SCIENTIFIC ABSTRACT KOCHETKOVA, L.I. - KOCHETKOVA, T.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000723510020-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 19, 2001
• Sequence Number: 20
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

SOV/137-56-11-Z3100
Translation from: Referativnyy thurnal. Metallurglya, 1958. Nr It. p 182 (VSSR)
AUTHORS: Beskov, S.D. Kochetkova, L.I., Golubeva. R.M.
TITLE: A Survey of Volatile Inhibitors (Obtor let uchikh ingibitorov)
PERIODICAL, Uch. zap. Mosk. gos. ped. in-ta. M7. Vol 99, pp IZ9-145
ABSTRACT: A list of the methods of application and the characteristics of the
protective action of 69 organic compounds investigated as possible
volatile Inhibitors published in the foreign and Soviet literature.
Bibliography* 54 references.
V. P~
Card 1/1

==To 8-D-1 tOCUMVAo Lelel OOWWjq R.N.
Vapor of ettianelaidue and its Oarbouste *&It. Vch. sapo "on
99tl4?-V#q 157o (KM 12t3)
(Ithawl) Clapor Proll-v")

83M
$/O8D/60/t33/W9/'0ftt2l
A003/AOO I
AUTHORSt Nukanov# 1,P,,11osk*vp Sobel,
Tl=t The Interaction 6t 0=6entratled Nitric Acid With Carbon su~ol
MIODICALt 2hurnal. priklaftoy Wall, 1960. Vol. 33, No. 9. PP. 2084-20%
14
IMS The nature and the mechanism of corrosion dostructior. of carbon
steels In concenSrated solutions ot n1tr1o sold were studied. rn the overl.
c so
ments Armloo ArorPaM steel-Pj 40 1 ~~ th A carbon content of 0.045. 0.195,
0.39 &M 0. , respectively, werSausod. 11 samples were Immersed in sold
solutions with a concentration from 70 to 92 94% HPO 1hty were covered with a
dark-gray a passive film which could not be ;lImInaal by washing. In a 95-99%-
solution gases are liberated very vigorously during 1-2 min which points to the
active Interaction between the metal wA the sold, The **%&I surface assumos
a dark color and on the metal-sald Interface a concentrated solution of Po(**#3)3
is formed, The conclusion is drom that with an increase In the carbon content
the dissolution rate of steel Increases. With an Increase In the carbon content
of stool the amount of nitrogen oirAdes In the M*3 solution Inare"os. I%* con.
contratlon of Iran Ions In the sold solutions after their Interaction with the
Card 1/2

83M
S1tW1fPA33100qAO"21
A003/AOOI
The Interaction of Concentrated Nitric Acid With carbon Steel
steel samples confirms the conclusion that the dissolution rate of steel in
&o1d solutions dop"s an the carbon content In It, This Is explained by the
greater heterogeneity of.the stool surface and by the number of cathode wmJ anode
sections with Increased potential diftes as. It was also established that with
an Increase In the W'?3 concentration mid In the size of the crystallito grains
In the stool composition the rate of Uttercrystall1to corrosion increases. The
destruatlon of Armoo !rm in highly-ooncentrat*d (97-99.5$) solutions takes plao*
mainly at the expense of Interarystallito corrosion. The weight of oarbon stosl-
40 " .70 dooreamos due to stole d1ovolution of Iron. The corrosion rate of
carbon steel In vapors of nitric "Id changes analogously to the corrosion rate
In the corresponding solutions. The dissolution rate Increasts also with the
temperature. The temperature coefficient within the range of 2O-3DOC is very high,
within the range of 30-WC It decreases attaining Its 11mit value of 1.2-1.25.
There are 11 figures, 8 tables and 11 references- 7 Soviet, 3 English, I Oarman.
ASSOCIATIONi Hoskovskly gosudarstvannyy p*d*gog1th*#kiy in*%-Itut (Moscow state
Pedozoateal Institute)
SUBMITn s March 2, 1960
Card 2/2

KOMMUMAI W.I.
a
Asprisnos In worklm with sabool phplai"s an bealth *""-
lion of obild"20 Gis.1 "a-66.210-55 7 134. (nn 712)
1. Is Safttowskop tam saaltaroogo 1promsbabsulla.
(Sealth eftostion)

MOKWn'. T.A.1 ;M~-- At-1*4 p rvd-; SMMMV, A.A.,, teklm. rgd.
(Nower7 devicos Of OlsetrOu" dIgItAl cm;mterej Za
ustrolstya s2skuvwWu tol*Mkb Vehislitelft7kh mashin, No.
akwas 'Bovetskoo radio#$ 1961. 126 p. (KMA U110) ~
(21"tr*RU digit&2 em"ters)

NEsKk7A=p AfXo.o 4W#J NDCIMMA# NJ4; UTIRMA, R.P.
Aeotyl derinUr" Of Pfttfi*th"OWenv*m*. Dokl.U WU L16
n0*511096-1098 I I". OMA U15)
is lutitut flmmt*orpnl*b"klXk~ Soyollaftly AN WAR.

I
08MVp lowtantin Daittlyntehl PASMOT, litevolod TUdlairovishl ldclzk
IOTA# X.A*O rods$ SUMUMp Tu.l*# redol MMffq B.lfv tok6. red.
(Handbook on radio amwn-mftt davloos) Spmoabnlk ;o radiolmarl-
tellays priboram Pod red O.AaMme"o Moskrat l9d-vo 93mUkoe
radiost Part 2;-j"uZ; m"murItC devioes and IwUwmat oseU.
latoral PrIbory dlia I=m-eniia chantoty I imerltollMs Ovemmewl
19W. 203 p. (Rafto iwaaure~te) (KMA Uo6)

LITMMKO,, O.N.1 MSMXOVO Volel FELID, Y&.N.j profs, ratsententj
AYZBOVI M.N., profog retsenswit; KOCHMOVALI.A*p rod,
(Tbeory of nommifom lines arA their use In radio engimer-
ingl Teoriia noodnorodrarkh linil I ikb primenenio Y radio-
tekbn1ke, Moskva# *So"takoe radio,m 1964. 535 p.
(MIRA 27W

OSIMO X.D.1 PASYXM# V.V.1 RSWO G.A, red.; GOLOVANOVA, L.V.,
red.1 X.OC~~~ red.; YUKOLEVAj T.V.p red.
[Reference book an radio maturing devices) Sprarocbnik po
radloizteritelliqu priboram, Pod red, G.A.Remosao 14oskvag
Sovetskot radios Pt,5* (Supplament) Dopolnitollnela.
1964. 397 p. (MIR.A 17t6)

HMaUSUV, Xikhall N.A., red.
iMicrombilaturizatIon WA xiniaturs electronle equip-
mmt using nonlitsar rsslatimces) MlkrmJnI&tiurI&&'-
talimi I &lkro#IsktrcrAk& na nelineinykh soprottyle.
nitakho Moskvsp Sovetakoe radio, 19C5, I.ES p,
(MIAA 1811)

KMZ# S.P.1 GRIMCIMVt A.S.,, k&W* tekhn, rAukp retsenzent;
XRASWOV# I.F.t kaM, tekho. nauko retsment; GELIM, I.N.v
red.1 XOCMMj6&A. red.
[Searching for faults In radlooloctronto systwu usinp a
functlonal test zeUmd) Polsk nelspravnostat v redloslaktran-
nykh mistmakb metodou funkta tonal IrWkb Frob, MDskvs, .13ovot-
skos radlo, 1965* 135 p, WRA 18-4)

KocHETWVA,. N.J.; BUWVSKITq LI.; SHIBAITY9 V.N.
Struatilre and functicm of mmleotift dlpho"hato ansrso
Blokhlalla 28 nooA#741-750 32,-Ag 163. (mm 1813)
1, Institut khWl prlrodnykh soyedinenly AN SSSRp Moskva*

ZOCEMTIGTA, N.M.
Ostracods, In the lower Suan subsiage In western Mashkirla.
Top. geol. vool. okr. lb=. platf. I Wsh. 'Urals mo.b5-37
159. (Bashkirio-Ostratods. Yossil) Oau utu)

KOCHETKOVA9 No Mog CARD GtOL-MIN SQrSt "UPPER PERMIAN
y
OGTRASGDA Of W98164H UAl"K AT AND THEIR STRATIONAPHIC
SIGNIFICANOto" UF*q 1960, (SARATOV UTATK UNIV in No Go
614
C"ERNYINSVSKIY# MINING-990L IMST OfABASHKIR WILIATI ~PZ14
AOAD SCI USSR)6 (KL9 3-61t 207).
96

KOMTKOVAO N.M.
Strativaphis correlatles of upper Persian sediments in vistern
-
Bashkiria based an astratods. UP, gtol. vost. okr. Bus tr
1 IVA, Urols. no,41134-152 159o (14iiA
(Bashkirla-4vology, Stratigraphle)

3/576/61/000/000/004/020
9032/9514
AUTHORSt Kochot~~a and Rezukh.ins, T.N.
TITL19i The specifie heat of gallium. antimony and their
intermetalli* oompoundsot high temperaturts
SOURCE! Soveshchanlys po poluprovodnikovyn materislan, 4th.
Yoprosy metallurgii I tiziki poluprovodnikov; polu-
proyodnikovyyo soyedineniya I tyerdyye splavy.
Trudy.soveshchanlya. Moscow, lad-vo AN SSSR, 1961.
Akadbmiya nauk 838R, InstitUt motallurSIL In*nI
A, A. BAykovs, Fialko-tekhnicheskiy Institut.
pp-34-37
TRXIt The gallium and antimony employed was 99.99% pure
(zoTial recrystallisation) and the compound G*3b was obtained by
heating a stoichionstrIc combination of G& 'and 3b In evacuated
quartz ampoules, followed by struttural X-ray analysis. it Is
stated that there to no published Information about the specific
heat of QaSb. The specific heats of the above substances were
measured by the method of mixtures In a massive calorlmet*r In the
following.t*mp*rsture r&nS*st 20-7000C (Ga and Ga5b) and
Card 1/4

The specific heat Of gallium -9/576/61/00o/000/004/026
B032/95i4
The discrepancy is ascribed to the fact that Schub*1 did not take
into account the cooling of the specimen as It drops from the
furnace into the calorimeter. 11sat losses by evaporation of the
calorimetric liquid were not corrected for by Schubel.
There are I tabla'and 8 referencest Soviet and non-SovIet,
Card 3/4

The specific beat of gallium ... 5/576/61/000/000/004/020
9032/9514
Table,
Amount or Temperature range, c
ac: p
Card 4/4
r"jma (Ga I I I $1N)
31311-MIOI 0,00100
4M,1-30.05 0,0613D
to I= 111.2-30.02 O.Ow
612,5-M.00 O.MW
712,0--N,02 O'MM
cab
312.1-40.01 0.06161
431.2-M,01 0.0=1
SIt.$--AOO 0.01M
611'1~-20'02 0.06w
W13--moof 0.0"M
C06m (Anti man )
313,9-M.01 O.W10
4n.0--m.011 0,06416
$13.2-20.01 0.05"
of,?-M,00 0.056t0

36799
0/137/6
AO%VA 10 1
AVrfl=o Kochetkovao V. N.j, Resakhina, T. X.
The heat eapaoitles of p1lium, antisony and of their intermietalue
compound at high temperatures
PERIMICALs Referatly"y dwrnal, Netallurglya, no. 4# 1962, 6 - 7, abstract
4144 (V ab. *Vopr. metallurgii I f1s. poluprovoidnikovIO, Noscowe
AN SM, 1961# 3k - 37)
TEXTs The heat oapacitles of 99.90 pur* 0& and 8b and of O&Bb compound
were meaxured, by the method of wAxing In a s"elve Cu-calorimieter in the tespers-
ture rw4ge of 2D - 5900C for 3b kd of 2D - 7000C for Oa and O&Sb with on SOCUrwy
of 0.2%. The obtained values of mean heat capealties.Vers rooomputed Into trus
speoifla heat "paoities by the fonoda
OP(t - WO) opdto
Mw temperature dependews, of tru*'molar beat "psolty is deserlbed IW the eW-
Card 1/2

S/13?/6z/000/00k/OOcv2DI
The Mat capacitUs of... AOWA101 j"
tiorAt for Oa op - 6.445 3.72 10 t "1/4"m.g-atom; for 8b
+
+ 5.644 10-3 t oWdegmog
-atml for Oa8b op a 11 .313 + 3.042 - 10 t
The obtalmd maults Wa well with the publidod data@
[Abstraoteris notes Complete traftlatlon]
C&M 2/2

KOCHETROVAO Memo
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Now Vtoean Ostrao" species In Bashkiria* Palsont. thur. no-P
7341 ; 6/,. (MRA l8t2)
1. Gorno-geo log I cheskly institut Bashkirskogo fillsla AM SM.

raise) nmWAO IsA*
[Imstructims of saptatme of vowels amigating botmen Smthnu
SUVALU ckf)wqa ImIA (Tuprold Straits Un Gate Strait) or
ftp NowlUs ad %be Port of lpoft an tU ?=lad Rival jutmb.
t-44- dlim-kapitemv xWov o p2qwmli msbft NORM IWON"llskip.
mi pnUvui (10amrskim Sharmt1mrskimi Vorotamd) IU mg ZboUp.
MU I portom Igarka-sm reks Zaiwi* Nomkvap 1960. 22 pe
(KMA U17)
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Title i Tho Effects of MUcylAto Thompy on C*pillwT ftrma31li-
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Abe Jour S Iter 1hur J101., so 3s 1959o IW
Author I zfthetkofts Lp.
rhot Swasibirsk Ndjmj jusitvu -e,&,~vq
AM-1
Title 00blittOW Reftex VesculAr Reactioas
SUMUOU'vilth Rbomttn Vith owsid6rattaft t6 th's
PIOU MA 811pdtImmo Of %WtUAr Md Iksopharyupal

Orig pub Tre YAMIM.Molp Md. la-taj 1"7, 97, g?&"
Abstract I In mot of the psUAnts (12 - 98 y"" of 60) vIth
A "r"44 fbm Of rhaufttlem in the seuu VM90,
th4r0 V" W46d an vastAble backammd by piethravo.
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Obtained by Addition of Mercury bolts to Olefins in an Amino Xedium.0
Inst of Organic Chemistry, Acad Sol USSRO 13 Feb 47.
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AUTHMS I Nessoyanovo A* Not Usabor of the Acad*m7j 20.vlh~%-
TITUt the Synthesis of AWIforrecones by Irisdol-Krafts Reaction
P
Sintes'sAkIlterrotsonov roaktslysy YrIdelya-Kraftes)
(
PBRIODICALi Poklady Akadesil Vauk MR# 1957, Tel# 114t Ir 4, ppo.8so&8s2
(USSR)
ABSTRICTo The authors were the first so describe the alkylatlea reaction
of.forreasno by hzloldal~yls In the presence of anhydrous ohlo.
realualnund.,The surplus of haloldalkyl was used assolvost. the
authors succeeded In the present work to carry out the saas re-
action without having to use the surplus of haloidalklI..Thors.
by the yield of the moso- and dialk7lderivatives of the forre-
can* was Increased# As a solvent the used n-hoptans or absolute
ps trolous other (boiling poll it Oo-ONC). By forrooons
tion through halsitalkyls (014~osothyl I ablorsisepropyl) *nd
through unsaturated hydrocarbons (ethylene) the authors have
obtained hitherto 1kaknown alky1ferreconost a*thylforro**A" vhoso
two alkyl groups are In a nucleus of the eyclopentadlenes Tho
Card 1/2 isomori+lkylforrooones wore separated ahroastographleal27 ever

/1AC- rA.,.~
AUTHORS: Noonoyanovt At log Academician, and
Koohatkovat No So
TIM: A late on Ferrscone, losologves with a Tertiary Alkyl
Radical (0***logl forroteons. 9 trotlohnys alkillva
radikales)
PZRIODICALs Doklady AN BSU,, 1957, Vol. 117# Ir 1, pp. 92-94 (USSR)
ABSTRAM. Among the number of alkyl-forrocones, which have boon
known up to novg a series of monoalkyl hemologues (01 to
0 war* produced$ and furthermore di- and polyalkyl
hiaLlogues. The Infrared spectra Indicate, that the
dialkylforroeenoo contain both alkyl substituents In the
same cyc2opentadione ring, In the present paper Isobutyleso
was employed spart from haloidalkyles for the purpose
of alkylising. According to the conditions, which were
selected, up to 50 % of nonot#rtl&ry buty1forrecone (at
a total rate of production of alkylized products of 30 %#
table 2) we" obtained. tertiary butylterrecone, di-
tertiary butylforrooons and di-tortlary smyl-
forrecons each contain a free cyclopontediono ring and show
Cnr4Vjt-. characteristic frequencies in the range of 1003 - 1107 as-,.
A Note on.Yorrooono Hosologu*s with a Tertiary Alkyl 2O-l.Q4/42
Radical
A comparison of the values found for molecular refraction
shows# that In the hosologuous series of alkylferrecones
a habitual additivity (nadditivaost") of molecular
refraction occur* (table 1). This is in accordance with
an almost complete Identity of the absorption curves In the
ultravielstorangs, as well of ths, forr*ctn* itself as of
its homologues, The difference between the molecular
refraction found bore and the sun of the atomic refractions
of 0 and H In the ferrocens homol9gues fluctuates between
13t5d and 13#69 03,74 on the average). It comprises the
atomic refractions of.iron and the inaroaant of the
forrocono structure (W combinations and others) and, on
certain conditioneg say be called forrecene-increaent.
This value to the case of forroesnoyields a computed
molecular refraction of 4801 (not 46,8, as according
to reference 3). So statements can be mads, concerning the
stobilitj of this value In the came of other forrecone
derivatess There follows an experimental part with the
usual data, There are I figuroal 2 tabloss and 4 reforlactst
cat&-410 3 of which are Slavic.

The Interaction of Ferrocene With Olefinets 62-2-23128
tain tri-i-butylf rroctne (43,5;4), melting point 880C and tf-
tra-t-butylforroo:no (21#4A), boiling point 195-2ooOC. The
measurement of the IK-spectra of tri-i-buty1forroceno and to.
tra-t-buty1farrocene showed the absence of the characteristic
frequencies within the range of looo and 1107 ca-11 consequent-
ly alkyl group* exist In these substances In both nQclel of
cyclopentadiene. The IX-sp*ctrum of pontaaethy1ferrocono., how-
ever, shows the char
.joterist.ic frequencies within the range
of loo3 and 1W ca' , and thus combines all 5 nothyl-proups in
ono nucleus of o7olopontadiene. There are 5 Slavic ref*ronces~
ASSOCIATION* Institute, for Blement-Organic Compoands AN USSR (Institut #I*-
m*ntoorgsnichesk1khsoy*dinenIy Akadeall nauk SSSR)
SUBMITTEDs October 5# 1957
AYAIL&BLEs Library of Congress
1. Per"4emi-Exchangs reactions 2, Mefines-Rubange reactiom
3. Alumimn chloride catalyst-Applicatlans
Card 2/2

5 (3)
AUTRORSt Nesmeyanovg A* X.# Academician, WY/20-126-2-22/64
Kooh*tkova# So So
TITUS Pontsethano-difer"oens (Pentastanodiferrotsen)
MIODICALs Pokledy Akodeall nauk SSSR, 1959t Vol 126g Xr 2.
pp 307-309 (USSR)
OSTRAM The authors have realized the reciprocal effect of forrocons
with a great excess of 1#2-41ohlo" ethano without foreign
solution, Thlo forms a continuation of the study of ferrooone
alkylation under the conditlons of the Priedel-Crafts reaction
with halogen-alkyls and alkylenes. low# instead of diffeTeovMt-
ethane and relatively high molecular resins (which he,* a
structure of several forrooono nualsig due to there being
connected by 0~2-092-brldgos) they obtained a series of
polyethano-po~yfsrrocenes* These contained no Wogen# are
soluble In chloroform and'Unteno, but not In methanol* They
differ fromlesoh other by t%eir solubility In ether. This :
different solubility was utilized In **paratine the reaction
same In individual substances, The substance with the least
Card 1/3 molecular weightt with a doeomposition-tesperature of 1300t

Pentaothano-diferrooone
WY/20-126.2-22/64
oontalned#.acoording to the analysis# 2 forroatne nuclei and
5 ethane bridges* Its malsoslar weight proyodo that It was
the substance named In the title. According to the Infra-r*d
spectrums this substance a&& only have the structure of model
(l)o A further proof to the donsityo compared with hrrocorkst
which Indicates a very dsaso packing of the carbon &toes la..
molsouloo the substance under r*vI%w at "on temperature
exhibits no Dobyagras of a crystalline substance. this can
be caused by an arbitrazy.outual orientation of the tun-
shaped molecules alars slog axis# time oonsualse Investigations
will be noosseazy to prove the structure of the aforementioned
substance chemically., According to provisional resultst:its
brouluating 2sad to pontsbro60-cyclopentane. The polyethan*-
ferroosa*s# with a higher (about 1000 and 2000) molecular
weight can be Isolated thr*ugh freationated precipitation
with methanol, They are less soluble in other and contain 4
or 8 forrocene residues, According to the analysis they are
closely connected to the firstmention*4 substance and produce
possibly 2 and 4 similar molecules which are bound by ethane
bridges. This Is confirmed by Infra-red spectra. Thors, followle
Card 2/3 finally$ an experimental partq entitled IP e r r o a a n o

Pentsethano-diferrocone
SOV/20-126-2-22/64
a n 4 D i a h I o r o * t h a n a The theoretical
calculation of the donsit7 of the substance I was made Uy
O#-Y, Btarovskly# undsr the supervision of Prot* A* Is
Kitaygorodukiyo latra-red spectra were mi#asured by N. A.
Chumayevskly In the laboratory of 1. V. Obrelmovp Acadoulclam.
There are I figure and 4 references, 3 of which a" Soviet.
ASSOCIATIONs Institet slementoorg"Ichoskikh soy#dlnoniy Akadeall nauk SM
(Institute of Slazental-organto Conpounds of the Ao&domr of
Sclenosep 9331)
SUMITTIDs January 8, 1959
CA" 3/3

28738
9/026/61/006 011/004/004
%J 00 D038/Dll3
IVMRSI Kochatkovs, V.S,# Haterikovat Mit and Slinkin, A,A.
TITLEs Forrocene
PERIODICALi Pr1rodaj no. 11, 1961s 98-100
TEM This article deals with the structure and application of various aroutic
compoundn, particulurly ferrocone. Scientists from mWq countries, Includinig A.S.
,Iesme~anov of the USSR, are aentioned in connection with the development o forro-
cone - a diamagnetic organometallio compmmd with a dipole nozent equal to 0, X-ray
analyses have shown that, In the forrocene molecale, the iron atom is in the mean
position between the cyclopentadianyl radicals lying in parallel planes, the carbon
atoms af the upper ring being located above the gaps between the carbon &too$ of
the lower ring, Two horizontal five-wabored rings with alligned CC and CH bonds
rotate in parallel planes around the central iron atom, which Is sizilarly connec-
ted with all ten carbon atoms. Wickelcenop cobaltocene and other similar compounds
are likewise constructed. In the last few years, a sufficiently accurate Ida& or
the electronic structure of these compounds was originated. In Investigating the
chemical properties of ferrocens, it can be readily seen that, In amAy reactions,
the metal does not expose Itself in the molecule and the reaction passes along the
Card 1/ 3
V*

'srql_n
sni"6/4 l'/0r)o'/0 11 /00"./001.
Ferroceno DOM/D113
zoleculo's organic part. Like benzene, ferrocene Iri, cai~able or sib:41tution reac-
tions of its own hydrogen atome. Not all the metallocenes aro as resistant t* oxi-
dation as ferrocene; nickelcone, cobaltocene and other *cones" a" resistant on17
in the form of cations which do not Induce reactions chtracteristic of arolatic
compounds, whilst in the form of neutral compounds they exist only in very ptWe
nitro,goen and are very sensitive to oxidation. Cyclopentadlenyl rings can be conneo-
ted with the central atom of the metal not only covalently with the forzation of
multicentric orbitap but also with the Lon bond. Dicyclor-entadienylaangansto Is so
constructed. Many so-called compound astallocenes are now knoun, uhich have only
one cyclopentadianyl radical In the molecule, the second ring being composed of 00,
NO groups otccontaining W-electrons. Similar to ststallocenes are a class or
wareny", t~eA the central atom of the metal is connected with two benzene rings,
parallel to one another - for example, dibensolchrome. Discussing the various appli-
cations or ferrocene and other metallocenes, the author states that these compounds
aro still In too early a stage of development to talk of their wide applicationj
however, "cenes" and other substances are used as antidetonstors. Several are anti-
burn substances - In their presence metals are more resistant to the errect of fire
and high temperatures. Ferrocene Is used in the redox polymerization of styrol,
whilst a similar titanium compound is the component part of a catalyzer for obtain-
Ing polythene. Soluble rerrocene derivatives can be used for pharmaceutical v4r-
Card 213

Ferrocene
26738
8/026/61/000/011/004/004
D038/D113
poses. Data have been collected on beat-resistant ferrotene derivatives containing
both Iron and silicon atoms In their molecules. The chemistry of benzene, naphta-
lens, anthracine and other aromatic systems is being developed for similar purposes.
In the very near futurej now aromatic systems will come into being; the differences
in their properties will depend not only on the dAmerence in the substitution pro-
ducts but also in the central atoms of the metals uhich ccnatituto the heart of the
molecule, There are 6 figures.
ASSOCIATIONs Institut clementoorgmicheskikh aoYedinenly AN Sm /Moskva/ (Inati-
tuto of Elemental Organic Compounds of the AS U93H/Moscou/).
Card 3/3

IL
5.1100
AUTHORS:
TITLZ;
PnIODICALs
2205, 1115, 11 Of
S/020 61 136/005/017/032
B103
Nossoyanove A@ lot Academician# Koohotkovat No
and Matorlkava# R. D&
Aostyl derivatives of pentaothans diferrocone
Doklady Akadosil nauk $382# V. 136# no. 5# 1961p 1096-1098
TXXT, The authors correct the composition of the substance pr vlovely
termed "diforroosnyl ethane" by then (Rot. i) (molting point 1;500).
Actually# this to a mixture of Isomers: dlf*rrooonyl ath"o-l"I
(molting joint 147-14900, and diferroconyl ethane-1#2 (molting point
192-192.5 C, small quantity). This mixture was obtained by reacting
forrocons with 1,2-dichloro ethane In the presence of anhydrous A1013
(in addition to pentaothan* diferrooese, PZDP). The authors wore able
to isolate the Isomers by a modified treatment of the reaction productso
I.e.# after chromatographic purification on aluminum oxide in benzene -
a-hoptan* mixture 0:1). Diferroconyl *than*-l,2 Is Identical with that
obtained by A. N. lessayanov and 1. 1. Kritskaya (lots, 4t 5)t wW
cam 1/3

Aootyl derivatives of pentast"As
A. N. Nessoyanovo X. a. Porevalovat and Yu. T.
authors further correct the confusion (Refs.
sation product of formaldehyde wAh f*rrooono
structure CiArs/ CH2 CIOBOYO (so* Rot.
2030
3/020J61 /136/005/017/032
B10312200
Votynyuk (Rot. 6). The
4t%9#10) of the oondon-
with a substance of the
ii). Actually# this
condensation product was-1,241forroosoyl ethane. The authors acylstod
PZDF (Rot. 2) with acetio anhydride In the presence of 85% phosphoric
said, and obtained mon"oetyl PZDF* This Is a yellow povd*rq well soluble
in alcohol, acetone# and benzene# slightly soluble In water and other.
Aoylation by aoetyl chloride In the presence of anhydrous aluminum
chloride in mothylons chloride (as the solvent) give diaostyl MY and
several polyacetyl MP. The former to an *rang*-yellow powdert and
was recrystallized from a heptan*. ?he authors found that these aoylation
results confirm the strua;ure of PIDP previously assumed by them.
N. A. Cbumqovskiy studied the Infrared spectra of the afore-mentioned
soetyl derivatives, They disclosed a oarbonyl group# and a free
Card 2/3

W399
8/020J61/136/005/017/032
Acetyl derivatives Of P4At&Gth&ns ... 2103/D208
forrootne ring in monosootyl MY. Diacetyl MY also contains the
oarbonyl groupt but its two &o*tyl groups belong to two different rings
of MY. The presence of two noa-substituted rings In PID? is thus
thought to be oonflrn~4. both MY and its sastyl derivatives are
amorphous# and have no distinct melting point. On boatInSt they gradually
darken, and soften at IOOOC. the heating curve taken with turnakov's
RX-55 (PI-55) pyrometer up to 2000C reveal@ neither tzothersal nor
ondothoraal effects. V. H. Koshin and Ye. 1. Yareabash are thanked
for thernographle measurements. Tu. luo Saaltov determined the spectra
of nuclear magnetic resonaneep which indicate an absence of nothyl
groups in PZDF. There or* I f1gurs# 1 tablep and 11 references:
6 Sovi*t-bloo and 5 non-Boylot-bloo,
ASSOCIATION: Inatitut slosentoorganichosklkh soy*41nenly Akadeall
nauk 8882 (Inatitut* of Blosental-organic Compoundeq
Aoademy of Soleno#sf USSR)
SUBI(ITTZDi November 90 1960
Card 3/3

8102 yomf$/006/013/02 0
B103 M7
AUTHORS. Nsgmsy&n*,v# A# lot Academician, lorshak, V. T.,,Corr*sp*&41ng
Member AS VSS10 foyovodskly , V. 1. t Corresponding Member "
13 USSR# 4*Qh4tk2v�_t_J12 ev Sosing S. L.9 Materikovat 2. Wet
Dolotolkovat T. 1,j Chlbrikins V. M.,~and lathing I. No
TITLE: Synthesis and some optical-magnetic properties of pol'y-
ferrocenoll
PnIODICAL: Doklady Akadesit Aauk $961, v. M, no. 6# 1961, 1370-1373
TEXT: The authors studied the magnetic properties of ferracene derLwativestef
1) of the polyforroconyleass (table is nos. 1-6). 2) the polydilsopropyl-
t*rrooon* (Table i, nom. I-S)o 3) the polynothano- and 4) the POIY*thano-
polyforrocones (Table Is nos. 9-13). They were synthatised by: A) Poll-
recombination., To 1) and 2)o I pals forroasne (or of Its dileopropyl
homolog) was treated with t sole tertiary butyl peroxide In nitrogen
atmosphere at 2000C.t i) and 2) are assumed to be formed as follows: the
Butoxyl and methyl radicals formed during peroxide decomposition separate
the hydrogen from forrocene (or the a-hydroggga). The radicals thus formed
'Card 1X5-

Synthesis and some
recombine and form linear 1) or 2)v easily soluble In b*nzone. Ln In-
oluble polymer (Table lt:noss 5-6) with a two- or tridimensional network
truo,ture to formed simultaneously. The conversion of forrocone to high-
:
olocular products amounted to 25%. S0#. 1-3 have a softening temperature
:f 290-3000C and are a dark-red powder# whereas nos. 5-6 bad their softening
temperature at about 4000C &nd were light-yellow. D) Polyalkylonation of
forrocone by nothylens chloride and 1#241ohloroothant In the presence of
anhydrous aluminum chloride. Aluminum chloride solution in 50 al of 41-
halogen alkans was added gradually to 40 gferrocone dissolved to 250 al dry
dthalogen alkans. The mixture was stirred for 6 hr at the boiling Sespora-
turo of the solvent. The next day# 10 1 altminum chloride In 25 al d1halo-
gon alkane were added and treated for 6 hr #a above. The stituro was
decomposed by too and HCI and treated with sodium oulfits. The obtained
and 4) were well soluble in bonsen*1 differed, howov*ro by their solubility
in other. Table I shows the molecular weletits, the always equal g-factor
and the sagn*tIo characteristics of all subetances pro4uoed. The docomposi-
tion temperature of 9-13 was 115-12000. All substances or* amorphous
powders, nos. 9 and 10 lIght-yellow, no. 11 er broVA- Nos. 10 and 11 are
of a chemical composition similar to that of n:!-9 (pentaothanodifferroasno)a
. T37/006/013/020
8102g0j?
BiO3 21
Card 2t&T-

23854
8/020./,61 /137/0"/0 111020
Synthesis and ease ... B103/12i7
They consist possibly of 2 and 4 molecules similar to the latter, connected
by ethane bridges. 4-5 methyleAss In the molecule of acs. 12 and 13 belong
to 2 fsrrocone radicals. They do-not contain halogen. The Infrared spectra
of nos. 9-13 have frequencies within the range 1000-1100 cs'l. To 1).
Derivatives 1) having a a-oonjugation between the f*rrocone links give a
signal the electron paramagnstia resonance (*-p-r) , similarly to the poly-
aromatic hydrocarbons, This cannot be explained by the presence of a
corresponding quantity of the oxidised form of the f#rricinius cation.
Table I shows that also polymers In which the forrocens links are separated
by the -CB2--Mi- group give an a. p. r. signal. It Is known that the
delocalization of the unpaired electrons between the two phenyl rings is not
prevented by this group# In the substances described h*rs, which give an
a. p. r. signalt this signal Is the smaller, the smaller the number of
.Jerrocens links to. This sigual vanishes in 2). Polya*rs with a lam
molecular weight give no es"'pa r. signal In the solution (bensent)l but in
solid state. This Is explained by the fact that the Intramolocular
Interactions cause In solid state a conjugation of the adjacent polymer
Molecules. This causes for its part as *. p. r. signal. III polymers
dard )/*,v-

Synthesis and 90819
9/020161/13lo/006/013/020
D103/D217
giving this signal show a Stagle symmetrical lite of the *. p. r. of the
Lorenz type. The I) obtained from ths reaction I Yields a wide so pt rt
line of 120-160 ooratedet its width bAng dependent on the polymer struaturo*
This line becomes broader on reducing the measuring temperature. Its width
to changed most consider 'ably in low-molecular polymers. The authors
believe the nature of the measured signals to be untlarifled, they cannot
maintain that the number I of the unpalred electrons per I member, doter-
mined by a comparison with the standard, corresponds to their actual number.
I may, however, be a certain characteristic of the magnetic properties of
the system,- (4o$. 2-4)4' 9 reaches an anomalous size In the Inooluble
.Ii~:Polyaor no. 5. This Is &soused to be connected with a collective effect of
the forroaagnotic type, The ultraviolet (UV-) spectra of 1) dissolved In
n-oatane, which give an so p. r, signal In solid state, differ from the
ultraviolet spectra of such thstgivo no signal In solid &tat" In the
f 0 no dis-
first case the OV-spootrum agrees completely with that o I orroco
solved in CCI*, It was proved for these spe3tra (10f. 7) that the charge
4 + -
CC14`
transfer takes place here under formation of &n ton pair Yor On the
contrary, the VV-spootrus of suah 1) that five V(O so po r0 signal to similar
Card 4x Sr
23%
Synthesis 'and
some 0/020 61
610
1101
,

t
-that 4 he
0 it

'
fat,
oly
L e
under -*hich t -ohs Ail
hl~
'Otani) to under- con
~ 04M
f0r"do finall
that th
yo the &Ut
eir results
hors Point out
6
concerning tilt UY-0totra Ipp&nAtly con
"Pasudof "romaps"
ll
firs th
e
Sa
of-th*
PO YAUQI*Otld#t and of
hydrocarbons (gets.
and S) the Wyaroaa-tia
Th
7 Sovittabloo and Ino
en are I fleint I tablet and a refereft #a$
U-SOVItt-bloo
th
.
e
publici
tion roads is follow- on", reference to English
anguage
J-
C- D
B
d
o
ran
.53p 894, 1957~-
~
, Rtf- 7: Trans. y&rad.
Boo.
ASSOCIATIOX.. Institut ell
Ment"rirsilchwskM i0
0d1
Y
no;kjy
(tails
tute of'slowntill.c Akadenit nauk S"
*
t
C
o
ompounds a
'
Soldness
f the A6940my of
1
SUBU
ITTED: December 20t 1960
Legend 'to Table-I.
*
5-6) insoluble pol 1) current nuab r, 1-4) linear polyforrocon
l
f
*n,
y
Orroconyloaq, 7
like 7, insolub
polydilsopropylferroc*no, Ila#&
Is 9-11) 1
r
cond
8)

o
ensation Products Of forrocent with Di-Ig
chlorogthmg, 19_13~
2
with Mothylono chlorid
II) Substance,
e, 14) forricinjum cation.
20tscular weight,
IV) 9-fActo
r, line width, core
Card 5A. 5

A Ole Aelso "Oldki AVIIJUMMo A#M.l SLCKMIft O.L.1 $=no
A.Atjj~XMMA# Moo XATMOVA, 1.9,
MagnsUc suscepUbility of polymakanapolyferrocems wd palyferm.,
coWlenes, DW,Al SM 138 no,,D123-W Vq-4e 161
NDA llfil#)
1. Institut 01 - RP * skikh ~cV*dimrdy AX SM.
Irro one-4kpstle prVortles)

1189SUMOV, A.M.0 AkAdOffilki VILICREVSXAU, T.D.1 KOCRMM, N.S.
I'.
*-"rboxyb=$Qy2t*rrqos= ro"uom* Dokl*AX SSSR 138 wo2s39O-M
1619 (WA 105)
I* ImUtut elematoorpMeb"kikh soyd*inealy Akadadi nuk &M

1
2/062j62/000/011/002/021:
V101/3144
AUTHORS i Xosssyanov# At X.j larsanov# M, X.,.# SotkIn&# 1. X*#
Kislyakova, 1. Top &,A6 teaheslovat 1. So I
TITLUs Study of hydrogen exchange In nonbonsaidic aromatic systoas
(cones)., Communication 1. Hydrogen exchange of f*rroe*no#
and son*- and diao*tyl forrocanol, with said#
PkRIODICALs --Aka4saiya nauk 9331a Isvestlys. Otdolonlys, khtsiabookikh
nauk, no* 11# 1962g 1952 - 1936
TXXT# AA iUV~2tL7"tIOA Was &ad* of the hydrogen exchange between the
following, dissolved In bonsones. terroo*no#r ao*tyl forrocene, diaostyl
ferrocon*, or tolueno and tr1fluoro doutero acetic acid a% 250C# and at
-forrocone with doutero sulfuric acid. In imtylated-ferroconseg the .
-douteriua addedas the sootyl group was, removed by 160 - 170 bra standing
In io alaahcUo 109 solution# and the amount of deuterium added an the
oyalopentadl.enyl rings was deterained fron the density of the water ob.
talus& when the cospound was burned# The aospound o acid s benzene ratio
WAS 1 1 3 1 20* Isperiments with CY 3COOD gave the following rats, constants
Card 1/2

3/062/62/000/011/0021021
Study of hydrogen exchange Ino** BIOI/BI44
for the *Sabana@ reaction (sea -b 1)s forrocone j.6*10~41 acetyl forrocens
8
165*10071 dlaootyl forrocon* 7,7*10- 1 toluene 3e1O- Under the given
conditions, benzene did not react with C?3COOD. A 50% hydrogen exchange,
between forroa*ne and D230 4ocaurrod after 5 min* But no Isotopic *qml-
114ri" *as established because part of the ferrocene oxidisoo to
forriolnium Ion# which dove not resat with D2so 40 as has been shown by
op*olal experlaonts* On the other hand$ dtuterims phosphoric sold had so
oxidising actioul hers the @Sabana* proceeded until reaching equillbriums
Th*ro are 6 tablese
ASSOCIATIONo Institut *Ion* ataorgaul cheek 1kh soyedinaniy Akedenti na%Lk
8852 (Institute of Blenontal Organic Compouads of the
A4&dsay of Sainass USSR)
SUBMI"01 March 28# 1962
Card 2/2

,,7
310113144
AUTHORSs A* 2 9jo9h*tkov!A_JbL_3Sj Tillchavskayal To be#
Sheynkert Ya. 1% Sanyavina, 1* Boo and Btruchkova# No 1,
TITM o-Carboxy- and oobydroxy bessayl forroesnes and their
derivatives
PXRIODICALj Akadenlya nauk SSSAo -~.Isvestiyao Otdolsaiyo kbialdheekikk
asukq no. 11# 19629 1990 - 1996-
TZXTs The 12 and VY spectra of the following compounds were atudleds
o-carboxy bonsayl forrocene (A)I o-hydroxy bensoyl forrome, (3) systbeei"d
fro& salloyl chloride and ferrocens In the presence of AM In CH Cl
2 2
solution at 45 - 500C1 0-methoxy tensoyl fmocese (0) obtained by
Z;thylatlnS B with dimethyl sulfate# yield 9.6%1 o-asetoxy bensayl ferrooems
obtained by aostylating 3 with soetio aMydridst yield 95%1 a-hydroxv
beasyl f*rraoen*.(Z) obtained by reducing B wi-th nine aaalgan, yield 77%t
o-methoxy bensyl ferrocene (?) obtained by nothyla%iog I with disethyl
sulfate,-yield 94%j o-hydroxy phonyl f*rrococyl carbinol (0) obtained by
.reducing 3 with LIA111
4' Yield 90%1 and o-sethozy ferrocosyl earblaol, (a)
Card 1/3

o-Corboxy- and a-hydrcxy##*
3/062j62/000/011/005/Oil
3101/1144
obtained by nothylatIng 0 with disethyl sulfates Yield 93A- Ztbera of the
type Clog 9P*-CI(oX)-CO4oH were obtained Vy rearystallising 0 In the
corresponding alcohols* for I * C234 the a,p, was 119 - 1200C9 the yield
89$1 for I a C225j a-pe il7OCo yield 94%1 an& for R w I-C,17, a-P. 79-80009
yield 89%. The spectroscopic studies sboweds (1) both the orystallizOd
and the 411801V~d A showed no tautossriss by ring olosure, the structure
of A Is therefore opew ft-CO-C a forroo4ayl)g although In an
16 4'('F'o
Coog
earlier study (Dokl. AS $6829 1)6# )90 (1961)) derivatives of the tautoods
O-Co
torn Pa-C-0 684wore also synthesized fros this ooapound. (2 With 3 there
Is also so hydroxy quinono tautoserisa# but so intramoloonlar 8 bond
N
0 0 is formed. There are 4 figures and I SaVlOo The a**%
I - 4624
Card 2/3

11062J611000161 1/005/0a I
O-C&zboxy& and a-hydroxy,,4 J101/1144
important Inglish-lanfiusSe reforeace-les Be Le Schaafg.jo grgess Chess#
279 107 (1962).
ASSOCIATIM Iftstitut elemento*rgazichoskikh soyedineftLy Aks,demll mauk,
3332 (Institute of zles*&W Org&'Aio Compounds of the
Academy Of 8016AG08 USSR). Institut Wall prirodaykb
soyedluenly Akadenit nauk SSSR (Institute, of Chemistry of
Naturally ocaurrlag Compounds of the Ae&d*ay of Soleness VUR)
SUDMITTEDs April 4s 1962
Card 3/3

XMIZ f A* No 0 akada"; IMtSAXOV j, Do No I SZTKM p V. No; LWLUWVA p N.Vo;
XWHMOVAO N.S.) XiTMWVA9 R.B.
kdropn isoUpe exabage of ay*lq*nta&9my2mwws*trlcarbaw2.
Dokl. AN WS U3 no,2051-353 ur 162o, (KIM 2513)
2. lastitut 4srmto-wWdwsklkh sopWinw" AN SSM 2. Mlstp-
'kwnspcmd.ent AN SSOR (fir lurnnov)o

NOMMOTs AA* abAwas IOCHMOVAq 1.3.1 MILMIKOVAt R.B.
scission of stadionyl oaqwuds of metals b7
bradme and p0molm bMbrwdto& Dakle AN US 247
(MnA 15112)
le Institat soyedine, AN SM.
Lie compounds

wzX9UMj A.N.; MATZMOVAj, R.B.; KOMTRUfAt B.S.
Preparation of cyolo"ntadiovql motals via cyalopentadievyl th&Ul=o
Isve JUI SSSR. Serekbi-,, noo7tl33"36 JI 63. (MIRA l6s9)
1, InsUtut elowntoorgasdahoskikh seyedinaniy AN =R,
Organs"tallic compourds
(cyclopentadiene)

3/02OJ63/149/00i/01)/025
9144/BI86
WTHORS: Tavorstlyo I* VoL Koahot gwa 1 3 , Zaelavskayal as lie, It.
Nesa*yanovl A# tog Academician
MILS: Absorption spectra of mom* forrocono derivatives
Akn4talys taule SSSR. Dokladjr, v. 149, no. 1, 1961,
"'EXIN Absorpti;2n spectra *or* taken of ac-rl and alkyl ftrroc*no
lerivatIves diasolved in itoootane. Results: 1) The break at 520 OP
deacTibe4 by D# R4 -Scott g Bwaher -(J, Chem. Phjv. 9 35* 516 (1961)) -
-tan not observed. 2) An alaost coapleta eDnforaity sea detected in the
absorption spectra ('280 - 00 n;&) of: a)- n3raal wonowbetituted ferroc*ne~~
homologs, such is sonoothyl and mono-n-propyl ferroceno; b) norsal
heterocyclic dl:vubstituted ferrecene hoaoljigs, such as 1,1'-Ji#tIql and
.11-di-n---ropy.1 f*rrocenel o) normal monotubstitutel acyl derivatives oU
;'erroosne, such as sonoacetyll monopropionrl and mono-n-butyryl forro-
oer.2; d) normal heterocyclic diacyl derivatives of ferrocent, such as
11-diseetyl, 1,11-diproplonyl and 1,11-di-n-butyryl forrooene. 5) The,
Oard 1/3

SIQZOJ63114910011001023~
J,bsorption tpeotra Of SON* B144/Bi86
upectra of tho-heterocyolle-disubstitute4 ,rerroetnt 4erivativea differed.
from those of the corresponding sonosubstituted coapok;nia In the poettton,-
ske well as in %he intensity of the absorptLon bands. 4) The absorption
jipeotrn depend on the nature of the substituting group: a) The difference
17etveen the absorption bands of ferrocene tnd it@ alkyl hotologs is only
An Inalgntfioant Eypgoohrocie shIft of the 440 ap baril was
,)bogrved tog9thir with an Increase, In Its intensity In the order forro-
::on* - normal alkyl forroctnes . norsial heterocyclic 41alkyl ferrocenosi
)) In the 11 pectra of ferrot!9ne coip6unde with electron-acceptor aub-
atituents (monoacyl and heterocyclic diacyl ferrccene derivativert) a
.arkel bathochr5me shift of' the 440 mg bani was c,bsorvedi the Intensity
)f thia band increased in 1;he order farroovie - mnoaoyl derivatives -
ieterocyolic diaoyl derivatives. Instead of the 3Z5 x;A band of !erxrocene,
k band was detected at 318 agi the break was loentel a% 356 no. A flArthor
gtudy will deal with homoo3rollo ferrocene Jerivatives. There art 2 ficurm,
;,n.l 2 tablea.
iSSOCIATIONt Institut #%ementoorganicheskikh ooyedineniy kkadesil nauk,
SSSR (Institute of Slacental Organic Cocpounds of the
Academy of Sciences USSR)
Card 2/3

Ca:?d 3/3

NMWAMV# AoNsp ?'V'; 'MO ""
?snt"tlanWU*r"aws. DAL AN &M 152 no.4iV5.4M 0 163s
(XMA 16ill)
1. Inistutut elmentoorganichookikh so7WJnwdy AN SSSR.

NESMANDY, A.N.j VILOCREVSMUp T.D.; 90CH~NVAX.Sq PAL1151N. NIP,
Synthesis of pbosphorus-containlng derivatives of fe, a one,,
ltv. AN SM. Bor. khts. no.Ut2O5l-;NM 9 163. (KMA 17 11)
1. Institut elementtiorganicheskikh w7edinenly AM SSSR.

NESMTANOV, A.N.t skadsaiki VILICHYMBIATA, V,D.; KOCHMOVA, N.S.
9~.mthools of 1-forrwonyol-2--oarboutboxyotbylene. Dokl. AN SM
152 no.3s627-628 S -163. (MM lb#12)
1. Institut olsomtoorgaidehoskikh sc7odinonly AN Me

AR6017230
AtrMORSt Ttvarakir, . X.; KGCb4Ntk*T& 1*!Mww# A* &#
TITUt Absorption spectra of certain derivatives of ferroceme
SOUNIt Rat. th. Fisika# Abe* UMS
MV SOURat Tro KmIso -12 speklm"11 - ALMIL t. 3s Trp- Is 19A s 3W354
TMO TAM absorption spe~trwvm# ferroeene# absorption band
AMTRACT: The authors Investigated the absorption spectra of fearoo of Its "17i
4M acyl, derivatives In the resion 300-180 va, and also the absorption spfttrs of
of forrovene and their ethers In the 180-230 fm region* The osell-
of all the Investigated bands an calculated for absorptlee. tarlior
ti":t'Elt ming the position of the buds and the laws goyming their shifts
us confirmod. (Translation of abstract)
mm ems 20 "07/

AcaMON Nit, AA033414 810OW16411561=IOMIOM
AVMlls Neawyswvt Ae Me )$ K"betkWas so so; YLUP so Ves
Dondarevo V. bt$ 94"MVP 14
TITISt ALkylatuft of to
SCUICZ1 AN 8WHe DOklW# Te'Wo no- Is 19Aj "-101
TMC TAGM ferrocovAj dkyUtica Triedal Cr&fU;p QtbylfOrT**ft6* dlethWIftrM-
canie, triathyltiorroamw# tort ;~Wel. a butyl to . I PrOlPSMUMS Is
spectmp M speatra
AwraAmt in tMa'vork forrocews vere alkylated to give eO-90% yields, In
coaparison vith two Yriedel Crafts usuwds vhich give 90-30%0 of allwWas,
Ferrocene vas reacted vith othylbradde In the proem* of equimlar wx=U of
AIC;1jand TJAI In a4m7tawl the reaction prodwts vere vater extracted wA Uw
0 a portion sub4sated to vwum distillations The U*-13W (at I M W
fr IwIterroatne wA isomers of Uetbylferz l wA Uw
Iw-15w/lM fraction adidtaLwA & mixture of loweria tristborIferrocausso Mono-$
di-* tri- MA tetft4ak__~~iiewxmws vere slallarly priopsrod. 1R *M M
Ca,4 2/2

RESHEYANOVp I.Nop akadenik; DVORTANTSEVAO G.G.; KOCAM.07A, K.S.;
HATMOVAj R*Bo; SHBIN j NNo
Properittem and stmoft" of dtoyaloponUdiony1morcurys Doklo
AN MR 1r no,WV-490 D 164 (MIRA 18d)
Is Thstltut olsmmmtoorpnichoskikb sclod1nonly All MSR*

F11,
7Z---
&p ~,rylb AS
M~ A
X), 18), ~(M43
to.
rims==

" ~i - AT ~ ),A A 1, k
. I .
I I
i

ACC Nti
AP6002867 SOUM GoDet tM/0286/65/000/0V,/M6/0O27
Ael
AMIM t Noommom I VU'4hq-VSkm-- V, 21) x4gifft-k-Mia'AtIt I Gardlkmp S
ORO I
TXMt A ~Sthod for cbU 22p No. Lwe
Lam
Lamwmcod by INUUM Hotorooriffaula Gomoi-*W AN SSSIR (Institut
elomoatoorganiab4akikh sayedinenly AN SSSR)-/
3OM=t ByuUstoul isobroltonly i tovarvIM snabnp no. 24.1 190# 26-27
TOPIC TAGSs forrocenes to obadcalt orpais dwaistry
ABSTMCTt This Autbor Certificate describes a - parative motbod for forrocas-
artbrequinone in the form of

21!
MA6
1
ACC-Nts- AP6=867
To obtain a produat us*W foir owl# *Llkp and ~rWlcLma flbwe, Uw fenv-
comanthrone is moted with a viogmes d'Wd4.i mampenelon in bommmee Orlse art.
hams I forwala.
SUB COISs 07/ SON DAM 19W45
2A
h4fll

KFS,%VTAhovt A.N.o akad-4miki pATtAtKOVA, R.P.1 .~CCOlYVIAj N*S.j T&9j.:OOZKX, L.A.
Baits of 2,11-dialkyloobsilticinlum. rekl. AN 656R 160 no.W37-10
ja 165, (MIRA ISR)
is Institut slosentoorgarichaskikh doyodinonly AN SM.

f sku It mtk; W.'D~ZKif , A.P.
.4.3.
Abn.-frption spectra or tiv.-vi furro"no derlvqtii-'s-el- ickl. AN SOR
IU, no.4t837-840 V 165. (WRA 18-2)
Inoitut kh 307011nollly AN "SVP0

H f in r oc tr~f-l
re L L da

'. . , .~- , ~~ f
.1 . j f%

WMSYANOVg J,Hsj skadsw~k; Vll,#CMSKATA, V.D, $ KO:H&TXOVJj NeSs
Roaotions of r.-oarbcaybougay! fox roaans # Dakle AX SEER !65 .
no,W35-01 D 161* (KIPA 28112) . .1
2@ VwAtut iolemon tomgan I che ski kb poyvelbonly AN SSM*

SO= CODE I
AUTHOM XssVAYAnoVjj A* NO; Y111chovskays. Vo Del KeSbStkod No L
Offit I-n9=tW9 9 nQ00tallic Cgopoundmi AN 555R (Institut elowntWpnicAlkh
sc inenly
off $MR ri
TIVAS Ma I - - is csrt2N~!n%cY1f9rroantA
SOUAMS AN WSR, Do'T-&4 V, 165 no, 4 1 $35-437
TOPIC TAGSs forrocens pfancIp ;Wphorto Mag cationp chemical reactiont molecular
structure# Ift spectrum: phosphorus chloride, U analysis
ABSTRACTI A study was a&& ot'the reactions bobteen 4ar ~ I; *Usrro~
-i in the prose"o of
nuoloopUlic reagents mob as thiophenol and phow
phosphoric acid. This results In the formation of S. and C6PAstitated and
34arrocaWl phthaUdes. An attempt to acco%&Ush those reactions in the
absence of R was fruitless, Evidently# the first stage of the reaction
is thi formaeog of an alphs-forrocanylooUVI cation, with xubsopent, attack
of the cationoid, center bW the nuoloophilla agent, This reaction is a now
oxaple of tho &lpb&-fsrrocwy2mt)W1 cation reaction# The structure of 3-
forrocettyU341dophonylphthaUde has been confirmed by the findings of ultimate
analysis as well as IR spectral data., Me IR spectrum of this substance contains
frequencies in the regions of 1000# 1107* anid 1763 c3CI, Dims, the Wesum
of a lactone ring may be considered proyWa This was first ocncUWW thocroUG&W
during a study of the rasotd= botiteen o-carbombonsoy1formwe mad phospboru
trichloride. which yielded a substanoo resembling Boydo's aoid ablaride mA
believed to contain a free orolopentedlawl v=lms wA a laatorA rug.,
jJ'PMj 36,4527
SUBCOMs 07.20/SUBMDATZs07:un65/OR1GWs OD4/MRC?s 001
#----A .1 A "Y 1W.* Jul-111-M ,

v
ACC N" AP601M2
SW= COD91
Mt/W2/66/0001005/0938/0940
AUTHMS Noswy*novp As $,I vulohevskg!, V, D.1 joebetkoval St S.
Offis 1houtute,of OCOMM&"a 9MORM40, AGA&U.Sf Od nog, $339-M%stitut els-
mentoorganich6skM soyedinenty Akadad! nauk 333it)
TTTIXI CY011"tion of ft"dZgMftDEL2LsWM!rj* I
SWMI AN SWR. Isvestlya. Swlya khbdoh*AkW&q no. 5p 19"0 9Xj-"O
TCP1C Wast 4YOUSation, Iron compom-49 ferrocene
phams per
ABSIRM 07011ution of in the ws"w6 of owe
tachlorlde at 600C In a nitrogen stresm w f 0 i 1 an Analog of all! W c... (1) Containing
one forrooonyl rim In pl&oe of one for such anslosst'the authors sw
948t that the same somonelaturs, be iRtrOdUAWd &S for Ordinary arONStIC so with
ths, Prefix *Tom for each bewwne ring substituted by the fwnvom ring. Mms, the
(1) obtained alwald be termed Iro-w4hrems
owe 347.25 + 66.093,2s + 346.72
ACC Nts AP601702
e:
Mw Armturs Of (1) was connived by Mt and M Speotrs, &W b7 detendning the nol&-
culAr weights Hence, it is shown that the cyoUs&uon of o-mbwqbmvUwr***w
under the inavems, of PQ fonw a d7-aVwA&di*Wl rings 2w ?*-Ant~ns obtained
11=&qvinow or phUmialfe
readily mcidises to I an stirring Its bowns,
bAution with NAOzs
Under milAsr addising dorAtiomp A to forimed *&o" mt speotre, Inneated
the strootare Of 1044drm
2/3

ACC Hlo Awm
SUB COM 07/ SM DAM 180m" OW Ws 003/ M Wo 001
AL
L!:Er
.~U~ - -- Met %A? Ass to

S/075/63/018/003/001/0"
9071/9436
AUTHORS: Namodruk, A.A., Kochatkova, N.Yo.
TITLE.- A study of the r*action of totravalent plutonium with
arsonato III
POIODICAL: Zhurnal analitichoskay kitinii, v,18, no.3, 1963, 3'1'~_Ril
TVT: Arsenato III Is the most sensitive reagent for tstravalont
Piptonium but thq reaction Itself has been little ostudiedo This
t-Pork w4:ks undertaken to obtain data oii tho composition of complexes
formod, their stability and conditions for the development of
color. Two series of comploxes are fo.-med in this
rvi%ction depending on the concentrat~ion of nitric acid. At low
conc en tra t i on ( - 0. 1 N) the ratios of plutonium to arsensto III
in the complexes are ltl and It2. At higher acidities (4 to ?N)
thefi-e ration are lil, 1s2 and 1:3. Optical density measurements
Indicato that complexes formed in 0.1N and 5N nitric acid are
stable and that the method or molar ration in suitable for the
dr~tcr--,nination of their composition*. The following optimum
cunditiun~-s for the photometric determination of plutonium were
establishod: not less than three-Cold excess of areenazo IIi In
Card 1/2

8/075/63/018/003/001/006
A study of tha roaction Eo7x/E436
4 to 71N nitric acid. The molar extinction coefficient of the
cot:iplex formed (with 1:3 ratio of tho components) under thene,
conditions is 136000. There are 4 rigures and I table.
SUBMITTED: may 18, 1962
Card 2/2

L. 149t?~-6 VF(0-21EWP(q % &V Pu-4 iCdIJDIJG
.)/Wr'a)/F!DS
&CCW31C11 KRv LP3003682
ALTIROP3i Ifemodruk, A. A.1 Paloyp P. got Koohotkq!-#.L -W-Tq,
TITISj Ccaparatty* study of reagerts for the photosetric Werair-ation of plutor,
SIDITRCES'~'IdiokbildYao V* 5# no- 5# 1961# M5442
TOPIC TAGSs photometr1o determination, plutoniust photonetric r*%Ont torcco
&raenazo, chlorophosphoneavolp chlerophospbcrAso
ABVRAC,"s A ootparativ* study of toronl,, taron 11, u-ter=a 1. creerase 11.
&rsenato 1114, chlorophosphonaza, 1# and 0hl0t0-Ph0G,;kh0r&Z3 r1I has beta ptrforw*d
tc determlie their possible use as compleroattric roagente in the spoctraphatc.-
vetric determimtion of tetravalwt pluton1w. The optivia ocaditioas for the
aeter=ination of plutonium axe presented for each reagent Invest1gat.#44 The Intero.
fering ions for each reagent are pointed out.. It ves-doUrsdued that ansfAvolff
and chlorophosphonato Irl are nect sonidtive, in the determination of plutonium
and give good reproducibility, CrIge art* tass 7 graph@ and T formulaso
ASSMATIM none
Card 1/9/-

NYJMRUKO A.A,j ROCEW.TKOVA# NoTee
Reaction of tstravalent plutonium vIth aroonaso .111. Zhur,
anal. khIx. 18 no.)t333-338 Mr'63. (MM 1715)

EW t E C
ACC Nag AP6012905 4 0 CE CODES
UR/iDO75/*66/021/004/0427/0432
AUTHOR: Nemodruk, At A.; 5ochatkova,,-N, Ye.
ORG: none
TITLE: Interaction of trivalent and hexavalent pjMtonlum with
arsenazo III _0
SOURCES Zhurnal analiticheskoy khlmilp Yo 21, no, 4. 19660 427-432
TOPIC TAGS: plutoniump arsenazo III,, i n. rapid transition I
chemical reaction i
ABSTRAM The paper concerns the color reaction of arsenazo III with
tetravalent plutonium, It Is shown that in its trivalent and hexavaleni
states, plutonium reacts with.areenaso III over a wide range of concen-
trations of nitrio and hydrochloric acids. The sensitivity of the re-
action depends on the acidity of solutions. In strongIr sold solutions
trivalent plutonium (due to its oxidation by air ojqgen) and hexavalent
plutonium (being reduced by the Arsenazo III excess) gradually become
tetravalent, For rapid and quantitative transition or other plutonlua
valences to the tetravalent state, a mixture of salts of bivalent and,..
UDC:

AP6012905
0
trivalent iron should be added to the analyzed solution* Orlg* art*
has: 5 rigures and I table, (Based on author's abstraot) (AN).
SUB CODE: 07/ StMX DATEs 25Jul64/ OTUO PjWt 005/ OM Mi 001
Cmd 2a

MMHII,*11;A-MANMKAUp V.1.1 KMWVAv H.H.; KOCAMW
Volt-ampere ebanaterisUos &W oarrying c&paalty of raccalmar
tharvite resisters for cawatational disabargos, glektrichestwo
n*.2&74-77 F '62. - . - (KM 15t2)
1. VsesoyusW elektrotakholchoshy Izatitut in. looninae
(Meatric linea--Overh"d)
(1clactrio Frotection)

KOOMOVAl S.A.1 MINKINAt A,A.j DIYAXOVA, N.P.
4o-Pherql-&nltroqulmlluo* Not* poluch. kMa. reak.
I prepr, no.64&50 062. (KIRA 170)
1. Toosqusqy muohno-l"lodantellskiy Institut khisleMokIM
reakti"v i osabo chistyM khisdaheakikh v*shahestv,,

5(0)
L'UTHORSS Toyst Rs To # Orosova# To So SOT/20-122-6-28/49
Koohotkova# go 1.
TITLEs Isotopic Composition of Natural Phosphates (Isotoptwy sostav
prirodnykh foofatoy)
PIRIODICALs Daklady Akademil nauk SSSR, 1950, Vol 122, Ir 6, PP 1057 -
1060 (USIM)
ASSTRACTs The not hod of Isotopic paloothornonstry (Rots I - 3) is the
most important application of Isotopic analysis to the
solution of gooobesical problems. This aothod Is based on
the dependence of the distribution of the heavy oxygen
lootope.between the oxygen, of water and the mineral on
temperature, that means it is based on the Isotopic exchange
between thee* two coaponsAts. The cosano are an Immense
reservoir of oxygen that hardly obw4*s Its Isotopic compost-
tion in the course of geological -time. Therefore, its
isotopic oosposition, can U regarded as constant and equal
to a certain average value, However# this condition of
constant water background (Yodayy fon) Is not always and
not everywhere complied with. Therefore, the possibilities
Card 1/4 of Isotopic paloothermosotry are limited by Insufficient

'Isotopic Composition of Natural Phosphates SOY/20-122-6-2a/49
Information on the character and the causes for the
fluctuations in the Isotopic composition of sea water. At
prosentonly the carbonate paloothersomotry to elaborated,
as carbonate# In %be solution oxchango their oxyg*n quickly
enough with that of water. If It **ro possible to find any
reaction mechanism that would prompt the oxygen exchange of
another mineralwith the oxygen of watero two equations with
two unknown quantities could be obtained; the precipitation
temperature and the Isotopic composition of the aqueous phase
would be the unknown quantities here. The solution of those
equations with respeat to both unknown quantities would ask#
It unnoasss"7.to know the Isotopic composition of the
oxygen of water, which has been necessary up to not. The
authors succeeded In aso*rtaining that the oxygen of the sul-
fate is exchanged very sLosly with the oxygen of water (got
4). Thus sulfates cannot serve as mineral thermometers. A
phosphate temperature scale was then suggested (Refs 2, 30 5).
The phosphates exchangs their oxygen with water even more
slowly than sulfates. The heterogeneous exchange with
carbonic &aid was Investigated with two samples of apatits
Card 2/4 (from the Lake Baikal &n& from the thibiny). the velocity

isotopic composition of Natural Phosphatoo 901/20-122-6-28/49
constantl &jA the half-period* of the exchange at 700# 90
and 1100 or* given In table 2. Figure I shows the isothermal
lines of these mossuresentst whereas figure 2 gives the
lectoress by extropolellon of thles data Into the range of
normal temperatures (2o"), i.34io hours Is obtained for the
half-period of the exchange. the isotopic composition of
natural phosphates has never been Investigated. The authors
used spatitse and phosphorites for this purpose, The oxygen
of these substanoes be# proved to be lighter than that of
river water, is From table 3 it can be seen that spatito con-
tains lose 0 9r,river water, Contrs47 to-expectationsl
the content of 0 n the phosphorites of podolite was lower
than that of river water. It can be seen from the data of
the authors that there is a difference between the relations
between the isotopic composition of the oxygen of waterg the
sulfate* and the phosphates. Natural;oulfatoo mostly have
a coup* ition op caching the oquilibriua with the oxygen of
sea W&t:r (Ref TO whereas the oxygen of natural phosphates
is ocusiderably.difterent. There are 2 figures, 3 tables, and
Card 3/4 9 references# 5 of which are Soviet.

Isotoplo Composition of Natural Phosphates SOY/20-122-6-28/49
ASSOCIATIONs Institut gookhlaii J ansliticheskoy khlail Is. V. 1.
Ternadskogo Akadeall nauk 8581 (Institute of Ooochoalstry
and Analytical Chemistry Imenl To I* TernsdakLy of the Acadeaq
of Balences, USSR)
PRISSITSDo June 3t 1958# lby A. P. Vinogradoy,r?"4"Pn
BUMTTZDI May 20 t 1958
Card 4/4

%U I LIkA
Pa -4/Pe -4/oPr-44rW 44 RKAV
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r
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r v a
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C rip ~.he urronAsm, as well &!~ Lite prf_-'n(;UrICCI' U 4

r e, ri-, r i , c.
T. c~ r 4 -j
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i"'l-ilt t :~u 1 1 't L r 0;,- 1 0
n f, f pr,~ ) f,.
10 1~ wi; 111.1 ~ 1- A i fil tr , I 'A - * , , I 'T
of crt' ~rinp arvi tof) on 111% -:-~,,y 'i (:. L: .4, C. _, a 1~ ~
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le to th-pir low '70.14til 7n,~ ,,nlc~; I-.A I n 3f at. 1 do i Z a
IV Qf o--~,%rtosllicon
6,144r"":n, U10 tcxlcl-~y c un 0
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--.Ar
C 111j.,4 14 (!Vjeu~
ct:srwes or the r a f r Q,:~, i a
r. i.c Oil w Ith ary1chlorasilzaes &TO -!,.r.pxyrl c~ -I F~. s *11 1 q Ie 0 * tie
!t - !-u scept I bill t-Y of L-Icne L:( -~pounl,~ t-or i I r "r
Vii F4 v a
IIDUP4, Which parrAt thm Whule c.) Lhs,-
Crjr-J

0 !-jrjI Rjasically, silicachlorofam anci met ty 1p-*r,,Y1d1ch1or0%1!An* act &S
:A,~ 1-0 pek,,el r n rd i fit to
r Ov a t 11L- 1 r r
R ,,o, c, ti i o r~; e L r y'
r--,
ine may as,-FUfNIO WusL WT(- j.; in-i- 44- L M--
Aev,,Iopq by the Interaction ol tne -nspilt moic-cula f 6m~ WILn
Hydrolysis may Litus La?re pla ~e, wltii '.hfl fOr-A'.Ion of deco.-poslulon
"in statu nascendt", maklr4~ t,Are jCt,!v,.t. A f . P, r ,j!- DI~~rj-,ed syszcmatic
eKp:jn~jr,.) Lo low concentrations or monr;-4trl - or4C&nasillco~-, c: -i, ~4rw.R *." resulting
t,ocicity qf.'ect.s are of mio