SCIENTIFIC ABSTRACT SERGIYENKO, S.R. - SERGIYENKO, S.R.

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• Collection: Scientific Abstracts
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• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 12
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

14(5)
SOV/165-59-5-2/21
AUTHORS: Sergiyenko, S.R., Lebedev, Ye.V.

TITLE: High-molecular N-paraffin Hydrocarbonsl(C21 - C 30) of the Ro-
mashkin (Devon) Petroleum
PERIODICAL: Izvestiya Akademii nauk Turkmenskoy SSR, 1959, Tir 5, pp 16-19 (USSR)
ABSTRACT. The authors describe a method of study of high-molecular hydro-
carbons in Romashkin (Devon) petroleum. This method, based on
the chromatographic fractionation of hard hydrocarbons, was de-
veloped by V. Fuks Z_Ref 12. Characteristics of solid hydro-
carbon fractions, forming a complex compound1with carbamide (1)
and not forming a complex compound with carbamide (2) and liquid
hydrocarbon fractions forming a complex compound with thiocar-
bamide (3) and not forming a complex compound with thiocarbamide
(4) are shown on Table 1. The scheme of extraction and cracking
process of high molecular hydrocarbons is shown in a graph (Page
16 a). By simultaneous use of ASK type silicagel, activated
carbon and activated alumina as adsorbents, further dichloro-
ethane, hexane, petroleum ether (50 - 700), acetone, benzene,
Card 1/3 ether and their comDounds as substitutes, ten individually classi-

SOV/165-59-5-2/21
High-molecular N-paraffin Hydrocarbons (C21 C3()) of the Romashkin (Devon)
Petroleum
fied paraffin hydrocarbons C.,., C30 were obtained from Roma-
shkin petroleum. T-e fracti8nation of solid, high-molecular
hydrocarbons in a 3-section chromatographic column, showing the
number of fraction, nio, concentration and processing tempera-
U
ture is given on Graph 1. The quantitative distribution of N-
paraffin hydrocarbons in the fraction of solid high-molecular
hydrocarbons forming a complex compound with carbamide, showing
the yield, processing temperature, carbon atoms in the mole-
cule and TO of initial high-molecular hydrocarbons with a com-
plex compound formed by carbamide, is given on Graph 2. The re-
sults containing the number and Went of fractions, gram and
0 0
percent of yield, total yield, n D, T pl. (melting temperature)
Card 2/3 and the derived products are shown on Table 2. It was proved,

SOV/165-59-5-2/21
High-molecular N-paraffin Hydrocarbons (C C70% of the Romasnkin (Devon)
Petroleum 21 - ~ j
that with increase of the molecular weight of IT-paraf-Cin hydro-
carbons, their quantity in the petroleum decreases.
There are 2 tables, 2 6raphs and 2 references, one of which is
Soviet and one German.
Card 3/3

50), 15(5)
SOV/165-59-6-4/5 -Is-
AUTHORS! Sergiyenko, S.R., Yan, Tsuy-Din
:"-TrFLE1 Composition and Properties of the High-Molecular Components'of Karamay
Petroleum
PERIODICAL: Izvestiya Akademii nauk Turkmenskoy SSR, 1959, Nr 6, PP 37-48
ABSTRACT: The authors describe the results of studies on the composition and'pro-
perties of the high-molecular components of the Karamay petroleum, car-
ried out according to a method described in References 1, 2, 3 and 4.:
The petroleum from the Karamay oil fields in the province of Sinkiang is
one of the potential industrial petroleum%f China and its chemical pro-
perties differ considerably from all kinds studied previously. It has a
low sulphur content and is relatively heavy with only 110% of benzene-gas
fractions. The high-molecular components (above 3500C) isolated at a
temperature not exceeding 2200C consist of: 73% hydrocarbons, 24,19 tars
and 3% asphaltenes. The content of asphaltenes during processing with
varying quantities of pentane is shown in Table 1; 80% of the hljdro-
carbonic components are paraffin-cycloparaffinic hydrocarbons'l only 201,16'
are aromatic hydrocarbons. The saturated hydrocarbons are highly cyclic,
Card 1/4 containing an average of 2.5 cycloparaffinic rings per molecule. The

SOV/165-59-6-4/5 -1,5'
-:inosition and Properties of the High Molecular Components of Karamay Petroleum
distribution chromatogram of high molecular hydrocarbons is given on
Graph 1 and the chromatogram of the interfractionation on Graph 2. By
repeated chromatography of saturated hydrocarbons 16% of fractions were
isolated showing a density of 0.89 and a refraction coefficient n2D
D
1.48 - 1.50, due to the increased number of rings. The chromatogram
of the repeated division of saturated hydrocarbons is shown on Graph
and the repeated division of monocyclic aromatic hydrocarbons on Graph 4.
Amongst the aromatic hydrocarbons those of a bicyclo-aromatic structure
dominate. The division of high molecular hydrocarbons is shown on Page
39: hydrocarbons (above 3500C), chromatographic division with silica gel
ASK, derived products, interfraction chromatography, derived products, re-
peated chromatography, derived products. The distribution of fraction
upon chromatographic division of the high molecular hydrocarbons and the
results of chromatographic interfraction is also shown. Bicyclic aromatic
hydrocarbons have a smaller molecular weight and contain more sulphur
than monocyclic aromatic hydrocarbons. The composition and properties
,)f tars, particularly their poor solubility in phenol is a proof of low
aroi,iatization, which is also the reason for the low adsorption on silica
gel ASK. The adsorption of tar on silica gel is shown in Table 2, and
-ard 2/4 the results of the isolation by adsorption of tar from hydrocarbons of the

SOV/165-59-6-4/5- W
Composition and Properties of the High Molecular Components of Karamay Petroleum
high molecular components in Table 3. The quantitative distribution of
various hydrocarbonic groups within the high molecular components, their
composition and properties are shown in Table It, and a comparison of the
characteristics of saturated hydrocarbons before and after repeated
chromatography is given in Table 5. The dependence of the composition
and properties on the tar fractionation is shown on Graph 5, and the de- P
pendence on the molecular weight on Graph 6. The distribution of tar
fractions is given in Table 7 and the composition and properties of the
fractions in Table 8. The molecular weight and the number of heteroatoms
of the fractions increase with the rising polarity of the desorbing sol-
vents, whereby the number of their functional groups increases according-
I.Y.
There are 8 tables, 1 diagram, 6 graphs and 5 references, 4 of which are
3/4 Soviet and 1 English.

SOV/165-59-6-4/5 -/j-
.pposition ~~,nd Properties of the High Molecular Components of Karamay Petroleum
A 0 C I A!-!'-T') IInstitut geologii i razrabotki goryuchikh iskopayemykh, Akademil nauk
SSSR (Institute of Geology and Processing of Combustible Minerals, AS
USSR)
SUBMITTED: July 17, 1959

5 ('31, 15 (5)
SOV/165-59-6 -3/5 -I.T-
AUT HO RS Sergiyenko,.S.'R., Yan, Tsuy-Din
PITLE: On the Chemical Nature of High-Molecular Paraffin-Cy~llonaraffi Hydro-
carbons of Petroleum
PERIODICAL: Izvestiya Akademii nauk Turkmer-skoy SSR, 1959, Nr 6, pp 49-60
ABSTRACT: The high-molecular saturated hydrocarbons It of Karanay petroleum, which com-
prise 801% of all high-molecuiar hydrocarbons in -~t, were divided into
three fractions by chromatography on silicagel and selective solvents:
20
liquid hydrocarbons (nb = 1.475 - 1.48o) compy,ising more than 80%, solid
hydrocarbons with a melting point of -370C ( -106), and saturated liqu-i.-'-
hydrocarbons with a high refractive index (nBO = 1.48 - 1 50). Solid,as
well as liquid high-molecular hydrocarbons of Karamay petroleum consist
mainly of strongly branched paraffin chains, in which cyclopentane and
cyclohexane rings take the place of substitutes. This is proved by the
low melting point, the high refraction coefficient, the inability of solld
hydrocarbons to form crystalline complexes with carbamide, the high spe-
cific gravity, etc. The application of selective dehydrogenation in the
liquid phase made it possible to evaluate the total quantity of hexa-
methylene groups in the saturated part of high-molecular hydrocarbons, as
,'.'ard 112 well as to calculate approximately the character of distribution of five-

5 (3)
AUTHORS: Petrov, Al. A., Sgrgiyqnko, S. R., SOV/62-59-6-22/36
Ifechitaylo, N. A., Tsedilifia, A. L.
TITLE: Synthesis and Properties of the Monomethyl-substituted Alkanes
of the Composition C 12-C 16 (Sintez i svoystva monometil-
zameshchennykh alkamvsostava C 12-C 16)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh naulk,
19591 Nr 6, pp 1091 - 1097 (USSR)
ABSTRACT: Since the hydrocarbons of this structure are not yet suffici-
ently investigated, the synthesis of the monomethylated al-
kanes with a boiling temperature of more than 2000 was investi-
gated. With this monomethylated alkanes one may synthesize all
theoretically possible isomers (there are only 29 compounds).
They are furthermore of interest because they have thermodyna-
mically stable structures and meet with all technical require-
ments of motorization. The hydrocarbons were synthesized ac-
cording to Grignard's reaction (magnesiumbromoalkyls with me-
thylketones). In this reaction the purity of the compounds ob-
tained depends in a high degree on the purity of the initial
substances (alkylbromides). This fact was especially considered
Card 1/4

Synthesis and Properties of the 1,1,onomethyl-substituted SOV/62-59-6-22/36
Alkanes of the Composition C 12-C 16
in the present investigation. The methylketones were obtained
by decomposition of the corresponding alkyl-acetoacetic acid.
As intermediates tertary alcohols were at first obtained which
were dehydrated at 2800, redistilled , and hydrated 0in the
autoclave on nickel at a temperature of from 150-170 . The tem-
perature at which the hydrocarbons obtained crystallize was de-
termined by plottirgthe heating curve by means of the photo-
-recording Kurnakov pyrometer. The purity degree was determined
by means of a special thermographic device.N. I. Lyashkevich,
to whom the authors express their gratitude, carried out the
measurements in the laboratory for petroleum chemistry of the
institute mentioned in the Association. The purity degree of
the synthesized hydrocarbons was 97-98%. The thermogram was re-
corded by a special aluminum block which was designed in the
Institute
Institut obahchey i neorgan 'icheekoy khimii AN SSSR (.
of General and Inorganic Chemistry of the AS USSR). By this au-
tomatic recording of the heating curves the melting process
could be fixed exactly (Fig 1). With almost all compoungs ob-
Card 2/4 tained two stages in the melting process (-46 and -45.4 melt-

Syntheeis and Prorertiez of the Mo_ncrethy1-subs+-4tut=_d SOV/62-510-6-22-9/36
Alkanes of the Composition C
12-'16
ing and crystallisation temperature) were observed. The pro-
perties of the hydrocarbons are given in a table by which it is
shown. that the density and the refractive index scarcely de-
pend on the position of the outer methy! groups in the main
chain, what is w311 in line with data by Tatevskiy (Ref 5)-
The crjstallisat-ion temperature is, however, strongly influ-
enced by these methyl groupB. The change of the crystallisa-
tion temperature at tfte transition of one homolog to the other,
and of ona isomer into the other is not steady (Figs 2,3 with
comparative data from Ref 10). This unsteadiness is caused by
the presence of either an even or an odd number of hydrocarbons
in the main chain. The transition from an odd to an even number
of hydrocarbons exerts a parallel influence on the malting,
point, the reverse transition, that is an increase in the mr,-.
lecular weight, exerts an antiparallel influence. The laws
holdin,,- for paraffins, olefins, and greases, which are well
known, may thus also be applied to ramificated alkanes. The
crystallisation process of the latter takes pla;~e by forming
Card 3/4 such crystals as exhibit the shortest possible carbon chain.

Synthesis and Propertion of 'Whri Monome thyl-uubstitu SOV/62-59-6-22/36
Alkanes of the ComDosition C I -C.
.2 16
There are 3 fi6p_xes, 1 table, and 11 references, 5 of which
are Soviet.
ASSOCIATION: Institut nefti Akademii nauk SSSR (Petroleum Institute of the
Academy of Sciences, USSR)
SUBMITTED: September 5, 1957
Card 4/4

5 (3)
AUTHORS: Serg-iyenko, S. R., Chernyak, N. Ya. sov/62-59-7.-20/38
TITLE: Kinetics and Mechanism of the Oxidation of Dibenzyl in LIquid
Phase (Kinetika i mekhanizm zhidkofaznogo okisleniya dibenzila)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk;
1959, Nr 7, pp 1294 -- 1303 (USSR)
ABSTRACT: The present paper deals with 'he oxidation of hydrocarbona
which contain aromatic and aliphatic ingredients, and the resin
formation. Dibenzyl serves as an example; it contains two aro-
matic rings which are combined by an aliphatic bridge. Further-
more, only a small number of oxidation products is possible in
the case of dibenzyl. The kinetic rules governing the oxidation
and its reaction scheme are investigated. The experiments were
carried out in a closed system with circulating oxygen. The
scheme of the apparatus is represented in figure 1. The absorp-
tion of the oxygen was determined from the drop in pressuie.
Moreover, the intervals were determined within which the oxygen
content decreases to such an extent that new oxygen has to be
introduced in order to guarantee an uninhibited reaction ouarse.
Card 1/3 From these intervals the curve A V 02 versus t was obtained

Kinetics and Mechanism of the Oxidation of Di-berzyl SOV/62-59-"1-20/36
in Liquid Phase
(Fig 2). Furthermore, the time of the consumption of dibencrl
and the accumulation of intermediate- and final oxidation prc-
ducts were determined from the change of the functional groupe.
The content of dibenzyl in the reaction products was det--rmired
from the adsorption of the oxidizzod products in fire-grained
silica gel. The content of peroxides and acids was determined
potentiometrically, the aldehydes polarographically. The ex.-
perimental temperatures were changed for the investigation of
the reaction kinetics( 110, 130, 140, and 1509. It was fri:,id
that the oxidation proceeds at all temperatures autocatalyti-
cally. The reaction begins without induction period, acceler-
ates,, .'eaches a maximum, and dies dcwn. The reaction is
subjected tu an exponential law. Thle polaro-graphic anamorphoces
of the absorption curves of 0 2 show that the reaction proceeds
ia the chain mechanism. The curves of the kinetica of the con-
sumption of initial dibenzyl and the accumulation of intermedi-
ate producto are reprosentod in figurcs 3a and b. From these
follows thatihe-pzmess is inhibitled in the furt'her stage
Card 2/3 of the reaction under the in_rlUaIIte 01 produced inIhJbi`nC

Kinetics and Mechanism of the Oxidation of D4-benzyl SOV/62-59-7-20/36
in Liquid Phase
resin products. The activation eneray of the becginning oxid~--.-
tion (29 kcal/mol) was determined from the experimental datr-
and from it the activati 'on energj of the reaction of pe:,o:-y-
radical with dibenzyl 13 kcal computed accordine to the g-17c'-
reaction scheme. The reaction scheme which is based upon the
radical- chain mechanism reproduces all experimental rules
.-overninar 'Uhc reaction mechanism observed and takes into ac-
count the autoinhibitina effect caused by the destruction of
the peroxyradicals. The hydroperoxide of dibenzyl- and ben-zal-
dehyde were found as intermediate products. The influence-, olf
additions on the different roactior sta[;es (resinous inter-
mediate products cic.) represented in figures 4,5, and
There are 6 fisuy',-o, 4 tables, and 9 references, 8 of which
are Soviet.
ASSOCIATION: Institut nefti All SSSR (Institute of Petroleum of the AS USSH)
SUBMITTED: September 11, 1957
Card 3/3

50), 5W SOV/62-59-8-13/42
AUTHORS: Petrov, Al. A., Sergiyenko,_._~I. R., Tsedilina, A. L.,
Nechitaylo, 11. A., Sanin, P. I., Nikitakaya, Ye. A.
TITLE: Synthesis and Properties of the Dimethyl-substituted Alkanes
Having the Composition C 12-C 16
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, fir 8, PP 1421-1424 (USSR)
ABSTRACT: The present paper discusses the synthesis and properties of
some of the compounds mentioned in the title. The properties
of the synthesized materials are given in table 1. Nearly
all substances crystallize at low temperatures; only 2,4-di-
methyldecane and 3,5-dimethyldodecane.vitrify at much lower
temperatures than do their isomers or adjacent homologs.
Besides reference 3 investigations aiming at an explanation
of these phenomena have also been carried out by Petrov
(Ref 4)- It was assumed that the characteristic feature of
vitrification of the two compounds mentioned is due to their
structure. Various investigations were carried out to prove
this assumption (determination of viscosity as a function
of temperature (Table 2) and determination of molecular
weight). From the results it is seen that the influence of
Card 1/2 the structure on the vitrification effect cannot be limited.

SOV/62-59-8-13/42
S,ynthesis and Properties of the Dimethyl-substituted Alkanes Having the
Composition C 12-C16
It was only possible to establish a certain dependence on
the branching degree of the compounds. There are 2 tables
and 5 Soviet references.
ASSOCIATION: Institut nefti Akademii nauk SSSR
(Petroleum Institute of the Academy of Sciences, USSR)
SUBMITTED; December 10, 1957
Card 2/2

5W sov/62-59-9-9/40
AUTHORS: Levshin, V. L., Mamedov, Kh. I., Sergiyenko, S. R.,
Pustillnikova, S. D.
TITLE: Fluorescence Spectra of Aromatic Hydrocarbons of the Diphenyl
Series and Their Oxygen- and Sulfur Containing Analogs
PERIODICAL: Izvestiya Akademil nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Mr 9, pp 1571-1578 (USSR)
ABSTRACT: Petroleum fractions of high molecular weight can be analyzed
with fluorescence spectra, but the spectra of the individual
components of the fractions are not well enough known, so that
there is a lack of comparative information to interpret the
spectra. It is the aim of this paper to carry out further in-
vestigations in this field. The authors investigated the spectra
of the hydrocarbons of the homologous series of biphenyls start-
ing with diphenyl itself. The further compounds extend the
aliphatic chain, introduced between the benzene rings, to
pentane. A type of compounds was also investigated in which one
CH.-group of the aliphatic chain is replaced by oxygen or
Card 1/3 sulfur. The table shows structure and properties of the nine

SOV/62-59-9-9/40
Fluorescence Spectra of Aromatic Hydrocarbons of the Diphenyl Series and Their
Oxygen- and Sulfur Containing Analogs
compounds investigated. The fluorescence spectra of the com-
pounds solved in isooctane were recorded at room temperature
and at the temperature of liquid nitrogen. The spectra were
examined with a quartz spectrograph of the ISP-66-type. The
synthesis of the substances investigated is described. The spec-
tra of the individual compounds are represented on figures 1-8.
The influence of the elongation of the aliphatic bridge makes
itself felt by the strong splitting up of the spectral bands.
The spectrum is markedly more intense at low temperatures and
may be used for analyzing the substances. The luminiscence
spectrum changes considerably when an oxygen- or sulfur atom
is introduced. At strongly markedqc-electron bonds between the
two benzene rings, the spectrum is shifted toward the longer-
wave range at low temperatures as compared to spectra at room
temperature. There are 8 figures, 1 table, and 7 references,
4 of which are Soviet.
ASSOCIATION: Moskovskij gosudarstvennyy universitet Im. M. V. Lomonosova
Card 2/3 fizicheskiy fakulltet (Moscoyr state University imeni M. V.

SOV/62-59-9-9/40
Fluorescence Spectra of Aromatic Hydrocarbons of the Diphenyl Series and Their
Oxygen- and Sulfur Containing Analogs
Lomonosov, Physics Department)
Institut nefti Akademii nauk SSSR (Petroleum Institute of the
Academy of Sciences, USSR)
SUBMITTED: December 20, 1957
Card 3/3

SERGIYENKO, S.R.. DEMDIMVA. P.Ya.; ISLONE, 1.0.; KURM.TSKAYA, A.P.
Distribution of trace elements in petroleum tare and asphaltenee.
Trudy Inst.nefti 13:118-126 159- (MIRA 13:12)
(Petroleum products) (Trace elements)

S/08 1 /61/000/00 5/012/02 4
B1 I Q/B205
AUTHORS: Nozdrina, E. V., Sergiyenko, S. R.
TITLE: Application of methods of selective catalytic hydrogenation
and dehydrogenation for the purpose of clarifying the struc-
ture of high-molecular aromatic hydrocarbons of petroleum
PERIODICAL: Referativnyy zhurnal. Kbimiya, no. 5~ 1961, 532, absiract
94146 (5M146) ("Tr. In-ta nefti AN SSSR", 1959, 13, 127-144)
20 20
TEXT: Attempts to hydrogenate the fraction (d 4 = 1.0146; nD =1.5813;
molecular weight = 435; C = 85-50 %; H = 1M3 %; S = 4.43 %) of condensed,
bicyclic, aromatic hydrocarbons which had been separated chromatographi-
cally on ailica gel from the resin-free residue of Romashki petroleum,
have been made in a rotary autoclave, in the presence of the commercial
catalyst WS 2- NiS-Al 20 3~ at 250 and 3000C, sand at 180 atm for 40 hr. The
hydrogenated substances were subjected to a chromatographic analysis.
a -
Single hydrogenation at 2500C (100 % catalyst per raw material) resulted
in 89 % desulfurization and double hydrogenation (200 % catalyst in two
Card 112

S/081/61/000/005/012/024
Application of methods of selective... B110/B205
hydrogenation processes) in 95 % desulfurization. The hydrocarbonmolecule
was not very strongly affected. Single hydrogenation at 3000C (60 % cata-
lyst) results in 94.5 % desulfurization, and the second hydrogenation
removes practically all the sulfur. Under the conditions of hydrogenation
at 3000C, which lead to comr)lete desulfurization, the coi.densed, bicyclic,
aromatic systems practically vanish. LAhstracter's note: Complete
translation.]
Card 2/2

SERGIYENKO. S.R..; LEBEINT, Te.V.; PETROV, A.A.
Selective catalytic dehydrogenation of saturated high molecular
weight hydrocarbons in the liquid phase. Trudy Inst.nefti 13'-145-
160 '59. .(MIRA 13:12)
(Itrdrocarbons) (Debydrogenation)

50) SOV/80-32-3-31/43
AUTHORSi Sergiyenko, S.R., Semyachko, R.Ya., Galich, P.N.
TITLE: The Liquid-Phase Oxidation of High-Molecular Hydrocarbons of
Petroleum (Zhidkofaznoye okisleniye vysokomolekulyarnykh ugle-
vodorodov nefti)
PERIODICAL: Zhurnal prikladnoy khimii, 1959, Vol XXXII, Nr 3, pp 641-649
(USSR)
ABSTRACT:- In high-molecular hydrocarbons of petroleum, compounds are con-
tained which have condensated aromatic structures in their
molecules. These compounds are the sources for the formation
of resinous asphaltene substanczs. A genetic system exists in
these hydrocarbons which may be represented by the following
series: condensated bicyclic aromatic compounds--rcondensated
polycyclic aromatic compounds--,oresins--.Pasphaltenes. At an
oxidation temperature of 150 - 1750C the asphaltenes prevail in:
the oxidation products. The paraffin-cycloparaffin hybrid com-
pounds are transformed during oxidation in the liquid phase at
a temperature of 150 - 1750C to peroxide compounds which in turn
are transformed to acid saponifiable hydroxyl-containing oxygen
Card 112 compounds. The bicyclic aromatic condensated hydrocarbons con-

SOV/60-32-3-31/43
The Liquid-Phase Oxidation of High-Molecular Hydrocarbons of Petroleum
densate most easily of all hydrocarbons, followed by the mono-
cyclic aromatic compounds. The paraffin-cycloparaffin hydro-
carbons oxidize more easily at 1500C than at 1750C-
There are 3 graphs, 3 tables, 1 diagram and 10 Soviet refer-
ences.
SUBMITTEDt May 16, 1957
Card 2/2

50) SOV/2o-126-4-30/62
AUTHORS: Sergiyenko, S. R., Kvitkovskiy, L. N., Petrov, Al. A.
TITLE: Viscosity-temperature Properties of High-molecular Hydrocarbons
of a Mixed Structure (Vyazkostno-teml)eraturnyye svoystva
vysokomolekulyarnyhh u,-levodorodov sineshannogo stroyeniya)
PERIODICAL: Doklady Akademii nauk SSSR, 1950, Vol 126, NT 4, PP 79B-801
(USSR)
ABSTRACT: The viscosity of hydrocarbons is one of their fundamental
properties, directly connected with their chemical structure.
One of the most important characteristic features of the
working properties of lubricating oils, is the change of
their viscosity together with their temperature. The hydro-
carbons of the oil fraction of petroleum have a mixed (hybrid)
structure. Therefore it is of essential importance to observe
the dependence of the viscosity upon the molecular structure
of the hydrocarbon of such a mixed type, and especially
the character of the changing viscosity-temperature proper-
ties. The most complicated hydrocarbons of a mixe;" structure
containin- condensed nuclei of the type of naphthalene, tetra-
Card 1/4 lin and decalin, besides structural links of paraffin, cyclo

SOV/20-126-4---lo/62
Viscosity-temperature Properties of !figh-molecular Hydrocarbons of a
Mixed Structure
paraffin and benzene, have already been studied. The high-
molecular part of petroleums however, contains a number of
these structures. The present article has the aim of filling
thig gap. The first task was to define the effect of the
amount of the condensed rings mentioned, and their
position in the molecule, on the viscosity properties of the
hydrocarbon concerned. For this purpose hydrocarbons of the
naphthalene, tetralin and decalin series were synthetized
with 32 carbon atoms in the molecule (Table 1, Ref 1). The
measuring results of their viscosity are shown in table 2.
The replacement of 10 carbon atoms of the paraffin chain by
a ring of naphthalene: tetralin or decalin, makes its vis-
cosity twice or three times as high; a further replacement
of the next ID atoms by one of the mentioned rings causes
a rapid increase of viscosity, about B-17 times. The first
ring added, changes the temperature curve just little, by
increasing its curvature, while the second rin'g added, sudden-
Card 214 ly increases its curvature. Such an increase of the curvature

SOV12o-126-4-W62
Viscosity-temperature Properties of High-molecular Hydrocarbons of a
Mixed Structure
is characteristic of hydrocarbons containing 2 naphthalene
rings in a molecule (Table 2, Fig 2), especially in the
sphere of low temperatures. The position of the ring is also
important for the value of viscosity as well as for the
shape of the viscosity curve. The structures with 2 rings
of naphthalene dr decalin in one carbon atom show the
highest values oi viscosity. The viscosity decreases with
a greater distance between these rings, and the curve of the
temperature viscosity becomes less steep (Table 3). The
complicated hybrid structures with rings of naphthalene or
decalin or of cyclohexane- or benzene rings at the same
time, have been studied least and are of special interest.
If a cyclohexyl ring is brought into the molecule containing
already a ring of naphthalene or decalin, the viscosity increa-
ses much more than if a benzene ring is added (Table 4). The
shape of the curve mentioned is also increased. There are
2 figures, 4 tables, and 3 references, 1 of which is Soviet.
Card 3/4

SOV/20-1 26-4-30/62
Viscosity-temperature Properties of High-molecular Hydrocarbons of a
Mixed Structure
ASSOCIATION: Institut geologii i razrabotki -oryuchikh iskopayemykh
Akademii nauk SSSR
(Institute of Geolcgy and Mineral Niels of the Academy of
Sciences, USSR)
PRESENTED: January 13, 1959, by A. A. Balandin, Academician
SUBMITTED: January 8, 1959
Card 4/4

5 (3)
AUTHORS:
TITLE.
Sergiyenko, S. R.1 Perchenko, V. N. SOV/20-128-1--)7/58
Hydrogenolysis of Organic Sulfur Compounds as Dependent on
Their Structure
PERIODICAL. Doklady Akademii nauk SSSR, 1959, Vol 1259 Nr 1, PP 103-105 (USSR)
ABSTRACT: In the present paper 8 organic sulfur compounds were investigated.
A nickel-tungsten sulfide mixture on aluminum oxide was used as
a catalyst. The temperature range chosen guaranteed a process of
desulfurizing without any secondary or by-p=08S86B. From data
given in table 1 and figure 1 it results that the organic sulfur
compounds investigated may be divided into 3 groups on account of
the rate of sulfar separation during the selective catalytic
hydrogenatica. Dibenzyl sulfide and thiophenol may be classified
among the first group of the most readily reacting compounds.
The second group consists of aromatic and mixed alkyl-aromatic
sulfides. The third group is composed of tetra-substituted
thiophenes (dibenzthiophene and tetrapheny! thiophene). The
latter proved to be absolutely stable under the assumed conditions
(220'-' and 200 atmospheric hydrogen pressure). If the duration of
50%-dew.ilfuzzizatlon of dibenzyl sulfide is put equal to 1, the
Card 1/3 values given in table 2 are obtained for the organic sulfur

Hydrogeaolysis of Organ~le 10julfur Ccinpounds as SOV/20-1 2 8-1-2 71/5 8
Dependent on Their Structu-re
ct--mpounds investigated. These valuea charatterize the relative
rates of desu-Iflaxization. Further, +he amount of axomatic
hydrocarbone whi-jh have to form at the separation of the sulfur
atom from the sulf~ir compound is determined Jm the reaction
products (benzene, toluene,, ethyl benzene). In all. cases
investigated about 90% of the respective hydrocarbonvam determined.
6.7% of meT.-~aptan were determined in the hydrogenation producto
of n-buty! phany). sulfide, whereas with benzthiophene it attained
0.9%o This :icnfirms in the experimental vray that the reaction
of desulfuiig-ation. takes place in 2 stages over the marcaptan
as intermediate product - C6H5 so4H9 -- 0 C66H5SH + C4H10 . Dietbyl
phenyl sulfide and dl-benzyl sulfide were synthesized by S. D.
Pustillnikova. Z. K. Zemskrva and P. V. Ratulikova participated
in the anai-ytic-al part of the work. Mercaptans were determined
by means of potentiometric titration by a method elaborated by
1. A. Rubinshteyn and Z. A. Kleymenova. There are 1 figure,
2 tables, and 7 Soviet references.
Card 2/3

5)(4),50)
,iUTHOFi3: -Sergiyenko, S. R., Kvitkovskiy, L. "I., SOV/20-128-4-37/65
-Y-V_.--_7. -Petrov, Al. A.
TITLE: Adsorption Properties of Highly 'Molecular Hydrocarbons of a
Mixed Structure
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 128, Nr 4,
_3P 769-772 (USSR)
ABSTRACT: (Abstracter's Note: Under "adsorption property" the authors
mean in this case the "ability of being adsorbed"). In the
introduction, the authors refer to the manifold use of adsorp-
tion to surfaces of solids in industry and research work,
particularly to selective adsorption in chromatography. The
adsorbability of various hydrocarbons is best characterized
by their adsorption isothermal. The adsorption capacity of
hydrocarbons of the benzene-kerosene fraction of petroleum
rises in the order: saturated hydrocarbons ~,olefines <
< diolefines < monocyclic aromatic hydrocarbons 4,polycyclic
aromatic hydrocarbons. The order mentioned is, however, not
applicable to the chromatographic investigation of highly
molecular petroleum fractions having complicated molecules
Card 1/3 with a mixed structure, and containing, at the same time,

Adsorption Properties of Highly I'violecular SOV/20-128-4-37/065
Hydrocarbons of a !~!ixed Structure
phenyl-polymethylene- and other rings. Therefore, this paper
is concerned with the study of the influence of individual
structural constituents of such molecules which, in part,
were SDecially synthesized. The adsorption isothermals (Figs
1,2) were statically determined by the contact of the hydro-
carbons dissolved in n-dodecane with silica gel (brand ASK)
or aluminum oxide (quality "for chromatography" of the
Stalinskiy Zavod = Stalino Works) by the method of K. D.
Shcherbakova and A. V. Kiselev (Ref 2). Table 1 indicates
the experimental data. Adsorption increases with the rising
fraction of aromatic and other cyclic carbon atoms in the
total content of carbon atoms. Adsorbability depends on the
ratio between carbon atoms in aromatic rings and carbon atoms
in paraffin chains. The position of aromatic rings within
the molecule and their type are of inferior influence. The
introduction of decaline- or cyclohexane structures into the
molecule, which already contains aromatic rings, raises the
adsorbal,ility. Silica gel adsorbs, a little more selectively
than aluminum oxide, the hydrocarbons containing two aromatic
Card 2/3

Adsorption Properties of Highly Molecular SOV/20-128-4-37/65
Hydrocarbons of a Mixed Structure
rings. The results suggest that a chromatographic separation
of hydrocarbons, with the same molecular weight but different
content of aromatic rings, is well possible. There are
2 figures, 1 table, and 3 Soviet referenceB.
ASSOCIATION: Institut geologii i razrabotki goryuchikh iskopayemykh
Akademii nauk SSSR (Institute of Geology and Mining of
Mineral Fuels of the Academy of Sciences, USSR)
PRESENTED: May 25, 1959, by M. 11. Dubinin, Academician
SUBMITTED: May 23, 1959
Card 3/3

3/710/60/000/001/001/ood
D055/D113
AUTHORS: Sergiyenko, S.R.; Lebedev, Ye.V.; Alikhnovskaya, A.A.
TITLE- The structure of high-molecular oil hydrocarbons
SOURCE: Kiyev. Gosudarstvennyy nauchno-issledovatellskiy i proyektnyy
institut ugollnoy, rudnoy,neftyanoy i gazovoy promyshlennosti.
Nauchnyye zapiski, no. 1, 1960. Dobycha i pererabotka nefti,
13-24
MEXT: An account of the chemical structure of high-molecular oil hydrocar-
I
bons, based on experimental data obtained in the study of 15 oils from dif-
ferent deposits, mainly in the USSR, is given. It was found that oil hydro
carbons which contain 20 and more carbon atoms in the molecule,consist
mainly of hybrid structures. Only paraffinic hydrocarbons are an exception,
'their content rarely reaching 10%. High-molecular hydrocarbons are an imz
Do-.tant Dart of oil (30-50%) and determine its ba:,-ic composition and proper-
ties. 'Elie paraffino-cycloparaffinic hydrocarbons, which are richest in
Card 113

S/71OJ60/000/001/001/004
The structure of D055/D113
hydrogen, as a rule form the basic part (40-60%) of the high-molecular
h7drooarbons; dicyclic-aromatic hydrocarbons are poorest in hydrogen; in
between both as regards hydrogen-saturation and proportion to the other
groups, are the monocyclic-aromatic hydrocarbons. The differences in the
chemistry of oils are seen most clearly in the composition and properties
of paraffino-cycloparaffinic hydrocarbons. In oils of different structure,
50-70 of the carbon atoms in the molecules of high-molecular hydrbearbons
form paraffinic carbon. Liquid-phase dehydrogenization on platinized coal
can be used as a method of selective dehydrogenization of hexamethylene
rings. In high-molecular para'Lfino-cycloparaffinic hydrocarbons of Romash-
kino (Devonian) oil, the ratio of hexa- and penta-methylene rings varies -
-1:1-1-5. Tri-substituted derivatives of benzene (the position of the sab-
stitutes in the benzene ring is 1,3,5- and 1,2,4-) predominate among the
high-molecular monocyclic-aromatic hydrocarbons of Romashkino oil; mono-
substituted and 174-di-substituted benzenes were found in small ouantities,
but no 1,2- and 10-di-substituted samples were found. Sulfur contained in
Card, 213

Ir
PHASE I BOOK EXPLOITATION sov/4726
Klyev. Gosudarstvennyy nauchno-lssledovatells~kiy i proyektnyy in-
stitut ugollnoy rudnoy, neftyanoy i gazovoy promyshlennosti
Nauchnyye zapiski, vyp. 1: Dobycha i pererabotka nefti (Sci-
entific Reports of the State Scientific Research and Project
Institute for the Coal, Mining, Oil, ~nd Gas Industries, No.
1: Extraction and Processing of Petroleum) Kiyev, 1960. 91
p. 1,000 copies printed.
Sponsoring Agencies: UkrSSR Gosudarstvennaya planovaya komissiya
Soveta Ministrov; Gosudarstvennyy nauchno-issledovatellskiy i
proyektnyy institut ugollnoy, rudnoy, neftyanoy, i gazovoy
promyshlennosti "Ukrniiproyekt."
Editorial Council: V. P. Aksenov, S. Ye. Anushin, S. I. Balinskiy,
V. Ya. Volchanskly, D. I. Golltsev, V'. S. Grinshteyn (Resp.
Secretary), B. V. Dzbanovskiy, M. M. Zherbin (Chairman),
A. F. Kotov, M. I. Logvinov, Yu. M. Ostrovskiy, L. M. Orzhekhov-
skaya, G. V. Prisedskiy, V. T. Sklyar'(Deputy Chairman), N. Yu.
Stasiv, and V. V. Tsaritsyn; Resp. Ed. for this Collection:
V. T. Skylar, Candidate of Chemical Sciences; Ed.: A. Novik.
-f,~~5
Scientific Reports (Cont.)
SOV/4726
PURPOSE: This collection of articles Is intended for petroleum
researchers, engineers, and refiners.
COVERAGE: The collection of articles deals with the production
and refining of petroleum. Individual hrticles discuss the
effect of bound water on the depletion of petroleum deposits
under dissolved gas conditions, the effect of pressure on the
viscosity of degasified petroleum,'the structure of high-mole-
cular petroleum hydrocarbons, the asphaltene and tar compo-
nents of Carpathian crudes and menilite shale asphalts, and the
aliphatic composition of alcohols produced by selective hydro-
genation of the CO and H2 product of synthesis. Other nrticles
describe the carbamide dewaxing method for filtrates of wax dis-
tillates, the production of flotation agents with the use of
oxidized petrolatum, and the investigation of six-membered aro-
matic and naphthenic hydrocarbons by means of infrared absorption
spectra. The remaining articles are pn the relations of pressure-
volume-temperature-ethylene and on the phase equilibrium in
ethylene-n-hexane, ethylene-cyclohexane, and ethylene-benzene
systems. Specific volumes and compression coefficients at
Card--2/5

Scientific Reports (Cont.)
SOV/4726
pressures up to 150 atm in the 30-1500C temperature range are
given for the n-hexane-ethylene system. No personalities are
mentioned. References accompany most of the articles.
TABLE OF CONTENTS:
PETROLEUM PRODUCTION
Ostrovskiy, Yu. M., and V. A. Kisell. On theEffect of Bound
Water in the Depletion Process of a Petroleum Deposit Under Dis-
solved Gas Conditions 3
Maradov, A. A. Effect of Pressure on the Visc.osity of De-
gasified Petroleum 8
PETROLEUM REFINING
,2-ergiyp~pko, S. R, Ye. V. Lebedev, and A. A. Mikhnovskaya. On
the Structure of High Molecular Hydrocarbons of Petroleum 13
ta-a*4~,-,374 - 5

S/165/60/000/002/001/008
MOVA129
AUTHORS: ~,S 1L., Krasavchenko, M.I., Delone, 1.0., and
Rutman, L.I.
TITLE: The effect of the separation depth of distillate fractions
on the composition and properties of hydrocarbons of heavy
residues
PERIODICAL: Akademiya nauk Turkmenskoy SSR. Izvestiya. Seriya fiziko-
tekhnicheskikh, khimicheskikh i geologicheskikh nauk, no.2,
196o, 13-20
TEXT: This' article is a continuation of two articles published in
the periodical Trudy Instituta nefti, 1958, v01. 12, no. 175 and 187 (Refs.
I and 2) and describes investi.-ation,s into changes of the composition of
oil products at varying processing stages. Products were studied which were
derived from heavy and light Illskiy petroleum; their composition and pro-
perties were described in Refs. 1 and 2. The hydrocarbon portion of the
products was separated by adsorption (Ref. 3, Sergiyenko, S.R., etc: Trudy
Instituta nefti, 1954, iv, 103). The chemical nature of the separated
Card 1/3

S/165/60/000/002/001/008
The effect of the separation depth A104/A129
hydrocarbons and the effect of the separation depth of distillate fractions,
cracking degree and degree of oxidation on them was determined by chromato-
graphic analysis. (Refs. 4 and 5, Sergiyenko, S.R., DAN SSR, 1953, no. I
and Trudy Instituta nefti, 1954, IV, 103). The analysis was carried out in
an adsorption 40x17 cm column filled with 200 ml of activated porous silica
gel; 150 ml of the hexane fraction containing no benzene passed through the
column at 60-BOOC followed by 10 g of test fraction diluted with the same
solvent in the ratio of 1:3. Desorption of hydrocarbons is carried out with
the help of the solvent in the following order: 200 ml hexane fraction, 100
ml benzene, 100 ml dehydrated alcohol-benzene mixture and 100 ml of the same
mixture with non-dehydrated alcohol. The solvent is distilled on a water
bath in nitromen current; filled tubes were brought to constant weight and
the refractive index of the residues was determined. Refractive index lim-
its of different groups were based on information of Ref. 6, Clerc, R.J. and
Kincannon, C,V., Analytical chemistry, and T.P.Wier, Jr., 1950, vol. 22,no.
7. With the raise of cracking depth and the parallel reduction of hydrocar-
bons in the cracking residues the amount of asphaltenes, carbones and car-
boids increased. The transformation process of the hydrocarbon portion in-
Card 2/3

The effect of the separation depth ...
to asphaltene substance is assumed to be as
hydrocarbons - condensed aromatic hydrocarbons
The heavy Illskiy petroleum contains 18-5% of
paraffinic cycloparaffinic hydrocarbons. There
ences: 5 Soviet-bloc and I non-Soviet-bloc.
S/165/60/000/002/001/008
AlOVA129
follows: monocyclic aromatic
- tar-asphaltene substances.
hydrocarbons of which 50% are
are 8 tables and 6 refer-
ASSOCIATION: Institut geologii i razrabotki goryuchikh iskopayemykh Akade-
mii Nauk SSSR (Institute of Geology and Processing of Combus-
tible Minerals of the Academy of Sciences of the USSR) and
Odesskiy neftopererabatyvayushchiy zavod (Odessa Oil Refinery)
SUBMITTED: September 29, 1959
Card 3/3

SERGIYENKO., S.R.; NOZHKINA, I.A.; MAYOROV, L.S.
Character of the sulfur distribution in the high molecular weight
hydrocarbon'fraction of Romashkino crudea., Khim.sera*1 azotorg.soed. sod.
v neft.i nefteprod. 3:173-182 160* (mm li,:6)
1. Institut geologii. i razrabotki goryuchikh iskopayemykh AN SSSR.
(Hydrocarbons) (Sulfur)

SERGI.YENKO, S.R.; PERCHENKO, V.N.; MIKHNOVSKA-YA, A.A.
Effect of the structure of sulfur organic ccppounds on the rate of
the reactions of oxidation and catalytic hydio e*tion. Xhim.sera-
i azotorg.soed.sod.v naft.i, nefteprode 3053-M 160- (MIRA 14.-6)
1. Institut geologii i razrabotki goryuchikh iskopayemykh AN SM.
(Sulfur organic compounds) (O*Wati6r4 (Hydrogenation)

84858
Z 2- 0 S' L-/-L-~ S/062/6o/ooo/ol 0/012/018
BOI 5/Bo64
AUTHORS.- Petrov, Al. A., Sergiyenko, S. R.,,, Tsedilina~ A. L.~,
Sanin, P. I.,--Ifikitskaya, Ye. A.,-and Nechitaylo, N. A.
TITLE. Synthesis and Properties of High-.molecular Hydrocarbons of
Mixed Structures. Information 1. Synthesis of Hydrocarbons
of the Composition C 24
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh
nauk, 1960, No. 10~ PP- 1848 - 1657
TEXT: The authors synthesized several hydrocarbons that-, up to a cer-
tain extent, may serve as models for the hydrocarbons contained in high-
boiling petroleum fractions. The present pape..- reports on the synthesis
and properties of 23 hydrocarbons with mixed stru--tures, containing 24
hydrocarbon atoms per molecule. Compared to a similar investigation car-/
ried out by R. S,,,hiessler et al. (Ref.2), the present studies were made
on a larger scale. The influence of the degree of cyclization of the
hydrocarbon molecules, the effect of the relative position of some
cycles in the paraffin chain of the molecules, and the effect of the
Card l/.3

84858
Synthesis and Properties of High-molecular S/062/60/000/010/01-2/0118
Hydrocarbons of Mixed Structures. B015/BO64
Information 1. Synthesis of Hydrocarbons of the Composition C24
degree of substitution of the aromatic or cycloparaffin rings in the
molecule upon the properties of the whole molecule were investigated
(cf., Scheme of -the structural changes). The hydrocarbons were syn-
thesized by the Grignard reaction. The alcohols were dehydrated in the
vapor phase by means of an aluminum catalyst used (method of the
American Petroleum Institute); this was, however, done in vacuum (3-4 am)X
Purification was carried out by distillation and absorption. The Oondi-
tions of synthesis are-described in detail for !~,!-diphenyl dodecane,
while only a short information is given on the preparation of the re-
maining 22 hydrocarbons. Since a peculiar behavior of 2,4,,6.-trimethyl
chloro benzyl was observed under the preparation conditions of the
Grignard reagent, the characteristics of the reaction between methylated
benzyl halides and magnesium are discussed (Table 1, data on diaryl
ethanes obtained by reacting some substituted benzyl chlorides with
magnesium). Table 2 gives the structural formulas and the most important
properties of the 23 hydrocarbons o~.btained. The anomalies of vissosity'
as a function of the temperature of the polymethyl--substi-.uted benzene'
derivati7es are remarkable, .",,e., the aromatic hydrocarbons having
Card 2/3

84858
Synthesis and Properties of High-molecular S/06 6o/000/010/012/018
Hydrocarbons of Mixed Structures. B015YB064
Information 1. Synthesis of Hydrocarbons of the Composition C 24
several methyl groups on the ring have a much higher viscosity than the
monosubstituted isomers. In the near future, the authors will publish
a paper on the physico-chemical properties of the hydrocarbons described
here (data on various spectra). There are.2 tables and 10 references:
5 Soviet, 3 us, 1 German., and 1 British.
ASSOCIATION: Institut.geologii i razrabotki goryuchikh Iskopayemykh
Akademii nauk SSSR,(Inatitute-of Geology and Prospecting
of Mineral Fuels of the Academy of Sciences USSR)
SUBMITTED. , May 6, 1959
Card 3/3

SERGHIENKO, S.R. [Sergly~q~__~ R.1- NOJKINA, I.A. CNozhkina, I.A.1;
--I- -- -WOROVO LO.T.- LMayorov, 'E.S.1-
Separation of macromolecular compounds of petroleum by the combined
method of molecular distillation and chromatography. Analele
chimie 15 no.4:127-135 O-D 160. (EEAI 10:3)
(Macromblecular compounds) (Petroleum)
(Hydrocarbons) (Distillation) (Chromatography)

-SF,RGIYENKO, S.R.,
-------
"Academician Sergei Vasillevich Lebedev; his life and scientific
activities" by S.R. Sergienko. Nauka i zhiznl 27 no. 4:76
Ap 160. OKIRA 14:5)
(Lebedev., Sergei Vasillevich, 1874-1934)

S/080/60/033/04/29/045
AUTFORS, Sanin, P.I., Petrov, Al.A., Sergiyenko, S.R., Nikitskaya, Ye.A.
TITLE% The Viscosity Properties of Some Cyclic Hydrocarbons of the Composition
C . k- I
24
FD'U'jDII'_4L-, Zhurnal prikladnoy khImii, 1960, Vol 33, Nr 4, pp 919 - 930
TF-K-1: The viscosity Properties of 22 hydrocarbons of the composition C24.were
studiled within tt,,e temperature range from 150 to -400C. The results are shown in 2
-~Wbles. The study of viscosity properties of bicyclic and tricyclic hydrocarbons of
the composition C24 containing isolated hexamethylene and benzene rings showed that the
transit-ion from an aliphatic hydrocarbon not containing cycles to mono-, di- and tri-
sycliz hydrocarbons (by substitution of the hexyl group by a hexamethylene or benzene
ring) is accompanied by an increase in the viscosity and a deterioration of the temperature
dependence of the viscosity. Bicyclic aromatic hydrocarbons containing methylated benzene
rings are distinguished by a considerably higher viscosity than the corresponding hydro-
oarbons with non-methylated benzene rings. Naphthene hydrocarbons formed during hydro-
genation of aromatic hydrocarbons, which do not contain alkyl groups in the benzene ring,
have a higher viscosity and a correspondingly weaker temperature dependence than the
Card 1/2

S/080/60/033/04/29/045
The Vis.3osity Properties of Some Cyclic Hydrocarbons of the Composition C24
initial aromatic hydrocarbons. The opposite is observed in the case of hydrogenation
of aromatic hydrocarbons containing methylated benzene rings. In this case hydrogenation
leads to a decrease of viscosity, which is especially considerable for hydrocarbons withV
disubstituted rings; the temperature dependence of viscosity improves correspondingly.
The phenomenon observed, which was noted earlier for condensed polycyclic aromatic hydro-
carbons, should be allowed for in the investigation of higher aromatic petroleum fractions
by the hydrogenation method.
T'here are: 3 graphs, 3 tables and 20 references, 9 of which are Soviet, 5 English, 3
American and 3 German
ASSOCIATION. Institut neftekhimicheskogo sinteza AN SSSR i Institut geologii i razrabotki
gory-achikh iskopayemykh AN SSSR (Institute of Petrochemical Synthesis of
the AS USSR a-yid Institute of Geology and Development of Mineral Fuels of
the AS U33R)
SUIEMI=. October 3, 1959
'lard 2/2

~OV120-13c-2-205169
AUT110iij: S---nin, F, I~ , Petrci , A! A, , St~r~;iyenko, S~, R. , Academician
AS Turkm S37R, Nikits,:aya, Ye. A.
TITLE; Visccsit il roperties of kikyl-arv-.,~-Ltlic -H.-dr,~-carbc.-is and
Th, e i r 1: v d r c. - e n -- t e d A 1-1 a 1s
PLRIODICAL: Do~-lady Akademii nauk SSSR, 1060, Vol 1 '-0, Nr 2, DD 278 - 340
ABST.-IACT: An investi;Tatiun of U16 Viscosity of aromatic hydrocarbons
co:,taining isolated benzene rin,~s. and their hydroi-enated
arialo~~s, showed (Table I ) that the charioe in viscosity on
h~fdrogenation considerably depends or- the structure of the
hydrocarbons- HydroZenation of certain structures reduces
the viscosity extraordinarily. The arom,&tic hydrocarbons
(C ) investi-at2d here may be divided into 2 groups:
24 C,
without substituents on the ri-e (Table 1, Nrs 1-5); 2) with
met-hyl groups on tle rine, (Nrs 6-6). flydro,,enaticn (;Dr tra-is-
formation of aromatic into naDhtliene liydrocaarbotis. resFecti-
vely) of the hydrocarb---ns of the 1st ~7roup increases the
Card 1/3 viscosity, arid causes a higher viscosity increase with de-

1,_-O;~erties of A!Kyl-aromat_~ c ff~-drocarbuns aad SOV120-1 -2-2611
T~.eir H-dro-enattad Analo:-s
creasing te::~i~eratura- According to the data obt-ained by
the authors, this '11-Incwn phenomenoa also app-lies to polycyclic
arom,atic hydrocarbons -mith isolated benzene rin.-s (-,-iith-
out alkyl groups as substituents on the ri:16), Hydro:-cna-
tiQr,, of' bicyclic aromatic hydrocafbons with :Let;.Yl groups
on the bfmzt~i,e (i~ra 6-8) produced naphthene hydrocarbons
witl, cuasiderably lower visccoity thai that of their initial
substances, The viscosity decreused wk:,re ir. the hydrocarboas
with 2 methy! groul.s on the rinE. This dependence is con-
tr,.Lry to that observed in hydrocarb,)ns without 3ubstituents
on the ring.. T,-ble 2 shows comparative d--t-- ef the viscosity
for both types of hydrocarbons~ The above phenomenon is of
ge:.eral importance to the deperidence of visc,_,sity of hydro-
carbons on their structure. It also renders possible a new
interpretation of some results of hydroSenation of aaro!catic
petraieum fractions. Thus, tht: v-scosity of synthetic poly-
cyclic aromatic hydrocarbons consiii-ting of condensed benzene
rings is reduced by hjdrogenaticn while the viscosity index
rises. The contrary applies to kVdrogenation of aroml-tic
Card 213 hydrocarbons containing ijulated bnnzene rinCs (Refs 1,2),

Viscosity P-roperties of Alk~-1-ar!_,Liatis Hydrocabons and SOV12C-130.2-26169
Their Hydrogenated An-%loga
The data obtained by the authors make it possible to assert
that the viscosity on hydrogenation of the higher-boiling
petroleum fractions may also be reduced by the presence of
polycyclic aromatic hydrocarbons with isolated benzene rings
containing alkyl- kaiethyl--) groups on the rinS, The cause il
of the viscosity change of some types of aromatic hydrocarbons
on hydrogenation is unknown and must be investizated yeti
U
There are 2 tables and 4 references, 3 of which are Soviet:
AS30CIATION: Institut neftekhi:richeskogo sinteza Akademii nauk SSSR (In-
stitute of Petroleum-cheiiiical Synthesis of the Acader,-y of
Sciences, USSR) Institut geolo--g-'i--'-i---i----r-a--z-r-ab--o--t-ki-g-o-ryuchikh
iskopa,yemykh Akademii nauk OSSR (institute of Geology and
the Working of Combustible Minerals of the X-cademy of Sciences,
USSR)
SUBMITTED: September 22, 1959
Card 3/ 3

SERGIYENKO, Semen Romanov~ch; LE1j;EDhV, Yevgraf Venediktovich; ARTYKOVA, T.V.,
S.C., tekhn. red.
I
z -va;
(Selective catalytic dehydrogenation of high molecular weight
hydrocarbons] lzbirateltnaia kataliticheBkaia degidrogenizatsiia
vysokomolekuliarnykh uglevodorodov. Ashkhabad, Izd-vo Akad.nauk
Turkmenskoi SSR, 1961. 71 p. (MIRA 14:12)
(Hydrocarbons) (Dehydrogenation)

SERGIYENKO, S.R.
Outstanding Soviet scientist Academician N.DZelinskii; on the
one-hundredth anniversary of his birth. Izv.AN Turk.SSR.Ser.fiz.-
tekh., khim.i geol.nauk no.1:3-12 161. (MIRA 14:8)
(Zelinskii, Nikolai Dmitrievich., 1861-1953)

GARBALINSKIY., V.A.; SERGIYENKO, S.R.; ANBROKH, R.V.
Chemical mechanism of the production of oxidized petroleum bitumens
from the cracking residue. Izv.AN Turk.SSR.Ser.fiz.-tekh., khim.i
geol.nauk no.3:33~-39 161. 04IRA 14:7)
1. Institut khimii AN Turkmenskoy SSR i Odesskiy nefteperera-
batyvayLishchiy zavod.
(Bitumen) (OxIdation) (Asphalt)

JL1
S/202/61/000/005/004/004
AOo6/Aioi
AUNIORS: Pustillnikova, S. D.
T-l'I'LE. On the genetic connection In the chemical structure of asphaltenes,
resins, and high-molecular naphthahydrocarbons
PEKODICAL: Akademiya nauk. Turkmenskoy SSR. Izvestlya, Seriya Flziko-
tA4dmichesk_4kh,khimIcheskikh I geologicheskikh nauk, no. 5, 1961,
47-59
TEXT: An investigation was made for the purpose of bringing about the
gradual transition of naphthaneous asphaltenes according to the scheme: asphal-
tenes --->resins ----3;,hydrocarbons. The final purpose of such a transformation was
to obtain pure hydrocarbon molecules where the carbon skeleton of the original
asphaltene molecules had been preserved. To solve this problem the authors used
the reaction of selective catalytic hydrogenation in the presence of a skeleton
nickel catalyzer. The initial material were asphaltenes singled out of Romash-
kino (Devonian) naphtha with 1700 molecular weight and the following elementary
composition: C - 84.04; H 7.96; S - 4.70; 0 - 3.30%. Skeleton nickel was
used as catalyzer and was prepared from Ni-Al nickel alloy (50 : 50). The
Card 1/4

S/P-02/61/OW/005/004/004
On the genetic connection in the chemical ... AOo6/Aiol
hydrogenation pro:ess was conduoted in a rotating 1-liter-capacity watoclave at
150'C; 11~0 atm pressure for 10 hours. The amount of the catalyzer was gradualiy
increased beginning with 150% during hydrogenation within the first 10 hours.
fhe results obtained were analyzed. The composition and properties of hydro-
carbons obtained were compared with corresponding hydrocarbon groups singled
directly out of the same naphtha from which the asphaltenes had been selected.
The following conclusions are made: The paraffin-ey3loparaffin hydrocarbons
obtained by hydrogenation of asphaltenes approach, in their composition and
properties, the group of hlgh-molecular hydrocarbons, singled out directly of
naphtha. Their basic difference is a higher cyclicity (2.1 of ring per molecule
against 1.2) and a small sulfur content (0.23%) corresponding to the presence of
sulfurous compounds in an amount of 2.3%. Complete desulfurization of this
hydrocarbon group will still increase their resemblance with an analogous hydro-
:arbon group contained In naphtha. 2) The group of monocycloaromatic hydro-
carbons obtained by hydrogenation approaches also the composition and properties
of corresponding hydrocarbons singled out of the high-molecular portion of
Romashkino naphtha. The basic difference is a lesser molecular weight of the
former (338 against 400) and a somewhat higher -cotal cyclicity (2.9 against 2.7);
':hIS causes the lower content of aliphatic carbon atoms in the molecule (43
-ard 2/4 11~

s/2o2/61/ooo/bo5/004/bou
On the genetic connection in the chemical ... A006/AI01
against 516) a higher carbon content at an elementary analysis (87.37 against
85.87) and a higher specific weight (d~O = 0.9445 against 0.9184)'. 3) The
bicycloaromatic hydrocarbons obtained from asphaltene hydrogenation have vexty
different compositions and properties than high-molecular bicycloaromatic hydro-
carbons singled out of Romashkino naphtha. The former have a higher molecular
weight (440 against 374) and 5,3 total cyclicity against 3.9 including that- of
aromatic rings (3.0 against 2.3) and cycloparaffin rings (2.3 against 1.6).
Phese basic characteristic features determine all the other properties of bi-
-~ycloaromatic hydrocarbons, as well as their structural group and elementary
composition strongly differing from those of hydrocarbons singled directly out
of naphtha. 4) Among the hydrocarbons produced by hydrogenattion of asphaltenes,
there were 42% polycycloaromatic compounds containing on the average 3.6 benzeng
rings per molecule. From the high-molecular portion of naphtha such compounds
sould not be singled out. There were 71% hydrocarbons and 29% sulf'urous compounds,
when assuming that the molecules of the latter contained one atom of sulfur.
5) The investigation shows that in the asphaltene molecules the polycyclic
systems are the prevailing structural links. in these polycy:-!lIc struct-ures a
great part is played by the multi-nuclear condensed systems containing both
purely carbocyclic (benzene and polymethylene) and heterocyclic rings which
Card 3/4

3/202/61/000/005/004/004
On the genetic connection in the chemical ... AOo6lAlOl
contain sulfur, oxygen and nitrogen atoms. 6) This first experimental transi",lo-n
of naphthaneous asphaltenes to resins and hydrocarbons under conditions of soft
catalytic hydrogenation proves the genetic connection in the chemical structure
of asphaltene.9, resins and high-molecular hydrocarbons of naphtha. The analyses
were carried out with the participation of Z. K. Zemskov and L. V. Ratnilkcv.
1here are 2 figures, 6 tables and 18 references (9 Soviet-bloc and 9 non-Savie-k-
bloc). The reference to the most recent English-language publication reads as
follows: Weller, S., Pepiletz, M. J., and Friedman, S. - Ind. Eng. Chem. v. 43,
no. 7, - 1951, 1972.
SUBMI-TI I'F-D: May 15, 1961
Card 4/4

s/2o 2/6 1/000/006/'003/100 4
AOO6/AlO1
AUTHORS- Sergiyenko, S.R,, Kurbskiy, G.P.
TITLE- The chemical nature of Dzhebol petroleum
PERIODICAL: Akademlya nauk Turkmenskoy SSR, Izvestiya, Seriya fiziko-tekhniches-
kikh,khimicheskikh i geologicheski-kh nauk, no. 6, 1961, 64 - 73
TEXT- The authors investigated petroleum from wells 14 and 26 of the Dzhe-
bol deposit in the Timano-Pechersk province (Komi ASSR), and present information
on their hydrocarbon composition as to fraction, components and groups. The pe-
troleum was distilled in a MAT14M-58a (TsIATIM-58a) device into a series of
fractions up to 500OC' Distillation up to 2000C was performed at atmospheric
pressure and in a vacuum at up to 3500C, and up to 5000C in a direct-heated Xlyay-
zen retort. Residues boiling at over 5000C were separated in large-size chroma-
tographic columns (2,280 mm high, 30 mm in diameter) by two variants: 1) using
as desorbents a series of desaromatized 60 - 800C fractions, their mixture with
benzene and alcohol-benzene; 2) separating the residue into a hydrocarbon por-
tion and then into 3 resin fractions using a smaller column containing 150 g sili-
cdgel. The results obtained show that both these methods yield comparable results
Card 1/2

The chemical nature of Dzhebol petroleum
s/2o2/61/oOO/006/bO,3/004
A0061AI01
concerning the hydrocarbon content and the total content of resinuous substances.
There is however, a marked difference in respect to the distribution of res-in
fractions due to the different polarity of desorbents employed, The second meth-
od should ce preferred. Tne total. balance of the two types of petroleum investi-
gated shc..4s the fc)-1.1owing distribution of components- Petroleum from well no.14;
hydrr,carbcns 96-7, resins 2.9~ asphaltenes 0.4; petroleum from well no. 26-
915.7, 4.01 and 0,3 reSpectively. Detailed date are .contained in a number of
tables, There are 9 taDles and 6 references: 5 Soviet-bloc and 1 non-Soviet
td. c c .
ABBOCIATION.,,, Nef-;yanaya lac,-)rat-criya
upravlenlya (Petrnleum
cal. Administrati-~in)
Ukht-~nskog,_-) terri-~oria!'nogo geologicheskogo
Lar-cratci-y of the Ukhta Territorial Geologi-
SUBMTTMD - SeptAmber 4, 1961-
Card 212

S/202/61/000/006P04/004
A006/A101
AUTHORS: Serglyenko, S.R., Kurbskly, G.P.
TITLE: The nature of the effect of high-temperature distillation on high
molecular petroleum compounds
PERIODICAL. Akademiya nauk Turkmenskoy SSR, Izvestiya, Seriya fiziko-tekhniches-
kikh,khimicheskikh I geologicheskikh nauk, no. 6, 1961, 74 - 87
TEXT: Using petroleum samples from the Nizhne-Omrinskoye deposit, the
authors studied the nature of chemical changes In the high-molecular portion of
the petroleum under the effect of high distillation temperatures. For this pur-
pose the composition and properties of the high-molecular portion were determined
by employing method I when the specimens were subjected to extended heating at
high temperatures (singling-out of fractions boiled away at up to 5000C) and
method II, exbludi-..g heating over 200-2500C. The characteristic properties of
20
the petroleum investigated are: d~o - 0.8284, nD = 1.4695; molecular weight
200; kinematic viscosity at 200C = 6.23 cst, acidity number 0.14; Konradson
coke number 1.2; sulfur content 0.27%. The content of basic components is: oils
60.2%; paraffin 5.5 (melting point 510C), resins 3.1 and asphaltenes 0.2%. The
Card 1/3

S/2o2/61/Wo/O()6/004/004
The nature of the effect ... Aoo6/Aloi
results obtainedere tabulated and show that in the case of light petroleums with
low resin and sulfurous compound content, and major amount in the hydrocarbon por-
tion of paraffin-cycloparaffin-hydrocarbons, vacuum distillation with gradual tem- V/
perature increase up to 5000C, has only a slight effect on the yield and the prop-
erties of the hydrocarbon groups. Its effect is marked, however, on the proper-
ties of resin-asphaltene components, manifested in the process of asphaltene-
formation and changes in the nature of resins, such as age, molecular weight and
the content of heteroatoms. About 99% hydrocarbons are extracted from residues
over 3500C by a 60 - 800 desaromatized-fraction of petroleum ether during chroma-
tographic separation. Therefore it is not expedient to employ mixtures of petro-
leum ether with carbon tetrachloride on ACK(ASK) silic-agel.. The information in-
cludes details on the chemical nature of the Devonian petroleum investigated.
There are 10 tables and 15 references-, 11 Soviet-bloc and 4 non-Soviet bloc. The
reference to the most recent. English language publication readsas follows: 14.
Knotnerus, J., - J, inst. Petrol. .Xii, vol. 42, 396, 1956)
Card 2/3

GORDASH, Yu.T.; SERGIYENKOj, S.R.; SEMYACHKO, R.Ya.; REKUFOVA, B.A.
Chemical nature of the macromolecular hydrocarbon portion of
Mukhanova pptroleum. Dokl. AN BSSR 5 no.3:112-117 Mr 161.
(MIRA 14:3)
1. Institut fiziko-organicheskoy khimii AN BSSR. Predstavleno
adademikom AN BSSR 'B.V. Yerofeyevym.
(Mukhanova region-Petroleum-Analysis)

SERMON., S.R~
New stage of development
Ser, fiz.-tekh... khim. i
of Soviet science. Izv, Ali Turk. SSR,
geol. nauk no-4:3-9 162. (YIDU 14:12)
(Research)
I

SERGIYENKO, S-.R.
The 22d Congress of the CPSU and problems of science. Izv.
AN Turk. SSR. Ser. fiz.-tekh., khim. i geol. nauk no.6,.3-
12 161. (MIRA 15:3)
(Turkmenistan-Research)

SERGIYENKO, S.R.
M.V.Lomonosov and the development of Russian science; on the
250th anniversary of 4is birth. Izv. AN Turk. SSR. Ser. fiz.
-tekh., khim. i geol.,nauk no.6:13-28 161. (MIRA 15:3)
(Lomonosov, Mikhail Vasillevich, 1711-1765)

SERGIYENKO, S.R.; KURBSKIY, G.P.
Composition and properties of natural bitumen of the Voia and
Niamed' deposits. izv.AN Turk.SSR.Ser.fiz.-tekh., khi-m.i geol.rauk
no.1:35-43 162.
Composition and properties of Lemliu petroleum. Ibid.:44-50
(MIRA 16:12)
1. Neftyanaya laboratoriya Ukhtinskogo territoriallnogo
geologicheskogo upravleniya i Institut khimii AN Turkmenskoy SSR.

sov/6146
PHASE I BOOK EXPLOITATION ovich Lebedev
and Yevgraf Venedikt
S6men Rom~nOvjch,
SergjyenkOj ;ellizatisiya vysokoMOlekul-
7a degidrog ydrogenatiOll Of
al'Ytjc Deh
lzbiratel'naya kataliticheska' -tive Cat d Jzd-vO AN TurkSSR1
uglevodorodov (Selec
yarnYkh fdrocarbonB) Ashkhaba',
Hi h-14olecular H1, copies printed-
I
19K. 71 p. 500 .,auk TurkraenskoY SSR.
Sponsoring AgencYj Akademiya V. Artykova; Tech. Ed.: So Go FlutkoVa-
Ed. of Publishing House: To ded for technical personnel in the
': This book is inten, etrochemi drogenation
PTJRpOSF stry.
fields of petroleum and P tive catalytic dehy
ok describes a selec r high-mOle,ular saturated
C GF. conj,11nation with
OVERA , This bo, authors f0 ~d in
process developed by the When us(lyis,- thelprocess
the liquid phase.,
hydrocarbons in Lon and spectral ana e and-the ratio Of
. separatJ structur
chr=atographiO ermine ring
makes it possible to det
Card 1/3
selective Catalytic Dehydrogenation (Cont.) siDv/6146
five-member rings to six-member rings in molecules of high-
molecular petroleum hydrocarbons. The experimental data are
presented in tables. The authors* state that the selective
catalytic dehydrogenation process will eventually be used to
obtain aromatic hydrocarbons from the high-molecular fraction
of crudes. 'No personalities are mentioned. There are 76 ref-
erences: 55 Soviet, 14 German, and 7 French.
TABLE OF CONTENTS:
Introduction
3
Ch. 1. Selective Catalyltic Dehydrogenation of Hexamethylene
Rings in the Vapor Phase 7
Ch. 2. Features of the Chemical Structure of Saturated
High-Molecular Petroleum Hydrocarbons 13
Card 2/3

AUTHORS: S!~~
and Petrova, A.A.
S/202/63/000/001/003/Oo6
E075/E136
Garbalinskiy, V.A., Medvedeval V.D.'s
TITLE. Selective dehydrogenation of paraffinic hydrocarbons
on zinc chromate
PERIODICAL: Akademiya nauk Turkmenskoy SSR. Izvestiya. Seriya
fiziko-tekhnicheskikh, khimicheskikh i geologicheskikh
nauk. no.1, 1963, 30-37
TEXT: In an attempt to produce olefins from hydrocarbons
having more than 2-5 carbon atoms, n-heptane and n-hexadecane were
on ZnCrO4 supported on ZnO. ZnO was used as a
support, since it was previously reported by S.R. Sergiyenko that
it promotes the dehydrogenation of ethylbenzene to styrene and
minimizes cracking reactions. The catalyst was prepared by adding
(NH4)2Cro4 to Zno suspended in the solution of 203 9 ZnC12 in
2 litres H20- For n-heptane the dehydrogenation proceeds most
.satisfactorily at 500 QC and the space velocity of 1.5 h-1. The
~liquid product contains 10~o olefins and no aromatic hydrocarbons.
:Card 1/2

Selective dehydrogenation of ... S/202/63/000/001/003/Oo6
E075/El36
About one quarter of the olefins is constituted by 1-heptene.
The remainder contains 2-heptene and 3-heptene, their cis and
trans forms being in equal quantities. n-hexadecane was
dehydrogenated under the same conditions as n-heptane and gave
2.5 times as much olefins. Cracking in this case amounted to
3 - 8% and the liquid product contained 25 - 27% olefins, two.
thirds of which were C16 lefins.
There are 5 figures and tables.
.ASSOCIATION: Institut khimii (Chemical Institute)
Fiziko-tekhnicheskiy institut AN Turkmenskoy SSR
(Physicotechnical Institute, AS Turkmen. SSR)
SUBMITTED: November 12, 1962
Card 2/2

PERCHENKO,, Vladimir N:Lkolayevich; 5ERGIYENKO, Semen Romanovieh--
ARTYKOVA, T.V., red.izd-v-a-,-7I-V-6RT-IYEVA, G.A.,. ieklh~n~.re
(Selective catalytic hydrogenation of sulfur-organic compounds]
Izbiratellnoe kataliticheskoe gidrirovanie seraorganicheskikh
soedinenii. Ashkhabad, Izd-vo Akad. nauk Turkmenskoi SSR,
1962. 91 p. (MIRA 16:4)
(Sulfur organic compounds) (Hydrogenation) (Catalysis)

KVITKOVSK-U, L. N.; SERGIYENKQ,_~. R., akademik
Sorption by molecular sieves of the type A Dokl, AN SSSR 147
no.6o.1399-1401 D 162. ~MMA 16si)
1. AN Turkmenskoy SSR (for Sargiyenko)o
(Zeolites)

L 1~3 27-n6 EPR/EWP(J)/tFF(0)/tWT(m).,"3M AFFN/
I i
APGC/RPL F s -4 /P c - 4/Pr 44,e Imi -1. RM/BW/WW/JW/,,IWD/H
ACCESSION 77-4 ;T7oo3853 0
S/0020/63/151/003/058T/ 5
Seriziven1to. S. R
AWHOR: ---------- Academic an, AN Turkmen SSR); Kvitkovskiy, L. N.
TITIE: Thermal stability of synthetic C32 hydrocarbons of abybrid structure w
SOURCE: AN SSSR. Doklady*, v. 151, no. 3, 1963, 587-590
TOPIC TAGS: C32 hydrocarbon, hybrid hydrocarbon, aliphatic-aromatic hy drocarbon.,
synthetic hydrocarbon, hydrocarbon thermal stability," Kurnakov pyrameter, endo-
thermic effect, exothermic effect, cracking, polymerization, condensation, satL-
q rated hydrocarbon, unsaturated hydrocarbon, al*Lminosilicate catalyst, hybrid
hydrocarbon synthesis, aoclecene, 1-1-dinaphthyl-l-docosane, alpha-naphthyldocosenel
differential thermal analysis 4
ABSTRACT: A number of synthetic "hybrid".c hydrocarbons vith a3iphati -i
aromatic (benzene, naphthalene, tetralin-,:decalln, Tycl:o exane) radicals7las
part of their structure haye been synthesized. The effect of such a strilcture,
which is similar to that of hydrocarbons occurring in high-boiling fractions of
pe-r,roleum, on thermal stabilityllwas studied (by differential thermal analysis]
with a KurnaLkov pyrometer. A [DI!A] curve of saturated. C.2 hydrocarbons is
Card

L 13327-0
ACCESSION NR: AP3003853
shown in Fig. 1 of the Enclosure. Section OA of the curve, corresponding to
the lowest temperature range investigated, is characterized,by the absence of
endo- or exothermic effects. Section AB(corresponling to 385-400C)indicates the
course of endothermal cracking, a section BC (corresponding to 405-470C), the
course of exothermic po rizatioAnd condensation of the radicals and reactive--,
unsaturated molecules formed during the cracking. The section of the curve to
the right of point C characterizes simultaneous cracking and condensation. Study
of the thermal stability of unsaturated C32 hydrocarbons showed that the presence
of a double bond in the molecule reverses the sequence of the endo- and exothermic
processes, as shown in the thermogram of 1-1-dinaphthyl-l-dodecenel(Fig. 2).
Gbservation of this reversal can serve as an indication of the presence of olefins
in hydrocarbon mixtures. The sequence of endo- and exothermic processes in
.saturated C hydrocarbons is reversed by the presence of an aluminosilicate
at twas shown, that at 220-245C the catalyst produces an exothermal
alySt. 12
c
effect in 11-ot-naphthyldocosane which is probably caused by chemosorption. Crig.
art. has: 3 figures and 1 table.
ASSOCIATION: institut khimii Akademii nauk Turkmen SSR (Institute of Chemistry-
.Academy of Sciences Turkmen SSR)
SUBMITTED.- 01hi_ai-63 DATE ACQ.? 15Aug63 IENCL: 022
SUB CODF,.* CH NO W SOV: 009 OTHER: (100
Card

prof., dro; GARBALINSKIY, V.A., dipl. ing., cand. sci.
Ghemistry of the process of obtaining oxidized petroleum bitumens.
Acts. chimica Hung 37 no.2:213-225 163.
1. Akademiya nauk'VtrrRft6wkoy SSR., Ashkhabad.

SEHGF--TT'KO,. S.H., akadernik, red.; SHNEYER, M.S., red.izd-va;
IVOI'TIYEVIC-, G.A., tekhr.. red.
[PetrocherUsti-j] Neftekhimiia. Ashkhabad, Izd-vo Al,
Turkr..S,9R, 1963. 340 P. (MIRA 16:1-2)
1. Akaderiiya nauk Turkmenskoy SSR (for Sergiyenko).
(Soviet Centi-pa Asia-Petroleum chemicals)

MURADOVA, G.A.; SERGIYENKO, S.R.; KOIY)TKIY, A.G.
Spectral characteristics of high molecular weight of hydro-
carbons of Aligul'skava oil. Izv. All Turk.SSR. Ser. fiz.-tekh.,
khim. i geol. nauk no.2:16-23 '63. (MIRA 17:8)
1. Fiziko-tekhn-icheskiy institut AN Turkmenskoy SSR i Institut
khimii AN Turkmenskoy SSR.

SERGIYEJ?.()l
l,",9 UL'- i,' h-2
of we;7 !.-.~:-n p, troleurris ec
c iem-'. -,r-. t,..; itia te r a 1. Izv. AN luarl-~.3z'E. Ser. f.!-,,.-tA--kh., khim. d
".v.-k- Y'0-2:30-3-~ (Ml.lA 17:,~)
f;FR.

PHASE I 1300K EXPL01TATION SOV/6491
Perchenko, Vladimir Nikolayevich, and Semen Romanovich Sergiyenko
---------------
lzbiratellnoye kataliticheekoye gidrirovaniye seraorganicheskikh
soyedineniy (Selective Catalytic Hydrogenation of Sulfur Organic
Compounds) Ashkhabad, 1962, 91 P. 700 copies printed.
Sponnoring Agency: Akadetniya nauk Turkmenskoy SSSR.
Ed. of Publishing House: T. V. Artykova; Tech. Ed.: 0. A.
Ivontlyeva.
PURPOSE: The book is intended for the study of selective catalytic
hydrogenation of waste and side products of processed petroleum.
COVERAGE: This book is a study of properties, reactions, and chemi
cal structure of waste and Bide products of catalytic and therma
processing of petroleum, These sulfur-aontaining organic com-
pounds are considered as hidden reserves in the exploitation of
Card 1/4

Selective Catalytic Hydrogenation (Cone.) sov/6491
various cbtsdnable commercial product3, as a means of increasing
raw material utilization, and as a means of effecting an im-
provement in petroleum processing, Also the optimal conditions
for the differentiation of sulfur organic compounds with various
structures are s-tudied by the use of selective catalytic hydro-
genation reactioni. There are 16u references, mostly Soviet.
TABLE OF CONTENTS:
Introduction
3
Ch. I. Selective Hydrogenation of Unsaturated
Hydrocarbons 6
Card 2/4

SERGIYENKO, S.R.; M01SEYKOV, S.F.; KOZLOV, M.I.; LOOKIPANINE, G.A.
Prospects of the development of the petroleum refining and
petrochemical industriesin Turkmenistan. I%v.AN Turk.SSR.Ser.
fiz.-tekh., khim.i geol.nauk no.3:3-12 163. (MIRA 17:3)

SERGIYENKO, S.R.; GARBALINSKIY, V.A.
Chemical characteristics of saturated high molecular hydrocarbons
of Aligul petroleum. Izv.AN Turk.SSR.Ser.fiz.-tekh., khim.i
geol.nauk no.3:45-52 163. (MIRA 17:3)
1. Institut, khimii PN Turkmenskoy SSR.

MURADOVA, G.A.; SERGIYENKO, S.R.; KOROTKIY, A.G.
Spectral characteristics of the products of catalytic dehydrogenation
of saturated high molecular hydrocarbons of Aligul petroleum. Izv.
AN Turk.SSR.Ser.fiz.-tekh., khim.i geol.nauk no.3932-39 163.
(MIRA 17:3)
1. Fiziko-tekhnicheskiy institut AN Turkmenskoy SSR i Institut khimil
AN Turkmenskoy SSR.

SERGIYENKO, S.R.; TAIMOVA, B.A.; GARBALINSKIY, V.A.
Potential possibilities of high molecular hydrocarbons of Aligul
petroleum. Izv.AN Turk.SSR.Ser.fiz.-tekh.p kh--m.i geol.nauk
no.3:40-44 t63. (MIRA 17:3)
1. Iristitut, khimii All Turkmenskoy SSR.

Semen Ramanovich; BA1311.511KINA, S.I., ved. red.
[iligh-molecular petur-oleum compounds) VyaokorrolPk-uliar-qje
soedi-r-eniia nefti. 2. perer. i dop. i--d. l4oskva, Khimiia,
!()64. 540 P. (MIRA 17:8)

L~MGIYENKC, PAi-,10(.1HEV,
ChemisT~r-j as a decisive factor in increasing the productivity
o,- agriculture. Izv. AN Turk. SSR. Ser. biol. nauk no.1:3-8 164.
(mlw- 17:9)

S.EFoOJ!T-IT*rl-)) 'L.',DVED.E',VA, 'V.D.,- GARBALUISKlY, 7.A.
Seler-',Ive actlorl (,,' cataly--fs in the dehydrogenation of para-f-
~k. SSR. Spr. fiz.-tekh., khim i
fin. hyd:-ocarbons. Izv. -411 Turl
.g e o I . r. aul, P. o . 3 -.2 5-3 0 1 U (MkIRA 18:1)
1. ln-*~Itut i L%' 'EV.-k-menskoy SSR.

:31j--,F%GiTI.J'Y('l, ,
Scittntif ic and tec~--nollc~gllc%i in d0rlng-
trIG -,ast , yea-~s. All '71"rk SSR. f.lz.-Lek-h-, khlr-
40
( ~ ', -ip;i 2 ~
1k 1o4. . t
.L, geol. nau nc -5: 3-1i

-9MGIXENY,Ok GARIIALINaIY, V.A.~ PEMOVA, A,A.; CHIROVA, Ye.V.; MURADOVA,
G. A.
Composition and properties of hydrocarbons from condensates of the
Islim deposit. Izv. A' Turk. SSR. Ser. fiz.-tekh., khim. i geol.
nauk no.1:37-47 165. (MIRA 18:7)
1. Institut khimii AN Turkmenskoy SSR.

ACCESS1014 NR: AP5008890
AUTHOR: Sergiyenko, S. R.,; Garbalinskiy, V. A*; Chelpanova, lk.~ F.; Gukasova, Ri G
-TITLE: Chemical nature of undersea petroleum of the Cheleken deposit
SOURCE: AN TurkmSSR. Izvestiya. Seriya fiziko-tekhnicheskikh, kh,imicheskikh L.
geologicheskikh nauk, no. 1, 1965, 48-53
TOPIC T&GS: offshore oil, undersea petroleum, petroleum-composition, Cheleken
petroleum, selective dehydrogenation
ABSTRACT: Low-tar high-paraffin petroleum from an offshore wel 1 located west of
the Cheleken peninsula in Turkmenistan was investigated. Selective liquid-,
phase dehydrogenation of the high-molecular hydrocarbons followed by chromato-
graphic separation and spectroscopic anallysis enabled the authors to explore
the hybrid structure of these hydrocarb0is and-to determine the relative propor-
tion of the hexa- and pentamethylene rinigs present. The content of the aromatic..
hydrocarbons in the benzine fractions rsiaged from 7 to 20%, and in the kerosene
fractions, from 30 to 33%. In the lattei,'the content of normal paraffins via,
about 257., and in the higher boiling fractions., 30 to 35%. The saturated
(paraffin and paraffin-cycloparaffin) hydrocarbons comprised from 61 to 86% of
Carci 1/2

VCV? y URI-
V.
t.llcn and ~ropertiert of ozncerite in the ~hehkerl deponnits.
lzir. AN Turk.S-E?-.Ser..fiz.-tekh., kbim. i geol.nauk no.r:25-31
1
165- (MIRA 18-.1-1)
1. in.9titut khimii AN T-Lirkmenshoy SISR. Submitted June 30, 2965.

Ai],LFANOVA, N.P.; V.A.; F'V ', . -k ..; .
'~i+~;IYENKOf ~, I I.
Chem-ical na-,urs- o,- Lhe high molecular part o' -,he sea petroleum
of the Cheleken f '41:1dLi. Izv. MI T,,irk. SSR. Stir. fiz.-tekh. khim.
i geal. nauk no.3:33-43 165. (MIRA 18:12)
1. Institut Ainilil AN Turknenskoy S3R. Submitted Dec. 14, 1964.

ACC NRi
for engineers of the petroleum conversion and petroleum chemical industry; and
can be of interest for students of petroleum higher educational institutions.
TABLE OF CONTEMS (abridged):
Forwm-d --3
Introduction --5
Bibliography --10
Part Okie
Composition, Properties and Reactions of High-Molecular Hydrocarbons of Petroleum
Ch. I. Peculiarities of the cwTosition and properties of high-molecular compounds
of petroleum --11
Ch. II. Paraffinic hydrocarbons --24
Ch. 11I. Hydrocarbons of the hybrid or mixed structure --114
Ch. IV. Higher-molecular aromatic hydrocarbons of petroleum -258
Part Two
Composition, Properties and Ileactions of 1ligh-molecular Reteragenous Compounds
of Petroleum
Ch. V. Carbonic acids of petroleum (petroleum acids) --304
Ch. VI. Sulfur- and nitrogen compounds of petrolem --329
Ch. VIL Petroleum asphalts -493
Conclusion --536
BiblioGraphy --539
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