SCIENTIFIC ABSTRACT ARBUZOV, S.Y. - ARBUZOV, Y. A.
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ARBUZOV, S-To.. prof.
0-:741A =10 t a
_,gWO ro ective effect of certain phnrmacological
prepArations in radiation
?01"- injuries. Yest-ANN SSSR 13 no.6:10-22 158 (MIRA llt7)
1. Otdal radiobiologil Instituta ekaverimentallnoy meditsiny
AMN SSSR.
(RAD IAT ION PRMGT ION,
chemotechnics, review (Rua))
11BUZOV. S.Ya.
~Dataon comparative pharmacologiaRl characteristics of ethanol
phenatine derivatives. Farm* i tokso 21 no.2:25-28 Mr-Ap 158
(MIRA 11:6)
1. Kafedra farmakologii i farmatdii (nach. - prof. S.Ya. Arbuzov)
Voyenno-meditsinskoy ordena Lenin~ akademii imeni S.M. Kirovd.
(ANAIMPTICSO
beta-phenylosopropylamine nicotinic acid phosphate
deriv. (Rus))
(NICOTINIC ACID. rel. cpds.
same)
.AnTJZOVj,-6Ja., MUIHIN, Ye.A.
Scientific activity of Prof. A.I. Kuznetoov; on the 60th
annlveroax7
of his birth ?am. i toks. 21 uo*2t9l-94 ifi-Ap '58 (MIRA
11:6)
(aUTSOV, ANATOLII IVANOVICH)
ARBUSOV) S. OYA -
"Comparative Data On The Evolutionary Pharmacology Of
Mcdern Stimulations Of
The Central Nervous System."
report submitted for the 21st International Congress of
Physiological Sciences)
Duenos Aires, 9-15 Aug 1959.
KHARAUZOV, N.A.. prof., glavu.V red.; MIKMYLOV, V.P,,,
prof.p zametitell
glavnogo red.: BIRYUKOV, D.A., prof., otv.red.; AVzTIKWy
B~Ggt
doktor biol.nauk, red.; ANICHKOV, N.N., akademik. red.;
S.V,, prof., red.;-ARBUZOY4--S,76.
.___j_yrof., red.; VESELKIN. P.H.,
prof., red.; VOYIIO-YASKIETSKIY, M.Y.. prof., red,;
DANIWVO I*Vov
kand.biol.nsuk, red.; IMOTINUCIT, Tu.M., prof,, red.;
7.11MINp
L,N,q prof., red.; WIN. V.S.', red.- IOFFH. V.1., prof.,'
red.;
KARASIK, Y.M., prof.; red.; KUPALOV, P.S.. prof.i red.;
MWINA, A.A.,
kand.med.naulc, red.; VWFAKH. S.A., doktor biol.nauk, red*
P
A.Vol-prof., red.; 3VMOV, F.G., prof., red.; SMORODINTM,
A.A., profol
red,;~ CHISTOVICH, G.N., doktor med.nauk, red.; BESBDIN.
I.K., tekhn.
red.
(Yearbook of the Institute of Xxperimental Medicine of the
Academy
of Medical Sciences of the U.S.S.R. for 19581 EzhBgodnik
za 1958 god.
Leningrad, 1959. 538 P. (MIRA 14:1)
1. Akadomiya meditsinskikh nauk SSSR, Moscow. Institnt
eksperimen-
tallnoy meditsiny. 2. Chleny-korrespondenty Akad-3mii
maditsinskikh
nauk SSS"R (for Biryukov, Veselkin, Win. Ioffs. Karasik,
Svetle"
Smorodintsev). 3-Daystvitelln'M chleny Akademii
meditsinskikh'
nauk SSSR (for Anichkov. S.V., Kupalov).
(MEDICIRE, WERIMENTAL)
:AMWZOV, Sergey Yakovlevich prof.; VINOGRADOV, V.N., red.;
SHEYCHINKO.
7.U., teilli~.-r'ed.
[Awakening and antinarcotic action of stinmlatore of ihe
nervous
49teml Probuthdaiushchee i antinarkotichookoe deistvie stimu-
liatorov nervnoi sistemy. Leningrad, Gos.izd-vo mad.lit-ry,
Leningr,otd-nis, 1960. 268 p. (KIRA 13:7)
(grINULMS) (MYOUS SMIK)
ARBUZOV, S.Ya.j STASHKOVj A.M.; KOROTKOVA, V.P.
Effect of ionizing radiations and certain chemical protective
agents on physical endurance in animals. Farm. i tcks. 23
no. 5:459-464 S-0 160. (MIRA 13:12)
1e Otdol radiobiologii (zav. - prof. S.Ya. Arbuzov) Institut
eksperimentalinoy meditsiny AMN MR.
(RADIATION-PHYSIOLOGICAL EFFECT)
(RADIATION PROTECTION)
BAZZOV, V.A.,- NEXACHAIDUpI.Ya.; PATALOVA, V.N*j
_AWZO--r,A,Y
PETELINA, VoV.1 SHAMOVAp BoX.
Distribution of sUfur meroamine in the organs and tissues of
irradiated and non-irradiated animalo. Med.rad. uo,5&62-66 061.
(141RA 14%11)
1. lz otdela radiobiologii (zar. - prof. So7a. Arbazor)
Instituta
eksperimentalvtoy meditsity MN SSSR.
(Smmmau) (RADIATION PROTECTION)
ARBqZ-QVI S.Ya.; STASHKOV, A.M.; KOROTKOVA, V.P.
Comparative data an the protective and therapeutic effect
of the
derivatives of dienides of imidazoledicarboxylic acids in
radiation
injury. Radiobiologiia 1 no.3:385-393 161. (MIRA 14:10)
(IMIDAZOLEDICARBOXYLIC ACID)
(RADIATION PROTECTION)
ARBUZOV, S.Ya.
Problems in uharmacological protection from radiation
injuries.
Vast. =1 SSh 17 nb.)S58-74 162. (MIRA 15:4)
(RADIATION PROTECTION) (NERVOUS SYSTEM,SYKFATHETIO)
(PHARMACOLOGY)
ARBUZOV, S-Ya.
Effect of some now stimilants (phenatine and its
deriva-
tivem, pyridox7phen) ont he cardiovascular and
nervous
system. Uch. zap. Inst. farm. i Aimioter. AMR
SSSR 3:
206 - 217163. (MIRA 16:9)
1. Chai:r of Pharmacology pnd Pharmacy of the
S.M.Kirov
Military-Yedical Academy, Leningrad.
(STIMULkNTS). (CARDIOVASCULAR SYSTEM)
(NERVOUS SYSTEM)
ARBUZOr P"Wofs
Role of:49 central nervous system in restorative and oom-1
pensatory..;processes following the action of radiation-protee-
tive agents. Sborn.ved.prac.lek~fak.Karlov.Unir.(Hrad.Kral.)
6 no.ls57-75 163.
1e Kafedra farmakologii i farmatsii (zav. kafedroyt prof. SoYa.
Arbuzoir) Voyenno-meditainskogo ordena Lenina akademii imo SoMe
Kirova i Otdel radiobiologii Instituta eksperimentallnoy medi-
tsiny AM SM.(zav. professor S.Ja.Arbuzt)v).
w2wad
A-MUZOV, S.ya..; C)V, V. T.
Effeat Cf sm-~ isothluronium y,~T.J_dcnxine cp
b3cod
C*r0U2at_*Cln a-d SOME t~aicLiinms of fbe
n,;:m%,uz: syzti.-m F rm.
A I . a
toRs. ;?6 no.5:5].9-525 S-0 163. (WiPA 17A~
&f,~dzra farmkologil i tmrm,~itt-li 0~4,70 - Prof.
-_ ; - 1. oya o
krbuzov) Voyenno-i"ditainskoy crdema lkin--'rou
e-kadeirdi !men!
Yd --:)Va.
FETROVA~ L.A.; BELITSOVA, N.B.; ARBUZOV,,S. Ya.
Alkylation of -phenylisopropylamine by pyridoxine
bro-
mchydrins. Zhur. ob. khim. 34 no.7s2390-2~92- JI
164
(KIRA 17t8)
1. Institut eksperimentallnoy meditabny PM SSSR,
Leningrad.
ARBUZOVY S.Ya.; SMIRNOVA, S.M.
Sympatholytic and hypotensive effects of
pyridokiphen. Farm. i
toks. 27 no.4:420-423 Jl-Ag 164.
(MIRA 17:11)
1. Kafedra farmakologii i farmatsil (zav. - proi. S.
Ya. Arbuzov)
Voyenno--meditsinakay ordena Lenina akademii imeni
Kirova, Lenin-
grad.
ARBUZOV, S.Ya.p prof.
Ilikolai Pavlovich Kravkovj, 1865-1924; on the
centenary of
his birth. Voen.-med. zhur. no.3:91-92 165.
(MIRA 18:11)
ARBUZOV, S.Ya., prof.
Nikolai Pavlovich Kravkovp 1865-1924; on the
centenary of
his birth. Apt. delo 14 no.6:3-6 N-D 165.
(MIRA M12)
1. Voyenno-ineditsinakaya ordena Lenina akademiya
imeni S.M.
Urova, Leningrad.
ARBUZCrV S.Ya.; G&NER1,1OV, V.I.
Fhammcolo,zlt-al cha-racterintlt~s of 5-ilsothi~,;m-nium
and 1,,5-diisathiuranitm- pyrldcxtne. -Fanm, 1 toks. 2e
noo6:6.86-
681) N-D t65. (M-1p", 19:2)
1. Nifedra farndrologil t fm-Tatoli Gav-, - yr-n'. -'-'
. Ya, hr bu z ov)
voyorrio-mediW"vokoy (ti-dann aRademil hncril Xf.roval
Laningrad.
_N _Ip~ 'jE..__3EPLT
T,g~"r"&
ACC NR'AP60-34256 SOURCE CODE: UR/0390/66/029/005/0521/0
AUTHOR: Arbuzovo S. Ya.; Aleksandrova, A, Ye.; Smirnova., be iqo
ORG; Department of Pharmacology and Pharmacy, Military Medical
Order
C,
of Lenin Academy int. S, M. Kirov, Leningvad (Kafedra
famakologii i
farmatsii Voyenno-meditsinskoy ordena Lenina akademii)
TITLE: The effect of pyridoxiphen on the central nervous system
SOURCE: Farmakolo.-iya i toksikologiya, %~. 29, no. 5, 1966,
521-522
TOPIC TAG8; central nervous s stem hematoencephalitic barrier,
drug
effect, animal experinienty 91)WEA104'(f rlC- 4)RVe,-
The effect of a new adrenolytic agent, pyridoxiphen (a can-
ABSTRAVOT: densation product of phenamine and pyridoxine) , on
the
central nervous system was studied. Experiments showed
that pyridoxiphen did not disrupt conditioned reflexes in
rats or change spontaneous bioelectricity in rabbit brains.
In addition, pyridoxiphen did not decrease the group tox-
icity of phenamine in mice. It wags-concluded that, like
most adrenolytic agents, pyridoxiphan does not have a cen-
.tral adrenolytic affect. Apparently this substance is' also
-brain barrier. [is)
Incapable of overconing the blood
SUB CODE: 06/ BUBM DATE; 06Apr65/ ORIG REF: 004/- AR~91 891 No.
141
Card 1/1 of
=;615.717-092:612.82 0'
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A X I z AA 11111 11 t
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log
ExPOZIMONIS 04 two-layered aluteriagg tiether to the
Makeev ithiloring wolke. A, I. him-Um. it
'W"vv~t?rd1. lift. 1937, Nu.
chem. '.e'str
Aj
_
IOU. 1, 3M.-Hillits. mtried out on a plant sade un the
2-layered
sinictins of Fe urvs %hoWCA that Under like %Julv
vomlitions the
output of the plant WILS IC14% With 2-14VVItAt
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ARBUZOV, V.A.
Drying and preparing samples of ore and concentrates for chemical
analysis. Zav.lab. 22 no.5:599-601 '56. (MM 9:8)
1. Korchenskaya. rudoispytatelinaya stantsiya.
(Iron ores--Sampling and estimation)
'c!L -'t-
f- f 14 lo
NIKITIN,- Aleksey Ivanovich;
ARBUZOV,..-Y~~4~;#,-*A.topoy.~ch;.,BAZANOV, F.M., red.;
YABIOBSKAYA, L.Y., red.izd-va; NMSON. I.X., tekhnered'o
Cair*)ring iroA ores) Aglomerstaiia xheleznykh rud. Moskva,
Goa.
nauchno-tekhn.lzd-yo lit-ry po chernoi i tavetnoi
metallurgii, 1957;
195 P. (MIRA llt4)
(Sintering)
-11 - I
-~ - I -, ",
, Z
ONOPRIYENKO, V.P., kand.tekhn.nauk; LEDEDEV, A.Ye.,
kand.tekhn.nauk;
SOLDATKIN, A.I., kand.tekhn.nauk; LOZOVOY, P.R., inzh.;
PETRUHIN,
B.A., inzh.- ARBUZOV, V.A., inzh.; Prininali uchastiye:
FUREAN,
D.Mq
Pilot-plant production of sinter with a basicity of 1.2
from
Herch ore concentrates. Biul. TSIICHM no.10:17-22 16o.
(MIRA 15:4)
1. Ukrainskiy institut metallov (for Furman, Konoplya).
2. Kamyshbu-
runsk~y kombinat,(for Kotov).
(tintering) '(Kerch Peninsula--Iron ores)
ARHUZOV V.A.- LOGUNOV) A.Aq TAVIMLIDZE, A.N.; FAUSOV., 4.N.;
FILIPPOV., A.T.
A quasi-optiol model and the asymptotic behavior of the
scattering
amplitude. Zhur. eksp. i teor. fiz. 41+ no.4:1409-1412 Ap
163. '
(MIRA 1634)
1. :Ob"yedinennyy institut yadernykh isaledovaniy.
(Nuclear optical models) (Scattering (Physics))
ARBUZOV, V.A., akademik; DIANOVA, E.Ni; VINOGRADOVA, V.S.;
SHAMSUTDIIZOVA, A.K.
Reactions of tri-(Vv-c~anoisoproFyL) phosphite,
ethyl-di-tert
( ~ , p , A -trichlorobutyl) phosphite, and tri-( A , g, 0
-trichlo-
roethyl) phosphite with chloral. Dokl. AN SSSR 160
no.1:99-102
Ja 165. (MIRA 28:2)
16 Khimicheskly instit,7' Im. A.M. Butlerova pil Kazanskom
goSu-
darstvennom universitete im. V.I. Ullyanova-Lenina.
LEBEDEV, A.Ye., ANTONOV, V.K.,; TATSI-YENKO,
P.A.,-kRWZOV', V~Aq NEVOYSA, G.G.;
PrInimali uithastlyc-2 ZAP.ArMIKO, V'.Yf-,,c KARPOIJETS,
B.S.
y
Experience in the eintpriti.-, rl raw %unconcentrated I
'~-.,Iba,-,3011
ore. Sbor.trud. UNII-M 161:
(KRA 18:11)
L 2om--66 EWP(J)/EWTW RM - - - - - - -
---ACC INN 'AP6012034 SOURCE CODE: UR/OC)20/65/1601001/009-97611
AUTHOR: Arbuzov, V. A. (Academician); Dianova, E. N.,- Vinogradova,,
V. S..
Shamsut d"I
ORG: Chemical Institute i-mo A. M.,Butlerov, Kazan' State University
im. Vo Io Ullyancv-
F
Lenin'(Xh=c1ieskiy institut prl-Kazanskom-gosudarstvennom universitete)
TITLE: Reactions of tri-(alpha-cMoisorME41j eos~hitej
ethyl.-di-tert-(bets'pbetat
~.beta-trichlorobutyj) phosphit oetbyl) phosphite
e$ and tri-tbetapbsta.beta-trichlore
with chloral.
SOURCE: AN SSSR.~ Doklady, v. 160 no. 1 5, 99-102
TOPIC TAGS: ga compound, A"o,
or n;Lc pho4E chlorine compound, ester, chemical reactior
ABSTRACT: Tri-(alpha-cyanoisopropyl) phosphite'wan found to react with
!chloral at room temperature# forming.the di-alpha-eyanoisopropyl
ester of alphas
'hydroxy~(beta,bet~L,beta-trichloreothyl)-phosphinic acid,
splitting'off methac*l-
onitrile. The reaction between-chloral and
tri-ter-(beta,beta,beta-trichlorobutyi),
phosphite produced
di-ter-(beta,beta,beta-trichlorobutyl)-.~phosphorous acid, which
in turn reacted with chloral to give the
di--:ter-(beta,beta,beta-trichlorobutyll)
ester of alpba-hydroxy-beta,beta,beta-tricUoreotlxylphosphinic acid.
The reaction
of chloral with.mixed di-ter-(beta',beta,beta-trichlorobutyl)-ethyl
phosphite pro-
duced the di-ter-(beta,beta,beta-trichlorobutyl).eater of
alpha-hydrox~-betapbetag
beta-trichloreoethylphosphinic acid and
di-ter-(beta,beta,beta-trichlorobutyl)-
:(betapbota,--dichlorovinyl) phosphate. Another complete pbosphite
with electro-
negative groups in the est.erl-radicals#
~ri!-(~4p~a,,~q~a,beta-trichloroethyl)
~-tarcj- 1/2
ARBUZOV, V.N.
Strangulation of the Pregnant tube in inguinal
hernia. Xhirurglia
no.2:69 7 155- (KM 8:5)
1. 3rhirurgicheskoye otdolemys Beloyodskoy rayonnoy
bolinitey Voro-
shilovgradekoy obl&ati.
(MMIUA, -INGUMAL, in preg'nancV
strangulation of pregn. tube$
(PNIGNANO, complicitions.
hernia, inguinal,-strangulation of pregn.tube)
ARBUZOV, V.W. (Iugansk,, ul. Alekseyeva, d.3, kv.33)
Stomach resection with an invaginate in retrograde
intuamoception
of the jejunum. KLin.khir. no,9984-85 S 162. (MM l6t5)
le Kafedra goopital4noy khirurgii (mv. - dotsent N.N.
Zemskov)
luganskogo meditsinskogo instituta.
(STOMACB-SURGMY) (J&MNUH-nMSSUSGKPTION)
ARBUZOV, V. N,
ARMOV, V. 14. -- "CERTAIN PROBLEMS OF STA81LITYCF
RJI~OiT-AW;LE OLADCS ELYONU ~P-CPCVPTIOUAL
L i mi T. "SuD 21; Occ 52, Mon-cow OpDcr? or Lcum
AVIATION 1142T IMEW SERGC, (-,;',0Ztf0NJKIDZE
(DISSERTATION FOR TUr DrGREE OF CANDIDATElt4 TEcHNICAL
SCIUKCS)
50: VECHERUAYA MOSKVA, JANUARY-DECEMUER 1952
AHBUZOT, V.N.
Stability of rectangular kreel,,~ supported plates shearing
beyond
t.he elastic strength. Inv,' v7s, nchebe zav,; av. tekh.
no.2:44-52
'580 (XIRA 11: 6)
1, Noskovskiy aviatsionnyy institut, Xafedra ooprotivleniya
materialov.
(Blastic plates and shells)
A-UTHOR: -Arbuzov, V. N. SOV/147-58-4-6/15
TITLE,: The St-abTI-Roy of Compressed Rectangular Plates
with
Various Bounda.-y Conditions Beyond the Limit of
Proportionality (Ustoychivost' szhatykh pryamougollnykh
plastinok s razlichnymi granichnymi usloviyami za
predelom proportsionallnosti)
PERIODICAL: Izvestiya Vysshikh Uchebnykh Zavedeniy,
Aviatsionnaya
tekhnika,, 1958, Nr 41 PP 36-50 (USSR)
ABSTRACT: The stability is considered of compressed
rectangular
plates under the following boundary conditions:
1. all the sides of the plate are fixed;
2. the longer sides y = 0 and y = 2b-are freely supported
while the shorter sides x = -a and x = a are fixed;
3. the sides x = -a. x = a and y = 0 -are freely supported
while tfie.side y = 2b is free;
4. the sides x = -a and x = a ate freely supported, the
side y = 0 is fixed and the side y = 2b is free.
It is assumed that there is-an-axial stressed state. The
difficulties attending the determination of the critical
stresses in a plate beyond the limit of proportionality
in an analytic form are due to the presence in the
Card 1/2 formulae of various mechanical parameters
depending on
SOV/147-58-4-6/15
The Stability of Compressed Rectangular Plates with Various
Boundary Conditions Beyond the Limit of Proportionality
the required critical stress. For this reason the
author introduces numerical tables from which the
essential critical stress curves can be prepared, Minayev
(Ref 1) has obtained formulae for the critical stresses
by solving Bleykh's differential equation but the
solution does not express the real stable state of the
plate because o,' approximate relations which have been
used. Stowell (Ref 2) has also derived a
solution but thi-s is considered to be unrealistic due
to an incorrect choice of Poisson's coefficient. The
author of this paper bases his solution on Illyushin's
equation wh-eh he solves by Galerkin's method,
There are 4 figures, 7 tables and 4 references, 3 of which
are Soviet, 1 English.
ASSOCIATIO'v,: Kaf.edra soprotivleni-ya materialov (Chair of
ftrO*.-.irxtIh rif Materials) Moskovskiy aviatsionnyy
institut
(Moscow institute of
SURAITITED: January 13, 1958
Card 2/2
UNKSOV, Ye.P.,, doktor tekhn.nauk, prof., red.; ARBUZOV, V.N.,
kand.tekhn.
nauk, red.; MCIELI, B.I., tekhn.red.
[Innatigating the-atrength of materials used for the manufdature
of tvrbine blades] Issledovanie prochnoati materialov lopatok
turbin. Mookway Gos.*nauchno-tekIm.izd-vo maohinostroltellnoi,
1961. 165 p..-(Moscow. Mentrallnyi nauchno-issledovatel-le-
lit-M.
skii institut tekhnologii i mashinostroeniia. Trudy,, vol.103)
(MIRA 15:1)
(btrength o mat;;~ialis)
SHCHEDROVt Mtor Sergeyevich; ARBUZOVt V.N.v
kand,takhn. naukq retsen-
zent; YAMINSKIY, V.V.9 kan a tekbn.-Wa-uk#
red.;NIKITIN, A.G.,
red. izd-va; ELIKIND, V.D., tekhn. red.
[Fundamentals of the mechanics of a flexible
stritig] 09novy me-
khaniki gibkoi niti. Moskrap Goe. nauchno-tekhn.
izd-vo mashino-
stroit. lit-ry, 1961. 170 p. (MIRA 14:6)
(Elastic rods and wires)
TARABASOV9 Vikolay Dani:Lov-iohv doktor tekhn. nauko
prof.; CHERNYSBEV9 N.A.9
kand. tekhn..naukq retsenzent; -ARWq.OVI ~ 9 RancL
tekhn. nank, red.;
, _ff
SAVHLIYEVp Ye.Ya., red. izd-va; ELIKIND9 V.D.p te-kbn.
red.
[Calculating wringing fits in the manufacture of
machinery] Raschety
napria.zhennykh posadok v mashinostroenit. Moskva, Goo.
naucbno-tekhno.
izd-vo mashinostroit. lit-rys 1961. 266 p. (MIRA 14,&6)
(Strains and stresses) (Machinery-Design and
construction)
KOZHESHNIK, Yaroglav [Kozesnikp Jaroslav], prof., inzh. doktor;
GOLIDENBERG, G.M.v inzh.[translatorj;_ARBUZOV,_V.N,,, kand.
tekhn. nauk, red.; BYSTRITSKAYA,.Y.V., red. izd-va; MODEL',
B.I.9 telft, red,
[Dynamics of machinery; selected works] Dinamika mashin; iz-
brannye stat'i. Moskva, Gos.nauchno-tekhn.izd-vo mashinontroit.
lit-ry, 1961. 423 p. (MIRA 15:1)
(Machinery) (Mechanical movements)
n /n
!ACCESSION NR: AT3003031 0/r.942/63/000/001/0228/0146
i AUTHOR: Arbuzovp V. N. (Candidate of technical sciences)
TITLE: Calculation of wall beams based on limit conditions
SOURCE: Moscow,, Aviatsionn~ty institut. Voprosy proohnosti i
ustoyohivosti
elemontov tonkostennykh konstruktsly~ no, 1, 1963, 128-146
TOPIC TAGS: wall beam, diagonal stress., Wagner theory., beam
force,, strut force,
rivet stress
wall shear modulus
ABSY=T; Based on the 'Wagner" theory which treats the "ideal"
field of diagonal
stresses in wall beams after shear instability has occurred in the
wall (see Fig.
1 on the Enclosure), working equations were derived for
calculating beam speoifica-,
ttons for other than the "ideal" case. The 'Wagner" equations for
the diagonal
(see Fig. 1 on the Enclosure), the beam forces s and s ..
compression
stress erl,
forces in the strutas stresses in the rivets, bending momen s alon
P
X g the beam,
bangle of diagonal stresses, and equivalent shear modulus of the
wall were modified
Ifor the case of a real wall beam.* The complete set of equations
is given below
~'(the equations for the ideal case are given on the lefto the
modified equations on
Card I
ACGFZSION NR: AT3003031
Ithe.right, normal nomenolature oxcept as noted):
Diagonal Stressj!.-
2-c
(I k) + 2kz
sIn 2a
Forces
'M P
Af
TcIga
SO 7 ctga
n
Compression forces in strats'
Intl Ig a
Sar
Compression stresses iA struts
- %a1 tg kT Ig a
%t r- 7 ppr
st
Rivet. forc6s.
Of
P., P bt (I + 0. 414k)'
COS CL
Local bending of span
C2
MMIIX -i2 %b'2 to krb[2 Ig3 a
12
AGG=ION NR: AT3003031
Amie oL
too -
Alga
I+ - - ---- ---------
x + -ILI
sin 2a
Equivalent shear modulus of-wall
2
T q;r-
3
2
_P C2- on Fig,- .2
10. tcr
ACCESSION NRi AT3003031
102 is given in Figs 2 on the Enclosure, Orig. axt. has 1 15
figures, h3 gomdas,
and 1 table.
ASSOCIATIONt Moscow. Aviatsionzv*y institut (Moscow Aviation
Institute)
SURUTTED: 00
130 CODE: AP
DATE ACQ: 27Jun63 ENCL: 02
NO REF SOV: 009 OTHERt
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tAlewrhirfly oft' enuan, French anti E ligilAt litt"I urv
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j
The
reaction-ii, of diatomethant-s with antincs.
=00
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l k
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rhy
stlh~fijuird and unsul"tituttA Rh
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so
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Cbwmiwy cd dw Astir"Wfic viumalus.
imul-
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o Dj, Ds, 1). and It, citiefly " twed a* 0
thesis of vits"lix
upon the wl"k ol Windmit, et al. (44 .C. A. JI, 4UP,
32, 21W4,). It, It. Rathmann
90
90
000
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St. AtIALLLR(lcaL Loted'I"t C&AStwicallow
tD10414 .10 Ov off
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040
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10 S".M" P-
wpnw
a.. list 13,344
q.( lit
-1r- I a-r-. '4.
it t, ,u b 4 0
so see 0 to 0. 22 .0 LM
!goal*
a
Ka
19-
MM
k 66
coo
00
1 r I
61:966600600,69: q -#M~ I I I . ~ ~ ~
L -43. MI. I R 39 w 35 a V a is a 41 a is 0
A -MILLI-a'a-CCAP U'110.k
.40 jl..VPVf?t_-
VOCKMIS A
I Coated Cooversim ol the sli-membered ring into the
it andVu.A-U1wj&_--
Ave-wImbendooe. N'.D.ZclinA,
Compf. read. ared. sti. U. R. S. S. 23, -.114 SM139011
HngIijh),-%%%en qThaftexene was pasaed over curn. Allf h
or over silks wrl at 4160", nirthyleyriopentene wal, (unut-4.
~Nltthytryrlohexene wits similarly movetted into dhurthyl-
cyrIanwrilene. ]n each taw tile wl%atd. mAlkict wa% hy-
drogertated to the corresp, ditig cycloalkanc uvrr plat -
00 InIzed charonal or silks get. Whun tile cyritlalkatir will,
pawal over platinized charroal (,r silica gel at 27"', 1114.
00 -3 ago
ring was broken to fom tile open-chain h)Atocarllclu.
00 Cre% at cS410 dehydrogenated Cyclollexclic and flictlay]. no*
lollelene to benzene and w4ume, rcitti., utz.-tcas Cyclo.;
~Ylzsue and cyclopcittenc were menti2fly unchnnied.
Ttout. It.
age
If lie 0
i
H LAO, too
~-_S L 4 SIETALLtlAtfKAL WERATIO111 CLASWKAIIO
I
too 0
1411641 map Qw O&C
00
u III AT 10 It alkali
1-- 9`1
to, IT X, IN, -0, n-mr-Ig it a it of I t a (W a 11
0
~-o
: o 0
0 0 0 0 0 0 0
I I-Is a ~3. 1
00-A
060
00.4
10400,
Ott
0*2
0*8
*08
00-0
004
0490
0*4
OOW
8.4
rate
Ulm
XV
Cato
1.41
coat
1.9-9111 d-oo OAM).
pentaneand 3-tudhyllvexane.
a I a. S L & SITMAINIMAL UTMTWW CLASWICATION
so
.00
.09
Me*
.0
0
alo*
age
no*
000
Coe
Igloo
fee
see
see
see
l-41TAM,&Ww, wee
1 9*0
b U is AV in I at N a a 2 1 N a 9 do a a 11 9
a&
00000 0 0 0 0 0 e 0 0 41 0.0 0 0 **is 0 0 0 0 0 0 41 0.0 0 to
*see ..4
00000 00 000000 0-0-0 0-0 414:0 0 090 0 0 0 - 0 0 * * *~* 4
Lgk~ ~-D,414dy A W. Nauk S. S. S.
1 4. toe was twkv PaWAO at a
- ou-cm. layer of allies, gel In a I &.
~lhtova. Themainfrution(blW-1W
i
11 h=ted with a platialsed charcos,
1 to oce a satd. hydrowboo mlxt.~Mto
was dehydrogenated with the ",me "t.-
restid" bydrocaboo tubt. (.,; 1.
b ,'
ITZt. Of toluene. wbicb was removAdb
Ile residual Mist. (1) (hn, 92.b-
LM, d1' 0.78M) was proboMy moody 1,2-
wane. Thia istratise was supported by
1. under condlitions favoring opening the
i a bydrocarboo mist. (bm 83-916. xV
tbought. to be moody 2.8-dimethyl.
W. Perry
'.16 6-W0 0
L Ax PDAL W A-
~'JL Its P ;M~ "0181,
TI
0-&txtt%4,* .-K,
Oxidation of cyclo1exents by saleolous acid and a ue.
miatmd of StIon of 1.3-c1doltemilictoo. X4. A.
r! . . 0t a.
Arbititov IO~Zsllmkil. acid N. 1. Shuticin (in t
Chm ISd USISR) If 11 41rad. st i. U. R.S.S
t. nteflught lot thr
Vtltiop set cychshcxens, air given. (I) The ryciohexcitv
P- M-4') is o"filk-d with wkniow acid at WW" its
AtO; two substaism me (omml.
esevieste (1) (yield 48-52%), be 67 9% *V 1.461, aml the
"
a 0 As d
s- A
op ..r. it. q-1pt
7~66
00
f
0
fiacetate (11) of cyclohexenectiolp be 112-13
. nV 1.471.
6011
c
1n one of the expts. I and It with the (otlowitig mi,ts.
.00
wm- obtained. 1. he 68-0', cf." 1AW. NJ.' L-RIMM. 4g
900
JAMR,
AIRD a coluslem mobile liquid with 4!
"
zoo
k 1.1225, NVV
plemut froity odor. 11, be J.
1.4710, URn 49M. Ught yellow rather mobile liquid,s
is al'o oxidiz
ith
d
Th
lofieXtu
k
t
d
coo
o
w
*smu
or.
e
t
unp
e Cyc
"
with 5--0l at W-0)
in a tuixt. of AciO and glacial AcOl I
wgive I 1.45R. Forth
pttVn.
,o o
(1111 the 3-cyclolsrietc-l-ol 4cretietr
.1
for ttd with a frt*hly inrlted and fitsely pow-d.
KIIS06 at
150-W'. III (W74 yield), Is. 80.5-l",
9w
0
as obtesiotil with th~
oVI.475. In one of the extitz. l
"
qoq
, d1.1 0.8411. mi: 1.475(t.
following consts.; th.v 1111.4-1 D
hl R o M2. Makk suhydtide
(2.94 g.). Pidded to 2 40 g.
lose
of III In 7.5 cc. of pure
beugene, gave 5.17 g. of addu
200
ptoduct, probably
3.0-endoctil),kite-~il-tetmhytlro-
hthislie anhydride, crystir.
froen petroleum heptime Its
C
ve 0
right needless b.. 14"'.. G. Ubedeff
tie 0
11tTALLURGICAL
LITINATM CL&SSWKAI#CN
tie
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&L It AV to is It
it
0 0 0 0 0 go** a 0 0 *1* 0 *1* 0 0 0 0 0 0 6 6 0 0 a 0 0 0 a 0
go
IST.4
mass&& at 61 a a a a a a a a a S a e a a -0 A-41 e 0 00
046
4
0 0- i
oSo9q0o0*'**eOoee-be
p Wil uct"all uuu l6lava g
A&CD1r4TSXLfi1k Opus$ 1w 1111-1-q- 4 ~~ 9; IT (m AT u "
L
it,
1.6MVIO af~ 11-0.0t J;i r0'.
-Ott
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A
o
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liql-to J111 J01 liffuLlop all 11111tIVII.Mill u043pli
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qllA% 110113w) 4w j0 11taulluW1 All Imirinq ma 1qtr:t.jw
W
.olx(3 p3luryun pum martatIotl(a lo %&ivul louriuml
.0PA31AII1.1111
l1witi
IV 41.111 mm, I"myll.41
'Nil
IN, E y "A
-p 5"j)"S 13"W03
fill.. 1111414044 -1.1 1
so
of
so
oo
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sor
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03 inlmq lump
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'tw
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9
s V
IL 00
-
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09 1
91 ;qal 0 NJ %om
"a P"Ut" &am
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l
r
nee
P
q
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vt.
e
1-mdaq[Aquul-g PM Anivam
*
UMAP3 VVIAMN atLL
::
94
191tu an P
AID= 31mmoq F AM"
"I
so
N"11003 1119111 pal 4 - law
van
01
'
I
u
a
6 I
1
Foe
j0
P
--q 6u
03 99 sea a 91 oat "11
km
t
4
s
iMpow sql lo mW A-
VVA
M SNAG
a &Jim 0 IV .00 IV
- Fo-
,%q
ow jQt6l
,
1W.110.100 'mm
so
-wpm --n-1 -P
killki tal㛜 MY *"123004
r so
7
r
W. w. -2. - .01 We 7, 1 UK all T
I
-
-
o sit,
110, VI 0. W, W. wit
111 10 41;
41 -4 to
JAI r-1-1
11 K-1111 -V--
00
R
ti
f di
i h
10
eac
on o
en
ydrocabolis with nitro&* com.
pounds. Addition of 1
3-butaillene to nilrovols
,
enteno.
V"JilL41tiv. Poklady Mail. Nusk S.S.S.R. 60.
C.A. 42.
I,hNo alld 10 fort"
in
lullo"' alruc te 14 c0lifirlited by fornnittion of 4~mi-
;
ints-2-birks-1-d (11) on reduction by Zii-Ar,011. Ph%o
1
(10.7
g.) and 10.7 g. 1,3-butadiene ki-pe. 24 htn. in a %ralctl
vcsqci at 5-10* gave (11).9% 1, :it. .591-l' (froin EMU);
'
th
i
ld
6
too
60
e
e Y
f
m to 91.2% on 7 (lays
,tanding Willi ivv-
emAing, m loP07t, if the conilxmcul, In
UtOll art, allowed
10 litit"d 24 hot. With IM-MIling atilt tile PToduct then
dkttl.(bj.&l07-8*). Reduction byZit-AcOll gave.M.1-P
*
"
U
:ire*
. N 151-
. d:
LORIG. xj: LW7: trrainit-sit Aith Ar.0
at Hill' 3 Ism. gave 9301
of the di-Ac derir., It, 160-1
zo
.3
d!* LIMM. x1p 11-271. Thi,
(2.47 g.) in 11N) sill. hl"CO
7
i
h 4
w
.
t
, g. Khttin, its hh-,CO gave N-aertyl-N.
pkewylgly% ixe. in.
194-S' (front A sticir). t Ism giving a final
structure
confirmation. G. M. Kcsolal.-ff
zoo
VIIIIIIII
A
STALL
?RGKAL 1.111441101 CLASSIPICA111014
~,gq 0
_
7
all
5
An
44:
U It AT .0 It
a plan Itall
tv to 44 1, 14 4
IkUlft
.
00000
00 * 0 0 * 0 0 0 0 * * 0 0 *
.00o0
00 so* Ills Go*
40
RAW - OF it
**too 0
U If 9 13
IV 141,1 J_
*0 A
04iX9011, A.6 000014141 INDIA
0044
fie
C bmwbm" d Cy
x. 1. eat*". and M. D. Zerlitakil. U-0-P. V
21. ildf 31. 1946. P. 124.
snafus of, AbOrdds. V- '
ova Abstract row Sidi- A;W Sci. Uxw. Ct- dr,
""58*
090 , CycoMxem , was ental.tically loomorized over
_d__te *" doogi, irsetionated,
IIIIAM OX14C C
00 #3 tractions Identified.
redistilied, and the
AA2
ji
4 S V.$ L A 'PKTALLURGKAL LITIMAIUNt CLASSIFICATION
smiama .10 O.V car-
DU, 9 AV " , I T I I W I
m U t, it
0-0 0 0 0 0 0 0 0 0 0 0 0 0 a
0 0-,* 0.0 0 0 0 0 0 0-"
.0
n
r
C04
Nei
204
**%arm
h31111 OW a".
'A An a I a [W o a a -I IF 6; 9 a Is 7 it V
is, W,m
0 0 0 0 9 0 0 * 0 0 0 a 0 0 0 0 0 0 0
2j. t-t-O.-t 0 0 0 0 0 a , 0 0 0, 0 0 0
3keea on theoretical data two system
wher4by 1,3-
lutediane can be added to nitrosobanzine.
, Deacriba
,viwjoua emparlments conducted: 1)
addition-, of 1,3-
butadlone to nitroadbanzina
2-PhwWl-3,6-dshy&o-
orthecalne; 2) reduction of
2-phenyl-3,6-dWWdro-
67T2T
USM/Chealstry 10-Batadiene (Contd) my.,
1948
arthocalne by 4-phanyl-Indbutane-2-01-7.,-
3)
&Ootylltatlon of
4-phaqyli=lndbutane-2-ol-l;.4)
oxIdization of diacetyl produced IV In
N-acevji.
V-pheWlglycine. Submitted by
Academiciau!A.N.
Nameymov, 2T liar 3.948,
6-M7
8:
ARBUZOV, YU. A.
PA?6T9
~N MIV,g
1~1 N-fw
Olefins,*
fie chf=istry
RM
ene 13~rdrocarbcns With NI
i lteiictlon of Di Ltroso
Ounds)" Yu. A. Arbuzov, N. L: Fedyukina, PP
Ak Nauk SSM' Vol LK, No 7
ribes the addition of I 3,tutad-'ens to
diene
osttolu6ne, and 'the addition of 1,-3-penta
4-%axadlene to ultrosobanzane. Submitted Mai---
NO
2~
ARBUZOV$Yu. A.
witty nitruNa cont-
Addition ut A~) to friollicric llitrn!;O-
Addifion t 1,J . 11clitildie'lto allot
1i nitr4ril ;U141 1171`7116WI,
117!1 6
60,
71.
lind Oll )-. IVIIXII~1. LvIll ilk -.111 aml,%lt
~,I III-.
;it 5-10, gave tfi.7 z. Z-o-PIX-1-3 -4-JA V,11 o -
1,
zine, 974-5' ill' I a j" I ,5 6; 11 -. ~ t 7 ( I
INC i k: I t I
was welwl 4M,6 %V.;4 ii'AA ill a w1vvIll.. I",
ONCLI14Nte (INA .) will 2J g. 24 lim al,
0 51, gave of (Itv ?~km4al ,vt im,mrr, lj,.% 115-
1 V, it.'
1-0715, it' I IJAIN), sim: ill. it-.; slllvo~,llt
gave .1 7 7,11k
I., e-ONUMMe g;)vt
(finiti McOID; the
OvId %vaq ra ist-11 It, SIA% Ily ushig CHU, llu
golvViti.
.e
I,I%NO(:Mj g.) ill 300 lilt.
witil vu :Ifl;:r 21 1 11r.%. ti.~Olalvll by
stealil distil.) Zk-ldiriii-I-Nar
tit o- 1,2.Zt1-Ox=ille, to, A
Mimilar n-ioviiii,ij ~vijjj
.jvc jj I,,!
AM-1:21, ill,"
G. ~(,
0 0 0 0 0 0 A 0
1
L
1"
1
)4 ri 14 If W I- If it 14 it to 11 11 vm.1
4) 41 " 0 l" Ill
A I
, LL 1~ 1
0 Itr a 41 If .11
4, 1
I
0AI '1 44 0 CIL I* u
t
U-40tot
00
-00
Reactionsoldlene h0tocatImms a ith
nitiosocampottisda.
ti
n
f 2 W
6 dih
d
2
d
1 3
1
R
o
so
uc
o
,.
e
.
,
y
At litatt v. v Akad, Aawk Ns R, 63. 1 1
1=
C.A. 43, Wslr.
-toxa:inr (1) KIM g.) ill IN' itti. A0111 hAvii
'.99
with 2.1- C. Zn sltj~t 35 n2in., flit-if hm.&IM la 11141' 7
fu%_
civ(s, Oil licuttalit.161111 alid stv'11114161111_ 3A K.
I-Phrn-vl-
,
00
in. 1M-2
00 v:
ill of fill. AcOll willi 25 It, Zit Ivail, ill
I-
w(i ... 1. aft.'f MvIl Irlimmi: I hs~ 1(m., If It
'
o J
flit 11 Ill I
l C I Phr"I;
iNvf"'Idift'. b.
w. 117-18' t(mm Fi;)IM. kOltixiag 16-:4 g.
MiNfl.
c1l;0I.ClIciloll flill %%fill fit g' zlicl: its *of fill.
7
ji
01 fill. lwt all,
AcOll 4 hm g,tvc 7:11. 11. 1 J:12.2 g.! in 6.
61011. ItvallA
wilh 511 g. Na ovrf Ill mill., lwat.'f tilital
tit.- N,i Ji-4ml.
mul mcam di,l.l
00
.,kets-s'. tiv), 1'~ SO Nl-, 1.1" 11 061A.IA
Imatull fit 67", )-wid liv mmilm s-loomn 4 Ill ill, fill,
00
C.M.
Illepreftlit" I.'s7'-.S-)-. IV Klv- with ll/Cf in N..,M
00
Or Ih
deriv.. tit. 90-1' iftom E1011): As dtt;r.. It.
'
'
00
PIS I,,, 1xi. 1
.41 I'm .'f t hi, t.v KNI 110
ine. sit. I'Ll.."4"). koNction
'
0
M r%vhdlv\.t11c with PI-C ove N-haYid"t.
'd IV by It
7
ille, I)$ 0-s" 1:* 11.9111, f1j" L.
0;i; ji- de"r" ill
(t'"11 jwtr. 0 IwF 1. C.. M. K-1.11.41
010'
All-St A
Of
Lillg4lkvE CIASSIFIC-740. I I
it
1; %A Vt AV to is!
v
.4 KIt It q Pt Ct If It X
IV rw0 1- W 44 -j di .3 -iI
An k
a114
T
,
go 0 0 : r0
00 00 10
0 0 0 0 09 00 0 9 9 0 0 0 *
000 0 00 00 0 0 0 e 0 0 *
0 0 0 0 0 0 0 * - 0 0 0 6 0 0 0 to
1.0 :
0 0 see* 0 0 0 0 0 0 0 0 0 0 0 9
41100 Is
0 ei
ARBUZOV Yu- A.
ry 'D" 48
MR/ tit'
Charlitry Nitroeo, Compounds
*eacticw of inene Hydrocarbons With filtrozo
Cbvip6urida. Raftetion,of 2.-~hOnyl-3,'6-DihYaro-
C&thoxazine," Yu.-A. ArbuzoT, Inat of Orig Chem,
Aceid Sei UM, 4 PP
nk)k Ak Nauk SM" Vol LXIII, No 5
We bited from a poevio-as article shake that)
i4r6ducing 2~.PliOYI-3, 6-dihydroorth*2;ine by
a tivim. afid a*6hol, 4-'phenyl-amdhobuteEe-2-ol-1
le,formed. Thin is fu-Aher reducett to &6tylanj+
lene. gi~bmitted by Acad A. N. Nesmayanov VNIMN
55142T14
Structwill formula of diams-nitroito compound addition
ducts. A 11hilarl'ahlivin, It'll, A. ArNiFow. and 1'. 1'.
I
rt-twy In
fis, f, Aloc 14, 413 IIIIJUNI). lite .4
414-kit's tit llitl~ 14 1.1%. 1.4 ~.tllltvs '1111% , .4 3,1%
aillytilt.nillowille (1), e.g.. Initudiclic Ph%O - I
CILL111'. The conibiwition disi-crsion -IxAint I)( C:C tit N.
I
~;tnd 6-nivinIvred liciefocycles "ere dc(d. The intest,ily
t,1
"llic Put) rill. I hind vibmiltmi of the Villa ring "lily Iw
itwil
ws lilt inifiemor tit lite v;ilrner swir tit the N aloin
rt-tinert"I
I., thk lilic. ]'Ill. k.111. A Ow bllvll~ilv 4.1 lilt
C-C ImIl't Illdie.'I'd thal it, III IIWi'A Owl'.
III 111, 1,41. 11"Ir 1.01". .. ......... ...
I oj%~l 11. Vmd W.
"Addition of cvclohexadi ell e-1) 3 to 01-,roben~zenp."
Vel-i. 2ap. Mos!-. un. po.
132, 1950.
-K: IMLRA, October) 1950"
ARWZOV-Yu~Aj FEDYUXINA, N.L.; SHAVYRINA, V.V.-
Dienes
InteractLon of di-(cycloh-qx6ne-1-yi-1). 2, 3-dimethyl-butadiene-1,
3 and 1-phenyl-butadiene-
lt 3 with nitroso compounis. Uch, zap. Mosk. un.,*No. 132, 1950.
Monthly List of Rassian Accessions. Library of Congress, October
1952. UNCLASSIFUD.
Reaction of Mohr hydrWarbms with nitrotic, com ounds'
and J-m-tolyl,11,01hydro.
2,oassins. Vu. A.-Alibutoy 01. V. Slate.
Vitiv., Abad. Ximit S S S. R , Odd,
Nk"Ps. Namk JOS;. 013 01-11111"dirlie (11%, 1.) saild 72 -,
1.
III ClICI, after 2.1ave III 11rAl 1) 0"% r 141 a I.
W6 0,11'. .1.0, 1 07:111.
at? NU15. Which will% Zit duut and Acoll save X2.5%
(111, th 181-;1*, all- LOUIS, III,-
1 .57,113, yirlding wills Ar,O altrt 3 hm at Hill' 04",'
di-Ac
.fr,lr . 14 1-,* IAW, aV 1,5243. %hicli wilb
Nfr,ct ),-K %trio, rr4.111V gave NX.Al" N-Oerjyj-.V~-44114-
.C1.11me (111). tit. '--11-13* (imm 11,0):o It the
1"lucli'm if
the ousine nlt,%c is alone at reflux, 47"
dihydrepyrrale. Lot-* 904-1,5% all." 1.032N). ml,* I.&R42,
bt
a'blahird. 11 In rrallithis nits. I"1011 with Na uirtal
gilve
-.5"t, I-t-t,4yhm4x*-:-bu1rme. 14 ISO-1)0% d" 0.9314, mj~*
which with hot Ar.0 ravr the A( dcrir.. C.,II,,0N.
1" 11.1 - 14.46% JAXIIII, xf.* LAL'97. 3-ichling with
NXICtO.
It, slycitar dmiv. Similarly but-lient, with
1
111INC., I.Nle lrave 86.37, 1"401yi iseta" (If 1, 1., I(M.6
5.0'.
1.071.1. at* IZA178. which tit rtwin temp. will% Zia olim
ill ArOll vIVI,I% A2.:r" M-14yhlmiae i,,,mrr tit If. 1'. 1
$7 ,;,.
,I:* 1 0:46. at' who,r di,4c I., M W. I-.
I IWWI. -it.' I with KNIIA1. lit "le'CO givvx W."', I's.
Ad Ill. lit. 145-0, (trallit dil. VIM),
0. M, Koscil.11,011'
Reaction W these sydrocautwas with nitroso coinpounds.
C reducdw of 21ski yi-36-dib dra-1.2011,~oxa-
M"-' A, Ariniurl
dbo!
PPkw ". .14*' 79,
&k S.S.S.R T6, 491 NT _--i I--r7r-
4.1. ILVI Alksolls III) C ICIUCII'l, i"lls 111'.1 r
11.11c,l I,h%*I) In I I VIICI., 1,,Iliilx .1,410 .,%villight,
.410
411.1c Jbi 1. 11,
Im W, N) I 110ti,
tutlAIM ill Oliv, 1 .1 it. Pt-C it 1-111 truill Ishii,
111),14,011111, It, Acid 4 K-IfINAIWIP"'PIN-Ji- till -''*.
,41 1 WAKI. all 1 .54,61). Till- I MA x'. I till. A0111
trrAl"I its 4 lxxlkmtx with 4,1 it. Zn, iluA % ith
till ~ttnsll-fii,ld '.11.1
'Allitc.11.; lite ec,t.
4-phrOY&S tug I-0- I-buldstal (1 1* 11' 154 %'. it'* 1(411-
foil LAWO, drid MV141r. deo"Ill). 1.24,5-5.0" (It"Ill Mt-Off I
Ilydroxenation of I'liXIM1,4011:0101,011 Ili Viso at
sticull tritill. O%vt PI-C virl'ItA 11111,011, Ph.N11,, /,A.
114 1 W% 11'. Il'l* 11.0391. mi., I "3M i /is dent.. tit 41,
"'t
told I7.1r., 1, lilroil6-al %Ilh till- Mitwv. 1,,.. 147, A',
ii,,,
1 114111, mi,* LbMb~ C. M. Kowl.11hill
OA
It"Waimii,s d time by*--b- -ft
2
-T 64 W 2 R. 71.
~*'~MVA 6d -are bli I V-HS ~~ SW
723 1. p.MtC,)I.NO, 78 1. butildW., Mi. ClIcAl
'mnight at o' ga- 94-2 g- Y"."A
stand 4 Eloll
1.2(111).ozatime (1). bs 112-13'. m. 47-8 (from
Aken 0.5 hr. with AcOH-Zn dust. ninittaUted, and ateam-
Sh
- .4 (U). b. 139-0'.
td.. pvc 78 SAO.""Me I
0 I.M53, a %7 1. i.Bxd&riv.. in. 130-11 (from MIT);
s J",.t 167- & d - I.Orm. MV 1,3m. The tattft
.61 Jr.) in IOD nollMo tmated with 4.7 9. Oftl()o In
~2-.A co
2J5 kn. 55.6% N-"#I*N-P"vt-
0 (fmm
(ciude (ITm) 175.b-7.0'
_qj4j, a ust I..,AtH
30M _j!j it
. j Ut
b Z"Cl, mid AeOll 6 hn. U with Kmnth
py-ok. in.
is or HCI-FeClo 9&vc I
1 33 L) in =1. abs. RtOH led with 60 C.
t t 69%
%,& ortr coal
1-0 '94m;
Is, 7'. mV I. I
"0 Ac dorip.. t%
1.5
IW70 dl* 1 1. . S.
12f)-io.3 . dl- I. I. a 1. . 0. . K Doff
----
MMIMI
A-A-43-OG-7-0 VJ-YIA
Chemical Abst. The reactions of dlenic hydrocarbons with n1trosoNom
Vol. 48 No. 9 pounds, Addition of I 3-butadlene to n1trosobewens.
\11.
Vu. A. WrbuVv, BJ. Icad. 3d. U.S.S.R., Die
. 47* C"!
May 10t 1954 translation).--See CA * 4874
Organic Chemistry H. L. ff.
"a-, ~' M*- 9 A M M~MZFQM
Awl
~ ~t
Its reatims of diente h n1trow com-
y
Ghemical Abst.
Vol. 48 No. 9
.fS-I-I 3- fliene, I-phen*
pmds. Addiflonaf 2-A-d.
1,3-~ =adle 0, AndX-IW-C0heM-I- aronutle n1troso
COM me *K- Vi
- YU.A. 'zov
kina
V.
N. L. Fed3
Hay 10, 1954
,
,
.
W
Sbawrwa,aUdR.-Usbede va. ffuU.Acad.,Yd.U..Y..Y.R.i
-
-1
Ch
S
Organic Chemistry
My.
em.
C
S
952, 2(Engi. tmndation).-See
C-4.47,43421._ H. L'. H,
7~v
--R-ROuzo-v
yu.-tq.
VC/
R6actlons of diene hydrocArbons with tdtrosa compounh
A dditio f 13 1 h dl I iobenzene. ~
j-cyc o exa ~q~"o n troi ~7,nA:
--Fu C cl.,~
rh
Div tion).
y
e C.A. 47,R-6.
iiABLID)v Yu. A.
Chemical Abst. -3-i~y'd
to 0 I-ELryl r0
Vol. 48 No. 9 TMOO &nmCl T1115W, B3111. Acad.
rtu. Sci. 1952, 09.5-0(Engi. trasi%=1011).-Spe C.A.
.May 101 1954 47, 5927c.
Organic Chemistry
ARBUZOV, IU. A.: KfUZELINITZ)KIY, L.I.
Fyrrolldines
S.~nthesis of 1-aryl-3-hydroxypyrrolidines. Iav. AN SSSR.
Ot,-I. Khin. nauk, 1110-4, 1952.
Monthly List of Russian Accessions Library of Con,gress,
T)ecember 1952. Unclassified.
UM/Chemistry - Diene,Synthi4es'', M&y1J=
52.
Witroso Compounds
ReaLation.Between Diene Aydrocarbons arA
Nitroso, Compounds. Addition of
Butadii"w~~J,3'to
,:,Ikt~rosobenzene. Part 2; Yu.A.
Arbuzov; Inst of
Oig Chem, Acad Sci USSR
."It Ak Nauk, Otdel Xhim Nauk" No 3., pp
547-555
In,energetic reduction of ?--phenyl-3,
6-dibydro-,
orthoxazine with zinc powder and acetic
acid I-
phinyl-2,0-dihydropyrrol is formed. The
reduction
,of:2-phenyl-3,6-dibydroorthoxazine with
sodium
220r2l
4m4 alc results in formation of N
crotylaniline.
The intermediate product in these
reactions is
)+,pbenylamindbutene-2-ol-l.
22OT21
UNR/Chemistry - Pyrrole Derivatives
Vliy/Jvn~~52
"Reduction of I-Phenylpyrrole," Yu.A. Arbuzov,
N.M. Garburg., Inst of Org Chem, Acad Sci
USSR;
lbscov State U imeni M.V. Lomonosov
""Iz Ak Vauk, Otdel Xhim Nauk" No 3, pp
556-563
Reduction of 1-phenylpyrrole was studied,
using
zinc powder and hydrochloric acid at 60-750,
zinc
powder, hydrochloric acid and acetic acid at
40-
50 and at 50-650. Under those conditions, 4
hydro-
gen atoms are added, resulting in the
formation
22=2
0.f 1-phenylpy.Lxolidine and N-crotylaniline.
The
reduction mechanism is explained by the
intler-
mediate formation of
1-phenyl-2,3-dihydropyrrole.
MR/Chemiatry Dieiie: 87nthes6s May/Jua.
5,R
Nitroso Compounds
"the Reaction Between Diene Hydrocarbons
and Ni-
tr6so Compounds. Addition of
2,3-Dimethylbutediene-
1,3, I-Phenylbutadiene-1,3, and
Di-(Cyclohexiene-l-
,yl-l) to Aromatic Nitroso Compounds,"
Yu.A. Arbuzov
N.L,. Fedyukina, V.V. Shavyrina, R.I.
Shepeleve, Inst
pf Org Chem, Acad Sci USSR; Moscow State
U imeni
.M.V. lAmonosov
"Iz Ak Nauk, Otdel Khi-m Nauk" No 3, 'PP
566-569
Studied the reactions of
2,3-dimethylbutadiene-1,3,
trans-l-pbenylbutadiene-1,3 and
di-(cyclohexene'-l-
71-11 v-itb aromatic nitroso compds.
Obtained
220T21A
the adft products of
203-dimethylbutadlene-1,3 with
nitrosobenzene and p-altrosotoluene,lof
trans-1-
phenylbutadiene-1,3 with nitrosobenzene,
o-nitro-
~sotoluene and p-nitrosotoluene, and of
di-(cyclo-
~hexene-l-yl-l) with nitrosobenzene and
p-nitro-
totoluene.
ARBUZOV, Tu.A.
Reaction of diene hydrocarbons with nitroso compounds.
Addition of 1,3--
b~~&dlene to p-nitroGotolusne. Isvest. Akad. Nauk S.S.S.R~,
Otdel,Xhim-o~
Ni~k 152, 658-64. 5:9)
(CA-47 no.20:1049) 153)
1. M.Y.Lomonoso* State Univ., Moscow*
WTRYUKOV , T.A.
Ae
]j! A
.R&qyoj
Reactions of dionshydrocarboas with nitroso
cyclobexidiene t6, 'nitrosobenzens.' Izvest.
Nduk '52, 665-7o.
(CA 47 no.2o:Ao493 '53)
compounds. Addition Of 1,3-
Akad. Vauk S.S.S.R.. ~Otdsl. I[him.
(MMA 5: 9)
1. M.Y.10monosov State Univ., Moscow.
1 1 'A (~ ~ ti 6i , f
. . . %;- T. ~ ", : . , - ,
- . . . . .
- --- -1-
, , ': , , . I"
:7 , , - , ; "; i~ ! q44~,
MTJZOV. Yu. A.;DYATKIN, B.L.;SIMVBLNV, S.A. II
.~Z-
Some reactlons of 1, 4-dichlorobutanone-2. Dokl. AN SM
112 no.2:
261-263 Ja 157. (XLRA 10:4)
L, Moskovskly goandaretyanVy univernit*t im. N.V.
Lomonosova.
Predstavleno akademikon A. N. Nesmayanovym.
(Butanone)
C) v
I/
&THORS:
Arbuzov, Yu and Pisha, T. A& 2o-1-19/44
A ~-
TITLE:
Reactions of Diene Hydrocarbons With Nitroso Compounds.
The Addio
tion of Pentadiene-10 to Nitrosobenzene (Reaktsii
diyenovykh
uglevodorodov a nitrozosoyedineniyami. Prisoyedineniye
pentadiyena-I.,
3 k nitrozobenzolu).
FERIODICAL:
Doklady AN SSSR)
1957, Vol. U6, Nr 1, PP- 71-73 (USSR).
ABSTRACT:
It was already
proved earlier that conjugate diene-hydrocarbons
react with
aromatic nitroso-compounds according to the dione-aynthe-
ais-scheme under formation of derivatives of
3,6-deh_vdro-1,2-oxazine.
It is the purpose of this paper to clear
up the structure of the
reaction products,, as mentioned in the
sub-title. The reaction of
the diene synthesis,, in which conjugate
unsymmetrically built dienes
participate, was already earlier
studied in a number of examples*
In 30MO cases either o-isomers or
their mixtures with m-isomers
respectively develop,in which the
former are strongly predominant.
In other cases p-iaomers develop.
These data are in good agreement
with the ionic mechanism of the
diene-synthesia-reaction in which
the transfer of an electron from
diene to the dienophile takes place
under formation of a ion
complex. The second stage is the regrouping
Gard 1/3
of this
comp3Lex under formation of a stable adduct. In a number of
Reactions of Diene Hydrocarbons With Nitroso Compounds.
20;~9/44
The Addition of Pentadiene-1,3 to Nitrosobenzene.
papers, however, data were obtained which contradict the above-
mentioned mechanism: o-isomers were predominantly or
exclusively
obtained. The problem of the reaction mechanism, as mentioned
in
the title, was hitherto never discussed. In case that the
reaction
mentioned in the sub-title took place according to the
ion-mechanism.,
a 6-substituted polymer Ia, possibly with an admixture of the
3-aub-
stituted po]~7mer 1b, should develop. Transpentadiene-1.0 was
pro-
duced from croton aldehyde and bromo-nethylmagnesium pentane
2-01-4
and dehydrated over magnesium sulfate at 3oooC. Further the
authors
produced the above-,mentioned addition product from a mixture
of ni-
trosobenzene. and pentadiene-1,3. The production speci-
fications ana the constants of the substances produced in this
con-
nection are given. The yield of the latter addition product
amounted
to 72% of the the6ratically possib '1e yield. By its reduction
with
zinc dust and glacial acetic acid, amino alcoho1LCIH,50N was
proo
duced with a 71 O/o yield as compared to theory. This alcohol.
was ace-
tylated with acetic anhydride and finally
N-acetyl.44-phenylglyetine
IVa was obtained. From the above-4nentioned data follows that
the
addition product under review consists of a mixture of
2-phenyl-6--.
Card 2/3 methyl-3'j,6-dahydro-lp2-oxazine la and of
2_pheny1_3methy1_3.,6_d*hydro
Reactions of Diene Hydrocarbons With Nitroso Compounds. 2D -L,19/44
The Addition of Pentadione-1,3 to Nitrosobenzene.
-IL,2-oxazine lb with a predominance of the latter isomer. This
result contradicts the conception on the ionic reaction-mechanism
of the diene synthesis and is' in agreement with the assumption of
a radical mechanism of this reaction.
There are 26 references, 14 of which are Slavic.
ASSOCIATION: Moscow., State University imeni M. V. Lomonosov
(Moskovskiy gosudarsts
vennyy'universitet imeni M. V& Lomonosova)*
FRESEw?TED: By A. N. Nesmayanov, Academician.
SUBMITTED: April. 12, 1957. -
AVAILABLE: Library of Congress.
Card 313
AUTHOR:
Arbuzovo Yu. A. and Ovchinnikov, Yu. A. 20-117-5 24/54
TITLE:
The Synthesis of 3-Oxypyrrolidine and 3-Ox thiophane
(Sintez
3-okbipirrolidinov i 3-oksitiofana~
PERIODICAL:
Doklady AN SSSRO'
19579 Vol,-117, Nr 5, PP- 813-816 (USSR)
ABSTRACT:
At present many
compounds are known which contain a
pyrrolidine -iinge The series
of the functional derivatives
of the pyrrolidine remains, howeverp
only to a small extent
known*up'to now* After a short reference
review and a
criticism of,the known methods of the mentioned
synthesis the
authors have decided to use for this 'purpose
1,4-dichlorine
butanol whi6h.can be produced easily and with high
yields. In
the heating of butanol with okuimolecular
quantities of
primary amines in a medium of absolute alcohol
in prose.nce*of
potash N-substituted 3-oxypyrrolidine are
formed 'with high
yields. Thus 1-phenyl-, I-p-tolyl-, 1-p-
anisyl-, 1-n-butyl-, and
1-benzyl-41-oxypyrrolidine were
produced. By catalytic
debenzylation of the 1-benzyl-3-oxy-
pyrrolidine in presence of
palladiumoxide the authors obtained
3-oxypyrrolidine with a high
yield which up to 1957 was not
Car4 1/2
known. By condensation of
1,4-dichlorine butanol with 3odium
AUTHORS: Shemyakin, M. M., Kolosov, M. N., SOV/62-58-6-34/37
Arbuzo .,.W,.Onopriyenko,' V. V.,
a enshteyn, G. A.
TITLE: The Course Taken by the Synthesis of Ring A of
Tetraoyclic
Compounds (Putl,sinteza kolltsa A tetratsiklinov)
PERIODICALs Izvestiya Akademii nauk SSSR, Otdeleniye
khimicheskikh nauk,1958,
Nr 6, pp- 794-795 (USSR)
ABSTRACT: Already in 1957 the authors of this report described
the
synthesis of tricyclic compounds in which 2 rings, with respect
to thdir structure, resemble rings D and C of tetraoyclinic
compounds. The third ring, which corresponds to ring B,
contains a binary compound or a potential carbonyl group. At
present the authors are studying the possibility of synthetizing
ring A and describe this synthesis. The group CRX . CO 2 is
introduced into the initial ketone, ketone ester is
ethylated, ethynyl carbinol (formula III) Y-C~CH is hydrated
in the neutral medium and oxy-ketoester (formula II;Yzr-Ac)
is cyclized into an ox diketone (formula III; Z=:H).
Card 1 (Formula III; Z=CONHZ. The scheme has the following forms
The Course Taken by the Synthesis of Ring A
SOV/62-58-6-34/37
of Tetracyclic Compounds
x
I\C02Et
\\0
(I)
x x
1\ CO2Et / OH
Y ~-~ "-\( -1z
HO HO
(II) (III)
There are 2 references, 1 of which is Soviet.
ASSOCIATION: Institut organicheskoy khimii im. N. D.
Zelinskogo Akademii
nauk SSSR i Institut biologicheskoy i meditsinskoy khimii
Akademii meditsinskikh nauk SSSE.(Institute of Organic
Chemistry imeni N. D. Zelinakiy, AS USSR and Institute of
Biological and Medico-shemistry of the Academy of Medical
Card 21,~- Sciences of the USSR)
5 ~W
AUTHORS. Shemyakin,, M. M., Kolosov, M. N., SOY/7-1-29-6-13/72
Arburov, Yu, A., Karapetyan, M. G.,
Chamanp Te. 3..q Onishchenko, A. A.
TITLE,- Investigations in the Field of Tetra-,yelines
(Issiedovanlya Y
oblasti. tetrateiklinov). IV. Investigation of Different Syn-
theses of the Tricyclic System DCB of the Tetracyolines (IV.
Izucheniye putey sinteza tritsiklioheskoy sistemy DCB tetra-
tsiklinov)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 6, pp 183! -
1842
ABSTRACT: The structure of the well-known tetraoyclines (I) has a
speci-
fic characteristic which indicatesthe ways and methods neces-
sary for carrying out the complete synthesis of compounds of
this type. On the basis of certain theoretical considerations
the authors tried to synthesize such ketols of the hydroanthra-
cone series of type (III) and (IV) in which two rings had to be
similar with respect to structure and spatial arrangement to
the rings D and 0 of the tetracyclines. The third ring had to
offer the structural conditions for the subsequent building-up
Card 1/3 of the ring A and for the introduction of the necessary
func-
Investigations in the Field of Tetracyclines.
50V/79-29-6-13/72
IV. Investigation of Different Syntheses of the
Tricyclic System DCB of the Tetracyclines
tional. groups of the ring B of the tetracyclines. The
adopted
method of synthesizing these compounds consisted in the con-
densation of the 194-naphthoquinones with butadiene or its
derivatives and the transformation of the resultant adducts
(II) into the ketols (M) which, on their part, can easily be
hydrolyzed to give the oxy-diketones (IV). The first step,
the
diene synthesiag takes place readily by heating
naphthoquinone
with-the diene. By condensation of the 5-methoxy-naphtho-qui-
none with 2-methoxy-butadiene two isomeric adducts - (II d)
and (II e) in the ratio 4 ; I - are formed. The second step,
the selective transformation of the Cq-keto group of the ad-
ducts (!I) into the tertiary methyl carbinol grouping meets
with some difficulties, it was howaver possible to carry out
the reaction by means of magnesium methyl halide. The third
stop of the synthesis of the compounds kIV), the hydrolysis
of
the enol-methoxyl up to the keto group is only possible when
using dilute acids. The synthesis of the tricyclines (XV) was
thus performed on the basis of naphthoquinones, in which two
Card 2/3 rings are analogous with the rings D and C of the
natural tet-
Investigations in the Field of Tetracyclines.
SOV/79-29-6-13/72
IV- Investigation of Different Syntheses of the
Tricyclic System DCB of the Tetracyclines
racyclines with respect to structure and spatial arrangement.
The presence of the reactive double bond, the enol grouping or
the carbonyl group in the third ring of the compounds (XV) Of-
fers further possibilities for the introduction of
substituents
and for the building i,.p of the fourth ring of the
tetracyclines.
There are 12 references, 4 of which are Soviet.
I
ASSOCIATION: Institut biologicheekoy i maditainakoy khimii
Akademii medi-
tsinskikh nauk SSSR i Institut organichaskoy khimii Akademii
nauk SSSR (Institute of Biological and Medical Chemistry of
the Academy,of Medical Soien-7es,USSR9 and Institute of
Organic
Chemistry of the Academy of Sciences; USSR)
SUBMITTED: June 99 1958
Gard 3/3
50)
SOV/79-29-9-11/76
AUTHORS:
Arbuzov, Yu. A., Vatsuro, K. V.,
Volkov, Yu. P.
TITLE:
Synthesis of 1-Methoxy Pent.'07A_ on-3 and
Diene Synthesis
With It
PERIODICAL:
Zhurnal obshchey khimii, 1959,
Vol 29, Nr 9,
pp 2857 - 286o (USSR)
ABSTRACT:
I. N. Nazarov and I.
V. Torgov (Ref 1) obtained 1-methoxy
penten-4-on-3 on heating
1,5-dimethoxy pentanone-3 in va-
cuum in the presence of
p-toluene sulfonic acid. In the in-
vestigation under review, the
synthesis was made in a differ-
ent way: by addition of chloro
methyl ether to butadiene-1,3
under the action of ZnCl 2 (Ref 2),
the authors obtained a
mixture of isomeric methoxy chloropentenes
(I)'and (II). The
catalytic isomerization of the primary chloride
(I) under
the action of ZnCl 2 (Ref 3) resulted in the separation
of
0
the secondary chloride (II) (6oal yield); its saponification
with
sodium-carbonate solution (Ref 4) yielded a mixture
of isomeric
methoxy pentenols (III) and (IV), from which
If
Card 1A
pure alcohols were obtained on fractionation. 1-methoxy
pen-
Synthesis of 1-1,lethoxy Penten-4-on-3 and Diene Synthesis
SOV/79-29-AVAi'll,'T-6~
L
with it
ten-4-0n-3 (V) resulted from the oxidation of compound (IV).
The manganese dioxide first used as oxidation agent gave a
67~'o yield of ketone (V) which was still mixed with the
initial
alcohol. When using chromic anhydrides the yields amounted to
35-50~44 only, but the ketone was obtained in pure state, with
a glass-like residue always remaining in the distillation
flask,
which is safely to be regarded as a polymer of the ketone.
To prevent this, and to increase the pure product yield, the
ketone was extracted with chloroform, and hydroquinone was
added when drying the chloroform solution and when distilling
the ketone. The yield of pure ketone amounted to 6el~.. A
higher
yield (94%) was obtained by oxidizing the alcohol with the
pyridine complex of CrO . The condensation of the ketone (V)
with cyclopentadiene reLlted in compound (VI) (yield 76%); the
reaction of the same ketone (V) with cyclohexadiLne-1,3 yielded
compound (VII) (yield.72%). There are 8 references, 3 of which
are Soviet.
ASSOCIATION: Moskovskiy gosudarutvennyy universitet (Moscow
State Univer-
sity)
bUB?-fj September 15, 1958
arl
50) SOII/20-128-1-30/58
AUTHORS: Shemyakin, M. M., Academician, Kolosov, M. N
4rbuzov,_Yut
1, 1 ~ -A... 9
Hsieh Yu-yYan, Sheng IluaiL.3ft"., Sklobovskiy, K:'A.,
Karapetyan, M. Q., Gurevich~ A. I.
TITLE: Intermediate Stages in the Synthesis of Tetracyclines
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 128, Nr 1, PP
113-116
(USSR)
ABSTRACT: In 1956 the authors Wntbesized tricyclic ketols of
kind (1)
(Ref 1). They are similar to tetracyclines (III) as far as
the structure of two rings is concerned. In the third ring
they have a reactive double linkages in position 2,3. The
present paper investigates the addition of heterogeneous re-
agents to the 2,3-double linkage of compounds (1) for intro-
ducing active groups into their molecules. The active groups
are necessary for establishing a 1-grouping (II) in the B-ring.
and for a further extension of the A-ring of tetracyclines
by a method previously elaborated. Investigations have shown
that compounds (I) with typical electrophilic reagents such
as Hal 21 RC03 H and HOHal react readily. Thus, corresponding
_qard 1/2 halogen derivatives, epoxides, hydrine halides, and
halogen
SOV/20:-'128-1-30/58
Intermediate Stages in the Synthesis of Tetracyclines
ketones with good yields are formed. Constants and analytical
results of synthesized compounds are given in table 1. The
Synthesis of tricyclic ketols with active groups in the B-ring
made by the authors provides the possibility of building up
the A-ring of tetracyclines. There are I table and 3
references,
2 of which are Soviet.
ASSOCIATION: Institut organicheskoy khimii im. N. D.
Zelinakogo AN SSSR
(Institute of Organic Chemistry imeni N. D. Zelinskiy,
AS USSR).
Institut biologicheskoy i meditainskoy khimii AMN SSSR
(Institute of Biological and Medical Chemistry, AMIT USSR)
SUBMITTED: June 4, 1958
Card 2/2
5 (3)
AUTHORS: Shemyakin, M. M., Academician, SOV120-128-4-30165
Kolosov, M. N., Arbuzov, Yu. A.,
Berlin, Yu. A.
TITLE: Investigation of the Methods of Ring Synthesis of A-.Tetra-
cyclines - Method of Introducing the N,N-Dimethylglycine
Residue Into the Cyclohexanone Ring
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 128, Nr 4, PP
744 - 74.7
(USSR)
ABSTRACT: For a further utilization of the tricyolio oxydiketones
of type
(I), described by them, in the synthesis of tetracyclines (11)2
the authors developed a general method of transformation of
cyclohexanones (III) via keto-ester (IVa) into compounds (V).
The (Va) have a characteristic oxydiketone-carboxamide system
of the A-ring of tetracyclines (Ref 2). To build up the A-ring
itnelf in a similar way (this ring having a Me 2N-group in posi-
tion 4 (Vb)), the method of introducing the N,N-dimethylglycine
residue into the cyclohexanone ring (III) had first to be de.-
veloped, and the reactivity of dimethyl-amino-keto esters of
Card 1/3 type (IVb) had to be investigated. The present paper
deals with