SCIENTIFIC ABSTRACT BOGDANOV, L. M. - BOGDANOV, M. N.

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TSARMV, B.A.; BOGWOV. L-X-; KLMSH, G.G.; LIPGHLNMTA, V.I. -Possibility of partial substituting of synthetic polymers for gelatin in photographic evalsions. Tekh.kino i telev. 4 no. 8:8-11 Ag 160. (KERA 13:8) 1. Leningradskly institut ldnoinzhoneroy. (Photographic eft1sions) T. -33056*.66 Wr TJP(Q)' SOURCE CODE: XCC Me -AM240 DR/0077166/du 0 1 0 7 AWHOR: 1(hismatullina, Ls' A Levi, S sMs; Boeanov, Le M.; Kukhtin, V. A*' ORG: All-Union Scientific Research Motion Picture Institute (VseooyuzTVy nauchno- issledo-vatelskly kinobt-ofiwititut) - TITLS: Investigation of the application of grafted gelatin oopol~mrs for graphic omlsions p SOURCE: Zhurnal nauchnoy i prikleAnoy totografti i kinexatograM, v. L1. no. 2. 1966, 81-87 TOPIC TAGS: photographic emasion, graft copolymr, photographio processing, photographic property ABSTRACT: Conditions are worked out for synthesis of grafted gelatin copolymers. As a result of physico-mchanical and photographic investigations of the grafted gelatin copolymrs, introduced to the emLlsion in quantities of 25-50%, it has been establish that these materials have no negative effect on the photographic properties, but increase, the eldsticity. strength and heat stability of the anx1sion layer, which makes the layer imune to separat n during high-temperature photographic processing, Orig* site hast 9 tables* FAVY SUB CODE: 14, 07 / SM DATEt '15Sep64 / atIG REFt 002 / OTH REFt 001 BQGDAHOV.- L. -N. Training of radiologists and radiologioal laboratory assistante on a local basis. Zdrav. Roo. Feder. 6 no.6:25-28 A 162. 1. Is rentgenovskogo teentra, (sav. L. N. Bogdanov) Kirovskoy oblastnoy klinicbeekoy bollnitsy (glavnyy vrach V. N. Potapenko). (RADIMOGr, MEDICAL-STUDY AND TEACHING) ',~~Ioty I-f Rnentg nolc- 6, 1 d Rad logi 8 t Vr 6 t r" 11 BOGDANOV, L.S. Tenth Pacific Science Congress. Okeanologiia 2 no.1:185-188 '62. (MIRA 15:2) (Pacific Ocean--Congresses) BOGDAFOV, L.1% Organization of X-ray servJLca il-I a corsolidated district. Zdrav. Ros. Feder. 7 no.5:111-14 lo~,163. (IVIR.A 16:6) 1. Rentgenologicheskiy tsentr (zav. LX.BoCdanov) Kirovs!-,oy oblastroy kAmicheshoy bollnitsy (glavirry vrach V.I-.Potapenko) i orranizatsiorno-~metodichesliy otdol ( zav. - prof. 1. 1-1. Yalchnich) Eauchno-insledovatellskogo rentgenorad-iologichesko- go instituta (dir. -- prof, 1..G.Lagunova) Ministcr5tva zdra- voohhranoniya RSFSR. (MIDIOLOGY, vE DICAL) BOGDANOV, Leonid Pavlovich [A knowledge of economics is importantl Znanie ekonomiki - jol'shoe delo. Moskva, Mosk. rabochii, 1961. 33 P. (MIRA 17:2) BOMANOV, L.V.- LOSW, H.Z* The MA-1010-type six-spindle drIlling-machina unit, Blul. tal&.-okon.inform. no.12129-30 158. (HIRA 11112) (Drilling and boring machinery) 10151 - ROZH1SSKIYJ. M'O.), starshiy rauchnyy sotrudnik; 11 IA!'OV, 1 V,, aspirant; MARRUVA I , starshiy laborant I. . I - I ~ 11 1------ Determining the volume of circulating blood in adult horses arA dairy cow:3 by the T-1824 homatocrit method, Izv. TSKhA no.5: 217-221 '61. (MIRA 14:12) (Blood.--Circulation) (Horses) (cows) BOGDANOVI L.V., aspirant Blood volume And erythrocyte indices in connection with the productivity and body type of dairy cows. Izv. TSKhA no.6t 160-171 161, (NM 16:8) (Blood) (Dairy cattle) BOMMOV, L.V. "The Blood Volume and Total-Content of the Basic Components of the B192,1woof Milk Cows of Various Constitutional Types"; dissertation for the degree of Candidate of Biological Sciences (avarded bj the Timix7asev Agricultural AcadmW, 1962) (Izvestlya %,Lmir~mzevakoy Sellskokhozyaystvennoy Akademii, Moscow, No. 2. 1963, pp 232-236) BOGDANOVIO.K.; KnCOWMG, M. Stimulative effect of the peat and lignite humic acids on the striking of vine grafts. Zemljiete biljka 11 no.01325-328 v62. 1. Poljolwivredni fakultetp Zwm. I - I I I BOGDANOV, -M. Ps Hov ve imerease the productivity of pumping equipment. Zhil.-kom. khos. 5 no.lt27-28 1556, (MLRA 8:5) lo BrigAdir elesarno-zontashno), brigedy Kalizduakogo tresta wVbdo- kana3m. (Ruoping machinery) BOGDANOVO M. 'r... ........................... The new face of the Pechora Basin. Sov.shakcht. 3-1 no.11:24-25 N 162. (KMA 15:12) 1, GILavnyy insh, Kombinate, ugolinykh trestov i predpriyatiy rorkutskogo rayona. (Pechora Basin-Coal mines and mining) WD-MW, It.; MUSSON, A.; -VOLKOV, V.; VOUESEIMMY, S.; ZEUNMIN, S.; N.; KOREIW. P.; IMVINSXkYJL. I.; KULAGIN. M ; MARSAVIN. M.; MINAKOVA, P.,- POPOVA, M.; BUKKUY, S.; SHTAlTOVNff: A.; FAINTKU, L. YAOITISTOV,.P.; CHUIAFOVA, M.; YATSYNIN, N. Obituary. Ptiteavodetvo 0 no.2:48 F 159. (MIU 12:3) (Shutov, Nikolai Ivanovich, d..1958) BULGARIA B-OGANDYs Pr_ M_ t OVL, Ruse "Mcperience in Prophylactic Treatment of Hene.Against Broodiness on a Large Scaleff Sofia# Veterinarna Sbirka, Vol 63, Wo 3, 1966, pp 26-28 Abstract: It was established in work conducted in the USSR, Hungary, and Germany that developmen t of the mass instinct f6r',brooding~by!.-hens results in considerable losses: every yearg from March ~, to,IV11 4o% cof the hens discontinue egg-laying for 20-40-60 days. A number of reme- aiees- for the condition in question has been developed, among them Ovogen-1, which has a therapeutic effect and has been proposed by MO Bogdanov and P. Gabrovski. These investigators also developed the prophylactic Ovogen-2, which contains the vitamins A, E, and 29 112 BULGAMIA BOGI*NQV, Dr. M.; District Veterinary Hospital, Ruse "Application of the Blood of Pregnant Mares for Raising the Rate of Conception in Ewes" Abstract: It was found inwork conducted In the USSR and elsewhere that serum of the blood of pregnant mares can be used to advantage in sheep breeding because it raises the rate of fertilization of ewe.s. Prof. P. Shatalov develoDed in 1960 a method whereby a preparation that Is richer In ho-rmones than serum or citrated blood can be prepared from the blood of pregnant mares. This pre- paration, designated KZhK (blood of pregnant mares), has been produced in 1965 under the supervision of Prof. Shatalov at the laboratory of the District Veterinary Hospital at Ruse. Tests carried out on ewes indicated that the preparation was effeetive when applied In optimal doses, Table. END - CE-110 CSO: 2000-N (53 pages) V, U PHASE I BOOK EXPLOITATION SOV/5463 Sovetskaya antarkticheskaya ekspeditslya Vtoraya morskaya ekspedillslya na d/e "Ob"', 1956-1957 gg.; obshcheye opisaniye i nauchnrye rezul'taty (Second Marine Expedition on the Diesel- Electric Ship "Ob' 1956-57, General Description and Scientific Results) Leningrad, Morskoy transport, 1950. 175 p. (Series; Its: [Materialy] no. 5) Errata slip inserted. 1, 200 copies printed. Sponsoring Agency: ArkticheBkiy.i antarkticheskiy nauchno-issledovatel'skiy institut. Ed. (Title page): I. V. Maksimov, Doctor of Geographical Sciences, Professor; Ed. : L. G. Kaplinskaya; Tech. Ed. 0. 1. Kotlyakova. PURPOSE: This book is Intended for oceanographers. meteorologists, and hydiochemists. Card 1/6 Second Marine Expedition (Cont.) SOV/5463 COVERAGE- The present volume. the fifth in a aeries of seven, is a collection of articles (except for two) devoted specifically to the oceanographic, meteoro- - logical. and hydrochemical findings of the Second Soviet Marine Expedition conducted on the diesel ship "Obl" (L A. Man. Captaio during 195G-57. The first two articles outline the Expedition's organization and program. and provide a general account of its activities during the 223-day voyage, which covered more than 40, 000 miles of the Atlantic. Antarctic, and Indian Oceans. The expedition was sponsored by the Arctic and Antarctic Scientific Rcs6rch Institute of the Glavscvmorput' Ministerstva morskogo nota SSSR (Main Ad- ministration of the Northern Sea Route of the Ministry of the 17%lerchant Ma- rine of the USSR) as part of the International Geophysical Year pr4ogram. Its purpose was to investigate 1) atmospheric processes In the Antarctic region and their effect on the earth's general circulation; 2) basic regularities in the distribution of waters in the southern oceanic one, 3) exchange of the waters of the southern seas with the waters of the world ocean. 4) geological structure of the sea bottom in the Antarctic region, and 5) the plankton, benthos. Card 2/6 Second Marine Expedition (Cont.) SOV/5463 ichthyofauria. and microorganisms of the Antarctic waters. Observations of the magnetic field of the earth were also made. The expedition, headed by Professor Igor' Vladislavovich Maksimov, Doctor of Geographical Sci- ences and Professor at the Leningradskoye vyssheye inzhonernoye morskoye uchilishche imeni S. 0. Makarova (Leningrad Higher Marine Engineering School imeni S. 0. N-Takarov). consisted of the following 8 scientific task forces: nerometcorological (headed by Leonid Gennadlyevich Sobolev); hydrological Wirill Vladimirovich Nloroshkin); geological (Aleksandr Petrovich Lisitsyn); hydrochemical (Alekscy Nikolaycvich Bogovavlenskiy); hydrobiological (Viktor Aleksandrovich Arsenyov); geophysical (Nikolay Panteleymonovich Grushinskiy): geographic (Gravrila Dmitriyevich Rikhter); and hydrographic (Yuriy Aleksandrovich Gordeyev). A complete list of the names and affiliations of the 65 scientific and administrative members of the Ex pedition Is contained In the first article. The articles were written by members of tho Institul oke~inologii Akademii nauk SSSR (Institute of Ocean- ology Academy of Science-. USSR), Gosudarsivennyy okcanograticheskiy insti?.t Gidrometsluthby SbSR (State Oceanographic Institute of the Hydro- Card 3/6 -Second Marine 'Expedition (Cont.) SOV/5463 meteorological Service of the USSR), Vscsoyuznyy nauchno-issledovatell- sMy institut rybnogo khozyaystva.i okcanografii (All-Union Scientific Re- search Institute of Fisheries and Oceanography), and the Arctic and Ant- arctic Scientific Research Institute. There are no references. TABLE OF CONTENTS: Foreword 5 Maksimov, 1. V. Second Antarctic Marine Expedition 7 Man, I. A. Second Voyage of the Di6sel Ship "Ob' 19 Khromov, S. Atmospheric Circulation and Weather During the Course of the 1956-57 Voyage of the "Ob'" 27 Gutnikov, V. P. Synoptic Processes in the Southern Hemisphere 84 Card 4/6 Second Marine Expedition (Cont. SOV/5463 Sobolev, L. G. Work of the Aerometeorolo~ical Unit 101 Moroshkin, K. V. Hydrological Investigations 106 Moroshkin, N.V.. and M. A. Bogdanov. Results Obtained With an Electromagnetic Current Meter in the Indian Ocean and in the Southern Part of the Pacific Ocean 124 Morozov, A. P. Observations on Sea Dist0bances 138 Gordeycv, Yu. A, Hydrographical Works 144 Tomashunas. B. Ya. Ice Observations 154 Bc)goyavlenskiy, A. N. Hydrochemical Investigations 159 Card 516 Second Marine Expedition (Cont.) SOV/5463 Kutyurin, V. M. Determining the Content of Chlorophyll in Sea Water and the Spectral Analysis of Phytoplankton Pigments 173 AVAILABLE: Library of Congress (G860. S58) JA/dwm/bc Card 6/6. 11-1-61 :BOGDANOT, M.A., mladshiy P-auchnyy sotrudnik Measuring surface water temperatures with electric thermometers in the southern part of the Pacific Ocean. Inform. biul. Sov. antark. ekep. no.20133-37 160. (14IRA 13:9) 1. Voesoymnyy nauchno-iseledovatel'Bkiy, institut morskogo rybnogo khozMstva i *akeanografii. (Pacific Ooean---Ocean temperature) S/194/61/000/008/019/092 D201/D304 AUTHOR: Bogdanov, M.A. and Ivanov, Yu.A. TITIE: Sea currents and flow measurements by the 9M%4T (EMIT) instrument PERIODICAL: Referativnyy zhurnal. Avtomatika i radioelektronika, no. 8, 1961, 17, abstract 8 V143 (Tr. In-ta okeanol. AN SSSR, 1960t 39, 80-84) TEXT: Comparison of results of flow measurements by the EMIT (electromagnetic flow meter) with those carried out by direct methods has shown that large discrepancies exist in certain cases, the E241T output signal varying during the observation period by as much as 1.5-5 times. The cause of the error is the existence in certain sea regions of telluric currents. In regions where these currents are absent the EMIT measurement results agree with those of instrumental methods. The need is stressed for studies of tellu- ric ocean currents with the aim of understanding, their character aud Card 1/2 S/19X361/000/008/019/092 Sea currents and flow measurements... D201 04 determining the regions where the MIT measurement method can be applied. 7 references. Z-Abstracter's note: Complete translation-7 .001, Card 2/2 TIHOFMV., I.A.; FOTAYCHUK, S.I.; BOODANOV. M.A. - Apropos of V.V*Roasov's article "Tidal variability of hydrological conditions." Okeanologiia 2 no.4:731-734 162. (MM 15:7) (oceanography) (Rossov, V.V.) 5,0,~ MMACHMW,, I.A.; POTAYCHUK, S.I.; EDELIMAN, M.S. BOG~W Hydrology in the Faeroe-Iceland area. TRUDY VNIRO 46-.63.-64 162. (MIRA 15:10) (Faeroe Iolands rAgion-Oceanography) (Iceland Igion-,oceanography) BOGDANOV, M.A. -,., - ~., ~ - ~, ~ - . . 4'. " Semiconductor rectifiers reduce the consumption of electrim power in nonfemous metallurgy. TSvet. met. 28 no. 12:4-6 D 165 (KITLA' 19:1) BOGDAVOV $Mail .497ich; ARKWORLISKIY,S.B., redaktor; TMMMff,M.N(; I. k-hnnichookiy redaktor (Work-pro, protection and safety engineering in the cotton veaving industry] Okhrana truda I tokhnika basopasnosti v khlopkotkatskom proigvodstve. Moskva, Goo.nauchno-takhn. izd-To Ministerstya pro- mysh.tovarov shirokogo potroblentia SSSR, 1955. 137 p. (XIMA 9:1) (Cotton manufacture--safety measures) BOGUANOVO X. I. "The Problem of the Role of the Nwrous System ip i6munogenesis During Brucellosiso" Cand Vet Sci,, Inat of Experimental Veterinary, Sci,, Moscow,, 1953. (RZhBiolj,'No 7,, Dec 54) SurvW of Scientific and Technical Dissertations Defervied at USSR Higher Mucational. Institutions (12) SO: Sum* No* 556, 24 Jun 55 USSR / Microbiology, Microbes Pathogenic for Man F-4 and Animals. Bacteria. Brucelli. Abs Jour: Ref Zhur-Biole, 1958, No 17, 76773. Author t Boadanov. M. I. Inst 7Er-yat_MongoT-2W6vrter1nary Institute. Title On the Immunological ReorgantEation of Animals with Brucellosis Depending on the Method of Intro- duction of an Antigen. Orig Pub: Tr, Buryat-Mong. zoovet. In-ta,, 1956, vyp. 10, 147- 154, Abstract-. It Is shown that with a subarachnoid Introduction of brucellosis antigen, the corresponding agglu- tinins in rabbits appear on the third day; with subcutaneous Introduction - on the fourth, and in the lowest titers; while with intramuscular intro- duction, the appearance of agglutinins occur more Card 1/3 3z USSR / Microbiology, Microbes Pathogenic for Man F-4 and Animals.. Bacteria. Brucelli. Abs Jour: Ref Zhur-Bfol,, 1958, No 17, 76773o Abstract- Infectious diseases, the immediate introduction of antigen In the region of CNS causes a more rapid Immunological reorganization of the organ- Ism than during other methods of Introduction. M, Ya, Boyarskaya. Card 3/3 33 BW didat t0dinichaskikh nauk. Modm,m standard Iwacting design for pipeline trenches. Sbor. trud- VNIIGS ao*6:107-322 155. (mm 9:7) (pitches) (pipelines) PQQD,ANOV, FaTROFAN IVANOVICH N13 735-91 .B6 Remont Eleictroka' Na Iesosekakh (Repair of Cables Through Wooded Section Clearnings) VVk;a ' Goslesbumizdat, 1955. 25 P. Illus., Diagrs. (V Pomoshch' Mekhardzatoram lesozagoto Vok) m lp 4 U I PA t -0 401fa* f, 1 0 00 "t*0- 6- Oytol* mb 01141114 all owvl..- lubimt 14 SWrt" all tbt it go - O0 s um I r the 11 ,m - ut 1:, 1XI14400M.-A cl-PfCVA'Wva (N and Cl it, tbt llf~v, h N j v .; 0 v t W I 19is. its wkkb Wit Was trt W& of PhNOo and phe" j 90 c kd V 1 111WOU"ll W018 va usald 4 ' 00 a " 0 ..og .11ALLUKICAL Ll?t&4?Vfl CLASIVICATIOP: 'we U 0 11 10, a It lt I I( It It It OIKL*ll 1:1. t, It It P, 00 0 filb cot so q* It. K. 191khman and M. 1, it, 1 Nov 30 1034. The uxit[at~.tj 1,1% 1 ant bracrat bt di;;i;;d In coned. i ISt k, and atithta l q is OrM. by Introduelkstalstmm into the Qn. f W J I q 0 A - J '.go .90 [hule .00 zoo 00 A IN. L A StIALLU116KAL LIT984T%*9 CL41WICAT" Ij Ott I I 131041a w 0 lei u It It 't a tt itxw a 1 114 0 ;01 4; 01111.1 00, J. q o 0 0 a $14 0 0 0 0 0 C 0 a 0 ee 00 i lit d 43 goo :g x ItIvulliw 19U. 4. ft*", (AugI AUbWd. ii ft~_"%L YW 01~m']W I .. 'it t1) bft hrwd aftm (41Q m,vemvvd by attem- 3 Q6 roamt (U lo - . W Id, #NJ 0Y - I ) jS Mae PY .1 f. As a =by-Wt uf *W"d Sony is ]%ON,, '14. Wsx" tj"~Ij. "wjww she se of PhOH it Th materw eco-nd- aw *a lmtnmwmg (2-,,1* Z owwv voc," 11*60 R. T. X 46 fth ago sloe* see goo gee see j, *A '0., Ist vivo I &&1i c"t It NI IIm 0 alla it It 11.0 ~19, AV to0 000000 0 see 1.0 Lee 09 17 Solution --A-bg. M;-, s;6n- ast-d ;n"u the ~An o ,!v7 ~-,ter. iad ttv~; v!i '01,, -77-77~7:-777 BoMkMTKO, A.V.; POGDANOV. M.I.; FARBMOV, M.I. Industrial synthesis of vinyltoluene. Uch.zap.IArosl.t9khnol.inst, 2:33-46 157, (MIRA 129.7) (Chemistry, Technical) (Styrene) ~-v- ~~, - J- I BOADAMINKO, A.V.; BOGDANOV,.M.I.; FARBEROV, R.I. Investigating the dehydration process of ethyltolueas and vinyltoluene. Zhur.prikl.kbim. 30 no.6:927-932 Je 157. (MIRA 10:10) 1. Yaroslavskiy Takhnologichaskly institut. (Dehydration (Chemistry)) (Toluene) i KOLOBIKHIN. T.A,,, ISUOTAI N*Ao; OARMONOT, I.T99 red*; ZONIS. 6.A,, rede; IMIMIRA, Ye.T., red.; XRT-TK , Ye.Te., tekbn.red. (Analysis of the products obtained in the industrial preparation of bivinyl from butane] Analis produktov proizvodstva divinila iz butana. Yod red. I.Y.Oarmonova. Leningrad, Gos.nauchno- tokhn.izd-vo khimelit-ryp 1939, 115 (MIRA 13:2) (Butedlene) (Butene3l 87675 ZZ004 1 Is 2~ A005/AOO1 Translation from: Referativnyy zhurnal, Khimiya, 1960, No. 21, P. 331, # 85707 AUTHORS: Bogdanov, M. I., Bol'shakov, D. A. TITLE: Thermodynamical Calculation of the Main Reactions in the Process of Producing Isoprene From Isopentane PERIODICAL: Uch. zap. Yaroslavsk. tekhnol. in-ta, 1959, Vol. 3, pp. 47-62 TE(T: The equilibrium output of isoprene was thermodynamically calculated for for the dehydrogenation of isopentane, isoamylenes, and isopentane-amylene mixtures In a wide temperature range at 1 at without dilution and In the presence of an Inert diluent (water); on this basis it Is concluded thitt the one-stage dehydro- genation of the lsopentane-amylene mixtures diluted by an inert diluent is most efficient. In case of the dehydrog8nation of isopentane, the maximum conversion in Isoprene amounts to 34.5% at 600 0 and the molar ratio of Isopontane : water 1 :' 5. In case of isopentane-amylene mixtures, containing 30 Imolar % of isoamylen% the maximum conversion of isoamylene in isoprene at 6250C and the molar dilution by the Inert diluent in a ratio of 1:5 increases up to 38.1% instead of 16.4 without dilution. I. Konenko Translatorts note; This is the full translation of the original Russian abstract. Card 1/1 50) SOV/80~32_3-24/43 AUTHOPS: Bogdanov, M.I., Krushinskayn, Ye.P. TITLE: The Study of the Process of Separating Butylene-Divinyl Mix- tures by the Method of Chemical Sorption (Izucheniye protsessa razdeleriya butilendivinilovykh smesey metodom khemosorbtsii) PERIODICAL: Zhurnal prikladnoy khimii, 1959, Vol XXXII, Nr 3, pp 603-608 (USSR) ABSTRACT: The effect of the chemical composition of the solution, the temperature and the divinyl concentraticn on the sorp'tion capacity of the water-'ammonia solutions of copper acetate is investigated here. These solutions were prepared from elec- trolytical copptr in the.form of wires of 0.3-0.4 mm in dia-. meter, technical acetic acid of 98.74,9-ammonia water with a content of 25% NH3 and lip .id ammonia. The scrption was tested on mixtures containing 91,.7 divinyl and at a temperature of OIC. The sorption capLLcitf i_-. ~.etermined by the content of monovalent copper in the .solution. 1f this content is 3.3 0-atom/l, the solubility of d.ivinyl is 4-4 weight percent. At Ia lo--.Yer contePt the solubility decreases. A higher content has only a slir-h~ Card 1/2 effect on solubility. The solubili!,.' V1 :.!11.111-1 1 SOV/BC-32-3 _44.`,'3 fl-, I The Study of the Process of Se-,.,arating Butylene-Divinyl Mixtures ty :.-e Method of Chemical Sorption its concentration (Pigure 2). The effect of thv teiulierature was investigated within the range of from -9 to +200C. The solubility increases noticeably with the decreaso of tempera- ture. There are 2 dinUrama, 3 tables, 1 graph, and 12 references, 4,of which are Soviot, 5 English, 3 American, 1 German and 1 French. SUBMITTED: October 19, 1957 Card 2/2 ATHOR: Bogdanov, M. I. s/o6A A 0/000/01/05/024 B0227BOO8 TiTh:' -Calcula-t-lo-n-7-or the Equilibrium of the Dehydrogenation Reaction of leopentan I ls6amylenes,jand Their Mixtures to Isoprenel PERIODICAL: Xhimicheskaya promyphlennoott, 1960, No. 1, pp. 25 - 31 TEXT! The investigation of the thermodynamioslof the dehydrogenation processes mentioned in the title was the aim of the paper under review.' The dehydrogenation of isopentane to isoamylonesp which in their turn are dehydrogenated to isoprene, takes place in this process. The single- and. two-stage process of inoprene production is described and the importance of thermodynamic calculations for the determination of the maximum iso- prens yield under given conditions is pointed out. Equations for the cal- culation of the reaction equilibrium at the dehydrogenation of isopen- tane to isoamylenee and of isoamylenes to isoprene are mentioned, and the dependence of the values of the equilibrium constants at the dehydro- genation of isopentane to isoamylenes and of isoamylenes to isoprene in Card 1/2 Calculation of the Equilibrium of the Dehydro- S/064/60/000/01/05/024 genation Reaction of Isopentane, Isoamylenes, B022/BO08 and Their Nixtures to Is9prens the temperature range of 427-7270 is given (Table 1). The composition of the equilibrium mixtures at the dehydrogenation of isopentane to iso- amylenes and isoprene at 427-7270, atmospheric pressure, without dilu- tiong and in the presence of an inert diluent, as well as the equilibrium composition of the gas mixtures after separation of the inert diluent, were caloulated on 'the basis of the equilibrium constants calculated (Tables 20). The same Yalues were also given for the dehydrogenation of isoAmylenes to i o r n (Tables 40) and of isopentane-isoamylone mix- a fTeb;es 6P7)- N- 1. Shuykin and his collaborators tures to isoprene a M. I; Bogdanov and D. A. Bol'shakov are mentioned. There are 7 tables and 10 referenoesp 6 of which are Soviet. Card 2/2 S/064/60/000/007/003/010 B020/3054 AUTHORS: Bogdanov, M. I. and Krushinskaya, Ye. P. TITLE: Iso ation of =aj From Hydrocarbon: Mixtures by Chemisorption With Cobper Salt Solutions PERIODICAL: Khimicheskaya promyehlennostly 1960, No- 7, PP- 10 - 15 TEXT: The most complicated and hitherto insufficiently studied stage of synthesis of isoprene from isopentane is the separa-tion of hydrocarbon mixtures with isolation of highly concentrated isoprene. Extractiong azeotropic and extractive distillation, and chemisorption can be used for this purpose. Selective solvents used for separation by extraction are acetaldehyde, propionaldehyde, propylene oxide, methyl formiate, methy.1 alcohol, citric acid triethyl eater, dimethyl phthalate, furfuroleg lactonitrile, ethylene glycol and its monomethyl eater, ethylene glycol mono- and diacetate, ethylene chlorohydrin, aniline, toluidine, phenyl hydrazine, esters of low polyglycols of ohlorocarbonic acid, etc. To increase selectivity, it is convenient to add water to the solvents, or to extract hydrocarbon mixtures by a mixture of two immiscible solvents. Card 1/4 Isolation of Isoprene From Hydrocarbon s/o64/60/000/007/003/010 Mixtures by Chemisorption With Copper Salt B020/B054 Solutions The industry used extractive distillation with aqueous acetone combined with a simple rectification. The volatilities of the most important hydrocarbons C 5 (referred to isoprene) mixed with aqueous acetone, (80% by volume of the mixture) are compiled. A comparison of these data in Table 1 shows that the volatility of paraffinic and monoolefinic hydrocarbons increases considerably in the presence of aqueous acetone, whereas the volatility of piperylene does not change. Besides acetone, it is possible to use various polar organic compounds containing oxygen, nitrogeng and sulfur (furfurole, pyridines amines and their mixtures with water$ low aliphatic nitriles and their mixtures, dimethyl forms- mide, dimethyl Sulfolane, etc.). The authors deal. with the separating components for the azeotropie distillation, the extractiveand simple rectification, the reaction menhanisms, and analyze the reaction products. The most efficient method of separating hydrocarbons C 5 with isolation of highly concentrated isoprene Is the chemisorptionl by aque- ous-ammoniacal solutions of salts of monovalent copper. The production of absorption solutions is described. Table 2 indicates the solubility Card 2/4 Isolation of Isoprene From Hydrocarbon S/064/60/000/007/003/010 Mixtures by Chemisorption With Copper Salt B020/BO54 Solutions of isoprene and isoamylene in aqueous-ammonlacal solutions of Cu +- salts of organic acids at OOC. The sulubility of isoprene and Of iBoamylene isomers in aqueous-ammoniacal solution of copper salicylate depends on the ammonia concentration (Table 3). The authors studied the effect of the concentration of isoprene on its solubility in a mixture with amylene isomers obtained by dehydrogenation of isopentane (by 2-methyl- butene-2f and 2-methyl-butene--l) at 0-500C for mixtures of different compositions (Tables 4 and 5, and Fig.). The solubility of isoprene does-not only depend on the composition of the mixtures but also on the molecular structure of the isoamylene isomer. A practically quantitative desorption of isoprene is attained at 800C. Table 6 shows the stability of the absorption solution on heating in ampuls to 1 OOOC. There are 1 figure, 6 tables,and 54 references: 16 Soviet, 28 USj 8 British, I French, and 1 Canadian. Card 3/4 Isolation of Isoprene From Hydrocarbon S/064/60/000/007/003/010 Mixtures by Chemisorption With Copper Salt B020/BO54 Solutions ASSOCIATION: Yaroslavskiy tekhnologioheskiy institut (Yaroslavl' - Institute of Technology . Nauchno-issledovatellskiy instiiwt monomerov dlya SK (Scientific Resear,-.h v Institute for Monomers of Syntheti-3 Rubber) Card 4/4 BOGDANOV,_M.I..,, inzh.; BELqVOLOV, V.T., kand.tokhnonauk; GELESKUL., M.N.P* BUIOW, A.S. Manufaoture and use of framed, reinforced concrete timbering under Arctic conditions. Sbakbtsatrbi, 5 no*4:15--10 Ap 161. (MUtA 24;5) 1. Kombinat Vorkutugoll (for Bogdanov). 2. Peohorskiy nauchno- insledovatel Iskiy ~gol IW institut (for $09lovolov). 3. Tzhtitut gornogo de3A AN SSSR (for Bukbman), - (Pechora Basin-Mine timbering) BOGDANOVp M.I. Calculating equilibria of the dehydrogenation reactions of butane-butene mixtures and of n-butenes to l..3-butadiene. Part 2. Neftekhimila 3 no.4:488-493 Ji-Ag 163. (MIRA 16:11) 1. Yaroslavskiy tekhnologicheskiy institut. BDGPLNOV.,,_1jj. , kand. takhn. nauk; ANISHCHENKO, A.N. , inzh.; ALEKSEYEVA, T.M. inzh. Comparative charaoteristics of aurface and underground laying of process piping. Prom. stroi- 41 no.6:15-17 Je t64. (MIRA 1. Vsesoyuznyy nauchno-issledovatellskiy institut i aanitarno-takhnicheakikh rabot (for Alakseyeva). 17-9) gidrotekhnichaskikh ..010 DIJLINp I.L.; KICHAYEVA, G.K.; POPOV, T,j red. [Long term planning of timber for coal mines] Perspektiv- noe planirovanie leson,aterialov nn udollnykh shakhtakh. Syktyvkar,, Komi knizhnoe izd-vo, 1964. 47 p. (MIRA 18:6) BOGDANOV, M. N. "On the amount of vitamin "C" in milk," Trudy Buryat-Mongol zoovet, in-ta. Issue 4, 1948, P- 100-03-3ibliog: 7 items SO: U-3850, 16 June 53, (Letopie Murnal Inykh Statey. No. 5. 1949)- BOGDANOV, M.N.- TITYURIVA, I.V., redaktor; PJVZM, V.L. tekhaicheakiv i i ma--O, Jr [Poultry raising] Ptitseyodstvoo Moskva, Goo. lzd-vo aelkhoz. lit-ry. 1956. 638 p. (Mm 9:11) (Poultry) zootekhnik; EMNEV, S.I., prof., doktor sel'skokhoz.nau1qjQ"qT GOFMAN, NJ., zootekhnik; GRIGORITEV. G.K., zQoMr6-'~*rZHILKIxff' Z.A.. kand.sol'Bkokhoz.nauk; PENIONZHKZVICH, B.S., doktor biolog. nauk,~prof.; PMO, A.A.. kan(l.biolog.nauk; TRETITAKOV, doktor leallskokhoz.nauk. prof.; USPENSKIY, A.A.. kana.seliskokhoz.nauk; USHAKOV, A.A., kand.veterin.nauk; SHAPOVAIDV, Ta.Ta., kand.sel'Bko- khoz.nauk; TAGODIN, P.Te., zootekhnik-, TATSWIN, N.H., zootekhaik;FZDO- ROVSKIY,X.P., kand.biol.nauk; SYCMK. Y6.V.,.red.; PAVLOVI, X.M.,tekhred. (Poultry raising; a manual for farm managers] Ptitsevodstvo; rukovodstvo alla zaveduiushchego fermoi. Izd.5, porer.i dop. goskva, Gos.izd-vo selikhoz.lit-r , 1957. 495 P. (Bibliotechka 17 1 po ptiteevodstvu, no.1) .(MIRA 12:4) 1. DoyBtvitellnyy chlen Vassoyuznoy aknaamii aellskokhozyaystvannykh nauk im. V.I.Lenina (for Smatnev). (Poatry) OV L BANNIKOV, N.A., red.; GORIKOU, Z.D., .i.1LO ha-01-AXI evich -WAIN. Kra [Making use of poultry for meat production] Ispolizuite ptitsu dlia proisvodstva m1ase. Moskva, Goo. izd-vo sellkhoz. lit-ry, 1958. 68 p. (MIRA 11:5) (Poultry) BOGULIDVj M.N. Valuable lnitiative..Ptiteavodetvo 8 no.9:13-15 S 158. - . .(MIRA 11:10) (POultz7 bresdiug-Study-iiil teaching) BOGDAMV, M. N. Importance of the production of meat-type chickens and principles underlying its organization. Ptiteavodstvo 9 no.6o.6-9 is 159. (MRA 3.2 - 10) ljGlavn" zootekhnik po ptiteevodetvu Hinisterstva sellskogo , khoxyaystva SSSR. (Poultry) BOODANOV, M.N. Raising Ibroilers for market an a specialized activity. Zbivotnovodetvn 21 no.3:7-13 Ur 059. (14IRA 12:4) 1. Glavrqy zootekhnik po, ptitsevodstvu Ministerstva, sellskogo kho- 37aystva, SSSR. (poultry) ARSDISHVILI, A.Yu.; BOGDANOV., M.N.; GORIZONTOVA, Ye.A.; YERSHOVA, Ye.l.; YELE14BAW, N.I.;-TOFS-,-lF.S-h.; URAVAYEV, A.M.;KOLOBOV, G.M.; LOBIN., N.V,., kand, sallkhoz. nauk,-, KUSM4ER, Kh.F., doktor bilog. nank; MISHIN,, P.N.; PATRIK., I.A., kando sellkhoz. nauk; RWIKHj V.K., kand. sellkhoz. nauk; SWTNEV, S.I., akademik; SZIOLETOV~ A.I.; FIIASOV, V.V.; SHKUDOVA, R.I.; SOKOWVA, G.S., red.; ROMANOVICH, Ye.F,,, red.; LETINA, L.G., tekhn. red. [Chickens for mat] WypBata na miaso. Moskva., Izd-vo 11-va sell.khoz, RSFSR 1960. 197 p. (MIRA 15:1) 1poultry) BOGDANOV Mkbail Nikolaye,!Ach; IOFEI Nokbm Shleymovich; DOBYCHINAp I.N.j red.; TRUKMA, O.N., tekhn, red* (Raising obiken for meat) Vyrashebivania miasrorkh t :List, Mo- skvap Gos.izd-vo sellkhoz.lit-ry, 1961. 87 p. 7IM3RA 15: 1) (poultry) 1-!a-(M)/T/EWr-W RM ACC Mt -~~6015055 (A ) SOURCE CODE: UR/0190/66/008/005/0903/0909 AUTHOR: Bogdanov, M. N.; Leshchiner, A. U.; Plyashkevich, L. A. ? ORG: Scientific Research Institute of Synthetic Fiber_(Nauchno-issle44$it6,l'skiy instituT-Iskustvennogo volokna) TITLE: lAtroduction of terminal aromatic amino groups into polycaproamide. (First report in a series on "Synthesis and chemical modification of polyamides with reactive groups") SOURCE: Vysokomolekulyarnyye soyedineniya, v. 8, no. 5. 1966, 903-909 TOPIC TAGS: polymer, amino acid, polyamide, polymerization, molecular weight, amino group ABSTRACT: The hydrolytic polymerization process of -,V".,#prolactiM in- the ptesence of aromatic diamines and other aminocarboxylic acids has been investigated. It was shown that these compounds are regulators of the molecular weight of the poly-c-capr amide'~;d that through them it is possible to introduce into the poly:mer a certain number of aromatic amino groups to preserve the fiberyproduck-4e capacUy. A method of quantitative determination of small concentraflo-n4of-aromatic aiftf*o groups in. the polycaproamide was developed. Orig. art. has: 4 fijurdb,"3 foifi6ldb, and 1 table. [NT] I CODE: 11, 07/ S UBM DAM 22May65/ ORIG REF1 009/. 0TH RM 006 a rd rd UnCt 541.64+601 :~j Awt A AcCRE -,VF5006358- Vnx-- ..,,SOURCE -CODES -~uR/0413/66/0001002/009410094.~ V_ M N-; INVENTOR:i Khar kov, S N'*,-; Bog'danovp M# I Spirina, I,-A*; Leshiner, A. U,-A.; Plyashkevich, L#~ C4 ORG: none, TITLE: Preparative metho.d.for'polyamide Class 39t No, 178102 --tannounced by All-Union Scientific Research 'Institute of*Artificial Fibers (Vassoyuznyy,nsuchn-o-looledovatelsity Institut iskusstvannogo SOURCES Izobreteniya, projiyahlennyye obraztey, tovarnyye xnaki no. 29 19669 94 f(MIC TAds, polyamidel, Carboxyl group$ interfacial polycondensation ABSTRACTS An Author Certll!lcate has been issued for a preparative method for carboxyl group-containing polyamides. The method involves. ~interfacial~polycondensation,of diamines containing no acyclic chains with,bovasuatricarboxylic licid,dichlorides. (BO) SUB 'CODE i 1l/ SUBM DATE t 26Nar63/ ATD PRESSi UDCs: 678o675,002.2 Ah Shilov, E. --n! Bor:damov, '-". N. , About. the mechanis:n of carboxylation and analojous reactions. p. 1060 The presenc-~ is established of a cross reaction ':.et,,men the s-:)Iiuri anilide of n-chloro-ph-myl-carbonic acid and a(-naphtholate *which p-was the intel,711olecullar course of the reaction of formation of anilide of o.---yacid. The Iv7nov Che;~Aco 1'eclinolo:-Acal Inst. Lab. of O.-ranic Gha:,Istry. y 11), 10,4 30: Jo~~--nel -)f Gen-m~l Chemistz7 (U33R) 18 (80) 1,110. ~') (1942-) m m vm/c~ - aft4larutun (COMU) Ain In aromatic reactices are =sauna, TrIphanyllso- 24" c7sawate at& ary1carlonlo &ciao yI&3A ovz2 spand- Ixe cmy-acid anilides on heatIng with pbezolates i24 za*tbalates. ZotablIshe& mativre or areas re- ActIzin between =traullIde of n-ablorphe=1carbonic &GIA avA oC-naphtWAts, thus proving intramolecular *oars& of oxy-aold an1lide formation. Sni=itted. 10 fty 1547. 9/49w, UMAMMMIOU7 CarbMIation lz= Chaalatr7 Phaw2ates :OProblm of the Ybobaciam of Carbox7latlan wA AuLlogaus Rmotions.1" Ye. A. Shilaw', M. N. Bog- Aim6vp ITSMYO Chem-Teoh Inst, lab of,. Org Chan., PP On= Obaboh MtW Vol XV13:r (=)p zvc 6 ZZmarftes Herahzen I awork on moobanimn of oarboaq- i 2ation of phenolates ama axalogous rmetions. SAMM tbiat proofe of intravioleavasr cc-arse cxf these Z~Wctlcns do not vithstwA critiolm. Damanstrates iisizWMMMU views on intermediate co~paunft 98~ BOGDANOV, M. N. Dissertation: 'Research Into tho theory of the Rearrangement of Salts of Amino and Hydroxy Aromatic Sulfonic Acids.' Gand Chem Sci, Inst of Organic Chemistry, Acad Sci Ukrainian SSR, Kiev 1953-~ W-30928 SO., fieferativnYY Zhurnal. No- 5. Dee 1953, Moscow, AN TJSSR *XrAgPPX Vlfcw wmpwunds Imni I nil 'ItL, 'M - N D ARM 7 d ObAcki Khiw, M. N. nord!l nd Q! It* '4 willi 95 10. a ill )IM in a r-ea)M t"heat 13015" PhNH fllterln~v cnpg, in mcxo and tjl,~b%- Save 0.1 S. FhMICIls- CRICI . (", Th f cil c y g A - 0 s C\ e . i t odl6ittatio a)ga %,Pk helm. l col l ti . Ail . btt" (14S g.)*and 44 nil-110 0 sahl with Co. 'dUd 11-0 with 01 am ti hr d 3 fl i . . . . , . uxe re 3.j filtem) and evalw'. Sivc ~on ad0p. of MeOll 20 g. Ilh.,V- IL t,, Olig 13;0 S.) licated withi 410 ml. (CHICIltro.)A' . O.I.VH*SOjl.br.,allovv tostand 4 tin., filltmsl, vvajll~ to a blrupi u-tan up in 10 ml. 2,U011 anti inhed with A.5 (Cf13XNH0j in E't'a jpvc on t1ii1fing 10 2 g. IIAN(Clt, i in: 172-S'. Ills (2,29jrAcs),into 100 mt, Ckl,:CIICN c4 NION 1016"W by hating tlW*prfxlu0 hl tohti 10 Jim Cst go- ItW MrAY(CHICHICA, lit ?J10 tAM2; R.)-ill-4ou lilt.-Iluoll Ifoltil with N f. NA pive after coinpletion of tractiun nnd a6fiAzat*a With Ucl, n., trraimml whb 40%,NaOli. atid. extil. %ith IRIO. N(C11,011,0111MIjbi-14 3W - 6 ulnes in air Ond glasc hich t Rill C; Low gulipin:140 groups in tba MiNC41I.A'All with 10 S. D-CiallsON2 thrillY I hr. at 13 " Save 19A% 2---JaPh1hW m. 179', irbith kmted to O-OD-101 toucly da;kent and does not chanse hR w.p. Similarly iras prepd. 29S'7o Iw9q.-wh'k1; daikerut at DOD-10'. Ph Wed -to form a polymtr bn btaling. Reating ClIgOir MCIN with .3 ntaky propoffloh of PhONQ at W), (ccc- th U9 ermic beginulng 1.6 hrs. pre 39%, Mr, CHISO, Ph C;j W,. 71IN . 'Ais hcattd with an cquiv. atnt. 0 11to 178485' gave it distillate of FhOH and lymer pLArd up pho" and a bralm a with-10% MOR rAyknedi3mine salt 17k 111H pi-crftm p4y"M - M. tOff,'and not in the 13tive humidity the, 'IS Its omithin U-3 7 C Z -E C: 11 tNP110.14-tv till'i 1M. N, 2, 1 0-1, "Ith Oight I;c -Lo!u Ar ff"m 'IP iq ftr- C'P, lvjlg y 7 1, V,.~f "I CP 1 1 1 11 ~, g14. 1, ith com , ". ITO, tile r. -,,I,$ the t,,t. rmwd ivi!h Lt.0 gav, i,-- F"Tul, I !w. ~,Il, Is eml e i~:,OSSA/62 stry Tracer lements I'Sei~ 517 Mechanism. of Rearrangements of Aromatic Salts land Oxy8ulfonic Acids," Ye. A. Shiloy, Act ~:,Xex.!Acad of Sci Ukr SISIR; M. N. Bogdamov, and,A. ~.Shilov, Inst of Org Chem Acad of Sci Ukr SSR DAN SSSR, Vol 92, No 1, PP 93-96 :.Used'Iradioactive s35 In the clarification of the iicba~ilsm of the migration of the sulfonic acid group Inthe salts of aminc. naphthylsulfonic and hydroxynaphthylaulfonIc acidu. Presented 30 Jun 53. 2TkTIO 0 SOV/81-59-5-16377 Translation from: Referativnyy zhurnal, Xhimiya, 1959, Nr 5, p 376 (USSR) AUTHORS: Bondarenko, A.V., Bogdanov,.M.N.,, Farberov, M.I. TITLEt The Industrial Synthesis of Vinyl-Toluenel PERIODICAL: Uch. zap. Yaroslavsk. tekhnol. in-ta, 1957, Vol 2, pp 33 - 46 ABSTRACT: The process of catalytic dehydrogenation of ethyl toluene (I) to vinyl toluene (II) was investigated at 54o to 6000C with a volumetric rate of 200 - 800 ml per 1 liter of the catalyst per hour and with dilution by H20 vapors in the molar ratio of 1:8 - 1:16. With an increase in the temperature to :.~- 580oc and a drop in the volumetric rate to < 400, the yield of II is reduced considerably. The optimum conditions of the dehydroge- nation process are.- temperature 560 - 5800C, volumetric rate 400 - 800 ml per 1 liter of catalyst per, hour, dilution with H 0 vapors 1:12 - 1:16. Thastandard catalyst for dehydrogenation 012 was used as catalyst. A thermodynamic calculation of the dehydrogenation reaction was made. The equilibrium constants and Card 1/2 the equilibrium composition were computed at 427 - 7270C, and also The Indusirial Synthesis of Vinyl Toluene SOV/81-59-5-16377 the apparent energy of activation of the dehydrogenation reaction, being 32,700 cal on the average. It is shown that, in addition to I and II, toluene, zylene, ethyl benzene and styrene are part of the catalysate com- position. A circuit diagram of the contact installation is submitted. L. Volkova Card 2/2 I - SHILOTO YoA.l BOODAVOT, N.V. ' Rearrangament of pelts of aromatic sulfouic acids, Ukr. khtme shur, 24 not W32-?,33 158 (MIRA lliO (Sulionic acids) (Rearrengemout s0bemie tz7)) AtrTHOR Bogdanov, M. No - SOVIT9-2a-6-42163 TITLE: The Chloromethylation of a,ri-Phonylalkane Acids (Khlor- metilirovaniye a, W-fenilalkanovykh kislot) PERIODICAL: Zhurnal obahohey khimii, 1958, Vol- 289 Nr 6, pp. 1621-1623 (USSR) ABSTRACT: The ohloromethylation of the a,A)-phenylalkane acids is of interest as it is connected with the work on the synthesis of monomers usable for the productibn of new fiber-forming polyamidea and polyesters. The chloromethylphenylalkane acids can serve as initial compounds for the synthesis of different a,d)-amines and a, w-oxycarboxylic acids which contain benzene nuclei in the methylene chains. In the pres- ent paper the hitherto not describe& chloromethylation of phenylacetoacetic-, P-phanylpropionidyiyTphenvlbutyric- and 6-phenylvaleric acid of normal structure is realized. This reaction was carried out by means of conducting a flow of hydrogen chloride through the heated mixture consisting of the compound destined for the chloromethylation plus zinc Card 113 chloride solution in 40 % formalin, which had to be careful- The Chloromethylation of aqw-Pherqlalkane Acids SOV/79-28-6-42/63 ly stirred; this reaction is conducted in a similar way in the case of alkyl benzenes (Ref 1). By the chloromethylation of phenylalkane acids a mixture of ortho- and paraisomers formed. However, only the paraisomers were of interest as fiber-forming properties show clearest in the polymers with p-phenyl groups. The p-ohloromethylphenylelkane acids were separated by crystallization of the final products from various solventst and then were purifie&. The use of vacuum distillation was not possible as in that case a polycondonsa- tion of the products took place under the formation of hydro- gen chloride and formation of a yellow, viscous resin. The synthesized p-ohloromethylphenylacetio-t p-chloromethyl- phenylpropionic-, p-ahloromethylphenylbutyria- and p-chloro- methylphenylvaleric acid are titrated with alkali liquors in aqueous alcohol, they quantitatively split off chlorine on their boiling with an alcoYol solution of silver nitrate and they are oxidized under pressure with 25 % nitric acid in terephthalic acid (8o - 9o There are 2 references, 2 of which are Soviet. Card 2/3 The Chloromethylation of apw-Phenylalkane Acids SOV/ 79-28-6-42/63 ASSOCIATION: Vassoyuznyy nauchno-isaledovateltakiy institut iskusst- vennogo volokna (All-Union -Scientific Reddnr~ch Institute foi- Syiithet3','c Fibers) SUBMITTED: May 12, 1957 1. Dipheny.Imthanes--Chemical reactions --Chemical reactions 2. Metbyl chlorides Card 3/3 _1- '-- . Q_LOG.DAIIOV. M.N. - MYAVTSNV, G. I. ~~. K Waye of synthesizing now fiber-forming polymers. Xhim.volok. no-3:3-10 159. (MIRA 12:11) 1. Vaesoyunyy nauchno-iseledovatellskiy institut iak-u9stvennogo volokna (VMIV). (Textile fibers. Synthetic) (Polymerization) 15M 5/103/59/000/06/006/027 ATITHORS., Budanov It N. Petukhov~ B. V, B000007 EMU_ TITLE: New Fibers on the Basis of Co-polyesters-" PERIODICAL: Xhimicheskiy volokna, 1959, Nr 6, pp 21-24 (USSR) ABSTRACT: The authors mention the disadvantages of the polyethylene- terephthalate fiber Lavean; bad colorabIlity, stiffness of the fiber,5roduoed herefrom. Arcording to Western publioations Refs 2. co-polyesters made from dimethyl-terephthalate ~DMT), ethylene glycol and small additions of glycols, di- oarboxyl acids or oxyacids do not have these disadvantages. The authors investigated co-polyesters of MIT with p-oxy--ethoxy benzoio acid (OAD). The synthesis of the methyl ester of this acid from p-oxybenzoic acid (Ref 4) worked out by Y. N. Bog- danov in cooperation with A. A. Strepikheyev (Deceased) is briefly described. It was oarried out in the presence of 0.1% LiOH + Al 0 in the following stages; Reaction of DMT and the 2 3 0 Card 1/3 methyl ester of OEB with ethylene glycol at 160 to 190 , dis- New Fibers on the Basis of Co-polyesters Card 2/3 S/183//59/000/06/006/027 13004/'BOO7 0 tilling of the excess ethylene glycol at 200 - 250 " poly- condensation,at 260-.2750o Figure 1 shows the influence exerted by the additions of OEB to D14T upon the melting point of the co-polymer. The most favorable effect was produced by additions of up to 10%. The authors investigated such co-polymers with 5 and 10% OEB which they denote as oxon-5 and oxon-10. Syn- thesis was carried out in the presence of 0.02,~ zinc acetate. Figure 2 shows that the reaction with ethylene glycol is quick- er in the case of oxon-5 and oxon-10 than in tbat of pure DMT. Table 1 shors the melt-ing temperature and the spaoifio viscosi- ty of the solution-of oxon-5 and oxon-10, Both co-Dolymers were thermographically investigated eccording to V. 0. Gcrba~- cheva and V. V,, Mikhaylov (Ref 6) (Table 2)and showed a lower vitrification temperature than Lavsan, but they are less re.- fractory. The fibers produced from oxon-5 and oxon-10 were investigated with respect to the breaking length 32-35 km), breaking elongation ~30-41.51,',), bending strength ~Fig 3) and elastic deformation Fig 4). Th6 rayon fibers had a softer feel than Lavsan but higher shrinkage 05 to 23%). An inves- Now Fibers on the Basis of Co-polyesters S/163/'59/000/06/006/027 B000007 tigation carried out"with a mercury lamp of the type PRK-2 shoved a better stabilityto light.. coloring tests with acetate dyes shoved better colorability than Lavsan (Fig 5),, There are 5 figureep 2 tableso and 6 references.. 3 of which are Soviet. ASSOCIATION: VKIIV - Vaesoyuznyy nauchno-issledovatelvskiy institut iakusstvennogo volokna (All-Union Scientific Research Inatituts for Synthetio Fibers) Card 3/3 9 3) A4HORS: Bogdanov, M. ff., Kudryavtoev, G. I. sov/79-29-3-50/61 TITLE: Synthesis and Polycondensation of the n-Amino-Methyl-Fhenyl- Alkane-Carboxylic Acids (Sintez i polikondensatsiya n-amino- metilfenilalkankarbono,rjkh kislot) PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 3, pp 966-989 (USSR) ABSTRACT: The compounds which are most suitable for the synthesis of the high-melting synthetic fibers are the polyamides of the homopolycondeneation type of unbranched a,co-amino acids which have n-phenyl groups in their methylene chains in contrast to the less thermostable heteropolycondensation polyamidee. In the present paper the following acids were synthesized; n-amino-methyl-phenyl-acetic-(I), n-amino-methyl-phenyl- propionic-(II), n-amino-methyl-phenyl-butyric-(II-1), and n- amino-methyl-phenyl-valeric acid (Iv) L NH2CH2C6H 4 (CH2)nCOOR(n- -1-4)3 - The corresponding n-chloromethyl-phenyl-alkana- carboxylic.acias (Ref 3) served as initial products. Since it is not possible to aminate the chloromethyl group of these compounds immediately with ammonia, this amination was carried Card 1/3 out by the decomposition of the complexes of Urotropin with Synthesis and Polycondenoation of the n-Amino- BOV/79-29-3-50/61 Methyl-Phenyl-Alkane-Carboxylic Acids the n-halogen-methyl-phenyl-alkane-carboxylic acids. The synthesis of the Urotropin complexes was not carried out according to reference 4 (i-e- it proceeded from the above mentioned acids in which iodine substituted Cl), but the above mentioned substituted compounds were used directly and quantitative yields and cleavage products without iodine admixtures were obtained. The chlorine hydrates of the amino acids obtained by the cleavage of the Urotropin complexes were converted into free amino acids by the evaporation of their ammonia solution. The dry residue consisted in a mixture of ammonium chloride and free amino acid which was liberated from its mineral ingredient by the recrystallization from water. The synthesized amino acids have no distinctly marked melting point and are not easily soluble in water. In the case of heating they are transformed into high-molecular polyamides. These polyamides bLre,produced not only in the case of a melted state of the initial products, but already at temperatures below their melting point, i.e. in dry state which is very important for the production of the thermolabile polymers. The Card 2/3 polyamides from (III) and (IV) are stable, horny compounds Synthesis and Polycondensation of the n-Amino- SOV/79-29-3-50/61 Methyl-Phenyl-Alkano-Carboxylic Acids which yield in the case of further treatment stable fibers which are easily extensible in cold state. The polyamides (1) and (11) decompose ' on - melting and can there- fore not be used for the above mentioned purpose. There are I table an& 4 references, 1 of which is Soviet. ASSOCIATION.- Vaesoyuznyy nauchno-isaledovatellskiy institut iskusstvennogo volokna (All-Union SCi6htifia 'Ifesearch Inefttate of synthetic Fibers) SUBMITTED: January 28, 1958 Card 3/3 VOIDKHIN&, A.V.; BOGDAVOT, M.N.; KWJRYAVTSEV, G.I. Polycondensation reactions In the solid phase. Part 3: Polr- condensation of n-aminoalkylphenylalkanecarboxylic acids in ths solid pbase. Vysokom.soed. 2 no.1:92-96 Jj6 .160. f(MId'13:5) 1. Voesoyuznyy nauchno-iaaledovateltakiy inatitut iskusstvannogo volokna. (Condensation products) (Acids, Organic) BOODANOT,_Bj.; PETUKHOV, B.V.; KOIMRASHOVA. S.M. New fibers based on copolyasters. Khim.volok. no.6:21-24 '59. 1. Vsesoymny7 nauchno-issledovatel'sIdy institut iskusstvannogo volok-na. (Textile fibers, Srnthetio) (Esters) IBr~ 5/190/60/0W/01/11/021 M29 U/ B06~ AUTHORS: Volokhina, Ao V., Bogdanov, M. N- Kudryavvi,~v, G. 1. TITLE: Polycondensation Reactionslirk the Salxd 111, Polycondensation of p-Aminoalkyl-phenyl Alkana Carboxy2ic Acids in the Solid Phase PERIODICAL: Vysokomoleku1yarnyye spyodinewya, 1960, Vc1l, ?, Nn, 1, pp~ 92-96 TEXT: The authors previously described the synthesis of :~arboxyll.~% acids of the general formula*H2N(CHOWC6H "n(CH,V00H (m 41 n - 1'29394) and their polycondensation (Rolfs~ The kinet!C3 of the poly;oondensation of the followIng a.tj-amino acidslis examined here; p-aminome thy 1 -phenyl propionic aoid (1), valerie acid (11); p-aminoethyl-phenyl acetic acid (ITU: p-amincqthyl-phenyl propionic acid 1IV),- p-umincethyl-phenyl htit-vr!,-~ 13L,~,'d ~V'i: am.1 P-amonoz- ethyl-phenyl valeric acid (VI)~ The kinetics of ~he were Card 1/3 V~ 82G60 Polycondensation Reactions in the Solid Phase. $/190/60/002/01/11/02i 117- Polycondensation of p-Aminoalkyl-phenyl B004/BO61 Alk~,-,ae Carboxylic Acids in the Solid Phase observed during the reaction by continuous weighing, and the degrea of polymerization was established by determination of the separated water. Fig. 1 shows the kinetics of the polyoondensation of the above i7caipounda' and Table 1 gives the experimental datat It follows from thi3 that the initial temperature of polycondensation falls with sinking melting point of the amino acid and with increasing content of methylene gr,Q(;' As regards p-aminoethyl compounds, the temperatqre range between tie initial temperature of the polycondensation and the melting point r,-f the acid decreases with increasing content of methylene groups and with decreasing melting point of the acid, This connection was not observed in methyl-aubstituted compounds, With increasing content of methylene groups, the polycondensation reaction rate increases, Fig. 2 shows the change with time of the degree of polymerization of compound (1), which is not linear. Table 2 gives the activation energies for the poly- condensation of compounds (1) to (VI)-, There are 2 figures. 2 tables, and 4 references: 3 Soviet and I US, Card 2/3 Polycondensation Reaotions in the Solid Phasc S/19O/6O/OO2;/Oi/11/O2i III. Polycondensation of p-Aminoalkyl-phanyl B004/BO61 Alkane Carboxylic Acids in the Solid Phase 82080 ASSOCIATION: Vsesoyuznyy nauchno-isaledovatei-skty ingtitul, iskusstvennogo volokna (A11,J1n)en Pp.-,earch - Institute of Synthetic Fibers) SUBMITTED: October 9, 1959 Card 3/3 5.361o 77397 SOV/79-30-1-58/78 AUTHORS: Bogd-anov, M., N,, Kudryavtseva, G. I., Spirina, I. A. TITLE: Synthesis and Polycondensation of p(Aminoethyl)phenylalk- anecarboxylic Acids PERIODICAL: Zhurnal obshchey khimii, 1960, Vol 30, Nr 1, pp 263-267 (USSR) ABSTRACT: A series of new p-aminoethylphenylalkanecarboxylic acids was prepared and condensed to polyamides. This Is a continuation of the authors' previously reported work (ZhOKh, 29, 986, 1959). The synthesis was made according to the following scheme: C6115(cill),C0011 C1C11A114(C112).C0011 - CNC112CG11j(C112).C0011 11G1 - N112(G11j):CG114tC11j)4,r0011 Card 1/5 Synthesis and Polycondensation of p(Aminothyl) 77397 phenylalkanecarboxylic Acids SOV/79-30-1-58/78 ASSOCIATION: Chloromethylation of the phenylalkanecarboxylic acids was made according to previously described procedure (M. N. Bogdanov, ZhOKh, 28, 1621, 1958). Hydrogenation of the p-eyanomethylphenylalkanecarboxylic acids was conducted according to the procedure described in: P. Ruggli, A. Businger, Helv. Chim. Acta, 25, 39 (1942). The following four acids were prepared for the first time: p-aminoethy;phenylacetic acid W, P-aminoethyl- phenylpro ionic acid (II), p-aminoethylphenylbutyric acid (1115, and p-aminoethylphenylvaleric acid (IV). The yields, compositions, and properties of the acids obtained are listed In Table 3. Some conditions of the polycondensation of the aminoacids and the properties of the polyamides are given in Table 4. There are 4 tables; and 4 references, 3 Soviet, 1 Swiss. All-Union Scientific Research Institute of Synthetic Fibers (Vsesoyuznyy nauchtio issledovatel I skiy institut iskusstvennogo voloicna) SUBMITTED: Janip- ry 2, 1959 Card 2/5 Synthesis and Polyconde nsation of p(Aminothyl) 77397 phenylalkanecarboxylic Acids SOV/79-30-1-58/78 Table 3 p-Aminoethylphenylalkanecarboxylic acids N (CH,, OOH "2 -j2C6H4(CH2)nC Y'.0.14 rMP t ~,A /e- VAL feel _T_N U 1 11 1 N 11 1 53 67.29, 67.24 7.17, 7.21 7.96, 7A 67.02 7.37 7.82 1 f 2 Cp 68.44, MOG. 8.12, 7.84 7.24, 7.18 68.37 7.82 7.24 (111 :1 50 69.50. 69.70 M2, 8.15 6.95. 7.W 69.62 8.20 6.75 (IV 4 53 199.0-A99.50 70.72. 70.49 &47, 8.3t) 6.32, 0.27 70.W &59 6.33 Since the temperature,at which polycondensation of (I), (II), and (III) in the solid phase begins is lower than their mp the latter cannot be determined. *** The acid is readily soluble in aqueous alcohols; therefore) aqueous acetone was used for Its crystalliza- Card 3A tion.