heptane, The absorp-
tion of ultrasound was measured for these substances, except for the latter two
ones. The selction of the substances is based upon the consideration that a
strong sound absorption must take place in those liquids whose molecules are
compact, easily polarizable, and have a comparatively large number of mobile
electrons and a "rigid" framework of atomic nuclei. In all investigated sub-
stances, except for heptane, a considerable positive dispersion-of the velocity
of hypersound was observed. In heptane, whose molecules do not have "rigid"
Card 1/2

S/058/62/0()0/012/030/048
The,hyperacoustic properties of'liquids and... Ai6o/Aioi
atcmic '1ramew3rk, tiespeed of the hypprsound coincided with the speed of ultra-
sound within the error limits of the experiment. The relaxation times yielded by
the experimental data are close to those calculated by Hertzfeld's formula. This V
is in conformity with the assumption that the dispersion of sound in the investi-
gated liquids is clue to intramolecular processes.
L. Filippov
rAbstracter's note: Complete translation]
Card 2/2

S/058/62/000/012/031/048
A16o/Aioi
AUTHORS: Akhadov, Ya. Yu., Shakhparonov,.M.'J., Kasimov, R. M.
TIME: Investigations of the molecular structure of individual liquids
and of their solutions by radiophysical methods
PERIODICAL: Referativnyy zhurnal, Fizika, no. 12, 1962, 16, abstract 12DI12
(In collection: "Primeneniye ul'traakust. k issled, veshc*hestva".
M., no. 15, 1961, 29 - 39)
TEXT; Investigations were carried out of the permeability and losses of
the following solutions: acetone-benzene, acetone-carbon tetrachloride, acetone-
-nitrobenzene, nitrobenzene-hexane, acetone-methyl alcol-101, and acetone-water
within a wide concentration and temperature range and on radio-wave lengths of
8.15 mm and 3.21 cm. An analysis of the results indicates that the molecules in
the mentioned first four solutions did not tend to association. It appears that
there are deviations from a chaotic distribution of polar-molec'ule orientations
In the acetone-nitrobenzene solutions. In the acetone-methyl alcohol and acetone-
-water solutions it seems that there are associated complexes of water and methyl
Card 1/2

3/058/62/000/012/031/048
Investigations of the molecular structure of.., A160/A101
alcohol molecules. it may be assumed that when adding small amounts of acetone
to water, the associated groups of water molecules increase.
FAbstracter?s note! Complete translation]
Card 2/2

LCX-IOVA F. t ~. - SKAMPAR0110 I LA. I.
-
Dielectric constant and molecular structure of nitrobenzone
solutions in heptane and octane. Vest.Mosk.un.Ser.2:1thim.
16 no-3:33-37 1-13-Je 161. (1-',IRA 14:10)
1. Kafedra fizicheskoy khiri!-i Moskovskogo gosudarstvennogo
universiteta.
(Nitrobenzene--Electric properties)

SRAKHPARONOVI M.I.
Theory of the dielectric properties and molecular structure of
concentrated solutions of polar molecules. Vest. Mosk.Un.Ser.2:
Khim. 16 no.5:69-80 S-0 161. (KM 14:9)
1. Kafedra. fizicheskoy khimii Moskovskogo universiteta.
(Solution (Chemistry-Y-Blectric properties)
(Molecular association)

KAS4WV, R.M.; AKHADOV, Ya.Yu.; SHAKHPARONOV, M.I.
Dielectric properties of acetone - carbon tetrachloride solutions
in superhigh-frequency electromagnetic fields and fluctuations
in concentration. Dokl. AN Azerb. SSR 17 no. 3:207-211 161.
(MIRA 14: 5'1
1. Institut neftekhimicheskikh protsessov AN AzerbSSR.
(Acetone-Electric properties)
(Carbon tetrachloride-Electric properties)

11
KASIVIOV, R.I:.; AMADOV, Ya.Yu.; SMITAROITOV,
Dielectric properties and v-iolecular structure of acetone
solutions of nitrobenzene, methyl alcohol, and water. Dokl.
AN Azerb. SSR 17 no.8:687-690 161. (MIRA 14;10)
1. Institut neftekhimicheskikh protsessav 0 fizerbSSR.
Predstavleno ak-ademikom AII Azerbaydzhanskoy SSR M.F. Nagiyenm.
(Dielectrics)
(Syotems(Chemistry))
9

SHAKHPARONOV. M.I.
Theory of isolutions. Part 12., Dielectric polarization and
molecular structure ofn4robenzene and acetone solutions. Zhur.
fiz.kbim. 35 no.6:1177-1185 Je 161. (MIU 14:7)
I
I.. Moskovskiy gosudarstvennyy universitet imeni M.V.Lomonosova.
(Polarization (Electricity)) (Benzene) (Acetone)

Lj I ~ D
31187
S/076/61/035/012/007/008
B101/B138
AUTHORS; Tunin, M. S., and Shakhparonov, M. I~
TITLE- Investigation of the "hypersonic" and ultrasonic properties
of pyridine benzene solutions
Pi,RIODICALc Zhurnal fizicheskoy khimii; v. 35, no, 12, 1961, 2-83 - 2784
TEXT; The authors seek to explain the molecular nature of relaxation in the
10 14
10 - 10 cps field ("hypersonic")by studying the dependencies between
these processes and the composition of the solutions. The propagation of
hypersonic and ultrasonic waves, viscosity, and absorption coefficient in
benzene pyridine mixtures were measured at 250C. Propagation velocity of
hypersonic waves was optically determined from the fine structure of the
Rayleigh line 4358 R) of scattered light,using the method described
by M. I. Shakhparonov, M, S, Tunin (Primeneniye ul'traakustiki k
issledovaniyu veshchestva (Application of ultrasonics for the investiga-
tion of a substance), Trudy 9-y konferentsii, no, 14, Izd. Mosk. ped,
in-ta, 1961) and L~ V. Lanshina, M, I. Shakhparonov (Dokl~ AN SSSR9 1371
830, 1961) Velocity of ultrasonic propagation) v0) and absorption
Card 1/p -

31187
s/076/61/035/012/007/008
Investigrition of the- - B101/B138
coefficient a were measured for f = 2016 -- 34~4 Mcps, The meter wave
.aenerator had an output voltage of 5~Y - 50 mv,. The values were calculated
according to the equations, ah 4L%3i/6qv1
h 2 2 2. 212 0 h
CL 7L W -r (v - v )/2v3(i + to i maxk 0)1/v2 where
01 0 a , n(v - V
h 0
a s the maximum value of the relaxing part of the absorption
,)Amax -
coLefficient, andA- the length of the sound wave in the maximum of h
r" aV *
Results are shown in Figs, 1 - 4, There are 4 figures and 2 Soviet refer-
ences~
ASSOCIATION, MoskoV3kiy gosudarstvennyy univers-itet im, M, V, Lomonosova
0
(Moscow State University imeni M. V. Lomonosov)
SUBMITTED- May 7., 1961
Card 2/6'

S HAMPAIU.NOV, _
Rayleigh scattering of light and the ordered orinetation of molecules.
Dokl.AN SSSR 136 no.5.1162-1164 F 161. OUA 14:5)
1. Moskovskiy goo. universitet im. M.V.Lomonosova. Predstavlen-) akad.
V.V.Shuleykinym.
(Light-Scattering) (molecules)

L;
~v
lilzlit ..c.-. LTer', m,,~ so'ut-Jc.~ s In carbon
0; 13 1 no 161. C T
1. i--;-.."..V.Lo:loacsovn. Fc.!d-
st,-xl eno aL-ade,-i' u 'T
Coll,
(Acetuone) k c i t r c' ~. 1 :t re

LANSHINA L.V.;-�HAKHPARGV0V ILLI.
Fine structure of the Rayleigh line of scattered light, and
the propagation velocity of hyperacoustic oscillations in
water. Dokl. AN SSSR 137 no.4:830-832 Ap 161. (MIRA 14:3)
1. Moskovskiy gosudarstvenryy universitet im. M.V. Lomonosova.
Predstavleno akademikom V.V. Shule7kinym.
Underwater acoustics)
ght-- Scattering)
M

SILAKUL1011OV, I'Alikhail Ivanoyj~~h
-- -- . doktor khim. nauk, prof.; KNYAZEVA,L.,
red.; KLMOVA, T., tekhn. red.
[Chemistry and philosoplrjj Khimiia i filosoftia. Moskva, Gos.
izd-vo polit. lit-ry, 1962. 135 p. (MIRA 15:3)
(Chemistry, Physical and theoretical)

S/843/62/000/000/001/010
D207/J308
Shakh~,)aroiiov, :.I.
V
T ITLE: -'en-.1ittivity molecular structure of solutions
SOWIIC:~! ~~troYcniyc i fizichaskiye svoystva veshchestva v
zhidkora sostoyanii; matcrialyJV soveshch. po probl.
zhiCkogo sost. veshchestva, v Kiyeve 1959 g. Kiev,
iz(',-vo Iliev. univ., 1962,' 4-10
T It The following formula is derived for the difference
betwee-a the expe rime rtt al I., deten-ained macroscopic pennittivity Q)
and the local average penlittivity Q:) of a solution:
E00 aci 2 +
OD 00 (5)
aFCO (2 + 8F
C
j
i
Gard 1/3

',Jerr ittivity and mol-ccular
where
400
00
and
CE
3CI
S/843/62/000/000/001/010
D207/D308
(6)
(7)
The subscript oodcuotes the -Pernittivity values at optical frequen-
cles* c- is the concentration of the component i in the solution.
Similar formulas for (1) the electrical conductivity c-, or (2) the
permeability A can be obtained from the above permittivity formula
by substituting c~ fo~ P- in the case of conductivity, c/~L for
6 in the case of peniica'Ality (c is the velocity of light). Com-
parison ..,ith the experinicntal data for solutions of nitrobenzene
and acetone in nunLiolar. solvents showed fairly satisfactory agree-
Oard 2/3

KORCHLI-13KAYA, KJ4.;
I ; LELOCHUK, S.L.; KORABLINA, T.P.;
BABURINAI I.I.; VOLDNINA, R.D.
Investigation of the vapor pressure and vapor density of binary
solutions of silane chloro derivatives. Part 4. Izv.vys.ucheb.
zav.; khimA khim.tekh. 5 no.l.-65-69 16,1. OIRA 15:4)
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova.,
kafedra fizicheskoy Idlimii.
(Silane) (Vapor pressure) (Vapor density)

EERIDZE, D.K.; SHAKHPARONOV, M.I.
Some results of studies of Rayleigh scattering of light in the
critical region of stratification of solutions. Ukr.fiz.zhur.
7 no.7:771-778 Jl 162. (MIRA 15:12)
1. 14oskovskiy universitet.
(Light-Scattering) (8blution (Chemistry))

S/185/62/007/0()7/009/010
1048/1248
J, D -2
S.
-L'tering of li~;ht -.nd
y1ei.,-n sc!
I-), o-I uiolecul,--.r orient-7-on in
th e i i. r i b..z tJ -1
D I L fi-ychn.-,,y zhurn-.1, v.7, no,7,
190-27 782-786
T 3:,-,,-T :."hp 7-uth,-~r ch-llen.~7es th.(, v;,.ILdity of the m~,thcvia-
1 ~i-ed f,')r, ~he c-ilcil!-.ion of the term, the
lor the -'a so--t'ering of li,~ht. The v--llue of the
e t: Iu
T, ~* scat'erin,- R c~,lculnted by the :instein method is
cpelilclPl 0. k, -
.I- 201A heighar th:~.n I? exp~riznental. IR cnlculnted by the other
Cz-,.rd 14

S/185/62/007/007/OOGI/010
1048/1248
i-; by j(Y,0' ~.h-.n the eyi)--~riraental v-.lue. Better
;i xr-'eT',cn,, io obt- _i!ied wit~i I-Ae -~,:;.zation (n~:;f (2) . A n
e qur,i i,-, ve(, fo co ,- ff i-ci ent of s cat t e ring caus ed by
u c i),z, s i n 46-h o,-, n t --ti-)n of thc~ molecules (RO.,) in a multi-
corr,;)onen't R IN 1. X= t I )
or x ~ (10)
ic-re x., is the fr-c~i~-m Of compone
nt is the opticn.1
ar.isotlropy, Y io the nWlibf~?r 0.1" components in the Solution, N1 is the
namber of molcc:d,~s of c-)i-,ii:nn,.2,it C, in one ml. of the system, -;.nd
!7 ~------j + There are 4 figures.
A
A3SOCL'%'I'ION: "~oslkovskiy Ltaiversitet (The University of Yoscow)
Card 212

S/185/62/007/007/010/010
1048/1248
A U T1 1, Gj~: ~3) Sh~tkhp-~roiiov, I-J.I., Tunin, M.S., Lanshina, L.V., and
T IT L E TIP, hyper,)colistic I)roperties of.liquids and the
structure of molecules
PERIIODICAL; Ukrninslkyy fi7ychnyy 7hurnp.1, v-7, no.7,
1962, 792-796
T,SXT: The di,-;,,)ersion of Sound vt~locities in the hyper-
acou8tic rz~n';ew!is stuai,~.,d in ~~ number of pure liquids, using the
techni(,ur2 described by I.L. F;ibelinskiy in UNF 63, 355, 1957. The
ekperiments were cprried out tt 20-850C and were based on the ex2mi-
nation of the fine structure of the 4538 1 Rayleigrh line. The
Card 1/~

S/185/62/007/007/010/010
1048/1248
'The hyper:i.coustic properties of...
ha-vin-, Tr-Plectrons, i.e. in all whose molecules --tre comp.-;.ct and
pos2ess a relijtively large namber o.,L' mobile electrons. The mecha-
nism of the rkcoustic dispersion in non-dissociated li.uids.is dis-
ca~;sed, ana n. certadn anslogy iti discovered between -the structure
of a molecUe and its tendency towards fluorescence and acoustic
relaxation. There are 2 tpbles.
ASSOCIATION: Nloskovskiy universitet (The.University of Moscow)
0
Card 3/3

AUTHORS: Shakhparonov, M.I.
3/1-5/62/007/008/004/008
D234//D308
Kasimov, R.M.t and Akhadov, Ya.Yu.
TITLE: Dielectric properties and molecular structure of
concentrated liquid solutions
PE:~70DICAL: Ukrayinslkyy fizychnyy zhurnal, v. 7, no. 8, 1962,
874 - 882'
T-".':(T: The authors give some of the results of a study of relaxa-
tion of.the dielectric polarization of the following solutions:
acetone-benzene, acetone-CCld, nitrobenzene-hexane, acet,one-nitro-
benzene, acetone-met4,yl alcohol and acetone-water. Dielectric con-,
suant and losses of these solutions were measured at 3.21 cm and
8.15 mm wavelengths by Poley's waveguide method. The experimental
values were used for calculating the macroscopic relaxation times.
Enthalpy and entropy of the activation of molecular reorientation
in an external electric field were also determined. It is concluded
that the solutions of nitrobenzene in hexane and of acetone in ben-
zene and M have random distribution of molecular orientation.
Card 1/2 4

S/185/62/007/008/004/008
Dielectric properties and ... D234/D308
The process of relaxation of polarization in acetone-nitrobenzene
solutions can be approxim%-tely represented as a superposition of
t,.vo independent processes. There are associated complexes of mole-
cules of the solvents in solutions of acetone in water and methyl
alcohol. Th-ere are 7 figures and 1 table.
ASSOCIATION: P'loskovskiv universitet (moscow University)
Card 2/2

KORCHEMSKAYAY K, M.; SHAKRPARONOV, M. I.
Thermodynamic properties of solutions of acetone-nitrobenzene.
Vest. Mosk. un. Ser. 2'. Khim. 16 (i.e.171, no.6:76-77 N-D 162.
(MIRA 16:1)
1. Kafedra fizicheskoy khimii Moskovskogo universiteta.
(Acetone) (Nitrobenzene) (Solution(Chemistry))

40734
6/076/62/036/009/007/)11
B101,/B102
A Ui 0 1
TIT_~L: prt:;'6jc%,.s in the theory of molecular light scatterin- in
41CUICS
Zhur-!al fizic~ieskoy khimii, v. 36) no. 9, 1962, 2030 - 2035
TF,*"T: The calculation of is analyzed. A COMDarison of the cal-
(V T
culated values rith experimental data shows that the calculation according
to K. Ramanathan and I.Ro,-kard gives values for the scattering factor,
which are too lov. and rhich deviate from the experimental value by an
averaf,e of 3_3~6. The calculation of the Lorentz-Lorenz equation according
to Einste;_n'is correct. Those vaLues rhich are too ' high by an averan,-e*olf
20c' with rc~pect to the experiment*are ex)lained by the inaccuracy of the
Loren t7-Lorenz equation, in %-ihich. the isothermal polarizability is out
val to -,ero. "'he calculation accordin(-. to Einstein - Smoluchov:sky dives
true v~tlue!i If corrections are made for the refractive index and the
The best resiilts are -iven by the calculation accord`nE.
to -rhereby t,-(., devirjtions from experiment do rot exceed 11~. By
Card 1/2'

- ",. _jv,
jrot 1,-ns in tiic. tl-co-oy ... B I '_'l /S 102
c 0-: i 3 r, n 1, m~~n t 1 .1.- ~ n t--. e c L! I c Ll 1::i t i on o f t ~: i e Lin i s o t ro c
-F -Lc 0 r R or c..;.~)t3.o-klly oriented molecules accorllin~-, to
a - a + a S
x
a r Of !.iO1CCLll0.-, -jer cr.-.3, a
'Y
1~:ri -at -t- iL i ty , ive-; ron,l ---reciaent for nonas-:ociuted li,uins. Ilt-
1 ,-ind propanol is causea,' bj association. The accuracy
errors in tieterlninin~-,
of c,Ilci:la2.~ r c; noss-
;a_- c yet be;~n devel:).-.Pd. me sur ;:i n t i -i
'U~ j e
ry ';'he-e is I 'a; e. ':",,e ~,os t im jcr an t
C n C 05 S ". k. -
j . - .11 - I /
n C..0 or. c o _E: F'vre, 1,e r evre
.90C., 1 '53- 1 - 7- 1:51j .3644, 1 `57; 1455, 19':6, 4.23, 1,- 1
_-)il'c.-.i-:~-Eia:-., '.2r-!nS. ? a ra d!7 o c . , 54, 611 , 1956.
i LJ --iniversitet im. V. iomonr),q-)vp
z~tat._- Universibv ii,,iLni T.'.. V. Lainonov-7%
Gard 2/2

.*14017346 BOOK EXPLOITATION
Shal,hparonov, Mikhail Ivanovich
S/
Methods of investigatine molecular thermal motio and the structure of liquids
(Matody4t isaledovaniya teplovogo dvizheniya molekul i stroyeniya zhidkostay),
(Moscowl, Izd-vo Moak. univ., 1963, ill*da-, biblio.* index. 4,750 copies
printed.
TOPIC TAGS: physics, liquid, molecular thermal motion, molecular structure,
dielectric property, dielectric permeability, polarization, light diffusion,
nonelectrolyte., radiophysical methods,, optical methods,
PURPOSE MM COVERAGE: This book examines the experimental and theoratieal bases
of a n'u;nber of radiophysical and optical methods of studying the molecular thermal
motion and structure of certain liquids and solutions of nonelectrolythes. The re-
sults of investigations of liquid systens withou'L. an intermolecular hydrogen bond
conducted by the author and his associates in the Laboratory of Solutions of the
Chemistry Faculty of MZU are given. A number of problems of molecular theory of
the liquid state are analyzed on the basis of these results. The author tried to
write the book not only for specialists in the theory of liquids, but also for
researchers in related fields,, advanced students and graduate students of physics
Card 113

Amw17346
and chemistry who are interested in the theory of the liquid state. Therefore,
relatively complex or long mathematical analyses and also many tables are placed
in the appendix, at the end of the book. The author gratefully notes that section
1 was written with the help of *R. N. Kasimov, Ya. Yu, Akhadov, and I. A. Vakalov;
D. K. Beridze part Ucipated in section 9; R. M. Kasimov wrote Appendix D. The
author is grateful to professors V. M. Tatevskiy and K. V. Topchiyev and Candidate
of Technical Sciences B. D. Zaloga for assistance in organization of the research
and to professors A. Ye. Glauberman and G. M. Panchenkov for reading the manuscript,,
the editor., Candidate of Physical-'MIathematical Sciences K. P. Gurov,andassociates
of the Laboratory of Solutions M. Ye. 111artynova. and K. M. Korchemskaya for assis-
tance in preparing the manuscript for publication.
TkBLEE OF CONTENTS [abridged]:
Foreword - - 5
Introduction - - 6
Ch. 1. Dielectric properties and molecular theory of certain liquids 12
Ch. H. Relay diffusion of light and the molecular structure of liquids - - 72
Ch. III. Molecular ther-mal motion and the structure of concentrated
Cord 2/3

1
~
1414017346
solutions of nonalectrolytes - - 115
Appendices - - 205
Bibliography - - 276
SUB CODE: PH SUBNITTIED: 21 Aug 63 NR REF SOV: 113
OTM: 090 DATE ACQ; 12 Mar 64
Card 3/3

SHAKHPIARONOV, 14. 1.
Thermodynamics of dielectrics. Vest.Mosk.un. Ser.2: Mim. 18
no.6:11-13 N-D '63.
!~ 17:41
1. Knl'edra fizicheskoy khimii Moskovskogo universiteta.

S/189/63/OW/002/004/010
A057/A126
AUTHORS: Vakalov, I.A.-4 Shakhparonovo M.I.
TITIB; Low-frequency dielectric permeability and the structure of acetoro -
nitrobenzene solutions
PERIODICAL: Vestnik Moskovskogo universiteta, Seriya II, Khimiya, no. 2, 1963,
22 - 23
TEXT: The mean macroscopic dielectric permeability F-s measured in low-
-frequency-fields has to be smaller than the mean local dielect ity
ric permeabil
e in solutions, where the vapor pressure shows a positive deviation from
RaoLt's law according to earlier papers of the author (Shakhparonov, ZhFKh, V.
32, 1958, 1,414; V. 34, 196o, 977, 1,478; V. 35, 1961, 1,177)-' Investigations
by F.M. Skirrov (Z. Phys. Chem., v. 41, 1902, 139) and W. Graffunder and E. Hey-
mann (Z. Phys., 1931, 744) indicate that the vapor pressure of acetone - nitro-
benzene solutions (250C) obeys Raoult's law. This is in disagreement with re-
sults obtained by K.M. Korchemskaya, and M.I. Shakhparonov in a previous work
(Vestn. Mosk. un-ta, ser. khimii, no. 6, 1962, 76), i.e.p* considerable deviations
Card 1/2

S/189/63/000/002,//004/010
Low-frequency dielectric permeability and .... AO57/A126
from Raoult's law were observed, thus proving fine-structure fluctuations of the
concentration. These experiments were repeated in the present work for an ap-
proval. The measurements were carried out with 8 . 105 cps on a Czech "Tesla"
W-271 device based on the change of the reactive conductivity of the resonance
circuit. The accuracy was 0.2 - 0.5% and the obtained results demonstrate devi-,..~
ations from linearity in correspondence with the equatioh for 79se - Es. This
deviation from linearity, which can be approximately deduced from the theory of
Onsager, is apparently caused by the effect of fine-structural fluctuations of
the concentration. It can be assumed, in relation to Onsager's thzory, that in
acetone - nitrobenzene solutions the mutual orientation of molecules is*distri-
buted chaotically, Hence, any mutual orientations of molecules of acetone and
nitrobenzene nan be considered with sufficient accuracy energetically equal in
temperature range of 10 to 40*C. There is 1 table.
.,he
ASSOCIATION: Kafedra fizicheskoy khimii (Department of Physcial Chemistry)
SMMITTED., July 4, 1962
Card 2/2

SHAKHPARONOV' M.I.
Theory of solutions. part 1_1: Effect of fluctuations on the
dielectric-constant, permeability, and electric conductivity
of solutions. Zhur. fiz. khim. 35 no.5:977-983 MY 161.
(MIRA 16:7)
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova.
(Electrolyte solutions)

SRAKHPARONOV, M.I.
Thermodynamics of dielectrics and the molecular structure of
liquids. Zhur. fiz. khim. 37 no-5:1169-1.172 My 163.
(MIRA 17:1)
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova.

YFREMI N, Ye.!,'., Prof.; KISI--LEV, A.V., prof.; KOBC)ZFV, N.I., prof.;
FA',!CFvN'r%C)V , GM, , prof ;:~OILITGRA.K.,
Ci ?:-.H
prof . ;
Yu.V.., prof.~ SHAKHFAIRONGV,
0 J!, ) prof . ; SKURATOV.. S.M. prof
FTCZU!-
K.V., prof.; - OVSKII, N.'
- n . .9
M.I.. prof.
lAkov ivanovich Gerasimov, on hds sixtieth birthday. Zhur. fiz.
khim. 37 no.12:11803-2-1804 D 163. (ff~ 17: 1)
1. Kafedra fizicheskoy klilmli Moskovskogo gosudarstvennogo
unfversf teta,

/020/63/149/002/028/028
BIOI/B144
'AUTHORs Shakhparonov, M. I.
TITLEz Nature of substances with intermolecular hydrogen bond
PERIODIM: Akademiya nauk SSSR. Dokladyj v. 140, no~. 2-1963, 374-377 j:_
J
TEXT. The usual concept that the.high stationary dielectric constant of
water and alcohols is due to dipole polarization and association runs
contradictory to the experimental fact thaf in water and alcohols Eis
linear function of VT and the Debye equation is valid. This is explai
by formation of.proton energy bands similar to the electron bands of
semiconductors. Valency bands and conduction bands are assumed separatedi
by a very wide forbidden band which can-be overcome by the protons in thel.
tunnel effect*only in the presenoe of 01 N, Fj GI, or 3 atoms creating an],
intermediary band similar to the impurity band of semiconductors. When a
weak electric field is applied, a redistribution of the protons sets in
between the "proton gas" and the.intermediary band. This entails the
electric polarization which is otherwise explained by orientation of the..:-
dipoles. Since the energy of this.redistribution is almost zero, uls t
linear function of I/T. Equally', the proton relaxation time is indep6n-
Card 1/2

1 9 002/02 28
/0
S 2Y63
B10 B
Nature of oubstances with ... 1 144
dent of the orientation of the moleculest but is a function of the A.
difference between the energy levels of the conduction band and the
intermediary band. With the exception.jof the critical region* this
difference is the same for all protons of the liquid and therefore th
Debye equation is valid. Owing to the anomalous mobility of the protons.''
in substances with intermolecular H bonds, the deformation polarization,
'of these substances also is abnormally-high. Water, alcohols and other
~substances with intermolecular H bonds are, so to speak, proton semi-
-conductors. In analogy to.the metal binding of electrons, it is her9
the case of a metal binding of protons. There is 1 figure*

FEThUSH-EVSKIY, S.A., otv. -red.; KOLBANOVSKIY, V.N., -red.; PLATONOV
IM
G.V., red.; SHAKHPARONOV, M.I., red.; SHIRG~ V, M.F.) red.;
VTI-OPGVICH red.
GD .1
(Dialectical materialism and present-day natural science;
materials of the All-Russian Seminar of Lecturers in Social
Sciences on philosophy problems of present-day natural sci-
ence] Dialekticheskii materializm i sovremennoe estestvozna-
nie; sbornik materialov Vserossiiskogo seminara prepodavate-
lei obshchestvennykh nauk po filosofskim voprosam sovremen-
nogo estestvoznaniia. Moskva, Izd-vo Mosk. univ., 1964. 403 P.
(MIIU 17:7)
1. Moscow. Institut povysheniya kvalifikatsii prepodavateley
obshchestvennykh nauk. Kafedra dialekticheskogo i istoriche-
skogo materializma.

1~4

SHAYMPARON07- P.I.
of a liqulr'~ having intermolecular h,,-drogen bonda.
Ukr. fiz. zhur. 9 n0-4-444-453 Ap 164-til 7 (M;iAA 17.:0

M, L.; D.
Rayleil.gri sca~,-.er-nig cf lig t &nd the mlecular structure cf acetone
gh, -
&nd e thy7 a ',h=r solutil-;ns ir, chicrofom. OTt. ~~ s::P-ktr, 17 ro.
-~ - -1
396 S 964. (MIPU 17:10)

tF
PSEIIKOVA, V.M.; KHROMOV, S. I.; STIAKPPARONOV, 14.1.
December PleniuQ of the Central Comittee of the CPSU and the
-),,:~raicai science at Moscow university. Vest. Mosk. un. er. 2:
F]-.jr,-. -19 no.1:3-19 Ja-F 64. (MIRA 17:6)

GOUNYKINA, V.V.; VAK-4UN, j. A~ ;SHAMPARONOV, M. i.
f)J6150tr-ic cOa---5.rT, arid mcdecu!Ea- otructure PP -.-vr
.L - . idtne-
.1
OL~croform SrJ,uti--.n,,. Vust. Mosk. un. S6r. 2.adm. 19 no.l-.
33-3-1 Ja-F '64. (MIRA 17: 6)
1. Rafedra fizl-,-hi:;zk,,y ~-!Ajrdi Vrj'v-oj-,k,-)go Lul-ivorsitsta.

an(4 ror--Iecul,~- Z f~nuct-.:-;, of P-c:e
n. C
-ne - t-~ "S.

-t Mr, e r

ACCESSIOIN~ NR: AP4019511 S/0076/64/038/002/0252/0265
AUTHOR: Shakhparonov, M. I.
TITLE: Substances with intermolecular hydrogen bond as proton semicoriductors
SOURCE: Zhurnal fizicheskoy kh1mii, v. 38, no. 2, 1964~ 252- 265
TOPIC TAGS: proton semiconductor, proton exciton; proton defect, hydrogen
intermolecular bond, proton conductivity level
ABSTRACT: The author assumes that protons, like electrons, in condensed me-
dia have a conductivity zone separated by the zone of forbidden states in addition
to the valence zone. Normally (for instance in saturated hydrocarbons) the
Nvidth of the forbidden zone is great and practically no protons reach the conduct-
ivity zone. But in certain cases, for instance, when the substance is capable of
formin- intermolecular hydrogen bonds, the forbidden interval, narrows and the
transition of protons from the vale-ricy zone into the conduction zone becomes
possible. A diagram of -energy levels in proton semiconductors is given, show-
C.rd 1/2

ACCESSION NR: AP4019511
ing proton exciton levela (exciprotons) and an intermediary level which is simi-
lar to the admixture level in electron semiconductors. After a detailed discus-
sion of topics such as dependence of dielectric constants on temperature, and on
frequency, on proton mobility in semiconductors and on the theory of proton
defect mobility and comparisons of theQretical premises with experimerital data,
the author arrives at theifollowing conclusions: substances with intermolecular
hydrogen bonds can be pi~oton semiconductors and proton dielectrics. Dielectric
polarization of water, of a number of low-molecular alcohols, of acetone-chloro-
l
o
;! rm solutions and other substances with intermolecular hydrogen bonds in a
wL
ide spectrum of frequencies can be explained with the aid of the concept of pro-
ton excitons (exciproton's). The anomalous mobility of protons and defects can be
e--.:plained by the theory of proton semiconductors. Orig. art. has: 6 figures,
1"I formulas, 1 table.
_'.'~'SOCIATION: Moskovskiy gosudarstvenny*y universitet im. M.'V. Lomonosova
k':--'1oSCQW State University)
-----:'D: 0"May63 ENCL: 00
~ ~ - V DATE ACQ: 3lMar64
J--_~" COD CH NO REP SOV: 015 OTHER: 036

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SIU, Kilt;JM41(~V , i i. i -
'7'tie~-Ify Cf* ',4-:t,' hydrogen buds. Zhur.
fiz, k--.i-.rq. 38 no.10:2478-4-483 C, 'bL. (MIR.4 18:2)
1. fakul'tet ,Iosir,c,,,,s.,,-cao gosudarstvenriogo univer-
, ~.? n
siteta imeni M.%'. i,omonosova.