SCIENTIFIC ABSTRACT BELOV, N. V. - BELOV, N. V.

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NO* Crylua 1"ructuilt of ram 111"I m lirlymev. Pokladly `"I.Xm-%N .14 o94t)l --Ji'lrolrllLirv .01 dilitell".m.. de1j. [own Wriassro, lWIgdWjr4"k%: a, - 11 :.";; 4 - 8 57, t. - AAVA.; MwT Imp ris a Pima. with 4 Viols. XAJ69" la the unit evil; d. 3.3S to 3 4;V ThtTr itre -I" indqwndent jmmmrtrr~. tit the coonlinmes of the istas (given in of the nxi-I length,&),. 1)(Sl: x Ill 8: 'v 9 13A, NW: % - 21 3: v - 1.%:t, Ill; x 15-t% y - 4~6; s - 45; th0l): X - V. - 17~.; g - 19: 011(g): x - 7,*-'; y - 0.8; s - *W; (hu(,14: x m 6.7, y - 1.11: s - 41. 110j,(24): x - 21-3.2; 7 - -117.5; # - 45,. (M41: x - 2:-; y fl; . - 2. D"tinves Si - 0 - 1.56: 1 --%; I Jrv-,. 1.-M A.., Ti - 0: 1 -At - L'.05 A.; Na - 0 - 2-T.? - IIAI A. The struttiste is chAracteriles] by IM)s), Chails.. -iooL.r its llus~ tit the Isyto%rucs, mnd in avertsmit wilh the AckuLtr-priitnmie hibit of the synthetic mineml Cleavage plasses am (2110) wid (lot)). through the 1a)WO all the 00" Itarcris The ~mzdlrr kmile radius of TP I and Na'~ in vor" riwm to Mg, I and C.61 , g%puns the hardete" t Pit .1 TbechAritarrottin tamavite, tkireffingence k% Itrit . IKVAUW of the strong= effects of the I'vt%l chAin* PAM110 to r Man thit of ISithl Ch4ins o~ IsYroxtrim The striseturr is its the Irt 4111114'"ti-MS identir4i with thAl of blookile. mod d4 is ac"Calf-br - P".4 .1 dun. side. %Vhilr in ltyrmrii- the t)#- 1,yns m, Lj,f,,ll. I, ratn~svitc Phst-s t)-rtvhl Wets of (be #Anse kind. Absto in flit directions 4 And Ort 48`03 211412 ljy"S. but the pdcking It not cubic as in ityToxent; it hjA a pLne 0( "Mnwtry Prallel to the Uyer, The o?kdir,,,tism of Xa* to (Y- m abo"t octahedral (but with I adIdilionA 01- in next ncth 4tnil4rtothAt%slCAt-jjjdiot,, shi ide Ch tost Osut with -1 t),- nrighIsixing) OVUll"IFAI VhjjjWN Me ArrAngesl with the jr.40.1 i's t1w -MV Mrlwtur4l "Kni'sr 23 CA os-uheslml Cluim Are in JIvl..Ujjs,I ondin'l wish IMR0.) Owjzql~ Atiltswigit i1,, .1% I.alis. ,, .4-1) j. o1 TAM-4vile .1plurcully 1:4-.5. in tit, N1111,111tv it 1, Irs~-jlv bs- ,sj_ I , j he 0, ;Ilr 1101 ImAll"I I., , 's. " I ~J, IstIMM the .1114,111jr else 1--kille in gl. Os-. Livors 6 very clutructtTi.lis. in the %ttitirtic, (,jAC,ACjjj. While In dk4nitle it is (A)ICAIICs W. Filet pELOys N. v.- n 441' 50 r iie" "Determining the Paramete s y the r o Method of Partial Projections," It. V. Belovj: ~Orr mem, Acad Sci USSR, R.. G. Metvayieva -3q2 .*Dok Ak Wauk SM" Vol IJXXIII, No 2, 3pp 299~ Discusses partial projections,'new method for -structural analysis of crystals. Previousl*' of atomic arrangement were synthesized In form of projections of the cell on MM. i- mate axet;, from which coordinates (parameters) vere read directly. In partial projections) 175T66 ':~V=/Minerals Crystallography 4 Jul, 50 Contd) only part of the cell e.g., 1. /3., is pro .-Jected. Results obtained for bei7l agree for s s 0 ne y ragg in 1W6. submitted 20 May 50- 17!s%6 AW BEMV, 1~. V. 1 NOV ice, Crysto ograft. .111nantiomorphic.Critekia," V. Belov, Corr Mem, -Acad Sci USSR "DOIL Ak Mask SSSR" Vol.LXXvo No 1, PP 33-35 enantiomorphic ("mirror form") crystals as~ that pair,of crystble, of any chem compn, belongido"to saw type of symetry, which are characterized by the ,79soct that if one,crystal has property which can be described by the word "right" (dexter) then the'same ,property in the othe. crystal must surely be dej ~~6rlbed by the word "16ft." (laevus). Describes enanti- M95 i7 I A . Stialk S.. .. . _. -75. fka- Ilk I *I), file 161jr differences in the prVivinusir given lon4loinn cipordinates puldialsomil by the authon (G.A. 45. 717.-ij. by IlAssolourger must Iturorgror (C.A. 43. Wi7c). and J-v Ilusnur saul Utjcrsrr (C.A. 44. 14100) mor i_shuLit,A The norlarly cuoriplorte afforreawnt of the rJectsun dru-ily In0ji'101HO Pylithfitill nkilUmill Anil Ills- very Nuisilloctory sointiudly its; the intmity of the (Alto interfatollsvot Is detil. lly the ajorcellivill in the lo"FlInulA evinortlinates in the 3 putslli~hcd stnicturv v.triatn%. Flip k-hirt diffirtflim luviolievirt, Is the mitswilit ut )..I- Ikinii 4a given fly Iturravor, 4 L. in the -Ittwtuir stmi I,v the authilts. They swre-litind tit the lisnitints, tit At its Ill, Inatimmotl of Fiattorfmon mu.1 llArkrr. (Al 4. 11) 6 tit t1wir oftili'llim 101.6fly W-1VII by the IN "14. altmillrd Willi Ilirw un file Vertivul dinrl, Its .1 fivilad'"I'll 1111S. volills 1,40.1 in ~hv uplwt anul I(Al. 1t*J.j its she lainvi tavvf. rhr distioniv %,I - Or - :.Mll A- NA - loss - ~' LN joint 3-It A. as orivs-is its liusnosr's minif J1uv;gvt% Na - Chv - 3.1110A.. Na - Oy - 2.10 A. IN uuj..i.nn~ al,o 6 the diffemniv W the runroliumiuss Isic Ilse Ali' 4,41 hma,6: jAlo.1 in thr structure given hy olov, aullins,i. JAII6.1 in fluergst-r'lo. too file Lillcr. the ijujimimble, di,mutv, :31A4 A. (nor At - I) irc 4-AA. Anil are mudi lpigh,r lhut the thellosittical value LMS A. Of the toctalinfrim rilgroo. two ve much too %hurt Anil I horm Illuch tin) king. The i.tuuwphnu4 mplitevinrut sit Miss lur All, it, tuntumlinc I% hy thu-11tvi. hat tit the mluvlutv~ .4 it. .oullims three Are it," a. tills it x1ols, k1kitilln.111-1 "ills Ill in nvt~h~ka. in iihich Sta- rrpL- At-' 1-2 Unt - - VVTU. The illtltulitlf itiWIS'Sk-Al GW F-t-ItItUtintv tit cusupArissin with %iff-tunnn2linc toliust give fiv Fe +- 0 .4 .4runforr ;wAk than fer *4 -t- At + (11, first twh A diffs-motv %14, I"A' al""vrd. Titt, .16mmm% chwily rimin-cin, Its, lir"-m tit "mtellitv" Iwak intemitit, in Ilse impliviltnu if he fully vaVil Nor the -4u.N- jonsup t. In Imot tons int C_' - R-Sm. The rwrvints, istat,tsity d4l~ of she nlllkW~ are Atippivisivinvil 10 IS IlilgIal" Of Ilk' 91t.1 intru,ilor. Int i1slill rilicsr, ininth aic us cN...11cut 4xit". 11"roll. if. I -;V. PHASE I TREASURE ISLAND BIBLIOGRAPHICAL REPORT AID 456 - I BOOK Call No.: AF54o841 Author: BELOT. N.-_X. Full Title: STRUCTURAL CRYSTALLOGRAPHY Transliterated Title: Strukturnaya kri stallograftya Publishing Data Originating Agency: Academy of Sciences, USSR. Institute of Crystallography Publishing House: Academy of Sciences, USSR Date: 1951 No. pp.: 88 No. of copies: 3,00u Editorial Staff: None Text Data Coverage: This small booklet discusses the principles of geometrical Crystallography and deducts the main mathematical formulae for indices. It does not go beyond the scope of geometrical crystallography. TABLE OF CONTENTS PAGE Ch. 1 Crystalline state - lattice pattern Ch. 2 Basic theorems of lattice crystallogra y 2~ Ch 4 transfer lattices (lattices Bravais . 5 Ch: i Elements of an=etry derivative from the lattice 73;' Purpose: Not given Facilities: None No. of Russian and Slavic References: None Available:. A.I.D., Library of Cong a BEWVI N. V. RMT. N. V. ., .Il'i'U'.1it"17-Nport on structural mineralogy. Minoebore no*5:13-36 151. (MU 9-.12) - 1. Institut kristallografii Akadsmii nauk S$Sk.Noskva. (Kineraixv) move -------- The nature of the austenite phase. Trudy Inst.Krist., Akad. Nauk S.S.S.R. 6. 141-6 151. (MLEA 4:10) . (CA 47 no.15:7281 153) d"M Iar 0 In -T W JY TZ"to of the nmtb. delia" of PdMitive gmap from DITichlet's no Varona's tbearem. wul Fedarav's waliewbedron theory of "C 6 ouillued u4 dismaW. on the ip"Ul batis t launar's Mekww's) reduclion log (cf. t,'jpfk*i Marmal Ovallk J. 4. 1AIM RV=lvm "-w tattkv Is rvd&emd to a systgM a prahive kwpcdic units (elesum ybedra) with nancomplana tranwa- tiorn; the to Parameters for die "Imots" are dil- the c0= to cussed for $pme opww geometric conditioub of centered VMPS In the 2J,4 dimasiond apAce (cf, Wtauns Kriji, 14, IODAP; M. 33.4!033)). W. Rrt;IZ- ~d V. 1. cr$ludft lom tw POW 6~ -iftow wbmi*w "ftwoty Comw bftvlwal~w vmrwtr us in wxw PoGkimu on do,, Wkw pkwl~ - Thm Pmknm-t#&Aa on to a tho D*Mbld -0 .god. It 7iZ:-A-,,miAmovA Am IL =;z jVmj~ $$M $a. 3" pXmwAowmn dWxW by of sm md aeg (z xrw- 06 si.0 arA 05-0 ON dWa bY UP, JL Abor 54a (19M- ' 2 ,41G40' saw an C17M Wave" d 1111wile PISWIK N-V. MIMOV-AWD~V.; L MouwA., OW. Add. NWA JSSJ% U14 (No. 4. 1"l) in Rodes. ~ 0 , "~ .- '96 AMIN a - I-S& 6 - IS-07. 3-l6A.Zw4xCWF%j,+F***#W,OAM A tAk o(olowAr pumemen b afvw4 uft a drawims o(lbs atomic I - Compus T. too. X-V sall- 164 (Toky% IM p~ - ISI) ad Y. 5, 1 (IM So aW Abur. SM ;A. & C. WUQN AOqL 34&7W6 BXM-AM- iL MOKWA,' AW. Aki*L,.- TWO 'in lotairitim Of N"dw *fto-*#Sl am ftmd -to N. V. D*V aw V. I mak"m AbW. QM~19M& Tlw &%nw k wm* critkbW 4m acmum tho b%cmtm%WAlftrxa eat&W& "Peculiartties In Solidification of Natural and Synthetic Aluminosilicate Melts in the Light of Crystallochemistry," SO: Vestnik Akademii Nauk SSSR, No. 4, M?, PP. 109-113 1. MLOV, X.. V. 2. USM (600) 4- Crystallography Crystallographic procedures in ablving geometric problems. Trudy Inst.krist., no. 7, 1952. 9. Monthl List of Russian Accessions, Library of Congress, April -1953, Unel. lolls 4 MOVP N%' Ve 20 USE (600) 4. Crystallography.. Mathematical 7, Simp3ification of the formula of & structure factor, Trudy Instkrist., no* 7. 1952. 9. Monthl List of Russian Accessions, Library of Congress, Ap ril 1953, Uncl. BMV) N. V. "Structuro of Crystals$" Nauk i ZI'dznI, 19, Mo.8, 1952 BEIIOVP N. V. .I'Secreta of Crystals," Tekh. molod.., 2o., No.6, 1952 it I 1F 4i, AOH-3~hk54Y-The cMitalln-hem fotmulation of d- ~ Akp~wt an an orihadlio ite nf thr phertakite gmup of the , ' type CusioOlth cmisIderable diffituld". I'doo 86jut , l- l Si*' i t, b mm Il b t di O f r j it ri in t o a centm s two o miM g 'higbir ~mtjmtxafilr; Therence 150(11KI)~ t Brlt)y (&f. 37 , , Me formil pe. Cu4S 40j%)JSHiO' taof Ititt) t; tybich th-Atil1cititTA t4 that In $ W "W~1 1840 l i fi, UrM & 0g ii S ( fKYY1 and loutinalitic., The U.0 Ino1s. wnuld have "Glitle f the, Ouractcr hi positimis betwomn.the silicatc ilrovp o " networit; the dehyrin qW' wvuld be m-' Atiou- abovil; symbesLi L trovil glv~n for the w-mitim, with an electron- d. pro*tion on' (xy). by using tile impliatim: title of:Bvier &ad . vertical - Pattmon sy'nlh,~~m for the accuedtL C positions. The t'-4 codrdim4t" fire.- CIS In M x/a, Nt2~-k jr1b. Nkitl s/c; Si in 0.1773'xlts. 0.1a, ' A "Y' - 'Y i'1 x1a, O.M yj&' -0.010 I/c; in 0. 1 ;t"b rip. Thtl- I.M.Ohl ring. wbkh his the symnictry di the Sym v juctt t I - --------- -- - 4 d _1 N V Some characteristics of the crystallochemistry of sulfides. (in: Akademiia nauk SSSR. Voprosy peti6grafti i mineralogii. Moskva, 1953. Vol. 2. P-7-13) (MM ?tO 1. Chlon-korrespondent Akadsaii nauk SSSR. (Sulfides) BELOV. N.V. Characteristic features in the solidification of aluminosilicate melts. (In: Soveshchanie po eksperimentallaoi mineralogii i petro- grafii. 4th, Moscow, 1952. Trudy, Moskva, 1953. No-2. P-133-136.) (MIRA 7:3) 1. Institut kristallografii Akademli naut SSSR. (Crystallization) (Aluminum silicates) cr tAc b, !a. BELOT, N.Y., akademik, laureat Stalinskoy premli [reviewer]; BERM, J.D. Cauthorl In defense of progreselvo dalftae. (0861suas and society. 0 J.D.Berml. Re- viewed by N,V.Bal0V). llaftk I ihisal 2b no.11:46-48 N 153. (KE" 6:11) (Bernalo John Dasmundi jqOi4 ) (Soience--Phllosopby) BELOV., N. V. 1 Jan 53 USSR/Physics - Crystallography "The So-Called Law of CrystalloGraphic Symmetry," V. V. Belov, Corr Mem Acad Sci USSR DAN SSSR, Vol 88, No 1, pp 63-65 Proves that if a structure has an axis of 5th order, or in general oLf (2n 4 1) order, then all plane networks perpendicular to this axis will possess axes of twice this order. Besides, a cryst,~ cariuoL possess a syr=etry grel-ter than the geometrical figare of symetrical element pertaining to the structure (see A. Schoenfliess~ Theorie der ,Kristallstruktur, Berling, 1923). Received 28 Oct 52. 262T79 all VSS R vz Ld --i,-F t, thq Cdi 259T44 US8R/*16gy':- Francolites 1 May 53 Irc bo'nate Apatites.." 1. A,'Born6man-Starynkevich aT' N. V. Belov, Corr Mei4cad Sci USSR DAN SSSR' Vol 90, No 1~.pp 89-92 Authors~state that since 1938 - 1940 they have suc- ceed6d 3'times (DAN SSSR, Vol 19, No 4 255 (1938); ibid ."o1 22 No 2, 90 (1939); ibid., Vol 26, No 8, 811 iiq~O)) in'-pointing outobjections to the pos- sibility.of isom6rphic substitution of calcium by ca,fbon in C02 apatites (francolites), this possi- bility vas proposed in 1937 by Americans J. W. Gruner and D. McConnell. 259T44 Ulak 56. ,j OR r4) VIT-Iww--v 14-- Ir -,~ Cubically symmetrical space groups. Trudy Inst.1crist. no.9:21-34 154. (MLU 7:11) . (Crystallograpby) A BELOV, N. V. Nature of Martensite Phase Tr. Tnst. KriglAllorar. AN No 9, 1954, PP 43-46 The former assumption by the author (Tr. just. Eristallogr.,No 6, 1951p 141) that the austenite carbon atoms tend to replace iron atoms in gamma-iron instead of occupying octahedral vacancies in dense Iron atom cubes, as has been previously assumed, is extended to martensitel The transformation austi- te-martensite is considered as a transofrmation of i carbide phase into another. It is also assumed that the carbon ions C3-p C4-) replacing alpha-iron atoms have an elongated shape and locate themselves parallel to an axis, which may explain the tetragonal system of martensite. (RZKFis, No 5j 1955 SOs Sum. No. 639,.2 Sep 55 j - - . USSR / Solid State Physics / Structural Crystallography E-4 Abs Jour :Ref Zhur - Fizika, No. 6, 1967 No. 11654 Author :Belov, N.V. Mokeyeva, V.I. 1n# I I Title sThe Crystalline Structure of Ilvaite. Orig Pub :Trudy In-ta kristallografii AN SSSR, 1954, 9, 47 102 Abstract :See Referat Zhur Xhinii, 1955, 31105. Cards 1.1 &c?.ftdv-_ of a M'a ef mixAraff. ta6 of -flich "I" ~t-r. ptricid -M A. ca.4cr wcxks h-kv- CIVM aciy ",4 C al the C-6.1 ", the Eruct Cmld IFTIMIIIU~- T_zdIkfuugu:zj. C.4. 26.6770; C.A. 21, 824; C~mnr_r ind Rcich~l. C.A. 27, 52g9)- A PINU ~~4W. OW*4 fl - 23 -k X-7 a I LSIUI T114 uq o t Tha _-Mft gvl(ii~ 01wahed-.21 cl~-Pz/~. The cooraim-tes - mr- f #l d (XIOV) i ! i i J - o , t ma ttc xe an. A g r (0: p - - -C 75- &M u . ist f 33.8; 75. 4.8, Sin O 63A _254,27.8), Sitsf (18,5; 73; Oj (Z3.3; 0. 4.2), gig 30.9; 0; 35,S), OilI1 (804, .0; 33.6 , Chy (4.6; 2-5; 1 13.1 . Ov (34; 73; 14-2). Gig (T.0. 75, 41.S1. OVII (51 .5; - 75; 25- 310) 011t (43,9; 2M. 10.0). Off M); 25; 414) 'r 16 - It n ( ;ry%t;gj,jtmctcLm themutt 1-1 it ,, tf4atm.,O arLd acfaWra, v4 Cm I~olylWra. The Aj atoms have ctukifinalikift no. 6. P:PMOle is L CICUIPIeX sit' 'Its VVIIrk 2 Ey of rjAUcrAI,-t: dimhqAtivitte IVAI ard l - St on 0 "Ad i O O . e- en a gq w i &MP uc not mWiltd with a SI molil. Tlxcr~ tile richt formula of epvotg,k w V, N. V. N NomogI omographic calculation methods in L-ray structural analysis. I U T~udy Inst.krist. uo.9:277-286 154. (MI-RA 7:11) (Radiography) (C27stallograpby) Wa 15-57-2-1779 Translation from: Referativnyy zhurnal, Geologiya, 1957, Nr 2, pp 90-91 (USSR) AUTHOR: Belov N. V. TITLE: The Atomic Structure of Glass (Ob atomnoy strukture stekla) .PERIODICAL: V sb: Stroyeniye stekla, Moscow-Leningrad, AN SSSR, 1955, pp 3144-350 ABSTRACT: The two principal theories on the glassy state--the crystallite theory and the theory of an unordered three-dimensional bond of the principal structural elements (S104 tetrahedra in silicate glasses)--are based on X-ray data.' Detailed examinationsroif the possibilities of using X-ray analyses have shown that the crystallite theory and the other theory indicated should be set aside.- it would be best, in investi- gating the atomic structure of glass, to begin with an ..Card 1/4 15-57-2-1779 The Atomic Structure of Glass (Cont.) idea on the structure of fluids and amorphous bodies, in which ex- tensive order is absent but immediate order in the distribution of atoms is preserved. Assuming the basic principle of continuity, that even in the still fluid glass the structural elements of the crystalline phase are present (separating from it~ a picture may be c6nceived of the structure of glass and the tendency toward an - amorphous state may be explained., In the liquid silicate glass, !!preparatory to crystallization," the structural elements of the future solid phase--skeletons, nets, chains--are already rather abundant. Their disposition, in the absence of any further ordering, cannot be parallel. The sizes of these structural elements are variable and the particles are differently oriented in space. This state explains the high viscosity of molten silicate glass and the tendency to solidify in amorphous bodies. In relation to the sizes of the parts of the structural elements, it may be said that their parallel contraction is possible only within the limits of 15 As ina,smuch as the regular spacifig in glass, as determined by Ye. A. Card 2/4 15-57-2-1779 The Atomic Structure of Glass (Cont.) Poray-Koshits, does not exceed 15 A. The length of parts of the chains in-metasilicates may,exceed 300 A. These particles,in meta- silicates, however,-are not detected on & debyeogram because of the unordered disposition of secondary cations and of the possible ' bending of, the chains. Consequently, the principal mass of silicate glass is made up of more or less large scraps of endless (in one, two, three dimensions) anions of SiO4 tetrahedra, which are present in the crystalline phase, and which separatid during devitrification. Devitrification is facilitated by the introduction of mineralizers, which are effective in reducing the severing of the endless chains and nets. Concerning sodium boro-s-ilicate glasses, the structure should be considered-a dense,packing of oxygen atoms, in which cations-of s,4* B3* 'Na"I are arranged according to chemical and crystal chemicai rules. The concept of the existence of two three- dimensional nets, in one of which oxygen is bound only to Si4~ and in the other only to B3', the nets penetrating each other, is basi- cally incorrect. Experiments on the leaching of boron and sodium Card 3/4 1 15-5772-1779 The Atomic Structure of Glass 09nt.) atoms and the determination of pore sizes in "silica glass#', con- ducted by Ye. A. Poray-Koshits, are not proof of the existence in borosilicate glasses of two kinds of oxygen atoms, one bound only to silicon and the other bound only to boron. The explanation.of the phenomena of leaching in borosilicate glasses must be sought for in the fact that boron may have the fourth coordination next to oxygen. The existence of boron in the fourth coordination has been tablished in many minerals and in boron gl !ses. The structure of solid B203 is composed of tetrahedra of Bot 0 At high temperatureP the boron is predominantly found in the third coordination. At lower temperatures it changes to the fourth coordifiation, a -process that takes a considerable length of time and does not reach coM6 pletion during the solidification of the glass. The continuous' process of changing to the fourth coordination destroys the Wholeless of the skeletal structures. The result is the development of weak places in the glass where the leaching action of water appears. Card 4/4 A. A. L. -5 ysical Chemistry-. Crystals. Referat Zhur. Mimi X02~ 1957 Abs 3524 Author Belov N.V. Inst ~in~;ro cal -Society at the Lvov University Title V1 sp ' t' of Con ec us structural.Mineralogy. Orig Pub Min-iialoj, ob. L".Vovsks geol, o-vo pri un-te, 1955) X0.9) 3 -14 Abstract The publica,tion.consists of two independent parts, Patt i is, a supplement of previously'published.vtrk (Rzmim) 1~551 3.5-799).. ConsidereA is the problem or- the mechanista- of-pblarization effects.--in crystalline structures CoAsS) CuC . AgCl,, CuBr and other - compounds, MAsS NiS,,MoS2, Coordi~atibh-ni6b.ers.of.,cathions-polarizers in-the struc- tures under-donside*ra'tio'n are very closel related, accar- Y~ *ding.to the author,-with the.tendency of cathions to form about theri-syr-metrical'configurations of 18 (or 32) elec- trolls. In inter&etationa of characteristic features of Card 1/3 14 4;7c 1~ ;- '. . ~ 1" - , ~: 1MR/ULTHEUTICS/Algebra CARD 1/2 PG 396 A U 1; H! o,., t Hkax 'Tus HERONOVA N.N., SMIRNOVA T.S. ji, 1 ? TITLE 51 ubnikov groups. PERIODICAL Trudy Inst. Kristallogr. 1.1, 33-67 (1955) rev-26ewed.11/1956 (1924)) have established the 47 motion F61ya and Niggli (ZoKristallogr,, 60,,. groupa of the plans. Assuming.the plane to be roflootingo then one obtains 80 motion groups.(Weber~ ZaKristallogr. 70. (1929)1 Alexander und Hersann, ibid. ). These can be denoted as bi and 70.. ed as biaoloured groups by giving the points the two ooloure white and black instead of the reflection at the carrier plane. Therefore the authors call them the 80 biooloured groups. The authors solve the following problems Analogously how the 17 onecoloured groups can be generalized to the 80 bicolourea ones, glo the 230 onrcoloured space groups (due to Sohdnfliea and Fedorov) oan b generalized to biooloured groups. The authors find,1651 groups which ar: named Subnikov groups. The authors' method is geometric: At first the 36 biooloured Bravais-Lattices are established, thiy are obtained by centering of the edges, tho surfaces and the cells of the 14 Bravais-latticea. Then there follow 10 theorems wbiob describe the mutual behaviorLof the symmetry elements for the bicoloured groups, they corresponj to +h rules of combination for the onecoloured symmetry elements* Then the 1651 lubnikov grorps or bicoloured motion groups are obtained by combining the 36 biool,~,)rea. Bra,,rp-is-lattices with all possible one- and bicoloured Trudy Inst~ Kristallogr. 11.,. 33-67 (1955) CARD 2/2 PG - 396 symmetry elements. The method is desoribed in detail with the example of the rhombio hemimorphy 02v and loads to 192 biooloured space groups. The authors have found the following numbers of bicoloured spaeo groups belonging to the aeveral crystal syetemst Trialialo, 7, monoolinios 91, rhombio, 562, t8tragon&l' 5709 trigonal (rhombobodrio)s 108, hexagonali 164~ cubict 149. The problem of the bicoloured, spaoe grotips has firstly been put by Reesoh (Z.K-~istallogr. 21L (1930)) and has teen solved for the case of the triolin and monoclin system. His groups No. 1-19 and 40 -t18 agree with the above 7 + 91. Then Burokhardt; (Comment. Math.Helv. 6, (1934)) has treated the prOlom vtth Arithmetic method@ And h4v given 4 number of btaoloured, groups for the hexogpnAl and the rhombo'hadria eyatono But the compartoon with Aolpvlp ropulta Phown that thic entabItahment woo inoomplotes SHIRNOVA.R.R.; RUMANCVA,I.M.; BRLOV &Y, CrYstallic structure of anspidima.%s:p.Vsee.mln.ob-va 84;no.2: 159-169 '55. (MIRA 8:10) (Ouspidins) f/ V ~ I ~ , v USSR/Solid State Physics - Structural Crys pby, 3-3 Abst Journal: Referat Zhur - Fizika, No 12, 1956, 34626 Author: Golovastikov, N. I.,-Delova, Ye. N., Belov, N. V. Institution: None Title: Crystalline Structure of Eremeyevite (Ricbwaltite) Original Periodical: Zap. Wes. Mineralog. o-va, 1955, 84, No 4, 405-414 Abstract: See Referat Zhur Mika, 1956, 28612 Catpgdry : USSR/Sb1id State Fhysics - Structural crystallography 1-3 Abe Jour : Ref Zhur - Fizika, No 1., 1957, No 1130 Author : Fesenko, Ye.G., Rum=om) I.K.., Belov; N.V. Title Crystal Structur-a of Oyosite. Orig Pub Dokl. AN SM, 1955., 102) No P-) P-75-P-78 Abstract An x-ray diffraction study v" made of cy*lg Ca2A13S'3012(OH)` a 16-20, b 5.50) c 10-14.kXj Z sr 4. Fedorov group*Z -- PnW. The structure was 'Rh determined from thi6 itisvAl and geameralized pr_o~etctions of the electr,)n density on xi. The'large number of Fhb'land anplitudes detexmi~md in radiation (407 and'277 respec_t3.V-eIY;)U.'x9 6 it possible t6'apply this statistical method to the determination"of the-RIkqp. The ib~ an e plitudei were obtained from the relativa ones taking into adcount, the`~perature correctiou'at B 0.7 kX2. Thq .re-ferrence 'group of 'eigae, waa -determined using a method ~I~ously described (Refear-at 22aurnal Fizika, 1956, 34590); this method, made it possible to determine 21 sips'of'%ol ard 218 F, The projections constructed from thise data'gaVe the approximate 'coordinafe;'of almst, all the stons; they were used-to det&u1ne the sips of All'ths e*litudes. The foundation of the structure is made up of single columas iof Al-octahedra, vhich extend along the Card 1/7- ~ry : USSR/Solid State, Physics - St:Fuctu:ral crystallography 3-3 Abe Jour : Ref Zhur - Fizika., No 1, 1957, No 13~30 b axis; adjacent to the columns are single octahedra, corresponding to the Fe-octahedra in Opi6te. Th* colimm of octsA~dra are joined by ortho-groups (SiO4), diortho-groupi W267) and Ca- seven-c6mered structures. The inter- atomic distances for Si -- 0 range from 1-53 to 1-70 kX, for 0 -_ 0 (ribs of the tetrahedrA) from 2-52 to 2.82, for Al --_O (in the'oct4heara. c6Mrising thG columns) fi-om. 1.93 to'2.02, and for Al. - 0 (in'the single octahedra) from 1.79 to 2.08 M The'SirO-Si valence angle is 1620. Card 1/1 GOLOVASTINT. H. I.; BUOTA, Te.1F.; RIW. N.Y., akadmik. . - i . I Crystal structure of eriqeyovite. Dokl,AN SSSR 104'no.l.,?8-81 S 155. (nM 9:2) 1.1natitut kristallogrefit Akademil nauk SSER. (Aluximm borats) (Crystallography) SUBJECT V301/11ATBUTICS/liet'istioa Cal) 1/2 to - 695 AUTHOR GOLOVASTIKOV N01 13zUMj6_v1 *:0-3-io-nof the statistic equation of Zaahariasone Geometric tntsrpr PERIODIML Doklady Akad.ftuk 104, ~40-542 (1955) reviewed 4/057 The equation of zaaharjason %+X n.3(82 -sIr (Act& Cryst, U 60 (1952)) has a goomatria interpretation by relating 4th, all possible situations of the a,toms in the elementary aelle For a twovdimensioual oentro symmetric crystal coo 2'K(hz Ay~)* The straight lines hx - ky - n we have PR Fhk fj integer coincide with the Kniza; of that oos-plans which In the Fourier series corresponds to the amplitude P al analogously for 7K* The straight lines which oorrespond-to IPK go through the Intersection points of the two first families& It two &tons are in the oellp then the structure amplitudes Fit 710 71+X are equal 2 oos,21ra(p 2, coo 27ro 0 2 coo 2jr (0(+A) rssp. where o~and #,'or* the ration of the distancob of thq Oon 'up to the next lines of the f4milles I sad'X to the periods of lattice lines of theme familioal analogously for a(+#* Itow the rsls,tton of zoohariason in satis- fied for certain regions (triangles) but not for other onese Zt results that Doklady AkadeNauk LUL 340-542 (1935) URP 2/2 20 - 693 for values of the structure product ace 21rck a cos 21r(3* cos 21r(Q(+P)>I/8 the equation of Zachariasen to satisfied positively, With Increasing numter of atoms in-the cell the applicability of the equation diminishes and symmetry elements enjoin characteristic restrictions on it, Ci 4 11 .......... fi:i ',X, th, ,Jg, 2 t"i ~ 4 1) ::7 3 f,,r4 lit x 4t, E-L N, V. SUBJECT USSR/JuTumATICS/Statistics CARD 1/1 PG - 687 AUTHOR BELOT N.V., GOLOVASTIKOV N.I. TITLE OF-91-rong and weak statistical relations between the signs of structural amplitudes. PERIODICAL Doklady Akad.Nauk 105, 978-980 (1955) reviewed 4/1957 The author investigate the question of probability of other relations between the unitary structural amplitudes than the equation of Zaohar,ia:sn (S H+K -SH-SX e0ge 31+2K - SH*3K' and they find that the following relations have the probabilities of satisfaction in the margin for two atomst: S3H 3211*5H Ot83 34H S3H*3H M7 S5H S4H*S 11 0,80 S6H S5H S 11 0,70 S5H S3R'32H 0,77 S79 S5R*S 2H 0976 3811M S511033H 0,73- DOLGCPOLOT, N.N.; SHCHIMOAXOT. D.I., akademik. otvatetvenW redaktor-, 13ZLOV,_ji_IV,, akademik, redaktor; YORWIYZT, O.A., redaktor; CEUMMff, YX.----rq-aator; KO, N.P., redaktor izdatellstva; ASWITZVA. G.A.. a . - takhuichookly redaktor-- [Proleme in geochemi atry and miaeralogy] Toprosy gaokhinii i mineralogii. Moskva. 1956. 174 p. (MLEA4:7) 1. Chlon-korrespondent AN SSSR (for Chukhrov). 2. Akademiya nauk SgSi. Oideleniye goologo-geogran eskikh nauk. (Gooobexistrjr) (Mineralogy). Category USSR/Solld State Fhysics - Sclid State Theory. Geometric E-2 Crystallography Abs Jour Ref Zhur - Fizika, No 2, 1957 No 368o Author Belov, N.V., Tarkhova, T.N. inst Institute of Crystallography, Academy of Sciences USSR Gor'kiy University, USSR Title Color Symmetry Groups Otig Pab Kristallografiya, 1956, 1, No 1, 4-13 Abstract Description of a new,method of obtaining 46 infinite flat two-color groups of sy~netry by selecting from among the 230 Fedorov groups those vhich produce fr,-a a single initial symetric figure derivatives that are located only In two levels.. The corresponding symmetry elements will be 21.0 42466 1 c, n, and the Bravet lattices A, B, J, F. The ne4 derivation of &-color groups is compared with others. The extension of the new p:inciple of the derivation to groups containing symmetry elements 31, 32, 61, 65) 6ps 64j, d, and. the Bravet lattice R has made it possible to establish 15 colored Fedorov groups of symmetry. On the basis of the theory of the Bravet lattice, and explanation is given for Card 1/2 Category : USSR/Solid State Fhy,,-"Lcs - S-:1.id State Theory. C- =etric E-2 CrystaUcgraphy Abs Jour : Ref Zhur - Fiziks, No 2~ .1-957 No 368o the existence clf r-c-r,-,:!,rystnIlc,graphic colored groups with 5, 7, and more Colors fL'-r the case of the lcw syngonies. Card -. 2/2 V) N.V Category :USSR/Solid State Physics- Structural Crystallography E-3 Abs Jour :Ref Zhur - Fizika) No 2, 19~7 No 3703 Author :Belov,_N.V., Tarkhova, T.N. Inst :Institute of Crystallograpby, Academy of Sciences USSR Title :On Stripping Methods of Calculating the Fourier Synthesis in Structural Analysis of Crystals Orig Pub :Kristallografiya, 1956, 1, No 1, 132-136 Abstract :The use of the complements to 100 in ordinary strips instead of negative numbers makes it possible-to replace the addition and substraction oper- ation with addition alove. New types of strips are described., and a scheme is given for obtaining any strip with the amis divided into 60 parts, and also tables for the cosine and sine strips for h from 1 to 30 and for the amplitude 100, and which tables it is possible to obtain new strips for any amplitude. Card 1/1 USSR Solid State Physics / Structural Crystallograp4y E-4 Abs Jour Ref Zhur - Fizika, No. 5, 1957 No. 11655 Author sFesenkp, Ye. G., Rumanova, I. M., Belov, N. V. Inst 2 Title :Crystalline Structure of Zoisite. Orig Pub :Kristallografuja, 1956, 1, No.2, 171 - 196. Abstract :The elementary cell of zoisite Ca2Al3./S_iO47 O(OH), de- termined from the X-ray patterns of totation and from the f ar pinacoids of the zero development, is rhombiot &=16.20, b-5 50, o=10.14kX; Fedoi, The total 0 -ov group D~6 - pnma .h determination of the orystallihe structure of zoisite ig effeoted through a direct determination of the science of the structural amplitudes by statistical equations. A pro- Oedure is developed in detail for the separation of the re- ferenoe &Toup of signs for such a distribution. Cards 1/1 V N~v Category : USSR/Solid State Physics - structural CrystallograPhY E-3 Abs Jour : Ref Zhur - Fizika) No 2, 1957 No 3698 Author :.I~~Ov N.V., Torkhova, T.N. al Factors Title : Nomographic Method of Computing Structur orig Pub : Kristallografiya, 1956, 1, No 2, 235-238 Abstract : No abstract USSR/Crystals. B-5 Abs Jour Referat Zhur Khimiya, No 6, 1957, 18220 Author N.V. Belov, T.N. Tarkhova, Title On the 'Rex;ctahedron Group. Orig Pub Kristallografiya, 1956, 1, No 3, 360-361. Abstract A simple way to find the results of operations of axes *f symetry and rotary-inversion axes on obliquely situated planes of symmetry is proposed and discussed takin,3 the hexoctahedral group. as an example. On the attached sche- matic picture of a hexoctahedron, the indices of all its faces and the only operations, by means of which any face is obtainable from the initial face hkl, are shown. Card 1./i - 44 - V~ All Category: USSR Physical Chemistry - Crystals 33-5 Abs Jour: Referat Zhur-Mimiya, No 9, 1957, 29631 Author : Belov N. V. Inst :"Hogiv~en Title : On One-Dimensional Infinite Crystallographic Groups Orig Pub: Kristallografiya, 1956, 1, No 4, 474-476 Abstract: Utilizia-.% the generally accepted "international" symbol system of denotation of Mstallographic groups the author segregates all possible groups of one-sided and two-sided infinite one-climn ional patterns (borders and ribbons), and also groups of those stems hav- ing a main proportion wds of 3, 4 add 6. It is shown that in the case of borders (one-sided patterns) there am 7 groups (plu, pmu, p1ml, olal, p=2, pma2) p112), for ribbons -- 31 and for "crystallo- graphic stems" -- 53 groups. Card 1/1 V7 BJWV, N.Y. Medieval Mauretanian ornamentation designed in ranges of symetry groups. Kristallograflia, 1 no.5:61o-613 '56. (MLRA 10:2) 1. Institut kristallografii AN SSSR. (Decoration and ornament. Hobammedan) BMDT, M.T.; TARKHOTA, T.N. Correction to the article "Color symetry groups.11 Kristallografiia 1 no.5:615 156. (MLRA 10:2) 1. Institut kristallografti AN SSSR-. Gortkqvekiy GosudarptvenrWy universitet im. N.1. Lobachevskogo. (Grystallogmpby) swv, TARKHOTA, T.N. Color-group symetry. Kristg~llogrsfiia I no.6:619-620 (HLRA 10:5) 1.1natitut kristallografti AN SSSR i Gorlkovskiv gosudarstvenW umiyarsitat. BELOV, 9. V. I ISIAOV I N. V. Three-dimensional mosaics with color syumetry. Kristallograflia 1 no.6:621-625 '56. OWA 10:5) I.Institut kristallogralfii AN SSSR. (Crystals--Models) Appliances used, f(kr tqodeling crystal structures and crystallochomioal patterns* Kristallograffla, 1 no.6:733-734 156. (XLRA 10:5) I.Institut kristallo affi AN SSSR. forystals-Models) r N*V* Part 7: Studies in structural mineralogy. Kin.e'bor. no. 10:10-32 J56. (MM. 0112) (Nizeralogy) )0 0, Pt Ut USSR Structural Crystallogiaphy. E-3 Abs Jour : Ref Zhur - Fizika, No 4, M7, No 9229 Author :Mamedov, Kh. S., Belov, N.V. Title :Crystalline Struct-uRe-o-f-Wherals of the Wollastonite Group. I, Structure of Xonotlite. Orig Pub :Zap. Vses. mineralog. o-va) 1956) 85) No 1) 13-38 Abstract ;Results of X-ray difieraction investigations are reported for the crystalline structure of a mineral of the Wollas- t6nite group) namely Xonollite 6 Casi0j. Epo. Only the Weissenberg method and rotation were used and the radia- tion was Ho a K,~, . Owing to the fibrous structure of the mineral-, X-ray diffraction patterns were obtained only when rotating about the b axis of the needles. The lat- tice periods were a 16-50, b 7-32 (with a pseudo-period b 3.66) and c 7-03 kX, 0900, Z a 4, and Fedorov group P2/a. The signs of the Fhol amplitudes were determined with the aid of the Harper and Casper-,-Inequallties and the Zachariasen statistical equation On the basis of the projection of the electron density jJxz(, and also with Card 113 USSR / Structural Crystallography. E-3 Abs Jb~ur : Ref 2hur - Fizika, No 4, 1957, No 9229 Abstract : all.ovance of the analogy between Xonotlite and cuspidine and telleite, a model of the structure was found and was subjected to consainutive refinement by the arbitrary pro- jection method. The base of the structure ofthe Xonotlite are Ca-octahedra, connectex together by the oppositely- placed ribs, and extending along the b axis. The octahedra contain 1/3 of the atoms of calcium, while the remaining atoms of calcium are located in the trigonal prisms., con- nected along the ribs into columns placed on both sides of the columns of the Ca-octahedra along the second-order axis. Columns-of the octahedra and the-prisms combine to form layers parallel to the (001) plane. The structure of the Xonotlite displays a characteristic new type of silicon- oxide radical, namely a chain (ribbon) of composition[st,q,7-0' Card 2/3 USSR / Structural Crystallograpby. E-3 Abs Jour :Ref Zhur - Fizika, No 4, 1957, No 9M Abstract :which are located parallel to the columms of the octahedra and the prisms. The Si-O distances in the tetrahedra are 1.54 -_ 1.63 kx. The length.of the ribs of the Si-tetrahe- dra are 2.52 -- 2.60 M The Ca-0 distances in the octa- bddra and in the prisms fluctuate in the range 2.34 -- 2.60, M The structural features of Xonotlite explain well the fibrous nature and both cleavages of the minerals. Me de- fects and faults in the structure of !Xonotlite and of o- ther minerals of the Vollastonite group are examined. Card 3X3 MEN L 1- L-, 1 Mf UShR/ physical Chemistry - Crystals B-5 Abs Tbur Referat Zhur Khimiya) No 3) 1957) '(269 Author Pyatenko, Yu.A., Bokiy, G.B., and Belov, W.V. Inst Academy of Sciences USSR Title Radiographic Investigation of the Structure of Chkalovite Orig Pub Dou. AN sssR) 1956, Vol 108, No 6, 1077-1080 Abstract Radiographic methods (X-ray gonioneter and oscillation method, using Fe-K_,,, , Cu-K,,, and Mo-K. radiation" have been appLied to the investigation of the structure of Chkalovite Na (BeSy ). The crystals are rhimbic (Pseudotetragonai) wi Ettice parameters; a 21.1, b 21.1, c 6.87A, r (exper.) 2.66, Z ; 24.; the space group notation is Md. The structure vas deterrdned .by -the interpretation of the F(uw) and F(vw) projections and cross-sections KuvO).and F(uvI,) (assuming the struc- ture to be analogous to :~'-cristobalite and using crys- tal structure analysis); -the results were refined by the Card 1/2 38 -- -- ------------------- USSR/ Physical Chemistry - Crystals B-5 Abs Jour Referat Zhur - Khimiya, No 3, 1957, 7269 application of successive approxivAtions in carrying out a Fourier analysis. The structure of chkalovite appears to be derived frora that of ~- -cristobalite. The filling of 2/3.0f the total number of Iavsov polyhedra by Na atoms and the substitution of 1/3 of the Si atoms by Be atoms lead to a tripling of the A and b p9riods in chkalo- vite compared with the edge lengths of ' ".-cristobalite. This leads to a small displacement of the atomic coordina- tes fron their ideal positions. Card 2/2 39 BIILOV,, N.V-- XUROGHM X-L, konstruktor. Ing turntables for cars used in =loading brick clay from th6 pro:$L [Suggested b",y N.V.Boloy imd X.I.Kuro*WdnJ.B&t%.1'I%dbr. predl.v. sjrojw* tio*146s3-6 156. (nU 10: 2) 1. Glavhyy makhAnik Zguberetskogo savoilasilikatnogo kirptcha, (for Belov). (Brickmaking) AS USSR "The Structure of Silicates" (Section 2.1; "The 1651 sbubnikov Groups"'(Section, 16-3)- tapera'submitted at the General Assembly and International Congress of Crystallography, 10-19 Jul 57, Montreal, Canada. 0-3Y800;189 cd 70-3-1/20 AUTHOR: Belovq N.V. Neronova, N.N. and Smi:mova, T.S. TITLE: Shubnikov groups (Shubnikovmme gruppy) PERIODICAL: "Kristallografiya" (Crystallography) 1957, VcL 2, No. 3, pp. 315 - 325 (U.S.S.R.~ ABSTRACT: 1 r551 Shubnikov groups are presented in the new inter- national notation, prefaced by few fundam ntal theorems, which govern their derivation. The derivation of these groups is easily performed if we start from two-coloured translation groups; 36 such groups existq of which 22 are two-coloured and 14 are ordinary Bravais lattices. An obvious theorem.states that with a two-coloured lattice every (two)-coloured element of symmetry e4her coincides with a non-coloured element of the same kind (plane, axis, Centre) or altemates with it. In the notati6n of such Shubnikov groups it is sufficient to place behind the symbol of the Coloured lattice only non-Coloured elements of symmetry, i.e. one of the Fedorov groups. With the non-coloured lattice, i.e. when we have the ord- inary Bravais lattice, we have in the notation Coloured ftrd 1/3 elements. Introduction of them is governed by two simple theorems. Accoiding to the first one, odd elements of Shubnikov groups (Cont.) 701-3-1/20 symmetry (threefold axes) can be only uncoloured or grey, i.e. Shubnikov groups with these elements of symmetry do not exist. According to the second, if we have a finite or infinite two- coloured (black-white) pattern and then restitute the black half of components for the white ones, we obtain one of the ordinary(one-coloured) Fedorov groups. This means that when the lattice is an ordinary Bravais lattice all two-coloured groups can be derived by systematic substituti-ng of one, two or three independent symbols in the appropriate Fedorov group by the twD-coloured symbols.. A complete list is given of the 1 651 Shubnikov groups (pp. 318 - 325)9 which includes also the 230 Fedorov groups and an equal number of grey groups. Two-coloured elements are denoted by an apostrophe. Grey groups are denoted by an additional 11. This symbol does not appear in cubic groups, where we consider it appropriate to displace this apostrophe to the symbol of the (odd) axis 3. The derivation of Shubnikov groups was first accomplished in 1953i by A.M. Zamorzaev (2,3,4). In 1954 the authors derived them by the more crystallographic method, which had Card 2/3 been used in a short textbook of Fedorov groups by N.V.Belov. In these two papers one can find all the theorems which are Shubnikov groups (Cont.) 70-3-1/20 of use in this derivation. This is an almost complete translation of the text. There are I table-and 6 references, all of which are Slavic. ASSOCIATION: Institute of Crystallography, Ac.Sc. U.S.S.R. (Institut Kristallografii, AN SSSR) SUBMITTED: March 9, 1957. AVAIIABLE: Library of Congress card 3/3 AUTHOR: Belov, N*V* 70-3-T/20 TITLE: Now silicate structures. (Novye si1JkatrWke struktary) PBRIODICAL: 'MvistallogmMya" (Crystallography) 19579, . V01029 NO-39 PP- 366 - 370 (U.S.S.R.5 ABSTR&OT: Numerous textbooks on cryotal. chemistry and mineralogy contain essentially much materialf published by W.L. Bragg about twenty~_five years ago,and do not reflect advances made in this field during the last 5 - 7 years. Particularly, much important work, which has been carried out in the Soviet Union, has not been included in book literature. In this paper, a short review is given of about 10 new silicon struc- tures, all from the authov's laboratory, uhich represent a substantial addition to the classical system of silicates of Bragg; particular attention is paid to six types bf chain structures at piesent known instead of the two classical types and also the reasons which govera their existence. .iSome 'of these new silicate structures malm some of the class- ical structures not so unique as-they appear in textbooks. Card 116 Dioptase, CaAS'601~ 0 GH201 is, after beryl, another instance of a silicate with sixfold rings of Si tetrahedra. Katapleite, Na 27'rlS'3091 02H201 is also, after benitoite, the second New silicate stnictures. '(Coat,) 70-3-7/20 instance of a silicate with threefold rings Isi 3093- Gexd 2/6 Another representative of silicates with endless chains SiO3100 in every respect similar to those in pyrozenes is raTnsayite, NA2Ti2~'209- D~stead of the metasilicate ratio Si:O = 1:3, which is characteristic for pyroxenes, we have in ramsayite Si:O-= 1:4-1/26* Three oxygen atoms out of every nine do not partici ate in. the Si-O radical, and the correct fonrala is NA2~i203F-2061' Important is the discovery of another Si-O radical with hexagonal,symmetry, which is two-storeyed i 120 30 9 in the rare Swiss mineral milarite, KCa2(Al2Be) P-120 301 A reser- vation about the rarity of this -t--.M Oses its 5i 'fican e after the discovery that similar rings (Bi.Al) 0 juare c 12 30 - characteristic for uniaxial (high) cordierites as compared to biaxial (low) cordierites with rings [(Si,Al)60lj of the Iberyl type. Card 3/6 Now silicate stru6tures (C=t.) TO-3-T/20 'Pyrosilicatel groups U2'~ have been found in a number of minerals. In some of them the existence of these radizals is suggested by the formula itself: cuspidine, Ca4(S'2oY2$ til- leyite, Ca 5LS'20,,I(CO3)2; but in such minerals as ilvaite, epidote, zoisite these groups were a surprise as the formulae of these minerals gave no masons to suspect their ortho-proper- ties. In ilvaite all Si atms are in these pyrosilicate groups, but in epidote and zoisite the same structure contains two kinds of radicals: (SiO land (SiO41. The eighth atom 0 in il-vaite and the twelfth in epidote-zoisite do not enter the Si-O radicalt and the corresponding formulae are: and CaFe*** Fe2..* O(Si20710H (ilvaite) Ca2AlgeO[SiO4j(S'20?IOH (epidote). The chains (SiO31.0 in pyroxenes and ramsayite are identi- cal, but in the p~Toxenold-wollastonite, CaSiO 3, we have New silicate structures. (Cont;) 10-3-T/20 disc-overed a radical.of the chain type with the same fo=ula i0 lab but with very different geometry. When doubling the LS 3 pyroxene chain by a plane of symmetry we obtain a lath of amp- hi-bole with a formula. 4 SiO ~ 0 =18i4 011100 , but when doubling the chain of the wollastonite type type, 6 Si%5 - 0 = 18:1601?3op owhich xondtlite 8a 6(S'60171(OH)2' ,Instead of two classical types guish now six of them: three with we obtain a lath of an other is characteristic for of chains (Bragg) we di tin- the same formula Isio 3100 but with different geometries and three doubled types (laths) with formalae: [S'20,1,, (sillimanite), (Si401130,(amphiboles), [Si60171 QO (Xonot"te) The Si-O radicals are strong but not rigid, and accordingly morphological peculiaritbs of silicates depend on the config- urations of catUons such as Mg(Fe), Al., on one sidq.-and Ca(ifa) on another. In all stretched (columnar, needle-like) minerals Card 4/6 we find endless colilmns of Mg(Fe) , Al-octahedra or of Ca-oota- hedra. As a result of very different lengths of edges in these New silicate structures, (Cont 70-3-7/20 two kinds of octahedra (2.8 and 308 2) differeit Si-O-radicals arrange themselves along the cathion columns: pyroxene and amphibole chains along the edges of Mg(Fe) and Al-octahedra, wollastonite and xonotlite chains (laths) along the edges of Ca-octahedra. In silicates with groups L43?1 these groups arrange themselves with their axes at ri6ht angles to the columns of Al- or Be-octahedra (ilvaite, epidote) but parallel to the columns of Ca-octahedra (cuspidine, tilleyite). When cathion-octahedra are arranged in sheets, as in micas and similar TaInerals, Si-tetrahedra form also sheets; but these sheets are (psdudo) hexagonal with sixfold rings when over sheets of Mg(Fe) and Al-octahedia, but tetragonal with altern- ating tetragonal and octagonal rings over Ca-octahedra (apophy- llite). The following step in Ca minerals is the association (enndensation) of these sheets in three-dimensional frameworks also with tetragonal and octagonal meshes with are character- istic for felspars. The great partition of rock silicates in two categories,, melanocratic with high densities and leucocratic with low card 516 densities, is entirely determined by the size of cathions and their octahedra. The small Mg and Al cathions associate with New --si1ieate,,Stxuctu=s. (Cmt.) TO-3-7/20 close-packed (pseudo) hexagonal Si-O radicals. whereas the large Ca cathions and their octahedra associate with (pseudo) tetragonal.Si-O frem s with large meshes. The size of Mg and Al cathions is dmilar to the sizes of a great many cathions a large part of which are coloured. The (isomorphic) entrance of these cathions in (Mg, Al)-minerals results in their melan- ocratic charader. The large size of Ca cathions restricts the posaible isomorphic substitutions only to Na and K and hence leu4eratie characteristics of felspars and a -a 11 number of similar minerals. (This is an almost complbte translation of the text.) There are- 4 figures and 16 references, 12 of which are Slavic. ASSOCIATION: Institute of Crystallography, Ac.Sc. U.S.S.R. 0,01, (Institut Kristallografii AN Ss&-JALJ SUBMITTED: March 11, 1957- AVAILABLE: Library of Congress card. 616 - i U r ), AUTHOR: Belov, N.V. 70-5-19/31 TITLB: On a Course in Geometrical Crystallography for Physicists (0 trurse geometricheskoy kristallografii dlya fizikov) FE'RIODICAL; Kristallografiya, 1957, Vol.2, 140.5, pp. 6?8-685 (USSR) ABOTRACT: Crystallography, lying midway between physics, chemistry and mineralogy, was formerly closer to mineralogy and is now closer to physics. Teaching courses have correspondingly moved. Points are here discussed in which more understanding of the bases of crystallography should be shown when the subject is being taught to physicists. The Miller indices are more than coefficients in the equation of a plane. By introducing a fourth (dummy) index the three-fold symmetry of expressions in the appropriate system can be preserved. The symmetry groups T=23, 0=432, 1=532 can be demonstrated by spherical triangles on a sphere. The combinations of axes can also be best seen in this way. The meaning of the term d1hedron needs c-larification. Group theory, useful elsewhere in physics, helDs in the combination of symmetry elements. Fedorov's terminology for certain solids is defended against those who would prefer purer Greek terms. The use of models is very important. 'The deduction of the crystal classes 'based on a 1--ardl/2 five-fold axis is of pedag6tic value. The more mathematical ?0-5-19/31 Un. a Course in Geometrical Crystallography for Physicists. theory of polyhedra is useful and interesting to physicists. The'demise of the Fedorov notation (L4, P, C; L41 4L2, 5P, 0; .t the international symbols have great etc.) is regretted bu advantages, although they do not describe'symmetry without introducing a particular aspect. Group theory should be thoroughly inculcated. The rhombohedral system cannot be entirely absorbed in the hexagonal as it is pseudo-cubic. The change of co-ordinates with oblique axes is rarely carried out in geometry but is an easy and frequent operation in crystallography. There are 5 figures and 3 Slavic references. ASSOCIATION-. Institute of Crystallography Ac.Sc. USSR. (Institut Kristallografii AN SSSR) BJJI'--ED: April 18, 1957. "J, 3: - J A "OIE: Library of congress. t .-,rd 2/2 14 1.W k ~ - AUTHOR: ~eio'v', *N*V. ?0-6-2/12 TITLE: On the Groups of Tetartohedry (T=23) and gyrohedr7 (0=432). (0 gruppakh tetartoedra (T=23) i giroedra (0=432). PERIODICAL: Kris tallo graf iya , 1957 , Vb1..2,Wo.6 pp. ?22 - ?24 (USSR) ABSTRACT: The inter-relationship of the elements of symmetry in the Point groups 23 and 432 is expounded by a treatment like that in Ktistallograftya, Vol-1, P-3601 (1956). The group 23 can be represented by a cube, each face of %nich is halved by an oblique line (the whole system having the symmetry 23). The first face is marked 1, hkl and the other equivalent faces are marked with the operation deriving them from the first and with the equivalent index as follow 2., hrcT ; 3-+, IkFi 1hk 3-1 +, klh 3-1 3+++" ++ -+-I M ; 2z ) HE 2y Ekl 3-1 IRk 3 la ', 3-1 k1-h The 2 k1h ; 9 1 simplest figure is the pentagonal dihexahedron. The group 432 isiimilarly treated (there are 24 faces forming a pentagonal tetzhexahedron) and the additional elements 4 x 4y, 4. and their inverses appear. The full multiplication table for the (;ardl/2group 23 is written out and shows how any two of the above 70-6-2/12 On the Groups of Tetartohedry (T=23) and Gyrohedry (0=432). mentioned 12 operations when multiplied together give a third which is also a member of the group. For 432 with 24 elements in the group the table 24 x 24 would be too big to reproduce usefully. Specimen combinations from it are given. There are 3 figures and 2 Slavic references. ASSOCIATION: Institute of Crystallography Ac.Sc. USSR.- (Inatitut Kristallografii AN SSSR) SUBMITTED: October 7, 1957. AVAILABLE: Library of Congress Card 2/2 1 ?0-6-3/12 AUTHOR: Belov, N.V. TITLE: of the Primitiveness (Emptiness) of the Fundamental Paralldepipbd andsCrystal Lattice (Teorema primitivnosti (pustot~) asnovnogo parallelepipeds. kristallicheskoy reshetki) MRIODICAL: Kristallograftya, 1957, Vol.2, No.6, pp. 725 - ?27 (USSR). ABSTRACT: The theorem that in a crystal lattice all points with absolutely identical surroundings must lie at the vertices of the fundamental parallelepipeds whose sides are the 3 shortest translations and that no points can occur inside or on the edges or faces has been proved, although it is an apparently obvious theorem, only at great length. In 1951, Belov (Dokl. Ak.Mauk, SSSR, Vol.78, Ao.1, 1951) produced a proof occupying only 3 pages but this was not as elementary a one as is poss- ible. This proof satisfactorily excluded all cases but those of body-centering and face centering. Calculating the lengths of the face and body diagonals readily shows that the existence of an extra point contradicts the assumption that the parallel- epiped was chosen as defined by the three shortest translations. (;ardl/2 If there are two extra points they can only lie one-third and 70-6-3/12 The Theorem of the Primitiveness (Emptiness) of the Fundamental .Parallelepi&d of.6 grystal-L6ttice. two-thirds of the way along a body diagonal. It has been shown (Structural Crystallography,,,m.V. Belov, 1951) Thai in the primitive parallelepiped 60 ' ~ a , 0 , y < 120 so tat one- third of the longest diagonal is less than o.~72e and this case falls. Three extra points can only lie at the centres of three faces and are similarly excluded. If there are 4 or more points, then they must lie on a subsidiary lattice rationally related to the basic parallelepiped and on this basis the case can be excluded. There are 2 figures and 3 Slavic references. ASSOCIATION: Institute of Crystallography Ac.Sc. USSR. (Institut Kristallografii AN SSSR) SUBMITTED: October 7, 1957- AVAILABIZ: Library of Congress. card 2/2 LZMAT, Nev.l akadaulk; LIRNW, T-I-t doktor Coologo-mineralogicheskikh muk, 1--mmmumme &orgy sources of geochouleal processes. Prlroda 46 uojilwo w '57, N-MOi6t6) - 1, lustitut kristallografti AbLdeuii uaut SSSR (Ka*va) (for Rialov). 2. Leniagradeldy CosudaretvauW urAverattet iu. A.A. Zhdanova (for Labed6y). (Gooohomistry) (Thermochemistry) I;;lQ 1e 9fk-t~Tr,-" the zi, IM BELOVIP # Studies on structural mineralogy, Part 8. Min.abor. no.1l.- 3-21 157- (MIRA 13:2) 1. Institut kristallografii AN SSSR, Moskva. (Crystallography) LZBEDEV. V.I.; BILOV. N.V. Goncerning O.P.Mchedlov-Petrosianis critique of the hypothesis of the accumulation of solar energy by crystalline substance. Min.sbor. no-11:371-374 1571; (KUM 13:2) 1. Institut kristallogmfli AN 838R, Moskva. (ogler energy) SOV/20 1,14-4-5~/63 AUTHORS: Favlov, P. B. and Belov, 11. V. Academician TITLEi The Crystalline Structure of Herderite, Datolite and Gadolinite (kristallicheakaya struktura gerderita, datolita i gadolinita) PERIODICAL: Doklady VT 335R, 1957, Vol. 114, Nr 4, PP. 884 - 887 (USSR) ABSTRACT: The structure of herder~ite CaBePO F was solved by-ditect methods G 1y determire d temperature-coef- (references 1, 2). The simultaneo fidient 0,50 was used to exclude the temperature-factor from F ko 15 among the afterwards calculated (absolute) individual ampl ~ >0,5- Yor 56 (36 C had a value of %) of largest U 0 tudes Uhk o sions Viere found according to the method of inequality. Again checked according to the statistic method by Zakhariasen (references 1, 2) they formed a supporting group. Based on the latter the signs of the other F were merely statistically determined. Altogether bk o 128 from 155 signs were determined with a probability of not less than 71 %. The electron-density-diagr'am built up on the basis of the F . provided with signs, in a projection along c - 4,80 1, at u o Ca-peaks and elded a wel4resolvable image with powerful once ~i 2 kinds of tetrahedrons, One half of these was identified as P, in Card 1/4 the other tetrahedrons with a triple axis normal to the projection SOV/20-114-,41456/63 The Crystalline Structure of Herderite, Datolite and Gadolinite under the 4- 0-(F)-atom lying on it a Be-atom was assumed. Pigure I gives the structure of herderite according to the atom-coordi- nates (table 1). Figure 2 gives the same structure in polyhedrons of Pauling and this proves the existence of two layers. In the low- er layer lie (somewhat deformed) twisted cubes, in the upper, layer a net of bound PO tetrahedrons in one orientation z.,Lnd tho BPO F_ tetrahedrons in ;Aother orientation. After thc deciphering of ihe herderite-structure was concluded, its great similarit,Y with dato- lite earlier interpreted by Ito (reference 5) became evident. The coordinates of Ito are Civen in column 2 of table.l. As far as the structure was solved by Ito by the method of the (medium-) heavy atom tho authors again calculated it by means of the same direct 2-stige method, but with the use of a much larEer number of re- flections (150 P as against 95 of Ito) in the range up to (gk sinla 1,1 .2 radiation). The application of the direct meth'od to the projection xz was especially suamseful. Here the B-atoms distinctly appeared. The obtained atom-coordim tes are given in the third column of table 1 The difference as compared with Ito's results is up to 0,025 (011; � in z-coordinates). The tetrahedeons of two types became much more reCular. The same direct method (with Card 2/4 inequalities in the first stage) was employed in the deciphering-