SCIENTIFIC ABSTRACT KHORLIN, A.YA. - KHORMUSHKO, S.P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000722310002-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 18, 2001
• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

KIffORLJN, A. Ya. and KOCUIMV, N. K.
"The Triterpenoid Saponine from the root of Aralia manschurica."
REPORT to be submitted for the Symposium on the Chemistry of Natural Produots,
Intl. Union of Pure and Applied Chem. (IUPAC), Melbourne, Canberra, and Sydney,
Australia, 15-25 Aug 60

@'. , ".),I
KITORL[@" A. YA., 7A'@JK'j'V')KIY, V. v. 'JI.IJ-11 'rul. @".7
(UsoR)
1'1nvestL-,-itL-ms of Triterpene Sap.)nins."
qe-p-)rt presented at t' 'ie 5t'i International Biochemi9try Congress,
1,
i-koscow, 10-16 Awl,ust 1961

KOCHMOV, N.K.j KHORLIN A Ya - VASIFOV-SSall, V.1e.; ZEY'RBLIS, V.1e.
. 0 *$
-------------,
Triterpenic saponins. Part Is Saponims from Manchuri= aralia.
Zhur. ob. khim. 31 no.21658-665 F 161. (MIRA 14:2)
' ' "'N
1. Institut khimii rirodnykh soyedineniy.Afl SSSR.
Saponine)

-- KHO A.19-1 VOROTNIKOVAP L.A.; Ko(;wrKov, N.s.
Amines with gangliolytic activity. Part J+s Tertiary aliphatic
amines with a branched chain, Zhurob,khims 31 no.6:1827-1830
je 161. (MERL 14:6)
1. Institut farmakologii i khimioterapii Akademii meditsinskikh
nauk SSSR.
(Amines)

KOCRETKOV, N.K.; KHORLI
--- 14, A.Ya.; CHIZHOV, O.S.
Chemical investigation of Schizandra chinensis. Part 1:
Schizandrin and related compounds. Zhur.ob.khim. 31 no.10:3454-
3460 0 161- (MM 14:10)
1. Institut khimii prirodnykh soyedineniy AN SSSR.
(Schizandra chinensis)
11-1;-.-, ... ;

KOCHETKOV, N.K.; KHORLIN, A.Ya.j BOCIIKOVp A.F.
Synthesis of k-straphanthin-@& Dokl, AN SSSR 136 no. 3:613-616
Ja 161, WIRA 14:2)
1. Institut khimii prirodJaykh soyedineniy AN SSSR. 2. Chl+ -Ir
korrespondent AN SWR (for Kochetkov). w
(Strophanthin)

KOCHILTOKOV2 IT.K., 1-TORLIN' A.Ya.,- CHIZHOV, O.S.; SHLYCILENKO, V.I.
Chemical study of Schizandra chinensis. Report No.2: Structure of
schizandrin. Izv. Ali SSSR. Otd.khim.nauk no.5.-850-856 My 162.
(MIRA 15:6)
3. Institut ldiimii priodnykh soyedineniy Ali SSSR.
(3--hizandra chinensis)

KOCHETKOV, 14. K.; !,-",Ol!LII:, A.Ya.; GIIIZI',%"V, O.S.
Chemical study of Chinese nchisandra. Report No. 3: Synthesis and
ultraviolet spectra of some derivatives of 2,,3,4,21.,31,,41-
ehxamethoxydiphenyl. Izv. AN SSSR. Otd.khim.nauk no-5:856-861
My 162. WIRA 15:6)
1. Institut khimii prirodnykh soyedineniy AN SSSR.
(Schisandra) (Biphenyl)

KHOUIN, A.Ya.; BOCHKOV, A.F.
Thin-layer chromatography of glycosides. Izv.AN SSSR.utd.khlm.-
nauk no.6:1121-1122 '62. (MERA 15:8)
1. Institut khimii prirodnykh soyedineniy AN SSSR.
(Glycosides) (Chromatographic analysis)

rELYAKOV, G.B.; STRIGINA, L.I.; KHORLIN, A.Ya.; KOCHETKOV, N.K.
Glycosides of Panax ginseng. Izv.AN SSSR.Otd.khim.nauk no.6:
1125 162. (MIRA 15:8)
1. Dallnevostochnyy filial Sibirskogo otdeleniya AN SSSR I
Institut khUdi prirodnykh soyedineniy AN SSSR.
(Glycosides)

YELYAKOV, G.-B.; STRIGINA, L.I.; KHO KOCHMOV, N.K.
Mycesides-frm ginseng roots (Panax ginseng C.A, VAT). lzr.
AN SSSR. Otd.khim.nauk no6ll:2054-2058 N 162. (MIRA 15:12)
1, Dallnevostochnyy filial Sibirskogo otdolemiya AN SSSR i
Imatitut khimii prirodnykh noyedineniy AN SSSR.
(Glycosides) (Ginseng)

YELYAKOV, G.B.; KHORLD, A.Ya.; STRIGMA, L.I.i KOGHETKOV) N.K. -
. I
Triterpene saponins. Report No l3aArallozido A frum AraliapobaWtii.
Izv.AN SS6R.Otd.khim.nauk no.9.160Fo'-1608 S 162. .(DURA 15:10)
le Dkilnevostochnyy filial S:Lbirskogo otdoleniya AN i Institut
khimil drirodnykh soyedineniy P11 S66H.
(Saponin ) (Glycosides) -.- -i-..

KHORLINJ. A.Ya.,- OVODOV, YU.S.; KOCIIETKOV, N.K.
Triterpene saponins. Part 21 Saponins from Gypsophila pacifica
roots. Zhur.ob.khJm. 32 no-3:782-791 Mr 162. (MIRA 150)
1. Institut khimii prirodnykh soyedineniy AN SSSR.
(Saponins) (Triterpenes)

KHORLIN, A.Ya.; F-OGMOV, A.F.; BAKlNGVSKIY, L.V.; KOUETKOV, N.K.
Glucosidation of 2-0-trichloroacet-rl-3,4,6-tetraacetyl-
/3-D-glucopyranozyl chlorides. Dokl. AN SSSR 143 no.5:
1119-1122 Ap '62. (MIRA 15:4)
1. Institut khimii prirodnykh soyedineniy AN SSSR. 2. Chlen-
korrespondent All SSSR (for Kochetkov).
(Glucopy-ranosyl chloride) (Glycosides)

KOCIIETKOV, ILK.; IKHORLIN, A.Ya.
OlIgosIdes, a new type of plant 21yousides. Dokl. AN SSSP 150
no.6.-1289-1292 Je '63. (MIRA 16:8)
1. Institut khimli prirodnykh soyedineniy AN SSSR. 2. Chlen-kor-
respondent AN SSSR (for Kochetkov).
(Glycosides)

KOCHETKOVI N.K.; KHORLIN, -Y" VASIKOVSKIY, V.Ye.
Triterpenic saponins. Report NO.5: Structure of aralosides A
and B. Izv.AN SSSR.Ser.khim. no.8:1409-1416 Ag 163. (MIRA l6s9)
1. Institut khimil prirodnykh soyedineniy AN SSSR.
(Saponins) (Glycosides)

KOCHETNOV, Nikolay KonstantinovUb; KHDYIIN, A. Yaq
00ligosides-New type of plant ZVosides."
Report to be submitted ior the 3rd Intl. Symposium on the Chemistry of
Natural Products (ITJPAC)p Kyoto., Japan., 12-18 April 1964.

KOCHETKOV, N.K.; KHORLIN, A.Ya.; VASIKOVSKIY, V.Ye.
Triterpenic saponins. Report NO.4t Structure of aralosides A and Be
Izv.AN SSSR.Ser,khim. no.8s139&-1408 Ag 163. (MIRA 16:9)
1. Institut khinii prirodnykh soyedineniy AN SSSR.
(Saponins) (Glycosides)
Lg

KHORLIN A.ra,,- OVODOV, ru.S..; OVODOVA, R.G.
Identity of gypsoside and triterpenic saponin obtaimd from
Gyp9ophila paniculata L. Izv.AN WdR.Ser.khim. nlo.8tl521-1523
Ag 163. (MIRA 160)
1. Institut khWi prirodnykh soyedineniy AN SSSR.
(Gypsophila) (Glyconides) (Saponins)

A.K4.; OIIODOV, Yu.S.
KOCHETKOV, N.K.;.MjQ
Triterpenic sapon1w. Report No.7; Monosaccharide composition
and size of the catbohydrate moiety of gypsoside. Izv.AN SSSR.,
Ser.khim. no.l:@3-89 Ja 164.
Triterpenic saponins. Report No.8-. Some data on the structure of
the carbohydrate moiety of gypsoside. Md.00-99 (MM 17:4)
1. Institut khimii Prirodnykh soyedinenly AN SSSR.

KOCHETKOV, N.K.; KHORLIN, A.Ya.; BOCHKOV,, A.F.
Monosaccharide orthoesters as glycosidation agents. Izv.
AN SSSR. Ser. khim. no.12:2234 D 163. (MIRA 17::L)
1. Institut khimii prirodnykh soyedineniy AN SSSR.

KHORLIN, A.U.; BAKINOVSKIY, L.V.; VASIKOVSKIY, V.Ye.; VEN'YAMINOVA, A.G.;
OVODOVY YU.S.
Triterpene saponins. Report No.6; Distribution chromatography
of triterpene saponins. Izv. All SSSR. Ser. khim. no.11:2008-
2011 N 163. (MIRA 17:1)
1. Institut khimii prirodnykh soyedineniy All SSSR.

KHORLIN, A.Ya.; IVANOVA, V.M.
Detecting and studying the chemical composition of the
active substances of,Patrinia tntermedia. Apt. delo 12
no.6:31-r36 N-D 163. (KIRA 17:2)
1. Institut khimii prirodnykh soyedineniy AN SSSR i farmatsev-
ticheskiy fakulltet I Moskovskogo ordena Lenina, meditsinskogo
instituts, imeni I,M. Sechenova.

KHORLIN, A.Ya.; VEWYAMINOVA, A.G.; KOCITETKOV, N.K.
'Structure of calopaw L-saponin A. Dokl. AN SSSR 155 no. 3:619-
622 Mr 164. (mIRA 17*5)
1. Institut khimii prirodynykh soyedineniy AN SSSR. 2. Chlen-
korrespondent AN SSSR (for Kochetkov).

XMIETKOV, N.,K.;-.-KHORLIN, A.Ya.; CHIZHCV, O.s.
Chemical analysis of Chinese magnolia vine. Report No.4:
Extractiono structurep synthesis of deoxy schizandrine
and the structure of T-schizandrine. Izv. AN SSSR. Ser.
khim. no.6:1036-1042 Je t64.
(MIRA 17:11)
1. Institut khimii prirodnykh soyedineniy AN SSSR.

,
I R
qjO LIN,_,A.Ya.; BAKINOVSKIL L.V.; VASIKOVSKIY, V.Ye,
N. Aralosides A, B and C from Aralia elata. Izv. AN SSSR Ser.
khim. no,.7:1338-1340 Jl 164. (I.MillA 17:18)
1. Institut khimii prirodnykh soyedinenly AN SSSIII.

KOCHETKOV, N.K.; KHORLIN, A.Ya.; OVODOV, Yu.S.
Triterpene Baponins. Report No.qt Structure of gypsoside.
Izv. AN SSSR. Ser. khIm. no.8:143E-1446 Ag 164.
(MIRA 17s9)
1. Inatitut khimii prirodnykh soyedineniy AN SSSR.

-KHORLIN, A.Ya; VENIYAMINDVA, A.G.
Triterpens saponins. Report No.121 Saponins obtained from
Kalopanax soptemlobiun (Thub.) Koidz. Izv. AN SSSR. Ser. khim.
no.8:144?-1452 Ag 164. (MTRA 1?19)
1. Institut khWi prirodnykh soyedineniy AN SSSR.

KOCHETKOV, JI.K.; HOMAN, A.Ya.; SNYATKOVA, V.I.
Triterpene saponins. Roport No-13: Halolysis of' glycosides of the
triterpene series and the synthesis of oleanolic acid glycosides.
Izv. IT SSSR Ser. khim. no.11:2028-2036 N 164 (MIRA 18.-l)
1. Institut khimii prirodnykh soyedineniy Ali SSSR.

KBORLIN, A. Ya.; BOGHKOV, A.F.; KOCIMOV, N.K.
New synthesis of sugar orthoesters. Izv. AN SSSR Ser. khim
no.12,.2214-2216 D 164 (@IIRA 18zl)
1. 'Institut khimii priroftykh goyedineniy AN SM.

KHORLIN, A.Ya.; IVANOVA, V.M.
Triterpene saponins. Report No.Jj,: Saponins from Patrinia inter-
mediate (Patrinia intermedia Roem. et Schult.). Izv. AN SSSR Ser.
kh-4m. no.2:307-313 165. (MLIRA 18:2)
1. Institut khimii prirodnykh soyedineniy All SSSR i Pervyy Moskov-
skiy ordena Lenina maditsinskiy institut.

KHOIRLIN, A.Ya.); CHEM, V.Ya.; KOGHFTKOV, N.K.
Triterpenic saponins. Report IN0.152 Clamatoside C, a triterpenic
oligoside from roots of Clematis manshurica Rupr. Izv. M SSSR.
Ser. khIm. no.5:811-816 165. (MIRA 18:5)
1. Institut khimii prirodnykh soyedineniy AN SSSR.

KOCRETKOV, N.K.-, KHORLIN. A,Ya.,, VASIK(,IvbK.IY, V.Ye., GUDKOVA, I.P.
Trtterpane saponins. Report No.16.- Strucrure of araloside C. Izv. AN
Izv. AN'SS3R, Ser. klilm. no.7s1214-1222 It,5. (MRA 180)
1. Institut khimii prirodnykii soyedineniy AN SSSR.

N.K., DFRE@---c3y,.Ayl@ I
4 ... V . I :@ @uc - I . . , . .
J. I ft . ; - I ..-I
EOCHKOV, A.F.
Syn'tesis -or me-' lyl ester o r (".( w 1. 1., @@ *-;i,% " .', ,.
1@ @, .. ll?r-,@ 165, anou i
..r, AN SSSR. Ser. kb-4m. no.q-,-I@:)?z, I (MIRA l8i9)
I. Ins'Atilt khimii pr.Irodryk'ti -"'

KOCIIFTKOV, N.K.,, @LIO@jlIN4__@Yq.; DOGROV, A,F.
..t,,
New way of synthesizing furanoslides. Synthesis of 3-0-(/,9-D-galactc,
furanosyl)-D-mannitol. Dokl. AN SSSR 161 no.6:1W-1345 An 165.
(M'FA 18:5)
1. Institut prirodnykh soyedineniy AN SSSR. 2. Chlen-korrespandent
AN S,9SR (for Kochetkov).

KWHETKOV, N.K.; KHORLIN, A.Ya.; BCCHKOV, A.F.
Synthesis of disaacharides. Dokl. AN SSSR 162 no.lil0l,-107 My 165.
(14IRA 1835)
1. Inatitut khimii prirodnykh soyedineniy AN SSSR. 2. Chlen-kor-
respondent AN SSSR (for Kochetkov).

h; 1 [^@, P "', -"".; ". yl. B(Ocliycllv@ A.F.; KOCKIJKOV, I'll:-
c)'Y-. 0
, nth@@sis of laminarabione derivritAvcs. 74,,I.,.P@1
166. :@,-j)
1. friotitut khirnii prirodn.0ji soyediri3nly AN
Dfvk:,r lgr",5.

ACC NR. AP7010718 SOURCE CODE,. UR-0062/66/0001012/2207i22O8
ALMHOR: MorlIn,_A.__Ya.._; Snyatlcova,- V. r.; Yovdakov, V. P.; ShIenkova, Yo. K.
ORG: Instituto of tho Chemistry of 1,Latural Compoundsv Academy of Sciences
USSR (Institut Wilmli pr1rodnykh soyedinenly AN SSSR)
TITLE: Syn6esis of 2,3,4,6-tatra-0-acetyl-,6-D-glucopyranosyldibutyl-phosphite
SOURCE: AN SSSR. Izestlya. Serlyn khimichosicaya, no. 12, 1966V 2207-2208
,0:11C TAGS: 6hemical synthesis, pyridine, phosphate ester, nuclear
magnetic resonance
L
;UB CODE: 07'
ABSTRACT: The action of dibutylacetylphosphite as a phosphorylating agent for
carbohydrate-derivatives with a free hemiacetal hydroxyl was investigated using
2.3,4,6-tetra-0-acetyl- @-D-glucopyranose as an example. The condensation pro-
ceeded without inversion of the configuration, forming 2,3,4,6-tetra-0-acetyl-,V_I;_-
glueopyrano*yldibutylphOGphite. The reaction was conducted in absolute benzene
medium, in the presence if absolute pyridine as an acetic acid acceptor. The
structure of the reaction product was proven by element analysis, hydrolysis upon
standing, acid methanolysis to the methylglucoside, and a study of the nuclear
magnetic resonance spectrum. The phosphite could subsequently be oxidized to the
corresponding phosphate... Orig. art. has: I formula "S 10 40 35:17
Card UDC: 542.91 + 547.4R."+ 661.319.1

'-se. ical Chemistry -'Kinetics,, Combustionj, ftplosions) Topo-
WL
chemistry, Catalysis. B-9
Abs Jour: Referat. Zhurnal Nbiwlys,, No 3j, 1958, 7257-
Author : A.A. Balandinp M.B. Taram-Polyak, A.Ye. Agroncsov,
I.M. Khorlina L.S. XmIkova.
Inst :ici@ie;;;%@Mscieoez of Us=.
Title :Catalytic Dehydration.of Alcohols on Anhydrous Magnium Sulfate.
Orig Pub: Dokl. AN SM, L957,,13.4,,Xo 4, 773-776.
Abstract: The dehydration of cyclohexanol, cyclopentanolpjItanol-2
and propanol-2 in the vapor phase at WO to 410 __ at the
volume rate of 0.4 in presence of anhydrous MgSO4 proceeds
practically to the end. The apparent activation energies in
the Z=P fr= 360 to 4000 are trow 14370 to 1593.0 cal per
mole, vhich, in the authors' opinion, is stipulated either
by the same orientation of alcohol molewles with reference
to the catalyst surface) or by that all these reactions are
Card 1/2 .42-

AUTHORS: Zakharkin, L. I., and Khorlina, i. M. 20-3.,W/L6
TITLE: Production of Aldehydes by Reduction of Nitriles With Diisobus
tyaluminium Hydride (Polucheniye alldegidov vosstanovleniyem
nitrilov diizobutilalyuminiygidridom).
PERIODICAM. Doklady-AN SSSRj, 1957, Vol. 116, Nr 3, pp. 422-424 (USSR).
ABSTRACT: other authors have proved earlier that (C2H5)2 AIH and ("C4 Hq) 2*1H
can be used for the reduction of the carbonyl group in the alde-
hydes and ketons up to the corresponding alcohols. The second sub-
stance is also cheaper and more accessible for the organic synthe-
sis than Zi AM V The authors have proved the production referred
to in the title. The reaction takes the following course:
H
P
RE + (14 4H9)2 A.1-H -+ RCH - N&L(C4149 RCHO.
The reduction of butyro-, capro- and benzo-nitriles, and of the
nitriles of the acids of phenylacetic acid-, anise-, tetraphtal.
and others, as well as of 1,1 di-.hlor 5 eyanic-penten-1. was
studied. The results are summarized in table 1. The yield of alde-
Card 113 hydes, especially in the case of aromatic nitriles, are good and

Production of AldehydoB by Reduction of Nitriles With 2o-3-w/46
Diisobutyaluminium f1ydride.
attain 8o to goc/oof the theoretically possible. The reaction cons
cerned can be performed in various solvents (ether, benzol, hepw
tans, ae oe), or without such soL-rents, what involves many advan-
tages. According to the nature of the nitrile, temperatures from
0 to 400 were chosen. In the case of almost equimolar ratios of
both participants in the reaction, nitriles were never reduced
up to the amines. The decomposition of the transition product of
the diisobutylaluminiu4 hydride to the nitrile should be carried
out with great precaution, especially in the case of such readily
changeable aldehydes as phenylacetic acid aldehyde. The transi-
tion product of the (i-C4H9)2 A.IH to capronityl cannot be distillas
ted in I mm-vacuum, without decomposition. Reduced yields of phes
nylacetic aldehyde and of 1,1.dichlorhexan-l-Al-6 can be explained
by the partial compaction ("uplotnentyen) of these aldehydes. This
can be remedied by the adaition of 2,4 - dinitropherVUadrazine,
so that the yield of corresponding 2.4 dinitrophenyldrazon comes
to 8o and 7219/. . The above report is followed by an experimental
part with the conventional data.
Card 2/3 There are 1 table, and 8 references, none of which are Slavic.

50)
AUTHORS: Zakharkin, L. I.,,_,Khorlina, 1. 1M. SOV/62-59-3-27/37
TITLE: Thermal Decomposition of Adducts of Diisobutyl Aluminum
Hydride on Nitriles (Termi6heskoye razlozheniye produktov
prisoyedinaniya diizobutilalyuminiyGidrida k nitrilam)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 3, pp 550-552 (USSR)
ABSTRACT: In the preceding paper (Ref 1) the authors obtained the adducts
of diisobutyl aluminum hydride and the nitriles
RCH=N - Al (i-C 4H9)2' in the present paper the behavior of
these products was investigated when they are heated. It was
found that a gas consisting mainly of isobutylene is separated
if the compounds RCH=N - Al(i-C 4H9)2 are heated to tempera-
tures of from 220-2400. In the hydrolysis of the residue,
howeverv the corresponding amine RCH 2NH2 forms with a yield
of up to 80 % of the theoretically computed value. Thus, in
heating a reduction takes place due to the displacement of
isobutylen- and the formation of new Al-if bonds. in this re-
Card 1/2 duction products of the following linkage systems form:

Thermal Decomposition of Adducts of Diisobutyl SOV/62-59-3-27/37
Aluminum Hydride on Nitriles
I I
N - Al - N - Al - In adducts of diisobutyl aluminum
I I
CH2R UtL2h
hydride and disubstituted amides a reduction at the expense
of the displacement of isobutylene is possible in principal.
It is, however, only unimportant and furthermore, is accompanied
by strong resinification. There are 8 references, 1 of which
is Soviet.
ASSOCIATION: Institut elementoorganicheskikh soyedineniy Akademii nauk SSSR
(Institute of Elemental Organic Compounds of the Academy of
Sciences, USSR)
SUBMITTED: July 16, 1958
Card 2/2

5.361o 77071
sov/62-59-12-15/43
AUTHORS: Zakharkin, L. I. ,
TITLE; Reduction of Substituted Amides to Aldehydes and
Amines With Diisobutylalwainum Hydride
PERIODICALt Izvestiya Akademii nauk SSSR. Otdelenie khimicheskikh
nauk, 1959, Nr 12, pp 21436-2150 (USSR)
ABSTRACT: Dialkylamides of aliphafic acids and amides of aromatic
acids are reduced with diisobutylaluminum hydride. The
yields of aldehydes are given in Table 1. The yields
of amines obtained by reduction of mono- and disubsti-
tuted amides with ('so-C4 H9)2AlH are given in Table 2.
Card 1/5

Reduction of Substituted Amides to 77071
AldehydeB and Amines With Dilsobutylaluminuin SOV/62-59-12-15/43
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61) 254 25i
I-101Y1,0111let 0,1 NrVY@4elrle 4elP ,,fi Ito Ito

Reduction of Substituted AmIdes to 77071
Aldehydes and Amines With Diisobutylalurninum sov/62-59-12-15/4.
Hydride
2
-y-
RA no OF YQP ,
AMIX. ro Or k
mlor (4w - ell.
Nhp rJoItIo
I/at
1 41114[
ffm,

j 1:3
i ; :)
f
p
A
1
qoe*--
je1o i 1: 2,s
7 1
OP "AA101t- *Ip 1 1 : 3
1-3
of 441'xyze &/p 1
1 1'3
4
io AV m r4N /0
(41 1:
U.- IS0AIflVY-dfAIMff1Pr q 1:4
7 5) 1' 20 a) IF,
71) M ILS
pt 120 120
INS 173 175

80 132 a) 132
95 132 132
1
91 8:1 0) W
93 1 165 162-65
95 45 146,
@95 *
d1hydtochlDrIde: 0 -- hydrochloride
-- picrate; b --
Found for Isobornylbenzylamine: 01 1.1.47
Card 3/5

Reduction of Subatituted Amides to 77071
Aldehydes and Amines With Diisobutylaluminum sov/62-59-12-15/43
Hydride
The reduction of d1substituted amides to aldehydes
occurs as follows:
11CON14% + Y-CA1102 AIII - 11 - CH - Nittill
nclio,
OAI V-C4II1)3
The reduction of amides to amines occurs according.to
scheme:
(1)+(i-C4119)2 A Ill - RCII,NII,R,+ (i-C4111)IAIOA I Y-C&II42
There are*5 tables; and 21 references, 1 Soviet,
5 Oermanj 3 French, 5 U.S., 7 U.K. The 5 most recent
U.S. and U.K. references are: V. M. Micovic, M. L.
Mihailovic, J. Org. Chem., 18 1190 (1953 0 D
Johnson$ J. Am. Chem. Soc.., 46., 7543 (1-44 L L
Braude, R. 1J. Jones, J. Chem. Soc., 498 (19 3);
J. D. Roberts, Ch. Green, J. Am. Chem. Soc., 6B, 214
(1946); R. E. Benson, F. L. Cairus, J. Am. Chem. Soc.
Card 4/5 70, 2115 (1948).

Reduction or Subst'ituted Amides to 7TG71
Aldehydes and Amines With Diisobutylaluminum SOV/62-59-12-15/43
Hydride
ASSOCIATION: Institute of Elementoorganic Compounds, Academy of
Sciences USSR (Institut elementoorgariicheskikh
soedineniy, Akademii nauk SSSR)
SUBMITTED: April 18, 1958
Card 5/5

5 (3)
AUTHORS: Samokhvalov, G. I., Zakharkin, L. I.$ SOV/20-126-5-28/69
Davydova, L. P., Khorlina, I. M.
TITLE: A New Synthesis of P-lonolidenacetic Aldehyde (Novyy sintez
P-ionolidenukausnogo alldegida)
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 126, Nr 5, PP 1013 - 1016
(USSR)
ABSTRACT: "9,13 dimethyl-7-(191,5 trimethyl-cyclohezene-5-Yl)-octatriene
8,10,12 al 14; aldehyde C,, @I)" is an intermediate product
of the P-carotene synthea Ref 1). The extension of the car-
bon chain of this compound by one atom and the creation of a
conjugate system of double bonds renders the transition to
stereo-isomeric retinal aldehydes possible, which corresponds
to the vitamin A. The above mentioned chain-extension is based
on the formation of cyanohydrins (Refs 20). For the reduction
of the nitrileaq arising after the dehydration, di-isobutyl-
-aluminum hydride (Ref 4) could be used. The authors describe
a realisation of this method with reference to a simple example;
The synthesis mentioned in the title (Ref 5) of 7-00P5 tri-
Card 1/3 methyl-cyclQhexene-5-Yl)-9-methy1 butene-8-al-10 of P-G 14 al-

A New Synthesis of P-Ionolidenacetic Aldehyde SOV/20-126-5-28/69
dehyde(n)(aae acheme). The interaction between aldehyde C 14
(II) with aicetone-cyanohydrine takes place ui.ler the influence
of a methanol solution of potash at 20-230. The oxy-nitrile
yield (III) amounts to 83-84%. By the reduction of the nitrile-
P-ionolide-acetic-acid (Fig 1) (IV) the substance mentioned in
the title (V) was produced as a stereo-isomeric mixture, and
was isolated. In the crystallization of the semi-carbazones of
the stereo-isomeric-aldehydes from alcohol trans-p-ionolide
acetic aldehyde semi-carbazone was obtained (melting point
195-50-196' W87,8), and a far smaller quantity of the ois-
-isomers (melting Point 173-1740). A far-reaching agreement of
the maxima of the ultra-violet absorption spectra of the car-
bazoneB of the isomeric aldehydes (Fig 2) allows the conclu-
sion that the isomery is caused by a deviation of the position
of the substituenta with regard to the newly formedp sterically
not impeded, double-bond of the carbon atoms 9-10. Out of the
carbazone of the trans-p-ionolide-acetic aldehyde free alde-
hyde was obtained. The infrared spectrum (Fig 3) is character-
istic of substances with a trans-position of the substituents
Card 2/3 at the double bond. Bands in the range of 6.25g belong to the

A Now Dyntheein of P-Xonol.Ldenauallu Al.dehyde 5OT/zO-1z6-5-Z0/65
oscillation@ of@the system of conjugate double bonday whilet
those at 6p oorrespond to the V-oacillation C+-O in the system
with conjugate unsaturated bonds. Prof. N. A. Preobrazhenskiy
showed interest in this investigation. There are 3 figures and
8 references, 2 of which are Soviet.
ASSOCIATION: Vaesoyuznyy nauchno-ionledovatellskiy vitaminnyy institut
(All-Union Scientific Vitamin Reaearch'Institute). Institut
elementoorganicheskikh soyedinaniy Akademii nauk SSSR (Insti-
tute of Elemental Organic Compounds of the Academy of Scienceal
USSR)
PRESENTED: March 11, 1959, by M. I. Kabachnik, Academician
SUBMITTED: March 9, 1959
Card 3/3

AUTHOR13: @,uchzirlchi, L. I.
TITLE: Bvlef' '[111proved 1,11@.Alh-)d of Diethylalumimun
ilydrlde pl-eparl"AL foil
PERIODICAL: Izve3tlya akridemil nauk S@'3,SR. Otdclenly-, Ich1micheskilch
nauk, 1960, Nr I., pg 1112 (US'sfi)
ABSTRAC A 1-Jriple mcLhod of' dl,et 'h.-italum[Wimi h% 'lot-l-de pi-e.,paratLon
fvom c1let.hylaILIMLnum broralde and lithlim hydride is
d 1. 1) c- d
P.rocedure: Add dro wise 15.5 ml (0.14M) ahsolute ether
to the 24 g (0.14m@ diethylalluminWn bi:,wiiide, to the
obtained prodUCt add 1.45 9 0of ground lithium hydride
and mix Por I hour all- 50-60 , @hen add 20 mdl of dry
Card 1/27@ benzene. -Separatc, tlrm: precipit@tlu-t-! Remove the
I

Briof C0jjjqjLjrjiea'Ljojjs. Tj!;j)j-)%`ed Met h0l.0
I.k I _ d
Dietlhyllaluminwii Hydride Preparation
solvent by distilling under vacuLun. Heat (150-600) the
obtained product in vacuum (I. mrii) for 40-60 min to
remove ether, and finally di3till t_-o 0obtain the pure
diet-hylaluminum hydride (92crV -0 7 7 1 A
simple method for prepal,ing bromide
by symmetrization of ethylal!_-t?;1',i-"1- sesquibromide with
bromide is also described:
(Q.113)4M.Br, + 111N,1131. -I I Ir -!.A! 11.r,.r;NjBr.
The reaction takes place on heating (200-2200) the
mixture for 2 hours. The obtained die thylal uminum
bromide (92%) is separated from the reacted mixture
by distillation, bp 84.2-85' (3 mm). There are 5
references, 2 German, 3 Soviet.
ASSOCIATION: Institute of Element-Organic Compounds, Academy of
Sciences USSR (Institut elementoorganicheskileh
ooyedj.neniy Akademii nauk SSSR)
SUBMIT11ED: June 23, 195@9 Cavd 2/2

S&140KHVAWV, G.I.; DAVTDOVA, L.F.; UKHAUIN,
TAKULOVA, L.A.; ZHIKH&UVA, L.T.; PRWBHAZHINSKIY, N.A.
Synthesis studies in the field of polyans compounds. Part 17:
low synthesis of retinal or 9,13-dimethyl-7-(1.1,5-trinothyl-
cyclobexon-5-yl)-7,9,11.13-nonatetraon-15-al. Zhur.ob.khin.
30 no 6tl823-1826 Js 160. (MIRA 13.6)
1. Ysesoyuzrqy nauchno-iseledovatellskiy vitaminnyy, institut.
(Nonatetrasnal) (Olefins)

S/079/60/030/06/03/009
B002/BO16
ATJTHORSs Zakharkin, L. I., Khorlina, 1. M.
TITLEs Symmetrization of Alkyl Aluminum Sesquihalides to Dialkyl
Aluminum Halides-in the Presence of Sodium Halides
PERIODICALs Zhurnal obehohey khimii, 1960, Vol- 30, No. 6, pp. 1926-1929
TEM In the present paper the authors outlined the oonditions for the
above method of synthesis devised by them. The symmetrization of the
alkyl aluminum sesquihalides with the corresponding sodium halides pro-
ceeds according to the formulas 2R 3A-12X3 + nNaX----b-3R2A1X + AlX3nNaX
(X = Cl, Brt I). The investigation was performed on methyl and ethyl
aluminum sesquichloride, ethyl aluminum sesquibromide and ethyl and propyl
aluminum sesquiiodideo The mixture of the above-mentioned initial sub-
stances with the corresponding sodium salt was heated for 2 hours up to
200-2200 under vigorous stirring, Two immiscible liquid layers were
formed. The upper one consisted of pure dialkyl aluminum halidep the lower
one of a complex compound with the sodium salt which crystallized on
Card 1/3

Symmetrization of Alkyl Aluminum Sesquihalides S/079/60/030/06/03/009
to Dialkyl Aluminum Halides in the Presence of B002/.BO16
Sodium Halides
cooling. This phenomenon was observable in all compounds investigated.
The separation of the dialkyl aluminum halide from the sodium halide com-
plex salt was not possible any longer. The influence of the amount of
NaBr used in the reaction upon the degree of symmetrization was investi-
gated on the example of the reaction of ethyl aluminum sesquibromide with
NaBr. Complete symmetrization occurred at a molar ratio of ethyl aluminum
sesquibromide to NaBr - 10-1.2. At a lower ratio a mixture of diethyl
and ethyl aluminum bromide was formed, In-which connection the former 1<
prevailed in proportion to the amount of the initial substances used. A V
more intense symmetrization did not occur any longer even at a higher
excess of NaBr. If the synthesis is made without stirringv a higher
quantity of NaX is necessary for the corresponding degree of symmetrization.
On evaporation in vacuo a mixture of dimethyl aluminum iodide and tri-
methyl aluminum is formed from methyl aluminum asequiiodide and NaI. On
evaporation under atmospheric pressure the total amount symmetrized
to trimothyl aluminum. In tho axperimen+&I pm@wt the syrithesoo a=a a*-
aaribdd in aatall. T66 161lowing compounas were ottaineds diethyl
aluminum bromideg yield 92@, without stirring 85@; dimethyl aluminum
Card 2/3

Symmetrization of Alkyl Aluminum Sesquihalides S/079/60/030/06/03/009
to Dialkyl Aluminum Halides in the Presence of B002/BO16
Sodium Halides
chloride, yield 84%; die thyl aluminum chloride, 85%, without stirring 79%;
diethyl aluminum iodidoo 98%9 without stirring 91%; di-n-propyl aluminum
iodide (twofold distillation), 75%; trimethyl aluminum (twofold-distil-'
lation), 80%. There are I table and 6 roferencess I Soviet, 3 German, and
1 English.
ASSOCIATIONs Institut elemontoorganichookikh soyedinenij Akademii nauk
SSSR (Institute of Elemental-ownic Compounds of the
Academy-of Sciences of the USSR)
SUBMITTEDs July 69 1959
Card 3/3

'0 ID
28277 S/062/61/000/010/014/018
B106/B101
AUTHORS: Zakharkin, L. I., and Khorlina, I. M.
TITLE: Preparation of dialkyl-aluminum. hydrides from dialkyl-
aluminum halides and sodium hydride
PERIODICAL: Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no. 10, 1961, 1694 - 1895
TEXT: The conversion of dialkyl-aluminum. halides into dialkyl-aluminum
hydrides is of great interest, since the latter are good reducing agents.
So far, only the conversion of diethyl-aluminum chloride (Ref. 2:
K. Ziegler, Liebigs Ann. Chem. 589, 91 (1954)) and diethyl-aluminum.
bromide (Ref. 3: L. I. Zakharkin, 1. M. Khorlina, Izv. AN SSSR. Otd.
khim. n. 196o, 142) has been known. The present paper describes the
reduction of dimethyl-aluminum. chloride and dimethyl-aluminum iodide to
dimethyl-aluminum. hydride, of diethyl-aluminum chloride, diethyl-aluminum,
bromide, and diethyl-aluminum iodide to diethyl.-aluminum hydride, of
dipropyl-aluminum chloride and dipropyl-aluminum bromide to dipropyl-
aluminum hydride, and of diisobutyl-aluminuin chloride and diisobutyl-.
Card 1/4

28277S/062 -'61/000/010/014/018
Preparation of dialkyl-aluminum... B1067B101
aluminum bromide to diisobutyl aluminum hydride. The reductions were
carried out with sodium hydride. The reduction of diethyl-aluminum
chloride and sodium hydride to hexane desc@-ibed by Ziegler et al. (Ref.2:
see above) is slow and incomplete. All the dialkyl-aluminum halides
mentioned above are quickly and completely reduced by sodium hydride to
the corresponding dialkyl-aluminum hydrides at 40-600C if aromatics
(benzene, toluene) are used as solvents, and if the reduction takes place
by seeding with the corresponding dialkyl-aluminum hydride. The
corresponding trialkyl aluminum can also be used as a seeding substance.
Dialkyl-aluminum hydride is added to dissolve sodium hydride as the com-
plex NaR2 AIR 29 which then acts as a reducing agent for dialkyl-aluminum
halide. The reductior thus follows the pattern NaH + R Alff---;@NaR AlH
2 2 29
NaR2AIR 2+ R2AIX -,,,.2R2AIR -t NaX. The resulting dialkyl-aluminum hydride
and sodium hydride again form a complex which reduces another portion of
dialkyl-aluminum halide, etc. Yield of hydrides! 75-85@ of the
theoretical value. The experimental results are given in a table. The
authors also reduced ethyl-aluminum sesquichloride and ethyl-aluminum
sesquibromide with sodium hydride in a benzene solution at 500C by seeding
Card 2/4

2 U; 2-7 S106216110001alOI0141018
Preparation of dialkyl-aluminum... B106/B101
with diethyl-aluminum hydride. The reaction takes place smoothlyp with-
out decomposition of its products, It is, however, impossible to obtain
an equimolecular mixture of diethyl-aluminum hydride and ethyl-aluminum
hydride. Usually, a mixture of v7V,,,) of diethyl-aluminum hydride and 30@13
of ethyl-aluminum hydride forms apparently due to disproportionation of
ethyl-aluminum hydride. For the above reductions, 1.5 - 2 g of the
corresponding dialkyl-aluminum hydride or trialkyl aluminum is added to a
suspension of sodium h Ivdride (excess: 3-55') in absolute benzene. After
mixing and heating to ----_(30oC, the corresponding dialkyl -alum! num halide
is added dropwise within 15 20 min; so, the temperature of the reaction
mixture does not exceed 50 600C. After addition of the halide, the
mixture is maintained at 500C for one hour. The sodium-halide deposit
is filtered off in a nitrogen atmosphere, or is centrifuged and washed
with twice or three times the amount of benzene. The latter is distilled
off in a water-jet vacuum at a bath temperature of 40 - 50 0C. The
hydride obtained is distilled in vacuo. [Abstractorla note: Essentially
There are 1 table and 3 referencest 2 Soviet and
complete translation.]
1 non-Soviet.
Card 3/4

, , i "If S/(J()?/f) I/
Preparation of dialkyl-aluminum ... B106/B101
ASSOCIATTON: Institut elementoorganicheskikh soyedineniy A-kademii'nauk
SSSR (Institute of Elemental-organic Compounds of the Academy
of Sciences USSR)
SUBM,ITTED; April 6, 1961
T. K11111. Kim
T
R,AIX A.,. L RAIX .
lilt JP. t-T. Cr. I
, ri P""At-LI. CT.)
W.
(CHlIjAMI 43 (3) (I.C.,@1'J'Alcl 70 91-96 (1)
(Ctfj),A1J 72 To we (n-C,t4,),A1Br 85 -
(C,H.),AICI 86 65-67 (1) (i-QUsAICI 70 114 (t)
(C,Hj.A1Br 82 - (i-Q1.),A1Br 80 To me CA
(qll.).,Nlj 87
Legend to the Table: (1) yield of 0 the corresponding hydride,
(2) boiling point of the hydride, c (p, mm Hg); (3) dto.
Card 4/4

ZAMULKIN, L.I.; KHORLIKA, I.M.
Z-
Reduction of mothyloyclohexanes with diisobutylaluminum hydride. ,
Izv.AN SSSR.Otd,,khimenauk no*6:1144-1145 Js 161. , (MML IA:0
1. Institut elementoorganicheskikh soyedineniy AN SSSR.
(Cyclohexans) (Aluminum hydrides)

ZAKHARKIN, L.I.; KHORLINA, I.M.
Preparation of dialkyl aluminum hydrides from dialkyl aluminum@
halides and sodium hydride. Izv.AN SSSR.Otd.khim.nauk no.10:
1894-1895 0 161. (MIRA 14:10)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.
(Aluminum compounds)

ZAKRARKIN, L.I.; SOROKINA, L.P.;_Y2RLM,,@
Action of triinobuty3AIuminum on cycloboxanons. Zinw.ob.khime
31 no.10:33n-3316 0 161. (MIFA 14:10)
(Alminum) (Cyclahexanone)

8/1079YG2/032/009/002/011
1040/1242
ALMIORS; Zakharkin, L.1, and 11iorlinA, I.M.
Intpraction between diethylaluminum hydride an
TITLEt d the
dlethyl compouryJa of Znj HS# Cdp and Mg
PERIODICAL,. Zhurnal obahchey khimil, v&32, no,9,# 1.962, M3-2785
TEXT.- The reaction of diethylaluminum hydride with the diethyl com-'
pounds of 11g,, Zn, Cd,, and Mg without a solvent was stiWind In an
attempt to prepnre triothylaluminum, Thn reaction of (G21f5)qA1H
rith (GoII,5)@jfg at temperntiire3 between -200C and -i-1000C yi.-I ed
Kip If 0 lIg and It the relative amounts of the different
(C2"15)3 2 2;
producto varM with the experimental condition3 (temperature order
of mlA-inr,, etoa)e, Tho formtion of othano tn(31caten that an inter-
Madiate untitnblo compouY4, -, ethylmorcury hydrido - is formed.whigh",-i 71"
Ither dooomposes yielding ethane 'and free 11g, or rnacts vilth tho
diethylaluminum hydride to -yield mercury hydride whioh.doc.omposou.,
into fred-118 nnd @ 112. -Tho intoraotion. betwoen, the d iothyla-Imilnum
hydr id e - and the d let*1 oo * ounrle 'of - Zn,, Cd,, and Mg at 25-400C
MP
06:rd 1/-.

3/079,/62/032/.009/002/011
1048/1242
Interaction between diethylaluminum...
followed the equation
2(C2H.5)2AlH + N05)08 2024)3" + 11011-
Only in the case of Mg was.the metal hydride separated,, as the hyd-
rides of Cd and Zn are unstable and decompose into the metal and 112"
in all cases, the yield of triethylaluminum exceeded BOX, and the
"yeactions can be used for the synthesla of this oompound.
S I I B TAIT TE DAugus t7*0 1961
CaH 2/2

ZAMARKINP L.I.; GAVRILENKO, V.V.; KHORLINA, I.M.
Effect of sodium hydride on ethyl aluminum dichloride and
dibromide. Izv.AN SSSR.Otd.khim.nauk no.3t438-441 Mr 162.
(MIRA 15:3)
1, Institut alementoorganichaskikh soyedineniy AN SSSR.
(Aluminum compvmWs) (Sodium hydride)

ZAKHARKIn.9 L.I.; KHORLINA, I.M.
Preparation of aldshydes by the reduction of carboxylic
asters with diisobutyl-aluminum hydrida. Izv.AN SSSR.Otd.-
khim.nauk no.3:538 Mr 162. (MIRA 150)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.
(Aldehydes) (Esters) (Aluminum compounds)

ZAKHAPXIN, L.I.; OORLIINA, I.M.
Interaction of diethyl aluminum hydride wJth diethyl compounds of
Zn, Hg, Cd. and Mg. Zhur.ob.khim. 32 no.9:2783-2785 S 162.
(MM 15:9)
(Aluminum compounds) (Orgmometallic compounds)

,-j. -; ZHIGAREVA, 4G.,G.
ZAKHARKIN, L.I.; GAVRILENKOI, V.V.;-PLQRLINA Ilt
Reduction of silicon and gerj6ukim chlorides and alko3dden by
means of sodium'and potassium aluminum hydridex.. Izv. AN SSSR.OtAi.%'
khiwp#auk no*10:1872-1874 0 1,62. WHA 15:10)
lo Inatitut elementoorganichookikhwyedineniy AN SSSR.
(Silicon chloride) (Gerimium chloride)
(Allrali metAl aluminum hydrides)

ZMARKIN., L.I.; KHO.UINA, I.M.
Reduction of carb*lic enters to aldehydes by diisobutyla-
luminum hydride. Izv.kN SSSR.Otd.khim.nauk no.22316-319 F 163.
(MIRA. 1634)
1. Institut elewntoorganicheakikh soydedinaniy AN SSSR.
(Esters) (Aldehydes) (Aluminum compounds)

ZARHARKIN, L.I,; KHORLINA, I.M.
Reduction of some derivatives of acids to aldehydes with sodium
diisobutylaluminum dihydride, Izv. AN SSSR. Ser.khiz. no.3t
465-469 Mr 164. (MIRA 1714)
1. Institut elemantoorginicheakikh soyedinaniy AN SSSR.

ZAMARKIN, L.I.; KHORLINA,
I.M. ,
Reduction of carboxylic acids to aldehydes with diisobutylaluminuirt
hydride. Zhur. ob. khim. 34 no. 3:1029 Mr `64. (MIRA 17:6)

ZAKIIAIU(IN, L@I.; KHORLINA, I.M.
Reduction of @X-oxides by d: i iobutylaluminum hydride and the
mechanism of action on X-OxIdes of simple aluminum hydrides.
Izv. AN SSSR. Ser. khim. no.5s862-870 165. (MIRA 1815)
1. Institiit elementoorganishaskikh soyedinenly AN SSSR.
I

50)
AUTHORSs Nesmeyanov, A. N., Reutov, 0. A., SOV/62-58-11-7/26
Loseva, A. S., Khorlina, M. Ya.

TITLE: -----------
Synthesis of Organo-Meroury Compounds From Hydrazones
(Sintez rtutnoorganicheskikh soyeOineniy iz gidrazonov)
Communication I. Interaction of Hydrazones of Aliphatic
Aldehydes and Ketones With Mercury Acetat- (Soobshcheniye 1.
Vzaimodeystviye gidrazonov alldegidov i ketonov
alifaticheskogo ryada s uksusnokisloy rtutlyu)
PERIODI
CALs rzvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
, 1958, Nr 11, pp 1315-1326 (USSR)
ABUTRAGD Earlijer, hydrazones - a group of easily accessible compounds
have not been used: for the synthesis of organDmetallic
compounds. It is demonstrated in the present paper that the
reaction of hydrazones of acetaldehyde, acetone, methyl-ethyl
ketone, and butyrone with mercury acetate in aqueous methanol
and absolute benzene medium may serve for the production of
some new types of organo-mercury compounds. The reaction
investigated takes place according to that of a "conjugated
compound" under participation of the medium.
Card 1/3 cc *&'-dimercury or oe-,o4! ,d /3'-tetramercury ether form in

Synthesis of Organo-Mercury Compounds From Hydrazones. SOV/62-58-11-7/26
Communication I. Interaction of Hydrazones of Aliphatic
Aldehydes and Ketones With'Mercury Acetate
water,oC-mercury or ot,/3-dimercury alkyl methyl esters in
methanol, and o-c- -mercury or o/-, @ -dimercury alkyl acetates
in absolute benzene. The chemical properties of the obtained
organo-mercury compounds were investigated. It is ilemonstrated
that a) dimercury compounds of the type (IV) - (VI) are
decomposed by concentrated hydrochloric acid when. heated.
In this connection they separate calomel and fcTm the
corresponding carbonyl compounds b) bromination of dimercury
compounds of the type (1Y) - (VI) with a bromine solution
saturated with potassium bromide leads in the cold to the
formation of a corresponding a4-bromoketone at the same time
with a ketone C) monomercury compounds of the type (I) - (III)
are decomposed in th6@dold by concentrated alkali.*On th@s
occasion they separate metallic mercury and form the
corresponding carbonyl compounds. There are 1 table and 10
references'l 2 of which are'Soviet.
AUNGIATIONt Moskovskiy gosuaarstvennyy universitet im. 14.@V.-Lomonosova
Card 2/3 (Moscow''State"Univeraity imeni M.''V.'Lomonosov;)

50) .1 sov/62-59-1-8/38
AUTHORS: Nesmeyanovp A. N., Reutov, 0. A., Loseva, A. S.t
Khorlina, M. Ya.
TITLE: Synthesis of Organo-Mercury Compounds From Hydrazones
(Sintez rtutnoorganicheskikh soyedineniy iz gidrazonov)
Communication 2. Interaction of Hydrazones of the Aldehydes
and Ketones of the Alicyclic and Aromatic Series With
Mercury (II).Acetate (Soobshcheniye 2. Vzaimodeystviye Eidra-
zonov alldegidov i ketonov alitsiklicheskogo i aromatiches-
kogo ryadov s uXsusnokisloy rtutlyu)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 1, pp 50 - 61 (USSR)
ABSTRACT: In th@ present paper the authors have shown that the hydra-
zones of aldehydes and ketones of t 'fie alicyclic and aromatic
series (hydrazones of cyclohexanone, 4-methyl cyclohexanone,
cyclopentanone, camphor, benzophenone and o-nitro-benzalde-
hyde) react with mercury (II) acetate in wator, methanol
and absolute ben,.,,ene and separate nitro.-en, mercury (I)
acetate*and metallic mercury, and form organo-nercury com-
Card 113 pounds. In most cases the reaction under the -action of

- e.
Synthesis of Organo-Mercury Compounds From Hydrazones. SOV/62-59-1-8/38
Communication 2. Interaction of Hydrazonen of the Aldehydes and Ketones
of the Alicyclic and Aromatic Series With IMercury (!I) Acetate
the solvent takes place in the way mentioned in Ref i
The reaction of hydrazones of cyclohexanone and 4-mothyl
cyclohexanone with mercury (!I) acetate in water and in
the presence of catalytic quantities of copper acetate is
very peculiar. As a result of this interaction orSano-
mercury compounds with a double bo-d are formed. Organs-
mercury compounds are listed in the table which were
synthesized by way of hydrazones of the alicyclic and Pxo-
matic series. The structure of the organo-mercury compounds
obtained was confirmed by decompositio"n Witfi concentrated
alkalt-or concentrated hydrochloric acid (Ref 1).*The
hydrazones used in this paper were synthesized according to
methods already described: hydrazone ot cyclohexanane
Ref 2 , of 4-methyl cyclohexanone (Ref 3), of camphor
Ref 4 , of benzophenone (Ref 5) and o-nitro-benzaldehyde
Ref 6@. There are 1 table and 14 referonces, 2 of rhich
@
are Soviet.
Card 2/3

Synthesis of Organo-Mercury Compounds From Hydrazones. 3OV/62-59'-1-8/38
Communication 2. Interaction'of'Hydrazones of the Aldehydeg azid Ketones
of the Alicyclia and Aromatic Series With Mercury (IT) AGCtUte
ASSOCTATION: Moskovskiy gosudarotvennyy universitet i,-,i. M. V. Lomonosova
(Moscow State University imeni N. V. Loi,-ionosov)
SUBMITTED: April 8, 1957
Card 3/3

5 (2; 3)
iDTHORS.- Pre alina, R. Kh., Corresponding Member S011/20-12e.-2-26/59
. Y I
AS USSR, Kost, V. N., Khorlina, M. Ya*q Neemeyanove A# Not
Academio'Lan
TITLE, Add�tion of Hydrogen Dromide to '!,,1,1.2-Tetra,~hloropropeng-.2
and 10 . 2.-Tri chi oropro pane -.2 1W t'llie Prosenca of Benz,:,yl Peroxide
PERIODICAL: Dc-klady Akademii nauk SSST-, ".9r.-9, Vo';'. *128, Nr 2, Pp 316-319 (USM)
ABSTRACT% The withors investigated the above topio in contirujitionof their
cnvn previous papers (Refs 1, 2) as viol! as in cooperation Yrith
L. I. Zakharkin (Ref 'I and A. B. B91yavokiy (
3. @Ref 4) on
rea--rangements of free radicalp. Tha interaction between HBr
and the aubstance mentf-oned firat :bi the title le'4 to a mixture
of products. 12 1, 2.2 -Tetra t;hl ozo-3--bromopzopan a -I I) with a
Yield Of aPPM-Xima@'GIY 30% Warj' t-_c@a the 1-atter in
adaition to other oompounds7'11) (IV) "eae Se-heme). The
existence of (1) and (II) shows -Vqat the addition prooeeds
hera with a repxrangement of the +ype mentioned in references
1-4. The intermediate radioalo exre a.pp=ently eompazlativply
little stabla and decompojo j-nder st3paratirai of a ohiorine
atom. The yield of (1) is thr-refore 1-ow, and (II) - (IV) occur

Card 1/3 al- 't

its CoMpOS, -;Oft,
_CtS. W4tl
in the reaction pro: @j reSpeCt 4

Addition of Hydrogen Bromide to 1,1,1,2-Tetrachlorc- SOV120-128-2-26159
propene-2 and 1,1,2-Trichloropropene-2 in the Presence of Benzoyl Peroxide
constants, and infrared apectnun@ substance I is identical
with the 1,,1,2,2t-tetradhloro-3-bromopropane produced by the
authors according to another scheme (see there), it differs,
however, from the '~pl,lp2-tetrarhloro-3-bromopropane produced
by the ohlorination of the CCI 2-Off--cli2Br With respect to
constants and infrared spectrum. Ethyl cellosolve HC1 is
split off from substance I by treatment with alkaliag which
results in the production of compound III. The latter was
identified as hydrcohloride of the diethyl-amine derivative
CC2.2==CCl---CH2 N(C2H02 -HC1 (Y). As far as constants and
infrared spectrum are cQnoerned5 compound II corresponda to
17'.2Z9L'93-po,-i'tachloropropane. Tric,hlorobromopropene III
together with diethyl-amine and thiourea yields derivatives
which were identified as hydrochloride and picrate respectively.
When reacting with Hgr substance III yielded the trichloroallyl-
merc!ury bromide which war. identical rith that produced by the
u3ual method (11of c;). As tQ its proper"'i.es, tetrachloropropene
IV corresponds to the well-known 1,1,2,3-tetrachloropropene.
Card 2/3 and together with diethyl-amiiie it yields the cnrresponding'
M

Addition of Hydrogen Bromide to 1,1,1,2-Tz'raoh-.1_(xro-- SOV1210-128-2-26159
propene-2 and 1,1.2-Trichloreprt@pene-.2 in ths Pro3qn,,,a of Benzcyl Peroxide
derivative V. The addition of HBr to ',1,2--trichloropropene-2
proceeds Nvithmt rearr angemeat -ander fo-wation of 1 Y-tT1.-
ethl6t6-11--bromopropane keee Sphome). Thia reacti-en course is
apparently ;@onnected with a greatg,-z stability of -@he radical A
prodused as against the radi-.al NOICC-1. 2CH2Br which might be
produced by a rearrangement. Ae to its constantf?@. composition,
and infrared spectrum, subsbwic@s VI, i.e. HOC:,, - CHCl - CH 2Br,
I
which was produoad in the laot-mentioned rear@tior,, J's
identical Yrith the The
-sothiourea derivat:Lve furthoxmo-re obtained as 1:iorate is
iaenti.@@al w.-Lth the ocrresponding derivative- Pynthesized from
thG well-knowa 10 7 2--tri oAloro-.3 --broincipro pane. There are
8 references, 7 of whiah are Soviet.
SUBMITTED; June 5, 11959
Card 3/3

KHORLINA, M. YA.# CAND CHEM 3G,I 0 F A L K Y L
POLYHALIDE RADICALS IN THE PROCESS OF,@HOMOLYTIC ADDITION OF
HYDROGEN BROMIDE TO POLYHALIDE,OLEFINS IN SOLUTION." Moscowt
1961. (MOSCOW ORDER OF LENIN AND ORDER OF LABOR RED BANNER
STATE UNIV IMENI tA. V. LomoNosov). (KL-DV# 11-619 211).
-49-

5/081/62/000/014/009/039
B166[B144
AUTHORS: Nesmeyanov, A. No, Freydlinap Ro Kh., Kost, V. No#
Khorlina2_X._".# Sidorova, To To. Petroval Ro Go,
Vi-i-e-nt#yevV-A- B-0
TITLE: Connection between the structure of polyalkylhalide radicals
and their ability to regroup in solution
PERIODICAL: Referativnyy zhurnalo Khimiya, no. 14, 1962,.178, abstract
14Zh41 (Tr. po khimii i khim. tekhnol. (Cortkiy] 9 no* I,
1961, lo6-115)
TEXT; A review of the authors''work on the homolytic'addition of HBr,
Cci 3P Br, Br 2" C6H5 SH and C6H5CH2SH to olefine XCCI2CY - CH2 (1), where
X - C19 F, H, CH 3 and Y - H, Cl, Br, CH 3* The results of the work show
that the aforesaid reactions proceed according to the general scheme;
I + HBr --+ HCClXCYClCH2Br + CClX a CYCH 2Br + HC01XCYClCH 2Clo This
indicates that the initially formed polyalkylhalide radicals (FR) are
Card 1/2

S/081/62/000/014/009/039
Connection between the structure ... B166/B144
rearranged and then stabilized either by adding an H or by dehalogenation;
moreover the latter leads to the chain of reaction being continued. The
exception is compounds with X - F, which along with rearranged products
also give products which are not rearranged. It was found that the
rearrangement of PR tends towards the formation of more stable radicals.
A table of the relative stability of the PR is drawn up:
6cl2CHUCH 2X > eel 3 tHCH2X (when-X - Br, 01, eel 30 C6 H5);
dcl2Ccl (CH 3)CH2Br > CC1 3d(CH3 )CH2Br; dCl 2CC12CH2Br > eel3 OCICH2Br;
dHClCHClCH 2Br >,CHC1 26HCH 2Br; CHC12dClCH 2Br > dHClCC12CH 2Br;
CH 6Cl,HClCH Br >-CH CC1 6HCH Bri GFC1 6HCH Br f;@:sCFMCHUCH Br;
3 2 3 2 2 2 2 2
CF ClCB@C'CH2 Br G FC 12 6BrCH2 Br. 15 references. [Abstracter's .note:
Go e translation.
Card 2/2

Fi-U:',YDLL'lA, R.Mi.; KOST, VX.; K11101"IIII, M.Ya.) MMILYAHOVp A.N., a%ademik
Rearrangements in the hor-olytic addition of hydi@ogen bromide to
poly(ha:Lo alkenes). Do!d. Ali S@;Sll 137 no.2:3/+1-344 ?4r(161.
ba,-',A 3-4:2)
1. Institut, elcnientoovganic:-@cskillch soyodineniy All SSSR. Chlen-korres-
pendent AN S3SR (for Frey,11iuO.
(HydroGen bro-mide) (Unsatwated compounds)

KHORLINA, M.Ya.; KOST, V.N.
Homolj[tic isomerization of 2-bromo-3. 3-dichloro-l-butene. Dokl.AK
SSSR 137 no*5:1133-1136 Ap 161. (MMA 14:4)
1. Institut elementoorganicheakikh soyedineniy A14 SSSR. Pred-
stavleno akademikom A.N.Nouseyanovya.
(Butene)
T-4
@t w

M;IDLIIIA,, P.H. [Freydlina., P. Kh.]; KOST, V.N.; HORLINA, YI.I. [norlina,, M.Ya.]
Rearrangement of radicals in solutions. Analele chimie 17 no.3:131-
174 J1-S 162,
.0

FREYDLINA, P.Kh.; KOST, VA; KHORLINA, M.Ya..---
Rearrangement of radicals in solution. Usp-khim. 31 no.l:
3-38 Ja 162. (MA 15:3)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.
(Radicals (Chemistry))

M Ya C, -I
re, otions. of a dichloro."Iny." r;,, our.. D"V. 7S, R . S,:@ r
(HIRA 18:10)
1. institut soyadlntniv Ali -S"ISR.

K H OR LNA
M.fa.-- .','REYDLI14A P. Kh.
Ef f ec of reaction cond! tir-ns on the rearrangement of radicals
-1 solution. Izv, AN SSSR. Ser. khim. no.8-.11483-1485 165.
(MIRA 18:9)
U
1. Instil t, elementoorgan-IcheBk'kh sovedinenly AN SSSR,

SOURCE: AIT SSSR,
1788-1792
1
Izvesti-yao Seriya khimichoskaya, no. 10j, 1965,
TOPIC TAGS: chemical reaction, halogenated organic compound., mixed
halogenated organic compound, organic sulfur compound
ABSTRACT: The radical addition of various reagents to compounds
containing an u.nsymetrical dic.hlorovinyl group was investigated. The
addition of HBr to lil0-trichloropropene-l (A), to 1,1-dichloro-3-
lbromopropene-1 (B) and 1,145-trichloropentene-1, butylmorcapti
f
or thiophenol to A was accomplished at low temperatureo f(:35 to 37 C)
s
under ultraviolet illumination, Hydrobromination of B ave lsl-dichloi
a
2
.,3-dibromopropane. Reaction of A with the mercaptan or thiophenol
yielded the sulfides C
HC12-CH(SR)CHnCls where R is butyl or phenyl,
Homolytie addition of HBrand mereaptans to the dichlorovinyl group
resulted in the formation of,compounds containing a terminal
Card 112
0,7 9;@:
ACC NRI AP5027687 /SOURCE CODE: UR 062/65/000/010/1788/1792
AUTHOR: Frevdlina, R, Kh.; lihorlina - M. LLost, V.@ nN.' (Deceased)
ORG: Institute of Organo wpound"p- a d a My qt S
wtallic Go _�cienges S SR
(Institut elementoorganicheskikh soyedineniy Akademii nauk SSSft')
q 4. K
TITLE: Homol-ytic reactions of the dichlorovinyligroup

L 8153-66
ACC NRs AP5027687
dichloromethyl groupo These radical addition reactions were hindered
by introduction of substituents in the beta-position to the double
bond, Orig, art. has: 3 tables and 5 equations.
SUB CODE: OC/ SUBM DATE: 17jul63/ ORIG REF: 001/ OTH REF: 000
nw
Card 2/2

P
Ir
AUTHORS: Timofey-eva, T. V., Khormushko, S. P. 48-1-3/2o
TITLE;: Screens for the Recording of Slow Neutrons (Ekrany dlya recistratsii
medlennykh neytronov).
PLI.IODICAL: Izvestiya jLN SSSR Seriya Fizicheskaya, L958, Vol. 22, Yr 1,
pp. 14 - 2o (USSR).
ABSTRACT: It was the purpose of the present work to develop a scintillator with
an efficiency as high as po5sible in the counting of the thermal neu2
trons in the presence of a powerful T-background. For this purpose
the reaction (n, a) with boron was used. Of the three methods for the
production of a scintillator for recording slow neutrons on the basis,
of zinc sulfide with an addition of boron: the method of common pane=
tration-bardening, the method of the mechanical mixture and the men
thod of sintering the first-mentioned method gave the best results.
It is shown that the efficiency of neutron-counting increases with
an increase in the thickness of layer and the grain size of the scin-
tillator up to the optimum, which corresponds to a thickness of layer
of 2-3 grains. It i shwon that the introduction of the scintillator
into a varnish diminishes the efficiency of neutron-counting by 2-3
-fold. With screens in the shape of a hollow bbay (sphere, cylinder)
card 1/2 which are internally covered with a scii'illator-layer it is F.@0551ble

Screens for the Rece-rding of Slow Netitrons. h 8-1-312.,)
to count 8-lo times as many neutrons as with a flat covering. The
scintillator is hydroscopic and does therefore not require any humi-
dity protection. Two types of screens are recomended; a flat one of
a scintillator-powder and a cylindrical one which is covered by a
scintillator-layer on varnish. The efficiency in the counting of the
neutrons with a cylindrical screen is three times as high as with a
flat one. The coefficient of neutron-counting in the case of a flat
screen is evaluated with some p---cents (r-.,501o) which is close to
the theoretically possible value.
There are 7 figures, and 9 references, I of which is Slavic.
AVAILABLE: Library of Congress.
1. Chemistry 2. Boron-AppUcation
Card 21/2

8 5768
3/048/59/023/011/002/012
43 Boig/Bo6o
AUTHORS: Timofeyeva, T. V., Khormushko, S. P.
TITLE: New Data on a Slow Neutron Detector
PERIODICAL: Izvestiya Akademii nauk 89SR. Seriya fizicheskaya, 1959,
Vol. 23, No. 11, pp. 1283-1285
TEXT: In recent years, the authors developed a slow neutron detector con-
sisting of a luminous material (avetosostav) based on zinc sulfide with
boric acid impurities. The neutron count is done by the (n,a) reaction in
B10; the scintillatiorBcaused by the a-particles were recorded with a
photomultiplier, on the photocathode of which the detector was placed. The
latter was equipped with plane and cylindrical luminous bodies. The present
paper is devoted to the investigation of the dependence of slow neutron
counts on the boric acid content and on the increase of the count coeffi-
cient for neutrons due to the use of boric acid concentrated with B10. An
increase in the B10 content gives rise to an increase in the neutron ab-
sorption, which leads to an attenuation of the neutron flux in the lower
layers of the luminous material, and to the occurrence of the self-shield-
Card 1/2

AIJTHORSt Golahkay, G. I , S/020/60/131/04/059/073
Tovetkov, 0. S. B011/BO02

TITLEs Comparison Between Neutron Radiation in the Atmosphere and the
Earth's Crust
PERIODICkLi Doklady kkadenii, nauk SSSR, 1960, Vol 131, Nr 4, pp 933-935 (USSR)
ABSTRACTi The authors give a survey of investigations of neutron radiation
since 1937. Since they now dispose of better apparatus than they
did then, the authors attempt to compare the intensity of cosmic
neutrons at sea level with the neutrons in the rocks of the
Leningrad underground. For measuring the neutron flux, they
designed and constructed a scintillation counter consisting of a
disk-shaped slow neutron detector (Ref 16), 153.5 ma in diaseterg
and a photoelectron multiplier of the type FEU-2B (150 am in
diameter). The pulses coming from the multiplier were fed into a
circuit containing electron tubes which intensify and nalyse
simultaneously and were recorded by a conversion devic: (Fig 1).
The elements of the block diagram illustrated were developed mainly
on the basis of the system of a standard neutron counter of the
type SCh-3. The measurements were carried out
in the city of
(1
Zelenogorsk, (2) in the harbor of Zelenogorsk (3 in a station
:
j
Card 1/2 of the Leningrad underground in a depth of 70 m. The counting rate

Comparison Between Neutron Radiatio? in the S/020/60/131/04/059/073
Atmosphire and the Earth's Crust BOII/BO02
was measured with and without cadmium. Table 1 gives the results.
Hence# the intensity of cosmic neutrons measured by the author on
the surface of the sea in similar to the value de ermined by
N. Kaplan and H. Yagoda (Ref 19) (230 neutrons/om ). The authors
found the neutron intensity above the sea to be stronger than over
the mainland. This divergence is probably due to a plexiglase light
pipe which the authors attached to the detector. The intensity of
neutron radiation of the rooks in probably lower than 5@ of the
intensity of cosmic neutron radiation on the sea surface. This in
in agreenent with K. Mather's measurements (Ref 12) and differs
largely from those by J. Sugster (Ref 10) and others (Refs 14, 15).
N. M. Lyatkovskaya, A. G. Grazmakov, V. S. Zhadin are mentioned.
There are 1 table and 19 references, 8 of which are Soviet.
ASSOCIATIONs Radiyevyy institut im. V. G. Khlopina Akademii nauk SSSR (RAdinn
Institute imeni V. 0. Xhlopin nf the Aa&damy nf AnjoncPa IT-qRR)
PRESENTEDs September 23, 1959, by A. A. Grinberg, Academician
SUBVITTEDs September 18, 1959
Card 2/2

22171
8/046/61/025/004/020/048
B104/B201
09'- @' cu 9
AUTHORS: Grebenskiy, B. S., Timofeyeva,.T...V., Khormuehko, S. P.,
and Tsvetkov, 0. S.
TITLE: Increase of the effioienoy of a scintillation detector for
slow neutrons
PERIODICAL; Izvestiya Akademii nauk SSSR. Seriya fizicheskaya, v. 25,
no. 4, 1961, 500-503
TEXT: The present paper has been read at the 9th Conference on Luminescence
(Crystal Phosphors), Kiyev, June 20-25, 196o. The authors examined a
dispersion deteotor for slow neutrons on the basis of ZnS-Ag and H BO
10 3 3
using both natural B and such enriched with B . The detectors were
prepared by Joint sintering of ZnS-Ag with H 3BO,, and also, for a compari-
eon, by a method described in the literature (Ref. 2: Sun K., Malmberg P.,
Pesjak F., Phys. Rev., 2@, 600 (1954); Nuoleonics, 14, No- 7. 46 (1956);
Ref. 3': Vorisek M., Czechoel. J. Phys., 'I, No. 6, 757 (1957))- In the
first method, a sinter of B 203 was ground with ZnS-Ag and sorted in frao-
Card 1/6

22172
S/048/61/025/004/021/048
.2.2- 9 B104/B201
AUTHORS, Gorshkov, G. V., Grebenskiy, B. S., Khormushko, S. P., and
Tsvetkov, 0. S.
TITLE: Dispersion detector for fast neutrons
PERIODICAL: Izvestiya Akademii nauk SSSR. Beriya fizicheskaya, v. 25,
no. 4, 1961, 504-505
TEXT: The present paper has been read at the 9-th Conference on Luminescence
(Crystal Phosphors), Kiyev, June 20-25, 1960. The detector considered here
is made of grains of a ZnS-Ag scintillator, which are uniformly distributed
in a medium containing hydrogen. The sc-ittering of neutrons in the deteo-
tor leads to the formation of recoil protons which, when hitting a
scintillator, result in a scintillation shich is recorded by a photo-
multiplier. The deteotore considered here were prepared by polymerization
of styrene and methyl methaorylate with ZnS-Ag. The resulting detectors
were up to 300 mm in diameter and had the shape of hollow spheres,
cylinders, hemispheres, etc. The grain size of the scintillator was
12-25 P, the afterglow had a duration of about 10-4 seconds, the intensity
Card 1/3