SCIENTIFIC ABSTRACT SETINA, R. - SETKINA, V.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001548210006-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

SETINA, Rudolf, MUDr.; VESELY, Emil. MUDr.
Experience in the protection of the perine,= with hyaluronid-ase.
Cask. gyn. 21 n0-5:304-306 Sept 56.
1. Gyn. por. odd. OUNZ Piestany, prednosta primar MUDr. Emil Vesely.
(PERIMM, wounds and Injuries
.laceration in labor, prev.*witb hyaluronidase 00)
(LABOR. complications
perineal lacerations, prev. with hyaluronidase (Cz))
(HYALURONIDASE, therapeutic use
prev. of perineal laceration In labor (Cz))

SEETINk, Z.
Safety of train traffic without regular signals on the tracks. p. 177.
ZELEZNICNI DOPRAVA A TECHNIKA. (Mnisterstvo dopravy)
Praha,, Czechoslovakia
Vol. 7. no. 6. 1959.
Monthly List of East European Accessions (EEAI) LC, Vol. 8, No. 11.
Nov. 1959
Uncl.

SETINEK, K.
Silicon organic compounds. XIV. Inhibition of the direct synthesis of
methylchlorosilanes by nitric oxide.
p. 639 (CHEI-11CKE LISTY) Vol. 51, no. h, Apr. 1957,
Praha., Czechoslovakia
SO: Monthly Index of East European Accessions (EEAI) W, Vol. 7, No. 3,
March 1958

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CZECHOSLOVAKIA/Organid Chemistky. Synthetic Organic Cnemistry. G-2
Abs Jourt. Referat Zhur-RhImlya) No 4, 1958, "362.
Author Beranek, L. and Bazant, V.; Bazant, V. and Vavruska, M.
and Setinek, K., Bazant, V., and Sor. F.
Inst
Title Organosilicon Compounds. IX. The Gas Phase Methylation
of Chlorosilanes. X. The Hydrolysis of Phenylchloro-
silanes Over Alumirum Oxide. XI. Mass Balance in
theDirect Synthesis of Methylchlorosilanes.
Orig Pub: Sbornik Chekhoslov Ehim, Rabot) No 4, 1292-3298, 1293-
1305, 1306-1309 (1957) (in German with an English sunmnry)
Abstract: See RZhKhim, 1957, 446o6, 6o627, 68912.
Card : 1/1

CZECHOSLOWJWL/Orc~panic Chemistry - Theoretical and General G.
Questions in OrGanic Chemistry.
Abs Jour Ref Zhur - Khft-iiya, No 9) 1958, 2!")643
Card 2/3
later becomes very marked. In the opinion of the
authors nethyl radicals are presant in the reaction
space both in the Gas phase and on the furface of the
Si or at the surface of the consact mass (CM). The
radicals in the Cps phase combine to form silicon-
free reaction products while the radicals localized
on the surface of the Si or on the CM form the methyl-
chlorosilanes proper. The gradual decrease in the
yield of riethylchlorosilanes contInues until the =di-
cals present in the (.;iLs phase are exhausted. The sharp
decrease in yield bc(,ins when the NO which is added
beGins to react also with the radicals localized on the
surface of the CM. The reactions of the methyl radicals
in the gas phase are discussed, in particular, the reac-
tions with CHCl3 and H21 thernal decomposition,
CZECHOSLOVAKIA/Orcanic Chemistry - Theoretical and General G.
Questions on OrGanic Chemistry.
Abs J3ur Ref Zhur - -Khiraiya, No 9, 1958, 28643
and. disproportionation reactions. The theoretical con-
clusions are compared. with the e)q.,criraental data on the
composition of the reaction products (see RZM(hiu, 1957,
68912).
Card 3/3

arlo M X - Law-q.Ac
L
, ff:7
MeCl which increasts w-ab rising L~:mp. The app. and p o-
cedure were the same as alr~-tdy described (C-A- 51. 493f ~') -
T%e authors suggest that NO reac'-s prcftrent~aUy with - fie
irte ~je rn(firaig present in. thit gastQas phase which are i tit
in direct contact witt. the surface ot-S:- Oa!7~ vzlz= iu
higher comm. NO rCuts with the.-Afe radleakibich -pir_
ticipate directly in the synthesis of r, thus -ifigiU [ahibitu a.
uroptions are in conformity with th previcois fu d-
li~-S-Sthat tile noni-liceous ;R;:v-r0QdiiC-U0f A no Un-
Whited s;yntfiesla of I arise from the free

Z/009/62/000/008/001/002
E112/E435
AUTHORS: Set:(nek-,-Kax-e.1-,, Cernys'ev, J.A.
TITLE: Thermal decomposition of trichlorosilane
PERIODICAL: Chemicky' prilmysl, no.8, 1962, 41.9-422
TEXT: The pyrolysis of S"'C'3 was studied in a silica tube packed
with crushed silicate glass at 525, 550, 6ob and 750*C,. partial
SiHCl3 pressures of 0.1 to 0.5 atm and flow rates of
10 to 70 mole/hour per I litre of reaction space. The products
of thermal decomposition were identified by gas chromatography,
using nitrogen as carrier gas and thermal conductivity as method
of detection. Trichlorosilane was found to be stable at 5250C.
Decompo'sition began at 5500C, giving rise to te-Lrachlorosilane and
hydrogen. A solid decomposition product was also detected in
minute quantities, collecting on the walls of the silica tube and
over the silicate packing. A quantitative analysis of the solid
substance was not undertaken because the collected quantities
were insufficient. Analyses of the gaseous decomposition
product. under varying experimental conditionsare presented in the
form of graphs. The rate of decomposition of SiHC13 increases
Card 1/3

z/ooq/62/ooo/oo8/ooi/oo2
Thermal decomposition of E112/E435
with temperature. However, during the initial stages of
decomposition, pyrolysis proceeded at a considerably diminished
rate. Therefore, it is postulated that the solid pyrolytic
decomposition products may catalyse the thermal decomposition,
and that the smooth non-contaminated walls of the silica tube may
inhibit it. To clarify the effects of surface characteristics on
the course of SiHC1 decomposition, a series of experiments were
carried out in whicg-the surface areas within the silica tube were
varied by varying the granular diameters of the silicate packing.
Although the effect of the clean non-conta-ininated wall surface was
again clearly discernible, influences of surface areas or
characteristics were not detected. It was confirmed that swooth
and clean wall-surfaces inhibit the decomposition of
trichlorosilane. However, as soon as-the walls of the silica tube
are coated with a thin*film of the solid decomposition product, the
cause of inhibition is removed and pyrolysis proceeds entirely in
the gaseous phase. Stoichiometrically, the pyrolysis of SiHC13
was assumed to proceed according to equationt-
4SiHCl 3 = Si + 3SiC14 + 2H2- Although analyses of the
decomposition products showed agreement with the above equation in
Card 2/3

KRAUS, Milos; KOCHLO&FL, Karel; SETINEK,__KMel; BFZAMK, Ludvik;
HOUDA, Miloslav; BAZAN
The course of potassium phthalate rearrangement to potassium
terephthalate. Chem pr;= 12 no.10:529-534 0 162.
1. Ustair teoretickych zakladu chemicke techniky, Ceskoslovenska
akademie ved, Praha.

KRAUS, Milos; SETINEK, Karsaj JOST, Frantisek; BAZJ.NT, Vladimir
Some properties of catalysts rar rearrangement of potassium
phthalate into potassium terephthalate. Chem prum 13 no.2:67-70
F 163.
1. Ustav teoretickych zakladu chemicke techniky,
Ceskoslovenska akademie ved, Praha.

SETfNEK, K; RATHOUSKf, B.
Czechoslovakia
Institute of Theoretical Bases of Chemical Techni ue,
Czechoslovak Academy of Science -- Prague - Nor both)
Prague, Collection of Czechoslovak Chemical Commun-icationeq
No 4, 1963, Fp791-996
"Apparatus for the Differential Thenioanalysis under
Pressure aad Pouring Gas through the Investigated
Matter."

RATHOUSKY, 4iri; SETINEK, Karel; KRUGHNA, Oldrich; EAZANT, Vladimir
Basic principles of terephth-glic acid isolation from potassium
terephthalate. Chem prum. 13 n0-4:170-173 Ap 163.
1. Ustav teoretickych zakladu chemicke tedhniky, G6skoslovenska
akademie ved., Fraha.

SETINEK, K.; BAZANT, V.
Preparation of dienes by pyrolysis of cyclic compounds. V. Preparation
of butadiene by pyrolysis of cyclohexane. Coll Cz chem 26 no.2:
F 161. (EEAI 10:9)
1. Institut fur theoretische Grundlagen der chemischen Tachnik,
Tschechoillowakische Akademie der Wissenschaften., Prag.
(Olefins) (Pyrolysis) (Cyclic compounds)
(Butadiene) (Cyclohexane)

RATHOUSKY, Jiri,- HRUCHM, Oldriah; SETREK, Karel; BAZANT., Vladimir;
SILADI, J.
Practical problems of terephthalic acid isclation from the
rearrangement product of potassium phthalate to potassium
terephthalate. Ghem prum. 13 no.6:295-299 Ja t63.
1. Ustav teoretickych zaklAdil chemicke. techniky., Ceskoslovenska
akademie ved., Praha (for a.U.9 except Siladi).
2. Spolek pro chemickou a hutni vyrobu,, Usti nad Labem (for
Siladi).

SETIMKJI K.; RATHOUSKY, B.
Apparatus for differential thermal analysio under pressure
with gas passage through the examined subs-:ances. Coll Cz
Chem 28 no.4:991-996 Ap 163.
1. Institut fur theoretische GrwxUagen der chemischen Technik,
Tachechoslawakische fikademie der WiasenscluLften,, Frag,
i

SETINEK, Karel; BAZM, Vladimir
-
Study of potassium terephthalate prepara",ion. Chem prum 13 no.10:
509-512 0 163.
1. Ustav teoretickych zakladu chemicke tfjchniky, Ceskoslovensks,
akademie ved, Praha.

hATHOUl-'KY, Jiri; Kare-,; ~RUCHN:',, 1)-Cir IC ti; ai. ZANT, V1hd1rELr
Kine+,ic3 of L-e foruatior, acid by V;~:.' of
potassituri hy, rogen terephthalate with plit'r-"Llic anhydride In aque=3
medium. R-um 14 no.5.-2;~'4-2-29 My 164.
1. Institute of Theoretical Principles of Chemical Technology,
Czechoslovak Academy of Sciences, 11'rague.

CZECHOSLOVAKIA/Electi,onics - Photoce2lls am'. SeYrdaoz!Zm_1;~t-.)r Devixes H-8
Abs Jour : Ref Zhur - Fizika, ITo 4, 1958, ITo 8882
Author :Siebe:~ Bohmil YLOU-nac Setf-ek.0takar
Inst :Not Given
Title :Effect o-' Dec.--lexating Lens z)n Przperties of Raotiation Pa'._
tII:Jrr_ of R.~ctanfraltir Horn with Miase Correction.
Orig Pub Slaboprcmdy -,)bzor, 3.957, 18, No f), 320-323
Abstract The allthO:73 consider the we-11 -1mown- theory o fL Plea-trMagnetic
lense,- an-a give certain little Imown relatioaships which are
of great importance in the caLculastion of antenna lenses,
and which are. irt usually faj_nd. in the literattre. A quanti-
tative v~etezmination i's made of the influence of the deceler-
ating lenb on the radiation amplitur'le f~7am a rectangLil-azz horm
with phase correction. By a suitable construction it is pos-
sible to obtain a sharp reiuction in side lobes at the cost
of a sman broad.ening of the prLncipai lobe.
Card 1/1

JELINEK, M., Dr.; SNKA, J., Dr.; VOSTA, j., Ph., Mr.
LamblIssis with febrile course. Cas. lek. cesk. 93 no.7:
166-171 12 Feb 54.
1. Z interniho oddeleni nemocnice v Tabore-primar MUDr.
Marian Jelinek.
(GI ARDI AS I S,
febrile course.)

MARATKA, Z., Doc., Dr.; SKM, J., Dr.
Therapy of tanniasis with atebrinj experience in 66 cases.
Vnitr. lek., Brno 1 no.10:765-767 Oct 55.
1. 11. vnitrni klinika KU v Praze a vnitrni oddelani nemocnice
v Tabore II. vnitrni klinika. Praha 2. U nemocnice 2.
(TAPWORM INY TION, therapy
quinacrine.)
(WINACRINE, tber. use
tapeworm infect.)

SETKA, J.
*---
Relation of bacillary dysentery and ulcerative colitis in rectoscopy.
Gas. lek. cesk-. 96 no.38:1193-1197 20 Sept 57.
1. 111 interni klinika, prednosta akademik J. Charvat, Praha.
(DYSENTICRY, BACILLAM, differ. diag.
ulcerative colitis, value of rectoscopy (Cz))
(COLITIS, UICNATIVIC, differ. diag.
bacillary dysentery, value of rectoscopy (Cz))

SETKA. Jaroslav; PILUCHA. JIRI
Gastritis chronica, Gastritis in alcoholics. Cas.lek.cesk. 99 no.Z:
50-53 8 Ja 160.
1. 11. interni klinika, prednosta prof.dr. 7. Herles. Vyzku=y ustav
pro adelovaci techniku A S Popova v Praze.
(GASTRITIS e;i;l.)
(AIGOHOLISM comple)

BEDNAR, B.; MARATKA, Z; SETKA. J.
Histology of ulcerative colitis. Cas.lek.cask. 99 no-5:147-152
29 Ja 6o.
1. 1. patologickDanatomicky ustav KU, II. interni oddeleni ne-
mocnice na Bulovee, II. interni klinika KIJ v Fraze.
(COLITIS UWZRATM pathol.)

GREGOR,O.; SrPKA,J.; BBDULR,B.; JIR&SXK.A.
Gastric biopsy in pernicious anemia. Gas. lek. Cask.99 no-17:
528-531 '22 Ap-16o.
1. 1. interni klinike, KU, prednosta prof. dz. M. Netousek,
II. interni klinika KU, prednosta prof. dr. Yr. Heries, I.
patologicko-anatomicky ustav, prednosta doe. dr. B. Bednar.
(AHMIA PXFSICIOUS ppthol.)
(STOMALGHLpathol.)

1-U.RATKA, Z.; SETKA, J. -__
Role of the small intestine in chronic intestinal disorders.
1. Screening by the determination,of fecal fats with the aid of a
chemical method. Cesk. gastroent. 16 no.2:130-133 Rr 162.
1. 11. vnitrni oddeleni nemocnice v Praze-Bulovee, prednosta doe. d--.
Z. Maratka II. vnitrni, klinika Karlovy university v Praze, prednosta
prof. dx. F. Herles.
(ITTESTINAL DISEASES) (FECES) (FATS) (SPRUE)

SETKA, J.; 1URATKA, Z.; ANDRYSEK, 0.; KOCANDERIS, K.
Role of the small intestine in chronic intestinal disorders.
II. SUreening with the aid of the determination of labeled fats
in feces. Cesk . gastroent-. 16 no.2:134-138 Mr 162.
1. 11. vnitrni klinika Karlovy university v Fraze, prednosta prof.
dr. F. Herles II. vnitrni oddeleni, nemocnice v Fraze-Bulovea, prednostadoc.
dr. Z. Maratka Biofyzikalni ustav lekarske fakulty KU v Praze, prednosta
doe. dr. Z. Dienstbier.
(INTESTINAL DISMES) (FATS) (FECES)
(TRIOLEIN) .(OLEIC ACID) (SPRUE)

DVOHAKOVA, Hana; S:,-"TKA,-Jaroslav; STM".OVA, Bohumila; TtC;SNAKOVA, Rilena
Tetracyclinc in tho diagnosiv of gastric cancer. Preliminary
communication. Cas. lek. cesk. 101 no.41:1244 12 0 162.
1. 11. interni klinika fakulty vseobacneho lekarstvi KU v Fraze,
prednosta, prof. dr. F. Horles, DrSc.
(TETRAGY-CLIT-1,S) (STOMACF ITEOPLASYS)

V4
:!-Vall"I., Z;
1.0coad ln'"xT.U ;'.0dioing Olinic. of ;harlau Univaralty
(11 vnitrai 'clini EL !;6)q j?ra,-,Uo; 2. 3ec*ud
into,rmal Madicine *.-.'ard of tho 1;0Qpital (11.
-mitmV. oddelarl namoarAoe), Piu,~uu-3ulov;ua;
First Pathalogicnl AnatomIcal Inatituto
?1.-. ;aL310'-flokil kl-.;ato,Ac*,cy Uatav KU), ljm~;Ua
B=0, VIWItmi le!mrpt7t, 170 6, 19VC3, 41-562
*Tha Sigulflomom Of Biopsy of %wtria
a

CZECHOSLOVAKIA
DOIRM, L; SETKA, J; HOUSKOVA, J; SETKOVA,, 0.
Z-~
Second Internal Medicine Clinic (II. vnitrni Rlinika),
Prague
Brno, Vnitrni lekarstvi, No 9, 1963, pp 886-8Sio
"The Significance of the Investigation of Blood Coagulation
in Cirrhosis of the Liver."

A11DRYSEK, 0.; ANDRYSKOVA, J.; DIENSTBIM, Z.; JEKLER, J.; JEKLEROVA, J.;
SETKA, J,
Isotope examination of the portal circulation. Acta univ. Carol.
Imed) (Praha): SUPP1. 18: 4~,-48 164.
1. Blofysikalni ustav fakulty vseobecneho lekarstvi University
Karlovy v Praze (prednosta: doc. dr. Z. Dienstbier); II. chirur-
gicka klinika fakulty vseobecnebo lekarstvi University Karlovy
v Praze (prednosta: prof. dr. J. Lhotka); III. detska, klinika
fakulty vseobecneho lekarstvi University Karlovy v Praza (pred-
nosta: prof. dr. 0. Vychytil); a II. interni klinika fakulty
vseobecneho lekarstvi University Karlovy v Praze (prednesta:
prof. dr. F. Herles).

ANDRYSEK, 0.; SETKA, J.; !,1AFATKA, Z.; FROITDL, A.; SKALA, I.; KOCAIIDRLE, K.
Examination of' regor-ption disordara of the small intentine with
radioisotopes. Acta univ. Carol. [med) (Praha): Suppl. 18: 59-62
t 64.
1. Biofysikalni ustav fak-Uty vseobecneho lekarstvi Uriveristy
Karlovy v Praze (prednosta; doe. d--. Z. Dienstbier); II. interni
klinika fakulty vseobecneho lekarstvi University Karlovy v
Pr--ze (prednosta: prof. dr. F. Herles) a II. vnitrni oddeleni
nemocnice na Bulovce (primar doe. dr. Z. Maratka); Ustav pro
vyzkum vyzivy lidu (reditel: prof. dr. J. Masek).

AIIDRYSEK,O.;.�E J.;- PITHA,J.; SUP,M.; VIDRYSKOVA,J.
TP,
The value of gammagraphy in diffuse lesions of the liver.
Rev. czech. med. 10 no.1:8-16 t64
1. Biophysical Institute, Medical Faculty, Charles University,
Prague (director: doc. Z Dienstbier, IM.D., C.Sc.); Second
Medical Clinic, Charles University, Prague (director: prof.
F.Herles, M.D., Dr.Sc.) and First Institute of Pathology,
Charles University, Prague (director: prof. B.Bednar, M.D.,
Dr.Sc.).

ANDRYSEK, 0. ; OSETKA, j.
Diafrnonis of liver tumors with garinagraphy. Cesk. radios. 18
no.5:289-294 S 164.
1. Blefyzik-aln] uot,-.-.v (prednc)L;t.a doc. dr. ~'. DientsIrder, FjrS,:.', a
II inLerni klin-1ka (prednosLa prof. dr. F. Herles, DrSc.) fakulty
'Isco-lecnPho lekarstvi Karlovy v Praze.

JEKLER,J.;V12,'CEI'(,'OVA,B.; SETKA, J.
Contribution to the treatment of ascites in liver cirrhosis
with entectropy of an ileal loop. Rozh. chir. 43 no.lz
47-50 Ja'64-
1. 11. chirurgicka kl--'nika fakulty vseobecreho lekarstvi
KU v Praze (predrosta: prof.dr.j
..Lhotka) a Minteimi kai-
ni1ka falmlty vseobeeneho lei:arstvi KU v Praze (prednosta:
prof.dr. F.Herles).

DVORAKOVA, H. (Praha 6, Na Stahlavc9--9);AkM Jj- JEKLER, J.
our eAveriences with the treatment of hiatus hernias and irrita-
tion and inflammation of the esophagus. Cas. lek. cesk. 104
no.24;545-650 18 Je'0'5.
1. 11. interni klinika fakulty vseobeaneho lekarstvi Karlovy
University v Fraze (prednonta : prof. dr. F. Herles, DrSc).
a II. chirurgicka klinika fakulty vseobeeneho lekarstvi Karlovy
University v Frans (prednosta; prof. dr. J. Ihotka, DrSc.).

S,E,TK,A,, J..; ANDRYSEK, 0.; PITRA,J.; SUP.M.
Func'-ional ammination of diffase liver lesions Vith ge-magraphy.
Acm univ. Carol. [Ta;-:-d] (Praha)a Suppl. 18: 53-5-7 '64.
1. 11. interni klinika fakulty vsaobemeho lakarstvi Univer-
sity Karlovy v Praze (prednostau prof. dr. F. Herles); Bic-
fysikalni ustav fakulty -,~Eeob,-,-neho lekarstvi University Karlovy
v Praze fprrdnosta,. doc. dr. Z. Wlenstbier); I. patologickc-
anatomicky ustav fakulty vseobGnnehc, lekarstvi University Karlovy
v Praze (predpostas pr,-,f. dr. .3. Bodnar).

ANDRYSIT, 0.; AHDRYSKOVA,J.; DIEVSTBIER,Z.doc. dr.; JEKLEROVA,J.;
SETKA, J.-
Isotope methods in the examination of the por~;al circulation.
Cas. lek. cesk. 101+ no.lOt257-262 12 Mr 16).
1. Blofyzikalni ustav fakulty vigoobeeneho lekarstvi Karlovy
University v Praze (prednostat doc. dr. Z. Dienotbier);
II. chirugicka klinika fakulty vseobecneho lekarst-vi Karlovy
University v Praze (prednosta: prof. dr, J. Lbotka); III.
detska klinika fakulty vseobeeneho lekarstvi Karlovy Univer-
sity v Praze (prednosta: prof. dr. 0. Vychytil) a 11. interni
klinika fakulty vseobecneho lekarstvi Karlovy University v
Praze (prenosta: prof. dr. F. Herles).

erences. (IMs . received Apr bb).
CZECHOSLOVAKIA / GERMANY UDC 612-332.7( :5546-59.02)
ANDRYSEK, 0.; SETKA, J.; GEORGI., P.; GUTZ, H.J.; ALTEN-B,iUNN, H.J.;
BERNDT, H.; Biophysical Institute, Faculty of Gen. Med. Charles
University (Biofysikalni Ustav Fak. Vsoob. Lek. KU), Prague, Chief
(Prednosta) Frof Dr Z. DIEDISTBIER; 2nd Internal Clinic Fac. Gen.
Med. Charles University (II. Interni Klin. Pak. Vseob. Lek. KU),
Prague, Chief (Prednosta) Prof Dr P. HERLM-; Robert Rossle's Clin-
ic, German Academy of Sciences /-orig. version not given 7, Berlin,
Chief Prof Dr H. GIMMEL
"Passage of Au198 Through the Small Intestine."
Prague, Casopis Lekaru Ceskych, Vol 106, No 8, 21~ Feb 67, PP
210 - 2
Abstract /Authors' English summary modified 7: Au198 is not ab-
sorbed in the intestinal tract, it is inert, and when only 0.1 mg
is used,it does not irritate the intestinal wall during examina-
tion; the passage is checked by repeated scintillography. When
administered while fasting per os it takes 2 hrs to reach Bauhints
valve; Ba meal influences the transit time. 2 Figures, 1 Table,
I Western reference.
1/1

SETKERESTY, B.; SHNITZLER, I.
Synovectomy in tuberculous-gonitis. Probl. tub. no.7:59-6i 164.
(MIRA 18:10)
1. Tuberkuleznaya klinika Debretsenskogo meditsinskogo instituta.

S. 1.
Teytile SchooLs
'Iew syste-,i of teaching in tecmical hi~~h schools. Tekst. prom. 12, no. 3, 19"2.
9. Monthl List of Russian Accessions, Library of Congress, koril -1953, Uncl.
2

VERFSHCHAGIN, A.P.; SETKINA, G.A., studentka VI kursa
Effect of exteroceptive painful irritation on the action of
camphor in hypothuroid animals.. T-ady lzhev.gos.med.inst..21s
40-43 164.
(MIRA lgrl)
1. Kafedra normallnoy fiziologii (zaveduyushchiy - dotsent A.P.
Vereshchagin) Izhavskogo meditsinskogo instituta.

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ft'"n 'he change 10 The nmatant con only Je CIO 0
evul"aled hY nelllatlU end mcuit inicturtions. and Xive,
r.0 0
values 14% t- low; hence this inteiactiun esnact be
tat" nesiated. zoo
G. W. King
e0 ;-1ago
60 411
-.0
00
!,too
A j a I i A b[TALLUROKAL L.TffRATL*1_CLAjUFKAT?Q*
t
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lit ft
on 411, Go so 10, ;;J*o;;04;g 0 0 0 go 0 0 0 1 0 0 0 6 6 000 0 0 0 Or
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6660 0 660 0 0
IS IS U
a
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Z_
66
Jl~
k
00
0.0. 1, O's a
'
Pb0WVqhk Plot" to ultra,loki rays
Zarodskajw Lab. 9. No. 2. =-3(1941);
Kii-: Xlf-l- Zk-'. 19W. No. S.
Plates (2 H. & D.) can he utilized wi,bou, wasitiz&lion
for exP's. With Ultraviolet light dOYM to 2000 A. Scusiti.
"IM With refitted muhhwe oll inctwes 14igbtly the de-
tree of dukening withOut AhIfthIS the limit in the dirwim
Of short Waves. Lantgru.swc Plates (regardless of the
kind of wnsitizef used) are not suitable for j,"114,1M of
WR%T len
pths abmter than 2M) A. Unsemihised plates
of IWX) & D. and arthochroutatic plates of &%) and 2LI()
IL & D. can be used for r-ditk. down to 1854 A. if
wnsitized with 12-14% NSCYH,(h 3oln. in a1c. or with re.
fitw-d machine od. Methods for sensitiz with thpw
-IbLitizers are dexTibed.
iw R. Ifent:
. . .
see
0 a a V X V 4*8 40 4 45 41 0 in*
lee
lee
lee
me
See
a* 0
Ve
goo
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a m So 3 Al v Al SO 4 dl a d
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a

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ASMI-IL. OCT.LLU"ICAL LIT61RATWE MASSIFICATON
v 14M 1 Iwo NJ two .-- -- - - - - --.- -- - - -.-- I tow. va"Aftv
falabo "I t *0 d#; mallal.aw (MV 411 AN
4 0 c
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ASA-ILA SETALLUROKAL LITERAlljoe CLA$StFKA?16* 147"f", nee
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A IC A-L-,L a 14"!.q 41 t-4 1 is 41' ttit 1 0 1
g~
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r
-00
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mbatb" of pbokumvitik taliarpoution. V. K. Prokolaw
And Pc V. Selkina. Ct-mitt. rend. 4,ad. its. V.R.V.J.'
Mady .4 W. Xajs k S.S-V R. Q.
00 fl ,V
Twwp6m alualyis can Iw "CV11rat, IT vjjtt~rjj qit Ily 111P 00
11iftN41 Owl WC I IQ MUM, IIA" 'NIX41111 v0
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=fto=-
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it
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. Z
~ Apo" Cbm. (U
Is.
A
f
2
a curves
or
meth
I414tbo
d
d

68 mv, i were
ct
.
y
arm used " a msam cd lodiarlag the rate of forms.
the 0 pd-. 1vom acetamIdIme byckochlorlde and
thecRmao(
011 which were also dctd. A musiderable difermce betwien'

,3
0
:
the respective curv" r4em a goA possibilk y of ItAkTwing
the reaction course by spectropapby. 71m mrtion rair
0013 Is giveq gnLphk&Uy.. G. Ift. Kowilapoff
0-3
:
OW

0 * * 6 * 6 & 6 G
5 L A OCTALLUaGWAL WERATUM CLASSIFICATIM
also rmail" 9 34M 00. v
-P Impow MAP Imov ded - 40, 831LI'l dad 4"v At&-
- It r 1 9 Od 0 16 NI M 0 9 A 4 2 0 T
u 19 AT go a D'P -0 t-9a69 It a ;JI -1 11 1 it a do I as - "
9 0 66 0 -o ffi- ire 0 m 0 0 0 40 0 00 op 0 a 0 G 0 0
0, 010 * 0 0
ease@ 00 a of 0-0 'UN4 -0 (100 0 0 00 *so **#*a of

Ultraviolet zbwption specirtun of the 11trLICILO&I W010108
of be muscle, Kit Af, Itavikovirls 0 N" S~Ikin'j. and
K. It. L~"Wms- Pok1wiv Ak.t.1, 41W
151171: cf, C-1, 44, C*dIf twot vobtm nium-le
0.113f KCI *'1. r%.41114. I'lle spn'trool I,- comple" '11"W.
mg mkxhna which in trito cocrrsimind t(v td~ Rittics1k hamh of
irvi,iophan, tyrosine, anti phrnylalanhir: -494). VR),
iNAW). '11n, '~MM . =1157, 247T) A. Spectrum of actin
-Ilvmed liv tilt solos (1111,1wifit-all %how,; utax. at 2710,
Iti W. 111d 1.14w) A ~ arimsiv,-in litil arl mily. in It m
"fificiat mittc J ."tivmc4l Liefin 111141 11mal ite 1 :21 p"'ittst.
lion) AiowtA umm. at 215%). 21WIt. *-*',,"At, '-11111 A
In cach case the Spectrum corre'Itond.4 to thr coull".ite .I
antim, Acid itt addit, to ahwrittion bv the protein it.
14-1.11~ff
4's ujp~

SET Kills, Cl. '.l.
"Research in the 1--lold of Anthracane Derivatives. Report E. Structures and
Adsorotion SDectra of Rijbic.-me and Isorubicene", Iz. Ll,. Nawk- SSSF ITau? 5, 191r);
ins'll. Org Ch=-.-.I, Acad Scl. -1948-.

0. I'T.
Inst. Crganic DeDt. Che.-Ii. Sci., .~cad. 3ci., -1948-.
nor., Lab. 3peectrun Analysis, State Optical inst., -11*?43-;
Inst. Biol. L Ked. Chea., Dent. 'Nedico-Biol. Sci., Acad. "Vied. Sci. (,:-Lbr., Lab. Phys.
Chem-, -1947-; 1-1,br., -c1948-3;
"br., t
11, Cancer ?es. Dep ., Central Roentgenological Rad-olog caly, Inst., Laningrad,
-194-8-
-uantitative Analysis frovi Adsorption Spectra by the Nethod of Photometric
Interpolation," Dok. AII, 42, No. 1, 1943;
"Adsorption Spectrwri of Structural labunbi of Eluscles in the Ultraviolet Range,"
ibid., 58, 3, 1947;
"Variations in the Spectral Properties of the Structural idbu-mns of the 1--luscles in
the Presence of Adenosin-Triphosphoric Acid," ibid., 60, No. 06, 1948;
;lCompounded EAraction, Fractioning and Spectroscopic Studies of Nucleo-Proteins
0
from iat 3arconas," Biokhim., 13, !Io. 4, 1948;
VIII :'Adsorption Spectrwil in Ultraviolet of Some 1~--ri-%ratives of Pyrldine and Elicoti-ne:
ii''' Zhur. Obshch. Kbin., 18, 1. 1948; (19OC955).

R;;E at lmx.. iga -9. 14. only Aftht
a a A widin relitive-WIL 2mEW_-kWtWo"r1
Wd OlCoUtte. L ad,
Setkitia, an& L. -MR StSDI
Gets.- Crem T -1871WRt IMe_-The-s aa Iiiq m- , T C"j)oWte At:
th
49 Itroin of I -methyl-2-pyridaniniftie (1) In C,H,4 qf-T!X4f-3W-& tots-14, Its 1116666&t-1
f 3 w0 and at 2W A.; them axe prtiterved in cascd. 16C 9 33, ILIMIZId-tin
2 triv ii in rt0li. but in dil. solts. (0.01 mj.)J.), - (tir Nises. T% 0. H. Setkinit, Yv- L. Dan
flic ln.i x ~ arv milfted to M and 2300 A.; the cause of this ar:4 Ya. 1, Gol"darb. lkd. 1324T.-Absorlsdort
deviation from 11cer's law !a Rk. "a. is siot rim., tis spectra at Ch tallawlat Camp&. an Kim In patit's va4
iiii. ioln. in LqOtl - 2--anittiopyridine -1
with mlx.-A ba
ntadve-tc - - _k - - -
it) CO 1,4 (-vters and Wiliatit, C.A. 31, 52726); W taw HU _'1M*C bw
t lie liand i9 sbifted to longer wavn by about 400
00 A. Tit, -hift is not to be attributed to tautc,.L., t,,- an 2960 (1.8), N-aithytiticatatte-MI) 3M5 3;8~;
00 (111), which is not cap- I -methyt-24 nivio-1,Uffiyelsonicistirse
a!-!, 4 t-llomeit,m, shows, in ale. so(n., a further shift (V
0 t L, i! , i ~ .1 12~) A., tog 9 3.8, the spectrum dr-twing closer (VII 3= (3-48);
i,) oi;jt of I -riie shifts are interpreted by no increased benzyl-a'-ardsionicatine (V111 3G45 (4-00); I4xuzyl-6-
of !,r Irtzrtijr,'~ in the Ist excitt-,-1 state of H. as a imiria-l'"i lydrorricortine (VM) 13M (3.74 -. 1-benzyl-
Tv.utc l- It the dotible-bond chamcicr 4 C: N is en- I -2-itnina-1,2- Rhydranicistirse (IX ) 3010 (3.7?; at-ausino-
li,rw~rl, tins effcct is increased by su-1,stontign on thc nicotine mehicilide (X) 3W (3.75);
NHT group with W1. Substitution %vith the zlectrot. methiodide X11) 2M (3.75); a'-aminoakotine p Wid
noplidic groups PIt or Ac, gives rise to a shift in the op. (XU') 2970 3.4); a'-aminanicotine benz[410.
Q -6 (.1.25); carl:iatutte of IV* (XIV') 3050 %9); carbona!e Ct
po.,ite direction; 2-4:phenylatninopyridinc (IV) has a max.
tt 2 170 A., log E 3.4, nod 2-acetamidopy; Aine (V) has v I (XV 1) St 20 (3.9); carbartate of V1 (XV1 1 3= (3-61.
wt. 2-170 A.. log E 3S, lit dihydrochlorideoEW 305C! (3-9); nicadne isameth-
00
group r3u Vand 11'reta-
nicthiodide (VI). it% which the X atorn of the NNfe, M iodide (Xv S3). The shifts Let
Onnot pirticipate ir. resonance with Ilse ring, tbm are 3 tive to n~itlne am the sause ajgthe~shifts in Imittopya-
-By- artalis". these shifts'-
-dlm~ relative to Pyddhie.
close max. at 2"W0, 2550, arid 2430 A.0 log E 3. 3.7
arid 3.65, cFp., i.e. clase to the specfruin of CTfsN (max. are dctd. ty resonance fCrr=.. That alkyiatfam of 1, and
it, Stons, is tvident
mat lit 1.111 (VII)-where the NH, results in substitistiats'at the: ritic -N
as vxpected.
group is free to t;I~C Part
-7-7 -7 -

USSR/Ck4mlstry Spectra, Absorption My 1948
"o
C'q *Tar
E-4 latlons In the Spectral Properties or the
E~Btruotu%l Albwdns or the Ikeoles In the Presence
M. Ravikovich,
,of.Adsmosin-Triphosphorio Acid,w Ih
O.S. Betkins, K.D. Leontlyeva, Inet of Biol arA Ned
Ohm, Acad Ned Sci UM, 4 pp
"Dok Ak lauk SSW, Nov Bar" Vol IZ, No 6
DworlUe results of studies cmducted on the absorp-
t1ca4pectra of albumin and adenomin-triphosphoric
&aid (AN) In the ultra-violet band of the spectrum
to detwulne the physical and chesical. properties of
67T26
~/ftmistry Spectra, Absorpt1cm Nky 1948
(Ccutd)
aotmr *1n, and their Tarlations in the
wssswo:~ot AWI~ Submitted by Aosdivalolan T&.0.
PUTAN',23 lbr 1948.

Antbfgt#no derivatfir". Vltt. StruceArl and absurp-
tk)n 0 tra of rubkono and lacrubkout. Set"
ol'.l Fl*C 11. prolloorov. Invol. '1k,I& V.14k S.8-S.R.4
ilt,41 KApm. Xosk 1949. fw, Ul; cl, CA 41, V"
ClItavi"Irs Ab-opti,"I Jcoolra 44 Ful.4VII, (1) IIII'l s.).
rjabi,-clic IU), pirrIN1. fmat the rwirj."ubaot di.,k. A.,vr
the f~.ilooeiiig Iluti.: I-M), 4115. 375. :.74% 34:1.
M15' 'Xi. '67, and 257 nus: 11--448, 415, 3S1, '101.
al.r. :fm, U76. mul Wims. The SUIA..Irkv likell for
11 toy CLAr (( J. 26. 4411) ig cwt 11, all't 1u . lite 641,14ing
ljlx~ t ..1 11 '11.,w a fullp.-hr."lli. 11111 111 ".1so
with authr.wmr tOw lwul- rrw -1 .1 'Ukl XIJI
Ciontjwri-cs 14 1.4 Joehh-c--
olul fit. AI'lly'll"Ic '-f
4vId jjv
thc,c how comidorrahle sioniUrity (no r.jt-t ftvtpirzwi~
given). G.. !.J~ K..Vl.tt.,Il
IlMll: 513. 4st. Ild. 4:311, .041, 31W, 3N, 312. :.'Vl,

C-A
mew Zell f" a ordrook 0. tN.
Molncrx~"
.4etkin4 and R. ht Tt= Im
1400diboys IAO, 10, 4WO(ISM.-Abomption sprctrul
ft" be 6ken with a turtal cell. rtmalsting at 2 111frbuk4l
Cylindrical wetkww providod with circular quotts orindow
ran be stainiessfited or At-plated
br.Lo. The threading permits easy adjustment of cell-
thickness, when a calibrated micrometer thread 7s used.
A filling devkv (funnel) is readily threaded into the cylin-
der. G. 161. x0owapoff

SETKINA, 0. N., Cand of Tech Sci -- (diss) "Infrared spectrum of minerals
and their practical &pplication." Leningrad, 1957, 16 pp (Leningrad
Technological Institute im LBnsovet) 100 copies (KL, 32-57, 94)

KHI NIKOVA, L.Ya,;__~ O.N.
'~ - t- -- - -
Spectrum determination of mineral compouents in rubber. Sbor, at,
LITMO uo.24t140-145 157, (KIRL 11:5)
(Rubber-Speollra)

-
ot d'i ~q
ylin

I 11heit. YAW y $P,

-VII
cWhi

if Ta
,
-
Li
W
t
4

,
I' skektd Coe
-9r.

pec aw
tr
e sup"
-.09
.011

t 01-1
-i6d t
tLe Mth-a-sn'bc

'__777~-
'J SSR / Chemistry of High Molecular Compounds, L.
Abs Jour s Ref. Zhur. - Khimiya, No,,2, 1958, 6782,
Author i Setkina, O.N., Okhrimenko, I.$.
Inst i Lensoviet Leningrad Technological Institute.
Title Determination of Unsaturation in Three-dimensional Polymers
of Caoutohouc by means of the Infra--;Red Spectrum.
Orig Pub Leningrad tekhnol. in-ta im. Lensoviet 1957, V61.37,
91-97.
Abstract : 7he relationship of double bond content in positions 1,2
and 1.4 in caoutchouc (SKB) subjected to thermal treatment
was investigated by means of absorption bands at 910 and 970
cm-1. During the treatment of SKB at 10,000 k4/cm pressure
and 1600C. the relative concentration of -CH-CH- groups
gradually decreased from 100 to 28% within a period of 8
Card 1 1/2

6-7989,
s7's-1310 SOV/81-59-12-42059
Translation from: Referativnyy zhurnal. Khimiya, 1959, Nr 12, p 118 (USSR)
AUTHORS: Aleskovskiy, V.B.,_Setkina, O.N., Kochneva, V.A., Lyadov, V.S.
TITLEt Spectral Determination of Lithium and Cesium in the Flame of Ther-
mite Blasting Cartridge
PERIODICALz Tr. Leningr. tekhnol. in-ta im. Lensoveta, 1958, Nr 48, PP 90-93
ABSTRACT: In order to excite Li and Cs spectra a thermite mixture of 65% Mn02
and 35% Mg metal has been used, the radiation of which is free of
background. The mixture is easy to ignite and has a sufficient du-
ration of burning. The 2substance is pressed into tablets under a
pressure of 5,000 kg/cm ; the weight of a tablet is 2 gy the dia-
meter 10 mm. Within the tablet a hole of 2 mm in diameter and
6 mm deep is made, into which the sample is placed in the form of
a powder prepared on NaCl base. For preparing the sample 1 ml of
an aqueous solution of Li and Cs is mixed with 70 mg NaCl, the
water is evaporated and the salt is placed into the tablet covering
it from above with a mixture of 65% CuO and 35% Mg. The tablet is
placed into a chamber on the optical axis of a 3-prism glass spec-
Card 1/2 trograph. The substance is kindled by a match, the spectra are

SETKINA, O.N.
Infrared absorption spectra of aluminosilicate ad5orbents. Trudy
LTI no.48:191-196 '58. (MIRA 15:4)
(Aluminosilicates--Spectra)

SOV/138-59-3-3/"M,
AUTIIOki;~: Setkin O.N. and UrIgan, R.S.
rl- -- - P~-V
TITHE: Spectral Analysis of L11ineral Components in Rubber blixtures
(Spektrallnyy analiz mine i-al ~ nykh komponentov v rezinovyk~i
smesyakh)
la]-RIODICAL: Xauchuk i rezina, 1959, 14r 39 pplO - 12 (USSR)
ABS-.LUCT:~t'uality of rubl~er articles is stl-0117"lly --;2-:-!------,--'k-,::(I by the
c'
L-~jant and distribution of mineral (components in the
ori inal rubber. Such Diineral comDonents (chalk, sulphur,
metal oxides, et,!3.) are present in amounts varying from
0.1 to 40c,.0, depending on the type of rubber. The present
paper describes a ~P'e:ctro-cheLical method ct-' determination
of the amount of magnesium, zinc, calcium and barium in
rubber mj-,ctures and the results obtained with this method
at the 'I.In-rasnyy lu-reu~Sollnikll factory. This method was
de-v-eloped by 0.14.Setkina and L.Ya.nlebniko-,.Ta at zhe
Opectral i1nalysis Laboratory of the Leningrad Technolog-
ical Instute imeni Lensovet (see Jubilee Collection of
Research Work Ione at the Leningrad Optico-Lechanical
Institute, Gostekhizdat, 195?). Rubber was burnt in an
alternating-current arc (220 V, 4,5A9 2 mm gap) and the
Cari 1/3 spectrum was examined with an SI .10 steeloscope. A small

SOV/138-59-3-~"/-;1_6
S-ectral Analysis c-' 1- eral Compenents in Ecabber Lix=;Ur~s
pieoe of --r-ubl--r IL-L -was plac~-~ in a
ropperelectrods :~,nd its spectj:,jm was obser-\Ted. after
bua.,nin,- (first 10 seo). Observation of -uhe spectrum and
,.I.:.te I'LrLLna- ion of the amount of one element tock 3-4 min
(a.ncludinE placing of the rubber sample in the hollowed-
out electrode); anul3rsis of 4 - 5 elements took 20 min.
..,lialitati,i-e valuet; for 1311e amounts of various elements
w,:~ru obtained u~:ing a dispersion curve for the instrument,
and spectra-l"line tables. quantitative reSults- ,,,,ere
obtained ''-y deteriaJrin- the intensities of the lines of
paxticular element with resrec-lv- to the cI
a opper lax~es and
comparinS these irl-tenisities with tnose obtained previous'4
u~:j-n't, samples --;f rubber with Imo%rn amounts of" -uhe element
Card 2/3 in que--tion. FiE;urea I - 4 zhow the spectra of zlnc,

SOV/138-59-3-3/1'0
.`spectral Amalysis of 1,11ineral Components in I-LIubber I-Jixtures
ma-Sne~3ium, calcium barium and copper (calibration lines)
as obsei-ved by iae4ns of the steeloscope SL-10.
There are 4 fig-ures.
AS&,)WIAT1aIi*. Zavod "Krasnyy -'-U-reugollnik";IeniiiG~radskiy tekhnolog-
ichesk-iy institut itrieni Lensoveta, ("L,:r-,snyy treugollnik"
factory; Leninz-rad 'Oechnolo--ical Institute imeni Lensovet)
Card

24 (7)
AUTHORS:, Setkina, 0. N., Libina 4 R. I. SOV/32-25-6-24/53
TITLE: News in Brief (Xorotkiye' soobshcheniya)
PERIODICAL: Zavodskaya Laboratoriyal 1959, Vol 25, Nr 6v P 714 (USSR)
ABSTRACT: The authors report here that they have obtained an increased
sensitivity in the spectral determinations of Lip Rb, Cs by
causing scattering coronas of alkaline trace-elements. Two
drops of a saturated NaCl solution and one drop of a 10 % K01
solution are added to the liquid sample concentrates and
standard samples (volume I ml) and one drop of the mixture
is applied to the carbon electrode. The absolute sensitivity
10
of the determination then amounts to 5-10- g for Lip
5-10-9 g for Rb and 5-10-7 g for Co. An increased
aensitivity in spectral analyses may be attained also with
other elements in a similar way, and a few examples are given
in this connection. There is I Soviet reference.
ASSOCIATION: Leningradskiy tekhnologicheskiy institut im. Lensoveta
(Leningrad Technological Institute imeni Lensovet)
Card 1/1 1

KCKURIN, A.D.; SEWINA, O.N., GRUZDEVA, V-V-
Decomposition of organic matter in an electric arc discharge.
Trudy LTI no-51:102-112 159- (MIA 13:8)
(WdrocarboneY .(Electric arc)

SETKINA, O.N.
-- infrared spectra of minerals and their practical use. UP. VBeg- min.
ob-va, 88 no.1:39-47 '0- (MIRA 12:3)
(Spectram. Infrared) (mineralogy)

"MOIR:)DINA,
Spectral determination of selenium in tellur-Jun. 1?.v,vys.ucI-eL..zav,; -
khin.i khim.tekh, 4 110.4:565-568 16i. (FIRA 15:1)
1, Leningraoskiy tekbnologicheskiy institut, imeni Lenzoveta, kafedra
analiticheskoy kbimii,
(Selenium-Spectra) (Tellurium-Analysis)

SOKOLOV, I.Yu.; AYDINIYAN, N.Kh,; BELEKHOVA~ V.N.; BRODSKIY9 A.A.9 starshiy
nauebaVy sotrudnik; GLEBOVICH, T.A.; DALMATOVA, T.V.; KOMAROVA, A.I.;
KOMAROVA, Z.V.; KOPYLOVA, M.M.; KWWAVTSEVA9 M.M.; IJBINA, R.I.;
LOGINOVA, L.G.; MARGOLIN, L.S.,- MARKOVA, A.I.; NEDVEDEV, Yu.L.,-
MILLER, A.D.; MULIKOVSKAYA, Ye.P.; NECHAYEVAq A.A.; OZEROVAp N.V.;
PALKINAv I.M.; FETROPAVWVSKAYAv L.A.; POPOVA, T.P.; REZNIKGVv A.A.;
SERGEYEV, Ye.A.; SBTLM,-D~H..-, STEPANOV, P.A.; SUVOROVA, Ye.G.
[deceased]; SHERGINA, Yu.P.; PANOVA9 A.I., red.izd-va; IVANOVA,
A.G., tekhn.red.
[Methodological handbook on the determination of microcomponents
in natural waters during prospecting for ore deposits] Metodicheskoe
rukovodstvo po opredeleniiu mikrokomponento..- v prirodrykh vodakh
pri poiskakh rudnykh mes-torozidenii. Moskva, Gos.nauchno-tekhn.
izd-vo lit-ry po geol. i okhrane nedrr 19bl. 287 p NIRA 34:7)
1. VsesoyuzMy nauchno-issledovatellskiy institut gidrogeologii i
inzhenernoy geologii (for Sokolov, Brods1dy, Glebovich, Ozerova,
Kudrysvtseva, Loginova, Markova, Medvedev, Belekhovap Palkina,
(Continued on next card)

SOKOLOV9 I.Yu.-(continued) Card 2.
Popcrva., Petropavlovskaya). 2. Instibit geologii rudnykh mesto-
rozhdeniy petrografiip mineralogii IL geokhimii AR SSSR (for
Aydinlyani. 3. VsesoyumVy nau-ohne-iss.0ledovatellskiy imstitut
metodiki i tekhniki razvedki (for MiU,A-rg Sergeyevp Margolin).
4. Vsesoyuznyy nauchno-issledovateleskly geologicheskiy- institut
(for Mulikovskaya, Reznikav)- 5. Vsesoyuznyy nauchno-issledava,
tellskiy institut minerallnogo syreya (for Komarovag A.).
(Prospecting-Geopt7sical methods)
(Water, Underground-Anal7sis)

S/138/62/boo/oil/bo8/boB
A051/A126
AUTHORS: Setkina, O.N., Popova, A.M., (deceased), Galanovj O.P.
TITLE: Determination of organic ingredients in rubber mixes and their vul-
canizates by the method of ultraviolet i4pectra absorption
PERIODICAL: Kauchuk i rezina, no. 11,-1962, 53 56
TEXT: Ultraviolet spectra absorption curies of certain organic ingredieats
(diazoaminebenzene, Neozone D, peroxide, benzoyl, diphenylguanidine, quinodiox-:
ime, chloranil, altax, captax, thiuram), are submitted. A description is given:
of their extraction conditions from rubber mixes and vulcanizat-2s based on natu-
ral sodium-butadiene, butadiene-styrene, butadiene-.nitrile, chloroprene rubbers
and butyl rubber. The HCH-22 (ISP-22) spectrograph was used to photograph the
spectra in a metal cuvette of varying thickness. The M.K. Ivanova. hydrogen'lamp
system served as the ultraviolet beam source. The quantitative ingredient con-
tent was determined by comparing the extracts spectra of the raw rubber mixes
and their vulcanizates. The qualitative changes of the investigated ingredients,
noted in the vulcanization of butadiene-styrene rubber with diazoaminebenzene,
Card 1/3

S/138/62/000/011/008/008
Determination of organic ingredients in .... A051AI26
are explained by the presence of ?Jeozone D and benzoyl peroxide in the rubber.
The interaction of these ingredients with diazoaminobenzene was studied: the
spectrum of mix, diazoaminobenzene and Neozone D, after being heated to 143*C,
acquires a "new" strip of absorption in the range of 5,000 A, similar to that
noted in the vulcanization of butadiene-styrene rubber and diazoaminobenzene.
The results also showed that the appearance of the "new" strip is caused by the
interaction of the diazoaminobenzene with the Neozone D, at elevated tempera-
tures in vulcanization. An analysis of the addition spectrum, obtained from the
reaction of the latter, indicated the constancy of the Neozone D structure. Con-
clusions: 1) By means of the ultraviolet absorption spectra, the qualitative
and quantitative changes of organic ingredients-in rubber mixes and vulcanizates
can be dc-termined through an analysis of the spectra of alcohol extracts from
raw and vulcanized mixes; 2) the quanity of unbound ingredients introduced into
the raw mixes.decreases with an increase in temperature and vulcanization dura-
tion; 3) during the vulcanization of butadiene-styrene rubber and diazoamino-
benzene, ihe reaction of the former talkes place with Neozone D, included in the
composit'-on of the rubber, resulting in the formation of phenylbetadiazobenzene;
4) the ultraviolet spectra absorption method can be used in studying the vulcan-
Card 2/3

CIIZIIAN LINI-NA; BOY'VIIIKOVA,, Yo.S.* SETKINA) O.N.
2
Products of interaction of silica with phosphoric acid.
Zhur. neorg. khim. 9 no.6.-1472-1481 .Je 163 (WRA 17:8)

I :W--69.-;63 E6'F((F)/9n(M)/bDS_ AFMIM Fq4 'Wil
.ACCiSSY81T 3/00b0/1b3/0W004/0712/0717.
G"
AUTHOR-: Shteynber YU B2tkina 0. N.
TITLE: Structure of strontium-silicate glasses studied by their inflvxed
absox-ption spectra. Report 1. Glasses of the SrO--Si0 sub 2--CaO-SiO sub2
%~System
;SOURCE., Zhurnal prikladnoy khimiij, v. 36, no, 4, 1963, 712-717
:TOPIC TAGS: structure of strontium-silicate glaBBes, SrO-SiO Bub 2-CaO-SIO vab,2
system, crystalline and vitreous metasilicates, crystallite
!ABSTRACT: The IR absorption spectra of crystalline and vitreouB metasilicates of 1:
the binary system Sr0_-Si0 sub 2_-Ca0__Si0 sub 2 were measured; presence of pre. i
;seeding group (crystallite) was proved. A'direct relationship was established
between lowered crystallizing ability and weakening of the Si-O-Si and Sio sup,-'
.and Me suD + chemical bond in pre-seeded-glasses, and changes in the relative
percentages of Sr and Ca. This confirmed the existence of such a relationship
~in alumo-silicate,Sr-Ca glasses,-where ~epax-ation of crystalline phases occurred
similar to that observed in the presently investigated glassds (continuous series'
of solid solution; of Sr and Ca. metasilicate-s). "'rhe glasses were mixed by
Associa n: none
C

ALESKOVSKIY, V.B., prof.; BARDIN, V.V.; BCJYGH11,40VA, Ye.S.;'
BULATOV, M.I.; VASILIYEV, V.P.; DOBYCHIN, S.L.; DUSHINA,
A.P.; KALDiKB,., I.P.; KEDRIIISKIY, I.A.; LIBBA, R.I.;
FRIK, K.Ye.;,_~ETKIZIA, O.R.; KHEYFETS, Z.1.; YATISDMSKIVY
K.B., prof.; VASKEVICH, D.N.., red.
[Physicochemical methods of analysis ; a laboratory marrual)
Fiziko-khimicheskie metody analiza; prakticheskoe rukovod-
stvo. Moskva, Khimiia, 1964. 451 P. (MIRA 17:12)

SFIBINA, ZHK'NA, V.I.
O.N.; D013KINA, Ye.I.; DERYU
S Lurly of a wour re, a catalyst by the infrared
9i.t3tant vnnadiw
opertroscopy inet-hod. Izv.vys.ucheb.zav.; lijim.i khim.tx:kh.
7 no.6:1019-1021 164. (~gRA 1-8-.5)
I.. Leningradskiy tekhnologicheskiy institut imeni -Tensoveta.

L 6,3042-615 !~Vi- (M)/G~F
-Xic-E-Bimi NR, 17776 URI
AP50 0080/6510*007/1476/1482
546.42'284+665.11.2 +535.34
AUTHOR: Shteynberg, Yu..G.; Setkina, 0o -No
TITLE- Study of the structure of strontium silicate glasses by~meahd of their
infrared absorption spectra
SOURCE: Zhurnal prikladnoy khtmil, v. 38, no. 7, -1965, 1478-1482
strontium'-silicate as:: C t -glass structure
TOPIC -TACS
--gla ry-s. allizatLon,
A_
ABSTRACT: Measurement of theInfrared absorption spectra of crystal.lized and
vitreous ailicatee of the same:composition in the binary systen SiO* SiO2 - M90
Sio howed that the spectroscopic method confirm;3 the sequence of:separation
of ?he*g phases and the nature of tha change- in their crystallizability
earlier in a study of the phase diagram of this sratem. 'It was shown that,
during the precrystallization period in the vitreius silicatesj nucleation
centers of the crystalline phase are formeds ioes, aggregatesof structural
grOUPB similar in chemical composition to crystalline silicates.6f the same com-i
position as the vitreous silicates. It was found that when the crystallizability--',.
Card 1/2

L 63042-65
77ACCESSION NR: AP5017776
of silicate glass decreases-under the ~_Lhf luerice 0: t -..:a ~.-pitir df._~ divalent cations..; ----- --
(Sr2+ and Mgz-+) and under the influence of-increa3ed founding temperature, the-_
nuclei of the crystalline phases are dispersed anl,break down completely (pri,
marily because of the rupture of ionic bonds between the cations and the oxygen
of silicate chains). These properties of the glasses confirm their similarity.,.
to colloidal systems. An earlier hypothesis concerning a direct relationship
between the difference in the forces of electrostatic fields of two alkaline
earth cations and their influence o2 the crystallizability of glass was con-
2+%. The spectroscopic invest
firmed (examples: Sr2+-Ca2+ aud Sr +-Mg Lgation
of the fine structure of crystalline and viltreous silicates having identical
compositions within the range of the phase diagram of their equilibrium system
was shown to be a fruitful method. Orig. art. has: 2 figures*

GALI%1,1011, O.P.; SETKINA, O.N.; URIYAN, R.S.; FAVLOVA, A.Yu.
Quantitative spectral determination of tit3nium dioxide in T-,lbber
compounds. Kauch. i rez. 24 no.5:53 My `65. rmlitp.. 18;9)
1. Leningradskiy tekhnologicheskiy institut im. Lensovota i zavod
"Krasn3rj treugollnik.11

--;w6030781 SO-URCE CO5E;:"__dKj6_3_43
ACC NR, (A) 766166il6o /fffi/fff~
AUTHORI Zorinax M. L.; Setkina# 0. N.; Ushakov$ L. F.
OIG: Leningrad Te.chnolozical 3:nstijUtq lonqQ=t (Leningradskiy tekhnologicheskiy
g_
institut)
TITLE1 Infrared spectroscopic study of the course of crystallization in vitreous-
crystalline enamels /
1.7
SOURCE: ALI SSSR. Izvestiya. Neorganicheskiyo materialyp v. 29 no. 99 19669 1712-1713
TOPIC TAGS: catalyzed crystallization, silicate glass, lithium glass, /'V JPVC
ABSTRACT; The course of directed crystallization of an acid-resistant vitreous-crys-
talline enamel and coating obtained from this enamel was studied by analyzing IR ab-
sorption spectra of the multicomponent system M20-YgO-&190~-SIO~. The spectra showed
that the main crystalline phase in enamel whosc crystallization occurred at 7000 in
the prosonce of TiO2 is P-eucryptito, f-:;-)odUMGnq5or thoir solid solutions and the
solid solution A-eucryptite-quartz. In '.a~ditlonla cortain amount of forsterite and
rutile also cr7stallizes. The study of M spectra made it possible to draw certain
conclusion with regard to the phase composition as conpared to x-ray structural analya.
sis. However, even though the necessary data were obtained on the crystallization of
the enamels the IR spectra could not be fully interpreted because of their complexity*
It is possible that some intermediate compounds responsible for the appearance of the
12 uDci 666.29:542.6

XICd-NR, AP6030781
unidontified bands are formed during the arystaUization. Authors thank 0. M,
Rimskaya-Korsakova and V. V. Gordiyonko for providing the aamples of the almral
studied. Urig. art. has: 5 figures.
SUB CODEs II/ SUEX DATEs 19Dao651 CRIG RRFj 007/ (rL HRar 002
Card

&
0000000000000000 000 1*1
OX I lost ?1 91011411 U11 V4 1#302in n it 15 M 17 31 11
A K L 9 1 T Z M -H AX,.RP-A
06 4 99tn*
PROCCtigs 0.0 00.1t."Es ~.Gl'
0
Isvoodatift of the SPPUCAUOM Cat it Islet OF Ch10MTlUYl
96 A ,
:! tofte fibers. Chlocovityl rosins. 11. P. Vik- a
I rows N. xtkift. Va%th-1zj4%krmk1. Dftdy
~~Vikl;rfjiijA_ -No. 1, 3-35(1939); Kkim, &Jtral.
so 9h.Kk7_iq940, No. 4, !~j'.--Cottoti textiles treated With
00 a N&OH (38' W.) ar 'PU% ZnCl, Ptie satd. with a boiling
r-hul soln of chlorovinyl resitt and dilmtyl phthalate (I: "
0 in ~51.C~ and dried. The satd. fabric was testeO
06 1strength and clonzation to the breaking point, for I, uftc
IIins, for dyeing propt-rtirs, for stability toward Cbeld.-ojf,
00 agents sxW for creaw-fesisesum. The strength of -.
fabric does Dot deermie and the elongation to the breakin
0 oz S! I i
U point incress". by several percent 'ne swelling ability
oqJ of the fabric aft" Pam. with resin is considerably smaller;
00 0 however, the sutmquent treatment ('aponificstbm' etc.)
ricreases the swelling ability of the fabric. Tibe d
00 a sburbing power decreases, owing to the poorer esp=ty
oqu wW vvetting of the fabric. fista. o( the fabric with resin
after dyeing inten%ifics [be color arml incresies slightly
of 'a
the rt~i.taftcc to Water, to saponification it In Ci
to light. binizig nierceriza,iot
By coul I
t wi,b 4 resin
9 wi b t"11to-, + Plasticiaer (1-V
it
am -reuse 'be elasticity Of the fabric to
! W. R. He=
W
4) o 0 o 0 o
x 31 1: 11 34 15 1, U a $I a 4j " es'c 0
-t- j t -j -A k- I_ k --R j -&--I _rL
a
=00
COO
zoo
0
Aro 0
A 14 - I L A SITALLUSIG&CAL LITERATURE CLAUWKATICII
IJONI 11,131TO ISOMPIT
I'Aa.0 .1 1 SAPRORO J, a., Oft H11131 W CUT ISI -
990
voo
!:Oo
t1go
1:20
role
too
b U 6 AV 10 AS An I I a ad 0 a s I W M 2 a a 3 1
10; 4,1 0004600000000900000
: : : : : :I: : : : 109 00 00 018 00 00 :_:I* 0 0 0 0 0 0 0 0 0 0 0 a 0,00

11 ft .1 W 15 14 U t$ if as M to a it k? If u u M IS is v is Is 40 At a 4u of age
o3i;
1 AA PP U I j_j I
a Jl_ A-L. X.-P, P 9 VA v - 11
90 C-pert 1`00
"O'XII-Stl !_Oe
Go
UtWAajjQQ of w&st~ waters from I swchl sizing audtr-
treati4gvogstabts fibers tot a yeasts. .4. A. Milin-
ic if
0 Akaend vigAtkina. rawil. 1043, Nu. 3.
-A d6a for growing edibic yeallt
tm temile-mill waste. Itowh
4i
-06
0
coo
'3 coo
tee
:0
zoo
W
boo
A 1, M - I L ALIALL4,RGICAL WIFIFATURE CLASSIFKAMN ~!~r tee*
I 111~4 .0. LIT wee
it
A Kai
It AT PO All' S I I W M 2 a a 3 2
;v W01141, (11,411C eta Try KCtU It X KM n 1 14 d44
:112

0 0 0 0 00000000 a
1 4 1 a 1 0 0 V It 11 If 14 Is 4 1/ as if Mif a D M 14 .7 x )v x; j! At if ad a is Ar ad P a 41 a If
f r. M_ EL It _L__A_L I s_. A-1- k
__r -I- K .1-1-AL
PRIX f$let "119111, C I I't I I
at
C~frd_tro ph-a If I -cc If Uu-tow. -a p-a-ra-t-i-o-n -and pro---
0 i of chlafromethyl others of the aliphatic sorted, PfeIkL: 11610('11,0 h. 131',
i
Kurianovand V. S. J. App(ird CAeM. (U. S. (30%). b. 217-18% for higher a". larnfactic soln. %atd.
S, R.) 16, summary).-In the with HCI was wied and the following etbeirs piarpd.:
00 a reatime of tht- %fully of thr int"wtism It( efunprts. of The ('011000faO (SIO 111. 124-5" ClillmOC1120 J&S%). -410
Velall tYtw f14 %ilter-rarlivilent tirainarnt (A vOlulome the III till- 21.56. ( X11.0 its)AA) 6. 1-a-V. i:.H.-
go 4 dilth(W4 %tti'll"t the prelln. fill, I Follcirt It, of varku* chh- OCUstl h. I IM*. Ill. V "1111% ( "1140CUIC7. 14. to.-
of If 91"Itirth I r1hev- lly meant I swilvolyniethylene, IICJ 21 V; mixed aki. from perm ml yieloictl an ether b, I
&A, 1117111C talej., the folk-whis rtheti well.- 11110-W, ak~" '.'M kjKlf"Itokald If" Ulf gave An
ether til..IST-87 All of th~- ethen arrallily calatuirmelf
with pyricluti: by iniating flat reactants with cloolin
00 It it the
faruducja~. being poorly vlol. tot litiO. are tradily purined fly
0 %3 zoo
wailhing with HtO. Theyarv all %cat. tit water. the hialliet
0: a metubco forming opidetvent "its. The octadveyl ether coo
wasaLsocatianifensed with.%Ie,.N;ijj lacnatruesuln. the product
09 a being in-A. in beanne, sol. in water. Ph."Itv was used
00 in a conuemation with the tetradecyl ether; only 507c Co 0
yickl of pmfuct was obtain.1 cvrn after 24 hn, Sampk%
00 of cloth vvert, treated with eq. mAn4. of thew rtlivras corag.
i: N&OAv. 41tial. lactatted at 11113" for '11) Inin., lAinsalcard and see
Witaffeall With LPCJIZCUC &Ulf Water. CIXU;kf$.%A(Cj*QrWahCl`
like, imperial definite water repeLlcoce to cloth. Shifilar
treatment in bentene-pyatitine %oln. sbowned that
Ji based oil Mr,;.N rarquiml a letvptu( 140' (at chernical hind
Ind to cvIlukloc. I he detirm Of Zak Cc trPellencat latting nwn:
Nally anaffected fly the nature ad the nitrogenous bdw free,
used. KMARPOO
ISO*
1V IS4048
CLASUPKATtInd
to's
It T_ 101481 -1 1111110.9 4"T Ialk 0
1A L t 4 ew a a N I IF IN '3 Ad a 3 a T
EaU it AV 00 U KX
;0 vF pa, IV It it K it it It It it it n 1 14
0 0 0 0 0 0 0 9 0 0 0 0 0 9 0 0 0 0 0 0 0 0 0 0 0 41 0 0 6 0 0
0 * o 0 a 0 0 0 0 0 0 0 o 0 0 0 0 0 0 41 0 0 I111to 41 0 0 0 0

V.
K Ns
i-.br., inst. OrE--anic (,hemistr7, D--z)t. Chem. Sci., Acad. Sci., -1948-
'IReactions of Exchange and Separation in the Group of 1-uaternary krmwriiizi Salts:I"
Iz. POk. Xlaul- SSSR, Otdel. Khim. Naulk, No. 2, 19L0;
"Salts: II. Interaction of -,Uaternarv il=aonium- Salts (rch 2-N-) X i,,-ith Carbonous
J~Ici~ls a-id with Their Salts," Tx. ibid., Wo. 2, 1949;
":-L-cellai-ige Reactions and Decomposition in the Group of the Quaternary, Salts of
~jnnorda. III Reaction of the -,uaternax-j Salts of Ammonia vith Complex Ethers,"
ibt-~., ~7,o. 3, 1949;
'ICo=ounds. IV. The Problem of the of the Reaction of uat----nary Amoniun
Salts vith Alcohols," ibid.;
"The interaction of -,uaternarj Salts of A-7raonium. vith SLaple Ethers," Dok. 65,
iio. 6, 19-19.

0 a 0
*0 01 Fv lA A. ii kik LL

0: .2.

Exchange and cleavage reactions in quaternary am 0
monium ssltx. Reaction of alcohols with quat~rnari
0 0 onjum salts of the t"e ROCHINX. D, N. KUMA120".
N. Bull. oe'llf 3ft
e Scs Ch M. 948 T28 34 - ticating WL-
oxymethyl)pyridiniurn ehlkwid;; of falkoxymethyi-
quinalinium clilorides with a". resuits in an exchAng,
'
g reaction which yields ROCHtOR
and pyndine (or quino- c
line)-fiCl. If the resulting formalli "e tot symmetric,

31 -4 the reaction is complicated by syrnmetruation of the for.
mats. (Hutusymethy0pyridinium chloride (30.3 j;-1 am'.
11.1 1. RUQIl heutecil 4 hirs. to 130% cillow, and trraird

:x with 100 rni. 11,0 save 85.3% b. 181'.
the reaction does not proceed at 60 . Heating 9
4 C
.
tetradecyl ak. and 16 C. (netradircylarytinethy!rdmium
hl
id
4 I
1
5V
5
di
c
e
or
to. to 1
.3%
game 9
k& ry
fiwom.21.
'
"

bia 270-4A)
. in. 42.2
(from MesCID) -
A similar reptictior.
using AmOH give 27.8% diapity(farwill, ti~a W% 47.2~
am
U
li
k
r
1
l
b
t
f
d 25% du
206%
d
i

~ c
ap
pi
filroa
pin
ro
t
orma
.
,
y
,
y
"y(

0
i Ileilting 20 9. (ortyloilyinethy0pyridinium ch1c;-ide and
r*
77
l
I
3
dib
1f
l
b
17
O u
ortria
ve -
.
9% 48.5
uty
n,
,
%
,
bul I I or , I 0-2D', and 24-21', diorr "a. th ,
o'n
176 If ting 10,7 g. (isoarry1myrnethyl
idmium:
chl e it 4A g. iso-AmOll 2 brs. it 140' save F101-, -
diisoomy M5'. Heating S'A X. (nonylmy- - 9W
inethyl)quinolinium chloride will 4.3 X. nony) a1c. 4.5hrip. a: - z,

I W
-4W gave 84"/% dixvx*
Waist. lis I A9 11ratinr
_
15 it. C,MnOll and 15 C. dibutyllorrnml J, lits. to 14.1-6)
gave 2.7 g. RuOll, 6.8 C. dibury1formall. 6-1 c. Ctsil,,oll.
H.9 z. buzyMecyiformill, bit,-. 164-41% and 2.d C.
for"tal.th-1.210-16'. Similairly,gz- ditnityllomal an-! V
WK x. W011 heated I0 hm in a seal"i tube to

1
1 gave 2 g. dimethyllormal. 4.5 g. McOll, 6 C. mettlyllviltyl.
0 hirinal. b. 76-7' . 5.7 g. HuOH. and 3.2 g. dibuty1formal
Ilealing 9.4 g. dibutyllormaill anti IG.I C. EjOll 10 hr~
'
to 150
ga%-e nil disproptirtionation; use (d i;~iH ca%-e th~
same result. I)iikmtnylfu"ual underg(it-l exchange with
actyl. drcyl and tetraderyl ak-s., llut not with EtOll or
NMI, although MeCH does MUCI, &A, an exception.

11 N
l
l
~Mpflrtrlt 9fas pill $I Sipi ti
0
6 * 0 0 0 0 0 0 0 a 0 0 0
0 0 *so
*411so **Osseo* It

aifimsiii~
*000000
0 0 0 0 0 0 0 0,401
061
A A L r 1 16 71 1. 4. if 1: t! U 1'. U 1, 1. 1, a. it M
L r
Q L ~A 04 PO it a IR a Ps
_

00 qua il"Iy
Exchange reactions and cleavages of the t
00 ammonium solltr. 11. Reaction of quaternary Ammonium
llc Acids and
box
ith
X
ROCII
N
0 -
w
car
salts of the type
II
y
o
Izveil
d 1)
K
N -00
A. .
ursin
v.
.
.
their salts. V. N.Sotifinuati
Akad, Nafook Oblet Kkim. Nauk 1949. 1111 -00

: vf, C.A. 42, 4!-~%.'.. Qu.itcruaty anini,iniuni ~115 Contg. NOY-JW) in the at-ve juvr 54~e
chloride C Y
1-00
0 the HOCII: radical tvact 'Aigh 1911t Of CurfKjjyliC Adak, 1hj:tNH5'- IW OMI 1, jai I.-irs. 1
hrof.'0414' !
vidding Aksix)-iiirtfivi vstcri, %%hi1c tile free aci& yield
(j FII
tile CII
n
h
l
IW
h
0 .
I'lethy r 0 1.2 X -) and 0. 1 X. PhC I 1
,
-
""'
l),
*1f"1l"
11ACII
Co
cli 1,60
I,
%vamt
,
c,t,so, wit
mit
ou
p,
*
y
a .IVC.
a
:
.
'
C.(),Nja ter3hrs.at I.
.
g
981
If
1
4
AlnK 411111111.0.4 J~ 1.6
J
1.111"1111itilflt.lll.ofi,leiiii.1 8,2g.lify NA-
1,"
illj%.I),
I
1
l .
.
y
falft.b. .
e KA%-r
-A
f ti
A
1
~;
,11
l1
)
1
OAC .3 fit, M 1.*0-711, gave 72111'~ 11A.M.71,11eig, bft~l 114-
-
fi l
4o
r
Y4
t fir votteitiontfing 34-1414.
1 '00
1
n-
. W. 1;' go 032S. A. ..d quinn
19% 1" lfi vDtIttimolinbain chfiwiod~ und 5 It. ALOIf t-j In, .
=00
rIv. xavc 57% INOAc. while PrC(hII -it Ifel` 00 give NO).-
0: ~IAI (0, , .", It.-typ'la-1A)i wri-JO. boo, 11117.5 , till.
g
11111. 1 MccVloxvitirt In I Tyridiiiitim chlotiale and AniC-
,
,
3

07~
mV I.I.
1) %l 1%
boa-, 1
9-1,11 it Mo i1a)
X.1ve
001
CAM
ha
- P - 08611)
11
O
C
I
00 - .
_
-imil-irly i I;jd)-W*) gave 764~O k1radoxylotirymethyl
chloride st s
I
'
I.
21
,
,
nl,
()x)f)A, x V 1 L-1:015. and 2.5 g. (C,,11.0).-
013-14' do* I
00 a "rldk. boaa 211 '. d:- U-89(9). ItV 1.43W. Ileatin& 13.8 C.
methyl ifluiticatinium chloride with 6.2 &- PrCOs-
(butcoz
I d:--- 11.8451, otj- - 1.4110) (the Preiota.

P-
I-(Butu)L
meth
li~tit
)
-Cli
O
l

a0e
-
y
-PUMP VACU T
51 at a water out gave 5%
I 1. 11
-
.
.
yniersont
y
dL-rivs.giv
y
po
&$
go -
Nj 2 by,. to
do' 1)
FiJ7 1.4147, while Am
Sl *
"-.)
1)
01J
11 rs. At I
quinulinium chloride unit PhCII-CI1 Yl in 1; h
*
-
'
.
,
u.
.
1
PrCOIC
,
AmCO,0108u. bl,
210),
tre 697
0o 11,VO.HM. b,. Xj
Sit
gave Ph(
li
i I::s 0
-
g-
0
C(,hN.L;lt l
diaiium
-II
Upyri
11f)
front 11-f[butozymeth
--
, I uni
n
1.400S W,17~). Heating 1-tl)ut')%YTllcthyliquino
d
di
i
:
.
-
.
0.9121. j,
y
1.
at a water-
OIJI at 180-21M
1 N ounst
t
.
r with AcOll in AclO fin in,ure anhy
Chlorid con
" as 0
J
1
chloride; tho: fatter An
" L-3440
158 '
al
AV
Ifl
b
1
6 -j I
guye M , But)
5 hes. at 151j4W ;sit,[ 8 tars. at l6o ~ Ac
.
at,
u
,
.
1
pump vaciluill g.lvc 1j:00
methy0pyridittitins
lox
d
f 14 IuOCIIIOAc (17 g.) unit IS it. AL011 licutcof 3.5 hri. at
1 zO 0

zoo
ecy
o
y
I'llbititiltioll vaith recovery of the volatiles, KL%-r CIII0 10
A 0
falclectnt As the dirnedon dcriv., ;it. INV), LP)::;jluOAc I
00 and 11 g. sturting ebtt:r. G. M. K too lisiod t:0 0

00, E Z-- -_O 0
20

-
U is AV aij Ls. I 'n

0--
it It A, 111--~
9 of An I t V 'd 0
6
Ilro-o.;;;Oooo
0 0 000 0 0 0 00 0 0 00 0 00 0 0
00
*
~16 0

i
-?
443

0
e
0
06006000000
0
0 o
oooooooeoeo ol
6
0
00 0
00000000000000000
0

Exchange And CIGATaCe (OACtiUn% of quaternaty ommo-
nium, salts. Ill. Reaction of quaternary ammutuum salts
with eaters~ It. N" kutinov ~iiitl V. N. tktkina. lvyji.
.14ad N.,kk % _N )J? , 0414 ikki,it. Natik 1049, ~'74 S.
il-1, it-Is 1 I:t'wA.- w ', 1,,, it 170
N titfhit~ ."A .11. It ..II - .44
quitlultil'. ki. I It I g. I
and 126 s 1:(()A,- kit W lir- .,1 1115 gAve Ito) %. V(-
OAc and Jecyl at etale, 1). -, I 18- 19% nj; 1. 12%,.
EtOlls (32.3 It.) and 28.4 11. 1 -benzy1pyridiniurn chloride
in 8 lub. at 193-1:14' live 4 S. pyT41kne, I Z g. BxOll. And
W;~ UJOC11,1112. rbe teAction probathly procceds by
form4lion W an n-unium slrriv. at The I) of the mirr Art
cleavage of the 14 gioup from the tituitrtnary comikitintf.
IV. Mechanism of tho reactions of quaternary ammo.
nium salts with alcohols. V. N. Mkitia mid 1). N. Kitt-
4.iitoy. IN.I. :111 W. I'vridine-M.-I (37 ir~) and 211-i-
r, dkv,otol ist 12 his. At givr ;Is";, iinvor, 1~,.
167'. Me deryl ether. 111, 9.3-11'. Nr::.,. mV
1.42W, -iii-I didevi r.*he,, b. 1.1-11K Ill. 01141.1N,
1. 1.1111. 11"Lln'd Amil.aly jpvp In 0 llr~. at L'P~ :b?,
16", At, 1.01
1,- 1 111.,. 'It"I 51":. It., if, ,.
. I - - I I , 'I I VC., ". I I.-.11 lotit IV, 11 it I , NO." ~ it.
4111widi, '410 IAA a. I'lW11,011 I I'l, I"
INO-Lhlil' rave Ad", llCllt08tj),. 111t, INIK11,14s.
#',.L% BU01 Ilk Clits)) 01" b. Ils-11)" d- 1P.1"IM ,i-
1 OCIO, an-I 4.4 g. (l1hCII,ItO; the m t , ,
idue contAined
hinzy1pyridinium ion. slio%si by thepscrair. m.
The results are discu!ksed in terms of formation of th,
protlucts through otionium dcriv3. formed from ridical
cleavAge of tht quaternary salts. G. Xt. K.

jp .... .....
A, If
-1--V V I-A-1-1-AA
POCOWS111 ka,(` psept"!-1-
Reaction of quaternary ammonium "Its with others
0 M N. Kursallov and V, N. Setkint. P441dy .11.1j.
-Xank S.S.S.H. 63, I-,t()Cif,l*h (110 g.) I
and W.5 g. I-brillylpyridinitun ~hloridr after 0 firs.. at
of: 141-111)' gave 8.7 c. nurricled ether and (Ph-
Cl IdiO, bia 17' V, tiful the acidic ext. give$ -ben: y1p -m-J1-,.
00 i.4itrIf as the pirrair. in. W-W. RuO K.) .11i'1
01111 1-(clccyl,)xysnethyl)pytitlinium chkwi,le (III g.) in 5 hri.
at IA)-M)* pvc 11.8 C. unreacted Dust), IW; 'I'vVI
00 chletride. h1b.4 103-5.3", 0.4% it,
I 14-fW, d"O.8472, nit
.1', ine, J:- wu&l. aw 1.441111. ~itinbflv HICIISN' #t0 0
HiNle.0 and Iluio r.%ve under the 4tmlvr tinidttiolt% I I"
I PhCI I,)tO a a J- be Vi V I... Al
11-411, - " P.~ I%K~. ' MONIC amt I -t-vt
Ill'. d.. a 1.0129.
nhant ChlMi'le ift 3 he$- at 1:4 W
I-
1117'. nrid 81'~ ut tuixnI
W1 2.5% and fit rib o
.go' the aeil Cit. (11titailml 4 -1-'V It.% t f. lute. Wrlittfinl
06 a% the pierate. rat. UPS*. '17hr uw4 I'lif W( fit jjjcat-v~ so
-gave M.2- PhOC11,11h. aful 10-, Ini%"i
phetryl"Iethafte and the 4.1-.,t0 deriv., as Avelf as a little
9
C.- M. K,-.Ijr.,IT i :coo
J voo
_ASMI - 11 L A ItIETALLILIRCICAL UT911.11V41 CILMIPICATIC0.
roe
t laid., .1. 4- Cat
11 1 a V 7A 66 A S V rap 0 q IT -1 If N 0 jj-07T rp-;,~Wi so*
a
U 5 AT so IW K it 9 In n rt It cc aw n
a In r' up
4111 * 0 * *1* 0 a 0 0 0 0 0 0 0 0 * 6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0:
- - :I- * 000000*0'000 a a - 6,A-*-L 0 0 & 0 0 0 0 0 0 0 0 C

SETKINA, V.N.
"Concerning the Reactions of Exchange and Decomposition in the Group of Quaternary
Awonium Compounds." Thesih for degree of Dr. Chemical Sci. Sub 31 Oct 50,
Inst of Organic Chemistry, Acad Sci USSR
Summary 71, 4 Sep 52, Dissertations Presented for Degrees in Science and Engineering
in Moscow in 1950. From Vechernvaya Moskva, Jan-Dec 1950.
1

Reactions of decomposition and substitution romong
quaternary ammonium Compourlds, V. Debytilzative
action of ammonium derivatives and the mle of oploolum
compounds in dehydration torlpictions of alcohols
tilde/. Ahow ~Namk 1930. :.'16 2'-'; &
C-1. 44. PAIla-Thl: anallxv drhvdT.tii-it .,I
A '. and the trartioll If toks. " ith quatermiry Atli Ill"tti" III
t"'if,tot, ic) and the r"k, oil Ililog'-to, Ilik"JI
u.1111orl III deliv.1r, III, L. .1 toll-led orlettiol-1111W I-vtwil
Ilraling III it. C. oith :4 K. I -61'r1 Its
KNIA1 1; Itt%. to -.01 20' ICAVt 1.1covill'. III M 5'.
,1!0 II.-Will. x1f L-12143. %I'.'. poll A Ill it'. 1-14 1 if, F . bo IC"
'I.,. 11.241111C. NJ* oil -,)-mlinillill
mW 4:1",' didrvi eikrr. b, IS7-9'. it.'" WSINS, NJ" 1.1111.
Sil"il,ttly. 15.8 it. C'14,011 ;suit 2.3 K. I'v6dille-11cl ICAVC
ill 7 hr,. at 4.0 g. decirisir 4331,1. llf'~ Imyl
chlioride, 1). 101 ', it-' O-NAX1. 0' 1.43811. aul III,-; didevyl
" her. Ot-tatiol in &I ~isuilar reaction gave IS' ~ 1-owleNe.
lo," 120.5-2.0'. d:' op.7, IM. Wj'- 1-4141to. R6. astil di-
"(yj dkrr, It. 171 ', IvV 1A.M. till IISIXIS. lleiting 15,S
je. ClelfroOll 3nif I g, Wine 1) hr.,. to 185-:01 -' gave I g.
(7%) deccipor, asort 46% dirlmyl ortht-or, as well as p-tric Roll
,nd w; nctantil Arnilarly gilvo, 2.7~: xiettle and
R to. Neither n1c. i, chingal by such heistalor alone t7-S
hr,,. at *.!LNI-:b)'). G. M Ki-6tonif

Exchange reactions and Cleavages in tho q,,i,&tvc"rY am-
tnomiumealcKfoup. V1. Reaction of salts of Alkospriattlys-
pyridinium with phenols. 1'. N. Setkina and 1). IN. Kur-
~31111v. lr~,I. Akad. Y,:uk S.S.S.R., Kkim. Nauk
1050. cf. C.A. 42, 41022e; 44. 1=7t.-PAtemd; anti
ia/I, yiV(d, a-, ptilmiry protfurts. I
phellyl AW jortmiti, ""lidary reactions vichl dialkyl
f-9111411, mins, and aliphatic Alm
The dialkyl fi-rmak react %tell Arill-1, yielding 11011 and
the te~itm WhOlfcIll :tplwArs to react witb pyridinc-
I I Cf i, i.i.in tot, -ch.tin r-t-tion triechanism. yielding protonaled
hi,h cl,.a~e into Mill an.) -PhOCH, ions. the
Loirt cvrviw: the ch,tio irmiction that vi,'il.12its9thl.(rb"uittsoxbyy
hyl Ii,tjo_ Jjjori~jc mid 25.2 g. PhOll 70
0" 1 - 9C ; j
L,-, 7.,~.. nt.' I vv~j, 7.1~, r-in. all-I all Ull
I
6 Ill,. at 'W-5, ItA%e N.""
57'.!, 4 Bil()iCff,. ane jq-tWinc, And M.75; 9-41.
j4decylo%plictil -viij)Yri-fillillill 0110ride yieftled, ginlilarly,
hr. t)% PhOlf, 5% decyl chlori,lc. 4.8%
decyl AIV.. decyl 114 farmal.
1.47YO, d"" -1,11JI-O". 57.5"; dife, 'vi forows], W 21W- Ill". NV
1 4 11 %. d.- i i s HIS, and 62% ri~in. 14Tt-tralf-YI-1-
mrshirl ~ o-1-4 X.." ~-*_-,-,; diles"Itin.vt ill. 12 2IJ;, .
.oA it',' temit. 2-NAphthol ON KA And 19-2 it. 14(eft.4-
. I~ox vill, I It v I -pyridinill"I chloride in 11) hm At
givir ej-41, factirt,lecyl form.d. lirridine-110, an,l an un-
r
*(A(Vd Viet-! of 1`~Afl: I-n--phthul g4ve 19070 of the isbove
IcAllig 4..', f, Mill and
LN C. (Buo),elf, 3.5 his, at jw-ipp gj,,, W; 1JU011 And
4 g. P110101fortnaldehydi: rc~in; 2.lljphljlol rr~cted similarly,
l1t`2 PhOll and 10 x, didecyl furinji a hill. At 1&,~
lolt"I'11:94. drcvl "I, - It. 14W
U.M: lot? 1-437-s. m.
IL-A11412-6g. -jh~abicncrof(R.
holicli, ill th,, p".111"Ib i. CiipUlled I,%- the (.110.ing f,Ct.
"tiog thL, foctit,l it) it.) %clh K pyridifle-11cl 10 his.
At 1O."LMLI, KA%C I'a g. S.,(M-ol, rv~in Pholf, and
K. Tv'ina", rt'i, 'lf(Vr diqtl~ of the
lue Will.
N1. )C.

Salts f q% yft~
Vill *note. 1) -V ursanov
Ol, % N ~X-Ikwj
Khfow. 170M-Mrp~;' S '.5. K . (W4"
Ilrating2831
1-4,1(1 yIo%vnsvIhYDp~ ridinition chloride with M.14 C. litt)llh
S to 1 A) AV (sraltAl tutle) Inv c 229 it . Et0i'll, I S. drcy I
chl4mi,jr. 4.41 g. tl,-cyl a1c., 6 115", %1? 1* 43"A'its, 'KM
. tr-141
2 g. PAOCHOCW[n. b. 2fX)-3*, x1f 1,47M. d"' ):
and 7 X. (C..JI.0h(71,. fin 232--l'. at? 1-44A), 'I.- U.S102;
sorne 5~2 S. (*417,P pAvnPI-fa,#rtslIdsrhyJe Pirsix was is,"iml
frons the rvi,61urv. (Butoityinethyl)p)-vidiniam chforith,
131.1 x ) with 111.14 it, MvOllh (I hri. at Itave 1.4 x
litioll, 1.1 g. (Iftsohell" b. 17,14-&.1% N ir?', stir 1 14)76~
1.' 1) SIM. 1.4 C. unknown ;xboaxte. b,. 45-775'. im] 7.7
If)%% phtnol-formakichyde resin. ficating fit )t
~C~III,Ohi-l Aith 3 U g. J'h0l( if bell, to g.%, ~M X
dery) :11c. and 2A C. solhi which is-is clas,tic at tir,t, thrii
furd,-tjrd an attcalpictl ifisin.. i.e. a form of
Afrhyde resin. Ifence, the pyridinislist salts undergo
tMnSVtheViSL-AtiOG With the phenol ethm. friet,fing forinals,
hich symmetrize and then react with the 10MAHMI Of the
Zmeric mini. The reaction of phennis and of their
;
ethers with salts of (alko-4ynirthyl,'llyridininist ion are

Exclum and cleavage reactions of quaternary ammonfurn
me
"Its. . Reaction with alcohols and phainials of sub-
stituted anutionium "Itit with a bentyl radical. V. N.
"ILut-ifid 1) N. Ktif,imw. Invit. Akak. Xamk.V~S~S.M_
Obl. Kkim. Yajok 101. S1-5: cf. C.A. 43. IlLN111. 9:01t. -
Q'Silefliary allullmlillill %.kII% Coutat. Imnlyl ammillcuk form
%ith aics. or phen"I - Ix-it; v lh(. t heirs A I lie rorre" Mill
,if Produces of exElLifige it a r ninhile 11 of I tie phencals fare lie
I1hCII, group Imith ill Or Oil group as well as In the onlif
and p4m l"illoss,; wilh nalthilsoli the reaction is predoill 1-
11LIfIlly nuclear submittation ill the ortho anal para gmasitiolls
%iih r"pect to 011. Ifrating 15 C. PbCH,IlhtePhCl and 9
g. AmOlf Shmat 144-55' save(S.4 K. PAC11,0AM. hit lIfV_
17'.,1:' 0.9142. 111: I.-IS51. Similarly. 13.4 if 1-benzylpyri-
dinium chloride (1) tand III, g. CiellisOll 8 lim. at 100-
gave 7 g. PAC11,0C,.11,1. 14 3177-8*,Al.'OM~4
2-Cml I r4 )If (24 4 ae.)jnil 41 .2 ae. I in 6 he%. at I& I I
it-Ave a wide
wain of fractioni: 12`7~ immicted naphthol, tY)% 1-bem*-2-
hydrivervia4phlbalext. m. (fmm M% HC(Nlf).
th.. u Z!&-4;." (crude), and 1.2 g. CalloO. an. 189.6- 90.0 ..
c I'- :uuul,orly,~Mhg. I-Cliaillifill
.,,!:'fh4 1'2!"',. al i It fl. At IN P -IN I' g.4% e L~# 5' U It re-K I "I
1-hydroxy."rnsylitophthakne. bi-to 2J7% m
Itplithril,
1.5", al-it 9.5 x. % iWtiu- it. hA,_.4a-3Io-.(oarIPo%4I of w,
,rat PF(Xitli:[% from %hich ill vwi. *life haremne gave I g
"HwO. m 7;.,*. WrIltified
~`Pte. ficiliting 18.8 K. IIII011 %ith 41 g. Itilars.st IW--21W
r-Ave 251/-4. P11011, IN, .~ NOC11,11, its. :39% IN 113-tV,
1817. naixt-d i,oturrie hen~yl r1hert of bvxzy1phrfr,,!). [it 2511
,Wphe-l.
nakni Johem:Ylphem"A, 1% C.. M. K-L.1-11

USSR/Chemistry - lYdrocarbons. Aug 52
sotopes
"Hydrogen Exchange in SaturiLted Hydrocarbon's Result-
ing From the Action of Sulfuric Acid," V. N. Set'-
kink, D. V, Kirsanov 0. D. Sterlingov and A. L.
Liberman, Inst of Drg Chem Acad Sci USSR
"DAR SSSR" Vol 85, BO 5, pp 1045-1048
The exchange of H in a no of hydrocarbons was stud-
ied with the aid of sulfuric acid having an atom of
heavy A. It was found that the reaction passes
through the following stages. Radicals or car,bonium
ions are formed by oxidation. They are capable of
exchanging their a atomr. for deuterium, 9 extha=e
239TI~6
continues from one radical to the next in a chain
reaction. The final stage is breaking off of 'the
chain :taking place in the usual manner. Submitted
by Aced B. A. KazanskiY 3 Jun 52.
239T16