SCIENTIFIC ABSTRACT SEMENCHENKO. I.V. - SEMENCHENKO, V.K.
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CIA-RDP86-00513R001547810002-3
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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VORONKOVA, N.M.; NELESHKO, K.Ye.; SEMENCHENKO, I.V.; SNMINq A.V.;
SHIESHKINA, T.A.
Use of the spectrovisor in studying the spectral-brightness of
landscape elements. Geod. i karta' no.,12:20-2.5 D 160.
(MIRA 14:1)
(Spectrophotometry) (Aerial photogrammetry)
3/169/62/000/004/046/103
D228/D302.1
AUTHORS: 'Semenchenko, I. V. and.8nytkin,.A. V.
TITLE. Investigation-of the sea.'s spectral brightness from an
aircraft
L
PERIODICAL: Re'era'tivnyy zhurnal, deofizika, n6. 4,2962, 15716
abstract 4V72 Okeanologi-ya, 1, no. 5, 1961, 856-859~
T-EXT: The experimental results of resea-rch into the sea's spectral
brightness, obtained when operating from the air, are stated. A
summer spectrovi3or, developed at the Laboratoriya aerometodov AN
SSSR (Aeromethods Laboratory, Academy of Sciences, USSR) was emp-
loy-ed for the measurements.'Th6 results are presented as curves of
the spectral -brightness,coefficient -- determined in overcast and
clear weather, and also at.different angles between the observation,
direction and the vertical. Thelexamination of the curves shows thct
in the presence of cloud the sky radiation, reflected from the wa-
Uer, substantially influences the sea's brightness. The sea's
-brightness varies with the change in the angle between the direc.
Card 112.
3/16 62/000/004/046/103
Investigation of the D228YD302
tion of observation and the vertical.- The sea brightness-coeffi-
cients, measured with a summer spectrovisor from an aircraft and
with a ~N-~6(FM-46) hydrophotometer from a boat in the same sea
areas, are compared. The comparison shows that the results, obtained
in the aircraft measurements, much surpass those of the boat mea-
surements. This is due to the presence in the sea-water's surface
layer of a large amount of air bubbles which bring about further
diffuse scattering, As a result the authors give preference to the
measurement of the spectral brightness from an aircraft (despite
the smaller precision of the method as compared with boat measLxe-
ments), since the aerial method allows values to be obtained for
the sea brightness coefficient over a large area of the sea in a
very short period of time. Abstracter's note; Complete trans-
lation.-7,
Card 2/2
ZDANOVICH, V.G., doktor tekhh. nauk, prof.; RA34M, X.S., kand. tekhn.
nauk, st. nauchnyy sotr.; SHARIKOV, Yu.D., kand. tekhn. nauk,
st. neizchnyy sotr.; YANIJTSH,-P,'A,, kand. tekhn. nw, , st.
nauchnyy sotr.; CHERKASOV, I.A., kand. tekhn.nauk; ALEKSEYKV-
SHEMYAKINI V.P., nauchnyy sotr.; KOLITSOV, V.V., nauchnyy wtr.;
KOSHECHKIN, B.I., nauchnyy sotr.; $EMENCHENKO,_I.V., nauchnyy
sotr.; UGLEV, Yu.V., nauchnyy sotr.; KUZINA, A.M., starshiy
laborant; KUDRITSKIY, D.M., kand. tekhn. nauk, dots., retsenzent;
VEYNBERG, V.B., doktor tekhn. nauk, retsenzent; LOSHCHILOV, V.S.,
kand.geogr. nauk, retsenzent; REKHTZAHER, G.R., kand. tekhn,nau3c,
dots.,, retsenzent; KOZLYANINOV, M.11., kand. geogr. nauk,
retsenzent BUSHUYEV, A.V., inzh., retsenzent, ZAMARAYEVA, R.A.,
tekhn. red.
(Use of airborne methods to study -the sea] Primenenie aerometodov
dlia issledovaniia moria. Pod obshchei red. V.G.ZdAnovicha. Mo-
skva, Izd-vo Akad.- nauk SSSR, 1963. 546 p. (MMA i6:4)
1. Akademiya nauk SSSR. Laboratoriya aerometodo,~. 2. Laboratoriya
aerometodov Akademii nauk SSSR (for Zdanovich, Ramm, Sharikov,
f,
Yanutsh, Cherkasoy.,' Alekseyev-Shemyakin, Kolltsov, Koshechkin.,
Sqmenchenko, Uglev, Kuzina).
(Aeronautics in oceanography) (Aerial photogrammetry)
SEMENCHEINKO., M.
______R_egi-ona-economic council and technical schools. Prof.-tekh.
obr. 19 no.12:7 D f62. (MMA 16:2)
1. Nachallnik otdela kadrov i uchebnykh zavedeniy Irkatskpgo
sovets. narodnogo khozyaystva.
(Irkutsk Province--Vocational education)
RE . t-n'~
TARASOY, N.M., inzhener; HVIIQ9I=6.A4,,,IAnzhoner.
The affect of grain size in 2OIhW steel on the deformation and
strength of automobile gears subjected to heat treatment. Metalloved.
i ebr.met.no.1;53-56 Jl 155. (HLRA 9:7)
i.Gorikovskiy avtomobil!nyy zavod imeni Holoteva.
(Stool, Automobile--ffeat treatment) (Automobiles--Transmission devices)
61:9
AUTHORS: Tarasov, A.M., Ing. and Semenchenko, M.R. Ing.
-
-
-
-_
-
'-
Mol
o
Yo
imeni
(Gorky Automobile Works
V. M.
v).
TITLE: Influence of the content of BaCO
in the carburiser
3
on the quality of the carburised layer. (Vliyaniye
soderzhaniya uglekislogo bariya v karbyurizatore
na kachestvo tsementovannogo sloya).
PERIODICAL: "Metallovedenie i Obrabotka Metallov" (Metallurgy and
Metal Treatment), 1957, No.5, pp.49-53 (U.S.S.R.)
ABSTRACT: In the Gorky Automobile Works the carburising mixture
consists of 25% fresh and 75% used carburisation
material whereby the fresh carburising material
contains 60 to 700% peat semi-coke, 20-25% BaC0_,
0.5-1.5% SiO and up to 0.1% S. *Data
3.5-5% CaCO
,
collected over two years showed tliat the BaCO content
in the carburiser varies between 3 and 11% ana for the
most frequently occurring contents, between 5 and 7%,
the carbon content on the surfaces of the carburised
components usually varies between 1.5 to 2.5816,
although the optimum would be between 0.8 and 1.0%.
The work described in this paper aimed at determining
the optimum content of BaCO
in the carburisation
3
mixture which would ensure obtaining a carburised
layer with a carbon content near to that of eutectoidal
saturation. The compositions of the investigated
Card I/-
Influence of the content of BaOO3 in the carburiser--
on the quality of the carburised layer. (Cont.)
steels are given in Table 1, p.50, the carburisation
regime and the depths of the carburisation layer in a
mixture with various additions of the fresh carburiser
are enumerated in Table 2, p.50. The dependence of
the carburisation depths on the BaCO content is
plotted in Fig.2, whilst the distribLion of the carbon
in the carburised layer for various percentages of the
content of freshcarburiser is plotted in Fig-3, whilst
Fig.4 shows the carbon content in the carburised layer
at depths of 0.025, 0.05, 0.1 and 0.3 mm as a function
of the BaCO content in the carburiser for two steels.
It was foQ that changes bet-tieen 0% and 25% of the
fresh carburisation mixture containing 20 to 25% of
BaCO has a negligible influence on the depth of the
carbLised layer. An increase in the content of BaCO3
up to 5% brings about an increase in the depth of
the carburised layer and of the zone with above
eutectoidal carbon content; further increase, beyond 5%,
does not bring about any further increase in the depth
of the carburised layer. It is advisable to reduce the
conlent of BaCO n the carburising mixture to between
1 and 3%. 4 fiau~es, 2 tables; 2 Russian references.
Card 2/2
~qf 61 W4 -04 4 w it I.
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Orb.-
SOV/129-58-9-9/16
AUTHORS: Tarasov, A.M., Candidate of Tec~i-nical Science and
Semenchenko, M. R., Engineer
TITILE: -Tfij'-98~ssDoillity of Increasing the Carburizat !on
Temperature Inside a Solid Carburizer to 980 0C
(Vozmczhnost' povysheniya tempegatury tsementatsii
v tverdom karbyurizatore do 9~O )
PERIODICAL: ~.Jletallovedeniye i Obrabotka Mletallov, 1958, Nr 9,
PP 39-42 (USSR)
ABSTIUCT: The Gorky Automobile Works introduced in 1954 a pgocess
of carburizati8n inside a solid carburizer at 950 C
instead of 010 C. In this paper the possibility is
studied Of applyinE still h-JE~her carburization
temperatures for the purpose of increasing further the
productivity of th e process. In earlier work of the
ut
authors (Ref 1) it was established that in the case of
carburization inside a solid carburizer at an increased
temDerature, the der-ree of carbon saturation of the
periphery of the carburized layer decreases. The
intensive growth of the austenite grain for fine grain
steels (20, 20Khl 20KhGR agd 20KM11) begins in the
Card 1/11. case of heating above 1000 C. Daily inspection of
SOV/129-58-9-9/16
The Possibility of IncreasinG thS Carburization Temperature
Inside a Solid Carburizer to 980 OIJ
manufactured components indicates that as regards
hardness, Uhe depth of the .'ase h,-xdened layer gnd
warping of the components, -_arburiza~ion at 950 C does
-not differ from that effectuad at 910 C. In the
.experiments described in this pa8er the carburization
tetaperature was increased to 980 C. Investigation of
the quality of the carburized layer and deteraination
of tlie*mechanical properties was effected on speciinens
of the steels 20KhGR, 2010abIM, 20Kh and 20 for which the
Cr contents and the size of the austenite grainF,
are entered in Table 1. The investigations were
extended.to components (gear, cam) which were case
hardened to depths of 1, 1.4 and 1.6 mm.. As a
..carburizing agent a mixture of a solid (peat) carburizer
with an addition of 20% fresh carburizing material was
...used; the content of barium carbonate in the working
'mixture was 3.4 to 5.1%. -Particular attention was
devoted'to the deformation %-vhich was verified on the
higbest stres!:~ed ~,nrl'uios iplicated components; theso
t c o i,
Card 2/4 measurements were ecarried 'out under blie uidance of
SOV/129-58-9-9/16
The Possibility of Increasing ths Carburization Temperature
Inside a Solid Carburizer to.980 C
A. A. Shlyapnikov. The results obtained for specimens
which were incorrectly case hardened and for specimens
after'carburlzationl hardening after reheating and
low tbijiDerature te-,.ipering are entered in Table 2 and
these silo,.,,, th.at the strength, toughness, ductility
and surface-hardness of the specimens do not deteriorate
as a r8sult,of increasing the carburization temperature
to 980 C. The results obtained for a cross piece of a
ihotor-car differential and for gear teeth are also
graphed. - The obtained results have shown that
provided a second heatinS prior to hardenIng is applIed,
it is recommended to cagburize components inside a
solid carburizer at 980 0; the quality of -the case
hardened layer as reEards carbon 'content and its
distribution improves and the static strength of the
components does not decrease. Whe productivity of the
process of carburization atu 980 C is 40 to ~00116 higher
Card 3/4 than f or.a carburization te-a-perature of 910 C and
SOV/129-58-9-9/16
The Possibility of Increasing tchS Carburization Temperature
Inside a Solid Carburizer to 980 C
15% higher than for a carburization temperature of 9500C.
There are 4 figures, 2 tables and 2 Sovietreferences.
ASSOCIATIOR: Gor1kovskiy avtomobillnnr zavod
(GorkiyAutomobile Plant)
1. Steel--Hardening 2. GrainS (Metallurgy) --Growth
Card 4/4
-GIC - -u
'~n ~ Ov, c ~
na k; SEI
-S I andt -f-el.-hr - w -Eh ~ 11KC. III R, inzh.; G WnEVA, 7,,!,,
inz -h~
Use of structural steels with small add-iticris of boron at the
U L - L
Gorld ~ iltutomobile Plant, Ifetalloved, -i no.12:
A-21 D ';6h. (I-IDU-. 14-12)
I. Gcr-k-'.Dvski-y avtoraobil'n~y zavod.
(Gorldy-Auto-r-wbile industry)
. (Boron steel)
L 31307-66 ENT(1)/T JK
ACC NRt AP6022585 (A,N) SOURCE CODE:
AUTHOR: -Somenchanko, N (Chief of section)
ORG: Veterinary Section, Karel'skaya ASSR (VeterinarrC7 otdol)
\1
TITIZ: Eradication of,foot-and-mouth disease in the primary focus
SOURCE: Veterinariya, no. 1, 1966, 36-37
TOPIC TAGS: foot and mouth disease, disease control
ABSTMCT: This article is a report on the recent foot-and-mouth disease situation in
the Karel'skaya. ASSR. The author notes that outbreaks in recent years have cozm
mainly from transport of coarse foods. In all cases the disease was eradicated in tht
prinary focie A detailed description is given of the largest outbreak-on the
"Vidlitskiy" Sovkhoz, Olonetskiy Rayon. Party, militia and farm workers cooperateds
It is notable that the many workers with Jobs outside the quarantine zone were re-
assigned to work on sovkhozes during the outbreak. VetDrinary workers were d1vided
into two groups: one in the primary focus and the other in the zone threatened by
the disoaue, The republic has no outbreaks at the present time, but prophylactic
measures are still being strictly carried out.
SUB CODE: 06 SUM DATEt none
SEWCUMMO, N.A.
Thirtieth anniversary of a republic veterinary laboratory, Veteri-
nariia 35 no*6:69-72 Je '58. (MM 11:6)
1. Nachallnik vaterinarnogo otdela Ninisterstva, sellskogo khozyaystva
Karel'Bkoy ASSR.
(KELrelia-Vaterinary laboratories)
S:~MEENCHMNKO, N. 1.
589 Moy opyr rabory na love 1--atipiyskoy kef-M. (sulakskiy rybokolkhoz
"Pamyat' Chapayeva". Lit. zapis' B. M. Petrova i V. S. Gotfrida).
Makhachkala, Dagkaigoizdat, 1954. 43 -3. s ill. 20 sm. (Dagrybakkolkh-
ozsoyuz). 2.000 ekz. Bespl. - (54-5465~ P (639.22 4 639.2.08)
(262.8)
SO: Knizhnaya Letopis, Vol 1, 1955
TUK7Z, F.I.-; SU,-!ENCHENKO; S.A.
Dete=ination of the potentials of zero charEe )n eolid
electrodes from their dispersion rate in the ultrason-fe
field. Elektrokhimiia 1 no.12:1454-1458 D '65.
(MIRA 1921)
1. Novocherkasskly polite kd- niche skiy instltut. Subudtted
Sept.ember 21, 3964.
KUKOZO F.I.; SEMENCHE.NK.O..S.A.
Determination of the potentials of zero charge of solid electrodes
from their vibro-abrasive rate. Elektrokhimiia 2 no.1:74-78 Ja 166.
(MIPA 19:1)
1. Novocherkasskiy politekhnicheskiy institut imeni Sergo OrdzboD-i-
kidze. Submitted December 7, 1964.
SEMENCHNUKO, Va.
Inversion of the uterus due to P80sage of submucosal fibromyoma.
Akush. i gin. 32 no.6:86 N-D 156. (MMA 10:11)
1. lz rayonnogo rodillnogo dome g.I&ibrq (glavnyy vrach - zasluzhenrvy
vrach USSR A.V.Kotlyar)
(UTIMUS-TUMORS)
MURXVIYETA, D.A.; MENCHENKO, V.P.
Saparation and identification of ragweed alkaloids by meanm
of paper electrophoresis. Apt. delo 14 no. 4:21-26 Jl-Aff 165
(MIRA 19tl)
1. Pyatigorskiy farmatsevticheskiy institut. &ibmitted September
15, 1964.
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wcal mirm. of 0.1 and 0,001 N with ratim of curnpi. .0 0
nents 3: 1. 1A anal 1: 3: KLI + A1040i at 1oW cratens. J
O.Wl. 0.01. 0. 1 and 2 0 N In the mune, mtkx of rampa. .00
"Tnts. XCI + Naliter + INISSO, at tow conens. U( OAM .40
O-OM with fall- of -Rawwnts 1. 1. 1 and 1; 1 ~2
~
ta on the doulAr and tril& lnijtt,,, in Una mur
ns
In gfkkl agnvincut with the VIM CtMkC Values CAW
.'"I
the [mL%b W &dditiVity .1 p, C,,d.
W. P
Ecicks
3. .
a coo
z
A 0 go 0
go
-.1 V'21 A~ I a Od 0 a 3 1
AV -0 A U Is It Of 9 Pt Of n 1 .14
0,0
0 a 0 0 0 0 0 a 0 0 0 0 0 0 0 6
: :
0
0 0 0 0 00 00 0 6 0 4 4 0 0 0 0
0 0 0 0 0 0 0 0 0 0 0 0,4
eel. I j A 1 0 1 S 9 w u 11 m Is Is 1 40
'.A &,-c a r FI X I K L m1! 6L-2 11, U" 01F. I M-1
0o A
ONOCIS246 A.* OSCOINVII& -*I-
Saujoity md imfus tmst=- V- K'
3, 710-451).-
TISCH khi KbIm.. 1934. : c icle&
aud th of
u,
Ut
LU
0
OL
00 go ralimed movaents'. u ty and swfwa tension see
DOIS for thO
00 txplalned on.& amrawbads off-(cff,.OH)x-
tM,T)raoH-Nacl- woo-callu.
a =00
00-
00 a
4r
elf
coo
as*
logo
MOR I t
A S aI a AtTALLU116KAL LIMAlUll AIYPXATICII
be*
ire 0
t I told#,) "it a.. M
An L S 0 rAd 0 09 N I N M 0 a it
u AV' 00 LSI; al
Cp at
C K at w Ic a
0 00 00000 0000 010 a 0 0 0 * -
0 : 0 We 0 a 0 * 16 ~00
0 e 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0.0 0 0 0 0 0 0 * 0 * 0 09 :10
.-A
A
M AND PtOPINT
lot, A.C. I. C.01ji:
Joel
L. I'Arovokiy (Kolloidpiii Mumal (Mo J.T"1011.-L MV2115; C
0
0
19M. $0, 7975).-fln Rumian.) Cf Rel. .141., this vol., P. 523. Antawnts
60 wrre obtained of milrer, cadmium. vid sine by direvt m4ulim td mi-tal in
jiwrvum-. of barium by electrolysis of lW
k 411.1 of sodion) and I.-taAmifull I,Y
;
a
distillat itin of vapsur
into ni"vury. ItiLl rm~emrx-pt that til xill"Aluald"m
z the ourkor teamitmi at fint dectr#am with inermaing conoent rat iwt .r nit,(Al att't
then is almopt eonstant. '11m effect of antalgamat"I metal deermsem in the
order 1,otamium. modinto. barium. Wrer. (whuiuna. And is spvttivo for tine,
Values for ivnvvntmliona and wrrmponding surfatv, IA-twitm wrW;
111Vh4kry 411) dYl)Cs:Cto. ; JMA~sitlltl 11 (MM1.4 alont.1%, .192; 4) tR40) mt.,tjW',,.
0 0183 AtOUP"- '.'tk;; kl"VM Mont ...... .1M. 01M.
.3 337; t~nuuj uvt4:.~, 407; 0.22, 358; radinjuill 0-tfillf. 409: I-_12. 4i9;;
egg sjM-r U-0129. 4(M): 0-02W, 406; inc, 04J245. 411 1-315, 4210-S. G,
A.
AS*-SLA AtTALLURCICAL LITFOATLAI CLAIIWbCATW.
11-hia'I ~ I I QW1 u9(
vallit dwi~w ~il
u is tv _4 I r T, _11-4. 5 ftd a it 6 1 W a I T
93 it 17 go K 9 a 1C K ff It it AW 4 1 X0
1100 00 0 00 0 0 0 0 0 0 00 0 * 0 0 0 0 0 0 0 00000 0 0 0 0 0
00: 0 0 0 * 0 * 9 0 0 0 0 0 0 it 0 0 0 0 0-0 a a * 0 0 a 0 0 0 0 0 0
00
*0 40
~00
"0 0
*0 a
nee
Xe 0
SO 0
so 0
400
uo 0
US
0 f 10 It a I' U 11
~ A ?.,I
Bultst P
SCU*4c
00
Yk
bu
the amt. c
buffer con
11,0. L e.,
vent. PH
06 :dded Na'
00 j "d buffer
06 ale. oymm
11, it-O.C
i
00 j
0 W " .
W5 1
0.011 MB
1
0
00 V
D
v The equed
1
109
R
0
.
~ function 01
1
0
O
0 at 0', 20'
z %tandpoint
00
6
'
. results are i
A $ 4 - I L A mETALLURGKAL LITEOATuRE
ID U IS A' 10 ISI; Ip op K K it
0 0 * 0 Ole 0 0 40 9 0 6 0 0
0 0 * 0 *10 0 0 0 0 0 0 0 0
W 1? 4 it I
.~0111
It I _1-- V. ACA A' M' K" If *, 14' T e-' .0 0. '1
~261!81
0
mommena is the lWd of surface tensim. v. K.
o. A. F. Gracheva and E. A. Dsvuklav4m)ra.
U. s. s. R -) t. mr, -831 JW5) .-For both aij.
slycol solm. of iso-AMOH there is a definite
- for which the sm(ace tmilou is Indgpendent of
!mm 0.5 to 2.8 M NOW. This
1=0111 sk. In IPC9 is Pester than in
:00,86
greAter the less the die const. or the A-
1, BuOR and iao-AmOH In the presence of '00
show practically the same "act tvmlotu
Dints. At 0-1*1* the buffcr point 6 at higher zoo
1. c., the althig-out rflect 6 less. A 4.0 M .00
M BuOH sotn. has a const. surface trianion Zoo,
so 0' to 80' and above 4 M NaBr and below
)H the a values increase with increasing temp.
i C - go + . Nrc-I for surface activity as a re 0
mam. h" foe RUOU-N&B-HIO $Olu%.
id 40*. Ile results are explained [nnu the
I the theory of generalized moments. Ile
40 0
Dwn by 6 tables and 20 figures. F. 11. R.
t's 0
~g
L41SIFICATICO WOO
Ar
xx
I K K
0 0 a 9 0 9 6 go 0 'r. Goes 0 o o414104 060 0 0 46 W
a0 a 0 0 a 06 6 0 * 0 00 *1
10 0 0 0 a 0 0 0 0:0 0 0 4
we go 0 so so so 0 0 0 a 0
1
Ou 1 3 4 s 4 Y A # 10 11 U 11 is Is
I I C-A A_j -A I I _L I-* P -9
00 A r
00 A , z
90 V. I
Mom
19&
coo4
0 coin
and
049
* C g
Ic.~
* 0 j f
I
1
Mil
so
00
so A S a S L A of?ALLUP.GICAL LITFR~TURE
n AT It
ti 3 " ; ; of is K it
(I tt at
a 0 0 0 0 0 0 0 0 0 0 0
0 a 0 6 0 0 0 0 0 0 0 * 4, 6 0 0 00 a"
9 a 0
1 9? M Is u a so S is V a x 40
LL it &1 0 is 45:4 0
j i -
cc 901
".08usat . buls,
I a t..
F #cc I its IA-0 ONVOW-91 ..M.
of Mixtum of
V. V. Serpinskil.
liad Chow
1932 2
Pt
2
Th
t
W
C
A
.
.
wra
.
m
onjr.
.
.
pp
00(19M); cf. C. A. 27, 3382; 28, 11W.-Elec. 0 0
ctivities of a series of binary and ternary mists. at
-00
. total coams. but different ratios of the components
t diff t tat Icom's"'. were meastured with the aid of
crest -00
ial device t is described. The data obtained were
r -so
tent with the Debye-Hfickel-Ouzager theory and
.00
rmed tt. adequacy of the method applied. Th~
- i seems to be mitfirmed for the additive
.1. A
(.j th= played by the given electrolyte in the
6 =00
expressed in equivalents, Ai the elec. cond. of the 0
eift-trolyte of a cmicn. corresponding to that of the a
E. H_ Stelanowski, 0
coo
~$SjFjCATjC. IZ
J&Sjl CA C" it
a I I ad 0 x a I IV Of
t
of -t U rt 11
s
, * g i
6 6 0 41 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 0 9
g 4014
00 AP
00 j
00
0 all
0
001
JLL~x ~~!
da g :!j
Prop"U" of
Snumammmo (Act&, Phy6cbdhim.'U.R-8-S-,L 1935;
twnfan of amalpm of
Pb, Sn, Ba, Uj-%k-JE;ftj&w-Wshm.bwn mmasurc&
v the differ.
The influeam d t6 &*ambied b
X16mmu Of odvmt
eum betwwn the
and solute. C.S. ILI!
A $a- SLA METALLURGICAL LITERATURE CLASSIFICATION
slow SIV1031"
tanoma 1113GOO Mir ONT 449
I T
U IS AT v It I I I 1 11 ~ it
0 It a
S 0 0
1
000000*00000
93G.. MONOW
111IL"CH9 511131 OK ON. III
Uarl IRS" v I It IN 9 a 4 2 1 v
144,
0 0 0 0 0 * 0 0 0 * 0 0
00000000000000609
-00
-00
goo
=so
.00
roe
COO
v*0
COO
to
woo
e O"o 0 0 0 a 00 0 0 a
00 1 1 11 m
I-L4 1 4 1 1 4 11 1 -
A a-JL-L--&- k A IL L it PI. I
ilf A.0
so,
so
00
00
00
jtt
S L A *lTAktUft'.KAL LITEN&TU
46 a
ID 0tj S.W., .4
U U A- -0 AS:
P rp IV or K K
0 so 0 4 0
0 0 0 0 0 0
o 0 0 64 *as ago 0,
u it A 16 V 0 Op a 41 40 of a 4
04101QA., .0 *1" -arns
1.441
-04.
I-A. F. Orwhem mW rz. A. DavuidovAays.
Adsl&drjpkw 6 ix" im, No. a mo-a-
~e wilts. the suf?ace temlon within the fimits Q( 0'
'dounatftendupocthecoom.o(Iin oft.1th,,
Lents: therefure itrannot pays as an ludicathus of
"me of ceftald liulatanc," iu tho usist.
R. V. &.~Wwrx
CLASSIFKATION
al.. a" in.
3- Q.L .)Ili, da-ze. its
An A S V Od 0 0 11 1 W 61 9 A 4 2 9 1
X S K U U it x La n I
0 a 0 0 0 c 0 0 z 0 0
* 0 : : 0 : 0 si: : : : : : : : : : : 0 0 0 * 9 6
-00
00
ago
too
as*
see
also
'00
a v - ? t . . . I - fio--_
It f I p N f I ~ I - r I I ; *
A f r t !
A
00 c A
go
00 A
0, 00
00
:0 r
00 Mut"I aduhilifty and nuum tonsim. U. 00
gulp" imam xM ftok nwmmt. V. K_
pso and T. ~ N. IvANuvk (J. Gen. LUtft.
awrface tonsi 00
III at 25* is do
by -Il_rC,O_NII (I Pra W110 jiv), PrCN,
llj~). to L extent which ineroa-
P~Olt suld Rx~lt
00 With ihgv murn. In tho cam of If*0 via ObTlinto
tvinioxion milats botoe n murfavo, activity and dlIK&
limmilso, It; III T1 mW 01) It rimen with Inomaxing 0
t containing N, and falls for tham a**
for vubstanam
containin N. Tbe'v*1 teftp.A mlwlbilitY of
with is It (Wkiid M. In unaffm4ml
Pro by the mmak substanem,
'.6
Ineremme linewly with the mim. 0
Co
The vW. id a at 704-M a HO-([) Ifitufam riam with 0
lurmamlig amtft. 61 Ptcl, (IV, and PrCN, hu& ill
1wrat,timlly unalfoctorA by "ll, and ix lt)wvml by zoo
111) atui (v). It. T.
t:0
1 tie 0
0 A OCTALLUNSKA& LITINATL49 CLAISWKATIO
odt a.. M.
UK 0., too
0 u Ali; a KWO "NIL salvo "plArm
0
IF! j 0 00 0 0 0 a 0 0 a
03 1 1 1 A 1 6 1. 0 $ W 11
A I r.
09
go
00
CAI~
00 r;
00 41
00
go
410 X11
00 13
00
of
0
00 zi
00040000000 0 000
0 0 0 0 4[ :'V_ . . "
9 18
0 00 0 0 0000 0
:1 32. '- 4R. ' 0 * 0 0 0
If
It Is " a a J1 a a v x 20 all 111JU15 littism tv 41 41 &1 is J! 0
C1 __j -4--d 9-1 A 6 j I of
riled by aladmWes. U.
larface I
UN-out and the d1slacirk constasts. V. K.
00 1
IGO
00
g
0e E
A 5 S S L A EIALLUPGKAL LITESITURI
00
00 it,
-j -i--, -r -j,
It ~F M K It
IT
0 11, 10 0 0 4100 0 0 0 & 0
1* 0 0 0 0 0 0 0 0 0 0 0 0 0 0
DavidovskAys. J. PAY#. CAwm-
~ a. S. R.) 61 on the
face ten-4 of wins. of ioummyl &k. In water and In
ylem slycol in the pre- of the elecuolyte NmLHr
W that the safting-ced effect Of the electrolyte decreases
01y with a decrease of the dielve. coast of the solvent.
s t explained on the basis of the seneralized moments -*0
he mob. In both solvents at a %inn collen. of Imanayl
00
the surface tension 6 independent of the cown. of
Br. The surface te"ons for 11r. Bu and Am a". goo
~k"y equal at the buffer pcAut in NaBr mjnm.
D"eadevice of the surface tension an the tempera
o. V. K. Semcnehenka and A. F. Gracheva. ]bid,
roe
U.-In *o1m. of Bu sk. in water end in the presence zoo
'TaDr the salting-out effect of the electrolyte decreases
increase: of temp. At a cown. of 4 M NxSr and for
iota comm. of Bu. Lic. the surface tension is practically
0
st. frorn 0* to W. The equation for surface tension 2 goo
- ft + a N61 Is applicable Irmn 0* to 40* where f9
.8. 254,3 wW 244.M. and a 213.0, 10R.9 and 45.7
1', 20* and 40% resp. F. It. Rathmann
;600
.0 0
O
W
0
:
1_-OO
ASSIFICATICM
000
-r'n
1 11 It tt It Or 1#13 n 1 14 -0 -AT 0-3 -1 goo
0 0 0 0 0 - 0 0 0140 0 0 ai 0 0 0 0 0 0 0 0 40 0 0 0 0 0
-0 0 a 0 0 0 0 0 6~6 0 & * 4 0 0 0 0 0 * o 9 0 0 0 0 v
0 0 0 0 0 a 0 0 0 0 10 0 4 0 AL
0 0 0 0 0 0 0 0 : 0 9 0 0 0 0 * 0 0 0 0 0
Tj 11 f,
A L I .14 D is /I A p
L it j OL L A #I A I" P v 1) U 13 At v As ft v 41 4v I I Ad a
A t h k
o eneous reactions with atomic hydrogen.
Hetero
e g
duction of olides. sulfides and halogen cOOPOu'W' 0
: Kit. S. lldzdw~f'yall And V. K. J. Pby,.
-
0 1 T'"ll ,(
6. Iltr,- MITTIT
S. S. H. ) zoo
the Tettucing action IA at. it I'll Colkituts. of
66 ( - 1, it i,
111111;11~ it) tile -AAM pba-~ Riv"ll aS (+) Or
b
0 y
iss,4A that the f"'ItIcibility or 1111111 M114-ji wilily i~dvtsl.
tile Iseat nrvV1%tTv for di-.11- t~- tile CIC111t,11t, If tile
13,1111. W ellarxe. all Fr,lllts
and tile
so "I'tJ111.11 Iwil,jt tit a
so R"111141atin
%drFARMI1.
00
zoo
00
U
00
two 0
60
00
00
r
--
10 -2A
AO
j 00
If A '1
it L
0 Aj
o
13 n I v& 3 6
0 0 0 a 9
go 0 0 00 00 0 0 0 go 660 0::
Joe
00
to
00 it
got
00
90 a
00 &
00
804
00,3
v x
propffum, 61 am"aw- L Y. K.
BwMliTWWMW TACW Phy*00bbs. U.B.S.8., IM.
4,z` 90"10R.W' thle - ivk.: I 1").4TW surfam
mn" of of Mg Co. Za, Cd, Ag, Ca, Hr,
Pb, So, Be. a. K. Rb, Ni Ov has bwn &tmmind
for Tuious ccmw~ Them is good agmement with
nummts. The effect of
the thmy of vwmup!u~
minute quandtim avimpurm" on-the nwebmical
propwUm of md*k as&Wkm and thst of aufface.
ictive me" ai the mulm4WO(Ifty of hm moUls
ars diwu*wd. TWO ACUDU of PAmotem may be ex.
pl-i-M on L4 fleoy_ A- J_ M.
AtIALLUMCKAL LITISAtUAl CLASSWKAIION
U a AV lo Lsl;-. I
a K
00 0 00 00 a
lei: M 0 0 0 w 0
0 0 0 *;-Wo 0 0* 0 00 0
a Al 41 a go
-00
o, .00
la
0
=00
COO
C:OO
ao 0
0 0
net
son. so"Im.F Ito 0
allill ce
I rw 0 * it V 94
41
00 00 age * 0 & 0 0 0 0 0 06 0 a
0 so go 200 00906000 ODD *, 9900
a 16 r a a 0 0
A[
30".. fr"wtkn of blaudUc BdutWoo. Pwt 1.
W.
W., ~ AAU PAysiWUPaiad. L & PP,. 676-704. MI. In M%q"
1u 14,mtagcs of considrAng the pueralind molumt an a, clWacterialic
constant of a mol"No The mutual sWubUity of metals au~ I
the influence o( baf v0WA surface tension and the Induemv of
impurities affecting Uw subw Aumba.upon crystallisatim are discuseed
0 from tbe: #499MUNd Moment -Vkwpoiat. The sudace phewmena de-
s
ar
'bed Uvof considerable importance in twlmoloa. as is abown. [See
13 aW *bA#%ajP4U 11,36).1, H. J. H. S.
fee
Ae
do
-ILA LITIOA19*1 CLAIIAFICATIChi
At*
Ificou Qkv Ott
A Yv Mg
u IT so u i An I I a 04 0 M I if a AA 9 3 1
0 it IF 11 a 11 49 K ff Ij d4di
0 *0 0 a 0 v 6"i7 00 1* 0 0 0 0 00 of 0 0a 9 4 0 VA
0 0 0 0 0 0 0 * 0 0 0 0 0 0 0 0
11 it U w 0 11
040. K:StiT,-AF-N-NE NED
00 Ai
of .4 t - 0/
0 5021. Properd" of
8"Meatchgako, D, 1-~ in
with X.-R. Shva"Va.
09 A In EVIkA-lu the study i
j
I have found It necessary to I
I
of the mode of -.reparatkm
work [m Atotracts 3043 a
of the surface tension of th
j
Sa. Ag, Cu, Zn. Bi. Co, Al
'
00 O j obtained for activ
e metals
equation but certain discre
-
w
,
hich are,better rcllresenk
complete equation of Gibbs.
in the Sbishkovsky equation
6
x a
cti"tionl k fnurul to ha
a
AD tA
-00
-00
- 1. .00
WILC 80judws. Part M.-K
i
a. N. L. Prok"vsky. In catllsbora
4&i
Physic"Aismica. pp. 181-192,,934.
surfs tension of amalgalus the autimca;
re pure specimens and an account is given
j
thqn used in the present and in foxmer
D36 (igU)-] A complete series of valu4w
'
aig"
of Co.- Rb. K Ms. U, Ba, Sr. Pb.
o0
d Cd, at 18-200 Q is given. The data z
ow concentrations satisfy Shishkovsky's
es are found in the experimental curves
an equation derived by integrating -the ze 0
D logarithm of the Product of the constants
kpproximate value of the ultimate S=f&co
fn~4~ or fl- AM- .1 #1~. --I- t
i
--,~7.,, x see
0
A I a S L A OCTA%LURGICAL UtERATUAl CLAM 9
old..
wilt ;J, axli i F.
q w a Ill 0 a At A - a ' 0 0 # * * 0 to Ol e,
Im
a s A 1
9 0 *1 It It 13 14 is 16 111
33 41 a a
2 T
It
OE
4 j
'40 AND at. CINI
S
P4C-CISS11 A.0 000FINI'll h-ach
'P-PtrU" Of EdUtiOU& IM-- lulfm* Twaian of AmaInarim lee
JU mil,J ."Oe
All v ich Khtmsi (J. PAys, ('Aqm,), 1930, 9, p), 311,1 :171 till
'
45n The surfmv trusion tit 1,%
Lo i
r
and various imumnimi~,-i was slul
w ill Ille mm~ of %miriAtIld milldamllo mil
t.%ming vomium. m1+14 - W.I. tin, plirt'r, mplarr p1tvWillill. m%fillill. 1111lisills, see
j X: hismsAill. 1AW'. tarillm. .1mutium. 014MIRM11111. t'r ed,111.11111i. Th.'
t
i
i
I f gee
va
mm %s
tta
llv%
or Iketiv" nivilds at 1,,w mincentralionA
(XVISTS above a rritival C4,111.1-ilimlit-n whith ia a lim-ar fistictimi 4 tit., activity 'u do*
tustic. curviv ftir otatfam tenAiml remmiltrAtis,ij on.
I
tt
l b
zoo
te
er cxpmvft~
y . 0, - a 's trbc + 1) - de. Ithilgintil by inlegratioll
of Utbtm' t4suntimt-N. A.
go 0
' s;%
p*
.
all a I L A at fat LUROCAL kjTfN&TU9t CLASIWICATIC),
SIGN, *(Wtl%V
_
-
411111 a" (I". &is
$#)a#.) 0-v dat 43133,1chl"
.
.... . Sill a
u AT V . .
Im 0 W v I W Ill5 43 a 3
X9 pre in, It A, 1 1.
ntpolfw4w KA
Ill a 0
00
00
-000 j
0.0 0 0 0 0 41 0 6 6 a 0 0 4 0 a 04 a 4 0 470-9.. 4,64 we e 0 a 0 9 0 0 00 0 0
00 11 ) 4 1 A I a 9 to 11 11 13 W is it ull"Allual 4 Z5 b 7y a n to It 11 14 is m V 39 Or 4L At 1: It 46 Is
A V I "_Y-1- AA of CC DD It t I
1; m j I L
P
0o 4 -
.
;s
0*
00 0/-
60
09
00
h
Denalty cat caltacitY and compressibitity ol Solutions .0 9
0 of e$
ejectoj~
NLA 'kU&M-h
,-- I enko. V2Pekhi Khim s
0 fp
: 1xim.,
A review di"im d dat.
-00
0 I-Cmm the fitcralurr, chic"y for tirri. and bi"fent mrial
00 'Ar 'alts, F- If- k2thUllinn
-
00
~
A 0
It ji .
09
l
a A 0
00
0:0KI ~o 0
~o 0 1 Ao
zoo
J* Ao
of,
so L A MIIALLO%,~(Ak LITINkfullf CLASSIFICAMN t:0
09 3
~; I k j i r 16; 4
r, An S 11 OW a
t -1 U
t
1
4 3
tv 0 1, Of 44 I
i
a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9 0 0 a o a a 0 a 0 o 0 o 0 0 0
OZO 0 0 0
6
0 0 0 e I 1 0 a 0 0 a 0 0 0 0 0 a * 0 0 0 0 0 0
: e 0000;004 00000
. 0 0 0
Sol
A p OU I TO f V 41 &d
a -4 11 A-1-t-A F A t t- fa-A. V A I. R
00 4
A-0 P40#14f4t "t
AUWL
bohm Pb6awftft a"
tM.7.(41.50j-jwm).-AV. A.
go
00
::i
..ILA -ITALLUACICAL LITERATURE CLASUPICATION
1.0041 .1. Gh. off
u a &1 10 It!; , . . I I , I I-- 1A-p
0 IP or K K a It a it It
IF*
=00
roe
ago
goo
'so
Woe,
C40 0
Too
OK 4.1 isF
a PW 0 -1 w 1, 9a
0 0 0 0 6) 0 0 0 0 0 0 0 0 6 0
AOL 0 00 00 a 000 * 0 0 0 0 0
a;jIL~iK~ :sr-AZZ MA 9 2 9 a 9 a th a a 0 0 W a W W -
go 6 0 a - IKIL Vt to toot** 0 0 O;W
all III it I I q1tItIlt?'119 t-% r F VT Ww--
A I. J .9-- X r-4 DD.
'it -I loo
i -00.
00
go 00
00 .00
*PTOPUUN of MOWW Achillons. L-Thistandmi. V, jK~,4uuvuc6,k,. 00
00 (ZA-wmil FixicA,tikuy KAixsii (J. PAys. CArm.). IOX 7,(4).
Runian.1 Incaiimw o1mutual solubility and surfam phenomena. the behaviGur
00 of the molute is determined by &ho difierence between two quantitice, one
0 referring to the s4yrut and the tither the Isolate. which S. calls " generalized
momentiO Uquid metal entwipts of ions, the potential rwrily of which is
lirituarily determinitA by their Malkin to the surrounding elem-umlo ami. Zee
K-r 000
Ppherv-, and In Inky I* taken " go " genctali" monmut." W brn-
Cto 0
RZ 4-774 X, 10-10.Z W the valeary Orthe lon. &M r thr, ionic radito. Expects.
00 rivetl 6
.1. at" de W thesurface. triw4on ar.1 limiting ourfam activity. DiI~r- too
ininationa it( tho surfitve tenskus of sliffen-sit 3wW amalgams corifirm tho
00 a JTiolsh-s" with 11w, motfificatiort of alloys atul thr, mutual
N.A. 0
zoo
woo
Koo
tfoo
Cleo
9 1-
A I a . S L a of T A Ll UIIGX: A LLITIRATU89 CLAI$WKATION
Rio., lillsi
*&,,It 4a 4.1 it,
A
An I Atilt
U U Iv 10 it! IV IV Caj ,,g ICU OCUlt ICKKWn 1 14
10 0 0 9 0 0 0 0 0 0 0 0 0 41 0 0 a 0 a 0 0 0 a
:10 0 0 0 o o * 0 OA 0 0 0 e.ALAjLftAA.&.ftJLo 0 0 0 0 0 0-0 0 0 0 0 0
0 0 All 6 0 0 0 0 0 0 0 go
0.0 9 0 a 0 0 0 a e 0 0 411 0 0 0 00 *41'4"- 044'go so goo I
to to
I I f L 1. s I It Ir-f--k I- LAA M CC 90 U.0 0 A t 4
P. Befing.
filliff)"i mild K. ic. Slivart.va 11kVI. (",
00 8 '4. RXI.M4 .-MMUti; 4, 10.
411 K. No, 1.11, 14A, 4r. .
Col. Coto 1.11,
Age Cu ond Iii st,1#18611, A,
00 too "I.IWIN. Ill, A.-Jiv'. i
rt"60t)cYthr,'thi-hL,,v,Lle,il.usik)4t. TU-u~ -09
00 *Web dorviallom% fr%411 Shishittivski
brain III to linear ItIttelitm, %I be Illniting activity. py
00
as 41,41 fibbee 74flillillk'f Id-16111he rqlj4 I kin. tlwcAMahm
which Agreed liellet with the 04 00
00 a data. V. It. kathinsitts
00 c 0
00
00 goo
00 t~ .;Zoo
0=0 !1! 600
00 00
0-0
00 P-00
00
U00
w0 0
OW 0 43 a
it a It It AA L S 4 .04
0 W-F-r-
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9 a 0 0 0 0 0 0 0
0 000 so
0 0 0:0 0006 0 to 0 0 0 00009
0 0 -*,0- 1 0 0 o 0 a 0 0 o 4 0 * 0 0 0
0 0 0 a 0 0 a 0 0 0 0 0 0
04 1 114 alin )627xh 11ill 12U It D 14 11 IS q Re 0
.6 -'L.' 1. a it p tat 11, 111, "U MY Ll- ~ Y A AA N (X DD U it W 1 f B 4 4
00 7&j
00 ... ....
go
00 Surface satlatt-out by sls~"Jtss. IV. Suds" salt- L 00
ift-"t -d temPtatim. V. K. Semenchtnka " Kit-
~00 austanmv. :-~*
of N 4-C.A.29.77(121.-ThcsyswmHeo+'iigS(X+AmOii,,' -00
Was studied at 0'. 20'. 40* and 00* atconcrts. offlf")~ Innn
so 0 to it Af and of AmOH from 0 to 0AJ W, - On raiting the
00 temp. there m-Curn ill the %LjtioJg~)ut elltvt A Illill. dur
of the inmausingsurfam activity of the electittlyte.
00 F. 11. Hathtntinn
gas
=00
00
coo
coo
00 ;:0 o
off
go zi ve 0
z:G0
so
is t:00
ties
At* it A flAttt,]-,HAL 11114ATW!~' CLOWICATION
,is
U At is L S a ad a 1 31, 1. .3 Aj v4s 0
L ~;Ot
91 K 99 U It of mW n I H
0 0 0 0 0 0 0 0 0 o 0 o 0 if 0 0 4 0 0 0 0 0: a 0 0 0 0 o 0 C 0 o 0 0 o 0
0 * 0 * 0 6:0 0 0 0 0 0 0 0 To 0 of * 0 0 0 0 elf 0 go 00 9 of 900 1 0 0 0 0 41 M
OL, I i. r.. I ~ ".. Liu .
J
FA7LOV, I;Orip illukatu-yvicii, 1~~2-154t z;ricjrt coursein chawiatry lzd. 2. , sterootipnoo.
Glav. red. x1im. lit-ry,15;7. '126 p.Dliazastercv flotsiuliaticheukoLo truda)
.,i"37 F-r lc;f7
On
0
go,, IF
0- i
*dp:
00-
L a N u an
POLITIC$
-uzra
ax " u a It
M Ay u n to
tog 4WO 41. "ttfit 0401~1
~kO'LW3IJI%%V'W 11011LIVIL11 1,31%4 RA-
"me'a 'llull 61
olqviflo Slittullt.Litl ell(Imu 041 JO IAJ!AJJ V 1-UV!Wtl)l ul) -,(I iml .1m 't
."IV P- imom, vallox 18 acmd% OmIl"S
414vi
r
at x
0000 0000 Ilt of
71lgo
00
00
00
VO*
I* q 0 0 a 0 0 0 0 0 0 0 0 a
0 0 0 0 0 0 0 9 6 0 0 4 0
o'
0 1 8 IF 9 of a a k 4 it I# Ap-t' -i-Ar -Ar'
A.
00,4 61 .100 Deal I
0 41
00
00
W-6 go *****so**@* oft-
Poalls X&I'MING" 000
.4 11 A Y
00 a Sbrfsc* trimalon ditailten m*Uls and alloys. J1. Theory
66 oil the surface t4akon of metaA and alloys. It'. K.
L. I'okruvAff.
Cipekki Akrmr-6-,~
o
.4jid N
!
.
Cf C' A. A M41. -S alld 1'. ditteliss The
.
1
lectron theory of tuyfacc tension in pure inctals from the
06 illmilmunt of the thermodynamics of it two-ditnensional
00 a tAterri-ti; xm5, Is hilt for alWym they consider the innic kmrv~
..J.1ing. 11%, .."InIbilling I It(- Illut Ila] rfircl i of [.it 111'1115 Mid
09 t'G'Ie6 and Otmont. tht-rubtititith~rqiiiitit,iitn(; - In IV
' ? v (m, - W, P - In t I. - 1"), wheic 1; v, th, niff.-
it wivin, in. and in, are I* jencralized moincilt-if the wl-
4141 v int and wifult intilti., -f is a function of Imp. and ratwe
4)( the ,,t)l%t:nt. 1"s and V, Alre the at. vols. of sWvcnt and
so
sa
lute and 11' is a characteristic coast., and find that it
i!ms (little well with exptl. data from the literatuir.
Ki Rathatann
m
,
-I,.- ETALLOSC!~AL WE
as"
solooo lilt amv Oat
see
CIS 0
0.
go 0
goo
90 0 ~
200
goo
tie 0
bee
age
Is U a p to MI.- K' t1t to aw 0 is v 1 0 a 4 1 If
0 0 9 6 0 0 0 0
0 0 0 0 0 0 0 * 0 0 0 0
Ise 0 ~64
11
PRIK93193
Is It 9 13
la k v x do 41 a 41 a 4a
J_j - A_ _f " jr I.
00
00
-00
-00
-0*
-00
ago
age
ct go
too
goo
ago
:60
9j, tag 0
AND psurgavill MOIR
4
00
l
W
6m
a
"
4
Aft~ st 91"
~dww
00 w
U
X
A W
[1
j
.7,687 the
p
d
V.T w pobve-Hadestihm , qM9Wl4U0b. Ol
I 4on
rwm 60109M., tbml= it, F,,,Kraw coviviez
of ),j
aftunab" fAw., coed. MW Its tbm R 16-s' lntop-
tbo-Ye mik ,n* a awls. we dlls-
IrcWl'"lal
and sv-
tk
-
)n
ta
F. U. R.
cummed "d eatheavatkaft treated.
04 el
00
if
Wo, AS.-ILA ETALLUPfKAL LITIRAIVRE CLASSIFICATICk
VCaj 1, 0.1
411
u s% In-cc _r IT-
A,
0 0 0
to 0 000 090e 0 0 01
811111 ad a- AS,
s a bd 0 N 0 1 so 5 a a 3
~0000 70060 * 0000 4::::c::!
0 0 IS 0 0 0 0 0 0
/wit, SoMard Pts.-
Awl, hid, 11bikkiol t Port, Xhirm A&WJ'
S.8,S.k. 10, IM 020010). -464. dlqwf;~A plutw,
UZUAHY rVits"Ied as it lamwquii. IJILA". to CtM161.1.1.11 Ott
equil. state indecd, an in the caft of vapor condensation
maxitscrit.point. Firstamformedmol.orat.compicu-s
with an Increasing enember ot units. The compkan In-
clean to an extent when opitkoce" appears. At this
point the symem U for example. an aerosol. GmduOY,
I he cromol ~Uugf to a fostru, which phase diffen
but slightly=811quM. (1.1mitertain'rjit, and ocon.
ditions. the disperved phase can rem-'u as such in4efirtitely.
A ham transitim of the 2nd order in defined as one in
.htb-. (1) The beat of transition Is sefo, Le., the entropies
of both phases are equal. (2) The beat capacities tit her
have a break or pan through a very sharp max. (3)Tbe 4
thermAl caeffs. change in a inanner sitnitar to the beat
capacitks. The contention that a dispersed phase Is an
equil. phase is analyzed and Illustrated with the mme of
f - pamaugnetic tnutsformation and oforder
bei in W". Nf. Ifooth
i; -;~V-
00 A is? A" J"D DOOM
flocis"s AND 0,0004111t95 $-H4
00.4 V-PMI"WXOW odubWty of
fumd swo. "y bealto MW T. 1. Sba-hicum.
-'
ZA kv
read.
jMr
s- 30. 1-%-$ (194 1) (in
g an givt1i In 1- md
for the temp. 6f I nxA. of Coa, RbCl, KCI,
C
LIC1. B&C16. &", CdClov UgChs
MR. 91. XHr. KCI
004 KV IS r"P-.*Of TlOracid KNO,.
'
thr VOW of at (change to q1t. win. temp. per I sow. %
064 4 added salt) vurim wkh uw geommosed UbDOWN (,,Ip.
h
b
h
*0 1 w
e c
-v Vs I
"We and r the "Man) td the km except
U"I
hC
t
w
t
-s
twu the at val..4
the genmdxed nvmncnt of the kma, wp. of
"
"
e'
r
obt
l
d f
lk
d
r
!r
a
e
a
me
or o
. wi
Wk. cuth coflom
b
b ind
s
k
al
that grnnxHwd numaj vWt" orjy rMahly approximate
the chasurtcriatku
of low. The rtwlts avve with the
3 thomy of &Mwmhenko wW Davidov*kay
(C. A.
60 W. Aym
ooS
LFTWXATVOt CL411WIC470"
is" 4
r.-ax=
-410
-416
.410
-040
'44
1410
.4'jj
.440
adis
U410
r
ace
do
ad*
Ste
bit 0
We ill
Mom W I 1 .10 CO-W gat
ZA An
1 0 a 1 5 A a 3 6 v
s IT 10 It K K 99 X K 09 K N
0 'T 301
00 " a -~912
~* 0 0 0 a 0 000
flaw-16-tiou of the Gibbs-Curio theortm for udzed crystals.
V. K. Sdmwawjxqukg (Conept. rend. Acad. Sci. U.R.S.S.. 1941, U.
175-177).-The effooct of admixtures an equilibrium crystal form
depends on the manner of their adsorption at the tiquid-crystal
interfue. Positive adsorption retards crystal growth at low concn.
and accelerates It at high concu.; negative adsorption has the
reverse effect. L-
PI
1 file in L-J- ra,-- of t0onr-rcss.
Air Tn'on, o-,-1 Dil-l" lorl.
0
a C 0 EF Of I U
X L Al 04 0 R S T IN 30 11 31 33 34 15 M
J# 40 41 42 U SA
IT Cot Ay IS n
It. P.sf.
Alf 0 ly3oanii,11. .1v
9
o;;
00
as- 1
,
r
A&V
4-4111411-
4I2
sex 4M op < SOAA01 1111" to "Jif'"'
'Sunivlwpv x
Gen LIM 11-9 mn to snww 3jqdiuvulvn%Aj3 MR A j,UAA (3U*IVA
jjujaq s -alt m in urn tm in joalla aq.L .91 t Aq #,x- aqj aj3*ol ILwa
eom W % -'P- I A > 13 > 10 > I Pug Oil > SK > 10 > J"' , '-' wit
ea > rl > X > qH > r.) sjopio vqj u1 11 joaul oil" niijo pogg
-
-
'
'
so
1m.,%
xvw aqj
%-Tm 99 111 on of # in
WV $.Alit) 1340 10 %,
j*vA I
wItAs aip to AliAv"Paw l"a" 041 umil Paujiusojap in qJ411LA.
l
o *
1jus oat- )a # dimas 0U--(jtl-gCl @I
N
ug
4ILL t
oK
I P
1
Vitt m".7 -SAVi -1 'JL Pug ollu"Muoms lip 00
-V A nwpft %Up $*'I* 1111IMPTI11" 10 wn
0o
00-
-T- r-
o.l. 'r 0 a 0, w 09 if R
or arm-W-m smJ401i d.Vaft. All
y
ti
T
0 0 Of 000 0 * of IT er I a
0 0 K a
al
-
I. ~211 It if III A, A
0
A ALADL 0 0 0 0 0 0 0 0 0 0 0 0 0
- -w,v v ig g % q g g & & III & - IF IN
I *E 3SP ~R% EPA
W:
irlrff -w-ir- 0 0
@goal'
::A
2
A
00
Jill
It
00
-00
.00
.00
;- goo
Zoo
loo
boo
goo
Tbwm,~OY~ Gof mmaH bode& It V -X,
. . . , _�
t. Ploys., UnIv. UGICOW PA.' -
"t-SO-A-19, 3W 70946); cf. C. aiv.-!Two-
sm d6sc~unmed. Aid. 4LV-W.-
mranl=oobm an m.p., etc., Is dimcussed.
1. Dikenrum
ILA ARTALLUNKAL#,ITKNATURIECLAt$WICATIC11
,ago 111"I1
100040 -4 585080 Not (3-V oaf a II&II GIC Gov
u x ill 10 LI An A III ad 0 0 a I w
OOT4040 ****1* 0 9 0900 go 0 sol 410 000 to 9 *0000 00,00.00.
I
0 a 2 3 1. 7
W 9 a a a a a A
0 0 0 0
...... it ti 14 it 4
r".". , if is
g J7 X M"ll lilt 11194U 41 41 4) Of
at 4 k
A
7- bases" *1 "Mistum an thA of !011 OVUM.
0 8: v Sementschenko and T, S1th&schkJnS~A=(f4WPA-YVji4rWAm VAS S.. j-oo
1945. 16, ja3--~I(sp.-The crit. solution temp.. T., of two fused
:4 ligits can be determined with an ILCCUMCY Of 0-5% (Mn the ch"Ite
00 in the electrical conductivity when two Phases unite into one or
vice vem%. The system KN(I.-Tittr. as modified by the addition of
numerouS halides (1-0 and 0-5 mol.,~). has been examined by this
J! M in 7. is etermined by the grnendiSed
el
0 thod The reductk
go t of the ions, of the added halide. tha effect in Inctcasm-4
/'-.'-U= *solubility inam!.ml in the orders U < Hl; < W < Li
1W. I < Cj' < V.
of 11 < < se* < ca!* < ug < Be. and r < Hr re &
The phenoviena, are interpmKw as follows: tke introduction of ions
0 with high generAtised momistits incrissm the adsOtPt10a Of the
surlace-acbw component At, thS - iAbff1&Ce of the liquid phasm
00 000pauistrig am increase of the
Ibis increase of Adsoupson Sot .only
0 surface tension (y) at the interfacryoduced by the introiltiction of
the admixture. but nvn ovcrcomes 1. md y dvallawa, The dec
foe
of V is equiv. to the decrease of the potentiall barrier at the interf
All 1! and lead3 to an incrisse in the sojubifity and a reduction of T..
C. R. H.
Ines
too
A S 411. A ETALLURrICAL LITERANNE toll
CLASUPICATIal,
00
ISO- 4111.111. 1 Z- boo
00
r
00
0 'a 00 K It K it PC it It 41 An I
64 0 00 0 0 o 00 0 0 a 0 g
0 0 0 a 0 'a0
0 a 0 a a 0 10 Is Is 0 6 0 0 0 400 00 41
00 0 1; 0 0 0 0 0 00 0 0 0 0 00
A
tpo&
so
00 NE
so
v. V-,xammdwdm,. comp. m
48, 9"(19042AWy AM
A amedmW
cartsy of mWM* asd edid w1m. I
adv"tago of bd4 rWma, but
the amow tcmp. twp in wW
AS&.iL& agIALLURGXAL LITINAIL411 CLAIWKATKII.
Mam IMajavo
-0--f -aw a V W v v ,
11-14-40-16 V 0 0 0-4r-w-a-wamw
7-
lofts* ".at%
iiiii "W16 of S"'Amm.
td.-"OL-Sci. U.N.S.S.
f. No%* S.S.S.M. 48.
of detir. the hv-* mirl"e
i pumard. It has 6%
Its chkf ohmemning b
It is a
Ito*
Soo,
'300
7
log
3e6
0*0
Boo
logo,
we*
voo~
3 u 0 AV 03 !ali i i i i i a i i i i i i in a S a "d a w a a I dol a 3 a v
_0 0 0 0 OF *I Ot 0 0 0 * *,* 0 * # 4 0,
0 it
0 a 0.0 0 **goo
I,* 0_11 0 0 0 o 0 0 0 0 0 0 a Se
0 0
I I 1 10 1, u 11 14 is '6 Ili$ 1,1101 said 11 a 41 one
till _C f H I a L v ~.t -1, t A, I -I I -s
-C
PFOSMW ittato at the periodic low and tb* now elements.
X-K~Semrnchcetka and V. V. Kar&ov. Ujp4AiKAsxv.
15. IM11-840946), Clit. review of rett"t iklvnllcn ."1 4
nucleft structurr 81111 including Nj,,,aud
IV 3s) Ftlefellvo. N. T
at
~;i aloe
0 ~Ov`
;800
too 0
t
A S a I L A tTALLUGGICAL LITfIlATUNt CLA$lWKAl1Ct4 CIO
.1
a.! ire 0
W1 I PW I M IM a di a NX
f? IV it CO 69 Is It It K H It It of 64W n 1 :1.
0_0 0.0-0 0'0~0_0 0-0 0 0 0 0 0 a 0 0 0 0 0
it
of
00 0
OoW :t
0o A
Z
4
& G a 6 a a 4 & & a G I ~p
000044664608
a a 43 a
L
j"-Apo 41. clot
[too
coo
too
400
VOCCISUS AW FOOP1101195
The offoctive toms in solutions as the basis of dazslfi
cation of solutions V 1~.
vow 11. PATI. skil vimi
i it I It 11- LA it 1. 1 Iw 1'.1. - I.-f vi,w is I Ile Ill. 4'. . A I he "All 1.
1 lit- .... LI- A it,, 6-1% -it t h, A lAttt,
Will At' CIM111.11fAll. Atilt aof ~4,1-
Oil, rd"ti- "tagmit"I" if tIw_I.w.-1, W..L'd
It f1w .1-traw it fltvvtl,~Iv .4 Ow- f.mi". M, M.
"frA,11's life illiffill"I. di'laml- 1.4W., 1.4.11fival Ia., F."
fit,, tit,t still Ow thirst 44 the al.,%r t yj-. (It,- Ati vi--alhd
limlivi 41 Vito Ill w, 4.111vi"Im. Vila 1111'.
t
ik
144woo ; S
Sake" WIF ONY alit
'610
00
;A If fm 0 It w A 4 3
* 0 0 0 1 a 0
'W 64 4
004
&dV
002
004,
10
0 z
0 1
004
-0
--soi-me mistmerm of tha Mdm 41191mkdow. *,d Ag in various Mme" -00
M, fl. No. 6, 774-) dm
with sam.; the smhp~, of
V. K. ~Tbwjw- Faft
is poramisd a A k~9630 of (at 4509 ambd ves o: the domemodlas brawk. "*s
N (2) mwu*w arm the "livity Coeff. a
dim, of stoments 0 of wiv"
a of the 4i"m ssoL the solift, the V" pressm of the Solvent th* beat of
solute. the e ulul~ d9n., the op. beat of the Kds., &W the zlz activity .00
sort to the ZSCIEV In Ithhes rJahwWASo Came. n As tw pro-
t fector between Ube potential OMW I of the of the solute sm a functim of the differewe of the w.
It Is abmm LEW at equality 4d tin m of solvent and Solute.
and the potmthdof the 0111- (Wid Of the the sofa'. Is MW at an=. (3) The properties of a 200
othff VW. ml. Tbg pumUnd &*. emw w a fmactift Sim solm. an dttd. by pedtion on the gmeralind a*.
Cm*bd1A" mmumwwftq-~- -
differ of the
me
of the
000 nm. coffespooding to equal" of me of solaft m t* call so a &w(ka it t6 &Swmm of dw a. Scim.
00 43 1 and a branch. Velificatfaft it am by mwesafted -by a pabd an t* -poesdin branch have an
;.kAc
46 1 either the dkiec. can" * or the ft I I I 2tivity - less them 1. a yam x - - - of the wivw
- SUKUCU?s SO by Avqpa&o's an. and divided by the i w th= of the Ideal low.. a on. bw of-dilm.. oW
mol. vals uv6gd
00% h this convention. the folawl" at s, a aft. MAIN activity. and vice wave. Saba.
HOCANO, end of ftCOA In WiGul schwis, w by points situsted swummukany an both sides of ibe
s a function of the differem kf % Complete Qfs "cWWpftdbW eaft." in the . that Alma"
1 1 Wthsecoditigbraoch. - Im thf 161 and the above therzoodyasmic properties of
the soly. curve of Ra she" Wt lee dexcemOssr 4m such Car"poodims ma=. hi'm the Sam
tlmt of KBr only the sacesdius bn acb. For tottak a M.E~y curvv- The Clow a 901A. is
resentedbralrikimem the gentramad soy. cmm the
Is assumed to be NO
::i coup, a vskum of the metal Iom, r ftedo-4,10101. *.4emp. cur". N. 7%m
so
til
It
154.11A 49TALLIJNKAL (ITERATURf CtAkW Aylbi 9
4"OF "$Inv
444m -t - I INJO40 MAP o"T 4*9 do VILS11 am Ali
so
0 v IZA m L I a ad 0 N 0 If Is 9 a 0 3 IN j
&I S AT 00 AS r 4 T, I 411C. Is
0 0 so so 00 00 a 0 0 .1 0 eo 000000 06000 0 41
-,* 0 *!*L'o o 0 0 0 o 0 0, 0 6 _*, G. 4 -s: s'e q.,
00 0.09 00
UM/Chamistrv - Surface Tarwx4
'Chemistry - Crystallization
Surface Tension and Crystallization--I: The Surface
Tonalon of Melted Salts," V. 1C. Semenchenko, L. P.
Shikhobalova, 10 pp
"Zhur Fiz JKhim" V01 XXI, No 5 - it. to
ZXP*rlments carried out on malted salts with tempers-
t*ares of 315 to 900 degrees C. Graphs, table and
diagrams included.. For the theoretical explanation
of the effect of salt, there vas evolved the formule..
which determines the relative deliquacence of crystals,
from concentrations of inpodients MOLaurements of
crystals and their surface tension. Published 10 Nov
18T93
USSR/Cbemistry Surface Tension (Contd) May 1947
Chemistry Crystallization
1946. Moscow State University, Ameni Lanonosov,
Laboratory of the Physics of Solutions.
IBT93
'-A L/,T!08
USSR/Surface Tension
Salts
lum 1947
"The Surface Tension of Solutions of Fused Salts.,
V. K. Ser-enchenko, L. P. Shikhobalova, 8 pp
"Zhur Fiz Khim" Vol XXI, No 6
Method of experiment and evaluation of results.
Diagram of apparatus and tables of results derived.
from using salts composed of Li 2S04 + XCL, L12SO4
+ CSC1, L12SO4 + F` C12, and Li2SO4 + RbCl.
14T108
I a Is A a V X w 0 $1 a a 41 4 0
7t.
00 semetichenka and L. P. ShIkbobalova (State Univ
-
1
002 C".
(U.S.S.R.) 11. WT-1
)
0 (1947)(in R-1-21); cf. C.A. 41, VW.-Surface tension
f 5 bina
welm was dctd th
00
:0 e max.
w o
ry
The w of
bubble preaure. .1. W and .
-04i
1100% resp., are: WSO& 224 and 211 dynts/cm .. XaCl
RbC3 83
d 06
Cl 72
0
Ka 91
d 70
C
d
d 93
1C PA2
s
an
9 an
an
1
.
,
,
59 (at. 1050')4 and HaW4 173 (100C)") and 172 (1050').
K*SOj at 10745 has ,r - 144.3. The error Is d, I dynclem.
00 The # of UWj Is Wwcnd by the above chlorides, mom so zoo
900 the smaller the e'of the c1daiMe. At about 1-8 md.% of I
-
f
so 13 otherwise the
the chloride w islulejx-ndent o
Its conen
curve of or against mote fraction Is ;;V-" and Ui~btly
w convex toward the arigin of the collrdinates. The curve
'
for L6W4 + _%Cls has a min. (103 at 1000
) at the
th
ll
f
l
i
L
l
F
ts
e curve o
r aga
nst
mo
or a
me
equ
. =
temp. is coseave towwd the origin of the co-
ordinates. The value of s is detd. by the "generalized
moment" of t1w Wn, Ie., Its charge divided by its cm-
tallographic radius. The greater the difference between
" see
the "generalized moments
of the loin ofsolvent and solute.
the greater the surface activity. J. Bikerman zoo
No
A 11 A - S L A ACTALLORGICAL &ITCRAT&WE CLASWICATM
sajaso Mir OwV cut VILM049 RIAL11 OK 410V Ot
9 0
I .10100100
Eff ME M.sk.&Ek.
a w it a
0 * 0 0 i
T 0 .
w .0 0 94 0-04 0 0 OP
11-6*0 0-0,41 0.-0 0 0 We v 0-0 w 0 WIG
0 O-W-6~0-9 *-*-a - W. IV
S
0 9-0 0 9 0 9 0
SIR I all WA~ X.- N'x 3r a-m v 5 So 0 In a a 46
_7
-,al a's
A c RF is A L a It a SIR a I I f Gm a I a
W TZ A 'a -
SST AND 300 LETTER --I A- _17" OWDERS I rh GSOLWS
Got AUTIMIMI #Mtlg MATERIALS TWSK
allmlys2ml
i4m
-pdn Rop jol I=oW* AM f" wo 10
PURUMOI* P" "-vw J* olpww
"4wp an ow
9 DR -
*smwm
o w
dwi
16 all -
pl flow
j
p
"m Paz a113 P1110-0 jo popaimps alp RUM la;m
oft Dw sl ,s=um wpow Rum VIRImm "m ou .:am g
. -
is
-/"p t
p- al
om
ov
06
I
,
dou
.
A
I:,.= p
on p p"
v
"-/-
-
ll
Sol
p
p
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OD5 )v WIN p 00
00
Dea l
00
1
wmvq IVW) of P
olls t 00
Ko .
x P
-appowampf,
% '
-
0'
p
1
I
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1111
= 70
WO p
P
l P
lro
t pm I
#
#I Ora p- Irjqj IIOX
v
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C)
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au
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119 SalrolaoW Aldols s%
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R
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Mp= p
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p I
00
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K 64TI6
UM/Chemistry -'Solubility, Squation of Feb 1948
Chemistry - Organic Compounds
"A Check of the General Equation of Solubility,"
V. K. Semenchenko, Moscow State U imeni M. V.
Lomonosov, M. I. Shakhparonov, lab of Phys Solu-
tions, Moscow, Ill PP
"Zhur Fiz RhinP Vol XXII, No 2
A
Previously submitted eqivitions for solubility vere
confirmed on the basis of Merlmental data obtained
during studies on the organic bords of the aromatic
series, aliphatic series, Euid. we&, average, and
strong electrolytes and elements having dipole
64T16
A-
------- ~Jra
metals
to aSolubility of Metals and Generalizecl xcm~int'*
'T.K Semenchanko, P. P. Pugaohevioh, Moscow. State U
t4 . 1, . .
%Imsmi X.V. Lamonosov; Sci Res Inst of Pbys,
PP
*Zhvr riz Ehim" Vol =, No 4
GraNde method to calculate the solubility of fia:.'Au,
AS, An. Ca, Bi, Cu, and Si in various metals., Makes
Use 'of state diapams. Shove how the g=ersllzed
manent, can be determined from the state of the metal
and the canIxessibility curve or the curve -abovina
67TI8
Um/dhemistry - Solubility (Contd) Apr 1948
thermal expansion. SubmitteL 4 Jul 1947.
6=8
SU-01CMIKO, V. K.
?A 45/49T25
USSR/Chemistry - Colloids Mar/Apr 49
Chemistry - Absorption
"Holecular Th:5ory of Surface Phenomena In Solutions:
I1, AbBorptioa in Mixtures'With Many Components,"
V. K. Semenchenko, Phys Faculty, Moscow Ord of
Lenin State Ui-Imani M. V. Lomonosor, 6j pp
"Kolloid Zhar" Vol XI, No 2
Purely mathemaitical treatment of problem. Sib-
m-itted 2 Apr 48.
-4W
45/49T25
"'-OV Y= Uud"RT, 71-1t. DkLdr=
/Nji].. 73. -VII-2(19W).-The prvy"Wy rrach"I.
eclUcluskin that the process iinizerlying mia 2tul-ori~cf
transitions is the formstitm of d6pccw (C.A. 42.
532th). and that the point at mversal %A the cmulskni
furmcd livar the efit. tecip. u( mislull of a Wlwy liquid
5ystcm calls ftw a Max. of the Viscosity V at that point
Yrimik Aloskov. G-utidartj. Unis. 3. No. 11, 103 (tVA8?),
nA t"ted by detas. u( q as a function of the temp.. for
ItIlms. W Colho with lbNLh 38 b. 40 2, 42.4, 43,1), Mul
43 7 mol -/4 fA the letter. Re"'the crit. temp.. resdiap a
W;;6 Qc t; temp. Intervals of the order of 0.(W. At
all the above compos., the awm allowed way sharp peak -
shaped maxima, extending ovw a tecup. Interval, of 1.23-
1.76'. RvtA man promounced me the posh of the temp.
coviT. aqi&. Their position mo be used for in amurste
drin. of the rill. temp. of misins of The sivenI lem.
IT TtkW
Cholbecri" !Ibo.Dor"t~
Wy A&J. Na , rl..v ii. 74;-
dynainle forioulatimi of the Itaint of view af:%vtdittig to which,
Otte crit. rnion, which bat a finite extetuflots, rather that% a
011111v evil. g"Ant. Tvprv"njs a fetidu of pttvft.-Mjvv "thaw.
its . 'A ofse John". rot"Intni; diminct tn"11 the 6141WF 11114114?
thnvoStiout the proveft, tnittlies the Identity of crit, Plitasom.
em antl of Phan triukititims at List 2nd kind. Wmn the
expression fit Use -'Xitank! of a 0 , of 2
Own, a Ipmard apnoft Is dat"d for he" c"ecity
lberod CM, I OW flits t2MP. Cates. of Juispose
win. pakdation, or, its is Viserd form, for the (leriv. of 1%
prisma.lised vollrtlimtts wills rftpwi to a pnmluW force,
I I taill of the Cormisanding fust-tism through a
i=v! KM
14z"tiuns tv"1111W Valid for a symtrus Involviest;
chem. chugets not accoutpaulrd ht it rhanse 4 the total nit.
of mols.. ez isomerialkso, Atc systenvi can be the wat
of Irlicaus"it. phtnuowne, inatillestifsp theiawlym in a nit*.
"I I Ise heat calvelty or of therinal isr Imvr c4svffs. lumonuch
lie 11 out 11M flusught WAS a dynaink, Winter of lie I..r
inufre ttmclly as a vohs~ .1 a i-mrT.4
lie in Hel, the tr"tkm between lie land lie 11cantwin-
terpectedosachemocrit.phcnou=on. Ocurfally.thecrit.
resion has 2 titults, ont corresponding to zerfs coucti. at ino6.
of we plivar, the other to Zero canto. W inols. of tbc other
phase. Consequently. there nisy e%6t 2 crit, unips.; this,
.4) [at hu item obtierved only bi smite jwlsts. find winietto-
electrics. Certain anowaticsJ the heat capacity ant utlict
thcrufal and force coeffs. obwvcd in polynien may sho
rrtyr-Cut -Chensocrit. phenomena. N. Thon
USSR/chemistry - Phase Conversions Ma r 51
CLS' "Phase Conversions of the Second Order and Crit-
ical Phenomena: III. Heat Capacity of Liquid
BiwOry Systems in the Critical Region of Layer-
Formation," V. K. Semenchenko, V. P. Skripov,
lust Phys, Moscow State 13 imeni M. V. Lomonosov'
"Zhur Fiz Khim" Vol XXV, No 3, PP 362-368
Using specially designed calorimeter, measured
beat capacity of binary mixts (triethylanine-
%0 and nitrobenzene-hexane) in crit region of
layer-formation by method of cooling. Results
USSR/Chemistry Phase Conversions mar 51
(Contd)
compared with those by direct --c-a-curc-man-t. Heat
capacity in crit region, rising after 1-1.50 to
temp of layer-f ormation, passes through finite
max. Secondary max appiars in absense of crit
concn of mixt.
185Tlh
Amdamental ce" and dtdWdm *I lk*=WY- I
--micsofsolutions. V.K.semenchenko. DohkdyAkd.
Saak S.S.S.R. 77, of the da-
tivity coeffs. f am derived for 4 types of only. in binarY
x st"I s. (1) the soly. of both components Is limited. Lc. -
tare L:n The thermodynamic equil. of the mist. with the
re phase%; (H) the suly. of hoth components is limited.
M the mixt. cannot lie In equil. with the pure phases. only
with a mist. of another compn., (111) the wAy. of one com-
patient is limited and the sofa. can be in equil. coly with b
that componto t; the soly. of the other component is
unlimited; (IV) the soly. of both componcuts is unlimited,
and the iota. can be in equil. only with a mixt. of the given
cmujn,, The component that at no finite concti. can be in
cqjltab the mixt. is defined as the solvent. Und.- Ibis-
d in sq. soln. of Ag7l(NO.)tand AgNIf,(%&,,j, the
ilete m6ci m
sol of which increases to comX %Wty at the (e
I I&
of W 11.0 is the solvent even when Its concn. It of 1 9
order of O.OUOI%. In case 1, one has for the tInTTodt-
'-,. P'. > J... > R..
"Mic P!)teutisds P*, - 0,
wnere ,; refem to the simIle subsLance. p4 to tze same, out,
stamiumixt.,asId"atestri. ForlN.Si(ithcompoutat
In&mIxt.=td.Inj),ja,~,