SCIENTIFIC ABSTRACT BOGDANOVA, A.K. - BOGDANOVA, A.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000205910004-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 9, 2000
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

BOGDANOVA, A,K.
Distribution of Mediterraneai waters in the Rack Sea.
1 no,6:933-991 '61.
(~?eano2oKilia
(MRA 15.1)
1, Sevastopollskaya biolog
~icheskaya stantsiya imen! hovalevskogo.
(Black Sea--Hydrology)

KROPACHEV, L.N.; BOGDANOVA, A.K.
Significance of winds in the Black Sea in the proper organization
and operation of seaside resorts. Vop.kur., fizioter.i lech.fiz.
kul't. 27 no.2%159-162 Mr-AP t62. (KM 15:11)
1. Iz-gidrometeorologicheskoy observatorii Chernogo i Azovskogo
morey v Sevastopole.
(BLACK SEA--SE&SIDE RESORTS) (BLACK SEA--WINDS)

BOODAROVAI, A.K.
Charaateristics of the hydrological regimen of the Miditerranetn
Sea in warm winters of 1960-1961 and 1961-1962; based on observa-
tions from the E/S "Akademik Kovalevskii.It Trudy SBS 17:159-191
164. (MIRA 3.8:6)

BOGDANOVA, A.K.
~ -,
Role of the southern and northern thresholds in the water
exchange through the Bosporus. Okeanologiia 5 no.5:834-840
165. (MIRA 19:11)
1. Inatitut biologii yuzhnykh moray Ali Ukr%SSR.

_jC
I ACC k, AT - 0~
AUTHOR: Bogdanova, A. K
ORG: none
SOURCE CODE: UR/3090/66/0001015/0045/0068
TITLE: Hydrological characteristics of the Red Sea and the Gulf of Aden according
to the observations of the expedition ship .'Acadentician KovaZe'vskiy
SOURCE: AN SSSR. Mezhduvedomstvennyy geofizicheakiy komitet. X razdel prograu-.ny
MCC: Okeanologiya. Sbornik statey, no. 15, 1966. Okeanologicheskiye iseledovaniya,
45-68
0 M9 A) PftPF 12 ?'L/, e !F,'5 F 4 *C V YI/ tSAII /t>
TOPIC TAGS: hydrographic survey, 1~_=ugt `iiig marine meteorology,
xnanstana=* 0 C e'q A~) 0 v k) A 1-n I e S / ;V-,Co 01 ozia 0'~ A) 0'F ) 1 \.5 0 r_-_
ABSTRACT. This abstract describes the hydrological characteristics of the Red Sea,
the Gulf of Suez, the Suez Canal, Bab-el-Mandeb, and the Gulf of Aden. The observa-
tions were conducted by the r/v Acadeprik A. Kovalevskiy from December 1961 through
January 1962 and from October through November 1963. The track of the r/v Aka&nlik
A. Kovalevskiy expedition is indicated on a chart. Several diagrams of the tempera-
ture and salinity distribution, T-S curves, and current velocity are given for the
Red Sea and the Gulf of Aden., This paper analyzes the influence of the exchange of
water through the Bab-el-Mandeb and describes the formation of hydrological conditions
of the Red Sea and those of the intermediate layer of high salinity waters in tht-_ Culf
of Aden. The waters of the Gulf of Aden enter the surface horizons and the inter-
Card 1/2 UDC: none

AT7003619
mediate layers (90-100 m to 300-400 m) of the Red Sea resulting in a richer sea
life at these depths. The author defines the influence of monsoons and the effect
of the "piling-up" and "upwelling" circulation in the regions of the Strait of
Bab-el-Mandeb and the northern part of the Red Sea upon the exchange of water through
the Canal and the Gulf of Suez. An analysis is given of the formation conditions of
steady areas of upwelling and the enrichment of the upper layers with nutrients i-a
the Gulf of Aden. In the summer these areas include the northwest coast of the gulf
near Aden, and in winter, the area of Cape Guardafui in the southeast. Tbe author
examines the distribution of Red Sea waters in the Gulf of Aden based on temperature,
pressure, and salinity data: the distribution characteristics of the Red Sea-
waters vary according to temperature, salinity, and rate of motion and mixing with
waters of the intermediate layer of the Gulf of Aden. The article investigates the
the mechanism of formation of the Red Sea water masses and estimates the values of
the salinity-water balance. in this formation. Discharge rate computations vere
made of the upper and lower currents in the Strait of Bab-el-Mandeb using the salinity
balance equation and data on the salinity of the deep waters of the Red Sea for
1958, 1959, and 1960. Orig. art. has:, 9 figures and 3,tables. (BA)
SUB CODE: 081 SUBM DATE,. none/ ORIG REFt
008/ OTH REP; Oll/
carO

BWDAVOVA, A.X. I ilntb.
Peculiarities of butt velded joints of pipes from l2XhHF porlits
steel. Xnarg. stroi. no.1:96-101 '59- (HIRA 13z2)
1,Hoskovskiy filial institut "Orgenergostroy"
(Pipe, Steel--Welding)

5/137/6 1/10W/O 12/093/149
A006/A101
AMORL Bogdanova,'A:'.K'.
TVM;I~' ouliarities of wilding 12XMO (12KhMP) perlite steel pipe butts
PERIODICAVi Referativnyy zhurnal'. Metallurgiya , n6' 12, 1961, 11, abstract
12E64 (v ab.-"Energ. str-ve', I (II), ioscow-LeningrAd, 1959,
96 - loi)
TUT3 Information is given on resul~,s obtained in welding perlite 12KhMP
steel pipe butts with the aid of '911 z 14 (TsL-14) and UA -20 BY (.TsL-20BU) elec-
trodes on a-c and Aj(_2oA (TaI,20A) electrodes -on d-c. The following conclusions
are drawn: 1. To prevent marteftsite and crack formation, preheating for pipe
welding can only'be recommended at'sub-zero temperatures of the surrounding atmo-
S.Rhere. 2. When welding*steam-iuperheater pipes with TaL--20A electrodes of 3 mm
in diameter, cracks are formed in the weld joint. Therefore these electrodba can
be recommended only after their improvement. 3. Weld Joints of steam-super-
heater gipes must be heat-treated under the following con&itionst heating to
970-980 C; holding at these'temoratures for 1.5 - 2 mfh. per I mm of pipe wall,
with subsequent cooling in asbertos packingg. 4. The welding of steam-conduct-
Card 1/2

Peculiarities of welding ...
S/137/61/000/012/09.3/149
A006/A101
ing pipes with 5400C wall temperature must be carried out with TsI-20 electrodes
on d-c with heating prior to and during welding At 250 - 3000C. Welding is per-
formed under-optimum conditions, with a short aro, small beads with jointscovered
over 25 - 30 mm, in partioular,in the flow portion of the butt. 5. TsI?_20BU '
electrodes produce pores in overhead position of the joint; therefore the use
of these electrodes In only permissible after their improvement. 6. Consider-
ing the fatigue strength of weld jo:Lnt3 produced with TsL_14 electrodes, the
latter can be recommended for the'butt-weldlng of 12MM steel beam-superheater
pipes with'5400C wall tdmperature, and steam conducting pipes woth 5100C wall
temperature. Heat treatment conditions of welded pipe Joints after welding are
given.
V. Tarisova
[Abstracter's notet Complete translation]
Card 2/2

VIKOIAYEVA,, Ye.A.;._R STEPANOVA, Z.A.
Microbiological purity of solutions for injections and eye
drops. Apt. delo 14 no.1:64-68 Ja-F 165. (MIRA 18:10)

GRINFELID., A.A.; NAU01AYEVA, V.L.; BOGDANOVA, A.,P.; ANGELI, P,N.;
GOLIDENHERG, V.A.
Study of sources and vays of the diatribution of opidomic
hepatitis (Botkinla diasasO. Report No.13 Erlemonalit-,- im!
periodicity of the occurrence of epAdemie hej)aMin (litr1ri *-
11 years (1953-1963) in 'various age groups of 11- ,,, 1. - t,~an
of Odessa. Zhur.mikrobiol.,~6pid. i imun. 42 no~12i29-3'
D 165, (KRA lggl)
1. Odesakiy institut epidemiologii i mikrobiologii Imeni
Machnikova i Odesskays, gorodskaya i Primorskogo ravona Odessy
sanitarno-spidemiologicheskaya stantsiya.

Candl Med So i
BOGDANOVAl A. S.
Diasertation; "Two-Stage Vaccine Therapy of Brucellosia."
2/2/50
AcadwW Hed Sci USSR
SO Vecbetyaya moskva
Sum 71

BOODANOVA, A. S.
Undulant Fever
Brucellosis. Med. sestra noe 4. 1952.
.Monthly Lidt 2f Russian Accessionst Library of Congress November 1952. UNCLASSIFIED.

WSR/Medicine Infectious Diseases Aug 52
"Brucellosio," A. S. Bogdanova, Moscow
"Ned Sestra" No 8, pp 13-18
Research in continuing on the pcesible use of anti-
biotics in treatment of brucellosis. Fen..zillln
has proved ineffective, promising bu-t conr,~sing
results have been attained with aureo:aycin and
chloromycetin. Vaccinotherapy has retained its
leading position in combating brucellosis. A new
and effective method is the 2-stage intraveneous
injection of the vaccine. The new method allows
injections of reduced doses of vaccine, i.e.y
100,000 - 300,000, - 500,000 of killed bacterial
221T32-
bodies. Such old and triel methods as roentgeno-
therapy, physiotherapy, and hydrotherapy also have
been retained. Transfusions of blood as well as
of dry plasma and erythrocyte mass, injections of
vitamins, glucose, etc., are also indicated in the
treatment of brucellosis. Soviet scientists
(school of P. F. Zdrodovskiy) within the past fev
years perfected a method of prophylactic f-muniza-
tion of human beings. Observations of this method
over a period of years demonstrated the vaccine L to
be vell tolerated by the patients, and ~!ffective
irt the prevention of brucellosis. It is now being
videly used when app:copriste indi-
cations exist.
22IT12
to

ROGDANOVA, A. S., (Cand. Mod. Sai and RUDNEVO G. 1',, (Prof.)
"Levomycetin in Typhoid Fever Therapy," pa-,es 72-90 of the book UTreatment
of Infectious Diseases," Moscow, 1953
Presented 6 Marbh 1953 (Moscow) at the All-Union Conference on the Control
of Dysentery dponsored by the Ministry of Public Health SSM.
Translation No. 474, 19 Oct 1955

BWDAMOVA, I.S., kandidat mediteinskikh nauk
Dysentery and aseariasis. Sov.zed. 20 no.12:37-41 D 156. (MIBA 10:1)
1. Iz,kafad,ry infektsioWkh boleznay TSentrallnogo instituta
usoverehenetvovaniya vrachey.(zav. - prof. G..P.Radnev) na baze
K6ek6vskoy goroidskoy klinichesko~-ordena Lenina bolinitsy imeni
B.P.Botkina (glavnyy vrach. prof. A.N.Shabanov)
(DTSNfl,xXRT$ atiol. and patbogen.
asca-rias In, mutual aggravation)
(ASURUSIS, compl.
dysentery, mutual aggravation)
Y. 1~ CAI 6 4. P-L

BOGDLNOVA A,Se
Problem of complications in rabies vacoination. Scv.med. 23 no.12:
117-123 D '59. (MIRA 13:4)
1, Is kafedry infettelonufth bolezuey (savedrquahchty - prof. G.P.
Radnev) TSentrallnogo instituta usovershoustvovaniya vrachey (direk-
tor N.D. loyrigina) i Moskovskoy gorodelcoy ordena Lenins. klinicheskoy
bolluitsy imeni S*P. Botk1w (glavWy vrach - prof. A.N. Shabanov).
(VACCINATION compl.)
WBIRS prey. & control)

BOOMOVAI A.S.4 kand.med.nauk
Differential,diagnosis and compound treatment of chronic dystentery
aggravated by lambliasis., Lech. infekta. boll. no.3s3-U-3-19'57.--,
(MlRk 14:5)
(DYSENTFM) (GIARDIASIS)

AWOYAp A.S.., kand.med.nauk
Side effects of synthomy-pin in the treatment of typhoid fever.
Loch. infekta., boll. no.31156-165 157. (MIRA 14:5)
(CHWROMYGBtIN) '(THPHOID FEVER)

BOGDANGVA, A.S., kand.med.nauk
Biamycin in the treatment and prevention of complications in the
urinary organs of patients vith typhoid and p&ratyphoid iftfeotions,
Lech. Infekto. boll. no.l+-.105-113 k6O. (MIRA 14:5)
(AUREOMYCIN) (URINARY ORGANS-DISFASES)
(TYPHOID FIN ) (PARATYPHOID'FEM)

BOG-DANOVA, A.T., insh.
Spanning of the Irtyah River using a "pioneer" method. Energ.
otroi. no.42239-41 .164o (MIRA 18:3)

1. BOGDANOVA, A. .; VARTANYAN, A. B.; PROKOPIYEVA, L. N.
2. USSR (600)
4. Cotton Spinning
7. Using cotton waste in spinning.
Tekst. prom 12 no. 10, 1952
9. MonthIj List of Russian Accessions, Library of Congress, JanuarY .1953. Unclassified.

BOGDANOVA, A. V.
"Synthese de Ilheliotropine on partant da pyrocatechine.w Soriguine, A. A.,
Simanovskajas et Bogdanova, As Ve (P. 980)
SO: idurzal of Geaeral Qemii3tr-v (Zhurnal Obahchei Xhimii) 1938, Vol. 8, No. 11

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BOGDOOVA, A. V.
USSR/Chemistry - Ethers
Chemistry - Halogen compounds
Mar 190
"Investigation of the Properties and Conversions of Alpha-Halotc,-en Dialkyl
Ethers," I.I. F. Shostakovskiy, A. V. Bogdanova, 10 pp
112%.ur Obshch Mixill Vol XVII, No 3 A
ExpUnation of a series of reactions of alphachloro-dialkyl-ethers, as in
their aesociation with Mr, organic acids and alcohols.
PA 15T88 -

Bogdanovii, A. V.
Caud Ch~!m Sci
T
Dissertation: "Smthesis 2nd Trannfor,,ations of the i'rodu7ts of
gonation of Villyl i~thers.ll
10 IMarch 49
Inst of Organic Chcnilstry, Acad Sci USSA
So Vecheryaya Moskva
Sum 71

salkyl ethem NL F. shmalamNU mail A~ V.
iAt-A,l 14-t. tw,(-- lkaJ. A-It
~~ N 'N N . 014d. Ahim Ximsk 1050. L11-41. -t~tss. Of too x
IIU0II with licl .I I -S'. midn. of AI 1. JXQY,-%Y1Ik1h)k-S.,
,.last LN, ig~ N'sW., ;md V.111walshell JUMASe 01 xms~
X.00147, is.. M W. NV I.tAuk. 4:141.101-h; tile Im%IWI.
liks-odwsr RmIIA:l AnAk4sk, van lie itsisr"I itith-fillitcly And I~
Illmlmlylrd. Ykisitill CIIA1 (drul. lay Ilwilt'.11.
,0191Y in AsrII -I Note vultw: it cast fair titt-stiml with NA III to
Kivy tht, Clmisirsit Arkal AgNth jitilatiosit a)-* coal 14- saiwil,
with W116TY14111614VIN AtV ~Wbll! tit 01111MM tit
jusk tat \IvCllClt)X. IvAting ots a aaart Wilt lit fir, -
tit Ruoff rvmldy )-iriti., I PtiOWIlt. Addis. %if I' ..'a a
ICIWBU it .',* t 1- 3 N, S J~11411 in .11, sill VIA) .11141
~
Suriltj is lit%. K;I%.k "A 6. XICI. whilat-di 'tia...f
Ilie .411~ gave 8.5 a livitetLil. is, W 17x*, -14WIS xmv mt
4J4m0('11,)IS.IhIIkS-0'. "%' " 1-41441. '
d.- - OAM3, % Wit sivir, wi itamol. I. with llgcl,. 01hrl
pt,xisacts fons-1 hiclutivil (11*0),C)TI, lit K3-4'. all I Alkkl.
J.* OXIM, Ilk. 2,10 :hl,. mul it Imullia-1.
14 157-8'. xj,' LWltl, it'.* which wist, mit kiristais,&
lirmisis liu(MICl to *.144) 10* Astiev. (nMISM.., a "hat. Lit
it
G. N1. Ko-)Ltpoff

CA
ISYNIIIIII-eiltill ~net filactions tit -t-holoothVI alkyl *%art.
Ill. I.111mitiorthy, Alkyl othiefts, fil, P. mskillakilvilkil NOW
A V 1&,,Ipiiwv4 (A.--I. S,+ V.S.S.R.. lettleterim). Zkur.
L- .film. A I Cwti. Chrm.) ;0. 13lb-25(19W), cf,
.A. 42, 4510J "IrCIMOR arr mnm rracti-fv
hein tile Cl I"Vml- -I a hTwm.II)orm-
ivr rff~t Ito else, hie jj,mp aml =,#.I b--ni"gol thr
tit It.% to IT'lli-i"t ..t le 6016416.1 The
1-4 It I't l1w.'slie 1-1 l1k.11. 1.1 olil. jmjels. he *n
Ativinpi W 1::,, villyiderin., was show"
10 fw 'lliew --Ilwts with sq. alkali (N4011)
y*14 AM and Roll at a rule
'N-m1mrshk to that of nro-
%litir MiNFI, wavc 11117VIAlle, 14fvCII(0R)I.
imigingthlif fl,ml the UJI.Atk ley llw A111111r.1114 oil The fiber
411. whih ",ill, it. 111111. Irlerts With the,
t" isiltal title I, %kW-I: It" Olh-'i d~VIAI'. X)I, MAC-10 VVrij
V.111h. t1w NA waction confinju tht ionic
plate of the, tit ter T"'Iduix acvtal&, as aboyr. butt-ad of
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JIl at 0i
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6; 1 1110 1'- 1 '-.1iml. Cite. -
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1-vii"clitiroFt. 1,., 4-1 ,, ";,, viiivs. I:, i2mi. ciit.--
C 110%jr. h,.. ,j I :J-.30. J: V 7723. rAvr Me---
At,0114,i III,. I,_ 'A A -, It'. -V 1 4 MO. -W
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mrisl iihmj NAIISA), rov, v--fitiAjIv i1twil -it"". MAcif
(Womorw ilcm.). A.I.In. 111 26 g. N1,C1111rollu t,, 21 4
IIINNI-11 tit V ruvr !k1`;. liesOll as .I.
vrnt Are Or %1:11VIII milt, "fill%- 1%1%~ljv- or dry \11# int-,
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it, is,
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('11011u. Addis. tit MX111401`1 to I&AW. 1-4011-N.011
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wability tieing Orritter in hisher hornalliss: all are effective -
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111%, Pro inselcus, Which laterviI.Wit tile v.,Valrul full, %oh If#..
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I =% 111, 1.1150. and UrC11,11rollh 015.417.11, N 8'-41 .
,,I,, I MIX).1116 LN40, SlialLiax MrCl ICIOM 45 min. wit It
to :.I N Nall.10, ilayr 4 qu,,,ut. sunt, it( Act[; titratiom -till
11 1 N NA011 at.. CAVV J* tclumml lit C1. At illd 1114-
iliolluird dou. A subs. tit Ote effort it, Ituoil late if ji,fly.
turric V"uct (Viselioust ml slum), slid lit) flue rrakthm Sri.
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a N lltm.; EtOlf-ROll at So MAIM)' XAVV SK", MVC11-
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Kt)It-lIu(1l1jMvv VrCjj(()PA)01lmju moltl.4,1Cn.
.1,11 (IJIM143. licating tIm irther with AtOll qavv 11CIand a
Sell Itutyliter; Ito reaction occurril with N.,(fAc fit Ff,t),'
I "till Iltist 4*- JICI had 41,14-flect at '-NI*. While MIN'l-:11
x.,vo, Cil'XI10141, mot"Ine 1,11011, Still Ill-01(0114, Is't
14t, 8% OV 1.6w. d,- ViNOK ..G. M.

el A
ScomrINIM of . Issio others. 1. .4141001hyl alkyl
1. P. Shoslallovskil mitil A, V. 110#144110-4-
lismo. c"llir) Oita, I J. (*sell, Cbrov.) It, MIN W(IM!1 -
Contrary to runrot islews, a4mlorthyl alkyl ttficilt Io* 1'1X
only in contact with stilt. moisture or with cxrm of IW)
The decompti. Induced by JISO praimbly first yields i1x,
Roll. and 04yrillyi firsiswus Ptadmit. *tnI the forn"tion of
RX is a sevonlmy, msction of J1IX with the Roll, V,-
CiII91#011%. be 63.411-31t'. %V 1.44MI. 4:* 1-14vtl (flat a,),
was -gnktually d6td, thioughi a 25-cin. cstutust. vt~1,14"a
07.1% Built, 15 g. IItO. anti tramsof AcIf. I-ellittIN)II.
ether stand 3 weeks In a staled tube In difluml light g-sve
110.3% DuOr anti II$0 upon dislit. &1 150 nins. ShnilAt
treatillent of the ether 30A 1.) inized with 13 g. ClI,:CII-
C111"r 14ve 108.7% Built. 2. a. 114). and 907v unchomite.1
CII,:CJ CIlitir. as well as it little thak trislo and tno~ of
Aell. Now clbtn. of AlrO111,0V ilinill4dr x4vt W76
HIM and 11,C), along wish AOL MtCHBPOMP. the
7.0", %V 1.440, dj* 1.4233. kept 3 weeks In 4ifloW light
III a OtAled tube gave Idellf liviltate sold NftCII(O.%fr)j.
well ass little rcala(C M.S. If 0,97pland an oil-
statett mont. of Dr. It. HaloothP
.. Mal othafs. lind,
394-6-Keetsing 10 g. MeCII11POI 4, to'. uIr
d'0 1.31WO. 7 days In a sestled tube In diffused light yicl,lcd a
;16k Porous solid which mptured The veml; trIsetilion In N
still. gave the Saint Material which is partly Oct. in m"CO;
the losol, purtim analyses at Cull"CN, aplutcolly a PAWA,q.
aljei*f rrsix; Ili* sol. portitio ItAil a tilutilAr ounlin. It the
ether is allowed to stand In itsolst sit 0 vinlilm I'loluct forlus
rapk.%(3t) mitt.), along with a little fret PhOll. Asoln.ol
the e er In Oll,010flu and illosalle slowly (2 days) de-
posits armiall montit, of solki, the killer contains fir. while the
win. =10.11t and 11.0. Slow disin. of MeClIC101%
ICI. Pholl. and an "n.

Hydrolysis of vinyl ph@ ther %I F q1-takovskil
itild A. V. 1109414110VA. 711.0, xk,,,s~ (J.
of 114001:01.. 1-
145 4;*. dll 0.9767. %flh 11.,m), fit wAlol
,sit[" at 1110'. followed by drin. ul the Acif 1,miuml, I,
miboantially complete In 2 lim.; 1% llt'W), Isi 2 lirs. givi,
N4-b% hydrolysitt. The rruction prum"Is by forinatloa f
all monium Complex by Isrotonatioll of 0. followill by AM11111.
of 11011. with ditifilacrinctit t-f Ow proton .110 .-I"mcilmit
VIV:%VAtr of the hemiacetuil 16 Ad I mid R(111. C.. NI. K.
(c, q(A

1800, Tranoloo am leas Oact) lenUrbs ami alpha
0141hyloilrono in ohs proff"o *I hydrogon pareame.
It 1'. d%gl 41.11 A. %. 1141f ,
J,.fklgj. 11fal, 34. ('Atw. Of
1!04, 44, 1 al. ~140
all-iffit% .I 11W
,I I.V411.1LI-ft Ier"I'Mc, vitei a 14', 1y lw-lwt
j"Idy .4uhle all 1-colicriew4d mclont. A4,1-4%omi
-1111 W1 CUV" 44 -I)Irfle 11441 htW IMA"'IdAt OCIght.
Othef t,10" ISO the Of the
mwomicts site irlxmml. WHIM2212

ep
-1-4
0' j;
- 'f '%
Th-P..f.v7p, d.. M, 24.
, th. " f h~d I
. 1".. *90 1 - - t~41 Co-.
.I nz .. t. 46 i. it.
~;" I-AlArA

NOVA;
Btiio 1*nc-Rale, At. F.-Shmmkovkil;
vy Afad. A uk 4 j-, AA,
2, 15-8(19,52); cf. C~I. 42. 4519d; 43, 3795i.-Three
methods are ile-wribed. To 100 g. Bu0CH:CI1, %ras added
"ith stirring at toont temp. 60 g. AcOH, after which the
mixt. was kept 4-5 lirs. at GO* and allowed to stand over-
ught; cliqtn. in dry N itin. gave DI %-1[eC11(0l3jj)02Ic. (1).
To I I K. AcOll wr'- ridded dropivNe M g.
MrOiCIODu tat Mow 20% ofter AvItlelt the mixt. wa-1
1,(i1r.-q12_ljj~.;jt.')11 V -I fill allmve'l (1) strind ovrt night; disill
gave 23 g. crude pmduct, Jjj4 67-70". which was washed 3
tinle-1 %.~jtll NAIM and dikd: ditAn. gave 851"'t, 1, h46
67-8'. To 13 g, AcOCIIX11, and 160 R. 111soll 0.41 g.
10,0, lva~, Ildfic"t .1;A tile 1,011logencents -,oln. wwi kept In
30 flavq at 20, (111-atifir yields resin). I)i,;tn.
gavc,lfll/p 1. N!, 52-1.5%,111d I g. polyvinyl ftentle. Pure I.
1), h 1.5- tA*, b, A7 -9', On 0.9 1 S!, n It 1.40-10. Similarly
were ptepd.: .137%, F10CHMeClAc (from MOCUTIrMe and
KaWv in dionaitO or M.11% from AKICII:Clit and Moll
wit 11 I;7.,Q,-, 1 he produrt, It. I hot -IS- 80', d:o 0.9 14"
.1 1_31)30: 'WCPAIroilc (front ArOCIIXII, aid
11,55', d% 0.112 LIPSO. iw.
Ijn0ClHt,0,I(: ~rrmn A,-0CII,CII, rind iso-AtnOll with
ATF
14-IS

IU&j)ANOVfi' O.V.
r-4,nNn V149 and A. V.
B
%r- ";'I- - - ' "00
1 b~-Tg;875'97~ l-75-l-.b3,RtOJihndded.t
&-7* slowly 23.6 C. hIeCHCIOPh. After stirring 2 hrs.
longer and allowing the mixt, to stand overnight, it was
filtered and the filtrate di-.td. vielding 87% AfrCjj(OIU)OPh.

A. V.
Analytical Abst.
Volt I No. 2
Feb. 1954
Orgwr4o Analysis
3011. Methods of mmlysii O'-f
L AnjYSIS of a-halogen-dWkyl sod a Y
'-d
others. BI F It v and If
Y. A Plat, Chem.,
( ninunds of the type HCHIC whom
w
IC
I't - I or CIII.. X - Cl or 11r. and R' ~*Alkyl or
nd Alkyl or
Aryt are hydrolyied instantaneously at "m temp.
ternp.
y
to IICII,cllo, IIX avul R'011 by emm cif water,
Iwater.
))%,tmt on of the compoonds can be based on tests
be on tftt'
for aldthyde, halide, or acid. They can be deter.
I-y I
be d' --
unined by hydrolysis followed by titration withl
'y titmtio
'n th
(I-Ix V~011, titration with O-IN AgNO. 0
~1' Ag
h 0.
fitration of the aldchyde with Nsulphite.
'te
.1p
h h A
number of different compounds, were deterrrilril
~e rn~,e
in W3 11"11. with excellfI)t mults, G. 5, smjiw.

as aft 1111COCADIS a als.: I. -.:iYMWasA" trans-
F- btkrbr'KbM1;M1
Sukle Ve LVA11g, 217 X. Q% 16" , in and
IlkfA I If "alcif that Metid is - but, vo*,
tier 1. fillt L-1 given) there W91-11 pa,4"I. a 5 OP
11, It prIe"Ure at CSIfj Ilf 13_15 atilt. was "i ed Wild'
I.. "I -- I "fl, rotaflou I hr, to 91-105% aftcr
II. of Illorle Wit IttAithip; K-as rtimutd IM, 3 bmi W[Wi
~ttmptlcu 61 43A. L Cills. The re0juaVo
lit Irtated with Iona ,An and tljc~h-ncttou
Led lit the iuunc app.' Th-- filimte after i
e 80.8% 1.44lidynedidA w. 55- 7$ in erlld~ !t-t-wldli,
his pve W.K. (08.3%) = 1 -21% hill
anfroduct (I" Un 151
-81, m. 57-8 . To 43 S. an 50 g. Aloxam waA edited
ro micil. 1IC1 folluwed by-addii. &er 3 lurs. *175
n
UIXIlt-at 3042"; after 2.5 hm- at-4&4;0-, the milt.
trentWith dry KIM, fillesed-and distd. yieldint
Xj)~ib. 120-
88
bM254W (Aught tkoompall.01" 1-4400,40.9749. A
1910 Vield Is obtained when 43 g. ?lend 75 jt~ UtOCH-CHt
heated in autoclave without catalyst 9 Itt's. at 88-900;
.bo.&12R-9',xV).4400,cl*O.riti2.
.041U.1crIby-products scmane
OArly. .13 g. I and 87 j,LRtOCjj-
.CH. 41jer 1.5 lit
R4. F,~uvo 69.1% FJOCUMIOCHICIC014M, Ilp ]'4-
',' it" 1,4650. do 1.019A. Reaction of 4 j. I its Jdj N.
ftlll~ %, lik 110 S. atkOCILCH in the Intsi'lo of I dmjl
t (a% above) gave 14 g. Malosu~ and 6% (11140C11- -
9CIi ,~ I *:),. h, IW3". ag 1,4445i do 0.9353; il tho r"cl:'.
I i5 run ivithout catat"t in autoclave (as:aboye, for PA -
100.8.5 Iwo. at.wflol. then Is farmed:"Me.nuo
Mi(O)JOr. A724% abarc di-So deriv. bit 151 M
M, du 0-9M. and i my small test. C1 I OUOCH
VICA POU (10 be 121-2*, ng 1.4571% (6 0.
Ni-INO gave MtC"1WW)I am 38% 11, bt IW7 NY
I GJ7*0. Wbesi the aboore ethen frem shaken
s 2 HIS% and e"A vd. cd H10 In the lVeseactof ez-
~02 WIJISO~ ~or 15 win. asA let stAnd.15 win., back?
stioa of untmed N&HSD, ap"Od for esta. cif tk extent of
Volysio. Ill as cams this W42 tsoratay quint., Hy-
genslion of tim &%a r am Pt(h ft BuOH and
Viene It. JW76- 1 1 3W. Uimm
n. m. rmllllpnf~.

_TJ

i t t

J :z_ Q_
ard
T~Iyl ar
l
U RadItill p
y
1
l ~
f vtl
y
~7
7T -~O
8:!tjjvj.
jj
r,
V.
SY,

-
L
T

v -.77
~
pl
lm

;L

=WChWd6tr7 Syntbox"
Card t IA Pab, W - 15/27
Autboars Shostakovskiy,, M. FO 0 ~aod Bogdanova' A. V.
Title Investigation of acetylene alcohols and glycols. Part 3,- Multistags~
synthesis of acetale of -acetylene glycols
Isve AN SM, Otd,:kbim, nauk 4. 677 682$ July - August 3.954
Abstawt i-Experimental "tk'are -presented showing the maltiatage ajohani3m of the
formation of dlaostale of acetylene glycols. The two basic methods
catalytic and thermal - by which multistage synthesis of diacet-als i;
reaUxed, axe described, Symnstrization which intensities with the
increase of molecular.weighte of the radfoale of the basic vifiA others,
waa observed during the. derivation of mixed diacetals from hoiologoas
monoaoetals. It was estabUshed that symmetrical diacetal is a product
of vubstitution-of the low-molecular alkoxy group by a high-molecular
12 USSRj 3 Frewh; 1 USA and 1 Oerman
'group. Seventeen rehronaos;
.
(1912 - 1954). a Tableas
Inetitation
The N. D. Zelinskiy Institute of organic Chemistry
I Made of.Soe -USSi
Ikbuitted s.Sept~er 21 1~5)

1MVCbemistry Or&wic chamiptry
cud 1/1 Pub 22 23/50
Authon s Shostakovskiy, M9 -and- Bogdanovas A* V,
Title. Study of vinyl aryl others. Reaction of vinylphonyl other with dibuty~
Metal
lPeriodical e
Dbk. - AN, 100/19 89-920 Tan it 1955
Abbtib&Ot Investigations were conducted to determine the reactivity of vinyl aryl
others during contact with compounds containing active hydrogen. Results
Indicate that vinylphonyl ether will react with dialkyl acetals leading
to the formation of alkoxyphenoxyalkanes with a carbon chain of various
length. A study of phonoxydibutoxybutane hydrolysis products and lol.3-
tributoxybutano~and,but:~lphenyI acetal formed during th-4 basic synthesis
led to a conclusion that this reaction.is also followed by the separation
of the alkojW-acetal group. Seven references: 5 USSR and 2 USA (1949-
1954)-
Institution Acad.'of So*, USSR., The No Do Zolinskiy InBtitute-of Organic Chemistry
Presented by i Academician I. No Nizarov. lune 24, 1954

:3-

.,.JITT9~7, 330-44; d. C-1. W, 7-M-U.-Addn.
17-18 atm, to an autcelave conta. IN) Z. 2-Cl,11701.1, 30 rill.
HA and 113.3 9. T%Dwd. KOH ~--t 18)-S* 91-e -13% 2-ClsH,
OCIPCIII; hs -114% N 14-j*, ril.,34' (rururmnlrfl, nj,9
I.C!-72, JD -3143 hyrjrolyztd m-napIctt-ly wi Iwal
Ing wilh 21,7,) IIrSOj on a sltnm h-Cl, Pan.-igr of d? y I I VI
at -7* into tbC CIhCr g-.-IV-- ill 5 irrs, P11.3"O 2-Cr.)I,OLJI-
CIIIIII!, a powilu. decomp. ~hkl. fuuo,~q ir. air;
tl,,i-- bcab-d irl vnrllo to W und:-i N gnvu 9W"' ii
11:4
2-C,HjIC)CIiClMc (5 n~) ill
llt,o was Irmted vVith 6 g. 2-cs-.11) and treated vrith
ng
xtrean, of dry NiL, yie3jillgailty stamb.
trr ITI
-i;-jihu rc;%,tion ill B,.aOjj rave 7.%--Jc~ ahor~ T,Y,;,o -C
'

,;,OCTIC[Nfe to
: Me. -
6~~o (BuO CIIJ Addn~ of 15 r. - C,~
EtOlNu 1,7.9. NIa in 13*.(.)H gave 215% durcr, m I ~,C
nith that de~trlhi'd above and 47.5`~, P-;Mn
ITV. idapUc-d with the abaye, along with NfeCF-
Adding 10 g
CH3 sTid 5S V, PhOR in Ciffs asid heatinK 5 firs. at 50"'
Vt 82% dieve pyT4n deiiv., Tn. 1. 1 ith

Yj rtbt!rs in seritt of cats3yuc htn-!. -of
e VIA

---- 7-7

~5,, 7

,
-
Cch.. (,'If-
vad ixmqa r. toN pwm 1001,* 311
10,
b~ 46~71'l 3 4W9. 1,14W,1-1 CCI~: C11 (.'1[-
w7,
-
11 .,4fl1wtdjAn,)t0 fell 1A n6Nve:
crud
T
Na
t
W-MCMCNIOD-110C
,&-
-ic- t
c
t
I I t
4
I *1fh anfl~Q.5 jr.11vim
Vwe r- am It-2 1 with:
e
"P
t
a
l
1
0
"Lt iD
ve
ri
o of. Cana
rA
1
e
"(f
011~1
n
AU 1AD72 &0585
f
C
b
1
c
-
-
e
n
F
f
.
4
All' 6 AM% JAM, 0.0=j ou44MV, -Afecy_

I V

7
the mcftIfiv~! -bdas-
w";
pro
t4k-for-11-t- inyl
tyrloheryj -tth--vInyj jih-yl ethcrj prcdc,~j'lmiacL Of Mkyl
Vinyl ether, compmtrit. When the Jst 3mfmoam-s Knt!
16-
l
i
o
~
i,
Rr-
ymirs
j or po
heated Wt
l
mib-ed -*btn 3-457pcutaly3t n" viR~. aK.Magh
)ield.- wtam o
10% swid pol-m-~r 4bo fmMIA fm-m ciii:CNICTI-11., :32
heat U's v"thout b CaU
7- t -~'f fjjr.'-'. 3 olmomas mith cli': C HCO.Me
ved~ed with- DtA czteilysti

'
0.270)-ia boo 6 rs hra. gave appmpriate
h
t
h
f
i
uUs.
3-lelds w
pitJonihmt content o
t
e acry
t

77
Witi
chz!rll..
S. !R?.. ST 1141 --.1, c1 CA 30. 105fc
$1. loulk-le"v= ol 09 S. llccl'iJOD~i~. 2b. 5 g. v in y!
r cy6obtry) et)w =d 0.1 vl. 251~7,,, BF, ID EtO at 125-3i)"
pcvdu~u from wbh-h wivi 61lard
WW 7,2
-0
bad=, 106m;
CH;rjj# 9.4-rt McCMJ()1)4-XOPh) at 70' i,;~e 669,
attempts ;Z with MeCH(Oft~ gil-ri un vj?d pnly..
--nnrhWproduc;ts. Tt"cllm6fll.Big.HCICCII.CBO]3t;~
~nd 33 x. MeQ3(Ol3uN wltb a fevr dn" et OF,, RUO In !t

4U
f LwAfol-"
6h ti tM F ~!I '6
o
f
'
'? Oblaid
Alami PIMMM', Ma,- 11. 'Intpramon Ortween Son, c VIUL
4---JaLp Ima Carbon Tet'le-blorld'i VIACT the Influt. Ce 0 lilt.
f O=t InItIptw. "VZ4TM I-00 DAOIDrvS;Ii
d W, ON IOVY" OfIrvaV 2 ClIttyrAtUhhiriftyrik pgl--t- p~[
n1m m-HrImykit InUaInjurvy. A. ~. Bo_qdvz)vn and 'A F

2' FC-L~
-A mudy of the condition of Inteyaction of ftt'nOe vim'l etilers
With-ma Unkhm ibL hifluentm Pf varipum reagents and factom
4h8wui*te it 3-mmion with the ftev radical,

BOGDANOVA.,~,,!.; SHOSTAEDVSKIY, M.F.; KRASILINIKOVA, G.K.
Investigationa in the field of vinrlarrl others. Report No.6: Some
proportion and transformations of vinylcyclohexvl other and its
derivatives. Izv.AN SSSR.Otd.khim.nauk no.3:345-352 Mr '57.
(KLRA 10:5)
l.Inatitut organicheskoy khImii im. N.D. Zelinskogo Akademii nauk
SSSR.
(Vinyl compounds)

AUTHORS: Shostakovskiy, M. F;,.JLQAdanova,
w.,hm ~ , A.V., SOV/62-58-6-16/37
a.
Plotnikovaq G. I., lbrova,
TITLEs Investigation in the Field of Low-Molecular Polymerization
(Issledovaniye v oblasti nizkomolekulyarnoy polimerizatsii)
Communication 3. Interaction 'Between Divinyl Ether and
Carbon Tetrachloride (Soobshcheniye 3. VzaimodeystViye
divinilovogo efira s chetyrekhkhloristym uglerodom)
PERIODICAL: Izvestiya Akademii nauk SSSR, Otdeleniye khimichaddkb nauk,
Nr 6, pp. T56-759 (USSR)
ABSTRACTi The investigation of the properties of tettachloropropyl-
alkyl- and tetraohloropropylaryl.ethers (Refs 1,2), which was
carried out by the authors, showed that these compounds,
because of the mobility of a-chlorine, are similar to
a-chloric ethers with respect to their reactivity. However$
the presence of 3 chlorine atoms in their molecule (in the
y-situtation) renders this~molecule more stable., and all
transformations of these compounds are loound to lead to the
formation of P-dichloroacrolbin'derivatives. It was
interesting for the authors to compare -the properties of
Card 1/3 already previodsly obtained tetrachloropropylalkyl ethers with

Investigation in the Field of Low-Molticular sov/62-5e-6-.16/37
Polymerization. Communication 3. Interaction
Between Divinyl Ether and Carbon Tetrachloride
the properties of the products of the compound composed of
carbon tetrachloride and divinyl ether. The conditions of
the interaction %etween divinyl ether and carbon tetrachloride
und-er the influence of benzoyl peroxide and nitryl azobutyrate
are investigated. Conditions for the formation of 1,3,3,3-
-tetrachl6ropropylvinyl- and bis-00,30-tetrachloride)
propyl ethers were establisheu. Moreover, the separated ethers
are nharacterized and structure of tetrachloropropylvinyl
ether was determined by hydrolysis, The increased resistivity
of bis-(tetrachloride) propyl ether in the reactions of
hydrolysis was demonstrated, There are I table and 10
references, 7 of which are Soviet.
ASSOCIATION: Institut organicheskoy khimii im. N,. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D~
Zelinskiy,AS USSR)
SUBMITTED: December 25, 1956
Card 2/3

Investigation in the Field of Low-Molecular SOV/62-58-6-16/37
Polymerization. Communication 3. Interaction
Between fivinyl Ether and Carbon Tetrachloride
1. Divinyl ethers--Chemical reactions 2. Carbon tetracliloride-Chemical reacutions
3. Ethers-Properties 4. Benzoyl peroxide-Chemical effects 5. Nitrobutyrates
--Chemical effects
Caid 3/3

SHOSTAKOVSKIY, M.P.; BDGD&NOVA, A.V.; USHAKDVA, T.K.
Vinyl compounds in dione synt a. 8. Report No. l- Interaction of
ooms vinyl others with cyclopentadiens and hexachlorocyclopentadiene.
Izv. AN SSSR Otd. khim. nauk no.10-1245-1249 0 157- (MIR& 11:3)
l.Institut organicheskoy khimii Im. N.D, Zolinakogo AN SSSR.
(Ethers) (Cyckopentadions)

BOGDANOVA, A.V.; SITOSTAKOVSKIT, M.Y.; PLOTMOVA, G.I.
,~ -X" " ~~
:4
Dephenolizing tar water with vinyl ethers. Zhur.prikl.khim.
30 no.12:1872-1874 D 157. (MnA 11:1)
(Ethers) (Coke industry) (Phenols)

AUTHORS: Shostakovskiyq M. F., Bogdanovay A. V.9 -20-1144>-31/54
Krasillaikova, G. K.
TITLE: The Interaction of Diaoetylene With Some Hydroxyl-Containing
Compounds (Vzaimodeyotviye diatsotiloua a nekotorymi
gidrokellooderzhashohimi soyedineniyami).
PERIODICAL: Doklady AN SSSRj 19571 Vol. 114, Nr 6, pp. 1250-1253 (VSSR)
ABSTRACT: Because of its high reactivity diaoetylene is of interest for
synthetic organic chemistry. But its use is restricted by its
small accessibility. The authors describe the 3 known
production methods of diacetylene (references 1-8). The aim
of the present investigation is the study of the interaction
conditions of diacetylene with butanol, cyclohexanol and
P-decanol, the isolation of the products and the comparison
of their properties. Diacetylene reacts with alcohols under
the influence of caustic alkalies on heating. On that occasion
ethyl-vinyl-ethers form. In the case of an excess of alcohol
they are converted to butine-2-Al-4-acetals (equation 2).
CHIC -CwwCH + ROH ---~ CHt---C-CH CH-OR, (1)
Card 1/4 where R - 0 4H9 (1); C6H11 (11); clon 17 (111)

The Interaction of Diacet~lene With Some Hydroxyl- 20-114-6-31/54
Containing Compounds
CH~ --CH-CH-CH-OR --- >CH-C-CH 2- CH(OR )2
CH 3 - C~C - CH(OR)21
where R - C4H9(IV); C6H 11 (V); 010H17 (VI).
The reaction takes place in steps. In contrast to the alkyl-
acetylenes the first alcohol-molecule is added to diacetylene,
in opposition to the Markovnikov-rule. This is done by the
influence of the second ethenyl group. The next molecule is
added to the ethylvinylether according to the Mark-ovnikov-
rule. It is followed by an isomerization discovered for the
hydrocarbons by Favorskiy (reference 9). On heating to 1000
only ethylvinylethere are produced. Acetals only develop
above 1300. The interaction of diacetylene with P-decalol
begins at 900 and only ethylvinylether is obtained. At higher
temperatures denanol is obtained. In order to prove this
structure of isolated ethers and acetals, the authors used
brominationg hydrolysis (reference 2) and hydrogenation
(a partial and a complete one). In the partial hydrogenation
1-alkoxybutadienes develop, in the complete one - saturated
Card 2/4 ethers of the C 4H9OR,aeries, where

The Interaction of Diaoetyiene With Some Hydroxyl- ;~0-114-6-31/54
Containing Compounds
R - C4 H9(VIII); C6H11(IX'C1OH17 (X). From the butynal-
acetals the authors produced the corresponding butyralaoetals.
Ethylvinyl ethers are easily brominated. The addition of the
first bromine-molecule probably takes place at the double
bond and is accompanied by an isomerization. The second
bromine-molecule is added to the triple bond and
1-butoxy-1,2,3,4-tetrabromobutene-2 (XIII) forms.
The reactions described indicate a considerable reactivity
ethylvinylethers in the ionic conversions. In this connection
some peculiarties of their double bond become recognizable.
16 compounds, 10 of whom were unknown in literature, were
synthesized on the diacetylene-basis,
There are 2 tables, and 13 references, 2 of which are
Slavic.
Card 3/4

The Interaction of Diacetylene With Some Hydroxyl- 20-114,4-33/54
Containing Compounds
ASSOCIATION: In3titute of Organic Chemistry AN USSR imeni N. D. Zelinskiy
AS 'USSR(Institut organicheskoy khimii im. N. D. Zelinskogo
Akademi*i nauk SSSR).
PRESENTED: February 9, 1957, by B. 1. Kazanskiy, Academician
SUBMITTED: February 9, 1957
Card 4/4

SOV/62r-=8-8-12/22
AUTHORS: 3ogdanova, A. V., Shost-akovskiy, M. P., Krasillnikova, G. K.
TITLE: Investigation in the Field of Vinylaryl Ethers (Issledovan,~ye
v oblasti vinilarilankh efirov.) Note 7: Ior.-- and Rqdical
Polymerizatiou of the Simple Vinyi Ether of Cylciohexanol;
P-Decalcl and P-Naphthol (Soobshchen~Ye 7- Ionnaya i radikal'uaya
o~ 4 -
"'imerizatsil i sopolimerizataii prostykh vin!'ovykh efiro-Y.
p
tsiklogeksancla, P-dekalola i P-naftola)
PERIODICAL: Izvestiya Akademii nauk MR, Otdeleniye khimi.-heakikh n&ukt
1958, Nr 8, Pp- 990-995 (USSR)
ABSTRACT: In publications there have hitherto been no notes concerning
the polymerization of vinyl-p-naphthyl- and vinyl-p-decalyl
ether under the action of the nitryl of azoisobutyric acid. In.
the previous papers the authors dealt with the polymerization
of vinyl-phenyl and vinyl paraternary butyl...phenyl ether (Refs
1-3) as well as with their copolymerization with vinyl ether
and vinyl-butyl ether. The present paper deals with the iln-
vestigation of the conditions required for the polymerization
Card 1/3 and copolymerization of vinyl-o-naplithyl-, viuyl-p-deoalyl-.

investigation
Polymerization
A-laphtholl
Card 2/3
5011162-r-B-8-12122
in the Field cf Vinylary" Ethers. Note 7: Ion- and Radical
of the Simple Vinyl Ether of Cyclohexanol, 0-Decalo! and
and vikyl-oyclohexyl ether under the actIon of BF3, the
benzcyl per4~-xide and the nitrile of the azoisobuiyric acid.
The conditiozs were found on which the polymers of vinyl-cyol-.-
hexy'41.2 -y-iny'A.-P-decaly."Ll-and vinyl-p-naphthyl ether (and their
copolymers) with vinyl eihy'-, vinyl-butyl and vinyl-phennyl
ether may be produoed in good yie'Lds ;,,n the acti~;n Cf the BF 3-
ethe-rate. The majority of these polyzers cons.'sta of sclid
products. It could further be found that the polymerization of
vinyl-cyQIohtxyl, vinyl -p-decalyl, - and ether
on the aGtion of benzoyl and nitr'Lle peroxide of the azoiso-
butyric acid needs a great amount (up to 6%) of the initiatoz,;
mcre heating and more timeo The polyme- yield is small. Viny,..
o.YQIohexyI--, vinyl-p-decalyl- and viny~-phenyl ether caup under
the action of benzoyl peroxide; be included into the copo:ymeri-
zation w,-!'%,-h methyl ethers of the acryllic and methacrylic acid.
On this occasion copolymers of divers structures are formed
whizb contain simple vinyl ethers (up to 44%).

SOV/62-51~-8-12/22
11iYeatigation in the Field of Vinylaryl Ethers. bote 7: Ion- and Radical
P01YX&r12&tiOn Of the Simple Vinyl Ether of 6yel7ohexanol, P-Decalo! and
P-Naphthol
There are 6 ta'bles and 10 references, 8 of which are Soviet.
ASSOCIATION: Institut organicheakoy khimii im. X. D. Zelinskogo Akadomii
nauk SSSR (Institute of Organic Chemistry imeni X. D. Zalinskiy
As USSR)
SUBMITTED: January 9,.1957
Card 3/3

t1.A Y,
AUTHORS: Shostakovskiy, M. F. Bogdanova, A. V., 20-3-29/59
Ushakova, T. M.
TITLE: Vinyl Compounds in the Diene Synthesis (Vinilovyye soyedin-
eniya v diyenovom sinteze). On the Diene Synthesis of Thio-
vinylether With Cyolopentadiene and Hexachlorocyclopentadiene
(0 diyenovom sinteze tiovinilovvkh efirov a teiklopentadiyenom
i geksakhlortsiklopentadiyenom).
PERIODICALt Doklady AN SSSR, 1958P Vol- 118, Nr 3, PP- 520-522 (USSR).
ABSTRACTs In an earlier work (reference 1) the authors proved that the
simple vinyl ethers (CH2= GH-ORI where R is an alkyl-, aryl-
o
,,r saturated hydro-aromatio radical) can take part in the
diene synthesis with oyclopentadiene and hexachlorocyclopenta-
diene as a philodiene compound. Other facts from this field
follow (references 2,3). The authors continue the systematic
investigation of the syntheses mentioned in the title as the
thiovinylethers now became accessible (reference 6). The first
two mentioned authors (reference 8) reported a greater tendency
to the reaction according to the radical mechanism of the
vins-i-aryl-ethers than to that of vinyl-alkyl-ethers. The
Card 1/3 latter also occur more easily in the diene syntheses (reference

Vinyl Compounds in the Diene Synthesis. On the Diene Synthesis 20-3-29/59
of Thiovinylether With Cyclopentadiene and Hexaohlorocyclopentadiene.
1). Also the greater tendency of vinyl-sulfides to free-
-radical transformations than is the case with their oxygen-
-analogs was reported (reference 6). Because o-f this similar-
ity an easier course of the reaction of diene synthesis with
thio-vinyl than with vinyl-alkyl-other could be expected.
This was proved by experiment. The reaction mentioned in the
subtitle takes place at lower temperatures and with greater
yields than is the case with vinyl-alkyl-ethers. The syn-
thesis is accompanied by the formation of bicycloheptane-
-thioethers as well as of corresponding derivatives of octa-
h,ydro-naphtalene. The thiovinyl-ethers with hexachlorooyclo-
pentadiene form thio-ethyl- and thiophenyl-hexachlorobicyclo-
heptene. The stepwise courde of reaction results from the
fact that the isolated biovoloheptene- (I and II)-ethers con-
dense with hexachlorocyolopentadiene forming "dihydraldrinell
(VII and VIII)-thioethers. An experimental part (not mentio-
ned as such) with the usual data follows. There are 8 re-
ferences, 6 of which are Slavic.
AN USM
ASSOCIATION:i Institute for Organic Chemistry imeni N.D. Zelinskiy/(Institut
Card 2/3 organicheskoy khimii imeni N.D. Zelinskogo Akademii nauki3SSR).
7

Vinylpompounds in the Diene Synthesis. On the Diene Synthesis 20-3-29/59
of Thiovinylether With Cyolopentadiene and Hexachloroeyolopentadiene.
PRESENTEDt July 25, 1957, by A.V. Topchiyev, AcMe=401an
SUBMITTEDt July 24, 1957
AVAILILBLEt Library of Congress
Card 3/3

AUTHORS: ShoL;takovskiyf x". F.,
11lotnikova, G. I.
TITLE: The Interaction Between Diacetylene and Ethyl V*ercaptan,
and Some Properties of the Compounds Obtained
(Vzo,imodeystviye diatsetilena a etilmerkantanoin i
nekotoryye svoystva pcluchennykh soyedineniy)
PLRIODICAL: Doklady Akademii niuk SSSR, 1958, Vol. 12o, Nr 2,
PP- 301-304 (USSR)
ABSTRACT: Several ethynyl-vinvl-ethers (References 1,3) were pro-
duced by synthesis on a diacetylene basis. They are
interesting from the point of view of their reactivity
and the possibility of producing 1-alcoxy-butadiene-1,3
(Reference 4). It was interesting to investiaate the
interaction mentioned in the title ', as publications on
this problem are restricted to one single patent men-
tioned (Reference 5). The authors obtained this inter-
action already on slight heating; under the influence
of alkali the reaction already begins at rooia tempera-
Card 1/4 ture and is accompanied by self-heating. There are

Interaction Between Diacetylene and Ethyl SOV/2o-12o-2-2o/63
Llorcaptan,and Some Propertios of the Compounds Obtained
proofs that the first stage of the interaction under
review takes place according to an ionic mechanisms
According to the ratio of initial substances and tho
temperature the reaction follows scheme (I) or in accom-
panied by the formation of ethynvl-vinyl-thioethyl-
-other and a product of the ad4ition of 2 mercaptan-
-molecules which has a butadiene-struoture Cacheme (11)).
The interaction takes a stepwise course, as the second
stage can also take place independently Yeith another
mercaptan. The addition of meroaptan to the ethynyl-
-vinyl-thioethyl-ether may take place under the influence
of different reagents (alkali, HU, radical-initiators
and heating). In the last 2 cases the yields of the final
product are higher. Thus this addition reaction takes
place more advantageously according to a radical mecha-
nism than according to an ionic mechanism. The chief pro-
ducts in this connection are dithio-alkyl-butadiene-1,3.
A certain difference of the physical constants and a
strong axaltation of the molecular refraction of the
Card 2/4 addition product of 2 mercaptan-moleoules to diacetylene

The Interaction Between Diacetylene and Ethyl :30V/2o-12o-2-2o/63
Mercaptan,and Some Properties of the Compounds Obtained
is apparently explained by the presence of 2 isomeric
compounds, others than those with a butadiene-structure
also being possible among them. Ethynyl-vinyl-thioethyl-
-ether reacts with a sublimate solution in alcohol and
quantitatively forms ethyl-mereapto-mercury-chloride,
an equivalent amount of RCI and apparently ethyl-vinyl-
-ethyl-ether. Thus this method can be employed for the
determination of ethynyl-vinyl-thio-alkyl-ethers, In a
kind,of experimental part details of the reactions,
constants and yields are describedunder conditions
of. a) interaction of diacetylene with ethyl-mercap-
tan; b) decomposition of ethynyl-vinyl-ether and the
product with 2 mercapto 'groups by sublimate solution
in alcohol (table 2); C) hydrolysis of the latter
ether and the 2-mercapto-group product in the presence
of sublimate (table 3); d) interaction of ethynyl-
-vinyl-thioethyl-ether with ethyl-mercaptan and thio-
phenol (table 4); e) condensation with maleic an- -
Card 3/4 hydride.

The Interaction Between Diacetylene and Ethyl 30V/2o-12o-2-2o/63
Yercaptanand Some Properties of the Compounds Obtained
There are 4 tables and 9 references. 7 of which are
Soviet.
ASSOCIATION% Institut organichoskoy khimii im. N. D. Zelinskogo
Jkkademii nauk SSSR
(Institute of Organic Chemistry imeni N. D. Zelinskiy,,
AS USSR)
PRESENTED: January 8, 1958, by B. A. Kazanskiy, Member, Academy of
Sciences, USSR
SUBMITTED: January 7# 1958
1. Acetylenes--Chemloal reactions 2. Thiols--Chemical reactions
3. Ethers--Synthesis 4. Cyclic compounds--Properties
Card 4/4

50) SOV/62-59-2-21/40
AUTHORS: Shostakovskiy, M. F., Bogdanova, A. V., Krasillnikova, G. K.
TITLE: Investigation in the Field of Diacetylene Deri vatives
(Isoledoyaniye Y oblasti proizvodnykh diatsetilena). Communica-
tion 2. Some Transformations of Alkoxy-butanes and Preparation
of 1-Alkoxy-butadienes-1,3 (Soobahcheniye 2. Nekotoryye
prevrashcheniya alkoksibutanoy i poluoheniye 1-alkokei-
butadiyenov-1,3)
PERIODICAL: Izvestiya Akademii nauk SSSRI Otdeleniye khimicheskikh
nauk,
.
1959, fir 2, pp 320-326 (USSR)
ABSTRACT-. In the present paper the d3compoaitioa of the 1,1,3-trioxy-
butanes synthesized by the authors and some transformations of
products of their thermal decomposition were investigated and
a method of synthesis of alkoxy-butadienes-1,3 suggested. A
notic8able thermal decomposition of trioxybutane begins at
r-j200 , butyl alcohol, 1,3-dibutoxy butene-1 (IV), its dimer
and the partly polymerizing 1-butoxy butudiene-10 (1) being
separated. 1-butoxy butadiene-1,3 M was also obtained on the
thermal decomposition of (IV) which indicates a gradual proceed-
Card 1/3 ing of the reaction. 1,3-dibutoxy butene (IV) obtained on the

sov/62-59-2-21/40
Investigation in the Field of Diacetylene Derivatives. Communication 2. Some
Transformations of Alkoxy-butanes and Preparation of 1-Alkoxy-butadienee-1,3
decomposition of tributoxy butane may be regarded as a P-sub-
stituted vinyl ehter. It really displaces some properties of
vinyl ether. On its hydrolysis the alkoxy group in the y posi-
,tion is split off and vinyl acetaldehyde (VI) formed, it reacts
intensely with gaseous hydrogen chloride and forms a-chloro-y-
butoxy-dibutyl other (VII). On hydrogenation of 10-dibutoxy-
butene-1 under usual.conditions alcohol is split off, but no
dibutoxy-butane is formed. On condensation of I-cyclohexoxy-
butadiene-1,3 (II) with maleic acid anhydride the copolymeriza-
tion of the anhydride with butadiene took place in addition to
the formation of an adduot. kn apparentlj regularly built
polymer was separated therein. By means of condensation of
I-alkoxy-butadiene-1,3 with croton aldehyde methyl-alkoxy-
tetrahydrobenzaldefiyde was obtained. In addition to the thermal
decomposition of 1,1,3-trialkoxy-butanes the hydrolytic cleavage
of these compounds was investigated. On the hydrolysis of
1)1,3-tributoxy-butane (X) and 1,1-dibutoXY-3-phenoxy-butane (XI)
3-butoxy-butanal (XII) and 3-phenoxy-butanal (XIII) were sepa-
Card 2/3 rated. It was found that the hydrolysis on permanent heating is

sov/62-59-2-21/40
Investigation in the Field of Diacetylene Deriyatives. Communication 2. Some
Transformations of Alkoxy-butanes and Preparation of 1-Alkoxy-butadienes-1,3
accompanied by separation of the alcohol molecule and the
formation of -finyl acetaldehyde (XIV). This indicates that in
the aldehyde the fdrmation of the alkoxy group in P position
is not stable as compared with trialkoxy-butane. In the lattSr
this group is split off only on continuous heating up to 220
There are 12 references, 4 of which are Soviet.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of organic Chemistry imeni N. D. Zelinskiy
of the Academy of Sciences, USSR)
SUBMITTED: May 31, 1957
Card 3/3

'k -t
7 3 0P17
~-P~ 67038
AUTHORS; Shostakovskiyy M. F.q_z~ SOV/153-2-5-23/31
Chekulayeva, I. A.
;~
TITLE: and
synthesis of New Monomers on the Basis of A2.e~len
Diacetylene
PERIODICAL: Izvestiya vysehikh uchebnykh zavedenly. Khimiya i khimicheakaya
tekhnologiyaq 19599 Vol 2, Nr 5, PP 769 - 775 (USSR)
ABSTRACT: From acetylene and diacetylene, as well as from compounds con-
taining a mobile hydrogen, monomers (ether and thioether) with
a vinyl-ethyl-vinyl- and a diene group can be obtained. The com-
pounds with mobile hydrogen si-4in particular; alcohols of various
structure, ami , alcohols, meroaptanesp phenols, silanoley etc.
According to the method of A. Ye. Favorskiy and X. F. Shostakov-
skiy different types of vinyl compounds with a total formula
CH ~CH-XR can be obtained where X m O,N,S,Si,, and R is an alkyl,
2
aromatic 9 hydroaromatiog or other radical (Ref 1). The most in-
teresting among the recently obtained unsaturated compounds on
acetylene basisq is the vinyl-other of the amino alcohols
(Refs 5,6). They may be used as initial raw materials for several
Card 1/3 nitrogen-containing macromolecular products including some with

67038
Synthesis of Now Monomers on the Basis of Acetylene SOV/153-2-5!-23/31
and Diacetylene
a Ures-dimensional structure (to be used as ion-exchangwre-
sineYe it present diaostylene becomes.interesting because it may
serve as a starting raw material for -various synthesesp and be-
cause it has both a scientific and a practical significance. In
the laboratory for vinyl compounds of the Institute in which
the authqrs work, the hitherto neglected chemistry of the di-
acetylenes concerning the interaction with compounds containing
mobile hydrogen has been systematically studied. By the reaction
of diacetylene with alcohols (Ref 8) and meroaptanes (Ref 10)
(constants of the reaction product@ in Table 1),* as well as with
amino algohols (Ref 10) orgauic.oompounds with a simpleether
(also containing nitrogen)and with a thio-ether-grou in the
conjugated system of the double and triple linkages TI) oan-be
obtained. Additionally, butadione-a-ether (II), a,6-di-thio-
ether (III) and mixed a96-thio-ether are obtained. The synthesis
method of.the I-alkoxy-butadiones-193 on the diaostylene and the
alcohol basis makes possible the production of several repre-
sentatives of this class which contain alkyl- and cyclic radi-
cals (Ref 16). The alcohols reaot with diacetylene under the in-
Card 2/3 fluenoe of alkali and on heating. In this reaction, ethyl-vinyl-

67038
Synthesis of Now Xonomers on ths Basis of Acetylene gov/153-2-5-23/31
and Diacetylone
other (I) and aoetals of butin-2-al-4(see Scheme) are formed*
The reaction of the diacetylene with meroaptanes occurs gradual-
ly. Unlike the reaction with alcohols, the 2-meroaptane molecule
,adds itself to the threefold linkage and di-thio-alkyl (or
phonyl) of the butadiene-I 93 is formed'( Scheme). The clompounde pro-
duend are highly reactive. The authors recommended a new method
of synthesis for the I-alkoxy-butadiene-1,3 based on partial
hydration of the ethyl-vinyl-ether (Table 4). Tables 20959
and 6 list the constants of adaitiozial products synthesized.
Finally, they-established-the conditions of the synthesis of
:!inyl other of ethanol aminesVof various structures, and ex-
amined their properties. There are 6 tables and 18 references,
13 of which aTe,Soviet.
ASSOCIATION: Institut organicheskoy khimii AN SSSR im. K. D. Zelinskogo
(1-notitute of Organic Chemistry of the Academy of Scieno-ego
USSR imeni N. D. Zelinakiy)
Card 3/3

5 (3) SOV/62-59-8-35/42
AUTHORS: Shostakovskiyq M. _A. V.p
Plotnikova, G. I.
TITLEs Letter to the Editor
PERIODICAL: Izvestiya Akademii nouk SSSR. Otdaleniye khimichoskikh nauk,
1959, Nr 8, p 1505 (USSR)
ABSTRACT., The authors state in this letter to the editor that they were
able to.synthesize the bia-thiobutgLdiene into disulfones while
reserving the diene structure, starting from the synthesis
Ref 2) for the first time carried out by them of bis(alkylthio)-
T
and bis(arylthio)-butadiene: 1 11
005 3GH-GII-CII-GH-SC (1) C H 0 C
05 6 5S('2)'H-CH-CH'CH(O2)SC05 (n)
H20r---+
C2H SCH-CH-CH-CH-SC )CH-CH-CH-CH( H
5 2H5 (III) C2H5S(O2 02)SC2 5 (1V)
Physical data and biementary composition of the two compounds are
given. There are 3 referenoesp 2 of which are Soviet.
Card 1/2

Letter to the Editor
SOV/62-59-8-35/42
ASSOCIATION: Institnt organicheskoy khimii im. N. D. Zelinskogo Akademii nauk
SSSR (Institixte of Organic Chemistry imeni N. D. Zelinekiy,
Academy of Sciences, USSR)
SUBMITTED: may 7v 1959
Cara 2/2

5 (3)
AUTAORS- Shootakovskiyj 11. F., Bogdanoval Ae V.y SOV/74-28-9-3/7
Kraaillnikoval G. K.
TITLE: Diacetylene and Its Derivatives
PERIODICAL, Uspekhi. khimii, 1959, Vol 28v Hr 9, PP 1052-1085 (USSR)
ABSTRACT: In the present paper the authors give a survey on the actual
state of the chemistry of acetylene and its derivatives.
First, the methods of obtaining these substances are described.-
the synthesis of the diaoetylene derivatives from acetylene
and other substituents ong them aimerisation of mono-
substituents, acetyleneenRefe 1-27); magnesium-organic
synthesis (Refs 28-31); d6halogenation of halogen derivatives
(Refs 32-37). The methods for obtaining diacetylene can be
subdivided into three groupst The syntheses of the first group
based on the oxidative dimerisation of metalliG salts of the
acetylene have, at present, only a historical value (Refs 34,
38-41). The second group comprises methods using the effect
of an electric discharge on various hydrocarbons (Refs 42-48).
The third group comprises the syntheses based on a gradual
splitting-off of elements of the halcgen hydracide from the
Card 1/4 halogen derivatives of the butane series (Refs 49-71). The

Diacetylene and Its Derivatives SOV/74-28-9-3/7
physical properties of diacetylene are treated according to
references 31, 32, 39, 40, 45, 75-90, and its explosive
properties according to references 39, 42, 47, 91-95. The
purification and the analytical determination of acetylene are
described according to the references 45, 48, 57, 59, 60, 72,
97-100. Then follows the description of the chemical properties
of diacetylene and its derivatives. Diacetylene is the first
member of tba homologous p6lyine series with conjugated triple
bonds. The separation of first acetylene compounds from
vegetable products stems from the year 1892 (Ref 101). Since
that time about 50 of such compounds have been obtained.
References 17, 18, 102-107 are devoted to a close investigation
of the separation and of the synthesis. The informations
contained in publications on the properties of diacetylene
and its derivatives chiefly refer to the reactions of
substitution and addition. Among the substitutions we fina the
reactions with magnesium-organic compounds (Pa* 29, 31-34, 49,
55, 98, 108-115); with metals (Refs 51, 54, 57 100, 111, 116);
with halogens (Ref 31) with carbonyl compounds (Refs 7, 10, 46,
Card 2/4 481' 117-122), and with methyl olamines The field of additions

Diacetylene and Its Derivatives SOV/74-28-9-3/7
to diacetylene covers: the addition of hydrogen (Refs 123-127?
29, 32, 55)t of halogens (Refs 29-32, 128-132); of nitrogen
dioxide (Refs 133-135); of water (Refs 66, 99, 136), of alcohols
(Refs 48, 57-59, 62, 65-671 137-140)9 of Clycols (Ref 137); of
i,,,.ercaptans (Refs 62, 141)s of amino alcohols (Refs 46j 63t 122);
of acrylonitrile (Refs 142-144); of HCN Ref 14~), of thio-
cyanogen (Ref 146) and of dialkylamines Ref 48 - Parthermore,
the oxidative dimerisation of the diacetylenea is described
(Refs 1, 4, 6, 7, 17, 18, 29, 33, 101, 105-107, 147, 148). The
following section of the paper is devoted to the ethinyl
compounds. The physical properties and the spectra of the
ethinyl vinyl ester are described, an ascertained by the
authors. Among the chemical reactions of the ethinyl vinyl
ester the substitutions of acetylene hydrogen and the addition
are the most investigated. Substitutions were investigated in
reactions with metal (Refs 57,'11), with ketones (Ref 149), and
with the magnesium-organic compounds (Refs 150-151). Additions
to ethinyl vinyl ester were investigated in reactions with
alcohols (Refs 58, 59, 62, 6 , 66, 91, 137, 138, 150-153) with
mercaptans (Refs 62, 156-152; with water (Refs 57-60, 64, 159);
Card 3/4 with carbonyl-compounds (Refs 48, 57P 124P 150P 160-162); with

Diacetylene and Its Derivatives SOV/74-28-9-3/7
aoetgls of acetaldehyde (Refs 163, 164); with bromine
(Ref,59)- Furthermore, the addition of hydrogen (Refs 59, 1581
165-173) and the dimerisation of ethinyl vinyl ester (Refs 17,
21, 148P 174N were investigated. Finallypethinyl vinyl
thioester (Refs 62, 156-1 8, 175); ethyl vinyl ester,
containing N (Refs 63t 6B and ethinyl vinyl ester, containing
Si were produced. The table contains a list of some of the
functional diacetylene derivatives. The following Soviet
authors are mentioned: V. 1. Yegorova, 0. M. Kuznetsova,
Go I. Plotnikov, I. A. Chekalayeva, L. V. Kondratlyev, I. I.
Strizhevskiy, M. Do Ohekhovioh, Zh. 1. Iotsich, E. So Shapiro,
and L. references, 33 of which are
Soviet.
ASSOCIATION: In-t organichaskoy kh'-ii AN SSSR, im. No D. Zelinskogo
(Inatitaio of Organic Chemistry AS 'USSR imeni No Do Zelinskiy)
Card 4/4

50)
AUTHORS: Shostakovakiy, M. F.9 Bogdanoval A* V.t SOV/2o-124-1-30/69
Plotnikova, G. I. I
TITLE: Investigation in the Pield of Diacetylene Derivatives (Issle-
dovaniye v oblasti proizvodnykh diatsetilena) Interaction
Between Diacetylene and Phenole, Thiophenol and Benzyl Alcohol
(Vzaimodeystviye diatsetilena a fenolami, tiofenolom i benzilo-
vym spirtom)
PERIODICAL: Doklady Akademii nauk SSSR, 19591 Vol 124, Nr 1,
PP 107 - 110 (USSR)
ABSTRACT: The authors had earlier reported on syntheses based on di-
acetylene with aliphatic and hydro.-aromatic alcohols as well
as with ethyl mercaptan (Refs 1,2). In order to introduce the
corresponding aryl derivatives into the substances available
the authors tried to add phenol to the diacetylene. These two
substances, however, did not react together according to the
usual scheme under conditions suitable for alcohols. The
authors wanted to investigate the reaction mentioned in the
subtitle. They wanted to elirinate the influence of the
Card 1/3 benzene nucleus which is caused by the oxygen atom. This

Investigation in the Field of Diacetylene Derivatives. BOV/2o-124-1-3o/69
Interaction Between Diacetylene and Phenols, Thiophenol and Benzyl Alcohol
was expected to be changed by means of the sulfur atom in
thiophenol and by the distance of the benzene nucleus from
the oxygen. In fact, both reactions proceeded smoothly under
gentle conditions (1). The junction of the second molecule
of the benzyl alcohol or of thiophenol forms the next stage
of the reaction and can also proceed independently. In the
case of benzyl alcohol, this stage proceeds according to
the ionic mechanism. Butinal-dibenzyl-acetal
CH 3- C mift C-CH(OCH 2C6H 5)2 (111) is formed. In the case of
thiophenol the second stage of the interactl%~,n with di-
acetylene proceeds mainly under the influence of radical
initiators. Dithio derivatives of butadiene-1,3 are formed.
Thus,either thiophenol or ethyl mercaptan is added to
ethyl vinyl thiophenyl ether yielding dithiophenyl- and
thiophenyl-thioethyl-butadiene-1,3 (2), respectively. This
reaction is accelerated by KOH, azo-isobutyric adid-nitrile
or by increased temperature. The yield of the end products
depends on the temperature and on the initiator. Dithiophenyl-
and thiophanyl-thioc-thyl-butadiene-1,3 undergo the diene
Card 2/3 synthesis with maleic acid anhydride, forming adducts that

Investigation in the Field of Diacetylene Derivatives. SOV/2o-124-1-3o/69
Interaction Between Diacetylene and Phenols, Thiophenol and Benzyl Alcohol
lose two mercaptan molecules and forming phthalic anhydride
(Refs 2,6). An experimental section (not designed as such)
ensues. There are 3 tables and 6 references, 4 of which are
Soviet.
ASSOCIATION: Institut organicheukoy khimii im. N. D. Zelinskogo, Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D. Zelin8kiy
of the Academy of Sciences IUSSR)
PRESENTED: May 17, 1958, by B. A. Kazanakiy, Academician
r-" *
SUBMITTED: May 15? 1958
Card 3/3

BOGDMVAO A.V.
". -
New vinyl ether polqparse Vysokom. soed. 2 no.4:576-58o Ap l6o.
(MIRA 13:11)
1. Inatitut organichaskoy khimii AN SSSR.
(3thers) (Polymers)

S/062/60/000/007/014/017/xx
B004//BO64
AUTHORS: Shostakovskiy, M. F., Bogdanova, A. V., and
Ushakova. T. M~
TITLE: Vinyl Compounds in the Diene Synthesis. Communication 3.
Synthesis and Properties of the Ethers of the Series
of Bicycloheptene and Di-endomethylene Octahydro-
naphthalene Containing Aromatic Radicals I
PERIODICAL: Izvestiya Akademii nauk SSSR,. Otdolenlye khimicheskikh
nauk, 1960, No. 7, PP. 1286 - 1290
TEXT: The present paper continues the authors' investigations on the
diene synthesis by means of vinyl compounds of the CH 2-CH-XR type. The
authors report .9n the reactions of cyclopentadiene'land hexachloro
cyclopentadiene'kwith vinyl-p-naphthyl-, vinylphenyl-, and vinyl-p-tert-
butyl phenyl ether. The condensation of the vinyl aryl ethers ith
cyclopentadiene proceeds according to the scheme: (1)
Card 1/5

Vinyl Compounds in the Diene Synthesis. S/062/60/000/007/'014/017/XX
Communication 3- Synthesis and B004/BO64
Properties of the Ethers of the Series
of Bicycloheptene and Di-endomethylene Octahydronaphlwhalene Containing
Aromatic Radicals
The ratio between the forming adducts may be varied by the initial
ratio of the components. As in the case of the vinyl alkyl ethers
also with the vinyl aryl ethers the second stage of reaction may be
carried out by means of hexachloro cyclopentadiene; ether and di-
hydraldine result from this reaction., (2). With hnxachloro cyclo-
pentadiene the reaction proce,.ds under the formation of ethers of
hexachloro bicycloheptene: (3). These compounds could be easily
hydrogenated on the platinum oxide catalyst; the saturated compounds
of bicycloheptane or di-endomethylene-decaline r~,sulted, The authors
describe the syntheses of: III and VI (2-0-naphtho-oxy-bicyclo-(2i2,1~,-
heptene-5 and 1,,4,5,8-di-endomethylene-2,0-naphthoxy-1.2,3,4,44~-5,-'8-,Sa-
octa-hydro naphthalene) by reaction of vinyl-p-naphthv1 ether with
cyclopentadiene in the autoclave at '1170OC; II and V (2-D-tert-butyl-
phenoxybicyclo-(2,2,1)-heptene-5 and '11,4,5,8-dl--endomethylene-2-p-
tert-butylphenoxy-11,2p3,4,..4a.5,8,8a-octahydronaplitlialene under the
Card 2/5

Vinyl Compounds in the Diene Synthesis. S/062/60/000/007/014/017/XX
Communication 3~ Synthesis and Proper- B004/BO64
ties of the Ethers of thp Series of
Bicyoloheptene and Di-endomethylene Octahydronaphthalene Containing
Aromatic Radicals
same conditions by reaoting vinyl-p-tert-butyl phanyl ether with oyclo-
pentadiene. X1. X, and IX (2-0-naphthoxy-1,4,5,6.7.,7-hexachicrc
b_isyclo-(2,2,',)-heptene-5, and 2-p-tert-butyl phenoxy-1,4*5,6,7,
7--hexachloro bicyclo-~2,2,1~-heptene-5 and 2-phenoxy-1.,4..5,6,7,
7-hexachloro bicyolo-~2,2,1)-heptene-5 by reacting the :crrespz;nding
ethers with hexachloro cyclopentadiene at 110 - *1200c in the tes'. 9,-ass
with reflux condenser, VIII-(1,4,5,8-di-endomethylene-2-p-napht~lioxy-
5.,~6,7!,8,9,01,-hexachloro-1t2,3v4,4ai5,8,8a-octahydrcnaphthalA,ne
(:Uhydraidine)) was obtained from compound III and hexachloro cyclo-
pentadiene at 120 - 1351DC. Crystalline derivatives of theae compounds
wexe obtained by means of phenyl azide. There are 2 tablei, and
9 references: 5 Soviet, 1 US, and 3 German.
Card 3/5

Vinyl Compounds in the Diene Synthesis, S/062/60/000/007/014/017/Xx
Communication 3. Synthesis and Froper- B004/BO64
ties of the Ethers of the Series of
Bicycloheptene and Di-endomethylene Octahydronaphthalene Containing
Aromatic Radicals
ASSOCIATION: Institut organicheskoy khimii im, N.. D. Zelinskogo
Akademii nauk SSSR
(institute 2_LOrganic Chemistry imen' N., D. Zaling3kiy
of the Academy of Sciences USSR)
SUBMITTED: December 29, 1958-
Card 4/5

S/062/60/000/007/014/017/YX
B004/BO64
CH2-cti--mok OrAr
Ar=C~Hs (1) Av=CsHs(lV)
- tort.
Ar-C,AC41`1,-P;~~ (11) Ar-C,H4C4H,'fi'jpe Av)
Ar-CoH,-p (VO
cl
OAr
W: cljjcl Cl
c1 cl I:B, ~
cl (2)
cl, c1
A,,C,oH,-p (Vill)
Cs
1c: OM
CC12
-c
cl
zAr com ox)
Card ~/5 Ar: Clt Ctl
t,

ZO
AUTHORS:
TITLE:
110 1106 Z205
Shostakovskiy, M. F.,
864 5
S/062/60NOO/008/030/033AX
B013/B055
and Plotnikova, G.L.
On the Diene Synthesis of 1,4-Dithioethyl 1,3-Butadiene
With Cyclopentadiene
PERIODICAL:
Izvestiya. Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1960, No. 8, pp. 1514-1516
TEXT: This is a brief communication on the diene synthesis of 1,4-di-
thioethyl 1,3-butadiene with cyclopentadiene. The ratio of the initial
substances and the time or reaction were varied in the experiments. The
synthesis proceeds by stages, addition products being formed which con-
tain varying numbers of cyclopentadiene molecules per dithioethyl-buta-
diene molecule. The ratio of these addition products depends on the
ratio of the initial substances and duration of heating. Three addition
products were separated from the reaction mixture. The first, formed by
reaction of one cyclopentadiene molecule with one molecule of the diene
investigated, reacted readily with an alcoholic sublimate solution with
quantitative formation of ethylmercapto mercury chloride and HC1, which
Card 1/2

86415
On the Diene Synthesis of 1,4-Dithioethyl 1,3- B/062/60/000/008/030/033/XX
Butadiene With Cyclopentadiene B013/B055
January 19, 1960
can be easily titrated with 0.1 N NaOH. This indicates the presence of a
vinylthioethyl group. (I) may therefore be assigned the structure of a
2-thioethyl 3-vinylthioethyl bicyclo(2,1,2)-5-heptene. The second product
I
kII) contains two cyclopentadiene molecules per dithioethyl-butadiene
molecule. Neither it nor the third product react with alcoholic sublimate
solution. The second product may be regarded as bis[2-thioethyl-bicyclo
(2 1 2)-5-heptenej. According to its composition and constants, compound
(IIII~ is [1,4,5,8-diendomethylene-2-thioethyl-3-(21-thioethyl)-bicyclo
(21,11,21)-51-heptene]. The preparation of analytically pure samples was
rendered very difficult owing to the formation of cyclopentadiene polymers
which are very soluble in the addition products. The 1,4-dithioalkyl(aryl)
1,3-butadienes prepared from diacetylene, which give the typical diene
reaction with mal6ic anhydride, exhibit dienophilic properties in the
diene Synthesis with oyclopentadiene. There are 1 table and 6 Soviet
references.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D.
Zelinakiy of the Academy of Sciences USSR)
SUBMITTED:
Card 2/2

SHOSTAKOVSKIY, M.P.; BOGDANOVAp A.V.; FLOTNIKOVA, G.I.
Synthesis of maroaptals and dimercaptals of different aldehydes
from corresponding aoetals, Izv,AN SSSR Otdakhimenauk no,831524
Ag 160. (MIU 15:5)
1. Inatitut organicheakoy khImli im, N,D.Zelinskogo AN MR.
(Moreaptals)

sHosumvsm, m.r,; BWDANOVA, A-V-; PWTNIMVA, G.I.; DOWIEH. A.W.
Method of synthesizing mwdAPtOlS5 aDd tritliated enter's of Orth4OrvdC
acid. Izv. AN SBSR Otd. khim* nauk U0910:1901 0 160- (M331A 1340)
1, Inotitut orpnicheakoy WMil Im, H,DO.Zelinekogo Akademii nauk
SSSR.
(Orthoforr4c acid)

SMSTAKOVSKIY, M.Y.; BPGD4W-Tjk-,,Ajr -_USWOVA. T.H.; WPATIN, B.V.
Vixgrl compounds in dione synthesis. Steroospecific orientation
of the diene synthesis of vizWl aryl others condensed with
oyelopentadione In relation to the temperature. Dokl." SSSR
132 no*5:1118-1121 Jo 160. (MIRA 13:6)
1. Institut organicheBkoy khimli im. N.D.Zelinskogo Mmdemii nouk
SSSR- Predstavleno akademikom B.A. Kazanskim.
(Itbers) (Grolopentadione)

BOGDANOVA# A,V,; SHOSTAKOVSKIT, M.G,; PI M IKOVA, G.I.
Synthesis of unsaturated other acetalo, thioather acetals, and
mereaptala. Dokl. AR SSSR 134 lio.3i587-590 3 160. (MIRA 13:9)
1. Institut organichakoy khimii im. N.D. Zolinskogo Akademii nauk
SSSR. 2. Chlen-korrespondent AN SSSR (for Bogdanova).
(Acetals) (morcaptals)

ShwTAKOVSKIY, IA',F.; DOGDfI*CVI P A V 1 USKAKOW., 71.1-1. i LOPAT11-19 D,V,
Vinyl compounds in the diene synthesis, Report Fc,. 4., Comprj-,Aive
charactoristics of the Cienophilic activity of vinyl and
thiovinyl otherst and optical -+-i-dy of the &dducts obtained. I2v.
All SSSR. Ctd. khim. muk no. l.-120-127 Ja 161. (~MIIA 14:2)
1. Institut organicheskoy khimii im, N.D. Zelinakogo Alt' 5551"..
(Ethers)

,,PMANOVAt A.V.; SHOSTAKOVSKIYP M.F.; PLOTIMOVA, G.I.
Stereo-oriented syntheses based on diacetylene, and isomeric
conversions of 1j,4-bis. (arylthio)-1,3-butadienes and their
disulfones. Dokl. AV SSSR 136 no. 3:595-598 ja 161. (MIRA 14:2)
1. Institut organicheskoy khimii imeni N.D. Zelinskogo AN SSSR.
2. Chlen-korrespondent AN SSSR (for Shostakovskiy).
(Bvtadiyne) (Butadiene) (Sulfones)