SCIENTIFIC ABSTRACT KLEBANSKIY, A.L. - KLEBANSKIY, A.L.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000723010011-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: December 30, 2016
• Document Release Date: June 19, 2000
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

S/1~8/60/000/008/003/015
A051/AO29
The Effect of Various Types of Stabilizers on the Change in Nairlte Properties
During Aging
2 Soviet, 1 English.
JO -
ASSMIATIONs Vassoyuznyy Mauchno-issledovatell IV -
skiy institut sintaticheakogo
kauchuka lm,.S#Vo rAbedeva (Sien-
tifia Research Institute of Syn-
thetio Rubber irani S.V,. Ubedev)
Pigure at 7he Effect of Polyphenols on the
Stability of Nairites of JV -
N
I - Controlj 2 2% dimethyl-
phenyl-n-cresoli 3 2% para-
dit;rtiarybutyldioxyphehylone-
Card 5/5
sul i4e; 4 2% lignin.
Duration'of Heating at 1200C. min

5.3831 V350
SOV/79-30-1-11/78
AUTHORSt Klebanakly, A. L., T imoreyev, 0. A.
TITLE: Copolymerization of flexafluorobutadiene With Dienes
III Solution
PERIODICAL: Zhurnal obshchey khImii, 1960, Vol 30, Nr 1,
pp 60-61 (USSR)
ABSTRACT: Copolymerization of *hexafluorobutadiene with chloropreneo
fluoroprene.ani isoprene was studied. Copolymerization
of hexarluorobutadiene with chloroprene proceeds faster
In polar solvento (chloroform, chlorobenzene) because
they facilitate the orientation of molecules# ani
this probably, Increases the rate of polymerization.
13enzLyl peroxide fLnd the dinitrile of azolsobutyric
acid are the most effective initiators for this
type of copolymerization. The effect of the ratio of
monomers In the startIn3 mixtuve on the rate or
polymerization Is shown In Fig. 5.
Card 1/5

Copolymerization of Hexafluorobutadiene 77350
With Dienes in Solution SOV/79-30-1-11/78
Z
J
X
0 J01
TIME (UP)
Fig. 5. Dependence of rate or polymerization on
Initial ratio of monomers. Ratio of monomeribenzene
= lill temperature 50 0; initiator, hydrogen peroxide
of isopropylbenzene (0.6 molar %). Ratio of chloro-
prenethexafluorobutadiene (1) 2-5:7.5p- (2) 5.015.0;
(3) 7-W-5-
card 2/5

CopolyrnerIzatlon of flexafluorobutadlone 77350
With DIenes In Solutlon SOV/79-30-1-ii/78
Card 3/5
Tne more hexafluorobutadlene in the starting mixture,
the more of it Is found In the copolymer. Copoly-
merizatIon of hexafluorobutadiene with chloroprene
carried out at 40# 50, and 600 Inlicates that rising
temperature (600) Incroaaes the rate of copolymerization-
But temperature has only a slight effect on tho com,-
position or copolymer. Tne rate of copolymerization of
fluoroprene-hexaflttorobutadiene and isoprene-hexa-
fluorobutadiene, taken in ration 7.5t2.5, 5.Ot5.Oj
and 2-517,5, decreases with the increase of nexa-
rluorobutadiene In the starting mixture. Tne constants
or the copolymerization or the monomers studied aret
obloroprene-hexafluorobutadiene, r. - 5.47, r. - 0#101
rluoroprene-hexarluorobutadiene, r, - 2.93,, r2 - 0.24;
Isoprene-hexafluorobutadiene, r I - 1.19, r. - 0.78.
The comparative activities
shown In Table A.
or monomers and radicals are

Copolymerization of llexafluorobutadlene
With Dienes in Solution
MONOMERS 14CAAFC
OROGut
GUM
....... 1060
irl"relpetAo. .. . - - . 4.16
t1affshm. . . . . , . , . f.27
1Wd&(I0deAdt&JI*#A IA
77350
SOV/79-30-1-11/78
TABLE A
PADICALS

rso- 40-
FaI6
I c"Wo,
FACH9
FAING ,
7.52 4A5 In
- cul
1.0 028
OA4 &34 0.18
Card 11/5

Copolymerization of Hexafluorokutadieric 77350
With Dienes in Solution SOV/79-30-1-11/78
Increase In the activity of chloroprene In comparison
with butadiene Is due to the polar chlorine atom, which
upon Introduction into the butadiene nialecule disturbs
ita symmetry and causes the displacement-of Its electron
density and polarization of the molecule. The dipole
moment of the molecule In 1.42 D. Tne shift or the
electron density Is due to conjugation of 7r-electrons
of the double bond with localized electrons of the
chlorine atom. As a result of strong polarization,
,the molecules are mainly oriented In a 1,4 manner and
are more active in the polymerization thanbutadiene
molecules. The same Is true In the case or fluoroprene,
b,At the latter is less active than chloroprene.
According to their activity, the Investigated monomers
can be arranged in the following order: chloroprene >
rluoroprene > i9oprene > hexafluorob-Atadiene. There
are 14 figures; 1 table; anJ 6 references, 4 Soviet,
2 U.S. Tne 2 U.S. references aret Carotheraj J. Am.
Chem. Soc., 54, 4(Y70 (1932); Simha, R.'Wall L A...
Research Nalt. Bur. Standards, 41, 521 (1946).*
SUBMITTEDs August 9, 1958 Card 5/5

5- 3600
SOV/19-30-3-15/*69
AUTHORSt Klebanakly, A.',L..* Fom!.na, L. P.
TITLEt Concerning the Radical and Ionic Reactions of
Tetraethylthluram Disuafide
PERIODICALs Zhurnal obahchey khimit, 1960, Vol 30, Nr 3J.
pp 794-798 (UssH)
ABSTRAM Radical decomposition of thiuram in carbon tetrachloride
without I Itiator at 1450 yields compound
(C2H5)2 HTSCI (yield 116%), mp 46-46.50, 'which could
obtained only by the reaction of the (C,2H5)2u- _S
radical with CCI Ca;:wbon disulfide and a compound
(02H 5)2NCl were aiso found ariong the reaction%-
products. The formation of carbon disulfide and
the other compound Is evidently the result of the
Card 1/4 secondary reactions of thlurwn radicals with COI 4

Concerning the Radical and Ionic Reactions 78261
or Tetraethylthiurain Disulfide SOV/79-30-3-.15/69
+ (:st
~(A)
+ cri, rr.1,
Card 2A
Studying the ionic reactions of thluram, the authors
reacted tetraethylthiurrin disulfide with bauesy NaOH
and 111f OH The following products wers obtainedi
tetraethyithiuronium su'Lfide, mp g4-65 ; sodium
diethyl dithiocarbamate, mp 94-96,; and NaS and
Na 80 scheme of the reaction lot
2 3.
4- + N&IS03 + 31119+N*tS.
The above reaction scheme wa3 confirmed by the

(;(Pilce I'll III,', Hw H:o i 1, ~-d Id I i
~)i' To LvW, ttlyl till u r'w~; DI ?-,!I I I d~~ S OV ,/1"-.30-J-15
of, thlor"'Im W.It"I 't1k:1111 It-, ths! prc-3s,~nce or
Ctlomt!ntal milfur. ThItteoldim milflAt', was riot obtaltied
.111 thlo (FIZ0,1111il(k. wau Converte-i
abnoi,,t quarit.1tatively Irlto t;'Allim diethyl-
I I n c a rbama L i~! Na,S -vid Nn-;3O-j were! al3o rormed
III "tMchlom-tric umoi~iwli T' i ~, I o; i I (~ na t u re Q r tht',
11(1~11.(Alon of' thluram witri alkali, It., kin-Alco, wan
atuflic-d in the Pre"I(mce of' all 11110atf # jouilinlum
pf'riollf"utu and an ItillIbItorp Pherlyl- naphthylamine
(neozone D) . Neither 1~iltlator not, ~~ tihibitor arrecto
the reaction rate or thluvani w1th alkall. The reaction
of* t(Araethylthluram dl-mll'Ide with dlethylamine at
j -il. o c trip 48-1190.
600 -1olds tot; rapthyldlim Itiod ILI a r bayma t c
Theve In 1 figure; I table; and 1h U.S.P
2. U.K., 3 (101*marl, 1 Sovlet- Tfv~ 11 mont rir!cent U.S.
r'rA,vve1IC(!s arpt 01,.01,-,, Davidimn, [Obb. Chetm. Techn.,
211, P62 ( 191A a ra I if, , Da v 1, do, 0 ri, J . Vo 1.ym . S C 1 8,
326 01-1,x1g, 1XIVI-1o.011, J. Volym. 0", 177
(19-j); Torbell, Chem. Rov.,., 148, 161 (1951);
3/L

jCorxcevritnj, th(- Radical and lonle! RV!, ottonw, TlKi f
.1011/fli-30-3 -15/69
'10 1 N3)"f'3.

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and by the ounds 0
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B/079160/030/05/06/074
synthesis of Bass DIOhlOrO Derivatives Of B005/1002
Octedisoo-296 is and .turf's.red spectrosCO15', clearly reveala
he chemical &Still sent in the ;;actigi pro-.
synthesiso Vthe issiv4d compound (1) to Pro authors prooseded from
ed that, OnlY ~, compound (11) the , condensation
he gyntbalis 01 produced by t1
duotdi 0 lor t, irootsdions-296 (09 that 998 f ankqdrous 74013
2,60-trichIc in the Presence 0 be conversion
f compound (111) with oblO"Pr*"* were ,6mined for t chlorine by
0 tion methods
(R-f. j). Various reduo 'Ouplete replacement Of uble bond*:192
of (y) into compound %ouserv&tIon of the doin the presence of
under the sisults"Ous 4 with hydrogen
hydrogen the -catalytic hydrogenation binding Of the resulting by.
j@ for the his Toy,
&obi*VQd 13, and Of sodi= &6091 Fit) synthesised in A
Itsusy nicks q1h, structure. 0,f Compound ( V. All the OpOrs""
drogsn'oblorld66 jefrar8d gpootrosOOP; point#
Was Welt doftusdbY the aid Ofilporisental Parts yield, boiling specified
ers accurately dosoribtd In an A per Osnt analysis are ' Cana
Irefractive index# density, and.sle0sAtIry , the Infrared 2POctr* or
for all products obtained& Two tigureetsba a and interpreted by Go
and (11). The Spectra were sk* t; ~&r
pounds (1) a described in great detail. The
BosenoTe ?),Sir interpretation I i American, I Drittabs and i Cars"-
a and 4 reference#' i Soviet$
oard 2/3

5.3700 17526
OV/BO-33-1-35/49
AUTHORS:
L., Dablere Z. F.
Dolgopol'skiye 1. M.,.AK
TITLE% Concerning Proportion or complex Compounds of Acetylene
and Vinylacetylense Formed in CuCl-MC1 Solutions
PERIODICALs Zhurnal prikladnoy khimiij 1960, Vol 33, Nr lp
pp 195-200 (USSR)
ABSTRACT; This is the first paper or a aeries on the conditions
of formation# properties, and compositions or com-
plexes formed by the reaction of acetylene andlits
dimer with Cu01-M01 solutibne. The study was under-
taken in order to explain,the mechanism of catlytio
polymerization of,acetylone and vinylacetylones; it
is a continuation of tho authors' previous work, a
short review of which Is given. The following changes
of properties of solutions connected with complex
formation are reportedt color or the solutions and
precipitated oomplexesj increasing solubilities of
cuprous chloride and acetylenic hydrocarbons; VH
Card 1/18 changes of GuCl-MG1 solutions with dissolution of

Concerning Properties of Complex Compounds 77526
of Acetylene and Vinylacetylenes Formed SOV/80-33-1-35/49
in CuCl-MO1 Solutions
SUBMITTED:
acetylene and vinylacetylones. Complexes C6H6(CuCl)2
and C8H8(CuCl),# formed by the reaction or cuci-Nyi,
and corresponding hydrocarbons were obtained for the
first time. It was found that the color of solutions-
containing C2H2. CuCl, MClj and vinylacetylones,
chan as an a result of complex formation. The colors
of t9a solutions and the complexes depend on the
component concentration their ratio, nature of hydro-
carbonp and the cation tm+) of the complex forming
component. The above is Illustrated by the followtog
data(see tables and figure). There are I figurej 4
tables; and 11 references, 1 Oerman, 1 French) 9
Soviet.
April 29p 1959
Card 2/8

I
Concerning Properties of Complex Compounds
of Acetylene and Vinylacetylene.s Formed
In CuCl-MC1 Solutions
77526
SOV/(30-33-1-35/49
Table 1.
M
(W -(d)
OXG
OJU
015 1 (1) (7)
0.50 (4)
M75 151
1.00 16)
Card 3/8 (see Carl 4/8 for CAOtiOL to Table 1)

Con rning Proportion of Complex Compounds 77526
OC A,:etylene and Vinylacetylenes Formed SOV/80-33-1-35/49
in CuCl-MC1 Solutions
Table 1. Color of crystalline precipitates
in.a. solution of: 2.5 mole CuCl. 5 mole NH401,
depending on concentration of acetylenic hydrocarbon.
a) Concentration of acetylenic hydrooarbon
~tn mole/litor)j (b) color of precipitated com-
plexes; (c) acetylene; (d) vinylacetylenel
divinyl acetylene; (f) acet lone tetramer; 1 red
ellow; (2) orange yellow; 13) canary yellow;
4) Palo yellow; 5) colorless; (6) colorless; (7)
T
canary yellowl (81 yellow; (9) orange yellow.
(SOP 041'd 3/6 fe)r TnI.-Io 1)

Concerning Properties of Complex Compounds 77526
of Acetylene and Vinylacetylenes Formed SOV/80-33-1-35/49
in CuCl-MCI Solutions
Table 2. Effect of different cations on color or
CuCl-MC1 solutions on saturation with acetylene at
Boo , (a) Chloride cationp (b) electric field
intensity of cationj c color or CuCl solution;,,
(1) KHO (2) KI (3) Ca; (4) mg, (5) Al; (6) orange
7) yellow orange; (8) yellow; (9) straw yellow;
0) pale yellow. 6
R
W (C)
(1) ....... M48
21 ....... O.W
i
131 ....... IJJ t1
A .......
(Card 518

Concerning Properties of Complex Compounds 77526
of Acetylene and Vinylacetylones Formed SOV/80-33-1-35/49
in CuCl-t.;Ol Solutions
Table 3.
(d)
(C) (9)
. 0.25 W
2.5 S.
0 46 O
M (2
- CO ,
,
M75 (1)
& 0-23 0 (2)
0 5.0 40( 0675 S)
( (3)
. 1
UZ (6) 0 PO
5.4 .10 0.75 (7) (S)
C ard 6/13

concerning Propertlea of Complex Cbmpounds 77526
of Acetylene and Vinylacotylenea Formed SOV/80-33-1-35/49
in CuCl-MC1 Solutiotin
Table 3, Effect or concentration of components
in solution on the color of acety lene complexes.
(a) Concentration of components In solution (in
mole/liter); (b) color of the pre cipitate of ace-
tylene components at HCI concentr ation (in molo/liter).
(c) (d) (e) M
( 1) orange 1 orange yellow 1 colorless 1 colorless
2 yellow 2 colorless 2 yellow 2 colorless
3 colorle ss 3 colorless colorless colorless
4 orange 4 orange orange yellow yellow
5 yellow
' colorless 5 colorless 5 colorless
6 orange 6 orange
(S)
7 Yellow 7 yellow
colorless
l
i 2 colorless
i
colorless
card 7/8
concerning Properties of Comple-x Compounds 77526
Of Acetylene and Vinylacetylenes Formed SOV/'80-33-1-35/49
in CuCl-MCl solutions
V19. 1. Increase in Cucl solubility on passing
th
rough C2H2j de n Ing on cation ? radius.
pe d 4C
(A) Increase of CuCl Solubility (in %); (B) radius
of cation M+ (in A).
card

5.3400 77528-
SOV/80-203-1-37/4,
AUTHORSi Dolgopol'skiy, 1. M., Klebanskiy, A. L., Dobler, Z. F.
TITLEt Concerning the Solubility of Alkynes in Solutions of
CuCl-MC1. Communication II
PERIODICAM Zhurnal prikladnoy khimli ig6o, Vol 33, Hr 1. pp 209-
212 (USSR)
ABSTRAM The solubility or acetylene and vinylacetylene in solu-
~tions of CuCl-MC1 sharply increases in comparison with
their solubility in aqueous solutions of MC1. The
solubility of acetylene and vinylacetylene increases
with increasing field.strength, of cations and of the
polarity of the cations of ammonia derivatives. In-
crease of polarity of mono- and trimethylamine occurs
with increase of the degree of substitution (weight
of cation or ammonia derivative).
SUBMITTEM April 29, 1959
Card 1/3

Conc6rning the Solubility of Alkynes in 77528
Solutions of CuCl-MCI.. Communication Il SOV/80-33-1-37A9
Table 1. Solubility of acetylene in solutions of M01
and CuCI-MCl (ratio CuCl t MCI, 1i1).

CO."Plew
SALA f ( MCQ MCI
too I w to* W-
NN&fCl OX4 0.010 035 a13
043WHij 4 HC1 OA42 0.013 Ow als
04 H14 - WC1 0.043 0.013 (L60 all
KC1 OMO Ulf M40 Q15
MiCIA. (X014 O.Ous 0.20 W6
Card 2/3

Concerning the Solubility or Alkynes An '17528
Solutions or cucl-mcl. Communication II SOV/80-33-1-37/49
Table 2. Solubility of vinylacetylene in uolutions or
CuClIMCI at 800. Molar ratio: CuC1:MC1 1.
CA roon
im 1)
C.0-P14%
It IL MCI)
f4m,j
c,q,NM.I& 14el
Kitt
(cI4j)A Nk - 14 4C 1
N - HC I
C,v NJ NNk 0 tic 1
Is U10
46 #A 14
74 1 (XIM
Card 3/3

5.262o '17630
SOV/80-33-2-5/52
AUTHORSt Dolgopollakly, 1. M.p Klebanakly, A. L., Dobler, Z. P.
TITLEt Concerning the-Stability of Complex Compounds of
Vinylacetylenes In CuCl-Mv"l Solutions
PERIODICALj Zhurnal prikladnoy khimil, 1960, Vol 33, Hr 2.
pp 283-289 (USSR)
ABSTRACTs This article is the third In a series and deals with
the investigation of formation and decomposition
conditions of complex vinylacetylene compounds in
CuCl-MC1 solutionej with different cations of the
complex-forming MCI compound. It was found that
the bond strength between vinylacetylene and the
central copper atom decreases the cation size (i.e.,
weight of the cation in the ammonium chloride
derivatives Increases. The stability of complex
compounds is given in Fig. 1 as a function of the
cation field strength and of the cation molecular
Card 1/5 weight,

Concerning the Stability of Com lex.Compounds 77630
of Vinylacetylenes In CuCl-MC1 golutions SOV/80-33-2-5/52
Card 2/5
VMAM-0
4
/r/1), oil
Ismi -h
Fig. 1. Stability of vinylacetylene complex compounds
in CuOl-Ml solutions as a function of the ~Cl-cation
nature# (A) CgH4 evolution rate -v . 10-4 (in moles/
GOQ)j (B) cati n field strength; (C) cation weight
(In g)v Ij metals; 11, subatituted amnonia.

Concerning the Stability of complex Compounds 77630
of Vinylacetylenes 1n CuCl-MCl Solution.,) SOV/80-33-2-9i^2
When the bond strength between vlnylacetylene and
the copper atom was determined by incanu of ab3orptloti
rate of the former, It wazi found that the foiinatlon
rate of complex compounds is Inversely proportional
to the filed strength of the MCI cation and to the
catlon molecular welght, Jn amir-onlitm clilorlde derivutiveu.
The absorption rates are given In Fig. 2.
Regular lowering of the stability iz caused by
varying polarization of the acetylene or vinylacetylene
effected by the central copper atom. The polarizing
effect of the copper atom depends on the cation
structure In the complex particle; the stronger the
cation field, the smaller the thermal stability of
the complex compound. When the cation field strength
Increases, the polarizing effect of the copper atom
decreAhea because the central atom elharge is counter-
polarized by a similar charge on the cation. Thin
also, expl-7 iris the decrease In complex compound Lrlrid
strength with Iticreaalng degree of aubatittation of
Card 3/5

Concerning the Stability of (.,-,mplex Compounds 77630
of Vinylacetyleries In OuCl-MU1. SoluLlusia 3OV"4UO-33-2-5/52
ammonium chloride derivatec. It wan found that the
stability of complex compounds also dependa on the
nature of the hydrocarbon and decreases according
to the following sequencet acetylene,:-- vinylacetylene
-L---divinylacetylene --acetylene tetramer. There are
2 tables; 3 rigures; and 1 Soviet rererence.
SUBMITTEM April 20, 195P
Card 4/5

Concerning the Stability or Copiplex Compovnda 77630
or vinylacetylenan in CuCl-MCI ISOV/80-33-2-5/52
-C
pig. 2. nate or formation of vlny~acetylene complex
compounds In cuCl-MCI solutions as a function of the
cation nature. (A) C4 Hj, absorption rate -v.10-q (in
moles/seo)j (B) cation weight (in g)- (C) cation field
strength. Givent MC H (in Moles/il. (1) 0.37; (2)
Card 5/5 0.26; (3) 0-13. 1, Xhituted, at=onia; II, metals.

5-33UO
AUTHORS:
TITLE:
PERIODICAL:
ABSTRAC T:
Card 1/2
?8235
SOV/8 0 3 - 36P T
Klebanskiz, A. L., Dolgopollskiy,
Concerning the Increase of
Accompanying the Formation
Vinylace,tylene Compounds.
Zhurnal prikladnoy khimti,
Pp T16-723 (USSR)
1. M., Dobler, Z. F.
the Hydrogen Ion Concentration
of Complex Acetylene and
Communication IV
1960, Vol 33, Nr 3,
The authors were the first to show conclusively (Trudy
VNIISK, Gookhimizdat (1), 8o, 1948) that the dissolution
of acetylene and vinylacetylene in acid aqueous CuCl-MCI
solutions and the formation of complex compounds Is
accompanied by an increase of hydrogen ion concentration.
In the present paper) the above phenomenon was studied
in CuCl-NH4C' solutions, and the ion concentration was
measured chemically and potentiometrically (with 0. A.
Seryahev' method, using a glass electrode) after
dissolution of various amounts of the above gases.
The Increase of hydrogen Ion concentration depended
on the CuCisNH4C1 ratio and on the concentration of

Concerning the Increase of the Hydrogen 78235
Ion Concentration Accompanying the SOV/80-33-3-36/47
Formation of Complex Acetylene and
Vinylacetylene Compounds. Communication IV
CuCl In the solution. In concentrated solutions# the.
increase corresponded to the ionization of 2 g-lons
for acetylenej wid to about I g-ion for vinylacetylene.
There are 7 tanles; 3 figures; and 11 references,
2 U.S., 2 French, 3 Oerman, 4 Soviet. The U.S.
references ares H. Gilman, K. Z. Bebb, J. Am. Chem.
Soc.. 61, 109 (1939); L. H. Ryerson, B. 011lesple,
ibid.0 591 900 (1937)-
SUBMITTED: April 19, 1959
M

4o(08D/60/033VO#/3D/045
AtrMORS t --Klebanskly. A.L., Dolgopollakly, I.M., Dobler,_Z.F.
TIM: On the Effect of Various Factors an the Degree of-Ionization of A
and Vinylaootylono In CUM-HRO solutions. Communication 5.
PERIODICALs Zhurnal prikladnoy khbdl, 1960, Vol 33, Hr 4, PP 931 - 934
TEETt It has been shown that during desorption of acetylene and vinylaostylono
from C6Cl-NHn Cl solutions a decrease of tho-soldIty of the solutions or correspondingly
a decrease ol the concentration of hydrogen tons in the solution takes place. With an
Increase in the to Atu the quantities of acetylene anid vinylacetylone, bound in the
form of comple -compounds with CUM-NH 01 decrease and the concentration of hydrogen
tons in the solution decreases aorres;g"ly. The degree of Ionization of acetylene
in CuCl-NH4Cl solutions decreases with an Increase.in the h7droahlorio sold concentration
in them, which is explained by a change in the composition of the complex compounds formed.
During the formation of complex compounds of acetylene hydrocarbons which do not contain
active hydrogen in the acetylene bond (like divinyl acetylene and acetylene tatromer),an
increase in the concentration of hydrogen Ions does not take place.
There are: 4 tables and 2 graphs.
Card 1/1

a-/0-8D/60/033/04/39/045
AUMOP.Si
TrIM
Dolgopol'skir, . LM , Klebanskly, A.L., Dobler, z.P.
e
On the Effect of the Mature of
Ionization Degree of ketylen and
1
Zhurnal priklaftoy khWi, 1960, Vol
PERIODICALI
Cations In CuCl-PeCl- Complexes an the
Vinylaostylone. Comounication 6,
1
33, Nr 4, pp 975 - WS
TEXTs All factors affecting the stability of complex com;winds have also a certain
effect an Ionization. It was established that the degree of Ionization of acetylene and
vinyl&6*tylww deareases with an increase In the field Intensity of the M+ cation -in
CuCl-MC1 complex* .'j* The Ionization degree door*aB~x with an Increase In the degree of
substitution in the cations of the ammunium derivatives or the also of the alkyl radical.
Analogous laws were established concerning the effect of cations an the stability of
oomplex compounds of acetylene and v1nylaostylens, with CUCl-MCl solutions, An explanation
Is given of the affect of cations on the degree of Ionization and the stability of complex
compounds of acetylene and vinylaostylene. The solanation Is based on the action of
their field, directed contrary to the action of the field of the central copper &too
(ocunterpolarlsing effect), causing the weakening of the polarlsIng effect of the central
copper atom and the decrease In the stability of complex compounds. There are 3 graphs,
1 table and 2 Soviet references,
SUBUTTED: June 19, 1959
Card 2/1

- -----------------------------------------------------------------------------------------------------
S/66 1/000/006/024/081
D205YD'302
AUTHORS: Ponomarevt A. 'I. and KlakunIfilt- L, L,
TITLE: Synthesis of silico-organio compounds with polar sub-
stituents in the organic radical and investigation of
their stability
SOURM Xhimiya i praktio'hoskoye primeneniyo kromneorganiches-
kikh soyedinaniyl trudy konforentaiit no. 6, Dokladyg
diskusaii reshonlye, II Vaes. konfer, po khimii i prakt,
prim* kromneorg* soyed.t Lon. 1958. Leningradt Izd-vo
AN SSSRq 1961t 116-119
TEXT; In addition to the published material it is stated th at-cy-
anomethyl heptamethyl,cyolol;etrasiloxane was obtained in 7714 yield
by the action of lithium mothyl hoptamethyl'oyclotetrasiloxaLne on
the solution of cyanogen in other. Investigations have shown that
dimethyl siloxane derivatives containing polar substituents in,the
side chain at thea-oarbon, atom are chemically and thermally un-
stable. When a nitrile or a carboxylio group to present in the
Oard 1/2

3/19IJ61/000/001/005/015
BIOI/B205
AUTHOM Mikheyevo Yet Pot Klebanskiyj A. L.9 Mal"novat go Not
Popkov, K, K,
TI?LZs Catalytic dohydroeondensation of silans chlorohydrides
with aromatic compounds
PERIODICALt Plasticheakiye massy, no. 1# 19610 19 - 21
TEXTs A study has been made of the reaction -4 Si-H+H-Ar--j H2+ -4 Si-Aro
the temperature of which can be largely reduced by such catalysts as BC1
3
93D0 39 A101 3' ota' A paper by A. J, Barry at al. (Hot. 1) is dicussed# it
which hydrogen is supposed to undergo alectrophilio substitution at the
aromatic ring, accompanied by the catalytic formation of the complex
tHiBC131: In addition, by-products with eyelohazadiene structure are
formed, These statements have been chocked here. Methyl dichlorosilano
Card 1/4

S/19 61/WO/001/005/015
Catalytic dehydrooondensation of B1019205
was heated in an autoolave with C6a6$ C05. CH 39 06a5 CH(CH3)20 and
069 01 in the presence of 00% 9 3803, and with C6HF in the presence of
0. ; H5BOY The molar ratio of methyl dichlorosilane to the aromatio hy-
drocarbon was It3a Remotion temperature was 230-290 OC. Hosting was
stopped as soon as the pressure in the autoolave bad become constant. Un-
der theme oonditionst which are described as being an optinuat the follow-
ing dehydrocondeneation products were obtained# 40% yield with C6H61
41% with C6H,*CH31 24% with C6H,' CH( OH3)2' 1e% with.C6B 5F# and 25%
with C6H501, The mixture of the remotion products was fractionated. 'the
rosulting mixture of isomers of the now compound nothyl-cumyl dichlorosi-
lane boils between 127.6 and 137.4*C at a pressure of 26-28 as HSI
d20 . 1.10201 20 - 1#5134, Analysis has show that this fraction fol-
4 S
lows the formula 010H 14 80124 The ratio of o-O m-9 and p-isomers in me-
tbyl-aryl dioblorosilanon was determined from Raman speotras
Card 2/4

.Catalytic dohydrocondoneation of , ... SIOI/D205
Compound Experimental ratio
o-Isomor m-isomor p-isomer
CH3(CH306 H4 )Biel2 1 10 3
CH3(CH 3)2 CHC 6H4Biel2 1 12 3
CH3(?a694 )Biel2 1 4 2
CH3(010 6H4)Biel2 1 6 4
The amount of CK formed by reaction with benzene and toluene was 3.6 and
4
3-40, prespeativelyi with cusens, 10.5&1 with fluorobonzate, 12*6%#
with chlorobenzone, 6.5%. Equal amounts of dimethyl dichlorosilane were
obtained by reaction with benzene and toluene. This is taken as an indi-
cation that CH 4and (08 3)2 Biel 29 are formed# not by decomposition of the
'hypothetical adductog but by disproportionation of CH 3SiRC12* The fact
Card 3/4

3/191j61/000/001/005/015
Catalytic dehydrocondansation of BIOI/B205
that primarily mat&-dorivativos are formed is explained in 4stail, Accor-
ding to previous papers of the authors (Refs* 4t 5), boric scid first
forms a silyl bydride boratet 8-ji-O-BC . As boron is a strong electron
acceptor# it shifts the electron density and caus as protonization of hy-
drogen bound to Si according to the reaction XC 9 [phone],
X 6 5
Si-O-B;' + H When the aromatic ring to substituted, the silyl
0- 1 24
borate anion is added in meta position. Similar complexes as formed with
boric &aid are assumed tor B? 31 D013v and A10131 Hli-cl-uual5o The for-
ation of such complexes is considered to be more probable than the for..
:
ation [Hflffial~ -. There are I table and 5 reforencess 2 Soviet-bloo and
3 non-Soviet-bloo,
Card 4/4

SAUDUS, A.0.1 XLSBARSNUO."QUUMDARMs moos
rilw-forming subAnces fl-m polyurs of 1.3-41chlorobutew4
and divinylacety2ons. labskrus. mat. i ikh. pria. nop27-29
161, (KM 26s?)
(ribu(Cbesistrl)) (Polyftre)
(lacqu*r and 2acquering)

0 26968 S/138/61/000/005/001/006
15'. Z01, I A051/A129
AVTMRSS Klebanskly A LOA Taukerman, N. Ys., YArtsev, V. N., Labutin, A, L.,
Trenke, YU, sp. laMna, L, P., Borovikova, N. A., Kamlina, 0. 0o,
Rozhkovs YU, P&
TITLEs A new type of chloroprene rubbers liquid nairite
(This work was awarded the second prize at the VXW Im. D. 1, Mendel*-
YOV competitions in 1959)
PERIODICALs Ksuohuk I resins, no, 5, 1961, 1 5
TECrj The high chemical stability, the gAsoline-petrolem stability and
ozone-resistanoe of chloropme rubber makes It a suitable material for anti-corr*_
sion coating mid hermotio sealing. However, the difficulty of producing highly-
concentrated solutions based an commercial nairite limited the application of the
latter in anti-corrosion technique, It has been assumed that the use of low-siolo-
cular polymer* for this purpose would.enable one to obtain low-v1scosep highly-Con-
centrated solutions satisfying the anti-corrosion techniques. One of the methods
for producing low-molecular polymer* Is the use of tho polymerization of increased
concentrations of regulator-compounds able to break the chains and to form now so-
cam 1/6

2690 3/138/61/000/005/001/0%
A now type of ohloroprone rubbers liquid nairite A051/A129
tive centers, Sulfurous compounds, such an mercaptans, thlosolds, xanthogeassulti-
des, are widely used an regulators. When studying the action of n-tstr&d*cylm*r-
captane, dilsopropylxanthogenedisulfide and bisothylxanthogenedisulfide during the
process of polymerization of chloroprens, It was established that with an Increase
In the concentration of the regulator the molecular weight of the polymer drops
oorrespondir4ay and the plasticity of the rubber increases. It was assumed that tw
use of greater quantities of b1sethylxanthogenedisulfide In the polymerization of
chloropm* In emulsion decreases the molecular weight of the polymer and yields
low-v1scos1t3r solutions of rubber, An attempt was made to produce low-moloaular
polychloropron* by Polymerization of chloropreno In the presence of sulfur with
subsequent destruction of the polymer, It was shown that the action of sulfur dif-
fers from that of other regulators, The *ftsot of sulfur on the polymers of chloro-
prene Is shown by the schemes -(CH2-CC1"0-"2)n-sx-(CH2-CCI-CH-CH2)m-37.1 whOr*
x-2-6, The sulfur f orms linear bonds In the. polymer chain. With an, increase in
the bound sulfur content In the polymer the molecular weight of the polymer dearea-
sea In the subsequent Interaction with thluram from 600,000 to 280,000 with 0.39 of
bound sulNr and from 300,000 to 410M with 1% of bound sulfur, The quantity of
reacted thiuram increases respectively. The destruction scheme Is given as folloves
1) The formation of free radicals under the effect of the Viermal action or thlurew
Card Z(6

26988 sll-4V611000100510011006
A now type of chloroprone rubbers liquid nairite AO51/AM
-(CH2-Ml-CH-CH2)n-S-S-8-8-(CH2-MI-CH-CH2)m-S-8-S-8- --?-(CH2-MlCH-CK2)n-S;
2)-Recombination of the polymer radical with molecular thluram and splitting
off of the latter along the -8-3-bonds
-(CH2-CClaCH-CH2)n-S' + (C2H5)2P-C-S-S-C-N(C2H5)2-_'P
-4-(CH2-CCl-CH-CH2)n-S-3-C-N(C2H5)2 + (C2H5)2P-C-S-
Based on the outlined assumptions of the mechanism of the sulfur action durIM the
process of chloroprens polymerization and destruction of the polymer under the ef-
fect of the chemical ustioating substances, the conditions for producing low-molo-
oular chloroprene rubber-"liquid" nalrite were developed. The liquid types of Wd-
rite can be obtained on &.typical appamtus, The sulfur can be introduced In the
form of solutions In mineral oils as well " aqueous dispersions obtained in the
presence of emulsifiers and protective colloids. It was shown by V. V. Kartsov,
M. A, Outman, 0, 0, Karellnaj P, Ye, Berman,. Yo, O,,Kalinovskaya, N. B, Shur at
VNIISK, no, 2389, 1951, that for mastication the mat effective system Is meroapto-
Card 316

3/138/61/000/005/001/006
A now type of chloroprens rubberl lijutRairlte A 03 I/A129
benzothiazol (captax)-diphenylguanidine (MO). To increase the activity of these
agents, tetramothyltblurand1sulfide was Mdod_(thturam D) or tetrasthylthiurandi-
sulfide (thiuram 9), Literature data indioaio,thst aotlya ustioating agelits of
polychloropreno an the p1porldine salt of hou"thylenedithiocarbamine wid or
Ammium hau"thylenedithlocarbamate, The order of introduction of the agents
plays an important role, The effect of the type md composition of the carbon
black an the solubility of the rubber mixtures from *liquid* nairit* was Iny*stl-
gated. Only the thermal carbon black helps to retain complete solubility. Higher
Indices of relatlys elongation when filling with 100 w,,V4 and over ov achieved
with thermal carbon black, The composition and technology for preparing the rub-
ber mixtures based on the "liquidw nairit* with thermal carbon black " filler
yielded highly-conoentraUd solutions (70 - 75%). Those solutions are suitable
for sealing various equipment by the same methods which are used In the case of
dye and varnish coatings, Tests of coatings made of liquid nairito in experimental
and natural samples In various industrial fields showed the expediency of using
this product as a material for protecting the metal from corrosion, erosion, oavi-
tation arid also as a material for hermetic sealing, There a" 4 tables and 21 rof-
orencess 2 Soviet-bloc, 19 non-Sovist-bloc, The references -to the 4 most recent
card 4/6

26988 3/138/61/000/005/001/006
A now type of chloroprone rubberi l1quid nalrits A0514129
U&llsh-languase Publications read as followst Corros, Tachnol., 5, no. 4, 107
(1958); R, Be Seymour a. oth., Plawtice for Corrosion R*slstant ApplIcationt X,Y,,
1955,,901 Rubb, .&, Plasts Agep 39p no. 8, 684 (1958); Corros, Tecbnol,~, 3, no. 3,
89 (1956).
ASSOCIATION# VatsoyusM nauabno-iseledovatellakly Instltut slutet1chaskoco, kauahu-
ka Is, so V, L$bW*va (Al-won Saientitic Research Institute of Syn-
thetio Rubber.im. S. V. Lebedev).
Card 5/6

27544
3/338/61/000/006/OW006
I C. 3X01 A05IIA129
AVMRSs Labutin, A, L. sb&ns Tsukerman, N, Ya., Mrtsev, V. U.,
Tranke, YU . Vept&!Mwmln~id. PL., Borovikovs, N. A.,, Kar*lIns, 0. a*#
Rozhkov, YU, P.
TMXs *Liquid nairtte" - a now mat*r1al for rubberl"
PERIODICALl K&uohuk I revinaj no, 6, 1961, 5 -8
TM(Ts The authors state that In the chemical destruction of ",liquid" nai-
rite, highly concentrated solutions can be produced which are applicable " a ma-
terial for rubberising. In the USSR a safer binafy solvent, consisUng of 2 weitht
parts of othylacotate &:41 w,p, of gasoline Is used In nairito adhosivto, Experl-
aents showed,. however, that this solvent In *liquid" nalrite Is Dot suitable for
many technical reasons, Bettor results more obtained in usir4 a ternary solvent
consisting of 76% solvent, 19% turpentine and 5% n-butanol. The latter component
does not dissolve the nairite, but facilitates the use of the brush for paintU*
mid good coating distribution, It was noted that film vulcanization from liquid
nairito at 200C does not show positive results. Thus various forms of thermal vul-
canization were Investigatedt vulcanization with heated air, 11vevapor, hot water
Card 1/6

ZT5Wi
S/13fV61/000/006/OOZ/006
"Liquid nairits" - a now material for rubberising A051/A129
and Infra-red irradiation. It was established that the mat suitable method was
vulcanization by hot air.; The phyalco-mechanIcal indices of nalrits coatings vul-
canized In air at various temperatures are given In Pig, 1. Fig, 2 shows the re-
latlonship between the temperature and duration of the vulcanization. The mat
suitable temperatures of vulcanisation in air are within the range of 100 - 1420C.
It was noted that the liquid nalrite coatings did not poasess the proper adhesion
to metal. Thus certain other adhesives or coatings ensurIng better adhesion be-
tween metal and coating were sought, The best results were obtained with the fol-
lowing three materialst standard leuconate (organic base: n, n, n" - trilsocyanate-
trIpheny1methane), chloronairits adhesive (organic base: chloronairits and nalrite)
and a primer, tentatively called epoxide primer (organic bases epoxide resin. Wo--
ronalrite and nairits). The chemical stability and anti-corrosion properties of
the vulcanized nairits coatings were studied. The conclusion was drawn that 1.2-M
nairite coatings in combination with a~water-reslstant coating applied three times
can reliably protect metals from corrosion due to aqueous solutions of many acids,
alkali and mats. The coatinip were not resistant to the action of oxidizing a-
gents, aromatic and halided solvents. Rubber coatings differ from varnish and
plastic coatings by an increased resistance to abrasive wear. An attempt was made
card 216

27544
"Liquid nairits" - a now notarial for rubborlslng A0514129
to determine the resistance of nairits coatings under conditions of dry friction
using the Orasselli-typo machine. It is concluded that coatings of so-called
crystallizing liquid nalrite obtained In low-temperature polymerization ars supe-
rior to other rubbers in their wear-resibtance, excepting vulcollme, which his a
unique resistance to abrasive wear. It was established that coatings of liquid oil
nalrite are superior to coatings of bakelite, polyethylene and caprons, when tested
in rapidly flowing sea water. Tests have further shown that liquid nairits an a
material for coatings will become widely used in industry In the next few years,
At present tests are being conducted in the North Sea ard the Atlantic Ocean on
propellers of fishing trawlers coated with liquid nairite for protection from car-
rosion, erosion and cavitation. mechanical plants am testing steel covers of re-
frigerators wA condensators coated with natrits, These were previously manufsa-
tured from non-ferrous metals. Certain chemical.plants have Installed diaphragm
valves, the interior of which Is covered with liquid nairite to prevent corrosion
from said solutions, alkali and salts. The possibility of using nairite coatings
in various Instruments as a means for preventing spark formation In percussl~m
has also been revealed. Finally, it was established that those coatings am be
used In certain constructions for hermetic sealing. At the Moscow TETs NO 12 a
vacuum-condensator of a mass-produoed 50 thousand kw steam turbine withstood a
Card A j

2754h
S11*61100010061OW006
"Liquid nairits" - a now material for rubberizing A05VA129
testing period of oni and a half years with the brass pipes aM steel pipe boards
coated with liquid nairite, K. S, Shmurey, 0. P. Abolina, A. 1. Konstantinows. and
0, A. Selivanovskaya took part In the work. Thor* are 2 tables and 2 sets of
graphs.
ASSOCIATIONs Vaesoyuznyy nauchno-Issledovatel'skly institut sinteticheskogo kau-!-
chuka Im, S. V. Lebedeva (All-Union Scientific Research Institute of
Synthetic Rubber Im, S. V. Lebedev)
Fig. 2. Dependence of the vulcanization
duration of the coatings made of liquid
nairite an the temperature "via
IV
&r&aTf4oftn^oOrvuTo1;rM ro%,
hrs
card 4/6

27500
31063116 1/tW/00/004/004
q -Lot. A05VA129
AUTHOM Ryazanova, R.M., Dolgopol'skiy, I.M., Klebanskiy, A.L:
TUISM Perfluorobutadions In the reaction of diene synthesis
M11WICALl Zhumal Voesoyusnogo XhImicheskogo Obahchestvalm.D.I'mendeltrevat
v.6. no, 3. 1961# 356 - 357
TM: The authors have studied the behavior of hexafluorobutadlene In
d-tene synthesis reactions, aharaataristia for a conjugated system of double bob,
They Investigated the motlon of hexafluorobutadlans with malfto anhydride,, 1,,4.
naphthaquinons, lorylonitrill styrene, methylmothaarylate, divbWl vA leoprene,
llexafluorobutadions was synthesized socording to Ref. 41 Ch. Slesser, S.R.
Schram, Preparation, properties and toohnology-of fluorine and organic fluoro-
compounds, N.Y, - Toronto - L*ndon, 1951. It was established that hoxafluorobu-
tadlene does not react with malelo anhydride nor with 1,4-naphthaquinono,, both
without a solvent as well as with a solution of toluene. The reactions with
aerylonitrile, styrene and mothylmethaorylate resulted in the production of ad-
dition products with satisfactory yields, boiling within a narrow tempamtur*
range. Theoretically It was expected that as a result of the interaction bet-
Card 1/4

Perfluorobutadlens ...
27500
SI'063A 1/006/W3/W4M
A051/A129
ween aorylanitrili and styrep~ with hexaf luorobutadions one of the following
structures would resulti
S; 104
where R CHs (~H.
The absence of structures (1) was determined from data of infrared spectra of
these compounds, In the fractionation of the product of Interaction b*tween haza-
fluorobutadlene and divinyl and Isoprene, two fractions each time were obtained,
The determination of the molecular weights, calculation of the molecular refrao.
tions and in analysis for unsaturation Indicated that the low-bolling fractions
were an addition product of on* molecule,of hexafluorobutadions and one molecule
of a diene hydrocarbon. One of the following Isomers was theoretically expected
Card 2/ 4

27500
3/1063/61/006/W3/W4/W4
Perfluorobut&UenS ... A051,1129
from the addition product and divinylo
We*
_10imcfjo HOI& -CF-as
CF -4F-a-CFa
For the addition product and Isopreno, in addition to the listed structures of
type (1) and (11)j the oyalobutans derivative can occur in the form of two Iso-
mers determined,by the position of the group-CH-j with respect to the cycles
CN-Cp-a-Cps CP'-.a_CF.CN
V~
The high-boiling fractions of the addition products with divinyl arA Isoprene
were assumed to be addition products of the second molecule of #.he diene hydro-
Card .3/4

2T500
Perfluorobutadione A051/A129
oarbon to the remaining perfluorovinyl group. Based on the properties mentioned,
the struaturs of these oompounds Is given &*I
cps-0-0-43fl CFG-CF CF-4FO
There are reforenoess 3 Soviet-bloo wd I norl-Boxist-bloo.
ASSOCIATIONI Vassoy=nyy nsuohno-isslodovatelskly institut sinteticheskogo
kaudiuka Im, S.V. Labodeva (All-Union Scientifto Research Institute
of Synthstio Rubber im. S.V. Lsbedev)
Card 4A

LABUTIN., A016 - PaxBANSKM-A.L.; TSUXM*tMs, N. Ya.; KARTSEVv V*N#;TREMip ru.T.I
MALISI A$ L.P.) DOROVIRDVA N.A.1 KARELINAO G.G.; ROMY Tu. F,;
Prinimali uabastiyes iiiiiap X.S.; ABOLIRA,, O.P.1 KONS;aMVAP A.L.1
SELVANOVSKATA, G.A.
Of-lauld nairitts a now material for rubberising. Kauch. I, res, 20
no315-9 Je 161. (XIltk Us 6)
1e Voesoyusny7 nauohno-ioaledovateltekil institut sinteticbeskogo
kauchuka im, S. V, I*bedeva,
(Neoprene)
(Rubberized fabrics)
t

^EZBA%
UU#-A-L TSUXZRWq N.Ta.; KARTSXVp V.N;; IABUTIVp A:L.;
*fU*Vss VSHIIIA, L*P.j BORMKOVA,, N.A. LMLINAs 0 0,;
Idquid mirit., a now type of abloroprone rubber, KaucbA r3A, 20
no.20il-5 My 161. (MIRA 1415)
1. Yeemayusnyy nauaftmo-inaloodystellskiy institut sintotichoskogo
kanabulm in. O.V.Ubodm.
(Rubber, Synthetic) (Nioprone)
. N. -A
P
M
I t ,

39845
5/190/62/004/006/003/016
B117/B144
AUTHOR3s Klebanskiyt A, L.,# Chevychalovat Ke K., Yefremovap Ye. U.
TITLEt Formation conditions and struotur* of dimers obtained by the
bulk polymerization of chloroprene
PERIODICALt Nyookomolskulyarayys soyadineniyat.v- 4, no. 8, 1962,
IM-MO
TIAT: The polymerization of ohloroprens in the presence of peroxides or
tetraalkyl Thiuram disulfide with sulfur at 50 - 550C, and the.effect of
individual factors on the formation of dimers, were studied. Ibeformation
rate and the dimer-to-polymer ratio increase when the polymerization
temperature rises. Dimers are the main products obtained in the presence
of inhibitors. Increasing the degree of polymerization to >70% brings
down the relative amount of the resulting dimers to 4 - 5%. The high-
molecular polymerization of chloroprene in the presence of tetramethyl
thiuram disulfide yielded dimers, of which 65% have the structure of
1,5-dichlorocyclooota-195-dions, whilet 12% were 4-(I-chlorovinyl)-i-
chloroeyolohoxone, The structure was determined by oxidation, ozonolysis,
and hydrogenation at 200C in the presence of platinum blaokg' yielding a
Card 1/2

S/190/62/004/008/003/016
Formation conditions and... Bii7/Bi44
product with the physiooohvmioal constants of cycloootane. The structure
of the latter was confirmed by oxidation with n1trio acid yielding
suberic acid, The prevailing formation of 8-membered disers was explained
by the stabilization of the primary 8-membered cyclic complitx owing to
an increase in viscosity of the medium during polymer formation, and owing
to the absence of catalytic inhibitors. There are 4 figures.
ASSOCIATIONs Vaesoyuznyy nauchno-iseledovetallskiy Institut sintatichoskogo
kauchuka ims Be Vs Lebedeya (All-Union Scientific Rosearch
Institute of Synthetic Rubb*r,imeni S. V. Leboday)
SUBMITTEDs W 5# 1961
Card 2/2

8/06 3/6 2/007/00 2/0 11/014
A057/A 126
AUMORS: Grldlnn, V.P., XlebanaXly, ALL.,-Dartashev, V.A.
TITLE: Boronorganic compounds. Synthesis or sow fluoroalkyl derivatives
of boron
PERIODICAL: Zhurnal vsesoyuznogo khimlcroakogo obahchestva Imeni D.I.
Mandelerva, v. 7, no. 2, 1962, 230 - 231
VEXT: No-cent publicationa treated the instabillty of. perfluoroalkyl
derivatives oA* boron. 71w Instabilityof these compounds with the fluorine atow
in the ~ -positlon can be explained by an Inductive effect. The present authors
observed that this effect to reduced In compounds with the fluorine atom In
-Position Of the tYP6 RFOP.012BX2 where Rp stands for CF3. and X for OH or
OR. Four new substances or this type were synthesized being relatlyely stable
against heat and oxidation. The 3,3.3-trifluoropropylboronbutyleater was pre-
pared according to the folldwing reactioni
C'-?.3C112M1ZMgC1 + B(OC41b)3 - -1 CP3CH2CH2B(OC411))2 + Wl(OC4119) (I)#,
The 3.3.3-trifluoropropylborle aeld CF3CHe-0j2D(0jj)2 was separated from the Mg-
-com.plex of reaction (1) with 10% H2SO4 and subsequent treatment or the mixturd
Ca rd 112

S/063/02/UO7/002/0 11/40 14
Boronorgan1c compounds...., A057/Al--6
with water and benzene. 71-a acid can be obtained also by a heating of the ester
with 5 .14 11C1, The third substance 3,3,3- tri f luoropropy lborone thy 1 -enter
CF_',C'1;1C112B(OC21~5)2 was prepared from the obtained ;'luoropropylboric acid by
he~tlng with excens absolute ethanol. From the same acid was obtained the an-
hydride (CF302012BO)~ by heating with benzene, removing the evolved water as
azeotrop mixture, or y heating In vacuum over a dehydrating agent, such as cal.
cinated A1203. There are 2 references.
ASSOCIATION: Vseao-jruznoy nauchno-issledavatelokly Institut sintatichaskogo
kauchuka Im. S.V. Lobedeva (All-Union Scientific Research
Institute of Synthetic Rubber Iment S.V, lAbodev)
SUMITM August 26, 1961
rd 2/2

=MwErr, A. L.J rCMAj, L. P.; DOIAKWMNO 8, B.
- ----------
Sme methods -of synthesising allazane polymers having pb*sW2
14nu in the chaii. Zb=. MO 7 no.51594,595( 162.
MIRA 25310)
1, Vnso!yuzrqy nnobno-issladovatellskiy institut, sintaticbeskogo
kauchuka Imani. Be Vo l4bedeva,
Mum, 0)

Is- A 9Q010
15'. .2 40
33936
,/62/032/001/014/016
8/079
D204/D302
AUTHORSt Gridina, V.P., Klebanskiy, A.L., Bartashevt V.A., and
Sharov# VA.
TITLEt Fluoroalkyl &ryl derivatives of boron
PERIODICAL% Zhurnal obehchey khimii, va 32, no. 1t 1962, 322
TEXV The compound m-0?3.06H4* B(00 2H5). was prepared by the action
of a Grignard reagent on m-bromo-benzotrifluoride and ethyl borate,
decomposinlothe Xg compi8i7with gaseous HCI. Its b.p. was 900 0/10
mm Hgp d20 1,1433t nD 1.4341. Decomposition of the Mg complex
with 10 % H 280 4 gave the anhydride (a-CF3' 06H 4# BO) 39 melting at
162-1630C. There Is I Soviet-bloc reference*
ASSOCIATIONs Voesoyuznyy nauchno-iseledovatellskiy institut sinte-
ticheskogo kauchuka Imeni S.V. Lebedev (All-Union
Scientific Research Institute of Synthetic Rubber Im,
S.V. Lebedev)
SUBMITIED: July 20,, 1961
Cardw

33937
5/079/62/0--e/ooi/m/016
Is.- C2 402 0 D204/D302
,57 .2 V/ 0
AUTHORS: Gridinap V.Pot Klebanskiyp A.Lo, and Bartashev, V.A.
TITLEs The poculiarities of behavior of the organic eaters
of boron with fluoroalkyl aryl radicals
PERIODICALs Zhurnal obahshey khImiiq v. 32, no. l# 1962t 323
TEXTs Interaction ;of aryl borates with POI 5 give', generally the
correiponding dichlorides. The action of PC1 5 on m-C?306H4B(002H5)2
resulted# howeverp in m-0013'0000012 of b.p. 1120C and a small
amount of m-CP 3.06H4 B01 . of b.p. 740C, m-CO13C6H4BCl2 splits off
all 5 chlorine atoms on boilin with alkali and hydrolyzes in air
to the anhydride (q-001 306H 4B013 of M.P. 19200 and not to m-001 306
H4B(OH)2 as expected. There to 1 Soviet-bloc reference.
ASSOOIATIONi Voesoyuznyy nauchno-isoledovatellskiy institut sinte-
ticheskogo kauchuka imeni S.V. Lebedev (*&*NXW&en
CardA0

AUTHORSs
TITLE:
MIODICALs
S/079162/032/001/016/0,t
D204/D302
Klebanskiyj A.Lj Yuzhelevskiys Yu.A.j Kogan~ )t.Vf
and Kaganolesu*
The isomerism of 1,3p5-tris(3t3t~,-trifluoropropyl)-
10t5#trimethyl cyclotriailoxane
Zhurnal obahchey khimli, v& 32# no 1#1962t 323-324
TEXTa A description is given of the hydrolysis products of 3#3#3
trifluoropropyl mothyl dichlorosilane# at 190-2100C/18 mm 0-' in
the presence, of 0.5 ~ KOH (as 50 4, aq, solution), The distilglats
collected at 1300 0/18 mm It consisted of --80 14 of castals Sl$
of map. 35.200# baps 2430 V759 mm Hg, d 440 1.2309, nD4U 1-359 and
,',v 20 % of a liquid (II) of maps -15,5009 bep, 23900/759 = Hgt
20 20
d4 1.2576 and nD 1,3669. The molecular weights were practically
identical, Either compound rearranged to a mixture of I and Il whon
heated with KOH under Ahe above conditions and it i7ang therefore#
concluded that I and II were aterooisomerst
Card 1/2

DR=OV# GV. :LLZBUSKIY A9L.j BAHTASHOVp V.A.
hvparation of psrf2uwvo*yUxy dorlratives of
titanium, Zhursobakhiso 32 noo7s2390-2391 JI 162o (WA 1517)
(Titanium orgazda ocapounds)
t
MK`

S/079/61/032/012/008/008
D424/U307
AW1101115: 11onomarev, ji.i. and Klebanskiy,_!~A.
TITIZ: Oromination of octm.%athyleyelotatrasiloxane. III
PERIOD ICAL: Zhur~al obahchey khimii, v,'32, no. 12, 1962,
4022-4025
T= ,Vr: Bromine does not rcact thermally irith oct.-nothyl-
cyclotetrasilw.cane at temperatures up to 1500C, and with ultra-violet
irradiation the mixture reainifica even at room tenqmrature. It is
now found that octamethylcyclotetraniloxane can be brominated smooth-
ly with bromine chloride under the influence of the radiation from
an electric Ion. i. The fact that no rcaction takes place in the dark
shows that is i's a free radical reaction and not, like moat reactions
of bromine chloride, an ionic one. The action of 80 g of bromine,
in the presence of the necessary =ount of chlorine, on 636 (S of
octcn.athylcyclotetraniloxana yitlded 212 S (45.5;o on the siloxam
that had reacted) of monobromo derivative, 139 g (23.1%) of dibromo
derivative, and 44.7 g (6.3") of tribomo derivative. It was shown
Card 1/2

:;/D79,/62/032/012/008/003
Brominationlof D424/J307
by hydrolysis of the dibrdmo and tribrorAp der.,.-iativea with potassium
hydroxide and the icolation:of methylene ;)romAdc and chloroform,
.respectively, in high yieldb that these corVp4nds were dibromowthyl-
and tribromoma thy lhexam. thyl cyclote tras i loxans a, the latter cotkiound
being the first reported.to:contain a tribrofao'methyl group attached
directly to a silicon atora.! There is 1 table.
-11TTED:
S
UBI January 0, 102
Card 2/2~

KtZBANSKIY# A.L.1 SOROKINAp R,M,
Autoxidation of chloroprene by oxygen. Zhur.prikl.khin. 35
no.'l2s2735-V40 D 162. 1.615)
(Chloroprone) (Oxld&Uon)

DOLGOPLOSK, S.B.1 CHEBYSHEVAt L.M.; -KIZBkNSKIY A,L.; SHVARTSj Yeolu.;
FWMA, L.P.
Some properties of rubbers made from sib=ane polMrs contAining
arylene links in the principal chain. Kauch. i res. 22 no.9&
1-2 S #63, (KIRA 16oll)
lo Voosayusayy nauchno-isslodovateltskiy inotitut sintati-
-Oaskogo kauchulm in. SV. Lobodeva,

LARIONOUs M. A., UMUM= A. L.1 BARTASMITO V. A.
Systhemis of mom 3,3p3-trMuereproffl derifitITOO Of
pboophorus. Zhur. ob. khts. 33 no.11265466 163.
(MMA 16t 1)
1, VasmayusVy nauchno-issledantellokly Institut mintsti-
abaskago kauebuka issal S. V, l4bodeva.
(Phosphons orcanic oampoumb)

21/023'
Be/0047y63/033/001/0
m D3
07
1UTHORSs A
Ponomareirs A& It%# KletgnqkiyA_A_,ju jLarionova# Yu.
and Bogdanovag V,'V.
:TITLEs The preparation of 2-cyanophenylmethyidiethoxysilans
:PERIODICALs Zhurnal obahchey khimii, V. 33, no. 1, 1963t 31
6
TEXT: Broxopbeny1methyldisthoxysilane (1) was'obtained by react-,,
',ing metj;loh1orqdiethpxysi1ane with 2-BrO H MgBr. The Br in I was
6 4
.'then replaced with a nitrile group to iva n-ayanophany'Sethyldi-
iethoxysilans (b.p. III - 11206/3 mm Hg! nie- 1 050329 di a 1.20589
D 57.69)t in 45 - 50% yield. I"Abstracter's notes Essentially
icomplete translation,.7
ISUBMITTEDs August a. 1962,
ECeqd

UOAVO Ye.C.1 XUMEKne A.L.1 UWANWAS I.V.
Synt.besis of I sow etlwx7sil=v9 AM disl1=421~6 vith
3.3 3-trinuomropyl sr*ups* Z,hur.ob.khis. 3) no.2*701..705
7 1 (KMA 164)
1.,Voeooyuww naucIbno-issiodavateltakly inatitut sintetichOskWO
lcauchWcs imed 3J.,labodm,
(SlUcon organto compmms) (Propane)

rut ijhxrrp A.Lal WIAOPOLISUlp IoMj DOBMp Z.F.
cam~lsx oo%mnb of aostylons vith CuM - Miel. Part 1. 1.
,Zhurobokhim, 33 no,,)s761-768 Hr 163 (=A* 160)
(Aoo+.ylsno oampounds) (C"r Worldom)
(Ajmni= cUoride)

EMANSM- A-Lot D0140POLIMalt I*X,; DOB=, ZJP,
"t of variou facUrs on the formtIon of the ouglax
r.-S Of OAWtYUM with CuC1 - ~H,4CI1 and properties
Of the latter. Part 2. Zhur-ob-kbis- 33 00*3:7W772
mr 163. (KIM 1613)
(Acetylene comeowds) (C
err chlorides)
tAnmmiun chloride

DOLGOPOLISKIX$ LMj Kno A.L.; DOBLERp Z*V*
4in
Stfact of the natwe of cations M M* on the composition of complax
compounds of acetylene jith CWI - MC1. Pgrt 3. Zhur-Ob-,k a* 33
X106010744076 Ap 163* (Copper chloride#) (MIRA 16.f
(Acetylene coqwws) (iZo;iX chloride)

" lill~ 'l;~?,..,.-,-,l .-
~z !~ '. !" ~.; I-, - r- :
7 - -

BMHTEYNO L.L.1 YUZHFJMSXITV TuA.; MN, E.V.1 KLEBANSXIY# A*L*
Struoture of Isomero of 1,3,Jvtris (3.3.3-trifluomroPYI)-lo
3p5-trlmthylcyolotrlsll*xm*, Zbur. ob. khIm. 33 noA2789,~
2790 Ag 163# (MrPA 16M)

DOLGOPOLISKIY, I.M.; KTXWA IT, A*L.; DOMER, Z.F.
Iffeat of W uturs of aation 0 in mol an the adalytic aauvlty
of CuCI soluUcns# 2mroprikl.khim. 36 oo.lolft-W Ja 063.
(XMA 160)
(Claorldes) (Aaotylans) (Catalysis)

DOLAOFMISMi I.M.; XUUMXITI I.Lj DOBWO WO
Woof of the nature of cations An JC1 on the catalytia 'astivity of
solutions cum - 14 dwring the process of vimla"ty2sul dinerlsatims
lhur-priklekhiml 36.mo*2094-398 7 163. KM& 160)
(P017mrimuon) (Olorides)
ilk

P1
A k-P3-601404 8/0020/63/150/004/081310813
04 6-,;_
V12~M11-11JW TO
wRcs I AN SSS11 t6kI dy-" 'ISO -A -813-815
a Ve no*
TOPIC TAGS t siloxane polymers, pheftyleine groups# tatramethy1disilaxans#
I-disethylailyl-4-dimthylailonyph 4ailane, elasticity, x-ray patisno* thenw-
mechanical curve$# glass transition temperature
~Gssarch ,Kb the object of UWroving the beat
ABSTRACTt has been undertaken v
reslstaft4 and resistaftee.to 1!g%dI$tIo01%f siloxana polymers and the pbYlIC-11
and mechanical properties of vuletnizates. The authors synthesized's ausbar of,
now rubberlike silaxane polymers of high molecular weight (intrinsic viscosity
in benaent, 1.2 to 1.9), with phanylano groups In the b&ckbofte and various
aromatic groups and substituonts at the Si stoo. In.one of the compounds# the
CH;,,CHC?, group -- is - uded - so- asubstitus"t. - The effect of phsayleim- groups- on -
the properttes-of silaxano a was-studiod on copolymers containinev
"A
Card
- L;

ACCESSION NRS A?4oi$osS 8/0079/64/034/002/0702/0702
AUTHORt Dmokhovskayajo Yes Ponmarsvp A* I$
TITLE: Synthesis and some properties of silines with dinitriloamwi
radicals
SOURCIfs Zhurnal obahchey khimii, v. 34, n). 2-, 1964, 702
TOPIC TAGSs silemej dinitriloalRyl radical 'I *orpnosilicon compoundp j
methyl-Beta, Beta-dioyanoothyldiethyloxyallanep dicyanvpropyld1ethoxy-,,..,-.
silane# ohmical synthesis
ABSTRACTs In order to eMlain tho effect of the ni tril oalkyl radical
combined with a silicon &too on the proportion of an orpno*IUG*n
-thoxysilane was synthesiseds
pompound,, methyl-,0. ,d -dioyanoathyldie
avicoo~v$), ,M CHACONMIh V4 CHACN)l W!M
NAMCK)l + SWA=j1,(0C^h V'C)%MC*v1(CMoCqff4h
Cwd
_F"
5 - -

ACCESSION NRv AP4018058
0
Mothyl-.,d,.g-dicyanoethyldiethoxvellans Is an extremely unstable
spontaneously resinifIG4 compounds When stored in darkness for a
month in a medium of inert gas at',room temperature the product was
'converted froma clear liqutdp boiling point 145C t7M),j into a via-,
cous black resin. The resinification of this compound is explained
:by the protonization of hydrogen,, combined with the 4-carboWatom.
1he substitution of the free hydrogen atom in the electron donor
group should lead to the stabilization-of such a compound. As a re-
sult of synthesis from -the diethyl eater of methylmalonic sold#
mothyl-A,0,4-dioyanopropyidiethoxysilane was obtained in which the
1nitial properties were unchanged over a prolonged period. At pros-
ent, the conditions ofhydralysis of methyl-,,0,v;0-dicyancpropyldi-
ethwWailane and the composition of the hydrolyzate are being studlodf.'_
Hydrolysis-In neutral and slightly alkaline mediums with an'excess of
ws,ter provides a vitreous product with*a softening point of 1250.
Hydrolysis in said sodium leads to a breakdown,of the nitrilo
group
Orig. arts hist no formulaeg figureap or tables,
cam

ACM=CN M AP4034370
AVMRI Xenon, N.' Lj Chupmvp Vo A.; Mebans3dy,, A, L.
TI=: Synthesis of certain Morino containing
diisoprq?oxidess
SOMMI: MurnalobahahOY W111's, v- At no- 4* k9S6* 1355-3356
TOKC TAGS% 110MIMIM
alimovorpoxme.. axylsilaxpli-im- CIA 0-5
A U~
isynthemisp trI VaIndm- 0p trio
Alumium tri"Opropoxids,
AWnV=: Previously unkmom OX78 coutidnim
trUluoroprqVl and a-trifloorometbylphoWl gwVs at the al 14 am &tom were
synthasize& by re"Ung the 40zvpdate taqvilanes with Aluminm
trilsopropoxida In bwmwo vith Owtim is "Ootrago r"Naval ot the Isoprowl-
aceutel
Card, 2/2

nt*-'AAoA570'
(11)1.,21000CUS + Al("-OClNs%,
BoMns towratum dwsities =& reftvative JAUces &re givm tar tU foUaw-
sAg C=WMAS s Y. r, 7 trulwlwvopyjAlwtl*utl**%l=lrm
amilva4mus
Y. Y, 1( -trJMuor*pr*w*=tw"
trifluo .)s4 103wij"Ajm~
I Orue 0b" I IL tabU I "timso
A&SOC=Cff: Now
SMMr=s UOa"3 UM AMs M&A MCLS
M
BOVI 000 MM'S
am ome, OC 10 Aw
cOrd
2/2-

ACCE=CN'NRt'- AP403 7059
AUMOR: Orldimp To Yet akbmskiyj, A, BartAsboys Vo A*
TETIM, "si*.4_pf flwroollql derivatives of baiwolso
SOUPM Zlnsrnnl obahche% Alidis v. 3ho no..5,, 19&,t AM-W3
TOPIC TAGS. borsiole) flwx*&%JW2bor&t*le# flwrlm omtsining borazole.. syntheslm~
AMTRACT: Tim now f1wrice-mtolniag derivatives of borazols vere syntbesizede
B-triabloro-B-tri(tMIlwioetbyl)bmwls,o melting st 25OCj vas preWvd by
boilin&,C:F=-HC1,snd for 15 bours and pre"pitatue
DC13 'a
:3Bch+3cF$cH2"ul-Vcl cr3cul-d . -cl[,cFS+9HlR
Icl-A L-cl
A bitmatioma B-cono0mroal)WI-owtainin borazolm, B-WW(3,3,3--trLfluozqpr*pA
-8-triphaw2boralales, meltias at LPA-1300# vas obtained by alkylatim 9-tripbawl-

-ES'
ACCESSION NM AP4042083
;fx 4
~17:THQ
AUTHOR: Yushelovskiyo V~. A.; Xogan, 1. V*-, Klebanskiy. A. L.; Lariomma. 0. 1.
TITLEs 3,.3,3 Trifluoropropyloothyleyelositaxanos isomrs
SOURM Zhurnal obahchey khimii, vol. 340 no. 6, 1%4, 1780-17U
TOPIC TAGSs trimer, pentamer, stereolsomer. hydrollsate
ABSTRACTI the authors established that a triverl obtsinWduring the catalytic
destruction of the hydrolisate 3031,3-trifluoropropytiothyleyclosilaxa"g is
a mixture,of two stereolsoffifirse Wring thi catalytic destruction Ffft*S$,O In a
Claisen fask at 2000 (4 =)# a distillate was obtained wbicb was a cyclic 3g3#3-
trifluoropropylaothyleyclosilsxm" Mum. the authors concludeA that fardwr
InvAhigation is necessary to clarify the structure of the composed.
''.ASSOCIATIONs none
SUBMrMDs 04feb" UCLI 00
i SUB COM 00 NO R17 SOVs 001 MRs 003

YUZHEMSKIY,, Yu.A.j KOGAN# E.V,; KIYJMMKIY.. A.L.1 LARIONOVAv O.N.
Ift"Wh"
Rearrange0ant of 3.3t3-trifluoropropylaothyloiloxan@s in
acetone tmder the effect of,basio catalysts* Zhure ob& khIm.
34 noo8o2810 Ag 164, (MRA 170)
1. Vassoyusnyy nauabno-Issledovatel'skiy Institut sinteticheskop
kauchuka imeni S,V, Lebadevao

ACCESSION MRs AP4017643 3/bl90/Qwt"/0O2/03V/0334
AUTHOFS r Xyullerp 9 Yo o Apukhtins No Pe
ilk
TIMs Chemical chain structure and properties of 01yesterurethan elastamrs,
Dependence of vitr"%oatlon temperature upon the nature of the po2ymeric Ch&$A
SOURCIt Vy*sokdao1sku1yarny#A sOP"'ItYMP To 6# rp& ~, 1904 329o334
TWIC TAGS: elastamero urethan, Alkyl carbamate$ polyesteru rethans polymer,,
polymeric chain,# vitrification, slasticity* mathylene group, adipurethan
AWTRACrt Polyurethans (average molecular weight. of 20 M') with an Increasing
concentration of 04-C link in the main chain, such as,p*lydiethyleneadip"Othan
MAU),, polytriethyloneadipurethan (PTA19)* and polyhexaethyUnsadipurethan (MaL
were studied* Ether bonds were introduced into the polymeric chain to increase LU
flexibilityp which in turn would enhance Me frost resistance of the dedy"
The Arost resistance of rthe polymers was evaluated br means of the U
elastometer of the,'pandulum, rabound'type vithin a temperature range from -90 to'600
and by determinations of the vitrification tomperaturej using Way's apparatuso
It was found., that Vithin the PDA% PTAUj and FRAV sari" a lovering of the vitri~
Lirtiqn- temperature accurs with a diminution in the concentration of "ter groups

- -- - - - - - - - - -
ACCESSICH NRS A?4%760
i~ in the repoatW unit of the corresponding polymers. It was also established that
the magnitude of. the difference between vitrificatAon tomiperstures of the
linear polymers and of their 00464~ minimms in the Slast"ity curves re-
I mains strictly eonstant* ammtbw 6C* A certain periodicity in the ohm
-of vitrification toopperature in the Imestigated po2prethans coWA be relatiod to
an oven or odd ambor of metWons groups In the glyool links,of thothalne Orils
art. has: 1 table-pi 2 formulasp CA 2 charts.
AWOCIATIONt VsssoyusnM nauchno-isslodovatellskly institat sintotichaskov.
a (An-Union Scientific Research Institute of Synthetic Rubber)
kauchuk
SUBXTTTEDs 04J&*63 DATS AM t Mar& IVOLS 00
10 RV MY t 003
SM ODDEs. CH
Card 2/2

ACCESSION NR: AP4042194 8/0190/64/1006/007/1330/1334
AUTHOR: MYullors 13- YG-t APUkhtinat N. P.# Klobansidye A. U
TITLE: Effect of the chomied structure of polyester urethane on their crystallIzabilitY
SOURCE: Vy*so1wmolskulyaMy*yG 0"dinonlyao V, Gj no. Tt 1964g 1330-1334
TOPIC TAGSt urothant polymer crysts.111sability, KS pendulum Islas tar, owtiow
modulus, aliqladiphtate urethan# polyester, polyester urethan, jzl~mor stnioture,
dUatorneter, glycol aster
ABSTRAM In order to clarity the relationship between the chum loal structure of urethm
polymers and their crystallizability, the crystallization process was sbAsd dllawmdria~w
and : pondulum-type KS olastomoter on the basis of the variation In the modulus of .
4w0 lasUcity with temporahwe (see Fig. I in the Enclosure). The eqMrimental. curves
Ized fim' glyoolosters of dl-j tri- and hexasthylone &*p1&W
show that polymers synthes
I urothans. as well as polymers with mitfioxyzii~ and propylethylons adiphu" urethans,'
are amorphous polymers, The amorphous nature of di-, tri-and homothylone adipinate
urethan in due largely to the disorienting effect of flexible C-0-C bonds, proventing die
formation of nuclei Its oxygen atoms of the other bond destroy the regular chain
structure. In po;;~ethoxymotbyl and propylethylons adl*stos, the large chains FMWA

ACCESSION MR: AP4042194
q
crystaffization. Polymers obtained km glycols of the pDlymethylene sod" (ethylens,
Arimethylene, tatramethylone aW pentamethylene adipinato urethan) are crystalline poly-
more. 2%o highest rate of orystallix-ation Is shown by tetramethyleneadipinate urethan and
pentamethyleneafthuft urethan (2.2% per hour), Mowed by trimethylene and ethylene -
adipinate urethane (0. 11 and 0. 06% per hour, respectively). 7he half time of crystallization
dfor the last three polymers were 40, 1120 &W 1060 minutes, and the degree of crysiallizallon
Vas 2. 1, Is 7 and L 0%, respectively. 7'he fad that tetramethylen" U urethan allow
pim
'the highest crystallizability among the orystallins polymers is due to the Very regular am
!symmetrical structure of its macromolecules. U Is characteristic that t4trAm4dWU"_
adipinate urethan has the highest molecular weight. This indicates a denser
macromolecules. lower ystallizability is due to the fact that In forces
Increase the chaotic arrangement of do macromolecules. . render Umm Uss mobUs, and
thus interfere with the orientation pwoess. Orig. art. has: 4 figures.
~ASSOCXATION: Vassoyasyn*1 nanchook"IsdovaWfaldy institul; sintedchaskW Wuichulca
4.411-Union Scientino Reseazv~ Ludituts for Synthetic Rubber)
SUBUMSM Mlepa =14 01
SUB COM 00 NO REP SOVt 003 OTWM No
2/3 -
Car

,ACCEMON NRt AP4042194
Fig. I Temperaturtv
depeadwas of the
modulus of dynamto
elasualty of UNUM
polymers based on
glyool odors:
16,
-JM
?6~
#10
I - diethylawwUptate-urethant 2 -
3 hexaOthylawwdi*MA-U~.
3A
rn

299L9_65 W(M)1UF(G)1iWP(J)A PC-j,/Pr-b RY
v A.P5005388 S/01 38/65/0W/002/W0l/0W2
AvrHoRst Wbkov, V. Doi Klebansk ;L~_,
A. L. I Aoran. K, V.
TIMB: The affect of oxide derivatives of phosphorus on viloxane Polymers
SOURCEt Kauchuk i retina, no. 2, 1965, 1-2
TOPIC TAGSo phosphorus compoundo silicon organic polyiker
ABSTRACTs The primary act of interaction between 04 (.A)-dihjdroxy1-diMtbY1.silox_
anes and oxide derivatives of phosphorus is the formation of -imwourds 7
that activate the condensation of siloxandiols and the oxidati. n of organic radi-
cals, enveloping the silicon and phosphorus atoms with bydrogen at low temperatures.
Preliminary data an the kinetics of ox7eon sorption 'u-49sphorosiloxans Eg4=rs
shcw that the rate of oxygen sorption at LrAr. is twice that at 60G. But at 1000
no oxidation of the polymor is observed. This mav be due to decal if tne coordi-
n.ition tonda at this temperature. The 41metoiy1allomane polyvmr does not, oxidire
uMor these conditions if oxide derivatives of phosphorus are not presnnt, Uries
art. hami 1 table.

L 29949-65
ACCEM081 Mt AP5005368
A39M WIGN i ToesoyurW amobno-isalodmtel okly inatitut sintat ichaskogo
kauchuka in. S. V. Lebodwra (All-Urdon Scientific Research Institute of Syntheti
Rubber
"~UTTM 1 00
EMLi 00
SUB COM OC
NO RU WVi 000
orml 000
CcwJ 2/2

EWT(in)/L-_PF(c)/UW(J)/T IIC-4/rT-4 RM
ACCESSION KRi A.P5003839 5/0190/651/007/001/0163/0168
AMORS1 Lobkov, V. D-i Xlebanskly# A. L. I Kopn, E. V ; L'y-ov, Yu. A.
TITIX: Effeot of ox~rgvn oompounds of phosphorus on silarane 3 M ri
i-'.! 7Yqokozo1eku1yarnyy9 80yedinentla, V. 7, no. 1965,
TOP!-' TAGSt phoophorua compound, polymer
A&M'RA7-ri The effeate of oxygen cowpounds of phoophonts on eiloxane polymers were
rixperimentally investigated. The addition of 0.% of orthophosphoric acid (PiSl
to a , 61 -di1VdroVdLmethYlsiloxs;ne9 (Of DS) atr_--ophere at room
) in an argun
temporature produced a very viscous rubberlike pobrr-arl(after I day H - 26o om
after 3 days-350 000; after 20 daye-400 000). k4ding :_% of triphmVIphiosphate
(P: S i - I t 2 50) at room temtperature in argon produced a rubbor I i ke polyzer (af tee
1-v M - 1,19 CKY)i after 2 daYs 395 000; after 50 days 400 000). Reaction with
n----,'.pho~phite I )or trinony r
lphoophite did not p oduco a vimroeity increase. The
9~awth of a phosphorosiloxane Tol~m;;r -lbt%inel by polly=~irizing
with metl~rTphoaph(mic ftcid by vaigbt~ in tho
if HC1 at 150C is shown in Fig. I on the Fncloguro. 'It was established
that roaction of DEIDS with derivatives of 5-valent phoophorna produces coordinated
Ccrd 1/3

L 33511-65
ACCMSION RRi APW3839
polymers. The coordination in apparently carried out by Meann uf the unshared
Plectron pairs of the oxide and ailoxane ox7gens and the vacant 5d orbitals of the
7on and phosphorus atoms. The data augges ted that the o-grCt-n compounds of
cause condensation of the ailoxanediols; with liberat.'on- of water and
fo-mntlon of ailoxane bonds. To prove this premise, ft P