SCIENTIFIC ABSTRACT VINOGRADOVA, M. B. - VINOGRADSKAYA, YE. L.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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umc: 621. -z),96.6T7.001.5 USSR VINOGRADOVA,,._M.,..B.., GUSLY, V. D.. "Concerning the Question of Reduction of the Directive Gain of an Antenna DUring Reception of a Fluctuating-signal" Moscow, Radiotekhnika i Blektronika., Vol 17 Vo 9, Sep 72, pp lft6-i322 Abstract: The problem op variation in the directive gain of a large linear antenna during reception of a fluctuating signal is considered. It is sho,6-n that directive gain depends on the ratio, between the powers of the "mirror reflection" and scattered components of the signal, and-may differ consid- erably from the theoretill.cal value, If there is no mirxor image conponent of the signal, then the directive gain of the antenna,is determined by the ratio of the correlation radius of the field to the wavelength, and does not change with an increase in the length of the, antenna. TTSSR UDC 577-391 MAKEELINA, A. M., _VUQ4kR2V~A ~_M_ f.., ab.d. VODOP YANOVA) L. G. "Mie RelativeIRadiation Sensitivity of Some Animal Organstt Llenin~rad, Vestnik LeningradskoGo Universiteta, Biologiya, No 2, 1973, 88-94 P p Abstract- At the peak of radiation sickness (72 hrs aft-r irradiation of rats and rabbits with a lethal dose of X-rays,amounting to 1,000-1,200 and 3,000 R,: respectively), changes in the. proteins,~ laucleic acids, and lipids of the arlmOs' small. intestine, liver, spleen, :brain, and skeletal muscles w,2re Studied. On the basJ's of changes established by the investigation of orGan and tissue homogenates, the small intestine,:spleen, and liver must be regarded As.radiation-sensitive, while the brain and skeletal Euscles are radiation- resistant. The results obtained for rdtochondria isolated from the organs of the animals agreed w1th those obtained in the study of homogenates derived from the organs ir. question.- The conclusions reached in regard to the relative radiation sensit.krity of the organs and tissues studied are In a greement with those arrived at by other investigators, except in the case of the liver, -4hich Is regarded as radiation-resis-vant in some published wor'lec'.. According to the data obtained in the present work, the biosynthesis of total lipids In the 1~ver of rats decreased by 32%., while that of ch,oleaterol increased by a factor /2 USSR MAMMA, A. M., et al., Vestnik Leningradskogo Universitetal, BioloZiya, No 2, 1973$ pp, 88-94 ofthree. The content of lipidz + cholesterol increased by 11-12%. The biosynthesls of tot-al lipids.and proteins~ln the mitochonaAa of the rat liver increased significantly, Valle a change in the content of these two components did not take place. The biosynthesis of lipids and proteins was studied by,means of a tracer introduced by the addition of.ra-dicactive Ila acetate (2JA6). Me results of the.work described indicated that the radiation sensitivity increased with increasing intensity of the,metabolic activity of the organs and tissues. BidChOndAti6- USSR F VI INT-0 C IMMYM, D. D~ "Intensity of Lipoid Mletab6lism and Com-olexes: of Lipoids !,!ith Proteins in the Mitochondria.of the Small:Intestines of Irradiated Animals" Nauch. dokl. vyssh. shkoly. Biol. n, (3cirntifLu Renorts of SchooIa 0 i 'er =UFation. Biological Sciences), 1971, No 7, PP 59-62 (from RZ]h--Riologicheskaya, lrhiniya, No-1 23, Dee 71, Abstract No 23PT61M Abstract- The intensity of restoration of lii)id..; and their FOMP 671cs ivith nrotain3 ch-*nges significantly In the nitochondria u of the small intestines of rata LL8'-hoiws after 800 roentqens of x-irradiation. The radiloactivity of.the entire susnension of mitochondria a-nd Drotein co=lexes In the irradiateil animals drops. SeDarate determination of the radioactivity of the proteins and liDids of these co?rmlexes demonstrated that 2-04-acetate is included both in th~-. linid and the protein par' of t;'-rie liT)o-orolein molecule. llormally, more than~half of all the activity of the liDonroteins qoas to radioactivity of the lipids'; under the USSR UDC: 621-315-592 VDiOGRADOVA, M. N., DRAMIN, I. A,, 'YELISEYEVA:, Yu. Ya., and "Optical Characteristics of p-Type Pb, DlnTe SolidSolutions" Leningrad, Fizika i tekhnika,poluorovodnikov, No 8, 1972, pp 1478- .1482 Abstract: The work described by this paper is the investigation of infrared reflection and absorption spectra in solid solutions of Pbl-xMnxTe, with the purpose ot explaining the energy structure of these alloys. The reflection spectra were measured with specimens having various carrier concentrations and with an Mn concentration of up to.9lio at 3000 K, and such spectra are plotted for alloys in which x = 0-03t 0.06, 0.09 with identical. Eall concentrations, The absorption spectra were obtained for po-1yorystalline specimens of Pbo. 'In Te and Pbo ~14~no jTe and are reproducea as well. It is founglth,at,~h'e introdu~-Uon'*of VIn into Pbj-x1-1nxTe ,Uloys leads to a change.in the respective Dositions,.of light *and heavy hole zcnes, and that the structure of.the alloys! val.ent tones differs substantially from those of~PbTe. 1/2 052 tjNC,L ASS IF IF D. ..PROCtSSl%G DATE--02OCT70 TITL,&--THE ACTION OF PULSEJ SKiCk- WAVES~ 6N PDLYMF:t~S -U- ~.-AUTHOR-(04)-VINOGRAOUVA, N.Got PAVLOV9 A.I., PASHIKOV, P.(*,., KHARDIA, A.P. _C,0UNTPY Of I NFfl--USSR -,SUURC E--~-i4EKH. i3GL I M. 6(11,: 76-80 --DATE PUEL ISHEO ------- To ':~.~`SUBJECT AREAS-MATERIALS- CHEMISTRY, PHYSICS -TOP.iC TAGS--SHOCK WAVE,, P CL YMETHY LMET HAC(ZY L AT E,' NYLON, T~FLD'4, VI&RATIDN EFF E C T COMPRESSIVE STRESS, AN I SOTR OP Y POLYMERLPHYSIC',AL PR-")P,cRTY CON TR 0 L -MARKUNG-NU REs'raiCTIONS CLA SS--UNCLASS I F I V 0 i0-tLJFRAHe7-1992/029 STEP fiO--UP/037,'*/70/0061!01/0074/0030 C I RC.. A C C 5 0 N N U-- A P 0 1115 2 3 UNCLASSIFIED 212 052 UNCLASSIFIED PROCESS[44G DATE--020CT70 ~-,CIRC.ACCFSSION N3--AP0111523 ''A8 RYLATE)l NYLON 61 OR STRACT/EXI -,PACT--tU) GP-0- ABSTRACT. PULY(ME METHAC' TEFLON WERE.-COVERED WITH A, SX.EEL PLATE AND SUBJECTED TO A SINGLE SHUZK WAVE IMPACT, OR MULTIPLEv VIBRATIONAL IMPACTS. IN THE LATTER cASE A CHARGE WAS EXPLODED ON THE STEEL PLATE COVERIN(-,'~THE POLV4FR, WHICH WAS -SUPPORTED BY ANOTHER STEEL PLATE. DUE TO THE OfFFERENCES'lN THF ACCOUSTICALI-O. OF STEEL. AND PLASTICS.'THE SHOCK WAVE 1,4AS REFLECTED AND THE PLASTtC'SUt3JECTED TO REPEATED COMPRESSIONSo 1~ THE MIETHOD PFR'AITTEf) TO APPLY SMALLER THAN OR EQUAL TO 3501KILOBARS-PRESSURE TO THE P9LYMERS WITHOUT DE$~TRUCTION. SUCHSHOCK WAVESIDECREASEDITHE~ANISOTROPV OF POLYMERS AND THEIR 0- UNCLASSIFIED USSR UDC: 669.24'26:620.183 DAVYPOVA, V. V., ~IAKHM EjQLRADQj MK, G. V., PETROVA, S. N., ,SADOVSKIY, V. D., Leningrad Polytechnic Institute imeni Kalinin "Application of a Metallographic, Method for Determination of the Depth of Surface Hardening in Nickel-Chromium Based Alloys" M,oscowr, Zavodskaya Laboratoriya, No 11, 1972, pp 1359-1360. Abstract: The inf2uence of the chemical.composition of alloys on the possibil- ity of metallographic determination of strain hardening by dfcoration of dis- locations.with the carbide phase liberated,upon aging is studied. The method can be used for nic.Iel-chromium alloys of~,any, con osition writh carbon contents 1P of at least 0.05%. Hardening 20-30 ~~up~to~several millimeters in depth is revealed. -7 USSR uDc: 621-319.4 NEMAN, M. 1. SOKOLOVA, M. A. SVERDIDVA A. N. VP A" ,,.V. , RYN DINA, L. P. , STARENMMO, V. G. KOTEWNIIKOVA,,L.!P-,. "Thin-Film Ceramic CaT)acitors With High~,Specific Capacitance" Elektron. tekhnika. Nauch.-tekhn. sb. Radiodetali (El6ctronic Technology. Scientific and Techiical Collection. Radio -'Components);I 4(21), 19T0' vyp- 3-9 (from RM-E~&iotelkbniiA--~.~ NO May.~_ 71, Abstract.110 5V322) -film ceramic Translation. The authors discuss a new method of mv,.in thin capacitors vith high specific capacitance. Their basi&. electrical charac- teristics aregiven. USSR UDC 612-741+154-~ RADOVA 0. L.. Ya. M. RODIONOV, I. M., and MOMVSKTY, V. I., L. Chair of Huran and Aninal Physiology, Soil Biology Faculty, Moscow State University; Chair of Physiology, State Central Institute of Physical Culture; L and Depai-tipent of Labor Physiology,.Institute,of IaboT Hygiene and Occupational Diseases, AcadenV of Medical Sciences S5SRj-J1oscow, "Independence of an Emotionally Induced Increase in Muscle Ifork Capacity From the. Blood Flow Through Working Mseles" Leningrad, Fiziologicheskiy Zhurnal SSSR imeni 1. M. Sechencrv Vol 59, No 51 1973, PP 781-788 Abstract: Yeasurements were made on young human subjects instructed to conpress the hArdle of a fist dynamometer for as long as possible while performing mental calculations of mathematical problems presented at 3-sec intervals, with the time allowed for each problem indicated by light flashes and the beat of a metro- no . The results revealed that:emotional excitation increases the endurance of working muscles 'by about 50% on the average and accelerates blood flow through resting muscles, (plethysmographic' measuxennent)-'. However, there is no increase in blood flav through the working muscles Vnen the force of con- traction is 60~ of the maxim= force that can be generated voluntarily. Similarly, tha enduxance of work-ing. muscles is, increase'Ll by 405% and 30% 1/2 USSR VIXOGRADOVA, 0. L., et al., Fiziologicheskiy Zhurnal SSSR~imeni I. M. Sechenov, Vol 59, 140 5, 1973, PP 781-788 respectively when the effort is only 30% of the maximm but an increase in blood flow is -Drevented by partial occlusion of the brachial artexj or the flow is arrestid by complete occlusion of that vessel. The emotionally induced cholinergic discharge by th-- sympathetic system not only causes vasodilation in resting muscles but also stimulates~~iy~oiysis, production of lactic acid, and activation of phosphorylase, It is,therefore concluded that the emotion- ally induced increase in muscle capacity~todo static-work is due to an augmented anaerobic metabolism in muscle tissue and is independent of the blood flow prevailing in the working mu6clesp 47 214; 2 1 UNC LAS S i!F I E 0 0ATE--20P,4L)V*70 C I R' CA C C E S I'liG 0 134 4 Iti ,374. P.witb 30-7(Rc and- liwa-d. CZ. fillers. Thus, a 0.5-0.5-1.0 isophthaloyl ~ dichlo rid e-.M~PO CI plithalein mixt. was polycond6jised in a rhlorinaW diphenyl Sol- vent at 220'-and 4.0 g oi th,e poNester obtained ~i-ijs blended with rnin t)~fore 6impression mold- 6 g MOS! and 4 g.powd. Cu fo~ 3-5.1 ing at 220-50' and IOW-15W, kg/ciW~ Polvesi Eirs conig. P were aL,;o prepd. by condensing AerephihMoyl ~hlonde with phenol- phthalein and Op'-tiieth~,lph6sphiti-N,Iide~ebis(bi;nzoyl. chloride) and were used Pitheralone or were bfended with phenolphthalein phc-nol-formaldehyde resins. CQP.N E Acc. Nr. A trac '0 S iag Servic/~ - Ref. Code C~ EMICAL AB$T _U 80 q paly(methylenaphthal- 03k behavior of 9 r T idel Vin 69 -.b 1411~1:61 . ~kH:1 A; A.- Mihel skii A L idze. rkii G: ..;Asbad. I 4T .1 1 - - (Imt. Elernen0or SoOdin.,: jmo.~, , ' , US06 - i I 2W_1j MUSM. l duL. Ser. A I "M12M) l tl_~- )Wa le t polymer ij; ind soln. pnk~m pd~ by, bulk muNio ' pre 'n. of rr~itl~ylenephthal- (I - 'of, ~er6xides ni 1tF,,HCONMej.. 11 -was ide 1) imth6 pf&ence ymd--' in HCOMM.a.- in air at 160 also thermall - _ , 1, o - . I z , to give I of higher mol.,wt, than I 66tairw d similarly tinder argon. Increa, ing the temp- to 80* had -no effect oi~.the Tyield find viscmily- I with r 'N a IV educed v~osity 0~647~ df/g~ MUlTjiCOM 25 Obtaint(I by.' Wn..poiyj~xi. :of 11 In tht of &A or (NH,hS Ooi ..%1n. bolyrnm'.W It was suMmIt-seniffive. I with - 2:'' - %~', 't l.- '. , 1, ~- : , , 1~: . , Ei6ctrO64mi-stry USSR UDC 541.67:537-311--j7) KOPjMtY,, V. V., IMMITKOVA, JJ., SELIM, S. A., VINOGIMOVA. S. V. and 19-SATOCaKIN, V. I. I'Structure and Pro'certies of Po yn-aric Semiconducto:rz Basea on Pyrron I.Iitic Acid Tetranitrile an". p-Ph-enylenediamim" q Moscow, Vysokomolehulyarnyye Soyedineniyn, Vol 14, Series AJ No 3, 1972, pp 701-705 p Abstract: 'Me licating of a lol,,t7!,,-r based on pyrromullitic acid tetranitrile and (np7iIyhc!Fazocyclane PF) from 20 to 50-0, " -0, 'too U" 700, 800, I-Ind 9,"P W,; 5 x 10-3 torr, yielded polyrz,~~rs vith specific resistance f rom 101~ to 5 x 10-1 oh"r Cm and activation anf3xiTy of conductivity A- B, from 1.7 to 0.1 ev, dependin,- on thr-, he~:t tmatiri3nt. The r-;tructure off the polymers ims deterj,-,ined by X-ray diffraction nnalyspes,' rnir atudies, and IF, spectrozeoAlf, At hz~at-treatrantk temperatures above 5D)13C the polyiner under- goas degradation ard crass-linkin:$ accompanied by the -Normation of bundles of arozatic layers consisting nmainl-j of Coli.den-Ped aromatic'7tompounds. 112 016 UNCLASSIFIED PROCESSING DATE--30OCT70 ,~TITLE-THE INFLUENCE: OF THE TYPE,OF VULCANIZING SYSTEM ON THE EFFECTIVENESS OF THE PROTECTIVE...A.CTiON..;OF STABILIZERS -U- .:AUTHOR--;f02)-V-lN0GRADOVAv T.N.jr F*ELDSHTEYN* MoSe. -CC-UNTRY,GF INFO---USSR ,~,_-SOURtE-KAUCH'. REZINA 1970t 2 92) 1 7-li'g.'_ wl~'.DATE P UBL ISHED-!---70 SUBJECT AREAS-MATERIALS ~'v UPIC TAGS-.NATURAL RUBBERt BUTADIENE RUBBER, PHENOL, DIAMINE, PHENYLENE, ~.T CARBON BLACK9 CHEMICAL STABILIZER* SULFUR COMPOUNP, VULCANIZATEv THER14AL STABILITYv OZONE ~,'-.CCNTROL MARKING-NO~RESTRICTIONS 00CUM ENT .:.CLASS----UN(;LAS 4; 1 F I E 11 ~-_P ROXY REEL/FRAM&;--2000/0827 STEP NO-UR/0138170/029/002/001710019 ACCESSION NO--AP012449.4- UNCLASSIFTEO 2/2 016 UNCLASSIFIED PROCESSING DATE-30OCT70 CIRC ACCESSION NO--AP0124494 ABSTRACT/EiTRACT-(U), GP-0-- ABSTRACTI NATURAL RUBBER AND CIS 1,4 BUTADIEN&RUBBER MIXTS. (30:70), STABILIZED WIT,11 2,6 01 TERT BUTYL 4 METHYLPHENOL (I)o 14 PHENYL N PRIME USCPROPYL P PHENYLENEt)IAMINE (111, AND PHENYL BETA NAIIHTHYLAMINEIIWERE FlLLED WITH CARBON BLACK AND VULCANIZED IN THE PRESENCE OF (ME.SUB2 NCS)SU02 S SU6Z (1111, S PLUS (HNPH)SUB2 C:NH,-S PLUS SULFENAMIDE M~IJV)P~AND SP 10.55 RESIN (V) PLUS S COMPN- VUL CANIZATES OBTAINED IN~THE PRESENCE.OF SPLUS IV AND STABILIZED WITH JI-EXHIBITED SUPERICIR7FATIGUE STRENGTH DURING WIDE RANGE FLEXING* WHEREAS VULCANIZATES OBTAINED IN~THE PRESENCE OF:,S PLUS V HAD HIGH ~FATIGUE STRENGTH ONLY WHEN STABILIZED~WITH I~ Ill VULCANILATES HAD EXCELLENYTHERMAL STABILITY REGARDLESS.OF THE STAOILIZER USED, WHEREAS S -VULCANIZATES EXHIBITEO HIGHEST THERMALSTABILITY WHEN STABILIZED WITH 11, THE 0 SUB3 RESISTANCE OF THE,VUL~ANIZATES, WA$ INDEPENDENT.OF THE VULCANIZING SYSTEMt BUT DEPENDED'ON TkE~ANT11OZONANTIS ~FiFECTIVENESS. FACILITY: NAUCH., ISSLED. I NS-T SHINNO1 PROM-wiMOSCOWs USSR4 UNCL ASSIFIED 1 2 031 UNCLASSIFIED PRO'CESSING DATE"-230CT70 TITLE--CHANGE IN THE ~MlGkATION ACTIVITY.OF LEUKOCYTES IN DOGS WITH ACUTE RADIATION SICKNESS -U- AUTHOR-VINGGRAOUVAt V.G. COUN.TRY OF fNFO--USSR ao' ;. _SOURCE--RADIOBI0LOGIWi t970, 10(i), 65_9~ OAT E PUBLIS~HED -------- 70 .,-SUBJECT AREAS--BIOLOGICAL AND MEDICAL SCIENCES -S -RAMA TOPIC TAGS--GAWlA IRRADIATION, RAD 1, AT I bN MKNC-So TION DOSAGE, ~LEUKOCYTE,, BLOOD PLASMA -C-ONYR OL, MARKING--NO RESTRICTIONS DOC U M EN TCLASS--UNCLASSIFIED REEL/FRAl,*,E--1997/023& STEP ;,10--U-1/02C,.5/70/01,'J/e)0110~)f>5t,0069 ,'CIRC ACICESS.ION NO--AP0119232 UNC LASS I F E OCES 2/2 031 UNCLASSI FIED Pik SS ING DATE-230CT70 'IRC ACCESSION NO-AP0119239 ABSTRACT/-E_XTRACT--(Ul,GP-0- ABSTRACT. THE EFFECT OF; ALu'r;-: GAMMA RAY IRRA9N. ON THE t"11GRATION ACTIVITY OF LEUKOCYES WAS STUDIED I N, f) 0 G S .THE CED WITH GAMMA RAYS FROM PRIME:60 C-0 THE ANIMALS WERE IRRADIAT IN DOS' OF 300 R ILD SU399-45). THE MIGRATION ACTIVITY ~DF LEJKOCYVES WAS UE T 0 . THREE TIMES PRIOR TO THE IRRADN.,AND 1 HR, 24 HRt AND 3,5,7,lort2,157 17, 20, 25, 30, 40, AND 50 DAYS AFTER IRRADN, THE BLOOD PLASMA OF IRRADIATED ANIMALS WAS ABLE TO MODERATE THE MIGRATION ~31: LEUKOCYTES Z -~ INED FRO E OBTAINED FROM IRRADIATED ANIMALS,! AS WELL' AS OF THOSE .1 TA 14 c -HIS INFLUENCIt :OF.T-iF. Mk~ I01ATED BLOOD PLASMA Oil CONTROLS. THE DETN.~OF THE MIGRATIOIN ACTIVITY OF LEUKOCYTES.FRON-INTACT 4N I MAL SIS SUGl',ESTED FRO ESTG. TOXEMIA DEVELOPED IWAUMALS, AFTER WHOLE BODY:IRRADN. FACLLITY: VOENNO-MEO. AKAD.1 IM~. KLROVAt~.LENI'NGRADI US:SR. UDC 5471,944/945 VINOGRADOVA, V. 1. ISFAMIARIOV S. , aIrd YUMUSOV, S.~YU.o Order of the Labor 7,1. zis,ti-tute of the Chezistry! of Natuxal Pri,-.Iuctdf Academy of Sciences "Ditermamine i a new Biiaolecular Alkal6id-From Thernopsis Lexceolata" Tashkent, Dimiya, P3:-Irodnylch Soyedinenly,. No L, 9'14 pp b7-gv- Abstracts From the Plant portion of The=opsis Luceplata, a new bimolecular alkaloid of the quinalizidi-me series was isolated, in., addition to thexxopsamine thernomine, citizAne, N-methyleltizinet paclkyearpine ~aml xhorl'bifoline. On I d I - A .2 -- 4 30 plus ne faat ti3at on vacuum aarta.L.Lation it 5 product ma identified as 51,61 -dehydro- USSR 547.944/945 ISKIANDROV, S. , 11GRAg"41 Wl' DANOV, R.A., Order of the Red Banner of Labor:InqtJtute ot C emistry of Plant Subotances, Academy of Sciences of the Uzbek SSR "Dimethamine it Naw Bimolecular Alkaloid.isolated from Thermopsis Alterniflora" Tashkent, Kbimiya Prirodnykli Soyedineniy, No 2, 1972,~pp 218-222 Abstract: A new alkaloid, dimethamine, was isolated from the Thermopsis alterniflora by column chromatography onisilica get. 'The melting point of the new alkaloid is 216-2171 Cj.accompanied~by decomp(isition. The alkaloid is optically active and yields crystalline dthydroch lor ide, dipicrate and diiodomethylate, The composition,and the,nat%ire of sa~.Its iyildlc~i,%cs ti),it this substance has b1mol(--cular structvre. on'the basirlo~laf 111, MR and mass spectrometric data the following structu.re-Iu.proj)osed;Ifor tile now compound. 40 2/2 025 ~NC L AS St F I ED, PROCESSING DATE--30OCT70 CIRC.ACCESSIGN NO---AP0129084 ABSTRACT/EXTRACT-(U) GP-0- ABSTRACT. THE EMBRYOTOXIC EFFECT OF EPTHAME (A DERYVATIVE OF THIOCARBAMINE ACID) WAS STUIM:1) IN 53 WHITE 'olAfS AND 250 ChICK Ef-11BRYONS. GBSERVATIONS ON THE DEVELO;>mEwr OF CHICK FETUSES AND RAT PROGENY oF rHOSE RECEIVING.JHE- DRUG DURING rHE ENTIRE PERJOD OF PREGNANCY INDICATI: THAT SMALL,~ DOS E5: ~OF IEP THA,14~ ~.A) I o - No T EXERT ANY E.46RYOTOXIC EFFECT. FAG I L UN INSTITUT GIGIYENY rRUDA I PROFZABOLEVANIIY, KIYEV. .,-FACILITY: lNSTlVUVINFEKTSI0NNYKH 5OLEZNEY MZ USSR, KIYEV* UNCLASSIFIED ganobldtA itti C, or ompoun vi, 1JSSR Mr- 542.91:547-1'13.546:72 MSIMEYANOV, A. N. FAMOVA$ L.* G., and. VjW44WA Institute of Q&j V. N. Wtalorganic Compounds, Aead. Se. USSR "Synthesis and Pri3perties of)7-Cyclopentadiepylirondicarbonyl- ~T-feirocenyl" 10 7, Moscow Izvestiya Akade Sq4': Xhimi, rie'pikaya'h Jul 72, 606--l( Abstrict: Peaction of diferrocenylmerc-ury v-ith cyclopent-~dienylirondicarbonyl 'iodide. yields -~IT-c~relop---,itadienyllrondicarbonyl- 6--ferrocenyl (I) -- a cryeULUine comTound of orange color. ' In solid atate it is:stable in air, dissolves easily in organic solvents, but:th6 solutions are less stable. The L ~structilre of W was proven by TR, PM and NOR apdatrosicopy as well as by reactions with FX1, bromine, arA- mercuric chloride. R6,action of W with (C6115) P takes place without rearrangement, -evidently,ohe C01group being replAck by (C6H5) P. 3 0 USSR UDC 542.91.547.257.2:547.514.72:546.725 INESMEWNTOV, A. N., IMAROVA, L. G., and V_INOGR-kQ-Q-V_Aj._L1-_N,- Institute of Metal Organic Compounds Academy'of Sciences USSM ."Synthesis.of a-Ferroceayl and a-Ferrocenoyl Derivatives of, Iron and Tungsten Cyclopentadieny1carbonyls" Moscow, Izvestiya Akademii Nauk SSSR,,Seriya Khiihicheskaya, No 12, Dec 73, -2798 pp,2796 Abstract: Reaction of ferrocenyl lithiuifi with 7-cyclopentadienyliron- dicarbonyl bromide yields 'ir-cyclopenta(lienylirondicarbonyl-a-ferrocenyI -(I) . Ferrocanoyl chloride reacted with ir-cyclonentadiviivlirondicarbonyI sodium gives.-.T-cyclc)peritadienylirondicarbonyl-a-ferroceiioyl., Respective tungsten derivatives were obtaine&in an analogcus manner. Decarbonylation of the ferrocenyl-tungsten complex by heating,yields cyclopeatadienyl- tungstentricarbonyl-:i-ferroceny'. The iron co plex reqidres more drastic M conditions and some 8ecomposition takes place',in thisriactiOn. .1/3 023 UNCLASSIFIFED PRnCESS.ING DATE--27NOV70 .,'..T'I.TLE-'-VAR I AT IONS I NTHE: r-PEQUENCY, OF, mcufmEmE of: ~~CL I NTHE MIDDLE ~_LATITUDES -U V. N. ..COUNTRY OF INFO--USSR SOU.RCE--MOSCOW, GEOMA GNET I Z MIAu` I S OF PCL CBSERVATIONS BY THE NETWORK OF. SOVIET STATIONS CO-,NFIRMS TH IS I CONICLU 5 ION. THE A.-m~IIJAL ~11AVE IS CHAP 1 ZED BY MINIMA OURING SOLSTICE, PERIODS AND MAXIMA AT THE EQUINOX; THE AMPLITUOE- OF THE ANiNUAL WAVE IS TWII-E- AS GREAT As THE AMPLITUDE OF THE SEMIANNUAL WAVE6 THE ~MOST FAVORABLE CONDITIONS FOR THE APPaARANCE OF PCL ARE OBSERVED IN THE YEARS BEFORE. AND, AFTEIR THE SOLAR ACTIVITY MINIMUM; IN THE YEARS OF THE MINIMUM~(1964-1965) THE FREQUENCY OF APPEAR01CE OF PEARLS IS OECREASEO 13Y.-.40-50 PERr,,vjNlTv At.TH0UrH THE FREQUENCY OF PCL DURING THIS PERIOD IS'FIVE,OR SIX,11MES GREATER THAN THE FREQUENCY OF THE!R APPEARANCE DURING T14E PHASE OF ~4AXIMUM SOLAR -,ACTIVITY, THUS, IN THE CYCLIC VARIATION OF THE FRE-trwENCY Of' OCCURRENCE OF PCL THERE IS A DEEP' DEPkESSION DURING.YEARS~rjF HlGli iOLAR ACTIVITY AND A FLAT (PROLONGED) MAXIMUM BETWEEN THE YEARS OF.MAXIMUM AND MVNIMUM ..SOLAR ACTIVITY. FOR PCL PULSATION5,100SRHERIC TR06PAR.ENCY SHOULD INCREASE FROM THE MAXIMU4 TO THE MINIMUM OF,~SOLAR ACTIVITY. IN ~PARTICULAR, IN THE E LAYER THE NUMBER OF'~ rREE ELECTRONS INCREASES BY A FACTOR OF ABOUT 1,5-2.Cl DUPING THE PERIOD~ BETWEEN THV: SUNSPOT MINIMUM AND MAXIMUM, UNCLASSJFfE0. 020 UNCLASSIFIED PROCESSING DATE-20~'JV70 T. I:TLC---Di IjRt~4L CHAINGE I 1,~ D I R ECT [On' OF TkJE POLAR IZAT WN Axl SOF PCL P UL SA T1 CN S--U-, v. Z. .-:AtiTHOR~-(ID3)-Vlh--CGRADI;V, P.A., V INOGRADOVA ,V.N. GOWINI? COUNTRY OF INF0-_USSR PCSCCwt GEOPAGNIETILM IA #ER0 NO M I Y A;r VOL X vNo..; 3, 1970, PP 557-558 FE PUBL [Sf-tEC- -70 _~'SUBJEC-T AAEt4S--EARTf- SCIENCES AN OCEANOGRAPHY :,.::,TOPIC TAGS--UIUkNAL VARIATION1 M.ICROPULS.ATION, GE0,44,GNEttC FIELD CICNTRGL MARKING-NO RESTRICTIONS --DOCU, 4 EN TCLASS-UNCLASSIFIED :PROXY REEL/f:R4ME--3005,f0524 STEP NG--UR/0203,'TO/OLO/003/055T/055-3 CIRG ACUSSICN NO--AP0132719 213 .020 UNCLASSIFIED PRGCESSrNG DATE--20NOV70 ~-.C LRC ACCESSICN NO-AP0132719 _ABS TRACTI EXTRAC T--( Ul GP-0- ABSTRACT. THERE ]l S A DIURNAL (;H.,,NGE IN THE R C 0 MAIN AXIS CF THE POLAkIZATICN ELLIPSE FOR'PCL P U (A AT 10 N5, CONS! (j Tf ,,I OF POLARIZATICN ELLIPSES OF THE 1+ VECtOP,- OF THE P(*,L FIELD FOR Sc,,GRA AND I)IAECT'1014 ar- o~lii mm.,~ Axis OF THE IRKUTSK STATir_NS REVEALED THAf THE POLARIZATION ELLIPSE.CHANGES AT 0500-0800 (LOCAL SOLAP.rlm). IN THE EVENING AND NIGHTTIME HOURS THE AXIS OF PCL P LA,' 1 7 TION IS DI ECTED TO a 't I- A R. THE NEt EARLY 1N THE MORNING; PRIHARILY TO THE N, A N 0 DURING THE DAYTIME NNW. H06EVERT UNTIL NOW THERE HAS BEEN EXPER11MENI'AL 001CUMENTAYION ONLY :..FOR A MOkNING INTERVAL OF MUTATION OF :THE. SIGN OF. THE ONGLE OF OEVf ATION OF THE 14,411-v AXIS OF THE POLAPIZA,rto~4 r=LLIPSG C-Rom rHE m4mEric MEPIDIAN, -ALTi--OUGH IT HAS_ BEEN POSTULATED [HAT Tfil~.ALSO OCCURS 101 THE INTERVAL 170C-2000 HOURS. PCL PULSATIONS ARE SPORADIC ANG THEJR APPEARANCE CANNOf 13F PREDICTED, ALTHOUGH YIPIES FAVORASL& F0RjliSF*VATI0N AkE KNOWN. MlOkETjVF.R# rNE J?Eitlffl) 1700-2000 IS THE --:MININIUM JIN :THE CURVF OF DIURNAL dlSTRjbtj,rlCN GF PCL CCCUPPEN STUDY Gf- 'RECGROS REVEALED THAT -C~a CAREFUL -AT ABOUT IdOO THERE I'S A GRADUAL STz.1-51117-ATION OF :DELTA PHI ANU E SUBX -E SUSY; iELTA PHI EQU`LS 1.80DEGE REE S I S' ToVPfCALr A,LTHOUGH 1400EGREE.S LESS THAN CIR EQUAL IG J=-LTA EPSILON LESS'rHAN,:OR Ef.'~U4LS TO 230DEGREE::S IS ALSO OBSERVED. TH E MEAN UIRECTION CF: 'THE POLARILATION AXIS WITH THE F TO THE EASTWARD t;IRECTIC,% ~ RMS A' NGLE MINUS 9DEGRr&S (AYISIDEFLECTED c LC Tr-E POLARIZA' E.RENT TIMES WAS.- SOUTH). f-;E DIR'CT"-%f T 10iN AXIS AT 0IFl 160C-1.630, PLUS 30DECUREES; 1630-1:700, PLUS 36VE-G'REES; L700-1730* PLUS MINUS TOEGREES. 39DEGREES., L750-18uo, MINUS LODEGREES;i L800 1815v _-jJ -1 ILLJ 0119 112 L UNCLASSIFIED PROCESSING DATE--160CT70 OF THE SHORT PEkIOD GSC,ILLATIONS OF THE GEOMAGNETEC. -FIELD -U- :,~p~.:A UT-HOR--VINOGRADOVA, V.N. ,,,-CbUNTRY OF INFO--USSR SOL)RCE--l"2="BMA%';1-4~~::TIZ,4 I AERONOM11A, VOL. 10, NO. 2 1970,t P. 371-373 ...."DATE PUBL I SHED------ 70 ~t,~~',UBJECT AREAS--EARTH SCIENCES AND OCEANOOR-APHY S .,:TOPIC TAGS--GEOMIAGNETIC FIELD$ OSCILLATIONt GFOMAGNE; I C ACTIVITY, -RNATIONAL QUIET SUN SURVEY ,"CONTROL. MARK I NG--NO RES Tii~ ICT I OWS 'DOCUMENT CLASS--UNCLASSIFIED ::~__:PROXY REE Ll FR441,'~' E--l 99t 7/0 L 5 5 STEP /01WCW;?/o_i I t/03 72, CIRC ACCESS ION 140-- AP01 19 151 Wr 212 019 UNCL. ASS UF I ED P R QIC E S S IING DATE-160CT7C C I PC A C C E- S S I ON N J-- A P 0 119 15 1 ABSTR-Ar-T/EXTk.,%CT--(Lj) ~~BSTRACT. DISCUSS16% OF Cc"RTAui, Rl-GULARITIES I N' THE PERIODS JF PC AND P1 G E Q'4 A GN T I C 0 S C I L L," ff! S E R V tt D 0 U R, I N G I)E 1QSY PERIOD AT IRKUTSK. ATTENTION IS GAVEN TCj TI-Ji7 Fi~EtUEN'CY JIF OCCUPENCF OF USCILLATION' WITH DEFFFRENT PERUOI)Si AIND THE f'EP"-NOENC~: iF A 'N' TIC ACrIVITY Atli) TJ 3F, ')AY IS SEASO-NAL PC PERIODS 0' M G L L L CURVES OF PI 1~ Pf 2, PC 1, PC 21 PC, 3V PC 4t AND 5 A AN A ; Y Z E: D . V -q ~FACILITY' AKADEM11A NAUK S55R, 1.NSTITUT zE 1, cx' AGkF-T1ZMA, IONOSFERY I RASPROSTRANENIMRADUOV0,U14f I RKU T SK i. US sl'." Rif, USSR UDC 542.91:547.1.118 ARBUZOV, B. A., NOVOSELSKAYA, A.,D.,.and VINOGRADOVN, XT. S., Chemical Institute imeni A. M. Butlerov,.Kazan' State University imeni V. 1. Uilyanov-Leain "Reaction of Some Vicinal Dihalide Compounds With One Electron Accepting Group Containing Sodium Triethyl Phosphite and Diethyl Phosphite" Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), Nol,2, Dec 73, pp 2604-2608 Abstract: The reaction of methyl esters and nitrates;of a 0-dichloro- and a,a-dibromopropionic acids with sodium triethyliphosphice and diethyl phosphite was studied at several temperaturesi-7% to -100, + 70, +20% +110' and +150*] as well as the reaction of~'a,O-dibromodiethyl ester with triethyl phosphite at room temperature. The intermediate and final products were isolated and identifiee, by means of IR spectral data and comparative analysis of physical properties. USSR UDC:539.4 KONOPLENKO, V. P., ARTYUKHINA, L. L., OVSEPYAN, Ye, S., VINOGRADOVA, V. S., Moscow "The Level of Equicoliesive Temperatur& of VM-1A Molybdenum Alloy Upon Short-Term Testing in a Vacuum" 'Kiev, Problemy Prochnosti, No 10, Oct 73, pp 51-5s Abstract: It is established that the equ icohesive temperature of VM-1A alloy in a vacuum of 5.10-4 or 5-10-5 mmile, is approximately 1250* C and increases both as a result of preliminary'tTiple washing of the chamber with argon (to about 1450' Q and as aresult of protection of the surface of specimens with a heat-resistant coating (to over ISOO' C). The level of the equicohesive temperature of the alloy results from the rate of development of surface microscopic cracks which develop at points of sep- aration of hard and brittle oxygen-containing phases on grain-boundary surfaces, which are enriched with residual oxygen during high-temperature testing. 72 USSR UDC 542-91:547.1'118 ARBUZOV, B. A., DIANOVA, E. N.i and VINOGRADOVA. V. S., enemical Institute Imeni A. M. Butlerov, Kazan' State University'lmeni'~'-. 1. Ul'yanov-Lenin "Reaction of 2,5-Dipenyl-3,4-diazacyclopentadien-1-6ne-3,4-dioxide With Trialkyl Phosphites" ~Moscow, Izvestiya Akademii Nauk SSSR Seriya Khimicheskaya, No 6, Jun 73, pp 1422-1424 Abstract: Trimethyl- and triethyl pbosphite react with 2,5-diphenyl- 3,4-dia7acyclopentadien-l-one-3,4-dioxide yielding I-alkyl-3,5-diphen Yl pyrazolyl-4 dialkyl phosphates.- USSR UDC 5412.01.547.772.2:547.P118 ARBUZOV, B. A., SOROKINA, T. D. FUZHERKOVA, A. V., '~LN-OGRA-DOVA V S. "Interaction of 1,2-diphenyl-4-banzalpyrazolidine-3,5-.-dione vith Trimethyl- phosphite and Tri(dimethylamino)phosphine"...,, Moscow, Izvestiya Ikademii Nauk SSS.Rj Seriya Khimicheskaya,,No 11, 197" pp 2577-2580 Abstract: A study was made of the effect of trinethylphosphite and tri(dimethy- lamin0phosphine on 1,2-diphenyl-4-benzalpyrazolidine-3,5-dione (1). The study was,made using thermography and Wrared.spectroseopy. Trimethylphosphite interacts with 1?-2--diphenyl-4-benzalpyrazolidi-rie-3,5- dione via the bipolar ion stage-with theformation of the methyl ether of the enol form of the dimethyl ester of 1,2-diphenylpyrazolidine-3-5-dione-4-benzyl- phosphonic acid. On interaction of tri(dimenthylamino)phospLine with 1~2- diphenyl-4-benzalpyrazolidine-3,5-dione~ a,stable adduct (1:1) was obtained having,the structure of the bipolar ion with the F-C bond. 24 USSR UDC 511,7-24l ARWZOII, B. A., DIADIOVA, E. M., and VINOGRADOVA, V. S', Chemical Tnstitute imeni A. M. 'Datlerov and Kazan State UniveftTW 1"Bf` Vv; Pv,Ul ya nov-Lenin "Reaction of 3-1,.'~ethyl-k-benzylid6nisoxazolinone-5 and 1,3-di-phenyl-4-benzylidene- pyrazolone-5 With Tri(dimethylainino)pho.spUne"' Leningrad, Zhurnal Cbshchey Ehimii, Vo1142(lok), vyp 4;, 19721, PP 750-753 Abstract.- The title reactions result intheformation of 1:1 bipolar adducts. The adduct (I) of the 3-meathyl'coupound is soluble only in polar C: 4 solvents; however, the adduct of the diphenyl compound is soluble in a wider range he rme of solvents. Trace amounts of product f9 d~by tM. condensation of two pyrazalone rings were detected. Physieal,.' propoTties, INH data, M spectra, and experimental procedur'eS are given.. USSR UDC 542-91:547-l'118 AFOMOV, B. A.) POLEZRAYEVA.. N. A., and VINOGRADOY-A,.,V. -S., Chemical Institute Kazan' State ersity Imeni V. I. Ullyanov-Jenin Imeni A. M. Butlerov Univ "Structure of the Products Obtained in the Reaction of Trimethyl. Phosplhite Vith N-Acetyltrichloroac-etaldim:Lne" Moscow, Izvestiya Alzdemii Vault oss. eriya Y&imichenkaya, No 5, May 73, m1112-1116 Abstract: Sevei -al products are obtained from the reaction of N-acetyltrichloro- acetaldimine (ATD] with tr:Luethyl,,phosphite,, djending on the reaction condi- tions. When the reaction in carried out at.-13 , tvc? crystalline products are obtained: dimethyl ester of 0( - (N-acetyl) -amino- P ~ 13 ~) /3 -trichloroethylphos- phonic acid (I), m. p.. 150-5-1510, and the, dimethyl ester of 0( - (N-acetyl) amino- ~6, P-dichlorovinylphosphonic acid (II), m.p. 96-9s)o. The same reaction carried out without cooling is exothermid,.the temperatuxe of the reaction mixture rising to W-450, and it yields the p~osphonate;,(I) plus an addition product of I mole of trirr4ithyl phosphite to 2 ~ moles ATD. The' melting point of this addition product is 153-5-1540- -With~cooling~to 40') the reaction pro- ducts are, (1). (11), and an inseparable mixture of severril liquid products. USSR UDC 547-775-547-261:L18 ARWZGV, B. A. DLOOVA, E. Y., VINOGRADC;i( V. S.' and PEBOVA, M- V-, Chemical Institute imeni A. M. Butlerov a~d-ff' "Uni.versity,imeni V. I. Ul'yanov- Lenin "Reaction of Trimethyl Phosphite With 1-Phe~yl- -nethyl-k-isopropylidene- 3 pyrazolone-511 Leningrad, Zhumal Gbshchey nindi, Vol 42 (io4), vyp 4, 1972, PP 746-749 Abstract: The title reaction does not occur at room terWerature; however, if the reactants are. allowed to react for 6hours at 1 00 in an atmosphere of dry nitrogen, two products are formed- compound (nio, if the entering methyl group bonds to the 2-nitrogen and~cowp'oud.(III), ifthe met~hyl group bonds to the keto oxygen. The two products,aredifficult to se~sratti. on: -0 CH3C-C --- ;C-P(oC11--). C11zC-C-C-1 10~1 C C; Uzi ~-O N CH 1/2 USS-i UDC 341.6 5,47.11118 and SERGEYEVA, G. N., ARBUZZOV,' B. A, SO OKINA, T. Dd Chemical Institute Imeni. A.-M. kt*e~qv ~,z -a Trivtftt Universith Imani V. 1~ Uillyanov-Lenin, uSt~~uctures of the Reaction Products or Some A, -,Uhsatwated Carbonyl. Compounds With TrJDiethy1phcsphitb.ani Tri(cZimethylanino)-Phosphi-iie" Moscow, Izvestiya Akademii Nauk SSSR, Seriya Khimiehoskaya, No 4, APr 72, PP 65)5-871 Abstract: Trimathylphosphite reacts with 1, -4-dJ hcn "I nvalharbituric acid -be J-P ),.-5 at -140 yielding a 1:1 addj,tlon pro-duct with bipol;ar,structura which. isomer- iZe--, eaSi 1y tO L MCthyl aster of the enol form of ~~~,(1,3-diplie--ilylbarbituryl-5)- benzylphosphonic acid di-mathyl ester (1). The latter forni's when the reaction, is carrio-I out at room temperature. Hydrolysis.of (1) yields an onol form of a dimethylester of &-(1,3--dipheiiylbarbitury-1-5)-banz~,lphosplionic acid. Re- action~ of tri(di-,ae'Lhyl=ino)pl~osph:Lne with .1,3-dip:--et-iyl-5-benz~tlbarbituri,~ acid:yields a 1:1 arystal1ine addition produet, a '.bipolar ionic structure. t Dipole moment values and UV spectral parizie ars of a abries of bipolar ions obtained from tri(din-3thyl.-~-mino)phosphine: are roportal, 47. USSR UDC 542,91:661.718.1 ARBUZOV, B. A., POLEZRAYEVA, N. A., and MW&&O.VA jd e sr~, Chemical Institute imeni A. M. Butlerova,:,an~ KOM State 'V 'I, y imeni V. 1. Ul'yanov-Lenin "Structure of the Reaction Products of Trimethyl Phosphite with Acetyl- and Benzoyl-p-quinone Moscow, Doklady Akademii Nauk SSSR, Vol:201, No 1, Nov-Dec 1971, pp 91-94 Abstract: The reaction of some p-quinones with trialkyl phosphites and phospines was studied. Benzoyl-p-quinoae~,reacts with A-rimethyl phosphite in-dry nitrogen td form dimethyl- p-methoxy-o-benzoyl:l)hcnyi-ohosphate (1); p3l nmr showed the presence ofanunstable bipolar ioh,JII),~the latter rearranged to (1). The results lndicate~.the formation,Of (H) as an inter- mediate in the presence of1 miole of-acetic. acid;:the~otily product is dimetliyl p-hydroxy-o-benzoly-phenyl phosphatejIII). The reaction of acetyl.p-quinone with trimethylphlosphite~at low temperatures produces a phosphorane which in methylene chloride rapidly isomeriz~s into an enol ether...Physical data, structural formulas,'compositions'.and infrared spectra for.these and several other..compounds are given.. USSR uDc 54~6.91:60j.-718-1 GAZIZOV, T. 11ai MAM, )MV) YU$ 111.1 PUMVIK, A. IT., and ARWZOV$ B. A.j Chendstry lm~titute'ir6,ehi-Ao M.,, Eutl-rov,~ 'Kazan' State University imem'. V. 1. Lfllyanov-ienin,'~ and-,Inst'ituta:.~of Organic and PLYsical Cherdstry imeni A. Ye. Arbuzoy..- A,cadenV~of sciences. 1jS.SR "Interaction of.Trialkyl Phosphit*es with 6(,/-?-Vnsaturated Acids" Moscow Izvestipi Akadeirdi KAU),.. SSSR Be. i-ya Khimicheskaya,, iTo 6 Jun 71, -PP IP59-1266 erial indicates:that the addition of trialky! -D os- Abstract: Experimental Ynat -h phites to (Y, /1 -unsaturated acids xPay proceed by ,?rellwimary protonation of the trialkyl phosphites by the unsaturated acids., -,rlth~ subsequent addit-ion of the resultant diaLkylphosphorous. acids to., esters of th4! unsalturated acids to give tria-Utyl cutr.-rv of the corresponding 13 -Phosphono~arbo>;ylic acids, accard- ing to the scheme 0 + (R0)3 P + C111--cl-l~-Coolf- (1,10)3 I'll -f1Z*-C11-C---!-O 0 0 P-.11 Cif 1=C11-000 a (110, -cm-Clincoon 1/3 35 USSR GAZIZCV,.T. Mi., Izvestiya ALkademii Nauk SSSRJ,~Seri:~a Xhitlicheskaya, ITo 6, Jun 71, PP 1259-a266 It is also possible that these reactions proceed. accordinG to the scheme sug- gested by V. A. MKnET and G. Kh, F_A~ky, v i z 7~ G 0 C11, C11=C ~C'~ (RO)3P+CII-CII-C_- ]I- .fRo)"P- clh.-CI12 -COOR (110)3 P (RO)* 11 cll. Glh 0 1) 0 C=O but without the forr.,iation of an interrmedi~te cyclic prQd:uct of the phosphorane type. The reaction malr proceed oJimaltaneousIl r-.ccOrdjr_,q to I)oW, ~,chejjes. The interaction of ztlrimthyl ?hosplhlt~e with acrylic acla, along with tri- roethyl, ester of /9 -I)hospbonopropIonic acid- Gives asrm~- 1 a-miunt of the cyclic anhydride of nethyl es'ter of /3 -phoophonopropionic acie- Me latter is obtained in much Greater quantities in tht~~presence of acatic acid. One 2/~ USSR UDC 542-91 4- 547.241 + 547-589.4 ARBUZOV, B. A., DIANOVA, E. N., and VINOGRALOVA, V. S., Chemical Institute imeni A. M. Butlerov, V. IVU lyanov-Lenin "Reaction of Trimethyl Phosphite-With Benzylidenebenzoylace- tic Ester" Moscow, Izvestiya Akademii Nauk S3SR, Seriya Khimicheskaya, No 11, Nov 70, pp 2543-2548 Abstract: Continuing their study~of phosphorane-type compounds obtained in reactions of trialkyl phosphites with: x, e -un'satu- rated carbonyl compounds, the, aurhors found 'that the 'rieact~on of trimethyl phosphite with benzylidenebenzoylacetic ester gives crystalline 2,2,2-trimetiloXY-3,5.-diphenyl-4-carbe-choxy-l-oxc) -2- phosphacyclo-4-pentene (I).- The structure of,11 was proved by IR, X14a and LIV spectral data, as well.as E; study~of its chemical properties. I does not react with.' ethani on.neating-to 70' for 7 hours even in tne presence of phosphoric acid as~ catalyst, but is readily hydrolyzed on neating ~ With. an equimolar quantity of 1/2 T~z:nl ~ F - . -r- - r ~- - - - ;~ -1 - - 1-:;~! m ilil rlMWlfl"iiiWW &l. . I . USSR UDG: 661.718.1+547.24,1+541.6 ARBUZOV B. A., DIANOVA, E. N., VDIOGRADOVA V. S., and PELCROVA, M. V., Chemi- cal Institute imeni A. M. Butler&V"W-*tL~ii!f~K4t&n--4i~'State-U-niversity Imeni V. I. Ullyanov-Lenin IlReaction of Trimethylphosphite With Isopropylideneacetoacetatell Moscow) Dolklady Akademii NaWk 555H) Vol 195) No 5~ Der, 70, pp ioq4-io96 Abstract: Trimethylphosphite reacts with igopropylidime Beetoacetahe at room spho~ana. -at 2*10 imi Hg temperature to eld the, cyclic* pho A~ b.p. 85-87 20 y20 d 1.1132. 1.4721, CH3-C C-COOC2H5 C2H5IO-C(I -C .=-C-Cl13 0~1 (CH 3)2 (CH3)2G .10 3 WU1136 "A" 1/2 : : , , !, t :- III M: F1 IT ;;,If [ 3ilt " u - 111,33i;!i 1 .1 -.1 1 , , . , - . , . , , 3iii'tkit4fifill'.. 1. i g , 1 1. . I ilwl.;f! I .- I R~fi~ USSR UDC: 54-1.26,118+547-775 ARBUZOV, B. A., D-TANOVA, E. IT., tQ,1A,,V,.,~c., Chemical Institute imeni A. M. Butlerov Affiliated. With Kazan': State n versity imeni V. I. te n Ve Ul.yanov-Lenin "The Structure of Froducts of the Reaction of 1-Phen*Yl-3-~lothyl-4-Isopropyli- denepyrazolone-5 With Dimethylphos'phorous Acid' Leningrad, Zhurnal Obshchey Khimii, Vol 112(1o4), ITo 6, Jun 72, pp 1212-1217 Abstract: The strkicture of dimet-hyl (1-plienyl-2,3-dinetkl,ll;yrazolone-5-yi-4) isopropyl phesphonate and dimethyl (1--~.Phe~a"fl.-3-rp-thyiL-5-rl;ethox~,pyrazolone-4) isapropy-1 phosphonate was identified -by. the additiom of dinnethylphosphoroas acid to 1-phen,,rl-3-iriethyl-4-isc)-i)ropylidc-nepyrazolone~-5 followed by alkylation. Tautomprism of the adduct of dimethylphosphorous acid.[ with 1-phenyl-3-yrethyl- is proved.~~T~p authors tbank,Ym- Yu. SELmitov and E..I. Colldfarb for taking the nmr sipectra. USSR uDc 661.718-1:51,7.642 ARBUZOV, B. A., 14AMY-EV, YU. M., and SA14ITOVY YU. YU., Chemical Institute imeni A. M. Butlerov,A(~zan' State University Imeni V. I. Ul'yanov-Ienin Spirophosphoranes Based on Acrolein and Methyl. Esters of Ethylene-glycal- and Butyleneglycol-1,3-phosphorous Acid" Yoscov, Doklady Akademii Nauk SSSR, Voll 205, No 41- Aug 72, pp 843-846 Abstract: The reaction of acrolein urith cyclic phosphites was studied. Addi- tion of acrolein to the methyl ester of.ethyleneglycolphosphorous acid in absolute ether ,~-ielded 1,6,9-tr xa-[(5-irethoxy)-5-P'."O~-PilasPirc)-(4,4)1 2-nonene b-p. 55-560/lo-3= nM 1 14820 d201,3016. Vnen butylemglycol- 1 .1 D ' - ) 14 phosphorous acid methyl ester was used,:th6 product was 1,6,10-trioxa-9 20 methyl--[ (~-metho-.vf)-5-pliosp.qaspiro-(4,5)1-2-aecene, b.p. 63--(--O/.-LO-3, mm, n D 1.478o, d4ol.2041. Addition of joethyl vinyl ketone to the methyl ester ol but.ylei-nglyco osphorws acid yielded, after a somew!lat Sj.VWer reaction, 3-,6, 73- 740/10-3 p-jn, , 1-4745, 1.1707. The reactions. vere cRrried out witli exclusion of moiSture.. uuder continiloa.6 iBtirring, keeping the temperature, below +250C. The products were found to hydrolyze easily in air but ware stnble enoijih t be distilled under hii,.7h vacuiw.- --25 urganoppospn9roui.3, compounaip USSR UDC:542-gt+661,718-1 AMMOV, B. A., SOROXINA, R. D., and Chemical Institute imeni A. M. Butlerovf Kazan' State University imenI.M. I., Ullyanoy-Lenin 'Kazan# "The Reactions of 5-Benzalbarbituric Acid with Trimethyl Phosphite and Tris(dimethylamino)p1hosphine" Moscow, Ievestiya Akademii flauk SSSR, Seriya Dimicheiskaya, No 3, Mar 71~ :PP 573-577 Abstracti At minus 140 trimethyl phos~hita (I) addea to ~-benzalbarbituric acid (11) with the formation of a lil addition product (m.p. 80-50) that had a bipolar structure, This product~isomerlzed to.the methyl ester of the enol form of the dimethyl ester of barbituryl-5-benzy1phosphonic: acid (IIII a.p. 220-20). The latter compound formed directly When the reaction was carried out at room temperature. On treatment of III with~ HC1, the dimethyl ester of barbituryl-5-benzylphospho-nic:acid.(IVI m.p. 2440) was obtained. Dimethyl phosphite reacted with Il to foma,product uhich;on reerystalliza- tion from dioxan yielded the dioxanate of the enol forn of the dimethy.1 ester of barbituryl-5-benzylphos~honloacid~(M.P. 154- 0), -reatment of the p dioxanate with HCl resulted in the. formation of a prouot that proved to be 1/2 USSR UDr: 621.391.19 KATYS, G. P., ZOTOV, V. D., POLIKARPOV, S. P. V Itj "Order tJE[Ak of Lenin" Institute of Control. Problems tiotr~w-d Rctnote Control), Acadeqv, of Sciences of the USSR "An Image Converter" Moscov, Otkrytiya, Izobreteni Obra:7,ts-,.Tovarnyye Znaki, ya, ProiVshlennyyr- 'I No 36, Dee 71, Author's Certificate No' 322781, Division G, filed 19 May 1~0. published 30 310V 71, p 1.63 Translation: Mis, Author's Certific6t~e introduces, an, 11niage coriver-te:r madle in the forn of a semiconductor plate to which metal ring electrodes and a central point electrode are applied for a radial ficl.d. Ar, a distinguish- ing feature of the patent, converuion ex-rors which res-alt from rotation and change of image scale are eliminated by using a cawtooth voltage source and by placing an additional electrode on the semiconductor plate inside the ring electrode. ~Tlhis auxili--vj electrode is made from a r-a- terial inith conductivity opposite. to that of the, semiconductor T)Iate and takes the for,,;,: of one 1--lu-n of an Archimedes spiral with one end cornected to the ring electrode and the other end connected th-oughla load to the source of sawtooth scanning voltage., 52-0 am", VMF M 'HIM .... .... ......... USSR UDC: 621.383.8 ZOTOV, V D., Moscow Avestigation of a One-Dimensional Solid-State Image Con- Verter" Moscow,.Avtomatika. i Telemekbanika, No 1, Jan. 72, pp 189-191 2- Abs1ract: The article is a description of a solid-state one-dimensional image converter which utilizes the inverse Hall effect (the Suhl effect). The inain scanning element is a rectangular semiconductor plate, :with one. light-sensitive face and a point contact or PN-junct-ton ifor sagnal takeoff on the opposite face. An attracting plectric~field is applie,1 lengthwise of the scanning clement. The plate is p3aced in a magnetic-field.whose strength is a linear function of time. iffien an image is projected on the light-sensitivesurface, nonequilibrivr, carriers are generated in accordance with the ~intensity of the emission on~the surface. These carriers are subjected to Lorentz force, Hall force, and the force of the 1/2 USSR VINOGRADOVA, Ye. P... ZOTOV, V. D.,'Avtoirtatika i Telemekhanika, No 1, Jan 72, pp 189-191 electric field. This results in redistribution of the car- riers in the bulk of the semiconductor. Current takeoff affects the minority carriers corresponding to sequential sections of the surface asthe magnetic field strength in- creases. If the laws of redistribution of the minority car- riers are known, this process can bacon.trolled a-nd optimum parameters of the device can be selected.depending on the job to be done. Preliminary calculations show that a reso- lution of the oTder of 30 lines/mm and a line conversion time of.the order of a few microseconds' can be achieved with a main scanning element about 30 microns. in width with a,light sensing surface approximately l0iM, long when the long di- mension of the current takeoff is About 5 microns, and the illumination is approximately 100 Ix. Two figures, bibliog- raphy of three titles. 2/2 _112 019 UN(: L-A. S S: I F I E 0::- PROCE SSING DATE--18SEP70 -TITLE--SUBSTITUTION ON THE BENZENE RINQ~QF INDOLE. XI. SYNTHESIS of- SUBSTIJUTED 5,NITRDv6tAMI.NOINDOLINE-~~'-U-: ~AUTHOR-(04)-TERENTYEVv A.P.j VINOGRADOVA.t YEoV.r Cl-lETVERIKGVv V.P., DASHKEVICH, S.N. ,-.C.CUNTRY, OF INFO--USSR ..t0URCE--KHIM. 4GETEROTSfKL. SOEDINt 1970't (2)t 161~"~ ATE PUBLISHED ------- 70 SUBJECT AREAS--CHEMISTRY C TAGS--BENZENE DERIVATIVE, INDOLE#, ORGANIC NITR(3 COMPOUNr, NE, UV CHEMICAL SYNTHGS I S ~7 c' 6: 4 T0. LMARK I NG--NO RESTRICTIUNS 1)OCUMFNIT CLASS--UNCLASSIFIED RE-EL/FRAME--1987/1093 STr-P N.0--UR/0409/'rO/000/002/0161/01(->3 ~.,CIRC ACCESSION N0--AP0104491 UPIC LASSIF IED 2/2 ~ 019 UNCLASSIFIED :PkOCESSING DATE-18SEP70 ~tIRC ACCESSION NO-AP0104491 ABSTRACT/EXTR4CT--(U) GP-0-7 ABSTRACT*' CF. CA 71: 221LOD. I (R PRImEl -XCESS AMINE TO GIVE EQUALS H, R PRIME2 EOUALS NO SUB2) WAS HEATED WITH E I (R. PRIME1 EQUALS M) IR PRIME2# PERCENT YIELD,,AND MI.Pv GIVEN): CYCLOHEXYLAMIN0, 91, 134.5-5.50EGREES IALC.); PIPERIDING, 80, 103-4DEGREES (HE 'PTANE): HOKH SUB2)S,U.BZ NMi 76a5t 193-40EGREES (MEOH OR MENO SUB21; BUNH (11) 691 144-50EGREES,(IAQ. MEOM; PHCH SU82 NH Milt 90, 172.5-3.5DEGREES (ETGH). I (R PRIME1 EQUALS ACt R PRIME2 EQUALS NO SUB2 ) A IV) f 3 G) AND 10 ML BUNH SUB2~ WAS HEATED 16 HR,,AT 78DEGREES TO GIVE 82PERCI-NT 11. IV (3.1 G) ANO 15.ML BUNH SU132 WAS REFLUXED 2 HR ro GIVE 30PERCfNT I IR PAIME1 EQUALS AC~ R PRIME2 EM)ALS BUNH)t M. 142-30EGREES MOM. SIMILARLY.PREPO. WAS 47.13PERCENT I (R PRIME1 EQUALS ACI P PRIME2 EQUALS PHCH SUB 2 NIH) M t M. ~ 22 1.5- 22DEGR E ES (HCONIME SUB2Y. 111 (0.1 G) AND 5 ML AC SUB20 WAS HEATED.:2.5 HR TO GIVE 9605PERCENT V. N SUB2 H SUB4 *H SU8270 (3 ML:) WAS ADDED TO 3 G IV IN 25 ML ETOH TO GIVE 4aPERCENT (R PRIMEI EOUALS AC, P-PRIME2 EQUALS NMNH SUB2), M. 208-90EGREFES (ISO-PROM, 77PERCENT I (R PRIME1 'EQUALS H, R PR f ME2 EQUALS NHNH ~ SU82) i~ Me.: .1 79--8ooEGR EES IETOH), WAS OBTAINED FRO,M-10 ML N SUBZ H SU64 9H SUB2 0 AFTER, .4 Hk IN THE PRESENCE OF 0.4 G K S062 CO SUB~. UV SPEVrRAL- DATA W E R CE Gil VENt: UNCLASSIFIED ----------- ---- i fill 002003000- USSR UDC 547.51 +541.15 + 661.718.1 BABKINA, E. I., VINOGRADSKA.YA, L. S., DOBROVA, Ye. I., and.GUR'YEVA, N. A., Branch of the Physical Chemical Scientific~Research Institute imeni L. Ya. Karpov "Radiochemical Synthesis of Organophosphorus Compounds Based on Indene and Phosphorus Trichloride" Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 9 Sep 73, pp 2084-2085 Abstract: Gamma irradiation of the mixtures of indenr:.- and PC13 under can- ditions favoring either addition of PCI on 3 0 the double bond or polymerizati as well as under conditions practically excluding the possibility of polymeri- zation. yields, fails to induce the,additiOn Of PC13 ta'the indene along the double bond. This may be due to an extremely unsaturated state of the indene double bond leading principally to the pblymerization products. 014 UNCLAS~SITIED:': PKOCESSING DATE--230CT70 'TITLE--ADSORPTION BEHAVIOR OF A.MIXTURE OF-BUTYL AND. NCROTYL ALCOHOLS ON -':"-.--ZEOLITES -U~ U-THDR-(0.3)-VINOGRADSKAYA, M.V.v.KELTSEVV N.V., LVOV, S.V. '_CWNTRY. OF INFO--USSR ,-,SOURCE-LH. FIZ. KH114. 1970# 44(1)r- 238-40/ ~DATE PUBL ISHE-D------70 OBJECT AREAS--CHE?4 ISTRY -TOPIC T AGS--ADSORPTIONt ZEOLITE, ISOTHERM, BUTANQL~ GAS CHROMATOGRAPHY, _ALC OHOL X:04TROL MARKING--NO RESTRICTIONS dOCUMIENT CLASS--UNCLASSIFIED %-O'ROXY iZEEL/FKAME--1995/1262 STEP NO--UR/0076/70/044/OOL/0238/0240 CIRC ACCESSION N10--AP0116724 W"I 1-1 L_ IA j1. 1 1. 2/2 014 -UNCLASSIFIED PROCESSING DATE--230CT70 1C.I.RC ACCESSION %'tl--AP0116724 _A4STRACT/EXTRACT--(U) GP-0- ABSTPLACT. ADSORPTION ISOTHERMS OF 11EMCHCH SUB2 OH I I ) AND BUOH 0111 CAA ZEOL-I TE II ) AND INAX ZEULITE 1111) ~IERE DETD, AT 80-300DEGR EES AND 1-10MM HG.' 014 BOTH ZEOL I TES r I IWAS MORE STRONGLY ADSORBED THAN 8UOHI BUT III WAS:MORE -SELECTIVE THAN 11. 1 PRESE.NT AS AN, 8PERCENT TiMPURITY IN SAMPLES OF SUO)tf IWAS COMPLETELY -REMOVED BY PASSING THE SAMPLES T11ROUGH Ill AT 1300EGREES, ANO CHECKING -THE _ELUATE BY GAS CHROMATOG. IN A 3000,TI.MES 6-MMICOLUMN FILLED WITH CHROMOSOPB W IMPREGNATED WITH POLYETHYLENE GLYCOL.ADIP~ATE AND ELUTED ~WITH,K. FACILITY: ~.MQSK.ANsf. TONK01 KHIM. TEKHNOL. IM. --LOMONOSOVAP MQSCOWv USSR. -UNCLASS-1 F USSR UDC 911.3:616.9:576.895.771(67+57) SHIPITSINA, N. K. XNUFRIYFVA, V. N. BtLKDIN, A. I., YINOGWM&, .".11W ",4, GORNOSTAYEVA, R. M., KUPRIYAN.JOVA, Y. S., MARKOVICH, N. Ya., MSNITSYN, S. P., and TIMOFEYEVA-, L. V. "Study of the Biology of Blood-Sucking Diptera as Basis for Combating Vectors of Infection and Blood-Sucking Insects in die Soviet Union" yashc' V ab.. Materialy Nauchn. konferentsi-i Dosy h. 50-letivu In-ta Med. parazitol. i trapich. Med. 1970 (Proceedings of the Scientific Conference Devoted to the 50th Anniversarv of the Institute of Medical Parasitoloa, 0Y and Tropical Medicine 1970 -- collection.of works), Moscow, 1970, pp 48-49 (fromEh-Meditsinskaya Geografiya, No~ 2,, Febn, Abiitract No 2.36.48) (No abstract] ------------ BI Agricult6re 'USSR uDc 6il~-449-57:615.285-73-576-895-77+595-771 KRIVmOVjI, Ye. 1,,., MiMCFANOV, A. M.1 KOZIN) 11. P.) TM,0~7t, Y ~,W~ . L . V . TULbJPOII._A_I~ A. 114.) VIINOGRADSKA~; PD_)TIIj!k6A, A. S. ~6., Yr-,R~ijSfEv) Yu. V. I and RYAWTS-Py,"',7 Tnstitute of Medical.ParasitoloC,,y and T~~pical Eedicine imehi Ye. I. Martninovskiy, Ministry.of Health USSR, and Institute of Agri- cultural and Specialized Application 9f Civil.Aviation "Testing of Some Organophosphorus Compounds ard Carbairates against Larvae of Aedes Mosquitoes (Culicidae) in Experi3Lents.vith Aerial' Spray:big" Moscov, M4ditsinskeya Parazitologiya i Parazitarn3rre Bolezni, Vol 39, 110 5, Bep/Oct 70, PD_ 599-603 fibstract: The use of organophosphorus compounds and carbamates against mosquito larvae was tested in the Yakut ABSR,~ in the axea of the villageB of Novy, Aik:hal, and Mirny, and the Udachnnyu deposits. Miter reservoirs wre treated by aerial spraying from an AN-2 plane. The following pesticides irere tested: bytex, methy1niturophos, trolen, sevine) and dipte-rex; DDT was used as the reference. Comparatively uniform marshy territories -with occasional for- esto and Imshes were selected. lkytex vas sho,,rn to be especially effective as a larvicide) a doce of 40 g/hecure.proving to be cuffIclent. Methy1nitrophos 1/2 2/2 WSR UDC .911.3.616.9.576.895.771(571.56) TIMOFEYEVA, L. V., MITROFARIOV, A. 14., R,1SNITSYN, S. P., PETRUCRUK, 0. Ye., RYAZL14TSEV, V. A., and'.Y ERMISHEV, Yu. V. IfOrganizational Principles in the'Struggle A ainst Blood-Sucking Midges and .9 Aedes Mosquitoes on the Basis of Their Biological Characteristics" V sb. Materialy Nauchn. konferentsii, posvyashch. 50-letiyu In-ta med. parazitol. i tropich. raed., 1970, (Proceedings on the Conference Commemorat- ing the 50th Anniversary of.the Institute of Medical Parasitology and Tropical Medicine 1970 -- collection of~woxks), Moscow, 1970, pp 50-51 (from RZh-36. illeditsinskaya Geograftya, No,l, Jan 71,~Abstract No 1.36 75) [No abstract] 2/2 017 UNCLASSIFIED ~:PROCESSING DATE-30OCT70 CIRC ACCESSIGN NO-AP0123996 - . .- ;. GP-0- ABSTRACT. THE FAUNA AND BIOLOGY OF NDER CONDITIONS OF. A TAIGk ZCNE OF THE RIGHT BANK OF THE OB HOSCUITOES U. RIVER IN THE LOCALITY SITUATED IN LATITUDE 61DEGREES 15MINUTES NORTH AND LONGITUDE 73DEGREES 30MINUTES,EAST.WERE STUDIED. THE FOLLOWING SPECIES OF MOSQUITOES OF THEGENUS ACE05S WEREIFOUND IN'~THE LARVAL STAGE. HEAXODONTUS`.'~`YAR, EXCRUCIANS WALKs PUNCTOR KIRBY9, IMPLGER WALKsqIGRINUS ECK, RIPARIUS, Do Ko AS WELL AS ANOPHETES MACULIPENNiS. TRANSITIONAL AND HIGHLAND MARSHES ON TERRACES AND WATERSHEDS,SERVED AS T14E 14AIN BREEDING PLACES FOR AEDES MOSQUITOES. FLUODLAND.~AND.ASSOCLATED WATER RESERVOIRS DURING FLOUDS PRODUCE INSIGNIFICANT EMERGENCE OF AE. EXCRUCIANS W. BEFORE FLOODS AND AN..MACULIPENNIS.~PIG AFTER FLOOD. THE PAPER PRESENTS PhENULOGICAL DATA AND THE SEASONAL PREVALENCE.GF LARVAE OF DIFFERENT SPECIES DEPENDING UPON THE TYPE UFlWAYERIRESERVOIRS. TIME OF TREATMENT WITH NON RESIDUAL-INSECT;,ICIDES IS IN'DICAtE04 ,~-FACILITY ISENTRALINYY NAUCHNU.~. OWNPEKYSIONNYY INSTITUT, ''MOSKYA& UNCLASSIFIEG .. ..... .. ..... ...... USSR UDC 678.742.2;66.018.86.01:53 VINLOGRADSKAYA Ye,-L AGAMALYAN, S. G., and VDOVINA, A. L. "Influence of e-Radiation on the Physical Mechanical Properties of Polyethylene and Poly-carbonate". Mosedw, Plasticheskiye Massy, 7, 1973,~pp 10-12 Abstract: A study was made of the influence of i-radiation on the molecular structure of high density polyethylenel(HDPE) and polycarbonate (PC). In- creasing the dose to 25 millirads resulted in an increase in the stability limit during stretching,for HDPE; increasing the dose from 25 to 200 milli- rads resulted in a decrease in av. Density, module of elasticity, hardness, and fatigue stability for HDPE in general.increased with increasing dose. The molecular weight and fatigue resistAnce decreasedfor PC. Values for other parameters are given. The radiation.of HDPE res~ijts in "linking" processes and leads to the breakdown of.spherulite formation, and to the breakup and subsequent compaction of the.structural elements. In PC, however, irradiattin results.in.destructive,processes leading to the frag- mentation of the polymers. toiffifflli 'M 0 Vi~r