SCIENTIFIC ABSTRACT BORODKIN, G. Y. - BORODKIN, Y. S.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000206510001-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 9, 2000
• Sequence Number: 1
• Publication Date: December 31, 1967
• Content Type: SCIENCEAB

0
~ *A f(4bn*vo 11 ollob
0 ta~ 0((*Jlu aoov o
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9 1 445i*os MJQ
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:10 :Pat; 9 NI 15 2

BORODKIN, G. Ye.
Int-?auediillary outeosynthesia with a metallic nail for frEictures
of the long bones in young children and adaleRcents )rtop.
travm. i protez. 18 no.5:36-4o S-C- '57. (ilb'k 12:9~
1. Iz Qk-nizhnogo voyennogo gospitalya (nach.. .- R-N-Sokolov) i
Icliniki gospital'noy, khirurgii (zav.kafedroy - prof Khelim-
skiy) kidharovskogo r-editainalcogo inatituta.
(FROTURMS)

KARASEVA, Anastasiya Fedorovna; BQ&UKI&j*Af., ppets. red.;
~ "r - -- 1-6. 1..-,.
UVIMMA 0
., A.M., red.) GUOUTMOVA, o.S., ek . red,
(Now method for planning diversified article production]
Novyi metod planirovaniia mnogonomenklaturno o proizvod-
stva. Moskvas Fkonomizdats, 1962. 93 p. ~MRA 15:6)
(Factory management)

,~ffl d-
Qpy~W,jgqrl._Arka 'yovich; ZAVIYALOVA, A.N.., red.,
[Economics and plannirg in the rubber induntry) Ekonomika
i planirovanie rezinovoi promyslilennosti. Moskva, Ekono-
mika, 1964. 201, p. (MIRA 1!1:-t)

XATSURA, leonid Borisovich; .1inRM-Tu. Isir,jAkeeJ2,vich zhurnaliat; LARINA,
L.K., radaktor; KeSANOTA,
[An innovator's days spent In improving the xectice of various
plants] Nez,hzeyodskie dni novators. [MoskV115 Izd-vo VTsM
"Profisdat," 1957. 92 p. (KIRA 10:11)
1. Zaveduyushchty otdolon proizvodetyenno-wistiovoy raboty lenin-
gradskogo oblastuago soveta profaoyuzov (for Katsura).
(Afficiency, Industrial)

BORODKIN, lay Isaakovich,; ZZLIMIKO. G.A.. red.; RAKOF. S.I.. tekhn. red.
[Begisming of a great work] Naebalo boilshogo dels. (Mosicval
Isd-ve VUSPS, 1958. 74 a- (MIRA 11:12)
(lani-agred-Works coancils)

BCR=llp L*Io; GRAJWATMWq ToAo, red.; LWOMMLYA. L~Go, takhn. red..
-
[Worlmrof wastings A the plantl lbboobis ijobranto naprooplistii;
in opyta, provedsaiia, obehohikh sobranlig prolsTodmtv*nao-tekhr4,-
.ohoskikh konforentali I proluvodetvanuM oureshoban' i a& pro-
vWshlonmWft.prodprilatilaft Ierdugnda. CTA)Uirgradl TonlaUt
1958. 111 P. (ftatory swasomelit) (misk 6:9)

I~ I V
B030DUR, H.
The school lathe work shop. Prof.-tekh.obr. 11 no-7:20-21 0 '54.
(MLRA 7;11)
1. Prepodavatell remeelennogo uchilishchs No. '30. (Mookovskaya
oblast')
(Machine-shop practice--Studly and teach!ing)

AUTHORs
Porodkin, M., Teacher
27-58-3-6/1-T
TITLEs Lessons in Special Technology (Droki spetsiallnoy tekhnologii)
Theoretical Training Including Practical Demonstration of
Working Methods on Machine Tools (Provedeniye teoreticheolcikh
zany&tiy s prakticheskim pokazom priyemov raboty na stanke)
PERIODICALt Professionallno~e Tekhnicheskoye Obrazovaniye, 1958, # 3,
pp 14-17, 01%
ABSTRACTs A close contact between theoretical and practical training
must be maintained by teachers of special technologies, d.,..-,-
signing, metal technologies, mechanics and mathematics. A
detailed description of teaching methods, preparatory work
and practical demonstration-on the T-4A machine tool is g4;6ven.
Educational aide and handbooks are utilized and laboratorlr
work is carried out. Field trips have proved benificial Und
jatisfactory.
The drawing up of technological cards for the treatment of
machine parts, is suggested as a means to connect theoretical
and practical training.
ASSOCIATION: Remealennoye uchilishche # 30 (g. Kolomna)
(The Industrial School # 30 at Kolomna)
AVAILABLEs Library of Congress
Card 1/1

BORODRIN, M., prepodavate2l spetsia2lncgr tekhnologii
Models of measuring instruments. Prof,-tekh. obr. 20 no.9t
~k,%% (MIRA 16:12)
1. Gorodskays professionallnb-tekhnicheskcye uchilishche
NoL.30, Kolouna. '

1. BORODKIN, N. A.
2. USSR (600)
4. Ural Mountains - Ore Deposits
7. Report on the magnetometric activities, carried on during the fall of 1942
in the territory of Volkovskiy copper-vanadium deposit. (Abstract.) Izv.Glav.
upr.geol.fon. no. 3, 1947
9. Manthly List of Russian Accessions, Library of Congress, March 1953, Unclas3ified.

BOB IN, T,
00-
Problems of classification In chemical lndustrlen.Sots. trud no.4:41-44
AP '57- (KERA 10:6)
(Chemical industries) (Job analysis)

,~,DORODKIN, V.;,POGOSTIN, S.
mOrganization and. planning of a chemical enterprise" by M.M.Pedorovich.
Reviewed by V.BorodIcin. S. Pbgoetin. Sots. trud 5 ao.6:156-159 Je 160.
(KM 13:11)
(Chemical industries)
(7edorovich, M.M.)

a
it
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see
coo
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W 9 * v im jo
sIT.
00 a oil Aq )bv 0"1
9 johikKO Mimes. V. V..F.
:0
Wro"11" 91 W * -00
a" V.. N. x1mi'mikov. J. Ap#ia MOW.
(M-18 zYJWkc ruixt. OW
94 m4mmms MW 38% 00-W-) is clir.*vd
6=01000 aw OW the W. d ZYWke acetat. h
oo = off ad wmW with AcOH; Wim- -*Wts me
Obtsjmd uft IWr AcOlf In 10% snai. stut. at 20', wIWn
a 45-7 is obtWnW W W-27. pwc scrixtr I-so
00 a Z of tjW=( Ms: 4-amicuAlettitenc). Thr
13
is tII.;=_I eqWv. cd dif. HsSO.,
*0 A sod the pptd. =11ate cd the jl~.6orucsr (1.4. .00
0 d dij~.2-mmstivAbcaame), mized with the sulfatie of the goo
:0 .4momm. is Aftemd off (the ppt. anatyxing 83% p-i--) =00
iu2b%yW. llwfinWwAtherliqumuPonueutraimtkm r
sod gave mi&W zylWbm averbsins 44%0 IM C,& 0
"d W% m4sunter.
=00
go
004
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to
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1"bawn at chl"Oultroc fill fle!" W101 Podium
I N.
29, WCM SUC-
eclidully reduMl fly wettilig thein with 5-41 I-Art$ HIM
and a wirwient anit. of a cad wd. 60111. of N*A.S, Wit.
lilt W-60 111111~ until the OtIhIr ShUtAt dillidill-rart4l, filter.
III$, wallhil%0. JlY1111. alld tt-TyNIK, Ittlill NOW 3.
Ivirlili, It-kil 3A X, :9 lite
11111o ileriv., 13 till. R1011'.1LIM .4) till. NaS whi. W4161
:01 min. Ivit-MV1140. m.titV. -)Iv. (ig. lit I(k14-
fill, wliviii at 211") In avelone 33. RtOll rifirr 1.4.
2 g. tit lite nilia drriv., Ill till, M011. 41, m), Nwi dll..
111111.1 tit. Ithl'. wly. ill al:Ctolic !M.A. rIlwt O.S. 1-'ttlll
from 0.7 c. of the nitto detiv., W till. HtOll. W
-tit. X4~4 suln.. Ix)i1vl 26 inin.1 tit. ItW, 4rken. tit the
air. wily. lit arviuste 18.3. PtOli 0.7. Aild ether 2.1
11,11 Iti J. jill";-I
from 1.13F. ilittodefiv.. Ill till. littill,
M) till. Na.S. 15 m1n.1 tit, 1.14'. etiltirs viWet lit the air.
only. ill amcme 33.1, ether 5.5. 10011 0.5 S. Also wav
lid. lly. this olettim the InvvicItisly dewsibled 4.2-
-171(1l#N)C.lI,NlllIh and
OPIT"alrOO04 loans 010111 lilt
AV -00 A
0
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lee
lee
tie 0
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BORODKIN, V. F.
MR/ChftlRU7 3hdileators
Chemintry Alks" try
PA 64T7
Fob 1948
"Allm" fxlo Identif lositlon of 0 arbazole.-213,618-
Tatra-Sul-vo Acids," V. I. Borodkin, T. V. Iki'kovap
Ivanovo M%am Teohnol Inut) 2 pp
"Miur PrIk Xhle Vol IXI, No 2 -2-
Describes subject am-thod in the presence of isomers
of carbazole sulfo sold and sulfuric acid. Submitte&
2 Jun 194T.
64T7

4t
-4 IM 3 0 9 Zoo
Mal I p it 41 4, it I,
A AA be ki. it, It
All
Catbasoliplikulfoole sidd, v, it. flor,balkilt land T. %,
00
KA(k. /40
Applied
00 It"it of "balsbabobst~M of
o0 r! VAItORS0110 IVAII W Will. iskiltiftl
Iskith Oult lat'l.killets (Tali
w1fonic arid. C.Tlubtotc .1) tlb a.) saddled with istirrins
'N, heated 2 hirst. at W
go 7 - sit 2Z,,10' to 50 g. called. 119SL
lilt'. rooted to ;W, dild. with 15 1. M% bukum. again .-OG
00 buted2lars-tal,ove and nrutralind with BaCOpvr the
0419 Ba valt, which yk-lded that tre-K sak, C,%11jHV(SObbK)& needles
(from water). The stone stalt is obtained firsban (a) 17
00 Z! C. I addaril to 50 t. 11,90.at 30-40'and heated with 0,15 VO 0
00 It. [it WWI: 3 hm. at OU--IW*; (b) 1.7 It. I and 640 It.
Ratio, Ittrattal 0 It". at (lov"T Iftlit. jjiv%~ Illilas.
00 roatig. animal- told dkirklt); cil (c) N11 z. I adited W tril
16SO.. IWAIMI %I till. at IVO, And 4311rd out
00 lot. UP'.
withKCI. 'llit, tri -9. ,alt is ~,hvv it ill he that of thr
*0 isomer as ftIll,--. t7st) 1.) is asiddO tit 0
3W to 270 C. coned. 110).. heatcal U.5 hr. at 1113-100". footit acid, sivollv~ (front filial. ilm its) S.1 ill ',(its bad.
00 :1 :
cooled to 4.5'. treated with 05 S. 20's, olcum, kept 2 11,0 and Ill till. AtOlt was irivival at the lo.p, u bill ;0)
Igo s) ha's. at IM-11W. let %land overnight, anall the-lipt. u. K. CIISO, ill INI toll. flit). tile Illi-t. licutrali"'I "ith KIC(h.
liesatedly tvy~lll. front ouler. giving 1511 Jr. :-dmixo- lilttTard, alibi thr Ohms: Irvati-d with KCI. vichlillat the
Illbal, Wholse tri-K stalt was all. sri-K ill. idt-utical oith that obtaiticsf oat %adfluation Ill 1.
alvared; thi, arid tm g.) ill Nail aid. flit) atial NJ Ill. concti. Addisir '-15 k .11 1114. Iii. K th U. (k) C. K( III at I jib :dl
IICI wai di-luittiI,I -it 45' vvith 12.11 g. NaNO, its 70 till. firring 0.5 hr. at =1,10* and 0.5 hr. at rar3ling,
Itto, thv diawtvittin ,oullut. ~,-tlted out with Nact, n%ixrtl dilft., and acidifying Save 12-13 g. I-hydroxy Trb- 1 0
'4111 lilt, tMil. 110. thc 111M. Willett at 10 azoledisvVervic acid, colorless plAtc,,: ih!; (4 gA mrid 441
S. SoCis it% Ilk, jul. lash. IM added slowly, 3:nWwith a
%ill% ~ ith 135 r1. 107,, 11,50, heated (I firs. tit 170 S' in A "Al"t toile
IiIIIHAT aull. m oil-, Iimil 2 hirs., and let stAnd gave 1.6-1.7 It. all. 163-4'.
ovrrniVfd. bliviiag 1141 bl. 0. Al. Kosolapalff
If
11 111:10il IM lift OF 9 K (I
0000000 4 000000000 go 0 0 090 0 00000 0 a lsw
0 0 0 0 * 0 0 0 0 0 0 0 * go i2
0 0 0000 0 0 000 0 00 o Its 0 a 0 tpb~

WSR/Cbemistry - Phenylamines Oet 48
Chemistr.~ - S.7nthesis
"S~mthsals of Chloro-2-Nitrodipbeny1mines," V. F,
Borod3rin, Ivanovo Chem, Tech Inst, 8 pp
"2;hu.r Priklad EhieVol In, No 10 q.,
Studies cm~ditions of s~mthesis of possible chlo=~'
2-nitrodiphenyqamlneo by substitution for a chlorf.ft
atam In phanyl- and chloro-phenylamine groups of
chloro and dichlormitro compounds. Shows that
Aln they..are,synthesizod. from isom~r1a.,I-.;,AIoro
nitrobemenes. wvsmmt of ablorlaiD'atow C'", be
arransed in the series: 2,,v,-dIchlcro vltrobenzmm~
M> 2,3 M> M, W-
9 Feb 4u.
43/49T15

BORODKIN, V. F. PA 43,149"P-2
USSR/Chemistry Hydrolysis Pct h8
*HArolysis of Carbazole-3-3ulfo Acid.," V. F.
BorodkinP.T.. V. W11kova., Ivanovo Cip?m T-ch List,'
5 pp
"Mir PrAlaa Miim" Voi XXI, no 10
Studies hydrolysis of subjedt acid dn presence of
hydrochloric and sulfuric acid. Shows that deges
of bydrolysis is not proportional to concentration
of acid, and depends only on temperature and dura-
tion of the reaction. Un4er similar conditions,
reaction Is conpleted more easily in presence 9f
Vdroobloric acid. Submitte(I 17 Oc;,',, 47,
*W 43A9T22

bd" d milimb md mAwilwas km mw mftv~-
loft, ft. ML -.7ftf.
sulpimmAtiom askstam Is pkvpwW byaddift CIA4NII acki to dry
NI%MNd6mWvW im dry Ph(T To this. the nustureof carlm"
and antmatese or mw ambmcv.-~ in ate kwm of a Sumpop" in
NI%M% 6 &6&d at 111-301. The remulti" rArtasuiv,P(N).
00"Witic MCA is ""tra"d a" tbm ~"Mtpd in the usual way.
Peom a 45% amilwavom centsimimil 4111% of carb"als, 4 OD-416%
cafbabl& mW bw uMaimed in " way. w6lit two a 10% raw
q1thrace" ":?Ptekili 419% of carbamub,& WinicALS"P
is .hj, Aji imcreams im, rgso.
b Pz..=
tvactice increase dw famatma. of rA . -11kk "I
1. ft, 1. ZAVA.

C6
,a
Ar,#wd
IS.
In
C.4. 41, Offiv.-Tole rew.- of pwo 'Mono. OW dkup-k
Seib CO (11) Nader - as ;Mwkiow w" 910died.
H015-isparts I Wall tOW-10' and tmtrd with
V417b" amw d it ) at Moffat temps. am than.
"W Insist. *it N win., the IMNVO somm-
:=4 be sq. amb. WmW to "own 1,
mus we pptd. as Ma spa. varkdon, of the
-110. 1, '100) of
time (I or 3 lars.) 4w (Io 5~170. 25,
ftc im mob Me (d I -.*W. atowl
Jill). Mm1wwd at,
itx "hl., fth 11).M.219A.16.0 : Ilar4mab.111-
INW. I bet w) 3,64wbook-
dim 'AM IV). ill
water. I Bove a of ill Red IT; a mok.
2w
at 16-1 ady ?MIN 1.3
wu fm . 'IV to =tbr
do ib aft mad With NMOH lob".
ill and IV Wan t t bet. ill cmM be arpd.
"hime set a" The ambol of SMAin am
I C"A o 071 ). I v" 11141111, IN I led III the
Must ). A
to a swilo, of n OW T&a. do ukt, watrawd with
NOOM mob. WNW 2 bra, at a Cmast. temp., ytesm4w, to
rownew do -k-%Md Skarld'" femme amew" a 1:
d W.IW-A-V--k M (VU
al
(0% of TI ims alptained by 3 WAU
r 302". 7U
a' 6 91h ~ A.. ow~vmt
age"' w T ---Wk - -Md in
or agave, Is w MIAM the reardw fts"p. "m'
The powww" 41 nth" gamic ad&%y in arm oak.
spad welabbo the I hami =1. AbRuria

d wbwAs Md assm"s hem web
r w I rasa" Invi. clorm. Tww".).
JT =AppfWwTK-m. V.S.S11 A& tfuns.-
121kin).-An attempt was moft to 4wpxftmw* (1) trom
el-Mle Anthmvnr by wilhW4414" of I h CMAMI in M
INXIes &W PhC1 to Woubtlaoirflulkloic add (11). folk"mi
by"brOol, cillial.
inists, of I and exibra"se (111) by the pnomturt of ft. (cf..
f-l4ovW" Mmtr.)~ 'Me brot gommy vms 90.51% of I of
W 14% purify ftom a tuist. of 40% 1 sm! 00%. 11. An
r-urichell rtwir authracene ctaf1g. 44% 111 and 47% 1 was
-b to thk wd"IT. but thr hyd"Full of the tv.
revintantimated with fatty fmjlurities-
Purifyft thl:we vkhed cruck %xithrarem, fir-At evith super.
en
1-ted itteam "wil"t in a t*n). I of about 00% putity.
The YW v* 11 drpeml. on k"Ping Ow Mot, wid ",actim
fill* o"%, Rl"wovtoft of tkit cont. I d I not Wwase
the IntHty, A 120% vnp* withrartor vmOnd with hot-
watertmirran eaviched mWeantbruvue owtt, 30%1 and
195f, M; sullottatkat antler Ow marne condidmil gave a com.
Io(M-n% purify Ill up to 39% ylekL R. 1. A.

qv4T -i I I T i~ T i I I M I M -P Tj
A
00 4
09
go A 11F
09,A
2402. CARDMIZ ISOIATION. 09roWn. V~.,Y. (2h. 'vriklad. MIm.
AML Chou.), June 19501 abstr. in 40' byors and Col., Dec. 1"01
00 V~ And in Chem. ?r. J.0 12 Jan. 1"l, Va. in, 86).
068 too
It has been round that maphowtIon of carbasole In solution bV
chlorosulphomic &aid leads to formation of the 3-sulphanic acid and
i
*9 the 31641rulphonc v- rid, the ratio of the jpmbwto depending on the
00 amount of chloromaphonic acid usedI, but not to an appreciable degree 1441
0 on thtv taVerature and duration of the reaction. When the restation
Is carried out in prooew.,% of dime,thylanllin6 at 2000.p the main pro-
duct to carbasolo46~u2pkm1c said, but at higher temperatures the
3-oulphonie acid Is formede - By treating crude anthrevene witb chloro-
vUphonto acid at 180-20*0 In prosenev of dimethylanilinep using
ehlorobenzene as diluents ;b; carbasols, present my be converted into
the N-sulrhonle aeld, Vbe remaining constituents being unaffected.
The X-mulphonle acid IF o"ratood as an aqueous solutim, and is then
)qdrolysed with acid to regmerate the owrbasole. The process Ia best
-carried cut-on. crude has-been samewbat enrichod-AW
LAI .1TALIk-MOCAL LITERATURE CLASUFKATION as 0
%Ana.! Is k
V MIS
AV '40 it., v-d a A v -1 v IA 5 A
It IT It K 9 (1 it it it ; 1% 4 "
44
1 0 L;41
d0
0 0 0 0 0 a'* 0 0 0 0 0 0 6 * 0 0 0 a 0 * 0
to : 10 ages-00 66-0 0 A0 q Idi

treatment with boUing water. The quality of the technical carbasole
obtained Is stated to be in no way Interior to that produced by
methods involvW, t6satment with pyridine bases or fu-sion with caustic
00 'Otash*
00
00
00
go
0.0
0.
0
:
i~10_0:0 lie 0-0 0 0 WAV 0
006~09*0 *-*go o 0 0 go** oo 0 0
1 0 0 19"Wi-O 0 64 WO 0 Is 0 Is * Is 0 0 G, Is 020 0
so
00
0 0
0.0

NN-

Utphout-tiou of carimmile in orsanio soivenu. F
CA,.- LS.,S R , 1931, 22. 734- 1 of
c4ul,arole (1) b-v CI-SAIji in PbNO,. PhC1, WIllf. Ac,t)
anti it% a mixtum nf MC-1 and Nllhlqir, uai im-ligatmi When
I g-mol W CPSIVI is U"l IVI I g In'-L "t 1. arlmr'.1"J.
sulphonic arid is ohtwn"i. wfirmii whrn 3 1; nitil, (if `;0,11 are
u%,s!. a d.vililmnic acid is prWu-,I. \%'Ii,n PhNO, is u-d A,
*)Iv%nnt. tht )ield of carlwole-3 sulphonic arid is 82 S 47,4 %,
and thr peld of c&rtvxo!e.,l : ti-dk j1phonic ak M it 94 4 WS tlvl~ At
10- 30'; tte )Ieltl thics not deliend (in thc tinit-of mictimi ~,ulphtm-
At-I fil 1--mv ,I Rl,- carl...1, .,.,I
.1 21 the is 326 "W"; dq-1mg ~,n th,
CI I anti I lie lir,)Im,rt itin tol ~wl ~ cant%. At It'gherl"'l, 4ti I'S
acid is f"rille'L 1. 11 J"Iku'%

50
AUTP 0 R S Borodkin, V. F., Usacheva, K. V.
TITLE: Copper Phthalocyanine Synthesis From Pftthalic
(Sintez ftalotsianina medi iz ftalevogo
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy.
khimicheskaya tekhnologiya, 1958, Nr 3,
S0V/1 5-56- 7-24
Anhydride
angidrida)
Khimiya 41
PP 142 - 145 (USISR)
ABSTRACT: One of -the industrial prod-u.2tion methods of copper phthE.lo-
cyanine is that mentioned in the title. A mixture of
phthRlic anlVdride, 0urea, copper chloride and catalyst is
heated at 170 - 220 for several hours k"baking"). inert
organic diluters supply higher yields. In publications
there are, however, no data available on the dependence
of the yields of the final product on the nature of the
catalyst and diluter. This gap shoul(~ be filled by the
authors of the present paper. In reactions with nitro-
benzene or trichlorobenzene as diluters 18 compounds were
tested as catalysts. The most active catalysts were
molybdenum ccmpounds, with ammonium molybdate being the
best 06),(Ylo yield of the final product) ~Tablp 1). Nitro-
benzene offered the best yield, 85,5~'b, f all diluters used.
Card 1/3 Table 3 shows the yield- without dilute-s. Also in this

Copper Phthalocyanine Synthesis From 1~hthalic SOV/1 r'z - = 8 -:1- 24 / 2 0
J
Anhydride
case ammonium molybdate proved to be the best catalyst;
yield up to 84%. Thus, the influence of the mentioned
diluter increases -.he yield by 10 - 15'/~- The temperature
influence at the end of the baking process is as follows:
at 2350 the yield of the final produ~:t is by about 10 -
13~ higner than that obtained at 200~. The increase of the
amount of urea decreases the yield if boric acid is used as
~ catalyst. If in such cases Ammonium molybdate acts as
~ catalyst the yield increases by 2 -- 4%. When using cupric
chloride instead of cuprous chloride the yield of copper
phthalocyanine decreased by 10 - 15%., The presence of
crystal water is of no importance to the yield. There are
4 tables and 4 references,
ASSOCIATION: Ivanovsk4A.y khimiko-tekhnologicheskiy institut (Ivanovo
Institute of Chemical Technology). Kafedra tekhnologii
promezhutochnykh produktov i krasiteley (Chair of the
Technology cf Intermediate ProductFj and Dyestuffs)
Card 2/3

Copper Phthalocyanine Synthesis From Phthalic . SOV/153-58-3-2,4,/30
Anhydride
SUBMITTED: September 10, 1957
Card 3/3

50 , 2, S-0`V//-, C- - 2/~
AUTHORS: Borod,~in, V. F. , U;4achra%rni, K. V.
TITLE: The Dis.,3oi-,tion and Reprecipiti7titlion oj' Go,.,per Fhthalocyanino_-
(Pvreosazhdeniye ftalotsianina inedi)
lj, 11
PFRI" .'!CAI,: L~-Von t _~ ~ya vy--nhilkh uchobilykii z- vede)niy . KhimJ Ya i khim-i cheskayi~
'1058, Nr F), pp 13-11-1;1, (LTSS;0
kBSTRACT: Only after "he dissolution and reprecipitation of the
modif:ication of copper phthalocyanine (dissolution in sulfur-i(-
aoid, separation with water) it is transformed ~
.o ihe a-
modification wi-th valuable coloric properties, and which, in
c,.~ntrast to the P-modif--cation is widely used as blue dy-2. The
conditions for this process determine to a high degree the
quaUty of the dye. None of the data in publications at hand
mentions the dependen--e of the coloristic properties of -,he d-,--
upon its production conditions. The Soviet "goluboy ftalo-
tsianinovyyll (phthallocyanine light blue or sky-blue, respectiv,--
ly) has for a long time beer. insufficient especially as regazd's
shade. The present work is part of a comprehensive investi-
gation and deals with-the dissolution and reDrecipitaion. Cx-
mercial copper phthalo6yanine synthesized according to the uree
Card 1/1~ process was used for this investigation (42,48%6 -.dmixt--rE-_,'...

5 3 - ~r ~E -2 2/
The Dissolution arid Rep:--ecipitation of Copper Phtha.LOc~,-!-.-*--.C-
furthermore that copper phthalocyanine which had been pilri- -'iu,
'by I-,oiling with HC1. The'investigation is divided into :Dour
sections dealing with the effect of the following facto-zs -.-PI.7
the shade of the dye: 1) The state of the copper phthal:)cyP_Ti_`.-
in the acid; 2) The temperature p.Eevailing during the proc."3!2*--
73--:Castor oil, and 4) Dispergators. Based on the reSUltS ob-
tained the authors arrived at the following conclusions: The
use of castor oil in this process renders this process dif-
ficult and does not secure good col.oristic proDerties of tlie
dye. Among several substancoo used as dispergators in th,is
process "Emullfar F.M11 ('riethanol. am-' ne soap) proved to be the
best, The optimum condizions for CJ.-, process are: Dissolution
of the cnmmercial copper phthalocyanine in 96~o sulfuric acid
at a rat..o of 1 : 10 at a temperature of not above 250. Then
the -crecipitation by injection of the solution through it jet
into a 30% sulfuric acid contain-';_ng triethanol amine soap is
carried o,at. The sulfuric acid and the water used for this
process must not contain any mechanical impurities.
There are 7 references, 6 of which are Soviet.
Card 2/3

SOV/153-58-5-2"7'/2e
The Dissolut-'-or and Repre(Apitation of Copper Phthalocyanine
ASSOCIATION: 1,,rano,,,skiy khiiiiiko-teklinologicheskiy institut, Kafedra tekhno-
logii krasiteley i promezhutochn,ykh produktov (Ivanovo Chema-
Technological Inctit-ute, Chair of the Technology of Dyes and
Intermodiates)
SUBMITTED: October 5, 1957
Card 3/3

BORODKIN, V.P.
;111 IVAIIlz-~.;
p ~
Synthesis of phthalocyanine from phtlialonitrile. Zhur. prikl. khim.
v. 31 no.5.'813--816 My 158. WRA 11:6)
(Phthalc.)cyanine) (Phthalonitrile)

_ ITANOV, F.F., red.; FAbTJWTOV, A,I.,
-4~
tekhn.red.
[Silk from wood, paints from petroleumi Shelk - iz dereva.
kraski - it nefti. Ivanovo, Ivanovskoo kni2hnoe izd-vo, i959.
72 P. (MIRA 13:5)
41 -C~ (Textile fibers, *ynthetic) (Petrolelim chemicals)

50) SOV/153-2-3-22/29
AUTHOR: -Borodk~~V. F.
-------------
TITLE: On the Color oflhthalocyanine Dyes and Figments
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Khimiya i ZkhimicheBkaya
tekhnologiya, 1959, Vol 2, Wr 3, PP 424-429 (USSR)
ABSTRACT: The tetraazoporphine cycle, a closed conjugate system (Formu-
la (A)), is the basic substance of the phthalocyanine dyes and
pigments: I - I
N_~31 N - N-
~N
N N :~ ~ff
L (A) Cu (I) Li (II)
N 14 N"_ N-1 NLi LiN
N i
This conjugate system is the reason of the deep color of all
compounds of this type. The author synthesized two cycloiso-
Card 1/3 indolenine3 hitherto not described in publications: Cu-cyclo-

On the Color of Phthalocyan:Lne Dyes and Pigments SOV1153-2-3-2212'9
bisdiphthalidimine (Formula (I)) and tetralithium-cyclot-etra-
isoindolenine (Formula (II)). Compuund (I) was produced by
heating diphthalide with urea, copper chloride, and ammonium
molybdate in nitrobenzene. The blue product has the absorption
maximum in bromo naphthaleni at 675 mg and is insoluble in
most of the organic solventt,, and in weakly mineral acids.
Compound (II) was produced by heating phthalic acid nitrile
with metallic lithium in aboolute ethanol. Tet:alithium cyclo-
tetraisoindolenine is red-violet and has its absorption maximum
in bromo naphthalene at, 500 m~A- It is insoluble in water,
methanol, and ethanol, in butanol, isoar,.yl alc,hol, aromatic
hydrocarbons, nitrobenzene, chloro- and biumo iiaphthalene it is
soluble. The two syntheses are described in detail in an ex-
perimental part. Moreover, also Co-dimethoxy cyclotetraiso-
inriml-4- -;;~Z synthesized (according to reference 13), The
measurement of the absorption spectra was made rith a spectro-
photometer SF--4. By means of the three compounds synthesized
the author showed that only a disturbance or a shortenini-, off
the conjugate system in the tetraazoporphine nucleus leads to
a shift of the absorption maximum towards shorter wave lenCt'n5
Card 2/3 and thus to li.Rhter colors. Table 1 gives a survey on the

on the Color of Phthalocyanine Dyes and Pigments SOV/153-2-3-22/219
published data concerning the absorption of substituted tetvv-
azoporphines, phthalocyanines, and their complex compounds.
Table 2 shows the absorption maxima of macrocycles with a
structure similar to that of phtha'.ocyanines. There are
2 tables and 14 references, 1 of which is Soviet.
ASSOCIATIOV: Ivanovskiy kiiiiniko-tekhnologicheskiy institut Kafedra
tekhnologii krasiteley i poluproduktov (Ivanovo Institute of
Chemical Technology, Chair of Technology of Dyes and Semi-
products)
SUBMITTED: March 25, 1956
Card 3/3

5(1,3) 132
SOV/153-2-4-28
1
AUTBORSt Borodkin, V. F., Smirnov, R. P., Prigullnaya, V. A.
TITLE: Interaction of Diimino-isoindoline With Diamines
PERIODICAL: Izveetiya vysshikh uchebnykh zavedeniy. Khimiya i khimicheskaya
tekhnologiya, 1959, Vol 2, Nr 4, pp 619 - 621 (USSR)
ABSTRACT; The product mentioned first in the title (1-imino-3-amino-iso-
indolenine) is an intermediate product of copper-phthalocyanine
synthesis (Ref 1). It reacts readily with aromatic mono- and
diamines (Refs 2,3). At the same time, compounds are formed which
can be used in the synthesis of mac-.~cycles (Ref 3). In connec-
tion with the investigation of maciocycleB, the authors obtained
interaction products of the substarce under discussion with
substituted m-phenylene diamine, benzidine, and its derivativps~
diamino-carbazol and.diamino-ditenzyl (see Diagram). In th, dia-
gram, A denotes benzene, toluez,e, chlorobenzenemethoxy benzene,
diphenyl amine, diphenyl, 3,3-dimethyl-diphenyl, M-dimethoxy
diphenyl, carbazol, and dibenzyl. Upon interaction of diimino-
isoindoline with aromatic diamines, condensation products with
good yields are formed. These products have abscr-ption spectra
Card 112 in the near ultra-vlolet and violet part of the spect--,tm. Elec-

Interap.tion of Diimino-isoindoline With Diamines SOV/153-2-4-26/32
tron-donating substituents (CH , OCH ) shift the absorption
maximum in the substances prodLed w1th m-phenyiene-diamine
derivatives into the range of longer waves as compared with
nonsubstituted products. The same substituents shift the maximum
in the direction of short waves in the case of compounds pro-
duced with benzidine. Attempts are nade to explain this pheno-
menon. There are 3 references, 1 of which is Soviet.
ASSOCIATION: Ivanovskiy khimiko-tekhnologicheskiy institiat; Kafedra tekhnolo-
gii krasiteley i promezhutochnykh produktov(Ivanovo Institute
of ChemieLl Technology; Chair of Technology of Dyes and Inter-
mediate Products)
SUBMITTED: June 21, 1958
Card 2/2

BOROKIN, V. F.
Reactive dye3. Ijv.v.-a.ucheb.z&v-; tekh.teket-prom. no-3:lC2-105
16o. (XIP~. 13:7' ' -
1. Iyanovskil khimiko-tokhnologichookly instiVAL
(Dyss and dyeing-Cellulose) .;.

87424
S/153/60/003/004/030/()40/XX
0 B0201BO54
AUTHORS: Burodkin, V. F., Smirnov, R. P.
TIT'IrE, Analogs of Naphthalocyanine, Synthesis and Study of
'Fr(rertiee
PERIODICAL: lkv~~Ftiya vysshikh uohebnykh zavedoniy. KhJ.miya i
khImi=askaya. tekhnologiya, 1960, Vol. .`~ No- 4,
PP- 7118 - 720
TEXT-t Th-~- rialn component of the strvcture of naphthalocyanine (tatra-
napltthenot~-trazaporphyrine), as well as of phthalonyanine, is a closed
conjugate ~-etrazaporphyrine chain (Ret-1). As was shown by the example
oZ phthaloojanine analogs (Ref.2), the changes in the conjugate chain,
oqnno~;ted iith ita breakdown and shortening, lead to a change of pirODer-
ties of the newly obtained compounds. Therefore, an investigatlon of the
naphthalz.r.-yrmina analogs containing one or two (II) phenyl radicals, one
phe%jyl-. %n~` caa (III) Or two (IV) 13oindole radicals., and a comparison
cf their propertien with those of phthalocyanine analogs, were of inter-
ezitz Naphthalocyan-ine analogs differ from phthalocyanine analogs only by

87424
Ana2ogs of Naphthalocyanine, Synthesis and S/15 60/003/004/01-'0/040/XX
tudy of Properties YB
S
4 B020 054
v,- higher content of n-electrons and benzoindole radicals Instead of iso-
lnac~~a radicals. It is, therefore, to be expected that the differen~-.e in
properties of naphthalocyanine- and phthalcoyanine analogs will bs small..
Iike the difference between naphthalocyanine and phthalocyanine. Naph-
thalocyaaine analogs were obtained by the procedure described in R~f.2i
they were, however, isolated from the solution in butyl alcohol by praci-
pita'.ion with methyl alcohol. The substances were then purified by -rys.-
tallization from ohloro benzene until reaching the constant melting
--ol-1A. The authors describe synthesis and properties of the following
~ompl)unds: 9918; 28,34-tetraaza-29,33-phenylenetribenzo~-soindrline W~
q,lqj 24,30-tetraaza-10,1,i I 25,29-diphenylenediberzoisoilidol,~ne (U)i
9'1 6;25,32-tetraaza-26,30- phenylenedibenzotriisoindoline (III), and
7,16;23~29-tetraaza-24,28-pheiiylenebenzot.-iisoindoline (IV). It is shown
I n. -
..-'at the substitution of the benzoisoindole radicals in naphthocyanine
by pLenyl- and i3oindole radicals effects a shift of the absorption
maximam. to shorter wavelengths. TherA are 2 Soviet references.
Ca r d 2 /4

Analogs of Naphthalocyanine, Synthesis and S11531601003100410301040117
L
"tud.v ot Properties B020/3054
ASSOCIATION: Ivanovskiy khimiko-teklinologicheskiy institut, kafedra
tekhnologii krasiteley i poluproduktov (Ivanovo Institute
of Chemical Technology, Department for the Technoloa of
Dyes and Semifinished Products)
QUBMITTED: JulY-15, 1958
Car'l 314

S/153/60/003/004/030/040/XX
B020/BO54
N-O-N
N
Card 4/4
N
Vy
N dN
IV

S/153/60/003/005/012/016
B013A058
AUTHORS!t '.~~~~-Smirnov, R. P.
TITLE& Substituted Analog,,j o-&'.Phthalocyanine. Synthesis and Study
of Properties
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Khimiya i
khimiohoskaya tekhnologi,~-a, 1960, Vol. 3, No. 5, pp. 915-919
TEXT: Eleven macrocycles - analogs and subEtituents of phthalocyanine
not described in publications, were produced in this study:
11-nitro-2,14,21,27-tetraaza-22,26-phenylene ~.riiisoindoline, C 30 H16N8021
boiling point 3800-382OC; 3,18-dinitro-7,14,21,27-tetraaza-22,26-phenylene
triisoindoline, C 30H15 NQO 41 boiling point 3870-388-500; 3,11,18-trinitro-
7,14,21,27-tetraaza-22,26-phenylene triisoindoline, C30H 14N10 061 boiling
point 4200-421OC; 3,17-dinitro-7,13,20,26-tetraaza-6,12,21,25-dipheny'~ene
diisoindoline, C,,,H 16 NS 04' boiling point 4380-438.5 OC; 11-amino-7,14,21,
27-tetraaza-22,26-phenylene triisoindoline, C 30 H18 N., boiling puint
Card 1/3

Substituted Analogs of Phthaloc-yanine. S/15,;5V60/003/005/012/016
Synthesis and Study of Propertiei B013jB058
315.60C; 3,8-diamino-7,14,21,27-tetraaza-22,26-phenylene triisoindoline,
C30H19N9, boiling point 3080-309OC; 3,11,18-triamino-7,14,21,27-tetraaza-
22,26-phenylene triisoindoline, C 30H20 NIO, boiling point 3910-391.50c;
3,17-d~amino-7,13,20,26-tetraaza-8,12,21,25-diphenylene di-ILsoindoline,
C28H20 N., boiling point 3720-3740C; 7,13,20,26-tetr;aaza-6,12-pyridyl-21,25--
phenylene diisoindoline, C 27H16N7) boiling point 3BBO-389OC; 9,15,24,30-
tetraaza-10,14-pyridyl-25,29-phanylene dibenzo isoindoline, 0 35H20 17 7'
boiling point 4150C (decomposes); 2,3,4,5,15,i6,17,18-octachloro-7,13,
20,26-tetraaza-8,12,21,25-diDhenylene diisoindoline, C 28H10 N6 C18P boiling
point 4500C (decomposes). The inaximum of the absorption spectrum is
bathochromically displaced on introduction of amino groups into isoindole
radicals of phthalocyanine analogs with a benzene radical (Table 1). On
introduction of nitro groups a bathochromic displacement is also observed
at the beginning. This displacement is greater on introduction of only one
nitro group than on introduction of only one amino group. An accumulation
of nitro groups, however, results in a hypsochromic displacement. This is
Card 2/3

Substituted Analogs of Phthalocyanine. S/15 60/003/605/01'2/016
Synthesis and Study of Properties B01-,~%13058
presumably connected with a decrease in electron dei.sity in the ring. The
presence of two amino or nitro groups in phthalocyanine analogs with two
benzene radicals is of no consequence in the absorption spectrum. Batho-
chromic displacement occurs in the presence of 8 chlorine atoms. In
phthalocyanine analogs with a benzene and pyridine radical, the absorption
maxima are in the range of longer waves than in analogs with 2 benzene
radicals. This can be explained by the fact that an."individed" electron
pair of the nitrogen atom participates in the conjugation. The absorptiot'l
values (Amax) of the substituted phthalocyanine analogs are tabulated.
There are 1 tab~le and 3 Soviet references.
ASSOCIATION: Ivanovskiy khimiko-tekhnologicheskiy institutKafedra
tekhnologii krasite.'Ley i'poluproduktov (Ivanovo Institute
of Chemical Technology, Department of Technology of Pyes
and SE:Mifinished Products)
SUDMITTED: July 9, 1958
Card 3/13

S/C)79/60/030/05/30/OT4
WOW
AUTHOR: Porodkin, V. F.
TITLE: Analo IgIa'.." of Phthalocyanine.1 Synthesis and Investigation of
Proper-ties
PERIODICAL: Zhurnal obahahey khimii, 1960, Vol. 30, No. 5, pp. '1547-1553
TEXT: The author of the present paper synthesized 15 analogs of
phthalocyanine. From among theme 15 macrocycles, the following 12 have not
yet been desoribed in publioations, 25-chloro-7,1492'1927-tetraaza-22,26-
phen,yler&triisoindolizq 24-methyl-, 24-nethoxy-, and 24-chloro-7913,20,26-
tetraaza-8912,21,25-diphonylene diisoindoline; 7,12,19,25-tetraaza-8,11,
20 24-diphenylene diisoindoline; 23-methyl-, 23-methoxy-, and 23-chloro-
7,;2,l9p25-tetraaza-8,1lp2O924-diphanylens diisoindoline; 7,14v21p27-tetra-
aza-6,13-naphthylens-22,26-phonylone diisoindoline; 25-methyl, 25-mothoxy-,
and 25-chloro-7,14,21,27-tetraaza-8,13-riaphtbylone-22,26-phenylene
diisoindoline. To synthesize these compounds, equimoleoular quantities of
the correspondingly substituted derivative of 193-di,-(-l-imino-3-iso-
indolinylidene-.amino)-benzene and 193-diimino-isoindoline (1,3- or
Card 1/3

Analogs of Phthalocyanine. Synthesis and S/079/60/030/05/30/074
Investigation of Prope-Aies B005/BO16
1,4-phenylene diasine, or 1.4-naphthylen* diamine, respectively) were
boiled in butanolic solution under reflux until the separation of ammonia
was completed. The precipitate was filtered and washed with hot methanol
or recrystallized from suitable solvents,~ The author determined the com-
positions and solubilities of the resultant macrocyclic compounds and took
their absorption spectra. The substitution of one or two iaoindole nuclei
of phthalocyanine by one or two benzene rings was shown to cause a shift
of the absorption maximum toward the region of shorter wave lengths. Sub-
stituenta on the benzene nucleus have little or no influence upon the
absorption spectrum. In two special sections of the paper, a rational
nomenclature and the scientific nomenclature for the 15 macrocyclic com-
pounds synthesized are given on the basis of the Soviet nomenclature of
organic compounds. The experimental part gives the individual initial
products used for the synthesis of the macrocyclic compounds.1 Yields,
melting points, and the results of the ultimate analysis are given for all
15 compounds synthesized. The students V. I. Yerichov, M. 1. Sorokina,
and A. L. Smirnova took part in the experimental work. A. P. Terentlyev
(Rol. in mentioned in connection with the nomenclature of macrooyclic
compounds. There are 6 references, 2 of which are Soviet.
Card 2/3

Analogs i)f Phthalooyanine. Synthesis and 3/079 60/030/05/30/074
Investir,ation of Proportion B005YB016
ASSOCIATION: Ivanovskiy khimiko-tokhnologiche ekiy inatitut (Ivanovo -
Institute of Chenical Teohnology)
SUBMITTED: JulY 11, 1958
Card 3/3

KLXUXEV, V.N,; BORODKIN, V,F,
Transformation of o-carboxyphanylsulfinic acid. Izv.vys.lacheb.zav.;
khim.-,L ld3lm.tekh. 3 no.6..IM9-1081 160. (Mk 14:4)
1, Ivanovskiy khimiko-tekhnologichookiy institut, kafedra tekhnologii
krasiteley i poluproduktove
(Benzenesulfinic acid)
f

BORODKIN V F.- KUZNETSOVA, S.S.
Dyeing with aso dyes containing methyl sulfonic ester groups.
Izv.vys.ucbeb.zav.: tekh.tekst.prom. no.4:80-83 '61. (MIRA 14;9'
1. Ivanovskiy khimiko-tekhnologicheskiy institut.
(Dyes and dyeing--Textile fibers)

BORODKIN, V.F.; AMI OV,.R.P.
Phthalocyanine and its derivatives fr= dliminoisoindolines,
Izv. vys. usheb. zav.; khim. i khim. tekhe 4 no. 2:287-290 1
161. (MM 14:5)
1. Ivanovskiy khimiko-takhnologicheakiy institut. Kafedra
tekhnologii krasiteley i ppluproduktov.
(Phthalocyanihe) (Isoindolin-3)

BORODKIN, V.F.
Chlorination of copper phthalocyanine in a fluidized bed. Izv.vys
ucheb.zav.;khim.i kbim.tekh. 4 no.4:665-66.7 '61. (YLIRA 15:1~-
1. Ivanovskiy khimiko-tekbnologicheskiy institut, kafedra tekbnolorii
krasiteley i promezhutochnykh produktov.
(Phthalocyanine) (Chlorination)

L 161~9=63_; EMR/Elip (j VEPF Wj~FWT (M)/tDS ASD Fq-4L~ 4/ RM
ACCESSION M: AR3OD5156~ M58/63/000/006AD26004
SOMCE: M. Fiziks kbv. 6 D168,
AWHORS: B irk.V rt J, %Idmov., R., P.
in.V
TITLE. Absorption spectra of substituted ogs of pht!loc L analogs of
na-phtalanyemine
CITED SOURIM: Tr Vses. A_jLQ9qreUtsiA. 20 Vapr. sinteza i
m -
!Primenenl orgaA k_rasIkq1ejv. 2962. Tvanovo., 2962,, 30-33
TOPIC TAGS: ultraviolet' upectaum, visible spectium, substituted phtaloeyantie
analog mpbtalcayanine analog
TMNSIATION: The absorption spectra of sy=etrlcal and asymetrIcal substftuted~
isnaloes of -phtalocyanine ~,substituteo -- nitro:Jor amino-groupd)and analogs of
nambtalocymine. are investigated in the ultraviolet and visible regions. It is
-found that in the case ar accumilation of amino-groups in the iso-indole resicbms,
'the maxi=ft of the absorption is displaced bathbohromal1y to the long-vave regiont
Is sbil"ted. to the shb,*rt-
while in the case of accumr-lation of the zdtro-groups it
i VWre: region. Substitution of the benzoisoindole residues in naphtalocyanine by
(.03rd V2

BORODKIN,.Y.~~ KUZNI?.'TSOVA, S.S.
Prepars,tion and properties of dyes with methyloulfoester groups.
Izv.vys.uch6b.zav.~ khim.i khim.tekh. 5 no.l.'141-149 162.
WRA 15:4)
1. Ivanovskiy khimiko-tekhnologicheakiy institut, kafedra
tekhnologii krasiteley i poluproduktov.
(Dyes and. dyeimg)

BOTRODKIN, V.F.
All-Union Interuniversity Conference on the Synthesis and Uses
of Dyes. Izv.vys.uchob.zav.; khJmA kbim.takh. 5 no.1:177-178
162. (MIM 15:4)
1. 'bAovoditell aek~sii sinteza krasiteley Vaesoyuznoy
mezhvuzovskoy konferentsii po sintezu i primeneniyu krasiteley.
(Dyes and dyeing-Congresses)

51 -
L 17'?57-,63 !."1 )/EP!
PDS 1~q74ZP
ACCESSION NRx 03005599 8/0153/63/006/003/~4!Y0478
!j
AUTHORS.: Borodkin, Ve Fe) Gnedina* Voko
loyanin Synthesis and study of properti
TITLE: Analogs ot c2pper phthalc es
:'BOURCEit IVUZ e Kbimiya J. kh1mdcheWeya tekhnologlyaj ve' 6s no* 3j 1963s 475-478
in analog
"Torm -rAGs:. phthalocyau copper phthalocyanin analog , di-iiatioiso.
indolines neita-phepylenediamines dimetlWlformamide,, copper acetat46
ABSTUCTs In previoue papers, the authors described the synthesis and prqpei-~'
ties of the products of the interaction of di-iminoisoindoline with meta-pheryl-~
enediamine and its subsiltuents and of phthalocyanin analogs obtained from these .1;
'compounds and containing one or,two hydrogen atoms. Here they. repprt on aom- I
pounds achieved by subsiAtuting metalofor these H atomse They synthesized 2
etrical analogs of phthalocyanin containing 2 diphenyloyclohexane remnants ::j
SYMM
and seven analogs of copper phthalocyanine The f ormer had the same properties
as phtbalocyanin analogs co ning bernzene and naphthalenq remnants, and,$ like
r~ oun per.
the latter, yielded SERE-11Q d3 on boilinS in dimetlVlformaml4e with cop
acetate* The copper phthalocyanin. analogs were less soluVle in organic solvents
2/2
1. Card

BORODKIN, V.F.; ICUZNETSOVA, S.S.; SMIRNOV, L.N.
Sulfoxyyaethylation of pigments. Izv.vys.ucheb.zav.;khim.i khim.tekh.
6 no.5:847-850 163. (~aRA 16-12)
1. Ivanovskiy khimiko-tekhnologicheskiy institut, kafedra teklino-
I
-Logii krasiteley i promezhutochnykh produktov.

,; LIFF
PPRODKIN,.-I.-T _NTSEV, O.M.
Interaction of 1,3-indandione with m-phenylenediamire and its substi-
tution derivatives. Izv.vys.ucheb.zav.;khim.i khim.tekh. 6 no-4:647-
651 163. (MIRA 17:2)
1. Ivanovskiy khimiko-tekhnologichaskiy instituU K&fed~-,& tekhnologii
kraniteley i promezhutochnykh produktov.

SMIRNOV, R.P., GNEEDINA, V.A.; BOROD-",,,U-1. V.F.
Synthesis and study of the properties of macroAveles. Part 1:
Interaction of' diamino-A -isoindigo with hydrazine salts. Izv.
v7s. ucheb.zav.i khim. i khim. tekh. 6 no.6slO22-1024 163.
(KRA 17:4)
1. 1 -novskly khimiko-tekhnologic,,heskiy Institut, kafedra
tekhnologii organichemkikh krasiteley i poluproduktov.

SMIRNOV) R.P.i BORODKIN, V.F.; WKIYANOVA, G.J.
Synthesis of metal complex compounds of asyzwiietrical macrocycles.
Izv.vys.ucheb.zav.; kIdm. i khim. tekb. 7 no. Ii.118-121. 164.
WRA .17:5)
1. lvaziovskiy khimiko-takhno7ogjcheskiy institut, kafedra
tekhnolugii organicheskikh krasitaley i poluproduktov.

ACCESSION NR: AP4025264 S/0153/631006/006/1022/lU.14
AUT1101., Smirnov, R. P.; Gnedina, V. A.; Borodkin, V. F.
TITLE: Synthesis and investigation of properties of macrocyclic compounds.
I. Reaction of diamino-beta-isoindigo with hydrazine salts*
SOURCE: ivuz. Xhimiya L khimicheakaya tekhnologiya, v. 6,.no. 6, 1963, 1022-1024
TOPIC 1&GS: macrocyclic compound, diaminoisoindigo hydrazine reaction product,
copper macrocyclic compound complex, nickel macrocyclic compound complex, IR
spectra, stability, structure, imino group
ABSTRACT: 71he properties and stability of the macrocyclic compound formed by the
reaction of diamino-beta-isoLudigo with hydrazine.hydrochloride in nitrobenzene
were investigated. From the lLterature the product would be assigned the formile,
1. The authors however maintain the product has laidLe hydrogen otows as in tbe
formula 11:
Card 1/3

ACCESSION NR: AP4025264
N-N/
The latter structure is supported by IR spectra (maximum at 3230 cm' character-
istic for imino group, which disappears on complexing with metal). Uopper and
nickel complexes of the macrocyclic compound were prepared -- ~:hesc are new ill the
literature. The complexes are very stable. Their absorption bands were shifted
toward the long wave region of the spectra in comparison to the spectrum of tile
uncomplexed macrocyclic compound. Orig. art. hast 1 table and 2 formulas.
ASSOCIATION: Ivanovskiy khimiko-tekhnologicheskiy institut Rafedra tekhnolog:Li
or.ganicheskikh kraciteley i poluproduktov (1vanov Chemical Tacbnological Institute)
Card 213

ACCESSION NR: AP4025264
SUIMII--=: llJan63 DATE ACQt IOApr64 ENCLt 00
SUB CODE: G~, NOW SOVt 004 OMR: 002
Card 3/3

ACCESSIM NR:- AP4Q37233 8/0153/64/00T/001/0118/olu i
AVMOR: Smi=ov,, R. P.; Borodkint V. F.; Wklysnovap Go Iq
TITLE- Synthesis of metallic complexes of uasymmetrical macrocyclic compoundo
SOURCE; Ivuz. Mximiyu i lebloicheskaya tekbnologiya., v. 7, no. 1, 1964, 118-321
'TOPIC TAGS: unsy=etrical macrocyclic compound.0 metal c=plex., cobalt complWC.,
nickel complexj, copper complekp synthesis., absorptioa spectrap thermal stabi4Ltyp
'chemical stabilityp naphthpisoindoline contaluin macrocycle
~ABSTRA(Ir: Nev metallic complexes of unsy=etrical macrooyclic compounds vere
'Synthesized and the effect of complex formation on the absorption spectrap and the
thermal and chemical stability of the macrocyclic compounds were stucliede Ccupoun"
of the formaa A
N
N
*+ILI' *A/V
N ..;O,~N
R
.1/3

were prepared by reacting 1,,3-a-(l-tdw-3-:LsoindoLWUdenamino)4mnzene vitIm
;:l-amino-3-iminoisoindollne or I-emino-3-naphthoisoindoleninee , Copper,, nickel and
!'cobalt complexes (fonwile,"E) vere prepared by dissolving the previously'prepared
-1~-compounds in pyridine., d1methy1formsmide or butanol vith equimolecular &zounto of
it :!
the Matal acetate or chlorldej, boiling for hourep filtering the PrOCIPit8ts
'no 2
T
ar
3

WeEssioN n: Ap4o37233
~nd'washing- The metal complex empounds have higher thermal stability and lover
solubility in organic solvemts and acids than the nonmetallic compounds. The
3380 cm-1 maximum is absent in the IR spectra of the metal complexes, indicating
the metals are in the "windoV' of the macrocyclic compounds. The absorpt" I - - '
spectra are shifted toward the longer wave region of the spectnza.. Uie amount of
shift depending on the metal (greatest with Cu and least with fii)* Orig. art.
has: 1 table and 2 forzuUs.
ASSOCIATION: Ivanovskiy'kbimiko-tekhaologicheakiy institut (Ivanov Chemical
lEngineering Institute) Kafedra, tekhaologii, orgaaicheskikh krasitelay i pollmroduk-
tov (Department of the Technology of Organic Dyes and Intermediate Producta3
I SUBM72ED: 08Feb63
ENCL: 00
SUB CODE: .00 No MW SOV: 004 OMR: 002
Card 3/3---

BOGHENKOVA, ll'.A.j BORODUN, V.F.
Synthesis and study of active azo dyes with a chloro,3thylsulfamide
groupJIzv.vy-s.ucheb.zav*; khim, i khim,tekh. 7 no,2!287-291 16j'po
(MIRA 18:4)
1. Ivanovskiy khimiko-tekhnologicheskiy institut, kafedra
tekhriologii krasiteley i promezhutochnykh produkto-i.

PETROVA, R.A.; BORODKIN, V.F.
Chloroinetbylation of arylaminoantliraquinone dyes. Izv. vys.
ucheb. zav.; khim. i khim. tekh. 7 no.3:472-475 164.
(MIRA 17:10)
1. Ivanovskiy khimiko-tekhnologicheskiy institut., kafedra
tekhnologii krasiteley i promezhutochnykh produk*.ov.

BORODKIN) V.I*-. DANIWVA, A.I.
Means for improving the assortment of petroleum refinery
products in the Lvov Economic Region. Neft. i gaz, prm.
3:57-59 J1-S 165. (MIFLk 16:11)

L3-555-66 F-wT(m)AwP(j) - ~~ Rm
1ACCESSION NH: AP5024hO2 UR/0206/6.5/0001915/00WD081
44'6 A.4'0;
A(MfORSt Borodkin, V. F.; Semenova,, T. 3.; Silantlyeval V. 0.
0
TITLEt A method for obtaining colored R21ystrole Class 39 Hq-.-1U!0-O
SOURCM Byulletent isobreteniy i '4ovarnykh znakov, no. 15o 196.5t 81
TOPIC TAGS: polystyrole) polymer, styrole,, monomer, acryl
ABSTRACT: This Author Certificate presents a method for obtaining colored
i--polystyrole by polymerizing styrole in the presence of a plgmerr~ containing an
active grout) instrumental in the formation of chemical union between the pigment
and the monomer in the process of polymerization. To broaden the assortment oir
materials for dyingyelystyrdle, pigments of the acrylic active group are used,,
ASSOCIATION: Ivanovskiy khimiko-tekhnologichoskiy institut (Iranovo Institute
of Chemical Enginei!qng)
suBmITTED, o5jun64 ENCM 00 SM3 CODEw 00
NO R& SOVtr' OTH&Rt ODO
Card.

BOCHEITKOVAp K.A.; BLIRODKIN, T.F.
hesis and study of active azo dyes with a chlo=-
el-,hylsulfamide group. Izv. vys. ucheb. zav.; kh-Im. i khim.
tekh. 8 no.31:459-464, 165. 0AIRA 18:10)
L lvanovskiy khimiko-tokhnologicheakiy institut.. loafedra
teldmologii It-masiteley i poluproduktov,

BcKeDKINQ~V 6, kandidat ekene'miche*ikh n&uk: SIREPNIK, I.M., kandidnt tkanami-
nauk; BEDW, A.Yai, Imndidet t*khnichaskikh nauk.
wBeenomic aspects of the nelnforrous metallurgy in the U.S.S.R."
S.A.Pervushin and others. k~viewed by V.I.Borodkin, A.M.Skripnik, Ma.
Berman. T~vst.uot.29 no.9:86-88 S 156. (MMA 9:10)
(Nonferrous metals--Ketallurgy) (Perrushin, S.A.)

BORMKIN. V. 1.
0,
Normaii.ouxT...- tandard efficiency of apparatus Rnd installations.
IMIm.prom. no.3:170-173 Ap-IV 157. (KLRA 10: 7)
(Chemical engineering-Squipment and supplies)

14(7) SOV/92--58-8-26/36
AUTHOR: Borodkin., V.I. L.agineer
TITLE-. Fixing the Length of the Continuous Operating Period of a
Processing Unit (Normirovaniye prodolzhitel Inosti mezhremontriogo
perioda tekhnologicheskikh ustanovok)
PERIODICAL: Neftyanik., 1.958, Nr 8.. pp 29-30 (1JSSR)
ABSTRACT: The author states that the refinery processing unit
shutdowns for maintenance occupy 10-20 percent of the calendar
year. That is why an extension of their continuous operating:
periods and a shortening of the time needed for maintenance are
an extremely import,-;,.nt matter. Regulations on the length of
continuous-operating periods of various petroleum-refining
apparatus have become obsolete, and it is evident that" the
prescribed length of uninterrupted operations can be extended
without damaging the equipment. It is therefore necessary to
make a study of how an extended operating period would affect
the equipment. Data given in Fig. 1 make it clear that an
extended length of the continuous-operation period increases
Card 1/2

Fixing 'the Length (Cont.)
92-58-8-26/36
the amount of repair work to be carried out very little and lowers
the cost of repair operations in relation to each day's operation.
However, a number of factors should be taken into account for
establishing respective rules. The consumption of lCuel, steam,
and electric power, increases with extension of the operating
period length, but not in the same proportion in all processing
units. The extension of the length of the continuous-operat-ii,-ig
period affects the cost of production in two different ways. The
limited number of repair operations increases the quantity of
products yielded by the processing unit. On the other hand, 'the
higher consumption ratio of fuel and electric power burdens the
production cost in this case. Analyzing the economic aspect of the
problem, the author shovis in Table 2 to what extent expenditw?es
depend on the length of the continuous .-operating period. As a
result, the author comes to the conclusion that the most economical
way to run his processing unit at the Llvov refinery Is to shut it
down for maintenance and repairs after '90-120 days of continuous
operation.
ASSOCIATION: L'vovskiy neftepererabatyvayushchi.y zavod (The L'vov
Refinery)
Card 2/2

30BDDKIN. V.I.
Method for calculating the cost of production in petrolouts re-
finilig. Izv.vys.ucheb.zav.; neft' i gaz 2. no-ll:IZ3-130
'59. , (MIJU 13:4)
1. Llvovskiy politelchnicbeekiy institut.
(Petroleum--Refining)

BORODKIN, Valentin Iosifovich; YNNISMUVA, O.M., vedushchiy red.;
'-Ui ed.
[Analysis of production planning and industrial management in
petroleum refining] Analls proizvodetvanno-khoziaistvannoi
deistallnosti v neftegazopererabotka. Moskva. Gos.nauchno-
tekhn.izd-vo neft. i gorno-toplivnoi lit-ry. 1960. 173 P.
(MIRA 13:3)
(Petroleum--Refining) (Industrial management)

STEFAIIOVSKIY, Yevgeniy Yevgentyevich; BP40PNIV, VJ.. nd. tekhn.
, _, ka
nauk, dots., retnenzent; VEDI, Ye.I., kand. tekhn. naak,
dots., retsenzent; RYDKIK, V.L., kand. ekono nauk, otve red.;
FISHCHENKO, B.V., red.; TROFIMMKO, A.S., tekhn. red.
[Economics of the silicate industry of the U.S.S.R.] Bkonomika
silikatnoi pron7shlennosti SSSR. KharIkov, lzd-vo Kbarlkovskogo
(KIRA 16:12)
univ.. 1962. 204 P.
(Silicates)

-BO~~1411,1allIntin-1011f0vich; POGOSTINP S.Z., otv. red.; GRINSHPON,
F.O., red.; MALYAVKD, A.V., tekhn. red. ---,
-
(Setting up technical norms for industries using prdaisi-q'ing
equipment]Tekhnichoskoe normirov&nis v apparaturnykh proizvod-
stvakh. L'vov, Izd-vo Livovskogo univ., 1962. 281, p.
(Chemical industries-Production standards) (MIRA 16:2)

-BORO -oaifovjqb,-_, GAL I PERSON, Ye.B.,, red.; TITSKAYA,
B.F., ved. red.; YAKOVIXVA, Z.I., tekhn. red.
[Organization and planning of work in petroleum refining]
Organizatsiia i planirovanie raboty neftepererabatyvaiushche-
go predpriiatiia. Mos1cva, Gostoptekhizdat, 1963. 285 p.
(MIRA 17:1)

M M

ACC NRs AP6025243 SOURCE CODE: UR/0057/66/036/007/119t3/1201
AUTHORS Borodin.-VI.S.* Kagan YU.U*;,Lysgushchenko R,I,
ORG: none
Tr=: Investigation of a hollow cathode discharg�. 2.
SOURCE: Zhurnal tekJaulcheskoy fiziki, ve 36, no. 7$, 1198-1201
TOPIC TAGS: gas discharges hollow cathode, electric fieldo electron energy, electron
distribution
ABSTRACT: This paper is a sequel to an earlier paper by V.S.Borodin and Yu.M,X:xgsn
(ZhTF, 36, 181, 1966) in which the experimental techniques were described and th
earlier results presented. The previous work showed that the electron energy distri- I
lbution in a hollow cathode differs from that in a positive column in that itx maximum; i
occurs at a lower electron energy and it falls off less rapidly with incrensing energy9i
Probe measurements in a 10 cm long 2 cm diameter hollow cathode have now shown, in
agree-meat with the findings of E,Badareu and I.Popescu (Phys. Rpv., 5, No. 1, 1960
'fAbstractex's note: the reference appears to be to Rev. do Physique, Bucharest7),that
the electric field within a hollow cathode is very weake Measurements of the ;;lectron
energy distribution within the hollow cathode were extended beyond the previous upper
~lizit of 40 OV to some hundreds of OV with the aid of a two-grid electrostatic allalyzcr
UDC: 537.525

SOV/124-58-3-26,10
Translation from: Referativnyy zhurnal, Mekhanika. 1958. Nr 3, p 14 (USSR)
AUTHOR: Borodkin V. V.
TITLE: A Method of Experimental Determination of the Resistance of'
Free Wheels to Rolling (Metod eksperimentall nogo opredeleniya
soprotivleniya svobodnykh koles perekatyvaniyu)
PERIODICAL: V kn.: Sb, tru.dov po zemledel*- cheskoy mekhanike. Mosco,~,F,
Sel'khozgiz, 1954, Vol 2, pp 61-72
ABSTRACT: Making use of the works of V. A. Zheligovskiy, the author
derives a theoretical formula for the traction required for a
free wheel with a smooth rim. The formula tikes into account
only the energy expended for rolling and not that for slippage,
For the purpose of verifying the formula, experimental deter-
minations are presented of the traction required by a two-wheel
cart in the condition of an earth canal. The results of the above
experiment are presented in tabular form as are the numeriCal
values obtained in accordance with the formula given and wit1-.1
those of Grandvoin and Letoshnev,
Card 1/1 N. P. Rayevskiy

BCRODKIN, V.V., kand.takhn.nauk; SHAROV, N.M., inzh.
Results of testing caprone bushiW on plows. Trakt. i sellkhoma-gh.
32 no.10:24 0 162. (MW 150i'l
1. TsentralInaya mashinoispytatellnaya stantsiya.
(Plows)

.to I 'Y E
.BC)t DYJI',,-.Vasili:y-Viadimirovicli, karit. teklm. nauk; AINIKE V, Yo.
red.
[Reclaindng brushlands by plowing the brvsh under] Osvoenie
zaku3tarennykh zeri.elt metodom zapash3ki ku;,:t,arr)ika. Srao-
lensk, Smolenskoe knizhnoe izd-vo, 1963. 49 p.
v.?)

BOBCDKIN,Ye., inshenor
: ~
Dolly for removing and replacing gear boxes and the reducing gears
of the rear axle on freight trucks. Avt.transp-33 no.7:36 Jl'55-
(Motor trucks--Repairing) (MLRA 8:12)

L 02307-67 EWT(l
AR6ol6563 SOURCE CODE: uR/o.1q6/65/000/Ql2/BO03/B003
AUTHOR: Borodkii, Ye. A.
4J
TITLE: Experimental investigation of incremental hysteresis cycles by the ballistic
method
SOURCE: Ref. zh. Elektrotekhnika i energetika, Abs. 12B16
REF SOURCE; Tr. Mosk. ererg, in-ta, vyp. 60, ch. 2, 1965, TT-85
TOPIC TAGS: magnetic hysteresis, hysteresis loop, ferrite core, alternating
magnetic field
ABSTRACT: The ballistic method was used for studying theyrocesses by which incre-
mental hysteresis cycles are established for ferrite core641hade of 0-1000, K-65 and
VT-2 materials as well as for OL-28/40-6.5 ribbon cores made of cold-rolled grain-
oriented steel. The specimens were demagnetized by heating above the Curie point or~
by using a damped alternating field. A steady-state (symmetric) IWsteresis loop is
produced in specimens demagnetized by heating after the magnetizing field is
switched 10-20 times.. A symmetric cycle is produced immediately in specimens d(.,-
magnetized by an alternating field. The incremental cycles are established in an
identical manner for all materials. When ribbon cores are demagnetize(! by a
damped alternating field and then remagnetized, the total change in flux density iii

L 02307-67
,r~6016563
20-30% greater than when heating is used for demagnetization. The method of dercag-
netization has a weak effect on the total conversion of flux 4.!!nsity in ferrite
cores. [Hoscow Power Engineering Inatitutel. V. Glotov. [Tyanslation of abstract]
SUB CODE: 09
rnr.4

BORODID. Yu..S.; UMSH&VA. N.V.; TOMILIML, I.V.
GoiMpexative features of action of tetras thylawoniin iodide
and its monochlor derivative on the N-cholinoreactive systems.
Tr%d3, LSW 371163-170 '58. (NIU 12: 8)
1, lafedra farmikologit, Laningvadekogo panitarno-giglyaniche-
skogo moditainskogo lAstituts, tsay.kafedroy - deystvitellayy
chlen ANN SSSR prof..S.T.Anichk.ov)~
(TBTHOTRTZA$KONPM. off
totraii0ii1immonimm Iodide & its monochlor
dorly. on N-cholizoreactive aystem in skeletal
ause. In cate (Rua.))
(MMLIS, off. of dxugs on
- mail)

BORODKIN, Yu. S. Cand Mod Soi -- (diss) "Effect of derivatives of imidazoledicarbo-
xylio aoi-d upon the central nervous system." Lan, 1959. 14 pp (Inst of Experi-
mental Mod of the Aoad Mod Soi USSR. Department of Pharmacology), 200 aopies
(KL, 44-59, 129)
-43-

ANIGHKOV, S.V.; BORODKIN, Yu.S.
Iffect, on t central nervous system of new competing antagonists
of pwIne series alkaloids. Vest. AMY SSSR 14 no.1!14-19 159.
(MIRA 12:2)
1. Iz otdela farmakologii Instituta eksperimentallnoy meditisiny
ANN SSSR (zav. otdolom-deyetvitellnyy chlen AMN SSSR prof. S.V.
AnIchIvv).
(PURMS. antagonists,
W-methyl deriv. of 4,5-imidazoledicarboxamide, eff,.
onCNS (Rus))
(IMIDAZOISS, effects,
same)
(MTRAL NERVOUS SYSTEM, eff. of drugs on,
N-zethyl deriv. of 4.5-imidazoledicarboxamide (Rua))

B(MODKH, YU.S.
Centia--l--tdf-~ct of imidazoledicarboxylic acid derivatives rwitb
summary In Znglishl. Poxm. i toks. 22 no.1:11-15 -T&-P '59-
(MIRA 12:4)
1. 'Otdal farm-alk-ologli (sav. - daystvitellnyy chlen ANN SSSR pref.
S.V- Anichkov) Instituta ekwPerimentallnoy meditainy ANN SSSR.
(D(IDAZOIRS, eff sets,
N,N,l-trimeth;rl-4,5-imidazoledicarboxamide & NeN.-
dimethil-4 5-imidazoledim-boxamids, on CNS (Rua))
NI Vb-U� SiSTEM, effect of drugs on,
N.N.1-trlmetNrl-4,5-imidazoledicarboxamide &
N,N-dinethyl-L~,5-imidnzoledicarboxamide (Rua))