SCIENTIFIC ABSTRACT KAZANSKIY, A.M. - KAZANSKIY, B.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000721310020-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 13, 2000
• Sequence Number: 20
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

I
I ~ - i

KAZAIISKIYFA.M., professor, doktor tekhnicheskikh nauk
About thermal capacity of peat and an academic dissertation.
Torf.prom.32 no.4:151-24 '55. (MLRA 8:10)
1. Hoskovskiy torfyomoy institut.
(aalorimetry) (Peat)

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KAZANSKIY. A.N. (Kookys.)
Stability limits 4)f oxyacetylene velding flames. Izv.AN
SSSR. Otd.
tekh.nauk no.11:139-140 N 155. (HLRA 9t2)
1,Voaso"nyy nauchno-isaledovatel'skly institut
avtogenney obra-
betki metallov.
(Gas welding and cutting)

AID P - 508
Subject USSR/Engineering
Card 1/2 Pub. 107a - 10/12
Authors Bykov,, V. V., Eng., and A. N. Kazanskiy, Eng.
Title New equipment for processing metals by.flame
Periodical Svar. proizv., 10, 30-31, 0 1956
Abstract The authors briefly describe several newly designed
gas-
welding and gas-cutting equipment, such as: the GS-53,
OSM-53 and GAO-55 torches, the FP-53, RAP-55 and RZP-55
cutters, and the RGS-53, ROM-53, RAT-55, RAO-55 and
RAZ-55 insert cutters. They provide some technical
characteristics of the cutters and torches. Five 'tables,
1 graph and 4 photos (showing numerous pieces of equipment
and parts).

AUTHOR:
Kazanskiy,,A. N. (Moscow). 24-4-28/34
TITLE:
On the velocity
head and static pressure in the oXv-acety-.

lene welding flamd.(O
skorostnykh naporakh i statiiaheskom

davlenii.v
atsetileno-kislorodnom svarochnom plameni.).
PERIODICAL:
"Izv. Ak.
Nauk, Otd. Tekb:, Nauk"-(Bulletin*of the Ac. Sc.,

Te0bnIC&L.Sciencas bection7_17957, No.4,pp.161-164 (USSR).
ABSTRACT:
For recording tb~ static pressure in the'zone'of t1m
fla-me

core a c6 er*jr6be with an active canal diameter of 0.3 mm

was usedtlig.l; the full flow pressure,was recorded by

copper
probes with canal diameters of 0'.3 and 6.7 nm

respectively, as
shown in Figs. 2 and 3. One variant of

the recording arrangement is
shown in Fig.4~. It was found

that in the zone of the non-ignited
gas mixture in the

flame core excessive static pressure exists;
during igni-

tion of the gas mixture the excess static pressure
drops

sharply and changes into a clearly pronounced vacuiun and,

following that, the pressure gradually increases to the

atmospheric
pressuret remaining constant at all the other

sections. It is
assumed that this rarefication represents
Card 1/21
one of the
stages of'thd reaction of the combustion of

acetylene at which two
molecules or two radicals combine

forming a single particle; the
reduction in the number of
AUTHOR: Kazanskiy, A. N. (Moscow).
24.5-23/25
TITLE: On the thermal regime of the edge of the nozzle mouthpiece
of an acetylene-oxygen welding torch. (0 teplovom
rezhime kromki sopla mundsb*uka atsetileno-kislorodnoy
avarochnoy gorelki).
PERIODICAL:"Izvestiya Akademii Nauk,Otdeleni7e Tekbnicheskikh
Nauk",
(Bulletin of the Ac.Sc., Technical Sciences Section)
195?, No-5, pp-139-140 (U.S.S.R.)
ABSTRACT: In studying the temperature regime of the nozzle of an
acetylene-oxygen burner rc-53, the temperature of the
mouthpiece was measured during the process of burning of the
flame by means of a thermocouple consisting of a
constantan wire whiCh was hard-soldered to the copper mouth-
piece. The results are graphed in Fig.2, P.139. In the case
of stable burning of the gas mixture emanating from the
nozzle the heat is trpn mitted from the flame to the nozzle;
if the edge of the nozzle is cooled by gases flowing through
it to a temperature lower than that of the ambient medium
the flame will tear off. The highest quantity of heat will
Cexdl/l be transmitted to the nozzle mouthpiece in the case of
mixtures containing about 40% acetylene.
There are 2 figures and 1 Slavic reference.
SUBMITTED: February 13, 1957.
AVAILABLE-

135-8-6/19
TITLEt Investigation of the Stability of the Oxyacetylene Torch
Flame.
(Iseledovaniye uoto chivosti plameni svarochnoy ateetileno-
kislorodnoy gore] I
The article containe 7 diagrams, two sketches of torch nozzles
and 9 bibliographic references, 5 of which are Russian.
ASSOCIATIONs IIVNIIAvtogen"
PRESENTED BYt
SUBMITTEDo
AVAILABLEi At the Library of Congress.
Card 2/2
25(l) PHJE I BOOK EXF~UITATION SOV/2281
Vseooyuznyy nauchno-issledovatell skiy inatitut avtogennoy obra-
botki metallov
Ki8lorodnaya rezka I avarka (oxygen cutting and Welding Moscow,
Mashgiz, 1959. 268 p. (Series: Its: Trudy, VYP. fl Errata
slip inserted. 4,800 copies printed.
Ed.: A.N. Shashkov, CandIdELte of Technical Sciencei, Ed. of
Publishing House: G.N. Soboleva; Tech. Ed.: V.D. Ellkindj
Managing Ed. for Literature on Heavy Machine Buildingi S. Ya.
Golovin, Engineer.
PURPOSE: This collection.of articles is Intended for engineers,
technicians, scientists, designers, and students of vtuzes.
The book may be used for improving operational methods of
oxygen and gas metalworking. '
COVERAGE: This book contains articles on theoretical
investigations
of oxygen cutting and welding and problems related to the gas
Card l/ 7

Oxygen Cutting and Welding SOV/2281
acetylene ratio and employs the SV-100S Welding rod,
develop-
ed by VNII Avtogen.
Strizhovskiyo 1.1.,,and D,X. Tesmenitskiy [Ungineer),
Using Fine-grained Calcium Carbide in a Mixture With
Fuel-
Oil 256
Kozlovsklyl A.L. (Candidate of Technical Sclencep). New
Mat-
erials for Metallizing 260
The author describes a method of metallizing, claimed to
be new, in which metal powder embedded in a plastic
filament
Is used instead of the usual metal wire or powder.
Because
of the high degree of dispersion of the metal, coatings
produced by filament spraying have a fine-grained
structure
and are more uniform than those produced by the wire or
powder methods.
Kozlovski , A.L., I.A. Nemkovskiy [Engineer] and N.r.
Filimonova
L
[EngineerT. Developing Production Methods for
Manufacturing
Polyamide Powder for Metallizing 263
Card 6/7

KAZANSKIY, AIN,, kand.tekhn.nauk
Regulators of now design*. Svareproizve no*6:42 Je 161.
(MIM 14:6)
1. Vaesoyuznyy nauchno-issledovatel'aki7 institut avtogennoy
obrabotki metal2ov.
(Gas welding and cutting-Equipment and supplies)

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XAZANSKIT. A. S. (Inglueer)
5An Investigation of the Process of Crushing Large Lumps of
Anthracite With a Single
Implement." Can& Teeh Sci. All-Union Soi-Ree Coal Inst, 29
Doc 54. (VM, 20 Doc 54)
Survey of Scientific and Technical Dissertations Defended at
USSR Higher Nducational
Institutions (12)
SO: SUN No. 556, 24 Jun 53
~_A

BERON, A.I.., kand. tekhn. nauk; POZIN, Te.Z.j,
kand. tekhn. !Ia,-k,,
KAZAVSKrY A S kand. tekhn. nauk; SFAVRINA, R.F.,
rod.
[Improving coal breaking methods and the
actuating mecha-
nisma of mining machinery to better the
fractional composi.-
tion of coal output; short scientific report)
Sovershon-
stvovanie metodov razrusheniia liglia I
lspoinitellrWkh or-
ganov vyemochnykh mash-in s tselliu uluchsheniia
fraktsion--
nogo sostava uglia; kratkid. naucbx*ri otchat.
Mos"ra,
1962. 50 P. (M1IRA 18:4)
1. Moscow. Institut gornogo dela Jin.
A.A.Skochinskogo.
Laboratoriya mekhanich(iskikh sposoboy
razrusbeniya gornykh
porod.

KAZANSKIY,A.S., inzhener
Brief survey of tests made on large coRl crushing plAners.
Nauch.
rab. VUGI no.11:177-2o4 54. (MLRA 8:11)
(Coal preparation)

TEKHKISHMAV, Azat Vagramoriabi kamd. tekbn. nauk;
TSMARSKlYp Igort
Alekoandrovich, jnzh.;.,,KAZMSKlYj Apatolly S=geyevl*,p
kand. tekhn.
nauk; SEMOV9 Radlidir Mikbaylovichy kand, tekhn. na*
KORABIZV,
AnatQUY Aleksandrovicb, kand. tekhn. naukj SEMOV, I.B.,
otv. red.;
ABARMCHUX, F.I.j red. ied-vaj ILINSKATAg Me, tekhn, red,
[mining maohineryl Gormia'nekhanika. Moskva, Goa.
nauchno-tekhxi.
izd-vo lit-ry po gorucmu deliz-0*1961' 291 (MMA 14:6)
(cclal mining ma;hinej

BERON, A.Lp kand.tekhn.nauk; -KAZANSKIY A S.t
kand.tekhn.nauk
Research on stresses and deformation ifi rock during
straight cutting.
Trudy Inst. gor. del% 5:57-63 160. (MMA 14-5)
(Boring)
-7

BEROV, Abs. Isaakovich, kand. tekhn. nauk; KAZA14SM
_Ai~Ataliy-
Sergeyevich,, kand. teikhn.nauk; LtTWV-,-Toris
Mikhaylorvichp
sotr..-, POZIN, Yevgeniy Zallmanovich,
kand.takhn.nauk; SHOROKHOVA, A.V.p red. izd-va;
PROZOROVSK&YA,,
V.L.p tekhn. red.
[Cutting of coal] Revanie uglia. 14oskval Goa ort
khizdat,
1962* 438 P?Coal mining machinery) 15:7)

KAZANSKIYt A.S.
Determination of contact stresses under the puneh.
Fiz.-makh.-
svoia.,dav.i razr.gor,.porod no.ls236-242 162. (MIRA
16:3)
(Coal-TeBting)

-KAZANSKIY, A.S.; ROMANENKO, Ye.S.
Effect of an open slit on the size of contact stresses
durinC: the
impression of a punch, Fiz* mekh, svoise,dave i razr, goro
irod.
no.2:26-29 '63* r1aft 17:1)

K-47ANSM, A. V.
Voprosy razmeshcheni~a t s~etsialiuatsii
sotsialisticlieskoEo sellskogo khozyaystva
~Problems of Alloc~tion and :)necialiwitiori In. ;Malist
Lr.~,icultvre), coliectim.
Sellkhozgiz, 33 -.s.
of articles, compiled by AIT.
The np.-posium describes prollums of the allocation of
socialist agriculture
according to individual oblasts and rayons of the UISSR;
prol-Imms of the co-*:;nati~%ri
of br-mches of agriculture within varicusly specialized
kolkhozes.
The book is intended for agrictiltural specialists and
scientific workers.
50: U-6V29 16 '0v 1954

MANSKIT, A.Y.; TOKARI, V.:K., red.; OREMMINA, V.I.0
takhn.red.
[Decimal system of classification of industrial
drawings and
obJects] Detaimallaoia obaslichennais sistema
klaosifikHtsii
cherteshel I ob"ektov proisvodstva,* lzd.2. MORkva,
Gos.izd-vo
obor.prorashl.. 1959. 75 P. (MIRA 13:2)
(Classification, Decimal)

K-RUGER, M.Ya., inzh.; PANOV, V.A., kand. teklm.
nauk; KULAGIIII, V.V.,
kand. tekhn. nauk; FOGAREV, G.V., kand. tekhn.
nauk; KP.UGM,,
Ya.M.p inzh.; LEVIEZONI, A.M., inzh.; Prinirral
uchastiye
KALINKEVICH, V.141., inzh.; KAZANSKIY, A.V., kand.
tekhn. nauk,
retsonzent; DMITRUN, A.A.j ir~zh.; SIM011,0VSKIY,
N.&I red.
izd-va; MITARCHUK, G.A., red.izd-va; SHCHFUNINA,
L.V., teklm.
red.
(Handbook for the designer of optical instruments]
Spravoch
nik konstruktora optiko-rokhanicheskikh priborov.
rLty) M.U.
L
Kruger i dr. Moskva, Masligiz, 1963. 803 p. (MIRA
16:12)
(Optical instruments)

numny, B.
Saientific Ressarolk Institute 'of the loo'noulas
of'Constructim,
VOR. 01ODn, M007t17>475 JI '380 (MM 1198)
(Building)

VINOGRADUT, Andrey Hikolalvvich; KAZAHMIT. B., red.;
TEMINA. T.,
takhn.red*
(Planning the lowering of housing construction
costs] Plani.-
rovanie mAsheniia sebastoimosti rabot v zhilishchnom
stroitoll-
stva. Moskva. Goefinisdat, 1959. 103 P. (MIRA 13:3)
(Construction industry--Costs)

K&ZI.NSKIY, B.
-~I-d-allsctlon of articles on construction economics
("3conomlc
effectiveness of' capital Investments and now
tocbnology lit
constriiction "R#rviewed by B.Kazanskii). Vop.ekon.
no.11:
141-144 N 159. (MIRA 12:12)
(Construction industry)

KAZANSKIIp B. A.
B, A. Kazanskii, A. V. Kiperina, and 0. A. Zemskaya -
"Concerning the oxidation of
B-mathyl cyclohexanol. The synthesis of
1-mathyl-3-propyleyelopentane." (p. 1212)
SO: Journal of General Che-mis&rv., (Zhurnal Obshchei
Khimii), 1920, Vol. 20, No. 7.

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At "It In &VIS!
o o q 1~ 0 o 4 0 0 0 0 0 0 0 0 0 0 0 0 go 9 0 0 0 0 0
0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 a 9 a 0 a 0 0
o o
AND Ps"11111% lhtlll

*00*6*0000000000 sees, 0 0
to do kv spoof U&J"or
A-A-L-A-A A*- A. L t__j A_ a '4 9 S a
- Il -L-1-M A m a -nit
New 117111114leve by sea" of
1R_ A- X_4pouall. I*sp,&k
' "I'm - J. A W 41'.41434)- A
"Yelic Mye"M cyclic un3mtd, 0 rings moch as
furev, 9(c.. Wtutd. N rings ftwh as pyjrj4mmjd gmltk_
00 a esides. ate.. with tf, ak"Wil. Anlaydrues. krumles. We,
"es' qqbu-"- "Llff"-ft"slilliffol OnItildriles, r4rtin~
end slerly"ir buku" in
so
ItrUctured 0( The Prodorte fminrl art disrumni, as u4 u a, .00
dM10"Im" V1 ftmpjex unutd. c4mllids. s-kWing ujlmljj~ goo
at f Comflib. MoCh as irth-flent, i*Vnipylethylene, etc. CI..
traW WA vwiotn Sylvo (It 1W1fnVr'iQlt ChArtwictit][6- ml
um4ed, cyclic and MVCVC[ic d"R avilemA err "-mwrml~
Tht tevim h tam) chielly tui tile wook -4 Pwh, Ahl~r -J
roe
11, RAthItlAllit
go 0
0e
See
a 0 .. 1~
ties
ago
too
Ali, 4.111INATY01 CtASUPICATIOn Ives
i -T
to M
A 0 0 0 "Iowa[ lofts[gi Man all -
0 to 0 0 4 f
000 ~0# 0 0 0 0
0 0 0 9 0 0 0 is 0 0 0 0 0 oi/_
a 004)60000

VOM

X Am sot ca

tiesoi t

o 9,011MUMIS At u A N a a SO a a 29 1) N a
Is 9 a of V

a) Q $1 me a fl,

cc cc a A I

A

q..P

POMISUS Age

Aliot "b"nks of c7dores4ass"
waSs loydro.

-0

garbles 11
4
*
M

ad wa N.

3
zrh1wia Z
4
.,

comp. row. ", am

it

a. A, 4. $. A
i
. IW70(193

4).-Z. p"Rim"Y obtained

h
h
I

*0 a

d (1
ev
m

n t
e
) by
d P

an
T
prot Aia

00

UwAry. McCaig. tK,.a ;1-2.b
d I',
d 3

Units In a attram t
W peow

00

aver thar"al wayam W11A ps (30%) at a role 01 44

.00
00 a

&tVVMhk, 14 105-1 vt a hydrueselms, boo W-3%
%kr

Thm cinctow we very rkw
*V-' I JroV. d144 0.
l

00.3

it.
tAA 0,00 f9t I-Owthripatow. 91colls,
l
l b

CIO 0
00

st. v
ePtiones,
sit t-UW. t6 03M, go" a m
,
1
1
?
b

Co

1
91 -0% OV lim, d#q ImW
. IWAls,
*# 121
.
OV-11 1.412.10 d,44 0.77W. Favs a mill. h. J(klt 21 1. vV
i
k
I
k
hi
i

to
00

c
t an Irwt
ustion gave a m
at.
n wkL
b the
jA012, w
i1o.lawn produminated. bha siV-1 JAGJ3,

a0
0
go

das 0.7117. The alkyky tag" Were synthetic

PlAwiticts lAttiAd.
(too cyck3l1butaftow. L. W. It.

Coe

90

tee 0

41.

nee

4
A

CL.StwiC&IO"

be

be

v

il A I
'It

A

u A a- R3 At

1

A A t a ?w ti A, 9. A# is

WA

tt
, 102 g
JI, fit 9
goo

g
0, to 0 0 0 0 & 0 o so 6 a 41 0 a

of 0 0

00 09

0 is 0 so go go * 0
**#)Go* 0

,, T
-KASANSMJt B. A. -- --- -- - -- ---- - - - - - -
"Sur la nature des homologues du cyclohexane qui composent la
fraction, octconaphteniquell
du benzine de Saourakhanill. KasanskiJ, B. A. at Markossawa, M. 1.
(p. 884),
SO: Journal of General ChemistrX (Zhurnal Obshchei Khimii) 1936,
Vol. 6, No. 6

KALNSKY, B. A.
"Synthese de quelouss homoloques mono3ubstitues du
cyclopentane a chaine laterale
bifurgues". Kagansky, B. A., Plats, A. F. et Gnatenko, K.
M. (P. 1593)
SO: Journal of General Chemistry (Zhurnal Obshchei Xhimii)
1936, Vol. 6, No.. 11

loss 1w w
lot:
a Is v Is a, v 41 41 0 N 4
A V--j -W I At. A
00 1- r
00
00
A
668WIMrbinol.
VI Ink 4 1398
13
am owt or
so Oil Ad
its*. :-vu-
bi .1
V~. ,
Lad.
R. T.
11,11 V- s- i, T -
o 19Is a to is 04 first* 1(tTtl Its! "D a I f
.0 0 0 a 0 IV 0 0 0 fol 0 6 0 0 0 0 0 0 0 a * 0 0 a 0 0 0 f 0 0
9 00
a 0 :10 0 See Segeli* *see a 0 0 *1* 0 a o 0 0 0 0 0 0 a * 0 1b
0 g : :
:.0O
I-so
.06
-00
so
-00
.00
go*
=00
Ce 0
goo
Coo
300
We 10
clot
age
tsob

*,, Mm-I've-,
T
W
Jk-A-
to
00
00
00
00000#040ifoos
-t'-* 0
ILL
1-00
a go

00

AroaAU&RUm of cor4ain homologuos 01 cyclo.

-00

0
:

fMW iu YrORMS of &tWmed
Pa*Lin~OU-M'I&M]3011.RMKAZAX*L~I A. F. LIATI (J.

-00
0

13 ).-Th6following
9
V"UdA; AN ObW=d
b
i
h

0 0

00

pam
ng We
ydrombons
over PI-C A 31")
l

*0

It"d ti-
C&H4MrXt froza x-butykylopentam; pz
kim from

0

00
u

y
Bus - PhEt md O.X)-WW fmm x.octme; M.
*
Ci4k

0
'of
0o

elh
from diimmyl. IL T.

00
too
goo
'Sip
too
wit
00
vi~ 10
It w 411 It a it W K a it it 40 41
0
, ~Ip

010000000060$06001100o 0 U 0 0 0-4 -0--~w is v 0 v W'w V-0
90000000046000611604: 400400840100*0*41io,
I I I, # 1 0 r a 0 a it Q U w v in a 111 a a p it v Is bo a a v
a 41 Q is a 4ze
A~111' t-A k r . . . . I "-.P- 11" 1 0 a ? I J* Ki:1, I , 1.--X
-I.., I It - .-A-1-TWO10
it, r ila, ".I.$ lip
:o if
HydropmUm of airmutic bydromboat by sneans of
Ca-M.-
Bali
mLAW.N. V. smistm1% A.
4.,Ij. pil. w s s. "dill. Vr. tArtm
t4r h4 ItunisknAil at-rd .4 It.
C4 t 4NII, CaIN11s). AtN11.1, I I IL
thits Cjl. gim cycluhtienc mind im," 0
0* J1 ficAndiew. 1.3-CyclohejAWlenegivabtgbyicidpoicyclo =00
.1rijiml which is not further bydrugenated under simiLat p
So coo
Mmhtsom. ThIeme slovs tatshydralolue1w. Aw C'Jj'
so giv" telt-alin. A( higher tirtups.. Cis(NI1,1, twmfftc, tin
=68
go. to .111r. 111"rtly UAISS its fmcirlwy "Witills KI4.1111irk
coo
001 00
Off coo
00
00' #f a to, %1. A &11AttUftKA% LIVIIAIWPO
00
.4. 0.. so
4-vaL 'I, tot
I "n an I
I :
1001144 0 60 1~ 0 o is g 1 0 0
00 04, 0 0 0 0 6~6*

1 9 ke it 14 q- N, is .6 It

A

a -I !k -L

#A IS JX P1

"4.1.1

00

of
aramtk hylimurbms by'rumans of a
%forsts
d 14
sh
y
M
J
Vif
F
A
K

r
l
dii
I
0:

ne
u
.
.
Cs-
aram
.
.
an
.
,

-
e
i
g
1
0

,
cfw.. C . W. S: 9. It.) 8, 612ARI MX); Cf. C. A. 32.
le .

1 04
x%?

t'
a "t',dificatkict (A thi: We
a

cart 1.4-dit

d rt."I i, IMM"11 in reart at to
t__
d
Y

-V

CA prrgxl. by paning dr

'
'P,*
r*
%*snd
dr,,
rualt4l
The h
%
n
d

iliffXultly hi
i0robochlor
00 j

.
.
.
y
g
p
at nitrowhImide ciffirs. formed vith EtN(h and 1110

A-5-trumet
41411

at Ity* terni". 1he skidn. t4 It V",oduc" bydiambuns

I- and
04v

,lith I dmiNct-md stlhr C atom finlird with the qubstitti.

pving cyclu
0 J~

ent. C.11, rS%V IN$% CVCj0hC19rVe. h. K-14% X%r

ectewl fir pri

4M."CO1. Pht-A g3ve 1-tthvi-l-cyckibext-ne, his, .
t34-

1.45417, nitropc4chloricle. M. 101-2*.

21

IS 0 0

-1byNI-cychibelene. JN4 127-11'. d!* O.W6.

n1trolocht(widt. m. 117-IR'. P-Xy"e

thv1,1~vv1,ihr%rnr. t-- 127-
11'. it'.* UJ401.
~_Odo
iltr-w~hkwide, ni. ht,"tylene i,

0 0
rogmalvil. giving a mixt., b. 141) CW. 11%
.
r, m. 13,21 3*
tdmnnpn.)t CINT?%ponds to

1-1-cyrinhexene. Tetmltn Saw a milt. of

tin. 1.4-Cyriahexachme smik 2 It almn..

-%enc. The hviinTrnatian
i% pichohly cf-

minary iwwn"izs1kmu
iew.

e
hill 111anc
Z

nyorwarlicin i ni punitration an4i menuumium im vur
hord",gruaini priiittaci ue bring inve%fitaud. m.Xylene
Zee
we 0
0 :4
a**
1, too
u 9 &1 00-1 r
I V 11 In 1 0 9
a of a 1w 4 4 14
0 0 0 0 0 0 0 0 0 0 0 0 do 0 0 0 0 0 0 do a 0 0 0 9 a 0 0 0 411 0
0 0 0 0 Ip 0 0 0 0
0 0 4111109,411 0 0 0 0;0 a 0 0 10 * o 9 0

11 Ij u Is I~ If it a a id a J* v a it 9 R J) Id p Is v ft 0

a N
IL 1-1 Aso a v 4
4

(jj

i C*Wytk trusistoraution of
2-snothylbicytIol,12.11-

, A.
!--bepwas and 2-nethylbitydoll.2.11heptane. 11
00 a'-
~
P) rrD"a. J. Gest, Chrom, ~ 1'. S, S.
Razan""

O
cf . C. A~ 29. #I=)'. %%'bcn :1.
1
h,t
Mt
t,
1) was b
j
54e
s
t
1
11
1
00
-
-
i
i
1
.
.
)A
(
W
me
&h
uslat UNN
ith 11t
ls
h
00
arc
m w
c
e p
Ax- luct was not a heterountotis mfitt, 'cf. ZcInt,kil,
7

,25), bit% -methy0j, w1...
nxkil and Plate, C, A. 27, 6
*

Anil
:.11hopkove (11) prrvkmtJy obtained frian I wnh )1

P. 16 nt
dehydrurt-failtil fit fit,-
7
=
o0
In N at 3W* but ghVI Mitur high.
h.

Wing prWucts which pulwa the catalyst. 11 with Pt
0*
1
0
H
d
li
l
d
l

-1
rav.
excess
at
9
chamou
an
un
erturs a cyc
c v

age wilb the forrustion of monocyclic pentanc% anti paraf-

fins. The cotalysate commans trams of artmuslic hvdio-

tartions
(so-sylent). This Indicates the clra%*Sr Q the

C--C-- bond
forming The Ifirthylene brWxv. C. to.
00

I Z -
it
u a W so
It If Or 14 a 41 Is 0 tun "KNO" I
0 0 41 0 0,40 0 0 9 0 0 0 0 1) 0 0 0 0 a * 0 0 0 0 0 0 9 0
0 0 *,G 0 r 0 a 0 to 0 0 0 0 0 0 0 0 0 @19 0 0 0
i-------
- 0
-40
-00
-00
-0 0
0
::S 0
46
A 0
too
00
a 4
0 0 0 0 0 0 0 a 6 0 0 0 0
* 0 0 4 0 a 0 0 0 0 a *,,A

4106--14-404-6 0 $14-0-0 41 -0-0-0 -2 $it q 0 0 1 0 0 04 0 0 0
41111 0
0 0 a 0 0 0 0 0 0 1111111, 9 -0-0-0 O-Off.- _V
,O_ 9-t-0-9-0-419 1111, 0 0 0 0 0
'a It s, Is I, It -ro
$1 1 it to If W I " 0
I I ? V-1 1'. 11 is A 0 11
Al I-l"fal
-It
A
C
v. A44111111am of by&"" to u .amsibe IsydroLarboas by tae
10 #use of lititism. sutiledum and
lAdim of Annit" am
buism. W. R. A. Katauskil sod N. P. Glu%hrwv.
aasm sti.ma. xas...%ir. (how.
PM, 10111-4; cf. C. A. 33, IZTW.-- Nits vvnplfxr4 -4 Li.
Its and Sr well prepd,.aZd then derouilml. in the pirience
4 CA trod PhMe. I cales it wall shown that It wai
00 al- added to the arornal". The Nils m-milkx III 1A Yk-111"I
00 tetrahrdroeoluene and =,!; c%villheal,11, Thl,
.;; "'Implex reduced Italy 4% of the Phkte but it vwW"I coo
00 12,190 of letrahydrubmseme; the miuction itt,ximls of coo
4111111111- txm It CA and PhMe wbmmi a weak dirne tract ilm. The
an compirz COVT plot ocally no mfuctiem with loWt. t.1 0 0
tip with C4H~ it ykided 32Z,% cyr~-hmx_. It. Z. K.
00
00
iwb-0_491 tip
~00
~
00 '100
.90
Iles
Of
00 es a
lie t AIN tLA -11ALLUrfICAL LITIF111001 CLASHFICATION
- U 1 It a i a bt 0 0
p fill 11044 Its it A 9 fitt it ORWA fim
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0
44 0 0 0 0 *see*** 0
0 q 0 030 0 0 600000 000 0 0 0 * 0 to 00 6 * 0 111 # 0 0 0 # 0 *
0 * 0 0.

0 0
J k L _a
00
00
t,
00
0 J*
00
a

4l see 6
0 a a 0 0 4 (1 0 0

a JL_1_1 U J- _t_J_J J

Pee-Cams m
.10#111,11 ..Lit

4 .4 0

__

to

naum" ammumpanytog me "Gum"

of dialkWilsk III bass by
mean o(

"khm4mmeldl- B.A. it vid N F. Glushnev.

.04
$all. "ad. id.
U.N. S. S., Oulim Sci. M41h. "W., Sir.

chimm. ION. 1OW71(in
English. 1W2). d. C. A. 33.

-0
12794~-Varicas dkkfuw mW arvattatic
bydruembum

0
anderga lamberizatWo upon redo"ka, with Ca(.Nlf.)#.

It
I -bu a 1
uction of 2.3-di 13 Lgt&dKw, cyclopenta-
:kO-,ethYIeUrIwnjrR;!o=1;;rIWv11 W 2A-di1nr111v1-
1"
l
I
il

-00

0
.
wopro'. I
sod m
vi
4

'Mot 0.. ..0
4twola,ne, .$hlh pf.,1.0

mr, Itsil, iteduct", W Itiv dulki'l 44
111%,110 W, d

wWuct which is believed (o be 2-ethyleyclolmetse. flic
;

0
results indlemot that Cs(Nifs)o reduces 1.3-dicnes. hydro-
bl
h
Ad
h
i
d
I
hi
h i
i
M

0
e c
m
s
a
n a
ou
e
w
c
carbom bay
ng in t
e
mt&ptcd with the double lKmds In the benrette rins,

0
M hyd...t. Mving double bonds in 1,3- arAl 1,4-

positions even
though they contain nonconjucAled diette

- carTied out at () 1.
Allisonjerixatiunsuct

so
D. Z. Kamich

coo
2
b,
A$J1,JtA NITALLWIMIC&L 4,11fRAIUNI CL&SINK4110b,
t1 %boos) .0 Nt all
--- r--j
It ; ~& a, I
0 (y It 9, of K . it a K Ct et 4
;
619 000, & ,
0 0 0 0 a * * 00 0 0 :J: : :10
0 0 0 0 0 ; 0 0 * 0 0 0 & 0 0 0 0 0 !*
bo 0
too
An I to two %*,IN 1113
ta
of 9 0 0 0
* 0 0 0 o * o 0 0 41 0 0 0 to gel

'T I- lip 9 0 0 g0#
TOM-,
03 x st a m 1, 11
I I Ij P 1 -97 ----I cc I it il, b t f -two,
1,1 L 41
&* A; .. -
so
00
00 Kai by* -don of dipbenyUlafteme. W A -00
00 C =nd G.T. Tatevos"n. J. GC". CAW. (U. S.
3:R.) A. hydn4matiom o(dipherlyf -* 0
Of g fulverm (1) was rqmstcd I: the Ixf-mv of IN end I'd -4100
'Aick Its ak AcOlf Htro rid cyckillexatmmm to the ,~Id
00 a cl.C.A.i&,4M-l. .00
so a adda. at the Itt mal. H proceeds slowly with only gradual
.00
Ind disappearance of the fulvene trd M.,
V 18 a minplex mist., canto. chiedv un. '0 0
so all presence of the dibrJet. d"iv. VP44 lkt ~00
detd. I abilimitm 2 matilit, it quite rrmdtly. Sivitig dopkrqW.
h. I IW-I*. sit. 1121 2.5'~ It is
00 oxidlized with JINOi to PhrCO. The addn. of the 3rd
smA. H proceeds very slowly to give eydopexty1diphemyl. ~.o 0
so meAstairprrviouslydescribed. Thesucressivemin.ofthe
3 doublit hands piticteds more distinctly with I'd in &k-. 0
Its rate and the Compa. of the catalyntes vary with the
:: is*
solvents and catalysts used in the reaction. C. it.
00
0 Ise
00
00 1 A WALLOWCAL LITCE&Tlyfft CL&11lFKATtC- A 0
00 9
j0 0'
11111141111 it T -.7-.,i I
-1 '", 0 -0 V ---V -I '5-A V-yj W, I j )d 0 a j. 5 41 1 3
U 1, 4 X .11 it a it U ft it is - n 00 0 0 of
" sy
0 0 o o 0 6 0 0 0 40 0 0 0 o o 0 0 0 V 0 0 0 0 4 1 0 0 0 0 0 0 4
0 Is so 6 0 0 0 0 0 0 0 0 0 4 0 0 4 0 60 0 0 0 0 0 0 00 0
0 00 0 0 4 0 6 0 41 000

0 Ill 0 0 0 0 C q 4
I I a a It 11 It m it 4 1? 10 Qfn nigh J11121AM 1; it v u H 131
% ly if lC -1
I L x JA 19 kt IV tt I I 1 1.
00 -A' 1. . I I
4 Ilk, -~f

Valaloc triminalamatlem of dimeric 1.3 -c) cioltexadjents

If. A.
Kastanstkill and L. G. Voll'l-m. J. t ex. Chrm.
to if

-R TA I;
MIX), 4~1' ('L .1 2~.
;-. - M . . 14W, Ill ,

,
eviou%ly it waft shown that

oclerse. thAmah Itels."Cilig It.
it"'.

Shich Im Sitam, 1, 4-4121vt% 11111

ClIhIr and formotkin fit
CS11, 81111 NINIt ~ It i"I'M 1.

Of
t

vilseti-tvil that dityWratsdirive + aml it, dikldr.~ drvjr.
*
I

till. dfri". of 1,1 AM, 1
1111-1 Sll ill.
09

C. A. 26. fs(F.W. %mil-I o1-, III, omp fit a
qsoalai mmoi~ I
00

forrissition of COG. 1 0. lit.fo-allis "11.1
D.n.11"
06 j

:Z. 12411) failiefl Io react ,of Im-mig if io Cc I;
-t I.I.iol-
to

u.-ft rhartiall of this'. At ;Ns# A" I its CO P.
sto,l If

00

iratu slinflarly to give III, Ill WHIIIIIII 1111011IFlPff I-V

flaming is In COl ovi-v i fir vatalym at 3to 15'. A13111 50-

-

i1 giv" a few crymalls with a C1,11, odor un(I tiocittaill tit,

We
72

1). In all the caws. the reacliou R.4, millaill"I &6m1 1131,

It sort no un-.ittl. coinlit1q. C114~. 1114114
to
11
-00
a*
;7 coo
Wes
t'4111 So
.2. too., 11-1- too
Im,
a OW 0 -W '-a'- I
u u so uia Its Its mt, it it g 11 9 V1 U ft It 111 "0 A I Nit
*'0 0 0 0 0 0 0 0 41 0 000 0 0 0 a 0 6 0 a 00 0 6 9 0 0 6 * v 0
0 0
p 0 0 0 0'a o 0 0 0 0 0 0 41 0 0 0 1111 0 0 046 0 0 4 0 0 0 0 0
* 0 O's 0 0 0 0 0

* * 4 * 0 0 0 00 4 9 a 0 0 sig a a -6- 0-4 ~60 'w'" ip v v iv v

*
000 000-0 0-0 0 9 0 0-0 of* 0 0 0 0 0 0 * * 0 * 0 4 4 * 0 a

1 6 )
s $ 4 0 it .1 U 11 12 a a B-11 p It N #1
I
41 v 0 a O'c 0

v I
LI A I I A4 a CL 10 U 4 f j I

14

Wi
Z
d H
1
r
0
O
W
.00

s.
ama-
.
.
.'s
.
AM
mu
4
f
-00

m6
ilwLK). Cf.
11. 1481-60a Hall" . 1

tkmjw Imtkno 1b. 134-411 a( the Baku and
Surakhan
-00

5*01ise Wete &hYdiragensted to The littectice of
cwt-m

mupmSmated with Pt (afm with NO and A160* imprrs-

point with
N1 esislots at XM 10% The pn%furts wrtr
-of

,
go
itithomirdiind The oulf-mic AM, tAilmin"it wrtr 11-6011-

.
OUT
WC.1fi.
ass

I.J-. 14- WW A, A

coo

coo

so

Of

too

s v, .0

a ff it Mi a I lik

00 0o0
o 0 41 00f 000 0 0 00 0 o 0 0 0 9 0 0 0
0
0
40

0 of 0 00 Go 0 0 FiAw AW 0 a 9
0 0 # 0 0 6 0 0 0 0 0 0 0 0 0 0 0 9 a 4 0 0 4 0
ft
U Is I# Is u It IT a a if Ai is is yo as )I v um b b Ir Is 0
'st
AU a F V JL--JL 1. L-AA 0 M W U 46 4 d
Pq "0161 i

Tbo catalytic tmadonsidtWe of some hom*Wp of

lasisr. D. A.
Kjuma%kil arul .4. R. N-tgunLo,
Yd
00

=.ElWM. *.* 4147 ALI(Ijklilp. in jjjr
ISO t

premev" W Ni
drinwited on A1,A), Alul In a 11 serratu,

bm
=1AIW lmk* 41smn even Ott LIM* it) Im"I 4
00

2
awl. W lim-Wilux timuWs. At blibeT
0 10

*tl* skint trAlftsce.
.044itting of the sing with
O
;;~h
l
I
jU
N

00

t4 4-
so mvins.
vrt
(QUIS
ykmiarse a
4 (w

Its a N Ottraus (..111%

4

of atumatir hydrmarimm. fit a It eliesin,
'
0
U
It. 11WI-14
. sit 1,4101, (1,.* 11.73;10, 161.

to
it. CAkd 48 38 At R f"41MI,
48.34. 0 fiWilled. S6-me

IV Ltatwil CIvCI CrIO, at 4.%1' In a N
-trrmn, it xi%, 11)

00

00

it
I a It WITALL(IRGICAL OTEPAILWO CLASSIFICA"I"
Is 01 It Is f%
0 0 0 0, 5, 04 i i i 0" 0") 0" 0, 0" 000 0 0 0 0.09
0 0 0 * 0 0 ;q 0 000 00 00 6 so 0 0 0 0 0 0 eje 0_0
-00
00
-00
00
-00
-641
.00
~66
ZOO
ze 0
Ire
CW 0 1 w I#
0 0 0 0 0 0 9 0 * 0 6 0
0 0 0 00410 see * 0

a a 6 0 0 0 9 10
lsr:j, M14
:0 a a a oo 0 0 0 6 0 0 o
0 of it to It Is to IF If a PMAJOVAPO." V M 11 ft 11 a III V 01
Q 1% od a re
A OF 4 4 1-7 V V. --l- 1- L. - AA 0 OL UD it I
ist 4p4? j%V pool*%
Ik
--as
11110 CAWYM OdiltaiWll Of PUARM IlYdfOCarbOus ever
lo
Kapapolill and A. P 14,114'.
i
so C "Hillids. wt 164"M liver 111411itift4l V ail 31M'10% lirwIll
04 Im"19 I.P.; C414. V-19webyllwaa1w sirro A V-1, :-oo
3-mt4h tanetivo3l% ulandil. tit HiPh ando. anti
A
as A j~-zykw11nqtwtky"ww jiv" 4% on-avierve. wW 4. -to
MetbYlIxtione titers 3.6% of aromatic- Vol"Jills., CNWI. -a a
Misting in part of PfPh and I livid, the -00
slealef t1w. lirm-binS of chains suil the hight-r the jmIl
UL. the roister the amt. of aromatit. ix"111%lo. xo*
When dilsoamyt It Passed over N1 delvosittil %-in Alp, it zoo
tenitis. fwug Item a(")* the amt. of an-Analic twil0s.
townied rides tram 2.11 to 2A,
V. 1-1. 161. 1xim-ter re 0
00 j
00 00
00
:!Sao
0.1 9
00 it
.00
i!:00
rife IF
2 tro 0
S.,%LA
Sao". 0`611"
-jV ",a
C4 6 0 V
u it A .0 or
10 1 0 11 ; 0* 04 11 o' 10, g' 0 0
i
0 0 0 0 V?V 0 0 0 0 0 0 6 0 0 0 0 0 0 0 0 0 0 C it 0 0 &
OT1408 0 0 0 0 0'0 0 0 0 : 0 0 to : 000 0 00060 0 14 0 00 0 0 0
0 0 0 9 Is 0 0 0,

as ILI a0 to 0
ALJL r A
A

pol

R

041 t

I

I

!I

the tamidws MW 9

DO)t OM 06twu

b awthed P"
kiwk Vdatity

tb4'11 Wwsted Is tl
Of

of artlysove of C
Goa

nowly 09W to
ilm
t1w, (we"Intim

lym (109M Cal./a

0

04

Of
rewdou em be mauurcd
The now appamt
bMf COW
C. A. 30, 67130). C. H.
041ALLUMIOCIL L"94MUll CIAMICATOW

A 0

2,

WOO

moo

too

woo

coo

moo

moo

moo

00

moo

cog

woo
u VT 41 9 a 4 3
ireloolt:016,66" *,, I We
0000

I I v it U 1)4 14 it 10 W to p 1 61 U k, r
A IL . %.' I "Ij V WO tot 4 .0 , , 4 , t : .
it a I AA A k
0 #.r "Pool
*a -OCK111,11 11 "1
OF~ -
tagu"Cop tif the Butildhasts as tho TrIticity of Catalytic 00
bytirtgoustIO11,0f WWII tfisubstlititt'd "OvIe"'if 'a ths
,Platinum. 11. A. Kastiviviliff and M T. Tal- -00
of
O.Gtv. Car". (U.S. S. R.) Iw4wtMol.
2.2-dipbessyl-M) "ttiCrnyletlivirne I'M yn"
by knowu methods, The ndiviritual ethvlenr% and
milts at i with n, in and iv were hvdnltnxltd
the pirrvirticir at lit h1ack as rfulin troll'. lov
00 .,a in
ht '3eshniltictrOped InanvartirT rowf (r. t 33. r-Nivi.
0 ne graphic multi,show that I bt~kqt-j tiv.1tc'n.-Won
of 11110bl'tituted ethylevirs dertra" with inttra-ing i- -A .00
aryl sub%liturfits in the inal. The drop In vrinritY ii, rlar-
=09
0 tk-ulazly Amp Ob The InIrnduclion of a 2nA arvl lulmitit
rnt. I he hydrogenation of mixed hvhnmrl~ont w-werdit
simfiltaprousjy. flowev", beirame ii! the diffe"fit eh'r-
actor of substiturnis and the ". siting diflerrnre in thr
0 hydrost-nation velocity of the Individual Wrnearlinn% --ind
tht ditribution of If 1wearen the comrwmenii .1 ynivI4..
fit teilction showii some w1rcilrfir, which i-"wc nimr
"citiounird with greater nit. of Ish sufnillaicni% in lbr 2nJ 121;
irovAtionent. Chit.. IlIn"r
see
IF bee
LITIM&7!09 CLAWPICATiops
00
Bill- lov.113 4il (PIT 44% ......
- -----------
U a AT to v
00111#11,4011 get fig RU n 19 a "a it to I W 0 to 0 A, 0 1 '-1W
IF"
0 q;q 0 0 0 0 0 0 0 0 0 0~
T4*0000-6*6600* too 069e0096 *;**go 004006600000000i

Ip Ab* to "N"
PRO plus &W "Opsoltes wool
oom
Ogg
0:
t
At A SAUSIX10-
r-ITT, 1
00-S L of
b YeDut
000 ;I=
so a Wsoda
r C!K' -Br
JI,
A11110-Itik OnALLMMAL t"MIMIS
u
0 6 1, OR, OR. To xw a T'wv
w 10 NJ;
00009410604104*:09*000 '0000
1440000,000,000*9,00000-00 4000
wbew 14.3211,
&still EM'e" Ali
N t 3
411 v i
000000606,06094009
.04
504
Sol
Vol
Vol
904
Vol
U04
sea
U04
Ire a

0 0 o 0 0 0 0 0 0 6 0 0 0 0 0 9 0 0 0
I A I Is It U is 14 u is IF is N a U a AS a A A 11VIIII1151011 v
h 6) t Q 43 a are
a.0 r -2 R_9_1 111,11 #A U. Cc 0 It I
ii"_Jifess of tke "boollifteeles as th 411W# of "Wytk
:so 19, 1 1
heyehnipastiass el e"Istime triatibefibet'l 0:eaft to the
enclit of palladium black. II.A.-Kox4p aleol U I
Ra A
0 C! 4 11110) ;~W III In fit 4 1 -erw1hyl-2.2 dulin I.
And tripbeitylethyletsee (IY? and rquirnal. mivt-. 4 1
with Us M &rA IV ravis mprated to tbr peromervirv tet 1`414mick
Ill
invited (4 111 WA " jeer"Ismisly IjW.I W. .4. 34. 27vrl
*)Ili I'd IlIvIreaws tharply Willi sulmlit"the" .-I I alml .1 Ph
:100 Im allipliatit- radii-eds in contrast to the traction "$Ill
Ill.
and t%mvidembly IteeTerams, With 3 Ph aithatiturms. liv.
4111111 d binary Mitts. Imiocirrill Ork-cliverlY 'Ailh 4
66 onskirtalely grftttT rater %,I mildn. of th# Ist It riwel.
I,* the
dr%tvaller ceesorAments than it- I t4
00 3 0141itmialive testie in the hyditleltation of I V,1111 AIM
00 witl3out the adders. of leite-DuPh. llh.CI[Ht and llh,Cll- 00
99 CH,Pb Allowed luillycly that the retardation of I
hyemst. at ion is caused by I"Keeming af the catalyst hir
00 the atianatic hydrocarbons formcd in the mactiore. The,
fail- of froardation ImTedseret with Iticreasills net. %-( 4111
40
ThN eff"l was folilict et-reffinmi 400
In I'w "m),
by the frid"latioll 'el 4-then'.114. in Ow 440
litchernOr CA C4116. Chat. 111411c
so*
T no 0
AIN-ILA ACTAitURGICAL LIIIPIATKI CLAIWOCATIC1111 92-
!use
a 1 6 lid a a a 1 11 a ft of a "0 too
1, 0 if 4 4 it a is of go "ID
0 0 9 g
0 fit 0 0 0 0 4110 0 0 f
100069 66 go 0 0 0 0of o 00 0 a 0 0 0 0 Wo 0 00 00 0 0 0 0 0, 0
0 0 0 0 0 0 0

KAZA.IISFIY4B8A8 600
1. KAZANSFTY, B. A., unwvosym, G. T.
2. USSR (600)
"The Catalytic Fixation of Hydrogen in Corpounds Having
Several Tiouble Bonds -
IT. The Eydrogenation of rdmethylfulvene", Zhur, Obshch.
Khim., 9, No. 24, 1933
Inst. of Organic Chem. of the Acad. of Sel. USSR, Div. of
Acad. N. D. Zelinskiy.
Received 9 July 1939.
9. IM Report U-1626, :11 Jan 1952

lo
0 0 0
..'.O*p 4*00
v 0 a a M a
-t-f- - -1 * 0 4L'tols
y1: a 'n
9--A,
F
w
I'D
iv. .11511ATIVIL"vII I v
P
tvi
0
off olul W"-U- 44 p4UOA) Jm
OOR 'wil ojvWjl vullusil III -Plb &%a 13nptw 44,
1144-1-mw~s Iv!II1Pd III AU131n"j -pk*M3 -paqu 8
it. ,III I it! ow WO IN allm =vp I qsntuqt
9
pzzltqlmd mm 110,
.1
awusjpAr4 lvs)L3),, -usup Aq 1g) Pull op del t, I Sto 00
00-: floc I - "41 1-mit-l"I It 7ulpl3!A -.,I. I I, qojjlq,,.!N
00
3u-1111.14.4111 pr, 'NA11,1143kilpAll Aq (I I 'Pdaid Immim
'jolvui I's I i Will l I (P.I& Iff W W 'o 'i 1 0 0
0 41- 4~,~ '%I 'it t" Avla V 0
A v lp"ftn"-,V -V" I"upp pj
V-- I""d to 44M
CA- is. r
r 1 i 1 0 )1 m 35 W-W-T ---J1 it
x a oltrilor Rota all III q ft
o 00 9
0

W
f

1 4 9 4 foo

LA -A A-4

.,
o. to
ntivelvelit As
" At
taltUie" I
A_L_JL A I Vg` At 1. T $A U M A A A A
I? .-p lkl, "Islas

I. As bre

I L,

go

rf~xltllf .14, .6.1191 11 ..tit

09
6

00

00
0 o a

0

0 p
1110411

!
Lj kan Somaithe octane sumber of asocilmas due to the
ura"Facmum of b7dramoulle" 0t the c 111113141
late I areasit is t" p"ame" It byd"Va.
thd S'. R. Sw Igo
I ho. oxi In* (16,11tool fruill (110111V K0,441nor one Igral"I

III, je,"'M(w
aloof 1hr tratilling tustrital %a. I,
/..Is I'Lli "not as"lli .1110 11"Al. It'll,
I I.-ina .4,10410"1 othk 1, an ..
look- It.. It.. 1.1i'l 11141'.0,11 "A. "%".. to
qs%tl lot 3~Al :kki.t tht, lot, .4 N Ow..
Ill. to ruptulto tinp with I,mii%4tkm lot pAral.
fillic lydrwartmat. The ppAuct 1). 35-1:U' and has 52
Octoth no.

-09

_409

it* 9
ago

ee

A MAIALL

M AL UtISAIM CLASUPKATMAI
Igo. do..n.

age
boo
Vol -0 1111114011"p go, am
I A
U to AT 10 uli A, 0, " "f-.r,-T-K"w--v"-~4f1r
N 0 0 9 0 0 0 0 0
0 0 0 * 0 41 0 0 0 0 0

littliwtl int
_11-11-TIABA-All ado a 9 11fol 9 a 41
Kw a I u an*,
to 9 go 09 vote 0 go****
j 9 a 0 0 Ib 0 0 o 0 is 0 e q * 0 0 o1

KAZANSKII,_ Doris-Aleksandrov12hf
Kazanskii, Boris Aleksandra;rIch, Ml- ed. Synthetic liquid-fuel from
carbon oxide and hydroxide 5 predisloviem 14, D. Zelins%ogo. Moskva,
GO3.
nauchno-tekhn. izdat. khIm. lit., 194'0 359

000
beef
fed
004
-00
OOW
-
OOT ".0 61i i i i i i i,i a, i if _i it-it' Ii ii i
*oOOOOO Is 00000010000160900!0
01"W84141
A pw be. of,
JAI Raft,
AU &WAY of,
or
N
=710 . I but do i
6 ve
10 we t
co~ar* us J. J. IL
10010.0 Ojos a !0
0*0
slow ""Inv
All 18110 PRIVIVIAG I* F-
dm
000009*00*00**00*0
goo
U's 0
go
see
Wes,
GOO
fee
me*
&0
boom

0 0 a a 0 4 ~gis a gosgo see
- 0 _~V# -0 -0 - AVOFO 14 0 o 0 a i
f. 4 L I Jig -A$-1- a i, a P. P 1. S b W A f 1 -4 to 9V U

00 a
Caeuct cydirsom of pstrafisk hrdr9Wbp99~ N. D.

A.,
10
0

Karan%lifl, A. L. I.Ovinan. 1. It. L-ak.
'

- R --*Tgirn1 o. CompC trad. acad. o, i.
A *F. mair itiml ~;
00
1'. R. X. N. 27. 443-Al 10401 (in Ftiglith)
.-The Present

M~t k a le"t on the exiensi,xi of earlier studies
and on
0

) and pritains
other rl,wly retat"! work (C. A. 13. 9212
tirii of the workin
eriod of
f th
d
bl
it

e
ura
eris o
P
to the pro
1

Z"

11w) 0011-
Y"1
talysts. Synthrin- ga"ine fractions (
CM 6

.Wing of paraffin hyd ocitriguiks Mfg. ? to 10 C at

00 a.

(1110011t I()-,
&nd a wnAll quatilitY of 1"WitiAl Ukfins

*0 4
"te clophyrd with a irsi"I CIA -PKilincia Mpd. fly
,

ppin. "Ith Nil, Ifunt a timakilt Cr Sall own. It finsigrery
00
Svitc in tatalytit4t the cychution reaction but its
"
'
"

10" 11
ariMty dectragird vadus1ly &I bough active fgr mom than

I'm
bi-. The behavi- of CrAh ignited at

A -mmilia-rd a noticeable so
lvity fur The first few hirs.

of tj~. and wiss constilettly
deactivated in 10-15 hirs.

wben CrA am det.-ited fr3m a suln. of
CONO.). on

kniiM aside used as a carrier. the resulting catalyst
h
r
t
a I 'D a qp
t. off
tnk%t, quxe~qully amrk-fai'll the lWaffinic cyrfignition
a gt,m~t tah,luy than C,qtij 1wepti. in th,
usual wwv. The t% h;tvkx of a rstalvsi tuixt. gnrpd. by
drim-itins 0,111, im Alg(h was Idirwi-v %tudird, Thu%
it viat ol,mi vvd thAt even %hen the c%iairat of Crgos in
Udl t1latar1% was at low at 77f. the regicuon of arrmatiza
liem of paraffins proct-ttletl with sulliwiral effect and th,
"' I
catsl)~t was c We of being rtgrneramed with air. An
sit 'At". inlruence of the mtrief m the activity and
falolify go "Isilysis in M4 fractiogii Was gfbwrv~nj in The
raw 04 11"'VOCts tN`11111. N',4% Of ThIN. Wink- A441%
V01a alone did nut pfognote paraflinte mlization under
the ciogglitions employed. the addig. of Vv(k o,
I h(N to the A4(h y1tided a catail"t which simigglat"i
to a considerable derre. The sanu.
olgervitfions in-te made with %to and 1.1 oxides.
W. A. Cook
o"
00 8
U 0 AV 18 At, t
17 it 0 at It a al U 9 is ft
it It KO n I ift
0.0 0 0 0 0 0
-00
.00
-00
.41040
",g to
-00
A 0
60
ts
Us
-1 a-
00

0 0 9 0 V
~

11
I a I to 'I U 61 M 4 is 11 Is S it
il ", &
4 4 1 4
(
U
2

of N 0 60 a b I., a P 6 0

fA

A
Z
I-A-
1-
-
W, 00..

I A

.00
00

C4*fAttcydiud"otpomNIkkydrwwbo"- Cobb*

0

action of chromic *aid*. A. L. lAlwiman.

-00
0

A. V. Plate. S. Compl.
1'
440-NOW
S
S
V
i
d
N
R
b
j
h)

.

. its.
.
.
.
n
a
. WA
.
.
-re"'
,
(
us

-o0

-The following c"Whaims am reported on crelization

00 a!-

au4ws al synthetic gwokow! fractions of the following

i

h.-p.
range: 04-123'. 83-1W. 122-130' and 138-62'.

*a

Ctol catalyst
mixt~ ("alved by depositinq an CrA
h to-tu
tt
is a ttKxv stabl
i
hi
f
f
t
i
l

i
e cata
ms
a
It
gni
yst
p.
y
p
rv
rlitatton reartioa fhan Is CfA preod
re tbe c
b
th

0 o

.
e
y
y

.

0

usual simple ppin. rarthod. In &it uninterrupted p"xv&q
tahles of dats still
1-
41
Th
rill
ti
i
l
l

t-ulvrn 111grth" "Uh aArtaded amount

,

e
y
a
a
On fract
on -
Yse
CrjOs rtmillnur% to ra
14 81,11. rulployid alut elptl.,Hail. Our i4clihiedL
-
O
b
120 h
I
J

":
of d

-
ons R
r2..
paraffinic hyth-
as
Is Arl
vily de.

'A A Ccxbk

*

rbuins with titne. list adda. of lint). 1,N). an.] %I t,,

00 0:

CtO. do" not Improve kt activity. Chromic hurate

00 4

ratalyzes
the cyclisation rnsction of Waffun during a

-0

abort time and
promotes the formation of pmducls of high

00

truil. wt. CyckVmffim
hive not been i:wmed among

00 it

the final cyclitAtion products.
The r%pta. with all th,

AlKnT.11wationnt rals"S were e,arr" on at
& temp .4

00 S
0
r
~*

425 sar, the hytitorwhons passing over The catalysts at

-
00
o
o
-

a rate 4 al-ut t). I the vol. rd liquid per I vol. of catalyst
i
k

-.0411

i

-k arognittic hydrocarbons in d
fferent
per hr. The y
"4

As

.

eapts. varied 14_
. Tht maz. incrt%w of octane no
41

Witt 62 points. The methild at prepu. of CrA has an

indutnee on
its act =vit b%r. none of the prepo. methods

described gives a
tky stable catalyst and gearches

for more perfect emlActs ibmid
be divercled loward The
f
i
4i
f
i
d

t:e 0

Lwace o
The
n
ers an
mT
prornoters. Sev- I
y o

o

too

"

I 1- 4 -M
r- V --V -,?I
An I % I

Od 0 W I If It 5 La 0 a T
,
0 a 9 a Ot a a ft Of

0 0 0 0 0 0 0 9 0 9 9 a 0 0 0
00
0
1

KO A I Is

1 0 0 0 a 0 0
W3
4

0 0 0 0 0 0 0 0 0 0 0 0 4111
0
:

~o 0 of & 0 6 111 * 9 * 0 0 P 0 0
0
0 0 *1* 0 0 0 0
0 0 * 0 0 0 0 0 f 0 9 0 0 0

0o00000000000
0 0 0 0 0 0 0 0 0 0 0 0 0 g-4110,11110,04100000*
:4 Ij 1 4 'J 11, al It It %Js $4, n _n JS It X M is 11 V 14 14 X
11 V III P 4, 4l 9 U 441 Orle
as 1 1. I-4A s a
0, P Q It m -A
a Ia a -7~0 o
0
00,
Comfort gythisfiflan parta a C 111dirlastsfild"S Cato
tolotatip $.'1'l1 I d At I ;?,;k!- 0 0
00 A~
00 it. N. V. 27. mb-70(lqul)(in I(Stalls Ila
00 X, J4, IM"dt'.-Tbe catalyst employed contained 33-il.316 .-Oo
Alt0st aad 67-7% CrA; the paraffinic hydrocarbon frac. I
II I-so
00 0 tass, j I I Pynthinr b. 83-1386 was intrestipted under
contli-
00 1%1,1q similar its 11MV-sr 'k-leritled In JWTVkVill, papirr.,
Chtly
the We it wh%,b the hyflitivotisson floctilm ,*I las-I -00
0 m. I the 4*1011.1 arass that, 1. will'ill A I $&$%Be -00
go t.-I ft-ner 44 the rololyals. r. the allopolly all raps. Ill.-
rate was allnut 0.1 Vaal. of Ilqukj Irrulhilar per I 'All, J -00
re"Alyst I r br. (for [Oscan", lot the Catalyst consisting MOO
06 Call I ttkA. CIA. 0.78 mol. At^). The rate at which the
hydrocatbon fractiou was passed through the contact
000' %pam had a emAderable indurnm upon the ykld of aro. roo
00 J~ Mask bythortattiom. but with a freshly carrpd. catalyst coo
rvers In e%pts. with the we%. rate of 1.4 vull. per I vast. of
%vtalv%t prt III., the atnt. 4 anantatic bytiftIcarbous --o0
!I'llor'l W41 arpstult, 20-26% tinting the first ht%. III the
1%, 1 atutUmrss"I ~M,Irvsbly In subsequent exIMS. K.,
.IIIII allow, the Itatitmins "anclusilart. Irsam the t
a% Udy": 4 Vatmalys" cuuts. differstal pfullsortions VZOIA a0
0
lit, 1: ftosiled ulmm AIA have been let". Catalyatt comic, !s0
IS
Olnect CrA wm Own ocilstv. but even the catalyst mixt.
go
0
C'WIS. CrA possessed a sufficient activity atut stabil.
r4i 4~ ZJ' is Y These catalysts C231 late regenerated with air $I
the
Spillp. of the =.' whefrhy their sarli%itv ias
114 a hill al mis, J W(N &rot Cut'l W "atah'11% I t!oe
rtmig. j.'#AN at"I A" to equitsulal. ttuatntitia-1 111111U%10"~Vrs
the meliviov ad the letter. W, 00
as latIA111.111POICAL If#41,111.0 C&MIFICATI11111111 I i:oo
ire 0
It it 2-11 It
ant'sol $0 146 a n it at "a I FM 0 It 0 1 19 0 5 A 0 V
0 0 0 0 0 0 0 0 0 0 0 * 0 0 a 0 0 0 0 0 o oie 0 o 0 0 1) 0 0 0 0
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sea
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43
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III Is It! I r
141-1. 1--- __VT=_;
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PICKV061 ale
000 1111110*1111 a**** 111111111011 oil,
0 0 1111111110411 so WWI
111,1MI66MOV isso is q4u iwaid&
-11. - �-- A - k -9 - I ..*_ L-1
14-;
kb *fV1 -
Conant c7disatiose of pu*Mjdc hydrocubo". Cala-
vastadhess pulaside ud thatim d6ji"'
~#,F. I'Lati, T. F. Bulanova and N. D.
iw. sea. sell. U. R. S. S. 27, 6"
QI1O1tA41017F"K(LL1; RNi 21-V61 hen a s yu t h In I n w t 6 a.
b. 9;- 13 A ".
was passed over VA at kpp"m. W. N114%Vft (prelim-
hary btatistit to WU1 In N) at SOW or AIA at 430-W*.
tbtm wes practically so fonwitiou of aromatic hydrom-
txm. Ahudua vrith 8-10% of VA at M-U)" cats-
Jym that farnation d aromatic hydrocarbacts from Wo-
this fracthwas which b. 83-LW wW 163-MO. feep.. but
gradaly lows Its odifte btp :V with Z;
the catalyft readily Its t by beat-
ins is a eaffea c 'k. th 10% Vz, at 46G
470. dwm4 costaiderble Ctytk wdvity but rapidly
Wet ka wtivity. Parby Ut*WW with 16% VO. did
ead"ores lots 'taromatle hydrocatbous from
walbdWritectlost, b. "83-13'8 . AhuUIVA With 10% ThOs
catallyaod the forizatles of aromatic hydrocubous Irma
the saw qattlebe fractim. The activity of
-UO
shodu wkb 10% Tb(h mi 110D0 for be =OW Cd srt)~
"satic it from Sin mum "atkits, fractiou its
then slowly demand. the caudyst
Maun be led by beatiAg with sk. Alumina with
10% and 2% TbOi at 473-6WO acted In the same
alumbus with 10% VOOS. Activated charcoal
with 10% TbOl at 450-4T0' catallynd considerably the
lorliesticts of womatic bydrocarbow; trout the VuWn
fractin, but do cualro "WAS1 MPWY in Kc-
tivitty am was tw satisfisdoruy regenerated with air.
WIFTALLYMOK&L 4FMNAI Gcorre Arm
I H* aftii;
-0 a ..1 w
0 0 46 0 a 0 0 0 a 9 a 0 0 0 1o 0
east 9 00 0 0*0109 MINI 190,90 lop 64 0 0 0 ft 10 e 0 a 0 a 1111
a 0 a
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1900
coo
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as
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poind Over a go. c# em.
ut&& bawba tbw 940
r-alks Sagim
swm pf Sad 10% (0,
4 .
=411M b7z~--'
IN wat
4760. 20m. 1. BL9, -
I't OW prepd. by N
IIJ4CIs aulim. and ban
dW mot wasmatim the
umgd. kydmcuwm
of Kmtwb" mdA. (I
coal at 3aU* armstl
t. tkt ~ dta
M
:MNA W the .11*
M11- 13 44% um'u-
affim pobt and 10 CCU" am. Was
Abs" at 435-awl. Sivias fte4cu.
Us vubm for %
tt (WAX.) WW oc=%oa
(pmbtated in H to 4B0') at 430',
-QA (re
1: 1 Mkt. of "M gtI
it 426-M 6.00, 14.6, W-0, 22.
IM at 00 , $An, IM 48-4.
JO# (prebasud in N to 4500) at
1. 36; 021 A" 241 CrA 90
I N at 4T at Db% M 28A2,
ad T MG% (pComiaw Is N to
j , No ZA dumate at
!4j! & 24.
daliad chumal (cwts. 23%
mignatim activatad cbwooal witb
as in H at 30"10') at 3DO-3W*
ratMa bactim. AlUr ftmoval 01
rm the No fraction by mcAm
A - 23, Oubcd dw-
d do el:dowbow to
i #A with 9c4=. Ak4*nrW baa
d I..Wt. cat.L11%..
mon Hit am. I SWV A%f
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KAZANSKIY, B. A. . EYDUSS Ya. T. and ZELINSKIY, N. D.
"The Influence of the Type of Carrier on the Synthesis of
Liquid Hydro-
carbLnB Over Ni-MnO-Al 0 Catalysts at Atmopheric Pressure." Iz.
Ak. Nauk, SSSR, Otdel
Tekh Nauk, pp 27-33, 1141

-1 M I S' J.
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(U. & & IL)
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a &L A "TALLVOCICAL tlytNATV" I-A&WCATON
1k
u at 10 At 0 It D 0 orl" T 0 qw 8 61 9 a a
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4 AV 00 &t I 'q A 1 8 ew 9 a 9 1 v so 9 43 0 .1 1
1. It OF

A
nThe relative Efficiencies of Laboratory fractionating Columns
of various Construction."
Kamnak~~. B. A , Liberman, A. L., Sergidenko, S. R., Tarassowa,
G. A., and Plate, A. F.
(p. 122)
SO: Journal of General Chomistry(Zhurnal Obshchei Khimii) 1942,
Vol 1.2, No 1-2.

Ki"21INSKY, 3. ~.
"Polymerisation of butylenes on an alumosilicate catalyst."
Ka~anpkv -B, A., and
Rosenr,art, X. I. (P. 254)
SO; Journal of General Chemj~~tr (Zhurnal Obshchei Khimii)
1942, Vol 12, No 5-6.

Oo'
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-ViAng the pmvku4y tocit (C. .4. 37.
dw autban studictl tbA PulywAmtkin d Imi
PrroP*Vbork WW dcpWted on kimickuhr
and ~q Go MWYMS 1. 40 art Zu at TI d"it ed
tEKI ol a Th catalpt depasitej tx, -00
90 som 'm NWW, The first 2 ea' ts give 1-1
likht"
'Anow to "Ch Otber In cumpa. towns the
.4tits y
1*:wiatnS actkm u( tbot cat=t C41.1 .1, see
g fit the type ww cWts. Zo (w [lieu 11 are 1101 see
Milt" ci iting The Th-bratins
is CAP" of PoLmer tint hiabutyletit but i,
Zsp'4V~~ ~~Wuve pr1wipir Of pulywriza.
tka cw a 01, ac 1, type u I ht hydnad"te of I he
00. kkb h the cartici it( the ackl prtqx.i - wee
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KASANSKY, B. A.
"Polymerization of lsobut lene an Hydrosilicate Catalysts".
Kwans ,, Be A. and
Rosengart., M. I. (P. 308
SO: Journal of General ChwListry (Zhurnal Obshchei KhJjaii)
1943, Volume 3,30 no. 4-5-

00
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002
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of -Obs" quismary C AIM
9

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and
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lo
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(7
-
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.
.,R. S. S.
).-*nw addn. tit jwjAjja
t2-10' fumbbes In
-
). bm 108.4'. oil 1.411t~ M

r4 0
.
-Inly b1.T -w _.jdtjfiW C, Con,
st, obtained- By ydro*mat6. 01 1 .6X d

Ch-081 -falyst
4.4-fimethyihex-c is obtained in
Ovid, btu 110.0'
a V 1
4014
d
0

.
.
.
. AVO.
r
L. Kuhn

,Dow OLWLVI#
I-*- I ZA
p~',f W An & Iv two $101gro 9 4
pp It 0 0
U AV 00 AIL, --'T , ,, Is a I Vf* - 0 0 0 0 & 0 6 0 a 0 0 0000
00000 a 0000*000*0::: 00,00*000*000040
6100000 *000*1)00 00

C-0-006 to (lots 0 & offill,
-000 10
0, It a i 066009 o0 0 9 a 0 0 0 0 04
I ITT I I I 1.141t t t 1#7 is I t 'S A; a M 0 -
a WN it a it ad a p it );
A -1 1 -11- W 1 -11-10 1 6 1 1 , - &- -
90 A APT.J.11-poply. -- - , -06
-/7 POLI&IONS, -Ld's
A. L. bi.inwis Aml 11 A
BOX. dfaj. 1, 1. 1'. R..% 'S , Od a I~ 1. -00
1%5, 77-4(in Rusilian). --Dintrillith it) in All. litilliellinn
of P'. black do" not silliorb It at ally pignitimlit rate And
lee
00 widn. of IICI does tivat Improve it; a maintwhAt
hydrogenation rate was observed In AcOlf. time this
r r2 W11 dwinallealtuO. land anall, suslical%ion a,( platin.
izA gabo do not abwrb 11; addiv. (A a little 11,11tCla.
00
however. led to throrctical absorption of If. 1 (411 C~).
00 It I&I tal. AcOll, 19. platialt"I C. arad 6 real. 114PIC1,
-4n. lee
00 19113 x. Mind.) were treated with 11 liver 45 65 hts. 00
With WICIFIllittirnt 4114,1111. Of 1.5 t. I'lAtillit"I C 411-1
V' ~NI
oo jail. IliPtCla, "a.; adiln. of N&Oll land -little. gaveau
aid. 59
(X9.5 C. from 3 expels.) whk-h m reilistia. gave III It, ].I.
thaaaaaUjakyde"ne. Ill. 119.3". it!" 0.7".19. ft',* 1.42'114.
xV-t 1.4313. and 61.4 l. of a mill. (47-6:511.15) of J.3-ift.
varthykyriethenteell and J1,3-dimalthytrycloAarryl inflate. b.
173--ZW*- treatment of the mill. with ArCl gave pure
eletUtai. haw d:1 IML17o,
01V 1.441 , aV 1.4387. similar hydrogenation of I ilk
Etto pve 18.8ee! 1.1-dimethylryi-follexane and 40.11~
3,3-dimethTicyclobextenall (itiolatni u-s the acrtatv);'
hydrogenation In allosAine pvc 10"t, and 40";.. rt~p . while
uw of Itoo for solvent gave exclutively the lAtter aut'. i
silence. Pyrolysis of 48 If. 3,3-dImcthyk-)chahv%vI awatr lose
at 430" bar jassup through a tube parked with
glass wa.4 lee,
Were d 4,4-
"tion without a wAvrnt over fit ack pre 1.1-di. t:0 o
methyleyclathexanc. by" 118.8', d:4 0.7810, IeV 1.4.hi:l.
C., ld. KilmdAIX30
S L A ACULLUSICKAL tiff*AIWI CLASUPKAtON DING,
tanotto -a 41. 0.1 an 01101clatf I od 4- is I
U 0 AV to I F r--r-r MI v -TA A a IU 0 a W 1 9 am -J a -li-31 V
00
a *0 it It U a u it 40
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A,

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41'0A
-00
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t*,W..A AW. V4aAk S.S.S.R. 16. No. 2. IV
:
A Fr%iCW Cal P.'s work jai togsitic chemistry. U. S.
go so
a*
Vale 0
r
e
:
*g
I 'Jav 1*41-V
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,"1 17 / - /'/ ? '
/I /7ZP/" 5, ~ )
n-,
"Catalytic Eydrcgenat ion of a-Nitronanhthtlere 11 by B A and
'". S. Fro,-yElcv
11 . . . I .
(P. F15)
SC : Journal of kG(Ineral Ohe,-'n (Zhurnp.1 Cbshchel hhl- i i
Ic4i~, Vc-lvne 16, No. 6
- --- -- -- - - - - MiLLU

goo
il, I it lie he I
A -I- 'it f
A.
-~,W bydrossnatints till cydopentane aydrowamr-ti, 1-- 1
o: lWarbsitissains. V1, -1111411
in Olit A earbea. U_A.
Well T. r-8-02.1"64 (kg. Cliem-'Acad. Ad
o0 IL, Missross). Boll il Sti. ft-R.S.S., C-ios"S 1:1) Under the
salor cundsli,ass. CJ1,1 hufinx IN, changr
C 1947, 26%-W(in RuisLLn); Cf. C.A. 29, 79&)'; 3A I'm the same
catal 1. 44) For purlalars 01 Ln&lys3% ~q
00 in
'OW; $7. 3MV.--M The calal)-st (40 ml.). having it~
lats.offendc.1 ,!s V""'allifille "d SJIL Voj~
&MVity thars"Clierd by Complete hydrognoatioxi 61 err drill.;
select I IN10intl - I M) X7, 7.3 40, A7.43, V
Calls at a BPS" VeWtr 0 of 0.3 and 110% dehydrogsintion
11-1-94f'r. MIr 1.401h. 1.31134. 1,3w, I .11,-.a, I *% %4,
'M aric the same it, was "ve to tbc Is' 0-7-U3, 07117. 0-6017.
11-0712. i1"14; aniline
of Cyclubletatie at ,
0: hydrog"tatkni of cyrioliestane (1) only when virgin; I%Aut
21.7. 31.3, 40.1. &1,o. 63.31. jr1l. ny*vgft&. 00
06 loader these conditims. at 3*Zbl And p - 0. 1. the initial
Unit ad =tgwr
I 001AL! the Watinco of platis,189,11 '40
44 1 am oxhla. 111. A. ko-&uskil
o: Alrol 181~ Call'i/fir.) loul fill insitisequeM runio,
tftcrb?pugv~ isuben 00
Activity 44 About I I V.11., hr. &fire aliout v his. and Z. A.
Ituoillamseva. lbki lKI-M. (1) With [a
uld, of a plolinit"i C catalyst 14, InlUrtd 'Alth lie
stalyals Previously traird' Ith C.11. or with cyckohrien, Up 10
310% hAVIIIS oil AMMY C1111MCkill" by Wj
were truseuve to the llydruCtoationof I at *W tuods ~ 0.1.
hydrogenafion of Calls al 130' &nil p - 0.2-1 and 1,y 43~i
3 (2) 71w catalyzate obtaintA at ZAV (in several runt of - U. 4.
the
bydrogroation all cycloWntatir at 27V
I -b- 2 ties. each) was fruclitmated Into b~ 3&9. WAQ. CaWytate
obtained in loyditWivation ~(Orurthylcyclo
19'. and rraidue. in the iami# PI ,h 6.3 10 6 and 3t%. facutaxat
(U) at 2W. V - 0.11%. Vuliluing gas 2 1 hr
maxis It the lSt and t1st 3ed 1116471141111 Were lvw~ In
;;;~Slst of Pure contained 40-lil", I~r.ffiu laWlim-Aillaina of
allok:iI 2:
Call.,andl.resp. The Sa-t was III, 9711141*j, said. We"'
carbon* 3-2%; hence. cracking products are practically
site 11 jo; WS CatAlyzate WNA tractimated Isito b"a
1. rates olemottion 1. at a nit rate 0.6. 60.&-W.5. (10.5-2.8.
R2.8-4.0.
-C,12. 1.1111st..Ou %equiv.tol /hr..&I228,23-,, 70.9. 704-1.8.
71.5-1.7.5% in the anits. 1.13. 17.M.
; :
Ira" p It. 0.34, OW -.77. and 2.(Fj 13.07. 3.37, 3.40.
12-96,3.39. 3ZA7%; maidue anti lotats
reV.., al 2W. the yield of C&lfjj was practicall ;
lejoendr"I of the rule of frefing (2 24-7.1111g~jhr.), 'tin.
2..W'" ; fractions 1-4 were alolost lW% paraffms, (rac-
J ' At 2"N" lion; y and 8 atillost oil 11, flActiou 54votalized
atiallut lu'l,
a "Ith I led at 2.24, 5 Ill. I-AW, 6.10 ii.illo.. the yields of
itaraffins. fraCtion 0. 15"iL. The caialyzate obtained at 110 o
CJI. seem 2-M. 3..-,. 3.01. 3.1ki. 3.11 g./br.. i.e., a rate M"*
was flactionAtell into h1j.-t M-0-9.5. WAIA
of 2 g,Aw. is insuffiricni for full utilization of all the
"ve ecritess of the catat rst; at 21,ki% R.b P. W.3-2.4. (U.0
Nit. in the &mi&
8 1. lilar., 4.70, 49.74, 16.76, 5.711, H.WS1j; reeklue and knars
I Ibe y*kl of C.1fol max al-tut 7 S. 'hr ~ The a 3-Mle; the 1*1
fiact,%uss cmaisli a1mc-t vitiurly
Ilratinim7f'r 4.1 like i4 al"ll :I,% r11A;7!lW&4CC.
Ago
.0 7` 1-4
n I
u n 0 It is n, it 09 Ill a it It It aft It a
0 0 0 0 o 0 a 0 0 0 0
:10 : 0* 00 0 0 0 0 09 0 0 0 : :1* Q 0 0 L_ 0 0 & 6 ig 0 it Goo 0

jatodma. Itis, tiltit- it AtIll "I "IVU111% AbUtit (04
parathns'.
l
diturthIliornialto aiul 1, With the Wire 1wraortunatins

thus,
The 1,~U
calslyi4le cutilains M% parArbas of which
UA) W, .j ut the
1144-liusil. Thus. flic JIL411 11-Action too -
00

6 fwi,
3-rulittoylpeutane 200W, htxano
'
'
ot the 3.4- tor tbir 4,3 toorni, Tbr gas
mots in song o1wroinj

12
r. I he gas evolved at :it$ was if,
W.V. cit.
.
'1011m oto of USA% I jort'l 1 4" imIll,
l
00

1.2. Lis 04.. N. 1.4"'. 1 he tAinlyfate ablairsed &1 317-
'
*
1
CfArkula is t~', 1.3

00

3A)
cuumsint Lai the syrooirr of 7.%-77
,, jostaff"Is but
,
(11). of 303'. vX4. fair S.%r A ",to. M

90
the twon"111 oxitcat
stiAto"i 1410,V In individual expla.
W', thAtAIRS.I.OV; 'Ill,
Cit.. .1 ~.-;A% ."I I.t,
*0
90
1 be cuerrsposidaig fract-us of she
;MI. 3LK". and 317-
. .
*
(1.2. the Mt&1YSA1C CloutAlntq only PAIA(hus. ]hr
*0

j0
catiolyzates were united it refractionated
0"
X119
quid obtained at 305* Was Itactionated under 7511 mut,
h

00
b- 62." 31 os-:W', 1. 1.- zv-&-9.8 ps.ao), 6110-
;
7
into b. 71-f!i W.U* t ltl.Fi). ?%Lu sl v ('3-u- ). slit
'
go

2.78 (13.
,61, 6w W.5-4.oo j 13, ~21. b,"., (4-40).
'
9.2*
(12.5%). 99.2 91.7 reidue
OV.).
00

I... I 6K~X
.1.4 i I IAN. bvm 0 71.4-11 (7.62). tvaititic
.
g by tint it.. wvttactkxt. and 4knilinc poont, the ist

09
by the
plovs volots.. I he P4144111 vitiolist of 2- -
7
j
to raction cunsists altmost entirely of piuathits. the 2nd wul
00
09
i
metbytpentant d
,j, Z1%. ticzatte
*
'
'
3rd entirely. the 4th approx. 411 c; 9,4 -thuseth) lt~utoir
of

11
,j. Tbc tv*lur vivniAturd 2
v Cj1j& tOLO&~
O of tht
piedowittattit in the 1-t and 2-1 6owt,- at"i
cs~-'-tut,s

00
total catitly"te). fly the Hattian 4xvits. the
COM1111.
about Ml,'o at the 3rd. the lot (14111041 LtHloosins A
MUA11
00

00
is 72, 2), and M;. and the coorents of the sep. (evictions
7
litut. of Cit Is. the residue about 171 ~v 111k.%Ir 0 r; A t
hv
0

2. 3. 4. 6 + 6. and
.: 2-awthylpentione. IOU, 01). X1, 0.
-tutalcuLtilyzate).
11yRantAn but I'llotunn-toy. over SO,

00
noidti7e; 3-morthy
Iperolane. 0, 441. 77. 0. and 01,-v, btsome,
of the tuilLw tit
Nd, and 31d flowlioll AIT
00
1*0
U. '), U. 30, and wi'i ; 11. U,
1.1, 0, -'(1, land V()%, (.1)
.
1watAue. not Over 10~~ 2.11lethyllwk.11C. ~,A 11"I -v, I tit',
00

With a M catallyst oti AIP., c1sawterised by 100%
3-methyffiesione: the 4th frw:tion ct.rosso. 4 about 50'
f

00
,
!!Tdroartuiliou of Cello at 160" and v - 0.19 WO by
.
Iunreacted 11. 2517s, 2-inctloy1hexanc, And L.Y.t 3-ttic1b)1
90

dithydrojettation of cyckh4toone to C411# It 290' and
s
hexane. king olkenting evidnitly takes pL"%- at the
*0

0.19. U
undergoes much cracking. At M
. the
biond. (3) At 2M'. undrt idenui-Al coudjuou,, tht

I**
gaintan products curialituic 40: of the 11 intmduced.
At Stlil% v - 0. 16
Or anit. of h cracitted dropped from
ratio of the nos. of
utoles; oti CyCk4brittAIM. 1,%, 1.-
t
1
d 11
d i
I h
00

.
n
opene
r. are approx.
ane,
, an
-pen
00

40.6 to IL3.071, in 4 consecutive runs. decreasing with
0.2:0.1. Thus. disubstituted cycluprutAtt" arc otwoed

09

"'
"
progressing so togotthecAtolyst, Typicalcompts.of
T
more Slowly than the mottusubstitut.rd tmuipil.. and 11
00
0
67
the C": I
. paraffin hyAriscarboots; 32.5%. TIte
I
'
reacts moire slowly than I owing to the presvice of 4 -14.
00

collected Catalyzate. no,
I-AISO (increasing front
sive" bonds (1-2, 2-3. 3-4. 1-5) as
ationst Mir 3 tit I

to IMIN in 4 consecutive runs), Q* 0.70M.
aniline point
(1-2, U-3. 1-3). Ix. Hydrogenation of
1.1-dunethyl.
00

414.7% was fractkounini into bo, 27.4-4W.3'
c
ycloopiniftne ovour platinim rd cat bon INJ 4"1 %U 0;
90

(37-VU),
troodur J OU'~, lotioce by the
I I-Ditutthylcycloistaimic tilli
-Aas vymbr-Aard w%%1%
'

phys. tvntotx~. it contains possiffusa; the residue actoo-
higher yield than could Ise ototwuni by tuvtl"~I.
a
00

Wots C4H*. At 2MO. v m 0.15, cracking att&intd 60%j I
-hiLhertociescribed: 83g.5,5-diiiicthvl-1.3-cyclul)entatir-
00

IV
a( the caloslyzate IM40. (3) With the oative Ni
dione (IV). in
HXX) ml. 95"t. Hoff. %as hydrogruAlrd

costalyst.
3-cowthylpentaile at 203% v - 0.13, ve 42%
M
in the presence of 17 g. Raney Ni, undi r au itistiAl pit-oic
00

catalysiole. his, 24.0-02 W. 0.* 1.37,83. df.* 0.667
, aniline

7.
6
1'. the I&S WAS Its 417.9. said. hydrxtearbous.

0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0
0
-*1 '0
0
It 4
f 1 0
1 *
It
i

VIM I To 0 0 0 0 0 0 0 0

4
.
.
f U I
is
.
s
.
1
4-A r . . I , j
"
.1 A.,? jIlk-M till
I
"

is a
ALJM-Z,
re

00 0

75-
I
5M
1 76 a In I $1A. UAI I P) In - Tr;
U
'
'

00 A

the Pressure row up to 140
; from
lbo
. it Ivil

1- /ol; tons, the tolal paraftins obtained consist oI &1=1
-

rapidly down to lo-Watti. After ctioUng. the Ili pre Buie

77% 2.2- and
albout 231~ a.311111lithylpentgn, :rIW

4Was Again increased to 7(l-W atin.
and the autisclave % as

catalveate obtained at ZC-aw-, vu;j. tAte u
LI
"llalivint

go

heated stpin to IIW (of a total (~ 8 lus. after which Ito

.
,
a )out Pit";, it %4s fravI14-1141"t (unilet 743 3
go

go

Kim If. w" absAxtbed. Distu. of the product v &I-
33j. (04-Mrof the theo-y) 1,11-dinitthyl-3
"- T.I
jk
in.) Into It, 77-2 8.11* ~37,4`j

6 2";" 1L.-Cs he I., ('action is
ain
a

This was allowed to drup into IOU oil. IIN (d. 1.41,
X
(
"
.
,
g
almost all 2,11-dinicillylpentant, the 2nd fraction contains

so MI. 13.0.
and U *2 a* MIN% at 53-W
; the mixt.
was then he
led until
s
ti
l
ti
a
f N
id
75-"D% luirlIffini Which. by kAntAw photwiletry, cau~i.t
Of
I
l

I
i
a
on
en
a
evo
on o
u
us
ea.
~ and evapd
to a sirup whi:~h an coolins
ave a cr
it
ni
sa
UW
Y equA
iuxits. of 2.2. and 3.3-dimethwl-
pentane (38%)
th
W

,I
.
.
s
g
.
7
e to
;
jW.Poctions of 2,2. and j.
I

00 d

1 i
j
the Mist. Of 0.4 - And $.A -4firtiethyladiplic acids (recrybid.
O,
f
If
d hi
d
11
SO
h
d
i
isomers are thus vrty neatly the witit: (74 &nil !N;',. rnp )

4

row
an
e
over
eate
w
l
.) was
,
th 2%,
2*)-W*
Th(Oll)
t
f
ZW
W
h
id
97
6

Unt.,00". rile liAlAncr W tilt LIld limetions t"Oalld;kl' j"

0
:

o
ront
t
.
.
e ac
;
s.
ji.
g.
of a mixt. of 2
2- and 3
3-41imetkylcyclo
lcutationce was

at U), anti 31lu", rr4p.) is untractcd 111 (31 The rate I-(

Zoe
0 0

.
,
.i
obtained. with a ricid or 69% Bitter militu. at 145-8*

III is very neatly
the %ame as that Ili Ill
hyttrogroatj, 4),
ee

(743 Mo.). The ketunts, actit converted into U.1 g.

motlusul)stittitcdtiicthylcycltvhciaiiv. Hingopritingtak

Zoe

. er redista.
at 1%4)* at
(yield. 77.6~~ art
ad.
-

place exclusively at the 2.3-, 3.4-, an(l 4,5-tionds, I

the extent of 24-1" And 36-h'~
res

e 0

.
he hydramies sefe decunfid. by heatilis

,
p
t
d
l
l
i
h
1
S
2
d I

I

Iwith fused KOJI and pi&Uni&vd C- fractionation 0; the
Q

. an
~
tsie
un
ergoes a
w
ng at t
e
y no nuS opetl
,
'
bonds
in contrast to inethytcycb-lientatic where this
ace 0

a 911

ymkI (with
respect to
b;dw Itli f
7 gj
r

,
type of ring olletittig dorm take ptAce to wine extent

) .
;.
lydrogellatiou of Ul Under
the Mme conditioas as lichire, with an ellcess of Ili (1,5 1.
'

N; Th-

e 0

,
Wi

lie outoplas per hr.). &I lnl
. vol. call! 02".30. save a

s.

catalyzate esid. to ctaltais 60.r~ paraffmal and fractioU&ICA.
'
1
7S2
5

1

.
win.. into Li. 2S
(W-4
,0. 792&

W.5' (62.174.). irsidur 3.7%, losses 3-717p. Fsom the

phyll.
(Onsta., the I&I kwilou is entirely 2.2-dimeth I-
t
th
d f
2
i
h

n
aitir;
e
raction conta
pen
ns s
out 40%

tto 0

which Ranum phototnetty shout I
0 "Amaist of approx.
l
L
f 2
2
2
1
)
d 3
3
di
I
i

4e

-
&m
*. o
- (
equa
.
an
met
,
%
.
sy
ntane

a ACIALLUINGIC At LITINAT1011 CLAS%iK&TM

t*0

BID., SWSIA..

ItW I*.I.V
live

cot
1

aw i;%V
-

-
o

I I a ?W 0 a 0
4
U SAY10411.
note 1001 walls a

"
;
~

0
a 40 0 0 0 0 0 0 0 10 0 41141114111 see 0 0 0!
0* 90 0 0 -9-"' -"
70 -.9-0 0 0 0 41 0 0 0 0 0 * 0 0

..............
a 1111 Alt
_A", J! it*
liscellus am
00
Coatact cadolyfic tiansformottlaosus of 1.1-dwaltoyltorcloc
#0 bips"s in the pittance of platintled ClUbtle. Ii. A,
Rasanslul and A. L. Willman U.S.S.K.. 1
00 4 11 It
0 1~ i -?.16"W). Mail. "dad. s, - U.N I STIa, Sri, thim.
0 RUWAQ.-I" 4varailction with the
a ;"in of the list-( ItAnimit of the catalytic AMMUSation
00
00 a,-;! of dimethylbriAllra, in plLfficular of
a.i-dirtiethytheisne _
Whitch, lit ;Kr' 3 IV, latinil"I C. rearts in The main
+ 3110 +
to
0 Act
~ I i 1,1111t. failure to detect it,tertnedustr ftvmatiOu of
i.1-di
09 1 nicticylCyclo1whalle 0) Ird to theitivratilatiors of
thttrans
j, jormitlons tit the lattef oil the same cotttalyd'. Its
activitj
i' .
06 Was characterix"I by W, hydrogrualiurs W Call# at Iii,
-sty 0
and a Space vrltw - 6.48. and 87% dtilytifolienation
00 of cyclohexane at Will, I - 0.49, in a vcry slow strem Of
Ila, (1) Without camer gas. 24.3 x. I at 300% 111 - 0.10,
. 68 s4c., on 75 ml. catalyst, pve 18.6
time of ewlact
or WAYEAlt anti 2.5 t. 11 10 4 1.) 949, lit OR. 1. Old 26.2.
Ns 3A. th 1.5 C(h The catairzate was frac
A&Z titillated Into fill, 110.3-13.1p
3,t, fesidue 12.0A. losses 3.9%.
(39..
By nitration. the conteuts of aromatic hydrocarbons in
the 3 fractsons and in the residue were 74.3, 70.5. 15.
and i.e.. with respect to the catallyulle, 14, 28, 4'.
dl 11 and lot' and in % of the theory with respect to the
'i
?I amt. of I 'U"' Ia. 26, If. slid 8 the aromatic bydra
i
;.I catboat of the ist 3 fmc~ions is IlhMe (total yield 43ro).
Alls-SLA MUtLUSCICA'. LITERATWOF CLAtINFICATION
b Ua IV 10 it:
411, All a a It a 9 a a It
Iloilo$ 104111
IA 4 A j I Ij 1 0
I.
those (A the r cld~~O- -Kn-'F;~T; In tll~ aiiiiiiidt".
vatic) orillo:11irts - 5: 1; the tatl,;, t4 . a
hA: 1. These is lil- A-C.H.Mr,. 1j) Ili a sir,mix orrani
14 lit, 4 I./hr. (31111' v%virsO IJ ~.!l g. 1. lit ~11W, on
Pill
fill. calsaffill. title Whose 6 1111%hr., o - 41.05,, - 34 w.,
12. catalylate still 2, 1 Ila&, It, W
tv 1 -11. 1.3. CII. 5.1,,
1.3. (h 09"i.. Tim rats ate was true,
tionated Into bre 91.8-111V NN?0'!)"
P. M
(51 5") residue 12.2,#, lotwsi 5.7"L. Contents (4 all)
Mal'ic'h the teisidue.
if.rruc-A bons in the 2 (tactOms and in
02-51 and 314", i.e., with respect in the rAtalyzate,
19. 6. an, 5%. or, in s" CA the thonry with mlwct to the
amt. of J! M 6, anti 4%; the h, drocarbon of the two
r
fractions being PhMe. that cd the residue CallAl",
the ratio Is 5.7: 1. i.e., practically the Panic as in The ah.
sence of lit. (3) On a catalyst Piv'riously used for hydris
111MAtion of Calls at 351' and tbrn twice Im dehyde,s
orcoadon of cyclohessur at XXI"t I 4kt YOU", withoat CAfriCt
at a rate of flow of 2.2 mI.P
!./15 nil. catalyst. 9
13. ir - W sec.. gave about 40, ( ittonatic hydrtivVirturivit.
(4) The ratios of SA anti cl-Colh-
~Ics: M.CJI&l~Ic approx. h: I we ind"nArrit of the aft.
aroce or Presence of Its as carrier gas. The final ywid
I arrintuatic Ilydrocarbon% is. within the interval studied,
-
a litstu function of r. being 27. 40, &tilt .10)% at ;;4.
5O.'andflillocc.,rcip. No ring ripeilifir takes place in lhr
Qrtion. The rate of the artnuAtization of I i% hAlfav
between that Of drhydragenation i( cyr
1-h,x.ne and that
of aroutatization of Imtruffins on the &Amt VAtalv'st.
N. Thrill
(OW is I
a rw o a -a 03 9
00
1-00
00
00
06
00
goo
=09
0
It, "00
-0 0
1 40
1#
700
; WO o
Uo 0
Its 00
0 0 0 0 0 0

M Tm M.M. 0.4
10000
ION,
A L &- "A
-A A 111 t 2 ti-r-MlILLL 1 -00
A~NI I kp ~~Yjl~o
,t
*0 .2 7
go
00

00

-00
0* a

-00

,OIL Catalytic Hydregenstim of Cyclopentam
Hydrocarbons
e
o
tio
t
VIL H
d
A l
CW
W

*0

r
na
n
b
&va^
"
y
g
lz
=t=
8

in the rr"guce of rlatl
10 eft
i=M-
=00

w Nickel on AhmIaL (In Russian.) B. A.
C

Ramnskil and Z. A. Rurplantserm. BuVelim of the
a**
so i
AMdmy of
Sciences of U.S.S.R., Section of Chemi-
190
183
l s
i
1947
2
as*

-
.
ca
c
tafts. no.
, P.
,

too

it j.

406

no 0

saldfa Kit umv M

0
T a ZA

. , I I" An A I I fw 0 a 9 1 9 0
; a, K Cli tt K KID 4

0 0 0
0 0 0 0 0 * 0 0 0 0 0 * 0 0 :10 0 6 0
0 0 0 0 0 0 0 0 0

[
d

94666**0694696009
A

ri. A.
um/almistry - Ime"mation Woot IOT
(ramistry - Hydrocarbons
*Catalytlo Hydrogenation of Oyojojxmtanlc Wdro-
ewbma When the Cycle Is Interrupted, VIII'" E. A.
Zuanvkiy, Z. A. RWantseva, M. I. Batuyeyp lust
Org Chem, Acad Sai USSR, 10 pp
*Izv A)md Nauk SM, Otd Khlm Nauk" No 5
Discusses bvdrogemtlm of trans 1, 2- an& trwin 1,
3-dinetbyloyolopentans In presence of platinizod
oarbca.
I&

u u it a a v v IN 41 4 -1 41
a AI r Q a 0 Av -'b' , I I a I , ! a 9. A 1_7
c c1
Nmliz
sa
Tel-
Ri ?v;
7E P
OM -WIZ
I
115 a
(q roe
j '0
A 21
AN c
b A
As
ago*
c;
A 'i
4,
Its-, Z. S. A 'req
Atb.~LA SITALLLOGICA4. LITEIATUtt CLASSIFKATION
Wo 0
to $Ift
An a 1 IN 8. 1 a a a V KX'
VIA Net Nctif to FgKwn 1. %a
0 9 0 0 0 * 9 * 0 0 e ; 9 9 e 00 0 * 9 0 0 ot
00 0 90010 00 0900 0 0 0 0 0 0 ~ ___ 11 000 0 00 0 000 0 0 OA

Whim im

so

W" InMgkb lUdbakff. R. A.

Num. 31C =1-2(1947): Chm.

off

008

god

00 U
-
I -
sell
.
ASS.ILA OTAWONC" UTMTM CLAWNWAIM
41 it J i A X- ~ [I Ii i 'it r I
00*oo::O:Oooooo so
zoo 00 0 0 0 * 0 ~10.0.40.0 0
Mm "NOW
CAM an off sit
6i
o *00096609000*0*99
00009tosesooosewoo
0 v 4-irapo
2
*60
off
off
use
we*
us*
fee
966
was
ties
400.
woo
'feel

llydrosewitlic of With rim opedo-4" in" the
of PIA U. A. Quaskil, A. I..
a A. P. Plate (AcAd: %SZ.R., Mw-
slow). Do" AW. Nsxk S.S.S.R. 37. 371-4(1947);
CAe". ~.aaiso Z. 1:
zealf. I d.) 1%8. U. 1M.-Hydru
gestation of cyclolventatic In the piew ce of pUtinisivil C
O;t. (c(.C.A.42.4&*W). Noccustals.having
yiekled;r ISO
a fewer C atoms were obtained. Inthecanotcyclo-
propane awl cyclobutaw situd, hydrogenation with ring
opening call be attrilluted to inner strains In the ring
llowtm. this i.%sumption cAunut be nude in The eAw al
rydopmumv. It is .4-Aum"I lb-11 In cyclopent4fir tiler,
air. 4 like C --C lxosul,i 4iml a '-Ih wit" is lei. .1.04e
*,,,I
1WrAk% 1111,11-1 11W ilitfUlth-e W.41 111.11Cd It A1111111.
M. G.

T Is lit f file.
-k- -Al. 0 11 1 1. 1- a A a -1 1 , I
it . 1#!,, 00
OOA -00
1. A. V I*#
I A X01M. A Aid. MOM *S 01" 'lb!=b= tol
x N-1111 11"N NO-10- d IC K cluding that "Irail t Sli
debydratim) wu 00,0,v
00 t jr A &4. MnAi SJ:YJt. i1; Whi I
IN .-Ca"n- based on the amid. ir"aw U 73 j. 1. 150 tal. RtOlf,
eon i4lemA and 2 mi. II.PtC4 (withAitit funber
0,08 WAG# Ke tb. .1 Mll L.M."V -3 owl" 01 it wriv taken up,
yiewns
"=411 ND% SOME-21PO .4.5% bmwk Mt~t mixt.. which contaload oveg
50%
00 1111011NA, - of the laomw b Tlx ftaWoe with vtookubande-
04's SM 8% HCJ jpvt dw jeWwksm, in. 182-2.8', the filtmte from
to 91 '. bw 78'. *V wk;& ssvp the cyclic mid. x1c., Cdl#.O. bo,.
176.81,
IWE -----tsd vadw 40treat m-'aV I.M. d*&* VAM, which on
dehydmdon with
falle"L I A WS =90
30-1W0; al. atom. 19. = (COX)e Pvt 8 j. unutd. bytbecuboas. bw
121.&-2'.
ifad C# Mid I OW. HOPM36 evin. (0.1 a 1. All. 0.79=; mid.
Posted with aboklas mad &Me, cl 4 =i. Aide. b. 310*. 7*=tmmt 410
the with
7-4 lift . the illall H tatilemptime was JOA I.; I Cl pvt tlw
kttow, C*IW, bw 169.6-73% which
IUIISUM*" Aide. vdth 'be Is was doe bollad awdy at 1704-2*, mi:
1.4M. ro 0
IDO pis" Ine all lb:Ofi WA dlad.. flvlait MSMT 'by= it:' OAM, W
f, aftch nolsaw matter an dian.;
it aWbose. after 611COMWAM &W No. OTU. OwM9 vah. the rielb a
Aryolftew, ba 0&1 . 4W. see
11, W
. Is, ter In the InAwnce
d Al bact1mvers obtalmail bk 110% H 183'. Dwmpo. al the lot a
Lid OH awf fee
The n"m was Mad. lb. IhA-76') AAAA 36 l. United plaidaind C pva,
from 17.6 j.. 11.1 j. mid. bydmwbon
i1i Airkh 80 It. (OVI)l 2 In. to 110-39% " 00 OD410' t*Ut-o WWA
bWW prindpaUr at IM-18.3% the lower-
aW Arritallitian 4 the dtbydmtim tm mi". Wait fim- wid
Wsher-balling Wnwi being Wtwat In small amts. Ime*
damMad YkW,t U.1 r. waud. b. JXIA- Thm, bydratenatIm In W"Y
AMIA: We. pvt $1.779
40 i4al; Ow ovaWmad praftO hvw 2 raw pv* wil. byAbomirba" I (M
9.), IW Aid. HIM, and 7 j. X00
the con wilkh 4a diate. ka No. bw UND-W. *V Rwy 20 by*vgemttd at
100 atm. G (Initlay) 20 bm too
1.406, 4-0.71174; hydi time of" Pladmiald C at at ftm itimp, tbm
braqlat tip to 100 We. It spin and
too, #Ave tu b~ taiLt. NW& CONAAM Saimly 41 1111MA healind to
80'. give 4.a% laid. bydrumbonAA, b.. 1201,
bamw b. 1100. the b. 122' was pw t In ItAsca. nV 1.4216. &W 48
app"Clal Colf"Ol bm
it;" Oxil Pa"W
Jon. %ydrWa4tional'the kelom in amWracld medium. latterandeby&a.
A
71
!3, MV
lvl~&) 0-;;- ai'.
6 -i -T-T-T--T-
U In AV to At a 419 All A it 2
0 0 0 0 0' *0' 0 0 0
-so 0 0 0 *1: too** 000000060 0060000

00
flan by 76 id. hydramirboa milt
R*

00
0
lim lw-
save do J WAMk "W. bj*awbms, witb that b.
*
nj
b
h
d
t
d
00

00
0
o
mm
est
.
l
pvd*wAaMWI the tOW 'a
y
1 to
" It GVAUW MOSM W" WAV Rt-
k
h

00
t
", qg te
$q
f th
u
h
so

e
o
m a
Imak"Ike 41 tin "NNW pmam's

go

Oe" MOB 49104b a w-owe wam pys the Pon In
Os

se
Ws" I'mroft

-
1103-10.81 felt
bm .10 01
T
00

00

,
L
~
AM

&

0.

00
an wipiwted am only by the plim
resp. lb4iff 1
Ila ;Id"'
-
R
b
0 0

-
ama sp
e
nde) but by l
PROP" G
mamedspoff
U
:

.
.
.

so

00

go

00

so

*0

100

00

go

00

go

go

00

Go

00

00

go

oo

go

00

00

*0
00

00

L

:

0
0
1

ooftooe**0000000 0000000000**00000,000*00*00

of P

1:

I. L i, j i

~Jdlvdvftfidon 4100110911114110 hYdFWAIba"
anilin Imtitils, At almor vfl,wols 0 it 4, wial

HY6020"11" at 1.
litill. 17 S a.. Ow litilt.. 1 1, 4 .1, 4wl
with Mt. -Ilm"i is Is
troli in -so TI ve. relill "All, 2AII, 4111.1 a.tNI 1. C.11"
III.. I~r,

has of tic it 3A
volume. u_A__K&"uouuu5 d
0
2&V
a
ioitA I to C
1t
of
t~
of conver

.
s
p.,
.
.
,
,
o
. =r
lasirss. Abed. Nootil. S.S.S.R.
Er"
KAI an, I
li
l W
HO)
968
r
r
th
&
of if
I

.
.
%v%
M
S.
t
rov.
rsp..
e
.
, c
.
4(4-11; cf. C.A, 42. 4&W.-Mitits. t4 cyclopentArm (1) 13M, and
11113 toil, 'hr.; the dvI;r" Ill delivilrtwenAliiOn 94

_

00 a

" cwtehellant (Ill in the onalar ruitt. 1:3. 1:1. 5:3. It wall
Vnd~r tho sanif "Vild,to-Ift. pure I

41110

3: 1. and 0: 1. all 11
hit b 3: 1 vivit
!COW* to the stivicloo. with rx~ Ill aAvr V.11,o 4.22 it hr ,
-vre-- 1;J
'

00

.
"Wine ratio X
fill's I Collis - U.1118 .4 Colls. tbv lot it* fl~ I nlliol..
jutsou'l In it Utt"'Ill ,I 1l.. K..v A 411

00 Z

.1 loollion 1.1
an ~kvk--. h4l the bill to & jetkAt 011 U. wetv f,/hr..
Lonvvirsion Al N111'. the mixts. 1 :1.
Allasiftl to lesict. witilout "priff Ivan
Tlix)
on plooliward C
314111
1~1 INO
,
:11) Ill
dl: I
v
rea
!1
3
1

00

,
.,
, 1
:
. An
.
.:
s.
,
.
"
l
C V Pt) at 276 anti 311111". In all mism, part of the I mi.
11frhr., (I m, I.xis, 2 sm, ati,j :tam a. VJI,, la . t~ut-

VIVAII ydrolog?"41vil Ito C.11'a by the III evoi%,ed In The
Jol- toproolon 37.11. 44.11. 41M.O. and 0.11",: &,~ -J Jehyd-

IN
ti-A 44 11; the amt. of Collis Itinoved per hr. ornalhort nI 11
neotiv 111111%. MI&I. 0: 1. tit it sirrain -4
0
itstivases with Intirsisw
vinat
of I in Sh
i
k
k

vir
.
ill
n
al.
uus lill per Celli, 0.114% II.Air., rimvir"hoti .1,
V Nor 1.
"M made in lutai 44 Ill into. diain. with 40 mi. catalpt in &
j,jMm of Ill, pvc., lot the oulat, Coll,, V.65 c./hr..
rvdaml In [is at tip to 3W*
tested in the hydrocautinin
01
l
OO
h
h
A
i
S
f
h
i
I

.
L
e runs w
t
rts..
CUVT Chil
ter t
e
m
33.
t
y
71p; a
of CiH# at 150% WIN ml./hy. for 5 hr*., then in tlw de-
C.V~lIu/hr.
4s.3%. 'Mis Indicates I hat. in the long run.

,
loydro"tion of 11 at 275% 3111-12 mi./hr. for 6 hors.. the
catAlyst suffee, polaming mith rvsnt to hydrlwoa-

lee

Ilits
flubed with pum No at the terfoop. of the Intended title ej I
x1jiteolh its O"livity with T~jw," to &h%Atv-

t2P1- 10 WVMlyr
tIMC" 1-4 If.; thAt orwh tracts artuatly jenation td it is
Fwv~rv-t. N, I h,m

remain vidsorbecl, was d"nonstrat"I by
Mnyftga of I

lato C.". in The vol-vi" of vitenoal tit. alwaing
0.3 a./-

hr. at )W'. 8 ml.~hr. Catalytiates (nun mixts. I + U
*
'

were tra"lonsited ilnt., h. M-40
anti >49
. In Ow lot

1111,01011. Collor W1114i 4IM411 hV tIW fTff4CtITT
111411rit IlkI tilt,

1
0

'U

o *1

0 0 0 a fa all 4) as 0 0 0 0 0 0 0 0
d

WP

11.6 a 0 0 0 411

a o o 0 0 Is 0
!a.

KAZANSKIYO B. A.
PA 66T24
MR/AcedoW of Salmoss Jon/Val) 1946
"Acadmiolan Aleksandr Itrulningelldoviob Arbuoy,"
D. A. razanskly, M. I. labaobnik, 6 pp
Olz Ak Nauk SMj Mel Ihim Naue No I
WItten in bonor of A. Ye. Arbuzov's 70th birthday,
with awmary of his solentiflo aotivities to date.
Inoludes details of his method of synthesis and
other experimental data.

B. A
A. V. Koperina and M. I. Batnev, Hydration of cyc1cpentane
hydrccarbons
B.
with splitting cf the cycle. XI. Tho hydraticn of stereolsomeric
cyclopentanos. P. 503.
During hydration of stereoinmeric
1,2.,3-trin-etbyl-eyelopr-.ntanes, there is observed a
transition of each re of them Into the mixture of atereoisomers
(always with a pro-
dom-Inanee of 10j 2 , 30-trimethyleyclopentane) and a partial
splitting of the five
numbered cycle with formation of 2,3,4-trinethylpentane.
Net. of Crganic Chemistry of the
Acad. of Sci. USSR
December 25, 1947
SO., Bulletin of the U.S.S.R. Academy of Sciences (Chemistry
Series)
Izvestia Akad. Nauk, S.S.S.R., No. 5, 1948.

ji B'~ A
I *D 11 U L) td 11 it If- Ik
L .1 14 11 IL a
00 A
00
00 A
so
PA
11 32 11 J4 a is IF is P III ti u a al.'s
CAWYtk Hydm=Om of Hidmearbom I ib. cy,j.
MV9.
(In Rus.
Man.) B. A. Kaju ImIj
(Progress
ChenistrY).-tk-17,- Nov.-Dec. 1 948. P. 641-662.
go
R"Ic"N "'Iflung forvin and URSR rt3plkreh data
COneerning the above. JWullgritirg of the proc to
:nd optimurn condition& are Indirs rd~ 1) uIrranIs
t
lid tables. 48 re(.
0 0 a
4%. 1 L A atTALLUKKAL UYINATURR CLASWIMIGN
mi;'ill ms ~v All
o.T as
r hdo fill 94 9 a 4 3 a v
u 0 a '0 u! I; It a am n 8 M dw
!0T64 0 0 0 0 0 a 0 0
lee
-00
-00
too
=0 0.
1:11110
coo
0
as
soo
Leo
bee

f I - - ----
-;Z~U=/Chaastry - 2hraff ins, Arcuatizatica
of Jul 48
Chemistry - AromatizatIon
"Cyclizationof Paraffin Hydrocarbons With a
Quaternam
Atom of Carbon and tha YAcbanism of the
Aromatization
of Paraffins on PlatIn-zed Carbons," Aead B.
A.
Kazanskly, A. L. Liberz=, M. 1. Batuyev, 3f
PP
"Dok Ak Nauk SSM" Vol LXI, No 1
Authors 1. previous experimenta
unsuccessful. Here the.7
describe cmccez-aft! arczatizatim of 3,
3-dimaUWlhaxane
at lower teeMeratures (2900 and 3000 instead
Of 3060
3460). 1,1-dixothylcyclohoxwo was present in
the
reaction -products, as wall as toluene and
metaxylme.
This shavs that the sequence of operations
is .
UM/Chamietry - Paraffins, Armatization of
Jul 48
(Contd)
paraffin -+ cyclohexane --) arcwatic.
SubmItted 3 May
19W.
-1W
I 8A9T9
i Ow

UM/Oheaiattry - Cyolopentrtne.
'H:Ydrogens- Say 48
tion of
Chemistry - Catalysts, Palladium
'*Me Hydrog,=aticn at' C7clopentane With
Nickel and
Paladium Acad B. A. Kazanskiy, T. F.
ZU11M07a, 1. pp
"Dok Ak Haut SSW' Vol LXII, No 1
Discusses &Ifferences in action of
platinized carbon
and nickel ns catalysts for hydrogenation,
based on
previously ~_-Ptablished data. Experiments
on bydro-
geration of cyclopentane over ninkel cm
kieselguhr
Acid over palladium, and on destructive
hydrogenation
35A9rll
USSR/Ohemist_ry - Cyclopentane, Rydrogerz-
Sep 48
tion of (Contd.)
of, ncrmal peentane over nickel on
kieseIguhr, led
autb~zrs to conclude that platinized
carbon. exerts a
specific action in the sense that hydrogen
is added
OWy to two neighboring carbon atoms,
whereupon
orpl-Itting ce-curs without any side
reactions. Sub-
mitted 6 zTol. 48.
C4-
35A9Tll'

MANSTY, B. A,, Acad
kA 36/49T13
USSR/CiIIISIRistrY - CYcIO"ntane, DerIvativeg sop 48
Chemistry - BIcycIo-(I.,2,2,)-I[eptane
"Structure of Bicyclo-(l,2,2)-Heptene," Acad B. A.
Kazanskiy, A. V. Koperina, M. I. Betuyev, 4 pp
"Dok Ak Nauk SSSR " Vol LUI, No
Discussion of experlment~il data on conversions U1
bicyclo-(1,2,2)-heptane, largely obtained in authors'!'
laboratory, points out that it should be considered
a cyclopentane derivative and not a cyclohexane
vith a methylene bridge connecting carbons 1 and 4.
submitted 6 Aug 48.
~A,

:. 1~ -1~.tlv-;..-,~",.z:l~:,."~.~,E~~Tr~I
KAZANSKIY B. A. and LANSBMG
.9 G. S.
"Complex Method of Ana3ping the Content of Different Gasolines, 11
Gostopte-khizdat., Moscow, 1949 .

A
so A
00
00
got
-3
I
13
2
* ~
so 0. It so
40 1006~LTZ-nl
4.", -el Zvi ~U-
iL
AW A Cc so A
"00

4

Calalytk by&vgmw*- at -1-.
1
41 and stollocill6ml. the Fl, milur Clatt4hil No- All'I --%)1.
fit.

Wok fin O"nins. X11, H
4
the fr4c

0MOUnc It, A. 1~4zan if. It. TemVeva, and
C7
-
I-
$1
K
k
l
S
k S
S
S
OW)
1
b. 114.11
'32 l
u
-69

iluey.
.
mr.
no
~
.
.
A
.
amo
.
.X..
-
itexlICIlEtt, In the fnwoms 1). 113'

Xhim. Nawk 1049, 017. cf.
C.A. 43, 1332b.-O) On
`
17.0% 2-1001171hephile was identified by RAmAn litics.

40 rill. 4 a !!%l
IV
, Pt im C catalyst, character 4 by an 99

12) The main roaction thus ctnoijits in a rupture of the .4,3.

-
Ilichl rA Colla Ill dthy4raptiation of cy0oloexam at 295
and
4.34lotods. To j lestmer estrur, twincl ~), I it broken.

00
arW
". %-,jocity o.2(), jvVmpyk-)TIopcvUne (1) + Ht.
and- t0 In MA
lesser ritent. bonds 1.2 and I.S.
The

-06

PASOVI at A 04MCr Velocity 'If 4) .06-0,21 at =5-. p,, A
,
Yield of armatk bydrucartirmiN dot. r.,-a
t
their formatilm
in Partivul
&I the 2:1 rilti~, t4
J

00
CS121y,,tte I.. I NJ? 1,4131-1.4150. by fractiljnA-
tion. ahnut of the CatAlysale b PAraffillS. the IT40 (At
.
,
on. du
li
It
Yt-r, And the l1tAr abwzm of PhMr. are diffi.-ult to v. *

met)
3.
bytInvarbous 2.0.
spacr velocity 0.00) is 11, W.2, sab
Wal". (3) The following is
a synth,%is E4 l giving Ltlrr
-
Id
h

At 3W1. sparv vckxity approx. 11.2. the
flo 0,3, No 1. 1 P'
t
t
&n n%
thotis Iiervicrululy d
vulit"'I' IT"'Illyl-
(100
1 di,,g,,
d i
l
A

5~bl I
c;=Atl te b. air 1.4105. and CMuunl 4
and the
I'l
zatell of the 2W
d c
tAl
bi
,
V~
9.
n an equa
. of V111 Ill I,
hydrogenat"t trader art inittAIjuxAgurr W 40-W un. m

CO a
u
l, com
ne
I
y
-3(1()- mail were fractionated into how., (3-5
the preseace of
Raney Nj (Ilr' cf the vit, c4 ful%-r

.00
1, an 1.4052. aniline
priint 61.4). 113.0-14.0' (4.9,
'
5
s
Ivroplmation is ttlaratedft-40 tial" Until no I. 11,is .1,
sco'bed, AZXI the sWil. washerf
stuken with c(med
lj
~y j

.0
-
I
(W.S. LOW. 119.1), 1 5.
4 r". 65.6). 114.0-IS.8
1
5' (4
441m
1
3
(IR
116
5
17
4
mg
0)
,
.
v
s,
washed avin. dritl. anddi-t& The %-kl,t is tial; if tjjv

a* C
-
.
,
1
.
.
.
.
.
1.
16.5
.
,
(5.2. 1.4!1k1, 62.0).

theory.
N. TtURI

oe

Bynitra-

,he*

I thee

ASS-14,11 '011FAMOGICAL LIMAIM CLASWKAIWO

10. 40

to 0

011460 541141100 .10 049 oft
0
.
NA&ASIC"ll i i iiw 1!
1 IVA"& I
rol 0
1 V
990:;1

0 9
11 9 AD 4 1
it a A
A, I
OTS so, : 00 00, a" 1* 000 0 0 0 0 41 0 0 0 99919 0 4 0 of
4011141111 000600 0 0 0~
009000 0 0 0 0910 00 00* *JLjA-v-qLA'P-O 0 00 00 0 00 0 000

ti
C W 11 b t %tl6n 4~j hydtoC&rhbnj of ~y:loptntaas
"A"Tr , v,3
T-,ny Kiffelik if i4xa
.11,:d. 01111-r.
'-doprntan.: ovcr rt-C cvcn at 290, ~lejds only plite u.
I'mmm. The appartnt entrgy of virlivatinn tf the re,wc-
Oni, u-, tntfl. Krijphically fmin the kint-tic data, 1, 33AX)
val./mOIC.. The fing vlfavag~ h appm-6ibie Cvc'i t!t 'DW.
1~1 awl Vr 11crim itt XW)jefil it Coinplex 1111"t. o1 vtodmts,
Wid ntily mn?[~. of n-alk.-mes are forintd. IMethxi-
r%-clopr-ntane rave-12% n-~exane. W"O -2-nirtlylventalle
band 221~,'Q .1-mvillOpentane in a maction run avir Pt-C at
3ky),; at 22CA', tfiIN Cleavage atrolintetj to mily 0%. I't-
Diwth)-IC~-ClOpentAnC g-.I,,e similarly 75% -P,2d;n7cth3l-
rniane, 257c 3,3-Jimcibylpentant and tracts of 2-indbyl-
Cune. Ira Fos- 1,2-Ditnet hyleyclopen tane sinfliarly gave
85% 2,3-dimethy nfinse, sme 3-methylpmtare, umt n-
liepta ne (total. 16191
~~Q)j Ira ni-1,3-dimethylcycloper tane gavt
a mtalyr-11te containing &5% paraffinic hYtimcartonq, com
of W111, ".4-dimethylbexmne. 2R7p 2-nmthj1h,-xnue
-1111d 2,1% 3-methy1hexane. The telative rates Df hvilro-
Senathist wrre fvnind to be-. cyclopentane I 1.5t nit thylcydo-
;ientanc 7. 1,1-diniellivicyclopeutane 7.5, 1,2dimethyl-
cyclopentalle 2, 1 .:Wilnethy1cyclopentant 1. G. N1.

"A Coowlex Method of Detailed Investigation of the Individual.
Composition of Gasoline"
(Kcnple-ksnyy Metod Detalisirovannogo Iseledovanira Individuallnogo
Sostava Benzinov)o
G. S. land:bergt B# 46 Uz&nqk1X,, P. A. Bazhulinj H. I., Batuyev,
A. L. Liberman,
A. S. Flat , and U. A. Taresova, odited by V. S. Fedorovp
Gostoptekhizdat, Moscow/
LeningrRd. 1949,. 68 pages, 3 rubles.
Subject nethod is based on spectral analysis.
SO% UsDekhi Khimii, Vol 18, A, 1949; Vol 19., #1, 1950 (W-10083)

A.--Aced PA 27/4M1
USSR/chemistry - cyclopentanes Fab 49
Chemistry - Synthesis
"Several Mono-Derivative Homologue of Cyclo-
pentane With a Branched Side Chain," Acad B. A.
Mzanskiy, F. N. Gakhanov, 4 pp
'Dok Ak Nauk SSSR" Vol. IXIV,.No 4
Describes method of obtaining, and characteristics
of two nev hydrooarbons of cyclopentane aeries:
2-methyl-3-cyclopentylbutane and 4-oyolopentyl-
heptane, synthesized from the corresponding fulve-
nee by catalytic hydrogenation. SubaLtted 9 Dec 48.
T 27/49T1I

USM/Cbemmistry. - Cyclobutam Apr 4.9
ChemIstry - Syntheels
"STnthesis of Hydrocarbons'of the Cyclobutane
Series," Acal B. A. Kazanskiy, M. Tu. TAkina,
4 13P
"Dok Ak Nauk SSO ' Vol LIV, Io 5
Synthesized 43-dimethYlcyclobutane and
I-methyl-
3-athYleyelobutane, ewh in form of two
stereol-
scmers. From by-products of their synthesis,
dl-
(3-methYlayclobutyll-~nethane vas obtained,
not
d-l-risible into stereoisomers. Describes
s7nthesis of these hydrocarbons and their
character
istics. 'hmt does not discuss zothod of
obtaining
'IM- 39/4m..-
USSR/Chemistry (Cont&) Ajr 49
them or characteristics of intermediate
1products.
sutmitte& 21 Feb 49.

KkZANSKlyt B.A.
Chemical. Abst. chmmatogtotphl" method of sepamoiino(hr
d,, n A It gA."Kjj'nisK~if,
Vol. 48 No. 6
1"W
(hapliva
Mor IC minalq.. Mad. N,,.4 S. Kbim.
- 25p 1954 Nauli` 195D. W-7l(Pub. 1952)~-A fletalled acenunt. is
General and Physical Chemistry LI~Nten of expti. v-pri. of
hydrucarbov ntixtg. on SiO, gel.
%it. 'if aromatics and unsutd. liptrocarbotm Irvin paraffins
is completely pnictirable. as Is the -,~pn. fn,ni
The inethod is pirtimiarly suitt4i for pri,11n. of pire sIA-ri-
inens of paraffin and w-iplillmne whichjine
completel-,- wpd. unt onlY froin tile olfrin frae-
ficuo, but also froul voutpds., M ridifv% N11 h. 00,16(tr%.
suid nles.

OzU&dm of 1-mathyltyclabousiont.
3yathes" W I
A. Xat."I, A. V.
A-minfitur *air Unly..
Orn, Client.) 20,
one with= a. It kd. 141tut, I I.O.And It
2 Z. N1 I.
!,,v %Jovr add.. uf lite ketme to lite
%4,,. at
kimal irt"In. pyr Kit' total iscids. A
anutl
1. 111 (041111. Atilt 14 I-Osaffil wki'.
lite
141tre 411013- its 78-5. allijulAit,
%visit 41 Ot 11114 ItAl"111. Uve
b)" YuJr Jismilitij I.I. IM 4b',
whil-ij, lintint with Me si
11AVI ewe") ana dbid. uver (CtSll)t to
Italmr, jAvr Pit ~
2 mixed olefine. yWdins cc o"Id
fructimmatioss In 1.4: 1.0
rutia .1,4-diwelk )eprwese bits 92.7".
111, 0.-7,15.
,=led :Y;cr Pt-C at W' to the Jamij.
1.4287 (rmdiiy I.
dt,tiv., tbw U0.0". %V 1.4(VG. till
0.7452). anti 1.:4imlefb,4
t in hilvalrat. tft 104 4 -A", Islit
1.4444, d:" 41-MU (sinsilaily
6y'drijewled to 0% dd-ul vail't. tj
ifdxl ~ 41 j'Offl. It 44 I'l.
dlivffsh~kjaloftmmmo. th't W.5 6.0".
Nit' 1410,1, 111*11.ViiIII).
A sinutair tvaction vrith 110,11tUr me,
utillin dchydrAti,le
v
distil. urctr Iodine, Larstily 1-wel
1.4 VIS. ill" 0. M 1. and a
iini~Allanit. at tic
LI-Isomirp. I'm 148 V, ar 1 441l1. d!-
It-RWQ; Imirosen
&IIIIIII t1f lite ItI118firt JAVC lint
147-7.8*, xj? 1.42U. d:- OM 15, bm
144.21- 01-4 .
(". Ill. K(-4Avwff

The oln"Don of i-mothylcyclobewarace. The synthesis
of 1-methyl-3-propylcYrJapentane. It. 1% K.kt4pi)kaj -A V,
K111wrina. anti 0. A. 7xindiorA. J. CiW. tlem. 17-6.R
20. 12,17-ttN l1l,**)XHnxl. twa%lAtion) --Soc C..J. 45,