SCIENTIFIC ABSTRACT BANKOVSKIY, I. U. - BANKOWSKI, C.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000103410014-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 9, 2000
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

v Y
PHASE I BOOK EXPLOITATION SOV/4226
Riga. iniversitat;
Uchanyye zapiski, t. 14, Khimicheskiy fakul'tat, 4 (Scientific
Notes, Vol 14,
Chemistry Facultyl 4) Riga,, 1957. 251 P. 550 copies printed.
Eds. (Title page): A.F. Iyevin'sh, Professor, Doctor of
Chemistry; L.K. Lapin',
Member of the Academy of Sciences Latviyskaya SSR, Professor,
Doctor of
Chemistry; G.Ya. Vanag, Professor, Doctor of Chemistry; Tech.
Ed.: A. Peterson.
PURPOSE: This book is intended for inorganic chemists and
scientists in the ceramics
industries.
COVERAGE: The book contains 22 articles on organic chemical
synthesis and analysiE
and the pbysicoebemical properties and compositions of ceramic
and refractory
materials. No personalities are mentioned. Figures, tables, and
references
accompany the articles.
TABLE OF CONTENTS:
1. Iyevin'sh, A.F., E.Yu. Gudriniyetsep -Yu.A. Bankovskiy Ya.A.
Tsirul. Reectaors
of Divalent Iron With 1, 1-Dimethyl-3, 5-c1(yc615h'!!e!5- ne
Trioxime 3
Card 1/4

Scientific Notes (Cont.)
SOV/4226
2. Yanson, Z., A. Iyevintsh, and E. Gudriniyetse. The Use of
Sodium
Tatraphenylboron in Quantitative Analysis 9
3. Groskaufmanisp A.j, A. Veiss.. and U. Alksnis. The
Luminescence of
Aluminum Oxide Hydrate 17
Balodis, Yu.R. Resistance of the Boundary Layer, Electrode
Potential,
and the Corrosion of Aluminum in Aluminum Sulfate Solutions 25
5. Vanagt G.Ya. Lignin as a Reagent for Qualitative
Determination of
Aromatic Nitro Compounds 35
6. Vanagp G.Ya., and A.K. Aran. The Interswtion of
2-Bromo-2-phenyl-1
3-indandione With Primary Azines 41
7. Romadans I.A. On the Predicted Mechanism of the Alkylation
of Naphthalene
and Dipbenyl With Alcohols Using a BF3 Catalyst 49
8. Gririhtey-A, V.) E. Kalninya, and G. Villere. Study of
Usninic Acid and Its
Derivazives 63
Card 2/4

Scientific Notes (Gont.)
SOV/42-26
9. Grinshteyn, V., and Z. Leymane. The Concentration of
Phytotoxins of
Prunus Padus and Their Influence on Ferments 79
10. IrArlivan, V.P., and P.N. Odintsov. The Problem of
Preliminary Hydrolysis
["Pre-bydroapis"I With Water and Acid Before Cooking
Cellulose in the
Sulphate Process 89
11. Eiduka, J. Properties of Typical Clays of the Latvian
SSR 99
12. Eyduk, Yu. Ya. Properties of Gypsum Calcined at Low
Temperatures 123
13. Freydenfelld, E. Zh. The Use of Lignophosphogypsum for
the Production
of Binding Substances 155
1 /,. Freydenfeltd, E. Zh. The Production of Caustic
Dolomite 161
15. Iyesalniyetse, A.A., and Yu.Ya. Eyduk. Properties of
Some Opaque,
Easy Malting, Non-Lead and Non-Boron Glazes for Structural
Ceramics 167
16. Freydenfelld, E. Zh., and U.Ya. Sedmalis. The
Possibility of Using
Mangarase C~en-Hswth slaU3 for the Production of Binding
Substances 173
Card 3/4

Scientific Notes (Cont.)
SOV/4226
17. Eyduk, Yu.Ya. Retarders of the Setting Period of Gypsum
Calcined
at Low Temperatures 179
18. Maksimova, O.S. The Interaction of a Fireclay Refractory
With a
Fluorine-Containing Glass Batch 195
19. Freydenfelld, E. Zh., and A.A. Apsitis. Physicochemical
Properties
of Compositions of the System CaO-BaO-TIO2 201
v
20. Ozoligs, J., and J. Eiduke. The Role of Magnesium Oxide in
the Pro-
duction of Silicate Brick FroutDolomitic Lime 211
21. Eyduk) Yu.Ya., F.G. Paukah, and O.S. Maksimova. The
Influence of Some
Technical Factors on the Properties of Enamel Coatings on Cast
Iron 221
22. Eyduk, Yu.Ya.p V.G. Reyne, L.A. Skuya. The Physicoehemical
Properties
of Easy Melting Faience Glazes 225
AVAILABLE: Library of Congress
Card 4/4 JA/rn/afm
9/29/60

BAHKOVSKIjj,..IU.. -
- ~ -~
GZMMA
PERIODICALS: VESTIS, No. 3, 1958
RARKOV.M1, IU. Analytic application of
8-mereeptoaquioline (thoixins) and
its derivatives. VI, Vanadium comnlex of thoixine and
its properties.
Colorimettlo determination of vadadium. In Ruegian. p.
121
Monthly liat of Fast Maropean Accesalons (EFAI) LO Vol.
8, No. 2,
February 1959, Unclasrs.

AUTHORS: K,,;metat)';, V. I.. Bankt.~vsk-lly, Yu. A., 7_ /2-
Iyevill I sh. A. F
TITLE: The A-vi- lytical' Use of S.-Morcaptcrquinoline and lt~
De:r'-gat-ires rinalit_inheski~ya primeneniye
8-merksptekh4r.-j-,4r_-_,
4-ye-g-1 proizvr_d_-iykh)
PERIODICAL: Zhurnal analiticheskc-,y khimii, 1958. V-o?. 1.7:
N-~- ~j pp 267-
-2'13(USSR)
ABSTRACT: has been knnvni ffor ri long time kRef 1), 11-aii;
hitherto; has not been met wit-h any inter,~st in analyTi-~al
cham-
istry (Ref 2). The reas,,n for this was the diffjoul+y of
synthe.,
ais and the low stability of thJ.s compound and its derivatives
which rapidly oxidi7e at the air. Onp of the authors of the
pre-
sent paFer worked ~vt a, syntheaie of (Ref 3)
wbereby 't became oasi-ly an-_ess'ible. i-t~vas found bat
ti7~n salt of hydro,.;h~'oric a-z~id *_i~ ,:~sistant to oxygen
and 4~h&, ii~ can thex-afore. ser-%-e fi-#2 storinq
T_h,~~ pioperties of anhydrous 8--me.7-captoquin-line and :f
the fel-
lowing der-*.vativei;. are deBctr:*Lbed in +.he present paper.
the. di-
hydrate, the hy*Tf)chloride, the sodium saltsnd the dieulfide
Card 1/4 whi,,h is produced from 8-mercaptoquinoline by
oxidation. The

The Analytical Use of 6-14ereap0quinoli.ne (Thiooxir-~)
; ., i , I ') -,
and Its Derivatives
authc,rs also investigatod the analytl.;~al pr:)pertiev, and.
rea-:i-
tians of 8--meraaptoquinoline. Th-, -a nev., ieagmen';
prt~-cipiLate,-~ the
element-,,i of ~he I12S-'-roup and. -,f the ammendlum. sulfide
Crou-P.
Some el-,-Ments which beside the Me-S bond aJs,,, yleld a
Stabl.9
bond with the nitrogen of 'he quincline ring are 17'VE11
PreClp?~--
ta.t.?d fr~~M -il-id solutions. Thin qualitat~-~Y,~. of
proof bast-d on this faut are distint-~,"hed by a high
sensiit-J,vity.
A nuraber of alament.,~ are libarat-sd as ct-m-ijounde ti'
cor"ai--a
-io -L I
s~lmpos~-, -in wh`~:h can be we`ghed o-a' ae svic-;.
Thd8--meTC-i--,'C-
quAnn-Jr.ates of %7 Za, 11,,T TI A- A V)~
V, N4 Pd
Sb(III), B.", Mc , Mn, Fe Co, ;i.--.Iubl-- -"..n crgan-
.qz~ solvents (especial -ly in brom,benzene, by~~imofcrm~ benz
-
~nF~ and
4-Oluene) and --.an be exfrai~ted- rhf--:ctby the ~7.+' small
amount3 of one element from very large amounts of other
elements
whi,~h dc n:,,+ rea,~~, with the xeagent iia mads SC.,U.-
tions of some in S are
tensively z;-,larad and can be The s,~n-
s
.1 0
lt-,ity of these -rea~ttiors J.9 hi.Sher than Jn the-
Card 2/4 and appx-aohes thrt th
4 L

- r-.
The Analytical Use of 8-Mercaptoquinoline (Thiooxine) and
Its Derivaives
zonates., As compared to dithizone, ':Ias the
advantage of a higher specIficity. The use c-f thi- ne-
-,~s~gent
also permits the titrimetric determ,--nation of i ralz-'-~e-r
ments, as 6-mercaptoquinol.ine is by oxidiziln,; ;,~&S7-Ly
converted to the disulfide, A disadvantage of the -eafrc,- is
its easy oxidizabilityv In aoid solutions. hoiye-er~ ~'np ~X.
dation by atmospheric oxygen takes place, so does
not disturb the analysis, As 8-mercaptoquino-,.4ne ;i; T'?ai_
stant to very strong reducing agents, eieme&6 bgE~-J.ne
in their lowest stages of val ence No' W, etc.' ) CW.1 b-- r
or.
plexly bound by it, which is impossible with dith'zoiv-, A~z
c-ompared to thionalidej 8-iaerc~ apt oqu--nQlin:?
vantage that it precipitates a number of elRmen"~~ av..'r.
very highly -acid solutinns. In subsequei.-
the determination of di.fferent elements by means of tl)e -oew
reagent shall be indivi.duaII7 described, There a:r,--? 'I f
.71-rps,
1 table, and 14 references, 6 of which axe 6ovie-~'
Card 3/4

The Analytical Use of B-Mercaptoquinoline (Th-ooxine) and
Its Derivatives
ASSOCIATIM Inatitut geoklimit J analiticheskoy khimi.j
im- V.".,, Vqr
nadskogo AN E;SSR i Institut khimiii AN Latviyshoy SSIR
(InstituT,,~ of' Geochemistry and Analytier.'-
Chem-4--str.-7
V.I. Vernadskiy AS USSR and lustitute of Chemist-y,AS La--
SUBMITTEDs March 28, 1957
Card 4/4

AUTHORS: Bankovskiy, Yu. A., Iyevin'sh, A. F.
SOV/75-13-5-1/24
TITLE: Ana'lytical Application of 8-Mercaptoquinoline
(Thiooxine') and
Its Derivatives (Analiticheskoye primeneniye 8-merkaptc-
khinolina (tiaoksina) i yego proizvodnykh) Communication II.
Photometric Determination of Small Amounts of Palladium
(Soobahcheniye II. Potometricheskoye opredeleniye malykh
kolichestv palladiya)
PERIODICAL: Zhurnal analiticheskoy khimii, 1958, Vol 13, Nr
5, PP 507-512
(USSR)
ABSTRACTi Many methods for detecting and determining
palladium that make
use of its high reducibility and the resulting formation of
deeply colored colloidal solutions (Refs 1-7) or of measuring
the optical density of colored complex compounds of
palladium,
are appropriate only for the determination of larger amounts
of
palladium because of their comparatively low sensitivity. In
this respect, organic reagents, especially those that contain
the p-nitrosophenylamine group, are more important (Refs
14-17)-
These methods have the disadvantage that neutral salts affect
the determination and that series of foreign ions have to be
Card 1/4 separated at first. A number of photometric (Refs
18-24) and

SOV/7-r-1-13-5-1/'24
Analytical Application of B-Ilercaptoquinoline (Thlooxine)
and Its Derivatives.
Communication II. Photometria Determination of Small Amc~Ants
of Palladium
gravimetric (Reifs 25-34) methods for the determination of
palladium are quoted in the literature on the subject. A
highly
sensitive reagent for palladium is thiooxine, which may de-
termine this element under certain conditions, also with other
elements present. Thiooxine forms, with Pd(II) salts, the
bright
red palladium-8-mereaptochinolate Pa(C 9H 6NS )2 -H20 which
is i4n-
soluble in water, but soluble in various organic reagents by
forming deeply colored solutions (pink or orange) (Ref 37).
For
the extraction of this compound especially chloroform, chloro-
benzene, and bromobenzene can be used. The compound is some-
what less soluble in carbon tetrachloride, diethylether, amyl-
acetate, and carbon disulphide; it is insoluble in alipbatic
hydrocarbon. The high solubility in organic solvents, the in-
tense color of these solutions and the high acid rbsistance of
this compound suggest that it is an intermolecalar salt. ?re-
8umably a stable pentacyclic ring is formed in the re?ction of
thiooxine with palladium ions, in which palladium substitutes
Card 2/4 the hydrogen of the mercapto-group and at the same
time is bound

sov/175-13-5-1/24
Analytical Application of 8-Mercaptoquinoline (Thiooxine) and
Its Derivatives.
Communication II. Photometric Determination of Small Amounts
of Palladium
by coordination to the nitrogen of the quinoline ringi
S__
I
cil I
P
This compound is very stable. It can be completely extracted
from highly acid solutions (4n HC1) and also from strongly
alcalic solutions. The absorption spectrun of the solutions in
chloroform shows three maxima, of which the maximum at 272 m~t
is the most sensitive one. This was, however, measured In the
visible scope of the spectrum (maximum at 485 mp) in a
?ulfrich
photometer. The solutions conform to Beer's law up to 27~L/ml
when extracted from 6n HCI. In order to eliminate the inter-
ference of foreign ions thiourea is added in highly acid solu-
tion as A screening complex-forming substance. With this
method,
palladium can be determined in the presence of Pt, Os, Ru,
Rh, Ir, Cu, Ag, Au, Hg, Fe, Ni, Co, Zn, Cd, Ge, Mn, Tl, ks,
Sb,
Card 3/4 Bi, Sn, Se, 'W, Mo, Pb, U, V, and of other elements.
The results

SOV/75-13-5-1/24
Analytical Application of B-Mereaptoquinoline (Thiooxine) and
Its Derivatives-.
Communication 11. Photometric Determination of Small Amounts
of Palladium
of several determinations are quoted. Oxidizing agents inter-
fere with the determination as they oxidize the reagent. lk
very large surplus of the reagent is desira~ble in the
determi-
nation, as this reduces the dissociation of the precipitate. A
photometric method for the determination of' 5-270,y of
palladium
in the presence of all the foreign ions listed was worked out.
The working directions are described in detail. There are 3
figures, 1 table, and 40 references, 12 of which are Soviet.
ASSOCIATIONi Institut khimii Akademii nauk Latviyakoy SSR,
Riga (Institute
of Chemistry of the Academy of Sciences, Latviyskaya SSR,
Riga)
SUBMITTEDt May 16, 1957
Card 4/4

5(2), 50)

AUTHORSt
Bankovskiy, Yu. A., lyevint.sh, A. F.
SOV/75-13-6-3/21
-----------------------
TITLE%
- -----
Analytical Application of 8-Meroapto Quinoline (Thiooxine)

and
Its Derivatives (Analiticheskoye primeneniye

8-merkaptokhinolina
(tiooksina) i yego praiivodnykh)

Communication III. Photometric
Determination of Small Amounts

of Copper (Soobahcheniye III.
Fotometricheskoye opredeleniya

malykh kolichestv medi)
PERIODICAL:
Zhurnal analiticheekoy khimii, 1958, Vol 13, Nr 6,
pp 644-646

(USSR)
ABSTRAM
Peyve and Ivanova (Ref 12) used the
reagent '.hiooxine sug-

gested by the authors of the present
paper for a rapid direct

photometric determination of copper in
soils without preceding

separation of iron and manganese. In the
present paper the

influence exercised by other elements upon the
accuracy of

this determination and the limits of its
applicability are

investigated. Thiooxine forms in neutral, acid
and alkaline

0
solutions with Cu2+ ions the dark-brown salt Cu(C
' 1/2 H
H
NS)

2
6
2
9

which is insoluble in water. The crystal water in this com-
Card 1/4
pound was determined according to Chugayev's and
Tserevitinov's

Analytical Application of 8-Mercapto quinoline SOV/75-1 3-6-
3/21
(Thiooxine) and Its Derivatives. Communication III.
Photometric Determination of Small Amounts of Copper
method (Ref 13) for the determination of active hydrogen.
Foj- the analysis of the complex this wae -ned in vacuum at
14 whereby possibly part of the crystal water is lost so
that the copper thiooxinate actually might contain a whole
and not only a half crystal water. The complex is well
extractable with chloro benzene, bromo benzene, chloroform,
amyl acetate-and isopropyl alcohol, to a smaller degree with
benzene, toluene, xylene and diohloro ethane and very
difficultly with carbon tetrachloride and carbon disulfide.
In aliphatic hydrocarbons the compl,yx is insoluble. The
extraction of the complex takes place quantitatively both
from
alkaline and acid solution. The absorption spectrum was taken
by means of a SF -4 spectrophotometer. The spectrum shows
3 maxima. at 252.5 mj4, at 275 m~A, and in the visible range
at 431 mA . The corresponding molar extinction coefficients
have the values 31,000, 29,000 and 7,530. The solutions of
the complex which are colored intensely dark-brown, obey
Beer's law up to amounts of 8r Cu in 1 ml chloroform. Very
Card 2/4 high concentrations of alkali metals and metals of
the alka-

Analytical Application of 8-Mercapto Quinoline . SQV/7550-1
3-6-3/21
(Thiooxine) aud Its Derivatives. Communication III.
Photometric Determination of Small Amounts of Copper
line earths, Al, Ti, Zr, Th, Ef and cther elements do not
interfere with the copper determination. Pd, Ru and Os must
be absent. Pt does not interfere with up to quantities of
50y- approximately. The thiooxinates of Ag, Hg and Au are
not extractable with organic solvents. Silver, however, irter-
feres with the determination of small amounts of copper, since
this is co-precipitated with the very stable Ag thiooxinate.
Ordinary quantities of Hg 2+ and Au 3+ (4 and 10 mg,
respectively)
do not interfere with the copper determination. The thiooxine
complex of molybdenum is stable in acid solutions. Amounts
of 5-10 Mo can be masked by ammonium thiocyanate. Tungsten
does norinterfere with as its thiooxinate is insoluble in
chloroform. Considerable quantities W can be kept in solu-
tion by oxalic acid. Antimony in amounts > 50 11 htly
increases the results of the determination of OrCu- It is
an important advantage of this method that even 'Very large
amounts of bismuth do not interfere with the determination of
Card 3/4 copper. High concentrations of the generally used
anions

Analytical Application of 8-Meroapto Quinoline
SOV/75-13-6-3/21
(Thiooxine) and Its Derivatives. Communication III.
Photometric Determination of Small Amounts of Copper
2-
(C1-, Br-, F-, SO 4 , tartrate, oxalate, etc.) do not
influence the accuracy of the determination. In alkaline
solution cyanide ions prevent, if they are present in con-
siderable excess, the complete extractability of copper.
Furthermore, a photometric method of the determination of
copper traces (3-30y) in the presence of very large amounts
of Bi, Mn, Fe, Ni and other elements was devised. The
procedure is described there in detail. There are 3 figureat
1 table, and 13 references, 8 of which are Soviet.
ASSOCIATION: Institut khimii Akademii nauk Latviy3koy SSR,
Riga (Riga
Institute of Chemistry of the Academy of Sciences
Lat7iyskaya
SSR)
Card 4/4

.1
BANKOVSKIT, Tu~A-, RAUXa. T-K-, IMINISH, A.Y. [Isvins,
A.F.1
GalcrJuetrio micromethod for detemining calcium In
blologIcal
miterial (with sumary in Anglish]. BioWaiia 23
no.6s&6-W
li-D 15 a (MIRA 11312)
1; Iustitut khiaii i Instiut biologii AN Latviyakoy
SSR. Riga;
(CALCIUM)
COLORIMSTRT)
CROMMMISTRT)
M

AUTHORS:"-' Bankovskly, Yu. A.P Iyevin'sh, A. F.,
SOV/79-28-8-55/66
Lu
TITLE: A Simplified Method for Synthesizing 8-Mercaptoquinoline
(Thioxine) and Its Potassium and Sodium Salts (Uproshchennyy
metod sinteza 8-merkaptokhinolina (tiooksina) i polucheniye
yego kaliyevoy i natriyevoy solo)
PERIODICAL: Zhurnal obshchey khimii, 1958, Vol. 28, Nr 8,
pp. 2273 - 2276 (USSR)
ABSTRACT: Thioxine was first synthesized by Edinger
(Edinger)(Ref 1).
As the authors showed, this reagent appears to be a very
valuable reagent for the qualitative and quantitative de-
termination of trace amounts of palladium, copper, molybdenum,
rhenium manganese, and other elements. Earlier, one of the
authors (Ref 2) had refined the carrying out of a single
intermediate stage in the Edinger thioxine synthesis. In this
bynthesis the production of an intermediate product, the
benzoyl derivative of thioxine, is not easy. It was shown by
the authors that this intermediate step can be by-passed. To do
this, only the sodium salt of thioxine is needed; this salt
Card 1/3 forms by reacting the alkali base with the chloro-tin
salt(,).

A Simplified Method for Synthesizing 8-Mercaptoquinoline
SOV/79-28-8-58/66
(Thioxine) and Its Potassium and Sodium Salts
The sodium salt is oxidized with hydroGen peroxide to
the disulfide (!I), which precipitates out of the alkaline
solution. The disulfide can be easily purified and reduced
to the thioxine (III). The most convenient and energetic
reducing reagent appeared to be hypophosphoric acid
(potassium hypophosphite in hydrochloricacid solution).
This reaction occurs without the formation of by-products
(see the reaction scheme). The synthesized potassium salt
of
thioxine.r,~Ln be stored without decomposition. The
compositip
of the potassium and the earlier synthesized sodium salt
was
established. The reduction of the disulfide to thioxine and
the synthesis of its potassium and sodium salts are
described
in the experimental section. There are 6 references, 0 of
which is Soviet.
ASSOCIATION: Institut kh4-mii Akademii nauk Latviyskoy SSR
(institute of
Chemistry,AS Latvian SSR)
SUBMITTED: June 19, 1957
Card 2/3

A Simplified Method for Synthesizing 8,-Mereaptoquinoline
SOV/79-28-6-58/60'
(Thioxine) and Its Potassium and Sodium Salts
Card 3/3

AUTHORS:
Ban!-ovslciy, Yu. A., Lobanova, Ye. F.
S0V/"1q-2b'-1o-5o/6r,
TTTLE:
Synthesis of 6-Bromo-8-Mercapto
Quinoline (6-Bromo Thioxene'),

and Some of Its Pro-oerties
(Sintez u'-brom-C---,erlcal)tol-h;.nolina

(6-bromtiooksina) i
yo6-o nel-,otoryye svoystva)
PERIODICAL:
Zhurnal. obahchey
khimii, 1958, V;jl 28, Nr lo,

pp 2857-266o (USSR)
ABS'ZRACT:
As
demonstrated by the present studies, 8-mercapto

quinoline
(thioxene) is a Cood analytical rea,3ent

for the calorimetric
determination of copper, palladium,

molybdenum, manGanese,
vanadium, and other metals

(Ref 1). For analytical purposes,
the derivatives of

G-mercapto quinoline can also be of
interest, as the

presence of substituents in the quinoline
nucleus affects

the properties of the functional atom
groupinoz, thus

being able to change the analytical
prop--erties of the

reagent. The synthesis of 8-mercapto
quinoline and of

5-bromo-8-mercapto quinoline was achieved by
EdinEer

(Ref 2), and has been improved by Yu.A.Bankovskiy
(Ref 3).

Later on Rie-el (Ref 4) described the synthesis of
4-chloro-
--.rd 1,2
8-mercapto quinoline. In the paper under
discussion,

Syntheois of 6-13roirio-8-Mercapto Quinoline (6-Bromo
SOV/79-28-10-50.1/',ro
Thiozene), and Some of Its Properties
the synthesis of 6-bromo-8-mercapto quinoline is
presented. By the method of Edinr~er, the synthesis
of 6-bromo-8-mercapto quinoline (VI) can be cari~ied
out in accordance with t",o Pat$.-orn specified. Its
synthesis and its hydrnlysio have not yet been de.,!oribed.
In aqiieous oolution.9 with cations of the hydrogon
sulfide- and ammonium sulfide groups it forms inner
complex salts which are Y.-ater-insoiuble and solve in
organic solvents. There are 6 references, 2 of which are
Soviet.
ASSOCIATION: Institut khimii Akademij nauk Latviyskoy SSR
(Institute
of Chemistry at the AS Latvian SSR)
SUB!-.!,'ITTEn: July 25, 1957
Card 2/2
%j

BANKOVS Riga); Ievin'sh, A. [Ievins,A.] (Riga);
LOKENBAKB, A.
mu~~
(Riga); ZARUMA, Do (Riga)
Zinc thiooxinate. Vestis Latv ak no.10:U5-121 159. (EM
9:10)
(Zinc)

5(2), 50) SOV/75-14-2-14/27
AUTHORS: Dankovskiy, Yu. A., Ijavin'sh, A. P., Lukahap E. A.
TITLE: Analytical Application of 8-Mercaptoquinoline (Thiooxine)
and Its Derivatives (Analiticheskoye primeneniye 8-merkapto-
khinolina (tiooksina) i yego proizvodr4yl:h). Communication 4.
Photometric Determination of Small Amounts of Maneanese
(goobshcheniye 4. Fotometricheskoye opredeleniye malykh
kolichestv margantsa)
PERIODICAL., Zhurnal analiticbeskoy khimii, 1959, Vol 14, Nr 2,
pp 222-226
(USSR)
ABSTRACT: In alkaline and ammoniacal solut4ons bivalent -man,
ganese re-
acts in the presence of tartrates and citrates ivith 'Whio-
oxine under the formation of an inner complex salt of dark
brown color. The preparation of this salt in pure form is
described in this paper. Manganese thiooxinate 'L~_-n(c 9H6
!TS)2
is insoluble in water, with dark brown color, however, 7e11
soluble in most of the organic solvents. In carbon disulphide
and corbon tetrachloride the compound is very difficultly
Card 1/4 soluble, and in aliphatic hydrocarbons it is
insoluble. Ex-

S 01T'/75-14-2-14/27
Analytical Api.-lication of 8-Mercaptoquinoline (Thiooxine)
and Its Derivatives.
Communication 4. Photometric Determination of Small Amounts
of Man:-anese
tracts of manganese thiooxinate are stable for two da,s in
toluene, benzene, chlorobenzene, and xylene. At a longer
storin4; the extinction of the extracts decreases. Soliitlions
of the complex in chloroform or bro-moform are less stable.
The complex is stable only in alkaline solutions and can
be extracted only at PH > 7. Two maxima are observed in the
absorption spectrum of manganese thioocinate: X 1 = 250 mil
(molar extinction coefficient E 1 = 34000) and A 2 = 413; M11L
( F-2- 7000). The solutions of the complex in carbon
tetrachloride are subject to Beer's law im the case of amounts
of < 4 7 Aba in 1 ml CCl 4" Alkali and alkaline earth metals,
Al, Cr, Zr, Th, Ti, La, and other elementa forming unstable
sulfides in water do not disturbihe dete:rmination of
man--anese.
Since the reaction of manganese with thiooxine takes pl&ce
in an alkaline medium, it is not very specific because all
elements which form sulfides stable in water are precipitated
as sulfides in alkaline solution with thiooxine. Iron, cobalt,
Card 2/4 nickel, palladium, copper, molybdenum, antimony,
arsenic,

SOV/75-14-2-14/27
Analytical Application of 8-Mercaptoquinoline (Thioox'ine) and
Its Derivatives.
Communication 4- Photometric Determination of Small Amounts of
11anganese
tungsten, and rhenium, may, if they have low valences, be
masked by potassium cyanide. The cyanide complex of manganese
is so little stable at pH 10 that it is destroyed by thiooxine.
The masking of iron as [Fe(CN) 61 4- is attained only under
certain conditions: iron must be completely bivalent and the
pH value of the solution must be 9.5 - 10-5 in the masking.
Silver and gold are reduced to metals in alkaline solution
and do not inhibit the determination of 1-amounts of manganese,
nor do iridium and osmium in mg-amounts disturb the determina-
tion. Amounts of about 20 mg platinum cause an intense blue
coloration of the extract. Lead, zinc, cadmium, thallium,
vanadium, and tin disturb the determination. The devised
photometric method of determining manganese is described in
detail in this paper as well as the production of the solution
of the reagent. Using the method described still 1.5 7 man-
ganese in a 5 ml extract may be determined by means of an
SF-4 spectrophotometer with satisfactory accuracy. Using
Card 3/4 a Fulfrich photometer amounts of manganese of 3 7 in

SOV175-14-2-14/27
Analytical Application of 8-Mercaptoquinoline (Thiooxine) and Its
Derivatives.
Communication 4. Photometric Determination of Small Amounts of
Manganese
50 - 100 ml solution may be determined. The results of the
determination of-manganese in the presence of various eluments
are summarized in a table. There are 3 figures, 1 table,
and 15 referencest 7 of which are Soviet.
ASSOCIATION: Institut khimii Akademii nauk Latviyskoy SSR, Ri."a
(Institute of Chemistry of the Academy of Sciences, Latvian
SSR, Riga)
SUBMITTED: June 19, 1957
Card 4/4

5(2)

AUTHORSt
Bankovskiy, Yu. A., Shvarts, Ye. M.,
SOV/75-14-3-10/29

-1-ev-19s, A. F.
TITLEt
Analytical Application
of 8-Mercapto Quinoline

(Thiooxine) and Its Derivatives
(Analiticheskoye primeneniye

8-merkaptokhinolina - tiooksina -
i yego proizvodnykh).

Communication 5. Photometric
Determination of Molybdenum

(Soobshcheniye 5.
Fotometricheskoye opredeleniye molibdena)
PERIoDICALs
Zhurnal
analiticheskoy khimii, 1959, Vol 14, Nr 3,

PP 313-317 (USSR)
ABSTRACTs
Thiooxine reacts both in weakly and strongly acid
solution

with molybdates under formation of compounds
insoluble in

water. Under certain conditions the green MoO
0
H
(C
NS) AH

2
6
2
9

is formed which dissolves in organic solvents with emerald

coloration. In the presence of ascorbic acid a pronounced

adsorption maximum is formed at 420 mp. The molar extinction

coefficient is 8,600. Figure 3 shows that the toluene extract

of the molybdenum thioaxinate obeys Beer's law. An excess of

Fe, Co, Hi, Zn, Cd, Pb, Mn, U, Tl, Ir and Rh does not
Card 1/2
influence the determination. Bi, Ag, Au, Hg and W form

Analytical Application of 8-Mercapto Quinoline
SOV/75-14-3-10/29
(Thiooxine) and Its Derivatives. Communication 5.
Photometric Determination of Molybdenum
voluminous amorphous precipitates which are insoluble in
toluene and xylene ad must therefore be masked like Os, Ru,
Cu, Pt and Pd what is done with thiourea. The determination
of molybdenum according to this method is possible up to a
molybdenum content of 1-5 - 200r. There are 3 figures, 2
tables, and 11 referencest 2 of which are Soviet.
ASSOCIATIONt Institut khimii AN Latviyskoy SSR,Riga
(Institute of
Chemistry of the Academy of Sciences of the Latvian
SSR, Riga)
SUBMITTED: may 19, 1957
Card 2/2

N
N
FHASZ Z 000K LXPWITATIO14 sov/4350
Zovoehchanlye po khlmil, takhmologil 1
primenentyu proiz~odnykh
pirld1^4 I khinolina. Rlgao 1957
XhImlya, tokhnologlya I primenantye
proizvodnykh pirldlna I
khtnolinal materialy moveshchantya
(Chemistry, Technology
and Utilization of Fyrld1ne ~,l Quinollne
DerIvativeal
Materials of the Conference) Riga, lzd-vo
All LAtviys;toy
SSR, 1960. 299 P. Irrata slip Inserted.
1$000 copies
printed.
3ponscring Agencleas kkadamlya nauk
lAtviyokoy SSR. Inatitut
khiall; Vossoyuznoye khAmichaskoya
obahct-astvo.
Zd.j S. B&ZhanOva; Tech. 94.s A. Klyavinya,
F41torial
Boar4i Yu. A. bankovskly, candidate or
Chemistry. E. V.
Vanaga, Candidate of Chemistry (Romp. Ed.),
L. P. Zalukayev,
Doctor or Chemistry. and X. M. Xalnyn-.
FURPOZZ- This book In Intended for organic
chemists and
ch*macal engineers.
COVXRAOZs The collection contains 33
articles on methods
Of synthesizing Or Producing pyrldine,
quinollna, and
their derivatives from natural Boorces. No
per3onjaities
are mootion*d. Figures, tables, &w referenas
accoVany
the articles.
P. mid s. r. xutK%yj,,t,-Aj. (Kookovskly
lostUd-F-Ir ~nt D. 1. P.Indeleyeva
(Fuscow Institute for Che.loal Techn Jgy
I.ent V. 1.
A9A`IQIeYQv SO- RO&Cti0n* Of 3-Hy~;oxy-
1,2,3,4.-
229'
(Chernovitakly go3udarstvennyy universitet
,-rwrnovtsy Stite University)) The
Interaction Of N-aryl-
IrAl-na:4ino Quaternary Salts With Mazo
Compounis 23T
VY, L. 1. IALk&bh na-and Davylove
ff=Ur.Lo-.'..lOntiria Ras.&rc h Institute
r.FU;Xffx1.hd
R
P acts " 0702' Ministry or the Chemical
Industry. USSR)
CYsnO&cOt&I And C7&n%Ofl%OthY1 DWrIv&tIvO5
of Some Nitrogen-
CoOtaIning BeterocyclLo Compounds 243
IT- TIM USZ OF MMATrM OF THE QUINOLM SERIES
IN ANALYTICAL CHZMISM
TO. 3 (XOGiMMAkay seltskokhozyaystvannyy
,u -6~a Agricultural In.t ut-)L The Us- or
8-Itydroxyqulmllne In Cheadcaa Anraysis 253
A-, A._E_jt-_-jfl_
P;PLI *ph~ and V. L
1~- 04 A~ -1~t Or the Academy of Scra-n,;.
Letvjy
";).8-Mftrc&ptoqulnolIne (Thioaxl~) as an
Anajytjc&j$k~y&
Reagent 271
;j~-1PKjff;aj11 I-
.(All-UAI--l.SO1-'1tIfIcSR.9 Or h In3titut.
r - aa nts) Stud on In the yntee3cs of 2,lo-
Fhananthrolloo
283
Bakk* A. K., and M. M. T&n&nayk~ JKlyevskly
gosudaretve.yy
(Klyev State University
imeni T. 0. =avchonko)) StUdY Of COmPlex
Formation
In the Syst**: Metal Ion - RhOdLnIde
(Iodide) - organic
289

BANKOVSKIY, Yu. Ellarikovskis,J.] (Riga); LOBANOVA,
E. (Riga)
Analytic application of 8-mereaptoquinoline
(thiomdme) and its
derivatives. Report XVI* Colorimetric method of
determination of
rhenium with 6-chlor-8 mercaptoquinaline. Vestis
Latv A no.l:
97-lo6 6o. (Ew 9:1.1)
1. Akademiya nauk Latviyskoy SSR# Institut khimii,,
(Quinalinethiol)
(Colorimetry)
(Rhenium)
(Chloroquinolinethial)

GUDHINI3TSE,Z.[Gadrinieo& I ](Riga);
IYEVIN'SA,A.fIevino,A.1(Riga);
VANAG,G.[VanagsOG.MQA); BRITNERE,V. (Riga);
BANKOVSKlYtTu.
(Bankovokis,J.I(Riga)
Sulfonation ofO-diketonea. IX.
Indandione-10-dimlfo-2,2-acid
and its salts. In Russian. Vestis Latv ak
no.3:103-106 160.
(WAI 10--7)
1. Akademiya nauk Latviyokoy SSR, Institut kbimii.
(Ketones) (Sulfonation) (Indandioulfonic acid)

BANKOVSKIr, TujBankovskiv,,T.1(RigA);
LOBANOVA,10.(Riga)
6-chlor-8-mareaptoquinolinat of vanady~. In
Russian. Vestis Ietv
ak no.3tll3-118 160. (EM 10:7)
1. Akademiya wuk Latviyokoy SSR, Institut kbi-ii.
(MLloroqUilkolinethiol) (Vanadium)

IBANKOVSKIY, Yuu..[Bankovskis, J.] (Riga)-
MISUIDVINA, Z. (Riga);
__ --l-MEMIS1, . MIevins, A.) (Rig&5; BUKA, M.
8-mereaptometbylquinoline and its interaction with
metal ions.
Vestis Latv ak no.I:L:103-106 160. (ux 10: 9)
1. Akademi7a nauk Iatviyakoy SSR, Institut kbinii.
(Hetbylmer,captoquinoline) (Ions) (metals)

BANKOVSKIr. Yu,[Bankovskie, J.] (Riga); MiDOTOVA, L.
(Riga); IYEVINISH, A.
J (Riga)
4~ 4) -diquinaldildioulfate and its reaetion with metal
ions. Vestis
Latv ak no.12:69-74 160. (RUI 10: 9)
.1. Akademiya nauk Latviyekoy SSR, Institut kbimii.
(Quinaldil) (Dioulfide group) (Ions)

5.5300
77739
SOV/75-15-1-1/29
AUTHORS: Bankovskiy, Yu. A., Iyevin'sh, A. F., Liyepinya, Z. E.
TITLE: Analytical Application of 8-Mercaptoquinoline
(Thiooxine)
and Its Derivatives. Communication 10. Relative
Stability of Thlooxinates and the Influence of Complex-
ing Agents on the Reaction of Thlooxine With Cations
PERIODICAL: Zhurnal analiticheskoy khimii, 1960, Vol 15, Nr 1,
pp 4-9 (USSR)
ABSTRACT: A relative stability of thlooxinates of different
ele-
ments and the relation between the thiooxinates and
different complexing agents was studied. Parallel
determinations,of the relative stability of thiooxJ-nates
of different elements were made by three different
methods: substitution, rate of thiooxinate formation,
and the limits of thiooxinate extraction. It was found
that the investigated thiooxinates form a following
series, according to their stability:
Card l/ 5

AnalytJcal Application of 8-Mercaptoquino-
line (Thiooxine) and Its Derivatives.
Communication 10. Relative Stability of
Thiooxinates and the Influence of Complex-
ing Agents on the Reaction of Thiooxine
With Cations
77739
SOV/75 15-1-1/29
Re>Au >Ag> Hg>Pd>Pt > RU> Os> Mo>Cu > W >Cd >
In > Zn > Fe> It> V >Co>NI >As> Sb>Sn > B1>Pb>Mn>T1.
This series is only approximate, since the methods used
do not always giVe reproducible results. The correc-
tions may be made after the dissociation constants of the
thiooxinates are determined. Reaction between the t',"lioaxi-
nates and H2S at different pH was studied in order to
show that the stability of thiooxinates depends not only
on the metal-sulfur bond, but also on the strength of
the metal-nitrogen bond. The results are shown in Table
1. Experiments were conducted in order to compare the
stability of oxinates and thiooxinates. It was found
Card 2/5 that in acid and alkaline media, the thiooxinates,
which

77739, SOV/75-15-1-1/29
Table 1.Reaction of H 2S with thLooxinates (a) thiooxi-
nates; (b) product of niaction of thioox-Inate with IS
at different pH; (c) decomposes; (d) forms.slowly; e)
partly decomposes; (*) decom oses to perrhenate; (**)
decomposes to tungstate; (*3) in an alkaline media in
the presence of oxidizing agent, forms vanadate.
(b)
W
Iii pli 3 10
Au
Ag
H
PI
Pt
Ru
os
MO
CII
W
Ag2S
HgS
-
-
-
-
-
-
-
AgtS
HgS
-
-
-
-
-
-
-
N.131?eO,
A92S
ligs
NagWOj
Card 3/5

77739
SOV/75-15-1-1-29

(b)

p
PH 3
p H 10
Cd

In

Zn

Fe

Ir

v
Co.

(c)
NI

As
AS*S3

N23-
As%

As,%

Sb
pb
Sb2S3
Sb2SS
SI),S,-

Sn
PbS
PbS
Pbs
BI
BIS,
BI,%

Mn
(c)
(e)

TI
TIS
TIS
TIRS
Ta
Nb

(c)

Card 4/5

Analytical Application of 8-Mercaptoqu .ino-
line (Thiooxine) and Its Derivatives.
Communication 10. Relative Stability of -
Thiooxinates and the Influence of Complex-
ing Agents on the Reaction of Thiooxine
With Cations
77739
SOV/75-15-1-1/29
form hydrolyzable sulfides, are more stable than oxi-
nates of'the same elements with the exception of
vanadium (i-n acid solution) and Nb and Ta (in alkaline
solution). Studying the effect of different substances
on the reaction between different elements and thio-
oxine, the authors came to the conclusion that highly
concentrated hydrochloric acid acts as a masking agent
for the following elemements: Fe, Mo, Hg, Ag, Bi, Sn,
and Sb; thiourea Yor: qu, Ag, Pt, Hg, Ru, and Os;
.3+ n ;
sodium.fluoride for Fe and SA4 potassium cyanide
(in alkaline solution) fort Fe (II), Ag, Au, Pt, Ru, Os,
Ir, Pd, Ni, and Co; Potassium thiocyanide is a good
masking agent for Fe (III) and for moderate amounts of
Zn and Cd. There are 2 tables; and 13 references, 4
German, 9 Soviet.
Ass6cIATION: Institute of Chemistry, Academy of Sciences,
Latvian SSR
Riga (Institut khimii Akademii nauk Latviyskoy SSR, Riga~
,SUBMITTED: March 18, 1958 .Card 5;~

_RMOV$Egs.~A.; IUMISH., A.F. (Ievina., A.]; LUKSHA,
E.A., [Luks"a, Ej;
BDCHUN9-,. P. Ya.
Analytical app3leation of 8-quinolinethiol
(thioquinolinol) and its
derivatives. Report 17: 8.8t Diquinolyldisulfide,, a new
selective
reagent for the photometric determinatift of sma3-1 i
ounts of co e
am _pp r.
Zhur.anal.khim. 16 no.2,150-157 Mr-Ap 161. (MIRA 14:5)
1. Institute of Cheinistry, Academy of Sciences Latvian
S. S. R., Riga.
(Copper-Ansaysis)
(Quinolinet7niol)

.01
S/079/60/030/05/44/074
BO05[BO16
AUTHORS-. Bankovskiy, Yu. A., ?edotova, L. A., Zaruma, D. E.
TITLE: Synthesis of 5-Bromo Quinolinel
PERIODICAL: Zhurnal obshchey khimii, 1960, Vol. 30, No. 5, PP-
1614-1616
TEXT: The production of 5-bromo quinoline from m-bromo aniline
by means
of the Skraup synthesis requires a long distillation with
water vapor.
Afterwards, the 5-bromo quinoline must be extracted with ether
from large
quantities of the distillate. Besides, an about equal quantity
of isomeric_
7-bromo quinoline is formed the complete separation of which
is very dif-
ficult. The yield in pure 5-bromo quinoline in this synthesis
is never
more than 10-20% (calculated for m-bromo aniline). Also the
synthesis of
5-bromo quinoline by diazotation of 5-aminoquinoline and
substitution of
bromine for the diazo group (Ref. 2) show several shortcomings
which are
discussed in the present paper. The authors devised a method of
synthesizing 5-bromo quinoline on the basis of
8-aminoquinoline. According
to N. N. Vjrozhtsov and I. M. Kogan (Ref. 6), 8-aminoquinoline
can also
be obtained easily by amination of 8-hydroxyquinoline with
ammonia in the
Card I

Synthesis of 5-Bromo Quinoline S/079~60/030/05/44/074
B005/ ~016
presence of ammonium bisulfite. 0. 1. MikhAylov (Ref. 7)
improved this
methodq and was able to raise the yield of 8-aminoquinoline to
81-83%.
The authors used this method for the preparation of
8-aminoquinoline. The
synthesis of 5-bromo quinoline devised is accomplished as
follows:
8-aminoquinoline is acetylated in benzenio solution with
acetic anhydride.
8-Acetylaminoquinoline which results in good yield is not
isolated but
brominated in the resultant reaction mixture at 0-20C. In this
way,
5-bromo-8-acetylaminoquinoline is obtained in yields up to
98.5%. By
hydrolysis with hydrochloric acid, the acetyl group is split
off. The
resultant 5-bromomB-aminoquinoline is liazotized in sulfuric
acid solution
at -20. By reduction with copper powder and alcohol, the diazo
group is
replaced by hydrogen, and 5-bromoquinoline results as end
product in a
yield of 40_51%. In an experimental part, the total course of
synthesis
is described in detail. The scheme of the synthesis is given
as well.
There are 11 references, 4 of which are Soviet.
ASSOCILTION: Institut khimii Akademli nauk Latviyskoy SSR
(Institute of
Chemistry of the Academy of Sciences, Latviyakaya SSR)
Card 2/3

I
Synthesis of 5-.Bromo Quinoline S/079V60/030/055/44/074 ,
B005/ .016
SUBMITTED: May 22, 1959
Card 3/3

BANKOVSKIY, Yu.A. [Cirule, J.1; TSIRULE, Ya.A.
[Ievins. A.]; IMIN'sif, A.F.
Use of A-ouinolinethiol (thioUine) and its derivatives
in analysis.
Report No.18: Gallium, indium, and thallium
thio*O'xinates. Photo-
metric determination of indium with thioBxine.
Zbur.anal.Wm.
16 no-5:562-572 s-0 61. (MIRA 14:9)
1. Institute of Chemistry, Academy of Sciences,
Latvian S.S.R.,
Riga.
(Quinolinethiol) (Gallium--knalysis) (Indium--knalysis)

BM KOVSKIY, Yu.A.; MULOVINA, Z.V.; IYEVINISH, A.F.
[Ievins, A.),
--TMk~ M. R.
5-Fluoro-8-wreaptoqu-inoline and its salts.
Matod.poluch.khim.
reak.i prepar. no.4/5M-78 162. (MIRA 17:4)
1'. Institut khimii AN Latviyskoy SSR.

����������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������������� BANKOVSKIY,-Yu.A.:_W,ZH$RAUFS,-G.;Ri---[Me-~ar4ups,,
G.]; IYEVINISH.. A.F. -
[levins, A.]
Analytical #pplication bf 8--uwwcaptoquinoline
(thiooxine)
and its derivativeb'_'R~port--No-20s Thioaxinates
of platinum
metals. Zhur.anai,'"~'V no.93721-733 S !62. (MIRA
l6sl)
1, Inetitut khijdi U Litviyakoy SSR, Riga,
(Quinolinothiol) (Platinum metals)

j-'L-15112-6-63, J~~G/ASD JD
ACCESSION NR: M003755 S/0137/63/000/005/1-011/011
SOURCE: RZh. Metallurgiya, Abs. 5K63
AUTHORi Mezharaups, 0, P.* Iyevin'sh, A. F.9 BankovakiyoTuo As
TITLE. The use of thioxino for the qualitative determination of plat
and
pallad in the presence of other platinem metal8'
CITED SOURCE: Izv. AN LatvSSR, Ser. khim.9 no. 1s 1969# 29-33
TOPIC TAGSt thioxine., platinum. palladium, iridium, osmium,
ruthenium, qualita-
tive analysis
TRANSLAII014: A method of qualitative determination of Pt and Fd In
the presence
of other platinum metals was developed. The method is based on the
co-precipi.-
tation of the thiooxinates of Pt arA Pd vith
8.81-diquinoly1disulfide. Ft can
be determ-bied in the presence of 120 times the amount of Rh and
)5_50 times the
amount of Ir, Os, and Ru. Pd is determined in the presence of
relatively large
amounts of F-h and Ir and moderate amounts of Os, Ru, and Pt.
Author's summary.
DATE ACQ: 21 Jun 63 SUB CODE., CH, EL ENCLi 00
Card 1/1

BANKOVSKIY, Yu.A.; WGULOVINA, Z.V,; TSIRUIX, Ya.A.;
IY.FVINISH, A.F.
F;F I --A-.9.
L----I
8-Chloro-8-mereaptoqainoline and its salts.
Metod.poluch.khim.reak.i
prepar. h0.4/5:79-85 162. (MIRA 17:4)
1. Institut khimii AN Latviyskoy SSR.

MVIN'Sliq J
BANKOVSKIX u ~.F,, Llevins, A.); BUKA, M.R.;,.
LUKSHA, &A. [Lukoa,, B.A.]
Innsr-complex compounds of manganese with the
coordination
number of 8. Zhureneorg.khim. 8 no.I&UG-3-18 J&
163. -
(MIRA 16;5)
1. Institut, khiTnii AN Latviyskoy SSR.
(manganese compounds) (Coordination compounds)

BANKOVSKIY, Yu.A.; CFMA, L.M.; IYEVIN'SH, A.F.
(IevinB, A.]
Analytical application of 8-mercaptoquinoline
(thioxine) and
its derivatives. Report No.25; Solubility in water
and the
extraction range of 8-mereaptoquinoline in the
system water -
organic solvents. Zhur. anal. khim. 18 no.5:555-561
YJY'63.
(MIRA 17:2)
1. Institute of Chemistry, Academy of Sciences,
Latvian S.S.R.,
Riga.

BANI~OVSKjy. yu-.:A.; CIMRA, L.M.; IYEVINIS11, A.F.
[Ievins, A.]
8-Mercaptoquinoline (thioxine) and Its derivatives*
Report No.28:
Absorption spectra and the state of
8-mereaptoquinoline in solutions.
Zhur.anal.khim. 18 no.6:668-686 Je 163. (MA 16:9)
1. Institut, khimii Akademii nauk Latviyakoy SSR, Riga.
(Quinolinethiol-Absorption spectra)

ACCESSION NR: AP4009722 S/0075/64/019/001/0048/0053
AUTHOR: Bankovskiy, Yu. A-; Chera, L. M.; 1yevin'sh, A. F.
TITLE: Study of 8-mercaptoquinoline(thi.oxine) and its
derivativeso
Report No. 29. Application of thioxine for extractive
purification
of reagents by removing heavy metal admixtures
SOURCE: Zhurnal analiticheskoy khimii, v. 19, no. 1, 1964, 48-53
TOPIC TAGS: 8-mercaptoquinoline, thiooxine, purification, heavy
metal trace removal, thioxine oxidation, purification pH,
coprecipi-
"Cation, 8,81-diquinolyldisulfide
ABSTRACT: Thioxine, when used as the sodium salt, forms stable,
mrater-insoluble, complex salts with heavy metal ions which can
then
be removed by organic extractants. By varying the acidity
selective
extraction can be achieved, and the thioxine excess,is removed
to-
gether with the thiooxinates; Thioxine is practically and
quantita-
tively extracted between pH 2-8.4; and at a pH 5.2 of a 10:1
chloro-
1:ord

ACCESSION NR: Ap4oO9722
form-water mixture, 1/1000 of the initial thioxine will remain in
the water layer after 2 extractions, 1/30,000 after 3. By increas-
ing thioxine excess, the pH interval may be significantly broadened.
Conditions for removing each or the various metals are listed.
Thioxine may be used for all heavy metals which do,not form stable
sulfides in aqueous solutions, also for uranyl salts in a weakly
acidic medium, and for purifying many organic substances soluble in
water and insoluble in the usual. organic solvents. The sodium
intro-
duced with thio ne is removed by subsequent crystallization. Purl-
fication to 10-61- 10-9% is possible. The procedure is described.
Instead of extraction, coprecipitation and subsequent filtration may
be used by oxidizing thioxine in alkaline solution to
8,81-diquinol-~
yldisulfide. Origo art. has: 2 figures.
ASSOCIATION: Institut khimii M:adem:Li nauk Latviyokoy SSR, Riga
(Institute of Chemistry of the Academy of Soienoes of the Latvian
SSR)
21
I Card

ACC NRs AP6033456 SOURCE CODE1 UR/0413/66/000/018/0039/0039
114VENTOR: Bankovskiyo Yus As; Gertner, Me Do'; Yaneon, E, Yu, I
ORGt none
TITLE: Preparation of a-dithionaplathoates of
tetramethylanmonium,
tetraethylammonium, or tatraphenyliarsonium, Class 12, No. 185907
(announced by Latvian State University im. Stuchka (Latviyrkiy
gosudar-1
istvennyy universitet)] I
SOURCE: Izobret prom obraz tov zn, no. 18, 1966, 39
TOPIC TAGS: tetramethylammonium dithionaphthoateg
tatraetitylammonium
dithionaphthoate, tetraphenylammonium dithionaphthoate, sodium
dithio
naphthoate/ /-%P~ -
ABSTRACT: In the proposed method, a-dithionaphthoates of
tetramethyl-
ammonium, tetraethylammonium, or te:traphenylarsonium are
obtained by
treating sodium a-dithionaphthoate with the appropriate onium
halides,
e.go, with tetrarethylammonium iodide. [W.A, 501
SUB CODE: 07/ SUBM DATE: O8Oct65
4

FAKULA, Roman; PI-EMOWSKA, Mroslaira; BANKOWSKA, Edmunda;
WALCZAK, WIodz:L-derz
A characteristic of DITA mediated transformation systems
of two
streptococcal strains. Ac-ba microbiol. polon. 21
no-3:205-222
162.
1. From the Department of Bacteriology, State Institute
of Hygiene,
Warsaw.
(DNA, BACTERIAL) (STREPTOCOCCUS)

Poi.M/Cultivated Plants Potatoes, Vegetables, Melons,
Abs Jour : Rcf Zhur - Biol.) No 3, 1958, 10778
Author : Malinowski, E., Bankowskn, H., Oskierka, 1.
Inst
Title Pxperiments with Potato Grafting. III. Grafting
Solanum Rybinii on Tomato.
Orig Pub Acta, agrobot., 1956 (1957), 5, 33-42
M-3
Abstract An attempt was made through grafting to induce
blosso-
ming in varieties vhicb. ordinarily blossom only
slightly
or not at all. The cultivated tomato and the wild vari-
ant'Lycopersicon esculentum (L.C.) were grafted in the
following ways: 1) on the tomato rootstock without any
auxiliary shoots, 2) with one or two young auxiliary
shoots, 3) with several blossoming auxiliary shoots.
The greatest number of blossoms appeared both on the to-
mato and on L.e. in the first variant. With self-polli-
nation one berry appeoxed only in the first variant.
Card 1/2 V

POLAND/Cultivated Plants - Potatoes, Vegetables,
Melons. M-3
Abs Jour Ref Zhur - Biol.) No 3) 1958, 10778
In order to study the forimtion of air tubers and sto-
lons, tuber shoots of potato were grafted onto the main
stem of a Golden J-.-.bilee tomato from vhich all
auxiliary
shoots had been removed. The tomato stem was cut off
above the second loaf, and the potato shoot was
attached
there) using a forked graft. Part of the plants
received
supplementary Ps fOrtili2atiOn (variant No 4)) and part
were grown under conditions of a ten-bour day (variant
No 5). The plants in variant No 5 hardly formed any
blos-
soms, but air tubers did form on their stems. The
great-
est amount of blossoming occurred in the No 4 variant,
the stalks seeming to form now, independent plants.,
upon
whose base there appeared a large number of air
stolons.
The new shoots had large, dark-colored leaves, and
tubers
appeared on some of the stolons.
Card 2/2

~A,
POr"/Cultivatcd Plauts Potatoes, Vegetables, Melons. M-3
Abs Jour : Ref Zhur - Biol., No 3) 1958, 10779
Author : Malinowski E., BankowsxL2._Dskicrka 1.
Inst
Title Experiments with Potato Grafting. IV. Grafting
Solanum. Commersonii on Tomato.
Orig Pub Acta. agrobot, 1956, (1957), 5, 43-54
Abstract Solanum, commersonii (S.C.) blossoms profusely
but has no
fruit; when grafted onto tomato, it gives normal fruit
and seed even after self-pollination. The largest number
of racemes and blossoms came from variant No 1 (cf. Part
III); the plants of the third variant blossomed much
worse than the control. The largest number of air tubers
and stolons formed on the first variant also. Seedlings
were grown from seed of fruit grown in the first variant,
and then these seedlings were grafted oato Lycopersicum
esculentum. Stolons formed on the graft seedlings much
Card 1/2

POIAM/Cultivated Plants - Pota,.ocs, Vegetables,
Melons. M-3
lqj,IF
-Aftiour Rcf Zhur - Biol4,, No 3, 10779
earlier (June) than on grafts from tuber sprouts.
(September). S.C. forms fewer air stolons when grafted
on-
to tomato than does S.Rybinii. In the beginning the
sto-
lons appear at the place of &vafting and then on the
new-
ed shoots where they accumulate reserves of nutriti-
ly form
ve substances in special tuberous growths. These
growths
my be analyzed in the same way as organs of vegetative
reproduction. The S.C. air tubers are different from S.
Rybinii and S. tuberosum in that they are formed from a
thickened part of the new-grown shoot and leaf base.
Similar stolon grovths and fascicles are also formed on
the racemes at the end of the vegetation period.
Card 2/2

POLAND/Cultivated Plants - Potatoes, Vegetables, Melons.
Abs Jour : Ref Zhur - Biol.) No 3, 1958.- 10780
M-3
Author : Malinovski, E., Bankowska H., Oskierka, 1.
Inst. : -
Title : Experiments with Potato Grafting. V. Solanum
polyadenium
Air Stolons.
Orig Pub : Acta. agrobot, 1956 (1957),, 5) 55-61
Abstract : Solanum polyadenlilm was grafted onto Golden
Jubilee toma-
to with the aim of getting fruit from the self-pollin -
ting S. polyadenium. blossoms. When g--afted with two
young shoots the graft's flowering increased markedly, and
fruit was produced by the self-pollination. When two old
shoots were left on the rootstocks, no fruit grew on the
graft; an average of 40 blossoms formed on each plant
(126 in the first case). The seedlings from the self-pol-
lination were grafted onto Lycopersicon esculentum. The
variants from the graftings were as before (see parts 3
Card 1/3

POLAND/Cultivated Plants - Potatoes, Vegetables,
Melons. M-3
Abs Jour Ref Zhur - Biol,.,, No 3, 1958, 1078$
and 4). The first variant flowered best, while the
third variant flowered worst. Self-po" ination
produced
fruits only in the first variant; this one also produ-
ced the largest aTrount, of stolons. The total length
of
all air stolons in the first variant was 447-15 cm-,
in
the second -- 261-7 cm., and in the third -- 100-5 cm.
On the grafts from seedlings the stolons emerged
approxi-
mately two months earlier than on grafts from potato
sprouts. There were fewer stolon fascicles on S.
polyade-
nium,, and tubers formed on them only when the stolons
took root in the ground. Stolons forming in spots
where
the components grew together were usually horizontal.
The stolon lateral shoots grow out at about a 900
angle.
Above the place -where they grow together the stolons
bend
over and down, frequently indicating norml leaf
develop-
ment. The author views these stolons as occupying an
in-
termediate position between genuine air stolons and
Card 2/3

- POIAND/Cultivated Plants - Potatoes, Vegetables,
Melons. M-3
Abe Jour : Ref Zhur - Biol.) No 3P 1958P 10780
lateral shoots, The atolona become progressively
ahorter in proportion to their distunce from the place
of grurt, No vtAAkn furmtIon vas rrot(Kl (.,n
Card 3/3

POLAND / General Biology. Plant Genetics.
Abs Jour: Ref Zhur-Biol., No 23, 1958, 103364.
Author Bankowska, Helena.
9---r n
Inst ot g ve-
Title Research on Variable Characteristics of Phaseolus
vulgaris L.
Orig Pub: Acta agrobot. 1956 (1957), 6, 71-137.
Abstract: The character of the inheritance of color distri-
bution on the seed capsule of the Icidney bean was
investigated. For the purpose of cyclic crossings
two white-seeded forms of the kidney bean were used
--Kaiser Wilhelm and Vitry--and one form which had
seeds of a pale flesh color with a slight sandy-
colored tessellation near the hilum. In direct and
reverse crossings of the kidney bean with the flesh-
colored seeds with the Vitry and Kaiser Wilhelm
Card 1/3

POLAND / General Biology. Plant Genetics. B
Abs Jour: Ref Zhur-Biol., No 23, 1958, 103364.
Abstract: sorts plants were obtained in the Fl
generation with
very different types of tessellation on the seeds
of various beans. In the F2 generation from the
crossing of the kidney bean having the flesh-colored
seeds with the Vitry sort there were 100 plants with
tessellated seeds, 89 with a solid black-violet
coloration and 62 with white seeds, whereas in the
F2 generation after crossing with the Kaiser Wil-
helm sort there were observed four solid colors and
numerous mosaics. The mosaic was observed only on
a flesh-colored or sandy background, but never on
white. The results of the dissociation in the F2
and subsequent generations are explained by the
author by the presence of an R factor in the !cidney
beans with flesh-colored seeds, the presence of
which accounts for the formation of the background,
Card 2/3
24

POLAND / General Biology. Plant Genetiest
Abs Jour: Ref Zhur-Biol., No 23, 1958, 103364.
Abstract: and of I and B genes which are responsible
for the
flesh and sandy color of this background, as well
as by -'U-he homozygotic nature of the white-seeded
Vitry bean with respect to the R factor, whIch is
epistatic to the other color factors. By comparing
the extremely complex dissociation observed in the
hybrids with the fact of the indubitable occurrence
of somatic mutations in them the author concludes,
in addition, that s specific hereditary factor is
present in them which is responsible for the muta-
tion of the seed capsule color genes. -- A. I.
Kuptsov.
Card 3/3

XALINOWSKI,p E.; BANKWKA, He; BIURKOWSKA, Me
Heterosis in maize (Zea mays). I. Correlation
phenomena between
vigorous growth and time of flowering in FZ, II.
Fixing vigorous
growth. Bul Ac Pol biol 8 no.1:23-33 160. (EEAI 10:1)
1. Institute of Genetics (Skierniewice), Polish
Academy of Sciences.
Presented by E.Malinowski.
(CORN (MAIZE)) (EETEROSIS) (GROWTH (PLANTS))

BANNOWSKA, Helena
On heterosis in general. Postepy nauk roln 10
no.6:25-34
N-D'63.

BUEDWSKA, Helena
OUervations on haterasin in Zea nays L. Acta agrobot
15:5-12
1640
1. Departzent of Geasties, Central Coilege of Agriculture,
Warsaw.

BANKOWMAP Helena
Observations on hoterosin in Zea Maya L. Pt.2. Acts.
agrobot
16t175-179 164,
1. Department of Genetics of the Central College of
Agriculture,
Warsaw. Submitted February 25, 1964.

BANKOWSKA., R.
Studies on the family Syrphidae (Diptera)
llelenomyia gen. nov.
Bul Ac Pol biol 10 no.8:33-1-314 162.
1. Institute of Zoology, Polish Academy of Sciences,
W&rsaw.
Presented by T. Jaczewski.

BANKOWSKA, Regina
Studies on the Palaearctic species of the genus
Sphaerophoria.
St.Farg. et Serv. (Diptera, Syrphidae). Annales
zool 22 no.15i
285-353 164.

4-.
Vcklofide. and. 11 RP
V;3-1
0 L o '-!i~h ~nfmmrN,~. -T!,E m-'01 I C_"iml' "f
It 11-0 t 111 1.1 01~
condent!r ~,.cn pLicrd 27 g- pz-vvd. N:,CN' vmd R5 ml
n z(,. 'L%tk ~nxmfd in 11.0 bath autil U:e NuCN di,
I-C,JI,C1I:C In I(F) g. EtOH a4d,4 drc- t,-0
tht rint. warmcd le .5 h-~ ~i-z,
"20 flitr~'! -:7, -,
mltl' t, ! " - wt,"I
W1 tT:I. 1-KOT" th- -and th.-' ru-n-tindc" dllmd~
r"l 2 17~-,
2W ml. 11,0' ~-d K, !-11 Et!:)Il in a f"F.'k
;vm pratri to Imilbig 3-60 hrt,, the FtO' 11 %was a6t-A, cO, Wit
rlxml Tvlth C, anti pptd. yvith 2Dc;Q FrSO.,
fafflni'50~u g.L;tr_~Std. frm1T'O- rn, -To ISO r,
IT 83 1. (ITINMIT-th-IfTO,
Ir. dCstn, fuk w4 addtd slow
and the mixt , distd.-,frls the bath,
thm Ila a. tio=d, 11CL
-2 1
I hr.* - Tbo temp. the bath ke t
of 110 d i th
I ht. st 2AG-W' -andAbe3i -anothtr br.- Rt M-70
2 Tj~
brown,- Vtass~r.-rr_Ldut-rvas -_:1v:d -g!th 2M irl.+-~t IL-Oi
Lhe w-,iip-mMon beated'ta bollin the m- Mue (SD S.) ffitemd
anzi xtashed u4th 100 ral. ~hzk Tw, the filtrate dmblariird
act,
fia*ied C. p"'kaliva wlt~ "O'l 1, N'
1"wi

r ctlow -~,d the SLJu. fAtd. zcvc.-J 1j:zc-i
%V it h I vmiuns of C,11.. The vxm 8vt:re "iddc'! ro th~
vellmy bil the mmbiaed soln. drictl with KOH, thel~ -t f9,".
MA emsta. ~ivii~tg 10-S.6
,111), m. M6-20'~ To 15 g. III diz-solved in 20 mL EtOll
7.7 g~cancd.'HCI wa3 idded. the ~u'&u, lt~krcd sLveral min.
L-,U_W~ 4calo'l-cd Tti:li C, tht rtsulting !11-14c1 fil
;Dtd, M,911 t1m: Saln. with b.'CO. Yielding .),n=
tered & ljptd, 1:',j
IC-,)% HCl salt. rurpalg. dram anl*~d. EtOH~ m- 253-5' (de-
collrqln.), &a). In Et0*4 Z:m. 11JO. sknErly, III.H";Oa,
m. 132' va-, LA-aintc! by mi-ting 4.3 S. In in
2 M1, NxO and'2121 g. corc~d. HN(h in 4.u1. EtOH~
~G-ANVO.Ilv

~.p
'Itio, ol' J)", 0"
Polacz Zofia ~'ankot:slca: "~',Ilol M
o1
1,1,3---~ric*,,Ic)r:,-)ac~~-'-~o!-,c," 'loemill-'i
C~e:li, YJ
r of r --.m ic ~-.2.Adstlrv a rs... . 1~0 11
ron

t3bg=ati~ vi -li~-

Distrt 4E2p(jl&jd
and chloroacetens in the pisence
i :101dratme.chloride. 1. So= cblwo dsdv&im of
Z. Safikowska
I- ~3;=:;;FM7"Wz-A
ac". $o.# gWvvpM.,I I- AJ
IMXin -1
prvu. by actowe a of Rt
L'tone
1110twetyl bromide
7 T, from e:
A AX--
=1 by freezing out at -80*.
In Partially substituted by Cl by WmMm with j
aq. HCI. On dista., U undirwtat pWW dismutation and
v on - dichlora. dibromo, and chlorobromo
r-MeZa=,62. chlorinatim of BrCHtCOCH& (M)
U mok Cl to I mok ketme) with dry HCI save I num
with other. derivs. The ratio UA in the products was estd.
at OMS:l for Mand 0.145:1 for C3CHjCOMe. 1,1-
Dichloroacetone ba.,1174-18W, %V 1.4472, and 1,8-
dichloroacetone ba 81-3* *V 1.4711. U. Enollution
of chlorowbromo- and lj~~acetons in the presence
of bydmzen Chlevi4e. IM. 473-7.--Quant. ratlos of r
XCICHCOMe to XCH9COCHjCJ derivs. ob
talued, bY
~-chlorinafion of XCH&COMe with dry HCI (X - Cl Br)
(1, 11) were: 1-.0.14-1;0.19 for 1, 1:028 for U, and simikuly
1:3.8 for "CHCOMe (10). 71ity were issumed to be
equal to the ratios of the corresponding enob exisft be-
fore chlorbiatiom. Amts. of JCI liberated 3 miu. after
titration of hato awane corapda. with N&vSAh in neutral
ip~ and acid (a) Was., were In the followlag order
x < 1.1-CIBr(N) < I(a) < 1.1-011r(a) < Igo). . InduL.-
tive effects in those mob. were
7.

t
Distr: 4E3d
and I- -hmmLacej a. fia
q1L 7
N
1. .
Politechnika Warsaw). Roaniki Chem. 33,
MOVOW-46(14599) tbng~lff~summary).-Ethyl a-chloro-a- i
bromoacetylacetate (222 -9.), b" 112% x1t-3 1.4724, du-s
1.5322, was heated U, hrs- at 105* with 1400 g. 36% HIS04.
The oily layer was dried and distd. many times in vacsto
to give 1-chloro-l-bromoacetone (1), Lost 47.5'. 1.4858,
1.700.yiddl7.6%. HBr soln. (46%,29.9 S.) was added-
dropwise to 22.5 S. diazochloioacetone in 50 ml. Et&O at 0
,the EttO byer ncutriillwd with MgO, and dried with
MgSO.. The resulting 1-chloro-3-bromoacetone (U), m.
M-80. 1.5072, -. 37.4%. was crystd. by successive evapa.
ofRt,Oat-500. II,when distd.,disproportionatedp.
aly
to IUkhloco- and 1,3-dibromoacetone. Both in acka
in c tral medium Cl- ;ons promoted the exchange of Dr
fornCluin U but not In 1. In presence of dry HCI no replace-
ment ol Br by Cl was obqerved In bromoacetone, 1, at
A. Krqg
C

c BANKOWSKA,-Z--t_
Influence of the halopm on the eisolization direction of
chlwo-
bromo-and 191-dichloroacetone in the presence of hydrogen
chloride. II.
Bul Ae Pol chin 7 no.7,.473-478 159. (EW 10:4)
(Chloropropanone) (Bromqoropanone) (Hydrochloric acid)
(Isomerization) (Halogens) (Dichlorpropanone)
(Trichloropropanone) (Bormochloropropanone)

BANKOWSKA,.-Z
Effect of halogen on the direction of enolization of
chloro- and
bromoacetone in aoid medium. Rocz chenii 33
no.6:1319-1332 159.
(EM 9:9)
1. Ratedra Cbemii Organicznej Politechniki, Warszawa.
(Halogens) (Chloropropanone)
(Bromopropanone) (Isomerization)

BAN
Enolization direction of brono. and chloroacetone in
the presence of
hydrogen chloride. I. Some chloroderivatives of
bormoacetone. Bul
Ac Pol chim, 7 no.7;469-472 159, (EEAI 10:4)
1. Department of Organic Chemistry, Technical
University, Warsaw.
Presented by T.Urbanski.
(Bromopropanone) (Chlortne) (Chloropropanone)
(Isomerization (Hydrochloric acid)

BANKOWSKA, Zofia, dr.,akiurkt
Moddrn aspects on tautomerism of Picabonyl
compounds. Wiad
Chem 14 no.6:376-399 Je 160.
1. Politechnika, Warszawa.

BANKOWSKA,.Z.
Enolization of ethyl (k- and .7- chloroacetoacetates.
-Bu.1 chim
.~r
PAN 16 no...8:401-405 ~ 162~
1. Department of Organic Chemistry, Technical University,,
Warsaw
and Institute of 6rganio Synthesis, Poliih Academy of
Sciences,
W~rs~w. Presented by T. Urbazwki.

AUTHORs Bahkowska, Zofia
-------------
TITLBx Enolization of a-ehloroacetoaceiia eater
PERIODlekLi Referativnyy zhurnal. Xhimiyap no- 4, 1963, 203-204,
abstract
4Zh5 (Rocan. chemet v. 36, nos* 7-8. 1962y 1159-1171 LP01-y-
summaries in Russ. and Eng.])
TEXTi Freshly distilled a-abloroacetoacetic ester (I) containing 30 -
36~
enol form reaches equilibrium in a few days with a 14-7~ enol
qontent. in
polar solvents equilibrium is achieved very rapidly, with an enol
content in
CH3OR, C2H50H and ether of 10.2,18.6 and 37*4A, respectively. In
nonpolar
aolvt-ntB I forms an equilibrium mixt-are with an enol content in OCI
0 H
4' 6 6
and 07U16 of 60, 32-5 and 40-4-50t, respectively, only when pyridine
is added,
which is explained by a -reduction In the basicity of I as a result
of the
induction effect of the CI mtom. Anomalously, the low enol content
(5-8%)
CH3C CCOOC 2H51'
A
Card 1/2 L 0 C1

S/681/63/006/004/012/051
Enolization of a-chloroacetbace-tic eater BW/Bia6
in I precipitated from its Na derivative is explained by the
formation of a
mesomeric anion (A). The UV and IR spectra of It as well as the UV
spectrum
of the methyl ester of I (II), show that the enol in I exists
exclusively
in the cis form. The enol-form content in I was determined by
bromometric
'Gitration. To 0.34 moles I is added CH A ether solution (from 70 g
nitroao-
-----.-mathyltirea)-,F-then--27-ml- CH -OH; -af ~er-3- days
-the-soluti-orf was-
0 3 0
c oled to -50 Cs giving II, G 7HII C103, b.p. 120-123 C/18 MM 11g,
M.P.
35-5-38o C, n40 D 1-4863. LAbstraeter's notet Complete translation.]

BANIKOWSKI, Czeslaw
QiAlItitative
Vol. 48 No. 9 There In
in in P",pperzilifitI Sn"i JCIJ c9ntaintd
Pay 10, 1954 e-s'---4-Wm-Avm_ kAd. AlQ(I pipaill" ,I
a 110. If. Van I
11hurmaceuticala, Comm-Aics, and Ferfurn --------- MCI
04
COZ,
h1c-1lbt Of the len%'" Of A[- PIPPerda was I S-3.3 Off ill t C
Iftilled 53-2~7 7-11t- baxis; L oil
ri"k. of lei 0 01(41cntll;~ I IV"
Hf). alld 41mmlu COUtellt lllcrra~
".q
'"P. falls with %ifuul-
cm'~v Of Illeuthol i'lu-111 11m, w
1, 10
'0. i"ll,liell

OLENOWSKA-BARANSKA, Krystyna; BANKOWSKI, Czeslaw.
Opium produced at the Pharmacognosic Station o-:t the
AcadaW of
Medicine in Wroclaw. Farm.polska 11 no.1:10-11 Jan 55.
1. Z Zakladow Farmakognozji i Botaniki Farmaceutycznej
A.M. w
Wroclswiu.
(OPIUM, preparation of)

BAIEDWSKI, Czeslaw, Ygr.
Comparison of medicinal properties of
Katricaris, chamomills,
with properties of Hatricarls. suaveoleas.
Parm.pols1ca 11
no.2:30-31 Feb. 155.
(PLAITS, Hatricaria. cbamomills. & N. suaveolons,
properties)
comparison of medicinal

L,,Rzdix ru--dds bydroUpftthl, raw mtekW tof titunna.
Z. OL-2ew-ski and C. M.*awAki (Zakfad Farm. Stmvmnel
A.M., 12, 121-7(10M)
(English summary).-SDrrel (R hydrok~dlhvm) was
...found to contain catechol amd pyl%l-Z-z4lDl tannim, reducing'
sugars (3.02%), and u=rtdumg suyars (9.98%). 71c'
alt. SOInS. Me. V0IO)V,7feM fluorentnce with Wtmvblet
light, r, xtu. by mrans of the Koch app. Y)tldtd at 60'
13.4~,,,, at 60~100* 19.055,10, and at 100-217.83% tannin.

BANKOWSKI C
SCIENCE
PERIODICAL: WIADOMOSCI BOTANICZNE, Vol. 1, no. 3,
1957
BANKOWSKI, C. New method of conducting study groups
in botany. p. 127
Monthly List of East European Accessions (EEAI) W
Vol. 8, No. 4
April 1959, Unclass

if
POLAND/Cultivated Plants. Medicinal, Oleaginous, III
wid Poisonous Plants.
Abs Jour Ref Zhur=Bioli, No 15, 1950, 63399
!-.utho:, Ban',oviski Czeslaw
Inst :4 Sciences.
Title The Content of Ether Oils ia Certain
Bazalik (Ocimum, L,) Species G:?own at
the Garden of I'ledicinal Plants o--;^ the
Acadew, of Yiedical Sciences in Wroslaw.
a
Orig Pub : Farmac. Dolska, 1957, 13, ITo 6, 145-14-C
I-Ibstract :The facts abou-'U- the histo-1- o-' the cultiva-
tion of bazalik sinee ancient times a,-.,,e
poifited out. Since 1952, the following plants
iiere gpown at tho garden j-- '.medicinal plants
7
-- the Acadenr~ of Medical Sciences ii-i
o
lar: 0. basiliciim L., 0. canwii Sims., 00
Card 1/2

POL'J':,D/Cultivated Plants. Eedicinal, E~Ujlior
Olear,*inous, M
'lm, Poisonous 1.1wits.
Abs Jou-2 Re_-P Zhur-Biol. , No 159 10/5531 60399
sanc-ti-li- L., 0. gratissimun L. All s-necies
acclimatized lr!ell to Wroslaw conditions,
0. gratissimum wne its variants, tha ether
oil o_~-' iihich contains eurenol, are worthy
of special attention. The racemes contain
the largest quantities ol' wromatic oils,
next in content o--:' aromatic oils are 'Ohe lea-
ves , and finally the seed,,-, in iihich aromatic
oils are contained in insignificantl,7 si-mall
quantities. It vas observed t-!-iat a dried
plant uhich had lain in an ordinary paper bag
since 1952, still contained a rather high
f
)ercerituage o -oil (0-30 percent). -- Ya. 1-4
Ginevskiv
Card 2/2
203.

a zi,~
I NA1:1
T r
loo'; cla, yIlarr-:Zjc
Of s
:~:JWRACT
occn--l C.", co-;~~ticrls of their nria~ lininary trig!- ac
resl--Its unalyses 0.0 fT)e~"imens. 1t 4s proj":~Secl it ze
1 a rlt F, ..I q r m a 3 e 111'. cia 1 rri ~-., m ~i t ea I
D . Y k
"A ~1-31

BANKOWSKI, Czealaw; SKULAp Zofia
mArtemizoin, preparation uaed against pedieulosis.
Przegl.*pidem.
15 no.2:199-201 t61.
1. Z Zakladu Botasiki Farmaceutyezaej AM we Wroclawiu
Kierowmik:
prof. dr J. Madalski i Wojewodzkiej Stasjl
Sanitarno-Epidemiologiczxej
we Wroe]Awiu Dyrektort lek. mod. S. Przyleeki.
(PEDICULOSIS) (PLANTS MEDICINAL)
(INSECT REPRLUINTS)

-:;zeslaw, Dr. -ia.,!~, 'Affiliation not &JIVarxi
rock Dv, Jozef ..dal Appointe(I
L;:~1.1,4a%.. ~~z~rn:iacja PoInka, Vol 1*3, No Nov Cl-,
r a C; t -.3io--raphle; sketch of scientific
acti-%,,ities of
Tli:=5-r. Jo zr--f I, di rec ror of tlie Chai r o I-
-Rhanua-
couticFA Eiotaniki und the
Plants Gardon (Og.rc~d Firuslin Liieniciyeb),
Pnax-,acOutical Division (Wlydzial F-Irmaeeuryczn)-) tmn
, ' f - -I c' -
1-3~Li:La ~!&dyczjia, Aedical Ac A
L
&i-,c Lip Ac,
-casiop of his Promotion to full profassor.~',-- P.

BANKOWSKI, Gags - KOWAL, Tadeusz
Investigations Ion the content of oil in various
organs of Ruts,
graveolens L. subsp. hortensis (Miller) Game.
during 1 year of
its growth. Acts. pol. pham. 19 no.6:497-505 162.
1. Z Katedry Botanild Farmaceutycznej Akademii
Medycznej we
Wroclawiu Kierownik-prof. dr J. Madalski.
(OILS) (PLANTS) (mm)

POLAYD
3 jkNTKOI,.ISXI Czeslaw, Department of Pharmaceutical
Botany (Zak-
V
ita" anirdi"I IM~eutycznej) and Medical Plant Garden
(Ogrod
Roslin Leczniczych) of the Medical Academy (Ak-ademia
Medyczna)
in Wroclaw (Director: Prof. Dr. J. MADALSKI)
"Observations on Geranium maororhizum -L." -
Warsaw, Farmacja Polska, Voll 19, No 13-14, 25 jul 63,
PP
23-2-283
Abstract: 'Ilia author describes the physical
appearance of
this plant, gives popular names used for it in East
European
countries, noting that it is particularly successfully
groun
in Dalgaria, describes the composition of its
distillation
products, and notes its uses for perfumery and
miedicine
(volatile substances of the oil, such as geraniol and
cytro-,
nelol have stronger bactericidal effect than phenol).
He
tells of bringing the plant from Sofia in 1961 and
succeed-
ing in growing it at the Medical Plant Garden
(ve.-etative
method, as seed did not germinate), indicating that it
can
grow in the Polish climate. -7here are 8 references.
one
(1) each Soviet, Polish, Cz6ch, and English; and two
(2)
each Bulgarian and German.

KOSTECKA-MADAISKA, 0.; BANKOWSKI, Cz.
Ethereal oil content in Heracleum Sosnowskyi
Manden.,
cultivated in Poland. Acta agrobot 14
no.1:25-32 163.
1. Department of Pharmaceutical Botany with
Medical Plant
Garden, School of Medicine, Wroclaw.