SCIENTIFIC ABSTRACT BOGDANOV, L. M. - BOGDANOV, M. N.
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CIA-RDP86-00513R000205820013-0
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RIF
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S
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100
Document Creation Date:
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Publication Date:
December 31, 1967
Content Type:
SCIENCEAB
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Body:
TSARMV, B.A.; BOGWOV. L-X-; KLMSH, G.G.; LIPGHLNMTA, V.I.
-Possibility of partial substituting of synthetic polymers
for gelatin in photographic evalsions. Tekh.kino i telev.
4 no. 8:8-11 Ag 160. (KERA 13:8)
1. Leningradskly institut ldnoinzhoneroy.
(Photographic eft1sions)
T. -33056*.66 Wr TJP(Q)'
SOURCE CODE:
XCC Me -AM240 DR/0077166/du 0 1 0 7
AWHOR: 1(hismatullina, Ls' A Levi, S sMs; Boeanov, Le M.; Kukhtin, V. A*'
ORG: All-Union Scientific Research Motion Picture Institute (VseooyuzTVy nauchno-
issledo-vatelskly kinobt-ofiwititut) -
TITLS: Investigation of the application of grafted gelatin oopol~mrs for
graphic omlsions p
SOURCE: Zhurnal nauchnoy i prikleAnoy totografti i kinexatograM, v. L1. no. 2.
1966, 81-87
TOPIC TAGS: photographic emasion, graft copolymr, photographio processing,
photographic property
ABSTRACT: Conditions are worked out for synthesis of grafted gelatin copolymers. As
a result of physico-mchanical and photographic investigations of the grafted gelatin
copolymrs, introduced to the emLlsion in quantities of 25-50%, it has been establish
that these materials have no negative effect on the photographic properties, but
increase, the eldsticity. strength and heat stability of the anx1sion layer, which
makes the layer imune to separat n during high-temperature photographic processing,
Orig* site hast 9 tables* FAVY
SUB CODE: 14, 07 / SM DATEt '15Sep64 / atIG REFt 002 / OTH REFt 001
BQGDAHOV.- L. -N.
Training of radiologists and radiologioal laboratory assistante
on a local basis. Zdrav. Roo. Feder. 6 no.6:25-28 A 162.
1. Is rentgenovskogo teentra, (sav. L. N. Bogdanov) Kirovskoy
oblastnoy klinicbeekoy bollnitsy (glavnyy vrach V. N. Potapenko).
(RADIMOGr, MEDICAL-STUDY AND TEACHING)
',~~Ioty I-f Rnentg nolc-
6, 1 d Rad logi 8 t Vr 6 t r" 11
BOGDANOV, L.S.
Tenth Pacific Science Congress. Okeanologiia 2 no.1:185-188
'62. (MIRA 15:2)
(Pacific Ocean--Congresses)
BOGDAFOV, L.1%
Organization of X-ray servJLca il-I a corsolidated district.
Zdrav. Ros. Feder. 7 no.5:111-14 lo~,163. (IVIR.A 16:6)
1. Rentgenologicheskiy tsentr (zav. LX.BoCdanov) Kirovs!-,oy
oblastroy kAmicheshoy bollnitsy (glavirry vrach V.I-.Potapenko)
i orranizatsiorno-~metodichesliy otdol ( zav. - prof. 1. 1-1.
Yalchnich) Eauchno-insledovatellskogo rentgenorad-iologichesko-
go instituta (dir. -- prof, 1..G.Lagunova) Ministcr5tva zdra-
voohhranoniya RSFSR.
(MIDIOLOGY, vE DICAL)
BOGDANOV, Leonid Pavlovich
[A knowledge of economics is importantl Znanie ekonomiki -
jol'shoe delo. Moskva, Mosk. rabochii, 1961. 33 P.
(MIRA 17:2)
BOMANOV, L.V.- LOSW, H.Z*
The MA-1010-type six-spindle drIlling-machina unit, Blul.
tal&.-okon.inform. no.12129-30 158. (HIRA 11112)
(Drilling and boring machinery)
10151 -
ROZH1SSKIYJ. M'O.), starshiy rauchnyy sotrudnik; 11 IA!'OV, 1 V,, aspirant;
MARRUVA I , starshiy laborant I. . I - I ~ 11 1------
Determining the volume of circulating blood in adult horses arA
dairy cow:3 by the T-1824 homatocrit method, Izv. TSKhA no.5:
217-221 '61. (MIRA 14:12)
(Blood.--Circulation)
(Horses) (cows)
BOGDANOVI L.V., aspirant
Blood volume And erythrocyte indices in connection with the
productivity and body type of dairy cows. Izv. TSKhA no.6t
160-171 161, (NM 16:8)
(Blood) (Dairy cattle)
BOMMOV, L.V.
"The Blood Volume and Total-Content of the Basic Components of
the B192,1woof Milk Cows of Various Constitutional Types";
dissertation for the degree of Candidate of Biological Sciences
(avarded bj the Timix7asev Agricultural AcadmW, 1962)
(Izvestlya %,Lmir~mzevakoy Sellskokhozyaystvennoy Akademii, Moscow, No. 2.
1963, pp 232-236)
BOGDANOVIO.K.; KnCOWMG, M.
Stimulative effect of the peat and lignite humic acids on the
striking of vine grafts. Zemljiete biljka 11 no.01325-328
v62.
1. Poljolwivredni fakultetp Zwm.
I - I I
I
BOGDANOV, -M.
Ps
Hov ve imerease the productivity of pumping equipment. Zhil.-kom.
khos. 5 no.lt27-28 1556, (MLRA 8:5)
lo BrigAdir elesarno-zontashno), brigedy Kalizduakogo tresta wVbdo-
kana3m.
(Ruoping machinery)
BOGDANOVO M.
'r... ...........................
The new face of the Pechora Basin. Sov.shakcht. 3-1 no.11:24-25
N 162. (KMA 15:12)
1, GILavnyy insh, Kombinate, ugolinykh trestov i predpriyatiy
rorkutskogo rayona.
(Pechora Basin-Coal mines and mining)
WD-MW, It.; MUSSON, A.; -VOLKOV, V.; VOUESEIMMY, S.; ZEUNMIN, S.;
N.; KOREIW. P.; IMVINSXkYJL. I.; KULAGIN. M ; MARSAVIN. M.;
MINAKOVA, P.,- POPOVA, M.; BUKKUY, S.; SHTAlTOVNff: A.; FAINTKU, L.
YAOITISTOV,.P.; CHUIAFOVA, M.; YATSYNIN, N.
Obituary. Ptiteavodetvo 0 no.2:48 F 159. (MIU 12:3)
(Shutov, Nikolai Ivanovich, d..1958)
BULGARIA
B-OGANDYs Pr_ M_ t OVL, Ruse
"Mcperience in Prophylactic Treatment of Hene.Against Broodiness on a
Large Scaleff
Sofia# Veterinarna Sbirka, Vol 63, Wo 3, 1966, pp 26-28
Abstract: It was established in work conducted in the USSR, Hungary,
and Germany that developmen t of the mass instinct f6r',brooding~by!.-hens
results in considerable losses: every yearg from March ~, to,IV11 4o% cof
the hens discontinue egg-laying for 20-40-60 days. A number of reme-
aiees- for the condition in question has been developed, among them
Ovogen-1, which has a therapeutic effect and has been proposed by MO
Bogdanov and P. Gabrovski. These investigators also developed the
prophylactic Ovogen-2, which contains the vitamins A, E, and 29
112
BULGAMIA
BOGI*NQV, Dr. M.; District Veterinary Hospital, Ruse
"Application of the Blood of Pregnant Mares for Raising the Rate
of Conception in Ewes"
Abstract: It was found inwork conducted In the USSR and elsewhere
that serum of the blood of pregnant mares can be used to advantage
in sheep breeding because it raises the rate of fertilization of
ewe.s. Prof. P. Shatalov develoDed in 1960 a method whereby a
preparation that Is richer In ho-rmones than serum or citrated
blood can be prepared from the blood of pregnant mares. This pre-
paration, designated KZhK (blood of pregnant mares), has been
produced in 1965 under the supervision of Prof. Shatalov at the
laboratory of the District Veterinary Hospital at Ruse. Tests
carried out on ewes indicated that the preparation was effeetive
when applied In optimal doses, Table.
END -
CE-110
CSO: 2000-N (53 pages)
V,
U
PHASE I BOOK EXPLOITATION SOV/5463
Sovetskaya antarkticheskaya ekspeditslya
Vtoraya morskaya ekspedillslya na d/e "Ob"', 1956-1957 gg.; obshcheye
opisaniye i nauchnrye rezul'taty (Second Marine Expedition on the Diesel-
Electric Ship "Ob' 1956-57, General Description and Scientific Results)
Leningrad, Morskoy transport, 1950. 175 p. (Series; Its: [Materialy] no. 5)
Errata slip inserted. 1, 200 copies printed.
Sponsoring Agency: ArkticheBkiy.i antarkticheskiy nauchno-issledovatel'skiy
institut.
Ed. (Title page): I. V. Maksimov, Doctor of Geographical Sciences, Professor;
Ed. : L. G. Kaplinskaya; Tech. Ed. 0. 1. Kotlyakova.
PURPOSE: This book is Intended for oceanographers. meteorologists, and
hydiochemists.
Card 1/6
Second Marine Expedition (Cont.) SOV/5463
COVERAGE- The present volume. the fifth in a aeries of seven, is a collection
of articles (except for two) devoted specifically to the oceanographic, meteoro- -
logical. and hydrochemical findings of the Second Soviet Marine Expedition
conducted on the diesel ship "Obl" (L A. Man. Captaio during 195G-57. The
first two articles outline the Expedition's organization and program. and
provide a general account of its activities during the 223-day voyage, which
covered more than 40, 000 miles of the Atlantic. Antarctic, and Indian Oceans.
The expedition was sponsored by the Arctic and Antarctic Scientific Rcs6rch
Institute of the Glavscvmorput' Ministerstva morskogo nota SSSR (Main Ad-
ministration of the Northern Sea Route of the Ministry of the 17%lerchant Ma-
rine of the USSR) as part of the International Geophysical Year pr4ogram. Its
purpose was to investigate 1) atmospheric processes In the Antarctic region
and their effect on the earth's general circulation; 2) basic regularities in
the distribution of waters in the southern oceanic one, 3) exchange of the
waters of the southern seas with the waters of the world ocean. 4) geological
structure of the sea bottom in the Antarctic region, and 5) the plankton, benthos.
Card 2/6
Second Marine Expedition (Cont.) SOV/5463
ichthyofauria. and microorganisms of the Antarctic waters. Observations
of the magnetic field of the earth were also made. The expedition, headed
by Professor Igor' Vladislavovich Maksimov, Doctor of Geographical Sci-
ences and Professor at the Leningradskoye vyssheye inzhonernoye morskoye
uchilishche imeni S. 0. Makarova (Leningrad Higher Marine Engineering
School imeni S. 0. N-Takarov). consisted of the following 8 scientific task
forces: nerometcorological (headed by Leonid Gennadlyevich Sobolev);
hydrological Wirill Vladimirovich Nloroshkin); geological (Aleksandr
Petrovich Lisitsyn); hydrochemical (Alekscy Nikolaycvich Bogovavlenskiy);
hydrobiological (Viktor Aleksandrovich Arsenyov); geophysical (Nikolay
Panteleymonovich Grushinskiy): geographic (Gravrila Dmitriyevich Rikhter);
and hydrographic (Yuriy Aleksandrovich Gordeyev). A complete list of the
names and affiliations of the 65 scientific and administrative members of the
Ex
pedition Is contained In the first article. The articles were written by
members of tho Institul oke~inologii Akademii nauk SSSR (Institute of Ocean-
ology Academy of Science-. USSR), Gosudarsivennyy okcanograticheskiy
insti?.t Gidrometsluthby SbSR (State Oceanographic Institute of the Hydro-
Card 3/6
-Second Marine 'Expedition (Cont.) SOV/5463
meteorological Service of the USSR), Vscsoyuznyy nauchno-issledovatell-
sMy institut rybnogo khozyaystva.i okcanografii (All-Union Scientific Re-
search Institute of Fisheries and Oceanography), and the Arctic and Ant-
arctic Scientific Research Institute. There are no references.
TABLE OF CONTENTS:
Foreword 5
Maksimov, 1. V. Second Antarctic Marine Expedition 7
Man, I. A. Second Voyage of the Di6sel Ship "Ob' 19
Khromov, S. Atmospheric Circulation and Weather During
the Course of the 1956-57 Voyage of the "Ob'" 27
Gutnikov, V. P. Synoptic Processes in the Southern Hemisphere 84
Card 4/6
Second Marine Expedition (Cont. SOV/5463
Sobolev, L. G. Work of the Aerometeorolo~ical Unit 101
Moroshkin, K. V. Hydrological Investigations 106
Moroshkin, N.V.. and M. A. Bogdanov. Results Obtained With
an Electromagnetic Current Meter in the Indian Ocean and in the
Southern Part of the Pacific Ocean 124
Morozov, A. P. Observations on Sea Dist0bances 138
Gordeycv, Yu. A, Hydrographical Works 144
Tomashunas. B. Ya. Ice Observations 154
Bc)goyavlenskiy, A. N. Hydrochemical Investigations 159
Card 516
Second Marine Expedition (Cont.) SOV/5463
Kutyurin, V. M. Determining the Content of Chlorophyll in Sea
Water and the Spectral Analysis of Phytoplankton Pigments 173
AVAILABLE: Library of Congress (G860. S58)
JA/dwm/bc
Card 6/6. 11-1-61
:BOGDANOT, M.A., mladshiy P-auchnyy sotrudnik
Measuring surface water temperatures with electric thermometers in
the southern part of the Pacific Ocean. Inform. biul. Sov. antark.
ekep. no.20133-37 160. (14IRA 13:9)
1. Voesoymnyy nauchno-iseledovatel'Bkiy, institut morskogo rybnogo
khozMstva i *akeanografii.
(Pacific Ooean---Ocean temperature)
S/194/61/000/008/019/092
D201/D304
AUTHOR: Bogdanov, M.A. and Ivanov, Yu.A.
TITIE: Sea currents and flow measurements by the 9M%4T
(EMIT) instrument
PERIODICAL: Referativnyy zhurnal. Avtomatika i radioelektronika,
no. 8, 1961, 17, abstract 8 V143 (Tr. In-ta okeanol.
AN SSSR, 1960t 39, 80-84)
TEXT: Comparison of results of flow measurements by the
EMIT (electromagnetic flow meter) with those carried out by direct
methods has shown that large discrepancies exist in certain cases,
the E241T output signal varying during the observation period by as
much as 1.5-5 times. The cause of the error is the existence in
certain sea regions of telluric currents. In regions where these
currents are absent the EMIT measurement results agree with those
of instrumental methods. The need is stressed for studies of tellu-
ric ocean currents with the aim of understanding, their character aud
Card 1/2
S/19X361/000/008/019/092
Sea currents and flow measurements... D201 04
determining the regions where the MIT measurement method can be
applied. 7 references. Z-Abstracter's note: Complete translation-7
.001,
Card 2/2
TIHOFMV., I.A.; FOTAYCHUK, S.I.; BOODANOV. M.A. -
Apropos of V.V*Roasov's article "Tidal variability of hydrological
conditions." Okeanologiia 2 no.4:731-734 162. (MM 15:7)
(oceanography) (Rossov, V.V.)
5,0,~ MMACHMW,, I.A.; POTAYCHUK, S.I.; EDELIMAN, M.S.
BOG~W
Hydrology in the Faeroe-Iceland area. TRUDY VNIRO 46-.63.-64 162.
(MIRA 15:10)
(Faeroe Iolands rAgion-Oceanography)
(Iceland Igion-,oceanography)
BOGDANOV, M.A.
-,., - ~., ~ - ~, ~ - . . 4'. "
Semiconductor rectifiers reduce the consumption of electrim
power in nonfemous metallurgy. TSvet. met. 28 no. 12:4-6 D 165
(KITLA' 19:1)
BOGDAVOV $Mail
.497ich; ARKWORLISKIY,S.B., redaktor; TMMMff,M.N(;
I. k-hnnichookiy redaktor
(Work-pro, protection and safety engineering in the cotton veaving
industry] Okhrana truda I tokhnika basopasnosti v khlopkotkatskom
proigvodstve. Moskva, Goo.nauchno-takhn. izd-To Ministerstya pro-
mysh.tovarov shirokogo potroblentia SSSR, 1955. 137 p. (XIMA 9:1)
(Cotton manufacture--safety measures)
BOGUANOVO X. I.
"The Problem of the Role of the Nwrous System ip
i6munogenesis During
Brucellosiso" Cand Vet Sci,, Inat of Experimental Veterinary, Sci,, Moscow,, 1953.
(RZhBiolj,'No 7,, Dec 54)
SurvW of Scientific and Technical Dissertations Defervied at USSR
Higher Mucational. Institutions (12)
SO: Sum* No* 556, 24 Jun 55
USSR / Microbiology, Microbes Pathogenic for Man F-4
and Animals. Bacteria. Brucelli.
Abs Jour: Ref Zhur-Biole, 1958, No 17, 76773.
Author t Boadanov. M. I.
Inst 7Er-yat_MongoT-2W6vrter1nary Institute.
Title On the Immunological ReorgantEation of Animals
with Brucellosis Depending on the Method of Intro-
duction of an Antigen.
Orig Pub: Tr, Buryat-Mong. zoovet. In-ta,, 1956, vyp. 10, 147-
154,
Abstract-. It Is shown that with a subarachnoid Introduction
of brucellosis antigen, the corresponding agglu-
tinins in rabbits appear on the third day; with
subcutaneous Introduction - on the fourth, and in
the lowest titers; while with intramuscular intro-
duction, the appearance of agglutinins occur more
Card 1/3
3z
USSR / Microbiology, Microbes Pathogenic for Man F-4
and Animals.. Bacteria. Brucelli.
Abs Jour: Ref Zhur-Bfol,, 1958, No 17, 76773o
Abstract- Infectious diseases, the immediate introduction
of antigen In the region of CNS causes a more
rapid Immunological reorganization of the organ-
Ism than during other methods of Introduction.
M, Ya, Boyarskaya.
Card 3/3
33
BW didat t0dinichaskikh nauk.
Modm,m standard Iwacting design for pipeline trenches. Sbor. trud-
VNIIGS ao*6:107-322 155. (mm 9:7)
(pitches) (pipelines)
PQQD,ANOV, FaTROFAN IVANOVICH
N13
735-91
.B6
Remont Eleictroka' Na Iesosekakh (Repair of Cables Through Wooded
Section Clearnings) VVk;a ' Goslesbumizdat, 1955.
25 P. Illus., Diagrs. (V Pomoshch' Mekhardzatoram lesozagoto Vok)
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BoMkMTKO, A.V.; POGDANOV. M.I.; FARBMOV, M.I.
Industrial synthesis of vinyltoluene. Uch.zap.IArosl.t9khnol.inst,
2:33-46 157, (MIRA 129.7)
(Chemistry, Technical) (Styrene)
~-v-
~~, - J-
I
BOADAMINKO, A.V.; BOGDANOV,.M.I.; FARBEROV, R.I.
Investigating the dehydration process of ethyltolueas and vinyltoluene.
Zhur.prikl.kbim. 30 no.6:927-932 Je 157. (MIRA 10:10)
1. Yaroslavskiy Takhnologichaskly institut.
(Dehydration (Chemistry)) (Toluene)
i
KOLOBIKHIN. T.A,,, ISUOTAI N*Ao; OARMONOT, I.T99 red*;
ZONIS. 6.A,, rede; IMIMIRA, Ye.T., red.; XRT-TK , Ye.Te.,
tekbn.red.
(Analysis of the products obtained in the industrial preparation
of bivinyl from butane] Analis produktov proizvodstva divinila
iz butana. Yod red. I.Y.Oarmonova. Leningrad, Gos.nauchno-
tokhn.izd-vo khimelit-ryp 1939, 115 (MIRA 13:2)
(Butedlene) (Butene3l
87675
ZZ004 1 Is 2~
A005/AOO1
Translation from: Referativnyy zhurnal, Khimiya, 1960, No. 21, P. 331, # 85707
AUTHORS: Bogdanov, M. I., Bol'shakov, D. A.
TITLE: Thermodynamical Calculation of the Main Reactions in the Process of
Producing Isoprene From Isopentane
PERIODICAL: Uch. zap. Yaroslavsk. tekhnol. in-ta, 1959, Vol. 3, pp. 47-62
TE(T: The equilibrium output of isoprene was thermodynamically calculated for
for the dehydrogenation of isopentane, isoamylenes, and isopentane-amylene mixtures
In a wide temperature range at 1 at without dilution and In the presence of an
Inert diluent (water); on this basis it Is concluded thitt the one-stage dehydro-
genation of the lsopentane-amylene mixtures diluted by an inert diluent is most
efficient. In case of the dehydrog8nation of isopentane, the maximum conversion
in Isoprene amounts to 34.5% at 600 0 and the molar ratio of Isopontane : water
1 :' 5. In case of isopentane-amylene mixtures, containing 30 Imolar % of isoamylen%
the maximum conversion of isoamylene in isoprene at 6250C and the molar dilution by
the Inert diluent in a ratio of 1:5 increases up to 38.1% instead of 16.4 without
dilution. I. Konenko
Translatorts note; This is the full translation of the original Russian abstract.
Card 1/1
50) SOV/80~32_3-24/43
AUTHOPS: Bogdanov, M.I., Krushinskayn, Ye.P.
TITLE: The Study of the Process of Separating Butylene-Divinyl Mix-
tures by the Method of Chemical Sorption (Izucheniye protsessa
razdeleriya butilendivinilovykh smesey metodom khemosorbtsii)
PERIODICAL: Zhurnal prikladnoy khimii, 1959, Vol XXXII, Nr 3, pp 603-608
(USSR)
ABSTRACT: The effect of the chemical composition of the solution, the
temperature and the divinyl concentraticn on the sorp'tion
capacity of the water-'ammonia solutions of copper acetate is
investigated here. These solutions were prepared from elec-
trolytical copptr in the.form of wires of 0.3-0.4 mm in dia-.
meter, technical acetic acid of 98.74,9-ammonia water with a
content of 25% NH3 and lip .id ammonia. The scrption was tested
on mixtures containing 91,.7 divinyl and at a temperature of OIC.
The sorption capLLcitf i_-. ~.etermined by the content of monovalent
copper in the .solution. 1f this content is 3.3 0-atom/l, the
solubility of d.ivinyl is 4-4 weight percent. At Ia lo--.Yer contePt
the solubility decreases. A higher content has only a slir-h~
Card 1/2 effect on solubility. The solubili!,.' V1 :.!11.111-1 1
SOV/BC-32-3 _44.`,'3
fl-, I
The Study of the Process of Se-,.,arating Butylene-Divinyl Mixtures ty :.-e
Method of Chemical Sorption
its concentration (Pigure 2). The effect of thv teiulierature
was investigated within the range of from -9 to +200C. The
solubility increases noticeably with the decreaso of tempera-
ture.
There are 2 dinUrama, 3 tables, 1 graph, and 12 references,
4,of which are Soviot, 5 English, 3 American, 1 German and
1 French.
SUBMITTED: October 19, 1957
Card 2/2
ATHOR: Bogdanov, M. I.
s/o6A A 0/000/01/05/024
B0227BOO8
TiTh:' -Calcula-t-lo-n-7-or the Equilibrium of the Dehydrogenation
Reaction of leopentan I ls6amylenes,jand Their Mixtures
to Isoprenel
PERIODICAL: Xhimicheskaya promyphlennoott, 1960, No. 1, pp. 25 - 31
TEXT! The investigation of the thermodynamioslof the dehydrogenation
processes mentioned in the title was the aim of the paper under review.'
The dehydrogenation of isopentane to isoamylonesp which in their turn are
dehydrogenated to isoprene, takes place in this process. The single- and.
two-stage process of inoprene production is described and the importance
of thermodynamic calculations for the determination of the maximum iso-
prens yield under given conditions is pointed out. Equations for the cal-
culation of the reaction equilibrium at the dehydrogenation of isopen-
tane to isoamylenee and of isoamylenes to isoprene are mentioned, and
the dependence of the values of the equilibrium constants at the dehydro-
genation of isopentane to isoamylenes and of isoamylenes to isoprene in
Card 1/2
Calculation of the Equilibrium of the Dehydro- S/064/60/000/01/05/024
genation Reaction of Isopentane, Isoamylenes, B022/BO08
and Their Nixtures to Is9prens
the temperature range of 427-7270 is given (Table 1). The composition of
the equilibrium mixtures at the dehydrogenation of isopentane to iso-
amylenes and isoprene at 427-7270, atmospheric pressure, without dilu-
tiong and in the presence of an inert diluent, as well as the equilibrium
composition of the gas mixtures after separation of the inert diluent,
were caloulated on 'the basis of the equilibrium constants calculated
(Tables 20). The same Yalues were also given for the dehydrogenation of
isoAmylenes to i o r n (Tables 40) and of isopentane-isoamylone mix-
a fTeb;es 6P7)- N- 1. Shuykin and his collaborators
tures to isoprene a
M. I; Bogdanov and D. A. Bol'shakov are mentioned. There are 7 tables
and 10 referenoesp 6 of which are Soviet.
Card 2/2
S/064/60/000/007/003/010
B020/3054
AUTHORS: Bogdanov, M. I. and Krushinskaya, Ye. P.
TITLE: Iso ation of =aj From Hydrocarbon: Mixtures by
Chemisorption With Cobper Salt Solutions
PERIODICAL: Khimicheskaya promyehlennostly 1960, No- 7, PP- 10 - 15
TEXT: The most complicated and hitherto insufficiently studied stage of
synthesis of isoprene from isopentane is the separa-tion of hydrocarbon
mixtures with isolation of highly concentrated isoprene. Extractiong
azeotropic and extractive distillation, and chemisorption can be used
for this purpose. Selective solvents used for separation by extraction
are acetaldehyde, propionaldehyde, propylene oxide, methyl formiate,
methy.1 alcohol, citric acid triethyl eater, dimethyl phthalate, furfuroleg
lactonitrile, ethylene glycol and its monomethyl eater, ethylene glycol
mono- and diacetate, ethylene chlorohydrin, aniline, toluidine, phenyl
hydrazine, esters of low polyglycols of ohlorocarbonic acid, etc. To
increase selectivity, it is convenient to add water to the solvents, or
to extract hydrocarbon mixtures by a mixture of two immiscible solvents.
Card 1/4
Isolation of Isoprene From Hydrocarbon s/o64/60/000/007/003/010
Mixtures by Chemisorption With Copper Salt B020/B054
Solutions
The industry used extractive distillation with aqueous acetone combined
with a simple rectification. The volatilities of the most important
hydrocarbons C 5 (referred to isoprene) mixed with aqueous acetone,
(80% by volume of the mixture) are compiled. A comparison of these data
in Table 1 shows that the volatility of paraffinic and monoolefinic
hydrocarbons increases considerably in the presence of aqueous acetone,
whereas the volatility of piperylene does not change. Besides acetone,
it is possible to use various polar organic compounds containing oxygen,
nitrogeng and sulfur (furfurole, pyridines amines and their mixtures
with water$ low aliphatic nitriles and their mixtures, dimethyl forms-
mide, dimethyl Sulfolane, etc.). The authors deal. with the separating
components for the azeotropie distillation, the extractiveand simple
rectification, the reaction menhanisms, and analyze the reaction
products. The most efficient method of separating hydrocarbons C 5 with
isolation of highly concentrated isoprene Is the chemisorptionl by aque-
ous-ammoniacal solutions of salts of monovalent copper. The production
of absorption solutions is described. Table 2 indicates the solubility
Card 2/4
Isolation of Isoprene From Hydrocarbon S/064/60/000/007/003/010
Mixtures by Chemisorption With Copper Salt B020/BO54
Solutions
of isoprene and isoamylene in aqueous-ammonlacal solutions of Cu +- salts
of organic acids at OOC. The sulubility of isoprene and Of iBoamylene
isomers in aqueous-ammoniacal solution of copper salicylate depends on
the ammonia concentration (Table 3). The authors studied the effect of
the concentration of isoprene on its solubility in a mixture with
amylene isomers obtained by dehydrogenation of isopentane (by 2-methyl-
butene-2f and 2-methyl-butene--l) at 0-500C for mixtures of different
compositions (Tables 4 and 5, and Fig.). The solubility of isoprene
does-not only depend on the composition of the mixtures but also on the
molecular structure of the isoamylene isomer. A practically quantitative
desorption of isoprene is attained at 800C. Table 6 shows the stability
of the absorption solution on heating in ampuls to 1 OOOC. There are 1 figure,
6 tables,and 54 references: 16 Soviet, 28 USj 8 British, I French, and
1 Canadian.
Card 3/4
Isolation of Isoprene From Hydrocarbon S/064/60/000/007/003/010
Mixtures by Chemisorption With Copper Salt B020/BO54
Solutions
ASSOCIATION: Yaroslavskiy tekhnologioheskiy institut (Yaroslavl' -
Institute of Technology . Nauchno-issledovatellskiy
instiiwt monomerov dlya SK (Scientific Resear,-.h v
Institute for Monomers of Syntheti-3 Rubber)
Card 4/4
BOGDANOV,_M.I..,, inzh.; BELqVOLOV, V.T., kand.tokhnonauk; GELESKUL., M.N.P*
BUIOW, A.S.
Manufaoture and use of framed, reinforced concrete timbering under
Arctic conditions. Sbakbtsatrbi, 5 no*4:15--10 Ap 161. (MUtA 24;5)
1. Kombinat Vorkutugoll (for Bogdanov). 2. Peohorskiy nauchno-
insledovatel Iskiy ~gol IW institut (for $09lovolov). 3. Tzhtitut
gornogo de3A AN SSSR (for Bukbman), -
(Pechora Basin-Mine timbering)
BOGDANOVp M.I.
Calculating equilibria of the dehydrogenation reactions
of butane-butene mixtures and of n-butenes to l..3-butadiene.
Part 2. Neftekhimila 3 no.4:488-493 Ji-Ag 163.
(MIRA 16:11)
1. Yaroslavskiy tekhnologicheskiy institut.
BDGPLNOV.,,_1jj. , kand. takhn. nauk; ANISHCHENKO, A.N. , inzh.; ALEKSEYEVA, T.M.
inzh.
Comparative charaoteristics of aurface and underground laying
of process piping. Prom. stroi- 41 no.6:15-17 Je t64. (MIRA
1. Vsesoyuznyy nauchno-issledovatellskiy institut
i aanitarno-takhnicheakikh rabot (for Alakseyeva).
17-9)
gidrotekhnichaskikh
..010
DIJLINp I.L.; KICHAYEVA, G.K.; POPOV, T,j red.
[Long term planning of timber for coal mines] Perspektiv-
noe planirovanie leson,aterialov nn udollnykh shakhtakh.
Syktyvkar,, Komi knizhnoe izd-vo, 1964. 47 p.
(MIRA 18:6)
BOGDANOV, M. N.
"On the amount of vitamin "C" in milk," Trudy Buryat-Mongol zoovet, in-ta. Issue 4, 1948,
P- 100-03-3ibliog: 7 items
SO: U-3850, 16 June 53, (Letopie Murnal Inykh Statey. No. 5. 1949)-
BOGDANOV, M.N.- TITYURIVA, I.V., redaktor; PJVZM, V.L. tekhaicheakiv
i i ma--O, Jr
[Poultry raising] Ptitseyodstvoo Moskva, Goo. lzd-vo aelkhoz. lit-ry.
1956. 638 p. (Mm 9:11)
(Poultry)
zootekhnik;
EMNEV, S.I., prof., doktor sel'skokhoz.nau1qjQ"qT
GOFMAN, NJ., zootekhnik; GRIGORITEV. G.K., zQoMr6-'~*rZHILKIxff'
Z.A.. kand.sol'Bkokhoz.nauk; PENIONZHKZVICH, B.S., doktor biolog.
nauk,~prof.; PMO, A.A.. kan(l.biolog.nauk; TRETITAKOV, doktor
leallskokhoz.nauk. prof.; USPENSKIY, A.A.. kana.seliskokhoz.nauk;
USHAKOV, A.A., kand.veterin.nauk; SHAPOVAIDV, Ta.Ta., kand.sel'Bko-
khoz.nauk; TAGODIN, P.Te., zootekhnik-, TATSWIN, N.H., zootekhaik;FZDO-
ROVSKIY,X.P., kand.biol.nauk; SYCMK. Y6.V.,.red.; PAVLOVI, X.M.,tekhred.
(Poultry raising; a manual for farm managers] Ptitsevodstvo;
rukovodstvo alla zaveduiushchego fermoi. Izd.5, porer.i dop.
goskva, Gos.izd-vo selikhoz.lit-r , 1957. 495 P. (Bibliotechka
17 1
po ptiteevodstvu, no.1) .(MIRA 12:4)
1. DoyBtvitellnyy chlen Vassoyuznoy aknaamii aellskokhozyaystvannykh
nauk im. V.I.Lenina (for Smatnev).
(Poatry)
OV L BANNIKOV, N.A., red.; GORIKOU, Z.D.,
.i.1LO ha-01-AXI evich
-WAIN.
Kra
[Making use of poultry for meat production] Ispolizuite ptitsu
dlia proisvodstva m1ase. Moskva, Goo. izd-vo sellkhoz. lit-ry,
1958. 68 p. (MIRA 11:5)
(Poultry)
BOGULIDVj M.N.
Valuable lnitiative..Ptiteavodetvo 8 no.9:13-15 S 158. -
. .(MIRA 11:10)
(POultz7 bresdiug-Study-iiil teaching)
BOGDAMV, M. N.
Importance of the production of meat-type chickens and principles
underlying its organization. Ptiteavodstvo 9 no.6o.6-9 is 159.
(MRA 3.2 - 10)
ljGlavn" zootekhnik po ptiteevodetvu Hinisterstva sellskogo ,
khoxyaystva SSSR. (Poultry)
BOODANOV, M.N.
Raising Ibroilers for market an a specialized activity.
Zbivotnovodetvn 21 no.3:7-13 Ur 059. (14IRA 12:4)
1. Glavrqy zootekhnik po, ptitsevodstvu Ministerstva, sellskogo kho-
37aystva, SSSR. (poultry)
ARSDISHVILI, A.Yu.; BOGDANOV., M.N.; GORIZONTOVA, Ye.A.; YERSHOVA, Ye.l.;
YELE14BAW, N.I.;-TOFS-,-lF.S-h.; URAVAYEV, A.M.;KOLOBOV, G.M.;
LOBIN., N.V,., kand, sallkhoz. nauk,-, KUSM4ER, Kh.F., doktor bilog.
nank; MISHIN,, P.N.; PATRIK., I.A., kando sellkhoz. nauk; RWIKHj
V.K., kand. sellkhoz. nauk; SWTNEV, S.I., akademik; SZIOLETOV~
A.I.; FIIASOV, V.V.; SHKUDOVA, R.I.; SOKOWVA, G.S., red.;
ROMANOVICH, Ye.F,,, red.; LETINA, L.G., tekhn. red.
[Chickens for mat] WypBata na miaso. Moskva., Izd-vo 11-va
sell.khoz, RSFSR 1960. 197 p. (MIRA 15:1)
1poultry)
BOGDANOV Mkbail Nikolaye,!Ach; IOFEI Nokbm Shleymovich; DOBYCHINAp I.N.j
red.; TRUKMA, O.N., tekhn, red*
(Raising obiken for meat) Vyrashebivania miasrorkh t :List, Mo-
skvap Gos.izd-vo sellkhoz.lit-ry, 1961. 87 p. 7IM3RA 15: 1)
(poultry)
1-!a-(M)/T/EWr-W RM
ACC Mt -~~6015055 (A ) SOURCE CODE: UR/0190/66/008/005/0903/0909
AUTHOR: Bogdanov, M. N.; Leshchiner, A. U.; Plyashkevich, L. A. ?
ORG: Scientific Research Institute of Synthetic Fiber_(Nauchno-issle44$it6,l'skiy
instituT-Iskustvennogo volokna)
TITLE: lAtroduction of terminal aromatic amino groups into polycaproamide. (First
report in a series on "Synthesis and chemical modification of polyamides with
reactive groups")
SOURCE: Vysokomolekulyarnyye soyedineniya, v. 8, no. 5. 1966, 903-909
TOPIC TAGS: polymer, amino acid, polyamide, polymerization, molecular weight,
amino group
ABSTRACT: The hydrolytic polymerization process of -,V".,#prolactiM in- the ptesence of
aromatic diamines and other aminocarboxylic acids has been investigated. It was
shown that these compounds are regulators of the molecular weight of the poly-c-capr
amide'~;d that through them it is possible to introduce into the poly:mer a certain
number of aromatic amino groups to preserve the fiberyproduck-4e capacUy. A method
of quantitative determination of small concentraflo-n4of-aromatic aiftf*o groups in.
the polycaproamide was developed. Orig. art. has: 4 fijurdb,"3 foifi6ldb, and
1 table. [NT]
I CODE: 11, 07/ S
UBM DAM 22May65/ ORIG REF1 009/. 0TH RM 006
a
rd
rd UnCt 541.64+601
:~j
Awt A
AcCRE -,VF5006358- Vnx-- ..,,SOURCE -CODES -~uR/0413/66/0001002/009410094.~
V_ M N-;
INVENTOR:i Khar kov, S N'*,-; Bog'danovp M# I Spirina, I,-A*; Leshiner,
A. U,-A.; Plyashkevich, L#~
C4
ORG: none,
TITLE: Preparative metho.d.for'polyamide Class 39t No, 178102
--tannounced by All-Union Scientific Research 'Institute of*Artificial
Fibers (Vassoyuznyy,nsuchn-o-looledovatelsity Institut iskusstvannogo
SOURCES Izobreteniya, projiyahlennyye obraztey, tovarnyye xnaki
no. 29 19669 94
f(MIC TAds, polyamidel, Carboxyl group$ interfacial polycondensation
ABSTRACTS An Author Certll!lcate has been issued for a preparative
method for carboxyl group-containing polyamides. The method involves.
~interfacial~polycondensation,of diamines containing no acyclic chains
with,bovasuatricarboxylic licid,dichlorides. (BO)
SUB 'CODE i 1l/ SUBM DATE t 26Nar63/ ATD PRESSi
UDCs: 678o675,002.2
Ah
Shilov, E. --n! Bor:damov, '-". N. , About. the mechanis:n of carboxylation and analojous
reactions. p. 1060
The presenc-~ is established of a cross reaction ':.et,,men the s-:)Iiuri anilide of
n-chloro-ph-myl-carbonic acid and a(-naphtholate *which p-was the intel,711olecullar course
of the reaction of formation of anilide of o.---yacid.
The Iv7nov Che;~Aco 1'eclinolo:-Acal Inst. Lab. of O.-ranic Gha:,Istry.
y 11), 10,4
30: Jo~~--nel -)f Gen-m~l Chemistz7 (U33R) 18 (80) 1,110. ~') (1942-)
m
m
vm/c~ - aft4larutun (COMU) Ain
In aromatic reactices are =sauna, TrIphanyllso-
24" c7sawate at& ary1carlonlo &ciao yI&3A ovz2 spand-
Ixe cmy-acid anilides on heatIng with pbezolates
i24 za*tbalates. ZotablIshe& mativre or areas re-
ActIzin between =traullIde of n-ablorphe=1carbonic
&GIA avA oC-naphtWAts, thus proving intramolecular
*oars& of oxy-aold an1lide formation. Sni=itted.
10 fty 1547.
9/49w,
UMAMMMIOU7 CarbMIation lz=
Chaalatr7 Phaw2ates
:OProblm of the Ybobaciam of Carbox7latlan wA
AuLlogaus Rmotions.1" Ye. A. Shilaw', M. N. Bog-
Aim6vp ITSMYO Chem-Teoh Inst, lab of,. Org Chan.,
PP
On= Obaboh MtW Vol XV13:r (=)p zvc 6
ZZmarftes Herahzen I awork on moobanimn of oarboaq-
i 2ation of phenolates ama axalogous rmetions.
SAMM tbiat proofe of intravioleavasr cc-arse cxf these
Z~Wctlcns do not vithstwA critiolm. Damanstrates
iisizWMMMU views on intermediate co~paunft
98~
BOGDANOV, M. N.
Dissertation: 'Research Into tho theory of the Rearrangement of Salts of Amino and
Hydroxy Aromatic Sulfonic Acids.' Gand Chem Sci, Inst of Organic Chemistry, Acad
Sci Ukrainian SSR, Kiev 1953-~
W-30928
SO., fieferativnYY Zhurnal. No- 5. Dee 1953, Moscow, AN TJSSR *XrAgPPX
Vlfcw wmpwunds Imni I nil 'ItL,
'M
- N D
ARM 7
d ObAcki Khiw,
M. N. nord!l
nd
Q! It* '4 willi 95 10.
a ill )IM in a r-ea)M t"heat 13015"
PhNH
fllterln~v cnpg, in mcxo and tjl,~b%- Save 0.1 S. FhMICIls-
CRICI
.
(",
Th
f
cil
c
y
g
A
- 0 s
C\
e
.
i
t
odl6ittatio
a)ga
%,Pk
helm.
l
col
l ti .
Ail
.
btt" (14S g.)*and 44 nil-110
0
sahl
with Co.
'dUd
11-0
with 01
am
ti hr
d 3
fl
i
.
.
.
.
,
.
uxe
re
3.j
filtem) and evalw'. Sivc ~on ad0p. of MeOll 20 g. Ilh.,V- IL
t,,
Olig 13;0 S.) licated withi 410 ml.
(CHICIltro.)A'
.
O.I.VH*SOjl.br.,allovv tostand 4 tin., filltmsl, vvajll~
to a blrupi u-tan up in 10 ml. 2,U011 anti inhed with A.5
(Cf13XNH0j in E't'a jpvc on t1ii1fing 10 2 g. IIAN(Clt,
i
in: 172-S'.
Ills (2,29jrAcs),into 100 mt, Ckl,:CIICN
c4 NION
1016"W by hating tlW*prfxlu0 hl tohti 10 Jim Cst go-
ItW
MrAY(CHICHICA, lit ?J10 tAM2;
R.)-ill-4ou lilt.-Iluoll Ifoltil with N f. NA pive
after coinpletion of tractiun nnd a6fiAzat*a With Ucl,
n., trraimml whb 40%,NaOli. atid. extil. %ith IRIO.
N(C11,011,0111MIjbi-14
3W
-
6 ulnes in air Ond glasc
hich t
Rill
C;
Low
gulipin:140 groups in tba
MiNC41I.A'All with 10 S. D-CiallsON2 thrillY I hr.
at 13 " Save 19A% 2---JaPh1hW m. 179', irbith
kmted to O-OD-101 toucly da;kent and does not chanse hR
w.p. Similarly iras prepd. 29S'7o
Iw9q.-wh'k1; daikerut at DOD-10'. Ph
Wed -to form a polymtr bn btaling. Reating ClIgOir
MCIN with .3 ntaky propoffloh of PhONQ at W), (ccc-
th
U9 ermic beginulng 1.6 hrs. pre 39%, Mr, CHISO, Ph
C;j W,. 71IN . 'Ais hcattd with an cquiv. atnt. 0
11to 178485' gave it distillate of FhOH and
lymer pLArd up
pho" and a bralm
a with-10% MOR
rAyknedi3mine salt
17k 111H
pi-crftm p4y"M - M.
tOff,'and not in the
13tive humidity the,
'IS
Its omithin U-3
7
C Z -E C: 11
tNP110.14-tv till'i 1M. N,
2, 1 0-1,
"Ith Oight
I;c -Lo!u Ar
ff"m 'IP
iq ftr- C'P,
lvjlg y 7
1, V,.~f "I CP 1 1 1
11 ~, g14. 1, ith com , ". ITO, tile r.
-,,I,$ the t,,t. rmwd ivi!h Lt.0 gav, i,--
F"Tul, I !w. ~,Il,
Is
eml e
i~:,OSSA/62 stry Tracer lements I'Sei~ 517
Mechanism. of Rearrangements of Aromatic Salts
land Oxy8ulfonic Acids," Ye. A. Shiloy, Act
~:,Xex.!Acad of Sci Ukr SISIR; M. N. Bogdamov, and,A.
~.Shilov, Inst of Org Chem Acad of Sci Ukr SSR
DAN SSSR, Vol 92, No 1, PP 93-96
:.Used'Iradioactive s35 In the clarification of the
iicba~ilsm of the migration of the sulfonic acid
group Inthe salts of aminc. naphthylsulfonic and
hydroxynaphthylaulfonIc acidu. Presented 30 Jun 53.
2TkTIO
0 SOV/81-59-5-16377
Translation from: Referativnyy zhurnal, Xhimiya, 1959, Nr 5, p 376 (USSR)
AUTHORS: Bondarenko, A.V., Bogdanov,.M.N.,, Farberov, M.I.
TITLEt The Industrial Synthesis of Vinyl-Toluenel
PERIODICAL: Uch. zap. Yaroslavsk. tekhnol. in-ta, 1957, Vol 2, pp 33 - 46
ABSTRACT: The process of catalytic dehydrogenation of ethyl toluene (I)
to vinyl toluene (II) was investigated at 54o to 6000C with a
volumetric rate of 200 - 800 ml per 1 liter of the catalyst
per hour and with dilution by H20 vapors in the molar ratio of
1:8 - 1:16. With an increase in the temperature to :.~- 580oc
and a drop in the volumetric rate to < 400, the yield of II is
reduced considerably. The optimum conditions of the dehydroge-
nation process are.- temperature 560 - 5800C, volumetric rate
400 - 800 ml per 1 liter of catalyst per, hour, dilution with
H 0 vapors 1:12 - 1:16. Thastandard catalyst for dehydrogenation
012 was used as catalyst. A thermodynamic calculation of the
dehydrogenation reaction was made. The equilibrium constants and
Card 1/2 the equilibrium composition were computed at 427 - 7270C, and also
The Indusirial Synthesis of Vinyl Toluene SOV/81-59-5-16377
the apparent energy of activation of the dehydrogenation reaction, being
32,700 cal on the average. It is shown that, in addition to I and II,
toluene, zylene, ethyl benzene and styrene are part of the catalysate com-
position. A circuit diagram of the contact installation is submitted.
L. Volkova
Card 2/2
I - SHILOTO YoA.l BOODAVOT, N.V.
'
Rearrangament of pelts of aromatic sulfouic acids, Ukr. khtme
shur, 24 not W32-?,33 158 (MIRA lliO
(Sulionic acids)
(Rearrengemout s0bemie tz7))
AtrTHOR Bogdanov, M. No - SOVIT9-2a-6-42163
TITLE: The Chloromethylation of a,ri-Phonylalkane Acids (Khlor-
metilirovaniye a, W-fenilalkanovykh kislot)
PERIODICAL: Zhurnal obahohey khimii, 1958, Vol- 289 Nr 6, pp. 1621-1623
(USSR)
ABSTRACT: The ohloromethylation of the a,A)-phenylalkane acids is of
interest as it is connected with the work on the synthesis
of monomers usable for the productibn of new fiber-forming
polyamidea and polyesters. The chloromethylphenylalkane
acids can serve as initial compounds for the synthesis of
different a,d)-amines and a, w-oxycarboxylic acids which
contain benzene nuclei in the methylene chains. In the pres-
ent paper the hitherto not describe& chloromethylation of
phenylacetoacetic-, P-phanylpropionidyiyTphenvlbutyric- and
6-phenylvaleric acid of normal structure is realized. This
reaction was carried out by means of conducting a flow of
hydrogen chloride through the heated mixture consisting of
the compound destined for the chloromethylation plus zinc
Card 113 chloride solution in 40 % formalin, which had to be careful-
The Chloromethylation of aqw-Pherqlalkane Acids SOV/79-28-6-42/63
ly stirred; this reaction is conducted in a similar way in
the case of alkyl benzenes (Ref 1). By the chloromethylation
of phenylalkane acids a mixture of ortho- and paraisomers
formed. However, only the paraisomers were of interest as
fiber-forming properties show clearest in the polymers with
p-phenyl groups. The p-ohloromethylphenylelkane acids were
separated by crystallization of the final products from
various solventst and then were purifie&. The use of vacuum
distillation was not possible as in that case a polycondonsa-
tion of the products took place under the formation of hydro-
gen chloride and formation of a yellow, viscous resin. The
synthesized p-ohloromethylphenylacetio-t p-chloromethyl-
phenylpropionic-, p-ahloromethylphenylbutyria- and p-chloro-
methylphenylvaleric acid are titrated with alkali liquors
in aqueous alcohol, they quantitatively split off chlorine
on their boiling with an alcoYol solution of silver nitrate
and they are oxidized under pressure with 25 % nitric acid
in terephthalic acid (8o - 9o There are 2 references,
2 of which are Soviet.
Card 2/3
The Chloromethylation of apw-Phenylalkane Acids SOV/ 79-28-6-42/63
ASSOCIATION: Vassoyuznyy nauchno-isaledovateltakiy institut iskusst-
vennogo volokna
(All-Union -Scientific Reddnr~ch Institute foi- Syiithet3','c Fibers)
SUBMITTED: May 12, 1957
1. Dipheny.Imthanes--Chemical reactions
--Chemical reactions
2. Metbyl chlorides
Card 3/3
_1- '--
. Q_LOG.DAIIOV. M.N. - MYAVTSNV, G. I.
~~. K
Waye of synthesizing now fiber-forming polymers. Xhim.volok.
no-3:3-10 159. (MIRA 12:11)
1. Vaesoyunyy nauchno-iseledovatellskiy institut iak-u9stvennogo
volokna (VMIV).
(Textile fibers. Synthetic) (Polymerization)
15M 5/103/59/000/06/006/027
ATITHORS., Budanov It N. Petukhov~ B. V, B000007
EMU_
TITLE: New Fibers on the Basis of Co-polyesters-"
PERIODICAL: Xhimicheskiy volokna, 1959, Nr 6, pp 21-24 (USSR)
ABSTRACT: The authors mention the disadvantages of the polyethylene-
terephthalate fiber Lavean; bad colorabIlity, stiffness of
the fiber,5roduoed herefrom. Arcording to Western publioations
Refs 2. co-polyesters made from dimethyl-terephthalate
~DMT), ethylene glycol and small additions of glycols, di-
oarboxyl acids or oxyacids do not have these disadvantages.
The authors investigated co-polyesters of MIT with p-oxy--ethoxy
benzoio acid (OAD). The synthesis of the methyl ester of this
acid from p-oxybenzoic acid (Ref 4) worked out by Y. N. Bog-
danov in cooperation with A. A. Strepikheyev (Deceased) is
briefly described. It was oarried out in the presence of 0.1%
LiOH + Al 0 in the following stages; Reaction of DMT and the
2 3 0
Card 1/3 methyl ester of OEB with ethylene glycol at 160 to 190 , dis-
New Fibers on the Basis of Co-polyesters
Card 2/3
S/183//59/000/06/006/027
13004/'BOO7
0
tilling of the excess ethylene glycol at 200 - 250 " poly-
condensation,at 260-.2750o Figure 1 shows the influence exerted
by the additions of OEB to D14T upon the melting point of the
co-polymer. The most favorable effect was produced by additions
of up to 10%. The authors investigated such co-polymers with
5 and 10% OEB which they denote as oxon-5 and oxon-10. Syn-
thesis was carried out in the presence of 0.02,~ zinc acetate.
Figure 2 shows that the reaction with ethylene glycol is quick-
er in the case of oxon-5 and oxon-10 than in tbat of pure DMT.
Table 1 shors the melt-ing temperature and the spaoifio viscosi-
ty of the solution-of oxon-5 and oxon-10, Both co-Dolymers
were thermographically investigated eccording to V. 0. Gcrba~-
cheva and V. V,, Mikhaylov (Ref 6) (Table 2)and showed a lower
vitrification temperature than Lavsan, but they are less re.-
fractory. The fibers produced from oxon-5 and oxon-10 were
investigated with respect to the breaking length 32-35 km),
breaking elongation ~30-41.51,',), bending strength ~Fig 3) and
elastic deformation Fig 4). Th6 rayon fibers had a softer
feel than Lavsan but higher shrinkage 05 to 23%). An inves-
Now Fibers on the Basis of Co-polyesters
S/163/'59/000/06/006/027
B000007
tigation carried out"with a mercury lamp of the type PRK-2
shoved a better stabilityto light.. coloring tests with acetate
dyes shoved better colorability than Lavsan (Fig 5),, There
are 5 figureep 2 tableso and 6 references.. 3 of which are
Soviet.
ASSOCIATION: VKIIV - Vaesoyuznyy nauchno-issledovatelvskiy institut
iakusstvennogo volokna
(All-Union Scientific Research Inatituts for Synthetio Fibers)
Card 3/3
9 3)
A4HORS: Bogdanov, M. ff., Kudryavtoev, G. I. sov/79-29-3-50/61
TITLE: Synthesis and Polycondensation of the n-Amino-Methyl-Fhenyl-
Alkane-Carboxylic Acids (Sintez i polikondensatsiya n-amino-
metilfenilalkankarbono,rjkh kislot)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 3, pp 966-989 (USSR)
ABSTRACT: The compounds which are most suitable for the synthesis of
the high-melting synthetic fibers are the polyamides of the
homopolycondeneation type of unbranched a,co-amino acids
which have n-phenyl groups in their methylene chains in contrast
to the less thermostable heteropolycondensation polyamidee.
In the present paper the following acids were synthesized;
n-amino-methyl-phenyl-acetic-(I), n-amino-methyl-phenyl-
propionic-(II), n-amino-methyl-phenyl-butyric-(II-1), and n-
amino-methyl-phenyl-valeric acid (Iv) L NH2CH2C6H 4 (CH2)nCOOR(n-
-1-4)3 - The corresponding n-chloromethyl-phenyl-alkana-
carboxylic.acias (Ref 3) served as initial products. Since it
is not possible to aminate the chloromethyl group of these
compounds immediately with ammonia, this amination was carried
Card 1/3 out by the decomposition of the complexes of Urotropin with
Synthesis and Polycondenoation of the n-Amino- BOV/79-29-3-50/61
Methyl-Phenyl-Alkane-Carboxylic Acids
the n-halogen-methyl-phenyl-alkane-carboxylic acids. The
synthesis of the Urotropin complexes was not carried out
according to reference 4 (i-e- it proceeded from the above
mentioned acids in which iodine substituted Cl), but the above
mentioned substituted compounds were used directly and
quantitative yields and cleavage products without iodine
admixtures were obtained. The chlorine hydrates of the amino
acids obtained by the cleavage of the Urotropin complexes were
converted into free amino acids by the evaporation of their
ammonia solution. The dry residue consisted in a mixture of
ammonium chloride and free amino acid which was liberated from
its mineral ingredient by the recrystallization from water.
The synthesized amino acids have no distinctly marked melting
point and are not easily soluble in water. In the case of
heating they are transformed into high-molecular polyamides.
These polyamides bLre,produced not only in the case of a melted
state of the initial products, but already at temperatures
below their melting point, i.e. in dry state which is very
important for the production of the thermolabile polymers. The
Card 2/3 polyamides from (III) and (IV) are stable, horny compounds
Synthesis and Polycondensation of the n-Amino- SOV/79-29-3-50/61
Methyl-Phenyl-Alkano-Carboxylic Acids
which yield in the case of further treatment stable fibers
which are easily extensible in cold state. The polyamides
(1) and (11) decompose ' on - melting and can there-
fore not be used for the above mentioned purpose. There are
I table an& 4 references, 1 of which is Soviet.
ASSOCIATION.- Vaesoyuznyy nauchno-isaledovatellskiy institut iskusstvennogo
volokna (All-Union SCi6htifia 'Ifesearch Inefttate of synthetic
Fibers)
SUBMITTED: January 28, 1958
Card 3/3
VOIDKHIN&, A.V.; BOGDAVOT, M.N.; KWJRYAVTSEV, G.I.
Polycondensation reactions In the solid phase. Part 3: Polr-
condensation of n-aminoalkylphenylalkanecarboxylic acids in
ths solid pbase. Vysokom.soed. 2 no.1:92-96 Jj6 .160.
f(MId'13:5)
1. Voesoyuznyy nauchno-iaaledovateltakiy inatitut iskusstvannogo
volokna.
(Condensation products) (Acids, Organic)
BOODANOT,_Bj.; PETUKHOV, B.V.; KOIMRASHOVA. S.M.
New fibers based on copolyasters. Khim.volok. no.6:21-24 '59.
1. Vsesoymny7 nauchno-issledovatel'sIdy institut iskusstvannogo
volok-na.
(Textile fibers, Srnthetio) (Esters)
IBr~
5/190/60/0W/01/11/021
M29 U/ B06~
AUTHORS: Volokhina, Ao V., Bogdanov, M. N- Kudryavvi,~v, G. 1.
TITLE: Polycondensation Reactionslirk the Salxd 111,
Polycondensation of p-Aminoalkyl-phenyl Alkana Carboxy2ic
Acids in the Solid Phase
PERIODICAL: Vysokomoleku1yarnyye spyodinewya, 1960, Vc1l, ?, Nn, 1,
pp~ 92-96
TEXT: The authors previously described the synthesis of :~arboxyll.~%
acids of the general formula*H2N(CHOWC6H "n(CH,V00H (m
41
n - 1'29394) and their polycondensation (Rolfs~ The kinet!C3 of the
poly;oondensation of the followIng a.tj-amino acidslis examined here;
p-aminome thy 1 -phenyl propionic aoid (1), valerie
acid (11); p-aminoethyl-phenyl acetic acid (ITU: p-amincqthyl-phenyl
propionic acid 1IV),- p-umincethyl-phenyl htit-vr!,-~ 13L,~,'d ~V'i: am.1 P-amonoz-
ethyl-phenyl valeric acid (VI)~ The kinetics of ~he were
Card 1/3 V~
82G60
Polycondensation Reactions in the Solid Phase. $/190/60/002/01/11/02i
117- Polycondensation of p-Aminoalkyl-phenyl B004/BO61
Alk~,-,ae Carboxylic Acids in the Solid Phase
observed during the reaction by continuous weighing, and the degrea of
polymerization was established by determination of the separated water.
Fig. 1 shows the kinetics of the polyoondensation of the above i7caipounda'
and Table 1 gives the experimental datat It follows from thi3 that the
initial temperature of polycondensation falls with sinking melting point
of the amino acid and with increasing content of methylene gr,Q(;' As
regards p-aminoethyl compounds, the temperatqre range between tie
initial temperature of the polycondensation and the melting point r,-f the
acid decreases with increasing content of methylene groups and with
decreasing melting point of the acid, This connection was not observed
in methyl-aubstituted compounds, With increasing content of methylene
groups, the polycondensation reaction rate increases, Fig. 2 shows the
change with time of the degree of polymerization of compound (1), which
is not linear. Table 2 gives the activation energies for the poly-
condensation of compounds (1) to (VI)-, There are 2 figures. 2 tables,
and 4 references: 3 Soviet and I US,
Card 2/3
Polycondensation Reaotions in the Solid Phasc S/19O/6O/OO2;/Oi/11/O2i
III. Polycondensation of p-Aminoalkyl-phanyl B004/BO61
Alkane Carboxylic Acids in the Solid Phase 82080
ASSOCIATION: Vsesoyuznyy nauchno-isaledovatei-skty ingtitul,
iskusstvennogo volokna (A11,J1n)en Pp.-,earch
- Institute of Synthetic Fibers)
SUBMITTED: October 9, 1959
Card 3/3
5.361o 77397
SOV/79-30-1-58/78
AUTHORS: Bogd-anov, M., N,, Kudryavtseva, G. I., Spirina, I. A.
TITLE: Synthesis and Polycondensation of p(Aminoethyl)phenylalk-
anecarboxylic Acids
PERIODICAL: Zhurnal obshchey khimii, 1960, Vol 30, Nr 1, pp 263-267
(USSR)
ABSTRACT: A series of new p-aminoethylphenylalkanecarboxylic
acids was prepared and condensed to polyamides. This
Is a continuation of the authors' previously reported
work (ZhOKh, 29, 986, 1959). The synthesis was made
according to the following scheme:
C6115(cill),C0011 C1C11A114(C112).C0011 - CNC112CG11j(C112).C0011
11G1 - N112(G11j):CG114tC11j)4,r0011
Card 1/5
Synthesis and Polycondensation of p(Aminothyl) 77397
phenylalkanecarboxylic Acids SOV/79-30-1-58/78
ASSOCIATION:
Chloromethylation of the phenylalkanecarboxylic acids
was made according to previously described procedure
(M. N. Bogdanov, ZhOKh, 28, 1621, 1958). Hydrogenation
of the p-eyanomethylphenylalkanecarboxylic acids was
conducted according to the procedure described in:
P. Ruggli, A. Businger, Helv. Chim. Acta, 25, 39 (1942).
The following four acids were prepared for the first
time: p-aminoethy;phenylacetic acid W, P-aminoethyl-
phenylpro ionic acid (II), p-aminoethylphenylbutyric
acid (1115, and p-aminoethylphenylvaleric acid (IV).
The yields, compositions, and properties of the acids
obtained are listed In Table 3. Some conditions of the
polycondensation of the aminoacids and the properties
of the polyamides are given in Table 4. There are 4
tables; and 4 references, 3 Soviet, 1 Swiss.
All-Union Scientific Research Institute of Synthetic
Fibers (Vsesoyuznyy nauchtio issledovatel I skiy institut
iskusstvennogo voloicna)
SUBMITTED: Janip- ry 2, 1959 Card 2/5
Synthesis and Polyconde nsation of p(Aminothyl) 77397
phenylalkanecarboxylic Acids SOV/79-30-1-58/78
Table 3 p-Aminoethylphenylalkanecarboxylic acids
N (CH,, OOH
"2 -j2C6H4(CH2)nC
Y'.0.14 rMP
t ~,A /e- VAL feel
_T_N U 1 11 1
N
11 1 53 67.29, 67.24 7.17, 7.21 7.96, 7A 67.02 7.37 7.82
1
f 2 Cp 68.44, MOG. 8.12, 7.84 7.24, 7.18 68.37 7.82 7.24
(111 :1 50 69.50. 69.70 M2, 8.15 6.95. 7.W 69.62 8.20 6.75
(IV 4 53 199.0-A99.50 70.72. 70.49 &47, 8.3t) 6.32, 0.27 70.W &59 6.33
Since the temperature,at which polycondensation of
(I), (II), and (III) in the solid phase begins is lower
than their mp the latter cannot be determined.
*** The acid is readily soluble in aqueous alcohols;
therefore) aqueous acetone was used for Its crystalliza-
Card 3A tion.