SCIENTIFIC ABSTRACT ZESENKO, A.YA. - ZETKIN, V.I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001964510008-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 19, 2001
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

KLEMM# G,.Ool 2WiTI(Op A*Ya-
Proopecta of usina tho concept "bull&*p factor" in =ino
radioacoloL7,, Report Voo I,, okowoloflia 5 roo6tlM-.U(fl
165, 0 Lum 19 11)
I* Submittod rmv=-ber 16, 29%o

ZESENROP A.Ya.; POLIKARPOV, G.G.
Gqefficle.nts of the accumulation and dJ.;ik-iI-PjtIon of ruthenim..,
106 in organa and tissues of marino mo~*Mska. Radiobiolcgiia 5
no,2:320-322 165, (MIRA 18sl2.)
1. Institut biologil yuzhnylh morey TMI Kovalevakogo AN
UkrSSR., Sevastopol'.
MOMMM ~wqw-,-2~ f-MMEM.

ACC NRs AP7013714 SOURCE CODE: UR/0213 5 /0 0 9/ 0
/6 /005 06/1 9 11 7
AUTHOR: Polikarpov, G.
ORG3 Institute of the Biology of Southern Sons Im. A. 0. Movalovskly, AN
UkrSSR, Sevastopol' (Institut biologit yuzhnykh morey AN UkrSSR)
TITLE: Prospects for application of the conbapt "Accumulation Factor"
in marine radioccology. Communication I
SOURCE: Okcanologlya,.v. 5, no. 6,, 19659 1099-1107
TOPIC TAGS: animal physiology, biologic ecology, chemical composition,,
radio nuclide
SUB CODE; 06
ABSTRACT*.
'This is a revi64 ofiecerit lite'iitute'in the held of radio..."'.
ecology Concerning the accwaulation factors of many radioactive and
stable nuclides in marine organisms. Particular attention, however,,
is given to the determination of now relationships between the
Accumulation factors and various parameters characterizing the accum
.ulation and distribution of chemical elements (radio nuclides) in
marink organis!aqq, their'organs and tissues. A method for.~omputin~3
1/2
UDC: 551.4164.679:557.47(26)

ZL-ML. F. Z.
-zetel's F. zo "Condition of the pulse in foot-bottom arteries of healthy
people (on the value as a sprq3tom of the absence of pulbe for obliterat
ing
ondarteritio).." Tructr Gospit. khirurg. kliniki (Sverdl. gos. med. un-t).
Vol. iv,, 19149, P. 319-44
SO: U 3850,, 16 June 53 (Letopis I Zhurnal 'rVUh StateY~ Ko 5., 1949)

15-57-.3-3477
Translation-'!from: Referativnyy zhurnal, Geologiya, 1957, Nr 3p
p 146 (USSR)
AUTHORS: Kakhadze*'I. R. , Tsagareli, A. L. ' Nutzub.idze, K. Sh.,
ZesashviliA.1.V',__T_."i
TITLE: The Geologic Structure of the Belt of JurassIc Coal-
Bearing Rocks of the Northern Caucasus Between the Malka
Is and Bol'shoy Zelenchak Rivers (Geologicheskoye
stroyeniye polosy yurskikh uglenosnykh otlozheni),
Severnogo Kavkaza mezhdu rekami Malkoy i Bol'shini
Zelenc hukom)
PERIODICAL: Irr. Labor. geol. uglya AN SSSR, 1966, Nr 6, pp 340-349
ABSTRACT: The oldest member of the Jurassic sequence is a coal-
boaring series of Liassio rooks, which lies Ydth mtirked
unconformity on a slightly undulating surface of red
Paleozoic granites and late Precambrian crystalline
schists . - It attains a thickness of 600 to 700 ni in
the middle and western parts of the investigated belt,
Card 1/3 and decreases to zero by depositional and erosional

15-57-3-3477
The Geologic Structure of the Belt (Cont.)
wedge-out to the east and north. The series is composed of massive
sandstones and units of thin-bedded quartz sandstones; siltstones;
sandy, argillaceous, and carbonaceous shales; mudstones; and laye~rs
and seams of coal. Autochthonous coal beds are confined to the mid-
dle (productive) part of the series., occurring toward the bottom of
this middle unit. Scarce fresh.-water fossils (pelecypods) indicate
that the rocks in the eastern part of the belt accumulated princi-
pally in a continental environment. The western part is distin-
guished by a dominance of marine sedimentation. The age of the coal-
bearing series is determined by the discovery of Pliensbachian fos-
sils. The elastic Tsebellda series (150 to 200-m thick along
the Bizhgon River in the western part of the belt), conformable with
the coal-bearing series, is referred to the upper Pliensbachian and
to the Domerian. Above this series there occurs a volcanic series
assigned to the Domerian and lower Toarcian. Possiliferous elastic
rocks of the upper Toarcian (up to 100 m) overlie older formations
transgressively. Clay-sand deposits of the Aalenian (50 to 120 m
thick) are divided into four zones. Conglomerates and sandstones,
Card 2/3

15-5" -3-3477
The Geologic Structure of the Belt (Cont.)
which have been described as upper Aalenian, are proved to be Bajo-
cian. The Jurassic rocks have a homoclinal dip to the northj com-
plicated by local secondary folding (coal-bearing series) and faults
which have produced block structure. The most significent of' these
structures are pre-Aalenian faults. Individual coal-bearing areas
suitable for exploration and mining may be discovered in the belt.
Card 3/3 A. Ya. D.

9==19 a Elm E kwu i I-M WM

15-1957-7-9037
Translation from: Referativnyy zhurnall Geologiyat 1957t Nr 7,
p 30 (USSR)
AUTHOR: Kalchadze, I.-R., Zosashvili, V. 1.
TITLE: A New Middle Jurassic Genus Kubanoceras g2ne no'v.
-
-
(Novyy sredneyurskiy rod KuU
anoceras Zen. nov
,T
PERIODICAL; Soobshch. AN GruzSSR, 1956, vol 16, Nr 9, p-p 707-
709
ABSTRACT: Perisphinctes (Grossouwria) asinus, described by A.
Zatrovnitsky (Izv. Geol. Tom., 1914, vol 33, Nr 5)
from the Upper Bajocian clays of the Kuban' River,
is proposed as the genotype of the new genus Kubano-
ceras, It is characterized by whorls subtrapezoiWal
.to subquadrate in section, with an umbo from 0.42
(with a diameter of 10 mm) to 0.47-0.54 (with a dia-
meter of 40-90 mm). The ribs are common, narrow, and
either radial or~inclined forward; they branch in the
Card 1/2 upper half of the whorl and pass to the ventral side

A New Middle Jurassic Genus Kubanoceras &en. nov. (Cont.)
without interruption; a sharp node occurs on each~rib beneath
-the points of branching; and the noden are compressed. Two
groups are differentiated: 1) Kubanoceras asinus, with ribs
radial or slightly inclinded forwara, s lWr -to Procerites
Siem.; and 2) K. ultimum sp. nov., with-numerous ribs bent
strongly forwaFd, 'similar to Ataxioceras Font. The 1*01lowing
new species belong to the new genus: K. depressum, LK. mar-
tiusifor is, K. kardonikensis, K. kita~i, K. stephanocera-
UT-des, K. gurami. It is possiBle-T-hat tWis-g_en_u_s_YUro_ngs, to
The MpRan-o-ce-RaTidae lineage.
Card 2/2 V. V. Drushchits

ZESKOVP P.; 1"SEKI F.
Abdominal epilepsy. Neuropelhijatrija 8 no.4:317-324 160.
1. Is &Unike za djecje bolesti (Predstojniks Prof. dr. IT. S,mivaneli)
i Nourolooko-psihijatrijoke k1inike Med. fakultata u Zagrebu (Pi-edstojnik:
Prof. dr. R. Lopasic)
(EPILEPSY diag) (ABDOMEN ACUA diag)

HAMISEK,F.,, HROKOpN.
Electroencephalographic changes in hydrocephalus of non-neo-
plastic origin. Neuropsihijatrija 11 no,1:39-47 163
1. InNeurolodko-psihijatrijake klinike (prodstojnik%prof.dr.
R.Lopasic) i Klinike za djecje bolesti Med. fakulteta u
Zagrebu (predstojnikt prof.dr.P.Erak).
'ww,
FIT MII
m4-

ZESKOVp P.; GRCEVIC, N.; LIJETIC, V.
Dumbbell ganglioneuroblastoma.of -the spine. Nouropsihijatrija 10
no.3,/2!85-98 162.
1.*Iz Pinike za 4jecje bolosti, Neuropatoloakog odjela Nourolosko-
psihijatrijake klinikei Ltrurske klinike Medicinskog Fakultatem
Zagrebu.
(GANGLIONEUROMA) (SPINAL CORD NEOPLASMS)
A

The final stage of,development of bioscope. Gas. lek. cesk. qB no.3:
89-90 16 Jan 59,-
1, Pracovnik V. U. Zdravotnicke techniky, Praha 9. Kurta Konrada, 6.
(3130TROMYOGMM, appar. & instruments$
bioscope (Cz))
AUNT M.-

CHICHIGIN, Vasiliy Grigorlyevich; PRINTSff, V.V., dotsent, retsenzent;
LeIH. 28S1U2hennyy uchitell, reteenzent; STAI-IKOV, G.A.,
retsenzent;. dotsent, retsenzent; KARAM, ?.A.,
doteent, retsenzeiit (deceased]; DUBNOV. Ya.S,p profep re-bsensent
(deceased]; PAZELISKITp S.Y., red.; TATURA, G.L., tekhn.1red.
(Method for teaching geometry.- plane goometry. Textbook for
high-school teachers] Hetodika prepodavanila geometrii; planimetriia.
Posobie dlia uchitelei arednei ahkoly. Moskva, Goo.uchabno-pedegog.
izd-vo M-va proov.RSM, 1959. 391 p. (KIRA 13:3)
(Geomtry-Study and teaching)
M

ZETEL~-men-laaakovich; BONCHKOVSKIYO R.N., red [deceased);
IWOVA, 14. 1.,,
IiIIIANSKIY, G.S.,, red.; aal te~!;. red.
(A new geometry of the triangle; textbook for teachers] Novaia
geometriia, treugollnika; posobie dlia uchitelei. Izd,2. Moskva)
Uchpedgiz, 1962. 150 P. (KIRA 15:6)
(Geometryp Modern)
aim
I -
Ed; U91

*W4 Iftai AW-I-q-ONY'a -Ew".S05 FJ WF41 W%RWAM.02
ZETEL-, S.
Construction of some models of successions Tr. from the Russian. p. 167.
(Pokroky Matematiky, FysikY A Astronomie, Vol. 2, no. 2. 1957. Praha..
Czechoslovakia)
SO: Monthly List of East European Acc~bssions (EEAL) LC, Vol. 6. no. 10, October 1957. Uncl,
NOR N-R-32-IT,

SWINSKIY, Vatilav (Sierpinaki, Waoliwl i prof i;_qTEL', S.I.,, red.;
SIDOROVA, L.A., red,; 'WVXO, B.M., tokhn.i"~,~"
(Pythagorean.triangles; textbook for'teac6ral Pifagorovy
treugollniki; posobier dlia,u6hitelei,. Pod red. S.I.Zetelia.
Hp'okva, Gos4uchebno-pe6gog.izd-io H- 'vaproov.,RSFSR, 19%-
110 p. (Translated from.the'Polishj".' (MIRA 1:2:7)
l
shavskiy nniversitet. Vitse-prezident Pollskoy Akademil
(for Serpinskly),
-(Triangle)

ZZITULI, S.I. (ffq.p!-n,a)
Approx-inn~tion n-'' function s by opcord-order curves.
15 0."
no.11:179-187 MU 12:11)
-try, Alcobrnin)

difference of thei
#236 157.
(MIRA 11:7)

PRM I BWK WTZXTATICK 30V/25W
Xataftatlaboakoy* prosvoshchenlyej aatemstlka~ yeye prepodavanlys,
tIon
l M
uca
Vril*rheniya I latorlya, "p. 4 (Mathematica
; .
Rathematics. Its Ze-hi Z, Application end History: .!rj 4)
Xoscow. 0ostekh_*zdAt. 1959. 25,000 copies printed
Zd.t I.N. Bronakta"i Witorial Board'of Sarlexi X.S. Bronahte
A.I. Karkusheylch, I.N. Yaglonj Tech. W.v a.M. Akh1amov.
MP=s Milo book: is Intended for persons without an extensive
mathe"tIcal ednaatlm who are interested In trends In con-
temporez, asthmatics. I The book war be useful to h1MA school
"th"Atics tesobArs.
COMAM The book conalmts of artiolas, reviews, and-solentiflo
and nothodological reports, some or which are translations. frox
otbAr unguages. Zia state of aodern nathematlas is covered*
Uo1%WImg applicatIcass history, teaching or m4thwastlcs In
schools, and nathmatioal developments in the USSR and abroad.
On* seatlom~daalm with "JaulLflo and pedagogical life in the
UMR'amd another contains revi we or osrtal-A amthematloal publl-
*
ckground Is necessary to underatand
catlons. 30se wathemazion2 ba
the booki certain articles require a knowledge or higher nathe-

Katilmatical. mucation; (CAmt.) SOVA5W
I=. win m-no-JOTUaDOWOXCAL REPORTS
T&A-hIng Exper.-Once and ?sd&90SIc&2 Zxpcrljmntation)
Ar&mAnOvICh# I.G- and 5.1. Zatell. On an ApproxImAtion or
Graph$ Or YncOtlons OF "rye$ Or -0 300ond Order lConical 179
Gradstela. Z.5. (Deceased) On One Sufficient Test of Indefinite
Integral# Turning to Zero leg
StVal B-1- On the local I124t Theorem in Probabillty Theory 193
Takaho, f- (Rumerry) Remax*s on the Theory of Geomzrlo Constru._
tions, 197
Brief Xop*rtas
2. Balk- X.B- Computing it 3um by Vaighting POS
2. alozburg. B.L. SIMligicatlon of r ran
~u~itipjjc&zLm p
to Fight
207
3. A.V. A Study Of the Roots of a Cubic rApatlon
Card 5/8

0 postroyenii nekotorykh pravillnykh mnogougollnikcV sverdlovsk, izv. ural'sk un-ta, 3
(1922-1923), 195-203
SO: Mathematics in the USSRP 1917-1947
edited by Kurooh, A.G.
I.Ioxkushovich, A.L.
.Radhevskiy, P.K.
1408COw-Lenlgrarl, 1941

ZMLI ---Seme- I kovich-- OSTrAVU
aft. "a N.M., reds; KWS, I.G., tekhn.red,.
[Geom`e-;t"r'y' of the line and geometr7 of the coMaeol Geometrits lineiki
i geometriia thirkulia. Izd. 2-de, dop. Koskvi, Goa. uchebuo-
.Dedagog. izd-vo H-va proav. RSFSR, 1957. 162 p. (MIRA 11:5)
.(Geometry, Plane)
7o-Z.7"

PoSsibilities for applying gbacose oxidase in th-
industry. Elelm ipar 18 no.6.-178-183 -je '64.
1. Central Rosearch Institute of the Food Industry,
Budsipe-st.

--ffj'u~
wrom, p - AHmgm~.. -mrw:m~a ~-71-n-aw MR
-ZF'-TFEX'- -7-. -'F-AFWErjj-K-._ -
"Poradnik kreblarza zelbetnikall (Guide-book of a desifner in iron-concrete
works by Z. Zeten and K. Karweg., Feported in New Books (Nowe Ksiazki), No. 12,
June 15, 1956.
IRRIORMIE", M,

all
9919fib
JUBA, Adolf, dr.,; SZANMIM, Gyorgy, dr..; 21,T]W, Gyozo, dr.
therapy of Sturge-Wober disease. 0". hatil. 96 no,.121
319-333 20 Mar 55
1. A Szegedi Orvostudomanyi Figyetem 2. Sebeazeti Klinikajansdc
(igazgato: Iaz4,, Imro dr. egyet. tanar) les a Gyulai Megyei
Korhaz Blme-idog (foorvos., Juba Adolf dr.) as liadiologiai Oostalyanak
(foorvoe Zeteny Gyozo &r.) kozlemenye.
(ANGIONATOSIS.
Sturge-Vaber dis.. surg.)
M - ~-Oml

KIBEDI, Tibor, dr.; ZMEff, Gyozo, dr.
Cardiac calcification. Magy. radiol. 7 no. 1:31-35 Jan 55.
1. A Bekesmegyei Tanacs Korhaza, Gyula (igazg'ato: Juba, Adolf dr.
foorvos) rontgonoaztalyanak (foorvos: Zeteny. Gyozo dr.)
k021emenye.
(CALCIESCATIONg
nVocardium, x-ray.)
(14YOCARDIUM, diseaseso
calcificatlon,x-ray.)

m
. -7
Z.E. nA"n A" foiskol,ai docemv(Eger)
~~7
I i : I
A-~Iaska. Term tud kozl 7 no.2:84-86 F 163.-

ZET
Basic principles for organizing the material and technical su;Mly
for the railroads. Zhel.dor.transpr, 39 no.6:15-20 Je 157.
(MLRA 10:?)
1. Zamestitell nachallnika Glavoogo upravlenlya materiallno-
takhnicheakogo obeepecheuiya Ministerstvn putey ooobehehenlya.
(Railroads-Rquipment and supplies)

Z.ETILOV, German tyevich; TAGUNTAV, Sergey Dmitriyevich.
-1'ri-riim-~i-uc-harsAlye ARASHKEVICII, G.M.; GOLOVACHEV, B.11.;
[Fundamentals of the supply of materials and equiFment
in railroad transportation] Oanovy ma-teriallno-tekhnicho-
skogo snabzheniia zholeznodorQzhnogo tran"porta. Izd.2
dop. i perer. Moskva,,Izd-vo "Transport," 1964. 315 P.
WIRA 17:7)

ft,
RM
Iyevi6h: TAGUBTSKY, Sergey Dmitriyevich; KRISHTALI
L.I., red.; VERINA, G.P., tekhn.red.
[Principles of supply of materials and equipment to railroads]
Osnovy materiallno-tekhnicheekogo anabzhaniia zhelesnodorozhnogo
transporta. Koekva, Gos.transp.zhel-dor.izd-vo, 1959. .354 p.
(KIRA 13:3)
(Railroads--Kanagement) (Railroads--Equipment and supplies)
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2. USSR (600)
4. Pine Dnieper Valley
7. Planting pine in clumps with peat fertilizer on Lower Dnieper sands.
Les i step' 5, No. 3~ 1953.
9. Monthly List of Russian Accessions, Library of Congress, Apdl -1953, Uncl.

M
13ARDMISHTEnF, S.B.; DZHAGATSPAIIYAN, R.V.; ZLPTKHIN, V.I.
Analysis ofa mixture of.inomeric trichlorobanzenes and of a
mixture of Isomeric tetrachlorobenzenes based on their infrared
absorption spectra. Zav.1ab. 26 no.2!i67-171 160. MRA 130)
(Banzena--Spectra)

USSR/Chenistry - Organosilicon Compounds 21 Mar 52
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r
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Nametkinj V. I. Zetkin
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"D
."Dok Ak Nauk SSSRII Vol 83, No 3, PP 423 425
0k
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.11exachlordisilane.-iethatic vras prepd from silicon and inethylene chloride. This wLs used
.asthe starting material for the synthesis of hexapropo.para>metha.
grig. art. has: 7 figures.
SUB CODE: 07/ SUBM DATE: 13May65/. ORIG REF: 0061 OTH REF: 007

I ~011 ~-r ~_tl
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ACC NRt -AP60151211
DAlaptnpanyan.. 11,, Ve; 4~~i
Mn,__b~# Gj F~lippoy,,_J~_T.; Sinitairi V
V. I.;
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10R.G: none
TITLE: Radiation chlorination of kerosano
i SOURCEs Khimichoakaya promyshlonnostl.o no. 50 1966, 18-20
TOPIC TAGS: karosene, gnmma radiation, chlorinationg photochomist
ry
I ABSTIUCT. Groznyy karosono, from which tho aromatic and unnaturatod compounds wore.
I ollminated by extgaction with liquid SO was used during chlorination initiated by'
,wy-radiation of Co made in the apparaius descoribod by the authors previously (K".
I prom. no. 4, 247, 1965)o After purification the kerosene had a 'molecular, weight of
177. Chlorine was passed at the rate of 0.1,69 g/min in tho reactor sot into a thormo-
stat with a controlled given temperature. The radiation source w4s introduced after
15 minutes* 1~he chlorination pioducts were purified from G1 and H01 by passing: a flow
of nitrogen. the donsities andrefractive indexes were moas&red'and the dogreo of
ahlorinatiofi was determined from the graph plotted ex
_porimentally, showing tho do"
pendence of donsitj d18 and the refractory Indoxen n20 of tho chlorinated products
on 'their chlorine content. Kinetic ourvas (conkerAt of chlorize, Y3 time-in 14in) -were
Card UDOS' 665*634-4 1 66.094o403485.3

-08659-67--
ACC AP6015121
NR.
plotted at various temperatures of chlorination (T 20, 40, and 60C) and at various
doses of radiation (P M 26.1s 7.31 1.8,,-and 0.81 rad/soo)o The do andence of the
p
radiation-chemical efficiency coefficient G (number of atoms bound with carbon per
100 oquivalent)on the radiation dose P was plotted from kinetic curvese The expression
well describes the results obtained* (Dis-
(1EO
G = 1,22. 1000r P-0.41 aereancat of experimental and calculated values
averaged 4 10,81%) This ovation can-be usod for designing a reactor for a temperature
range of 0-100G, a radiatfd~ dose of 1-50 rad/sec, and a chlorine content of 5-60%,
The apparent energy of activation was determined as 3200 cal/mole. The resultij of
radiati6n chlorination were compared with those of photochemical chlorination and
chlorinaluion'initiated by azo-bis-isobutyronitryl. It was shown that the some dogrel)
*
o
f chlorination was achieved more rapidly during radiation chlorination *A T =20G
and P 26 rad/sec, the prodtict containing Gl> 60% was obtained in 490 minutes during
radiation chlorinatione It took 23 and 21 hours to obtain the same product by photo-
cha-aipallchlorination and chlorination initiated by azo-bis-isobutyronitrylp respect-
ivoly, Radiation chlorination also has-other advantagea: it depends little on temper-
aturo and'is controlled by the radiationdose (odsily controllable rate of cb1orin-
ation), the rate of the radiation process does not depend on.tho color of the react-
ing mixturep and there is a much smaller dan&r of reninification because of an aboGnae
of local overheating* Orig* art@ bass 3 figs# 4 formulaap and 1 table*
SUB GODEs 07/ SUBH DAT&s~, none/ OR*IG REFS OM/ OTH RM 001
Card 2/2 j-e

WIMENKO, L.M.; SMITISYN, V.I.; TYA:;ElN, YO.C.;
V.I.; LIFIIAN, B.Ya.
ft~tdlo,-,hemif-,al sulfochlorination'of kiln-osine and sy-athline.
41 no-4:7-11 Ap '65. (min 18:8)

ZFTKIN, V.I.; ZAKHAROV, Ye.V.; KOUSSIKOV, I.M.; PANCHENKOV, G.M.
DestrueUve hl gh- temperature chlorination of n1trobenzene iind
somo of the its derivatives. Zhur. fi*A. kh1m. 39 no.5-1240-
1242 Mj 165. (MIRA 18.8)
1. ~bskovskiy institut neftekhimicheskoy i gazovoy pronV3hlennosti
imeni I.M. Gubk1na.

RM
'ACCESSION NR-. AP5019
676 UR/0064/65/000/008/0573/015
661.7:547,269ol1111-347
AUTHORS: Zetkin, V. I.; Libman,, B. YJ
TITLE Production of pe
phezkylohloride)
ktric.hioromethansulf
-8OURCEz Khimidheakaya promyshlennostIt no,. 8, 1965j, 573 575
MPIC TAGS: sulfur.compoundl, sulfur dioxAde~ mereaptan, chlorine inorganic COM-6
pound , chlorine organic compound chlorine, chlorination, perchloromethylmorcaptan.'_
ABSTRACT: The object of the inv'estigation was to determine optimun condttions .7'",
sor the synthesis of perchloromethylmercaptan (A). The product was obtained by,
The inf,
of iodine. Ruence of;'
..the chlorination of carbon disulfide.in the pre3ence
temperaturet unt of catalyst,, time, 4apth of chlorination, and impurit
ies on
the yield of product were determined. The exporimonts were carried out In a
cylindrica
I reaction vessel eqAppad with a thermometer and a stirrer* Tho opti-o~:-,
mum conditions were found- to ~ be: --teMierature 10-200; amount'-of--cata1~6f_,6.5:-1.
-'deptkof-d or tion-' up to -d 119-1 64 It was foland 'that 'the
__perceritj
4
aus
presence: Of irdn. impiwities c the formation of carbon tetr chloride -and-- it"
Car

Card 2/2-

------- ----Won
PrInimali uchastiyes OSPELOV, V.Ys.;
KOLDASOV~ V.is
Sulfool~11.,"rination kX polyethy)ene under ':he action of C060 g&-ama
y no. ]-Q 2 (MIRA 171.1,C)
radlation.

WTSAREV., G.V.; YAKUBOVICH, A.Ya.; ROZENBERG, V.R.; FILIPPOV, M.T.;
DZHAGATSPANYANp' R.V.; BARDENSHTEYN, S.B.; NOLBASDV, V.I..;
ZETKINY V.I.
Halogenation of ai~omatic silanes. Part l7t.Add~tt'on.of chlorine
to phenyl-trichlorosildne.'Preparation of h.exaA1bimyclohqxyl-
trichlorosilane and the mechanism of its formati6ii.,, Zhur. ob.
khim. 35 no.7:1178-1183 J1 "65. (MIRA 18:8)
WR R

*.-WAR
DZHAGATSPANYANY E.V.; FILIPPOV, I.I.T.; FIOTSAREV, G.V.; Zj~~,~K~,
ROZENBERG, V.R.
Radiation-induced chlorination of some organochlorosilanes and
organopolysiloxanes. Dokl. AN SSSR 155 no. 5zlI63-1166 Ap 164.
(MIRA 17:5)
1. Predstavleno akademilcom S.S.Medvedevym.

DZHAGATSPANYAN, R.V.; ZETKIN, V.I.; FOSPE-WV, V.Ye.; FEDCHENKO, V.S.
Radiation-induced chemical sulfochlorination of polydimethyl-
siloxane. Plast.massy no.W6-18 163. (MDU 16:2)
(Siloxanes) (Chlorosulfonj~ation) (4diation)

-,pFTr /Pr-4 RM/WW
P!j-VP:!"
R. 7. Ze ftzne7l~ 0V
T cn, Cf
SaJRCE: Plasticheskiye rAssy*, no. 5, 1963, 4-7
T-7 IC TAGS - sulfochlorination, Dolystyrerie, chlorine, svlnir ~Uoxide, cobalt sum
6o, sulfuryl chloride
ABSTRACT: Impi-owd properties were ant-ic-4-pated from the sulfachlorivation of poly-
styreene, achieved by reacting 1% Polyr-tyrene emulsion -.1th chlorine and nulfur
(~-Ioxiale (in molar :--tics. of 0.22:1 - 4.r~5-1) -Ilssnived in cs=bon te-trachLoride and
to fror. a Co sa-- source. Ove-r a range cf -D - 5K, the
eact'on _- te Jncreased with increasing to a max-1-n= a' 40C. Licreas-
ln,~; the total dose of radlation had little effect on the proceSG, whicL vas a.1.1 '-"-,t
cc=.lete -within 15-20 minutes. No clear relationship was found bet-ween the rate and
crtitcone of the reaction end the molar ratio -Df the t-wo gases: although the finp-I
sulfur content was more dei)cndent than vas t.-.e chlorine content on the ivAtiall
mtio, in no case did t-he final product contain T-.o,--e than 3$ su-In-'r. Un-liZe
the other polymers, polystyTene could not be s,_Oli'ocalorinated with s%il-fu--yl chlo-
ride. Sulfochlorinated polystyrene h d better araheslve aual-Ities (vith jr-4.ss wid
CG,d
PROHN I M _M _90

r.1/844/62/000/000/066/129
D204/D307
AUTHORS: Dzhagatepanyan, R. V., Zetkin, V. I., Motnarev, G. V.
and Pilippov, 14. T.
TITLE: The chlorination of phenylmethyldichlorosilane (I) dnd
dimethyldichlorosilane (II) under the action of r J.rradi-
ation
SOURCE: Trudy II Isesoyuznogo soveshchaniya po radiatsiormoy khi-
mii. Ed. by L. S. Polak. Moscow, Izd-vo AN SSSR, 1c)62,
386-389
TEXT: I was chlo'rinated in sealed ampoules, at 0 and 20001, tinder
irradiation (-120 r/seao over 15 or .30 'mi.) , with molar ratios
(n) of C1 I equal to 0.25:1, 0-5:1, and 1:1, aince polychlori-
2
nated silanee are of interest in preparing fluorinated .1ji-contain-
-ing monomers and polymere. In contrast to chemically initiated
chlorination of I, the present reaction was on(, of addition of (;1 2
into the aromatic ring rather than substitution into the meV.,iyl
Crard 1/2

S/844/6*2/000/000/0066/129
The chlorination of ... D204/1)307
[rro p, the main product being a viscous oil, which by chemical and
ir spectroscopic tests proved to be CH 3' C6H5CiGsiC12' A small am-
ount of CH 3-chlorinated compounds was also formed. No product in
which chlorination of CH 3- and C6H 5-groups occurred simultaneously
was observed, although it might form in initial MiXtUres rich(.~r in
C12, Silane 11 was similarly chlorinated at OOC, viith n equal to
0.30 and 0.50, under.2 min doses of ~' rays at -121U r/sec, to C'ive
U
-30~-' yields of the monochloride and 5 to,-17Vo yiulds of the d:Lchlo--
ride, the latter becoming greater with increasing n. There are it
tables.
ASSOCIATION: NII Goskomiteta, Soveta Ministrov SSOR po khllinaii
(NII for, Chemistry of the State Committee, Council of
Miniaters of the USSR)
Card 2/2

6/844/62/000/000/067/129
D204/ 307
kUTHURS: Dzhagaz Itip anya.n, R. -V., Zetkin, V. 1. and Zykova, Yf!. N.
TITLE: Hadiati6nal sulfo-oxidat-iozi of certain paraffins
"GOURCE, Trudy 1I',VFJ0soyuzn6go sov eshchaniya,po radiatsionnoy.khi-
mii. Ed.iby L. U. Polak. 14oacow, Izd-vo AN 355R, 1:9620
TEXT: The present work was carried out in view of the difficulties
in the continuous photochemical sulfo-oxid-ation. of higher paraffino,
which is important in the production of detergents, Aromatics- and
olefin-free normal octane, nonane and und.ecane were irradiated with
I-rays (110 r/aec, o Iver-2 hours),-at 2500, with 30 2 -.02 ratios (n)
ranging,from 1:1 to 3:1. For n-C 8 H18~ the yield Of M11fonic; acid
Mae, with increasing n# to a maximum of -Mo' at n equal to 2:1. For
'n-C 11 and n-C H - with n equal to 2:1 Z-Abstracter's note: n-
9 20 111.24?
C9H20 is described as n-octane in the text-7, the yields aunovioed
Card 1/2

S/832/62/000/000/007/015
D244/007
AUTHORS: Topchiyev, A.V., Nametkin, N.S. and
Zetkin, V.I.
TITLEs Alkoxy(aroxy)-derivatives of the reaction
products of methylene dichloride and 1p2-
dichloroethane with silicon
SOURCEI Issledovaniya v oblasti kremniyorgani-
oheakikh soyedineniy; sintez i fiziko-
khimicheskiye svoystva. Sbornik statey.
Inst. neftekhim. sint. AN SSSR. Moscow.
Izd-vo, AN SSSR, 1962, 146 -.155
T,%X T The alkoxy-derivativea of disilylmethane
and 2Zclo-trimethylbenzylti-isilane were oyntheeized to oluoi-
date the influenc e of various alkoxy- and aroxy- groups on
their properties. It was also of interest to establish the de-
pendenoe, of the r eaction rate of C1 exchange for the alkoxy
reiidues~ on the latter's size and nature. Rexaalkoxy-(aroxy)-
Card 1/2

S/1332/62/000/000/007/015
Alkoxy(aroxy)-derivati-ves D244/D307
-derivatives of dislylmethane and disilylethane were obtained
by the interaction of alcohols, phenol and.oresol with hexa-
chloro derivatives of the disilyl compounds. For primary alco-
hols the reaction proceeds under mild conditions, all six Cl
atoms being exchange'd for alkoxy groups. A secondary reaction
also takes place leading to the formation of condensation pro-
ducts.The reaction is more difficult for secondary and especially
for the tertiary alcohols. For these alcohols the application of
acid acceptors (pyridinep toluene,- diethylamine) prevents the
condensation reaction and facilitates Cl.exchange. Alkoxy deriva-
tives from the SZclomethylenetriailane series were obtained by,
reaoting methyl, ethyl, propyl, and butyl alcohols, with 1,1,3,
3,5,5-benzylchlorog2clotrimethylenetriailane, using diethylamine
as an acid acceptor. It was shown that the derivatives of disilyl-
methane possess the lowest temperature coefficient of viscosity.
There are 5 figures and 4 tables.
Card 2/2
IV

2
FILIPPOV, M.T.; DZHAGATSPANYAN, R.V.; MOTSAREV, GeV.; ZETKINv V.I.
Infrared spectra of some organochlorosilanes containing chlorine
in the organic group, Zhur.fiz.khim. 36 no.8!1751-1754 Ag 162.
WRA 15:8)
(Silane-Spectra) (Chlorine organic compounds-Spectra)

8/84 62/000/000/069/129
D204YD307
AUTHORS:
TITLE:
iS 0 Uq C I.;:
Yakimenko, L. DI., Dzhagatepanyan, R V,, Zetkin, V. ist
Korolev, B. M. and Maksimov, 1-1. P . ~d 0c,,b7CrT
Chlorine 'exchange between hexachlorocyclohexa.,ae (I)-and
carbon tetrachloride, under the do,tion of radiation
Trudy II VSeE;OyLlznogo' soveshchaniya po radiatsfonnoy khi-
inii. Ed. by L. 6. Polak. Moscow, Izd-vo AN SISSRp 1962,
398-402
TEXT: The behavior was,studied.of purified(.Y-, 3-, r-, and ~-iso-
mdrs of I, with M labelled with C 1136 , under the action. of rir-
4 0
radiation at 12U r/sec over 1.- 15 hour3, at -30 0. The mixtures
consisted of 250 mg of 1, 8 ml of CCl I and 1 ml of labelled CC1
4 4$
;Ind the chlorine exchange was assesued by the change in the acti-
,. No transfer of Cl-56
vity of I (dinuolved in 2.5 ml of benzene)
took place in the abuence of irradiation. The activity of~j-l and
--6-1 rose to a constian-tv- value of r~-I% (arbitrary unitri) after 5 - 6
1
ard 112
0

S/84 4/62/000/000/069/12"'D
Chlorine exchange be tween I:- D204/D307
hours? whil.';t that of 1-1 picreased to a constant -0.6,., ofter 8
10 hours. The --activity of 6-1 was 0.51,1) after 6 hours. ;Lt compara-
tively low dobea of irradiation the processes involved are chiefly
the chlorination of I and Cl-exchange, whilst further irradiation
allows a 5rd reuction, loss of HC1 by I (to form pentachlorecyclo-
hexenc!), to proceed. The rize of the activj:ty of I might be ascri-
bed to a dynamic equilibrium between these processes, but is more
probably due to: 1 ) radiolysis of CC1 to CC'1 I.uid CI, formation
4
of C 01 and Cl and recombination to CCI - (2) IM + Cl HCI
2 6. ;e , A. 4 '.,~ - --
* k-cl' A-Cl + ul H'Cl' H'C1 + Cdl-j R"61, HIC1 + CCI RCI
+ CC L
1 k5) WL i- C1 --:~ Al (exchange' reactJ oil); ECI +
3;
* HII'Cl (dohydrolialogenation). Reaction (4) and chlorination re-
action (:') are in ugreement with the observed considcrable ewolu-
tion of 11C.L. 'I'liere are 2. figures and 1 table.
AS30CIATION: Ifill drooco,"liteta, Zioveta Ministrov 8,'?.)R po khiilaii (N11
for Chej-Aotry of the ';tate Committee, k"Ouncil of ill,
oc the US'O'R)
Card 2/'r.-'

WSW
DZBAGATSPANYAN, R.V.; ZETKIN V I.; FEUCHO&O, V.S.
Radiative-chemicalsulfochlorination of polyisobutylene. Plast,
massy no.3:6-9 '62. (MIFA,15:4)
(Propene) (Chlorosulfonylation) (Radiation)
low

5/07 62/036/008/004/011
B101YB144
,U,n1jORS: Filippov, M. T., Dzhagatspanyan, R. V., Motsarev 0. V., and
Zetk
TITLE; Infrared spectra of organoch.!,~_-,;ailanes containing chlorine
in the organic group
"'ORIODICAL: Zhurnal fizichaskoy khimii, v. 36, no. 8j 1962, 1751 1754
TIEXT: IR spectra of'qH C H SiCl Siol (II)i CHM C H Sicl
i 3 6 5 2 (1); CI~12C'CO5 2 12 6 5 2
M-I); Cci;~C.,H S-101 Siol (VI", and
5 2 (IV); (CF-3)2S-C'2 (V); C:1201CH3 2
ChC12C= 3Sicl2 (VII) -were studied with the following re'sults: (1) The 3.35
and 3.4g bands correspond to the asymmetrio and symmetric stretching ......
vibrations of CH in the methyl group. (2) The position of the bands in
the range 11-16p strongly depends on the degree of chlorination: The
11-76 - 12.7g band of V in VI becomes weaker and is shifted toward longer
waves; i.n VII it splits into,two bands. (3) The 12.58g band of I
corresponds to the Si-bound CH 3 grg up. It changes with the degree of
Card 1/2

S/07 62/036/006/004/011
Infrared spectra of... BIOIYB144
chlorination and disappears in IV., (4) The bands of 13-151, for I-IV
corraspond~- to the C 6H5 groups. .(5) The 15 6211 band of VI and the 15-34
band of II are ascribed.to the SiCH 201 group. There are no bands in this
range for the other compounds. (6) In the case of IV, 11.36 and 11.90g
bands were observed which aDp ear due to symmetric and asymmetric stretching
vibrations of the C-Cl bond in CC! This was confirmed by the fact that
3*
ccl 3(CH3)Si(OC 2H5)2 and (OC1 3)2S'(0'C2H5)2 also shoved bands in the range
11-11.4 which were absent in compounds conta ining no CU 3 group, *There
are 5 figures and 2 tables.
SUMUTTED: November 9, 1960

115. qg&5' S/08 1J62/10FG01/01 2/058./0 63
B158/B101
'AUTHORS: Dzhagatspanyan, R. V.,,Zelkln, V. Is, Motnarev, G., V.9
Pilippov, M. T.
TITLE. Chlorination of ailioon-containing monomers and polymers
under the effect of gamma-radiation
'PERIODICAL; Referativnyy'zhurnal. Khimiya, no. 12, 1962, 612-613
abstract 12P282 (Sb. "Radioakt. izotopy i yadern. iz.'lucheni
v.nar.kh-ve SSSR. V. I.". M., Gostoptekhiidat~, 1961,
157-200)
TEXT: Polydimethylsiloxane rubber (I) and polyphenylmethylsiloxane (II)
as well as a number of monomers were chlorinated at OOC under the action,
of (Co6o w
j~'-radiati ith an activity of 1400 g-equi,~ of Ra). Chlorination
of I takes place easily and rapidly until the 'introduction of an average
of two Cl atoms into the chain of the polymer, after which the process
rate falls sharply. In a metal autoclave at both 0 0C and 60PC
destruction of the.polymer takes place. With chlorination of II (molar
Card 1/2

S/081/62/000/012/058/063
Chlorination of silicon-containing B150101
ratio of Cl:siloxane - 2:1 and 3:1) substitution-and addition chlorination
takea place in the aromatic ring. With chlorination of (OH ) Cisi
3 3
Onolar ratio of Cl :silano 0-51:1) the basic product is a monochlorine
2
derivative; chlorination of 18.6 g of ethyl-trichlorosilane (molar rat,io,
v
Of C1 :silane 0.35:1) gi es 6-5 g of a and P-ohloroothyl-trichlorocilanbs.
2
Chlorination of methyl-phenyl dichlorosilane.results in the formation
Of (C H Cl )(CCl )SiCl (b- P- 165-188/10 mm)- [Abstracterf.s note:
6 2 3 3 2
Complete.translation.]
Card. 2/2

36896
9
115/191/62/000/005/003/012,
BI I O/B101
/,S*, Pj) &.2
V. S.
AUTHORS: R. V., Zetkin, V. I., Fedchenko,
Radiation-chemioal a Ifoohlorination of polyisobutylono
TITLE: u
PERIODICAL: Plastichaskiyemansyp no. 5, 1962, 6-9
TEXT: Since vulcanized chlorosulfonized polyethylene has good technical
properties, the authors wanted to improve the cheapp accesuiblep but
technically imperfect polyisobutylene by oulfochlorinatioln.'.The solution,
of polyisobutylene in'dry oarbon tetrachloride waa sulfochlorinated in the-
-1400 (K-1400) radiation unit by means of a C060 radiation source
(90 r/seo) according to the following reactiono-,
RH --> R* + H; R + SO RSO* - RSO~
~2 2) + C12 ->,RS02C' + G";'
R4 + Cl ---,'~RCl+ W. Reaction with a mixture of sulfur dioxiaoiand
2
'chlorine under the effect of y-rays sets in at once and proceeds at a highi
rate, limited only bythe rate of heat dissipation, the efficiency of the
supply and the degree.of mixing of the liquid and gaseous phazes. After
termination of-the.reaction, nitlogen. is blown through in order to remove
the dissolved gases, and the same volume of methyl alcohol is then added
Card 1/2
a e,- Ju c Of te 'Tood
a,
atj pzacltj
Oil 0
f Sul 041
foohjo-

DZHAGATSPANYAII$ R.V,.; ZETKIN, V,I,j MTSAWN, G.V,; FILIPPOV, K.T.
Gamma-ray induced chlorination of organosilicoyA monomers anil polymers.
Part Is Chlorination of the polyphen;rlmethyl siloxane-liquAd and of
Olydimethyl siloxane, rubber. Infrared spectra of the chlorination
prqduatso. Vysokom.soed. 3 no.4:607-612 AP 161. (MM 14W
(Si-loxanes). (Chlorination)

PHASE I BOOK EXIUrrATION 80V/5w
VaesqYuznoye soveshebanlye po Tmedrenlyu radloaktivnykh lzotopor I ya4ernykb
jzluchenl-y Y narodnoye khozyaystro SSSR. Riga, 1960.
Radioaktivnyye izotopy i yademyye lzlucbeniya r narodnom khozyayotve 6=1
trudy soveshchaniya v 4 tomakh. t. 1. Obohchi:e vorrosy primeneniya
i%otopov, pribory a istochnikwA ra(Uoaktiynykh Itluchonly, raAUatsi0=My&
khimlyalkhArdehookayn,i nottepererabatyvayushebaya promeWitnnostl (Radio-
active Isotopes and Nuclear Radiations in the National EconM of the UMI
- roblems in tba
Transactions of the Symposium in ht Vblumes. Y. 1. General P.
'UtiLization of Isotopes; Instruments With Sources of Radioactive Radiationj
Radiation Chemietryl the Chendcal and Petrolcum-Refining Industry) moacow,
Goutoptekldzdat, 1�61. 340 p. 4,240 copies printed.
Oponnoring Agency: Gotrudaratmaxyy muchno-takhnicheakiy, komitat Sovets, Kinistray
SSSH, and Gosudarstvannyy komitet Sovets HLnistrov 6SSR po ispol'SoVaniYU
atomnoy energii.
Id. (Title page)z N.A.*Petroy, L.I. PetreWw =& P.O. Ravitskiyj E". or this Vol. 1
L.I. Patrenko, P.S. Savitakly, T.1, Sinitain, Ta. X. Kolotyrkinp N.P.: Syrkui
and H.P. Ro=; Executive lda.t Ye. 9. levina and B. 7. TitakAyaj Tech. Ed's
B.A. I 1kb1m

Radioactive 180topen (Cont.) NOW,

PaRPOU: The book is intended for technical pereonn~l concerned with problem
of application of radioactive Isotopes and nuclear radiation in all ~brsnchds
of the 3oviet economy.
COVERAGEt An All-UnIqn Conference on problems In the Introduction of riWioactive
isotopes and nuclear radiation into the national economy of the Soviet UWon
took place in Riga on 12-16 April 1960. The Conference was sponsored by:
the Goaudarntvennyy nauchno-takhnichookiy kamitat Sovvtn Minietrov W811 Onate
Scientific and Technical Committee of the Council of Ministers, USSR); Ol-noye,
upravleniye po inpolozovaniyu atomnoy enorgii pri Sovete Hinistrov SSISR (Main
Adminletration for the Utillzation of Atomic Energy of the Council oflu.W.aters,
U3SR); AcwlcLv of Sciences, USSR; Oosplan USSR; Gouudarstvennyy kotaitat Sertota
Ministrar SSSR po avtomatizataii I ma8hinootroyeniya (State a-Ittee of Ahe
Council of Miniaters, USSR, for Automation and Machine Duilding) and the C=cil
of 1-Uniaters of the Latvian SSR. The transactions of this Conference am
Publiched in four volumes. Volume I contains articles on the folloving ffebJectst
the general problems of the Conference topics; the state and proopecto of
development of radiation cbendatryl and results and prospects of applying radlo-
active iaotopes and vualear radiation In the petrels= refining and chemical
industries. Problems of designing and ==factaring instruments which cotctain
sources of radioactive radiation and are used for checking and automation of
t~-chnological processes am examined, along with problem of accident pmention
use. To personalities am mutioned. References accompany some ok the
I-13tth!ar
-
r - -
.
Card 24e .
7

Radioactive Isotopes SOV15,W6
Dzhagatspanyan,, R.V0.0 V.I, Zetkin,, Ye, N. Zykova., and M.T. Filippov
Sulfochlorination and du-Voi-oxidation of Polyethylene,, Polypropylene*
Polyisobutylene., and Paraffin Hydrocarbons by Radiation 201
Topchiyev., AV.) L.S. Polak., N, Ya, Chernyakp V. Ye, Gluuhnev.,
P. Ta. Glazunov, I.V. Vereshchinskiy, N.P. Syrkus, A. Kh. Breger,
and B.I. Vaynshteyn. Radiation-Thermal Hydrocarbon Cracking 206
Beer, A.A p M.A. Besprozvannyy T.I. 1rd-n and M.T. Filippov.
Radiation:&Mical Telomerization 23-1
Zimakov, F.V.p Ye. V. Volkaya,, A,V. Fokin,, A,D, Sorokin, and V.M.
Belikov. Utilization of Nuclear Radiation Energy in Fluorinated
Olefin Polymerization Processes 219
Breger, A' Kh V B Osipov,, and V.A. Golldin. -Universal Installation
(K-60000) WiZ'CogO* y-Radiation Source of 60,000 Gram-Equivalent
Radium Activity, for Si=32ating Radiation-Chemical Apparatus and
Carrying Out Investigations 227
a ard---8/12~-

24372
Ll to U S/063/61/006/oi)2/004/004
oD 22r5 A105/A129
AUTHORS: Dzhagatspanyan, R. V., Zetkin, V. I.., Filippov, M. T.
TITIE: A study of the radiation addition of silicochloroform to certain
olefines
PERIODICAL: Zhurnal vsesoyuznogo khimicheskogo obshchestva im. D. I. Mendeley-
eva, v. 6, no. 2, 1961, 231 - 232
TEXT: The authors refer to the reaction of addition of hydridesolanes at
the multiple bonds of organic compounds as being the most promising process for
the production of various silicon-organic monomers of high purity. The present
article de&ls with an investigation of the addition of trichlorosilane to nonuse
-1 and cyolobexene under the action ofY - radiation at two dose rates (78 0r/sea
and 123 r/sec), 25 and,-700C and a molar ratio of the reagents of 1:1. Co
was the radiation source having an activity of 1,400 g-equiv. of radium. The
reaction products were decomposed by fractional distillation. The fonned com-
pounds were identified by the chlorine content and the determination of carbon
and hydrogen could be carried out by transforming the halidesilanes irkto the
corresponding alkoxy-derivatives. Tables 1 and 2 show the*results of the in-
Card 1/5

S/063/61/006/002/004/004
A study of the radiation addition of-silicochloroform.. A105/A129
vestigations of the addition of trichlorosilane to n6nene-1. It is seen that
an increase in the dosage from 70 r/sec to 123 r/sec increases the rate of re-
action. Table 3 lists the results of the addition of trichlorosilane to eyolo-
hexene. The values of G calculated from the experimental data obtained by the
present authors in the. reaction of addition of trichlorosi-lane to nonene-1 and
cyclohexene were found to be comparatively low and close to the values of other
experiments (Ref. 4). Under the effect of Y -emission the addition of' trichlo-
rosilane to nonene was found to take place with about the same yield as.when in-
itiated with benzoyl peroxide viz. 60.9% at 850C in the presence of weight 3% of
benzoyl peroxide (Ref. 5). There are 3 tables and 5 references: 2 Soviet-bloc
and 3 non-Soviet-bloo.
Table 1: 1 - Addition of trichlotosilane to nonene'-1. Dose rate 70 r/seo, tem-
perature 250C, mol. ratio 1:1; 2 -' reagent chargeg; 3 - radiation tinie h; 4 -
- yield, % of theoretical; 5 - radiation-chemical yield G (mol/sec 1CO ev); 6
- nonene-1; 7 - SiHCl 3*
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is ~11G no~ 10S~l B101/B207
AUTHORS: Dzhagatspanyant R. 110tBarev, G. V,-,
Filippov, M. T.
TITLE: Chlorination of organo-silicon monomers and polymers under
the action of gamma rays. I. Chlorination of liquid poly-
phenyl-methyl siloxane and,of polydimethyl siloxane rubber.
The infrared spectra of the chlorination products
PERIODICAL: Vysokomolekulzarnyye soyedineniya, v. 3, no. 4, 1961, 607-0612
TEXT: In the introduction, the authors state that initiating the Chlorine-
tion of organosilicon compounds by means of ultraviolet light proce~!ds too
slovilyy' however, that chemical initiators as e.g., benzoyl peroxideire-
quire a highczr temperature at which a sufficient chlorination of methyl
chloro silarLes io not possible owing to their instability. Therefore, the
present study airaed at initiating chlorination by means of gamma rays of
C060 at low temperatures. The following compounds were chlorinated:
1) Polyphenyl-methyl ailoxane (poly-PMS) (molecular weight 2000), and 2)
three samples of polymethyl siloxane rubber (poly-MSR) (molecular woight
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Chlorination of B101 YB207
400,000,500,000- 4-51i~o' solutions of the polymers in CC14 were used,. to
which chlorine taken from the cylinder was added. The samples were irradi-
ated in sealed ampoules at OOC with gamma rays of Co60, activity 1400 g. equ
radium. Tables 1 and 2 list the results. Heating with 40,"o KOH of EL
chlorinated poly-PMS sample with 55-5~o Cl yielded a paste from which CrY6-
tale with a chlorine content of 64.3-66-7-io were separated. on the basis of
analytical results, they obtain .the empirical formula C 6H6 Cl4 or C61[4 Cl 4'
The infrared spectra of the oily residue of hydrolysis showed an intensive
band at 9-10 p which corresponds to tile Si-O bond. Chlorination of poly-
MSR led, according to the sample used, to quite different results with
respect to the intensity of reaction and the chlorine content of the prod-
uct obtained. This is due to impurities (catalyst residues) in commercial
poly-MSR. Study of the infrared spectra yielded 36S'0 and 3615 cm-1 bands
both in initial and chlorinated rubber. These band.,! are due to OH groups
(3690 ci,,i-1 free 011; 3615 cm-1 OH with 11 bond). Accordingly, commercial
poly-mSR contains silanol groups. As a result of spectral analysis the
following is stated, though tile IR spectra of chlorinated poly-PMS and
poly-MSR differ from those of the initial sampleog no absorption bands
were found to exist which are characteristic of clilc,rinated substances.
Card 2, 5

23.135
C 1
S/190/61/003/004/011/ 04
Chlorination~of ... B101/B207
There are 2 figures, 5 tables, and 14 references: 8 Soviet-bloc and. 6rion-
Soviet-bloc. The 2 references to English-language pVblications read. as fol-
lows: Ch. Tamborcki, 11. W . Post, J ' Org. Chem., 17, 1400, 1952; C. W. Joune,
'~P.,C- Servais, C. C. Currie, M J. Hunter, J. Amer. Chem. Soc - MO, 37581
194S.
SUBIMITTED: JulY-15, 1960
3arpylliello crxn'l .10plonfille
Ilictill(e Co,
pearcuTon, s D
x1lopa, %
011UT npe"ri NO
"Oneft cl UP0,17ins.
N Ivesm 1JUJI, milli 8 IN-4,14.
XROP
1 4,70 4,05 f,97; t 70 30 8 874 48,0 5
2 7.2 4,05 2,08; 1 10 30 11:425 59,5 61
3 4,9 3,12 3:1 120 2 0.4sig 50.1 Oj
4 4,9 3,12 3:1 120 5 7,0128 54.6 61
5 4,9 3.12 3:1 120 110 7,6840 56,7 of
6 2,43 4,08 1:1 120 15 7,tUI4 33,9 34,3
7 3,3 3,12 2,03:1 120 15 5,9615 50.2 51
.,Card 3/5

21135
s/igo/6i/003/004/010/014
Chlorination of ...
B101/B207
Table I Chlorination of a 40j-'4 solution of )(CH )Si-
I(C 11 01 in M at OOG.
6 5 3 in
Legend: 1) No. of the experiment; weighed portion, g; a) chlorinel b) poly-
mor; 3) ratio mole Cl: mole structure unit of polymer,- 4) dose, r/ziec;
5) time of irradiation; min; 6) weight of the product obtainedl 'I) chlorine
content; C) found; d) calculated on the assumption of chlorine addition to
the double bonds of the ring.
MUM DII D~AePMIAIIMS XJIOPA
OL ilea COOTI10 5 nPAIIIII. 6,;
06PA. I(Ma. Moutnoc" D"
Celt Moneft A031a
'WeW 40 In".
XJIOP IOIIHMCP
OCHOOOM011b
Rollo
0
1 3 99 3,93 1 1 09 .0 70 30 32,3
:12,8
2 7:77 3.83 1 2:05:1 ID* 15 41,1 50.0
3 7.93 3,83 1 .2,17: t 0 70 30 48,9 52,t
4 10 97, 3,83 1 3:1 22,5 70 30 49.8 59.2
97
5 10: 3,83 1 3:1 0 70 60 55,3 '59,2
6 13,2 3,14 2 4,4:1 0 UO to 64.0 (17 8
7 2.38 2,49 ':3 1:1 20 - 37,7 32'41",*
'5 W,
8 4.08 2,49 3 1,64:1 20 -5, 46.0 " :
9 4.44 1.87 .3 2,5: t 0 120 60,7 .54,2
10 5.28 1,117 3 2,97:1 0 120 5 03,0 58,5
Card 4/5

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23-135
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Chlorination of ... B101/B207
Table 2. Chlorination of a 4% solution of CH 3)2S'Oln in M 4'
Legend: 1) No. of experiment; 2) weighed portion, g; a) chlorine; b) poly-
meri 3) No. of samplel 4) ratio mole C1 t mole structure unit of polymer;
15) temperaturej 6) dose, r/sec; 7) irradiation time, min; 8) chlorine
content in the product; C) found; d) calculated; 6) 10 hr in scattered
light.
Card 5/5
MAWF MURIVI�RM Mc
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it,