SCIENTIFIC ABSTRACT MAYER, I. - MAYER, N.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001033020018-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 14, 2000
• Sequence Number: 18
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Istvan
Designing broken twill. Magy textil 14 no.10:436-445 0 162.
1. Mgyar Gyapjufono- es Szovogyar.

MYERS, Ist'van
Application of viscoee rayon in the manufacture of carded
fabrics. Magy teXtil 15 no.9.-423-426 S 163.

FAYER, Istvan 100
Tire-9--Zhanneled model directional receiver-transmitter. Radiotechnika
13 no.3s96-98 W 163. -
I

Ta
CATSOMY I
ABS, JOUR& I jRMdm,S Noe 5 1960j, NO. 20064
t Pop, I. N. and Mayer, I. A.
-If T. s Not given I -
On the R.Ardness ari -lq9tiCity Of -3elat;i
vinyl Chloride
CRIG, MR* s Rev Chim, 9, lio 10, 55?-560 (195t~)
ABS'IFACT The physicomechanical characteristics of pastes
made up with different polyvinyl chloride/plastici-
zer (dioctylphthalate, dibutylphthalate, tricresyl-I
phosLhate, dioct.vIsebacate) ratios are listed.
L. Pesin

- MAYER, 1,0.
Basic specific neural processes in preschool children. Zhur. vys.
nerv. deiat. 11 rio.1:92-98 Ja-F 161. (MIRA 14:5)
1. Institute of Higher Nervous Activity, of the Academy of Sciences
of the U.S.S.R.
(CONDITIONED RESPONSE)

[AI)IF-ki J.
j
Fuel Abstracts L,~~35t- AUP
Vol. 15 No, 3 454 465;-. Engrsl Dig., Mov. V)53, v-1. 140 1427-430. 1 ~~-IS. Z)~ ~I n,'Le
Mar. 1954. and double ~)AaMaLjc pags-out Ltirbines ana LhOr rovermri,~ frex. Um
Steam Raising and .1am-aen Gottvald voiks, r3rno, are ,.Iven. A systen, or jx;enon.: ;);,-s-c,ut
turbines is InWcatcd, (L).
Steam Engines

MAYER, J.
Pneumatic suspension.
P. 372 (AUTOMOBIL) Vol. 1., no. 3-1,, Nov. 1957.,
Praha, Czechoslovakia
SO: Monthly Index of East European Accessions (EEAI) LC, Vol. 7, No.3,
March 1!)58

MAYER, J., inz.; NAPRAVNIK, Vl.
Comparison of the technical and economic advantages of 11
meter and 12 meter buses. Siln doprava 1-1 no.1:2-4 Ja 163.
1. Vyzkumny ustav dopravni Praha.

Cbmdlctal Abst.
Vol. 48
A 10, Igg
Water* Se"ge, and Sanitation
pH12
en the
after
till.
'ad
COMA its
WIR(OH)R. red well in Hsiba. anti oxi.
I" the Prentice Of As* b dttd. m3 MnO. -
U 10 1. Hio is treated with *,moll to
I= washed with 4% KaOH. dimalv~d
nl.20 H.M.andwashellwitli][120toa
r-be Apmate is treated with I mi. 0.5%
If)% mt;
The xteam bath, CnolLd, atilt,
R CfYstAI of K,".,. dild. with IljO to W

Czechoslovakia /themical Technology. Chemical Products 1-14
and Their Application
Water treatment. Sewage water.
Abs Jour: Referat Zhur - Khimiya, No 9, 1957, 31706
Author : Hluchan E., Mayer J.
Title : Colorimetric Determination of Nitrates in Water
Orig Pub: Chem. zvesti, 1956, 10, No 6, 387-395
Abstract: A method has been worked out for the determina-
tion of Noa- at low concentrations by means of
sodium salicylate and CC1.3COOH. A direct rela-
tionship between coloration intensity and con-
centration of NC6- is observed up to 1.4 mg/liter.
Interfering effect of cathions is eliminated by
filtration of samples of the water through a
Card 1/2

Czechoslovakia /Ibhemical Technology. Chemical Products 1-14
and Their Application
Water treatment. Sewage water.
Abs Jour: Referat Zhur - Khimiya, No 9, 1957, 317o6
cathionite. The N02- ions are destroyed by
addition of a small amount of NaNj to the sample
of water prior to filtration through the cathion-
ite. I' and Br-, at concentrations above
0.5 mg/liter, decrease intensity of coloration.
C ard 2A

CZECHOSLOVAYIA / Chemical Technology. Chemical Products 11-5
and Their kpplication-Water Treatment.
Sewag e
,'~bs Jour: Ref Zhur-Yhir-riya, No 3, 10,59, 8649
Author :_I~.ayer, J., Hluchan, E.
Inst, Not given
Title Determination of Pluorlde-- in Drinking vlater
Orig Pub; Chem. zvesti, 1958, 12, "To 39 143-15)+
Abstract: Two colorimetric methods (by use of aluminone an(~
chromasurole) and ona volumetric one, by titrating
with thorium nitrate, using alizarin red as the
indicator were compare6. The latter was found to be
best. The effect of the presence of a number of ions
was checked. -L42- was precipitated as Ba,,Ll+.
--N. Vaksberg
Card 1/1

HLUCHAN, Eugen, inz.; MAYER, Jan, in2,.
Colorimetric detemination of fluorides. Chem zvestl 17 no.8:
569-574 163.
1. Ustav hygieny, Bratislava,, ulica Ceskoslovenskej armadY 40.

KRORP a.; MAYERY J.
--------- M-M---~'
Energy -transfer in
Bul chim PAN 12
the radiolysis of solid systems. Pt. 2.
no. 3:161-1-167 164.
1. Department of Radiation Chemistry, Tedhnical University, Lodz.
Presented by W.Trzebiatowski.

t A5262-66r EWP(t)/ETI IJP(c) Jp/jG
SOURCE COD91 Cj'i7o-o-5W57000701-27644-77044C,.I
ACC NR% Ap6024697
6MR: Abel, E Ya.; Hluchan, Eugen-Glukhant, E.
C~G: Hygiene Research Institute, Bratislava (Vysk=W ustav, bygieny)
.Tjr1r!.t Cesium losses in the thermal treatment of samples
SOURCEs Jaderna onergie, no. 12. 1965, 447-J448
TOPIC TAGS: calcination, cesium compouna, thermal effect, radioactivity wasuremont
.1
ABSTNOT: The article reports on the invostigation of cesium losses duo to the
,calcining of sone cesium compounds (chloride, nitrate and sulfate) at various tempe-
:raturese The results indicate the need to obaerve the proper conditions with respect,
to the calcining tenparature and time in the thermal treatment of samples to determin6.
issium-137 as well as the mod to deterklm total activity. This article wa~spre-
as by M. Kyrse Orig. art* has: 3 tables. fBased on authors' Enge at
JM: 34,666-7
MM COM 18, 20 WBH DATE: none ORIG REM 003 / SOV MF: 007
OM REF-. 002
Cmd 1/1 UDC: 546.36

gNmA =. (Bratislava, ulies. Ceskoslovenakej armady 40)
40) , Eugen, inz. (Bratislava, ulica Ceokoslovenalwj armady
Platinated electrode for detennining the redox potential,
Chem zvesti 16 no.6:.491-J+95 Je 162.
1, Oblastmy ustav hygieny., Bratislava,

GYORGY, Istvan; SZEPESI,, Karoly; MAYER, Janos; KOLAY~ Lajos
Use of permanent quality activated bentonite in fine ceramica. Epi-
4. oanyag 13 no.11:425-432 N 1631L.
j

VL(-,F,K. 1-A -(I'; Lql'; in?. 1,1 'rl.; :-lAYEFI,, ir7. ur-~-.
1: - . cl-~;ort-;. - , ,
, 1: 's ~; ~1,1,4ie r~ ! ~ ! "r r,,-~i i :i ' (,-:' - 1 , !111
L, ~ , -i!!. ,~ i, , -! I I ~., ,

T CM, Miroslav, Anz. arch.; MAYER, Jaroslav, inz. arch.
Arch-Itecture Rnd 1--)sation of airport buildings. 7, -, - !cv
ohzor 8 no.7-194-19? J1'64.

GRUSZECKI, Iudwik, MAYER.
Neurilemmoma of the stomnch (Schwannoma). PolBki tygod. lek. 13 no.10
359-362 10 Mar 58
1. Z* oddzialu wewnetrznego I Pracowni Anatomo-PFttologicv-nej Szpitala
Marynarki Wojennej, Konsultanci; prof. St. Wszelaki i praf. W. Czarnocki
(STOMACH NEOPILASMIS, case reports
schwannoma (Pol))
(EMMIL&HKOMA, case reports
Bobwannoma of stomnah (Pol))

PIUC, A.; KMAV I.; MAYERJ_ J.
Serum and cerebrospinal fluid transaninases (GOT and GPT) in
diseases. Cook. neur. 24 no.6:380-386 N 161.
1. Neurologicke oddeleni a klinicka laborator vojenske nenocnice v-
Ruzonborku.
(TRANSAMINASES metabolisn) (NMOLOGY)
(CMIEMOSPINAL nUID netabDlivn)

Czechoslovakia
.2
Pulmonary Diseases Section, Military Hospital (Pluene oddelanie
Vojenskej nemocnice v Ruzomberku), Ruzomberg; Director:
S. CYPRICH, MD.
Prague, RoahleU v tuberkulose a v nemocech plicnich, Ho 8,
Sep 62,
pp '57b-555-
"Serum Transaninases(BGOT and SGPT) In Recent Forms of Pulmonary
Tuberculosis".
Co-author:
MkYZEL J. ,Pulmonary Diseases Section, Military Hospital,
v-Tru-Romberg.

CZECHOSLOVAKIA
SOSOVEC, V; MAYERI J.
Pulmonary Ward of the Military Hos ital (Pluene
oddelenie Vojenskej nemocnice~, Ruzomberk
- (for all)
Prague, Rozhledy v tuberkulose, No 3, 1963, PP
16 2 7-77-
"Total Serum Proteins in Recent Cavitary Tuberculosis."

]MKYERo.,-,J,,,; HAGUCH, P.; HWKO, I.
Comprehensive amlyvie of the hygienic standard of the 11ving
onviromient near the atmic power plant as a basis for a report
an bygienic conditions. Cook. byg. 8 no.5-.249-253 Je 163.
1. Ustav bygieny, Bratislava.
AIR MOTION RADIOACTIVE) (RADIATION PROTECTION)
ANTHROPOWMI ~WUTOPOIETIC SYSTEM)
ABNORMALITIES) REPRODUCTION)
IRADIATIOR WETICS)

CZM11DS1jDVAKIA
SOSDVEC, V,- MUER, J.
1. Internal Medickne Ward of the Military Hospital
(Vnutorne oddelenie Vojenskej nemocnice), Kosici;
2. Palmonary Disease Ward of the Military Hosp-tal
(Placne oddelenie Vojenskej nemocnice), Ruzomberk;
3- Central bdu=x Lft Laboratory of the Military Hospital
(Ustredne laboratorium Vojenskej nemocnice), Rom Ruzmoherk
Prague, Rozhledy v tuberkulose, Wo 10, 1963, pp � 668-674
"The Electrophoretic Pattern of Serum Proteins in Recent
Cavitary Forms of Pulmonary Tuberculosis.ft

SUPNIIWSKI. J.; MAYRR, J.; KAMIRSKI, S.
Who
37nthatic D,L-tryptophan. Acta biocbim. polon. 2 no-3:
249-257 1955.
1. Z Zakladu Parmskologit AM w Krakowie i z Inistytutu
Farmaceutyc2nego, Oddzial w Krakowie, Kisrownik prof.
dr. J. Supniewski.
(TRTP-POPHAN, preparation of,
1),L-tryptophan. (Pol))

.POLAND / Chemical Technology. Chemical Products and H
Their Application. Pharmaceuticals. Vitamines,
AntiblotIcs.
Abs Jour: Ref Zhur-Khimiya, No 12, 1959, 43380.
Author : Supniewski J.,_Mayer J., Kaminski S.
Inst :Not given.
Title :Synthetic D, L - Tryptophane.
Orig Pub: Acta biochim, polon., 1955, 2, No 4, 1-4.
Abstract: Powdered indole is dissolved in a mixture of 33.6%
dimethylamine solution, glacial CH3COOH (I) and 36%
formalln. By the action of NaOH gramine is then
separated, which upon boiling In toluene in the pre-
sence of powdered NaOH and ethyl ester of the acet-
amidomalonic acid, causes splitting of the dimethyl-
amine and formation of the diethyl ester of the in-
dole- fi -methylacetamidomalonic acid. The ester is
Card 1/3

POLAND / Chemical Technology. Chemical Products and H
Their Application. Pharmaceuticals. Vitamines.
Antibiotics.
Abs Jour: Ref Zhur-Khimiya, No 12, 1959, 43380.
Abstract: saponified with a boiling NaOH solution and is then
acidified with a dilute solution of HC1 acid, Af-
ter cooling the free Indole-P-methylacetamidomal-
onic acid is formed. In boiling with water the
free acid tends to split C02 and to form a precipi-
tate, in the saponification of which (with hot NaOH
solution, followed by a treatment with I, washing
with absolute alcohol, and drying in vacuum) trypto-
phane is crystallized out. The yield constitutes
79%. Ethylmalonate in I with nitrates forms the
diethyl ester of isonitrosomalonic acid, which is
then reduced in absolute alcohol and with presence
of Ni catalyst conducted at a pressure of 20-30 atm
Card 2/3 H-41

CZECHOSLOW-KI.A / Crguniv Ch,---St.-y.
Oynthesis
Abs Jour: Rof Zhur-.,:hi.~-iyu, No 3, 6-~38.
Aftbor : Ctvrtnik, Josef., Mayor, Ji-ri. ~Temecek, Oldrich.,
HorakDva, Z'-L,)na.
inst : I'lot givan.
+10 : Now Dcrivativ-~,s 1,2-Diplionyl-3,5-Di4-~;.t,)-Pvrp--
Orig Pi.o: C asko3l. f ar.-inc. P,)58, 7, No 6, 3025-5o.11.
b,31 t,-, a C t .Ga:-ipz-~,hl.,-.r.)crotyl-iaeluri-c O:Acr (1) condomsuO.
with hydrezo-b(tnzcae (II) tt-~ 3,2-Aphanyl-4-
(gcima-cl,loro,croty-2-)-3,5-~a'ik,ito--pyrazolidin.-j
(III), which niso prcpnroC by alky1rition c,f
with 1,
3-Clichiorobutone-3, in aqu,::ous alcoholic ,~ulu-
tion of NaO,'.'. Treatm,lmt with HDSOA convorts III
to 1,2-di.rhenyl-4-(g,-,.ijaa-ketobuEylT-pyrazoli~l-
Card 1/2

CZZCH03LOV..a1, / Orgonic Chotaisti-y. Syntbesis. 2
.,,bs Jour: Ref Zj]ur-J~jjt.jiya, Fo 3, 19,59, a338-
;~.bstract: ine-diono-3,5 (IV), the Na-salt of vihich is
readily solublo in wate2. To a solution of
2 g Na in 40 i-d alcohol are addeJ 21.5 g I
and 16 g II, the ~iixture is lacaterl, 0-ri-,Ting -off'
the alcohol, 50 n1 watar are added, and the batch
is acidified to got 111, yield 20 g, IFT-1 167-1660
(cnrroctt,,d; fror.-i ncatona~. To 10 g III in 150
.--I GG1 are added dropwise 20 -.d c-)ncontrnted
A, 4
H2SO4, stirroq for abcut 2 hours, thc, aci(~ layor
is iiixod w'-th 1 liter of icu watur, and 1V is
separated, yield 3.6 g, ij!P 1200 (corrc-,ctQd; frofi
alcohol) ; sc--.a-i-carbazcno, IT 1720. -- D. Vitkov-
skiy.
Card 2/2
91

LIMLD, J.;KROUTIL, K.;BOCBK, K.;VfVRTNIX.J.;K&YXR, J.
Toxicity and anti-inflamcator7 effects of chlorocrotylpyrazolidins.
Gesk. fYsiol. 9 no.l.-87-88 A 60.
1. Yarmakologicky a histologlolW ustav lek. fak. PU a Farmakon, n.p.,
Olomouc.
(PEMNYL'BUTLZONB. rel. cpda.)

KROUTIL. H.: LINFEW. J.; CTVRTNIK. J.: MAYER, J.
Anti-Inflamnatory activity of now trasentin derivatives. Cesk.
fysiol. 9 no-3:294-295 My 160.
1. Utedra farmkologle leks fake FU a Farmakon n.p., Olomouc.
(PARASYMPATHOLYTICS pharmacol)
(INFLAMMATION exper)

NAPRUNIN, Vladimir; MAUR, Jiri, inz,
Dilmnsions, arrangement, and capacity of autobuses from
the viewpoint of economical operation. Automobil C2 6
u0s.51Ul-W MY '62o

MAYER, Jiri,, inz.; XAPRAVNIK, Vladimir
--l' prospect for using mathematical methods and automatic computers
in automobile transportation. Doprava no-3:202-208 63.

Al A YjE ~,
~.4
J as e, f
no im a" obel lodub7 in the smpw sm'di On-
SAM W- -,IlsdjokM UOY S. 25WIRMI
(," J,;Ja
.). _J4M, R. Gr&

Valeirska abeceft; zakladni prirucka pro valoirs)w uono a nove samostmance vo
valcoynach. Upravil Josef "r sa spolupraca a Ji~r Fridnanom a Aleisen
Bartown, a pmnitim. sovetskyah I moich prawnue , V d. 1-7 4aha, Prace; V-' +e1stvO
RDRv 1952. 151 P. Toohniclus prirwky Praceq av. 147 The A B 0 of rolling.~ a Oviao
nanual for rolling apprentices and now employees In rolling mine. illus.-/
SO: WALDIOLA ; kau.&Mauigub Val.3v RD.3v 14*%ry of 0 ongreso, Nhroh 1954,
11 unal.

emon, jarayp ~--rrofss drol i~. U-46 l~"lods.1"lorso afrol MAY"fis
jasof# O'er*
for 4114
i wust 19650
~;,srpawp W.4
prp 655*f4oo
laulzation detector
"Obarglaterlati-03
and tit axvmplt Of ita an-l-atestion In i4n,41at*m,
chemiatry*ff

MAYERs K.
"Work competition of clinker-baking brigsdes." p. 168. (Epitoanyag,, Vol. 5, no. 5,
May 53, Bteapest)
SO: Monthly List of East EurpMean Accessions, Vol 3 No 2 Library of Congreos Feb 54 Uncl
0

Y" "9- y e "e, Ac
PAMM L
I
Matwimilvwfebm, gabappatbla methods of treatmqV Pnn.
Arat IA40 33 Sept 50 P. 473-7.
1, NAX
CUL Vca. 20, go. 2 Feb 1951

ME.R. K.
Measurement of viscosity, specific gravity and pressure In peat bathe
used In rehabilitation. Acts, chir.orthop.traum. cech. 18 no-5-7 1951.
(CIJML 21:1)
1. Of the Second Orthopedic and Childrenle Surgery Clinic of Charles
University, Prague (Head--Prof.O.Hnevkovsky.N.D.) and of the Insti-
tute of Balneology of the State Faculty Hospital in Prague (Head--
Prof.F.Lenoch,M.D.).

MAYER, K.
Orthopedic rehabilitation of pediatric arthopedic patients during
vacations. Acts. chir. orthop. trunm. aech. 20 no-9-10:233-236 1953.
(CIXL 25:5)
1. Of the lirst Pediatric Orthopedic Clinic (Head--Prof. 0. Hnevkovsk,7,
Me be), Prague&

PROCHAZKA, Joe., Dr.; JIRSA, M., Dr.; LEMSNIX. V.. Dr.; MAYER, K., Dr.;
BRAUN, A., dr., Path. cast zpracoval.
Studies on the problem of generalized periostoses; byperostosts
generallesta with Uehlinger's pachydermia. Acts, chir. orthop.
traun. ceeb. 23 no.6:302-310 Nov 56.
1. 1. Interni klinika SFfi v Praze, predn. prof. Dro M. fistousek--
II. klinika pro orthopedickou a detskou chirurgil v Praze, predn.
prof. Dr. 0. Hnevkovaky--l. pathologicko-anstomicky ustav KU v
Pra2s. J. P.. Praha 10. Zabradni mesto. cp. 1325.
(OSTIOARTFMPATRY, HTPWffBDPHIC PUIMNARY, complications,
Uenlinger's pach3rdermis (Cz))
(SKIN DISEASES, complications,
Uehlinger's pachydermia In hypertrophic pulm.
osteoarthropathy (02))

--mg-mllarel-
A contribution to kineziology of walking and swimming; Oyace
orientation in condi.tione of increasing difficulty. Acta chir.
orthop.traum.cech. 28 no.3:261-267 A 161.
1. H.kllmika pro ortop. a detskou chirurgii v Praze, prednosta prof.
dr. 0. Bnevkovsky.
(SPACE PEMEPTION) (WALKING) (SWDOIING)

MAYERP Karel; HAICL, Zdenek
Congenital spinal abnormalities and their clinical significance.
Cook. pediat. 17 no.5/6:53,4-5:17 Je '62.
1. Katedra detske chirurgie a ortapedie fakulty detBkeho lekarstvi
University Karlovy v Praze, vadouci prof. MUDr. 0. Hnevkovslq.
(SPIN& abnorm)

HAM, K.
Pathogenesis of idiopathic scoltosis. Experivental studies and statis-
tics. Acta chir. orthop. traum. Coch. 29 no.1:101-102 F 162.
1. 11 klinika pro ortopedic)wu a detakou chirurgil Karlovy university
v Prasse, prednosta prof. MUT)r. Otakar BnevkmlW.
(SCOLIGSIS exper)
_4ftr

WMANIA/Cultivated Plants. Potatoes. Vegetables. Melons. M
Abs Jour: Ref Zhur-Biol., No 5, 1958, 20335.
Author : Part I Z7a_7: D. Belan; Part I Cb_7: D. Belan, L. Yayer.
Inst :Not given.
Title :The Leading Methods of Obtaining Early and Increased Vege-
table Yields. 1. The Selection, Veroplization and Stimu-
lation of Seed Cermination. (Belan). Obtaining High
Quality Sprouts. (Belan, Mayer). (Peredovyye metody po-
lucheniya rannykh i povyshennykh urozhayev ovoshchey. I.
Otbor, yarovizatsiya i stimulyatsiya prorastaniya senyan.
Belan. Polucheniye vysokokachestvennoy rassady. Belan,
Mlayer )
Orig Pub: Gradina, via Fi livada, 1957, 6, No 2, 8-14.
Abstract: At the testing station for vegetable raising at Tsigeneshti
Card : 1/2

1WIMIA/Cultivated Plants. Potatoes. Vegetables. Melons.
Abs Jaur: Ref Zhur-Biol., No 5, 1958, 20335.
(in the province of Bucharest) when pepper and tomato
seeds were vernalized for 15 days at 8-120 in temper.-
ature, the yield of the former increased by 82 cent-
ners per hectare (by 30-4%) and of the latter by 172
centners per hectare (by 84%). The vernalization of
vegetable culture seeds made it possible to obtain
an earlier harvest, to raise the vegetable weight
and dry mtter in them. These results were gotten
by processing tomato seeds with KBr (3 gmm per
liter of water for 6 hours). Cultivating the sprouts
in feeding pots increased the tomato yield by 42.9%,
the pepper by 50%, early cabbage by 52.4%, and cu-
cumbers bY 35.4%. Several mixtures am recommended
for preparing the nutrient pots.
Card 2/2

Y, AF, L .
Designing and constructing a rrddget water power plant. p. 29h.
(Villamossag Vol. 4, No. 10/12, Oct./Deco 1956)
SO: Monthly List of East European Accessiori (E&U) LC.~ Vol. 6,, Ho. 9 Sept. 1957, Uncl,,

MAYER, L.
SCIENCE
Periodicals: REVISTA DE CH'IMIE. Vol. 9., no. 10,, Oct. 1958
MUER, L. The hardness add elasticity of Jellied plastools on the base of
polyvirWl chloride. P. 557
Monthly List of East 6uropean Accessions WAI) IC, Vol. 8, Ho. 2,
February 1959, Unclass.

ANW, Jeno; MATEFFY, Sandor; VEN, Mihaly; SEMTYEN, Endre; FELKA1, Aurel;
j 1!!!zlo; GRWM,, Alder; RASCHOVSKY,, Iajos
GERVA10 Zoltew;_j!~~
FAmarks on the article '*The most Important problems of technical
develolvent of electric installations in industrial jolants and
taske for the manufacturing industry related to this. Villamoveag
9 no.1/3:42-46 Ja-Hr 161.
1, A Wlamw Eloomerelo Vallalat fomernoke (for Ando). 2. A Koho-es
Gepipari Miniesterium Tervezo Irodai villamos tervezesi soztelyenak
vezetoJa (for Vlateff'y). 3. A Villamos Allcmasszerlo Vallalat former-
noke (for Von and Felkai). 4. Vegimuveket Tervezo Vallalat (for
Sevestyen). 5. KonnyuIpari Tervezo Iroda, (for Gervai). 6. E.M.
Tipustervezo Intezet (for Gregor). 7. E.M. 2pari es Mezogazdasagi
Ter7ezo Vallalat (for Raschovsky).

... MAYER, Laszlo; SMELY, Andras
Development in the gluing technology of the clothing industry;
excerpts from an article. Mams elet 17 no.26W 20 D 162.

MAYER, L.
"Automatic machinery in today,s industry.,, P. 532. (Termeszet elk Technilm, Vol. 112,
no. 9. Sept 53, Budapest)
SO:'Monthly List of East European Accessions, Vol 3 No 2 Library of Congress Feb 54 Uncl

TS "77"ARY.
7-(-OST- ILMH-S TN
1 -,57
Vo' :l T
AFT ~ 1717) A 7,
30: 'A' '71 -7-.2. 7"q -- P7'~', !AE-r) V L. ( Nr,
x -1 . .. I

MAYER, Laszlo; FEKETE, Zoltan, Dr.
Investigation of the economic advantages of the automaticn
of tube manufacturing. Villamossag 9 no.6:169-172 Jo 161.

AMR,, Laigz1o
Utilization of polyurethan foam in the clothing indsutry. Magy
textil, 15 no.7:311. JI 163.
.."X
I,--,
.Z
11
I

MAYERO Laszlo
"-- 0'
Princi k:00f, the operation of the controllable silicon cell.
Elektrotechnika 57 no. 6:243 Je 164..

MAYFR, M., Inz.; STFIF, A., inz.; JFLSINA, M., inz.
New elements of control desks ef relay safety equiprent. Zel dor tech
20 ne. 3:75-79,89. 162

HDRAK, O.;DDBEEM, N.;MATXRq M.
Survey of surgical Intervention on the spleen and their results
at the First Surgical Clinic, 1939-1951. Roshl. chir., 31 no- 6-8:
144-155 1952. (CIRL 23:3)
1. Of the First Surgical Clinic (Read-Prof. Arnold Jirasek, N. D.)
of Charles University, Frmae.

BAIAS q V.;JUNGIR, L.;H&YER, M.;PASTOROVA, J.
%-WIMMOHM"M
Visnevsky's therapeutic method with novocalne blockade and oleo-
balsamic emulsion; experiences in theraDy of inflammatory diseases.
Cas. Isk. cesk. 92 no.27:743-755 3 J~aly 1953. (CIML 25:1)
1. Of the First Surgical Clinic (Head-Prof. A. Arasek, M.D.) of
Charles University, Prague.

?'gm' 1".
SCIENCE
Periodicals: STUDII SI CERCETARI DE FIZICA. Vol. 6. no, 2, Apr,/June 1955
MAYER, M. Experimental study of the nuclear active component of cosmic radiation
at energies of25 GeV. Note 1. Measurements on electrcr-nuclear showers with
10 GeV. p. 229
Moixthly List of East European Accessions (EEAI) LC, Vol. 8, No. 2,
February 1959, Unclass.

KAMM, Keria (Alej4oert)~ KCUSNIKOV, N.N. [translator]; IVANENKO, D.D.,
reT.-
Ellenentary theory of nuclear shell structural Blemanternais
toorile ladernykh obolochak. Koekva. Izd-vo inostr.lit-ry,
1958. 318 P. (KIRA 13: 8)
(Nuclear shall theory)

u%v

to
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CG, VQ
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pI

z-

21(2) RUM/2-59-10-23/39
AUTHOR: Mayer, M., Candidate of Physical and Mathematical
Sciences
TITLE: The Structure of the Atom Nucleus
PERIODICAL: Stiin~6 9i tehnicff, 1959, Nr 10, Pp 31-33 (RUM)
ABSTRACT: The article is preceded by an introductory note prais-
ing the achievements of the Soviet Union in the field
of science, like the "first atomic power plant of the
world", the first nuclear powered icebreaker, the
synchrophasotron of Dubna. The article is a condens-
ed and elementary presentation of the development and
present state of the nuclear theory. The theoretical
difficulties encountered in studying the N14 spin
have led to the discovery of the neutrons, the author
writes. In 1932, Heisenberg and Ivanenko formulated
the hypothesis that the neutrons and the protons are
building elements of the nucleus. The new theory
gave an adequate explanation of the isotopes. In
continuing, the author explains the nuclear forces
Card 1/2 and points out to the fact that they differ from the
7

The Structure of the Atom Nucleus RUM/2-59-10-23/39
electric forces. A good explanation of the nuclear
forces was obtained by Yukava's pi-meson theory.
Then the author shows that there are several nuclear
models but none of them is suitable to explain all
nuclear phenomena. Recently, in 1952-1954, a uni-
fied model has been successfully established. In
the final part of the article the author points out
that the structure of the nuclei and of the other
elementary particles is being studied, chiefly by
bombarding with high-energy particles. In this re-
spect, he emphasizes the importance of the synchro-
phasotron of Dubna, USSR. There are 8 figures.
Card 2/2

H/008/62/000/00611/001/003
D286/D308
AUTHORS: ~_rdbsi, N&ndor, and Mlayer, Y.~ty&6
TITLE;': Tensometry and its application to heat engines
PBERIODICAL: 7-'nergia 6s atomtechnika, no. 6, 1962, 244 - 250
rn-,, M -n of
Jnvesti6~.tion of operating con(litions and modernizati
.-_.achines requIres an accurate measurement of deformations an~ stres-
ses in comronents due to internal forces, and due to changes in tem-
perature. In the first Dart the electric strain gauge is considered
in conjunction with a Wheatstone bridge. After discussing the -ene-
ral theory of the strain gauge, the effect of size and nominal re-
sistance and the use of a high frequency bridge instead of a d.c.
one i's considered. The calibration is described and the two sup-.=t
bear., method is suggested as the most suitable. The characteristics
inciuding direction'al properties are analyzed. The effect of temne-
rature changes and methods of compensation are described. The secon,~.
part deals with the applications of the strain gauge. One major re-
search topic of 'Hbkil is to investigate the economy and operational
safety Of the Drincipal parts of the heat engine (boiler, main steam
Card 1/2

H/00 62/000/006/001/003
Tensometry and its ap;)Iication D286%308
line, steam turbine) under dynamic conditions. These investi '-~tions
have shown that the starting of the principal parts is safer and can
be more economical than suggested by the manufacturers. Theoretical
formulas for the maximum thermal stress in thick cylinders are given
and the method of using the strain gauge for practical measurements
is discussed in detail. The measurements were performed using strain
,,au.zes of American origin, marketed by Hottinger, West Germany. The
initial measurements suggest that they are of great value, and are
to be continued. So far only B73C turbine factory, Mannheim, conduc-
ted similar experiments. The initial results agree with those of
3BC. There are 12 figures.
ASSOCIATION: Hbtechnikai kutat6 int6zet (Research Laboratory for
Raoet Technology)
Card 2/2

AIIDEW. Yu.A.; MAYIM, N.A.
Study of Thwem"cwhain decarboxylation of mercuric acetate by peroxides.
Testsl AN BSBR. Ser.fiz.-takh.nav. Ao,37-49 160. (MIRA 13:10)
(Mercury acetates) (Carboxyl group)

RUMANTA/Theoretical Physics - Quantum Mechanics. B-4
Abs Jour : Ref Zhur - Fizika, No 4, 1957, 8418
Author : Mayer, M.E.
Inst
Title : Variational Methods in the Theory of Collisions.
Orig Pub : Studii si cercetarl fiz., 1956, 7, No 1, 201-222.
Abstract : Survey article, Bibliography, 24 titles.
Card 1/1

M q Yt-V5 M eiVf h ~ -y-,4 F(~ Lk) 'i W
Rumania/Theoretical Physics Quantum Field Theory B-6
Abst Journal s Reforat zhur FjzjjQ;, No 12, 1956, 33784
Author : Mayer Meinhard Edwin
Institution : None
Title : Wass Operator for Fields with Zero Spin
Original
Periodical t Ser. stiint. natur, 1956, No 9, 51-58, Rumanian; resumes in
Russian and French
Abstract t The interaction between 2 real scalar fields with scalar coupling
is examined on the basis of the general variational Schwinger prin-
ciple in the presence of external sources. An integral-differential
equation is obtained for the Green propagation function &r(x,x')
analogously to the well-known Dyson-Schwinger equation.

x
09
16
Sit*, "'SM,
10
ls~ All,
.. t 0 0* !
HIZIUMI
4 =0 I
HIS."
Js
of
q. ails
fro
-4.0,
.04
16
v I -** Q. 0.

%0- R IRKOV, D.V.
Thirring's tvo-dimensional model. Dokl. AN SSSR 122 no.1:4-5-47 S '58.
(MIRA 11:10)
l.ObOyedinennyy institut yaderafth Issledevanly i AiatamtIcheekly
institut Iment, V.A. Steklova AD SSSR. Predstavleno akademikon U.N.
Bogelyubvvym.
(Mathematical physics)

Y. L6 /V
AUTHOR: - Mayer, M. B.
TITLE: Compound models for elementary particles
S105816 2/O0Q/OO3/02_4,/o9,~
A061/A101
PERIODICAL: Referativnyy zhurnal, Fizika, no. 3, 1962, 43, abstract 3A383 ("An.
Univ. 'C. I. Parhon', 3er. 9t114. natur., 1960, v. 9, no. 25, 249 -
252, Rumanian; Russian, English summaries)
TEXT. Some consequences of compound models for elementary par-ticles, deve-
loped on the basis of four and six fundamental fields, are examined.
[Abstracter's note: Complete translation]
J5
Card 1/1

MA
merewy

MAYER, N. A., Cand Chem Sci - (diss) "Initiatory decarboxylation
of mercuric salts of organic acids." Minsk, 1960. 13 PP; (Belo-
russkiy State Univ im V. I. Lenin); 180 copies; price not given;
(KLI 19-60, 130)

5.3700 771400
SOV/7 9 -30-1 -,~ 1,/7
AUTHORSi 011delcop, Yu. A.,-Mayer, N. A.
TITLE: Reaction of Mercury Acetate With 1,1-Cyclohexylidene
Diperacetate and Benzoyl Peroxide
PERIODICAI,. Zhurnal obshchey khimil, ig6o, Vol 30, Nr 1, pp 2'7;.5-
282 (USSR)
ABSTRACT: This is a continuation of the authors' previous
study (ZhOKh, 30, 299, 1959; and others) of the
reaction of mercury acetate with l,l-OYC11DheXyli,dene
diperacetate (I) and benzoyl peroxide (II). The
present article deals with the effect of the tem-
perature, initiators, and the madia on the chain
reaction of mercury acetate free-radical decompo3ition.
The following experiment3 were conducted. Reaction of
mercury acetate with (I) in acetic acid at 80+0.50
(for 5) hours) and at 97-980 (for 2 hours). 1~e_actlon
of mercury acetate with (1) In benzene and In a
Card 1/4 mixture of benzene and acetic acid at 800. ReactAoii of
mercury acetate w.1til (II) in acetic acid at 800+ 0.5'

Reaction of Mercury Acetate With 77400
1,1-Cyclohexylidene Diperacetate and SOV/79-30-1-61/(8
Benzoyl Peroxide
and 97-~)80. Reaction of mercury acetate with (II) in
enzene and i riltsmixt tire of benzene and acetic acid at
W. The resu tire given in Tables 1 and 2.
T able 1. Reection of 0.03 M mercury acetate solution
wtth 1,1*-c-,%,clohexylidene diperacetate (I).

Nr T&". Ne I*&rt4drian Y, . Ids
CH3 -t "$,(DCOCN,~ CA C 0. c-

(on W.46)
(6.,z L ,
(I. -.JCS
, I

c
4-3) ~
O.OD5 IOD WO 57.3 3.21 0.0074 OA*4 0.00013 1.85
2 OAM IOU So 30.2 &L5 3.21 W)071 0.00(m 0.(0)12 -
3 0.01 100 00 95.4 0 1.16 0.027 0.00W ULM 14 11.0
4 0.01 too 80 94.-1 0 129 0.026 O.OU45 O.OU014 -
5 OL005 too 97-98 94.1 t:93 0.0258 (X(X)31 0.0004 - 21.0
6 0.01 101) 97-914 9&:1 0 0.04(m 0.0078 OAM) - 4.3.0
7 0,01 - 100 so 0.03:10 0.0022 0.00024 7.0 -
8 0601 - too 80 0.0374 O.OD2o 0.(XX)25 - -7
9 0.01 - too so 75.0 14.6 7.7 -- -
to 0.01 1.0 too 80 86:) 7.91 3.85 O.O.'W 0.0019 o.O(X)18 - -
I1 0.01 to.() too 80 93:1 0 0 0.0:92 O.W17 0.(X)U24 11.5
5 -
12 0.01 10.0 too so 96:5 0.0377 0.(X)2t 0.0tX12" - - 7
Card 2/4
A*

Reaction of Mercury Acetate With 77400
I,I-Cyclohe.xylidene Diperacetate and 3071/79-30-1-61/77
Benzoyl Peroxide
Table 2. Reaction of 0.03 M mer-cu"Y acetate sollation
with benzoyl poroxide (II).
e.r.

acet.c.
L&C 1 4
Scm-tc,oc

(,I AO

ooed v"
16,

Jo~411!4 o~ Oct-),~

, ,Ylecocj4j)]
to. ?.

m4LJ , :k

L,
, 2
'1
t,
;t cc., C14 11-C )4,, 'c"
2

(j. ma.)
3
1 O.OU5 Oto
1 - KP 82.0 2.24 0
1 14.15 0.02) 0.01 0.02 13 0.0019 0.000
V 5.24

14
LX01
1 OD
-
FA) 81 ,8
5.Sfi to 6.3 U.06 0.001 010295 O.INT16 1
OAX) 9 1 IA
f5
J6
17 (X"
0.01
OL035 too
100
100 -
-
- 97-118 95.5
97-1144 101.2
97-WI 39.
1 :1.()g,)
6.6
60.15 G
0
0 0.65
0
0 0.02
OAK)
0.25 0.02)
0.05
0-20 0.0302
O.U.368
0-067 ().(KXL4
(I(XJT)I
0.0151 O.O(X)Irl 42-5
U.1" I 16 63A
O.LN X)fj i
is O.OL15 0 100 so 40. 7.03 34.4 15.4 0.15 OXKJ 0.0194 O.LK)I I ().(XX-K)7
19 06005 It? 100 80 64.7 9A5 1) 25.7 0.14 OAKI 0.0225 O.OUU7 O.(Xk)15
2D (Lot 0 too 13D 70.0 11.7 f7.3:1 0.11 0.30 O.W96 (mg).!q fmm"m
Card 3/4

Reaction of Mercury Acetate With 774oo
1,1-Cyclohexylidene Diperacetate and SOV/Tq-30-1-61/78
Benzoyl Peroxide
The followin'.-T conclusions are made: increasing tlie
amount of the initiators, raising the temperature,
and addition of acetic acid have a positive effect
on the process of mercury acetate decomposit-lo.,; In
all experiments the evolved ---as is composed ofC C()-~'l
CH4, and C2H6 . Tliere are 2 tables; 2 figares; an'~
6 references, 1 U.S., I U.K., I German, Soviet.
The U.S. and U.K. references are: W. Cooper, J.
Chem. Soc., 1951, 1340; C. D. Wagner, R. H. Smith,
E. D. Peters, Ind. Eng. Chem., Anal. Ed., 19, a,76
(1947).
ASSOCIATION: Institute of Chemistry of Academy of Sciences
Belorussian SSR (Institut khimii Alcade.,nii nai-,,k
Belorus3koy SSR)
SUBMITTED: December 17, 1958
card 4/4

5.3400,5.3700,5.4300 77404
SOV/79-30-1-65/78
AUTHORS: OltDekop, Yu. A., Mayer, N. A.

TITLE: Reactions of Acetyl Per- _-Vin-Mercuric Acetate
oxide
and With Some Mercuric Salts of Inorganic Acids
PERIODICAL: Zhurnal obshchey khimii, 1960, Vol 30, Nr 1, pp 299-
302 (USSR)
ABSTRACT: In this work the authors continue the study of reaction
between mercuric acetate and acetyl peroxide (study of
reactions between mercuric acetate and acetyl, benzoyl,
m-nitrobenzoyl, and some other peroxides was started
earlier [Razuvayev, G. A., Olldekop, Yu. A., Mayer,
.N. A., Doklady Akad. nauk SSSR, 98, 613 (1954);
Razuvayev, G. A., 011dekop, Yu. A., Mayer, N. A., Zhur.
obshchey khim., 25, 697 (1955); Razuvayev, G. A.,
Olldekop, Yu. A., Papers on Chemistry and Chemical
Technology (Trudy po khimii i khimicheskoy tekhnologii),
lst issue, Gorlkiy, 178 (1958)]) to obtain new-data on
the mechanism of the reaction. A 15-16% solution of
Card 1/5 acetyl peroxide in acetic acid was prepared by the

Reactions of Acetyl Peroxide With Mercuric 774o4
Acetate and With Some Mercuric Salts of SOV/79-30-1-65/78
Inorganic Acids
method described earlier (Razuvayev,)G. A., et al.,
Zhur. obshchey khim., 25, 697.(1955 and analyzed
lodometrically (Smit. W. S., Rec. trav. chim., 49, 675
(1930)). The reaction was conducted at 97-98' in a
250-ml 3-neck round-bottom flask provided with a
dropping funnel, a reflux condenser, and a sti-_,rer. A
coil trap, cooled with a mixture of dry ice and acetone,
and three absorption tubes filled with KOH (for quanti-
tative absorption of CO 2) were attached to the upper
end of the condenser. The reaction products were:
methylmercur-j acetate CH 3HgDCOCN3, (collected as pre-
cipitate and converted into CH 3HgI with KI), CO 2
(weighed in the absorption tubes), CH4 , and C 2H6 (the
latter two collected in gas burettes and analyzed with
VTI-2 and Kh- 1M as analyzers). The rate of evolution
.of hydrocarbons fCH4 + C2 H6 ) for various initial quan-
Card 2/5 tities of acetyl peroxide is illustrated in Fig. 1.

Reactions of Acetyl Peroxide With Mercuric
Acetate and With Some Mercuric Salts of
Inorganic Acids
77404
SOV/79-30-1-65/78
Fig. 1. Effect of intial quantity of acetyl peroxide
upon rate of formation of saturated hydrocarbons.
Card 3/5 Acetyl peroxide: (1) 0.005, (2) 0.0075, (3) 0.01 moles.
0 50 73 000
r- Iffi4m)

Reactions of Acetyl Peroxide With Mercuric 774o4
Acetate and With Some Mercuric Salts of SOV/79-30-1-165/78
Inorganic Acids
Card 4/5
Reaction rate (A~) expressed by the volume of CH 4 +
V T
+ C2H6 is related to the peroxide quantities Used in
the ratio 1.0: 1-5: 2.0); It is increased by factors
of 1.0 : 2.4 : 2.7, similarly to the rate increases
obtained earlier (in the works cited above) for the
total gas volumes (cc)2 + CH4 + C2H6)' The increase
in volume of hydrocarbons is due to methane; the yield
of ethane is not affE!Cted by the peroxide (at 0.005
moles peroxide, yields of ethane and methane are
identical). The aut)iors have also studied reactions
of acetyl peroxide with mercuric sulfate, chloride,
and iodide, and with mercurous sulfated, and chloride.
All reactions were conducted at 97-98v for 6 hr.
CH 3HgI, obtained by addition of KI, was weighed
(CH HgI was tested in all experiments by taking a
mixed melting point with chemically pure CH 3HgI).

!"V Mercuric 77404
sov/79--4o-i-65/78
q1A~'1L1J1'Aeq_ of C1T_,11gI (from 0.83% yield, cal-
D1' the peroxide, for H92C12' to 9'8%
)i, .1 .,;ere o'btairied in all reactions except with
~nt_,re Is 1 table; and 4 references, 3 Soviet,
Academy of Sciences, Belo-
khimil Akademil nauk Belorusskoy
SSR)

5.3700, 5.3400 77405
SOV/79-30-1-66'--~
AUTHORS: Olldekop, Yu. S., Mayer, N. A.
TITLE: Photochemical Reactions of Mercurous and Mercuric
Acdtate and Mercuric Proplonate *
PERIODICAL: Zhurnal obshchey khimii, 1960, Vol 30, Nr 1, pp
103-307 (USSR)
ABSTRACT: Photochemical decarboxylation of mercuric acetate
in benzene, acetic acid, and their mi-xtures; of
mercurous acetate in acet1c acid; and of mercuric
proplonate In benzeno and tcetic acid was investlVated
in this work. Experiments were conducted in a
quartz flask provided with a reflux condenser and a
bubbler. A PRK-4 mercury-arc lamp was sealed
horizontally into the flask at such a level as to b,:~
immersed into thereaction mixture (0-03 moles of
salt in 150 ml solvent). The evolved gases were
collected in a gas burette, connected with the
Card 1/11 reflux condenser, and analyzed on VTI-2 and Kh-1M

PhotochemIcal Reactions -Df '7r
[40-1
and Mercuric Acetate and Mercurl( Propionate SOV/79-30-1-6,6,
Card 2/4
gas an~ilyz~--rs. Al'ter cooling of the reaction mass,
the solid product,- were washed with benzene or
acetic acid. and -irialyzed. The product analysis has
shown i-.hqt,--. (1) Photor-.1-inmical decomposition of
mercurlp a-etat(~ ;nd p-oplonate in benzene results
in formation of mEi,curous salts and compounds of
the type R11gOCOR(,,h,--rP R = CH 3 or C,H 5), their
c
reapectJve ydelds bi~Jng, bo-68, and 30-34%. Bo t. 1)
salts are stabli, to irradiation In benzene. (2)
Addition of acetl~~ acid speeds up photodecompositlon
of (RCOO),Hg with increasing yield of RHgOCOR and
a decrease in yl;~'Id of RCOOHgr; some .ietallic mercury
is also formed. (3) After irradiation of mercu-ile
and mercurous acetate in acetic acid and mercu-ic
propionato in propionic ,tcid, metallic mercury a-d
compounda of the type RHVOCOR (in 60-68% yield) were,
obtained. Thf, lattor ar-.~ d-rompos~-d upon prollont-cl
irradiatlon with forin'ttion of' metallic mercury. (4)
The gaseoui products werc~. methan,--, ethane, CO, .

Photochemical Reactions of Mercurous '77405
and Mercuric Acetate and Mercuric! Propionate SOV/79-30-1-66/78
and CO from Hg(l) and Hg(II) acetates; ethane, ethylene,
butane, CO 2J' and CO from Hg(II) propionate. (5) Oil
the basis of these results, the following scheme was
proposed for the decarboxylation of mercuric salts:
11COOlIgOCOR -h'* RCOO - + -11gOC011 V)
(R - CII, Olt C,IQ
MOO - --V. It - +Cos (2)
R - + - 11 gocoll ---9- It 11gocoll (3)
It - + IICOO HgOCO It It HgOC011 + RCOO - (4)
R - + 11111 It H + R'. (5)
RIH is
bydrogen-
c
i
t
i R-R (6)
211. ~
a
on
n
ng R
(7)
+ R
compound +H
-11 (pq R = C,11.)
2 - HgOCOR ---v, Hgj(0C0IQ2 (8)
h.
Hg2(OCOR)2 ---- I- Hg + 11g(OCOR)2 (9)
Card 3/4

Photochemical Reactions of Mercurous 77405
and Mercuric Acetate and Mercuric Propionate SOV/79-30-i-66/78
ASSOCIATION:
SUB14ITTED:
Thus, alkylmercuric salts (RHgOCOR)
'..Wnthesized by photochemi.-.al decarboxylation-
mercuric salts of aliphatic acids.
RC00 RCO - + 1/202
Rco R - + CO
There is 1 table; and 7 references,
can be conveniently
of
(10)
(11)
6 Soviet, 1 German.
Institute of Physical Organic Chemistry, Academy of
Sciences, Belorussian SSR (Institut fiziko-organicheskoy
khimii Akademii nauk Belorusskoy SSR)
January 14, 1959
Card 4/4

5.3400
AUTHORS:
TITIE:
PERIODICAL:
ABSTRACT:
Card 1/7
77904
S OV/7 9 - 3 0 - 2 - 5 51
Olldekop, Yu. A., Mayer, N. A.
Decarboxylation of Mercuric Propiotiate With Peroxides
Zhurnal obshchey khim:Li, 196o, Vol 30, Nr 2, pp 61g-
623 (USSR)
The decarboxylation of mercuric proplonate and
acetate on UV irradiation and the decarboxylati~-n
of mercuric acetate with various peroxides were
reported previously by the authors (this J., 196o,
our abstracts 77400; 77404; 774C5). The present
study investigates the mechanism of the decarboxylat-lon
of mercuric propionate in reaction with propionyl
peroxide, benzoyl peroxide, and hydrogen peroxide.
Mercuric propionate a:ad propionyl r-~:roxide (in 1:2
molar ratio) in propionic acid were heated at 97-98o C
for 3.5 hr. After distillation of ethyl propionate and
propionic acid, the residue was dissolved in water and
treated with KC1 to give ethylmercury chloride in 61.5%

Decarboxylation of Mercuric Propionate With 77904
Peroxides SOV/79-30-2
yield. The mother liquor treated with KI excess gave
ethylmercury iodide in 27.3% yield; the total yield
of C2H5HgX compounds was 88.8%. The reaction gases
contained GO 2-f CO, C2H61 C4 H10, and traces of C2 H4'
The same reagents as above, but in a 1:1 molar rat"e,
gave ethylmercury compounds in 65% yield, mercurous
propionate In 18.2% yie-ld, and 13.4% unreacted starting
mercuric propionate., Mercuric propionate and benzoyl
peroxide (in a molar rat8o 3:1) in proptonic acid, were
heated for 4 hr at 97-98 C. On filtering, 20,1%
mercurous propionate was separated; the filtrate,
after distillation of the solvent, dissolution of the
residue in ether, extraction with water, and treatin,"
the water extract with KI, gave ethylmercury iodide
in 54.2% yield. The solvent was evaporated from the
ether solution, the residue mixed with KC1, and steam
passed through the mixture. The reaction gave phenyl-
Card 2/? mercury chloride in 16% yield (24% based on benzoyl

Decarboxylation of Mercuric Propionate With 77904
Peroxides SOV/~9-30-2-55/78
peroxide), and also a small amount of m-dinitrobenzene.
The reaction gases composition was qualitatively
identical with that of the precedin, reaction. Mercuric
propionate with benzoyl peroxide (in molar ratio 3:1)
in benzene on heating at 80o C for 8 hr gave on
similar treatment 10% mercurous Dropionate, 50%
phenylmercury chloride (75% based on benzoyl peroxide),
14.35% ethylmercury chloride, 24.4% ethylmercury
Iodide, and a small amount of benzoic acid. Con-
sidering the products obtained. the decarboxylation
mechanism of' mercuric propionate can be explained by
reactions (1)-(10).
Card 3/7

Decarboxylation of Mei~curic Propionate With 77904
Peroxides SOV/79-30-2-55/78
(Rco.), --i. 2RC02 -: IIC02 It - + C02 (1)
(it = G.H. Celli)
c,2jJ5C00IIg0C0G21I.j +R -- Jill 90COC,11, + G2HrC0, -(INITIATION (2)
C21 1 rcoR C21 I.., - + C02 (3)
C2I',-,IlQ0C0(;2ll5 +
+(-2IJ,C0,.( PAOPAGAT10ti) (4)
119(OCOG211102 + C2111 01itE '"0+4
y
;~C__W, -.41), N." G,118comll + (5)
+ . J1go(fbL0;j1I,, TCf?mlHATspN
2. ligOCOC211, 11g2l(OCOG11,50h (6)
Card 4/7

Decarboxylation of Mercuric Propionate With 77904
Peroxides SOV/79-30-2-55/78
C2115 - + 11920COC0102 C211090COG2115 + HgOGOC2115 (7)
C*115 - + R'11 C2HO + R' - (8)
C41110 (01HEOLUATION) (9)
2C,11, C2110 + C2Hj (gp1SpSjOpDR7,jtO*rgDX (to)
The steam distillate, after filtration and separation
of b1phenyl, gave 1.21% ethylmercury Iodide. Total
yield of ethylmercury iodide was 55.41%. A convenient
synthesis of ethylmercury salts is the reaction of
mercuric propionate with 42% hydrogen peroxide in a
mixture of propionic acid and propionic aniiydride. on
heating at 97-98% for 2 fir, the reaction gave 2.16%
metallic H9, 795% ethylmercury chloride,and 6.35%
ethylmercury Iodide (sere method used in the decarbOxyla-
tion of' mercuric propionate with propionyl peroxide.in
Card 5/7

Decarboxylation of Mercuric Proplonate With 77904
Peroxides SOV/~9-30-2-55/78
propionic acid). Total yield of ethylmercury salts
was 76.35%. The reaction gave also mercurous
propionate in 1.95% yield, and 16.6% unreacted
starting salt. The presence of dimethylauccinic
acid was detected, and its formation can be ex-
plained by reactions (11) and (12)
C'11"' 4 C113CI12cooll ---b- C2116 + CH.'dHcooll
C113CHCO011
2CH,t11C0011 1 (12)
C113CHCOOH
There are 10 references, 2 U.S., I U.K., I Dutch,
2 German' 4 Soviet. The U.S. and U.K. references
are: F. E. Blacet, W. E. Bell, Discus. Farad. Soc.,
:L4, 70 (1953); J. N. Pitts, Jr., R. S Tolberj,
F. W. Martin, J. Am. Chem. Soc., 76, 2843 (195
C. D. Wagner, R. If. Smith, E. D. Peters, Ind. Eng.
Ch., Anal Ed., 19, 976 (1947).
ASSOCIA ION: Institute of Physical Organic Chemistry, Academy of
Card 6X