SCIENTIFIC ABSTRACT USANOV, V.V. - USANOVICH, M.I.
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CIA-RDP86-00513R001858110016-0
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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- L 10895-67
AM---
AUR6033804 SOURCE CODE: UR/0124/66/000/007/130-il/BO41
AUTHOR: Usanov. V. V.
TITLE: Some problems of averaging gas flows
SOURCE: Ref. zh. Mekhanika, Abs. 713317
REF SOURCE: Tr. Vses. n. -i. in-ta kriogen., RiBlorodn. -i kompressorn.
mashinostr., vyp. 10, 1965, 90-104
TOPIC TAGS: gas flow, flow velocity, averaging
ABSTRACT: A theoretical study has been made of the problem of applying a
one-dimensional model to various cases of gas flow. It is shown that any
averaging of parameters inevitably leads to the loss of some of the propel-ties
of the gas flow. Therefore, it is necessary to make a thorough analysis of errors'
resulting from each specific method of averaging. It has been shown that at a
great population of the velocity profile, the field coefficient exhibits a weak
dependence on the law of averaging of velocities. The application of equations of
a one-dimensionnl model, in this case, results in an insignificant error when
determinin the velocity. Bibliography of 4 titles. Yu. A. Lashkov. [Translation
Of abc-*ract
Card l -61~ SUB CODE: 13
GANDFLISMANp P..F,., kand. takhn. naukj MANOV,-1-ty.-P Inzh.) NAUPITS, I.N.,
inzh.
Now data an heat exchange and hydrodynamic resistance In the
nearsonic region of a-gas flow. Trudy VINNKIMH no,10:105-
114 t615. (KIRA 18,-9'1
/T
-ACCIM ------ A136021708 SOURCE CODE- Ult/01,18/66/000/003/0136/0139
AUTHOR: Usanov, V. V.; Postnikov, V. S.; Burmistrov, V. N.
ORG: Voronezh Polyteclmic Institute (Voroiiezhskiy politekhnichoskiy institlit)
TITLE: Certain features of martensitic transformation in steels of the auBte-nitic-martensitic
class
SOURCE: IVUZ. Chernaya motallurgiya, no. 3, 1966, 136-139
TOPIC TAGS: martensitiQ transformation, austenite steel, martensite steel., torsional
vibration, internal friction', metal grain structure
AVSTRACT: This is a conUnuation of previous investigations (V. S. Postnikov et al. Izv. VU2~!
Chernaya metallurgiya, 190, no. 11; V. S. Postnikov et al. Sb. InsbLuta 3etallurgii im, I
Bziykova, "Issledovaniye staley i splavov, " Jzd-vo "Nauka, 11 1964, 361)., with the difference
th-
pt it deals with certain features of the co"rse of j - NM transfo mation in zustenitic steels of
transition class, as determined by tests of internal Kcalstivity, and magnetometry
t4q,
a* dilatometry in the process of cooling. 'Peso steels, conditionally'denoted I and 2, con-
t4" 0. 0 7 and 0. 0 8% C, 16. 8 and 15. 9 8% Q, q and 1. go and 3. 087o Mo, respeci
P r~ 5.35 and 5.35% N1,
tilqely. In all tests the specimens were heated to temperatures Ton of the onset of martensitic
C
- le*_ I - __ __UDC_-~669_26124128:669. 011. 7_
NRc AP6021708
o"transformation (750-1000*C) for 20 min, after which the corresponding curves of cooling were,
',.plotted at -6 deg/min. Findings: the peak of Internal friction, as determined with the aid of~,
a torsional pendulum, consists of a principal peak A and a secondary peal: B, the latter
~detcctable during careful measurements of internal friction in the process of cooling below
the temperature of the principal peak (Pi--. 1). Curve 3 (Fig. 1) shows a change in tl height
ic
of peak A* on increase in frequency f rom U. 4 to 16 cps: the increase in f requency f rom 0. it
to I cps increases the height of the peaks but any further increase in frequency (to 16 cps)
reduces this height sharply. With increase in oscillation amplitude the peaks A and B get
displaced into the region of higher temperatures; then the height of the peaks (and particu-
larly of A) sharply increases (Fig. 2). The sharp increase in the internal friction of
au *stenitic steels in the temperature range of 120-160*C (Fig. 3) during their cooling from
normalizing temperatures is due to y - Al transformation. Tbus, the highly sensitive
internal-friction tests reveal the existence of a double y - M transformation due to the
inhomogeneity of the grain composition of cold austenite; this could not be detected with the i
aid of the other physical tests used in this investigation. The nature of the peak B and the
mechanism of y - M transformation are as yet unclear.
L
ACC NRs AP6021708
Fig. 1. Frequeneydepen-
Jence of the height of in-
ternal-friction peak for
steel 2 (3) and its position
Dn the temperature scale
when:
I - vl = 1 cps; 2 - V2 16
cps; Ton 850*C
IV Oow
IJO tqo
120 120 1
go
kV
60
go 10 -
j0 / jolt
4 6 1 30
time, min
Fig. Z. Variation iii the curvo of Internal-friction peak
3
for steel 2 when Ton = 850*C and v = I cps, as a function
of;
a -isothermal exposure; b - isothermal variation in in-
ternal friction
1, 41014-6-6
ACC NR- AP6021708
Orig. art. has: 4 figures.
Fig. 3. Amplitude dependence of internal-friction
peaks ALnd B for steel 1 when Ton = 850*C and
v 1. 2 cps:
I il = 0. 3 kg/mm2; ?. - -T 2 = 2. 5 kg/,,mm23 - T3
3.3 kg/nlm2
SUB CODE: 11, 20,13/ SUBM DATE: 18Jan65/ 01UG REF: 005/ OTII REF: 002
h9
t
ACC NR: AP6030180 SOURCE CODE: UR/0-~~48/66/00()/CO5/01"/()1,4cj
AUTHOR: Postnikov, V. S.; Sharshakov, i. M.; Usarov.9 V. V.
ORG: Voronezh Polytechnical Institute (Voronezheskiy politekhninhes~dy institut)
TITLE: Amplitude frequency dependence of the internal friction of certain steels
SOURCE: IVUZ. Chernaya metallurgiya, no. 5,
1966, 144-11,6
TOPIC TAGS: internal friction, austenite transformation, plastic defarmation,
carbon steel, chromium steel, nickel steel, torsional vibration/50 carbon steel,
Khl7N5M3 chromium steel., Khl6N6 chromium steeV Khl6NI1 chromium steel
Any measure' of internal fricti4~'s understandably divided into
ABSMACT-
two com~;onents: amplitude-independent and amplitude-dependent. This
,division is arbitrary since these forms of internal friction usually over-,
lap one another and likewise can be interrelated.
In connection with contradictory experimental data relative to
the frequency relationship of the contributions of both types of internal
friction and the almost complete lack: of these data for low-frequency
tor'siol i'vibrations, the present rescandp was un' bon steel
f! ~,ertaken. 9k.- .-.------
50~and chromium-nickol steels KIMN51M311'~KhIGN6) CL.1d KhlGN11-i~ero u_s'6d_.
~_he into-rn-wf,-f~*i-~-iT~,n---w"a-s- -measured on'- a torsion pendulum on hpecimens I mm
.in diameter and 100 mm long. The shear strain amplitude was measured be-
tween 3.. 10-5 to 8 . 10-4 and frequency from 0.4 to 18 cps. Recording of
data at low frequencies was done visually but at the high frequencies with
an N700 vibration oscilloscope.
Card 1/2 UB;C: 669.15!530.67
L V'927-~6
ACC NRt AP6030180
Before measurement of internal friction all spocimens were ann(.-aled
in a closed quartz tube at 10500C for 4 hours. The Cr-Ni-steel ap-,cimens
were later subjected to normalization at 800-11000C and the nteel 50 speci-
mens were quenched in water from 7400C.
Resulting data were in agreement with results obtained by others.
The increase in shear strain amplitude to 1-2 , 10-4 does not change the
value of internal friction. Further increase in the shear strain ampli-
tude leads to an increase in internal friction.
The increase in internal friction level with the normalizing tem-
perature decrease is'associated with the transformation of austenite into
martensite and their different inclination to plastic microdeformation.
The increase in vibration frequency of the specimen from 0.4 to 2.5
cps for steel Khl7N5NI3 (and KhM,411) and to 4 cps for steel 50 does not
have any noticeable effect on the internal friction components. Further
increase in vibration frequency of the specimen increases the internal
friction whereupon the greater the shear strain amplitude the sharper the
increase Ln internal friction. Orig. art. has! 4 figures. [Jnt5: 36,7741
SUB CODE: 11, 20 / SUEM DATE: 17Dec64 / ORIG REF: 006 / GTH FSF: 006
AZAROV, A.S., kand. tekhn.nauk, dots.; ~P~ 0V,,,Yq,,A.I,,-,inzh.,
retsenzent; KUREPINA, G.N.,, red.iii-va; DENINA, I.A.,
red.izd-va; LEYKIIIA, T.L., red.izd-va,- SMUCESYXIA, CIV.,
tekhn. red.
[Mechani7ation and automation of technological Processes
in the machinery industry] Mekhanizatsila i avtoiratiza-
tsiia tekbnologicheskikh protsessov v mashinostroenil.. Mo-
skva, Mashgiz, 1963. 414 p. (MIRA 17:2)
SIMONOVAP N.I.; USANOV, Yu.Ye.
Synthesis of 4-methyl-l-phenyl-3-pyrazolidinone (phenidone "B").
Zhur.VXHO 7 no.2.-239 162. (MIRA 15:4)
1. Leningradakiy InBtitut kinoinzhenerov.
(Pyrazolidinone)
BLYUMBERt'j, I.B.; DIMITMOV, R.V.; USANOV, Yu.Ye.
Kinetics of the r1rocesses of high-speed de7elopinp c--'
crraphic materials. Zhur. nauch. i prikl. fat. i kin. 9 no.5:
336-341 S-0 t64. (MIRA 17:10)
1. Leningradskiy institut kinoinzhenerov (LIKI).
BLYUMBERG, I.B.; DIMITROV, R.V.; USANOV) YU.ye.
Investigating the temperature dependences in high-apeed
Zhur.nauch. i prikl.fot. i kin. 9 no.6:405-410 N-D 1644
(MIFA 18:1)
1. Leningradskiy Institut kinoinzhenerov.
N6PFLOVAJ, G.L., nauclin. red.; USAl'.OVA, A.p nauchne red,
[New finishing materials and the nechRnization of the
processes of furniture finishing; materials) Novye otdeloch-
nye materialy i mekhanizatsiia protsessov otdelki mebell;
materialy. Moskva, TSentr. in-t tekhn. Informatsii i ekon.
issl. po lesnoi, bumazhnoi i derevoobrabat,-vaiushchei pro-
myshl., 1963. 43 p. (MIRA 17:7)
1. Soveshchaniye rabotnikov mebellnoy promyshlenn( ti na
temu "Novyye otdelochriyye materialy i mekhanizatsiya pro-
tsessov otdalki rebeli.11 Moscow, 1962.
KORSIHM.,'L.L.; NOTKIN, M.M.; STRADA, V.Yu.; TSVETKOVA, L.F.;
KIMRYAKOV, E.A.; US-ANOVA A.P., red.
[The IINKII nitrourea coating Nitrokarbamidnaia gruntovka
IINK" Moskva. TSentr. nauchno-isol. in-t informatsii i t-3khniko-
ekon. issledovanii po lesnoi, tselliulozno-bumazhroi, derevo-
obrabatyvaiushchei proUishl. i lesnomu khoz., 1964. 15 P.
(MIRA 17:12)
1. Vsesoyuznyy proyektno-konstruktorskiy i tekhnologich3skiy
institut mebeli (for Korstrun, Notkin, Strada, T.Svetkova).
1. Mebellnaya fabrika No.7 Sovetu riarodnogo khozyuystva Mo-
skovskogo gorodskogo ekonomicheskogo rayona (for Klmryakov).
I
BAIASHOV, V.I., podpolkoiWk meditsinskoy aluzhb - USANOVA, A.V.
~1'1
Influenzalike form of food toxinfection. V&e-n~~ed-.-zhun-nd-.4:86
Ap 160 a (FOOD POISONIM) (yj?.L 1r. -L 11
BALASHOV, V.I.; ARGUNOV, R.S.; SOKOLOV, I.A.; ROGOZHIN, V.A.; WAWjA,-AY-
Outbreak of food toxicoinfection caused by two types of Salmonella,
Zhur.mikrobiol., epid.i immun. 32 no.12:114 D 161.
(MIRA 15:11)
(FOOD POISONING) (SALMDNFLLA)
UM/Slectricity - Conservation mac 19 47
71ael - Conservation
*Rationslizing the Consum-ption of Fuel an& Elactrica'L
Pover," V. G. 'UsanoTa, QlavVostokftergo Heft, 4* Vp
"thergeticheskly Byull" No 12
Patimal use of fuel and electridal power wat la-
portant for the national economy. Most interesting
one-page table gives relative consuaption and noms
not for various enterprises. Table taken in ftml
and alectric pover. Also gives table showing
average expenditure of electric power during drIU-
Ing operations. Author states that for most advan-
Ic
50TIS
DSM/Electricity - Conservation (Coutd) Dec 1947
tageous use of electric power, equipment must per-
form at opti-, and new more efficient methods
should be adopted as soon ae'possible. 1PIgures In
tables for 1945 through 1947.
V'; V" Zr.- a
I'lur,,inal Tr3-atm3nt of Yibrom.l,lorjas." For
of Cand. -!diral S,i. 3ub 2.1. ""1
~IuqL Cor t-li'l A "r
Olyslclarls
Swrnary 71, 4 S-L) 52. j is s,~rtat ions
"rosented for 1jagrces in Sciancc and
-ng,m~erLngt in "Ibscow in 1~50. k rom
Va-chernyaya vloskva, Jan-:7e-cl~5(-]
L
USSR/Medicine/Biachemistry - radiology
Card 1/1 Pub. 17-11/23
Author : Usanova, M, I. and Shnol', S. E.
Title : Distribution of tagged coffeine in the animal organism, and its
transfer from mother to embryo
Periodical : Byul. eksp. biol. i med. 7, 41-44, July 1955
Abstract : Author investigated the progress of tagged coffeine in the animal
organism, dynamics of its transmission from mother to embryo, and
methods of its administration by experiments on rats. The rats
were &iven 1 ml of an aqueous solution of coffeine with radio-
active carbon C14 by subcutaneous injection. The coffeine was
found in all organs and in the cerebrum - in pregnant rats also
in the placenta and the tissues and organs of the embryo. One
hour and 40 minutes after administration radioactivity can be
observed simultaneously in all organs in the following order:
kidneys, liver, lungs, cerebral hemispheres. (Distribution in the
central nervous system will be taken up later in more detail.) 4
references, 2 USSR, 4 since 1940, graphs
Institution : Chair of Obstetrics and Gynecology (Head: Prof. F. A. Syrovatko)
and Chair of Medical Radiology (Head: Prof. V. K. Modestov)
Central Institute for the Advanced Training of Physicians, Moscow
Submitted : 24 may 1954
L 4482-66
ACC NR, AP5024651
6
muons mW 10-15,nuons/cu2 sea sterad B*V for 10 BoY mumts. orig. sirt. bass 2 figures.
stn3 omi xpl ovem vAnt 00/- . ORIG Oll 001/ OM MIPS 000
k -6c)
C.,.d 2/2
CHEIMOBLIMUSKlY, Yu.~I.j ZUWOVA, S.N.1 USANOVA, S.D.; AFANASIYEVA, L.V.
a
Study of the suspemion effect. Koll, zhur. 27 no.5:780--~/93 ^-o 65.
(MrRA 18:10)
1. Leningradakiy universitet, imeni Zhdanova.
KALYAYEV, A.;-USANOVA, Ye.
"Laboratory Mlethods in Soviet Sanitation Practices," Meditsinskiy Rabotnik, Vol
17, No 96, 30 Nov 1954 p 2.
Physician at the laboratory of a hospital in Yeniseysk.
Translation W-31326, 28 June 54
CULTIVPTED PLANTS. Potatoos. Vui!utabl,.~.q.
ftcurbitn
NO. 4. 1959, 1410- 15660
tlCLCGIYA
,
(jf JXF
AUTHOR Us?nov,~ Balyakova, G.
c . Acad.
TITI
Certain C-a*eqc'er1et1cq o" the. .rowt~-. r--na4
lnpmvrt of Amer'can artichol-,.P. In ti*&
-~ -,:
-C .1c0
V
M-P.
oRir; Sb. stud. lianchno-isslad. rabot. Fosk. 9.-kh.
. nkad. in. K.;t. T1ni-ya-evt-i, 1958, ,yp. 8, 99-95
ABLSTRACT iThe autiiora think It is Inaccurate to divide
the American artichoke qorts into t1he red-Vabe
and w.*- 1i te- tuber vRrletie~. Accordint
to bu6h type all sorts can be divided Into:
low-Src;-,t-.-i, drooping, 'Intensely branc:-in.-
Alevskaya krr-.Rnaya, Belaye. uro-
-naynaya, Vad1m) does not flower near
Ing ntalk, few branctivq ( 'N-.*ovt.,-',,.rvya
:Krasinaya, Suratovskaya, ilybrids
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0 9 9 0 0 * 0 0 0 0 0
0 0-41 _O__ w w
0
"ALLti-01 A*.
-A
A
.Ce
oil op AkO
00 0
0 0
di 6" 11114 b"". M. twillIvir A t;fv.
WO
I
G
A
(L
go ). -
r
x"
1 8. ". K.) to
"Ut 4
O
-fl
m awl th
4 The luit
ctim
of StW MA b
th
l
e
nu
or
i
s
ir
i
a
friwlkvw W wain"Ooft a" mat fwwiio lased tw ths,
0
00
00 literature wA tho mmwuus publikalko of V. Pruk-eed.
ius (rain (he obsemlim that Ow iKW ~10M take
It,,-- yby&9whawaloguirsuslow that (here iq
tho
, ".:, t;ttst The qIPMOOk NW4*w vq%U.
00
,
viewsolufftisted
i
kill
A
i
0
: A s
r
y
ok-fitied as thr &Wty to *M of cadow w Imill alnwo*
6"(.
400
0
0 4.
and buidtr 11sw abwy to alm patkaw or split ON Ofthutm.
The wk* wW basic krietim 4toeM on (he c"Orditsfiled
* .00
a 0
0 unatd.state of stow (kxw) pitse t In the -.-jmpn. cd a
J
The pimente 44 coftifivAlWit-unsaid
given tornild
do*
*
0 .
.
rkvt"m
of it wboosove imputs us t,~, -
aloem in the ewnpa
.
.
h
ddi
t
b
t
t
1
i
b
d
l
t t
e a
rr an
a
u
c
ectnmeg. istains. t
w
r c
ww
t
ibasic clarwirr. Swe lbr majority of cbtm. comptis.
Mee
0
0 runirAn skowLanemmly ceNAlawd unsaid. atoms of both CMWA.~~
00 qicns. the amp4muerk- state Is a gerlerst) property ut Ih4w
comptic. lJowtv-s the wt4gioterk cotlifitkin d(" not
Thr L.
4p
o
th
li
l
&
4
w f
i
d
4
f 0
s a
s
un
e "Aluir
4
t
uml
m
Jww
VT
*wut o
4.1 *V:kd vappmeat. 2A refffences. Cbes. 116nc
.%L,%
01TALL~AL UT111011ft CLAUVICATION we*
INNS SIVINIAT"
- v low,
41 d'W .114all ftc Oftv
119
w
t
14"w0 - #
1 '
92.610
U
i
_
u a -AV to a
-Mewil 11 'A ;r,.; all
1
Ji ~ : * J : o ; o 0 J 0 0 0 91 vi
0
: : 0 0 4 41 0 0 4 0 0 0 * 0 0 0 0 * 0 0 0 0 1 10 9 1 v 0 0 0 0
a 1 0 Is 0 tj u
~00 A
GOP
A
**A
God
Go&
self
God
of
004
owe
M V z I
I
a U m I$ it v a 0 a 41 da d a# ate
-00
awe 4"Pubbamaz
SUMAWCOVA.&W goo
Joe$, 9, 1"7-IV5). 1--fe
femalom 4" for the sy9ka at 0011-9., vW 25* do not s
v the
Weft mmpoqmd formadaL The max. on
Omd"Urky-omposmon eurve lo"cribed to lowering
00
R. T.
00
00
jgoo
Isoo
NO
000
I
woo
SISAL= UTIRATWN C&AUVItAfift
S"111" -
lot-000 k4tv env Ot
T
F
b 14- -8 AV 10 IS 91 a* ;
p a
0 0 0 0 0 0 0 6 0 0 0 0 a
:::::::*Soo* 4 0 9 0 0 9 0 0-0 0
000
66409 too
1114F, ait i'i. too
IV a A I I v14 1 aI
anq
0 6 0 0 0 0 0 0 0 41 0 0 0 0 0 0!
-0-0-6-6 0 0 0 0 0 40 00 0 0 0 0 * 0
A
0:
oo 8~
00 d
04 is
000
00 'S
lew OW Irv
7 V
.A-AL-f- F W. fly I Aso 310410
IND
PWIM149 APO PSOVINI-ftmatm
Tm gawk, A" team
M" I A" -0e
21
of die 9MO=
a" V. UAmeho. S. S. -00
bows
it, WS-20(im)(14 Owasso); . CO., chow. (U. S.
S. R.) 9. 1967-Mim). -As an. 1w Ow WMH*MWMS
detu. of din dw. COMA. wkmdty I OW wriew tension *
is demerbad. Pmm mm no p"d. by A". 4A TO%
h " HAMO Tbg comm. imere Aetd. at
mr. ". ; X ms 3h19, 3M&, 4.00;
33.90, 32.41, 31.W; q X Jos, IIAD, 9.46, 7.96; d.,
1.9129, 1.791& 1.7722. D the p It. 0.
a" d. Vohs" of wariama M3.1r-Z. The 9 -
f (Md. % HaWcurvesdad"trimptom)UNA. % fitso.,
then ra HfOi; it X 108 for 21A% H#90# -
4.52 a 0 . to* amd 250, mw , for M 76%
HX.. 10,0, UP, 6.31, The X -4 (;a. % H;W)S
curves pw t- ismmatatiout= NJA.xX10A-
14.6.13.3. 18.6. The xv curves we convex to the M41 %
axis* nocumv wommimtkipawbatoNghtlycomicavc,
wW obey fairly WA the Wbetawmgb equation *.v -
IWAIJI - X)q.jR' Ob"I X is tbt Mal. haction of
119SO
min. at 30 mol. % - 0.09M). It is concloded that
fhtei*2&c=powws of the system do not Internet with ow
Saab". F. If. Rathmam
INTALLURSOCAL LMNAVb41 CLAUVICATM
""Inv --
.00
-049
.00
-SO
goo
zo 0
400
d0$
goo
4109-
I
goo
400
A
Wool
U n U~; 41 it Og a; 'a I '11MUARL $#*do a "Irm-
10 *'a a X 4 0 a 4
0 0 0 0 o 0 0 0 0 0 * 0 00f 'a 'a 46
0 0 0 0 * 0 0 6 0 o 0 o 0 f,e 0 9 0 0 0 6 0 0 0 0 lp 0 0 0 0 0
00 0 0 04 ~.1*64R.0-0 0 0 a 0 * 00 * 00 0 * 0
GOA CS)
000
009
60
a
000
004
*Ou
The oseedws Ion sedbdend *I duft4w m-
i n ... UOMWO". Comte - rfed-
t"Sy. A. 0241w)(1.
MrZe"Leptim a# AffheWas dist cmd. Id
in Ub-
716d qel 10-0) 04- OV~71-1 rl) n -
where s - op. cond.. q V ty and # - the wa-cs~
-carncted" cand. Nag. cafts. cd cowd. (at ordinary
lemo.)wValmmill inswas. having low".
A I d.j 4, AMITALLMOCAL LITIRATUM CLASWICATION
*00
I ::**
X.
see
fee
see
fee
09 9'8~
600
%.am@ NPIWIN90639
roe 4 0
0
00
00
00
000
*0 9
008.
0 as
:
0
00
008
00 a
00
000
- - - - - - . . - V
F_w_w_V-w_v_"
- 11 0 a 0 a
0 41 0 a 0
the
'Und is Alt
rf". Is P"
Md. StL d a
UK raw. TA
of chnn. COW
-in pholl delen
A 14 - I L A 00TALL~AL WE WAYM
1"W
11114W Olt# Olow 444
00004
a: 0 0 4 4100004
0:6441
.__ __ -,--.1 - -F _ - - -
- 10 0 0 *!
0 0 0 0 too go *too!
LU a #1 41 43 a
Lj A
a a _A_j
-00
-00
-00
_* 0
-00
-00
ke see
Cbm. (U. S. 3. R
-Tbe md. wts.
0 tin
h Pit. Of gvuph-
rbmb b
U IF
ago
0. V
ft
Id. S y
hnnerpmemft wits
600
4d FW M a" us auryl de-
l" "amb bdkw tw It*
OMOCAUGWOWAGN
, s " by lbt kr=Mke 600
moo
s. The md. wft. of wMan
Ing vu".. a Q0
zoo
moo
too
loom
;I-ARA $soda "alwomil"d )Svz
YA
00660
0006ONM3000*0
0009M*0000 0 00000
~V;
O;j I I a I I , 10 Is if q U is 1, 11 is Is is la Is J& it lis It NJ it UU w a is V V A 4.1 U Ili m ai
r. I It. L A
j Q it I I W. of OC M A L -A If a
4 skC, cauto$
-1~4 ist I ..u .0. Olaf I
- - __ - - ___ - __ - ___,- - - __ 1~f~
C. 14 The naturs, of altraillififf; filixturgs. Up# 1-Illb.-P __-itG~,)
It SIM J.
:0 J. Gil Chm '1 0
-a S. k.,. 10, 211) - 22 (1944)).!-~j ht ac.
[loll misits. #A )IM), Wish wher subitantes in the 11,1[j.
fifin "fir. callirmli. is It) the light of the pre. 11. migration o(t.lucall? in the pfraweact of Static A,td ,,1 -00
Viou, trimly of file QVIA-61k~ louctiom of II'Vo. ain't the altrobeasectit. .00
A101 Mi. At-I,,%. 114.
mmttd. MMT ;,( Awm% (iqns) A the w-ullisx 223-41- I'll fully thir ffI'll .'I t"W
611. C. J. 35. VCA"~- 'Slil, I'metion of 11,N), to IIN*01, oil she IIIII'morl ,I ";I Ing. ~-44
all a niffmillig:4i 1.1 41.1 wattir-billfling agent is ft-filll. I,.-. I'lMe all"' tMOTC41 'Ill 0 114.011' 11,1111 'At tel flit 3 .11 Ist-
Cuts- f1w rcm-tiow Cliff 0- II.N0. - 1'11%0, -r tilt) is with IlNo, 61. 1 !"." (Illd, will[ V.4111--li 14 '00
kwt reverail-Ir. Clmbihiibin, helieving lbal 11se nitrating Avoll, Ili, loll. and Pli.M)" I tie str.41,111, 1, ,111, see
lf I larm I, the IINot riml. and t~w its ifm~. iwitsmed 111.11 the Ili-it with fit, FIA-Ing t"ll, If A Ilw ,I,, I,!, ir, I!;,-
00 j 41111,11.1t (it ili lut itillit-it Otte qlk.,all. of JIM), I'll otiXt. 111C W,kltv, yieldif ill
fit,- Ih- fit#% Y1,14 coo
*0 ihe dickc. r"fl.t. of 11,S), is irtrater that; ll:il 44 *fill a MINI 4, .1 ,!fo, If%(), And .41", A,41:11,1 .4114 1,,,
fill) Allof flit- 'll-liticti, (4 HNO, In film). (IIN(J. . - 11, ~ 11\1($1 And -U,." i'l&(h. Pra.-Il"ally it., k ll.\l 0, 4 COO
NO, I will rp-f lie ll,wrr thars in 11,0 (cf. )[&nitwit, C. A. f,,rzrt,-,l at von, its. (it if.%(Jr. As muiis M %I
2.91M. Stri'lles oil I h.. Vice, Cond, 14 IM0, billary tilt %I.. limp IlItNte Is antilitilm-I only Ili Ow 11", If if
6111pulili-Iml) firwrial"I tilt wilphowtic nature (.( 1IM". 1*11-frr fit( di. iml 1-~Ylljffll "I
It ravit. 4,l .11 ,, of I"WArd It,( 1 111141 as it how It'awal'i C.It'Noi *%to listim &'I fit- frilwilm 1, 4.
an't 11:tr 4fid-bust, flinelims '11 II.Nit, to )iWasitinnof Ih%fc I.) liftill, tri,. )1,1,1jol A
It
Omwo in it, orn, two with AvIiII and CCI,Ct 411, acting with Miller -1111i. it II.No.. Th.- lO,,Ilfl fit the zoo
0 Id 44 all sics4l tariff Igair, rc~li , imil in Its failure to fowin nitralkill of org. V4111110%. At t III, 1(~( 11 %, I gee
awrifil ClIXIC(Nif .11141 CIICI,COlf (cf. Kul- &I ticis" And ewt as inert III Nitration of
I w(Tand Willman. C. A- Victim' tv I, 110111RCLO in the PlItSVISICill Of sulfuric add and trichloroaciffic
lite 1 .1
indi'-ste that its all. ll,~( hasic ficid, M. Umnovi. Is unit 1. willilmV. AkI. Ll:;~!) - -
.:, m in the prese=
ctirnillis. file iiiisaimn of phaik- minpalvi, is due to) the Prol-tv.1fils 04 atowe, HINIC WA. t"ford Wish ICN01 in
N(I,. Iml fit paud, 11".4)" file Active agents (if thersircal-mrof I%stitioi IIPN), (it. 1 0) An,j :
nitraimn M simmisliv rimilmlil. jrv life catifitill INOWID11 trri-ptil.
'Ib, '- -n fail, gil- in the
and jNwIf),! 41. Larwr an.1 (ki.s. C. .4. 30. 37,911). flair trill twly fral". if any, Phellsx4t, liprol"I_
I. a atTALLUPrKAL 1.1111111,411,41 i:LAS1tJ`KATiCw
all .41" 1'~ 0
alit, 01,11,
At ;;:~
r__1 _T - i I-
4 r I An I 1 '6-7-.3 ii 1 3 all 0 -PA
~1 'A Al ll~ IS, a Of, all w IT a
1, tilt it 19"=" 1 :14
000000000*0000041000000000 0111111110000009649000009
Otte 0:0000040049000000000O'SOOGOOOOOOOQIOOOGOOQ
0 0 19 0 0 0 0 0
With inCtMing tOlAtilse ('011C is 411 fitso. in thc niiiii
the
.
Yields 4 *nil ilwtv.Aw (rk,
i% (twiticill, lh~ n-A,. vichl #4 ol.iw
vml!!, WtecsfI,%(h Is Olulkln,41 %still a Insist. rotile, 441 44"-r
00 With further diln. list, yidd a
deen-s" %h
l
h th'
d
f
i
i
i
64 s
sclone
orinv
w
t
up
y an
; 00
The yiefill of %IcC&Hs(N(h)j Int, awk with ffN(), ron,ii. 11111141111,
so to a max. cif W1% with 85-00% IINO,-
00 *tt.tlcqmqly. but fornist only Anil it.. 00
diriv, Tlstj~, lit the pirs,encr of a diluent, Wilk!, 1,,j, lit it, 00
00 IIN(h. the nitration is dim-ted toward the rinit. IV.
so filtration of toluene In the pre"ace of monochlomacetic 0*
*cld stud ethyl nitrate. %I. u-inovio, mim i.-ii. 00
00 Aid. 2:0-:1. 'It 1-1 41OWn thill 111V A-C. CTAW. 01 It.\'( 1,
00 devres,C4 with Increasing diln. Willi the- illrT1 qlllvrlll% of 00
CfICICOII and FtN(h. A, a result Of Ille .1-rcamlic 00
00 conen. of ICNO, catious and anlonq the nitnition of the
ring slid the Aide chain proxr,,,i%-rly decreast-is. The
'
'
'
" 00
yIrld# of 79,0
~ %IeC,lf.%
0, and 11
' PhCll,N(h at a
,
I
-
f M)""
con
il
11M)
111
d
d t
d
i 00
00
00 etmi-
c
. o
o
'
An
,
f", ft
,p_ W
lli
.
1#1-13%IINO,.
00
larly with dilts. of IINOj. Chaq IllAne 00
00
00 00
00 00
00 00
00 00
00
e0eO0000001111110:9
L 000 ::000900,1111,90,11111,04
G 000000000000
::::::::
OqO9O
,:
tit
eil
Off
OOA 000
0*0 -a I ~v , . . "o
ed 9%IPW`StWd (A
C44 tu a. s it 1!
J. r,;,= ibl, iu-
a Watts. - as" in cut:r;; ;,b0 tKutt"
c,mdl. ( --
prwM-, dUD- I& awl- SP'
SID&Z-9p. tb(SA
00 IS COD(Wr to cead WItb lacr melambas We0enc
IS
va" In OIP- In',jkh the the qmd, d"UCAI'm 000
w 5 bat
19 mod. IM -Stc`e Ms. b( tbas orm goo
.1 the cc t1ast
camirse"t cd to systtoo
eve,
o: ON "Safum 1010, 00
the cead. ppw WA,,Ay
goo
001, as camia dw campaoil" S. R.) Go WAI
a of 010 .1 tw rct s;a. sop. ctind, goo
so C6,, QJAW
w L4, (J. goo
o0 the twoor"W" c4D*d. that
0)) ty I W & * tGrwccOwqpt_DI_Ibkb coo
00 &r$6=L L) 19;Mliv the
the is no in thm &4aitc d1to. goo
am larv, . pdgoray
t9 of SO A..A goo
compd& goo
goo
woo
SlIALLUnKAL L"I"A"ga Ims, *a a0v Ali
futile@, I it
Me o 00
saftse a _T__T It a a
st 0 6 o o 0 0 o 0 0
0 a 0 0 000
LI go is 1, IS v v o o 0 0 0
0 0 0. 0. 0 0 Is 0
00 0 0 0-
0 0 100000 00 00 O_qj~
0 00 0 0 0 0 0 411 0 0 0 a 0 0 0 0 0 0 0 0 00 0
is Is it IS It It x 19 it 11 It a Ago
a J" A I JI.. t"I m IN it i
00 4 ."**
C7
00 A 0
0 * 'A
1040, IL 434-440). -Salts may be rded as d riyed from
so Imes (anines), but not from addL Thu. NAC111 a Wit of
a hAde (C11 but not of 110. The nactiono: -NaOEt +
KWI -* N&CA + Pip. MIMI, + AcCl NaCI + I-30Ac.
00 KaOA, , AC1 -1, NaCl + Av 0 111, SO INACI
so 2SO.. MAY 1111 he fV%Atd^d'R~ M4tQ3*1 Of salt 'Ffnalt.'",
2aff arr a"Ingous Iu NAO$ I -f HU) -* NACI I- JIqO. ") that
N&O may reprded as line Wt of the Ium NALIAc anti
the A I'l A Cl 'Solvolf-Sis of a "It &IWIU14 entirely III-n
the '1vent. 'NACI is alkaline in AC,IJ W113111,11. the 4,;W
P"U,cd (ACCI) being weaker than the tm~ jNaOAt)-
A I %t.
j
lees ~044114
zo 4p
tie 0
0, A S S L A StIALL"WAL LITERAILM CLASSIFKATICK LOW 0
'0 "* 10
too
ME u is if go S- --CW-0 a I It 66 - dl I I
It(Itt
0 0 0 0 0, 0 0 * 0 0 41.9 0 0 0 0 Go 0 go
0 * 0 a 0 0 0 0 0 0 0 0 & 0 Ole c 0 0 0 0 * 0 0 IN 0 0 0 0 6 0 0 0 0,
oft
Sas
go'
0o
ood
sod
age
0 3 104VOOICA& LITENOWS C&OWIC41"
-00
go
MOO
see
204
too
boo
T-7- IA A I I nd a a I 1 0 a I a 4 3 'n
u A* ul H A 0
0 of
*T,Q 0 0 6-col* 0 0 0 of
0 e . 0 a 4w 0 0 0 0 9 0
OG(T
--UL-2,102-AnUft UP
Me fleftEffil MHS
so
00
go
so MWZ I
deg.
oe, Wkv 1(d n ta* ump. cma. of
thaqww betwm the temp.
*0 dw 1~ one.
of
so* r) is k2 do.
ile ow the WA
b A. A. Dad~
00,
31
2 A I A. IA ARTAWMCAL LIFINATM CUUWICATM
I I WHO riviallyo -
laftio .4 1 . S00440 .1p 4mv all ZA" all
46 T--r I a r p V ; I
u wav,001; 0 Day watna,xwxxwu , 'a m I I a fw 0
It
go *0*; 000*00001646
0- a -00 0 4 0000 :109 so* 000~
0!
1,90
"so
ro 0
fee
W40 0
WOO
*so
1%0,
w lptv m
ilr:llimi 36 vim
4%
*Osseo
0*
00
00
90
06
W
#0
AND VOC0121.15 "Oil
aiiac-imbi6i" L Add-bame
krilrmc U. Uwmykh-4nd K.
nwtkyl Idleir. mWonj led. "A neutral red give tbtt odd
in pW% Aj40; trapomft 00 Sim Its UsaWt1cm
cow, JWW me" vwd Its aft. "imr. Tugs AOLO b" a
PH bttwm' I IW brwmph-a
Mue, vA bromon from
ed
thometo"418140. MW5rJW,1,.4,!.Wct1c0jI1
in AW an two mcM than AcM aM saw. d MQAc are
much AM. (pH 4.4-4-8). P;:,FdJ%i, WO a bow id
A lobdo W a" In
16V. M. S
sai~-M.-AcobdavesesgitipfbbftAcwAAcO
r,
inum. Whom mks dre Mod In Acv0. WAvolyalm Ott
animsumitift with Ac.amd catiorm with AcCl. Thus..4
mcciates in Afto give volms. mm alk. than Ac*O Itmelf,
Sulfaut &W tarbariates gNw weekly add AcSf).- and
am tbbrmn a" t" Aca and AcNO~.
WAtrates In ActO be p"w. The order
c4 decreembe "rixon."IM,
80,, CN8,
C1, NO~, Dr. I!, :Z*r. do at rkka Ity at catIoN if
K. No he, Sr. NH,. M. U. MO. C4, Y, CA. Cu. 34C. N).
Zn.
ONTALLOOMAL L11111670011 CILASSWWATIW
.00
'00
0
P re 0
W46 0
R-C. use
U 0 AV 00 Ujj ~ j j j I j j j j j j~`A, 0 11: M L I I Od 0 0 9 1 W a $ A 1 3 a I,=
sees *00 go *090
1,111 al no TO
6 0 A L a 9 0 PO I I T W 4.
AA
0%
4h
it
apa"wwwammun"m "ums vis-viv
%90
'INN 99
0
It"
v 00
r ,
I
T I I L
I 1
I
I
I L
1
00 A
4141 0
00 A
*# is
too
0* a
008
004
0*
000
004
00"'
_A4_ -a-- A__j_A_4 I P. i.. s aa_
111XII&I41 &NO ..Vie
3-&Mveed
VIK"ty 41twimc .1. 1. 1" is~Oh'
11 Add, N014 S-S-'i. k., (?Jfj. Tekh. Segae&, -JaBbl.
-314UMBW~__
adevealys. somkAdmis 00 vyda'wi zU4djkj i KelloU.
X-ftearl- (C-f- - Vis'-sle Sof L4%iitt and CaUta"d
S".) 2' 85 WIMY systtm. were
astablysted to aftarcriain whether S-,haped I (viscu%ity)-_
a
t;=rrs actually Wer the riesull 44 a flimptat"Ber., of
at 0 suflicienoly hJXh trjjt;.,, as Ur"Claimed by
N. S. Xuarteakov (cf. C.A. 33,84W) for the system CJI#-
SbC#.. To this end. the tcrnp. tiviriv. 4*141 was plotted
again't ct"Upat. few the systens above
and below the m.p. W the compd. (11.6*). The Values
ad daileff increaw with ridng lemlo. and shuve no tendency
to Peass; thertauxle x".. c4aniciturietly. there is A hint of a
all&%' of v at a b"t" te"111- The AteHie was found fur that
loicinsi(t,aA%Cl,ctndClICI,C(-X)II IICio,. 'rliccw.
1-1 inferwelatioal of S-eheepard curve* is that une of the
."ngm.nnlts it, as"mA. to a higher d,-,,, than the compd.
Ilse formation of which rnults it, a simplificatiog, of the
MaMlin-01thertaytitem. Such systemaceenuot haves, max.
so matter bow much the temp. is knrcrref. Asaruk,tbe
cearvature Weals Iti1xvreme kno with rising temp, leeptimae,
e tw T. TWV7,4 T'. itint'. and
only at "one hialitt tenw., latteatnifist miere pro-
att= with itifitur ri~c of the tenip. Th6itativervard
in itac s". train gv-vr~-l-dirnc1hy6niImr. where at V, (he 1
ivithrerm is cionlm% tit thraitis ail tiatipts., It" an naiderctitan
at M* and btaint" ilittinctly S~Ijajjrtl at III". In tht
yAlem (he 25' and 4W istaflacraras jut !;-
halvd; Inan A)" up, a in,sx. winw-A". wh;vh,in fuitlearr
rising temp. Shifts tovarverds the plavii-A. Thi:,; i~* a cast
'where a max., Absent at louver (envii., vaivjwars~ at higlerv
tvnip~. and it truns counter tiD Kuarnak,wls 1-tulasta4i
appetaneour of be max. of I on lanvetring the temp. Thar
last 2 system* have this in comm(m that the (emp. cmfi.
dif v tiarilbart librnol ow no-erraivi is verster than that of the
stableccatritids.fornavd. ChAnget4trenji.visain theratio
tit qof one ad the cutail-tivit. anal the c,;mjad.;%4i1b.-6Iug
trinjo.. q ad the coml.l. grows lasict than it of thr nw"
vi~,vus coinpunait said this, Lumbittedi with that Stability W
the compd.. kads to the appetarvince of a max. 71se
undarrlying fact is the artnuaiderable suagorn. of plearsagals, at
low temp. and its japial drop at bigtwar temp. Comic-
skin: 8-shalied q curvars casantit be interMttzi by a dia-
savrearance W a mats. due to ranarti Irmli. N. 71KM
3
4, - - , - - - ____ -_ ____ _ - __ ~ . . . - __
A 16CLUNICAL 1,1111110411111 C1,A$%WKAT1W
I lam# *011419
Blow Strives'.
ilk J;;rM1 . d I 04T 0#9 631111041f
6
6 _r 8 IW 0 0 0 1 It P 9 A 6 3 1 1
U sr so is, at 0 a, 114 S`4 ROW a, 11 Mas
0000001-0,0.000000000*00*000 -000000000**41006000*
000090000*060 M#402*04LO00000400000000
_
-so
.00
.00
-00
,
000
=00
-00
moo
Aroo
goo
414140
goo
11140
0
1900
J100
041.1
06 A
00
00
A
00
0(.
09-9
Sod
*ov
'009
11000
fA t Y-
It A U
AA w xk
1-00
is-CROOMI. M. u L.
J.Gm. CAM' (UAKR.Tg=1IMImRu2Sima).-
The condf. and y * t syde= If-Aca at 23'
M 3.5. wg = the ftsults we pruated v"kk-
ally. Tbepremeace of ittend. num. I :: thteXWeare
of interaction betweem-the i is a aciel-bail~
's*a
basis, with tomatiou of a (AcsOHM, In wbich
AcCl acts as the odd wW AcTO71. tbM(e base. Cdvm color
C' -4hyj vkW [a Aca and viok-t color In AcOll show
Abeforzoertobeflsestromigeracid. G.U.Kowkpolf
s Iii
.L
%,74- 1. -;.1 J44
woo* .0
t
so* 0000 0 0 00 0000000 0 0-
0
-04
so
-00
.00
woo
logo
Goo
909
*so
goo
4*0
too
use
Woo
861101 Ow S.. M
R 0 0 0
o
0
J 0., 0 0 0 0 060 0 * 0 0 0
.-A -A-IA 4. A-4 -1 &--A
A
*0 0 -7-
**A
In that urds,r) Im by drins. of vlammity 4
and op. tiec. "Md. a of the corr"Pothfirl b1=00.
A&W-M" properties of aceftaltrile. 1. IntmactlAm In CII#CN-CII,COOII, the 0' and 26 9 fff
I boftom mtoultille and "We. hi. Ustnovich susd V. coumve to the axis of eonspn.. the tatter , i wisat less
a Dulova. J. Grx- CJwm. (U.S.S.R.) 16. IVMS3(Ig*l) than tb-t lonner; In the otber 4 rewww"ll systc
M, the
1 its Rusdan); d. C.A. 39, 4&W.-The basic bhwiior a 9 Isotherm am convex. in all a system, The 4 imothersm -so
14CM towar4s CII,Clll)II, CIICOCI, ",,(NO~),Oll, (at 0, 23, W; 0, 23 *; 25, 111) 60 '; 23, 60
log a'. t!
CIjjaC(X)II, CC4COOIl (the pjI cWwtrf ijmfp4~i,jX In the order fiveu Above) have a distinct isax.; C, 'C',
00 CJIaCOOII am** two mait. (At about 20 md 40 mol. 7r
ClIsCO011), sepd. by a min. The max M-arvemd on
06 st I 001i M
,3 at WN curves; CII,CN:6 001i In
09 == wpd. by a spin.; CIf#CIl-CH#ClC3"YmiI 200
and 014CN-Cills(NO0,011 %bow an indection but the
usax. expected beyond it cannot be attolord owing to
limited&dy. Tbe sperialmsess(ClIlCOOH (two max. of
a and mi) is a1w reflected in the curvess of ihe ttwp-
too
of ciec. cond. wbkb dmw inflections. On the basis of tne
curves. the " tharrxttr towards CIIXN Increaws in log
the order Cl C0011. CII.COCI. jlzH,(,%O,)lOII.
&AW
CIItCICOOllDC4LVUII, Indkitton(p(cricocid.mala.
chitst grec%mNlityl VkAel ttopacollne 00, 4hmtbyl
Itr a 1. Ule Md 1. l1whyt oftw,
.711MIRr. I X- - t. I red.
itrDPkVAOI. neutral red) gna the cmrs~w I
M
ILCOC1. C4IIj(NOs)rOIII. CillaCOOll. CCICOOII.
Me b4sk prwmks at Clj.CN -.y be tImk*d witb the
structure Clik I.e. lmdctd. by the presenceof the neg.
1111MIll. N, N. Tboll
to solos* sp any 6" alai Air iiwi~'ltl
I A a F" I W I X, a a m 1 0 bi 0 0 0 3 w It 9 As a 2 0 V
U 0 AV It a A f NA
0 0 0 0 0 0 0, 0 0 0 0 0
0
;T.4 Os 0 0 0 sms 0
7 . I . - t rl
la r r I y f
A
A
*8&4#0" 04, 49 Oman
IN
so
Gfol CUM.
!to 7;11`11~
m. mmurld 44 W 100 to TIA
Man. comid. 0 v
.4,%llAMlA40 heft MI&SIAnd. %.EAW*Irm NO
G 0.73 ad. %; it h& ogedwasu* afA rapidly from
OAA ohm. -s qn.-$ 1w pars HAN (at OV) to ewticall
Ag
NO or CCV=H; do c-- fw 2D Niad 40
Arrop= that Our W, 0 how to Vey awly Sao at No*
On empes. Slow ohm, The ew of smal. cond. A =ew
fm WO, I&& shrug* to jmvvmrb~ wo at a dila. of about
dws Ambfy cavd. on fwibw d0n, Time ov.
temp. 0". d a bkwm 40 OW W* la abmt 9%. The see
liscoofty it lwb IN" pw* RAO# (9 - 0.106
St wo) to OAU); tin coam 14
can"% to C'sals ON "a Is cbs"Ciffleik of a
system of -amowdoo mom. amewsmosts. Tbt &b.
cambelutup tedby
A,KdbWg Ow da. camL to borkstim of saNcatiams mdkft
(Hanuach) A
1, nooks la dwimiaps. low the "ple HISO.
lawls., "~Mmwvolv of immissileft is that mordim. I
W. Tbm 'Fee
ties
WT"LONGOCAL L"140041 CLASWICATM lose
NNW 11"Nol"
IVUW- *A, Mal gas it -owv
'W, '19 49 'USM4296FA S I U v
10909991111909*0
0 1 1
3 4 1 4 1 411 do 4 0 : 00 0 414141
1 41 1J 'I A V .. 11 if if 164
11 vu job 1sv 180,4W
'rul)m Afro
A F 4 A J-1 It Y- 11 1-1 ~LM-K-7. WLU.+ -A 1 * t s i
4
of
The syskma formse4l by perchloric add with acetic &c'4 le
A" its ddwfA* iladvatives. T SumAnAt)vj and M.
so L:amwvkb (314kidle Aslis Stair VOwNty. T;I^hkent),
00 Arm Phypirorkim. U.N.S.S. 21. No. 6. 941 St M101-
d b
h
t
f
f
d
-00
unne
i
. o
Tlw vorM., y1misky. sai
t
e apt
r
so A if ItC10. with Aeoll, "Witu as with the wAm-. di., RAW ti
00 chwaderivs.(j(Ark)li.vmm~iwiint. Witi"gollfUth
&M CC4C(x)li is wromp-itA by etp-km, whe"M,
with the other mysternscontruction omn. Thecomixis.
CIRAICOOR-2111clo" ClICII(xx 111. Het().. C1f1C1C()- P
06 J; 011.1100.. unit "WO11.1100. wrfe detrctnf, v.,
-
i
i
i
i
It wf
i~
n t
ir4ra lit incyraw
orengi If I,( I heWWk. 1".. ripi t
Cl. V. 11.
A coo
'00
l
too
L(TERATU-f CL-it'SK4fPCO
i;;00.3 .1
t jft.
--
--
'
r
TF
j
i
It
0 0 49 '0
4"
0 0 * fall
o R It it .30 K K d X it K it It X
64000410696 0 * a 4; 00 ia
0 40 0 0 0 * 0 0 0 41111 a 0 so 0
re~ 00 0 0 0 40 9 00 0 0 411 to 0 0 0 411
9 0 to * toage es 0 fa 0 41 0 0 0 0 ,
4"!
0 0 1
000 0
*9*040999*004104110
Z* 0 0 0 0 0 so 0 0 so go 0 0 as 0
r I I I I , , it " o '. , " '. i .
a I . L Ur... I L 9 ft,j (14 1 1 1
I w, I.r, I.,
00 A
010 0 9
P 14 h J4 ft
- !' A I I "i 't W I I
and &WOMY of Ilklary
Ift mod by 11~rtjil. The -1 ! RaO4-
=010-11. 1% Nnual"i"V.4 e rut -r - J.
00 Gen. CAArwo. 17, Wliu =1111;
99 d. C.A. 41. 67in;c, CUM" am
fl-shaped. values for l(CIO. And f1t, 11C16COOH At 20"
oo anel
00 Arl At 1W. (mMOCS, anti fl.017.1k) Tlw curid.-MIC".
wfvrs fine In luther sharp max. at a conen. of lickh of
0 0 WIN mole !:~, the values of the roax~ cond. at W,35, &nd
0* hill twin& OACWT. 0.0262N). and WOMIS ohm-
'nc curve of lid. against concli. is slightly
41 visfing 90c"What from a itralflit fins. Vslurs of d. for
00 a' site LiNand I.W -Ice.
SoVi The data Atr hatmterl"I 1-1 Inaltrate the r-inte"M 5 two
jAm7 r,%ujd.. with the formulas 211006.010.4LAX)II
001 and tClO..C1lCl,C(x1lf. Vvitrj CI14L74C(X)l1 Itt-ing b"c
TV,
WWI
I'
U a AV
4 1, a It n 0 n
1411!
0 0 0 0 0 0 0 0 0 0 0 4
e 0 0 0 *is 0 0 0 0 0 4 0 0 0 0 0 0 411 9 4
-.00
-*0
ftlative to the 11CUP.. IV- The ?Ysftu RCIO.-Cut-
OCICOOR. M. t'sannrich &rut T. SumArokora. [bid. -410411,
curves show m*%. at a #4
.110(N of about 32-T mule % at 311and &J". but crysto. M(
' -09
Values 1.00
of man. viscosity at 35 and W* air OAMt anti 0.(12441
d". Cond. curves show max. at about au rank e;,
~ =so
ICIO.. values (or Mtd. Of I(CH), being O-OVI-71. anti of'
1(
CH.Cict)(MI IV" thAn w(M. (IrM soull trmp. de-
we). and the ittill . cond. at W. 35. mut ail' being
se' COO
l
( 1. O.O&MI, atul O.OTM ohni-I The curve
i Coo
6( It,otp. asaimt IICKN cone". is q--hat"t. Ilwag
fit4a prartivally 1.0 64 Ilk) mole ~; HC104 to &IIIut 4.u
Iw1ow23mole%ljCK)j. The curve.( I.A. acailmi eves". see
PA cunvv% towards the concn. nits; at W". v
"
',
fromOMfor IIC1OtoWMI,W:sI.t:1~; 1
W"
11W foilmall-Ml of tHle roml,ti. N Ind"t"t. having the
f
t
HCH
XII
CIC
1 64D 0
orinu
s
.
001
N
. thr ittlorr beini hwk
ee
rrlatiwv to the former. Arild Allier s
-:so
ties
Its*
ir,
v 7k
0 6is
0 0 0.0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
USANOV1,141, M.
Usanovich, M., and Sumarokova, T.- OElectroconductivity, Viscosity and
Density of Binary Systems of Binary Systems formed by HC104. IV. The
System HC104,--CH2ClCOOH.0 (p. 168)
SO: Jburnal of G,--~neral ghqaj�tr 1 1.1 cL~, 2
1, (Zhurnal Obshchei Khimii), 194~,Y!L_ _7,1 ___t
-- -W-W-0--G 40-4 0 0 0 o 0
40 0*000000000900000*0
I a . Is "
I 1 4 r I I Is if u is m ti Is u 9 If f If a a A a a V Is It a a so 2 31 V Is P 4 41 a a a 4
A-A--L r -in j a L F 1; -1 1__T Ll -L-L-A- I
4
8 #16Ct"It A410 O'SCOISfIft ~*fff
".beft proper" at befunkrue. 11. lateracts"
, rl~
Of "*bN*Rfk WWk 611401t. M. UNAMMiCh stiff V. VVIOVIA.
so J. Go. Close. l7','-WFrM917) (in itu"Lih):
d. C.A. 41. 6M.-(I) lit the "em MeCN-picoline I**
00 (saixt. of imonamrs). the vismaty (V) jintherms at ol arml
therm its straight line. T*m, oftkc.eoW.(M).AI .00
W. 25% MW 30% have a high am. at about M) mol, % AD 0
A4eCN* the aq pint Whows a sbarp max. (at ishout M mol.-
so Intherfer. moo
tng"k CA Mists. of this con". corresponding to the "tax.
of it, the AS anodke was vw No Of. wat evolved an
the Platiskmed Pt csilio~b; the mWMPI isms of a CUM.
plex R.MtCN (D - bam), Jimalmed bit* 0.)Ae* and CN coo
go tht disrhargod cation dimsm. into 8 + Me with subw.
tPk-ntMCOMbiUGtiftCd2MQ. ladfiMtC)r% With tf3n'J(kM moo
above pil 6 slum acM.esc ion in MeCNarml tumirmactkm
00 'ma adda. of Pkafisse. (2) 7u 9 imotberf" of IlecN.
Mr#LY), evocave to the "is I - Pa.. Wkste morme tic. moo
sees 41
mated by dem. of the apparent saw. at. giving curwt moo
e to the ask o( abscissas cu. t at extman dilms. 1100
On the OHM hand fix'"ton AM so change of "action
Cis .4 )&;M to mom. canctiumto, m4co we
a C-.; navv approx. the same wW -ban character and too
thrw lat~ka b nmW, dhook mamm. M. Thon
t
MCKAL L T I we CLASWICA11411
LL I I AT I
-- - -- I - ~ - - --- - 0 Ili*, N*. 11) 1
tic" "~:
-A solrs~ .61 04- --( 'fit & o"
1 10
1 ; 0.1 TjjAA1 ss-~io a .136 INTO* 3,-Gv
u 5 4, M) u ~ U, ; A
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
*Osseo** ***#-0, 4toof4p 0000 go # of 00*0 00 0
jo-04000411111000040104
4APLP!rff? P # f
A
*so
00-1
4w rAmlaw stanak cidwWa4wack scie'ded stanak
410411a I in am. , v nwi x H. Kalahanavl4ka"
It IiMp. Chem. Lalstla&a etc Univ,, Toblutnt),
of i AM DhAMd Kkiodf 17. 1=400947)(in Stusslan).-
00, It j 1) In throysictriSnCh + ACOH' tiseviseviltywisothela
of 0*,26*, and &)* bases sharputax. at IlSmok % SaM.
with is (nux.) - M.9.11, 2.7W4. and 0.11980 pobe. rrp.,
sea alKnv v of the c4muponscits. Tfw clec,
00 1% MuCt.. - (matJ - W X 10, 4 &nit 37M x w- .1 :5*
and W. reop.. Own through a "ux-- rnb.. at.!P) mote %,
1,uCl, at 60', shifting to 25% with fallbW temp. Iso-
I hmn% of 4 and of v have a single sharp stax. between 22
j Thachanceof
I&With terop, is unipustly high, IMT. Mr I'. Pkftofa-
'v
betwren 01 and !15 tban between 2h* and
An . All I plot* point to only we Suclez-
lowevve. the coropd. SaC4.2"ar.
so ArOll. I 'A M
in , a" In-
AAL! dimird the 9 and s diairmnts, oW undt-tectable by thr
awhW diamm twinit to I be teridency dt tha systcus In-
wads uwkwooling (Mranathan and Strong, C.A. 31.
3=0) coold be rtrystd. by stirrustinit In-exins and thavrinit
in a sealed (ubv; the crystals had the coasts., m. 192-
19.11', tP 1.11M. dft 1.81114, d" LAM, -0 2D.1212. it"
Fill I'ls". *a U-MM. 0 o3b x lu-~' 00, Jai X 10-4, &.0
0
a
j-00
-0:
1451 X 10-4, .40-10ArOlt is a -truesof acid thars
0if
b
b
A
i
1100
c
w
t
whk
l
01l) Id
t
11M
A
(
en.
ana
ogous
o
c
. ~99
tL-sl wkb the known SnclzAcOlf- (Z In SnCU-
I HCO01 I
I
l
l l
211
25
k
f
2200
, sega,
nto
t
aym oortin
rom
mo
qu
IWO, upwards nod pervi,,19 even at 70'. One I&
Z Zoo
-hi.
highly viscous. thl other is a Ycry duid, fluning 7
The amt. of the wiftvxu liquid increases w1th hleft&4114 go*
1
-FIC0011 and Is pradoettinant at the coapa. SaCl,.j- -
"0*
HCOOIL Tbbcompd.canbeerrotd.landatedin.m.
W
I
l
b
d
b
i
.
9
-
.
s can a
so
.
e crysi
y tow
ng i.be two-lar"
uid
the duld is
,Au
mo-
li
rrunder
novit
n
w rhob 00
1
a
o
,
s
e
y
x
q
b itruvottv "rm. with k%4 IhAn 2.1 mole %MV14 evolve CO.
N Tl.~
00
2040
0411101
ISO*
t;
MIALLURGOCAL LITIOATIA11 CLAIIWICATIOP
40
Iki -4 %$3o" .10 dhT Oet 1616&116-t'i qf'~Vi It.. I.,
V--v
tool
1) U 11 AV 00 111; Ct It a Or It It tt 1 4 'W a P1 0 1 w a a 4 q I
000010 0 * of 0 * 9 0 0000 0 0 0 ft
a 0 0 0' 0 0000 so 0 0 * 0 0000 00 0 e 0 L
oaf, I 1 4 1 # I 1 16 14 11 11 U 's 1. 11 to "Jot), n vidis AODS0,S), A; 1) M is * 1; P si of 41 43 01:0
A a _r A-L-VAL-9, -i-A. L a- If f CA M I L It AA MCCUPItfl-I C t,-& A I I A 4 '0 1 A A'
00 A
00 OcOZZ
A: RGiriw WCOsity.andd sitrafti Italy
00A sydinto beoW by pWChIWk uW grabof "I-
00.4
009 119W; cf. CA. 42. Were ffWk At
00 A.'; The viwasity-cown.curvesat all loops.
7. ttkited bave n%Ax. at X2.54 took 04 11004. The ckc-
00 trot,"mi.-amwit. curves at all 3 temps. rim sharply Irmo
liorr 1100. tit a otAx. at MAN "mile rl" IICIO.. then -inn,
111101. sI.'rj,Mq. IJW foA bliflill
00 Ar then drop fit the Unv "*at, ill 1%irr A,-( III. Valoi-,Id
hx-rra,* iiievatily Irwit putt MO. tit purr Arlill, v-daw,
lit III)', r.0 IJCIO4, 1.77 to; 61. 17 took"'. I ICIO.,
I,5746- 4.ez % 11M., 1.1176. Dals ind"te the
10maiW of the compl. 1100,1AcOll, with no fintica- Coo
tift of the st Investipted COM IICIOI.AcOll.
of a P.= `1 -
Y1. SyvtmffVl- add -water. bid. 1 MI-7.- zoo
U
41
j cam". curves d4e Irving the roo.l. of pure licit). to a %liKht
otaii. at IWA oo4r ra' 11CIflo. thrit ri-w rAjeWly tit ~t ,h-rjo goo
goo
cond. nI pure water. The vjwovjty_-ij~p=. cu
rves
thp)ugh A M-11. at &87 (centipaises) at 42.5 mole 70 TICIO..
data WIL given In the article. The rmltq IndivAte
the formation of the cotapd,. IICIO,.11,0 nil IICjO4._
AMA I %fill"
too
Ai.
3U S AV 00 14,; it Is It 19 K Of U If I V
00 0 0 411 0 0 0 41 0 4 0 0 0 0 0 10 *[i 0 *4 0 00 00 0 0 0 0 *4
"no"
"1761, fikgovod. Met_ Aq. 19,!kML;x-KAsw.,Ak,;4
Namb S.S.S.R. No. It, Z*30(114m): d. Strunathan and
Strung, C.A. 21. ill"l-Cryo. 4nCI,.2ArOII, prriml by
altemtely inamerling a mAW tube C'Nits, SnO, All'i
Acoll In a 111111f. 14 stAiij CO, skjad Ak-.. 01181 Ill "Whilig kv
until erritah apim-ared, using thew cry*1411 to omf latir,
vols. of sola., anif purifying by fractimul fteemij, m.
do IAKMO. do LW14. the IAI:11. q# ;!l0 12
v* 1.124. V* 0."1. op. corml. at 0' om x to 4. At ~p
3.33 X 10- $, at W 14.51 X 10 -1. It tom% SuC4-lAc.
OH.IftO and SnC4.2AcOIf.HtlO. Pyriditse dbpLbm
AcOli in form SnCf..2t,v. M. II'heh
USANOVI wLjjawmw~
Complexing as acid-bass Interaction. 1zv.AN Kazakh.SU Ser.khin.
no.3:3-5 149. (MM, 9: 8)
(Compounds. Complex)
USAITOTICH, K.I.
Viscosimetry of binary liquid system* IZIr, Sakt. fig. Ich4jo- anal.
18.128-138 149. (KIRA lls4)
(Systems (Chemistry)) (Visoosity-Neasure-gent)
. . . . .t4 . . . . " . .
vaARMN . M.
Chlorides.
Compound SnCl 4 with CACOOH., Izv. Sekt. plat. i blag. met. no. 25, 1950.
9. Monthly List of Russian Accessions, Library of Congress, April -1953(9 Unclassified.
U.UNOVICH, M. I.
,
I',;,,"",,- Acid-bass theories. Izv.AN X%xakh.SSR.S9r.Wx. no.4-.97-105 151.
(MLRA 9:5)
(Acids) (Bases (Chemistry))
V Sq
Chemical Abets
Vol- 49 No. 4
Feb. 259 1954
General and Physical Chemiatry
I"'", tems formed by SaCli, SbCl,, and AsC 1.
The SOCT,-'1H CICOOH [~Iup ~./T
---i, C 7
M45 X
Gex Ckear. 1 .11.21,
Zk.;. Obs"I Xhi.. 21, 981-4(1951); d- C.A. 44, OgWa;
46, Mli, 9402b.-From sinplar max. observed in viscosity
and cmd. isotherms, and shrinkage in sp. vat.. evidence was
obtained of chew. interaction in mixts. of 8nCl, and Clit-,
CICOOH. Detris. at 60. 60, and 70* give no definite Indi-
-cattans of the compn. of any compds. formed, 11. The
8nC4-CCWOO1l and SuC14-CHO COOH 5 tems. T.
Surnarokovit and M. Usanovich ?Katakh Vad. Set.).
J. Gen. Chem. U.S.S.R. 21, 1079-81(1951 anti. trans-
lation); Zhur. Obskhef Khim. 21, ON-Mg 1).-Vis-
cosity and d. Isotherms were detd. for the system
SnOcCO&COOH at 50, 60, and 70% and for the
system SnCIr-CIIC1jCOOH at 35, 60. 00, and 70'. Both
systems are noncoaductors. The abscnee of cond., the
additivity of voix.. anti the smooth change of viscosity with
=n. are taken as proof there Is no chem. interaction in
systems. In. The 5bC1;-CH'COOH system. At.
Usanovich and T. Sumarokova (Kazakh Acad. Set.). J.
Gen. Chem. U.S.S.R. 21, 10MAINIXEntil. translation);
Zhur. ObshcW Khim. 21, 08740(1961).-D., viscosity, and
cond. values were dttd. as functions of compit. In the Stich-
AcOH system at 20, 60, and W. D. datit show a sliqht
vat. shrinkage in mixts. of the components. The viscosity
isotherms exhibit max. at 52-3 mole % SbCI3 which shift
toward higher SbCI3 values sit higher temps. A cond. max.
at 70-80 mole % SbClj shifts toward AcOll at higher temp.
When cond. values are multiplied by the viscosity of the
f5ame schis., the car. cond. isotherms all attain a max. at a
compn. c-rresponding to 2SbCls.AcOll. The temp. ff..
of cond. exhibits 2 tnax. at the coinim. corre%pondilcig"to,
SbClj.AcOH. The latter cornrid was reporkil by It. N
Menshutkin (C.A. 6. 1280). - Thwstructurc% or the compds'
found are given as (SbClt.AcOH)* Cl- and (ShCli.AcOll) +
SbCV. the latter existing only in the liquid phase. A'
Bernard M. Z44"Ft_
I'L
- . -.n 11. T h ~ 11 cl-(X7
i .
a -', r-i: -~, -S-Gl Err, 1 1. - A;:C S7-f,77
"Binary co.~4, 1~ t --) I ( p - r" "4)
,1:1,,r1 SnC,:~,-CFM,.,GOOH-ff br: ~i an,~ 1'. U:~:-,(*rl~a~
r -
SO: Jourral of GeMral Cher..rLr:tr-r Ul"Umal Obslichcd- Kll:-,ruA) 1951, llolttmo 21, i:o. 6
USAWTIC-Ir!, M.
"Binary syst.-mas coniain-in,7 SnCiLr '. .
, SbC , and AsC'3' III. T*-;e 7jz3tem 5r C 13 - r' -;:3 C C'o: ~- a
by Er,&nqvJci and T. Smarokova. (p.98~
SO: JgaMg of General Chenistry (Zhumal Oloshchei Khiffdi) 1951, Vclume 21, ilo. 6
Ift"ry systems formed b -IV.
"he system sbcf,-Cu~~. x"A.0-U.".Aft
t
'j WK,
Aur. ObjkhAKkWi~~ 9.
.ct"W48k."1'7_870. d., ~h~o;lty, M.,nd a
-The elec. cond.. 1"t'.
the system SbC4--CHjC1CGOJ1 were det4. at 60, 60, and
W for changing values of the concn. of the components.
Rxistente of the com -CHiCICOOH and MC4,
&SWI,
,r
.d,9
(!H.CICOOH Is . The fuslw4 diagram fc* the
Itm Shows the resews of a c=pd, of c almoisr cowpn. -
it., The system 9 - =Arokova and
Id. Usanovkh. 16U. 1210-22-The ellee. tond., vikxWly,
sad d. of the system SbC4-CC6COOH were detd. at 50, 60,
tud 70* for different concns. of the compcoents. Vne -lee.
con4,compn. and viscosity-compn~ diagrams show that s4
%,cJd-bs" reaction occurs between the compoutnti. The
Lwamea of the compdj. SbCh.CC4COOH Arid 2SbC4,-
CC4COOH Is also ludicated. The fuslun diagram "Alts;
is m4x. corresponding to the compd. SbCh.CCLCOOH with
.;LML.P. of W. 1. Rovt4r Leach
USSR/Chemistry - Antimony Ccwpounds Jul 51
"Bin&ry Systems Formed by SnC14, SbC13, and A8013
V. The System SbC1 Cl COM T. Sumarokova,
M. Usanovich, Lab ;R;cs aem, Inst Chem, Acad Sci
Kazakh SSR
"Zhur Obshch kaiie Vol XXI, No 7, 1219-1222
Studied elec cond, viscosity, density of system
SbC'3-CC'3 COCIR at 50, 60, 70OC- Elec cond and
viscosity diagrams- showed presence of acid-base
interaction between components and of ccmpds
SbC13 - CC13 COOR and 2SbCI3 - CC13COOH-
191TIS
USSR/Chemistry - Antimony Compounds Jul 51
(Contd)
Dystectic max onfusibility diagram of system
I
represented compd. SbC!1 - CC2 3COOH (mP 560).
This is lst esiablishea case of CC13POOR actin'g
as additive or oxonium base.
192TIS
u8Azv11CH-,- I.I.
"On the acidic properties of 1-tn04- n (p. 19IS4)
SO: Journal of General Chemist (Zhurnal Obshchei Khimli) 1951, Vol 21, N10 11.
USANOVICH, M. 1.
USSR/Chemistry ziectrolysis of Water Jun 51
IfElectrica-1 Conductivity and Viscosity of System
I KOH - K2C03 - H20," M. I. Usanovich, T. I. Sushkevich
"Zhur Prik Khim" Vol XXIV, No 6, PP 590-592
Detd elec cond of 18.86-41.59% KOH soins contg 1-31%
K co3 at 25, 50, and 97~C. Sp cond of KOH decreases
Zh addn Of K20 Defd viscosity of 2 concne of
KOH with differen~,K2CO3' content &t-25 and 500C.
It increases with addn of K2CO Sp cond is lowered
at expense of increased viscosity. KOH solns of
these concns are used in industrial electrolysis of
water
193T46
i83r46
JL
Chemical Abst.
Vol. 48 No. 6
Mar. 25o 1954
General and Physical GhemttrY
?7410fled of UAWd buji. flov favil,
-J, "I" "Wov
-Akad. Nauh Kankh. S.S.R, - 101, tel,+hlm, No. 4,1
W-105t[ 951) -ge view with4 jTferences.
Al 0 V J C- /y, P 1. 7,
TIKHOV, G.A.. redaktor; USANOVICH, M.I.,,SUVOROV, N.I., kandidat biologiche-
skikh nauk, zame's"titelf redaktora; KkRIMOV, M.G., kandidat fiziko-
matematichoskikh nauk; KUCHMOV, N.I., kandidat fiziko-matemati-
cheakikh nauk; GORS191140, D.S.; FEDOROV, N.N., sekratarl redkollegii;
ROROFTNA, Z.P., tekhntnhPsk17 redaktor: RZffO11D)MvSrkTA, L.S., redak-
tor.
[Discussion on the topic: Pri=ipal achievements of the astrobotany
sector and the problem of the possibility of life on other plan6ts
(September 25-27, 1952)] Diskusaiia na texu: oanovnre dostizheniia
sektora astrobotaniki I Yoproe o vosmozhnosti zhizh:L na drugikh
planstakh (25-27 aentiabria 1252 g.) Alma-Ata, Izd..vo Akademii
nauk lazakh.SSEL. 1953. 167 p.~Almdemiia nw1k Kazakh-3koi SSR.Alma-
Ata. Sektor astrobotaniki. Trudy v.2) (MLRA 10:1)
1. Ds7stvitellnyy Phlen Akademii nauk ta2akhako7 SSR (forTikhov).
2. Chlen-korrespond3nt Akademii nauk Kazakhsk07 SSR (for Usanovich)o
3. Otvatstvenny7 sekretart redaktaii zhurnala *Veatnik Akademii nauk
KAzakhakoy SSRO (for Gorshenin). 4.Referent fiziko-matematicheakogo
otdeleniya Akademii nauk Kazakhakoy SSR (for Fedorov).
(Life on other planets)
Th A
~;.Q of nny
C
-2
TIKHOY, Gavr1il Adrianovich, astronom; USANOY_" H.I. otv6tIjtVOanYY
redaktor; RZHONDKOVSKAYA, L.S., r
A, Z.?..
takhnichaskiy redaktor
[Principal works; in five volumes] Oenovrqe trudy; v piati tomakh.
Alma-Ata. Izd-vo Akademii nauk Kozakhokoi SSR. Tol.l. (Astrophysics
(1897-1919)] Astrofizika (1897-1919). 1954. 334 p. (KLRA 10:3)
1. Chlen-korrespondent Akademii nauk SSSR. deystvitellnyy chlen
Akedemii nauk KazSSR (for Tikhov) 2. Chlon-korrespond.ent Akmdemti
nauk KazSSR (for Ussnovich)
(Astrophysics)
Lbis, 0 V
..UM/Chemistry Quantitative analysis
1/1 1 Pub. 223 - 29A9
Authors Usanovich, ix.*..; Sumarokova, T.; and MevskAya, Yu.
MU I Cryoscopic titration
PWelodlcal Dok. ANT SSSR 98/4, 617-618, Oct. 1, 1954
I The application of cryoscopy for quantitative analysis and for study-
in-, reactions of -formation of comnlex compounds, soluble and insoluble
in any given cryoscopic solvent, was investigated., The results ob-
ta,ined through cryoscopic t1tration of' complex conpounds appear to
satisfy all requirements of analytical accura,-y. in addition, cryo-
scopic titration reveals new very-broad possibilities for quantitative
analysis of orpanic substances. Two USSR referenoes (1941 & 1940.
Graphs.
Institution
Presented by: Academician A. F. Vino-7rador, I-lay 6, 1954
f
TMOV, Gavriil Adrianovich; USANOVICH, M.I.; VOMYED, I.Y., rodakt*r;
ROWNINA. Z.P.. tekhxi-c-h-i9YWiibiktbr.
(Principal works, In five volumes] Osnovnye trudy; Y plati tomakh.
Alma-Ata lud-ve Akadenti nauk 1(axakhokei MM. Vol.2 [Astrophysics
and atmospheric optics (1940-1945)]Aqtrofisika I atmemphernaia
optika (igio-1945). 1955. 381 P. (KLRA 9:4)
I.Chlen-kerrespondent Akadeeft nauk SSSR, deystvitelinyy chlen AN
XazWR (for T11hor).2.Chlon-korrospondent AN XazSSR (for Usanevich).
(Astrophysics) (Astronomical photography)
L-~, The (Itteruldnation i-f the compol .3iolk of ternary Gysterns
fr om tile data 0'
l -7.zeV Akad. A,
vmh and A I. ,. 11. - w4, S'.1":',
I'st".iIAO, 77 -1975-, ~). s . I I -9(ta Rlmwl).-At -'a' tht ~P.
gr, (h( v2rll:,~v tvsCmI5 %Vvr(: lllv.,~-
S
,-'rola tiv. ~p. J;r' and thQ Ili the rmapll~ of tilt! ttfilary syli,
ti m call be fimlid a5 weii ai from the Whet proptrfies htre-
ttA,,rc uwd fur tHs pirpose (clicut. Thk
111(jiv)(I has tile adviuloge of Will; inum mwie rapid.
..~~'erner jawbson
US Ire,; V C,
The questirm it decomposition voltaKa of ijuctitti molv
Leglane'o views on tht electicil;,tic mictio-t ir. thmi
prelenec. of miny i0w; (M. 1,03hiic, Z. -ik- c*--,n S
!,enlalic, reyi!40 k OfF,"Calml 01
Ltningrad 1930) (imn-slation) is Criticized "a PT-011cous.
On tLe contrary, in reversible prtjctss-!5 the clectratitt poten-
tial is considerc I to be deld. hir the final remult, arid not by
the primary sti.ge of the proet:Ls. The nu:chankrn Ul tb._~
electrode proms cannot b,~. judcd an the basis o! the Ok~c-
ttode potential, the Litter 1i 6ug a inacrogropic
Xantity.
In 1),articubtr, ditrinodynamicit docs not exclude e 130%9i-
11 Votential. In Carcil, where tim di,.c)mrgej ions yie.d
'different fin.d froducts, list (113chargc of it gimi Jon may Him
place at differint putentia!3. Rlkj!!~_
4
Ox6filuin -comprjunds-r~ egleys I
.1 1 Org-1:1)0 MCI&
11, IISRHOVICII~ K. BIJV W.
'kra~llwa4xw. Zhur,
~~~7251 47t-7(1955); 1. ch?,pl.
25, 430-4,l(I055XJ1jjLl. traliJallun).-The vajue.,, tj (I. ztet,l
'vistosity at 25', 40', and W" wcc detil. f)r the 1,;nmy
systems AcOII-EtUtAc, ]NOAc-AL011, AmO.kc-Acoll aw'
AlliOzM-AcOll, and the vapor pressures of tit(!
systvais BuOAc-AcOll, ArnClAc-AcOll. allif EtO.kc_.j_j,,ojj
wcredctd. Tito rr5ults. shwn Ktaphic;dly,"ll, slirlim"ritul
a.4 fullulYN: I" "It"m ofllV (lie awwn. u,(
,AcOlI is evident, tile phytt. pri,pertie"
oj tt;c s,steln 11"t
'sliriwing any definite component interaction. Iii
AcOll system there Is all indication of mUtuAI interaction,
althou-b the AcOlf assOco- is still tile PRdolainant factor;
the Val)(ir pressure of tile system SJUAY1 neg. ceviation from
Raoul('% law, anti has an -M&Ltion fic,int at n(ar molar
compn. The system AnIGC]"r-AL-011 ShfW9 a win. in
vlacu~ity ~ Lit III) -3o
I - (, cliter land till ijklefillu'l
.'Indicating mutual Ciffill'Unclit lit(cracti(Al. fit t the ub~ellet
lot eltetrkal couil, Ind el, tes til"i tills Is nj): jjj ;,cj,j_))ase
1 typ,._Th4 AtuOAC-AC011 symni khows 4 lijax. Qjj(I gk
min. Ili Ale Vi.-koiity. IvIlich 11114jalAv lVith tclicet-to
Wnp.; vapor prtwire thowi neg. drvialiOtl ftf)"'
f(jolalt's 131y; the toytacm b aguiti u0neOllit Ut till K, 111111C.Lfillg
that the itittractiou uf componcilts Is not Ili tfic avid-baw-
type. Thus, the interaction between tile Cs,~cr and Vic ncid
tentis it, increase in importance with an ital case of the size
cf the rAlcals (j tit c ester. 11. The systain acetic acid-
retyl acetate T. S,jmarnkova and K. Filyjlov. Zhur...
ObAchel Khilll, J. Gell. Chem. U3.S.R.
26, 4-15-6(1955)(Eviii. tran;4atiot*-Vi-:ctiity und d. bf
Call.Wc-AcOll 53'stclil IN'tie detit. at 40'. 60'. GO' alld
70'. Tito results, E~oiwn graphically, indicite that tit , 40'
gilig Its 5113 C
viscnsity isotherm liis an S-lorm, Chan PC at
higher tctnp~,, with 0imination of assocn. of AcOil; the
corivcx shape of the viscosity curves indfrales fairly strong
COM.Mneut Interaction, greAter than that Ili HtO.A~-AcOit
Ka,~L" SER
S i~ I F
o0'ElectrIii.1 conductivity, viscosity, and density at toe
ton WnIMA"NI. Mmovich and E. Yukovitva.
I --- - -
, , S -'-ETI( fill
.r.' 06 , 'I him. IA? S
T
of vi~cosjty and of Occ. cond. indicate the furknation of a
111trutally-unstable coujillex compli. of undetil. coinjin,
The IntemtIon is appartntly of all acid-Ijase eharactm as
evideiced by the eisc. cond. H., M.
_N\
rl ) -* -
A N C
I Sp I syztems: water- emanot- nenzo-
*Of the
in W"
-athancGuiphenvicarbinul.,
St -eva. and 9. K. KhaTrulina.
studictl pf
aeding a :Jrd ccj-ip,)-i,!nt, which is 9d. in EtOll but not in
11,0 011 thr:vaportirts~uret-of the Et0fl-1110syste-a. Ben-
'nphenanc (1) unel triph, ryk-abia-A (II) %vere uscd as the
3rd coukponmt, The vapor presiure was mealure,l at 20,
40, C-5, and 75*, am! We valued m!nt plottedrs. eompn.of the
binai-Y mixt. Tlv! addn. of I and 11 decreased the partial
Pr-ule of the EtOH and increased thatof the 1110. These
effects becnine more pfoaouncc4 as the contn. of I and 11
y~eze ir Qrtac;~A._ J. I G%-tar Lea,
S*kv-- u
V1
AID F 2786
Subject USSRIChemistry
Card 1/1 Pub. 152 - 14/19
Authors Usanovich, M. I. and A. I. Mun
Title : Determination of the compoBition of the system
NaCl-Na2S04-H20 by specific gravity and refractive
index
Periodical : Zhur. prikl. kh1m. 28, 4, 436-440, '1955
Abstract : A description of the method is given. The composition
of the solutions can be determined very rapidly and
with great accuracy (error:,4-0.5%). One table, 3
0~
diagrams, 4 Russian referendes; 1930-1947).
Institution : Institute of Chemical Sciences of the Academy of
Sciences of the Kazakh SSR
Submitted : My 3, 1954
KOZLOVSKIY, Mikhail Tikhonovich; GLAZYRINA, D.K., redaktor; USANOVICH,
M.I.. redaIrtor; FJWOROV, N.Y., tekhnicheekly redaktor. --- --
Exeraw7 and amalgams in slectro-chemical methods of analysis]
Rtut' i amallgamy v alaktrokhimichaskikh metodakh analiza. Alma-
Ate, Izd-vo Akadenit n&uk Kazakhokoi SSR, 1956. 185 P. (.MLRA 9-4)
(Mercury) (Amalgams) (Ilectrochemistry)
C
oj~ '..' /ff f
USSR/Atomic and Molecular Physics - Liquids D-8
Abs Jour Ref Zhur - Fizika, No 1, 1958, 825
Author Usanovich, M.I.
Inat
Title On the Viscosity of Liquid Mixtures.
Orig Pub Izv. AN K&zSSR, ser. Khim., 1956, vyp. 10, 30-39
Abstract The folloving empirical equation is proposed for the iso-
therm of the viscosity of an ideal multi-component mixture:
~'A -4
are the molar fractions of the components.
where XA and-x
This leads to a general equation for ideal binary systems,
fln *7 - lnl~p. V Un-VA -ln-9-7 ) r-xA- The formula (1)
is based on -me assumption that the activation energies
Card 1/2
d d
tV 4
;j LO
C/
,USSRIThermodynamics. Thermochemistry. Equilibria. Physico-Chemical 11-~B
Analysis. Phase Transitions
Abs Jour : Ref Zhur - Khimiya, No 8, 1957, 26169
Author ; M. Usanovich, Y6. Pichugina
Inst : Acad;M__y ~Ofs~iencea of Kazakh SSR
Title : System Stannic Chloride - Phenol
Orig Pub : Zh. obshch, khimii, 1956, 26, No 8, 2125-2130
Abstract : The viscosityrL, the density d, and the specific electri-
cal conductivity.V of the system C(,H,-OH (1) - SnCl )~_ at
20, 40, 60 and 80o, as well as the vapor pressure p at 4o,
60 and 800 were measured. The isotherms ofrL pass througa
a maximum, the position of which changes from 90 mol.% of
I at 800 to 85 - 87 mol-% of I at 200. The isotherms of0t
adjusted for 4 have a maximum at 84 to 85 mol-% of I at
all temperatures under study. The magnitudes ofq and the
adjusted~