SCIENTIFIC ABSTRACT UFINTZEV, V.N. - UFLYAND, YA.S.

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CIA-RDP86-00513R001857820008-2
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December 31, 1967
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SCIENTIFIC ABSTRACT
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ul~ 7:-, C- c ;n I'G.rl the rllc~icrl of nci-r c- of th-~; ;.C"Ai~n ri b- V N U i", r z ev cl-I the ,,. I , SO: Journal of -.'~ener~.d chc- , si~l:v Vcol,:-c- 1(,, Ro. 7 00 4 00 f 0 Ott 60.3 000 Hf 00,3 00. Of 9 F-C-6- O T f VO 1W ~ *0 is 12 11 4 V Is b It 2 4 to 4 Is V N 0 -6 0 0 13 14 _-L-A-A1, --A posit aft"A"I 04 "attak "W "Ibir V ?4 M - A 0 " - - ".0. C Oc 1 1 , Ph I upon heating to 24W untirtgo h f 1 e formatiots o doeompn. with t 1 40as 2-COGSOMe 2,7. and other products. The Na salt Is quite -stalge Inuirr such trrAttlwnt and its decompti. ran be acwlerAtedhywtdn.otl"f.,(,P(horIfOh. Thefornu.. .0 0 lion of the disulfonic &M excludes the intryWtation of -00 the reaction as a rearrangement, Wher, the mechanism Of such decompns. ("rearrangemcuts" of sulfonates) .100 would involve splitting off of ltpSO4 a dreptateld: 711na/ t' tion of the am. re idue m-sultins in ancCuMulat - HIC"t i(AbIC SU1100AIrS. I-CO161"INA (10 g.1 and &K. Ra* lb 6 =00 CON wrtr rvf1uxv4l for 2 hm., after which the hydrocuriltmi ' -A, vxtd. with 11.0; the ext. contAbled unreacted millanate. Adda. at 11~ either lf.PO. ar ZGSO, caused the =41110 f4winatian, under analogowt conditions. of soutu amts. of 900 7 11,SO., aud of I- and 2-"ItSO,11. However, when . 10C. 0-Crsllt.SOdiB3 was beated undera reftzcoadenser 600 4 hrs. at 23G-M. much C*114 subliumd and the residue 0 Aniounird to 8.1 X.; estn. with water left 1.25 g. iniol. while the aq. est. showed the pretence of coa. 1 7 bl d M S0 C 11OXII 2 C 1l l - - an -i-kra e 1 t* .(. C, &l . , )g (cletd. as the 2-naphthylAminc salt ); I-C,olf,"Ayl was AIMCIII. The Ph salt decamp. AmilArly, but much maer see 4owly than the Ila salt. G- M. ROSOIAPOff A I a -L A 41TALLORGICAL WERAIGNIC CLAIRFOrAlION saftso .4 Isla" .010 o1v 4C 1131421C.C1 ivill, 4 F." ass I 1,r Ir Tr 'I $A I 1 5 ad so A so I IF It U SAY 10A11" It IP Of a YA 0 '1 '~ 0 0 0 3 a 0 D W9 010 0 0 00000 0 a 0 '09 a Is I All$ is Mrslavvivimina" At ai*C9 a I, I I I x ',", 't' ' r IL a r. d a I T JL I 'L 090CItSIS AND PSOPINT1111, -Of- 00 00 A JA R6UMS C0111powds. VU. Action of phaylbydriziii -00 0 l and Godlizin libuffite an naphthol azo ay". V. N., - Vdintsev, (C ntir Ilt la iod I fit d A d a 00 so C . e a r nst.. . ca e . Sci.. Maq- raw). J. Celt, Chem. (U-S-S-R-) 16, -00 cf. C.A. 41, ~M(V-Tbe reaction of 111thill.1411, in the f N *0 o aIIS1Lh with IX 2. and 1.4-PhN.C*JWII =Inct'adducts ields K jalu of : y 2-h"rkjdrasivv-J Y-dAydrit-2-nopkkalexesalfoxie acid N k f i f i ld f l~ ~ i 094 e it -1.1. irti. y a :-p eysyl th Nall.S0, or sc%vfal a (I I-Ako#*; 1wx.YlAydratixo-1.4-dikydro- w rasono4-r -% culcklev 4 - julf-owle (VI) A 4 k l id ge -na& a istriu , fenic ac r reip.; the ~"ll group in . V I- .-Adll o s Alto obl i I b ll 11 I 0) ,. A - s . r t l " ( , y y hfte comptis. is labila to alk. reagents. The Na salt a( urci 1`1011 0 d 11) t f 0A III i lu Ft 0 t " also eed cc, ce. rea ment o 1l " a. j he lAsulfite coulpd. of 1,2* PhNiCIJ1,011 (1.0 it,), 1,0 10 d 10 Hiolt i h 5 N N f Ii it cc. 0. & vc. o an t (h C. , g. PhNI1,411t.11CI, 16 cc, 110, 10 cc. 951,"o HIM, slid 8 w 'l E d b 5 d I l O d zoo cc. conc . I it 33 cc. 3u t lf an CI y cc. Nli4fli% tioln. (d. t.37) followe were heated on a stem bath '0 0*0 4 firs.; after standing overnight, 2-04 g. of a yellow crywt. finally 41) cc. 11A The Na ialt of flit b6tilfite addu" of 80 "' 4-I'hN PhNfIN11 llcl 1 C IW1i (11) s xv I0 g d t 1 b i ) d i a** 004 . . , i , ,4 " . uc ) was o ta , , ne wh eh, fecr"td. front Ila tv. 1 ( 1`0 95% FtOlt i M X11 11S0 lf O A zoo cc. , ant cc. n. . s r 4 , 11.0. 150 cc. FjOlf. 1.3 cc. 11211, anti 10 cc. satti. KOAe r s nrl allo d fit t d n lli f 1 fl d 4 h ht 37) ( wee 00460 . s wc . . e uxe t s an ivri . g . was intensely yellow, filsol. In "It* anti firt.0, I. ,I 011 M011. Spajingly fol. In 11,0 aild a1c., on bratiul in yleldt-d. after rrym. fr-it 1111) L1011. k~a wd. Stn; t l litos HIM in the presence of alk. it brcaks down into I-&xyl- KOAc "a.. 3 g. 1101, anti charcoal, 2.68 a. . a ' *itb 50% E1011 in in d 30 il b U . m o e , coforlem necdk-s; 11 133.2-3.8 in 'N' K, ())I f2Yr f i d k % a _ .' al , sult int.. the pfe~cllcc o fir Ill --qfg an cartling the reawtion in olivir"tti, hoill NA12VAI if luillk4 It,4114ttlets Ill, IM-A"; 1511.7-1.31, r"t-birown pilio-, tit4lA fit UP, Witt, 41% k"11, And FIX1, di"t, ."Itty MA. ill thi. ill 6 o fit to) ve, M'0 sliO .141 v" W1611 goo , with I g. NaNLh lit to cc. 11,0 anti &)cc. ikl-~ Ett)IJ, then li'mil.'shith %%% oNi'46"n %,o it; 110 (ir-" IMA a Oak concil. ffQ in Wee. 247, hfOll, folk,wed gulit.) gave by,300c. an cqqdfr". ' W O (from FtOli)- 1. ACA J-m.7 11'0. yielded 0,41 g. (IV), tit. 14.14 M. 130.2-40' (from the emlic, mixt.); *Itiod. bill.1fitir an dy" dvived from i-anlitbal4-4attonic add. InAr lit dii. U.S0. It yields IKWQ.--Thr Allj'jk~bflily -4 flurbeftr rule U. m1pAilhaleive (V), or. It ro)"~~ V1011 e~akt. Chew. (2) 69. 41)(UNW) to the erilctilivis of %a- A##.OLA jdjALjUs$jC&L LlIffiATtall (jA$WKA1ft view vdwi" wee Islas* .19 Q.T Ott I U IS & if F I I I a 1 11 'A L 1 0 bit 0 0 a I W a A 4 > I I, AT, 10 0 911, a 10 1W U a a a a 9 a a If ipa if 1, 0 - - - - - - - - - - - - a 0 e 0 0 9 0 0 a 0 0 a 0 0 6 0 0 0 a a a a a 0 a 0 0 0 0 0 0 0 0 0 0 0 0 to 00 00 *0 S* R_ 00 .4 . . so PF i 00 00 Big 00 .14 pff:4 g. 00 7-41 .4 S' & - Foci a O-pq r Rj CHR A 94 0 is 04 a v 2 pli-SIE'S. t3 , `- Ure-" Wig -a~: so 00 00 00 00 P R~ 0e at WB~_ P.244%? ;Nhi I.Aulls 1 1* CT , 1 00 00 1 u U~X-l jr 1!,ff llq.~ .4zk L 1 00 oe 71 Orl-l'u'l ~ 2. a V :, G = - CLZ ~.5g - i 1- 00 41 di.-T 00 I 00 9 ITT zglm~.. w zR;. 00 0e -.0 0 A-0- 0 6_9 ffi 0 0 0 0 0 -0 0, 0 0 9.0 0 0 0 0 0 0 9 0 o 0 0 0 0 0 .7; a** 0019 002 a a 0o" 0003 094 0 O'W ;~i 004 0 0 * 0 0 0 0 *11 1.0 to so 11 U 0 14 X it It 9 yy a it Q a OL1 I it I It A. a t - I a k A ~ jl--F~ ,1111 !A-, "r so ---------- ^ The actim d pamsgium hydroxide on 2-inothyl-1.4- 00 ulaoste-3-stilloalc scid. The mechastiam of the -00 X. V. V. Vfiuttwv. COMP1. re"d-mut. - 111. U.S.S.S. 31, takes ISOUC with 111C 00 mechanism and produat "tulated -00 at., C.A. 33, 332.51-1, Gir the r"Ittion (1), and fm Men *0 irm-rpretallcm .1 file 111tvIla"Jim tit actiiIII if vilamill K. .00 Accurding t. U., KOH ald..trtm (lie 2.341~"Ifilv twit'lof I to*lda product contg. I mol. 11,0 more thati timeo(s., 804111 and havin; thestructure Cjl4.CO.CNIc(OK).Cjl(1*A)sK).- o (P CO (U). U and 9011 yield C lI"C(OK).C(SO'K).CO roo =00 (1U) CrYOX -with I mot. 11.0 fmin 50% MOIL A miln. of Ili uptin ~cklirbcaliott with IiCl to" Its igitcow ydlpw COO color to "d cIAm*m crystab of K 1,3-djazo-2-indAn,ul- too Ill. M + 1104111 + KIM yield the tl~mitnc tit IV, Are 0 light-grmn need1n, sol. in HrO, slightly mJ. irt E1011. I?flwin S-iferk- 1 (-~'JTJ MAI( S L A DETALLUROKAL LITERAT1161 CLASSIFICITION! vion, v90 Woo !10 0 t3of ;a- cl; amw a*1 III It is 17 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 'OTOO ": 0 .01 00004060000000***00*0 *0 4 e0 4 00 ow U is U a U a n a 0 0 a *IG, bonding in actrwilidat derivativols S R S 53 d d U C to . . . . its. . . aca , V. N. Vf4fptxx,., amr. F*n 131-40MAn irrvich .-The la.p. of d-CIC4114NIIAt *0 (1) is.,*)20 lower than that of its ums (11) and paril Ntiner (111) bemuse of the presence of siat Intran". If bowl. .00 The Up. of 16 higher than that (it 11. tahile tile Lp. a)( o- 000 CIC411,NNIcAc (IV), which U:L4 no ititraimal. If liond. i, inuch Umvf than thAt Of its RUCtA 60COCC (V). -rhk a, contrary tv the principle ul 21Wgialick (Einlroxic Da,,,wy 1041 of Vulexey. thiford (IVZJ). p. 147) that intratmol. it Liond. ing (rvwts in a lowering -if the I.P. CANW(feratiou of a Wife no. o(sutntituted benzenes in which the m.p. usuldly ISO incrt-Ases in the order ortho. tacts, para, whether or taut intrainall, H buinding is ptesunt, likewiw lermis no support to this concept, lit the fint phase of the nwthylmimi all 0 the ivniscric chlurouvtmanifilics, obt:ainctl by the fract4m of lite currispumfing chlorounifit" with Av,0 in IIOAv me* milli, (ThiclepiLpt: and Iluble, C.A. 29, 4# 141), lite ijiter. ramlwt. Na wit w" 1witat"I. Tit,- anuinalt"y high ~Ay. .. ar 1`0 lle te tile l e I ht i l 4 W f vil ni ta v % ll u) s t (alloot 1,11 4 t xy j " 1 4 ; rum of lilt itar.4111.4. all" A lkml. 1. 1 ul. 9 11 blo S31-8-14', tit. 70: lit th. tit. ly#)'. goo IV, vi.%-jut liquid, 13. t4ti-!W. 1,,. 2175.043% V. rev- toingillair Platt,. b'. .5S-4.5'. tit. W-1-2.6% 4-chloro- Tholtabil: crystall, ba b?'. 2M. 1 -5.9', tit. 90.9- 1.5 Arthur A. Dulnick see 111VIA&LOWAL UMAIWI CLAIWKAIM moo too W 0 C_MV=-W= goo i 21im a" Ali--- n OT40:1 goo 00 0 0000 0 0 to 11i- - j 4 1 11 1 1 1 W it 11 11 14 is Lk Iris lVW!jlZI 4144 -Ij U 11 11 4 11 r i,, At '; 41 d x J A A -1. lbactwe and pistatillkl4al activity. VII. 00." Sluthsob of psludrins. A. F. Ikkhlj ,V. -41t 0 and K. S. T"chlev. Ziuf. -Oft 09 Client.) 20, 601-4(1947); cf. C.A. 43.2W/.-4-CFjpl'.. 00 it N111 (37.4 C.), 33.7 mi. cooed. IICI, acil 24.7 s. dkpm- -0 40 diamikic heated on a steam bath 4 hn. give 62.3 g. I- 00 Al 3:;; M. 230.154.2' fron2 of jj7;:'! water); frov Mi* (by addn. of MkOll to the af~~' M. -181411 1200 (from benzene), gives on long drying and secilins JlCJ ovrr I hr.. let jUnd 0.5 hr., 4d evithl, in Weve, 00 the "k form, m. 144 % less sol. than the labile form then sulded to 1 1. 11,0 at 401 andalct stasW ovei Ight -00 0 above. Tfic stable form (3 x-) heated 6 lirs. with 6 ml. gave 11.4 g. 1-(4-thitwoph4rolyi)-34yugotuanidine (tj): a** 111. (from Water). U (3 g.), 2.3 g. istk-PrNll,. 00 Iso-PrOll and 2.5 x. Iso-PrI gives 0.9 g. 2-isopropv1- 00 '3 Alor Atay[)bigW4Xidt-HI, m. 215'; fire bass C. CuSOo. and 30 mi. water after 14 firs. at 100-5% 1.(#-( 00 a t". W (01torn heptane)- mQau-MCI s4k. m. 2l3*.(dIi-- ret stand overtilght, anti filtered, gave the Cu comp r10 0 IICI 1411. tn. 191 . p-6WI,N'lls (40.3 g.) diazatiml WhICh OU SUSIMI)SIOn IJI Water anti INS treatment, followeri 00 a in 125 mi. 2V'. IICJ and 2Y) ml. 11.0 by 28 g. NaNot ~y filtration, XAVC 1.4 g. of 'he frio paludyinf. us. 1.30' coo -yandi3mide (frons .1i]. U611); the sailic pr,,duct iA aim) A,t4incd in 7, O*V in 2W ". ire water, treated with 40 X. dk zoo in 2 1. water anti with 240 nd. 20% N and L71-9. yielil when 2.6 g. H is trittiratell with 1.0 g. - 40H. let at i"j 00 :1 PrNII&CI and then heated 3 43. HCJ several minutes, and neutralized by 300 ml. 1:1 to 150-WI, full..e'l 0* x :i! gave 89 g- P-C7Cff.VNIIC(:NH)NIICAV brown solid; by suits. in 50 fill. 5ff licl Aad 2:1da. of alkali to the filtAile. I is less to2io and less a i this M g. in 90 mi. Ec.0 satd. with woling with iM4kilial tbin palu- drin.itself. Paludrill3efOrlm with CuSO. in alkaliamni- C:00 t Ple's CU Salt living &L r""ViOltt 1101111, ill ClICII; PAJU- Nll drine It lkydrtAyzc,i to p-CICJ I.N1 1. by Impiling I hr. VO it 11 40% NuOll. G - hi. K. A-1 4EVAL,UVWCAL LITCOAtURE CLAS%SPXAIICN L t-149 00 T-W _0 W-i-i"i -T u- a t' if is JW a a if a of ff is it or 'W a it" oooooioooooooooooooo*0000fooofooooosoosoos090 * T: 000'0 *1** 0 0 000 00 0 000 a 0-0-00 000 0 0000e00 of 0906 *go' 4 111JIM" Ids mum] 4 is P 6 j 4 , 0 6 . - A K, L a 1. P 12 a .-A A 1 , , 1. ' 1. C, P We 4 actionts of resteirc!" Clin , ., -(:J1.(,% undes M Re m A 8L . l to po 0 0 with blitellfits. V. N. t1fineliev. Ater. PriAlad. KA' -solve (1.1.32) 12hJ`S.9AVr4fl.5g. 00 1). A& filled Chriffi-3 20,~j jWI2fM(I94j); C1, CA. wid (111) (41 X41 fall). Inaltelf 41, ' ' i ptrit. by 141 r AcOK; the ftee In 3% IICI all,[ l -RmxcijjW braled with a soln. of Nall.VA'h - W3a. 00 fr., yellow W414 U'l, its alkah ' isitifeletreterk. limilioh = . , the lrl- Nd -Alt-( 1.3-dohydroxy-1j, % 00 'A d4#4 (1). *hkli I% trattilly biroken down by alleali to 3- Santi dil. I lielorlil nebl*, leesol, In water; its 41 00 - 00 ic um-W.Ste,"Va (11), f4e.0frinol (111, X1 att'l 10(k) ml. Onmet Ae,0 In the litrewtim 44 KIWI, Irflaw'Irr-n i"llpf, 40 firetl of -1111fite sn't A. fit alleali, Ituall. ill ACWS; lid SAU Ul It. VVI14M latilli%. %411W. will. (d - t.32), Wiled 22 his. -00 , oo sulfate isms by lia(VAt-4. fillirtril. rv4lwl, it) iiiii) nel., anti 110 sall. ittry6h nos,wph,,us (by rvaln), of,ld, IICI -Alln l - 00 Z" tmated with 11. 85% Retell. Vittle 242.8 a, I (after reppla. File ilia I foll or III le,111IN 11-an a Ir-4. lum AIIA"ll-mv ft) fit.., 00 *~ as alewic). I Is quite stable in neutral ltr excid suln.. but give,,$ 11 6"11l 1. '4114 fit 4~411 IN- 11"Ill 1 .411, " leatme "t Nalf1ji JI fit fit, C 0010 X Diful . . , , p ~ 00 reaililrdet-am,pd.inalk.snin. 1000jr3ittloomiAleCelet ` ' compound of chryooldlue . 16a. i.!%i ^.. vwv., d gt. t *011, then neutrallite stand OTMIShet with 40 till. 151M N f 00 e' 4-0I N Pfl it) liders ti-S, the kn"*" Wine 2 CJI N) , j . # t , . , KIM. filteretf, the with Ilowltd. followil4l by 4W W, M to 0 e RIM. Rio (lyrs in thAt on trratilivilt with bisulfift its Nil, livoul, 400 Winter tile tevidur rvid. with but 991 is not replaml by 011. anti tile billulfite emn1wunif is but 00 and 5M nil, HIP ad.letl save WAM, jr. 11, in, 314* (frain jeo IMU'lly liall. In 11#01wifil'aritil: Ifer fallerd,wi not oinfain HIM). whk-b irrAilily cluples with -fi4simiurn wthis., tl4w% to 0 60 -51, reur affect, felits for till- leritt is atmit ill alliall otrial. I"%mite ,f the WtcrAct"m of not give a "ifirmtrus4i'le IL Nil ' 14ti I 141 N11 11 i SA l t L 1 COO , til . ll fi , ant it.). test 1 W , 00 a firup. Coupling with p-nifroatilline in the pm-sence ul " ' . 1.1011 orflatird LA Ill%.. 11"Ilrd W 1.36), anti lex) fill. K,C(N gave bnown- 7 coo ][4" the b"11111'r "allIWIL, jk4 (Irl,M (*v jqU, by atbill. of C,S(), hot with charto,ti, am -fl l m l 4111411 it% ow or titateir pr klilly of tile structisre i l). yt 09 'a solex.. "-twowu cery%t,16. Cimpling with beftsiltine xee~, Pro vrhk-h on boilill Witt) All";. V1011 hrrutle title- (2 78 Sj 9 . . amnse-irled prisms of I p-1 4,Y-110(K0*S) CAN: All CW, Iv l f f orlil y orallier. The a. 'itirl. Cill/Wh I, Ra and Ca salis (by metatheellit), yellow U, reddish p filsol. Ill xylelle; It is %table 14P Warill till pt. coupling of j;,~itro- sul. Iii AcOll, nt with fit. alkAh, even fit the 2,4,(II0)tCleI4SWI1 gives 24,54110), 'CkU but on treatrur i 1 lee* t regenerates . to. no NIf, k rvulml it! tile, repbrown. ;"t in" prmrss. The inother liquor from the prepti. contaisli Anlomholls bww" DWI& In Molt; Ag Pa anti ca Joe , . , 'wirt. S. If. but the rtumindcr of I is trinsfin-mvit into unidesiti. IW~ t l l f I f crys a -. I- y .i . tie I (), S in fit of I or Elio; Ag~rld lid Salt O illu'l Jollw- "'I'l w3fet . " . .t Wtlv)Wt,; CU14)..j.wsjjutxjvral,I,t. 'rhu. lhtxlibr > : , I f,N - a , ro,luct of t i 11 w Ii d :; IL f . p-r, v i w Ill.. a . t a tut p , an gr4i ' lle alm,ter 4'alplins In"llivi* ,1 11 WVto wo'llbulf.mAle, I illeo Prettil. Ittall Utt authrulic saillpir of It. U.-atins 1941r. =-I 0.. 4.9 -- -T -4- ek v a tie An L v FM a 00 1a so is" A I 3 0 1 if at U2 pt 0 1, ritol sit W0 Katt i o 0o o 0 0 7 0 0 0 a a a 0 0 0 0 0 0 0 0 0 6 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 - ---rw,l water.". Products, XI.- Blaulfte Cam"d of 00 so I. 4-neAdwquinciatt. Md. 74w. ObAkilid Ailim. (I - Alt 7 0* liirn' Chvin.) Is. U1114 A(IOU); if, V,*xublom 4. 10. ~ =Wt, PrAttkan of (I- - 9111". 00 0 (N NAIINN fV1111116 in AM"- 4012 111444 Of LiSSUIA1, . Jhf *0 99 ej has the %trurtare 1-1 the Nil lbr h &All of I O-J, sc;J (U) 1 00 00. I the umbal Propeniesilfbisuffile compda. T at.. 00 gne"t with alkali results In I and 1.3-diketo-2-hydrfifdrflr~ " 00 -sulfoclk " (M). ComPtexes at addwt%" tki6vihed 641111 00 by 11-3clivur. ft a). (C.A. 41. 747c). tould not t, &fill, oo 1 (2.2 X.) in 13 mi. Ittoll wits Imted with 4.4 -iii ;' ~ 00 IISO# solo. (d. Mi). tbie solvents tvinoved b- i-i'j, so eo o4 Parse, the rvsklue In 23 mi. water tmattA it. - A IF #11I l 4 (0A0 (43 30 JR) i Wi h 00 00 4 s m n. . lit I., n 1. g t ex. oI In wairr. less jibl. lit Rjoll. Illuol. it, Icip, 111 ,, oo 4 It*. the fliffetv onvoo iiii " tio trated with Chat 00 09 . . 1 $let flat 1410 avIj all. Millis . Fortiltv In-,If,llkl hy -I'1 OW,, 4111d Mfillfft4l; 161111". 14 Mind. 011"0 IflOst #Avv 1.10A 0 00 g. A-N4 bill lit 11, villorle" Iniallis, which. III Milli. NO* lo hi, K-441.01 -- givir vlAble tvaction with: ACNO.. U&CIO. ltd(OAO'. 60 04111 adda.ofeaustir 00 00 alkalies or carbimates gives I and Ill. The di-K sals 4il 11. Prepd, Sftnilarl~ Using K IISA. forms Cotoelm neirdtibi so hbellaving like the 4 analog; 2AA S. in I" mi. water. lei 0 411 44* slahil overnight with 24 S, KOII In .111 list. water atilt lihmil With all I hr.. yfffli-h4l 0.71 a. -6-K ~'Uof JU (titiato- so lev.1mir). Yellow timiks (front 7017,. 91011); addn. of 00 00 IICI to its wafin *if. solo. raive plates of the Puboo-K tali. 00 X11. Hisulfito compound of th" m"th [ph" th drattorte ,27Z 1 4 l h b h 1 1 z 7 00 ,4 c I -04p l tode. 1 iw. "31 , .. (I "U iiv,l Chem ) 20 IW 7 A Ali of . . gp 1 16 P1 % (I.N2 if.) (of. lifePhrriam. Ans. CAtwo. J. 211 301 00 00 (INN)) in 10 MI. Milli tmfcd (warm) with 3.7 mi.' so of N&tl9% adti. (d. 1.32). rrAuxed 16 afln.- filtmd, and l k l d h 00 coo e e biwa fite saiduct, I ow , pvto t ~. l h N 4 00 00 t e r. . Ial o4ItjO.j 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 oog* P 6 it x L a p 9 ru a s t km 191 AAO M &.117tit Ott go, 0t v an a it at n u is u r a w C 41 a a 41 4 lot cm AV Sut n 2.11111. lot 00 00 00 -"apadsa 03 Aft4t- 'Pug av r, A 'lip lp Aqptdvwv-m*jq-f ~;Pfff " - r c 10 '91A& Im (1) 11IN'll"Or ' ' m n I Ps"Y ' paw nCA D: -dvwn wo 10 071 D "A P" out =wq R r -t,-v5 1 'Ir-v- I I VC 'a a Iff" At 04 ft It U Vt f. 11 it A C, 11 11L. J A 00 - ** Al A 00 09090900008800 Ole it )f 00, if U #I it 0 4 it a P a 11 it it 0 09 fe 1. 4 PI"P 4 1 ""WW V A I- I A N % to It I A 00 1C NftkanLim of the b1sulfito reaction. V.-N.-VAUAWY. - 23941(1048) do S H we crick-its-d; their fumulottion of the main prod - h ( i t l h i 6 . -S- - Doblay Akd- Mank S- , e rVact ( em wforern rotp it ion c a l and Nall.S 16 go The roncluiiarts of Cowdrry sfut lliumbirlwood (C.A. 41, 6 hold to be faulty al: (1) in 411 ki"twil caes "I Alk. irra. usentof b1sulfile, runirkit. there uicur% lherleavagr ill Mr, not the rualical; (2) when or. arylatoine rr,Wur k, OW riadical which displaces the Ulf group, then shnult .11 Isn"'o with its entry therv takes lil4re the lois of the added bilul- 00 Me mot. Ifener, Cowdrry'~ inAin j,"Muct I, p"Juhly A *0 Nos N114 Joatif the bisulfite empj. .4 acid, white his secondary product must be a No sill 00 saft of the same cornpd. fit order to show that reactumt 0 olarrved by Coordrey do not Involve more deeply wisied : stnictural changes, the mAln trartio" product was 6u- 0 I lated and subjected to a typical ionic reaction with esce' ak. K1. The main reaction product was prepd. amording to Cowdrry; In the purification staige the ions of Cl and 0 SOj were removed by suldn. ofsain-4. of Ag and 9a acetates. 0 The Nor Nils suit of the hi%ulfile votopil. of 4.1 ("if (1) fin"" Joh'. (- .1do. n( Itto La - ha" P" - P&A~. 2 fortus. which differ In their content of Ut( ) Cr in,; at 10)"D ale. Comn. the pfoiluct ratile-Ins 1.5 mules 11#0 41:41 f-inth blunt needles. while W)% WWI gim a nurno- -00 -0 .40 -00 .0 0 Zoo i ;Jm 0 1;: . I IZOO I ;-9 0 -00 4160 -:9 0 9 -.00 zil hydrate, long ruvedles. A -4o. of #I X. of the product in d I ird. 11,0 treated with to g. KI in d ud. 1110 and then with -000 L) HtOll gave 5.79 1. K, salt of the bisulfite 150 ml. 951,'o op coapd.,.Ca1,,)VhKj.u.51/j(), of 1. G. M. Kmolapoff -00 7. ;-j1 It 'A AT -0 0 PW 0 0 1 IF 11 5 43 1 'M 11 An JIM At As it or g It It R X No n 1 4 0 a see *4*too 0 9000 0 00 0 0 0 0,4110 0 0 0 0 a 9 0 0 00 0 0 41P 0 0 6 0 0 0 0 0 0 Ce 0 0 0 0 0 0 0 0 * 0 0 0 0 0 0 0 0 Ole 0 0 0 0 0 0 * 0 0 0 0 04D a to COM bwtdre 0 te und of 2-me YI-1.4-naphlb"UIDWO and Ift reaction w ph"ylh Wue. ". t N~ Cf, CA. 43. :1 bowvtd SOMP4. of rmc thmutdIly *ith MAW- slit, oil stindiall. a Inlia, of tht Con"mmto In 1W In the pm.sence of MOT bruwti-otimSt nredles of the b). dratc Cdl.O.N~V.Va.311,0. which. treated with cold H(Olf and pptd. with HlsO. yirJd3 the Wight yvilow-greva exhyd. derir,; 66 can m6o be obtained front the hydrate on vacuum drying and treatawnt with MOIL 7he K salt Of the bisulfite adduce reacts aJmilarly. yielding the K amakj. allow nctdlc3 in anhyd. fonn, omnse-red amn in the Ydrated Imm (not analyzed (or HtO content). The reac- gm with PhNIINII& does nui prin-v the prmner of a cax- bOU) I group iU.thC COWIPd. 6111CC the FCaCtkRk n1&Y proceed 11 replacement of the Off group of the lAsulfitc adduct by.4 I'MIN11 rcidut ,which with alkali yields the phen)-l- llydrazone, of the (Wiginal Cartgnsyl '.0fughl. ((Autoulctiv with tilt-ali) deriv, I'l Ilm t-cwt"Imulins naphlbol). Thr bi,ulfitr adduct 44 t.5-110C.II.RMI could not be ueetylated VY hot Auto. the b.4111C bultIm for the b6ulfite adducts Uf M thul di3- proving the contention of Bochyar. rt a]. (C.A. 43, IWA). ronerming the tructure of these adduces. 0. M. K. UFLIME-Fe, V-14- Chemi.cal Abet. vol. 48. No. 5 Mar. lot 1954 .OrganiC ChemistrY & ci-I 71-1quiale C-0111 c 0 f co -Mp 0 lin-d a' rrO-mLLfi7-"a:I7Fu ue Ze. V~-M. I ~rflimItts;eIv. J. r,.- rA.- M I -] 'U.S.S.')?. 22, 723-5(1952)(Engi. tram7;&-tTo-n.--&e C.Ai 47, &10.3a. XVI. The b1suffite com?ound of I-arnlno-&~. tr Inaphthol-2,4-disulfonic and V N -t-;Pv and 1.1 1 Ch myak., Ibid, 983-4.-See C.A.47. 5403e.. 14. T. -Ti MI-77- 7 - , 1jr-Im-rSev, VN, udeus. Mobility of balogen ia 1q. 1-Hitr(l-t-hremn 33.3"; R-nitro-l-brojno P!5;~ 3-mtrv oroAhi ov , .. . mina ni2, -a f)~2-~romo ' I fl-nitra-2-hrrm,j 2 4 4r, kcmi,ric . "-oit -)nw 4,5J` ThE re in se 'Ic'! 11.)- Witt) !or I;.1 p1p, 1-5 bri. ~t anzi !n, amt. of Atr!k, roduccd pr" mu,! v Ic -..-A by thp Br ium v IcIrl Thv 2- ind 4 6,-r1Y3. react rapidiv ("ett Rt lf'W; OIC -o. -m o'. v -W. .r~A less activv ~Cf MCIxish alld Camplell. C 11 N).9 " (,I i,ri, Ls inte!"Ielfiatu- 1 I -, 0 ro-2-hromo avi,f 13-ti it r- - I ~h-mo ~iv - al! 1; 11911 It i, ~-l 2 Vvry weakly activC at Addn. of aecdorme-i arid prornoteg the rl~tivitv of the Br in th6 '- 2 ~r ,-11110 Ali otlmr durivi. do oot reaci '11 ICWI*. I-Brnnio- ) 4-, r,, -mid 8-imm deri- to wit renct m I ht . at P4-4 ---iit tl-- I -bmmo d,~riv. macts to an extent of ist I ~,r thYfatrliftc 11) 73 2 7 'J- ~"; 200' In I br 11~, dcri,. K.-e . , * 2 10- 1 f) 5 f-l-,ion at 1Ix)', :~)Ac*,, It (l4'-' it 1 -Al V I A',~, at c . --d i rig 1" :,.Id 1, 111,Z1 ,j, I?, ' 73 alld 97 1' a f .2110, At i1--,' i ' 2-tiitro d"i, (,t, t 1 10 2-BrC.,,Hi react: at (emP C10H, anti 21.7% . . , 2W, 1i -:ii - I , I -rved in I hr.; 3-nitro-l-hrarno lit f/1,9canirmionswertobs- I 6-nitro-l-bronlo 30-V',; Vf1mrsev, \/.~J- USSR/Scientists - Chemistry Card 1/1 : Pub. 151 - 37/37 Authors : Rodionov, V. M.; Vorozhtsov, N. N.; Smirnova, A. F.; Shchetinina, L. A.; Shestov, A. P.; Korolev, A. I.; Lukashevich, V. 0.; and Ufimtsev, V. N. Title : In memory of Evgeniy Alekseevich Ivanov Periodical : Zhur. ob. khim. 24/3, 579-580, Mar 1954 Abstract : Eulogy is presented honoring the passing of E. A. Ivanov, chief of the Central Laboratory of the Dorogom:Llov-Frunze Chemical Plant, scientist in the field of organic semi-products and dyes) recipient of Stalin premium. Illustration. Institution: ..... Submitted : ..... bo",11t/Chemistry - Physical chemistry Oard 1/1, Pub. 22 18/45 Authors. Ufimtsev, V, U., and 14alafeyeva, 14. M. ~Title VLobi3 ity of halogenin the benzene nucleus Periodical Dok. AN SSSR 99/4,, 555-558J. Dec 1, 1954 Abstract The effect of nitro -group.s on-Bractivity in a benzene nucleus,is explained. The method by which the activity of Br was determined is briefly described. It was established that the entry of one nitrogroup into m-position increases the activity of Br but the halogen of the m-nitrobromobenzene remains non- reactive; wherea's the entry of two nitrogroups into m-position sharply in- creases the halogen activity. Ten references: 6-USSR; 1-USA; 2-German and _(1888.0953).. Tables, graphs. :Institution The K..E. %oros-hilov- Scientific--- Resbarclf i_n_siA_,tu_te-,6f` and Dyes .Presented by: Academician A. V,.Topchiev, June 25, 1954 kVTHORS: Dashevskaya, L. D.,_Ufimtsev, V. N. SOV/79-29-1-6o/74 TITLE: Investigations in the Field of Dyes for Acetate Bilk and Synthetic Fibers (Issledovaniya v oblasti krasiteley d1ya atsetatnogo shelka i sinteticheskikh volokon). ii. Disyerse~Dyes_ Derilatives ' of 1-Alkylamino-anthraquinone-2-carboxylic Acid (II. Dispersnyye krasiteli-proizvodnyye 1-alkilamino- antrakhinon-2-karbonovoy kisloty) PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 1, pp 285-287 (USSR) .ABSTRACT: The chloric anhydride of 1-nitro-anthraquinone-2-carboxylic acid COC1 (I) has two reaction groups: the chlorine atom in the acid halide group and the nitro group in position 1 of the anthraquinone nucleus which are both capable of reactions, es- pecially-with amino compounds. The nitro group which is mobile in this case is under the influence of completion and activa- tion of the acid halide group which is in ortho-position and very reactive. In the case of reaction of this chloride an- hydride with amino diglycol (H NCH CH OCH CH OH) 01-oxy-ethyl- Card 1/3 1 2 2 2 2 2 SOV/79-29-1-60/74 Investigations in the Field of Dyes for Acetate Silk and Synthetic Fibers. II. DdLs]~erse'DyeB -Derli-mtives 1-Alkylamino-anthraquinone-2-carboxylic Acid P-oxy-ethyl amide of the 1-(Ol-oxy-ethyl-o-oxy-ethyl-amino)- anthraquinone-2-carboxylic acid which can be used as a pink dye for acetate silk. In the case of reactions of compound (1) with other amineB the nitro group showed a lesser activity than the halogen of the chloric anhydride group. The nitro group does not react with diethyl amine. In the case of a fur- ther synthesis of the thus formed weakly colored diethyl amide with primary aliphatic amines, the nitro group reacts also by formation of blue-red disperse dyes which in position 1 of the anthraquinone nucleus and in the carboxyl group have the radi- cals of various amines. This behavior is explained by dif- ficulties with respect to spatial distribution of the carbonyl group of the anthraquinone nucleus. The pink or red dyes syn- thesized which can be used for acetate silk have similar prop- ertie8. There are 2 Soviet references. ASSOCIATION: Nauchno-issledovatel'skiy institut organicheskikh polupro- Card 2/3 duktov i krasiteley (scientific Redearch Institute for Organic SOV/79-29-i-60/74 Inve-stiga Lions in the Field of Dyes for Acetate Silk and Synthetic Fibers. II. Disperse Dyes - Derivatives of I-Alkylamino-anthraquinonp--2-carboxylic -Acid Intermediate Products and Dyes) SUBMITTED: November 19, 1957 Card 3/3 GRINKVA, R.I.; TISHGHENKO, A.D.1 UFIXTSEV. V.N, Dyes for acetate Bilk and synthetic fibms Part 3: Clx,&tiOn 040 styrene and dimethinocyanine dyest dorivatives of indoline. Zhur.- ob.khim. 32 no.6:1919-1922 Je 162. (MIRA 15:6) It 14auchno-issledavatellskiy Institut organicheskikh polproduktov i krasiteley. (Dyes and dyeing-Rayon) (Indoline) GRINEVAO N.I.; FUCHKOVAI V.V,4~~ ~VV~-N Derivatives of cerazidtim 'Part 1s Debydration of 1.4.diar7laminoanthraquinones. Zhur.ob.Udz.. 33 no.2s5W-600 P 163. (MM 16 -.2) 1, N2chno-iseledovAtel'Bidy institut organicheskikh polupro- duktAl('-i krasiteleyo (Anthraquinone) (DeWration (Chemi8w)) GRINEVA, N.I.; SADOVSKAYAq V.L.;-LV-IHMFY+-V-tNt Synthesis of 2-phenylindole and its 1-methyl derivative* Zharo ob.khimi. 33 no.2s552-553 F 163. (MIRA 16:2) 1. Nauohno-issledovatellskiy inatitut organichaskikh poluproduktov i krasiteley, Moskva. (Indole) YEFREMOVA, T.K.p nauchnyy aotrudrilk; UFIMTSEV, V.P. Dust control measures in the mechanized longwalls of Chelyabinsk Basin. Ugol' 37 no-3:55-58 Mr '62. (141RA 15:2) 1. Gorno-pologicheskiy institut Ural'skogo filiala AN SSSR (for lefremova). 2. Glavnyy inzh. tresta Kopeyskugol' (for Ufimtsev). (Chelyabinsk Basin--Mine dusts) bTI1141IISTITY 77. V. An Attachment for the YyErostat. Meteorol. i gidrologiya, No 6, 1953, pr, /..7-1+8 The nroposed attachment to the hygrostat is designed to be successfully used not only for the mass verUication of hair hygrometers but also for the verMcation of aircraft meteorog1raphs, radiosondes, and hygror.,raphs. In a bygrostat wLth such an attachment the canacitv is doubled and a more un1from means for all in- struments under simultaneous examination is aftaLned; Ln addition, greater facilities are created for the installation of pens and pointers, and the oneration of taking down the rea6ings durLng testing is simplified and made more precise. (RZhGeol, No 5, 1954) SO: Sum. No. 568, 6 Jul 55 UFIMTSEV, Te. Success is achieved by cooperation. Izobr.i rate. no-7:30-31 Jl 16o. (MIRA 13:8) 1. RukavodJtell tRekhovo--o obahcbeetvennogo konatruktorskogo lAyuro Uralvagonzavoda, g.Nizhniy Tagil. (Nizhniy-Tagil-Founding) TIKHOTMV, S.A.; PrInimall ijohastlye, KRAYEVSKAYA, R.S.,- Mech 'anical carryirg out of pulp particles during flotation. 7Svet. met. 37 no.9s4-8 3 164. (MIRA 18s7) :7, - -7 7-- UFINT!0,P---.2-LL I FI-MLAND, T.M. A.A., ROZOV, N.N, N.A., IVANOVA, Ye. N. (Frof. Dr. Agr. .-;ci); and NOSIN, V.A. (Cand. Agr. Sci.). "Brief Description of the 3oils in the Are-as of New Land Reclamation," Fublished in- An aid to Agricultural Srecialists in "he Reclamation of Virgin and Fallow Lands, Sbornik Materialov, i Statey, Vol. 1, pp 25-144, 1954. Tranlsation No. 431, 30 Jun 1955. BOGATYIWV. K.F.: VADKOVSKAYA, O.A.; GERASIMOV, I.P.: GERASIMOV. Iv.P.; YEROXHINA,, A.A.; IVANOVA, Ye.N.; LETKOV. L.A.; LIVEROVSKIY, Yu.A.; LCBOVA, Yej.; NOGINA, N.A.; ROZOV, N.Y.; RUDHEVA, Ye.H.-, TKOB]OKO, V.I.; UFIMTSBYA, K.A.; FPIIFLMTD, V.K. Academician L.I.Prasolov; obituary. Izv.AN SSSR Ser.geog. no.2: 73-78 Mr-Ap 154. (KLRA 7:5) (Frasolov, Leonid Ivanovich, 1875-1954) KCRM, Mikhail. Adamovioh; MMYXf, Oleg Vladimiroviah; NOGINA, Mina Alekseysma; t? drevaj,"; SMIN. A.U., red.; IKRUM, A.F., to red. [Boil soning in the LaI0.0 Baikal portion of Siberia] Pochvennoe raionirovanie Beikal'skoi Sibiri. Ulan-Ude, Buristskii komplekanyi nauohno-inal.in-t. 1960. 66 p. (um 14:3) (Baikal Lake region-~-Goils) UFIMTBAVA K.A., nauchnyy ootrudnik; IYANOVA. Ye.Nej prof## oty.redo; T I IKEWHI 0 K, V.N., red.izd-va; TISHORDWA, S.G., tekhn.red. (Steppe and wooded-steppe soils of the Buryat A.S.S.R. and their agricultural characteristics] Stepnye i lesoatepnye pochvy Buriatekoi ASSR i ikh agroproisvodotvennais kharakteriatika. Moskva, 1960. 149 p. (MIRA 13:7) 1. Akademiya nauk SSSR. Pochvennyy institut imeni Y.V.Dokuchayeva.. 2. Pochvennyy institut im. V.V.-Dokachayeva (for Ufimteava). 3. Zaveduyushchiy otdolom geogrefii i kartografii pochv Pochvennogo instituts Al SSSR (for Ivanova). (Buryat-Konj;olia--Soils) IVANOVA, Ye.N.; ROZOV, N.N.; YLUTINJI, J'L.A~; NIOEEI" V.'i.; UI!K-MTEI.~-,-K A ; Pri.aimali uc~~;Stiyc: YP.14.; Ifi~')VTi, 4"i.11.1- BUDI'11?-, I.F.; VIST,-,:'IBY;.f~., T-.V.; GLIASIBNi- I.F.; 71- KOSPELE"Ill-, I.T.; E,7_, "' 1 SOh,-)LOVA, T.A.; V.0. New materials on general geography and soil classificalkli.)n of the polar and borea3 belts- of Siberia, Pocl~vovedenie no.11-7-23 NI ,61. (IURA 14:12) (Siberia, liorthern--Soi-ls--ilasEification) (Siberia, Northern-Ge3graphy) uFlmTSEVA, K.A. I Mountain taiga solls In Transbaikalia. Pochvovedenie no.3:51-61 W 163. (MIRA 160) 1. Fochvennyy institut imeni V.V.Dokucha va. (Trarsbaikalia-Zoilsf ADAMESKIJ, R.A.; UFIMTSEVA, M.P.; KUDRYAVTSEV, I.P.; GELID, P.V. Texture formation furing the annealing of strongly deformed silicon iron. Izv. vys. ucheb. zav.; chern. met. 8 no-5:133- 139 165. (MIRA 18: 5) 1. Urallskiy politekhnicheskiy institut. 011ENOVICIII N.L.1 UPIMTSEVA, S.N.1 11,0GACHKO, MJI, Separatinn and determtration of jgall,lium,, incitt-n, cadm-1.um, and zinc by paper pnrtltion chromatography. Zhur. anal.. kh1m, 20 no.12tI368-1370 165. (,vJRA 1802) 1. Odeaskly gosudaratveinnyy universAtot ivionJ I.T. Yechnikova. Submitted Januqry 18p 1965. Ewa Direct lrl(rCdukfA [,-,roup Lnt./) ant*-r--.-,-,- Of t and )OjyCyejJC all4nones. Zhur. ob. klilm. 34 D 16-1, 01-11',~A 18-1) i krasiteley. "jnVeZ-:tjf?r-l-*(~ 4n the :'Jelcll oz Lf: CC71, O-rlcls. (J-., U.L hydrazine and Disi-lph.ltp an the b- S(~: J:)i rnal of Gene---.-al Chemi ~ r-.," (-'L)hhchei K' ilri 1' 46, Vr SOV/5-58-4-17/4~ A,'17HORS: Adamovich, A.F., Zonenshayn, L.P., Sulidi-;'ondratlyev, Ye.D., Uflyand, A.K. TITLE: New Da`rr-,Y_,Y-the Stratification of the Sandy Cl9y Strata of theWastern Sayan (Novyye dannyye po stratigrafii peschano- slantsevykh tolshch Zapadnogo Sayana) PERIODICAL: Byulleten' Moskovskogo obshchestva ispytateley prirody, Otdel geologicheskiy, 19,56, Nr 4, p 144 (USSR) ABSTRACT: This is a summary of a report given by the author at a meeting of the Moscow Society of Naturalists on 11 March 1956. In 1957, the authors of this article, together with O.A~ Semenova, A.E. Kalis and others, tried to analyze the stratification of the sandy clay atrata of the Western Sayan. They reached the conclusion that -there are throp lifferent series; the lower series consists of the Syatkhollskaya ardUrskaora formations; the second series of a frequent, sometimes rhyth- mic alternation of green sandstones, Piltqtones and argil- lites; the third series, of the Shignetskaya formation, The names Card 1/2 SOV/5-518-4-17/43 N,ew Data on the Stratification of the Sandy Clay Strata of the Western Sayan of the following scientists are also mentioned- G.M. Vladi- Mkskiy, A.G. Sivov, 1.K. Bazhenov, N.A. Batov, as having worked in this field. 1. Geology 2. Earth--Struotural analysis 3. Sand--Geology 4. Clays--Geology Card 2/2 AP SOURCE CODE: UR/0210/66/ooo/oo6/0050/0059 ACC NR, 603 90 AUTHOR: Zonenshayn, L. P.; Natapov, L. M.i,yrly-and, A.K. nRG: All-Union Aerogeological Trust((Voesoyuzbyy aerogeologicheskiy TITLE: Structtnre of the Aldan branch of the Priverkhoyansk foredeep SOURCE: Geologiya I geofizika, no. (;, 1966, 50-59 TOPIC TAGS: geologic explv.,~-,tfon, anticline, geologic surveydw:q, _pM;*e=w, foredeep, I , K~"L' ABSTRACT: The structure of the Aldan branch of the Priverkhoyanak 4- foredeep is described. Steep flexures alternating with gen.ly sloping echelon brachysynclines characterize the boundary region between the Verkhoyansk folded region and the Priverkhoyansk foredeep. The limit~-iig folds are oriented at a steep angle to the foredeep strike, plunging east-southeast. These folds can be traced within the inner zone of the foredeep. A system of narrov anticlincs, separated by - broad synclines is also found in the inner zone of the foredeep. The entire Verkhoyansk complex consists of Permian-Cretaceous formations. The outer zone of the foredeep is composed of Juratisic and Cretaceous formations superposed on a Lower Paleozoic basement. The inner and Card 1/2 LLMI. CY3.99. ACC NR: AP603449o outer zones are separated by a, marginal suture-type deep-seated fault. Orig. art. has: 1 figure SUB CODE: 08/ SUBM DATEs 23Apr64/ ORIG RM 01.2/ OTH REF: oo6 -2/2 MITM AND Tootonica ard thir., hi -itorf of dfrn-:IapmA,rA of thr, rio~theastem end of the 'Palmyrides (BYT?,a). G6ot,-Atondka no-3;20-36 Mq-Ja 165. (MA l8j6) 1. Vaeioy-uzTiy-y a(-ogt--.I.ovjclwmkj.y trent C-c-.,qud:ir.'3tvonnoFo geologicheskogo kondte-Aa I-lo,-,kvL,. UFLYAND, AoX* Development of swell-like uplifts Arabian plateau as revealed by a Sov, geol, 8 no.2tl3l-137 F 165. In the northern part c"' study in northern Syria. (MIRA 18412) ROZENTSVEYG, S.A.; UFLYAND, N.Yu.- SHCHERBAKOVA, Z.V. Adsorption of sulfur in iron in alkali solutions. Zhur. fiz. khim. 36 no.3:557-561 Mr 162. (MIRA 17t8) 1. Gosudarstvennyy.soyuznyy nauchno-issledovatel'skiy Institut. UFLYAND N.Y, I FCZP,,`, Y U -14~ Effect of electrolyte concent:7a7lion- O~ tt- oxide-rdckel elec*lrcje. Part '1-. 7hur, 341-344 F 165. (KI RA 18, 4 1. akkurnilyatc), nyy RUKHOVETSO A.N.; UFLYA~Pulk;'-Sp Electrostatic field of a pair of thin Bpherical C*'o'liv .Z. problem), Zhur. t*--kh. flz~ 35 no.9jl532-1536 S 165. (MIRA 18ilO) 2. Fizikc--tekhnicheijk1,y inrititut Imeni A.F,Ioffe AN SSSR, Leninarad. 0 solutloils of (2) Lo the cor,,(,~z;popaxyT.7, eljkil~" Tilf- tva-zisi,ent hm--trer, can bo found -ef' e-ct;s Pre orm LdeTed Tor -the lateral ~60.y frOill L IP. I i-f-a 16'r's of --Arvt,~~j Pnd analogous,r iml-os are found. rl P16 I a took A a n 14 A A 1-7 is M N 11 U 11 w b A V Is P C it $4 09~A It- k -A _JL_I__6_ I I -A-t # _P ra AA to tx op is it 4 1 1 _ttv 0 4 TLW ChatractiorlAt ics of Rec lar Plates With Clamped of M-Oder the Effect of an Arbitrary d origWItext in usslan). MA.Grinborg. Y SAUII ~ AMM&th.& Mech. (USSR) 09 July-Avg 140112.4 w-Mififf1h 4 3-434; 6 Mus, 9 tb, 45,rq. 00 F';r the problem Of bending of rectautgular Plates Witt, l .00 C amped contours, which h" a great practical signUicsace, an 40 0 accurate solution b4p not as yet been fowwL The approxinute 0 00 00 avallAble solutlocts lead only to complicated Calculaitiona rven t = 00 I one Lm only Interested In the bialc calculated data (buckling in the center bending moment in the middle 01 aw c to 4;* 0 , on u 1 etc several Inte The article presents a solution of ral ) 00 r go al . . g , Uons. whicla alffiough wit very accurate load to a very effective IAIII approximation. Approximatiop formal" are given by meA" 0 09 of which, the bending elements (buckling, bending moments, 00 shleAring forces, etc.) for any exterW tomb can be easily A calculaitied. Several practical calCulAtIM3 wort made and their results are UbulatecL Is. 3 so 0 00' ~ It it AI 'A 9 Its ft it 00 0 0 0 41 0" 0" 1 1. 0 0 0 0 0 6 0 0 0 * 0 # * 41 111 0 0 0 00 a 0 0 0 0 0 0 0 to 0 0 a 6 0 0 0 0 0 * 6 0 4b * * 0 ep USSR/Physics- Elastic Theory Mathematics Jul/Aug 49 "Bending of a Rectanpular Plate With Supported Edges Under Arbitrary Load," G. A. Grinberg Ya. S. Uflyand, Leningrad Physicotech Inst, Acad Sci USSR, 31 PP "Priklad Matemat i Mekh" Vol XIII, No 4 Submitted 11 Feb 49 Problem of bending of a rectangular plate with reinforced edges, which has 6reat practical importance, has not been solved accurately up to now. Approximate solutions lead to cumbersome calculations. Reduces probLem to the solution of an integral equation which admits of a very close approximation. DeriNes approximate formular which may be used to calculate bending elements (sags of bending moments, intersecting forces) for zr- ious external loads. PA 61/49T90 gr-~RPp YA. 1; -26902 1 Krucheniya Prizmaticheskogo Sterzhnya S Profilem, Ogranichennym fugami rvukh Peresekayushchikhsya Ikhsya rkruzharostey. Doklady Akad. Nauk SSSR, Novaya Seriya, T. LXVIII, No. 1, 1949, S. 17-20 SO: LETOPIS NO. 34 UFL)6D_. JA- S. Bipoli&Me koordinaty v teorii uprugoati. Moskva, Goatekhizdat, 1950. 232 p.P cKagm. (3ovremawVe problemj mekhmiki) Bibliography: p. 231-232. Title tr.: Bipolar coordinates in the theory of elasticity. QA556.U3 SO: Aeronautical Sciences and Aviation in the Soviet Union, Librari of Congress, 1955. puts UFLYVID, Ya. s. USSR/Phyelcs - Ela$Ucity' I Jun 50 Vibrations "One Case o -f Bending in a Rectargular Plate," Ya. S. Uflyand, Leningrad Physicotech Inst, Acad Sci USSR "Dok Ak Nauk SSSR"' Vol LXXII, No 4y pp 655-657 Considers thin elastic plate In form of reciangle bent by arbitrary tren verse load q(x,y). Three sides are clamped, but fourth is free. Problem has never been considered before. Finds solution as boundary-ralue problem. Submitted 27 Mar 50 by Acad A. F. loffe. wMF 165Tio4 P '65T104 UFLYAND., Ya. S. USSR/Physics - Flexure (Bend) Plates PA 174T67 21 Sep 50 "Solving the Problem of Flexure in Rectangu- lar and Sectorial Plates for Certain Boundary Conditions," Ya. S. Uflyand, Leningrad Phys- icotech Inst, Acad Sci USSR -DOk Ak Nauk SSSR- Vol IXXIV, No 3, pp 437-439. Considers rectangular plate one of Vhose sides, for example x = 0, is Clamped and its opposite side (x w a) rest freely; here the other sides can be constructed in any 7-nner. Submitted 3.1 Jun 50 by Acad A. F. Ioffe. 174T67 R TT7F"L'_TAND3 Y. S. USSR/Mathematics - Transformation, 21 May 52 Mellin "Application of the Mellin Transformation to the Problem Concerning the Flexure in a Thin Elastic Wedge-Shaped Plate," Y. S. Uflyand, Leningrad Polytech Inst imeni M. I. Kalinin "Dok A Nauk SSSR" Vol LXXXIV, No 31 pp 463-465 Considers a vedge-shaped region in polar coordinate (r,9) and the deflection w(r,Q) satisfying the usual eq and boundary conditions. Proceeds to set V in integral form and solve by means of the Mellin transformation7, taking boundary conditions into consideration.- Submitted by Acad A. F. Ioffe LFFLZL-Mi. Ya. S. dhYAND KRtheniatical Reviews May 1954 Analynis /Grinbeg G A i Lebedev. IT. N.. and Uflyand, Ya. S. A 0 i~=15XIff6in-of -i-g-eneiiI bMaiii_a&7e_P_r6b_Ie_M_ for a rectangular region with given values of the function and Its normal deAvative on the contour. Akad. Na%ik SSSR. Priki: Mat. M.L. i7,73-86 (1953). (Russian) The boun, ary value problem in question is the deter- mination of w(.i, y) such that AAw- W-Q(X, A (0:0 a~p) CX3 T") ', awlap = g(s), on the boundary in a domain D, and w=f(.t) of D, where P denotes the outer normal and Q. f, g. are given functions. Section I describes the general method of approximation, which consists essentially in determining the harmonic function Aw-Awo %'where wo is any chosen particular solution of AAwq=Q(x, Y) in D) as a linear com- bination E.%caf. of an orthonormal (ff4.~.dxdy-o if =1 if w-Z11) coerce of functions )Y'1 which ore harmonic in D [scc Grinberg, Dn'Hady Mad. Naul. SSSR (N.S.) 76, 661-664 (1951); these Rcv. 13, 18.1; this inctin)(1 is --imilar to that propo5cd by Alif-and *1, Rend. Sent. Nl:it. Univ. Rortia (4) 1, 262-206 (1937)], Given an orthonormal sequence of harmonic functions for D, nunwri- cal approximations for Aw, which is of direct interest in the theory of plates, may be calculated. If approximations to w are desired, a knowledge of Aw, plus the boundary rondi- tions above, enable one to determine w by solving either a Dirichlet or a Neurnann problem. Section 2 contains the explicit construction and tables of a suitable orthonormal sequence of harmonic functions for it rectangular domain. Sections 3 and 4 contain applications to various problems of a square plate tinder symmetrically placed concentrated loads and to the plane problem of the theory of e1, asLicity. J. B, Diaz (College USSR jkmj=rtxdbz~~L MPOV 1443-61 (IM).-A aafluz is writtzi; for ilie =dl- don that the adsorption (in &.e grains of tile ads"ticat Is not an eqaII. value, but Irail's by a time v. This equation is - Ox/al) - I wlqb) - (bc/af) - 0, wh= v is. the velocity of the liquid In ml,lm, q the erm w-dozi of ' the mIumn, k a ocinst. (036 tum of the adsorption =St.. and ther coeff. of porosity) ''2nd c tile concil. Thiq cquelani wis; wlvcd by means of Lapta-ce transfers both for the cm oil frontal and of clutiNe chiumtopiphy. S. pakKvz-j - ; , q~~ z-z- 3.- !i~ f:4;?z 1MMAN. U.N.; SMISKAYA, I.P.; UFLYAND. Ya.S.: AXIMT. G.P., redaktor-, '~4 VOLCHOK, K.U., tekhnicbeskOyl"~~O.' , -- [Collection of problems In wthematical p~7slcsj Sbornik zadach po matenaticbeskoy fizike. Moskva, Gos.Izd-vo tekhniko-tearet. lit-r3r, 1955. 420 p. KRA 8:10) (Mathematical physica) U~ A GRINBERG, G.A. (Leningrad); POKHOVSKIY, A.U. (Leningrad); UFLYhUD. Ya.S. (Leningrad) Characteristic state of stress of an elastic thin wedge-shaped plate with a fixed and a free side. Inzh.abor. 22:193-198 '55. (ML'RA 9:5) 1. Leningradakiy politekhnicheskiy institut imeni M.I. talinina. (Elastic plates and shells) (Strains and stresses) FLY0 IV D~ Yo-S. Category :USSR/Radlophysics - Radiation of Radio Waves. Antennas 1-5 Abs Jour :Ref Zhur Fizika, No 2, 1957, no 4488 Author :Grinberg, G.A., Lebr-dev, N.B., Skal'skaya, I.P., Uflyand, Ye.S. Inst :Leningrad Physicotechnical Institute, Academy of Scirnces, USSR, Len- i-ngrad Title :Electrom6agnetic Field of Linear Radiator, Located Inside and Ideally- Conducting Parabolic Scretn Orig Pub :Zb. eksperim. i teor. fiziki, 1956, 30, No 3, 528-543 Abstract :Analysis of t-b ',e problsm of the reflectioa of an electromagnetic wave from a conducting screen, shaped like a parabolic cylinder. The source of oscillation is considered to be linear and placed inside tue cylinder, and the current in the sojxce is I-= IOeiVt where IO-A const is the ampli- tude of the currentandLO is the angular frequency. It is shown that the results obtained in previously-published works are not sufficiently well founded. An accurate solution of the problem is given and is re- duced to the ablution of an equation with separable variables; the fun- damental difficulty lies im a suitable choice of the partial solutions, Card :'1/3 Category : USSR/Radiophysics - Radiation of Radio Waves. Antennas 1-5 Abs Jour : Ref Zhur - FizilA, No 2, 1957, tio 4488 satisfying all the requirements, including the radiation condition at infinity and the correct behavior at the source. The author considers first thd case when the sourci of oscillation is located along the focal 1~ne, -,,The_partial solution to the prob&em is found in the form 'A 00. where u is the secotllry electric fiel and (Oc are the parabolic coordinates; O-L) and B V ( ~ ) are expressed in terma of degenerate hypergeometric functions; the real part of the parameterY varies in the range -1/2- < R (VI < 0. It is possible to assume that the general'solution is of the form X0. / 13 4 LL Z ~ J01 where 046e- 1/2. an the surface of the parabolic screen the electric field E vanishes, i.e., u - -E01 where EO is the field of the source. This leads to the equation ('70 Mae unknown function C is thus found by expanding the field of Card 2/3 Category ! USSR/Radiaphysice - Radiation of Radio Waves. Antennas 1-5 Abs Jour : Ref Zhur - Fizika ,, No 2, 1957, No 4488 the source in the integral in terms of the functions A(1)('~ ). It is proved, that the dolution obtained is a general solution of th e problem. It is shown that for the case of high frequencies, the solution assumes a form corresponding to the geometrical-optics approximation. The solution is generalized to include the case of arbitrary location of the source along the axis of the cylinder. Bibliography, 10 titles. Card 3/3 t Call Nr: AF 1108825 Transactions of the Third All-union Mathematicl Congress, Moscww, Jun-Jul '56, Trudy '56, V. 1, Sect. Rpts., Izdatel'stvo AN SSSR, Moscow, 1956, 237 pp. Uflyand Ya S (Leningrad). On the Solution of One n_~~ _ffixed Problem in the Theory of Elasticity for a Half Space. 213 UFLYANID, YX. S. Doe -i:-hys-~Aath Sci -- (diss) nrob'Lems of the theory of elasticity solved -.-d-th--b*e haIp of integral transformations." Len, 1957. P/ pp 20 cm. (Min of Higher Education US3R. Leningrad Polytechnical Inst im I.I.A. Kalinin), 100 coPies (KL, 21-57, 98) SUBJ-'-P,CT USSR/MATHEUkTICS/Differential equations CARD 1/4 PG - 564 AUTHOR UFLAND Ja. S, TITLE The contact problem of elasticity theory for a punch which is round in the plan for existing cohesion. PERIODICAL Priklad.liat.Mech. 20. 578-587 (1956) reviewed 2/957 The author gives a rigorous solution of the mixed problem of the theory of -r2 . ...... elasticity for the half space z,;~O, when in the domain z - 0, r,4a (r- x + the displacements u,y,w are given and in the domain z - 0, r> 0 the stresses 6"zt-C zx 9,,C ZY . The elastic displacements are expressed by the four harmonic functions (Pi (iwO,192,3) of Papkavid - Neuber. For the solution there qxe introduced toroidal coordinates o(, and Y by the relation r + iz - a th The six boundary conditione [u) .0 u0( ril, ... are completed by two further relations (since four Irmonic functions 41, are at one'E disposal)z co n in r r e where F - + X ~, + Y + z -P nX 0 4)0 ~2 and F nare unknown constants, Pri.klad.Me.t.Meeb. 1-0-,- 578-587 (1956) CIRD 2/4 D (~, 2. -fj- + y fV I - 2 ~3 z PG 564 where V is the Poissou ~oeffieient. These relations lead at once to two separated boundary value problems for the determination of q51 and ~2 0, 40 - V 21AU + x 0 2(1- V) -zj -I C, 0 X0 '0 -0 f-r ~2 0, 40- a 2 9 20- V '102 _ A-0 ruo+ 11Y Pwo TM Pair Yo In order to sati fy the remaining boundary conditions and the -relations 1. and 2., then 'P3 and F4 must be determined from the following systemi A ' 0' ~4 ' 0' ( IL + z _~2 ) (xu + Y-V modulus of shear AMO 2 ('1' - -47 bx2 -aY20 ol~ .0 Priklad.Mat.Mech. 20, 578-587 (1956) CARD 3/4 PO - 564 zo I Z~ [(3-41) 2rwo + [x 7-, + Y ~~z ] 3 t.0 4 242 [2 (1 - 10 +41 do + 4y 2V + -P; -Y ~-v ?z 2 1 PW%T t air [0-2Y) 20 IXr X0 + Yr 01 y F air For the solution of this boundary Talus problem the author applies the par- tioular solution of the Laplace equation in toroidal coordinates V.hd -+cosa �P' Pm , (.h CK) e'a - 1 +ir where P are Legendre functionst and he finds 03 and 44 in the form Priklad.Mat.Mooh. 20t 578-587 (1956) CARD 4/4 PG - 564 00 im Am +BM hr] J.~chD( )dC. ~3, 4 TOh-7+ -COSA - 0 3 9 4 (C) ChPC 3,4(C)a MO-00 0 The.- this solution method is applied to the following concrete problemt external forces effect on a rigid punch with circular basis which is connected with cohesion with the elastic half space z3~0. It is asked for the stresses in the half space and for the relation between the displacements of the punch and the external forces. It is stated that a force effecting in the base plane which is directed to the center of the basis does not only affect a translation but also a torsion. A force couple in the plane of an axial section also effects translation besides of rotation. INSTITUTIONs Leningrad. YIA. LIA D SUBJECT USSR/MATHEMATICS/Differential equations CARD 1/3 PG - 694 AUTHOR UFLAND Ya.S. TITLE The aMilayMmetric problem of elasticity theory for a half space under boundary conditions which are separated by a circle periphery. PERIODICAL Doklady Akad.Nauk 110, 531-533 (1956) reviewed 4/1957 The author considers the equilibrium of an elastic half space (z;,;,-0) under the following conditionst inside of the circle r - a the displacements and outside of it the tensions are given. Besides of this the problem is assumed to be axialaymmetric. The displacements u r and uz are expressed in cylindric coordinates by the harmonic functions of Papkovid - Neibers (1) 2 _YF 2,~Au. - - '~ F+ 4(1- V F -W+ zo r 15-Z Pur r where &J- LZ(r,z), (r,z), 4 W- At- 0, ~A- modulus of shear, 9 - Poisson coefficient. Furthermores (2) "a 1P fl(r) f ~to 5- (F - '~ z z ZWO -flzno 2(r); r-C a r e- a Doklady Lkad.Nauk 110, 531-533 (1956) CARID 2/3 PG - 694 and D [2 0 f (r) 1-2 1 f -57Z Z-0 - 3 tPI Z-0 4(r)' r > a r> a Two functions and which are harmonic in the half space and satisfy (2) and (3) must be determined. The interior and the exterior of the circle z - 0, r - a are the coordinate surfaces #. 0 and p- r of the toroidal coordinate system z + ir ai eth 0(+L (0 e-- 0( -< C4 . 2 Therefore T andf' q>can be written in the form of integral representations in terms of the Legendre functions P-1/2+il, (chO() Doklady Akad.Nauk 110- 531-533 (1956) CARD 3/3 PG - 694 00 Voh o( - con f [0("C) ch~V + D(-C-) sh PIC ] P- -1/2+i-C (ch o( ) d'C 0 If (2) and (3) are written in new coordinates too, then the defining equations for A,BgC,D are obtained. The results are applied to the determination of the pressure which is performed by a plans round punch on an elastic half space in presence of cohesion. If the vertical displacement of the punch is w and the vertical force effeotidg in the axis of the pilkauhkie P, then it holds P M 4 -mw a ln(3-4 V) 1-2 %v INSTITUTIONs Physical-tachnioal Inatitutep Acad.Soi. USSR. UFLYAND, Yakov Solomonovich (10ningrad Physico-Tech Inst, AS, TjSS`~) awarded sci degree of Doc Physico--Wath Sci for the 26 Jun 57 defense of disser- tation; "Certain problems In the theory of elasticity, solved with the aid of integral transformations" at the Council, Leningrad Polytech Inst inent, Kalinin; Prot No 13., 10 May 58. (BMVO, lo-58,21) rv -4L- SOV/124-58-1 I - 12973 Translation from: Referativnyy zhurnal, Mekhanika, 1958, Nr 11, p 159 (USSR) AUTHOR- Uflyand, Ya.S. TITLE: The Fundamental Mixed. Problem of the Theory of Elasticity for a Halfspace With a Rectilinear Border Between Boundary Conditions (Osnovnaya smeshannaya zadacha teorii uprugosti dlya polupro-- stranstva s pryamoline,(noy granitsey razdeta krayevykh usloviy) PERIODICAL: Nauchno-tekhn. inform. byul. Leningr. politekhn. in-t, 1957, Nr 12, pp 22-27 ABSTRACT: The author provides a method for the solution of the problem of the elastic equilibrium of an isotropic homogeneous halfspace (y > 0) the boundaries of which are subjected in part (x > 0) to given displacements (u, V, W~ (x < 0) to given stresses .) and in part (FYI TyZI T It is shown that, by means of integral Fourier transforms (relaMe to the coordinate z) and Kontorovich-Lebedev transforms (relative to the coordinate r) the system of the mixed boundary conditions for the Papkovich-Neuber functions is trans-- formed into a linear alllebraic system in the space of representa.- Card 1/2 tion. Having solved that system and having accomplished SOV/124-58-11-12973 The Fundamental Mixed Problem of the Theory of Elasticity (cont, ) thereupon the inversion (in the course of which one must surmount a certain specific difficulty encountered in connection with the regularization of the func- tion under the integral), it is in principle possible to obtain a presentation of the solution in a Fourier and Kontorovich--Lebedev integral. An example is given (without, however, carrying it through to completion) wherein the action of a concentrated normal force on an elasUc hatfspace is analyzed, assuming that a part of the boundary of the halfspace (x > 0) is rigidly clamped. There are numerous typographical errors in the formulas. [ The theory of the integral Kontorovich-Lebedev transform is expounded in sufficient detail in the book: Grinberg, G. A. lzbrannyye voprosy maternaticheskoy teorii elektricheskikh magnitnykh yavleniy (Selected Problems of the Mathematical Theory of Electrical and Magnetic Phenomena). Moscow- Leningrad, lzd-vo AN SSSR, 1948, Sections 55 and 56. N. A. Rostovtsev Card 2/? LURIYI. A,I.; UFLYAND 07ourier's transforms" by 1. Sueddon. Usp.mat.nauk 12 no.2(74):252-254 Mr.-Apr '57. (KIRA 10:7) (Tranef orimt Ions (Nathewtice)) 4 AUTHORS: Lebedev, N.N., UflyanAl--1.~. (Leningrad) SOV/40-22-3-4/21 TITLEs An Axial Sy-7mmetric Problem of Compression of an Elastic Layer (0sesimmetrichnaya kont;aktnaya zadacha dlya uprugogo sloya) PERIODICALs Prikladnaya matematike. i mekhanika,1958,Vol 22, Nr 3, PP 320 - 326 (USSR) ABSTRAM In elasticity theory it is in general supposed for the solution of compression problems that the body standing under the in- fluence of any rigid punch forms an elaatic half space. In the present paper now the considerably more difficult problem is investigated in which a punch of axial symmetrical form in- fluences on an elastic layer. It is assumed that the punch is loaded by a pure axial force. Furthermore the friction between the punch and the layer as well as the friction between the layer and the base plate which is assumed to be rigid is ne- glected. But it is pointed out that this neglect can also be omitted. With the method developed in the paper it is possible to ex- press by an auxiliary function the sought displacements of the elastic medium and the stresses occurring therein. This Card 1/2 auxiliary function is the solution of a Fredholm integral An Axial Symmetric Problem of Compression of an SOV140-22-3-4121 Elastic Layer equation with a continuous symmetric kernel. For the special case of a punch with a plane basis several numerical results are given in form of tables. Also for the case of a p=h without plane basis and under unsymmetric load the possibilities for the solution are considered but not carried out in detail.. There are 3 tables, I figure, and 4 references, 3 of which are Soviet, and 1 is English. SUBMITTEDs July 3, 1957 Card 2/2 UPLYAND, U.S. Spatial problem in the theory of elaoticity for unlimited bodies weakened by plane cuts. Trudy M no.192:60-70 '58. (KIRL 11:6) (Elastic solids) .000) -IT 007120-123-6-101.50 L.ifon: Uflyand, Ya. S. '~T TLE: A Mixed Problem for an Elastical Layer (Smeahannaya zadacha dlya uprucogo aloya) PERIODICAL: Doklad- Akademii nauk SSSR, 1956, Vol 123, lir 6, pp 991-993 (USSR) 113SZRACT: The present paper gives an exact solution of the spatial problem of the theory of elasticity for art unlimited layor (- oo