SCIENTIFIC ABSTRACT ARBUZOV, B.A. - ARBUZOV, G. A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000101920008-0
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 5, 2000
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

PETRUNIN, A.M.; LDKTIONOVAt N.A.; ALITMAN, M.B., rukovoditell
raboty;
Prinimall uchastiye.- DDZHICHEVSKIY, A.S.; SHKROB, V.A.;
POSTNIKOV,
A.S.; ARBUZOV B.A.; PANTYUSHKOVA, N.S.; POBOCHINA, T.V.;
PATRUSRi~~~-
J,
Mastering the production of large A18 alloy castin s, Alium.
splavy no.lrl50-l59 163. INM 16:11)

ARBUZOV, B.A.; GORBUNOV, A.M.
Casting aluminum alloys in,permanent molds using
shen-molded
cores. Alium. splavy no.l,:160-176 163. (NM 16:11)
L

ARBUZOV, B.A.; VINBERG, L.I.; GOLUBOVICH, M.p.;
STEPANOVA, N.M.;
Ye.V.; TSAREVSKIYp N.I.
Casting into chi2l molds from wooden patterns. Alium.
splavy
no.1:182-194 163. (MIRA 16:11)

OVCHINNIKGV, Yu.F.; SOYFER, D.V.; CHIKHACHEV, O.P.;
Prinimali uchastiye:
ARBUZOV, B.A.; GORBUNOV, A.M.; XLEYNER, L.M.
- MAW-OMW
Making aluminum alloy parts with-intricate internal
channels.
Alium. splavy no.1:195-201 163. (MIRA 16:11)

ARBUZOV B A VINOGRADOVA, V.S.; POLEMYEVA, N.A.; SHAMSUTDINOVA, A.K.
Esters of 0 -katophosphinic acids. Report No.12: Structure of
the products of interaction of some aromatic 0( -halo ketones with
triethyl phosphite and sodium diethyl phosphite. Izv.AN SSSR.
Ser.khim. no.821380-1389 Ag 163. (MIRA 16:9)
1. Nauchno-issledovatellskiy khimichaskiy institut im. A.H.ButlerLwa
Kazanskogo gosudarstvennogo universiteta im. V.I.Ullyanoval-TAnina.
(Ketones) (Phosphorous acid)

ARBIU W B A - BUMENKO, G.G.; YABLOKOV, Yu.V.
Study of some polyene ketones by the electron paramagnetic
resonance method. Iiv.AN SSSR.Ser.khim. no.8-.151-1-1514 Ag
163. (MM 16:9)
1. Kazanskiy gosudarstvennyy univbrsitat,im. Ullyanova-Lenina
i
Fiziko-tekhniches1kiy institut Razanskogo filiala AN SSSR.
(Ketone s-Spee tra)

ARBUZOV.) B. A. ~
"The Michaeles-Arbuzov-Perkov-Reactions.11
report read at the Symp on Organo-Phosphorus Compounds, Heidelberg,
20-22
may 64.

.69
ACCESSION M AP4045101 S/002C/64/1581001/0167/0169
~AUTHOR; P rb
odovike A* N. UshevarRylp Et A uzov,
(Academician)
fjildrituto edntilininji Atirivdtives tif nor and ins tbsaktliC~
-2.'
.acids
SOUILCE: AN SSSR.I. :DC11t1a'dy* V. 158" no. 1j 19649 167-2691
~-TOPIC TAPS: benzenesieie'n*oio-"-metha~ryloyl. chloride,,
sel6nlum tontaini
.Ing polymer, organosolenium compound, diphenyl phosphochlorldo-
selenvatiP . pc tees ium., pota,ssluta methacrylate,
phosphorus....
'~Oontllining: polymer- -argano hosphorus. --compound
p
-ABSTRACT f - -A study-hat` b6_18if-'taa-de 0 f ~ th6l-vle
action -of benzenes 8*16661;
;iwitb M8th2CT71OY1 chl~oride, This work wits done beeauise
there are no
I
date in the literaturp on selenium-containing derivatives of
acrylic
and methacrylic acidii. The reaction vau conducted in an ethyl
ether
solution In the presence of triethylamine with the reactants
tsken.~
in a 1/1 molar ratio,v Tvo reaction products were
obtai-addt.~l-,~.,,-,~:yi,~-17-1-
4,

y-7

-A?40_4~1
0

CH

WOOD 4 Cl CO C 40 CH2-
C6119sec
CH2-

C
rE

Cq -'CH
cw
6

Al
Sec
2 15 5

" I C~Aiiii~ 4 Uti-fied-by 061 1- 1
ca ana yblso~, -tifit'att
an
Capoun a.-, 4e

and:~.Mv
iii- retiactiou. Compound I
t
~pq C roscopy i

is-s- 00 1
,
ibir Aiqoia. C6 `Yi 1e, is one
yel Mroun

that-of-r-,
third.
and 11 imrs soluble in -
:ace to a#
h

o prove the presuraed course
g1jeohol
-,
. ,
of t.
-he reaction
,
Var also' Okepared 1 iow I 'And benzeneaslenol, PrelivAinary poly
mart 1

Batton. that 1. polymex Lzes in
the presence, Of
I ike ~f
product
boaxoyl psiox doi iit OCAO a rubber-
and
,
rit
of-,.aXob1*1aobutyron1trL1e at 'to ~id b

tle polymer vitb
" ql
120~"_A25C-and, at-1000-to a_-Polymor with tap
UP
of -,60?-4640
.
~

1 -7

Cam

ARBUZOV, B.A. ; VERESHCHAGIN, A.N.
Interaction of chlorine-substituted ethylenes with
cyclic dienes
and the structure of the formed adducts. Izv. AN SSSR.
Ser. k-him.
no.6:1004-1013 Je 164. (MIRA 17:11)
1. Kazanskiy gosudarstvennyv universitet Im. V.I.
Ulliwova-Lenina.

M:Q,~ -M 4T r~
e3to
Nna
WIN,
van
Ait-W,
-1
Rrffv
AX Rp
5T_
V4a one Wi._~
rv 10
ml
ARS

ARBUZOV, ~.A.; YEFREMOV, Yu.Ya.; TALIROZE, V.L.
Mass spectroscopy of the oxides of some bicyclic
terpenes.
Dokl. AN SSSR 158 no.4-872-875 0 164..
(MIRA 17:11)
1. Institut organicheskoy khimi.i. AN SSSR, Kazan',
i Institut
khimicheskoy fiziki Ali SSSR.

ION --nRoll" Ar, ~0/64M-8/003AI03
ACCESS-

akademik; VIZELI, A.O.; SAMITOV, Yu.Yu.; IVANOVSKAYN, K.M.
Derivatives of phosphacyclopentenel S~Mthesis and structure
of isomers. DAL AN SSSR 159 no.3:582-585 N 164 (MIRA 18-.1)
1. Institut organicheskoy khimii AN SSSR, Xazen'.

ARBUZOV, B.A., akademik,, ISAYEVA, Z.G.; POVODYREVA, I.P.
St,ructure of imsaturated alcohol acetates from the reactim of
63- carane cotide with acetla anhydrlds. DoU. M4 SISSR 159
no.0827-830 D 104 (MnU 18 t1)
1. Nauchnc-issledcrv&tsVskiy khimicheskiy bstitut im. A.M.
Butlerova pri Kazanskom goaudarstvannom universiteta im.
V.I. Ultyanova-Lanina.

ARBUZOV, B.A., akademik; SAMIT07, Yu.Yu.;
TIZIE'Ll, A~O.; ZfKOYA, T.V.
Structure and certain features of proton n=lear
magmetic
resonance spectra of phosphacyclopentene
derivatives wit-b non-
sy.yrmetrically located substituents in the eyole.
Dokl. Ah'
SSSR 159 no.5tlO62-1065 D t64 (mm 1.831)
1. 1nstitut organicheskoy khimii AN SSSR, Kazan',
i Kazanskly
gosudarst-vennyy universitat im. V.I.
Ull~anova-Lenina.

ARB9Z0V, Boris Afanaslyevich; KANTOR, P.I.p
red.
[Efficient methods of preparing coated
mixtures)
Ratsionallnyo sposoby prigotovleniia
plakirovan-
nykh emesei. Leningrad, 1965. 23 P. (MIRA
.18:10)

r,
S~tracture of acetates of unsaturated alcohcds
ebtained in the
reaction of 0~-pineno oxide with acetic anbydride.,
lzv.AS
SSSR.Ser.khl.m. no.12:2144-2152 165.
(Mlp,k 18.-22)
1. Nauchno-Jss3edovaWl'Ekiy MAmIcht6kiy Irstitut im.
P,,,M,Butlercva Uzanskogo gcsudarstvennogo
universitela I-M.
Vj.U."Llyanova-I,Anina. Submittied Auguat 15, 3963~

25780
8/020/61/139/002/01,0/017
B104/B205
AUTHORS: Arbuzov, B. A., Tavkhelidze, A. N., ana Faustov, R.-N.
5 J6.
TITLE: The problem of the fermion mass in a -invariant model' of
the quantum-field theory
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 139, no. 2, i~61, 345-347
-TEXT:, A model has been studied, in which a divergence is absent and
tb e
system of fermion fields interacts with the real field vector in the
two-
dimensional space-time continuum. The model.of interaction of a
massless
fermion with vectorial m4so~ns*having a mass has been discussed iri
several
articles (V. Glaser, B. JakW, Nuovo Cim-, 11, 877 (1959); 1. Soln,
Nuovo
Cim.1 L81, 914 (1960)). It could be shown that, by using a canonical
transformati6n, this model can be transformed into a problem without
2-
interaction. Therefore, the Green function'has no boles other than p
0.
This method is applied here since the results obtained can be
compared with
exact calculations. The Lagrangian of the system under consideration
reads
Card 1/6.

25780-

S/020/61/139/9N/UIO/017
The p'r
oblem of the fbimion mass
-B104
fB20

...
~
5
,

(X)
(X) - + 'ZI (X).

'dv
(X)

2

(2)
Ighkgmn !Ak OA~ n
n A,, (x) A. (x)
n
O

X
O

21 (.X) ~(x) T-V (x) A. (x):, n, k 0,1.

W
here is the operator of.the fermion field, avid An ~tr2 the
operators of

the real field vector. The infinitely small term -X x)y
X) is now
(

50"

introduced, and the LagrAngian is written in the fox!m

.

x (X) (X) +
21 (X)

20 (X) -To (x)M (X) 'p (X)
'(3)

.
:
(X) (X) + (M (X) 'p (X)

.
'

Th
e requirement that the total of mass corrections be zero leads to the

Card

2f
5
S/020/61/139/002/010/017
The prioblem of the fermion mass ... B104/B~05
'5:'(p) is the
equation Z(p) 4 M +;E*(P) 2 2 0, where
IP2 M2 p M
total mass operator obtained from the interaction Lagrangian This
a15
equation is called thecompensation equation. Using,y-----~ e
75
and (3), it can be shown that the compensation equation is
invariant with'respect to the group of y5-invariant transformations.
For,
the compensation equation' one obtains:
9.2 2 2
mexp 2 ln(V /M 0. This relation has only zero solutions, as
2ng
follows from the exact solution of the model. The.method-described
here.is~~
applied to a two-fermion model with vectorial coupling and with'the
interac-i
on Lagrangian
2i: lg,,Tyr.* + gtin +9
If2
Card
3/6

25780
3/020/61/139/002/010/017
The problem of the fermion-mass B1 04,(B205
and are the operators of the two different spin fields. As
compensation'
equetions one obtains
'to
711, (P) Mi + T-1 (P) )P,.t 0.
.0,
X1 (P) X2 7-1141 + 22 t
(P)
where (p) are the total mass operators of the Y.and^)( fields. Th-4
system
M, X1 In + In
27tIt' MS 2AIL2 2 1
M2 50
921MS
m2 - %j In 2- + In
m2, 2aAl - ms
2 2 2 2 2
of copipensation equations is investigated Sor g /V 9 /112, g, AL 1
The
2
hon-trivial.solutions to these equations can be written with
logarithmic
Card
7,

257bU
0
02/ 10/01,7
S/020/61/1 39/0
The problem of the f ermion -mas a BI 04/B205
+ g4
accurao,y: M2 m2 ml-, ~L' exp (gs + g2l - gI,)I 4 -00)
921922-
k Aa,
fill, g1l gis + + 4e
(01 2),
7-7 g2
g2 e
+ 4g.
92,
+
2 2
wHere*,'m is, much'greater.than i and'the solution has a11
suporconductivell',~
haraciter.'-,,.: Within the' framework of,the theory.of
s-upe:rI;Ondudtiv! ty Nj~
(0 m :covodimosti
miltoniane v.teorii sverkhp on
Bogo y~ v odellnom ga
Rdmilton model in the theory of superconductivity)),..pre.print of;
Ghq Joint,,:
m IX
Institute of Nuclear Res'earch, P-511 )_Ims shown' that -for a Bardeen
Haiiltol
~mod:el, the.solution to the compensation equation.agrees
asymptoiii,cally with
.,the exact solution. e solution of,
This supports the authors' opinion that tb
Academician N. K.-
act qplution.
the compensation equation reflects, the ex
-..Bogoly-ubov ahd*A. A. ar
-Logunov- e thanked for discussions and also for the r.
interest.~in. the work.' 'There are-6 references: 3'Soviet-bloo, a*d 3
'non
n 4
K _a
-5/6' __7
dard
1 iff
N
, "O"zo

. r.. 1_

66410
AUTHOR:
Arbuzov, B. A. SOV/20-128-6-14/63
TITLE:
On the
Asymptotic Behavior of a Photon Propagator in Quantum

Bleotrodynamice
PERIODICAL:
Dokla Akademii nauk SSSR, 1959, Vol 128,
Nr 6, PP 1149-1152

(USSR~
ABSTRACTs
Papers by Redmond Ref 1 , by N.
N. Bogolyuboy, A. A. Logunov,
R
~

and D. V. Shirkoy
ef 2
dealt with the structure of the propa-

gation functions in the
quantum field theory in connection with

the condition of existence
of spectral representations. These

papers showed that taking this
condition into account means the

elimination of the pole in the
propagation funation of the

boson '2 and that additional terms
appear which are nonanalytical

for e - 0. The present paper
explains the asymptotic behavior

of a photon propagator by solving
Schwinger-Nambuls approxima-

tion equations (Ref 3). To determine
the approximate Bpeotral

representations of the. Nambu type, an
information is used, which

is contained in the generalized identAty
by Ward:

(p ?- q),G(p)F4 (p,q)G(q) - G(p) - G(q'). The first
section, of

the present paper deals with the derivation of the
approximate
Card 1/4
spectral representations. The above formula
gives information

66410
BOV/20-128-6-14/63
On the Asymptotic Behavior of a Photon Propagator in quantum
Ilectrodynamics
concerning only that part of function. G(p)(-' (p,q)G(p)l which is
nonorthogonal to (p - q). The author restricts himself to this
part, and he investigates the significance of this approxima-
tion. The above formula directly supplies the asymptotic be-
havior of F4(p,q), if p 2 >> q2 holds, or inversely; the double
logarithmic asymptotios, however, cannot be derived from it.
The.approximation investigated here holds when considering only
the one-logarithmio terms in the vertex function. Function Gr .-JG
is then separated into an orthogonal and a nonorthogonal part.
The spectral representations of the vertex functions are
derived by means of the well-known formulas:
~ V1 ()C2) + 2(X2 2 k mk_~ 2
G(p) - ~ 2 2 dX , Dmn (k) - (9mn '- 2 j D(k
0 X P i F, k
where D(k 2) ~3 (a 2)da2 holds. The asymptotics of the photon
2 2
o a - k - i&
Card 2/4 propagator is derived in the second part. An
approximation equa-
ok"'

66410
SOV20-128-6-14/63
On the Asymptotic Behavior of a Photon Propagator in Quantum
Electiodynamics
tion is derived, which contains the radiation corrections to
the vertex function and to the electron propagator. The author
here restricts himself to the investigation of the approxima-
tion equation which considers the radiation corrections of
the photon lines only. The final equation has the form
?3 e2 -,%,(Ci Am2 ) - ?3 (w d&)' and its solu-
12,2 1 e2 ln I 'J-4m 2
12(rL2 4m 2
tion reads 2
M (6)) + 4mf) + _L The
12%2 e e
V3 2 9=,m2 1) 2+ 2 2 K
In 2,=-)
121it2 4m2
propagatioh function reads DW) 2 2- 2 (T2 +
e 4m _k k 0
i - 12112 In 4M 2
In the explicit form it contains no pole, and exhibits the
Card 3/4 1~/

66410
SOV/20-128-6-14/63
On the Asymptotic Behavior of a~Photon
Propagator-in-Quantum-glectrodynamice
known form with small k2. k nonanalytical additional term thus
appears not only in the propagator D(k 2), but also in the
spec-
tral function 93 (0). The result found here is a further il-
lustration of the nonuniquenesi in the summation of a series
of
simple diagrams, as shown by N. N. Bogolyubov and others (Ref
2).
The author thanks A. A. Logunov and D. V. Shirkoy for super-
vision and for interest displayed. There are 6 references, 3
of
which are Soviet.
PRESENTED: June 20, 1959, by N. N. Bogolyuboy, Academician
SUBMITTED: June 15, 1959
Card 4/4

ARBUZOV., B.A.- LOGUVOV. A.A.; TAVKHELIDZE, A.N.,
FAUSTOV, R.W.;
1----------F~ ~POV,,IA-T.;-ZARUBMA,
I.S.[transletor]; SARANTSEVA, V.R.Y
te r *
Regge poles and perturbation theory. Dubna~
Ob"edinennyi
in-t iadernykh issledovaniiq 1962. 4 p.
(No subject beading)

ARBUZOVY B.A.; KLADNITSKAYA, Ye.N.; PENEV# V.N.; FAUSTOV, R.N.
Elastic scattering of A -17paTons and K 0 -mesons on hydrogen.
Dubna, Obtledinem7i in-t iadernykh isslehvanii, 1962. 11 p.
(No subject heading)

S/056/62/042/004/009/037
BlOB/B102
AUTHORSt Arbuzov, B. A., Kladnitakaya, Ye. N., Penev, V. V.t
Pausto~,
0
TITLE: Elastic scattering of A-hyperons and K17mesons by hydrogen
PERIODICAL: Zhurnal eksperimentallnoy i teoreticheskoy fiziki,
v- 42, no- 4, 1962, 979-984
TEXT: A'and K0 particles were obtained from interactions of
lr--mesons
with a momentum of 7-8 Bev/c with hydrogeA and carbon in a propane
bubble
chamber placed in a constant magnetic field of 13,700 oe. 20 A-p and
16 KO-p scattering events 'were selected from 70#000 photographs
1
according to energy, momentum, and co-plaharity criteria. The elastic
scattering cross sections of A-p and Ko-p interaction averaged over
the
1
entire spectrum~of momenta are (36 + 14) mb and (22.+ 9) mb,
respectively. The angular distribt:tion of Ko-mesons in the c.m.s.
has
1-
Card 112

S/056/62/042/004/009/037
Elastic scattering of B108/B102
a sharp maximum for forward scattering. The A-hyperons show a
greater trend to back-scattering. This is indicative of the
exchange
of a scalar K-meson during _A-p, scattering. There are 5 figures.
ASSOCIATION: Ob"yedinennyy institut yadernykh ist;ledovaniy
(Joint Institute of Nuclear Research)
SUBMITTED: November 5, 1961
Card 2/2

ACCESSION NR:", AP4031148 S/0.056/64/646/004/1266/1280
AUTHORS: Arbuz
_Logunov, A. A.; Filippov, A. T.; Khrusta-
lev, (). A.
TITLE: The Fredholm method in the relativistic scattering problem
SOURCE: Zh. eksper. i teor. fiz.,-v. 46, no. 4, 1964, 1266-1280
TOPIC TAGS: particle scattering, relativistic particle, particle
spin, Fredholm method, Regge pole, asymptotic property
ABSTRACT: The investigation of the analytic properties and asymp-
totic form of the amplitudes for elastic scattering of two :3pinless
i particles with equal masses, obtained from solutions fo'%~,id by
the
Fredholm method, are described. The motivation is to d(ve-.op a
method.for studying the analytic properties of the scatcering ampli-
tude and its asymptotic behavior as a function of the cosine of the
scattering angle in the c.m.s. directly, without assuming the exis-
C.,d 1/3

ACCESSION WR: AP4031148
ASSOCIATION: Ob"yedinenny*y institut yaderny*kh issledovaniy- (Joint
Institute of Nuclear Research)
SUBMITTED: 20,Tul63 DATE ACQs 071-lixy64 ENCLs 00
SUB CODE: NP M REF SOV: 008 OTHER: Oll
Card 3/3~

ACCESSION NR: AP4031150 S/0056/64/046/004/1285/1294
AUTHORS: A~~bu~zov B- A.
TITLE: On the possibility of a geometrical interpretation of weak
lepton interactions
SOURCE: Zh. ekspere i teore fizoo ve 46, no. 4, 1964, 1285-1294
TOPIC TAGS: lepton interaction, weak interaction, spinor, space
time curvature, covariance, electromagnetic interaction, vector axial
model
ABSTRACT: In order to demonstrate the proposed connection between
weak interactions and changes in the structure of space-time curva-
ture over small distances, a model is proposed wherein weak interac-
tions of leptons are interpreted as hn effeqt of space-time curvature
over a distance on the order of (G/tc)1/2 - 6 x 10-7 cm (G --
tweak interaction constant).. The main assumptions of the model is
Card 1/3

ACCESSION NR: AP4031150
that the physical four-space is regarded as some*surface with a given
metric in multidimensional pseudoeuclidean space, the geometrical
i quantities which define the surface are constructed with the aid of
spinors in multidimensional space in which the physical four-space.
is a surface, and the leptons are described by a unique spinor in
the same space. The surface goes over into a plane at large dis-
!-tances. The equations of this surface are constructed in a self-
consistent manner from the values of the spinor on that surface and
with allowance for the condition of being euclidean at infinity. A
covariant zero-mass equation is postulated, for the values of the
spinor on the surface which make it possible to introduce electro-
magnetic interactions and which yields in first approximation a
description of the weak interactions. The conditions that lead to
V
-A type weak int--ractions are discussed. The model does not con-
tain the mass, but it can be hoped that the charged-particle mass
can be obtained in a self-consistent manner from the interaction.
Some,future problems to be discussed'in connection with this model
Card
-2/3
7

ACCESSION NR: AP4031150
are indicated. "In conclusion the author is deeply grateful to N. N.
Bogolyubov, S. S. Gershteyn, V. G. Kady*shevskiy, A. A. Logunov,
V. I. Ogiyevetskiy, A. N. Tavkhelidze, A. T. Filippov, and 0. A.
nrustalev for numerous and fruitful discussions." Orig. art. has:
48 formulas.
!ASSOCIATION: Ob"yedinenny*y institut yaderny*kh issledovaniy,(Joint
Institute of Nuclear.Research),
SUBMITTED:. 30Aug63 DATE ACQ: O7May64 ENCL: 00
NP
SUB CODE: NR REr SOV: 002 OTHER: 004*
Card 3/3
------ --------
-7- -7

Ml
Mw
Inue
m
dep
rt qu4t
u c0
S. -B
04

W,,RE,S11CMG Ill) A.N.; AF(J*.UZQV,_D~,A,
Dipole moments and structure of adducts of
acryicnitrile with
cyclic dienea. Izv. AN SSSR Ser. kbiri. no-1:35-4-2
165.
(MIRA 18.2)
1. Razanskiy gosudarstvannyy universitiat im. V.I.
Ullyanova-Lenina.

A IR. b I 4-'~ G 14) li..A.;
Dipole mcjmellt!~, and the struel" re o!' addurts
with some cy.--ilk, dienes,. 1;.~v, AN Ser. hiim.
no.1:155-158
165. (i.ilruL
1. Kszanski~~' gosudarstvennyy im. V.1.
Ullpillova-Lenilla.

L 01816--67- 1VT(M)/94P(j) P01
ACC Me AP6035640 SOURCE. CODE: UR/0062/66/000/001/0104/0107

AUTHOR:
Arbuzov, D. A.; Zoroastrova, V. It 13

ORG: ccientific Research
Chemical institute Im A.Mo Butterov, Kazan, State

University.1im.
Bi;I, Ullyanov-lenin (Mimic skly Institut Kazan'skogo

gosudarstvennogo
universitata)

TITLEt Esters of Pho 1~
~c and thlophosphoric acids containing heterocyclic

radicals. ..Report
7. Reaction of phosphoric,and thlophosphoric acid chlorides

with
carbazol

SOURCEi AN SSSR. Izvdsti-va. Serlya khtmicheskaya, no. 1,
1966t 104-107

TOPIC TAGSs organic phosphorus compound, heterocyclic
base compound, esterp

organic synthetic process

fitfi6s'lze- 'esters of
N-phospo.rl
In an off ort to iy

carbazol, the authors used the potassium salt of
carbazol num

aoetonitrile as a solvent, To a suspension of oarbazol In

anhydrous acetonitrile the didlkylphosphoric aold ohlorlde was

added.
After separation of potassium ohloride from the fil

,
.trate, the solvent was distilled under vaouum. The residue

-was purified by reoryntallization from petroleum other (b.
P

40-600). The authors noted that the resulto depend to & grG&t

1
extent on the method used to proDare the oart&Zol salt. The

Sqrd 112

ACC NRi AP6032859 SOURCE 60M, 9 W66i*Qi~~1003105831039
AUTHORt Arbuzovp B..A. (Academician); Vizollp A. 0.; 1vanovskayAj,
Ko X.
ORG: Institute of Organic and Physical Chemistry im. A. Ye.
Arbuzovp Academy of
Sciences, SSSR (Institut organichaskoy I fizicheskoy kJiimii
Akademii nauk SSSR)
TITLE: Phosphacyclopontene derivatives as catalysts in the
synthesis of carbodiimides
SOURCES AN SSSR- DokladYt V. 1709 no- 3o 1966P 585-588
TOPIC TAGSS organic'phosphoras compound, imide, phosphinio acid,
phospbonio acidg
phosphate
ABSTRACT: The catalytic activity of various phospholene
derivatives were studied by
determining the rate constants of conversion of phonyl isocyanate
into diphenylcarbo-
diimide. The-C02 liberation rate served as the kinetic parameter.
In all casesp the
raaetion was first order. The following sories of catalyst
activity in the s~ethesis
of carbodiimides was arrived ats phospholonephosphine oxides>
phospholenephosphinates
oxides of noncyclic phosphines >phosphinates >phosphonates
>phosphates. Despite the
fact that the derivatives of phospholonaphosphinic acid occupy the
second place in the
activity series,, their activity is fully adequate for practical
applications. *The ap-
plicability of these derivatives to preparative syntheses is
illustrated by the high
yield of diphenyloarbodilvide from phorql isocyanate in
the-presence of I-ethmg-l-axo-,

- I ~

ARBUIZOV, B.A.; SMITOV, YU.Yu.; KITAYRV, Yli.P.
Nuclear mamietic resonance srectra of protons and
the structure
of azines and pheny3hydre zones. Izv.AN SSM.
Ser.khfiq. no.2:55-
65 166. (mm!,, 19. 1)
-1. K~jmicheskiy institut im. Aje.Arbtizo7a AN SSSR
i Kazanskiy
gosudarstvenrKff universitet im.
V.1.1111yanova-Lenina.

ARBUZOV, B.A.; ZOROASTROVA, V.M.
Phosphoric and tl-lophosphoric acid ester-, containing
radicals. Report No.7: Reaction of phosphoryl and
tMcpho6phoi-yl
chlorides with carbazole. Izv.AN SSSR. Scr.kh-Lm.
nv.l:iO4-iO7
1660 (11-f[R-A -19:1)
1. gauchno-issledovatellskiy khimicheski~y inst-tut
in. A.M.
Butlerova Kazanskogo gosudarstvennogo universit8ta
i1r, V.I.
Ullyanova-Lenina. Submitted August 5, 1963o

ARBUZOV, B.A., akademik; YERASTOV, O.A.; REMIZOV) A.B.
Spectroscope study of the tautomerism of methyl and ethyl
esters
of 4-ketotetrahydrothiopyran-3-carboxylic acid. Dokl. AN
SSSR 161
no.1:103-106 Mr 165. (MIRA 18:3)
1. Kazanskiy gosudarstvennyy universitet im. V.I.
Ullyanova (Lenina).

USSR / Cultivated Plants. Potatoes, Vegetables, Melons. M-2
Abs Jour :Ref Zhur - Biologlya, No 2, 1959, No. 6289
Author :Ar
Inst :7-onza-Agricultural Experimental Station
Title :Soaking of Seeds of Melon Fodder Crops Before
Sowing
Orig Pub :S.-kh. Povolozh'ya, 1957, No 12, 24-25
Abstract :The effect of soaking seeds before sowing on
the yield of summer squash of the Saratovskiy
3 variety and of the Volga gray variety gourd
was studied at the Penza A$ricultural Experi-
mental Station In 1955-1956. The yield In-
creased by 21 cwt/ha, when the seeds of summer
40 squash were treated with a 10% solution of
sodium chloride. Soaking In a 10% soda solution
caused a decrease In yield by 80.7 cwt/ha.
Card 1/2

USSR / Cultivated Plants. Potatoes% Vegetables, Melons. M-2
Abs Jour Ref Zhur - Bioloslya, No 2, 1959, No. 6289
Soaking of seeds of gourd in a 10% soda
solution Increased the yield by 28.3 owt/ha.
The yield decreased by 106.9 cwt/ha when seeds
of gourd were treated with sodium chloride. --
E. A. Okorokova
Card 2/2
51

'11, 0 AP v
Luku
cool.,
pabctilis AND #tOP101(ti *oil
t
~T-
(VIA& 20*
! WIR
*Obt*L ~,-Xw age
law
X" tool
Owl Aw
A S A - I L A &FIFALLUCCICOLL LOCRATURE CL.AUrICATOR be*
we III
4#3443 4t. 4.W CIA 441111011 stal4al Ov All
a 0 3 v
p is
all x a 4 a 14 11
T FA #A I I V it s *11 ~119
0 Ws 00 0 00 0-0-0-04 9--o-WO-0 6 0 9A 0 0 0 0 0 0 0 0 9

f a I o it ti is if is 14 it if if F, I it it a it
L to L-1 &.11-4,L LON t 4 It I v T i v A T, I of (A vp Lt4l t
1-1. a 1.4
f0
the deration of tissaint the wst-
Isamer-wour Of joc, when swivap"Isd by stroWn.
G. A. AtWt*V. 0AWmis Tirkhmikof: koaknomew -69
pj- 'IWI, No. 1. 37-tt.-SwIled We is-more,
tborou" twined in the first 24 bra, than umwtlk'd
let- After this VcrW the tanning factor Is the same lot wilied
.nd umwdW hides. This is cmdained as due tu the
staboshmmt of an eqW. between thi, wWic hifte and I hr V, x**
liquar. The addic We contaim a higher amPunt of M11-
bined tammides. Itis conditim is equaliud in the cowsc
of The tamd" readim. A. A. fkwhtliuxk a**
zoo
00
Igoe
CIO@
""0
iL C.(7 C- '1~
ji
u a , , 4 ; . q
bd 0
Sp tt It a K K It V( a K j, 11 (4 ,10 4 1 !14 JA I 1 4
OP 0 0 of 0 0 00 0 * 0 0 0 0 41 * 0
M - 00000 0 0 * 0 0 9 0 0 0 4)

0 09 Does qq*oi~_Oo 0-0 a

W 0 0 9 bl"

0 0 0 0 a 0 * 0 6 0 0 6
0 0 9 9 a 0 0
It 000 00 0

C4 a 0 0 a
,
j,Q
"

1.
.0
Z; :j 24 :s . L. I I uIs m
AA A 44.

J.
ss 4
!
0 2

L

-00

00

The non-$" pirtaciples Upon the
dl*m"
e1 bm*'M 41"ts
N

-00

-
.
and
At 181wil

lya
7XIT
A
Wh

.
.
*a PrOl". 1932. No. 2, 8.0; Chow,
Zes&- IOU, 1. 4(W
,9p,,,t
i
j
k

.
lle
ml
p
jjllllll~ ,l liwi."m
011-141liq weir 1twd I%Wtllrg "ith Wllllt%%

f

or Oirst" I exts. hir lannittS. 'Allb
i* lk:ll d

0
O
j

ur lo the tum.11,11,111, ji,jjjrt,j 1%11 &,he,

00 "

plinciple. thruvw1v",

1=09

hl. V..

00

zoo

00

06,

06

00

00 S

keg

0 0 0 0 0
0 0 0 0 0
4 4.0 9

0 9 0 0 0 0 0 0

0 0 0 0 0 0
1
s a 0 0 : : 0 0 0
: 0 0 0 * 0 e o 0 O

0 0 0000 go q./

'
00 09 0 o

a 0

1000*00000000*00e 0 0 0 :

11 V Is U 15 36 V a C

-1 Q At W 83

0

-k-x Ah of IX IV
A.4 r

lit A%V 'W; ('00(p$

_,,pO

00

.00

bWfi- cd Mill am-Witing
itubstances from

.00

Phw - dw AWMI11100 PIOPFfles of tausides, N.
N,

'00

'rarawnit, anti 0, _Aqtbujov_, ltwai)w 1'watral,

0
"SAMY11mol 1931. No. 2.

0
/S V- HILIPts. VatrkA (ait With
Itititt'g. 0 plor atid qtw.

bracho)-wilb)w r%t!%. shovml that owriataising chaincter.
vall Ill. Ont
"tiv of plilt ett
itil
i
1 h
t
i

'00

,
c.
l
l
l U'llig a Isin
. 4l
m.tanniag %uIntant-es deriv"t (ron pitir wpivtlat with

quebtarho-climtslut t-XU. It is statc-41 that twertanairls

410 s
ith pine cut. il du.. U. tht, low vii.lige 4-411i"1 by
tit,,

so*

tacinit, Irtmi plite tit. A. A.

-_O0

bp 0

0

-F An I I it tu
0 's a
v

,
it or 84, a a It It Itn if 1,
s 0 0 OV 0 0 0 0 0 0 0 0 0 0 IS 0 0 0 0
: :

0 0

0 0 0 & 0 0 0
: : : : :
0 o : 0 0~ 0 : 0 0 0 * : : : : : :
10 0 a 0 0

0*&0#4689000 *fee k A
013, 1 1 9 4 if It 11 it 11 14 Ira t#212112 0 N 25 is z? A 1,
it V it M b k I) ft
I I M 14 IX VV Ct ..l- -W
00
Bid-lysis of leathet. Tile system leather + water at
00 100* and Its deliendence on pit 4uriAg tuminil. A_
.4v. -1ziestiw rwittral, ;-00
Atbup
GIs St.
wK Nei 1're". 1932. No. 2. 19-Ilidr powderja which
GO rtv vat tanned with willow and pine vitts~ at p,
3 -7.h were jinv%ligalt4l. It wus fixind that the Alm. it(
00 -441d plixturt. "t Ow Ilydr.4YAJO l'onabint-11 Willi the .60
tanuide protein, I% lower than thr I.,sul A
00 tannid" its lite tanned powdert alit) bighri ibso lite imit.
'00
00 of irttvVisibly K-1)Jubbird quitstances ill lite )Alt,.r. The
iliflorlive of the- pit of the tanning oil tile rolitl Ixtuve"
IL --00
j the lannid" acid proteins in the x4id lintdocts of hydrulyst
I. Phnilar to that ill the tallurd it i, Ilighel
014 3 har willow than For pine. Tile unit. ol Uttio~% whi%716
400 is combined with the protein In the pit i4mes is ou tile
hit
si
side (J the iupckc. point of collagen and it iticrmses with
1119 a dcvrraw of It". On comparing tile cumpil. of the 9olid
it p"urts of hydrolysis and that of the tanned powdrt it
is concluded that an addid. tanning takes pl&m in tht
xne clom to Lilt imiclec. point of collagru when hcat is
'a
ied. The rtslstam~ of hide powdem to water is at &
AM
tnax. when tanning with solus. having a Ill, clo~c to the
;Utelec. point Of r(alaxen, A A. Buchtlingla
s,
A Jk1TAkLURrKAL tlltt&VVXI CLASSIFKA710M Uz- 3
too., )A.. a.0,
all 01,41, OM 0-
U S IV so J"- 14 0
K It tt It Is KID fl 1 1. 63
VO 0 0 0 0 9 411, a 0 0 # a 919 0 9 0 0 0 0 0 0 0 0 0 0 0 0 0
0 0
10 0 0 * 0 0 a 0 0 00 0 a 0 0 0 0 0 04 0 0 a e GO at 0 4 GO c *
0 so

0-41 1191~
IRV-
0 000 0 0
it fz~
z, is
U is Is it A
3 'O!t)t IV
00, A
A
0 40
SO g
00
of Zia.
so .3
00
0.0
:109 IS
. - ~ t a 1 4
W j j
OU V
11
-% " ; %)
P CK it q- k 4
e"Itip" of tm mdo of
Afbutov
A
G
l
f U&
d

.
.
.
ur
S
d
"
d of - YtH o
manvooola
101jr
ISSWOmw
h
i
o
l
N
1

-
.
.
'Suc
ra
.
m
va torr
swit
Prom.'1932, No. 2. 19-22; No. 3. 13-20.-The $1,
lA

0
c
electrode can be used in the delm. of Pii of vrgtfA

tanning
solos. and of horizontally split leather and

bid"; the acid
fractions penetrate the hides mom rapidly
00

'
than the tannides in diffusion. thus the hide and
3P"
X
'
imYc1% (11 hidr%
,
hinding the tannides. The pol, of
,
-00
is lower than that of undyed and it is lower toward

-
0
the end of the tanning operation than that of tanning
.
%olns.
When taimins with pim ext. the pw of the dyed
-.0
tap LpZr is
lower than that of the flesh side; they are

identi Ifor willow
tanning and occupy art intermediate
d
d i
l

ance
n accor
yse
;xmdtian for ask-. thew data arc ana
11
-d b
t
d

foe
er an
with the sebeine for tanning propm
y
Wilson and give a theoretical exp1stnati n of practical
results obtained. A. An Boebtlingk

CLOSoFKATIO
MITALLORIKIL
4.(
6~1 t 1
it tt
LS a 5 a
Ls to
0 0 0 0 0,41
0
0 A 0
do 111,
.1 so 4. 5 a 434
0 9

TT
:00099011111110111000966::061tot-, 0 01; 0 0 4 o 0 Is 0 0 0 0 0
-6-0-0- -0-9-6-0-47-
90 1 1 4 s a I a 1 10 sill 1114111,16 UsIll It V M 10 10 11 12
U 34 5 36 V a * 4 41 U &I a a
i'~'M ~Cc of - I to - It- j 11-0 11-1-L-r
lit A.0 1-0 (AblE11%
Potcilits A.0 1,10tot t(.1
A
041 r
:1,11 V
Arbin cut propesilesof --slat used in vats find afhante origin
G-A.-Acbmirow;- .00
04) IM'sliellif rAhloilpi: K0444MIltdot Ploi&Odsho 193z. No. 3.
35.- The 111616119TUC'k~
iin parcuthe-") of the fanning iutoinnecs in the brad vat% are:
41) %diotit .00
04) r 12) willow !,s% +r~iue 716% t64.3); (3) willow 10% +
joint- 001jo (41.5); (4) pine
0 10 4E 141.0). ib) oak 60,0 + pine 33% (6) oak (54.11); (7)
tlak 13% + pine Wrv
a =00
09) j43.0); and pine (41.0). According to I'Tmtcr-WJPA the
astringency of taunins is
given by the p. d. between the ctillsoxcii and tile tallnills.
'Illerclore the low astringency ;;o 0
oft 0 of pine tannins i, due to their low charge %hich cannot
c%nnjTn%aic fin the Collagen
charge. This causes an accumulation (if ctillaCcit charges
which clog up the ultra COD
Capillaries of the fibrils, interfering with a ftitther
diffit,lon ill the tannin. There 1,
aW, a client. explanation for the plit-invincsion, naturly: Thr
lonluttion of aCM0 as a
rttji( of (cruittilation harrier" with the lprgkv3i% loccauw.
o( all inctraw in the charge
,of tile evollagrn accompanied by decrease of tile tannin
charge. A. A. Doehilinsk go 0
skoD I
tt
i-.! A I a. S k a WALLURGICAL. LITINATURT CLAWIFICATICk
Woe
0-
U a A, to is itit .12 Kurt Ito, W A ..
0 0 0 0 0 IN 0:0
000000000000000660090000;

A fff~~Si

A
4
11 L al -A AL
_jj 1 9 1 1 1
AA 10 M 0 Itt
.11 1 let, ~P#01.6

A-

a

Utd of the Preliminary tMatmeat of Mal kides on the

410 a

fixatiott of tabstin. U. A, Arvuln, 1grestov Tstatw.

-00

V4k(h.-1JSt140TWd. ]Xji. KotA~lvftwol Prom. IM, No.

0

10-11.
*)--h0.--A preliminary treatment of limed 111,1v

-00
:
11 r

tw-der with 0.1 N JI.So. &all 0.1 N Kaolf coup" tile

-00
v0
I
9IT&VI't switiling at Pw about 4.2. The min. imelling was
i
i
h
l
3
75
A
li

0

ose to
m
nary treatment w
.
t
C
found
.
pre
"
111

0
0
410 J
V
.
COO an I N HeWs does not affect the amount of tile
0

=00

ginnides fixed in neutral win. TreatinentwitbOANNa.

4100

/Oil, followed by neutralization i-res the fitation; this

10
410

I
can be explained only by assuming fundamental changes

COO
O&V

of
the alburtin. After preliminary treatinent with Cut)
and 0.1 N 11*50.. the mialmunt of fixation for liquor%

410 a

is
at I about 6.78. After preliminary treatment with
Vk

0
00 1

son. this minimum it at PR about 4.8. Tht-me
U.
facts lead to the assumption of a shifting of the 6mlec.

0
416 2

Point of the Collagen. The changes which occur on

406

treating with COO and Na0li cannot be explained by a

migration of the hiockc. Point of the collatten. They are

Ste

d
to changes In the structure of the
Y=
=

by this treatment which Influrners it.%
.

fixation ability. A. A. Dochtlitick

&$*-ILA OtTALLLFI&ICAL Ultasvu4t UsSUFKA11c"
"F;
I -
U Is IT to It I t__F I
OT 0 11 4 9
a1 0 0 * 0 oild, we 0 00 1 10 a * 0 0 0 0 0 0 0 4
1
0
0 0 0 0 614 0 0 so *#so 00609 0 4
Uz-
LW __7_T.U I V Ile 0 a a I ar 64 S a a 3 a V
11 1
0 0 0:0 0 0 0 0 0 0 0 0 0 0 9 0 0 0 0 a 0 0
0 0 010 0 9 # 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0
tI*
too

9

1~ AM 0411 00

114 1.1
a if m a as
".1 1
J
1
4
m 611 cc DRAO
1
I
1
J
1
A-

.
.
-
.
-
-
-
-
-
vp"V , I - - . ;

04 1
Of Mills 114: "i"g. 0..,Arbuwv.,;A.
on-m
h4
a
r

s
s
A
12 2 7(11133).-Diffusion of the vegetable
tallaid
I
th
k
d
i

e
n
e lina
e
raw h
de takes place in me phase.
Other Phevornrus take place betwom the tanni(le its th

0

:
e

likle slid the colis", i. P,, on the botin-l"y between the
0
plisfus Collagen a" gohl. Them 11hem4netia may belub-

too 41:

tlivided Into (1) the thermodynamic a -wittinu (mvv"j.
d

to 0 ;
ble) of the tolmide by the collavu. due to its lly
de k
M1 I
d
2
h
ffi
rr
l
Mi
rt
er luirraetion w
q
)
(
h is
= "%
IN
ay he calh-d the fixation proem. 71P!

go

6
' s
s tam: (1) a ivIloidal ombinalkm
-- b
E

.
lows, and (2) a more ;,nKkmjKvj
~
r

b(Mtin of a che?n nalum. A. A. %whilinck
Q 43 61
7 ;11
1.11111AU111 CLASSIFACATIOP
lit's jWq
MW
O-V Ot 414L111
-L% I OA a 1 or IN s
0 u is AN -0 10 0 a it lot 9 on ft It $1 KID A I ;I6
0 0 CO 0 4 0 * * 0 0 0 0,
to
00 0 000,000069
=09
=4 0
=09
a 016
W* 0
Z;90
see
be 0

0 * 0 0 06 00000060 0 4 1 00001

6 a V 0 . - - - a
,, 11 1 "l
-*~
;

0000 641

a
a
*
0

U q it JD!
h " , , " " :2 J~ . 1,. .
11 11 "1 11

,
ir te

A

An wad appliatka of cliecked methods will assure a

Material.
Q. Arbutov. K"11AM"Flo.
!ol'u
S
S

00
v
YG Fem. .
.
I
. R. 2, MrIMI).-Ilit. f"llfite

cellulose ext. developed by the
Moscow Crnival I.Mther

-00
00 v-
Rawarch Institute knotrn as ext.
"Tt.N.I.K.P. Ni~, V'

ptptim the Weill. matter of ask ext. Thir
amount of
ol
b1
t
b
l
i

ins
u
e ma
ter (
y vo
ume)
s Prater at pu 4,.~ th2n at

i
Pw 3. Boiling acidified sulfite cellulose and oak exts,

06 '
together cannot be recommended, because a comiderable

increase
of Ps takes place on beating. Inervil,ting the
d
i

urat
on of cooking improves to some extent the diffusion

d 0 dl~
prowties of the mix(.. leading also to some lam of the

thankles. Should it become necessary to coiA itic wilt.

41*
of
4n%ulfittd oak wad the Pulfitc! crIjuhm exis. ihi% opera-

4#6
tion must be carried out in the shortest time jxwtjhIe: the

410
kettle should be charged with the solid exts. without acidi.

fication of the inixt. beforit, it is completely cooled. The

06
best rairthold of mixing is that of combining The individual

e
i
l
cats. and adjusting the pl. The diffusion of tannides

i
'r
f
from the Investigated mists. into a completely delitne-d

OD-1
raw nwerigal Is slower than the diffusion of tannicles from

an umpent Lad still move from a sulfiled ask extract.

A. A.
Flochilinsk

0

00

-.

.00
00, J; S L A
;lip S:
x(jAkLVPf.KAL i,t4#0"t CLA&SIFICA110.

1!Lg it
j- T -ir I w 1045 41
'c' 1 t1 t, 1, c. it of a 91 oc it 11 It Ef ~u'j 41

0

0

o to o S
oo** 0 0

:90 0 0 * 0 0 a All 0 0a 0
'

0 0 0 0 0 0 * 0 006 16A O
s 0

U W 4 it M ?I a a )t J~ is 0 is M
to too it .10
l'
L M a M to U
j

VO

A
k
a
A X-
4
r it aof' two !-Nvlf~

0. x L-,&.

?be bdhkwo ot VkHe "d of dMemM
"poweds
t--
lo
U
d
l
t
1ft

-00

00
ffi
w
Co
ise
w s
iest &W An" a
w
and by increased pit. Tht introduction of Fe saltz cause%
Is. 0. A. Namb.
Tonlrd
Arbuzov

09 a

,
_
lowering in the btability of the leather (lowering the
Is
lost. stiormik RaW No. elsetkity modulus). The stability is
Increased by pickling
vith Fe
f hid

-4
041
e2
6,16- (K44).-Prellmhuiry treatment o
followed by suffite crifulaw tanning with an Increase of
Malto roves the fixation of sulifite cellulaft Wiling

.00

*a
n (probably because of The cementing of the tinues).
"at a. The sulfite cellulose tanning Materialis displace
f

-0 *

a
acrease In the PU of pdfite cellukoe aning. lowers the
url
F . The greatest diuphirement (up to t stability. The lowtt
xtability is obvived at tn 4.3:
~74
d
r

S* 0

at
s,
.
at Pv 4A the displarement Is afoul v an
this is due to the highest fixation under thew condition,
6, about 20%. The Fe salts do not replare "Iffite of FrO
Th
ti
m
Wlit
i
bl
d b
l
id
l

=110111
60
s.
e
a
na
i cons
era
owere
y a
y
y
ukot conning materials from their combination with tanning with
Fe milm
of a leather which was tanned with

9* 0

,
logru. It complex Awls of the Fe with lictiosullonic sulfite
cellulose. 'Ailfitv tvllulnm final tanning lowers the
d 6 I
2

60
an
We are formed, the fixetion ot FrA at to
s water adsorption in 24 W%. of [rather tanned with Fe and
At px 4.5 there is a Sharp Increase
rably lower

00
,
increases the adompilon in a 2-hr. perW, The riperl-
In the fixation of FCA. The water resistance of bide
l
d
I

see

as -a
enta
proce
ure
s described and the resulis err tabutweil
powders tanned with Fe and sulfite cellulose Is higher than In
and Plotted. A
Rmbilinck
A

i

;r* *

.
.
of tbome tanned with pure sulfite cellulose tafts, Probably

bwause the sulfite cellulose tans affect also The Fe complex
ul-
f th
i

z
O 0

tm o
e s
combined with the collagen. The perietrat
Ate celfuloot tans is hirfeased hy preliminsrv Fe treatment
A 2):

:
i

i A S 6, 1 L A atIOLLUcOICAL UURAUXI CLASSIFICATICk CZ*

0.1 )61
r.- q . r S_-1l_11'
U a AV to Ali I't 43

SM
_"__V-?1- _* - - . - - .
1 * la An A I a aw 0 1 It so a V

0
:

0 to

0 0 0 0
0 0 0

6 0

6 0 0

0 0 so 0 0 0 0 0 0 0
0 0~ 4 Wo
~

1) Is A
" 0
,
Vn Ij A 6 A 0 0 A
- .
'
~

$ V. 11
11
1
1

OU
"
-I I U
1
~
A

GwwW Ow"I" explamt1as of diftsim sad coin.

bwavas of %am" is &M
rseRtral.

*0

MWMA
JIMU No. S, 1' 31-41 IM).- The penettation kf

6 # a'

the leather
take% place hy: 4 1)
t1Q
hV ;6t
t;
dill

00 A

t
11jffu%hn
j
j
-
1
i
II
i
4
l
h
1

IM
11, 40
6 Ins
e I
on. trinp. 6114
v4MU
n
"v
y on t

cents win appear owy in the lit *1"r of the prok-4...'
this ma txpkw 1k. s1lownt" of vat tannin
in a vin
t~ vat

.00
0 e f

g
g
and Witt one ads. In a battery with Increasing ittvnith

of the
loosial soWj convrctkM ruffrnh arr obvervNI

either In each
trassfer or In tvncu. of the vAn., orbile the

Soo

diffusion also
increases because of the difftirm-e in -ilk.

.

gr-oftbroolm.
ln&vmtaikningthebideqarenul)jeoc4I

00 J
~
10 a PhYs- treatment
shnflor to contraction and ripano,kn

gee

*0

~f a vonle and the convection currents amume a nut~w

The
capWarks formed In the conagen are

go*

carriers of the tannin
sola. The tanning ioln. form% in
th
U
h

are 0

*

e co
&M senthkermes
ir films, which, If too denie, may
prodom a dead-tanned leather
w5i
h o
ur
r
idl

!Zee
0

s mo
c
cc
y
e rap
.
i
d
i

n
rum tann
vg, TU semipermeable film famed in th~

colWen acts as a membrane
which causes opnotic dif-
fusi
n
" l
d
id
W d
h
i
d

o
ea
s to a carta
tft
e
rat
on of collagen
;
y
and therefore a contractio
of th
ill
k
hi
d

n
e cap
ar
%
s tetur
s; t

the taw** sad causes dead-lanning of the bides. 11w

fixe.4on
of tanning materials depends on the Interaction
between them and Ow collem
1. r.
on their colloWal

t~q*

,
,
nature anel dimmsios. A. A. Bow dinsk

fife
t. A

WALLOPUCAL U11W"I
CLAWFUCATICft
- I

.

-- , - I - . - -

%.)Ova 4-1

os 0 0 a I it N I a a

Ana:

Is of
,act a. .0 A
0 * 0 0 0 0 0 0 0 0 a 0 41 * 0

M

0*0000*0000000940*40 0 of 0 00004110*00,0

/
0
I

also 990006
4 s a f 0. it 0 of It 11 t4 u 1? 1$ " a llbaml%~Aum )v m )I v u
34 is lis v a Q 41 Q u 41 are
AL 2 IL L AL-A 1 -0 it '. 1_1 - A A. -1-1-AA III Q 0 tL4A_ 1 -1
L, a I j t. ~v 1-11
'am' pow-P.0tal -01~t
so
'A
t -0
-00
00
go a .00
.00
of
TU faftelvem of tamalag wM various t"des om the
r . SOMA.-IS$ last.
Kom&w"tWIIpoiw. Skwaill A~W No. 4. 12 31. 1 =00
Tanning causms a lavering in #4 bwnvaW a of
timue wW an liscremsed clougatiah, tM letter being kf
09 *4tb Increm in the nonnal perfortne of the tanning '00
%tibsualre. This phenorneum can be explained by the r
00 degree of penetration of the tannide into the hide, L411
00 A. A. Bothtlinsk
00
'00
8 - I L AMETALLURGKn LITINATSME CLAISPICATION
II..41av.
V9 leful'I wit 0- 4391 014141 O.C 'I. INGO
"M
fu : AV
(t
'D : Iele.; 11:11 -.8 ' 090 0 0 a 0 0 9 *it 0 Q a 0 0 0 r 0 0 0

1 3 6 j A I 1 9 4 11 11 U W 11 10 If " 2 21 4 a x b :j v A 21 x
is All? 'W" 041
A a I
4
fF
Itals, play" by tM 06010c relationship between tan
.04
tannide Solnainsa and 00 611111mWoms pte in the diffuslas
10
ottanaides-0,A-Albugov. .00
4 let. Ifill, X'.1how"Iml Prommi. SiNirmik R4bw No. Is. M., 41
(IBM).-Infftam of the osinodc Pmaure of the Zdatill gel
PIW
to a valise where dehydration of the ad 41025 not tgkt
tanoldes which maY cause-
does not rievilam diffusion W13911
dead tanums am used. Inctrave in the ounotle
oI tannitlo tans. does not change %bv charactef oftZEW111",
Iffatim.
fo,14mrs and timfitniction fit the get throuah defly goo
-1
Thus the oxnotk relaWnships -tweet, the gel and the
tanning Oda. are not the cause of dood tanW14- The
k osmotic "Vity is the tog
00 "'
Imilme of the sppemfxv of AT
ulation of filmit of %-&6)us (leste" 01 Ivinicalkility on the
A. A. Itoclittivsk
houndavy surface.
!see
i goo
Idnove .4-r- Abjeara .0 0.1 ONE
U a AV 00 . . -I, N,
At
0 0 0 a 0 0 0 is 0 0 0
0 0 0 0 0 0 *0 0 0 0 0

0

-'W-7
Ito it 0

10
it JL-C
JL
L
L h i L C of I IL
Z
it a a id b h it x .4 v 11 1.- 1) 14 b k v v is a i1 i1
v L
1
it m 41 Pill
-
-
--
__
-
-1 CCMAE-1.1- 1 6 f t k I

t

0 fi! Up gj KxkWg All, pop-Oks of
I-&-- A. S.

- C.. A, Aibumv anti VII.S. Almitn%*A, T%"1141.

r,
Prow. SN"llik

PAW No. 9, W-41000MM.-l" 1101ing with 0 Pule
.
du
h
d i

ra
e
n t
All&., an IwTcww In the activt CuO ins" an
j Ul tMtKIMI IfIETC11110% the tanning (Wtor, ekmptkxt !;Wtivr
111.1- W Na'.; anti 16 Iff"I'mix"I tmatttftmt ifferfamm_

plasticity of the Inther AM lowe" Ito, herskins thP 10141
CkMK4tkln Anti 1114-tidlY find Itmrr the brmb-

: strength. I*hr
atilt. III C&O that shmild 130 "Witt"Itird In ilia strength.
The l"llitl 44 off tabulated.

;.!-09
0
Hinift cow hid" 1- 4% of the wt. ol the row hillr. wilk-11 A.
A. Hophtlinnk

! :
00
t
will Sum"S to It, v. COO pew 1. at a liquM lector 1:4.
nAdual elongation Was-
d O
fi

-
w
sM mo
i As innammiled by
the blifes becom
-absoebing pailre
t
h
d

e wa
er
.
t
i ticity) an
N,&.S soln. In liming
4111411 z ON" W-1- when w-hed In a Pure

with a combinstiort W
CaO le
-

#
F

o
O
,

S AS.-SL -il-WOLKIL 1111WATkAt CL.%%iFICAjlC.

uit At K)
,
An
1
411

3
A
ov-)Ws"'b a
0see o
* *
0
~1

0
0 a
0_000 00 0 00 0 0 0 0 0 0 0 00 4 0 0 0 0 9

1 1. 1: 11 L4 is Is 12 u it a Iv v 3 it ft is if 0 J4

x 1, v u
34 a Is
v M 1. L. 41 4' 41 a a r 0

-A--" L &--A- P -9 A _I-1- AL
-1 1_4_4A, 0 -CC OR. t14A t t J. -1- .1
'. 0 A r.

6 a _1 I L,
A - 7-o o

P.C1C( its t AND vacrtal -t t -;.I

N.

-

Aseelaraled drun
WI
"Cu" 610"t, as all-
A~ A
S
Zi
ftd
a
w
b
X

nsin
no
.
.
so
"
usov,
4
p
aad)A.G.Rumaltav. TmPital."Njisck 'Issininatti. last.

KoAximmsel
Promm., Shisemik RaW.Nts. 9. V4 90MIA).

A

The litard-ociftened
anti stretched hitivs we Iiickled with

-00
90 4i

amain. of UK)%
HO, hr.' NaO anti 2r;. IICI ten the

-00

The rawitide). A chratne
ritrairl, eviritS. 1131 ON,. 0104

*0 At
1

liquid.
(on the wt. W the vislit hide) ddd. instient picklit
i
i
i

-00
00 A. .

t
,
t bin 1.5 m
n, in it) rdium
it Jutmdtkvd in two ;m)Ftions w

see

go J

Aftlic In rotetion. The hides are Plavil on ffant" for 10
12

I =00

~bfs., treated in the drum with 4% thioxidtate ton the
split

90

hides). and istaced on frames it* 20 hr.4. 11w tanning

Coo
09 .3,

with spruce ext. is carried out with three wilivt.
with 121
'
I

'00

00

selin
l liquid
tawsifts (on the wt, of the bide) anti a 4 4..
in the third main.. the IsIter tieing heatmi tti:kl'. The

too

coams. of the sohis. are 9 - 14 g. per 1. in the fit %t
phAse.

18-23 g. per 1. in the second, and 23-4 g. per 1. ka the
third.

00

The pst of the bases is regulated with N&jCOj, in the
fit%l
h
hi
d
4

2
-
goo

in the secand tip to S. anti In t
e t
r
up
pbase up to 6

to 444.11. Twitting operations. the pFvl)n. of the
vprucr

zoo

sad., atutrallution of the leather anti finiAhing arc dc-

4er"d is deLau. A. A. Bvchtfirink

~

is* 0
00j S a - S L A

tTALLURGACAL tilOWL41 (L4%j1FK&TjG1i

t I

Ire*
0:
U_ 0 11 to

-
*

a 0 it to a a a 1q u n a rt it a
Kut A f in

0 0 0 0 0 0 0
*
~
I

0 0 0 0 0 9 0 0 0 0 0 0 0 0 0
0 * 0:9 0 0 9 0 0 0 0

0 0 0 0 0 0
a

&0 00 0 0 *10

0 9 0 0 0 090 0 o o go**
0 0 04 o go *goo 4 o 0

o *
goo 0 0 ql

*:::::ego 999996 & es goo,wo-o' .*~- * -"* 0 al * '00 0-4 0 0 0
-** 0 0
4 1 4 1 a I W 11111junli litil WU345 k u a it W 41 At 41
0- L -1 6 -IL-,L-JL -L a M F 4 Ft 3 1 0 1 L All U CC CC U I I I

~A

~:7

nzatim of dw tanning visakinrials of awnstialacal sAft
bi
tion
t
il
l t

go a :--
.
o Com
nn
iti
Covulm distradc" aw 00 extrac
app
G. &--AAMMv. rindral. bvit.
-
-K=;;
lilt 1911101)
9
I P
St
ok R
b
t N
so U
o
.
o.
x0
ww
a
row..
,

v1Ih adA, crillullo, follo-ctl fly odk V%t%.,
in $pdninj

I , In. rL'birse VVI'h ';~ co"A"D alrrally coll).
n

)06cd with the rAAte cellulose tannin%, and studually di-

"Plave the trulfitir tannins with Incttwills to. till to pit 4.

In tanning with ask ext. follottred fly sulfite-celfulow ext..
00 a
the oak tannins we partially displaced from combination

with
collagen, this dispIscement being lower, the lughri
00 W
the pill
of tanning. In the final tanning of hide I)nwtlrr,.
410
tanned
with tnized solmi.. with an onk vloln., an siddill.

fixistion
ofoalt tanalm takes plam, In wbich vulfitr-crilifer-
00
tannin%
are rmt distillaved. A. A. horhtlingk
1.!
t At-$ 1, 1TALtl'RfKAL U19401,01 CLAIMPKATION C-2 - t
01~
0-1111-1 Q- lit
if 84 1 a 13 3 1
UT1 AV 00 IS V r, it ZIP It arm INITRIF WITIT if 19 441) 4 1 dad
S, 0 0 0 0 0 a 0 0 0 0 0 0 0 0,0 0 0 : 0 0 0 0 0 0 0 0 0 111 0
0 0 9 a 0 0 0 0 0 0 0 0
o 0 0 0 o'o 0 0 0 0 0 0 0 0 * 0 0 0 0 o 0 0 9~6 0 0 a 0 0 0 * 0
0 0 * 0 0 0 0 0 9
0 0 W
up*
see
roe
too
121S*6
= 00
'gee
co is
ice

6 c 0
-AL t It (34 AT u n
At,
100
lit 4t. ORDI
es
-44
Wo
'"11!4 MIll Atli JO -jAA 4111 J-1-1.1ul
11"'Illaus &Jill 111 -1811111"1 P) lu-nis",
umit litulli'l p IllillillIK41%; Jill 'Llill, - m 0-0-
it -1 .-1, Ill 11 Iva 1.-1 -111 11 It# III 1111111,11m.1 I
.1.1 1. 1 1! wolt ".q. loplowl .111 JIM.S.W
all l, :114!ut.vl J.,
IIII, In. llp,lj ~11!jlljvj lit pamMillInA
Nutillivi p1dri Al"A it allyalwip JA411.1 IIJIMIJI'lum JIJ.J
ll~l -11 "'N `-,"j 1011.1liql)
j"11010. I 'Atli Poo
-00
f)o
jp 00
00-
00-
:See
16
TT.A list
0 Ir it a w (1 0( u a to
a It 64 of It ~t It ta I I it I c k
* 0 0
Ali

APBUMOV, G. A.
X"tralization of chrom6d le r Shivinp in tho
duction of A 0. . A.1 . , , t.'..:
got lesIbU. M Ai~ljl . .
7nI(Mch rq W. I rfo 'TWW~
not. DISI., ka PrAn70M. rM. AG 104 1, No.
3, 102-81=6C IN= IQ n Ipa Pr, subitit"L4 com-1
pounded of iv4ber. fibrour materiab
caulift agents, end acc
usually contalus 75% of chronte.leather absYlar., 16% ot-4
jxmd. chr6nie leather or vcg~table-tafined fibers anti
sRN usunfly MaLle up
gf Itnterg. -The fibrou-17TRWIV
)x. 35To ofthe recipe. The purpose of this investiga
Hen was to Btu Y the, Fro,pprtics (it chrow h vin i and
s a
1 theit tffectomle klual 1y of the produrt. Ord' I e,
lin:Fly th
chmine shavingsare acid (4-7% caled. as IHI 0
jS04 an m Is
jure-ffeerwt. of the shavings). In a 1: 1 rrub
bei-shavings
tard
mli, acidity of the alm. ings In exce-sis of 2 3% re S-VUW
canh~ation com;iderably. A 4% alky. (dry_",t.~ Is) Of!
the shavitip hastens iLdcanization but the uality of the:,
prod~wt Is lowered. Low acidity (below 2%) ardlyaffects'
th te of vulcanvU d the rod t t I all of th
l InIg p '"='
rtd quatitles. e coming shavin eutrazed~'.
referably with an approx. 10/0 NatCOLsoln. nt tem
r
r
27* for 30 min. and washed ME"Training the M, soln.;
A 2-tank neutralizing unit for chronic shavitigs k degeribed.1
M. Hoseh - I

J00 gee 0 0
3 Is is W 0 4
111,411; 1' J. A. L.-RUP2_11 T u
Mi.-
00
W-lwn: L
v x 31 At 34 a
&
_~vv AND St. 4;
.00
.00
.00
-00
'00
~00
-00
.00
9900
=00
ce 0
000
goo
Sig
too
v0 0
moo
NO*
00 A

Pftparados vicaule Abort ropistant tibot water, if.
00

A. 14.
Kate and . .
, J. Applwd Chem.
A
%
M

I
(U. S. S. R.) 16.
I
O
Prench summary); cf.
so C

C. A. 37, 425P.-With Increased temp.
and duration 4A
00 a

tanning and kk(her CHIO coma., the binding
of CHO

by coda Abers tocreases; bovem. locrejoed CH.0 con.
oom

tcof kmm the fiber strength. The best mudts wffe ob.
006

-visined
with CHIO comm. of 5D j./1., XasSOj 150 C./I.,
266
l
9
d
%Ob

00 It

-
temp.
"
on
m,pH 444. Retimainswitli
.
ClIso of Ma wiaved either with ClIsOurchrume incresum

00.9

both dry wd wet Amngth, In chrome tanning. Increased

CrA
coacm.. basicity. temp sod duration ked to bigher
oo 4

Cr comm.
an tbt fibtr; aft4 chrumt tanning and w*A-

000

Ing, the fiba ollsould be neutralized by 21k. Wts.

000

Oeu

A I a - I L A a[VALLU*GKAL UTIRATI)RE CLAIMCATION
11MAJIVA ---. ----
3, u s AV 4) LSI; 99 two 64 NIMOOSAM4 312 W RA
0. dFJ4
IGO -0 0- 0 0 0 0 0 0 0 a 0 0 0 0 0 0 0 0
:'00 : : : :1: 0 0 0 0 0 G 0 0 a 0 0 a 0 * 0 a 0 0 a 0

or
r

".
m
~Jxp I.

a e r v t. a

j K_jj~_jf 2 1 t
s

0

a

-CISSIS Amp PIM11119% N(A.
1,11e
-

~ T

I-bg binding of extract
tannin by collagam. G. 1. Kutirallin and I- A.-Attlistov

,

,-
Lr(*aw ]'pass. 1946, No. 11/1". 4()-2.-*Rr oilsiect idilm
r
7

vilill" was lot slvt~ lite 11141-011
.4 .4 ligno

%I1114"Istle tanitill with vAintlell. Willi tr%lpml
I-- le-i-tall"t

-09

"I the miction of alkali, luctra-ing the pil
v4hiv o4 lite

.00

Ili ial lannilic .4.1. decream4l lite
pefeelklitize -4 "Ir.

Irvorstilgy lwtlll.l in'tttill" (1),
defille'l 4. taullm IrlAilk'A

4

after 20 wakliluss vOth tibld. MO. Ilw twwrilialtes 1.1 1

ti-milting ft~"ki t4smaltr at fill 2 4), 3.4, still At

24.5, and
18.4, tv4jo., when lite tmunt Itithri A, %441

mithout dryirts.
These valit" wetv nist

c1lanxed fly dryinx previom-i to wa,hing
2,04, *list

P.I.M. After tteatmvit %ilh vmv- 11A.4 N Ns,120,

200

f-m 48 hm at with i-mabmal Iiakitig. I,v

ro

.14%flitilt, %ill% 11,0, thr liefccutAlc~ .4 44"11111

e

setaitied blvfva~l ill. 1.11 vaille rulpf"Yol ill tatillills

MN,
8.3, still VIA% GIC UndtiCd tratliCtIs UlMed at $ill

z*o

2.11. 3A aild IM), F"P.). li'Aht" file
shicil leatim-ts were 4.3, 7A, mill V] 1`~. lNilike title

verrial4t, tarmills. which Ric, fit part. e(1111141t4NI "Ievrf.

%H,Iv" IlY vtOmpris 0 v parl is( the talmill I% Irlilt'vol I-v

1110-mixed washing) ail 'd Ilie HIL'I'~111f,1114tv 1,41111in 1%

0 0

txmnd imveNtily. The absence of a revcr%ittly lk"ind

tannin
fraction In Itather lanned with ligumulfonstic ill

eliplosinod
fly (1) the weak callacity of livimullmlate Intl.

stin fnr
MIr4dal ctmatilation on the mufave of 111v '44141rn

iboo

rimurnis
still (21) lack is( Iguillsig sit lisn-tith"ik achl %iih

lwlvliilr minip, hir If l."sd* wAillit fit the trisitivr
waivily

9

slid wide distser-Al"I Ill pliellMe Oil xm1p* in
fillit.111.

boo

.

lonate "tticles as mulms"I with velristur
lailmill'.

W. R. Ilroin
94

%vow 111VI%flit"

too". so.4mv

Or

G%v Obt 1111114ml

' "
u S Aw

-
;
Is I ; a, ' U L I a list 0 a 4 '1 w In a a a
it a M It cc it IN ff It a WA A I .
' ;

-I

1

.
.
0 0 0 0 0 0 0 0 0

0 0 0 0 0

0
0

lsoeaei= U po-mt d ccliaLon. C,. A- Af' i.-.,v. Aa~:,,

PAVLOV, N.N., inzb.,- ARUZOV,. G.A... doktor
teIh,-nauIr,,. prof,
Modification of polyamide with chromium compounds.-,
Report No.l.
.Izv. vys. ucheb. zav.; tekh. leg. prom. no. 1:24-29
160.
(MIRA 14:5)
1. Moskovskiy tekhnologicheskiy inatitut,legkoy
promyshlennosti.
Rekomendovana kafedroy tekhnologii iskusstvemoy
kozhi.
(Folyamides) (Chromium compounds)

PAVLOV, N.N.., inzh.; KUZNFTSOV, A R., inzh,; ARBUZOV,
G.A.y doktor tekhn*
nauk,, prof.- I - -
Complexometry of trivalent chromium. Report No.l. Izv.
vys.
ucheb. zav.; tekh. leg. prom. no. 1:54-59 160. " (MIRA
14:5)
1. Moakovskiy tekhnologicheskiy institut legkoy
promyshlennosti.
Rekomendovana kafedroy neorganichaskoy i
analiticheakoy khimii,
(Chromium-Anaiysis)

PAVLOV, N.N., inzh. :- ARBUZOV,,.Q-.At, doktor tekhn.
nauk, prof.
Modification of polyamidem with chromium compounds.
Report
No* 2, Izv. vys. ucheb. zav.; takh. leg. prom,
n6.2.-15-24
16o. (MIRA 13:11)
3
.L. Moskovskiy tekhnologicheskiy institut lagkoy
promysholannosti.
Rakomandovana kafedroy takhnologii iskusetvannoy
kozhi..
(Polyamides)

PAVLOV, N.N., inzh.; KUZNITSOV, A.R.,
inzh.;---AR8UZOVT-G-L.,-doktor
takhn.nauk, prof. .
Oomplaxometric aaalysis of trivalent chromium. Report lip. 2,
Izv. vys.
ucheb. zav.; takh,legs prom@ nos2:55-61 160* (HIRA 13:11)
1. Moskovskiy tekhnologichaskiy institut lagkoy
promvablennosti.
Rakomandovana Imfedroy neorganiabaskoy i analitiabaskoy khimii.
(Chromium-Analysis)

PAVLOV, N.N., inzh.; ARBUZOV, G.A., doktor
tekhn.nauk, prof.
Using chromium compounds for the modification of
polyamides.
Report No. 4. Izv.vys.ucheb.zav.; tekh.leg.prom.
no.4:31-38
l6o. (MIRA 13:10)
1. Moekovskiy tekhnologicheskiy institut legkoy
promyshlennosti.
Rekomendovana kafedroy tekhnologii iskasstvennoy
kozhi.
(rolyamides) (Chromium compounds)

2101
S
S 61/000/018/027/027
081~
/ I
15.8150 B101/B147
AUTHORSt Pavlov, N. N., Arbuzov, G_ A.
TITLE: Change of properties of films of polymers containing
hydroxyl or carboxyl groups by chromium (III) compounds
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 18, 1961,
589, abstract
IG',,5z;6 (Nauchn. tr. Moak. tekhnol. in-t legkoy prom-sti,
no, 17, 1960, 29 - 34)
TEXTt A preliminary study was made of the modification
process of poly-
vinyl alcohol (PV) and polyacrylic acid (PA) by Cr3+
compounds. A
specific interaction was found to take place between the
polymers
mentioned and the Cr compounds. The properties of PV and
PA change
significantly when Cr salts are introduced. The modulus of
elasticity of
PV films increases. PV films containing strongly basic Cr
chlorides or
Cr succinates, acquire a certain water resistance.
Introducing Cr salts
into PA enables the latter to form films. The results of
this preliminary
study show that it is possible to obtain new hydrophilic
products differ-
ing from the initial polymers in their properties.
betracter's note:
Complete translation] V~
Card 1/1

PAVLOV, N.N. assistent; HUZNETSOV, A.R., assistent;
ARBUZOV, G.A., doktor
tekhn.nauk, prof.
Quantitative analysis of chromium (III) in the
solutions and Mms
of high polymers. Nauch.trudy MTILP no.18:~1-47 '60.
(MIRA 15:2)
1. Kafedra neorganicheskoy i analiticheskoy khimii
Moskovskogo
tekhnologicheskogo instituta legkoy promyshlennosti.
(Cbromium--Analysis) (Polymers)

PAVLCYV, N.N., inzh.; KUZNETSOV, A.Rvy inzh.; ARBUZCV, G.A.y
prof.9 doktor
tekhn.nauk -
Studying the stability of aluminum (III) complex compouncTs.
Izv.
vys.ucheb.zav.; te"leg.prom. no.2:22-28 161. (MIRA 14-5)
1
1. Moskovskiy tekhnologich6skiy institut legkoy
promyshlennosti.
Rekomendovana kafedroy neo6anicheskoy i analiticheskoy
khimii.
(Aluminum compoupds)
I

8/08 62/000/01 6/026/043
B168YB186
AUTHORS: Pavlov, N. N., Arbuzov, G. A., Panteleyeva S'.
TITLE: Investigation into the effects of adding aluminum and iron
(III) salts to polyamide films
PERIODICAL: Refera'tivnyy zhurnal.' Khimiya,'no.,16, 1962, 520,
abstract
16P50 (Izv. vyssh. uTchebn. z .aKedeniy. Tekhnol. legk.
prom-sti, no. 3, 1961, 20-25)
TEXT: The effects of FeCl 3F AM 3 and CrCl 3 on-the properties of AK
6.0/40
polyamide films were investigated vi 'th a vie* to using-polyamides as
finishing material and in the production of leather. The films
obtained
were subjected to mechanical and thermomechanioal tests', and their
permeability to steam and solubilfty in ethanol were also determined.
it
was found that s'alts of Alt Cr.and Pe affect the mechanical
properties
(by increasing the softness and elasticity) of the polyamide and their
-FeCl < AM < Crel
order of. increasing modifying action is given as; 3 3 3'
Polymer films retain their solubility in alcohol both before and after
Card 1/2

S/032/61/027/002/022/026
B120201
ALVIIHORSs Arbuzov, G. A., Kuznetsov, A. R., and Pavlov, N. N.
TITLEs Apparatus for the titration of dark-oolored solutions
PERIODICALt Zavodskaya laboratoriya, v. 27, no. 2, 1961, 225-226
TEXTe A special apparatus (see Fig.) has been worked out for those
cases
in which it is difficult to establish exactly the color changes in
the
point of equivalence in the presence of intensely colored
admixtures or
when the c9l 'or change of the indicator in the end point of
reaction is not
sufficiently clear. A certain volume of the analyzed, dark-colored
solution is poured into the 250-500 ml round and flat-bottom flask
1 which
resta upon the electromagnetic mixer 2. The titration takes place
by
intensive mixing, and, if necessary, also by heat treatment. A
parallel
beam from light source 3 is passed through the titrated solution,
and
forms a colored spot 5 on the screen 4. The end point of titration
is
determined by the clear change of the color spot, which is by far
better
observable compared with ordinary illumination. Contrasts can be
accentuated in the color change of the spot by way of color
shifting,whieh
Card 1/3

S/032/61/027/002/022/026
Apparatus for the... B124/B201
is brought about by placing an appropriate light filter 6 in the
path of
the light beam. Thus, e.g., it is suitable to use a blue filter for
the
transition from red to yellow, whereby the color changes from
violet to
green, which is visually easier'to detect. When the color change of
the
spot is masked by admixtures, color shifting can be attained either
by
illuminating the spot on the screen by a secondary light source or
by
means of a colored screen. In the latter case, the color of the
filter
or of the screen is complementary to the color of the masking
admixtures.
If, e.g., the admixtures are blue, filter or screen must be yellow.
No
light from other light sources must hit the screen. The procedures
described were applied by the authors to the trilonometric
determination
of trivalent chromium (Ref.1). The Trilon excess in the titration of
chromium is bound by a nickel salt, whose excess is titrated with
the
same Trilon B solution in the presence of murexide. The color turns
from
yellow over orange, red, and red-violet to violet. The color change
of
the indicator in masked by the dark-blue color of the chromium
complex.
When using the apparatus and a blue light filter, the color of the
spot
on the white screen turns from yellow over red to pale blue. The
latter
color change is abrupt, which fact simplifies the visual
determination
Card 2/3

2
S)1032/61/027/002/,022/0 6'
20201
Apparatus for the#** B1
of the end point of*reaotion, and reducesthe error of the
determination.
1 The point* of~equivalenoe exactly corresponds to th-Is transition.
When
using the device,described it was possible to reduce the determination
error from 5 to about 0.5%- The'ohromium content in the sample was
.32-3 mg, and the-Trilon consumption was 5.96 ml.- Abstracter's notet
This
is a full translation]. There are I figure, 1 tab e, and 1
Soviei-bloo i
reference.
ASSOCIATIONt. Moskovskiy tekhnologicheskiy institut legkoy
promyshlennosti
(Moscow Technological Institute of the Light Industry)
i -.-Car.d-3/3-..-

MIAMI
AnUZOV G A prof., doktor tekhn. naukj AFANASITEV, A.A., dote.,
kand. tekhn. nauk; YEGOROVA, Te.A.; KARZINKINAI K.D.;
KAMVAt A.A.; MURVANIDZEp R.M.1 MIXHATLOV ~,A,N., prof.,
doktor takhn. nauk, red.j KACHKO, I.L., inab., red.1
L.L., red.; YURCHENXO, D.I., red.;
MIKHLINt E.I.t tekhn. red.
(English-Rassian leather and footwear dictionary,] An -p-
rupskii koshevenno-obuvnoi slovarl. Pod obsbobei-reCt
A.M.Mikhailova. Moskvav Fismatgis, 1963. 402 p,
(MIRA 16:7)
(Leather industry-Dictionaries)
(English language-Diationarise-Russian)

CHESUNOV, V.M.; NAIJMOV, V.N.; XUZNETSOV, A.R.; ARBUZOV, G.A.
Apparatus for gas chromatography in the artificial leather
industry.
Kozh.-obuv.prom. 5 no.10-.25-29' 0 163. (KRA 17:4)

KUZNETSOV, A.R.; ARBUZOV, G.A.; YEZHOVA, T.I.
Quantitative determining of metals in films made from
SKS-30-1
latex. Kauch. i rez. 22 no.501-53 My 163. (MRA 16:7)
1. Moskovskiy tekhnologicheakiy institut legkoy
promvshlennosti.
(Metals--Analysis) (Resins, Synthetic)

KUZNF,TSOVt A.R., inzh.; PAVLOOV, N.N., kand. tekhn.
nauk- ARBUZOV G.A.P
doktor tekhn. nauk, prof.
Use of barium salts for ion. precipitation from latexes
of
carboxylate rubbers. Izv. vys. ucheb. zav.; tekhn. leg
prom,
no.205-59 163. (MIRA i6:10)
1. Moskovskiy tekhnologicheskiy institut legkoy
promyshlennosti,
Rekomendovana kafedroy tekhnologii iskusstvennoy kozhi i
plenochnykh
materialov.

ARBUZOV. G.A., IOJIi. j-,aixk, prof.; !".U'-x-'
tk'g" ~~'-w5746~' .. .... ...
ii r --ji Pep -t '~o.S: FcrEaz., on
of rlixel In solut-*L'n:S.
liaucli. :.r-,xly P'll-IT t 63. (NJILA .17:1-1)
1. KaCedra
;,.C,-7 promy--. -rnooti