SCIENTIFIC ABSTRACT BRESLER, P. I. - BRESLER, S. Y.

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• Collection: Scientific Abstracts
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• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

P- A-?2
81914
0 S/061/60/009/01/00~/031
A,UTHORS; s Brosler, F.I. and Rusin, BeN,
TITUR t The Optioo-Acoustio lfteotAn the Visible and Ultraviolet
R#gio
and Its Relationship mith Photochemical Reactions in Gases
PMC031CALt Optika. I spektrookopiya, 1980, Vol 9, Nr 1, pp 22-25
(USSR)
ABSTRAM The optiao-acoustic off*,*+, van discovered in the
infrared region.
Recently Gerlovin (Rof 1) re'
ported observations of the optico-
acoustic effect in the ultraviolet region in nitrogen, oxygen and
acetylene. The proment paper reports the existence of the optico-
acouatic-offect in the nestr ultraviolet region in chlorine and in
the visible region in nitrogen dioxide. The optic*-acoustic effect
me detected by means of apparatus (Fig 1) consisting of a typical
optico-acoustic gas analyser and Including appropriate light
sources.
The ultraviolet sources -were lamps UFO and PRK-4; the -visible
scur*&
was a 12Y, 30W incandescent lamp. The authors obtained also the
"gas characteristics" of a prototype optioa-acountle gas analyzer
t,la rd 1/2

81924
S/051/60/009/01/004/031
3201/8691
The Optico-Acoastic lff!5ai. iz the Via Me aW Ultraviolet
Regions, aM Its
Relationshir- wit Viaotocheoloal Reaetions in Games
.or chlorine. It we found that the optico-ecoustic effect
'Mm
atr,-ingly enhanced on addition of hydrogm to chlorine
contained
~,-n au optico-acoustic chamber. This vae due to an
additional
opt!&co-acoastic effect produced by a photochomical
reaction of
cl.21orine and hydrogen. There are 3 figures and 1 Soviet
referenco.
SUMaTTSDs October 29, 1959
14
of
Gard 2/2

S/051/62/013/003/003/012
E032/Z5i4
AUTHOR: Bresler. P.I.
TITLE: An approximate method of determination of the integral
intensity and half-width of lines in the vibration-
rotation absorption*bands of.ga.ses
.PERIODICAL: Optika i spektroskopiya, V-13, no-3, 1962, 313-316
TEXT; It is pointed outthat the relation between tl~e
.magnitude of the optico-acoustic effect*and the properties and
density of the gas under investigation which fills the chamber of
an optico-acoustic detector of radiation may.be used in an
approximate determination of the integral-intensity and half-width
of votational lines, This method is said.to havb been first
described by M. L. Veynge-rov- and P. V.-Slabodskayp (Izv.AN SSSR,
ser.fiz., 11, 420, 1947) and was discussed theoretically by tile
author in a previous paper (Opi.i spektr., 7, 616, 1959)- It is
Tiot,.ed that the optico-acoustic detector has a basic advantage as
compared with the method described by E. B. Ifilson and A.J. Wells
(J.Chem';Phys., 14, 578, 1946). The latter method involves the
spectral decomposition of the radiation and subsequent graphical
Card 1/3

An approximate method of ... S/051/62/013/003/003/012
E032/E514
integration, "hile the OPticO-acoustic method does not require this
spectral decomposition. It is now pointed out that there is a-
range'of values for the equivalent'thickness of the gas under
investigation in the optico-acoustic detector for which the ampli-
.tude of the acoustic vibrations is proportional to the square-root
of this thickness. By determining the minimum and maximum values of'
the thickness beti,;een iihidithe square-root dependence holds, it is
possible to determine the integral intensity and half-width
(a and 6 respectively). In fact,.these two quntitities are given
byz
4.96-B I
a (5)
rM
6 o.146-d Mill (6)
wj_
max
Card 2/3

An (Lpp.roximate method of 5/051/62/013/003/003/012
E032/E514
where B is the'rotational constant of the molecule and
m = Bhc/kT. Tri-al experiments based on this ineihod and designed
to determine the integral intensity of the 14.8 It band of CO 2
have shown that the method is only suitable for the determination
'of rough values of a and .6. This might be useful in studying
..ibands which are not well known and is, therefore, of interest
in gas-analytic practice. Tfiere are 2'fig'ures.
SUBMITTED: June 21, 1961
.Card 3/3

WISIRR, S.D.,-Ansh.: KAVAINRORIZ, M*Ya, 0 insh.
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shops.'Tekat. prom.
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(Textile factories-Reating and ventilation)

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BRESLER, S.
Mikhailov, A. Utilization of urotropine in mineral and chromium
tannin. Tr. from
the Russian. P. 15.
LF',KA PROMISHLENOST) Sofiya, Vol. 4, no. 2, 1955.
SO: Monthly List of East European Accessions, (EEAL), LC, Vol.
4, no. 10, Oct. 1955,
Uncl.

DRESLIM,S.M., kandidat tskhnIcheekikh z*uk
Effect of aluminum &&Its in chrome tanning. Leg.
prom. 15 no.4:
44-45 Ap 155. (MLRA 8:7)
(Tanning)

0 0 -\ fJK 3 f 'q tv, -'~> /V/
.
ekhn.nauk
BRICSIER, S.M., kand.t
~~- --:
Method of determining the tanning efficiency of
chromium B<B.
Leg.prom.17 no.9:32-33 S '57. (MIRA 10:12)
(Chromium saltB) (Tanning)

BRISUR, S.M., kand. takhn.-nauk; MIMUYWV.A.N., doktor
tekhn.-nauk pref.
Acidity conditions in chrome tanning. Kosh.-obuv. prom.
n0-8:15-17
Ag 159. (MIRA 13.1)
(Tanning)

MSIBR, S.M., kand.tekhnnauk; MIKHAYLOV, A.N., d0ktor
tekhn.nauk. prof.
Tanning chrome pig leather with chrome emulsions.
losh.-obav.
prom. 2 no.4:12-15 Ap 160. (MM 13!9)
(Tanning)

BRESLER S.M.; MIKHAYLOV, A.N.
- -__j
Effect of the methods of the basicity regulation of
chromiim
salt solutions on their tanning properties.
Kozh.-obuv.prom.
4 no.6:19-23 Je 162. (Tanning materials) (MIRA 15:6)

BRESLER, S.M.; HIKHAILOV., A.N.
Improving the chrome emLLsion method of leather
tanning. Kozh.-
obuv.prom. 1, no.8:32-34 Ag 162. (MM 15:8)
(Tanni )

BRESLER, S.M.; MIKHAYLOV, A.N.
Effect of the tanning temperature on the stability
of the
chromium-collagen bond in leather washing with
water. Kozh.-
obuv. prom. 5 no.llt29-32 N 163. (MIRA 17:1)

BRESLFA, S.M.; MIKHAYLOV, A.F.; ROGATYKH, N.I.
~ I-
Incrensed resistance to the washing out of leather ftyed
chrome -um compounds. Nauch.-issl. trudy TSNIKP no."0:33-36 --'
1.7
163 ~MIM 18:1) 11

BRESUR, S.M.; MAWLOV, A.N.
Changes In the composition of chromium complexes
oc=rring
during tanning. Nauch.-Issl. trudy TSNIYxP
no.33t:24-30 763
(Wm 181.1)

PHASE I BOOK EXPLOITATION
SOV16568
Bresler, Semen Y
.Vvedeniye v molekiflyarnuyu biologiyu. (Introduction to Molecular
Biology)
Moscow, Izd-vo AN SSSR, 1963. 519 p. Errata slip inserted. 7500 copies
printed.
Sponsoring Agency: Akademiya nauk SSSR. Institut vysokomolekulyarnykh
soyedineniy.
Resp. Ed. : S. A. Neyfakh, Doctor of Biological Sciences, Professor;
Ed. of
Publishing House: A. A. Frolov; Tech. Ed.: R. A. Zamarayeva.
'PURPOSE: This book is intended for scientists and graduate st4ents in
chem,-
istry, physics, and biology.
COVE-RAGE: The book reviews modern achievements in a comparatively new.
fieldofscience, devoted to the study of li,te.on--!.-a
7
Card 1/i8

Introduction to Molecular Biology SOV16568 7
level. The author defines the role~knd the place of molecular
biology in r
'trends in the
natural science and shows the direction of past and present
study of high molecular compounds occurring in nature (proteins and
nucleic
acids) and the progress being made in the Study of their structure,
functions,
and synthesis in the cell. There are 208 references.
TABLE OF CONTENTS:
Introdbction 3
Ch. L'' Structure of Proteins 9
1. Introduction 9
2. Chemical structure of proteins 10 f
3. Analysis of amino-acid composition of proteins 17
4. Determination of sequence of amino acids in the protein chain 20
5. ,.Classification of the macromolecular structure of proteins 32
6. SynthEltic polypeptides, models of proteins 36
Card 2/b

13HESLER, S.Ye.; PYRKOV, L.M.$* FRENKELI, S.Ya.
Sediine'ntation of graft copolymers In a density g?adipnt.
Approach
to equilibrium, selective solvation, and polydisorsity of
composition.
Vysok-om.soed. 5 no.9e1315-1320 S 163. (MIRA 17:1)
1. Institut vy-sokomolekularnykii soyedinenly AN SSSR.

BRESLER, S.Ye.; POPOV, A.G.
Gas-liquid chromatography. Part 3. Zhur. fiz. khim.
37 no.5:.
1178-1182 My 163. (MIRA 17:1)
1. Institut vysokomolekulyarnykh soyedineniy AN
SSSR.

BRESLER. S.Ye.; PERUMOV, D.A.
Mutagenesis on isolated DNA induced by ultraviolet
radiation
and chemical agents. Dokl. AN SSSR 158 no.4:967-969
0 164.
(MIRA 17:11)
1. Inatitut vysokomolekulyarnyk)i soyedineniy AN
SSSR. Prod-
stavleno akademikom A.N. Tereninym.

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40 and Tkor. Phys. V-S-S.R.. k 6. PP. 711-721. 1939. In Rwtian.
60 0
:0 j After a review of the experimental facts about molecular
structure of =00
4uids, the autbor developit a qualitative theory of the melting
of solids, goo
-4 on the ideas oforderand disorder Introduced by Bragg and
Williams.
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at
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PhPical & Chem:
A S A. S L A METALLURGICAL LMIATWI

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auk ISAR.. OW.Wkimv. ..k
0 mank 3, 10-17(199)(Pub. 1943).
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i=z ditaft to go" grost p*du.
ractsis. ;Tb
bility. I t the Am sitp In dkoe OoOmed.
sea 3. -1 an Imbatko. lu fact tug a OwDurna usitts
a =hk. kn wwd tbt dectm shft to the =d of the new
chain pervalts further chain H. M. L*emer
21*
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21
A MULLUMMAL LITCRATM MASWICATION 9.vrz=-.M=
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=00

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00".

ur '.ML"I in all. .11111. 44 tht'r 4411.1141'. (m. 10 Ill,.
nild

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m

and fit., Invduct. guell " in m4vrot, than the miltmal

oo
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BFMIER) S. Ye.
ConLptes Rend. Acad. Sci. MS. 1944, 43,
310-314 (cont.)
to an orderly packinj3 of the folded
polypeptide chain.
Inst. of Biochemistry, Phys, Tech Inst.
AS USSR

- - - - - - - - - - - - - - - - - -
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ll-tit,11 I,,, -a-, I-- 1w
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o: "Or
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111,111-411lig Itlahli- 4-1 newol all
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114.41 1 -11, t..
I.Mar ditilk 41,6'4-4 file I -,vial VACIIII
".1vt III A X lit .1 wa,, 14-1411 .11 AIMA lit V., V,", %mg 1--
filial j%j%ajjMo,V 11,Al,4141 101 IkIAO, 1~14 l6t,11-1 41 11411
X
Ila- M-Im~l %~4. ill 1A, t.% it% %stimi I" t,j-j.lj-j. 11,~
-'-k0 -i-
Atti-411 N', W, AXIII Malkill Kk. 14, At,%V-k I, Ikkki- ~.t
%4-c
-1" Ail. PI- 11111- 'If IlIC 141111 1-1 1 Atilt. %141114~ 11
IVa lp"I ad &A 10 AtId I'a M%11- It 1~
all 0 I.I.Jer I-Y .&N.It I'Ader atilt. littmur, ill 34%
I IIK. 4,1.mptt.,t~t
Ar Ow I-M ..."J 1, al."It L'.0 ~. M I vni,im. I.Q. 'C .4
'I
Ill lilt, A -tItAlavi Ind-1, 4 0414 P a&*
acts.1"I
Ow lilt, Lit. - to -I- it v
jjlj1kqlt- 1.1 A" 1 1-10
111weltil Willi a vaelluill 1111111111 .111.1 1"..
'ali'lavl4my. 11"I 1-tIll, obimil"I 'All'.1% till 4.1 t,
111111 allid wfirt awity ftq"lt tilt- I,v Ct 1: ~ I it ltmaw,t
Ille mo."If V 1( 1111111140%
go ..( it.. plv-mv, N't"urii N, goo
a ... I -.Ikt slim fir Vic "Itt'l ph--w wa, L.-pt .4 1 It wit
jlj~ 41111.1 11114411 %it. ill If.- I~Ml-. t4 till
A m It. - IM', m .. Fl."'t Ille amt. 4 liquell"I
If val.l. ill I fit . file 14,1111. vn-tr 144,11"1 its I.-Ilm
44 tj - Inst. Chemica.1 physads
N wilb,"It , AS
11saitill. I'll Ow %vadill"ll .)I 111tr wall'
ill I lic .141, 1" 14, lilt, ral hollfre, ,, I" ilia et"4.141-1
gill v Irs,
.0b I)w .411. 1.4~. I'l. no mu'li dilleirmi 000
11J. I. ,4implo, I," %v- 1~: J-~ $09
-plu J.V~ 1 41,1. )"a 2. k~ - slat"It .1.
Va. 21"; willi'm %141t 1-11,11tji, fil - al.nit 18, 32.
1. I"'ro t,pllt Ic, half p -U, 11. 2. to
age
!L
~Iog 41,10116 .11 Gv Got ilia 111m1 41111111 am "V law
u 5 al An L I a "it 0 A I ill
of IS a It x Kid al 1 4
a a 0 Vol a 0 6 0 6 0 0 0 4 0 0 0 0 o 0 e o all, 62

-A V F

11 U -11 is
I
II U
L 4A IW OtIc MH
179
A- k. -11- A I

n It c'

- -
-
L
4
I-
. 9 1
i

Litt &Wj FOUP141if

00
,

J

-00

00

d an bow NOR k me
-
-
-

n
R E. arm o
son a
" )" (Z 14. trwif

Z

W'410-411
tlL-lZp~ol tion of (CH;CH) (1)
a
n
l
W
t
i
i
& "

_
a
a
nwit
pte
e
i
:r
; M

see

go

v $t (
x
t. Initial temp.. the
mind equiv. of the lowc?
limit In chisin qm
k*M
hu bw dowila
tr
t
d
t
i
i
1)

a
t
con
a
n
s
k
, (
ng
p
-to
36~ of Hi's does Dot polynictive until the temp, is misW to
.

ee

-7
16
an autowacceleratlig reactlost sud&nly wts in and attalnl~,

ex "We Pr a
corre7,KPmdingO;rit. temp. for (M is
L end th
TM=r&D4conS samount9featalyrt

no*

00

!A~ Well as At Just O-OS-41% of BF, is n
i
h
=

0

e
init
ate t

&d

Leningrad Physico-Thchnical inst.
Acad. Sci
USM

.
)

;00

A S 4 S L -I TALO~POC&L UTER47M CLASSIVICA11CM
4V
U is A'F 10 is
t? Zv t, 00 St Is is 99 a K it it it M
too
too
An i v rw 5 w a i ir w j-7T
ism
05

047 1 1 1 1. IN 11 a ii so is IS U U a as it U a IS ;SM0
Is TTJ I ToTITIT1~1i,ii ON NAIADS
A A L F &i- a A L-A- ~K 0 -A L- A,!
__ft- -
okokly1b& The procedure Died In theentymicsytitbriki. 11
C19 was to place the lompul with a thin capillary opening,
I'l coutg. 3 ml. of the protein hydrolyLatc, In a rubber Lack 00
filled with 3 ml. of the loostur soln. The rubber wk was
placed it a thk -wal bomb surrounded by d fit. water, 06
-00
through which the Vmssum was communicated by a steel
s -ss. The rubber -ack prevented '00
piston of a hydraulic pro
contamination of the suln. with traces of heavy metals.
1, UITMIc sysithimils of des at MA I Is I Itill. a tryptic
hydrolysate wa% cut. 100
and III. V. 0111=0 odyid 1r,"W"-M40i W,',.dtm' of 0.1 X Wrote
buffer (till
00 1); cf, knes Involved In -00
C.A. 41,
protein metabolism usually art proteolytic Y when em. wit a
grialin coocn. of 1-47v. and the ratio of tryptin to
0 rl~ %cibstrute 1:30. The same gelatin Wn. could be repeat. r*
ployed in the tab, However. at a pressure ISM atm.*
'3 tryr, in, papain, rmp%in, and pepsin exert their synthetic,
kdly hydrolyzed (at atm. promsum) and th-n resynthesimA =0 0
(at WW atm. pressure) by toe action of the same sample
00 0 Action, forming polypeptioles and proteins from amino of
trypilin. The subsccluent enzyndc bydralyxis of the 4,00
wt&. The synthetic activity of the protecklytic enrymell
resynthesized gelatin promded at the Saint rate as the
09 .3 at high pressures is explained by Le Chatelier's
Principle. initial hydrolysis. After msyntlociis, the gelatin
Lxhavcd =00
00 High pressures reduce the mol. voill. The expts. of Berial
very much like the starting malcrial; solm. gtlatiuizrd reo
lb)arecited. Thus. inacrysitalcof after having been cooled to
mom temp. However. the
00 =00
a !b'e`diot'akw','ebetwer. She Inb. is 5.8 Agbereas exact Datum
of the resylithetimdtirotrius (mol. wt.,
tance betwern the alanine units in shin polypep Ide is
elecumbern.. and bial. properties) lot yet been elu. 2 coo
cidated. The hydrolyzcd ovalbumin after resyntht-%Is
by trypsin at high pressures was also quite similar to the
starting ovalbumin. The resynthesis of hemoglobin by I%*
If
palkalto ykided a product free Of Igment. and resembled
al wt
obulln. T1w mult -a% qui r iffemut Aith the -trum =00
.1-Andin w,rnilio-Iml I.y itvi-In. A xI ~4, Walw.l
If licit votild not 1W fit 0IL'S14-' '" lot .411
Leningrad Physicck-T~echnjeaj In6t. solos. Whco acted on fly
Nttong 110.kc. It Ilk
the form of a turbid colloidal solo. If. IT"llcy
--A oad.
ASII-ILA A1JAl.LU1RGKA~ MILLRE CLASSIFICATION t:0 0
all- - - --- ---- -- I io,, va.tn. W*9~
1419" IV ONT (111W 4311110-C, *j&i`i-17FW6;~--1%-1---'---- \ so
A 4 rw 0 a 111 1 Is IN 0 .0 a )I I I K311
at An L
A It It It dadi
U0 "0' ISO, 0" 0c, 00 or oft 0* 0 0 0 10, 00 0 0 0 0010 0 0 0 0
0 00 0 0 * 0000 000 :10

Bresler, S. E.
FA 2OT28
Oi
"PIrinciples-of the razyme System Vnder Pressure,
S. 1% Brealer, 3 PP
"Dok Ak Nauk SSSR" Vol Ut No 2
Submitted by A,. F.- Toffe', 1!~nln&hd Physical. Techni-
cal Institute, AoAdemyof Scieh~6es of the USSR,
,20 Nov 1946. Uper-Iments barried out under pressures
6f 6J.000 atmospheres. Canaltided that under suffi-
ciently high *essures a feirmentative synthesis
'occurs In trypsin and, anylase,

S. Ys
PA 60TI
WIPM1
Ch,-~-sstry Syntheals
~Gyrothesla of FolMptldrs Under Preaeure,"
S, Ya, 1~reolar, M. Y~ '"Ilkins, Phys-Teoh Inst,
Acad
SOA USSIR, lAnIngrad, 4 pp
"Poi.Akad- Nauj-, SSSR, Nova Ser" Vol LVII, No I
Describes experiments vbioh show that
proteolytj~e
ferments such an try-pain, papain, erepsin, and
papain
resynthesite under apressure of several thousand
at-
zosphareB. ltrpra~seea,tbou*e to N'. A.
Selezuevaya vho
took part.In the experiziente.

00 A
:a -
so-
a* e
09-4
Sig A'
00 i
d
001)
go a
""' -.1 -1- 41 9
I I I Is 7 9 WXX 11
W W.
A
UVWicaw"jise of whik" Materials. (In Russian.)
Brealer. Kolloidosvi Zhur
R V. AfAnm'ev "d 9, E
nist (Colloid Journal), v. 10,MY"Ug. 2948, p. 249-
258.
Presents results of attempts to ChSn90 the chemi-
cal and mechanical properties of the above by
forination of chemical bonds between the macro-
molecules of cellulose. that 18. A sort Of VUICSnIZA-
tinn. Thia process reduces the plasticity of the
fiber. Darticularly in a water-vapor atinospherv.
-ILA 81ETALL.'!~C.L MERATM CLASUPKATIO
9
141443 %to 0WV oft Will aw V III
$I AV 10 is 0 A V ZA a ad 0 j, .1 Nr #1 9 a A
9 0' a D up K Is it It a W a
No RA
0.0 0 0 0 0 0 0 go goes 0 0 0.* 00 000 0900o 0 0 a 0 0 *so a 0
0
0 0.0 0.a- 0 0 0.0 0 00 0 0 No 0 0 0 4 -0- ft 0 0 0 0 0 0 0
0.0 6.0-1& ,0, 0
goo
use
lose
so
0:0

UM/Chemistry Synthesis Nov/Dec 48
Chemistry Albumen
11'roblems in the Synthesis of Albumen
and Starch,
S. Te. Bresler, Physicotech InBt, Aced
Sol USSR,
16 pp
111z Ak Vauk SSSR,, Ser Fiz" Vol XII, No 6
Concludes that fermentation reactions in
hydrolysis of albumens and starch are
reversible.
Shift In equilibrium from dissolution of
polymeric
molecules to-synthesis is associated
vith.varla~-
tions in volume due to changes In the
peptlde
(and ozide) link in the chain. Experiment
re-
vealed correlation of volume
variationa,vith
synthesis-ifienomens for various
conditions
governing reaction.
25A9Tlo

he nrril-~Pm tf svmth~~is cf prn'.kv~ and F--(r!
44
g"c 't",
3u,c at &j' a product ~,ntainirig Ij- 15 anism, acid Lp.-
-ith - mol. --. 120i~- 14('-). F~T!-' on pr~,trm rc~, ,
-Ihrm~ b) uiuasm of enxy~mc, we rnt~ntioned I rf. P7rr,ltq , C A
41. 69-55g: 43, 704A.). Fo- 5iich wotk under high pre-iir~
Lbe borate buiTtr (pll 9) apDear5 to ~, the best, on the bau,
~f ol changes cb-r~-r,! dui-ing pm?iri:~ h-111Q1-:~ 'b,
5m. in pure Y110, prm~urc k-"yntheEis is uv.~,-ti;fact-
rrratment of alaiiine in bmate and -xxia butier ; p1l J. I
at CMI atm. with paricrf-atm lek; to Poly-nm "it"
dedine of sminc)-N by 27--W%. The pir-l-act, p-~f, i ~r-
ad-orpt-ior. on- C. shotef 2 firacricim: alani,e a-i the
6de Simikrly rnaltv,t was prqveandenst-I -n th, pr-ei-,
of malt amvla~,~ and s-alivary anMa-srl zh~ ~,nllvl m.
~;stedl if at~)ut A maltr," knits and pre a i--
C'Im -ith ~dinc. G N! K -a!"g-IfT

H
0"
C\J
UM/Chexistry - Amino Acids )by/j= 49
chemistry - Proteins
08yothesis'of Pro teins and Peptides Under
Presslre.,
81,;i Te.' Bresler, M. V. GlIkin ', A. P.
Konikov, N. A.
S*Uzneva, P. A. Flnogenov., Molecular
Dept, Phyq1co-
t*0 Mazt, Acad Sci USSR, Microblol Dept,
Inst of
Xxpirlmr.tal YAd, Acad Med Sci USSR, 14. pp
"Tz.Ak Nauk SSSR., Ser Piz" Vol X171, No 3
392 - Vol&
'MVIerixents showed, that. polymers
resynthesized by
aIatbdrabw6 ww~t characteristic
physicocben-tcal and
~4aq .. Wpal properties of 'natural
pioteins. A nmdmr
at'! Important conclusions' on structure
of protein
52/49T15
ule and connection of imwnologiq4~~ and
fer-.
.. - 8 , ""' ~ - , f
I"tatIve activity viih tructu", 0
'my, b-a drawn from resynthesis of
protein. Xkde~_,~~
t", ~,, " - in~
Artt~ -imccessful stepe,' In. synth6alz
simplest sibetrateii. Sulimitt6t
:Ayr

W10 0 0 0 0 a 16 0 0 0 0 0 W
t 4 1 1 IS It 11 11 14 It it 11 to to IV .1, b A It A A A, V V
1) Mb UP 1r 1#0 41 All) 410,~LW,
fij ~ 0. (A W
A N
- --------- -- ----
Structure a awbittin ofateorn toad their Interaction with J.60
the external Mewum. S. I?. If 118'Okkifflo,yu 14,
V-Vtl I Of
Cf. C.A.
-ldbutulu (1-3%) in phosphate buffer o( 7.
an Wit. ailb ttbtf (6,54,J), lieve a lower seditacutat"
const. than the conk", when subjected to the nilracirn-
trifuse in Svedbers's tall'. Sweden, Cak-H. shovml an
titicrva%e of 18.7% In the site of the protein mal. as a result
00 'elf of swtWnS. M" 5 and 101/p, acetone wits added to the
Iwoleiv soln.. The tool. increase was 8 aind 15.9%. rrsp. V* 0
In the preftwe cf urra, the sedimentation evast. of x"m
albumin Increased. 7%e protein mol. had become =00
btavk- because 300 mob. of uses W combined with It.
A soln. of scruan albumin vatd. with Coll. gave 2 scilimen.
tatkni peaks, one due to the lemm albumin, the other
06" due to the bimolocular, assocd. protein. The jnanoprv~
og"
7frin emM not be sepd. from the diprotelto by clectro-
06 a phoresis. H. Priestley Ve 0
010 V
06 gig**
CA 0
;0-0 ~;Ii III-Ir
Leningrad PhPiCO-TlOehnical Inst., Acad. Sci. Usm
V
A S.. I k WALUOGiCAL UUNATOf CL4111FKAUGH
7
U U
If 0
of
'--09
%* 4
HLO n 1 1.
*so 0 6~
0*000 0 *A

CA
or.
C*.Z.
A
US.S.R.). DrAlay A"J. J a 621
1
(1949); cf. C.A. 4S While semm Albumis 1.1
its an ic peopm IZ "..d.-ant ifielty upon Cv.
.xymicrydroly2U, tnMuic rulruthZeUnder 6W lb.
matam both pmpatits: so new specificities
e.speelficity mu%t be amtkd not to& mceo
molecule but to mue specific Wed" tbemrA.
0. it. xaswapDff
I Cr

MESLER, S.Ye.; FIXOGENOV, P.A.
Method of electrophoresis of proteins. Bi6khimiia,
Moslcva 15 no.2:
145-154 Mar-Apr 1950. (CDIL 20:7)
1. Physico-Technical Institute, Academy of Sciences
USSR, Leningrad.

Now slyndwsk c(pellypoodes by ondensation c4 WWdss
10, acids. S. V- litcIq ;%till N, A. Sk-Irtt%cv,t
I.T.I.V111-11 I'lin. ;,-I. 114S.S.R.).
An'. Ollikh" khow. (J. Gen. Chesil.)
A031, (40 c.) in Itks %131, at". Ftolt tc(luXed -NI all
tails.
with 11.5 1. RtONsa :-i%v a cryst, lmsshwt whk-h was
taken up in Mire Fto" and Mid. with k1TV lick. altemll,
Anil M%UL, r1fridius 100"A' in, ~41'- \"
hy-jimllucts, wrm dtitifti. iltwr list was as.-
plied iothe derivs. of 110ac-141% to lorin IstAyincrie
pruductN.
I,actic and was converivii by ltralluent of the Ft ester
with Nit, into the asuiAr which, txiiled with N4 in th.
isitrine, Vichled the NA dcriv.. AftCH(O-VOCON11s, n
tml. The product (8 g.) heated in an rVacual"I lubt 3Y
weeks to fill' gave a transprent "fill, "Itich was treated
in FiOll with dry IICI, filtrml. and evalxl.. yielding t
clear resin. dr= INN' without melting - it 1% M-4. in I I-A).
1V44 Ill Will In InFtO.dinxaue.orNIrtCO. Condell.
~itinns for is-, dars gives a miter reiin. Condensation of
the free arnide with nictattir \a at 110' pVC A dark prod.
urt and considersible Nils. Ilydrolpis of the isrialut-t liv
air. aq. IICI at .1.3' in 22 his. pre 40"; CIrAVARIE Of the
"tide links, while pancreatin gave 451,j. hydrolyti% in Ill
bri. In both iraws allinine wa% the end kyrocluct, hence the
resin was a poly~seplide of jisdyalassixt 41se.
Asisisr-itti4olon
cluktrisal and relractintiettic rxinin. 4 t1w -An.
established
The pc4ymrrir nature of the IsicAurt and ill hydrolyzale%.
INALrinsetric eliamn. allowed &117,, retention of the L-
configuration. Mol. wt. by viscosity detris. gave 500) -
WW 8v. Tnol. w1%. 01 M. Koldipoff

BRESISR. S.Ye.
Biosynthesis of protein, Usp, sovrem. biol. 30
no.1:90-112
July-Aug. 1950. (CLKL 20:1)
1. Leningrad.

A I. -j .27 Va. Frenliti. DokWy Akad.
R W~j 19M.-Rat akin procollwa is
globulin as shown by ultracentrifugal.
;==-Its diffuslon coeff. at 20' in 11,0 is 2.24 X
I0-'cm.1/we.&tO.34).ts%concn. It&mo1.wj.iSftfd.A3
M.4110 still the shaiv of the m(4. estd. Ittim the 1114.
Ifir.
tion coum. Is a cylituirr with ;MI: I axis ralki with the
length
about W A. Vitracrntrifugol study in OZ-1 U SaCt
sure a triply ptaked sedimentation curve. the 2 new peaks
being caused by more rapidly moving particles, ap1wrently
caused by lengthwise &&own.. ai, well " axial assorn.
G. M. KI".Poff -

bkis-LER, So.
From the Russian for Dr. Daniel Steinberg
Doklad,- Akademii Nauk SSSR 75, 1: 79-82, 1950
Enzymatic reaction of transfer of phosphate from
adenosinetriphosphoric acid to
ribonucleic acid
by
S. E. Bresler and E. 1. Widzian
Trearilated at tjw
rMU tranglati(M a"- iler'Ic. !Tj 10.11M.

PROOMIY* Samos we M01116-proloks, q, Ig. B
.-And N. A. Rotintsydi (phys.-Treh. Init.,' Lt;nln1;ft**
Akkkfailte 16 Si- " 1931).-Cocn. trZpdn. at the trypsin
lo pancrentic JuIC. 001111111111 1 MOM Vf tier Mfg. tWIVIVill,
Cly.l. Ilyl-n (0,14111rd by the 14-1-111. of I Inge V.,we.- q
i .1hilluill mild twortlylAfliniflArnhir
a~ l"khttentrs) k the &title. 111c Ct is 11"t firudy, bmsid.
Arl-I
ran be mnov"I hy aliAlv%k. I'stfifirti, bill unt-tyltil. mni,
trypsin i- mnipleltly inhibiled by the following cleg. nittal
in I -fornnins (n 0AIM41AU'l M coacn.':
-le,lillill. frinnaldoxinve, Na rhenylilikviliturnitte. thi
=
glycolic Acid. TnCMPtOtWU9UthL~OtC. nltrfrW~2-nflphthol.
and diplictivicarbari,le. \me ol chew
jpoi_n,= ISO effectively tu'ralyze the com. en"e hAvc
he 11. on cmid. (MR-Colits.) trylisin. On dialys.
Mtlki'try ith"i't I*% of the 11""tent"tie 4"t"'Ity i'
~~!j
van I.- Imply by the *.I,ln. of
1;
INVI it M 11 h It I I
'fiec
1!.',','d bi, by prolt~yli, 7,,ud,,'hi`ghpprr%Nurv%
i4 achievett lit the prr,4ttlcv of thi-sc vartat Ativat,K, .
lit
rhyinottypshl. the Avlive slirtal i, Mg, whi'll i% 1% M
itilliff
Ifimil,Y, and In imt rrmovvil by dWy.6. Chvinwivinhe
that minur disvilivi, diAwdcn in ntAn and in AnintAl. wt us
because of the xwcity of the metals entering into the compit.
of rilmdre emynics, oor limuse of a metabolic disturbance
of these tnetalq lit the ornritun. The heahvif rifea 4 so~
IF , r live M%orden 1i nwrilint to the pn-
cure lit thr wxter t4 tratv eirturtits net~~irv to the msuii-t
141ti. W Pr"ll'y
114

BRESLER, S.Ye.; PAVLOVA, S.A.; FINOaNOV, P.A.
" r
Diffusion of polymers in solutions. Zhur.Takh. Fiz.
2l,lo6l-5 '51,
(CA 47 no.17:8467 153) (MLRA 4:9)
1. Leningrad Phys.-TechJust.

//,07
jtt~= of bititagkally midtil iusWin.
M , and A. NI. Tonpir.
,;-~,s~ R. 78. &M-N irtwfin a. a 0.41%M.An.
ill 0.2,11 fwatv buffer at liff HA wa* w4if a% %tA".
ing malvrLij. Thi,& hydridyini toy 1)(01127c, trylp.
,III and 11 10111% rhynintryli-in for 4 A ht-,. in tht, e-
t"it -it
Af.rui 5% vkhich P. I'm thr'T clivylliv., Slorr the
~. suvills, IV 41,14-th im-11 timirr jorr"Ittv, I Ilry I%
tic %tabilil(A
lov. !h1c"r Kitivifte, hotmile sllva~lltvd fly III,
vir'k-A. III fire allsill'i ItImil". tv"cht-41 I'll
pIr%rIII I-
urwril hydnoly%i- by the ent)-int, xv r0raw III im-urr the
mi%t- WO- adplord illinledLitely to flit 2~5 and Imml tit
1uptid 44, The tvvnthmirvil mmilist, to wjjjj;j,j uids the
livibillmor, %homill ivilfral ilv,111111 milinwiltathm
41"l%1% .
fill. 111.1walf'I 4d it. 144"Itwit'd (mm 1-4-
t4virttv h,%% mill I , I tw 1-10 'wimtv %,I, Ir.
%,4jWi,km1 it, tile "%Vnt III tilur 101";. The fryIInslyzate
U,,,l a. *failing Illatevial (in rv.Yjjt)jti~ Ila. ilwvsivr~
(',. \I . K(~AAJKIO

RADIOACTIVE E~wdE'N Dre4lcr. m"'icolv

(Book
Lualngrad, GoatekhAzIdAt, 19592.

-va Conference)
ou diaplay ut Gem

A monograph oA the chatnistry of radio wivo. eubut=ou
s

and radiocbemloAl' Mothoda of invostigAtizal" Radioactive

scrics;
anslysta of the,proocaues of conc~ontratlon, acpara-

*ion of rAdloactive
subutAnces. Fundamimtals
tion and atlaorp,

of thc chemistry of and artificial radio-

activItj and
of nuol.car reactions, Mothiorls of produting

artificial radlone tive
clomv4ta And their compouada, Appli-

catioa of labalk!datoma L.
ohornical, biological, uiedioal

and gi:oloaltml r6c-rch; bibliog"phy
after each 4-h4ptur.

.
dx1bll4ar'.-j not,)

,

lZ
13A;1,16 Pill ",,in
prvtcascs. After hydrolysH lad occill-red 111C, mix,111" 'kas
...-yored
I 9E;3 to a pressure of 6000 atni. nnd (tic. resynthesis of the
pmfeiix Mudivd.
It is fou d that. with mixtures ~f different. ~"hstraks, e.g..
L,
-4 ovalbuminn'scrum alburnin, the ammint of protein lesvnthesised.
CA_T-__Z'X- was greatly reduced, although each of t1w pr,,teins
'separately
p Djw_~I~j cold be rwyntltesiqcd, Resynthesis Lakes phict: not in
steps
rbut rapidl nd it in not possibl,_- to is,,late any i-att-miediary
substancesyi.;tlwcen the ptoductq of hydrolysis and the rcyn- -'~ry
thasised protein. A 13. Smyrn.

B-I U, gr.-R~ S. Y8. ~ MkrLovj, S. ~. I FIIIOCI~IIOVI .0. A. I
cilmi-iot" K. V*
Polymers and Polymerization
Remarks on the paper "Diffusion of polymers in solutionsfI
Zhur. fiz. khim. 26 No. 3,
9. Monthl List of Russian Accessions, Library of Congress,
September -195,9? Uncl.

USSR/Chemistry, Biological - Prot~ins 11
Jun152
'n crystallization of Resynthesized
Protein," S. Ye.
Bresler, N.A. Selezneva
"Dok Ak Nauk SSSE" Vol LXXXIV, No 5, PP
1013-1015
Authors showed formerly that enzymatic
resynthesis
under pressure of products of deep
fission of pro-
teins yielded artificial substancea of
globular stzuc_
ture which exhibited a biol activity
(antigenic,
enzymatic, and hormonal) typical for
native proteins.
In the expts described now, equine serum
albumin was
split by trypsin and cbynotrypoin. Upon
addn of glu-
cose serv:Lxig to protect the enzymes
against fission,
223T22
the protein was resynthesized under
pressure. Inves-
tigatidn in an ultracentrifuge showed
that the re-
synthesized protein showed a mol wt
dispersion of 22%
in comparison Vith the initial albumin.
This disper-
eion explains the lower biol activity
per unit of wt
exhibited by resynthesized proteiris.
The product of
resynihesis cryst& with great facility,
however.
223T22
g17

Bonn, SJ.; KORSHa. V.V,.- PAVWVA, S.A.; FIVOUNOV, P.A.
X"rimental study of the molecular-weight distribution
function of
Tol,vamides. Boklady Akad.Nauk S.S.S.R. 87, 961-4
152. (MLRA 5:12)
13A 47 no.14:6738 053)
1. Inst. High-Hol. Compds.. Aoad. Soi. U.S.S.R.,
Moscow.

BREMR) SMI.
"Concerning the Article 'Synthesis of Proteins' by S.Ye.
Bresler
V.11. Korothoruchl~o, Kitv, reviewer)
Bidkhim, vol. 18, no. 1, PP 130-13b, jan/Feb 1953
Review is an exhaustive criticism of an article whic'n
appeared in Voprosy Filozofii,
no.3, 1951, pp 82-94. The reviewer accuses Bresler of devi
ating from the theories of
dialectical. materiali6m and of presenting theories whIcb
are-in direct contradiction
to his wwn (Bfesier's) experimental data. He quotes Bresler as
ienying the
existence of polypeptides in living tissue and accuses him of
disregarding the effects
of environment on the synthesis of proteins. His general
conclusion is that Bresler
has brought considerable confusion to the accepted ideas on
the biological synthesis
,of proteins.
257T3

of the
041de boj&-iin-ffL-
kei
ATQ
L
-metbDds' d 'cu
""Anw
*as tbus
M-0
n -thn-jams 't case
tive dei~.6. Could be obt..L., tein
InrI3. 9 c%talms in tj~ MI,
int - arti
;!.ytion ol dc.tire

'

. ..........
~rlttw for Coa&-
d mug Ion Ls

Oat the advarpu
mot wega. vabe
m cm the gnfts of the id"tbout
but traM by a timt v, - 7%b trostion

hen v h.

t&dsorpd=cDG3t,

-tion
ThI3 v

dm both f
tnm

q
or them"
E

-
of t)u*e &t=4 M I

S.

In vestipUrm by mum of an uitmmtd-

fuze o1 thu m~ulat vvdgbi
Wrl'bution of ymeral

v - -
BRn R end 11
FRr
zkar
Y
xj

.
'
.
-
, b
_1_.
N

Chip).
502-22i71 In Bn&rh ; Rv&h.

T,wlt*nt,, 1957, 30, 487- 595, A metbwl i,4
gj,~n (or

Wimr

pApnm in pfttrzJ. It im-Aves fract4mrAing tht,

pplyrner
into a porir, of nnrrov fraefions nnd invwti-

ga~rg nath uitb 6,,l
ultri-ritrilmzt,; plot4ng thn

1"t Fai7~ Irutviri atirt ~~,n, ew,
inau-tz d

cur,vs v~ bwld up 1-he d~~oibuli~p ILn-tion ;I Oo

rf th,
-Y,)!- 1~1-vrnor, tita

,ove?y of a pne,al lijr--vtmnpJ ~.-,lannrt
tot~-cev stMj-

and rwal- alu xv-gllta faT a

girt

of uhn of InOr-pull"
w6ghts of

7,7.2T,T',II '. . X'W", a
The Committee on Btalin Prizes (Of the Omweil of Ministers UBSR)
in the fields of
science and Inventions anDounces that- the folloving scientific
vorks., popular scien-
tific tooks, and textbooke have been submitted for competition
for Stalin Prices for
the Yesars 1952 and 1953. (BoveteMya, Maturs Moscov, No. 22-40j,
20 Fab - 3 Apr 1954)
I'Me
ye.
GlirLlrvi, I-,. V.
Title of Work
ITes.7nThes!F_of Diolof-i-
Calay Active T'rotc-11-Is
Un(ler T~-essurnl'
Nominated by
, - - ,Fi en! nnO.
-.113UT'l-LIM ff -
1',eeiwI Chci-istry, A .cadcrv
of 1-'~!dical scin Ssr"
SO: w-30604,, 7 July 1954

D-lsturbs=e of chtMkAL-tM9a-liA its VurhLr* tarvers
S, B d G. V
A tudT W~.. made Ed 1hr priabirm at the cqw:
'h-n-11T I'llvailml in th. jaqlm~ !-)v,
rlK j-'-
k4a,"'. 1, r,; -.1 1 i~;-
a-l I A ~ln~ W c~lr -1,
-al
t 1.1
Lc
ntv-~urvd by immn, o! a ;
u, ..ng thI ;-thd c4 br-illiff ij- PL-t
1,~j j~nnwicr i1 20 min The err~a U; ih,,
".: "ell ~a-, ~i 2! d~r- vl,~ F~ W;)IYI.E ;ht 6~7,
t c% -in ol arul and .1, ~n hex~c as employecl 71t~
ipphrd it. tht cluantity tif f-6 drop& tr(tri. a spezial,
ThI --h- z~f
d, L- d lan Pr-c-d in -hc P- ot pri-r~UN
re---rs of 4t,,l that thI tirtgmal ,aadtttc--j v zr,,
surfucr laktr timpiam !i;c chEtit Nuil. hom hydmi),tu

BRESLER, S.Ye. (Leningrad)
llnzymatic synthesis of protein. Usp.biDl.kbiM. 2;66-96
154.
(MIRA 12:12)
(PROTEINS,
synthesis, fermentative)

j .-BRESUZRI S- F-
.4
The molecular wels, t of
,(M
-.4renkc-116tit, lot. Comprin
and Na
I.I.A.R.,
.
A
Leningrad). P.Ohimiya 19, 88-95
(1954).-Sedinientation anTc
=ito-iutt coasts. and tool. Wis.
of two plasteins were detd. The plastchis proved to be
polydispersed low-mol. . I . I V. nial. wt. of
_nt2ijt_,Q_%vtt i an a
about 5W. The presenm ig -inol, fractions in pla-dein
V=
conipnx. reported by other% are explainable an the basis of
wndary.aggregution. P agjno icavy-ino
J,,Weins cont I I
fractions, The formulaorrutrreund 43.
6259f) yielded correct sedfiWe-utation constc. for-low-mol.
Polypeptides. Calen. of mol. wt. on the basis of distribu
tion in the diffusion layer close to the bottom of the tub
can be made with the aid of the barometric Boltzmann for
mula. B. S. Levine

BRESIM, S. Ye., MYADIIDVA, V. I. and EBAINW., V. Ya.
"Investigation of the 14schaniam of Rubber Vulcanisation aided by
Radioactive
Sulphur. I." Zhur. Tekhn. Fiz.) 1954, 24, P. 577-98
Thin rubber discs were coated on the under surface with sulphur,
isotope 35,
and radiation measured on the upper surface by a gieger counter.
There sas no
crosa-linking in natural rubber, using 0.01 to 0.02% S without an
accelerator,
the aulphur concentration becoming equal an both surfaces.
Treatment with thiuram type
accelerator or morcaptobenzthiazole, 0.3 to 0.5%, resulted in a
low concentration on
the upper surface. Combined and free sulphur were directly
proportionalY correspond
to a first order equation. Accelerators with 3% sulphur showed
secondary cross-linkage
dur to reverse diffusion. Radiation from the upper surface
reached a maximum and then
4ropped by 25%. This indicated the sulphur concentration on the
lower surSace to be
temporarily lower than that on the upper. Buna has only primary
addibion whatever the
sulphur concentration. The fidd diffusion constant shows the
sulphur molecule to be
Sg . Cnlv two thiuram sulphurs, those of the disulphide group,
take part in the
exchange reaction, 8-3'r-thiuram. These form a thermodynamically
unstable active sulphur
biradical, which breaks down a Sg ring to I~wther biradioals,
which then bond
hudrocarbone already activated by primary addition. Each
polysulphide bond has a
length of 10 to 20 sulphur atoms. The scission energy (2,700
cal/mol) suggests the
diffusion of most of the bonded rubber. Though valoanised natural
rubber has
considerable diffused sulphur, a Buna vulcanisate has litt" , due
to the
small nuirber of polysulphide bonds.

BIESIMI: S. Ye., KUSEM, V. P. and SAMMKIY, Ye. M.
"Study of the Mechanism of Vulcanization of Rubber with the aid of
Sulpur-3531
21ur. Tekh. Piz. 24j, 2150-68). 1954.
In various synthetic rubbers, and especially natural rubber, a
nonlinear addn.
ofS31waa observed at concra. > 1% and at elevated teraps (120-1550 ).
The primary adda
of S wits found to be partially followed by the secondary reaction of
S-forming
pokfau)Side bridges between the rubber chains. The departure from
simple
kinetic characteristics of the process is explained on the basis of
calons. of
the diffusion coeff. and the amt. of polydulfides in the rubber.
Similar measurements
were also carried out for rubber vulcanized under the usual conditions
(1-2% 3;
130-1400 ). The free radical S,--- reacts with rubber, even at mom
temp. The
app. itt described in detail.

I
tv 1,13 8 ~-i C-rnn, ~f a sp~i-~ "k-
the upp--r pvt a! the ctH (fr-ze f"Orn protein ma-~~,
showed tbht the pruducts ~,cre stihstancer. M rxiativety lo%v
mol. vn. 7lis matuial W p~rotease
which vem nniv Tt-d%act-.1 that of the oirv.Al
factm -ol A -hith
:01racentrifugredi; thi5. hq,,e-r~ -3s 5--~PJ time,
that fobnd f~ the au!c,4.,-zc- ;-cimcz.A 5p~t!-,n
-nymvT,-ypsm to thr !tnt

tion ol a stauana.,N fi-5rl

LER

f thesis of' tain' Mider prew 6. ;3. 'K;
or
Acad. Scl, -U.S.S.R.,
lost. H hmWeX
Compounds

.
,
Tw and
Biokkifti* 1^01 A"IM.-Tal

ut (C-4. 48, 6477b) and Muchebottd, d al.
(C-4.

43, M th i Inabitity to reproduce the

VY ed by Bresla. ef al. (C.4.
46. W30e).re-

Ing th Ittynthtifs of WteIM uMer preaure!' The
It
h
t
b
f
b
h

e
ned vw
emuse t
reac
MUM the resu
ts o
tA
I
ff

lauthars probably used tmpure enzyme ptepna. A method

I ndfi fion ms
described and new datij prmnted
M
;M

tCVIOU3 AMMUCInS. B. S- LCvIDe
CO PID

Y,

UCMff A XMICA Sec.2. Vol.10/2 Physiology, etc Feb57
572. BREMER S. E. and RUBINA Kh. M. Biochem. Dept..
I at (Pavlov) Med.
'In_e_t._._VFn_Fngrad. *Enzymatic transportation of
phosphate
groups from ribonucleic acid to fructose
monophosphate
(Russian text) BIOKMMIJA 1955, 20/6 (740-748) Tables
4
PhoBphorylated yeast RNA has beer enzymatically
synthetized. The substance ob-
tained in -the presence of 6-phoophofructokinase
delivers the phosphate group to
fructose 6-phosphate, forming fructose diphosphate.
It is believed that the phos-
phor7lated RNA is a high-energy phosphate.
resembling ATP. Enzymatic partici-
pation of'6-phosphofructokinsee seems to indicate
that the transported phosphate
group must be bound to the 5th carbon of ribose.
Szabuniewict - Gdafisk

277
WF MIR
.tj~

Category: USSR / Fhysical Chemistry - Surface phenomena.
Adsorption.
Chromatography. Ion exchange. B-13
Abs Jourl Referat Zhur-Khimiya, No 9) 1957; 30218
Author : Samsonov G. V.) Bresler So Te.,_Vansheydt A. A.,
KuznetBova N. N.,
Lavrentlyeva S.-F.-, Shesterikova M. P.
Inst :not given
Title :Sorption'of Streptonyqin '~y Carboxyphenol Resins
Orig Pub: Antibiotiki, 1956, 1,-No,5, 42-46
Abstract: Trivalent cathions of streptomycin (Str~_) are
sorbed irreversibly
at sulfocathicnites while with'purelly wboxylic
cathionites (hTU
and Kff) W.)sorption capacity for Str34-amounts to only
38-Mr, of
their capacity for simple inbraanic cathions (Na-'*and
Caz+), evi-
dently due to sterie ~indrance.t caused by excessively
close distri-
bution of carboxyl groups. 1P was found, in accorft with
the theo-
retical assumption,'that thd readily swelling, capable of
ion-exchange
Card 1/P_ -25-

.- - , .. . . I I 1 11
A -- i, i-f 1 '0". ., ,
-; 'i . I 1~ !

USSR, Rhysich:15h1kist . Surface Phenomena. Meorption. B-13
Chromatography. Ion Exchange.
Abs Jour Ref ZhtLr Khimiya, No 7, 1957, 22561.
Author : G. V. Samsonov, S. E. Bresle
: Not give,
Inst
Title : Ste.tics anA Drr-,mica of IStreptoqrcin Ion Exchange with Metal
and 1~jdrogen Ions on Carboxyl Tars.
Orig Pub : Kolloid. Zh. 1956, i8,;No 3, 337-343 (rez. angi.)
Abstract Carboxyl cationites-(CC).unlike sulfocationites sorb strepto-
mycin (1) reversibly from solutions, but only in case when
CC are used in Nka,~- , K + p or NH2 -t- salt form. Exchange capa-
city of CC in relation to I depends on the degree of tar
swelling, whichcreates new possibilities for increase of ac-
cessibility of ionite active centers for large ions I, in
comparison to permutites (FMWmii,l956,57703). Equilibrium
of the I ion exchange with metal cations conforms with B.P.
Nikol'skiy's equation, if we take in accowt.only those metal
ions incationite which can exchange with I. For one g-mole
of I - 3g-mole of Na+ are displaced and as a result of that a
Card 1/2 .198-
so-,.,odincniy tin Dnin-ra'.

and chrumatogTaphy of Aarcoinyc.,.,

Category ; USSR/Atomic and Molecular Physics - Liquids D-8
Abs Jour : Ref Zhur - Fizika, No 1, 1957 No 970
f~l
Author : Bresler, S.Ye-, P#uq') G-Ye- 1.4
Title : On tie -Separation of"lone by Their MIhilities.
Orig Pub ! Zh. tekhn. fimiki, 1956, 26, No 1, log-i25
Abstract : Development of a phenomonological theory of the
separation of ions by t4,ir
mobilities, using as an example the separation of isotopes of
liquid metal
by electrolysis. Expressions dre derive& for the stationary and
non-station-
ary distributions of the coace*Aratioz~~of the isotopes and for
the am*nt
of isot6pe concentrated at +~Ie adje,dr--the tube (for
the'stationary cases).
The laws derived are appliedlibr'the*analysis of the
experiiiental data on the
separation of Hg and aa and to the calculation of the
differences in the
mobilities of the isotopes of these elements.
Card 1/1

USSR/Chemistry of High Molecular F
Abs Jour: Ref Zh-or - Khimiyaj No. 89 19579 27064.
Author Jlr~~Y~ej Dolgoplosk, B.A. j
Krol.19 V.A., Frenke2l, S.Ya.
Inst
Title Reactions of Free R2dicals in Solut-ions. V.
Destruction of Pol.~qner Molecules -xidvr Influence
of Free Radicals.
Orig Pub: Zh. obshch. 1xhimii, i956~ 267 No. 81 2201 -
2200/.
Abstract: The reactionc of free radicals (forming in the
result of dissoeiation of alkylpenyltriazenes
and of dinitryl of aziisobutyric acid) with
natural rubber, synthetic polyisoprene and al-
vinyl polymer were studied in a wide range of
concentrations. The reactions of these polymers
Higli .'Myrer Inst. AN S" R, '-,cscow.
Card 1/3

of High Molecular Substances. F
Abe J,our:, Ref Zhur Khimiya, No. 8t 19V, 27o64.
with S2CI2 were studied also. The polymer
destriiation takes.place in all cases,,the de-
composition of the polymer chains.occurs without
any order, and the, probability of a rupture at
any monomer link of ~ the polymer is the same.
It it established that intrainolecular vulcani-
zation' does 66t place at the action of
free radicals an polymers under the conditions
under which the reactions have been carried out.
In the opinion of the authors, the destruction
proceeds in two stages: l/ tearing an H-atom
away from the polymer with the formation of the
polymer radical and 21 dissociation of the poly-
mer radical with the formation of the dione group-
ation on the end of the chain and of the allyl
radical. The authors arrive at the conclusion
Card 2/3